1st ps satl lab exp[1] 29th

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  • 8/8/2019 1st Ps Satl Lab Exp[1] 29th

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    SATL IN LAB EXPERIMENTS

    Ameen F. M. Fahmy*,J.J.Lagowski*** Faculty of Science, Department of Chemistry and Science Education Center,

    Ain shams University, Abbassia, Cairo, Egypt

    E-mail: [email protected]

    **Department of Chemistry, and Biochemistry, university of Texas at Austin

    TX78712.

    E-mail:[email protected]

    1ST PS-SATLC. Karachi

    Pakistan, Nov. 2008

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    SATL stands on the wholistic vision for phenomena

    where linking different facts and concepts take placeinto a dynamic systemic network. This reflects the

    relationships which settle them into the cognitive

    construction of the learner.

    It helps learners in obtaining a deeper learning

    experience, improve their understanding and ability to

    apply learning to new situation.

    SATL enhance systemic thinking, and increase

    enthusiasm for learning science.

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    Fig: 1a: Linear representation of concepts

    concept concept concept concept

    Fig: 1b: systemic representation of concepts

    concept

    concept

    concept

    concept

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    The Objectives of Systemic

    Approach ofT

    eaching and Learning

    Growing the ability of students global thinking,

    so that the student be able to see globally any

    subject without missing its parts.

    Growing the ability to see the relationships

    between things rater than things themselves.

    Increasing the effectiveness of teaching andlearning of science disciplines, connecting it

    systemically with other branches of knowledge.

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    Making disciplines of science attractive

    subjects to students instead of being repulsive

    to them .

    Growing the ability for analysis and synthesis

    to reach creativity that is the most important

    output of a successful educational system.

    Creating a new generation that is able to

    interact positively with environmental systems

    around them .

    Growing the ability for the use of systemicapproach in actingwith any problem globally

    to put creative solution.

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    SYSTEMICS AND LABORATORY INSTRUCTION

    Applying Systemics to laboratory instruction reveals thefollowing advantages, which constitute the principles of benign

    analysis

    * Smaller amounts of Chemicals are used.

    * Recycling of Chemicals.

    * Experiments are done with less hazards, and more safety.

    * Experiments are done more rapidly.

    * Students easily acquire a working sense of the principles ofgreen chemistry.

    Classical laboratory-oriented subject of qualitative analysis

    involves the application of linearly obtained chemical

    information to an unknown solution in a linear way.

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    In contrast to the linear approach of learning chemistry of

    cations from a laboratory experience, a systemic approach has

    been developed that focuses attention on individual species

    Figure 4)(

    Exp. 4

    Exp. 3 Exp. 2

    Exp. 1

    (?)

    (?)(?)

    (?)

    A+X-

    A+

    E-

    A+

    Y-

    A+Z-

    Figure 4: Systemic Investigation of species A+(SI-Plane)

    The diagram shows the Plane for qualitative investigation of

    the species (A+), the preparation of (A+) Compounds, and the

    interconversion of the species.

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    The formulas of chemical species of interest are expressed in the

    Figure (5) but reagents that bring about these conversions are

    not given. These reagents are revealed experimentally in a seriesof reactions shown in systemics (SD0-SD3) (Figure 5a-d), which

    the students can do in the laboratory on a small single sample of

    the species (A+).

    Exp. 4

    Exp. 3 Exp. 2

    Exp. 1A+X-

    A+E- A+Y-

    A+Z-

    (?)

    ()(?)

    (?)

    Exp. 4

    Exp. 3 Exp. 2

    Exp. 1A+X-

    A+E- A+Y-

    A+Z-

    ()

    ()(?)

    (?)

    Figure (5-a): SD0 Figure (5-b): (SD1)

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    Exp. 4

    Exp. 3 Exp. 2

    Exp. 1A+X-

    A+E- A+Y-

    A+Z-

    ()

    ()(?)

    ()

    Exp. 4

    Exp. 3 Exp. 2

    Exp. 1A+X-

    A+E- A+Y-

    A+Z-

    ()

    ()()

    ()

    Figure (5-c): SD2 Figure (5-d): SD3 FINAL

    Figure 5.a-d: The Laboratory - based evolutions of the chemistry of species

    (A+) as performed by students

    In Figure 39d all the experiments of the cycle were done. It is known as (SD-Final). The

    reactions can be performed in a single test tube on a small sample (

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    Applying this approach to laboratory instruction allows

    students to experience the colors of chemical species, their

    solubility characteristics, and their redox behavior.

    we have created. Qualitative benign analytical chemistry

    course for the first-year students of faculty of Sci., Benha,

    Zigzag University, and Faculty of Education, Helwan

    University, Egypt. The Systemic based course materials werepresented in 24hrs (2hrs period/ per week) From Sept.-Dec.

    (2001).

    The green chemistry aspects of this approach involve a

    very small amount of the cation-containing species, which is

    contained in a very small volume.

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    of experiments (1-4) in a single test tube on a small sample of lead nitrate (0.5 ml), then they

    recycle the product of (Exp. 4) to Pb(NO3)2 (Cf. SI - Final).

    (SI -1 - Plane)

    Exp.1

    Pb++

    Exp.2

    Nitrate Salt

    Exp.3 (White ppt)

    Lead

    hydroxide

    (White ppt.)

    Lead

    Oxalate

    HNO3

    (?)

    (?)

    (?)

    (Yellow ppt)

    Lead iodide

    Exp.4(?)

    (White ppt)

    Lead

    carbonate

    Na2C2O4

    Pb++

    i) HNO3

    ii)NH4OH

    Nitrate Salt

    i) HNO3ii) Na2CO3

    (White ppt)

    Lead

    hydroxide

    (White ppt.)

    Lead

    Oxalate

    HNO3

    ()

    ()

    ()

    (

    )(Yellow ppt)

    Lead iodide

    i)

    HNO3ii) KI

    ()

    (White ppt)

    Lead

    carbonate

    Recycling

    (SI -1 - Final)

    The students follow the plane (SI-1) to investigate (Pb2+) in a series

    Systemic Investigation of [Pb++] (SI-1): Lead Cycle

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    Systemic Investigation of [Ag+] (SI-2): Silver Cycle

    The students follow the plane (SI-2) to investigate (Ag+) in a series of

    experiments (1-3), then recycle the product of (Exp.3) to AgNO3 (Cf. SI-2-Final).

    (White ppt.)

    Silver

    phosphate

    (White ppt.)

    Silver

    sulphite.

    (White ppt.)

    Silver

    carbonate

    Exp. 1

    Exp. 2

    Exp. 3

    HNO3

    Ag+

    Silver

    nitrate.

    (SI-2 Plane)

    (?)

    (?)

    (?)

    (White ppt.)

    Silver

    phosphate

    (White ppt.)

    Silver

    sulphite.

    (White ppt.)

    Silver

    carbonate

    Na2SO3

    i) HNO3ii) Na2CO3HNO3

    Ag+

    Silver

    nitrate.

    (SI-2 Final)

    ()

    ()

    ()

    Recycling

    i) HNO3ii) Na3PO4

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    Results of Experimentation:

    The experimentation results showed that the Benign scheme reduces the

    consumption chemicals in Comparison with the classical scheme as shown in

    table(1). This means low cost, and less pollution.

    Table(1): Amount of salts needed for Experimental group (Benign

    scheme), and Reference group (Classic scheme)

    Salts Amount required (gm / 50 Students)

    Classic SchemeSolid/ (g)

    Benign Scheme0.1M Solution (1/2 liter)

    Pb(NO3)2 100 16.5

    Al(NO3)3 200 11.0

    CrCl3.6H2O 200 13.5

    NiCl2.6H2O 200 12.0

    Co(NO3)2.6H2O 200 15.0

    CdCl2 5H2O 150 13.5

    BaCl2.2H2O 200 12.0

    MgSO4.7H2O 200 12.0

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    Groups No. of

    students

    Means SD t

    value

    Effect

    size

    Experimental

    group

    60 23.81 1.95 10.77 2.26

    large

    effect

    Control group 33 20.30 1.22

    * Significant at < 0.01

    Table 3: Means, Standard Deviations, (t) value and Effect Size of the results

    of students in the final practical observation scale for the experimental and

    control groups

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    Conclusion

    Students of the experimental group are significantly improvedtoward the principles of Benign analysis.

    Benign scheme is less expensive, and minimizing the

    production of chemical wastes.

    Students of the experimental group achieved higher cognitive

    levels (Analysis, synthesis, evaluation).

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    (6) Fahmy, A.F.M., Lagowski, J.J.; Systemic Approach in Teaching and

    Learning Aliphatic Chemistry; Modern Arab Establishment for

    printing, publishing; Cairo, Egypt (2000)

    (5) Fahmy, A.F. M., Lagowski, J. J., Systemic multiple choice questions (SMCQs)

    in Chemistry [19th ICCE, Seoul, South Korea, 12-17 August 2006].