PowerPoint

2012/8/22

http://10.8.41.220/ghs/

MSDS

()(Formaldehyde)(FormalinFormic aldehydeMethanalMethyl aldehydeMethylene oxideOxomethane)

()

CAS.NO

(Formaldehyde)

HCOH

100

50-00-0

[ ] [ ] [ ] 1. 2.23ppm 45ppm1030 30 3.1020ppm 50 100ppm 4.( ) 0.2ppm23ppm45ppm 10ppm 1. 2. 3. 4.1. 2. 3.( ) 4. 5.

1. 2. 3. 4.

1. 2. () 3. 20 4. 5. 1. 20 2. 3. 4. 1. 2. 3.240300 4. 5. 6. 40606083(LEL)7.0 (UEL)73.0 1. 2. 3. 1.2. 3. 4. 1. 2.3.4.5.6. 1.2. 3.4. 5. 6. 7.8. 1.2. 3. 4. 5.

6. 7.8.9. 10.11.12. 13.14. 15.16.17.18. 1. 2.1. (1) (2)

2. (1) (2) 1. 2. 3. 4. 5. 1. 2. 3. 4. (=1) 10mmHg(-88)760mmHg(-19.5) (=1)1.067

-20 55g/100ml-118 pH2.84.0(=1)1.03()1.075() 1. 2. 3. 3750 4.37(W/W) cyclic trimer trioxane 3004000.44101kpa(1)methyl formate 1.2.()80100 (63KJ/mol15.05Kcal/mol)3.hydroxypropyl methyl cellulose methyl cellulosesethyl celluloses isophythalobisguanamine 4.5.AZOdithiocarbamate

LD50 LC50 TWA STEL Ceiling() () 1ppm() 100mg/kg()420mg/kg()87mg/lg()42mg/kg()300mg/kg()270L/kg()260mg/kg() 203mg/m3()454mg/m3()92mg/m3() IARC2A (Secondary Sterility) 1.2. (log Kow0.35)3.4272 stagnantdie-dway30 484. 1.2.3. (UN.NO.)22099(Hazard labels)9 1586106

0.2ppm1ppm(1.2mg/Nm3) 1. 8632.3. 86 54. 8345.Handbook of Toxic and Hazardous Chemicals and Carcinogens

(CNS6864 Z5071)

(CNS6864 Z5071)(Explosive)1.11.21.3

(Explosive)1.41.51.6

(Flammable, Non-flammable, Toxic, and Non-toxic gases)2.12.22.3

(Flammable liquids)4.14.24.3

(Flammable solids) (Substances liable to spontaneous combustion) (Substances which in contact with water emit flammable gases)

(Oxidizing substances) (Organic peroxides)5.15.2(Poison) (Infectious substances)

(Radioative) (Corrosive substances) (Miscellaneous dangerous substances)

http://10.8.41.220/ghs/

54

5555()56

56991001009

5758(1)59

59(2)60

1.2.3.Excel321(3)61

6162(1)63

63(2)64

(3)65

1.2.12?

(4)66

(5-)67

68(1)69

69(2)70

Examplek3797190k37971907172

1. page6~page72.3.Excel321(1)73

(2)74

74(1)75

(2)76

77

78(1)79

79(2)80

81

()82

IE83()

84:GHS(),(2) IE

(/2477)(/3311)8585

(:)

(EO Gas)

92

93

94

95

1F3F4F

98GHSGHS

99 100 101910 9:71() 10:71 10210()

10311 10412 105 13-30 -300 030 3065 106 14 107 1515 108

109- : 110 1955 62 25411163.04.16 80.5.1781.12.28 88.06.29 MSDS1696.10.19(GHS)9611GHS()()()GHS97.12.3197.12.31 APEC2008GHS112GHS Globally Harmonized System of Classification and Labelling of Chemicals (GHS) 200212() 20037GHS UNAPEC2008GHS 2005GHSGHS395-97 9510CNSGHSCNS 15030CNS 6864

113UNCED)IFCS1992OECDUNCETDGILOGHS GHS3GHS2002122006297123120071019GHS114GHSILO SAFEWORKSafe Chemicals Use ILO Strategic Approach to International Chemicals Management (SAICM) 2020National Chemical ManagementGHS Guidance Document, UNITAR, 2005/OSHA, USA GHS ()

115GHS2006200720082009201020112012201320142015UN

1. GHS 2.45 A: B: 1%0.1-0.3% 1 20.1() 3CNS15030()201512/112/15/3111/30AB1(2)(3)116GHS 961019 30960457032321( )96123124971231117118()()()UNAPEC2008.12.31(UN)119GHSCNS6864UNTDGMSDS16GHS27 CNS1503027CNS15030-127MSDSSDSSDS16120 121- 3122 ()123(1) 124(2) ()CNS15030 125

CNS1503012715030 22CNS68641262.CNS15030 2.CNS 15030

1.4.MSDS1.4.GHSMSDSMSDS23.3.127

Trichloromethane1,1,2,2-1,1,2,2-TetrachloroethaneTetrachloromethane1,2-1,2-Dichloroethylene1,2-1,2-DichloroethaneCarbon disulfide

()128(3) MSDS 129(4) ()130 OSHA HCS ()131 (5)() ()132CNS 15030(pitogram)(symbol)

133 (5-1)() ()134GHS

1 2.1 2.1 5.1 2.2 3 4.1 4.1 4.2 4.2 4.2 4.3 5.1 5.1 5.2 8

GHS135//~~GHS6.188

GHS136 DivisionCategoryType 1.1 ; 1.2 ; 1.3 ; 1.4 CNS15030CNS15030

137 DivisionCategoryType

1.5 1.6 1 2 CNS15030CNS15030

138 DivisionCategoryType

1 2 1 CNS15030CNS15030

139 DivisionCategoryType CNS15030CNS15030

140 DivisionCategoryType 1234

CNS15030CNS15030141()142 1.11.1

143 1.2

144 1.3

145 1.4

146 1.5

147 1.6

14820101.3 kPa1312

149

150(/ // ) 20

151 65oC

152

153

154

155

156(MEKPO)

157 LD50200mg/kg500mg/kg LD501000mg/kg LC5010mg/l LC505000ppm

158

159

160

161 (1)(2)(3)

1.2.

162123GHS163GHS

164(5-2)15030 ABAB ()165(5-3) () 166(5-4) 100

()167(6) 15030 168(7) 169(8)45

170(9) ()171(10-1) ()172

173(10-2)( ) ()174(11) GHSCNS 6864 Z5071 175(16) 176(12) ( ) ()177MSDSMSDS MSDSCf.MSDS()1.0%/1.0%/1.0%1.0%1 0.1%2 1.0%0.1%0.1%1.0% 1.0%: 179GHSMSDSALD502000mg/kg2AAGHS1MSDSMSDSALD50 5000mg/kg180 LD50200mg/kg500mg/kg LD501000mg/kg LC5010mg/l LC505000ppm 181 / ( CAS No.)() 182 pH/log Kow 183 184

/ 185 186

(CAS No.) () () 187 188() 189 190 191 192 // 193 194 (PEL-TWA)8(PEL-STEL)15(PEL-Ceiling) 195 pH / : : / log Kow 196log Kow (Kow)logP

197 198pH 70~33~68~1011~14

199 ()()() 200 11 201 ()() 202 ()()60.5 203() 204100g/100g100ml 205 206 (24~48

207LD50()(mg/kg)14LD50 LC50()()1414LC50(ppm) LD50 208 209 210 211 212 / () 213(14) ()707580214MSDS(15)3TMAHMSDSMSDS215(17) 3 MSDS 216(17-1) PDCAISOsay it, do it and document it!217(17-2)

218___________________ ___________________ _________ ____________________ ________________________________________________ _______________ ________________ _____ ______ __________ _____ ______ __________________________________________________________________________________ ()219MSDS(17-3) MSDS()220 MSDS50MSDSMSDSMSDS ()221MSDS(18)MSDS 222(19)MSDS ()223(20) 224 33 ()225212215030226(23) (24)

:227GHS96111996123197123120081231GHSGHS (MSDS1216)228 201 MSDSSDS

229200898GHSGHSGHSCD(06-2937-77002-8590-2777)GHShttp://ghs.cla.gov.tw

230