, central ethiopia are these lakes connected? shemelis fikre addis ababa university,department of...

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,CENTRAL ETHIOPIA Are these lakes Shemelis Fikre Addis Ababa University,Department of Earth Sciences POBOX 1176, Addis Ababa, Ethiopia

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,CENTRAL ETHIOPIA

Are these lakes connected?

Shemelis Fikre

Addis Ababa University,Department of Earth Sciences

POBOX 1176, Addis Ababa, Ethiopia

Topography of Ziway-Shala lakes area

400000 420000 440000 460000 480000 500000 520000 540000

780000

800000

820000

840000

860000

880000

900000

920000

0 10 20 30 K m

1 6 3 5

1 5 8 51 5 8 0

1 5 5 0

C h ila lo (4 0 0 5 )

A lu to

K a k a (4 2 4 5 )

C o rb etti

< 1 7 5 0 m (R ift f lo o r)

1 7 5 0 -2 0 0 0 m (E sca rp m en t)

> 2 0 0 0 m (H ig h lan d s)

L ak es

C atch m en t

L egen d

b o u n d a ry

Conceptualize the groundwater flow system in the area

Identify the subsurface hydraulic connections of the lakes in the area

Investigate the correspondence between spatial locations and statistical groups.

Assess surface water- groundwater interactions in the lake watershed system.

Conceptualize the role of geological structures on the groundwater movement

Sampling and laboratory analysis Hydrochemical techniques

– Physico – chemical analysis

– Statistical cluster analysis (HCA) and distributions of the clusters

Isotope techniques• 18O, 2H and 3H are analysed using plots for samples from the

different water bodies

Both hydrochemical and isotope techniques together– Scatter plots for the values of 18O versus EC, 18O versus chloride,

tritium versus EC and tritium versus chloride are prepared and interpreted

– Spatial variation of isotopes in relation with hydrochemistry using maps

Structural map of Ziway- Shala lakes area

N

r

r

rr

r

Shala

Langano

Ziway

Abiyata

S i lte

Debr e

ze i t F

aul t Z

on

Wo

nj i

Fa

ul t

Be

l t

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00

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00

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0 30Km

Caldera

Faults

Lake

Main fualt

Transverse ridge

Volcano

Recent fissurer

Legend

N

Sha a

Langano

Ziway

Abiya a

400000

400000

440000

440000

480000

480000

520000

520000

8000

00

800000

8400

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840000

8800

00

880000

9200

00

920000

0 30Km

Caldera

Faults

Lake

Main fualt

Transverse ridge

Volcano

Recent fissurer

Legend

HydrogeologyHydrogeology400000 460000 520000

7800

0084

0000

9000

00

0 1 0 2 0 3 0 K m

Z iw a y

A b iy a taL an g a n o

S h a la

1= Ignimbrite, tuff, local rhyolite2= Ignimbrite, tuff, local basalt3= Ignimbrite covered with lacustrine

soils, recent regression 4= Ignimbrite covered with lacustrine

deposit5= Rift volcanoes and volcanic ridges 6= Basalt, local ignimbrite 7= Lake 8= Volcano-tectonic structures 9= Drainage 10=Groundwater level contour 11=Cold spring 12=Hot spring13=Groundwater flow direction, Circles

represent the Hydraulic conductivity.

H y d rau lic C o n d u c tiv ity (m /d ay )L eg en d

< 1

1 to 4 0

> 4 0

(L o w )

(M o d era te )

(H ig h )

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126-127 5

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37

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944100 8

0 30Km

BoundaryRift floorEscarpmentHighlandlakesDrainage

ÊÚ Geothermal well$ River%U Cold springr Hot springÑ Hand dug well; Lake# Boreholes

N

The locations of sampling The locations of sampling sitessites

Na Ca Mg Cl HCO3 SO4Major Ions

0.1

1.0

10.0

100.0

1000.0

10000.0

C onc

ent ra

tions

(mg/l

)

Na Ca Mg Cl HCO3 SO4Major Ions

0.1

1.0

10.0

100.0

1000.0

10000.0

100000.0

C onc

ent ra

tions

(mg/l

)

Legend

Max.

75 percentile

Median

25 percentile

Min.

Groundwater Lake waters

1. Physico – chemical analysis

a) Major ion variability

390000.00 430000.00 470000.00 510000.00

X(m )

775000

815000

855000

895000

935000

Hydrochemical Map

Legend

100 0 100 m eq/l

N a C l

C a H C O 3

M g SO 4

0 1 0 2 0 3 0 K m

Groundwater flow direction

Major ion chemistry ………..

20

40

60

80 80

60

40

20

20

40

60

80

20

40

60

80

Ca Na+K HCO3+CO3 Cl

Mg SO4

H

H

H

HH

H

H H

H

H H

H

HH

H

H H

H

HH

H

H H

HH H

H

H

H

H

H H

H

HH

H

HH

H

HH

H

HH

H

H

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H H

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H H

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HH

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JJ

J

J J

J

JJ

J

J

J

J

J

J

J

JJ

J

J

J

J

O O

O

O O

OG

G

G

LegendLegend

H Borehole

L Coldspring

J Hand dug well

O Hot spring

G River

Escarpment

20

40

60

80 80

60

40

20

20

40

60

80

20

40

60

80

Ca Na+K HCO3+CO3 Cl

Mg SO4

H

H

H

H

H

H

HH

H

H

H

H

H

H

H

H

H

H

HH

H

HH

H

HH

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L

L

L

L

L

J

J

J

J

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J

LegendLegend

H Borehole

L Coldspring

J Hand dug well

Highland

b)b)Water types and physiographyWater types and physiography

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80 80

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40

20

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60

80

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40

60

80

Ca Na+K HCO3+CO3 Cl

Mg SO4

Rift floor

A A

A

A A

A

A A

A

I I

I

I I

I

I I

I

E E

E

E E

E

E E

E

K

K

K

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K

K

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K

HH

H

HH

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H H

H

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H H

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H H

H

L L

L

L L

L

L

L

L

LL

L

L L

L

SS

S

S S

S

S S

S

SS

S

S

S

S

J J

J

J J

J

J J

J

J JJ

J J

J

J J

J

JJ

J

JJ

J

J J

J

J J

J

J J

J

J J

J

J J

J

J J

J

J J

J

J J

J

O O

O

O O

O

O O

O

O O

O

O O

O

OO

O

O O

O

O O

O

M M

M

MM

M

MM

M

M M

M

M M

MM M

M

MM

M

M M

M

MM

M

MM

M

LegendLegend

A Abijata

H Borehole

L Coldspring

S Geothermal well

J Hand dug well

O Hot spring

I Langanoo

M River

E Shala

K Ziway

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80 80

60

40

20

20

40

60

80

20

40

60

80

Ca Na+K HCO3+CO3 Cl

Mg SO4

Rift floor

A A

A

A A

A

A A

A

I I

I

I I

I

I I

I

E E

E

E E

E

E E

E

K

K

K

K

K

K

K

K

K

HH

H

HH

H

H H

H

H

H

H

H H

H

HH

H

H H

H

H H

H

H H

H

H H

HH H

H

H H

H

HH

H

H H

H

H

H

H

H H

HH

H

H

H H

H

H H

H

H H

H

H H

H

H H

H

L L

L

L L

L

L

L

L

LL

L

L L

L

SS

S

S S

S

S S

S

SS

S

S

S

S

J J

J

J J

J

J J

J

J JJ

J J

J

J J

J

JJ

J

JJ

J

J J

J

J J

J

J J

J

J J

J

J J

J

J J

J

J J

J

J J

J

O O

O

O O

O

O O

O

O O

O

O O

O

OO

O

O O

O

O O

O

M M

M

MM

M

MM

M

M M

M

M M

MM M

M

MM

M

M M

M

MM

M

MM

M

LegendLegend

A Abijata

H Borehole

L Coldspring

S Geothermal well

J Hand dug well

O Hot spring

I Langanoo

M River

E Shala

K Ziway

c) Electrical conductivity• There are clear zonations in EC of natural waters

following the rift ward directions

400000 440000 480000 520000

7800

0082

0000

8600

0090

0000

0 10 20 30

K m

L a k eZ iw a y

L a k eA b iy a ta L a k e

L a n g an o

L a k eS h a la

< 1 5 0

1 5 0 -5 0 0

5 0 0 -1 5 0 0

1 5 0 0 -1 0 0 0 0

> 1 0 0 0 0

L eg en d

S tru c tu re s

G ro u n d w ate r

f lo w d irec tio n

2) Statistical analysis

• Spatial distribution and chemical differences of the HCA derived subgroups for groundwaters

14%

4%0% 0% 0% 0% 0%

6%

3%

0% 0% 0% 0% 0%

21%38% 48% 52% 49% 49% 50%

3%

3%

4% 1% 2% 5% 2%

2%1%

2% 4%0%

1%0%

46%45%

37%

24% 31% 25%38%

6% 5% 8%

20%16%

15%4%

1% 1% 0% 0% 1% 4% 5%

0%

10%

20%

30%

40%

50%

60%

70%

80%

90%

100%

Subgroup 1 Subgroup 2 Subgroup 3 Subgroup 4 Subgroup 5 Subgroup 6 Subgroup 7

% m

eq/l

SO4

Cl

HCO3

CO3

K

Na

Mg

Ca

Group-AGroup -B

Statistical analysis…

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1

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117118

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3334

41

43

57

61

64

75

79

92

93

106

110111

112

119121

122

124

126129

130

LakeLake

ZiwayZiway

LakeLake

LakeLakeLakeLakeAbiyataAbiyata

LanganoLangano

ShalaShala

0 30Km

N

Sampling sites#

Structures

Lake

Subgroup & Watertype

1 (Na-Ca-HCO3)

2 (Na-HCO3)

3 (Na-HCO3)

4 (Na-HCO3-Cl)

5 (Na-HCO3-Cl)

6 (Na-HCO3-Cl)

7 (Na-HCO3)

Legend

Hydrochemical evolutions and groundwater flow

• Starting from highland and escarpment waters and ending with rift floor waters; 1234. Total dissolved solids (TDS) concentration increases with increasing subgroup number

20

40

60

80 80

60

40

20

20

40

60

80

20

40

60

80

Ca Na+K HCO3+CO3 Cl

Mg SO4

AA

A

D D

D

C C

C

L L

L

J J

J

NN

N

GG

G

LegendLegend

A Subgroup-1

D Subgroup-2

C Subgroup-3

L Subgroup-4

J Subgroup-5

N Subgroup-6

G Subgroup-7

1

2

3

4 Chemical Evolution Path-From the recharge areas to discharge areas

0 10 20 30 40 50

NA+K

0

10

20

30

40

50

C l+S O

4

BBBBB

B

B

B

BBHH

H

HHH

HHHIIIIIIIII

A DC

L

J

N

G

EE EEE

EE

LegendLegend

A Subgroup-1

D Subgroup-2

C Subgroup-3

L Subgroup-4

J Subgroup-5

N Subgroup-6

G Subgroup-7

H Lake Langanoo

I Lake Shala

E Lake Ziway

B Lake Abiyata

0 10 20 30 40 50

NA

0

10

20

30

40

50

H CO 3

BBBBB

B

B

B

BBHH

H

HHH

H HHIIIII

IIII

AD

C

L

J

N

G

EE EEE

EE

Note:- Represents direction of anion and cation dominance in groundwaters and lake waters along flow path from recharge to discharge area

Groundwater-lake water interactions

N

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Ñ

Ñ

Ñ

Ñ

%

%

%

%

%

ð

ð

ððð

r rrr

r

r b7

b2-b5

b6f2

f19f20 f21

f22

a1

a2

a3

a4

a5

a1

a2

a3

a4

a5

d1

d2

d3

d4

e1e2

e3

e4

e5

e6

e7

e8

c1

c6

c8

c9c2

c3

c4

c10

c11

c13

c16

c17

c18

c20

c12

c14

c21

c22

f1 f3

f4

f5

f6

f7

f8

f9f10

f11

f12

f13

f14

f15f17

f18

f16

c19

0 20 30Km10

Cold springs%

Geothermalð

Hot springsr

Lake&\

RainÑ

River$

Well#

Legend

N

b7

b2-b5

b6f2

f19f20 f21

f22

a1

a2

a3

a4

a5

a1

a2

a3

a4

a5

d1

d2

d3

d4

e1e2

e3

e4

e5

e6

e7

e8

c1

c6

c8

c9c2

c3

c4

c10

c11

c13

c16

c17

c18

c20

c12

c14

c21

c22

f1 f3

f4

f5

f6

f7

f8

f9f10

f11

f12

f13

f14

f15f17

f18

f16

c19

0 20 30Km10

Cold springs%

Geothermalð

Hot springsr

Lake&\

RainÑ

River$

Well#

Legendsampling sites for sampling sites for isotope analysis:-isotope analysis:-

D = 5.4818O + 8.5

-60

-40

-20

0

20

40

60

80

100

-10 -8 -6 -4 -2 0 2 4 6 8 1018O (%0)

2H

(%0)

Cold well

Cold spring

Geothermal well

Hot spring

Lake

Rain

River

GMWL

LMWL

LEL (Lake)

Lake Abiyata and ShalaLake Ziway and

Langanof12f5

f1e2

f19

f22

b7

f18

a4

a2d1

d4

b2

b6

e3

e5

Oitu

Deuterium (2H) and oxygen(18O ) isotope

Deuterium (Deuterium (22H) and oxygen(H) and oxygen(1818O ) O ) isotopesisotopes

– The LMWL is plotted above the GMWL this is due to the isotopic The LMWL is plotted above the GMWL this is due to the isotopic concentrations of concentrations of precipitation in the study area has more precipitation in the study area has more deuterium excessdeuterium excess (that is D excess=2.35) than the global (that is D excess=2.35) than the global averaged precipitations.averaged precipitations.

– The majority of groundwaters, river waters and rain waters are The majority of groundwaters, river waters and rain waters are plotted near the LMWL .This indicate the plotted near the LMWL .This indicate the importance of present importance of present day precipitation for groundwater rechargeday precipitation for groundwater recharge..

– The lake Waters are plotted far to the right and shifted right down The lake Waters are plotted far to the right and shifted right down of the LMWL .This shows that of the LMWL .This shows that the lakes are more enriched with the lakes are more enriched with 1818O and O and 22HH resulted from substantial evaporative loss of the resulted from substantial evaporative loss of the lake waters as compared to the present day precipitation . lake waters as compared to the present day precipitation .

– Groundwaters (waters from hot spring, cold springs, cold wells, and Groundwaters (waters from hot spring, cold springs, cold wells, and geothermal wells) are scattered at different positions on the plot geothermal wells) are scattered at different positions on the plot and have differences in and have differences in 1818O and O and 22H concentrations. H concentrations.

• The relations between 18O with EC

a1a2

a4

b2b6

f17

f18f16 f12f1

-100

1900

3900

5900

7900

9900

11900

-5.00 -3.00 -1.00 1.00 3.00 5.00 7.00 9.0018O (%0)

EC(u

s/cm)

Cold spring

Hot spring

River

Cold Well

Lake Lake Langano and Horakelo river

Lake Ziway and Bulbula river f20

a1

f19

f21

f22f2

b4b6

b7

Oitu

c12 c9

c10c13f17

f18f1 f12

-300.0

200.0

700.0

1200.0

1700.0

2200.0

-5.00 -3.00 -1.00 1.00 3.00 5.00 7.00 9.00 11.00

18O (%0)

Cl(m

g/l)

Cold spring

Geothermal well

Hot spring

Lake

River

Cold well

c19

The relations between The relations between 1818O with ClO with Cl

The relations between The relations between 1818O with ECO with EC … … The The cold spring waterscold spring waters have negative have negative 1818O constituents and low EC similar to O constituents and low EC similar to the rivers( except Bulbula and Horakelo) the rivers( except Bulbula and Horakelo) indicates that they are rechrged indicates that they are rechrged by shallow circulating groundwatersby shallow circulating groundwaters which have undergone little rock- which have undergone little rock- water interactions.Groundwater flows from lake Ziway to lake Langanowater interactions.Groundwater flows from lake Ziway to lake Langano

The source of some hot springs is surface waters and shallow groundwaters.The source of some hot springs is surface waters and shallow groundwaters.

The relations between 18O with Cl ...

•The lake water labeled c12 (lake Ziway) has similar chloride concentration with c9 (lake Langano) but the 18O enrichment in c9 is higher than c12.This is due to the high evaporation water loss from lake Langano. From this it is evidence to conclude that there is southward migration of lake Ziway waters towards lake Langano

• The geothermal water labeled f19 has similar 18O enrichment but higher Cl concentration than lake Ziway waters (labeled c12).Lake waters labeled c13 has also similar 18O enrichment and Cl concentrations with the geothermal water labeled f20. This shows that there is dilution of the geothermal water by the lake Ziway water. From this it is evidence to conclude that there is mixing of the lake waters with the geothermal waters.

Tritium versus EC

b3

f9

f8 f11

f10f15f14

f7

f13

c12c14

0

500

1000

1500

2000

2500

3000

0.00 1.00 2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.003H (TU)

EC u

s/cm

)

Hot spring

River

Cold well

Lake

Bulbula

Tritium versus Chloride

0.30

b5

b4

f10f11f8f9

Ziway (2006)Ziway (1995)

Ziway (1992)

-100.0

0.0

100.0

200.0

300.0

400.0

500.0

600.0

700.0

0.00 1.00 2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00

3H(TU)

Cl (m

g/l)

Geothermal well

Hot spring

Cold well

Lake

• The lake Ziway water shows a decrease in tritium content and chloride concentration with time indicates the decrease in the amount of surface inflow in to the lake

• The borehole waters near the lakes have similar EC and tritium values to the lake waters indicating the interaction of the lake waters with the surrounding groundwaters.

• Boreholes near the geothermal system has higher EC and lower tritium values may indicate mixing

Spatial variation of isotopes in relation with hydrochemistry

a1

a2

a3

a4

a5

b 2

c5

c8

c9

c1 0

c1 1

c1 2c1 3

c1 6

c1 8

c2 0

d 2

d 3

d 4

e3

e4

e5

e6

e7

e8

f2

f4

f5

f6f1 7

f2 1e1

f1 0

f1 4

f1 5

f7

f8

f9

0 1 0 2 0 3 0 K m

0 to 0.5

0.5 to 10

10 to 100

O xygen-18 D istribution

Tritium D istribution

-4.5 to -3.5

-3.5 to -2.75

-2.75 to -1 .75

-1.75 to -1

-1 to 0

0 to 7

7 to 10.5

E C (µ s /c m )

F au lts

f1 2

c1 4

f1 6

d 1

b 7f1 8

c1

f1f2 0

f3

f1 9 f2 2e2

c4

f1 1

c3

c2

b 2 -b 6

c2 1

symbol label begins with “a” are cold spring, with “d” are rain and “e” are river samples

• The high spatial ionic variations follows systematic trend. This The high spatial ionic variations follows systematic trend. This reflects the different groundwater flow systems and the existence of reflects the different groundwater flow systems and the existence of hydrochemical evolution of waters along the flow pathhydrochemical evolution of waters along the flow path

On the highlands and escarpments there is shallow circulation of On the highlands and escarpments there is shallow circulation of groundwaters from direct recharge of precipitation and these waters groundwaters from direct recharge of precipitation and these waters have undergone no marked rock-water interactions.have undergone no marked rock-water interactions.

The low EC & TDS and isotope depleted waters in highly faulted rift The low EC & TDS and isotope depleted waters in highly faulted rift waters which have similarity in EC, TDS and depletion with the waters which have similarity in EC, TDS and depletion with the highland and escarpment waters indicates the southward migration highland and escarpment waters indicates the southward migration of highland and escarpment waters through faults and finally to lake of highland and escarpment waters through faults and finally to lake Langano. The tectonic structures play a great role on the Langano. The tectonic structures play a great role on the groundwater flow and chemical evolutiongroundwater flow and chemical evolution

There is deeper groundwater circulation of old age on the highly There is deeper groundwater circulation of old age on the highly faulted areasfaulted areas

CONCLUSIONS……CONCLUSIONS……

The lake waters, the majority of the groundwaters and surface The lake waters, the majority of the groundwaters and surface waters have similar tritium contents. This shows that these waters have similar tritium contents. This shows that these waters have similar recharge source.waters have similar recharge source.

Tritium contents of water from deep wells and hot springs are Tritium contents of water from deep wells and hot springs are different from lake waters indicates they have different different from lake waters indicates they have different sourcessources

Groundwaters north of lake Langano have similar Groundwaters north of lake Langano have similar 1818O content O content with the lake Ziway waters may show that there is subsurface with the lake Ziway waters may show that there is subsurface hydraulic connection between lake Ziway and lake Langanohydraulic connection between lake Ziway and lake Langano

The chemical composition of borehole waters between lake The chemical composition of borehole waters between lake Abiyata and Langano is similar for the nearby lake waters. Abiyata and Langano is similar for the nearby lake waters. This shows that there is flow of waters from lake Langano to This shows that there is flow of waters from lake Langano to lake Abiyata along the NE-SW trending faultlake Abiyata along the NE-SW trending fault

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