1

-

( 4)

KT 750 gCH4 gCO

- 1

LV - 2 .5.0 KT 750

1KT- 750

min.0t

PaP .10283,0 5

SIR .32,8

CHOCH - 2 3 0 n

R - 3

P - 4

V T R x P 0n - 5

- 6

880 640 560 480 400 320 240 160 80 0 mint 4.52 4.5 4.4 4.3 4.1 3.8 3.5 3.0 2.1 0 34 . mmolCH

- tfCH 4 min801 cm 3.11 mmolcm

- 7

- 8 gCO

dt

COd

dt

CHdv 4

- 9

2

( 4 )

239

nxTeMonPu : Pu23994 z1

0

135102

42

1

0

239

94

x Z - 1

- 2

Pu23994 - 3

( ) 1-

m 239 - 4

- 5

- 6 h24 239

g35

2- - 7

- 8

Pu23994 Mo102

Tez 42135

3

( 4 )

OAEX ..

-

ABU BCU

VE 0,6 L

10r ) ) 200R

st - 0 BCU ABU

BCU - 1

ABU - 2 ti

dt

tdi

BCU - 3 ti

5 4 - 4

BCU ABU

- 5

ti .

0I - 6

. - 7

. L - 8

4

( 4 )

gm 25 33,1 d

- 1

- 2S

TF

T

SF

G

R m TM

-3

Gv

2

Gv

( )

f Gv f 2

Gv

Gv

Gv f 2

Gv

Gvkf .

1.36,0 skgk

. -

Av - 4dt

dv .

A - 5

- 6

t

evv 1max k

m

maxvvl - 7

s.35,0 ( ) - 8

3/8,7 cmgfer

5

04

: 1

.

. 2

3

ml1 min/500m -

mlVS 50

S

aqOHNa lmolC /10 31 mlVE 4

OAEX - ..

4

5

ml2 6

7

min3 - 8

min/500m lg 2.0/

molg : /90

CHOHCOOCHCHOHCOOHCH) pka 33 /) )

9.3pka

6

( 4)

ggg : : 1- COCHCHOCH 43 ...........0.25

0.5........... : 2-

TRnVP

molTR

VPn

TR

VPn 3

35

00 1026,2

75032,8

105.010283,0

: R : 3- 2. mNPa

SFP

SFP ...........0.5

KmolmNKmol

mmN

Kmol

mPa

Tn

VPR

Tn

VPR ./.

.

..

.

.

.

. 323

0.5............ : 4-

gCO

+ gCH4 = g

CHOCH 3

mol

0 0 0n 0 .

x x xn 0 x .

fx fx fxn 0 fx .

: 5- 0n P x R T V ..............0.5

xnxxxn : 00 TRxnVP ... 0

molnxxnxx f3

0maxmax0max 1026,20

0.5 .... 0.5............ : 7-

3

3

3

maxmax

2

1 .26,2105.02

1026,2

2

/

2

mmol

Vxxt

min96 : 2

1 t

4CHnx

0.5...... : : 8-

:

dt

COd

dt

CHd

dt

CHnd

V

V

dt

Vxd

Vdt

dx

Vv

g 4

4.

..

1.

1

0.25........ - : : 9-

7

( 4 )

x : - 1 1351021239

: 042094 xz 3 x 52 Z ......0.5

0.5..... 9 9 3 3 - 2

0.5........ - 3

m 239 - 4

: *- 2... cmmZAmZE XnPl

Pu23994 : 22399423994 ..94239.94 cPummmPuE nPl

Mo10242 : 21024210242 ..42102.42 cMommmMoE nPl

Te13552 : 21355213552 ..52135.52 cTemmmTeE nPl

2135521024223994 .8360145524294 cTemMomPummmTeEMoEPuE npLLL

2135521024223994 .20 cTemMomPummmTeEMoEPuE npLLL

: ...........0.5

PuETeEMoEcTemMomPummE LLLnLiber

2.2

PuETeEMoEE LLLLiber

APu

A

EATe

A

EAMo

A

EPuETeEMoEE LLLLLLLiber ...

MevAPuA

EATe

A

EAMo

A

EE LLLLiber .2,2052395,71353,81026,8...

22,05,931/2,205/.2,205. 22 CMevmCmELiber

8

0.5........ - 5

- 6 h24 239 g35 ......0.5

NgM A

2323 10023,610023,6239

Ngm 35

M

NmN A 20

23

1002,882239

10023,635

........0.5

MevMevELiber

2020 1041,1809921002,8822,205

Mwwat t

EP 5,331035,3

606024

106,11041,180992 71320

0.5.......... 2- - 7

9

( 4 )

0.5............ - 1

- 2

tirdt

tdiLU AB .. tiRUBC . ............1

0BCU .........0.5 BCU 1-

ABU 2-

0dt

tdi

0.IrUAB BCU ABU R r

- 3 TRRr /

tiRrdt

tdiLE ..

tiRdt

tdiLE T ..

L

0.. L

Eti

L

R

dt

tditi

L

R

dt

tdi

L

E TT

.........0.5

TR

tL

eIi

..

0 1

mA R

EI

T

.6,28210

60

..........0.5

0.5.......... . - 7

tfUR 0 t VcstIRUR .72,5. 00

0., IR

VUUt RR .6,3.0063

0

ms.4,2

. L - 8

HRLR

LT

T

.504,0210104,2. 3 .........0.5

10

( 4 )

B A :1- B

AF

B A A

BF

: 2- 2

..

R

mMGFF sT

TS

ST

G : 3-

P -

-

f -

GGext : : 4- amfpamF

.. gVliq

..

gVkvgm : dt

dvm liqG

G ....

: m m

gV

mkv

gdt

dv liqGG..

1 ----- m

gVgv

m

k

dt

dv liqG

G..

Av *...... 1 :5- dt

dvG .

m

kB

s

liq

s

liqg

V

VgA

1

.

.1

0 dt

dvG

ll vAAv ..0 maxvvl

** .......... : 6- t

ll

t

l evvevv

1.

AvAv ll .

...........***

t

lG ev

dt

dv .

1

: * *** ** l

ll

t

ll

t

l vv

vevvev

......

m

k

1

m

Vg

k

mAv

liq

l

.1.

11

k

m Vm

k

g

k

gV

k

gmv liq

liq

l ....

m

kt

liq

liqeVm

k

g

k

gV

k

gmv

.

1....

fer

liqliq

lm

Vg

k

mAv

18,9.

36,0

1025.1.

3

17,08,7

133,1

fer

eau

fer

liq d

smvl /.56.017,0168,0

sk

m.07.0

36,0

1025 3

ss .35,05.07.0.5

12

5

0.5 2-

0.5 ....... : 1-

0.5........ 3-

OAEX .. .....0.5

-

13

0.5....... - 4-

BBAA = : VCVC .. ........0.5

( )

- 5- Laqaqaq OHAOHAH 2

........0.5

......0.5 ml2 6-

= ml2

9,3 PkaPH

acide

baseLogpkaPH

:

lmolOH

OHkOHOH e /1010

101010. 1.10

9.3

14

3

1414

3

aqOHNa =

OH

n =

initialen

6

1.10

3331.1033 10210

521021010521010102

OH : n

0

00

06

6

max

1001102

102

f

f

fx

x

0.5 ........ 7-

lmol

V

VCC

A

BEBA /1008,0

50

410. 33

BBAA VCVC ..

lmolCC /1041501008.0 33

0.5..... - 8-

lglg /2,0/36,0