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it

'...,

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12Marks

. ,.'Department of Higher Education, Govt. of M.P.

Under Graduate Semester wise Syllabusas recommended by Central Board of Studies and appfovj:9 by the Governor of

M.P.Practical

Session 2014-15Class: B.Sc. Semester ISubject: ChemistryPaper: Practical

Max Marks: 50

Duration of practical during the semester examination: 4 hours

Physical Chemistry(A).Any one experimentI. Calibration of thermometer2. Det,ennination of melting point3. Determination of boiling point4. Prcparation of solutions of various concentration, NaOH, HCl, H2S04.

(B).Any one experiment 12 MarksI. Determination of surface tension/percentage composition of given

organic mixture using surface tension method2. Determination of viscosity / percentage composition of given

organic mixture using viscosity method.

Organic chemistry 12 Marks1. Distillation2. CrystalJiz<.ltion3. Decolourisatioll <.lndcrystallization using charcoal4. SublimationS. Detection of elemcnts and functional groups6. Organic molecules through models with special reference to optical

and Geometrical isomerism.Viva: 6 marks

Records: 8 marks

~ fmTI fcl1wT. 11.>1". ~AICien cplffiW cf> ~ ~~«"!~ QlqllcpJi

~ 31~ ~ m 31j~iRiCi "d"m 11.>1". cf> ~1'fllQIC1 Gl""Xf ~Practical

~ 2014-15Class: B.Sc. Semester ISubject: '1'{il[l'1WB

Paper Title: \:l1[llfTlen -'1'1-i-I[l-rl

~ 3lcn - 50

~:4~

(31).~ "CfCP>r<:WT 3lcn 121. ~FltBlc'l:Cf)T ~~2. II c;H Ien "iilTCl q)~ I3. (fCf~.r;:ficn~1TCl Cf)~-;:n I4. f.'li1i~ "+l1;.-~-C'net f~~ Cf)l m- NaOH, HCl, H2S04.

(~). ~ "CfCP>r<:WT 3lcn 121.~c:r en1 "T'G ~c:r / ~ -{j-Sj-C:-'1 m ~ I2. ~cr <:F'-' v<1T"iill ~ / \:l R1~ICi ~ m ~ I

Cf>~ '1'Ii I[l '1 3Tcf>" 121. 3lT""{f(l~2. flh~c1l "RUT3. "7.Tf'1"cP1C"'! -q-,1 \3Lf[l1<f Cfi'[ fc1~\li .of) en'1uI ~ [ffi{cc11 en'1U I4. \j<c::cl~i5. ~ ~ ~1=jC:f) ~ q:)f cRIefUT6. lil~C'1 &TxT Cf>TeJf.1q:) 31~F'Jn l=i W~ ~ -s[lIf1'lR1[l ~Jilq[lcF11

~ R!l c5l 3fcp - 6~~ 3-TCP - 8

Depar.tment of Higher Education, Govt. of M.P.Under Graduate Semester wise Syllabus

as l-ecoJllJllcndcd by Central Board of Studies and approved by the Governor ofM.P.

PracticalSession 2014-15

Class: B.Sc. Semester II- Subject: ChemistryPaper: Practical

Max Marks: 50

Duration of practicals during the entire semester:Duration of practical during the semester examination:

Inorganic ChemiSti-yInorganic mixture analysisMixture Analysis for 2 Cations and 2 Anions

Separat.ion of cations by paper chromatography.

Physical Chemistry (Anyone)

90 hours4 hours

8 Marks

4 Marks

12 Marks

l. To determine the velocity constant (specific reaction rate) ofhydrolysis of methyl acetate / ethyl acetate catalyzed by hydrogeniOlls at roo 111 temperature.

2. To study the effect of acid strength on the hydrolysis of an ester.3. To compare the strength of HCl and H2S04 by studying the

kinetics of hydrolysis of ester.4. kinetic studies of decomposition of iodided by H202.(study of

iodine clock reaction)

Organic Chemistry: (12 marks)

I. Detection of 2 elementscompound.

(N, S and halogens) in same organic6 marks

2. Idcntification of 2 fUllctional groups 111 multifunctional organiccompound 6 marks

Viva : 6 marksRecords: 8 marks

_~o~/~~ ~S*~:\\'fY~

"

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Practical~ 2014-15

Class: B.Sc. Semester IISubject: '1filwl ma

Paper Title: !Oll41fTlq) xfil~'1 It

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4 3Tcn

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ftnm 'ChT Fc1~ 1l'C ftlJm ~ ~ cf; C114Ji 1'1 '4'<' m cpRf I2. ~ cf; \Jj'"(1' 3l4Qc'1 LR ~ "$I 3lJ:C1l~C11 cf; ~ cnT 31m..,

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~I Rsl c61 06 3Tcn~ 083fcn

Departmcnt of Higher Education, Govt. of M.P.(jnnel" Graduate Semcster wise Syllabus

as recommended by Centnll Board of Studies and approved by the Governor ofM.P.

PracticalSession 2015-16

Class: B.Sc. Semester IIISubject: Chemistry Paper: Practical

M.M.50 Time: 6 hours

Inol'gnic Chemistry 18 marksI. Calibration of the fractional weights, pipettes and burettes.2. Prep,lration of standard ~olutions. Dilution of D.I M to 0.01 M

Solutions.Quantitative analysis - Volumetric analysis.(a) Dctermination of acetic acid in commercial vinegar using NaOH.(b) Determination of alkali content- antacid tablet using HCI.(c) Estirnation of calcium content in chalk as calcium oxalate by

permagnatometry. (d) Estimation of hardness of water by EDT A.Complex Compound Preparation:I. Diaquabis(methyl acetoacetato) nickel(II)2. Diaquabis (nethyl acetoacetato) cobalt (II)3. Bis(methl acctoacetato) copper (II) monohydrate4. Potassium chlorochromate (IV)5. Tetraamminecopper(If) sulphate monohydrate6. Hexaamminenickel(II) chloride II

Organic Chemistry Laooratol'y Techniques 18 nlarksA. Thin layer chromatography

Determination of Rr values Clnd identification of organic compounds.(a) Separation of green leal" pigments (spinach leaves may be used)(b) Prcparation and separation of 2,4- dinitrophenylhydrazones of acetone,

2-butanonc. hexane-2 and 3-one using toluene and light petroleum(40:6).

(c) Separation of a mixture of dyes uSll1g cyclohexane andethylacetateJ8:5: 1.5).

B. Paper chromatography: Ascending and CircularDetermination of Rj values and identification of organic compounds.

(a) Separation of a mixture of phenylalanine and glycine, alanine andaspartic acid. Spray reagent ninhydrin.

(b) Separation 01" mixture 9f DL-alanine, glycine and L-Iucine using n-butanol: acetic acid: water (4: I :5). Spray reagent ninydrin.

(c) Separation of monosaccharides- a mixture of D.galactose and D-fructose using n-butanol: acetone : water (4: 1 :5). Spray rcagent-ani Iinc hyddrogen pthalatc.

VivaSessional

6 marksHmarks

:'

Department of Higher Education, Govt. of M.P.B.Sc. Under:,Grad~ate Semester wise Syllabus

As recommended by Central B<lard of Studies 'and approved by the Governor of M.P ...""~ ~~~;'I~lan IWli'l, 11.'Q" ..• ~

cft_'(~x-mt 'A Id Cf> 'Cf)1fff31T ~ ~ q I (HOIw~cB •.••'1£l ~ ~ &m.31:r~iR1d crm 11.ir: ~ ,<1~£lqlC'1 6RT 3ljJil~d

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1 "

Class B.Sc.--- "-_.'

Semester V--- .. -.

"T(English) Chemistry

Subject IR5;=;:fl '< '<'1 I ;q ., ~._-- -

Paper ---' .-

Max. Marks 85 + CCE (wm ~ ...:@!i~::O 15--------,----- - .. ----,-----

periO~

UNIT I

....."--'Unit--i- -" .., Syllabus' ---

T-"----Iorganic e;;'rlipounds of Nitrogcn~prepar~tion, properties andchemical reactions of nitroalka~es ~ndnitJ'l)arenes. Mechanismof nucleophilic substitution in nitr~lrenes and their reduction inacidic neutral and alkaline media, picric acids.Halonilroarenes; structure and nomenclature, and their activity.I\mines structure, and nomcnclature. physical propertics andstereochemistry. separation of mixture of primary, seco:ldar)'land tertIary amines. Structural features affecting basicity otiamines. Amine salts as phase transfer catalysts. Preparation or,C\lkyl and aryl amines (reduction of nitro'coI1l))ounds, nitnleS),1reductive ami nation of aldehydic and ketonic compounos.'Gabnel - phthalamicle reaction, Hoffmann bromamide reactIon.Reaction of amines, electrophilic aromatic substitution in aryliamines, reaction of amines with nitrous acid synthetic,mn,fonn"io" of "'yl di<zonium .>aIL" 'w couEling - ""--11 18

ci'>14f.1$ ~ : ~\1$0Q;:;qi"1 q ~ &.,. I Lectures.' fuft:rm. 'T1 -c;q' 'm1I<:1f.1$ ~. ~ \~ 11 ~g'jEfC'R~~ ~ c#I fSh<:11F21Rr C'fm \3~ _~, ~'T1)<:j.J''3~ 1ilUf11 11 3~. ~ ~ I'~~I$~'IC;;fH fSh<:1I'iTl('jC1I. ~c:r.-n -c;ci ;n'fm I;~~ c#I xi'-['i1'1T -c;q' "i 1Ii $ x 0 I. ~ 'T1 -c;q' ~ ~~1~ I\n~. pg ,T'1<:1$ -c;cr ~ <;i!l~ ciJ fl'r'>fUT Cf)f ~~<:fCfl{Ul~11~ qfr e-m<:nC1T cnT 1:r'l-fTfclc1 ~ crrc;Tl ,{1x i1 "11 C"i $ fct*l5fC1TC; I~~-;:r (1CfUl \.rrcRQlT '-[~~ '3(':>1'{$'1 ciJ ~ 11, ~<:'1 -c;<:1~ffi;l ~ ~ c#I fufUm (-;;r~ ',\4 ~ <:ltfTrcn1 '.~). ~t\I$:s'i ~ ~ <:i1fTrcf,T Cf)f 31qi1i-"l~W'fCf,!~-;:f)C!JXUT, l)l1t('j-iI c'1Ii1$:S 31fiifSh<:n. 1?fq-,~ dfi1 Ii1$ 'S ~[jliI~~~i c#I ~. ~ ~ 11 $c'1Cf~I"1 ~ ~~'];.IfC'1'(~. ~~ en") .~i ~ ciJ XiT?l ~. C;ft1

LJi ::';:;T~~<:r=r ~ ciJ xHc'1tt"II,"ICf, {iiQIC1'{OI.-c:;vn -gn:M I i I

_1 ..J~1

18Lectures

-!Carbohydratcs-IiClassification and nomenclature. monosaccharide, mechanism\01" osazone formatioFi,' chain :Iengthening and chain shorteningj01" aldoses. epimerization, confIguration 01" monosaccharide,erythro, threo diasterioisomers. Formation of glycosides, ethersand esters, determination of ring size of monosaccharide, cyclicstructure of D( +) glucose. mechanism. of mutarotation.Structure of ribose and deoxyribose.ICm'bohvdratcs-lI

. IAn inl;oduction to glycosidic linkages 111 di and poly-~ jsaccharides, l~ed~ and non-reducin" su"ars.

UNIT II i iCfJI<ligl~~C: I : ~ur CfW-'1T11~T. -So

I [ef; fcRT:r'l q-,'1 fth-l:lTfctfu. ~~lXl ~1 ~C'1T ~ q

\ \

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i I Icpr ~. fl~~CfJ>(I*'S c5'1 ",rif,I<:jm <:Bl ~. 0 (+)1. i ~~1x-r q-,'1 1T~-'l<:J ',<:m. -q~ ~ c5'1 fTh4IRl\U. ~:~

~

I -+-[ i(lm~3NCR~~I~<4~i~<1~ci 'Cly~~ -i'i~'lft~tl CfiT qftq[f. 31Qi:l14Ch ~ 3Pl31Qi:l14CfJ ~ I 1

(a) Photochemistry: Electromagnetic radiation, range o'

IIdifferent regions of the spectrum, dillc!'ent expression units 1'0

i lenergy. wavelength and frequency Interaction of radiation withlI \matler. difference between thermal and photochemical process.jLawS of photochemistry - Grotthus-Draper law, Stark-Einsteinl

Ilaw, Beer-Lambert law, Electronic transitions, Jablonskildiagram depicting various quantum yield. \(b) UV Spectroscopy: Electronic excitation, elementary ide;~ 18~)f instrument used, Application to organic molecules.l

f I LecturesUNIT III I [Woodward-Fieser rule for determIning Amo", 0 enes, pCllyenesl

! land a, 0- unsaturated carbonyl compounds. :r---p

- -'tl. ~ ~ : fugC'f ~c5'1<::l fc)fcnxuT, fcl FcP'<"01 cf; fup~~~~~ c5'1 '[j'ffi:f. \JJG11. eRrT ~u5 10l 3lT~fc'f! qTI UlCfn ~ cf; ~~\~ *CfJI$4i. ~cl Cf2.1l t:lfcr>'<ui1 cf,'r 'Cl1,<"fYRCfJ finm. \Ji~\~~T -qcprn xr~Cf) 31fiifin<:mn -i'i 3ic1'<"; qcm-vr ~";Of cf;j1F-1<:P'l; m2.R1-~ f.1<:rl:l. ,<~-311::;;'''(C:1*<1 f.1<:rl:l. ~,<-<:-~ti[R<:P:l. ~ ~. \:l~ 31m-m -i'i t::lftC1 ~ ;'.;Tfl\

I ~~~ ~~=~"','~:;~=:;:",=~J\

1'<161'C.1i1 ~ 011<1CfJI0. q-,-mR1-q-; "[j~fTr"ch.,c5'1 m-'1l ~TlCT c:ro",<~\r 3fjW:ITrT. 't-'r. ~ Cf~'l a. (3 ~ CfJIJiR1c;r <:ttfTr<r>1 m

L \AIl1~x cf; ~cl'<ur $ ~~.~-~-i,,< f.1<:rl:l1.-_ ..---~,--- ~----------------- ----------

18

IBi~inorganic Chcmisft-y ..•'IEssent Ial ,lIlel trace elements in biological processes,metalloporphYllns with specIal reference to haemoglobin andImyoglobin, Biological role or alkali and alkaline earth metal,ions with special reference to Ca2 •.

HBiOil10rganiCChemistr"y - II 18

IR.ole of metal ions in biological process, nitrogen fixation, Lecturesoxygen-uptake proteins, cytochromes and ferredoxins_

.1 .- -31CBI4f.'1CB ~ I : ~ ~3n if ~ ~ ~e+rl, mg ql'(4iI~R",('1-t'l'"l'\lC'1'1F<:l.., 10l ~~ ~ ~ ~II

I :1'1. a:rR C'f2-l1 ~:rRt<l ~ ~ 3ITlf"l'j cFl ~ ~ Ca2+ ~

i ~ X1C;-1{ -B I

6ru-31"".fe", ffim II : - 1ffil=3if ~ "'TI ~:~~ 1:L~~ . ..,1~~'lv1"l R~. ~\Jl"l" "lJTg) ~. ~W:rcTWrl12.lT~~1,_ ,-----1

Hard and Soft Acids and Bases (HSAB) •Classification of acids and bases as hard and soft, Pearson'sHSAB concept, symbiosis.\nalytical Chemistry: Errurs, thell- classification,,minimization of errors, precision and accuracy, gravimetric

; .estimation - concept, method and precautions, gravimetrickstimCltion of barium and copper.Ilnorganic Polymers: Introduction and scope of inorganic

I

pOlymerS, special charact~rislics, classification and t!lei!

L. applications: Structure and nature or boncilng In SilIcones aIF~

___~~ho2J)honltnllc chlonde. I:~ -c;ct ~ ~ -c;ct a:rR : 3-~[ ~ci an"'("[cnr CfJO)"'("~ct ~'1' Lectures~ ~ if Cl,Pi (}) '( 0I, ~ffl"'l' em q-,-ol",(" 10l 'lfi ~ -c;ct am etrERulT. ~~llf~ClT Ii fc'l 'i' c'l tl 0 II ~ CB ~ : ~, \3""lCti r Cl,Pi CB'( 0 I -c;ct -"'I{-'1~"'~1rOj'-,--.,:-uT.

<:l2-l1\CTm \!-d qR g<:& (11 I ~ 3ricf;c;f"'l' - tlT{OTI. fclft:r -c;ct~ TCi'i:.TTR<fl. il-R<:P=! C!2-l1 ~ q-,l 1~ ~ I

~ ~ ~c;' m. ~ "C'11a'1fUTc:p [JUT. JI DT"ff2.TI ~ I ft:rf~qj"l~l"ff2-l1 s;.ILj4iI'{:q)'1..,I~~~Q)

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..\~ 'I}~j(

~'I

--I

UNIT V

UNIT IV

3

~Ol'partmcnt 01'High,,* E4iucation, Govt. of M.P.B.Sc. Undel' Graduate Semester wise Syllabus

List of Books recommcnded by Central Board 01'Studiesas approvcd by GovenlO)' of M.P.

~ fulffi fcMFT, 11,~.m

~.~. 'Hlc1Cf> cnlffi3IT* ~ 41d£lffili ~ ~ ~rcl'i".:j~ ~ m3lj~iRiC1 ~ 11."Q. * \!1~41C'1 8RT 3ljli'I~C1 ~«1cn'j ~ ~

_._-----------_._-_._--------_ •.._- ----_._-----_._----------------------,

,-----------'---------

Recommended

Books

1 Physical Chcmlstry-Puri, Sharma ~nd Pt1thani;l, Vikas Publications, New De~hi

2. f'hyslcal ChemIStry -G.M. Barr':)w, In:crnat:onal Student Edition, McGraw Hill.

3 The Elements of Physical ChenllSlry, PW Atkins, Odord University Press

4. Physical Chemistry, R.A. Alberty, Wiley Eastern ltd

5. Physical Chemistry Through problem" S.K DOI~rJ and 5. Dogra, Wiley Eastern

6. Organic ChemIStry, MOrrison a,~d Boyd, Pre:ctlce I,all

7. Organic Chemistry, L.G. Wade Jr Prentice Hall

8. Fundamentals of Organic Chemistry Solomons, John Wiley.

9. Organic Chemistry, Vol. I,lL IlL S.M. MukherJI. 5.P Singh and R.P. Kapoor,

10 Organic Chemistry, F.A. Carey, McG:aw-Hd1 ~!1c.

11. Introduction to OrganicChemlstry, StrC'ltwlesser, Heillhcock and Kosover, Macmillan.

12 VO(lel's Qualitative & quantitative AnalySis Vol- 1,2.3, ELBS.

13. Advanced Organic chemistry, I. l. Finar, ELBS

14 13asic Concepts of Analytlc,,1 che,nistry, ~ M Khopker, New Age International Publishers.

15. Ana!ytical Chenllstry. R.M. Verma, CBS PubJ,catlon.

16 Analytical Chemistry, Skoog & West, Wiley Intel national.

17 Essentials of PhYSical Chemistry, BS Bahl, Arun Bahl & G.D. Tuli, S. Chand & Company Ltd.

18 AtomiC structure and Molecular spectroscopy, Manas Chanda, New A.ge International Publishers.

19 Vlolecular Spectroscopy, Sukumar, MJP Puhl,shers.

20 Ort:ilnlc Chemistry, Mac Murrey, Peal son Education.

21. Inoreanic Chemistry - J.D. Lee, John Wiley

22 Inorganic Chemistry - Cotton and Wilklll;on. John Wiley

23 Inorganic CheITlistry - Huheey, Harper Col:,ns Pub. USA

24. Inorganic Polymer - G.R. Chhatwal, Himalaya Pub.House

25 qUi \.ri:~l f%"<fl 1.T'Q.! 3~ ~ &Rl WnriVlct."m:f'l ~ $1 ~",rq; :26 11V; t;l~ ~ V-Q.! 3~ ..,'r:!1c'! liRT >i<l'iTR.trCl>irmflnl> ~ $1 "1TG~ :

"

4

nVp:\I'\ mc'lll "I' Highl'l' :':ducation, Govt. of M.P.,: I: ,Iv~' (; 1':ldllute St l1H'ster wise Syllabus

,,~ \'l't"lI.llllll'IHh'd In (,,111",11 i~mHd of ~';,lldil's and approved by the Governor of M.P.Session 2016-17

eL,ss : B.S\..' Semester VSlli),ic'CI ' C'jlt~mistr) Paper: Practical

,VI.M. :;() Time: 6 hour

InoJ'g~;nic C!tcmbiJ':, 12 MarksAl1~tly,is of i!luq:dl:ll' Il1lxture ClllltalOlOg five radicals with at leastDIll' iJllerferil1~ r~lcli\..'(\i or typical combinationG nnLnetJ'ic mJ:,I,\si~ ; 12 Marks

ilarium :1" hdl'llll1l ~lIlphate,(hgnr,ic Clwmi\li'," 12 MarksPn'p:l 'ation:Ii) /\(,'t~tylaIJti:1

( i l ) B l n zo y L d I() J !

(ill) ILctd-DIi1ilrl,\1l'!1':;(,lle

(iv), I":cric ,Kid

Vi\aSl'ssio:JaI

31q)I<if' en ~1T<.A Rn~I-;:r3ICfiT4f""Cf5 fi1S:{lJl c,J1 fc1r~t:'Ul f~T~=r:': :ri'C:l ~';I~,-i'i-cr)T:i "~"R"C:!; JI "I'~:.(:ll \)P~ ~'i:\JA it

'~1T,(1~l:rc:i~quri!r~)'ITl .nl ilf~;,~r;~:C-:'i;C' (i~ ~ill1.p. I

06lVIarks08 Mar1(s

12 ~.tCPit C'lQ.lT Cj')1'f it' 'CP"'Tf ~

cr;p\f'F-i ~n.Frfct~'G1-;:r(i) l< i~'.j r';] (~,:r;(I i 1)3~-;:mE',\ ,;0-\ ,,OJ

(i i) '(\JiT<::rcfl~(iv) il:tRP""Cf5 ~

12 3icr>

, n':'t';-qS'lj'~(f'-I~

/II

Department of Hi~er Education, Govt. of M.P.B.Sc. Under Graducti'e ~mester wise Syllabus

As recommended by Central Board of Studies and approved by the Governor of M.P.~ ftrafr ~. 11.>l".mx-Pf

ofr.~. ~ cpamJ1 ci? ~ Qldllw'i~ ~ ~ &NT 3lj~iR=td ~ 11.>l".ci?",<1~QI<1 &NT ~

Session / ~ - 2016-17 ~"<1"T'1 iA

I Clas,_s -------.----~--=------ ------..-.~-s-e-m-e~s~te-r-~~~(f,-:-n-g~-liSI;)--- ~Ihemistry - -----~

,Subject Le'-"'" ~~ "!r~

~;_~_~_~_'-a!:.-~-s_-_-_----:--'===---- 8li_+ CCE ( '{j:~ _~L1~~_=-~ --=

18Lectures

UNIT I

18Lectures

1

),

UNIT IV

II

I 1

L~,-

1----- ~~-~ ~~_._~--I'..TTCj CfiTi'iTf.'rcq ~ - cnr ~f.

I~T -c;cT <TtT-'l. mCj 3-fr~fqo--;:r ('f?.:f[ -C;~ ~ I 31ICRflCfilx!<:rPTi("l1Cfi3-I~ 1

~I, ~-~-~ ~: cnrJ~rlTl'! <itfrrCfi-f1PI"i,,g ,

tl:;ci ~ <:iWrCfi, ~, ~, ~ 31jl'l£(l'11----T----'iA .. Magnctic propertie~-~;'ansition metal complexes:, . magnetic moment (spin only and with-'L-S coupling),

; I orbital contribution magnetic moment. 'B. Electronic spect.-a of tl"ansition metal complexes:, Spectroscopic ground and excited states, types of electronic

transitions, selection rules tor d-d transitions, Orgel-energ 18:~ level diagram for dl to dl) states_ Lectures

C. Watcl' Analysis: ,Hardness, types of hardness, acidity andUNIT III alkalinIty, BOD, COD and DO '

T, ~ mg ~ ~ ~1~4Jll1 :rir--' -'3-kl-4J~'1-l1-3mfTT-~(~-(-- (1'--1~~UT Cf~r L-S ~) _~cP'l<:l 31IJuT ij cnafl<i <:f~ I" I~_ ~ mg ~' cnr ~Cf~If.'tCfi ~ : x-qCf~H:q):fqCfJ

1 ~ -c;cT \3ITif\J1\1 31CR~, :;;cYI<!S:;If.'tcn~ cF m'(, d-d !

L1 I 1F:;1;:~:.;;,:~t:I~;I~ q~ f.'!Wl, dl-n dl) WH{>.:f[3-i'i cB i

I 'fr_ \J'fc;T Fcl~c'lt:lUI ,,1,'1' cB1 q-,---o'Rm 3ff'o( ~-~ mx, \J'fc;T cB1 I

I

--- - 1-----r'-.p~"~l1\11~~, '4l,3Tr~, -m~3n~ Cf?:rT m~_' ll_._---i A. Infrarcd spectJ'oscopy : Statement of the Born-il

Oppenheimer approximation, rotational/l spectrum oil, I diatomic molecules. Energy levels of a rigid rotator'l

I', I selection ruk, intensity ot absorption bands, MaXWdl-

1I, Boltzmann distribution and population of energy levels_.B. Energy levels of simple harmonic oscillator, selection rules.!I pure vibrational spectrum. intensity and qualitative relationl

Iof force constant and bond energies, degree of freedom and!modes of vibration, vibrational frequencies of dif[~rent'I'

I functional groups.

IC, Raman Spect!'oscopy: concept of polarizability, pure '

rotatiOlnl and pure vibrational Raman spectra of diatomic I! molecules, Selection rules, application of Raman I 18; ,L spectrum_ _ , ---J Lectures----~---~ ~ -m 31lq"i@J'1~- x'1HCfic"i ,.f)l cn~, I'1~'Fnulfc1cp 3i':);3n enT ~ ~q-~T-{, ¥ ~ ciJ ~ "'{~', i.CRUT 17-:<:[11,3!cP"rIQUI etI ~. ircR1c)-c;r dle:-<V1~"i fumUT Cf~i

:v-,-0!j ~1-f1 cB1 "'{11iiTc I '~ffX0 ~ c:TPc-El ciJ ~ffi'Z, CRlJT ~, ~,~ ~!~:\'ref~8, -c-\l~m, 0lC1 f.1<:f('fi-cn "\q ,jq \:Yi\i11 ij Tl~ X1<iitT,'INd?l\11 cB1 Cl'Jlft Cf?:rT c:B-q-.,q-,'1 ~ ~, ~ tffimrJ1'T''-xlJ~ir cB1 q-,Y"f 31T~ I~. "'(1Ff ~Cf~fT:l<6'i : ~ cB1 'r-TRUTI, ful:l'PiIUIFclCfi ~31'i <f;I~~ ~ -c;cT ~oEl c~ ~ "'{~, CRlJT f.1<::p:, Cf?:rT "'(1Ff

_~ ciJ ~_~ L________'

UNIT V

1--1---- IA.

: l. NMR Spectroscopy Principle and Instrumentation, NMRactive nucleus, chen!jjcal shift, spin-spin coupling,spectrum of ethanol and ethanal.Surface Phenomena and Catalysis: adsorption of gasesand liquids on solid adsorbent, Freundlich and Langmuiradsorption isotherms, determination of surface area,characteristics and mechanIsm of heterogeneous./ 18

~alvsis. '-----13l ~ 1l'<;jrf)ll 3l~ «:l-~R'lCb"1 ~~ Cf~ \3Liq-,~, Lectures

~-<:l '3l""lCb"lll 31j~ ~l ~. xixilllf.1Cb fcR~.=r,'ft.q;'f-f~ -g'11-l, ~&.:ifc;r \'1211 ~ir-mcf; ~ I :

~

. T'O ~ ~ ~ : "Cffi13nu-~ "CR -rr-m Cf2ff"0if IChi ~~ll1fl'.-1. >B~"ij Cf21T~l~llx ~r ."'(1~ mn"l'f:l

____ ~ __ ~ af?l em f.1uRuT, fc)-q-.:rTr\T ~XUT cf; c;le-fUT ~ ftRl~ I ~.. "-- - ~ JP~~~~~* ibr ...

3

Department of I-Iight:I' Education, Govt. of M.P.B.Sc. Under Graduate Semester wise Syllabus

List of Books recommended by Centnll Board of Studiesas appl'oved by GovenlOl' of M.P.

~ ftran~, ~.~.m#r.~. 'H1~Cf) q')1ffiW c;? ~ 41cHlwli cf; ~ ~.>n£l ~ ~ m

~~ '!Ci ~.~. cf; xl"'£l41(Ylm 3ijJi~~~ ~'H1cpl eM ~

12.34.

Physical Chemlstry.Puri, Sharma and Pathanla. V,kas Publications, New a"lhiPhysical Chemistry .G.M. Barrow, International Student Edition, McGraw HilI.The Elements of Physical Chemistry. P W. Atkins, Oxford Un.ive"ity PressPhysical Chemistry. R.A. Alberty, Wiley Eastern Ltd

S. Physical C"ernl5try Through problems. S.K Dogra and S. Dogra, Wiley Eastern6. Organic Chemistry, Morrison and Boyd, Prentice Hall.7. Organic Chemistry. l.G. Wade Jr. Prentice Hall8. Fundamentals of Organic Cheml~try Solomons, John Wiley.9. Organic Chemistry. Vol. I,lL ilL S.M. MukherJi. S.P Singh and R.P. Kapoor,10. Organrc Chemistry. F.A. Carey, McGraw.HIII Inc11. Introduction to Organic Chemistry, StreltVJleSser, Heathcock and Kosover, Macmillan.12 Vogel's Qualitative & quantitative Analysis Vol. 1,2,3, ELBS.13. Advanced Organic chemistry, I. l. Finar, ELllS14. BasIc Concepts of Analytical chemrstry, S M Khopker, New Age International Publishers.15. Analytical Chemistry, R.M. Verma, CBSPublication16 Analytical Chemistry, Skoog & West, Wiley International.17. Essentials of Physic2l Chemistry, B.S. Bahl, Arun Bahl & G.D. Tull, S. Chand & Company Ltd.18. Atomic structure and Molecular spectroscopy, Manas Chanda, New Age International Publishers.19. Molecular Spectroscopy, Sukumar, MJP Publishers20. Organic Chemistry, Mac Murrey, Pearson Educalion21. Inorganic Chemistry - J.D. Lee, John Wiley22. Inorganic Chemistry - Cotton and Wilkinson, John Wiley23. Inorganic Chemistry - Huheey, Harper Collins Pub USA24. Inorganic Polymer - G.R. Chhatwal, Hicnalaya Pub.House25 "'U, J:lC:ViW~ 'P<-i 3~ ~ GR' >"l>~ X'!!rl:f'1 ~ ~ ~~ I26. "1~Zl J:l~Vi ~ 1J"'<J~ 3~-.t 'l~ &m ,,<'t>,fim J:lTUT-fi'r<n",1<:F! ~ ~<n I

------r------ ...-------. ------;

Recommended

Books

II

'-----.~--~-J_-3\-'h-~~-~ ~ ~ •••)l

II

4

II

DL'p.lI'( mvnt or Highel' :':ducation, Govt. of M.P.tJI':!Vl' (; I'.lc\uate ~>,'nH~ste •• wise Syllabus

as I'l'L,.nllIlL'IHI"d 1)\' eVil; ral Bmll'd ••1 Silldics and approved by the Governor of M.P,

Session "2016-17CL,>,<; : B,Sl Semester VI

SlIbjl.'C1 : Cilcmistry Paper: Practical!\1.I\ L ::0 Time: 6 hour

12 Marks

Hill,l; \' mixtule' ",u!,,'S'S CUI!Llllling ;\! (I solids: Separation. identification and

I)Iep;ll',,: IUll of Lkli \ "I! \ e",

i'hysind !:I';tl-Uml'nt.ltioJl

, i) (II)

/II

Mole-ratio method

12 Marks

B, IllOl'gani('CIH'misll'Y 12 Marks(I), i ,1TluC1l1 ..\II:II\'SI'

!"klllifil:li:,:Jl oj ,;Il.OIl', ,illc! allio'", III dillerenl waler samples,(II ) 'S a I('r ;m: I:\ , I'

;'0 delc"IIIl!l;L' I Ill' iJJ11UlII"of diss(" ed oxygen in water samples in ppm units,(Iii) ; )l'lel'llllli::lIOll llll'\;IIr.ill,',S of \\1;"','1

\/iV,lSessi 1m it!

06 Marks08 Marks

12 3icf;

'~,fr~!,'.f)N,PFi 12 3tq)

(I) ;;(10 iilm (i<1 ~ :~TTn0 fcrfSr0TCfil,H~!Cf) ~r[r,,"! 12 3tq)

(i) fn"-!-{r fcnr:,'p-iJl'~flr. ~,jT<3 ~;:i-;:' 1'1 \T-;::WFI --1~"U'jF':-q:j ~ ~ q l3 'tI1"1 I(I i) \J1';' fcl~(2i"i~i

-G'l,': cF -;::pr:-~: 1'1 qf(;;;,l Ji'fcfRl'5F'1 ;fil q'J'LfT'c:;11 i:f ~ I(iil)""":,1 ct3'] ;,,~r~;il -c;iT f;::r\iiXUT I

'1'rR:~:*;F<cri::~

Depart Jlll'llt Ill' Highl'" l':duc.ltion, Govt. of M.P.l.~,\(I,T Gnlduatc Sl'lllcster wise Syllabus

:1, 1"'Cdtllllll'Jlt1l'd Il,' {"'Jltl',ll noanl 01 ~itlldies and approved by the Governor of M.P.Sessioli 2016-17

\J~Li ~ fc;';'fTT, ",>r,mF!:cj'L!;Cj7i;'lT3il ~ m~,1>'l'{-<:,< ~ qlq'lOlCPJOj

q5'd.t<i 3l~~ rjlJ0"(Yi ~~nr ~(: elm +=f,>r,~ xlV"lOlqlC'1 6T'<T 3ijlil~d"{1?[ - 2016-17

eli"" ' H,St" VI Sem~'ster (Project Work)

!'l'ojCCi \\ \)Ik !Ol' till' student'; of VI Semester and its scheme willhe cO'ilplelcd :IS jlCI' directives issued by Department of Higherl::cil, ,_':\l, on. Co \: rli 11,,: 11\ () I \1, P,

,l~~ ,<c,

,3 r.'i:r I'! Ic:'n fil'l-! P ,

II

J COURSE MODULEPHARMACEUTICAL CHEN; iSiR V2()1~lfF ------

- B.Sc. Scmcstc,'- V* Each unit carries 17 Marks

lj n it I

Optical lsomerism- R-S nomenclature.

Conformational Analysis: conformational analysis of etha:ll'_ bU1ZlI;C_ c~cl()hcxane_ study of

Fischer, Newman and Sawhorse projections_

Organic Reactions: Introduction and elementary idea l)i- '-;uhstllLllilll' (SN I, S0J2) Addition

(addition of 13r2 and HBr to Symmetrical and unsymllletric,ti "Ikclies) and !-:iimin,i1.ion (EI,

E2)

Unit II

Drug Designing- A general study of the physic- chemic,ti :'I(;j1cl"lics in rel,nicn to bi()logical

activities. Stereochemistry and drug action. lsosterism and r~:()IS():,t(,!-,SIll 1'"1('I,,bolll- changes

of drugs and related of organic compounds in the body.

Unit III

Spectroscopic Methods: Principle, instrumentation ,'!1,' ,tpplication ,)1' I :I\raviolet

spectroscopy & Infrared spectroscopy.

Unit IV

Antimalarials: Classification, structure, synthesi~, mode oi _,,:l!(m did l!S,;S or c!:!(;roquine

phosphate, amodiaquine hydrochloride, prilllc.quine phosph_lk S\I~ ul-\nliI11,lidll,Jj.;

(jastro-intestinal drugs: - antacids, digestants, emetics & nr~ii -'I.1,cli~s-

lJ~1T V

Fundamentals of Potentiometer, Potentiometer Titratluns , l)l);:\U<.'\ Illdll'-- .11<:dSllrcments-

Ohms law, Conductance, Specific resistance, Specific con,_'l1,:lal1(:C, ~l()k::c,li,:r ,:oILluctance,

Equivalent conductance, their relationship, dcterminatil)n pi <.-<.'11 C\,J1S1,1l1l.dpp!ic1\ions of

conductomctry & potentiometry.

Polarography- Introduction, apparatus, factors affeclin:=~ lhl.' lim;lin(l C\ll"!<~J): :lI1d its

applications_

COURSE MODULEPHARMACl~UTICAL CHFi\IISTH\

201"-2011P,'aetieal - B.Se. Semesh~I'- V

Maximum Marks --50

1. Systematic separation and identification of organic binary m i" lll!"L'

2. (A) Interpretation of given UV and IR Spectra.

(B) Chromatographic Identification of given

Compounds/ ions through their Rf Values.

(C) Study of Various organic Mole.:ules through their ModeJ,;

3. Disintegration studies oftablcts- Weight Variation/Friability ullabkh.

4. Viva Voice

5. Practical Record

12 Marks

4 "vhlrks

4 Marks

12 ~v'larks

8 Vlarks

6 i\1arks

.jI)

/II

COURSE MODULEPHARMACEUTICAL CHEM1STRY

2016-20ii-B.Sc. Semester-VI

* Each unit carries 17 Marks

Unit J

Antibiotics:

a) Introduction, classification, isolation, constitution~. <\Iltilc"l:, and u~c~ of penicillin

and semi synthetic penicillin.

b) Study of structures and uses of streptomycin, neOnnCli1.

c) Constitution, Synthesis and uses of chloramphenicol

d) Tetracycline: SAR characteristics ancluses.

Unit II

sulphacetamide, suphaguianidine, Dapsone.

a) Sulphonamides: Mechanism of action of SUph,)I;,llllilks. synthesis ane! use of/II

b) Antitubercular drugs: Synthesis and mode of <It'-lion 01 j)l\S. 10:11. 1s,)lliazid

Rifampicin.

Unit III

c) Antiamocbic dr'ugs: Classification, s:,nthesis, stqlctll: ..' iWl! LI;;l'S(ll' \,lctmnic!,L(ole.

d) Antifungal: Synthesis and uses of kC!OCOI!;\/(lk. clotrinw/ulc. t<>iIJaftate,

griseoful vin.

Uni.tIV

e) Antidiabetic: Sti'ucture, synthesis, uses ancl 1ll,)l:~' ,)1' ,llllon oJ' Tolbutamide,

Chlorpropamide. Pharmacology of diabetics

f) Antineoplastic Agents: Pharmacology of ('el!!ler. cl;I~;si lIen i, 'n. ,,\'Ilthesis,

mechanism of action of 5-fluoro uraci I. 6-mercapuri Ill' Til iotCPll. !3u;;,ti I~l!l.

Unit V

Nuclear l\1agnctic Resonance spectr'oscopy. M agl''-'!!C prUI'l'l\ it's (, j nile lei. Ilcld and

precession, principle, chemical shift concept, isotopiC IHlck!. Ic~f<:rl'I\'_'l'st<1n<!,'lcis and

solvents. IH NMR spectra, chemical shifts. 11ll;\liplicil). coupling C,);lstants,

integmt i00 of ,i gna I'. in terpeeta Iion of 'peeo'a. In" ,n '" c'H,,. i"nand ;: i" n~ "'"

~~~ ~ ~~1