2-2 1h nmr spectrum of 3a in cdcl3
TRANSCRIPT
2-2
PPM15 14 13 12 11 10 9 8 7 6 5 4 3 2 1 0 -1
0.90
37 1.98
142.
0563
1.00
00
0.97
642.
9306
6.36
323.
1204
13.8
63
7.7
13 7
.542
5.3
00
4.7
25 4
.262
3.9
34 3
.881
3.7
39
1H NMR spectrum of 3a in CDCl3
x tol
x
2-31H NMR spectrum of 3a (top) and acenaphthenequinonemonophenylhydrazone (bottom) in C6D6
PPM15.0 14.0 13.0 12.0 11.0 10.0 9.0 8.0 7.0 6.0 5.0 4.0 3.0 2.0 1.0 0.0 -1.0
14.206
13.349
x tol
x
2-413C NMR spectrum of 3a in CDCl3
PPM200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 0 -10
190.518
185.614
170.254
168.839
167.153
164.874
63.861
55.856
54.326
54.203
53.298
52.878
43.795
x tol
x
x tol
x
x
x
2-5DEPT135 NMR spectrum of 3a in CDCl3
PPM200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 0
129.
892
124.
908
115.
324
54.
325
54.
205
53.
298
52.
881
43.
774
29.
670
x
x
x xx
2-6HMQC NMR spectrum of 3a (13C enriched) in C6D6
2-7HMBC NMR spectrum of 3a (13C enriched) in C6D6
2-8HMBC NMR spectrum of 3a (13C enriched) in C6D6
5.5 5.0 4.519
018
017
016
015
014
013
0
PPM
151.74155.06
128.66
145.24
135.77
147.88
2JCH
2JCH
3JCH
3JCH
3JCH3JCH
C(5)
C(10)
C(7)C(11)C(9)C(6)
2-9INADEQUATE 1D spectrum of 3a (13C enriched) in C6D6 (Jcc=57 Hz)
PPM200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 0 -10
190.
890
186.
177
154.
975
151.
679
142.
835
140.
991
138.
172
131.
972
131.
614
129.
321
126.
740
126.
397
43.
957
2-10Selective INADEQUATE 1D spectrum of 3a (13C enriched) in C6D6(OBS2: 190.9 ppm, Jcc=57 Hz)
PPM200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 0
128.645
128.
645
2-11Selective INADEQUATE 1D spectrum of 3a (13C enriched) in C6D6(OBS2: 186.2 ppm, Jcc=57 Hz)
PPM200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 0
136.504
135.904
136.
504
135.
904
2-12Selective INADEQUATE 1D spectrum of 3a (13C enriched) in C6D6(OBS2: 44.0 ppm, Jcc=77 Hz)
PPM200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 0
155.032
151.716
155.
032
151.
716
2-13Selective INADEQUATE 1D spectrum of 3a (13C enriched) in C6D6(OBS2: 155.1 ppm, Jcc=57 Hz)
PPM200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 0
145.867
145.189
128.880
128.403
44.095
43.828
145.
867
145.
189
128.
880
128.
403
44.0
9543
.828
2-14Selective INADEQUATE 1D spectrum of the 13C enriched 3a in C6D6(OBS2: 151.7 ppm, Jcc=57 Hz)
PPM200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 0
148.074
147.716
135.990
135.534
44.087
43.824
148.
074
147.
716
135.
990
135.
534
44.0
8743
.824
2-15ES-Mass spectrum (neg.) of 3a
529R
600 650 700 750 800 850 900 950 1000 1050 1100 1150 1200 1250 1300 1350 1400 1450 1500 1550 1600m/z0
100
%
020711_7 83 (1.522) Cm (71:85) TOF MS ES- 3.88e31144.42
3879
1143.401938
1145.441738
1160.411212
1161.44958