mark beasley to:bs>file

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Blue, Karen

To: Kilburn, DiannaSubject: RE: Lab report L974631

From: Mark Beasley [mailto:[email protected]]Sent: Sunday, July 15, 2018 4:18 PM To: Kilburn, Dianna Subject: Lab report L974631

Mark BeasleyNational Account Manager

Pace Analytical National Center for Testing & Innovation12065 Lebanon Road | Mt. Juliet, TN 37122615.773.9672 | Cell [email protected] | pacenational.com

ESC Lab Sciences is now Pace Analytical National Center for Testing & Innovation! Pleasemake note of my new email address and website.

Notice: This communication and any attached files may contain privileged or other confidential information. If you have received this in error, please contact the sender immediately via reply email and immediately delete the message and any attachments without copying or disclosing the contents. Thank you.

Rec’d Digitally

AFIN:_________________________

PMT#:_________________________ SW

DOC ID#:______________________ MD

TO:___________________________

By Karen Blue at 10:15 am, Jul 17, 2018

21-00036

0102-S3N-R4

74201

BS>FILE <KMB

ANALYTICAL REPORTMay 25, 2018

FTN Associates - Little Rock, AR

Sample Delivery Group: L995795

Samples Received: 05/04/2018

Project Number: 10453-1768-001

Description: Clearwater Paper Landfill

Report To: Dana Derrington

3 Innwood Circle, Suite 220

Little Rock, AR 72211

Entire Report Reviewed By:

May 25, 2018

[Preliminary Report]

Mark W. BeasleyTechnica l Serv ice Representa t ive

Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by ESC is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304.

12065 Lebanon Rd Mount Jul iet , TN 37122 615-758-5858 800-767-5859 www.esclabsciences.com

May 25, 2018


http://www.esclabsciences.com

https://www.esclabsciences.com/login

mailto:[email protected]; [email protected]?subject=ESC Lab Sciences SDG: L995795 - PN: 10453-1768-001&body=Email regarding SDG: L995795 - Project Number: 10453-1768-001

mailto:[email protected]?subject=ESC Lab Sciences SDG: L995795&body=Email regarding SDG: L995795



ONE LAB. NATIONWIDE.TABLE OF CONTENTS

Cp: Cover Page 1

Tc: Table of Contents 2

Ss: Sample Summary 3

Cn: Case Narrative 4

Sr: Sample Results 5

MW-8 L995795-01 5

MW-20 L995795-02 6

Qc: Quality Control Summary 7

Metals (ICPMS) by Method 6020 7

Gl: Glossary of Terms 8

Al: Accreditations & Locations 9

Sc: Sample Chain of Custody 10

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ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:

FTN Associates - Little Rock, AR 10453-1768-001 L995795 05/25/18 08:08 2 of 11



ONE LAB. NATIONWIDE.SAMPLE SUMMARY

Collected by Collected date/time Received date/time

MW-8 L995795-01 GW Michael Clayton 05/03/18 11:15 05/04/18 08:45

Method Batch Dilution Preparation Analysis Analyst

date/time date/time

Metals (ICPMS) by Method 6020 WG1113975 1 05/23/18 10:57 05/25/18 02:46 JPD




date/time date/time


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ONE LAB. NATIONWIDE.CASE NARRATIVE

All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated withinthe report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental sampleshave been corrected for the dilution factor used in the analysis. All radiochemical sample results for solids are reported on a dry weight basis with the exception of tritium, carbon-14 and radon, unless wet weight was requested by the client. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data.


Mark W. BeasleyTechn ica l Se rv i ce Represen ta t i ve

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ONE LAB. NATIONWIDE.SAMPLE RESULTS - 01L 9 9 5 7 9 5

MW-8C o l l e c t e d d a t e / t i m e : 0 5 / 0 3 / 1 8 1 1 : 1 5

Metals (ICPMS) by Method 6020

Result Qualifier MDL RDL Dilution Analysis Batch

Analyte ug/l ug/l ug/l date / time

Barium 121 0.360 5.00 1 05/25/2018 02:46 WG1113975

Iron 1940 15.0 100 1 05/25/2018 02:46 WG1113975

Manganese 198 0.250 5.00 1 05/25/2018 02:46 WG1113975

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Barium 164 0.360 5.00 1 05/25/2018 02:50 WG1113975

Iron 2990 15.0 100 1 05/25/2018 02:50 WG1113975

Manganese 308 0.250 5.00 1 05/25/2018 02:50 WG1113975

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ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1113975M e t a l s ( I C P M S ) b y M e t h o d 6 0 2 0 L 9 9 5 7 9 5 - 0 1 , 0 2

Method Blank (MB)

(MB) R3312988-1 05/25/18 02:15

MB Result MB Qualifier MB MDL MB RDL

Analyte ug/l ug/l ug/l

Barium U 0.360 5.00

Iron U 15.0 100

Manganese U 0.250 5.00

Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)

(LCS) R3312988-2 05/25/18 02:20 • (LCSD) R3312988-3 05/25/18 02:24

Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l % % % % %

Barium 50.0 47.3 46.3 94.5 92.7 80.0-120 2.02 20

Iron 5000 5190 5150 104 103 80.0-120 0.616 20

Manganese 50.0 48.9 48.6 97.7 97.2 80.0-120 0.611 20

L995361-12 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)

(OS) L995361-12 05/25/18 02:29 • (MS) R3312988-5 05/25/18 02:37 • (MSD) R3312988-6 05/25/18 02:42

Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits

Analyte ug/l ug/l ug/l ug/l % % % % %

Barium 50.0 324 368 370 88.6 91.4 1 75.0-125 0.382 20

Iron 5000 ND 5070 5070 101 101 1 75.0-125 0.0682 20

Manganese 50.0 467 502 503 68.8 70.6 1 75.0-125 V V 0.182 20

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ONE LAB. NATIONWIDE.GLOSSARY OF TERMS

Guide to Reading and Understanding Your Laboratory Report

The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative.

Abbreviations and Definitions

MDL Method Detection Limit.

RDL Reported Detection Limit.

Rec. Recovery.

RPD Relative Percent Difference.

SDG Sample Delivery Group.

U Not detected at the Reporting Limit (or MDL where applicable).

Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported.

Dilution

If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor.

LimitsThese are the target % recovery ranges or % difference value that the laboratory has historically determined as normal for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges.

Original Sample The non-spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG.

QualifierThis column provides a letter and/or number designation that corresponds to additional information concerning the resultreported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.

Result

The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state “ND” (Not Detected) or “BDL” (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte.

Case Narrative (Cn)A brief discussion about the included sample results, including a discussion of any non-conformances to protocol observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.

Quality Control Summary (Qc)

This section of the report includes the results of the laboratory quality control analyses required by procedure or analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material.

Sample Chain of Custody (Sc)

This is the document created in the field when your samples were initially collected. This is used to verify the time and date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis.

Sample Results (Sr)This section of your report will provide the results of all testing performed on your samples. These results are provided by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section foreach sample will provide the name and method number for the analysis reported.

Sample Summary (Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates andtimes of preparation and/or analysis.

Qualifier Description

V The sample concentration is too high to evaluate accurate spike recoveries.

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ONE LAB. NATIONWIDE.

ESC Lab Sciences is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn-around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. * Not all certifications held by the laboratory are applicable to the results reported in the attached report. * Accreditation is only applicable to the test methods specified on each scope of accreditation held by ESC Lab Sciences.

State AccreditationsAlabama 40660 Nebraska NE-OS-15-05

Alaska 17-026 Nevada TN-03-2002-34

Arizona AZ0612 New Hampshire 2975

Arkansas 88-0469 New Jersey–NELAP TN002

California 2932 New Mexico ¹ n/a

Colorado TN00003 New York 11742

Connecticut PH-0197 North Carolina Env375

Florida E87487 North Carolina ¹ DW21704

Georgia NELAP North Carolina ³ 41

Georgia ¹ 923 North Dakota R-140

Idaho TN00003 Ohio–VAP CL0069

Illinois 200008 Oklahoma 9915

Indiana C-TN-01 Oregon TN200002

Iowa 364 Pennsylvania 68-02979

Kansas E-10277 Rhode Island LAO00356

Kentucky ¹ ⁶ 90010 South Carolina 84004

Kentucky ² 16 South Dakota n/a

Louisiana AI30792 Tennessee ¹ ⁴ 2006

Louisiana ¹ LA180010 Texas T 104704245-17-14

Maine TN0002 Texas ⁵ LAB0152

Maryland 324 Utah TN00003

Massachusetts M-TN003 Vermont VT2006

Michigan 9958 Virginia 460132

Minnesota 047-999-395 Washington C847

Mississippi TN00003 West Virginia 233

Missouri 340 Wisconsin 9980939910

Montana CERT0086 Wyoming A2LA

Third Party Federal AccreditationsA2LA – ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789

A2LA – ISO 17025 ⁵ 1461.02 DOD 1461.01

Canada 1461.01 USDA P330-15-00234

EPA–Crypto TN00003

ACCREDITATIONS & LOCATIONS

¹ Drinking Water ² Underground Storage Tanks ³ Aquatic Toxicity ⁴ Chemical/Microbiological ⁵ Mold ⁶ Wastewater n/a Accreditation not applicable

Our LocationsESC Lab Sciences has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. ESC Lab Sciences performs all testing at our central laboratory.

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http://www.esclabsciences.com/technical/accreditations

http://www.esclabsciences.com/aboutus/locations.aspx

ANALYTICAL REPORTMay 17 , 2018










May 17 , 2018





May 17 , 2018









Cp: Cover Page 1





MW-8 L991325-01 6

MW-20 L991325-02 7

MW-21 L991325-03 8

MW-2A L991325-04 9

MW-9 L991325-05 10

MW-4A L991325-06 11


Gravimetric Analysis by Method 2540 C-2011 12

Wet Chemistry by Method 353.2 13



Wet Chemistry by Method 4500S2 D-2011 16

Wet Chemistry by Method 9056A 17






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date/time date/time

Gravimetric Analysis by Method 2540 C-2011 WG1107605 1 05/07/18 12:34 05/07/18 13:22 BS

Wet Chemistry by Method 353.2 WG1112166 1 05/17/18 11:30 05/17/18 11:30 JER

Wet Chemistry by Method 365.4 WG1109018 1 05/09/18 08:57 05/09/18 16:19 KK

Wet Chemistry by Method 410.4 WG1109260 1 05/10/18 11:01 05/10/18 15:03 TH

Wet Chemistry by Method 4500S2 D-2011 WG1107731 1 05/07/18 20:39 05/07/18 20:39 MZ

Wet Chemistry by Method 9056A WG1108018 1 05/09/18 06:14 05/09/18 06:14 MAJ

Wet Chemistry by Method 9060A WG1109262 1 05/10/18 18:05 05/10/18 18:05 EG

Metals (ICPMS) by Method 6020 WG1108022 1 05/09/18 08:52 05/09/18 19:29 LD






date/time date/time














date/time date/time












MW-2A L991325-04 GW Michael Clayton 05/03/18 13:10 05/04/18 08:45


date/time date/time


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Project Narrat ive

NO2NO3: It appears the H2SO4 preservative may be adding some nitrate/nitrite to these samples. Reruns from preserved containers confirm original results while analysis from the unpreserved containers were much lower (and match historicals).

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Gravimetric Analysis by Method 2540 C-2011



Dissolved Solids 426000 2820 10000 1 05/07/2018 13:22 WG1107605

Wet Chemistry by Method 353.2



Nitrate-Nitrite U Q 19.7 100 1 05/17/2018 11:30 WG1112166

Sample Narrative:

L991325-01 WG1112166: Run from unpreserved containers per client/CU, samples were above expected values




Phosphorus,Total 634 35.0 100 1 05/09/2018 16:19 WG1109018




COD 12800 3000 10000 1 05/10/2018 15:03 WG1109260

Wet Chemistry by Method 4500S2 D-2011



Sulfide U 6.50 50.0 1 05/07/2018 20:39 WG1107731

Wet Chemistry by Method 9056A



Chloride 27100 51.9 1000 1 05/09/2018 06:14 WG1108018

Fluoride 304 9.90 100 1 05/09/2018 06:14 WG1108018

Sulfate 8260 77.4 5000 1 05/09/2018 06:14 WG1108018




TOC (Total Organic Carbon) 3020 102 1000 1 05/10/2018 18:05 WG1109262




Arsenic 3.48 0.250 2.00 1 05/09/2018 19:29 WG1108022

Barium 112 0.360 5.00 1 05/09/2018 21:42 WG1108022

Cadmium U 0.160 1.00 1 05/09/2018 19:29 WG1108022

Chromium 0.766 J 0.540 2.00 1 05/09/2018 19:29 WG1108022

Copper 1.70 J 0.520 5.00 1 05/09/2018 19:29 WG1108022

Iron 1780 15.0 100 1 05/09/2018 19:29 WG1108022

Lead 0.469 J 0.240 2.00 1 05/09/2018 19:29 WG1108022

Manganese 184 0.250 5.00 1 05/09/2018 19:29 WG1108022

Nickel 0.870 J 0.350 2.00 1 05/09/2018 19:29 WG1108022

Potassium 2820 37.0 1000 1 05/10/2018 21:57 WG1109728

Zinc U 2.56 25.0 1 05/09/2018 19:29 WG1108022

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Nitrate-Nitrite 57.0 J Q 19.7 100 1 05/17/2018 11:32 WG1112166

Sample Narrative:









COD 7880 J 3000 10000 1 05/10/2018 15:03 WG1109260




Sulfide U 6.50 50.0 1 05/07/2018 20:40 WG1107731




Chloride 27800 51.9 1000 1 05/09/2018 06:29 WG1108018

Fluoride 296 9.90 100 1 05/09/2018 06:29 WG1108018

Sulfate 6890 77.4 5000 1 05/09/2018 06:29 WG1108018








Arsenic 2.04 0.250 2.00 1 05/09/2018 19:33 WG1108022

Barium 154 0.360 5.00 1 05/09/2018 21:46 WG1108022

Cadmium U 0.160 1.00 1 05/09/2018 19:33 WG1108022

Chromium 0.638 J 0.540 2.00 1 05/09/2018 19:33 WG1108022

Copper 0.936 J 0.520 5.00 1 05/09/2018 19:33 WG1108022

Iron 2700 15.0 100 1 05/09/2018 19:33 WG1108022

Lead U 0.240 2.00 1 05/09/2018 19:33 WG1108022

Manganese 283 0.250 5.00 1 05/09/2018 19:33 WG1108022

Nickel 0.506 J 0.350 2.00 1 05/09/2018 19:33 WG1108022

Potassium 3010 37.0 1000 1 05/10/2018 22:02 WG1109728

Zinc U 2.56 25.0 1 05/09/2018 19:33 WG1108022

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Dissolved Solids 3000 J 2820 10000 1 05/07/2018 13:22 WG1107605




Nitrate-Nitrite U Q 19.7 100 1 05/17/2018 11:33 WG1112166

Sample Narrative:





Phosphorus,Total U 35.0 100 1 05/09/2018 16:22 WG1109018




COD 3650 J 3000 10000 1 05/10/2018 15:03 WG1109260




Sulfide U 6.50 50.0 1 05/07/2018 20:40 WG1107731




Chloride 580 B J 51.9 1000 1 05/09/2018 06:44 WG1108018

Fluoride U 9.90 100 1 05/09/2018 06:44 WG1108018

Sulfate U 77.4 5000 1 05/09/2018 06:44 WG1108018




TOC (Total Organic Carbon) 331 B J 102 1000 1 05/10/2018 19:20 WG1109262




Arsenic 0.906 J 0.250 2.00 1 05/09/2018 19:37 WG1108022

Barium U 0.360 5.00 1 05/09/2018 21:50 WG1108022

Cadmium U 0.160 1.00 1 05/09/2018 19:37 WG1108022

Chromium U 0.540 2.00 1 05/09/2018 19:37 WG1108022

Copper 0.663 J 0.520 5.00 1 05/09/2018 19:37 WG1108022

Iron 17.5 J 15.0 100 1 05/09/2018 19:37 WG1108022

Lead 0.303 J 0.240 2.00 1 05/09/2018 19:37 WG1108022

Manganese U 0.250 5.00 1 05/09/2018 19:37 WG1108022

Nickel U 0.350 2.00 1 05/09/2018 19:37 WG1108022

Potassium U 37.0 1000 1 05/10/2018 22:06 WG1109728

Zinc U 2.56 25.0 1 05/09/2018 19:37 WG1108022

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MW-2AC o l l e c t e d d a t e / t i m e : 0 5 / 0 3 / 1 8 1 3 : 1 0




Fluoride 536 9.90 100 1 05/09/2018 07:31 WG1108018

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Iron 3710 15.0 100 1 05/09/2018 17:25 WG1108022

Manganese 597 0.250 5.00 1 05/09/2018 17:25 WG1108022

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ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1107605G r a v i m e t r i c A n a l y s i s b y M e t h o d 2 5 4 0 C - 2 0 1 1 L 9 9 1 3 2 5 - 0 1 , 0 2 , 0 3

Method Blank (MB)

(MB) R3307998-1 05/07/18 13:22



Dissolved Solids U 2820 10000

L991325-01 Original Sample (OS) • Duplicate (DUP)

(OS) L991325-01 05/07/18 13:22 • (DUP) R3307998-4 05/07/18 13:22

Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits

Analyte ug/l ug/l % %

Dissolved Solids 426000 424000 1 0.471 5


(LCS) R3307998-2 05/07/18 13:22 • (LCSD) R3307998-3 05/07/18 13:22



Dissolved Solids 8800000 8670000 8620000 98.5 98.0 85.0-115 0.578 5

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ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1112166W e t C h e m i s t r y b y M e t h o d 3 5 3 . 2 L 9 9 1 3 2 5 - 0 1 , 0 2 , 0 3

Method Blank (MB)

(MB) R3310763-1 05/17/18 11:27



Nitrate-Nitrite U 19.7 100


(OS) L993196-22 05/17/18 11:35 • (DUP) R3310763-4 05/17/18 11:36



Nitrate-Nitrite 2150 2160 1 0.186 20


(OS) L993331-15 05/17/18 12:01 • (DUP) R3310763-7 05/17/18 12:02



Nitrate-Nitrite 1990 1980 1 0.504 20


(LCS) R3310763-2 05/17/18 11:28 • (LCSD) R3310763-3 05/17/18 11:29



Nitrate-Nitrite 5000 3770 3790 94.3 94.7 90.0-110 0.397 20


(OS) L993331-01 05/17/18 11:37 • (MS) R3310763-5 05/17/18 11:42 • (MSD) R3310763-6 05/17/18 11:43



Nitrate-Nitrite 2500 ND 2490 2470 99.8 99.0 1 90.0-110 0.805 20

L993357-01 Original Sample (OS) • Matrix Spike (MS)

(OS) L993357-01 05/17/18 12:03 • (MS) R3310763-8 05/17/18 12:04

Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier

Analyte ug/l ug/l ug/l % %

Nitrate-Nitrite 2500 493 2940 97.9 1 90.0-110

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ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1109018W e t C h e m i s t r y b y M e t h o d 3 6 5 . 4 L 9 9 1 3 2 5 - 0 1 , 0 2 , 0 3 , 0 6

Method Blank (MB)

(MB) R3308365-1 05/09/18 16:04



Phosphorus,Total 35.7 J 35.0 100


(OS) L991037-01 05/09/18 16:07 • (DUP) R3308365-4 05/09/18 16:09



Phosphorus,Total ND 54.2 1 0.000 20


(OS) L991237-01 05/09/18 16:25 • (DUP) R3308365-7 05/09/18 16:27



Phosphorus,Total 140 0.000 1 200 P1 20


(LCS) R3308365-2 05/09/18 16:05 • (LCSD) R3308365-3 05/09/18 16:06



Phosphorus,Total 2000 1940 1810 97.0 90.5 90.0-110 6.93 20

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ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1109260W e t C h e m i s t r y b y M e t h o d 4 1 0 . 4 L 9 9 1 3 2 5 - 0 1 , 0 2 , 0 3

Method Blank (MB)

(MB) R3308699-1 05/10/18 14:58



COD U 3000 10000


(OS) L989534-01 05/10/18 15:00 • (DUP) R3308699-4 05/10/18 15:01



COD 15000000 14900000 50 1.00 20


(OS) L991498-02 05/10/18 15:06 • (DUP) R3308699-7 05/10/18 15:06



COD 28400 26800 1 5.90 20


(LCS) R3308699-2 05/10/18 14:58 • (LCSD) R3308699-3 05/10/18 14:59



COD 242000 224000 227000 92.7 93.6 90.0-110 0.972 20


(OS) L991494-02 05/10/18 15:04 • (MS) R3308699-5 05/10/18 15:05 • (MSD) R3308699-6 05/10/18 15:05



COD 400000 23800 306000 309000 70.5 71.2 1 80.0-120 J6 J6 0.928 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1107731W e t C h e m i s t r y b y M e t h o d 4 5 0 0 S 2 D - 2 0 1 1 L 9 9 1 3 2 5 - 0 1 , 0 2 , 0 3

Method Blank (MB)

(MB) R3307682-1 05/07/18 20:29



Sulfide U 6.50 50.0


(OS) L991325-01 05/07/18 20:39 • (DUP) R3307682-4 05/07/18 20:39



Sulfide U 0.000 1 0.000 20


(LCS) R3307682-2 05/07/18 20:30 • (LCSD) R3307682-3 05/07/18 20:31



Sulfide 500 508 505 102 101 85.0-115 0.592 20


(OS) L991325-03 05/07/18 20:40 • (MS) R3307682-5 05/07/18 20:41 • (MSD) R3307682-6 05/07/18 20:41



Sulfide 1000 U 1180 1190 118 119 1 80.0-120 0.762 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1108018W e t C h e m i s t r y b y M e t h o d 9 0 5 6 A L 9 9 1 3 2 5 - 0 1 , 0 2 , 0 3 , 0 4

Method Blank (MB)

(MB) R3308134-1 05/09/18 01:05



Chloride 118 J 51.9 1000

Fluoride U 9.90 100

Sulfate U 77.4 5000


(OS) L990597-01 05/09/18 02:07 • (DUP) R3308134-4 05/09/18 02:22



Chloride 43700 43000 1 1.49 15

Fluoride 513 497 1 3.11 15

Sulfate 33300 32900 1 1.10 15


(OS) L991272-06 05/09/18 04:57 • (DUP) R3308134-7 05/09/18 05:12



Chloride ND 96.2 1 0.000 15

Fluoride ND 0.000 1 0.000 15

Sulfate ND 0.000 1 0.000 15


(LCS) R3308134-2 05/09/18 01:21 • (LCSD) R3308134-3 05/09/18 01:36



Chloride 40000 40000 40100 100 100 80.0-120 0.303 15

Fluoride 8000 8000 8010 100 100 80.0-120 0.147 15

Sulfate 40000 40100 40200 100 101 80.0-120 0.318 15

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc







(OS) L990597-01 05/09/18 02:07 • (MS) R3308134-5 05/09/18 02:38 • (MSD) R3308134-6 05/09/18 02:53



Chloride 50000 43700 99100 87500 111 87.7 1 80.0-120 12.3 15

Fluoride 5000 513 6070 5180 111 93.3 1 80.0-120 J3 16.0 15

Sulfate 50000 33300 84600 77100 103 87.7 1 80.0-120 9.26 15


(OS) L991272-06 05/09/18 04:57 • (MS) R3308134-8 05/09/18 05:27



Chloride 50000 ND 54900 109 1 80.0-120

Fluoride 5000 ND 5150 103 1 80.0-120

Sulfate 50000 ND 49100 98.2 1 80.0-120

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1109262W e t C h e m i s t r y b y M e t h o d 9 0 6 0 A L 9 9 1 3 2 5 - 0 1 , 0 2 , 0 3

Method Blank (MB)

(MB) R3308737-1 05/10/18 09:19



TOC (Total Organic Carbon) 264 J 102 1000


(OS) L991259-05 05/10/18 16:55 • (DUP) R3308737-4 05/10/18 17:12



TOC (Total Organic Carbon) 9480 9580 1 1.09 20


(OS) L991334-01 05/10/18 20:53 • (DUP) R3308737-7 05/10/18 21:19





(LCS) R3308737-2 05/10/18 10:44 • (LCSD) R3308737-3 05/10/18 14:53



TOC (Total Organic Carbon) 75000 69100 69900 92.1 93.2 85.0-115 1.24 20


(OS) L991325-01 05/10/18 18:05 • (MS) R3308737-5 05/10/18 18:25 • (MSD) R3308737-6 05/10/18 18:43



TOC (Total Organic Carbon) 50000 3020 47800 48000 89.6 89.9 1 80.0-120 0.251 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1108022M e t a l s ( I C P M S ) b y M e t h o d 6 0 2 0 L 9 9 1 3 2 5 - 0 1 , 0 2 , 0 3 , 0 5

Method Blank (MB)

(MB) R3308417-1 05/09/18 17:13



Arsenic U 0.250 2.00

Barium U 0.360 5.00

Cadmium U 0.160 1.00

Chromium U 0.540 2.00

Copper U 0.520 5.00

Iron U 15.0 100

Lead U 0.240 2.00


Nickel U 0.350 2.00

Zinc U 2.56 25.0


(LCS) R3308417-2 05/09/18 17:17 • (LCSD) R3308417-3 05/09/18 17:21



Arsenic 50.0 48.9 49.0 97.8 98.1 80.0-120 0.259 20

Barium 50.0 44.4 45.2 88.7 90.4 80.0-120 1.85 20

Cadmium 50.0 51.4 51.8 103 104 80.0-120 0.777 20

Chromium 50.0 48.9 48.8 97.7 97.5 80.0-120 0.214 20

Copper 50.0 48.8 48.5 97.6 97.1 80.0-120 0.570 20

Iron 5000 4840 4820 96.8 96.5 80.0-120 0.388 20

Lead 50.0 48.3 48.3 96.7 96.7 80.0-120 0.000290 20

Manganese 50.0 45.7 46.0 91.4 92.1 80.0-120 0.801 20

Nickel 50.0 51.2 50.4 102 101 80.0-120 1.55 20

Zinc 50.0 47.7 50.5 95.4 101 80.0-120 5.74 20


(OS) L991325-05 05/09/18 17:25 • (MS) R3308417-5 05/09/18 17:33 • (MSD) R3308417-6 05/09/18 17:37



Arsenic 50.0 4.84 52.5 52.8 95.3 95.9 1 75.0-125 0.603 20

Barium 50.0 85.6 132 130 92.7 88.7 1 75.0-125 1.53 20

Cadmium 50.0 U 52.8 52.9 106 106 1 75.0-125 0.117 20

Chromium 50.0 0.681 48.3 48.5 95.2 95.6 1 75.0-125 0.470 20

Copper 50.0 1.40 47.5 47.2 92.3 91.6 1 75.0-125 0.735 20

Iron 5000 3710 8570 8560 97.1 97.0 1 75.0-125 0.0776 20

Lead 50.0 0.612 49.5 49.3 97.7 97.4 1 75.0-125 0.288 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1108022M e t a l s ( I C P M S ) b y M e t h o d 6 0 2 0 L 9 9 1 3 2 5 - 0 1 , 0 2 , 0 3 , 0 5


(OS) L991325-05 05/09/18 17:25 • (MS) R3308417-5 05/09/18 17:33 • (MSD) R3308417-6 05/09/18 17:37



Manganese 50.0 597 636 635 79.1 77.2 1 75.0-125 0.154 20

Nickel 50.0 0.387 50.0 50.1 99.3 99.3 1 75.0-125 0.0394 20

Zinc 50.0 5.22 50.0 49.4 89.6 88.5 1 75.0-125 1.17 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1109728M e t a l s ( I C P M S ) b y M e t h o d 6 0 2 0 L 9 9 1 3 2 5 - 0 1 , 0 2 , 0 3

Method Blank (MB)

(MB) R3308823-1 05/10/18 21:25



Potassium 79.4 J 37.0 1000


(LCS) R3308823-2 05/10/18 21:30 • (LCSD) R3308823-3 05/10/18 21:34



Potassium 5000 4940 4710 98.7 94.2 80.0-120 4.67 20


(OS) L992383-02 05/10/18 21:39 • (MS) R3308823-5 05/10/18 21:48 • (MSD) R3308823-6 05/10/18 21:53



Potassium 5000 ND 5470 5540 92.6 93.9 1 75.0-125 1.20 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc










ND Not detected at the Reporting Limit (or MDL where applicable).


Rec. Recovery.





Dilution

If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor.




Result










B The same analyte is found in the associated blank.

J The identification of the analyte is acceptable; the reported value is an estimate.

J3 The associated batch QC was outside the established quality control range for precision.

J6 The sample matrix interfered with the ability to make any accurate determination; spike value is low.

P1 RPD value not applicable for sample concentrations less than 5 times the reporting limit.

Q Sample was prepared and/or analyzed past recommended holding time. Concentrations should be considered minimumvalues.

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc



































A2LA – ISO 17025 ⁵ 1461.02 DOD 1461.01

Canada 1461.01 USDA P330-15-00234





1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc







ANALYTICAL REPORTApri l 23, 2018










Apri l 23, 2018





Apri l 23, 2018









Cp: Cover Page 1





MW-9 L986064-01 5






1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc









date/time date/time

Metals (ICPMS) by Method 6020 WG1098954 1 04/17/18 14:00 04/21/18 16:03 WBD

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc









1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc













Iron 4000 15.0 100 1 04/21/2018 16:03 WG1098954

Manganese 644 0.250 5.00 1 04/21/2018 16:03 WG1098954

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1098954M e t a l s ( I C P M S ) b y M e t h o d 6 0 2 0 L 9 8 6 0 6 4 - 0 1

Method Blank (MB)

(MB) R3303690-1 04/21/18 13:57



Iron 16.7 J 15.0 100



(LCS) R3303690-2 04/21/18 14:02 • (LCSD) R3303690-3 04/21/18 14:07



Iron 5000 5290 5160 106 103 80.0-120 2.55 20

Manganese 50.0 51.5 50.4 103 101 80.0-120 2.09 20


(OS) L986001-13 04/21/18 14:11 • (MS) R3303690-5 04/21/18 14:21 • (MSD) R3303690-6 04/21/18 14:26



Iron 5000 37.8 5110 5230 101 104 1 75.0-125 2.48 20

Manganese 50.0 0.540 49.1 50.5 97.0 100 1 75.0-125 3.01 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc











Rec. Recovery.





DilutionIf the sample matrix contains an interfering material, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor.




Result











1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc



































A2LA – ISO 17025 ⁵ 1461.02 DOD 1461.01

Canada 1461.01 USDA P330-15-00234





1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc







ANALYTICAL REPORTMarch 09, 2018










March 09, 2018





March 09, 2018




mailto:[email protected]?subject=ESC Lab Sciences SDG: L974631 - PN: 10453-1768-001&body=Email regarding SDG: L974631 - Project Number: 10453-1768-001





Cp: Cover Page 1





MW-1A L974631-01 7

MW-2A L974631-02 8

MW-3AR L974631-03 9

MW-4A L974631-04 10

MW-6A L974631-05 11

MW-7 L974631-06 12

MW-9 L974631-07 13

MW-10 L974631-08 14

MW-20 L974631-09 15

MW-21 L974631-10 16

LEACHATE L974631-11 17


Gravimetric Analysis by Method 2540 C-2011 18




Wet Chemistry by Method 4500S2 D-2011 26







1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc









date/time date/time




Wet Chemistry by Method 410.4 WG1079569 1 03/04/18 12:21 03/04/18 15:42 MZ


Wet Chemistry by Method 9056A WG1080350 1 03/04/18 16:56 03/04/18 16:56 DR

Wet Chemistry by Method 9060A WG1080485 1 03/05/18 17:15 03/05/18 17:15 SJM





date/time date/time










MW-3AR L974631-03 GW Michael Clayton 03/01/18 12:35 03/03/18 08:45


date/time date/time












date/time date/time











1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc









date/time date/time












date/time date/time













date/time date/time













date/time date/time









1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc









date/time date/time













date/time date/time










LEACHATE L974631-11 GW Michael Clayton 03/02/18 11:45 03/03/18 08:45


date/time date/time









Metals (ICPMS) by Method 6020 WG1081483 1 03/07/18 11:51 03/07/18 14:00 LAT

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc









1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc

















Nitrate-Nitrite 37.0 J 19.7 100 1 03/08/2018 16:45 WG1081168








COD 9790 J 3000 10000 1 03/04/2018 15:42 WG1079569




Sulfide U 6.50 50.0 1 03/04/2018 16:38 WG1080394




Chloride 66000 51.9 1000 1 03/04/2018 16:56 WG1080350

Fluoride 227 9.90 100 1 03/04/2018 16:56 WG1080350

Sulfate 44900 77.4 5000 1 03/04/2018 16:56 WG1080350








Arsenic 16.1 0.250 2.00 1 03/06/2018 14:38 WG1080281

Barium 265 0.360 5.00 1 03/06/2018 14:38 WG1080281

Cadmium 0.162 J 0.160 1.00 1 03/06/2018 14:38 WG1080281

Chromium U 0.540 2.00 1 03/06/2018 14:38 WG1080281

Copper 1.48 J 0.520 5.00 1 03/06/2018 14:38 WG1080281

Iron 8000 15.0 100 1 03/06/2018 14:38 WG1080281

Lead 0.515 B J 0.240 2.00 1 03/06/2018 14:38 WG1080281

Manganese 642 0.250 5.00 1 03/06/2018 14:38 WG1080281

Nickel 2.11 0.350 2.00 1 03/06/2018 14:38 WG1080281

Potassium 2180 O1 37.0 1000 1 03/06/2018 14:38 WG1080281

Zinc U 2.56 25.0 1 03/06/2018 14:38 WG1080281

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc














Nitrate-Nitrite 405 19.7 100 1 03/06/2018 15:39 WG1080683








COD 9250 J 3000 10000 1 03/04/2018 15:42 WG1079569




Sulfide U 6.50 50.0 1 03/04/2018 16:40 WG1080394




Chloride 33400 51.9 1000 1 03/04/2018 15:26 WG1080373

Fluoride 609 9.90 100 1 03/04/2018 15:26 WG1080373

Sulfate 16900 77.4 5000 1 03/04/2018 15:26 WG1080373








Arsenic 4.12 0.250 2.00 1 03/06/2018 14:53 WG1080281

Barium 111 0.360 5.00 1 03/06/2018 14:53 WG1080281

Cadmium 0.236 J 0.160 1.00 1 03/06/2018 14:53 WG1080281

Chromium U 0.540 2.00 1 03/06/2018 14:53 WG1080281

Copper 1.73 J 0.520 5.00 1 03/06/2018 14:53 WG1080281

Iron 914 15.0 100 1 03/06/2018 14:53 WG1080281

Lead 0.426 B J 0.240 2.00 1 03/06/2018 14:53 WG1080281

Manganese 254 0.250 5.00 1 03/06/2018 14:53 WG1080281

Nickel 1.03 J 0.350 2.00 1 03/06/2018 14:53 WG1080281

Potassium 2910 37.0 1000 1 03/06/2018 14:53 WG1080281

Zinc U 2.56 25.0 1 03/06/2018 14:53 WG1080281

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc






MW-3ARC o l l e c t e d d a t e / t i m e : 0 3 / 0 1 / 1 8 1 2 : 3 5
















COD 12000 3000 10000 1 03/04/2018 15:42 WG1079569




Sulfide U 6.50 50.0 1 03/04/2018 16:40 WG1080394




Chloride 28100 51.9 1000 1 03/04/2018 16:47 WG1080373

Fluoride 315 9.90 100 1 03/04/2018 16:47 WG1080373

Sulfate 9180 77.4 5000 1 03/04/2018 16:47 WG1080373








Arsenic 1.08 J 0.250 2.00 1 03/06/2018 14:57 WG1080281

Barium 359 0.360 5.00 1 03/06/2018 14:57 WG1080281

Cadmium U 0.160 1.00 1 03/06/2018 14:57 WG1080281

Chromium U 0.540 2.00 1 03/06/2018 14:57 WG1080281

Copper 0.618 J 0.520 5.00 1 03/06/2018 14:57 WG1080281

Iron 11200 15.0 100 1 03/06/2018 14:57 WG1080281

Lead U 0.240 2.00 1 03/06/2018 14:57 WG1080281

Manganese 1040 0.250 5.00 1 03/06/2018 14:57 WG1080281

Nickel U 0.350 2.00 1 03/06/2018 14:57 WG1080281

Potassium 1880 37.0 1000 1 03/06/2018 14:57 WG1080281

Zinc U 2.56 25.0 1 03/06/2018 14:57 WG1080281

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc














Nitrate-Nitrite 370 J6 19.7 100 1 03/06/2018 15:42 WG1080683








COD 23200 3000 10000 1 03/04/2018 15:42 WG1079569




Sulfide 9.00 J 6.50 50.0 1 03/04/2018 16:41 WG1080394




Chloride 47300 51.9 1000 1 03/04/2018 17:00 WG1080373

Fluoride 860 9.90 100 1 03/04/2018 17:00 WG1080373

Sulfate 388000 774 50000 10 03/05/2018 21:39 WG1080762








Arsenic 5.13 0.250 2.00 1 03/06/2018 15:01 WG1080281

Barium 109 0.360 5.00 1 03/06/2018 15:01 WG1080281

Cadmium 0.251 J 0.160 1.00 1 03/06/2018 15:01 WG1080281

Chromium U 0.540 2.00 1 03/06/2018 15:01 WG1080281

Copper 4.54 J 2.60 25.0 5 03/06/2018 15:33 WG1080281

Iron 10600 15.0 100 1 03/06/2018 15:01 WG1080281

Lead U 1.20 10.0 5 03/06/2018 15:33 WG1080281

Manganese 6380 0.250 5.00 1 03/06/2018 15:01 WG1080281

Nickel 2.46 0.350 2.00 1 03/06/2018 15:01 WG1080281

Potassium 261 J 37.0 1000 1 03/06/2018 15:01 WG1080281

Zinc U 2.56 25.0 1 03/06/2018 15:01 WG1080281

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc






















COD 8180 J 3000 10000 1 03/04/2018 15:42 WG1079569




Sulfide U 6.50 50.0 1 03/04/2018 16:41 WG1080394




Chloride 45600 51.9 1000 1 03/04/2018 17:13 WG1080373

Fluoride 244 9.90 100 1 03/04/2018 17:13 WG1080373

Sulfate 665 J 77.4 5000 1 03/04/2018 17:13 WG1080373








Arsenic 2.87 0.250 2.00 1 03/06/2018 15:37 WG1080281

Barium 243 0.360 5.00 1 03/06/2018 15:37 WG1080281

Cadmium U 0.160 1.00 1 03/06/2018 15:37 WG1080281

Chromium U 0.540 2.00 1 03/06/2018 15:37 WG1080281

Copper 0.927 J 0.520 5.00 1 03/06/2018 15:37 WG1080281

Iron 5760 15.0 100 1 03/06/2018 15:37 WG1080281

Lead 0.322 B J 0.240 2.00 1 03/06/2018 15:37 WG1080281

Manganese 476 0.250 5.00 1 03/06/2018 15:37 WG1080281

Nickel U 0.350 2.00 1 03/06/2018 15:37 WG1080281

Potassium 2350 37.0 1000 1 03/06/2018 15:37 WG1080281

Zinc 40.4 2.56 25.0 1 03/06/2018 15:37 WG1080281

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc






















COD 5480 J 3000 10000 1 03/05/2018 22:47 WG1080413




Sulfide U 6.50 50.0 1 03/04/2018 16:43 WG1080394




Chloride 46500 51.9 1000 1 03/04/2018 17:27 WG1080373

Fluoride 309 9.90 100 1 03/04/2018 17:27 WG1080373

Sulfate 184000 387 25000 5 03/05/2018 21:52 WG1080762








Arsenic 21.2 0.250 2.00 1 03/06/2018 15:41 WG1080281

Barium 66.7 0.360 5.00 1 03/06/2018 15:41 WG1080281

Cadmium U 0.160 1.00 1 03/06/2018 15:41 WG1080281

Chromium U 0.540 2.00 1 03/06/2018 15:41 WG1080281

Copper 1.39 J 0.520 5.00 1 03/06/2018 15:41 WG1080281

Iron 3450 15.0 100 1 03/06/2018 15:41 WG1080281

Lead U 0.240 2.00 1 03/06/2018 15:41 WG1080281

Manganese 1230 0.250 5.00 1 03/06/2018 15:41 WG1080281

Nickel U 0.350 2.00 1 03/06/2018 15:41 WG1080281

Potassium 1860 37.0 1000 1 03/06/2018 15:41 WG1080281

Zinc U 2.56 25.0 1 03/06/2018 15:41 WG1080281

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc






















COD 3890 J 3000 10000 1 03/05/2018 22:47 WG1080413




Sulfide U 6.50 50.0 1 03/04/2018 16:43 WG1080394




Chloride 43500 51.9 1000 1 03/04/2018 17:40 WG1080373

Fluoride 435 9.90 100 1 03/04/2018 17:40 WG1080373

Sulfate 137000 387 25000 5 03/05/2018 22:06 WG1080762








Arsenic 6.45 0.250 2.00 1 03/06/2018 15:44 WG1080281

Barium 102 0.360 5.00 1 03/06/2018 15:44 WG1080281

Cadmium U 0.160 1.00 1 03/06/2018 15:44 WG1080281

Chromium U 0.540 2.00 1 03/06/2018 15:44 WG1080281

Copper 1.45 J 0.520 5.00 1 03/06/2018 15:44 WG1080281

Iron 3970 15.0 100 1 03/06/2018 15:44 WG1080281

Lead U 0.240 2.00 1 03/06/2018 15:44 WG1080281

Manganese 636 0.250 5.00 1 03/06/2018 15:44 WG1080281

Nickel U 0.350 2.00 1 03/06/2018 15:44 WG1080281

Potassium 2750 37.0 1000 1 03/06/2018 15:44 WG1080281

Zinc U 2.56 25.0 1 03/06/2018 15:44 WG1080281

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc






















COD U 3000 10000 1 03/05/2018 22:47 WG1080413




Sulfide U 6.50 50.0 1 03/04/2018 16:43 WG1080394




Chloride 39200 51.9 1000 1 03/04/2018 17:54 WG1080373

Fluoride 310 9.90 100 1 03/04/2018 17:54 WG1080373

Sulfate 65900 77.4 5000 1 03/04/2018 17:54 WG1080373








Arsenic 1.43 J 0.250 2.00 1 03/06/2018 15:48 WG1080281

Barium 303 0.360 5.00 1 03/06/2018 15:48 WG1080281

Cadmium U 0.160 1.00 1 03/06/2018 15:48 WG1080281

Chromium U 0.540 2.00 1 03/06/2018 15:48 WG1080281

Copper 0.779 J 0.520 5.00 1 03/06/2018 15:48 WG1080281

Iron 5010 15.0 100 1 03/06/2018 15:48 WG1080281

Lead U 0.240 2.00 1 03/06/2018 15:48 WG1080281

Manganese 426 0.250 5.00 1 03/06/2018 15:48 WG1080281

Nickel U 0.350 2.00 1 03/06/2018 15:48 WG1080281

Potassium 3600 37.0 1000 1 03/06/2018 15:48 WG1080281

Zinc U 2.56 25.0 1 03/06/2018 15:48 WG1080281

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc






















COD 25700 3000 10000 1 03/05/2018 22:48 WG1080413




Sulfide U 6.50 50.0 1 03/04/2018 16:44 WG1080394




Chloride 47000 51.9 1000 1 03/04/2018 18:07 WG1080373

Fluoride 860 9.90 100 1 03/04/2018 18:07 WG1080373

Sulfate 392000 774 50000 10 03/05/2018 22:19 WG1080762








Arsenic 5.29 0.250 2.00 1 03/06/2018 15:52 WG1080281

Barium 107 0.360 5.00 1 03/06/2018 15:52 WG1080281

Cadmium U 0.160 1.00 1 03/06/2018 15:52 WG1080281

Chromium U 0.540 2.00 1 03/06/2018 15:52 WG1080281

Copper 4.93 J 0.520 5.00 1 03/06/2018 15:52 WG1080281

Iron 10700 15.0 100 1 03/06/2018 15:52 WG1080281

Lead U 0.240 2.00 1 03/06/2018 15:52 WG1080281

Manganese 6420 0.250 5.00 1 03/06/2018 15:52 WG1080281

Nickel 2.31 0.350 2.00 1 03/06/2018 15:52 WG1080281

Potassium 254 J 37.0 1000 1 03/06/2018 15:52 WG1080281

Zinc U 2.56 25.0 1 03/06/2018 15:52 WG1080281

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc










Dissolved Solids U 2820 10000 1 03/06/2018 20:25 WG1081033








Phosphorus,Total U 35.0 100 1 03/08/2018 16:03 WG1082257




COD U 3000 10000 1 03/05/2018 22:48 WG1080413




Sulfide U 6.50 50.0 1 03/04/2018 16:44 WG1080394




Chloride 65.2 B J P1 51.9 1000 1 03/04/2018 18:21 WG1080373

Fluoride U 9.90 100 1 03/04/2018 18:21 WG1080373

Sulfate 432 J P1 77.4 5000 1 03/04/2018 18:21 WG1080373




TOC (Total Organic Carbon) 193 J 102 1000 1 03/05/2018 21:14 WG1080485




Arsenic 0.849 J 0.250 2.00 1 03/06/2018 15:56 WG1080281

Barium 0.792 J 0.360 5.00 1 03/06/2018 15:56 WG1080281

Cadmium U 0.160 1.00 1 03/06/2018 15:56 WG1080281

Chromium U 0.540 2.00 1 03/06/2018 15:56 WG1080281

Copper U 0.520 5.00 1 03/06/2018 15:56 WG1080281

Iron 41.7 B J 15.0 100 1 03/06/2018 15:56 WG1080281

Lead U 0.240 2.00 1 03/06/2018 15:56 WG1080281

Manganese 23.3 0.250 5.00 1 03/06/2018 15:56 WG1080281

Nickel U 0.350 2.00 1 03/06/2018 15:56 WG1080281

Potassium U 37.0 1000 1 03/06/2018 15:56 WG1080281

Zinc U 2.56 25.0 1 03/06/2018 15:56 WG1080281

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc






LEACHATEC o l l e c t e d d a t e / t i m e : 0 3 / 0 2 / 1 8 1 1 : 4 5








Nitrate-Nitrite U 788 4000 40 03/06/2018 15:45 WG1080683

Sample Narrative:

L974631-11 WG1080683: diluted due to matrix interference




Phosphorus,Total 11500 175 500 5 03/07/2018 09:30 WG1081381




COD 656000 3000 10000 1 03/05/2018 22:49 WG1080413




Sulfide 19200 65.0 500 10 03/04/2018 16:45 WG1080394




Chloride 53900 51.9 1000 1 03/04/2018 19:28 WG1080373

Fluoride 54.3 J 9.90 100 1 03/04/2018 19:28 WG1080373

Sulfate 586000 774 50000 10 03/07/2018 22:42 WG1081809








Arsenic 47.3 0.250 2.00 1 03/07/2018 14:00 WG1081483

Barium 127 0.360 5.00 1 03/07/2018 14:00 WG1081483

Cadmium 0.303 J 0.160 1.00 1 03/07/2018 14:00 WG1081483

Chromium 29.3 0.540 2.00 1 03/07/2018 14:00 WG1081483

Copper 35.0 0.520 5.00 1 03/07/2018 14:00 WG1081483

Iron 4450 15.0 100 1 03/07/2018 14:00 WG1081483

Lead 3.90 B 0.240 2.00 1 03/07/2018 14:00 WG1081483

Manganese 419 0.250 5.00 1 03/07/2018 14:00 WG1081483

Nickel 189 0.350 2.00 1 03/07/2018 14:00 WG1081483

Potassium 221000 37.0 1000 1 03/07/2018 14:00 WG1081483

Zinc 37.4 2.56 25.0 1 03/07/2018 14:00 WG1081483

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1080304G r a v i m e t r i c A n a l y s i s b y M e t h o d 2 5 4 0 C - 2 0 1 1 L 9 7 4 6 3 1 - 0 1 , 0 3 , 0 5 , 0 7 , 0 8

Method Blank (MB)

(MB) R3291265-1 03/06/18 18:36





(OS) L974556-08 03/06/18 18:36 • (DUP) R3291265-4 03/06/18 18:36





(LCS) R3291265-2 03/06/18 18:36 • (LCSD) R3291265-3 03/06/18 18:36




1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1081033G r a v i m e t r i c A n a l y s i s b y M e t h o d 2 5 4 0 C - 2 0 1 1 L 9 7 4 6 3 1 - 0 2 , 0 4 , 0 6 , 0 9 , 1 0 , 1 1

Method Blank (MB)

(MB) R3291260-1 03/06/18 20:25





(OS) L974722-01 03/06/18 20:25 • (DUP) R3291260-4 03/06/18 20:25





(LCS) R3291260-2 03/06/18 20:25 • (LCSD) R3291260-3 03/06/18 20:25




1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc






Method Blank (MB)

(MB) R3290937-1 03/06/18 15:08





(OS) L973883-23 03/06/18 15:14 • (DUP) R3290937-4 03/06/18 15:15



Nitrate-Nitrite ND 0.000 1 0.000 20


(OS) L974631-03 03/06/18 15:40 • (DUP) R3290937-6 03/06/18 15:41



Nitrate-Nitrite 33.0 32.0 1 3.08 J 20


(LCS) R3290937-2 03/06/18 15:09 • (LCSD) R3290937-3 03/06/18 15:10



Nitrate-Nitrite 5000 3980 4060 99.6 101 90.0-110 1.89 20


(OS) L973883-24 03/06/18 15:16 • (MS) R3290937-5 03/06/18 15:17



Nitrate-Nitrite 2500 ND 2320 92.9 1 90.0-110


(OS) L974631-04 03/06/18 15:42 • (MS) R3290937-7 03/06/18 15:43 • (MSD) R3290937-8 03/06/18 15:44



Nitrate-Nitrite 2500 370 2410 2320 81.5 77.8 1 90.0-110 J6 J6 3.94 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1081168W e t C h e m i s t r y b y M e t h o d 3 5 3 . 2 L 9 7 4 6 3 1 - 0 1 , 0 5 , 0 6 , 0 7 , 0 8 , 0 9 , 1 0

Method Blank (MB)

(MB) R3291748-1 03/08/18 16:30





(OS) L972916-01 03/08/18 16:34 • (DUP) R3291748-4 03/08/18 16:35



Nitrate-Nitrite 1130 1130 1 0.355 20


(OS) L974648-01 03/08/18 16:53 • (DUP) R3291748-6 03/08/18 16:54



Nitrate-Nitrite 867 866 1 0.115 20


(LCS) R3291748-2 03/08/18 16:32 • (LCSD) R3291748-3 03/08/18 16:33



Nitrate-Nitrite 5000 4080 4150 102 104 90.0-110 1.92 20


(OS) L974313-01 03/08/18 16:36 • (MS) R3291748-5 03/08/18 16:37



Nitrate-Nitrite 2500 ND 2630 102 1 90.0-110


(OS) L974648-02 03/08/18 16:55 • (MS) R3291748-7 03/08/18 17:00 • (MSD) R3291748-8 03/08/18 17:01



Nitrate-Nitrite 2500 2250 4520 4570 90.6 92.5 1 90.0-110 1.03 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc






Method Blank (MB)

(MB) R3291104-1 03/07/18 09:03



Phosphorus,Total U 35.0 100


(OS) L974304-01 03/07/18 09:08 • (DUP) R3291104-4 03/07/18 09:10



Phosphorus,Total 171 152 1 11.8 20


(OS) L975033-01 03/07/18 09:26 • (DUP) R3291104-7 03/07/18 09:27





(LCS) R3291104-2 03/07/18 09:04 • (LCSD) R3291104-3 03/07/18 09:06



Phosphorus,Total 2000 1870 1940 93.5 97.0 90.0-110 3.67 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1082257W e t C h e m i s t r y b y M e t h o d 3 6 5 . 4 L 9 7 4 6 3 1 - 0 1 , 0 5 , 0 6 , 0 7 , 0 8 , 0 9 , 1 0

Method Blank (MB)

(MB) R3291699-1 03/08/18 15:31



Phosphorus,Total U 35.0 100


(OS) L974419-01 03/08/18 15:39 • (DUP) R3291699-6 03/08/18 15:40





(OS) L974419-02 03/08/18 15:57 • (DUP) R3291699-7 03/08/18 15:58





(LCS) R3291699-2 03/08/18 15:33 • (LCSD) R3291699-3 03/08/18 15:34



Phosphorus,Total 2000 1940 2020 97.0 101 90.0-110 4.04 20


(OS) L974368-03 03/08/18 15:35 • (MS) R3291699-4 03/08/18 15:37 • (MSD) R3291699-5 03/08/18 15:38



Phosphorus,Total 2500 ND 1970 1800 78.8 72.0 1 90.0-110 J6 J6 9.02 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1079569W e t C h e m i s t r y b y M e t h o d 4 1 0 . 4 L 9 7 4 6 3 1 - 0 1 , 0 2 , 0 3 , 0 4 , 0 5

Method Blank (MB)

(MB) R3290391-1 03/04/18 15:37



COD U 3000 10000


(OS) L973782-01 03/04/18 15:38 • (DUP) R3290391-4 03/04/18 15:38



COD 78000 79200 1 1.60 20


(OS) L974722-01 03/04/18 15:43 • (DUP) R3290391-7 03/04/18 15:43



COD 45200 51000 1 12.1 20


(LCS) R3290391-2 03/04/18 15:37 • (LCSD) R3290391-3 03/04/18 15:37



COD 242000 245000 242000 101 100 90.0-110 0.850 20


(OS) L974086-06 03/04/18 15:41 • (MS) R3290391-5 03/04/18 15:41 • (MSD) R3290391-6 03/04/18 15:41



COD 400000 11500 416000 418000 101 102 1 80.0-120 0.427 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1080413W e t C h e m i s t r y b y M e t h o d 4 1 0 . 4 L 9 7 4 6 3 1 - 0 6 , 0 7 , 0 8 , 0 9 , 1 0 , 1 1

Method Blank (MB)

(MB) R3290686-1 03/05/18 22:45



COD U 3000 10000


(OS) L974353-01 03/05/18 22:45 • (DUP) R3290686-4 03/05/18 22:46



COD 99800 105000 1 4.79 20


(OS) L974802-06 03/05/18 22:52 • (DUP) R3290686-7 03/05/18 22:52



COD ND 9700 1 0.000 20


(LCS) R3290686-2 03/05/18 22:45 • (LCSD) R3290686-3 03/05/18 22:45



COD 242000 241000 239000 99.7 98.9 90.0-110 0.737 20


(OS) L974631-10 03/05/18 22:48 • (MS) R3290686-5 03/05/18 22:48 • (MSD) R3290686-6 03/05/18 22:48



COD 400000 U 395000 398000 98.7 99.4 1 80.0-120 0.765 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1080394W e t C h e m i s t r y b y M e t h o d 4 5 0 0 S 2 D - 2 0 1 1 L 9 7 4 6 3 1 - 0 1 , 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7 , 0 8 , 0 9 , 1 0 , 1 1

Method Blank (MB)

(MB) R3290401-1 03/04/18 16:32



Sulfide U 6.50 50.0


(OS) L974503-06 03/04/18 16:35 • (DUP) R3290401-4 03/04/18 16:36



Sulfide ND 0.000 1 0.000 20


(OS) L974631-11 03/04/18 16:45 • (DUP) R3290401-7 03/04/18 16:45



Sulfide 19200 19200 10 0.104 20


(LCS) R3290401-2 03/04/18 16:33 • (LCSD) R3290401-3 03/04/18 16:33



Sulfide 500 502 497 100 99.4 85.0-115 1.00 20


(OS) L974631-01 03/04/18 16:38 • (MS) R3290401-5 03/04/18 16:39 • (MSD) R3290401-6 03/04/18 16:40



Sulfide 1000 U 818 826 81.8 82.6 1 80.0-120 0.973 20

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1080350W e t C h e m i s t r y b y M e t h o d 9 0 5 6 A L 9 7 4 6 3 1 - 0 1

Method Blank (MB)

(MB) R3290645-1 03/04/18 07:41



Chloride U 51.9 1000

Fluoride U 9.90 100

Sulfate U 77.4 5000


(OS) L974056-01 03/04/18 11:21 • (DUP) R3290645-4 03/04/18 11:33



Chloride 110000 112000 5 1.74 15


(OS) L974241-04 03/04/18 13:37 • (DUP) R3290645-6 03/04/18 13:50



Sulfate 130000 132000 5 1.58 15


(LCS) R3290645-2 03/04/18 07:54 • (LCSD) R3290645-3 03/04/18 08:06



Chloride 40000 40100 40000 100 100 80.0-120 0.169 15

Fluoride 8000 8100 8070 101 101 80.0-120 0.281 15

Sulfate 40000 40600 40400 101 101 80.0-120 0.492 15


(OS) L974056-01 03/04/18 11:08 • (MS) R3290645-5 03/04/18 11:46



Fluoride 5000 390 5620 105 1 80.0-120

Sulfate 50000 14600 64000 98.9 1 80.0-120

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc







(OS) L974241-04 03/04/18 13:25 • (MS) R3290645-7 03/04/18 14:02 • (MSD) R3290645-8 03/04/18 14:15



Chloride 50000 24000 75500 75500 103 103 1 80.0-120 0.00808 15

Fluoride 5000 635 5720 5990 102 107 1 80.0-120 4.49 15

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1080373W e t C h e m i s t r y b y M e t h o d 9 0 5 6 A L 9 7 4 6 3 1 - 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7 , 0 8 , 0 9 , 1 0 , 1 1

Method Blank (MB)

(MB) R3290643-1 03/04/18 07:54



Chloride 74.7 J 51.9 1000

Fluoride U 9.90 100

Sulfate U 77.4 5000


(OS) L974631-02 03/04/18 15:26 • (DUP) R3290643-4 03/04/18 15:40



Chloride 33400 33500 1 0.256 15

Fluoride 609 602 1 1.21 15

Sulfate 16900 16800 1 0.483 15


(OS) L974631-10 03/04/18 18:21 • (DUP) R3290643-7 03/04/18 18:34



Fluoride U 0.000 1 0.000 15


(LCS) R3290643-2 03/04/18 08:08 • (LCSD) R3290643-3 03/04/18 08:21



Chloride 40000 39900 39900 99.8 99.6 80.0-120 0.173 15

Fluoride 8000 8050 8030 101 100 80.0-120 0.190 15

Sulfate 40000 40600 40500 101 101 80.0-120 0.274 15


(OS) L974631-02 03/04/18 15:26 • (MS) R3290643-5 03/04/18 15:53 • (MSD) R3290643-6 03/04/18 16:33



Chloride 50000 33400 84900 85000 103 103 1 80.0-120 0.0436 15

Fluoride 5000 609 5610 6000 100 108 1 80.0-120 6.63 15

Sulfate 50000 16900 64300 68300 94.7 103 1 80.0-120 6.03 15

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1080373W e t C h e m i s t r y b y M e t h o d 9 0 5 6 A L 9 7 4 6 3 1 - 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7 , 0 8 , 0 9 , 1 0 , 1 1


(OS) L974631-10 03/04/18 18:21 • (MS) R3290643-8 03/04/18 19:14



Fluoride 5000 U 5490 110 1 80.0-120

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc






Method Blank (MB)

(MB) R3290774-1 03/05/18 18:57



Sulfate U 77.4 5000


(OS) L974700-01 03/05/18 22:32 • (DUP) R3290774-4 03/05/18 23:13



Sulfate 6310 6310 1 0.0317 15


(LCS) R3290774-2 03/05/18 19:10 • (LCSD) R3290774-3 03/05/18 19:24



Sulfate 40000 40300 40400 101 101 80.0-120 0.196 15


(OS) L974700-01 03/05/18 22:32 • (MS) R3290774-5 03/05/18 23:26



Sulfate 50000 6310 56500 100 1 80.0-120

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc






Method Blank (MB)

(MB) R3291381-1 03/07/18 21:25



Sulfate U 77.4 5000


(OS) L975141-01 03/07/18 23:28 • (DUP) R3291381-4 03/07/18 23:44



Sulfate 30300 30300 1 0.0710 15


(LCS) R3291381-2 03/07/18 21:40 • (LCSD) R3291381-3 03/07/18 21:56



Sulfate 40000 39600 39700 98.9 99.3 80.0-120 0.441 15


(OS) L975141-01 03/07/18 23:28 • (MS) R3291381-5 03/07/18 23:59



Sulfate 50000 30300 79700 98.8 1 80.0-120

1

Cp

2

Tc

3

Ss

4

Cn

5

Sr

6

Qc

7

Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1080485W e t C h e m i s t r y b y M e t h o d 9 0 6 0 A L 9 7 4 6 3 1 - 0 1 , 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7 , 0 8 , 0 9 , 1 0 , 1 1

Method Blank (MB)

(MB) R3290748-1 03/05/18 14:15



TOC (Total Organic Carbon) U 102 1000


(OS) L974350-06 03/05/18 16:06 • (DUP) R3290748-3 03/05/18 16:18





(OS) L974631-06 03/05/18 19:15 • (DUP) R3290748-5 03/05/18 19:27





(LCS) R3290748-2 03/05/18 15:34 • (LCSD) R3290748-4 03/05/18 17:37



TOC (Total Organic Carbon) 75000 78600 78500 105 105 85.0-115 0.0764 20


(OS) L974722-01 03/05/18 22:09 • (MS) R3290748-6 03/05/18 22:30 • (MSD) R3290748-7 03/05/18 22:58



TOC (Total Organic Carbon) 50000 15600 67400 67400 104 104 1 80.0-120 0.0742 20

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Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1080281M e t a l s ( I C P M S ) b y M e t h o d 6 0 2 0 L 9 7 4 6 3 1 - 0 1 , 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7 , 0 8 , 0 9 , 1 0

Method Blank (MB)

(MB) R3290926-1 03/06/18 14:27




Barium U 0.360 5.00


Chromium U 0.540 2.00

Copper U 0.520 5.00

Iron 21.5 J 15.0 100

Lead 0.249 J 0.240 2.00


Nickel U 0.350 2.00

Potassium U 37.0 1000

Zinc U 2.56 25.0


(LCS) R3290926-2 03/06/18 14:31 • (LCSD) R3290926-3 03/06/18 14:34



Arsenic 50.0 47.9 48.8 95.7 97.5 80.0-120 1.88 20

Barium 50.0 46.3 49.1 92.7 98.2 80.0-120 5.85 20

Cadmium 50.0 49.5 50.8 99.1 102 80.0-120 2.50 20

Chromium 50.0 49.7 51.3 99.5 103 80.0-120 3.05 20

Copper 50.0 50.0 51.6 99.9 103 80.0-120 3.29 20

Iron 5000 4990 5140 99.8 103 80.0-120 3.09 20

Lead 50.0 49.4 50.7 98.8 101 80.0-120 2.53 20

Manganese 50.0 48.7 49.7 97.3 99.4 80.0-120 2.06 20

Nickel 50.0 50.1 51.9 100 104 80.0-120 3.57 20

Potassium 5000 4820 4880 96.3 97.5 80.0-120 1.25 20

Zinc 50.0 50.5 51.1 101 102 80.0-120 1.08 20


(OS) L974631-01 03/06/18 14:38 • (MS) R3290926-5 03/06/18 14:46 • (MSD) R3290926-6 03/06/18 14:50



Arsenic 50.0 16.1 65.7 66.2 99.1 100 1 75.0-125 0.736 20

Barium 50.0 265 309 315 88.2 100 1 75.0-125 1.94 20

Cadmium 50.0 0.162 50.8 50.9 101 101 1 75.0-125 0.157 20

Chromium 50.0 U 51.1 50.3 102 101 1 75.0-125 1.65 20

Copper 50.0 1.48 49.6 50.7 96.3 98.5 1 75.0-125 2.19 20

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Cp

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Tc

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Ss

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Cn

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Sr

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Qc

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Gl

8

Al

9

Sc





ONE LAB. NATIONWIDE.QUALITY CONTROL SUMMARYWG1080281M e t a l s ( I C P M S ) b y M e t h o d 6 0 2 0 L 9 7 4 6 3 1 - 0 1 , 0 2 , 0 3 , 0 4 , 0 5 , 0 6 , 0 7 , 0 8 , 0 9 , 1 0


(OS) L974631-01 03/06/18 14:38 • (MS) R3290926-5 03/06/18 14:46 • (MSD) R3290926-6 03/06/18 14:50



Potassium 5000 2180 7100 7050 98.4 97.4 1 75.0-125 0.665 20

Iron 5000 8000 13100 13000 103 100 1 75.0-125 0.858 20

Lead 50.0 0.515 50.3 51.1 99.6 101 1 75.0-125 1.58 20

Manganese 50.0 642 689 682 93.8 80.3 1 75.0-125 0.985 20

Nickel 50.0 2.11 52.3 53.5 100 103 1 75.0-125 2.37 20

Zinc 50.0 U 49.1 51.2 98.3 102 1 75.0-125 4.12 20

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Method Blank (MB)

(MB) R3291242-1 03/07/18 13:33




Barium U 0.360 5.00


Chromium 0.576 J 0.540 2.00

Copper 3.17 J 0.520 5.00

Iron U 15.0 100

Lead 0.784 J 0.240 2.00

Manganese 0.478 J 0.250 5.00

Nickel U 0.350 2.00

Potassium U 37.0 1000

Zinc U 2.56 25.0


(LCS) R3291242-2 03/07/18 13:36 • (LCSD) R3291242-3 03/07/18 13:41



Arsenic 50.0 52.7 53.1 105 106 80.0-120 0.795 20

Barium 50.0 48.4 48.9 96.9 97.8 80.0-120 0.938 20

Cadmium 50.0 54.5 54.6 109 109 80.0-120 0.0636 20

Chromium 50.0 54.2 54.2 108 108 80.0-120 0.0696 20

Copper 50.0 51.1 51.8 102 104 80.0-120 1.36 20

Iron 5000 5540 5510 111 110 80.0-120 0.565 20

Lead 50.0 54.0 54.3 108 109 80.0-120 0.651 20

Manganese 50.0 52.2 51.9 104 104 80.0-120 0.612 20

Nickel 50.0 56.1 56.7 112 113 80.0-120 1.02 20

Potassium 5000 5370 5380 107 108 80.0-120 0.208 20

Zinc 50.0 54.1 54.4 108 109 80.0-120 0.516 20


(OS) L975238-01 03/07/18 13:45 • (MS) R3291242-5 03/07/18 13:52 • (MSD) R3291242-6 03/07/18 13:56



Arsenic 50.0 ND 55.0 55.1 108 108 1 75.0-125 0.0796 20

Barium 50.0 ND 49.4 49.9 98.8 99.9 1 75.0-125 1.08 20

Cadmium 50.0 ND 54.9 54.8 110 110 1 75.0-125 0.137 20

Chromium 50.0 ND 55.4 54.6 111 109 1 75.0-125 1.44 20

Copper 50.0 ND 51.8 52.4 102 103 1 75.0-125 1.21 20

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(OS) L975238-01 03/07/18 13:45 • (MS) R3291242-5 03/07/18 13:52 • (MSD) R3291242-6 03/07/18 13:56



Potassium 5000 ND 5360 5450 107 109 1 75.0-125 1.70 20

Iron 5000 144 5700 5720 111 112 1 75.0-125 0.332 20

Lead 50.0 ND 54.3 55.2 108 110 1 75.0-125 1.59 20

Manganese 50.0 ND 53.7 53.8 105 105 1 75.0-125 0.0588 20

Nickel 50.0 ND 56.9 57.2 114 114 1 75.0-125 0.481 20

Zinc 50.0 ND 55.3 56.0 111 112 1 75.0-125 1.30 20

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Cp

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ND Not detected at the Reporting Limit (or MDL where applicable).


Rec. Recovery.





DilutionIf the sample matrix contains an interfering material, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor.




Result










B The same analyte is found in the associated blank.


J6 The sample matrix interfered with the ability to make any accurate determination; spike value is low.

O1 The analyte failed the method required serial dilution test and/or subsequent post-spike criteria. These failures indicate matrix interference.

P1 RPD value not applicable for sample concentrations less than 5 times the reporting limit.

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A2LA – ISO 17025 ⁵ 1461.02 DOD 1461.01

Canada 1461.01 USDA P330-15-00234





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