| additiva overview -...
TRANSCRIPT
| Additiva Overview
Regional Footprint
Porto Alegre HQ
Food and Feed
Itajaí Branch
São Paulo Branch
Industrial Cluster - Curitiba
Industrial Cluster - Joinville
Textile Cluster – Brusque / Blumenau
Ceramic Cluster – Criciúma
Metal-Mechanic Cluster – Caxias
Leather Cluster – Novo Hamburgo
Petrochemical Cluster – Triunfo
Various Industries – São Paulo Region
South and Southeast90 % Brazilian chemical consumption
BU Home Care
BU Acrylic Monomers
BU Formulation Technologies
BU Dispersions and Pigments
BU Chemicals for Paper
BU Fuel and Lubricant Solutions
Business Partners - Distribution
EmulsionsOilsElastomers
Fluorchemicals
UB Industrial Chemicals Glicols Amines Specialties
Asian ProductsImportation
Aromatics Acids Sodium Naftalene Cond. Hydrotropes
Business Partners - Re-sales
Other Chemicals
Updated Website
Blog
Newsletter
Chat OnLine
Quick Acess
Products by segment
PRODIR- Responsible Behavior Certification
Guarantee of working with a distributor who is
committed with safety, health and environment aspects;
Additiva incorporates the social and environmental
responsibility rules.
Resinas e Dispersões BASF – Soluções de alta eficiência para Tintas Decorativas e Industriais
Décio LimaGerente Técnico BASF
Larissa GuaitanelliGerente Técnica Additiva
INTERN
06.2016
Tintas Imobiliárias e Dispersões Poliméricas
8
Para que Servem?Tintas Imobiliárias
9
Onde elas estão?
10
• Baixo odor• Fácil limpeza• Aconchego
• Uniformidade• Retenção de cor• Pouca sujidade
• Elasticidade• Permeabilidade ao
vapor• Sem trincas
ElastoméricaMadeira
Exterior
Interior
• Longa duração• Proteção• Aspecto natural
Do que são compostas?Tintas Imobiliárias
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Composição básica das tintas:
Água
Cargas (Ex: Carbonato de Cálcio)
Pigmento (Ex: TiO2)
Ligante
AditivosAguaLigantePigmentoCargasAditivos
Secagem da Dispersão e Formação de Filme
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Dispersão polimérica aquosa
Evaporação da água e empacotamento das partículas
Deformação das partículas
Coalescência resultante da interdifusão das partículas
1st Stage
3rd StageTamb. >Tg
2nd StageTamb. ≥ TMFF
Para que servem os ligantes? Tintas Imobiliárias
13
Ligam os pigmentos;
Conferem a adesão da tinta na parede;
São responsáveis pela resistência à água, ao
escovamento, às intempéries.
Acronal® BS 700
15
Alta resistência à abrasão;
Alta interação com espessante.
20 – 25MFFT (ºC)7,0 – 8,5pH2500 – 5000RVT 3/20 (mPa.s) 49,0 – 51,0Solids content (%)
20 – 25MFFT (ºC)7,0 – 8,5pH2500 – 5000RVT 3/20 (mPa.s) 49,0 – 51,0Solids content (%)
Acronal® BS 701
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23 – 28TMFF (ºC)7,5 – 8,5pH2000 – 4000RVT 3/20 (mPa.s) 49,0 – 51,0Solids content (%)
23 – 28TMFF (ºC)7,5 – 8,5pH2000 – 4000RVT 3/20 (mPa.s) 49,0 – 51,0Solids content (%) Alta resistência à água
Evita o escurecimento da pedra Resistente ao álcool Alto brilho
Mercado Acronal® BS 701
168 horas de imersão
Acronal® BN 373
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Baixa tendência em dirt pick-up Alta elasticidade de filme Excelente permeabilidade a vapor de água Baixa pegajosidade de filme
Acronal® A 508
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Leve tack Selagem dos poros Resistência à eflorescência
NV (%) 40,0 - 42,0pH 7,5 - 8,5RVT 4/100 (mPa.s) 800 - 2000DTMP (nm) ca 80
Tinta Concreto
Ca+2 ↔ Ca(OH)2
CO2
H2O
CO2
H2O
CO2
H2O
Ar
CaCO3
Exterior
• Blocking resistance• Low water absorption• Whitening resistance• Resistant to alcalis• Good UV resistance• APEO free
Acronal® LR 9014
Os testes mais comuns Tintas Imobiliárias
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Lavabilidade Rub-out
Viscosidade Stormer Comportamento Reológico
Estabilidade emEstufa a 60oC
Intemperismo acelerado
Resinas para Tintas IndustriaisBASF Resins for Industrial Coatings
S-ED/SET – Technical Service for Coatings&Construction – South America
Décio Lima
Agentes de Cura Epóxi
INTERN
Industrial Coatings - Market Segments Epoxy Curing Agents
23
We will help our customers commercialize the next generation of compliant technologies by developing better cost and/or performance solutions for:
Heavy Duty ( Marine, Industrial Maintenance, General Industry )
Civil Engineering and Flooring
Resins Properties Alkyds Acrylic PU Polyester Epoxy
Chemical Resistance
Corrosion Resistance
Hardeness
Gloss
For high chemical resistance the Epoxy Systems are the best !!!
Epoxy Curing Agents Why Epoxy Systems
The Epoxy System:
1. Two-component systems of Epoxy and a CuringAgent
The reaction happens even at ambient temperature. Just prior to use, the ECA is mixed with an epoxy resin Appropriate PHRInduction timeNon-reversible chemical reactionNew solid copolymer, crosslinked, high molecular weight polymer.
Reactive Resins Epoxy Systems
Pot Life: period for wich two mutually reactive chemicals remain usable when mixed. Also called working life, sometimes Gel Time
PHR: the necessary Parts of the Hardener for One Hundred parts of Epoxy resin.
Induction Time: transition time from reactants to build up a new copolymer.
Terminologies
Amine Hydrogen Equivalent Weight [ AHEW ]
Epoxy Equivalent Weight [ EEW ]
Amount of hardener needed per 100 g of epoxy resin
100 *AHEWEEW
The mixing ratio can be optimised in order to achieve the desired performances.
PHR =
Terminologies
Product Groups / Line / Chemistry Application Fields by Product line
Liquid Reactive PolyamidesVersamid 115 / 125 / 140 / ( polyamide )Genamid 151 ( amidoamines)
Modified Epoxy Curing Agents Versamines ( amino curing agents ) C 31, C 36 , C 300- Modified Polyamides, Polyamides Adducts- Modified Amines, Amines Adducts,- Mannich bases, SaltAmines
Marine, Protective ( Industrial Maintenance,Water Treatment, Water Storage, Tanks ) .Specially where corrosion resistance is the main issue.
Civil Engineering ( self levelling , concrete coatings ) .
Special Coatings (high chemical resistance performance,where year-round & low temperature cure applications arerequired / low odour accelerator)
MATRIX OF PRODUCT TYPES (MAJOR PRODUCT LINES AND APPLICATIONS)
Industrial Coatings - Market Segments Epoxy Curing Agents Portfolio
Good adhesion ( green and old ) Water repelence Good Pigment Wetting Chemical and Corrosion Resistance Flexibility Low toxicity
Why Polyamides and Modified Amines as ECAs
Versamine Serie “C”
Water resistance Corrosion resistance Flexibility
Good chemical resistance Very low viscosistyBetter collorLess-yellowingBlush resistanceExcellent flow and leveling
Versamid
Versamid & Versamine Resins Properties
ECA’s V 115 V 125 V 140
%Active 100 100 100
Viscosity 25C gel 300 Ps 100 Ps
Viscosity 31 Ps @75C 8 Ps @75C -
phr 100 54 51
AHEW 198 103 97
Gel time n/a 2:00h 2:30h
Tack free 5:00h 5:00h 6:30h
Color 8 max 8 max 7 max
PropertiesCorrosion Resist ++++
Chemical Resist + +
Flexibility +++
Viscosity +++
Obs: see the arrowdirection
Versamid® - Polyamidoamine Resins
*AHEW = amine hydrogen equivalent weight*Brookfield Viscosity
*Amine value: mg/KOH/g
*phr = parts hundred resin
*Gardner Color
ECA's Genamid151
% Active 100Viscosity 3Ps @25°Cphr 48AHEW 91Gel time 1:50 hTack Free 9:00 hAmine Value 425-450Color 0
Genamid® – Amidoamine Resins
ECA’s C 31 C 36 C 300
%Active 58 72 70
Viscosity 25C 0,5 – 1 Ps 9 – 12 Ps 0,6 – 1 Ps
phr 45 61 50
AHEW 86 116 91
Gel time 30 min. 14 min. 25 min.
Tack free 5:00h 3:30h 1:00 h
Color 2 max 4 max 4 max
PropertiesCorrosion Resist =
Chemical Resist ++++
Flexibility +
Viscosity +
Gloss ++
Leveling ++
Yellowing +++
Adhesion ++
Low temp. cure +
Versamine® C
Very good anticorrosive coatings.
Very good chemical resistance.
Improved Cost/Performance.
Very good adhesion on metal surface although not properly cleaned.
Epoxy Curing AgentsIndustrial Maintenance – Main requirements
Improved Corrosion Protection
Chemical Resistance
Easy applicability
Longer Coating Life
Faster Return to Service
Longer Warranties
Epoxy Curing Agents Marine Market Drivers
Total System Approach
Total System Approach
Versamine® CEX 13-379
Total System Approach
Versamine® C 31, Versamine® C 36
Total System Approach
Versamine® C 31, Versamine® C 36, Versamine® C 300 Polyurethane
Total System Approach
Versamid® 140, Genamid® 151
Total System Approach
Versamine® C 31, Versamine® C 36, Versamine® C 300 Polyurethane
Total System Approach
Versamine® C 31, Versamine® C 36, Versamine® C 300 Polyurethane, Acrylic
Total System Approach
Versamid® 140, Genamid® 151
Total System Approach
Civil Engineering ApplicationFlooring Application Field
Chemical Resistance & Mechanical Properties Ease of handling ( low viscosity ). Faster Return to Service ( fast walk-able time) Humidity Tolerance.
Improved Durability Appearance ( avoid blushing ). Improved Cost/Performance
Epoxy Curing Agents
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Application / Property Recommendation
Anticorrosion primers Versamid® 115, 125, 140, Genamid® 151
Chemical Resistance Versamine® C 31, C 36, C 300
Industrial Trowelable Flooring Versamine® CEX 13-379
Industrial & Decorative Self Leveling Flooring
Versamine® C 31, C 36
Industrial & DecorativeFlooring Coatings
Versamine® C 31, C 36, C 300
Industrial & DecorativeFlooring Primers
Versamid® 140, Genamid® 151
Joncryl® Polyol - Main products
2K Aliphatic Urethane Coatings
Polyols + aliphatic polyisocyanates
Catalyzed by amines and various metal containing catalysts
Heat not required
Excellent properties Superior UV / Weathering Resistance Gloss retention Resistance to yellowing and chalking Chemical and abrasion resistant
Solvent, Monomer, Initiator
An evaporator - WFE
A big tank
A valve
Or
Use Directly
Polymer “Batch” reactor vs SGO
SGO vs Conventional Solution
ITEMS SGO TECHNOLOGY SOLUTION POLYMERIZATION
PROCESS
Production Method Continuous/Bulk (Semi) BatchTemperature High Temperature 500C – 1500CReaction Time Very Short (<1 hour) Long (Several Hours)Consistency Very Consistent Poorer ControlEfficiency/Environment High conversion/cleaner More waste
Auxiliary Raw Material
Initiator No or small amount YesChain-Transfer
No Yes
Solvent No or small amount Yes
PRODUCTS
Mw 1,500 – 25,000 > 5,000Quality Narrow Mw &
composition distributionBroad Mw &composition distribution
Type 100% Polymer Depends on PolymerMw, <50% Polymer
SGO Polymerization
MolecularWeight
Rel
ativ
eFr
actio
n
SGO Polyol - Extreme Batch to Batch Consistency
Conventional Polyol
Low Molecular WeightFractions
Reducing or Elminiating- Promotes Flow and
Leveling- Less Tendency to
Crater- Improved Performance
at SameAverageMolecular Weight
High MolecularWeight Fractions - Hurts Viscosity
Reducing or Eliminating- Promotes Flow and Leveling- Lower Viscosity at Same Average Molecular Weig
What SGO Does for Us:
Joncryl 804
Tg = 70°C Flake product (100% solids); designed for conventional solids paints Soluble in many different solvents Low OH content for economical urethane formulations (1,36% OH) “Lacquer dry” = fast surface dry Excellent chemical resistance Excellent exterior durability High gloss and gloss retention Main applications: industrial coatings, conventional solids automotive
refinish
Joncryl 551
Tg = 49°C “Water white” in can colour Conventional Solids = 60% in xylene Equivalent Weight = 620
low NCO demand = lower cost in use “Lacquer dry” = fast surface dry High gloss, but not as high as J500 Used in blends w/ J500 Main application: industrial coatings Lowest price of all Joncryl polyols
Joncryl 587
Tg = 57°C Flake product (100% solids); designed for conventional solids paints Soluble in many different solvents “Water white” in can colour when solubilized Equivalent Weight = 610. “Lacquer dry” = fast surface dry, even faster than J550 Excellent chemical resistance Excellent exterior durability High gloss and excellent gloss retention Very nice when used in blends w/ J500 Main applications: industrial coatings, conventional solids automotive
refinish
Joncryl 507
Tg = -7°C “Water white” in can colour High Solids = 80% in n- n-butyl acetate Equivalent Weight = 400 Excellent flow and levelling: excellent appearance and high gloss Low VOC Used in blends w/ other polymers Slow reaction Pot-life controled by formula catalyst Main application: industrial coatings
Joncryl 935
Tg = 17°C 70% solids “Water white” in can colour when solubilized Highest Equivalent Weight = 375 Best chemical resistance Best UV resistance Main applications: industrial coatings, conventional solids automotive
refinish
Exterior DurabilityUV A Resistance
Joncryl 935 vs. 901,906 & 910White Topcoats
100
90
80
70
60
50
40
30
20
10
0
0 200
400
600
800
1000
1200
1400
1600
1800
2000
2200
2400
2600
2800
3000
3200
3400
3600
Hours UV A
Glo
ss60
Degr
ees
J 901 J 935 J 906 J 910
901 - 3.25#/Gal
935 - 3.38#/Gal
906 - 3.51#/Gal
910 - 3.53#/Gal
Joncryl® RPD Polyols
Joncryl RPD Product Line
Newly developed products designed for:• < 1 hour dry through times• > 2 hour Potlife• Excellent hardness development• Very low resin color (< 50APHA)• Superior color stability• 2.1 to 3.5 lbs per gallon VOC
Joncryl® Acrylic Polyols
Target market is AutomotiveRefinish Ultra fast dry – sand-free times ~ 10 min.
Excellent resin color & color stability
Outstanding usable pot-life Improved weathering
Joncryl RPD 950-B
RPDNon -RPD
Joncryl Polyol Focus Products
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OH Recomm. forProduct Solids Sol- Tg Content Visc. Baking Description and Applications(%) vent (°C
)(%) (cps) Applications
Joncryl® 804 100 - 70 1,4 solidHigh equivalent weight for low NCO demand. Can be
yes used to formulate low cost, two-component urethanecoatings.
Joncryl® 551 60 xylene 49 2,7 6.000yes Conventional solids polyol. Fast dry with long pot life and
good exterior durability.
Joncryl® 587 100 - 57 2,8 solid yesConventional solids, “workhorse” polyol. Very fast dry with long pot life and excellent UV and chemical resistance.Solid form provides cost benefit and formulator versatility.
Joncryl®
RPD 950-B 61 n-butyl acetate 27 3,3 4.500 no
Acrylic polyol for solventborne 2K polyurethane systems in auto refinish and general industrial applications; fast cure, early hardness, and long pot life.
Joncryl® 507 80 n-butyl acetate -7 4,3 3.800 yes
Acrylic polyol with good hardness, stain resistance, and pigment dispersibility. Broad resin compatibility and useful as a low VOC modifier for appliance, office furniture, and general metal coatings. Recommended for high-build maintenance finishes and other polyurethane coatings.
Joncryl® 935 70 MAK 17 4,5 8.500 no
High performance polyol for polyurethane coatings. Offers excellent chemical resistance and exteriordurability.Suitable for automotive refinish and industrial applications.
MUITO OBRIGADA!
Distribuidor BASF região Sul
[email protected](51) 3030 9100 / (51) 9172 3849
[email protected](51) 3030 9100 / (51) 9244 0560
www.additiva.com.br