呂良賜 博士研究室 research interests: 1. green technology 2. novel dye for dye-sensitized...
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呂良賜 博士研究室 Research Interests:1. Green Technology
2. Novel Dye for Dye-sensitized Solar Cell
3. Synthetic Chemistry
4. Organometallic Chemistry
5. Fuel Cell (PEM membrane); Fluoropolymer
6. Material Science
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Vacuum line
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Current Research Projects
1. Novel Dye w/ Fluorous Polytail (Solar Cell)
2. Catalysis (Organometallics)
3. Fuel Cells
4. X-Ray Crystal Growing (Catalysts)
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Current Research Projects
5. Green Chemistry Fluorous Biphasic System (FBS) Aerobic Alcohol Oxidation under FBS ATRP (Recoverable)
6. Lithium Battery Polymeric Electrolyte
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1. Lithium Battery Electrolyte
See the next chart for the procedure
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CF2I I6
+Na2S2O4 / NaHCO3
CF2NaO3S SO3Na6
+ Cl2
CF2ClO2S SO2Cl6
CF2FO2S SO2F6
metal fluoride+
+NH3
CF2H2NO2S SO2NH26
+ Li
CF2LiHNO2S SO2NHLi6
(A)
(B)
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2. Liquid Crystal Materials
C5H11
C5H11
O
F F
F
F
F
1
F
F
F
2
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Novel Fluorous Dye For DSSC Novel fluorous ponytailed Dye for Solar
Cell
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CV and UV/VIS Studies of Pt-based DSSC
-0.8 -1.0 -1.2 -1.4 -1.6 -1.8 -2.0 -2.2-4.0x10-5
-2.0x10-5
0.0
2.0x10-5
4.0x10-5
6.0x10-5
8.0x10-5
Cu
rre
nt (
A)
Potential (V)
Pt complex 2a Pt complex 2b
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Fuel Cell (Proton Exchange membrane)
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Green Chemistry
1. FBS:Fluorous biphasic system
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2. Aerobic Alcohol Oxidation under FBS
biphasic monophasic biphasic
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3. ATRP (Cu recoverable)H2C C
CH3
C
OOCH3
Cu(I)/ Bipy
toluene
H2C C
CH3
C
OOCH3
BrCn
MMA mw 100bp:100 oC
H3C
CH3
COC2H5
O
反應完成聚合反應
進行
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X-Ray
[4,4'-bis(C3F7CH2OCH2)-2,2'-bpy]
[4,4'-bis(HC4F8CH2OCH2)-2,2'-bpy]
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Departmental Seminar on May 18 Host Speaker: Prof. Thrasher
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Attending International Meeting in Yokohama, Japan (2007)
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Photo with Nobel Prize Winner, Prof. Grubbs
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Publication [A. 期刊論文 ( 以北科大發表之英文期刊 ; >10
papers)]
1. Norman Lu,* His-Chun Hou, Chien-Ting Lin, Yuh-Sheng Wen, and Ling-Kang Liu, “Synthesis, Structure and Electrochemical Property of Novel (2,2′-Bipyridine)-Metal (M = Pt, Pd) Dichloride with 4,4′-Bis(fluorous-ponytail) on Bipyridine” Eur. J. Inorg. Chem. 2009. (to be submitted) (NSC 96-2113-M-027-004-MY2)
2. Y. Akiyama, S. Fujita, X. Meng, Y.-C. Chen, N. Lu,b,* F. Zhaoc and M. Arai a,*, “Carbon Dioxide Pressure Tunable Heterogeneous and Homogeneous Media for Heck and Sonogashira Coupling Reactions Using Fluorinated Palladium Complex Catalysts” J. Organomet. Chem. 2009 (submitted) (NSC 96-2113-M-027-004-MY2)
3. Norman Lu,* and Ling-Kang Liu, J.C. Jiang “The Intramolecular Blue-shifting C-H···F-C Hydrogen Bond in Solid State”, CrystEngComm 2009 (submitted) (NSC 96-2113-M-027-004-MY2)
4. Norman Lu,a,* Yi-Chuan Chen,a Wei-Shung Chen, Ter-Lin Chen, Sy-Juen Wu “Copper-free Sonogashira Reaction under Thermomorphic Mode”, 2009, J. Organomet. Chem. (on-line release 2008, 10, 31), 694 (2), 278-284 (NSC 96-2113-M-027-004-MY2)(SCI:2.168, 12/43)
5. Norman Lu,* Tsung-Chi Chen and Ching-Lung Lin, “New Fluorous Bipyridine Ligands for Cu-catalyzed Atom Transfer Radical Polymerization of Methyl Methacrylate in the Thermomorphic Mode” J. of Applied Polymer Science, 2008, 110 (5), 2531-3303; (NSC 96-2113-M-027-004-MY2)(SCI: 1.008, 39/74)
6. Norman Lu,*, Shih-Chieh Chen, Tsung-Chi Chen and Ling-Kang Liu, “Pd-catalyzed Heck Reaction under Thermomorphic Mode” Tetrahedron Letters 2008, 49, 371-375; (NSC 96-2113-M-027-004-MY2), (SCI:2.615, 20/56)
7. Norman Lu,* Yan-Chou Lin, "High Fluorine Content Bis(fluoro-ponytailed) Bipyridine Palladium Complexes as Catalyst for Mizoroki-Heck Reactions under Fluorous Biphasic Catalysis Conditions" J. Chin. Chem. Soc. 2008, 55(1), 89-96; (NSC 95-2113-M-027-002), (SCI: 0.643, 91/128)
8. Norman Lu,* Yan-Chou Lin, “Efficient, Recoverable, Copper-catalyzed Aerobic Oxidation of Alcohols under FBS and Thermomorphic Mode” Tetrahedron Lett 2007, 48, 8823-8828; (NSC 95-2113-M-027-002) (96-2113-M-027-004-MY2) (SCI: 2.615, 20/56)
9. Norman Lu,* Jeng-Yung Chen, Chi-Wen Fan, Yan-Chou Lin, Yuh-Sheng Wen, and Ling-Kang Liu; “Synthesis, Structure and Reactivity of Novel Palladiumdichloride-2,2′-bipyridine with 4,4’-Bis(fluorous-ponytail)” Polyhedron 2007, 26, 3045-3053; (NSC 93-2113-M-027-005) (SCI:1.756, 10/25)
10. Norman Lu,* Yu-Mei Ho, Chi-Wen Fan, Fu-Ming Wang and Jyh-Tsung Lee,* “A Simple Method for Synthesizing Polymeric Lithium Salts Exhibiting Relatively High Cationic Transference Number for Solid Polymer Electrolytes” Solid State Ionics 2007, 178, 347-353; (NSC 93-2113-M-027-005) & (NSC 94-2113-M-027-003)(SCI:2.012, 12/61)
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(Continued) 11. Norman Lu,* Yan-Chou Lin, Jeng-Yung Chen, Chi-Wen Fan, and Ling-Kang Liu;“ New Bis(fluoro-ponytailed)
Bipyridine Ligands for Pd-catalyzed Heck Reactions under Fluorous Biphasic Catalysis Condition” Tetrahedron 2007, 63, 2019-2023, NSC 94-2113-M-027-003, (SCI:2.869, 14/56)
12. Norman Lu(呂良賜 ),* Yan-Chou Lin(林原週 ), Jeng-Yung Chen(陳政湧 ), Chi-Wen Fan (范己文 ), Yuh-Sheng Wen(聞昱生 ), and Ling-Kang Liu(劉陵 崗 )* “(2,2’-bipyridine)palladium dichloride Derivatives as Recyclable Catalysts in Heck Reactions” J. Chin. Chem. Soc. 2006, 53, 1517-1521. NSC 94-2113-M-027-003,
(SCI: 0.643, 91/128) 13. Norman Lu,* H. P. Sampath Kumar, James L. Fye, Jian Sun Blanks, Joseph S. Thrasher, * Helge Willner, and Heinz
Oberhammer” The Initial Synthesis of the Long Sought After Compound Pentafluoronitrosulfane, SF5NO2” Angew. Chem. Int. Ed. 2006, 45, 938; rated as very important paper. NSC 94-2113-M-027-003, (SCI:10.031, 4/128)
B. Using other affiliation to publish 14. Norman Lu,* Joseph S. Thrasher, Stefan von Ahsen, Helge Willner,* Drahomir Hnyk, and Heinz
Oberhammer*“Pentafluoronitrosulfane, SF5NO2” Inorganic Chem. 2006, 45, 1783 (SCI:4.123, 4/43)
15. Howell*, J. L., Lu, N, Friesen, C. M. “New Derivatives of poly-Hexafluoropropylene Oxide from the Corresponding Alcohol”; J. Fluorine Chem. 2005.126, 281-288 (SCI: 1.513, 20/43)
16. Howell*, J. L., Lu, N.; Perez, E. W.; Howell, J. L.; Friesen C. M.; Novak, I.; Waterfeld, A.; Thrasher, J. S., “The Preparation of Primary Poly-Hexafluoropropylene Oxide Halides (Poly-HFPO-CF2X where X = I, Br, Cl and F)” J. Fluorine Chem. 2004.125,1513-1518 (SCI: 1.513)
17. DesMarteau, D. D., Lu, N., Zimmerman* P., Miller* D.; “Polymers Based on a Novel 1,3-perfluorodioxole for Use as a Soft Polymer Pellicle in 157nm Lithography” J. of Photopolymer Science and Technology, 2004,vol. 17, 651-654. (SCI: 0.835 ; 43/74)
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International Meeting 1. “Fluorous Catalysis of Pd-catalyzed Heck Reaction under Thermomorphic Condition
without Fluorous Solvents: Facile Liquid/Solid Pd Catalyst Separation at RT" The 2nd International Symposium on Fluorous Technologies (ISoFT07), Yokohama, Japan, July 29-Aug.1, 2007. (oral); (NSC 95-2113-M-027-002)
2. “High Fluorine Content Bis(fluoro-ponytailed) Bipyridine Ligands for Pd-catalyzed Mizoroki-Heck Reactions under Fluorous Biphasic Catalysis Conditions” The 2nd International Symposium on Fluorous Technologies (ISoFT07), Yokohama, Japan, July 29-Aug.1, 2007. (poster); (NSC 95-2113-M-027-002)
“The study of using novel Cu complexes with fluoro-ponytailed bipyridine for the ATRP under thermomorphic mode” The 2nd International Symposium on Fluorous Technologies (ISoFT07), Yokohama, Japan, July 29-Aug.1, 2007. (poster); (NSC 95-2113-M-027-002)
4. “New Bis(fluoro-ponytailed) Bipyridine Ligands for the Pd-catalyzed Heck-type Reactions under Fluorous Biphasic and Thermophoric Conditions” The 2nd International Symposium on Fluorous Technologies (ISoFT07), Yokohama, Japan, July 29-Aug.1, 2007 (poster); (NSC 95-2113-M-027-002)
5. “Copper-catalyzed aerobic oxidation of alcohol under FBS and thermomorphic system” The 2nd International Symposium on Fluorous Technologies (ISoFT07), Yokohama, Japan, July 29-Aug.1, 2007. (poster); (NSC 95-2113-M-027-002)
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6. “New Bis(fluoro-ponytailed) Bipyridine Ligands for the Pd-catalyzed Heck Reactions under Fluorous Biphasic Catalysis Condition” The 18th Winter Fluorine Conference (oral), St. Pete, FL, USA, Jan 14-20, 2007 (NSC 95-2113-M-027-002)
7. “New Bis(fluoro-ponytailed) Bipyridine Ligands for the Cu‑catalyzed Aerobic Oxidation of Alcohols under Homogeneous or Fluorous Biphasic System” The 18th Winter Fluorine Conference (poster), St. Pete, FL, USA, Jan 14-20, 2007 (NSC 95-2113-M-027-002)
8. ‘Synthesis, Structure and Reactivity of PdCl2[4,4'-Bis-RfCH2OCH2-2,2'-bpy] (Rf= C3F7, HC4F8, HC8F16 and C10F21)” The 18th ISFC- International Symposium on Fluorine Chemistry (Bremen, Germany, July 30- Aug.4, 2006) 國科會計 畫編號 NSC 94-2113-M-027-003
9. “Using α,ω-Perfluoroalkane Bis-sulfonyl Fluorides (FSO2C4F8SO2F, FSO2C6F12SO2F) as monomers And The Application of Their
Condensation Polymers For Solid Lithium Battery Electrolyte” the 17th International Symposium on Fluorine Chemistry (July 24-29, 2005) 國科會計畫編號 NSC
93-2113-M-027-005 10. Deparmental Seminar “Two Industrial Applications of Fluoropolymers:
Perfluoropolyalkylethers annd Lithium Battery Electrolytes” Univ. of Alabama, USA, Feb. 1, 2005.
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歷年參與之研究計畫計劃名稱 起迄年月 委託機構
98-100年度國科會計畫 (合成新型含氟鏈聯吡啶及研究其應用在:一.陽離子型鈀錯合物催化,二.高穩定性及撥水之敏化太陽能電池,三.藍位移氫鍵)
98.8.1-100.7.31 國科會
96-97 年度國科會計畫 (一系列新奇之含氟鏈聯口比啶之合成;及以其為螯合劑所形成之鈀 ,銅及其他金屬錯合物之催化研究 ) (NT$2,655,000-2007-8; NSC 96-2113-M-027-004-MY2);
96.8.1-98.7.31 國科會
96年度國科會產學合作計畫:矽膠及相關產品之研究: 1.矽膠高分子樹脂之去除劑 2.使用超臨界二氧化碳回收矽膠 3. 水溶性矽膠介面接著劑之開發 (NT$ 459,550-2008)
96.11.1-97.10.31
國科會
特殊含氟化合物之合成及其在鋰電池,燃料電池及離子液體(ionic liquids)之應用 ( 2/2 NT$ 1,080,000-2006) (國科會計畫編號 NSC 95-2113-M-027-002;
95.8.1-96.7.31 國科會
產學合作計畫 (計畫名稱: 界面活性在高分子樹脂之應用研究 ) (NT$ 581,000) 94.11-95.10 國科會
特殊含氟化合物之合成及其在鋰電池,燃料電池及離子液體(ionic liquids)之用
(1/2 NT$ 1,113,000-2005) (國科會計畫編號 NSC 94-2113-M-027-003;
94.8.1-95.7.31 國科會
高分子鋰電池含氟素電解質聚合物之研製研究(國科會計畫編號 NSC
93-2113-M-027-005; NT $1,007,600)
93.8.1-94.7.31 國科會
註: 1. 皆為主要執行人; 2. 大約每年兩件研究計畫
3. 連續五年國科會一般計畫金額超過一百萬元 (總金額 7,486,150)
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榮譽獎項及其他 榮獲國立台北科技大學工程學院 97 年度優等研究獎。 2007.8 升副教授。 指導研究生學生林原週、陳宗琦及陳世傑投稿國際會議
(The 2nd International Symposium of Fluorous Technology; ISoFT ) 被接受;且每位學生獲得國科會 3 萬元之補助,去參與會議。
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Invitation You are cordially invited to join this group
for the cutting-edge research.