02-08-14 sr.iplco jee main (2013) ptm-1 final key & solutions
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Sri Chaitanya IIT Academy., India.A right Choice for the Real Aspirant
Central Office , Madhapur – HyderabadSec: Sr. IPLCO JEE MAIN – 2!"
#t: 2$%$!&'i(e : " )o*rs P'M$! Ma+Mar,s : "-
KEY SHEET
E/ S)EE'
P)/SICS C)EMIS'R/ MA')S
0.NO ANS1ER 0.NO ANS1ER 0.NO ANS1ER
! &
"! !
-! 22 ! "2 " -2 !
" 2 "" 2 -" && ! "& ! -& "
" " " - 2
- ! "- ! -- !3 " "3 " -3 !
% 2 "% ! -% &
4 " "4 " -4 !! 2 & ! 3 "
!! ! &! ! 3! 2!2 " &2 ! 32 !
!" & &" ! 3" "!& 2 && " 3& !
! " & " 3 2
!- ! &- 2 3- !!3 2 &3 ! 33 "
!% " &% & 3% 2
!4 ! &4 " 34 !2 & " % !
2! ! ! " %! !
22 " 2 & %2 "
2" 2 " 2 %" &2& ! & & %& "
2 " " % 2
2- 2 - 2 %- &23 ! 3 & %3 "
2% & % & %% 2
24 2 4 & %4 &" " - 2 4 &
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)IN'S
P)/SICS 1. Conceptual
2. Conceptual
3. Conceptual4. Conceptual
5. Let the particles meet after a time t1 after the projection of the second particle. Then for their motion
upto their meeting, we have
first particle second particle
!nitial velocit" u u
acceleration #g g#
time of motion t$t1 t1
final velocit" ( )1u g t t − + 1u tg −
The particle will meet, when first particle is comparing down and second particle is going up. Their
final velocit" must %e e&ual in magnitude, so( )1 1
u tg u g t t − = − − +
12
u t t
g
∴ = − ÷
!n this time, height
2
1 1
1
2h ut gt = −
2
2 2 2
u t g u t u
g g
= − − − ÷
2 2
2 '
u gt or h
g
= −
Thus 12
u t t t t
g
+ = + − ÷
2
u t
g
= +
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(. Consider motion of stones with respect to the %alloon. )t the instant of release of stones, the initial
velocit" of %oth stones w.r.t. the %alloon is *ero. The acceleration of stone w.r.t. the %allon
[ ] ( ) stone balloona g a g a= − − = +
+here a is the acceleration of %alloon which is 15.- ms 2
/ow [ ] 21 110
2 stone balloon s a t = +
( )1 4 ( 10t s= + =
∴ ( ) 2
1
110
2 s g a X = +
( ) 21.' 15.- 10
2 X m= +
and ( ) 2
2 2
10
2 s g a t = + +
+here2
(t s=
∴ ( ) 2
2
1.' 15.- (
2 s X = +
The distance %etween 1 2 s and s
1 2 s s s= −
( ) 2 21.' 15.- 10 (
2 = + −
'1( m
-. The displacement, 2 cos s R θ = and acceleration, cosa g θ =
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∴ 21
2 s at =
or ( ) 212 cos cos
2 R g t θ θ =
∴ 2 Rt g
=
'. if u is the velocit" of projection, then
0 3.5u a X = −or 3.5 3.5 -.5u a X = = 2(.25ms
/ow 21
1 12
y u X a X = −
21
2(.25 -.5 22.52
X X l m= − =
)lso 21
2 22
y h u X X a X + = −
212(.25 2 -.5 22
X X X = −∴ 15h m=
. Conceptual
10. Conceptual
11. 2.5dv
vdt
= −
⇒ 2.5dv
dt v
= −
⇒ 0
12
(.25 02.5
t
v dv dt − = −∫ ∫ ⇒ [ ]
012
0 (.252.5 2
t t v − =
⇒ 2t s=
12. 21
2h gt =
v gt = − and after the collision, v gt = straight line
Collison is perfectl" elastic then %all reaches to same height again and again with same velocit".
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13. ( )2 0sin2 (0
2 2
u R
g =
23
4
u
g =
2 2 0 2sin (0 3
2 '
u u H
g g = =
2 22 21
2 '
R u AB H
g
∴ = + = ÷
14. rom the graph,
22.522.5 .
150a s or = −
(0
0 0
22.5. 22.5
150
v
v dv X s ds = − ÷ ∫ ∫
∴ ( )
22 (022.522.5 (0
2 150 2
v X X = −
4(.4- v m s∴ =15. 6elative velocit" of 7 with respect to 8 should %e along 78 or a%solute velocit" components
perpendicular to 78 should %e same.
02sin sin 30
3
uuθ ∴ =
∴ 1 3
sin4
θ − = ÷
1(. .dv
f v a bxdx
= = −
or ( )0 0
v v
vdv a bx dx= −∫ ∫ ∴ 22v ax bx= −)t other station, v0
⇒ 2a
xb
=
urther acceleration will change its direction when,
f0 or a#%90 ora
xb
=
)t this 9, velocit" is ma9imum.
:sing ;&. i2
ma9 2 a a a
v a bb b b
= − = ÷ ÷
1-. Conceptual
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25. Conceptual
2(. rom the graph
2
25 ( 5 (
da d d s
dt dt dt
= = ÷
!ntegrate the a%ove
2
2
5
(
d s
t dt =
!ntegrate again25
12
ds t
dt =
!ntegrate again35
3(
t s =
=istance travelled from 0 to (s 3
1
5( 30
3( s m= × =
<elocit" at25
( 15 12
t s v t m s= = =
rom ( to 12 s, 215 5 u m s a m s= =2
2
11'0
2 s ut at m= + =
Total distance travelled 30 1'0 210 m+ =
2-. 6esistance force2 2dv
v m kvdt
µ ⇒ = − 2dv k
vdt m
= −
dv
k mv
= −,
0 0
v h
v
dv k dx
v m= −∫ ∫ ,
0log v kh
v m=
0
log
vm
k h v= )lso 2
dv k
dt v m= −0
2
0
v t
v
k
v dv dt m
− −
⇒ =∫ ∫ ( )0
00 ln
h v vt
vvv
v
−
=
.
2'. 2 2 1 1cos cos x u t u t θ θ + =
1 1 2 2cos cos
xt
u uθ θ ⇒ =
− also 1 1 2 2sin sinu uθ θ =
)fter solving we get ( )2
1 2 1
sin
sin
x
t u
θ
θ θ = −
2. Conceptual
30.
30, 5.0 25 .e M f cm and D cm= = = +e >now
0 0 0
25
1 30 1 5.0ee
D
M m X m m or m f
= = + = + ÷ ÷
+hich gives 0 5.0m =
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C)EMIS'R/ 31. ! 0.5 mole 3 324O g O=
ii 0.5g atom of o9"gen 'g
iii23
223
3.011 1032 1(
(.022 10
X X g O
X =
iv 2 2
5.(44 11
22.4 X g CO g CO=
32. /o.of moles of C?2 in 100 g mi9ture
((
1.544
= =
/o.of moles of @2 in 100g mi9ture
34
1-2
= =
100
5.401'.5
average M = =
5.4
. . 2.-2
V D = =
33. Let 1 mole of mi9ture has 2 4 x mole N O
2 9 2-.( ( ) ( )2 1 4( 0.2 x x x+ − =34. Conceptual
35. 1 mole 2 4 N H loses ' mole e− 1 mole / loses 4 mole of e
−
∴ /ew o9idation state of / is 2 4 2− + ⇒3(.
5 3
2 2 - 3
n Cr O X X O Cr + + − ++ → +
( )3 3( 10 ( 5 10 1 X X n X X n− −= − ⇒ =
3-. 3 2 22 12 10 ( ( BrO H Br Br H O− + −+ + → +
10 mole e− re&uired for formation of ( moles of Ar 2
∴ 2
10 5
( 3
n factor of Br − = =
e&. wt.. . 3
5 3 5
mol !t m M
n= = =
3'. Aalancing the e&uation, we have
( )2 2 - 2 4 4 2 4 2 4 233 Cr O H "O "O "O Cr "O H O+ + → + +
3. 1 1 2 2 N V N V =0.5 20 0.4 25 X X =
40. 8ince, phenolphthalein indicates onl" conversion of 2 3 Na CO into 3 NaHCO hence, x m# , of @Cl
will %e further re&uired to convert 3 NaHCO to 2 3 H CO . 8o, total volume of @Cl re&uired to convert
2 3 Na CO into 2 3 2 H CO x x x m#= + = 2 3 H CO .
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41.1 (.'
. . 3.42 2
n $ % $ eV = = − = −
2
13.(3.4
n $
n
−⇒ = −Q
n2 or first e9cited state42. Conceptual
43.10 13
10 10 m g kg − −= ⇒
( 2 14 10.000110 10 10 sec
100V X X m− − − −∆ = =
.4
h x &
π = ∆ ∆ =
4 4 .
h h x
& m vπ π ⇒ ∆ = =
∆ ∆34
13 14
(.(2 10
4 3.14 10 10
X x X X X
−
− −∆ =34
'
2-
(.(2 10 5.2 10
12.5( 10 x X x X m
−−
−∆ = ∆ =
44.2 2
2 2 2 2
1 2
1 1 1 1 13
3 R' RX
n nλ
= − = − ∞ 1
3 3
R R
λ ⇒ =
45. Conceptual
4(. 2l =
num%er of degenerate or%itals 2 1 l + =
ma9imum total spins 1
2
X
ma9imum multiplicit" 2 1" +
2 1 102
X = + =
minimum total spins 0
minimum multiplicit" 2 0 1 1´ + =
4-. Conceptual
4'. ?r%ital angular momentum ( )1 12
h
l l l π = + = for p#or%ital.
4. Conceptual
50. Conceptual
51. Conceptual
52. Conceptual
53. Conceptual
54. Conceptual
55. Conceptual
5(. Conceptual
5-. Conceptual
5'. Conceptual5. Conceptual
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(0. Bass of acetic acid adsor%ed %" 2g charcoal 100 10#3 0.(#0.5 (0
0.(0.( 0.3
2
x
m⇒ = ⇒
MA')EMA'ICS
(1. The e&uation of the line L %e ( )2 ' , 0 y m x m− = − <
coordinates of 7 and D are2
' , 0 % m
− ÷
and ( )0, 2 '( m− .
8o( )
( )( )
( )2 2 2
' 2 ' 10 ' 10 2 ' 1'O% O( m m X mm m m
+ = − + − = + + − ≥ + − ≥− −
8o, a%solute minimum value of 1'O% O(+ =
(2. 8olving given e&uations we get5
3 4 x
m=
+ x is an integer, if 3 4 1, 5m+ = ± ±
∴ 2 4 2 '
, , ,4 4 4 4
m = − − −
8o m has two integral values.
(3. !f 1 2 & and & %e the distance %etween parallel sides and E %e the angle %etween adjacent sides, then
6e&uired area 1 2 cos & & ecθ
+here( )
12
11
&m
= + ,( )
22
11
&n
= +
distance %etween F F lines
and tan1
m n
mnθ
−=
+6e )u*red area∴
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(4. !mage of the point 7 a%out the line ( )1, 4 y x *s (=∴ Transformation through a 2 units along the positive direction of x ax*s− , then new point
( )1 2, 4 R + ie, 63, 4
G 5OR OR∴ = =and tan 4 3θ =
4 3sin cos
5 5
and θ θ ∴ = =
Then , final position of the point is ( ) ( )( )G cos 4 , Gsin 4OR ORπ θ π θ + +
1 1 1 15 cos sin , 5 cos sin
2 2 2 2θ θ θ θ
⇒ − + ÷ ÷ 1 -
,2 2
⇒ − ÷
(5. ;&uation of L is 1 x y
a b+ = and let the a9is %e rotated through an angle θ and let ( ), X + %e the new
coordinates of an" point ( ), % x y in the plane, thencos sin , x X + θ θ = − sin cos , y X + θ θ = − the e&uation of the line with reference to original
coordinates is 1 x y
a b+ =
ie,cos sin sin cos
1 X + X +
a b
θ θ θ θ − ++ = HHHHHHi
and with reference to new coordinates is
1 X +
& )+ = HHHHHHHHii
Comparing ;&s. i and ii, we get
cos sin 1
a b &
θ θ + = HHHHHHHH.iii
sin cos 1
a b )
θ θ −+ = HHHHHHHH.iv
8&uaring and adding ;&s. iii and iv, we get
2 2 2 2
1 1 1 1
a b & )+ = +
((. Let the coordinates of ) %e a, 0. Then the slope of the reflected ra" is
( )3 0
tan5
saya
θ −
=−
HHHHHHH..i
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Then the slope of the incident ra"
( )2 0
tan1 a
π θ −
= = −−
HHHHHHHHii
rom ;&s. i and ii,
( )tan tanθ π θ + −⇒ 3 2
05 1a a
+ =− −
⇒ 133 3 10 2 0
5a a a− + − = =
Thus, the coordinate of ) is13
, 05
÷
(-. 2 2 1 2
1II 3I-I 5I5I I
m
n+ + =Q
1 2 10I 2 10I 10I 2
10I 1II 3I-I 5I5I I
m X X
n
+ + =
{ }10 10 10
1 3 5
1 22 2 2
10I I
m
C C C n
⇒ + + =
{ }10 10 10 10 10
1 3 5 -
1 2
10I I
m
C C C C C n
+ + + + =
( )10 11 2
210I I
m
n
−⇒ =
∴ 10m and n
= =@ence, 9#"$10 and 3 0 x y+ + = are perpendicular to each other, then orthocenter is the point of
intersection which is #2, #1∴ #22m#2n
and #1m#n
∴ 7oint is ( )2 2 ,m n m n− −
('. +e have ( ) ( )2cos cos 2 cos 1 y x x x= + − +
( ) ( ){ }212 cos cos 2 2 cos 1
2 y x x x= + − +
( ) ( ){ }
1
cos 2 2 cos 2 1 cos 2 22 x x= + + − − +
( )1
cos 2 12
= −
( )211 2 sin 1 1
2= − −
2sin 1= −
+hich is a straight line passing through2, sin 1
2
π − ÷
and parallel to the x ax*s−
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(. 1 , 22 2
% α α + + ÷
Q lies %etween the parallel lines 2 1 x y+ = and 2 4 15 x y+ = , then
1 2 2 12 2
02 1 4 2 15
2 2
α α
α α
+ + + − ÷ ÷
< + + + − ÷ ÷
34
2 0(
52
α
α
+⇒ <
− +
4 2
30
5 2
(
α
α
+ ÷
⇒ <
− ÷
4 2 5 2
3 (α ∴ − < <
-0. ( ),a a∴ fall %etween the lines 2 x y+ = , then
20
2
a a
a a
+ −<
+ +1
0 1 11
aor a
a
−⇒ < − < <
+1a∴ <
-1. 8ince =istance %etween parallel lines are same∴ 7arallelogram is a rhom%us
!n rhom%us diagonals are perpendicular to each other.
@ence, angle %etween diagonals 2π =-2. +hen x is rotational
let x)
ρ =
Then, ( )I 1.2.3....... . int &
n x n an eger )
= =
( ) ( )( )2cos I 1 cos 1
nn x nπ π ∴ = = −Q
( ) ( )2lim lim cos I 1 1m
m nn xπ
∞
→∞ →∞∴ = =
+hen x is irrational
Then, In x is not an integer
( )20 cos I 1n xπ ∴ ≤ <
( )2lim lim cos I 0m
m nn xπ
→∞ →∞∴ =
Thus, points are ( ) ( ) ( )2, 1 , 2, 1 1, 0and −
∴ 6e&uired area
2 1
2 11 1F F 4 2 .
1 02 2
2 1
s) un*t
−
= = − =
−
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;&uation of ?7 is y x=Then, 1 1 1 2O% %% = =
+e have, ( ) ( ) ( )2 2 2
1 1n n n nOM O% % M − −= +
( ) { }2
2 nO% y x= =Q
( )22 n sayα =
)lso, ( ) ( ) ( )2 2 2
1 1 1 1n n n nO% OM % M − − − −= +
2 2 2
1 1
12
2n n nα α α − −= +
2 2
1
12
2 n nα α −⇒ =
1
1
2n nα α −⇒ =
1
1
2n n nO% α α −∴ = =
2 32 3
1 1
2 2n nα α − −= =
HHHHHHHHHHHHH.
HHHHHHHHHHHHH.
HHHHHHHHHHHHH.
11
1
2n
α −=
1
1 1 1
2 2 2n n− = = ÷
-(. rom figure
( )tan ........2
R" R" *
%R r α = =
( )tan ........
2 2
%( %(**
%R r
π α
− = = ÷
Bultipl"ing ;&s. i and ii,
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( ) 2
.tan cot
2
R" %(
r α α =
∴ ( ) ( )2r R" %(=
--. Let ( ),C h k %e the centre of the circle passing through the end points of the rod )A and 7D oflengths a and % respectivel", CL and CB %e perpendiculars from C on )A and 7D respectivel". Then
C)C7 radii of the same circle
2 22 2 2 2
4 4
a bk h A# a and M% b⇒ + = + ∴ = =
( )2 2 2 24 h k a b⇒ − = −
-'. Let AO# θ =( )cos , sin A a aθ θ ∴ =
( )cos , sin M a a aθ θ ∴ = +cos x a a θ = +
( ) ( )cos .......... x a a *θ ⇒ − =
( )sin ..........and y a **θ =rom ;&s. i and ii,
( ) 2 2 2 x a y a− + =
2 2 2 0 x y ax⇒ + − =
2 2 2 x y ax⇒ + =
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-. Let ( ),h k %e an" point in the set, then e&uation of circle is ( ) ( )2 2
x h y k − + − =
Aut ( ) 2 2, 25h k l*e on x y+ =
then 2 2 25h k + =2∴ ≤ =istance %etween the centres of two circles
≤ '
( )2 22 'h k ⇒ ≤ + ≤2 24 (4h k ≤ + ≤
( ) 2 2, 4 (4locus of h k *s x y∴ ≤ + ≤
'0. Let coordinates of ) and A are ( )α β and ( ),γ δ respectivel".22 ,a bα γ αγ + = − = −
and2
2 , & )β δ βδ + = − = −;&uation of circle with )A as diameter.
( ) ( ) ( ) ( ) 0 x x y yα γ β δ − − + − − =
( ) ( )2 2 0 x y x yα γ β δ αγ βδ ⇒ + − + − + + + =2 2 2 22 2 0 x y ax &y b )⇒ + + + − − =
( )2 2 2 2 Rad*us a & b )∴ = + + +
( )2 2 2 2a b & )= + + +
'1. Centre and radius of the circle2 2 2 2 0 x y gx fy+ + + = are ( ) ( )2 2
1 1,C g f and r g f − − = + and
centre and radius of the circle ( )2 2 2 2
1 1 2 1 12 2 0 x y g x f y are C g f + + + = +
( )2 2
2 1 1and r g f = + Circles touch each other.
∴ 1 2 1 2C C r r = ±
( ) ( ) ( ) ( )2 2 2 2 2 2
1 1 1 1 g g f f g f g f ⇒ − + − = + ± +
s&uaring %oth sides then
( ) ( )2 2 2 2 2 2 2 2 2 2 2 2
1 1 1 1 1 1 1 12 2 2 g f g f gg ff g f g f g f g f + + + − − = + + + ± + +
( ) ( ) ( )2 2 2 2 2
1 1 1 1 gg ff g f g f ⇒ + = + +2 2 2 2 2 2 2 2 2 2 2 2
1 1 1 1 1 1 1 12 g g f f gg ff g g g f f g f f ⇒ + + = + + +2 2 2 2
1 1 1 12 0 g f f g gg ff ⇒ + − =
( )1 1 0 gf fg ⇒ − =
1 1 gf fg ⇒ ='2. ;&uation of chord can %e written as x y a± = ±
8o, length of perpendicular from the centre 0, 0 of the circle to the chordJradius
ie, ' 42
aa
±< ⇒ <
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'3.
8uppose chord %isect at ( ), 0 M λ , then
other end point of chord is ( ),h )−
where2
& hλ
+=
+hich lie on2 2 x y &x )y+ = +
or2 2 2h ) &h )+ = −
2 2
2 0h &h )⇒ − + =for two chords,
2 4 0 B AC − >or
2 24.1.2 0 & )− <or
2 2' & )>
'4. Let B/ %e the diameter of the circle whose e&uation is
4 - y x= + HHHHHHHi
and coordinates of ) and A are #3, 4 and 5, 4 respectivel".
;&uation of ⊥ %isector of )A is ( )1, 4 # =
( )1
4 10
y x− = − − ( )0 slo&e of AB =Q
∴ 1 x = HHHHHHHii
8olving ;&s. i and ii we get the coordinates of the centre of the circle as 1, 2
( ) ( )2 2
1 1 4 2 2O#∴ = − + − =
2 4 BC O# un*ts∴ = =
' AB un*ts=
tan 4 ' Area of rec gle ABCD X ∴ =
32 s&. unit.
'5. Let the circle %e ( ) ( )2 2 2 x h y k r − + − =
then( )2 2
1lh mk r l m+ +=
+
( ) ( )2 2 2 2 2 2 2 2 2 1 0or l h r m k r lmhk lh mk − + − + + + + =
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also 2 24 5 ( 1 0l m l − + + =
Comparing the coefficients of similar terms2 2 2 24, 5, 0h r k r hk − = − = − =
2 (, 2 0h k = =
20, 3 4k h and r ∴ = = − =5r ∴ =
@ence, centre ( )3, 0 and radius 5 .
'(. ?C is the diameter of the circle
0 0,
2 2
g f C*rcumcentre
− − ∴ = ÷
,2 2
g f = − − ÷
'-. +e have,2 22 3 2 0 x xy y− − =
( ) ( ), 2 2 0,*e x y x y− + = which represents a pair of 7erpendicular lines passing through the origin.
( ) ( )2 2
2 16e
4 4)u*red area
π π ∴ = −
3
4 s) un*t π =
''. Let line is 1 x y
a b+ =
( ) ( ), 0 0, A a and B b∴;&uation of circle since )A is diameters is
( ) ( ) ( ) ( )0 0 0 x a x y y b− − + − − =2 2 0 x y ax by⇒ + − − =
Tangent at 0, 0 is
0ax by+ =2
2 2
a AM m
a b∴ = =
+
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and
2
2 2
b BN n
a b= =
+
( )2 2m n a b d*ameter of c*rcle⇒ + = + =
'. Q The point [ ] [ ]( )1 , & &+ lies inside the circle2 2 2 15 0 x y x+ − − = , then
[ ] [ ] [ ]2 2
1 2 1 15 0 % % % + + − + − < page no. '15 &.no#1
[ ]( ) [ ] [ ]( )2 2
1 2 1 15 0 % % % ⇒ + + − + − <
[ ] [ ]2 2
2 1( 0 ' % % ⇒ − < ⇒ < HHHHHH.i
∴ Circles are concentric.
∴ 7oint [ ] [ ]( )1 , % % + out side the circle
2 22 - 0 x y x+ − − =
∴ [ ] [ ] [ ]( )2 21 2 1 - 0 % % % + + − + − >
[ ]( ) [ ] [ ]( )2 2
1 2 1 - 0 % % % ⇒ + + − + − >
[ ] 2
2 ' 0 % ⇒ − >
[ ] ( )2
4 ........... % **∴ >rom ;&s. i and ii, we get
[ ] 2
4 ' % < < which is impossi%le
∴ or no value of K7the point will %e within the region.
0. The image of the circle has same radius %ut centre different. !f centre is ( ),α β , then
( )2 2
2 3 2 13 2
1 1 1 1
α β − + −− −= =
+3 2 14α β ⇒ − = − =1-, 1(α β ∴ = =
∴ 6e&uired circle is ( ) ( )2 2
1- 1( 1 x y− + − =