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ECOLAB ZarenECOCARE 250

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[SECTION 1. PRODUCT AND COMPANYIDENTIFICATION 1300704)

Product name : ECOCARE 250

Other meansof identification : Not applicable

Recommended use : Skin antiseptic

Restrictions on use : Reserved for industrial and professional use.

Product dilution information : Product is sold ready to use.

Company : Ecolab Ine.

1 Ecolab PlaceSt. Paul, Minnesota USA 551021-800-352-5326

Emergency health : 1-800-328-0026 (US/Canada), 1-651-222-5352 (outside US)information

Issuing date : 11/07/2017

| SECTION 2. HAZARDS IDENTIFICATION |

GHSClassification

Flammableliquids : Category 3

Eye irritation : Category 2B

GHS label elements

Hazard pictograms

Signal Word : Warning

Hazard Statements : Flammable liquid and vapor.Causes eyeirritation.

Precautionary Statements : Prevention:Keep away from heal/sparks'open flames/hot surfaces, No smoking.Keep container lighlly closed,

Response:IF IN EYES:Rinse cautiously with water for several minutes, Removecontacl lenses, if present and easy ta do, Continue rinsing. IT eyeirritation persists: Get medical advice/ attention. In case offire: Usedry sand, dry chemical or alcohol-resistantfoam to extinguish.Storage:

Store in a well-ventilated place. Keep cool.Disposal:

Dispose of contents! container to an approved waste disposal plant,

Other hazards : None known.

| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture : Mixture

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Chemical name CAS-No. Concentration (%)ethanol 64-17-5 5-10 -Coconut oil, potassium salt 68783-34-6 5-10

glycerin 56-81-5 5-10fatty acids, 014-18 and ı '8-unsald., polassium 68002-80-2 1-5saltsethylenediamine tetraac 64-02-8 1-5

[SECTION 4. FIRST AID MEASURES

In case of eye contact : Rinse with water.

In case of skin contact : Rinse with water.

If swallowed » Rinse mouth, Get medical attention if symptoms occur.

If inhaled : Gel medical attention if symptoms occur.

Protection offirst-aiders : Na special precautions are necessary forfirst ald responders.

Notes to physician : Treat symptomatically.

Most important symptoms : See Section 11 for more detailed information on health effects andand effects, both acute and symptoms.delayed

| SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media ; Use extinguishing measures that are appropriate to localcircumstances and the surrounding environment,

Unsuitable extinguishing : High volume water jetmedia

Specific hazards during fire : Fire Hazardfighting Keep away from heat and sources ofignition.

Flash back possible over considerable distance.Beware of vapors accumulating to form explosive concentrations.Vapors can accumulate in low areas.

Hazardous combustion : Decomposition products may include the following materials:products Carbon oxides

Nitrogen oxides (NOx)Sulfur oxides

Oxides of phasphorus

Special protective equipment Use personal protective equipment.for fire-fighters

Specific extinguishing : Use water spray to cool unopened containers. Fire residues andmethods contaminated fire extinguishing water must be disposed of in

accordance with local regulations. In the eventoffire and/or explosiondo not breathe fumes.

| SECTION 6, ACCIDENTAL RELEASE MEASURES

Personal precautions, : Remove all sourcesof ignition. Ensure clean-up is conducted by

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protective equipment and trained personnel only. Refer to protective measures listed in sections

emergency procedures 7 and &.

Environmental precautions : Do nat allow contact with soil, surface or ground water,

Methods and materials for :. Eliminate all ignition sources if safe to do so. Stop leakif safe to do so.

containment and cleaning up Contain spillage, and then collect with non-combustible absorbent

material, (e.g. sand, earth, dialomaceous garth, vermiculite} and place

in container for disposal according to local / national regulations (see

section 13). Flush away traces with water. For large spills, dike spilled

material or otherwise contain material to ensure runoff does not reach

a waterway.

| SECTION 7. HANDLING AND STORAGE

Advice on safe handling : Keep away from fire, sparks and heated surfaces. Take necessary

action to avoid static electricity discharge (which might cause ignition

of organic vapors).

Conditions for safe storage : Keep away from heat and sourcesof ignition. Keep in a cool, well-ventilated place. Keep away from oxidizing agents. Keep out of reachof children. Keep container tightly closed, Store in suitable labeledcontainers.

Storage temperature : -10°C to 40°C

| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Ingredients CAS-No. Form of Permissible Basis

exposure concentration

ethanol 64-17-5 TWA 1,000 ppm NIOSH REL1,900 mgim3

TWA 4,000 ppm OSHA 211,900 mgim3

glycerin 56-81-5 TWA 40 mgim3 ACGIHTWA 5 mgim3 OSHA 21(respirable

fraction)

Engineering measures : Good general ventilation should be sufficient to control worker

exposure to airborne contaminants.

Personalprotective equipment

Eye protection : Ne special protective equipment required.

Hand protection : No special protective equipment required.

Skin protection : No special protective equipment required.

Respiratory protection : No personal respiratory protective equipment normally required,

Hygiene measures : No specific measuresidentified.

| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

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Appearance : liquid

Color clear, green

Odar slight

pH :89-92, (100 %)

Flash paint > 43 °C. closed cup, Does not sustain combustion.

Odor Threshold : No data available

Melting point/freezing point

Initial boiling paint andboiling range

Evaporation rate

Flammability (solid, gas}

Upper explosion limit

Lower explosion limit

Vapor pressure

Relative vapor density

Relative density

Water solubility

Solubility in other solvents

Partition coefficient: n-

octanolávater

Autoignition temperature

Thermal decomposition

Wiscosity, kinematic

Explosive properties

Oxidizing properties

Molecular weight

VOC

No data available

> 100 °C

No data available

No data available

: No data available

: No data available

No data available

No data available

1.02 - 1.03

+ soluble

No data available

: No data available

No data available

No data available

1759.259 mma2/s (40 °C}

: No data available

: No data available

No data available

No data available

| SECTION 10, STABILITY AND REACTIVITY

Chemical stability

Possibility of hazardous

reactions

Conditions lo avoid

Incompalible materials

Hazardous decompositionproducts

: Stable under normal conditions.

: No dangerous reaction known under conditions of normal use.

Heat, flames and sparks.

' Acids

Bases

> Decomposition products may include the following materials:Carbon oxides

Nitrogen oxides (NOx)Sulfur oxides

Oxides of phosphorus

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| SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes ofexposure

Potential Health Effects

Eyes

Skin

Ingestion

Inhalation

Chronic Exposure

Inhalation, Eye contact, Skin contact

Causes eye irritation.

Health injuries are not known or expected under narmal use.

Health injuries are not known or expected under normal use.

Healthinjuries are not known or expected under normal use.

Health injuries are not known or expected under normal use.

Experience with human exposure

Eye contact

Skin contact

Ingestion

Inhalation

Toxicity

Product

Acute oraltoxicity

Acute inhalation toxicity

Acute dermal toxicity

Skin corrosionfirritation

Serious eye damage/eye

irritation

Respiratory or skin

sensitization

Carcinogenicity

Reproductive effects

Germcell mutagenicity

Teratagenicity

STOT-single exposure

STOT-repeated exposure

Aspiration toxicity

Ingredients

Acute inhalation toxicity

Ingredients

Redness,Irritation

No symptoms known or expected.

No symptoms known or expected.

No symptoms known or expected.

Acute toxicity estimate ; > 5,000 mg/kg

No data available

No data available

No data available

Mild eye irritation

No data available

No data available

No data available

No data available

No data available

No data available

No data available

No data available

ethanol

© 4h LCS50 Rat 117 mgTest atmosphere: vapor

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Acute dermal toxicity : ethanolLO50 Rabbit: > 15,800 mg/kg

glycerin

LD50 Rabbit: 23,000 mg/kg

[SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Environmental Effects : Harmful to aquatic life with long lasting effects.

Product

Toxicity to fish : No data available

Toxicity to daphnia and other : No data availableaquatic invertebrates

Toxicity to algae : No data available

1 Aients

Toxicny to fish : ethanol

96 h LOSO Pimephales promelas: > 100 mg/l

glycerin

56 h LC50 Fish: 855 mg!

ethylenediamine tetraacetate96h LOSO Fish: 121 mg/l

Persistence and degradability

Poorly biodegradable

Bioaccumulative potential

No data available

Mobility in soil

No data available

Other adverse effects

No data available

| SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods : Do not contaminate ponds, waterways or ditches with chemical orused container, Where possible recycling is preferred to dispasal orincineration. If recycling is not practicable, dispose of in compliancewith local regulations. Dispose of wastes in an approved wastedisposal facility.

Disposal considerations : Dispose of as unused product. Empty containers should be taken toá an approved waste handling site for recycling or disposal. Do not re-

use empty containers. Dispose of in accordance with local, state, andfederal requiations.

RCRA - Resource > BOO1 (Ignitable}Conservation and Recovery

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LLIOGIUSGEISE

u020-2005

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ECOCARE 250

Authorization Act HazardousWaste

| SECTION 14. TRANSPORTINFORMATION

The shipper/consignor/senderis responsible to ensure that the packaging, labeling, and markings arein compliance with the selected mode of transport.

Land transport (DOT)

Not dangerous goods

Sea transport (IMDG/IMO)

UN number : 1170

Description of the goods : ETHANOL SOLUTIONClass 3

Packing group M

Marine pollutant : ho

[SECTION 15. REGULATORY INFORMATION

EPCRA, - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RO.

SARA 304 Extremely Hazardous Substances Reportable Quantity

This material does not conlain any components with a section 304 EHS RQ,

SARA 311/312 Hazards : Fire Hazard

Acute Health Hazard

SARA 302 : No chemicals in this material are subject to the reporting requirementsof SARA Title 111, Section 302.

SARA 313 : This material does not contain any chemical components with known

CAS numbers that exceed the threshold (De Minimis) reporting levelsestablished by SARATitle III, Section 313.

California Prop 65

This product does not contain any chemicals known to the State of California to cause cancer,birth, orany other reproductive defects.

The ingredients of this product are reported in the following inventories:

United States TSCAInventory :On TSCA Inventory

Canadian Domestic Substances List (DSL):

This product cantains one or several components listed in the Canadian NDSL.

Australia Inventory of Chemical Substances (AICS) :On the inventory, or in compliance with the inventory

New Zealand. Inventory of Chemical Substances:not determined

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Japan. ENCS - Existing and New Chemical Substances Inventory :not determined

Korea. Korean Existing Chemicals Inventory (KECI) :not determined

Philippines Inventory of Chemicals and Chemical Substances (PICCS):not determined

China. Inventory of Existing Chemical Substances in China (IECSC):On the inventory, or in compliance with the inventory

Taiwan Chemical Substance Inventory (TCSI):not determined

| SECTION 16. OTHER INFORMATION

NFPA: HMIS Ill:Flammability

HEALTH

£ 23 E AATe: ee

= 5

PHYSICAL HAZARD

5 O= not significant, 1 =Slight,Special hazard. 2 = Moderate, & = High

4= Extreme, * = Chronic

Issuing date 2 11/0712017Version : 14Prepared by : Regulatory Affairs

REVISED INFORMATION:Significant changes to regulatory or health information for this revision isindicated by a barin the left-hand margin of the SDS.

The information provided in this Material Safety Data Sheetis correct to the best of our knowledge,information and belief at the date of its publication. The information given is designed only as aguidance for safe handling, use, processing, storage, transportation, disposal and release andisnot to be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text.

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