maselli beverage analyzer ib05. ib05 beverage analyser uc04 carbonation analyser ur21 brix / diet...
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MaselliMaselli Beverage Analyzer IB05Beverage Analyzer IB05
IB05 Beverage Analyser
UC04 Carbonation analyser
UR21 Brix / Diet analyser (refractive index based technology)
Sampling pump
ControlPanel
ElectricalConnectionsInput / Output
Standard Parameters:
- Brix- Diet- CO2
Optional Parameters:- Sugar inversion- Alcohol- Oxygen
Maselli OEM Configuration
UC04 Carbonation analyser
MR03Control Panel
End Users OEMs
UR21 Brix / Diet analyser (refractive index based technology)
Approved by: Krones, KHS, Sidel, Miteco
Maselli UC05Maselli UC05 Carbometric TheoryCarbometric Theory
Gas dissolved in liquid
THE QUANTITY OF THE GAS DISSOLVED IN A LIQUID IS
GENERALLY INFLUENCED BY DIFFERENT FACTORS
• liquid nature• gas nature• PRESSURE• TEMPERATURE
The system is made of 2 components in 2 phases so
2 variables (p, T) completely define its status
Henry’s Law
For gas dissolved in liquid, without any reaction
at temperature T = k PGASxGAS xGAS: gas molar fraction
PGAS: gas partial pressure
k: constant
• At equilibrium status, where free liquid volume is gas saturated, reached after mechanical stressing of liquid, pressure p is PGAS
• Measuring temperature T allows to determine gas content
Gas content tables
psi 0 1 2 3 4 5 6 7 8 9 10 11kg/cm² 0,00 0,07 0,14 0,21 0,28 0,35 0,42 0,49 0,56 0,63 0,70 0,77
°F °C v/v32 0,0 1,61 1,71 1,82 1,93 2,04 2,14 2,25 2,36 2,47 2,57 2,68 2,7933 0,6 1,58 1,68 1,79 1,89 2,00 2,10 2,21 2,31 2,42 2,53 2,63 2,7434 1,1 1,55 1,65 1,75 1,86 1,96 2,07 2,17 2,27 2,38 2,48 2,58 2,6935 1,7 1,52 1,62 1,72 1,82 1,93 2,03 2,13 2,23 2,33 2,43 2,53 2,6436 2,2 1,49 1,59 1,69 1,79 1,89 1,99 2,09 2,19 2,29 2,39 2,49 2,5937 2,8 1,47 1,56 1,66 1,76 1,86 1,96 2,05 2,15 2,25 2,35 2,44 2,5438 3,3 1,44 1,54 1,63 1,73 1,82 1,92 2,02 2,11 2,21 2,31 2,40 2,5039 3,9 1,42 1,51 1,60 1,70 1,79 1,89 1,98 2,08 2,17 2,26 2,36 2,4540 4,4 1,39 1,48 1,58 1,67 1,76 1,86 1,95 2,04 2,13 2,23 2,32 2,4141 5,0 1,37 1,46 1,55 1,64 1,73 1,82 1,91 2,01 2,10 2,19 2,28 2,3742 5,6 1,35 1,43 1,52 1,61 1,70 1,79 1,88 1,97 2,06 2,15 2,24 2,3343 6,1 1,32 1,41 1,50 1,59 1,68 1,76 1,85 1,94 2,03 2,12 2,20 2,2944 6,7 1,30 1,39 1,47 1,56 1,65 1,73 1,82 1,91 1,99 2,08 2,17 2,2545 7,2 1,28 1,37 1,45 1,54 1,62 1,71 1,79 1,88 1,96 2,05 2,13 2,2246 7,8 1,26 1,34 1,43 1,51 1,59 1,68 1,76 1,85 1,93 2,01 2,10 2,1847 8,3 1,24 1,32 1,40 1,49 1,57 1,65 1,73 1,82 1,90 1,98 2,06 2,1548 8,9 1,22 1,30 1,38 1,46 1,54 1,63 1,71 1,79 1,87 1,95 2,03 2,1149 9,4 1,20 1,28 1,36 1,44 1,52 1,60 1,68 1,76 1,84 1,92 2,00 2,0850 10,0 1,18 1,26 1,34 1,42 1,50 1,58 1,65 1,73 1,81 1,89 1,97 2,05
CO2 in deaerated beverage
Experimentally the quantity of CO2 in the deaerated beverages
depends on equilibrium PRESSURE and TEMPERATURE as follows:
G z z t z t z t z t z t p z z t z t zp
t ( )( )( )0 1 2
23
34
45
56 7 8
291
where for a fixed beverage:
G quantity of CO [gr./l]
z z z z z z z z z z
p = equilibrium pressure
t = equilibrium temperature
2
0 1 2 3 4 5 6 7 8 9
, , , , , , , , , are constants
• Product sampling
• Mechanical stressing to reach the equilibrium condition
• Temperature and pressure detection
• Data eleboration and calculation for CO2 content
CO2 measuring method
UC05 Construction
Pt1000
Magnetic Elements
Pressure sensor
Main Motor
Cap valves
By Pass system
Stirring Element
Measuring Cell
Vacuum Membrane
UC05 Analysis steps
Sampling Creation of extravolume / stirring
UC05 Analysis steps
Pressure, Temperaturedata acquisition
Washing
UC05 Mechanical diagram of the cycle
DIAGRAM OF PRESSURE IN THE MEASURING CELL
DIAGRAM OF DIAPHRAGM POSITION
DIAGRAM OF VALVES POSITION
PRESSURE AND TEMPERATURE DATA ACQUISITION
STIRRING SYSTEM START
STIRRING SYSTEM STOP
TOTALLY OPENED VALVES
TOTALLY CLOSED VALVES
POSITION IN WHICH THE INDUCTIVE SENSOR SIGNAL STARTS THE CYCLE AND THE STIRRING SYSTEM.
UC05 Carbonation Analyzer
Test of stirring efficiencyUC04 pressure data
-0.3
2.7
5.7
1 11 21 31 41 51 61 71 81 91 101 111 121 131
sample number
Kg
/cm
2
3s of Stirring time before measuring pressure7s of Stirring time before measuring pressure
No Stirring before measuring pressure
Pipe Line pressure
Stirring time
Line off
Line in on
Transient time
Maselli IB05Maselli IB05 Diet TheoryDiet Theory
Focus on Diet Soft drinks
WaterDiet Syrup:- aspartame- phosphoric acid - caramel- caffeine- water- etc.
DIET COKE
Laboratory Analyzer(spectrophotometer):- phosphoric acid of the Diet Coke with spectrophotometer (the control established by measuring one of the components)
Maselli IB05 Inline:- nD of the Diet Coke with refractometer (the control is established by measuring everything that is not water)
Diet Analysis Laboratory - Line
The measurement unit in the laboratory is different from the measure unit in the line
A recipe with a specific conversion factor has to be used .
Maselli IB05Traditional lab methods
Diet Control
• The IB05 measures the refractometric degree • The IB05 has the capatability to control ‘what is not
water’ of a diet beverage correlating the results with existing lab methods
• The capatability has been demostrated performing several experiments with different products
How good is the correlation???
30 measurements: one sample each 2’
Valve change
Maselli IB05 Correlation with the Lab
Data from CCE Wilsonville, USA (QA Manager Will Looney)
Diet soft drinks readings: Maselli vs Lab
Our next step is to move this technology from the line to the laboratory!
Maselli Diet from the Line to the Lab
DR10
Easy DietLab Monitor
Maselli Diet in the lab
Maselli Diet in the line
DIET COKE
0.248
0.254
0.259
0.263
0.269
0.274y = 383.2x
R2 = 0.9992
94
95
96
97
98
99
100
101
102
103
104
105
106
0.2
20
0.2
30
0.2
40
0.2
50
0.2
60
0.2
70
0.2
80
0.2
90
0.3
00
0.3
10
0.3
20
0.3
30
0.3
40
0.3
50
0.3
60
0.3
70
0.3
80
REFRACTOMETRIC BRIX
% A
SS
AY
BY
WE
IGH
T
Refractometric Brix and dilution
COKE ZERO
0.2519
0.2557
0.2613
0.2662
0.2714
0.2779y = 379.3x
R2 = 0.9953
94
95
96
97
98
99
100
101
102
103
104
105
106
0.2
20
0.2
30
0.2
40
0.2
50
0.2
60
0.2
70
0.2
80
0.2
90
0.3
00
0.3
10
0.3
20
0.3
30
0.3
40
0.3
50
0.3
60
0.3
70
0.3
80
REFRACTOMETRIC BRIX
% A
SS
AY
BY
WE
IGH
T
Refractometric Brix and dilution
DT CAFFEINE FREE
0.2293
0.2354
0.2391
0.2438
0.2486
0.2536y = 414.95x
R2 = 0.994
94
95
96
97
98
99
100
101
102
103
104
105
106
0.2
20
0.2
30
0.2
40
0.2
50
0.2
60
0.2
70
0.2
80
0.2
90
0.3
00
0.3
10
0.3
20
0.3
30
0.3
40
0.3
50
0.3
60
0.3
70
0.3
80
REFRACTOMETRIC BRIX
% A
SS
AY
BY
WE
IGH
T
Refractometric Brix and dilution
DIET SPRITE
0.287
0.295
0.301
0.308
0.314
0.318y = 329.28x
R2 = 0.9986
94
95
96
97
98
99
100
101
102
103
104
105
106
0.2
20
0.2
30
0.2
40
0.2
50
0.2
60
0.2
70
0.2
80
0.2
90
0.3
00
0.3
10
0.3
20
0.3
30
0.3
40
0.3
50
0.3
60
0.3
70
0.3
80
REFRACTOMETRIC BRIX
% A
SS
AY
BY
WE
IGH
T
Refractometric Brix and dilution
CHERRY ZERO
0.2458
0.2509
0.2579
0.2638
0.2663
0.2718y = 385.93x
R2 = 0.9972
94
95
96
97
98
99
100
101
102
103
104
105
106
0.2
20
0.2
30
0.2
40
0.2
50
0.2
60
0.2
70
0.2
80
0.2
90
0.3
00
0.3
10
0.3
20
0.3
30
0.3
40
0.3
50
0.3
60
0.3
70
0.3
80
REFRACTOMETRIC BRIX
% A
SS
AY
BY
WE
IGH
T
Refractometric Brix and dilution
• Around 99.7 % of a diet beverage is water• Selective measuraments control only a fraction of what is not
water• IB05 and DR10 control everything is not water • The IB05 measurement is equivalent to the Dr10 measurement• IB05 and DR10 have the capatability to follow diluition • A linear correlation between refractometric brix and diluition by
weight has been proven for all the different beverage• In order to match DR10 and IB05 to not a selective
measurements a specific coefficient has to be used.
Conclusion
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
0.0
00
0.0
10
0.0
20
0.0
30
0.0
40
0.0
50
0.0
60
0.0
70
0.0
80
0.0
90
0.1
00
0.1
10
0.1
20
0.1
30
0.1
40
0.1
50
0.1
60
0.1
70
0.1
80
0.1
90
0.2
00
0.2
10
0.2
20
0.2
30
0.2
40
0.2
50
0.2
60
0.2
70
0.2
80
0.2
90
0.3
00
0.3
10
0.3
20
0.3
30
0.3
40
0.3
50
0.3
60
0.3
70
0.3
80
REFRACTOMETRIC BRIX
% A
SS
AY
BY
WE
IGH
T
DIET COKE COKE ZERO DT CAFFEINE FREE FRESCA CHERRY ZERO DIET SPRITE
282
330
385
415
IB05/DR10 and traditional methods
Maselli IB05Maselli IB05 InstallationInstallation
Maselli Diet Flavor Changeover
No, during changeover when the valveto the filler is still closed,the Maselli pump would circulate always the same product.
YES, during changeover when the valveto the filler is still closed,the Maselli pump would circulate more product being the samplemore representative.