2012 annual report · 4/30/2013 · 2012 annual report april 2013 pet solutions, llc permit no....

2012 ANNUAL REPORT APRIL 2013

PET SOLUTIONS, LLC

PERMIT NO. 3778-WR-5 AFIN: 75-00051

PREPARED FOR: PET SOLUTIONS, LLC 10511 GAUGE ROAD

DANVILLE, ARKANSAS 72833 (479) 576-2050

Prepared by:

8114 Cantrell, Suite 350 Little Rock, AR 72227 Phone 501.663.8800 www.HarborEnv.com

2012 Annual Report Pet Solutions, LLC – Danville, Arkansas

Permit No. 3778-WR-5 April 2013

Harbor Environmental & Safety P a g e | i

Table of Contents

Table of Contents ............................................................................................................................ i

1. Introduction and Background ................................................................................................. 1

2. Land Application Dates, Locations, Quantities, and Methods ................................................ 1

3. Land Application Nutrients, PAN, Metals, and Cover Crop .................................................... 2

4. Soil pH ..................................................................................................................................... 2

5. Certification of Annual Report ................................................................................................ 3

APPENDICES Appendix A: Facility Site Map Appendix B: Land Application Dates, Locations, and Quantities Appendix C: Land Application Nutrients, PAN, Metals, and Cover Crop Appendix D: Analytical Data –Wastewater and Soils Data

2012 Annual Report Pet Solutions, LLC – Danville, Arkansas Permit No. 3778‐WR‐5 April 2013

Harbor Environmental & Safety P a g e | 1

1. Introduction and Background

This annual report for the Pet Solutions, LLC (Pet) protein conversion facility is prepared in accordance with Part II, Specific Condition 19 of Permit No. 3778‐WR‐5. Specific Condition 14 requires an annual report be prepared and submitted to the Arkansas Department of Environmental Quality (ADEQ) prior to May 1 of each year. Permit 3778‐WR‐5 became effective on June 1, 2010, so this report reflects some of the transition between the previous permit, 3778‐WR‐4, and the current permit. Namely, the sampling for 2012 was performed in accordance with the previous permit, Permit 3778‐WR‐4. The waste and soil analyses included in this report were performed in accordance with EPA Document SW‐846, “Test methods for Evaluation of Solid Waste”. The following information is contingent on the fact that all information supplied to Harbor Environmental and Safety as of the date of this report is unquestionably accurate and provided in good faith. The annual report addresses the following:

A. land application dates; B. land application locations; C. quantities of waste applied in dry tons per acre per year and/or in gallons per acre

per year; D. methods of disposal; E. amounts of nutrients applied; F. total amount of PAN applied on each field (pounds/ acre); G. cover crop of each field; H. total metals added (in that particular year) in lbs per acre; I. total metals applied to date; J. copies of the waste and soil analyses.

2. Land Application Dates, Locations, Quantities, and Methods

Pet is permitted to land apply processed wastewater from the facility’s final wastewater pond, Pond 3, onto five (5) tracts. In 2012, Pet utilized three (3) tracts for land application, Tracts 2, 3, and 4. The wastewater is surface applied using irrigation hose reel with a traveling spray gun nozzle. If the waste is applied to land that is not vegetated, the applied area is then disked in to incorporate the waste into the soil. Appendix B presents for each tract the date and location of land application.



3. Land Application Nutrients, PAN, Metals, and Cover Crop

Pet land applies processed wastewater onto a Bermuda cover crop. The waste is applied in compliance with permitted limits for nutrients, plant available nitrogen (PAN), and metals. Appendix C presents for each tract the following:

amounts of nutrients applied; total amount of PAN applied on each field (pounds/ acre); total metals added (in that particular year) in lbs per acre; total metals applied to date;

Copies of the waste and soil analyses are presented in Appendix D.

4. Soil pH The pH values listed in the laboratory reports are not valid, as they were tested out of holding time. Pet sampled the soil and tested the pH with a facility pH meter, and these values are presented in Appendix D and as follows:

Area 1: 6.15 s.u. and 6.43 s.u. Area 2: 6.55 s.u. Area 3: 5.30 s.u. Area 4: 5.25 s.u. Area 5: 5.83 s.u.

In light of these results, Pet will seek and then follow the lime application recommendations from the University of Arkansas Cooperative Extension Service for Areas 3 and 4.



Harbor Environmental & Safety

APPENDIX A

Facility Site Map




APPENDIX B

Land Application Dates, Locations, and Quantities

Application Documentation - Tract 2 - 2012Volume of Waste, Gallons

JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC1 0 0 0 0 0 0 0 0 0 0 25,200 02 0 0 0 0 0 0 0 0 151,200 0 25,200 03 0 0 0 0 0 0 0 0 0 0 0 04 0 0 0 0 0 0 0 0 0 0 0 05 0 0 0 0 0 50,400 0 0 0 0 0 06 0 0 0 0 0 37,800 0 0 0 0 0 07 0 0 0 0 0 0 0 0 0 0 0 08 0 0 0 0 0 0 0 0 0 0 0 09 0 0 0 0 0 0 0 0 0 0 0 0

10 0 0 0 0 0 0 0 0 151,200 0 0 011 0 0 0 0 0 0 0 0 0 0 0 012 0 0 0 0 0 0 0 151,200 0 0 0 013 0 0 0 0 0 0 0 226,800 0 0 0 014 0 0 176,400 0 0 0 0 75,600 0 0 0 015 0 0 302,400 0 0 0 0 0 0 0 0 016 0 0 126,000 0 0 0 0 0 0 0 0 017 0 0 0 0 0 0 0 0 0 0 0 018 0 0 0 0 0 0 0 0 0 0 0 019 0 0 0 0 0 63,000 0 0 0 0 0 020 0 0 0 0 0 63,000 0 0 0 0 0 021 0 0 0 0 0 0 0 0 0 75,600 0 022 0 0 0 0 0 0 0 0 113,400 0 0 023 0 0 0 0 0 0 0 0 0 0 0 024 0 0 0 0 0 0 0 0 0 0 0 025 0 0 0 0 0 0 0 0 0 0 0 026 0 0 0 0 0 0 0 0 0 0 0 027 0 0 0 0 0 0 0 0 0 0 0 028 0 0 0 0 0 0 0 0 0 0 0 029 0 0 0 0 0 0 0 0 0 0 0 030 0 0 0 0 0 0 0 0 0 0 031 0 0 0 0 0 0 0

Total 0 0 604,800 0 0 214,200 0 453,600 415,800 75,600 50,400 0

Total, 2012 1,814,400 Gallons12.9 Acres

140,651 Gal/Acre


JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC1 0 0 0 50,400 0 0 0 0 0 0 0 02 0 0 0 88,200 0 0 0 0 0 0 0 03 0 0 0 0 0 0 0 0 0 0 0 100,8004 0 0 0 0 0 0 88,200 0 0 0 0 75,6005 0 0 0 0 0 0 63,000 0 0 0 0 06 0 0 0 0 0 0 0 0 0 0 0 07 0 0 0 0 0 0 0 0 0 0 25,200 08 0 0 0 0 0 0 0 0 0 0 0 09 0 0 0 0 0 0 0 0 0 75,600 37,800 0

10 0 0 0 0 0 0 0 0 0 0 0 011 0 0 0 0 0 0 0 0 0 0 0 012 0 100,800 0 0 0 0 0 0 0 0 0 013 0 0 0 0 0 0 0 0 0 0 37,800 014 0 0 0 0 201,600 0 0 0 0 0 0 015 0 0 0 0 302,400 0 0 0 0 0 0 016 0 0 0 0 100,800 0 0 0 0 0 0 017 0 0 0 0 0 0 0 0 0 0 0 018 0 0 0 0 0 0 0 0 0 0 0 019 0 0 0 0 0 0 0 0 0 151,200 0 020 0 0 0 0 0 0 63,000 0 0 0 0 021 0 0 0 0 0 0 63,000 0 0 0 0 022 0 0 0 0 0 0 0 0 0 0 0 023 0 0 0 0 0 0 0 0 0 0 0 024 0 0 0 0 0 0 0 0 0 0 0 025 0 0 0 88,200 0 0 50,400 0 0 0 0 026 0 0 0 88,200 0 0 63,000 0 0 0 0 027 0 0 0 0 0 0 0 0 0 0 0 028 0 0 0 0 0 0 0 0 0 0 0 029 0 0 0 0 0 0 0 0 0 0 0 030 0 0 0 0 0 0 0 0 0 0 031 0 0 0 0 0 0 0

Total 0 100,800 0 315,000 604,800 0 390,600 0 0 226,800 100,800 176,400


185,942 Gal/Acre


JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC1 0 0 0 0 0 0 0 0 0 0 0 02 0 0 0 0 0 0 0 0 0 0 0 03 0 0 0 0 0 0 0 0 0 0 0 04 0 0 0 0 0 0 0 0 0 0 0 05 0 0 0 0 0 0 0 0 0 0 0 06 0 0 0 0 0 0 0 0 0 0 50,400 75,6007 0 0 0 0 0 0 0 0 0 0 0 100,8008 0 0 0 0 0 0 0 0 0 0 0 09 0 0 0 0 0 0 0 0 0 0 0 0

10 0 0 0 0 0 0 0 0 0 0 0 011 0 0 0 0 0 0 0 0 0 0 0 012 0 0 0 0 0 0 0 0 0 151,200 0 013 0 0 0 0 0 0 0 0 0 0 0 014 0 0 0 0 0 0 0 0 0 0 0 015 0 0 0 0 0 0 0 0 0 0 0 016 0 0 0 0 0 0 0 0 0 0 0 017 0 0 0 0 0 0 0 0 0 0 0 018 0 0 0 0 0 0 0 0 0 0 0 019 0 0 0 0 0 0 0 0 0 0 0 020 0 0 0 0 0 0 0 0 0 0 0 021 0 0 0 0 0 0 0 0 0 0 0 022 0 0 0 0 0 0 0 0 0 0 0 023 0 0 0 0 0 0 0 0 0 0 0 024 0 0 0 0 0 0 0 0 0 0 0 025 0 0 0 0 0 0 0 0 0 0 0 026 0 0 0 0 0 0 0 0 0 0 0 027 0 0 0 0 0 0 0 0 0 0 0 028 0 0 0 0 0 0 0 0 0 0 0 029 0 0 0 0 0 0 0 0 0 0 0 030 0 0 0 0 0 0 0 0 0 0 031 0 0 0 0 0 0 0

Total 0 0 0 0 0 0 0 0 0 151,200 50,400 176,400

Total, 2012 378,000 Gallons2.3 Acres

164,348 Gal/Acre




APPENDIX C

Land Application Nutrients, PAN, Metals, and Cover Crop

Application Calculations (1/1/2012 ‐ 12/31/2012)

ADEQ Permit No.: 3778‐WR‐5 Permitee: Pet Solutions, LLC

Waste Source: Processed Wastewater Cover Crop: Bermuda

Tract: 2Nitrogen Uptake(lbs/ac): 300

Acreage: 12.9Max N Application(lbs N): 3,870.00 Nitrogen Per Gal (lbs N/gal) 0.0016 Max Application Rate per acre for Nitrogen (gal/acre): 187,257

Gallons Applied: 1,814,400.00 gallons Land Application Controlled By:Gal/Acre/Yr Applied: 140,651.16

Parameter Concentration unit

Maximum Annual Loading Rate(lbs/acre/yr)

Actual Loading Rate

(lbs/acre/yr)Arsenic 13.18 mg/kg 1.7E‐02 1.3E‐02Cadimium 0.59 mg/kg 7.8E‐04 5.9E‐04Chromium 11.76 mg/kg 1.6E‐02 1.2E‐02Copper 23.53 mg/kg 3.1E‐02 2.3E‐02Lead 17.65 mg/kg 2.3E‐02 1.8E‐02Mercury 0.24 mg/kg 3.1E‐04 2.3E‐04Molybdenum 35.29 mg/kg 4.7E‐02 3.5E‐02Nickel 11.76 mg/kg 1.6E‐02 1.2E‐02Selenium 58.82 mg/kg 7.8E‐02 5.9E‐02Zinc 17.65 mg/kg 2.3E‐02 1.8E‐02Total Solids 0.09 %BOD 673.75 mg/L 1,052.21 790.33 NO3 26.05 mg/L 40.68 30.56 NO2 20.60 mg/L 32.17 24.16 Ammonia 323.50 mg/L 505.22 379.48 TKN 269.15 mg/L 420.34 315.72 Total P 70.25 mg/L 109.71 82.41 Total K 76.80 mg/L 119.94 90.09 pH 7.65 S.U.O&G 13.80 mg/L 21.55 16.19

PAN 192.10 mg/L 300.00 225.33 Within Permit Limits for PAN? Yes

Application Calculations ‐ Tract 2 ‐ 2012(1/1/2012 ‐ 12/31/2012)


Permit Ceiling Concentration Limit

(mg/kg)Within Permit

Limits?Arsenic 13.18 mg/kg 75 YesCadmium 0.59 mg/kg 85 YesCopper 23.53 mg/kg 4,300 YesLead 17.65 mg/kg 840 YesMercury 0.24 mg/kg 57 YesMolybdenum 35.29 mg/kg 75 YesNickel 11.76 mg/kg 420 YesSelenium 58.82 mg/kg 100 YesZinc 17.65 mg/kg 7,500 Yes


Parameter2012 Loading (lb/acre) unit

Cumulative Loading Prior to 2012 (lb/acre)

Cumulative Loading (lb/acre) unit

Permit Cumulative Loading (lb/acre) Within Permit Limits?

Arsenic 1.3E‐02 lb/acre 1.3E‐02 lb/acre 37 YesCadmium 5.9E‐04 lb/acre 5.9E‐04 lb/acre 35 YesCopper 2.3E‐02 lb/acre 2.3E‐02 lb/acre 1,350 YesLead 1.8E‐02 lb/acre 1.8E‐02 lb/acre 270 YesMercury 2.3E‐04 lb/acre 2.3E‐04 lb/acre 15 YesMolybdenum 3.5E‐02 lb/acre 3.5E‐02 lb/acre N/A YesNickel 1.2E‐02 lb/acre 1.2E‐02 lb/acre 378 YesSelenium 5.9E‐02 lb/acre 5.9E‐02 lb/acre 90 YesZinc 1.8E‐02 lb/acre 1.8E‐02 lb/acre 2,520 Yes

Not Required by Previous Permit ‐ No

Data

Inputs from LandApplication Records

Nitrogen Application Rate

Inputs from Waste AnalysisInputs from Permit

Application Calculations (1/1/2012 ‐ 12/31/2012)ADEQ Permit No.: 3778‐WR‐5 Permitee: Pet Solutions, LLC







Actual Loading Rate

(lbs/acre/yr)Arsenic 13.18 mg/kg 1.7E‐02 1.7E‐02Cadimium 0.59 mg/kg 7.8E‐04 7.8E‐04Chromium 11.76 mg/kg 1.6E‐02 1.6E‐02Copper 23.53 mg/kg 3.1E‐02 3.1E‐02Lead 17.65 mg/kg 2.3E‐02 2.3E‐02Mercury 0.24 mg/kg 3.1E‐04 3.1E‐04Molybdenum 35.29 mg/kg 4.7E‐02 4.7E‐02Nickel 11.76 mg/kg 1.6E‐02 1.6E‐02Selenium 58.82 mg/kg 7.8E‐02 7.8E‐02Zinc 17.65 mg/kg 2.3E‐02 2.3E‐02Total Solids 0.09 %BOD 673.75 mg/L 1,052.21 1,044.82 NO3 26.05 mg/L 40.68 40.40 NO2 20.60 mg/L 32.17 31.95 Ammonia 323.50 mg/LTKN 269.15 mg/L 420.34 417.39 Total P 70.25 mg/L 109.71 108.94 Total K 76.80 mg/L 119.94 119.10 pH 7.65 S.U.O&G 13.80 mg/L 21.55 21.40





(mg/L)Within Permit







Arsenic 1.7E‐02 lb/acre 1.7E‐02 lb/acre 37 YesCadmium 7.8E‐04 lb/acre 7.8E‐04 lb/acre 35 YesChromium 1.6E‐02 lb/acre 1.6E‐02 lb/acre 1,350 YesCopper 3.1E‐02 lb/acre 3.1E‐02 lb/acre 270 YesLead 2.3E‐02 lb/acre 2.3E‐02 lb/acre 15 YesMercury 3.1E‐04 lb/acre 3.1E‐04 lb/acre N/A YesMolybdenum 4.7E‐02 lb/acre 4.7E‐02 lb/acre 378 YesNickel 1.6E‐02 lb/acre 1.6E‐02 lb/acre 90 YesSelenium 7.8E‐02 lb/acre 7.8E‐02 lb/acre 2,520 YesZinc 2.3E‐02 lb/acre 2.3E‐02 lb/acre



Data

Inputs from Waste AnalysisInputs from PermitInputs from Land

Application Records




Acreage: 2.3Max N Application(lbs N): 690.00 Nitrogen Per Gal (lbs N/gal) 0.0016 Max Application Rate per acre for Nitrogen (gal/acre): 187,257

Gallons Applied: 378,000.00 gallons Land Application Controlled By:Gal/Acre/Yr Applied: 164,347.83



Actual Loading Rate

(lbs/acre/yr)Arsenic 13.18 mg/kg 1.7E‐02 1.5E‐02Cadimium 0.59 mg/kg 7.8E‐04 6.9E‐04Chromium 11.76 mg/kg 1.6E‐02 1.4E‐02Copper 23.53 mg/kg 3.1E‐02 2.7E‐02Lead 17.65 mg/kg 2.3E‐02 2.1E‐02Mercury 0.24 mg/kg 3.1E‐04 2.7E‐04Molybdenum 35.29 mg/kg 4.7E‐02 4.1E‐02Nickel 11.76 mg/kg 1.6E‐02 1.4E‐02Selenium 58.82 mg/kg 7.8E‐02 6.9E‐02Zinc 17.65 mg/kg 2.3E‐02 2.1E‐02Total Solids 0.09 %BOD 673.75 mg/L 1,052.21 923.48 NO3 26.05 mg/L 40.68 35.71 NO2 20.60 mg/L 32.17 28.24 Ammonia 323.50 mg/LTKN 269.15 mg/L 420.34 368.91 Total P 70.25 mg/L 109.71 96.29 Total K 76.80 mg/L 119.94 105.27 pH 7.65 S.U.O&G 13.80 mg/L 21.55 18.92





(mg/L)Within Permit







Arsenic 1.5E‐02 lb/acre 1.5E‐02 lb/acre 37 YesCadmium 6.9E‐04 lb/acre 6.9E‐04 lb/acre 35 YesChromium 1.4E‐02 lb/acre 1.4E‐02 lb/acreCopper 2.7E‐02 lb/acre 2.7E‐02 lb/acre 1,350 YesLead 2.1E‐02 lb/acre 2.1E‐02 lb/acre 270 YesMercury 2.7E‐04 lb/acre 2.7E‐04 lb/acre 15 YesMolybdenum 4.1E‐02 lb/acre 4.1E‐02 lb/acre N/A YesNickel 1.4E‐02 lb/acre 1.4E‐02 lb/acre 378 YesSelenium 6.9E‐02 lb/acre 6.9E‐02 lb/acre 90 YesZinc 2.1E‐02 lb/acre 2.1E‐02 lb/acre 2,520 Yes


Data

Inputs from PermitInputs from Land

Application Records

Inputs from Waste Analysis





APPENDIX D

Analytical Data Wastewater and Soils Data

Pet Solutions LLC

Project: Monthly Lagoon SamplesDanville, AR 72833

10511 Gauge Rd.

Bryan Posey

17 April 2012

Date Received: 10-Apr-12 12:38

Lab Number:

Date/Time Collected:

Sample Matrix:

4/10/12 9:00

ANALYTICAL RESULTS

Sample Name: Lagoon #3

1204100-01

Water

Units Result Date/Time Analyzed BatchAnions MethodQualifier(s)

Nitrate as N mg/L 51.6 A204118 300.0/9056A4/10/12 18:21

Nitrite as N mg/L 40.7 A204118 300.0/9056A4/10/12 18:21

Units Result Date/Time Analyzed BatchTotal Metals MethodQualifier(s)

Arsenic mg/L 0.0112 A204119 200.74/11/12 13:13

mg/L < 0.000500Cadmium A204119 200.74/11/12 13:13mg/L < 0.0100Chromium A204119 200.74/11/12 13:13mg/L < 0.0200Copper A204119 200.74/11/12 13:13mg/L < 0.0150Lead A204119 200.74/11/12 13:13mg/L < 0.000200Mercury A204141 245.1/7470A4/11/12 16:22mg/L < 0.0300Molybdenum A204119 200.74/11/12 13:13mg/L < 0.0100Nickel A204119 200.74/11/12 13:13

Potassium mg/L 76.8 A204119 200.74/11/12 13:13

mg/L < 0.0500Selenium A204119 200.74/11/12 13:13Zinc mg/L 0.0150 A204119 200.74/11/12 13:13

Units Result Date/Time Analyzed BatchWet Chemistry MethodQualifier(s)

% Volatile Solids % by WT 35.9 A204161 160.44/12/12 15:13

Ammonia as N mg/L 92.0 A204151 4500-NH3D4/12/12 10:26

BOD-5 mg/L 37.5 A204204 5210B4/12/12 8:40

mg/L < 2.6Oil and Grease A204127 1664A4/11/12 9:00pH S.U. 7.25 A204125 150.2/9040C4/10/12 15:05E2

TKN mg/L 58.3 A204173 4500-Norg C4/13/12 9:29

Total Phosphorus mg/L 34.5 A204191 4500-P B5,E4/16/12 11:38

Total Solids % by WT 0.0850 A204160 2540 B4/12/12 15:13

Page 3 of 5 This report must be reproduced in its entirety.

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Pet Solutions LLC

Project: Pond SamplesDanville, AR 72833

10511 Gauge Rd.

Dan Craig

12 July 2012

Date Received: 05-Jul-12 10:26

Lab Number:


Sample Matrix:

7/4/12 6:00

ANALYTICAL RESULTS

Sample Name: Pond 3 Affluent Mid-Pond

1207033-04

Water


Chloride mg/L 368 A207063 300.0/9056A7/6/12 4:46ETmg/L < 0.500Nitrate as N A207063 300.0/9056A7/5/12 14:43ET

mg/L < 0.500Nitrite as N A207063 300.0/9056A7/5/12 14:43ET

Units Result Date/Time Analyzed BatchDissolved Sulfide MethodQualifier(s)

mg/L < 0.100Sulfide A207118 4500S2-D7/10/12 15:51E20, ET

Units Result Date/Time Analyzed BatchDissolved Sulfite MethodQualifier(s)

mg/L < 4.00Sulfite A207083 4500-SO3 B7/6/12 13:30E2, ET


Ammonia as N mg/L 555 A207101 4500-NH3D7/10/12 10:03E3, ETBOD-5 mg/L 1310 A207108 5210B7/10/12 11:32ET

Dissolved Oxygen mg/L 0.0600 A207069 4500-O-G7/5/12 13:20E2mg/L < 25Oil and Grease A207100 1664A7/11/12 9:39E3, ET

pH S.U. 8.05 A207086 150.2/9040C7/6/12 15:00E2Sulfide mg/L 0.172 A207111 4500S2-D7/10/12 9:45E20, E3, ET

TDS mg/L 1800 A207096 2540C7/9/12 12:52ETTKN mg/L 480 A207097 4500-Norg C7/9/12 10:18E3, ET

Total Alkalinity mg/L 1820 A207106 2320 B7/10/12 10:58ETTotal Phosphorus mg/L 106 A207123 4500-P B5,E7/11/12 15:23E3, ET

TSS mg/L 380 A207098 2540D7/9/12 10:43ETCBOD mg/L 258 A207108 5210B7/10/12 11:32B-01, ET


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Pet Solutions LLC

Project: Land Application Permit SamplesDanville, AR 72833

10511 Gauge Rd.

Bryan Posey

28 December 2011

Date Received: 21-Dec-11 14:06

Lab Number:


Sample Matrix:

12/21/11 10:15

ANALYTICAL RESULTS

Sample Name: Soil Sample #1

1112289-01

Soil


mg/kg < 2.50Chloride A112307 9056A12/22/11 9:33mg/kg < 5.00Nitrate as N A112307 9056A12/22/11 9:33

Units Result Date/Time Analyzed BatchCation Exchange Capacity MethodQualifier(s)

CEC meq/100 g 3.45 A112305 9081 mod.12/27/11 15:21


Arsenic mg/kg dry 6.55 A112306 6010C12/27/11 16:28

Cadmium mg/kg dry 0.352 A112306 6010C12/27/11 16:28

Chromium mg/kg dry 25.8 A112306 6010C12/27/11 16:28

Copper mg/kg dry 6.53 A112306 6010C12/27/11 16:28

Lead mg/kg dry 17.1 A112306 6010C12/27/11 16:28

Magnesium mg/kg dry 612 A112306 6010C12/27/11 16:28E20mg/kg dry < 0.020Mercury A112330 7471B12/28/11 11:03mg/kg dry < 2.10Molybdenum A112306 6010C12/27/11 16:28

Nickel mg/kg dry 14.0 A112306 6010C12/27/11 16:28

Phosphorus mg/kg dry 553 A112306 6010C12/27/11 16:28E20Potassium mg/kg dry 805 A112306 6010C12/27/11 16:28

mg/kg dry < 5.26Selenium A112306 6010C12/27/11 16:28Zinc mg/kg dry 34.6 A112306 6010C12/27/11 16:28


pH S.U. 5.01 A112292 9045D12/21/11 15:45E2Specific Conductance (EC) uS/cm 16.0 A112298 120.1/9050A12/21/11 15:45


Pet Solutions LLC


10511 Gauge Rd.

Bryan Posey

28 December 2011


Lab Number:


Sample Matrix:

12/21/11 10:31

ANALYTICAL RESULTS


1112289-02

Soil




CEC meq/100 g 2.11 A112305 9081 mod.12/27/11 15:21

Units Result Date/Time Analyzed BatchTotal Metals MethodQualifier(s)mg/kg dry < 2.99Arsenic A112306 6010C12/27/11 16:40mg/kg dry < 0.299Cadmium A112306 6010C12/27/11 16:40



Lead mg/kg dry 9.42 A112306 6010C12/27/11 16:40

Magnesium mg/kg dry 446 A112306 6010C12/27/11 16:40

Mercury mg/kg dry 0.018 A112330 7471B12/28/11 11:10mg/kg dry < 2.39Molybdenum A112306 6010C12/27/11 16:40


Phosphorus mg/kg dry 549 A112306 6010C12/27/11 16:40

Potassium mg/kg dry 496 A112306 6010C12/27/11 16:40mg/kg dry < 5.98Selenium A112306 6010C12/27/11 16:40

Zinc mg/kg dry 24.0 A112306 6010C12/27/11 16:40




Pet Solutions LLC


10511 Gauge Rd.

Bryan Posey

28 December 2011


Lab Number:


Sample Matrix:

12/21/11 10:46

ANALYTICAL RESULTS


1112289-03

Soil




CEC meq/100 g 2.16 A112305 9081 mod.12/27/11 15:21






Lead mg/kg dry 15.3 A112306 6010C12/27/11 16:44

Magnesium mg/kg dry 661 A112306 6010C12/27/11 16:44mg/kg dry < 0.022Mercury A112330 7471B12/28/11 11:12mg/kg dry < 2.22Molybdenum A112306 6010C12/27/11 16:44




Zinc mg/kg dry 35.5 A112306 6010C12/27/11 16:44




Pet Solutions LLC


10511 Gauge Rd.

Bryan Posey

28 December 2011


Lab Number:


Sample Matrix:

12/21/11 10:53

ANALYTICAL RESULTS


1112289-04

Soil




CEC meq/100 g 4.39 A112305 9081 mod.12/27/11 15:21






Lead mg/kg dry 18.3 A112306 6010C12/27/11 16:48






Zinc mg/kg dry 61.5 A112306 6010C12/27/11 16:48




Pet Solutions LLC


10511 Gauge Rd.

Bryan Posey

28 December 2011


Lab Number:


Sample Matrix:

12/21/11 11:02

ANALYTICAL RESULTS


1112289-05

Soil




CEC meq/100 g 4.71 A112305 9081 mod.12/27/11 15:21






Lead mg/kg dry 20.1 A112306 6010C12/27/11 16:52






Zinc mg/kg dry 59.4 A112306 6010C12/27/11 16:52




Pet Solutions LLC


10511 Gauge Rd.

Bryan Posey

28 December 2011


Lab Number:


Sample Matrix:

12/21/11 11:07

ANALYTICAL RESULTS


1112289-06

Soil


Chloride mg/kg 3.01 A112307 9056A12/22/11 11:35

mg/kg < 5.00Nitrate as N A112307 9056A12/22/11 11:35


CEC meq/100 g 4.07 A112305 9081 mod.12/27/11 15:21






Lead mg/kg dry 15.6 A112306 6010C12/27/11 17:14





Zinc mg/kg dry 35.1 A112306 6010C12/27/11 17:14




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Soil Sample pH readings 12/21/11

Sample #1 – 6.55 @ 10:15 AM (Area 2)

Sample #2 – 5.30 @ 10:31 AM (Area 3)

Sample #3 – 5.25 @ 10:46 AM (Area 4)

Sample #4 – 5.83 @ 10:53 AM (Area 5)

Sample #5 – 6.15 @ 11:02 AM (Area 1)

Sample #6 – 6.43 @ 11:07 AM (Area 1)

From: Andrew RikeTo: Water Permit ApplicationCc: [email protected]; Bryan Posey ([email protected]); [email protected]: Pet Solutions 2012 Land Application Annual Report - Permit 3778-WR-5Date: Tuesday, April 30, 2013 5:42:53 PMAttachments: Pet Solutions Annual Report 2012.pdf

Dear Sir or Madam, On behalf of Pet Solutions, LLC, please find the attached 2012 Land Application Annual Report forPermit 3778-WR-5. Thank you for your review of this report. Sincerely, Andrew Rike, P.E.

8114 Cantrell Road, Suite 350Little Rock, AR 72227501.663.8800 (tel)501.765.0440 (cell)501.588.0123 (fax)www.harborenv.com
mailto:[email protected]:[email protected]:[email protected]:[email protected]:[email protected]://www.harborenv.com/

2012 ANNUAL REPORT APRIL 2013

PET SOLUTIONS, LLC

PERMIT NO. 3778-WR-5 AFIN: 75-00051

PREPARED FOR: PET SOLUTIONS, LLC 10511 GAUGE ROAD

DANVILLE, ARKANSAS 72833 (479) 576-2050

Prepared by:

8114 Cantrell, Suite 350 Little Rock, AR 72227 Phone 501.663.8800 www.HarborEnv.com



Harbor Environmental & Safety P a g e | i

Table of Contents

Table of Contents ............................................................................................................................ i

1. Introduction and Background ................................................................................................. 1

2. Land Application Dates, Locations, Quantities, and Methods ................................................ 1

3. Land Application Nutrients, PAN, Metals, and Cover Crop .................................................... 2

4. Soil pH ..................................................................................................................................... 2

5. Certification of Annual Report ................................................................................................ 3

APPENDICES Appendix A: Facility Site Map Appendix B: Land Application Dates, Locations, and Quantities Appendix C: Land Application Nutrients, PAN, Metals, and Cover Crop Appendix D: Analytical Data –Wastewater and Soils Data



1. Introduction and Background

This annual report for the Pet Solutions, LLC (Pet) protein conversion facility is prepared in accordance with Part II, Specific Condition 19 of Permit No. 3778‐WR‐5. Specific Condition 14 requires an annual report be prepared and submitted to the Arkansas Department of Environmental Quality (ADEQ) prior to May 1 of each year. Permit 3778‐WR‐5 became effective on June 1, 2010, so this report reflects some of the transition between the previous permit, 3778‐WR‐4, and the current permit. Namely, the sampling for 2012 was performed in accordance with the previous permit, Permit 3778‐WR‐4. The waste and soil analyses included in this report were performed in accordance with EPA Document SW‐846, “Test methods for Evaluation of Solid Waste”. The following information is contingent on the fact that all information supplied to Harbor Environmental and Safety as of the date of this report is unquestionably accurate and provided in good faith. The annual report addresses the following:

A. land application dates; B. land application locations; C. quantities of waste applied in dry tons per acre per year and/or in gallons per acre

per year; D. methods of disposal; E. amounts of nutrients applied; F. total amount of PAN applied on each field (pounds/ acre); G. cover crop of each field; H. total metals added (in that particular year) in lbs per acre; I. total metals applied to date; J. copies of the waste and soil analyses.

2. Land Application Dates, Locations, Quantities, and Methods

Pet is permitted to land apply processed wastewater from the facility’s final wastewater pond, Pond 3, onto five (5) tracts. In 2012, Pet utilized three (3) tracts for land application, Tracts 2, 3, and 4. The wastewater is surface applied using irrigation hose reel with a traveling spray gun nozzle. If the waste is applied to land that is not vegetated, the applied area is then disked in to incorporate the waste into the soil. Appendix B presents for each tract the date and location of land application.



3. Land Application Nutrients, PAN, Metals, and Cover Crop

Pet land applies processed wastewater onto a Bermuda cover crop. The waste is applied in compliance with permitted limits for nutrients, plant available nitrogen (PAN), and metals. Appendix C presents for each tract the following:

amounts of nutrients applied; total amount of PAN applied on each field (pounds/ acre); total metals added (in that particular year) in lbs per acre; total metals applied to date;

Copies of the waste and soil analyses are presented in Appendix D.

4. Soil pH The pH values listed in the laboratory reports are not valid, as they were tested out of holding time. Pet sampled the soil and tested the pH with a facility pH meter, and these values are presented in Appendix D and as follows:

Area 1: 6.15 s.u. and 6.43 s.u. Area 2: 6.55 s.u. Area 3: 5.30 s.u. Area 4: 5.25 s.u. Area 5: 5.83 s.u.

In light of these results, Pet will seek and then follow the lime application recommendations from the University of Arkansas Cooperative Extension Service for Areas 3 and 4.




APPENDIX A

Facility Site Map




APPENDIX B

Land Application Dates, Locations, and Quantities


JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC1 0 0 0 0 0 0 0 0 0 0 25,200 02 0 0 0 0 0 0 0 0 151,200 0 25,200 03 0 0 0 0 0 0 0 0 0 0 0 04 0 0 0 0 0 0 0 0 0 0 0 05 0 0 0 0 0 50,400 0 0 0 0 0 06 0 0 0 0 0 37,800 0 0 0 0 0 07 0 0 0 0 0 0 0 0 0 0 0 08 0 0 0 0 0 0 0 0 0 0 0 09 0 0 0 0 0 0 0 0 0 0 0 0

10 0 0 0 0 0 0 0 0 151,200 0 0 011 0 0 0 0 0 0 0 0 0 0 0 012 0 0 0 0 0 0 0 151,200 0 0 0 013 0 0 0 0 0 0 0 226,800 0 0 0 014 0 0 176,400 0 0 0 0 75,600 0 0 0 015 0 0 302,400 0 0 0 0 0 0 0 0 016 0 0 126,000 0 0 0 0 0 0 0 0 017 0 0 0 0 0 0 0 0 0 0 0 018 0 0 0 0 0 0 0 0 0 0 0 019 0 0 0 0 0 63,000 0 0 0 0 0 020 0 0 0 0 0 63,000 0 0 0 0 0 021 0 0 0 0 0 0 0 0 0 75,600 0 022 0 0 0 0 0 0 0 0 113,400 0 0 023 0 0 0 0 0 0 0 0 0 0 0 024 0 0 0 0 0 0 0 0 0 0 0 025 0 0 0 0 0 0 0 0 0 0 0 026 0 0 0 0 0 0 0 0 0 0 0 027 0 0 0 0 0 0 0 0 0 0 0 028 0 0 0 0 0 0 0 0 0 0 0 029 0 0 0 0 0 0 0 0 0 0 0 030 0 0 0 0 0 0 0 0 0 0 031 0 0 0 0 0 0 0

Total 0 0 604,800 0 0 214,200 0 453,600 415,800 75,600 50,400 0


140,651 Gal/Acre


JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC1 0 0 0 50,400 0 0 0 0 0 0 0 02 0 0 0 88,200 0 0 0 0 0 0 0 03 0 0 0 0 0 0 0 0 0 0 0 100,8004 0 0 0 0 0 0 88,200 0 0 0 0 75,6005 0 0 0 0 0 0 63,000 0 0 0 0 06 0 0 0 0 0 0 0 0 0 0 0 07 0 0 0 0 0 0 0 0 0 0 25,200 08 0 0 0 0 0 0 0 0 0 0 0 09 0 0 0 0 0 0 0 0 0 75,600 37,800 0

10 0 0 0 0 0 0 0 0 0 0 0 011 0 0 0 0 0 0 0 0 0 0 0 012 0 100,800 0 0 0 0 0 0 0 0 0 013 0 0 0 0 0 0 0 0 0 0 37,800 014 0 0 0 0 201,600 0 0 0 0 0 0 015 0 0 0 0 302,400 0 0 0 0 0 0 016 0 0 0 0 100,800 0 0 0 0 0 0 017 0 0 0 0 0 0 0 0 0 0 0 018 0 0 0 0 0 0 0 0 0 0 0 019 0 0 0 0 0 0 0 0 0 151,200 0 020 0 0 0 0 0 0 63,000 0 0 0 0 021 0 0 0 0 0 0 63,000 0 0 0 0 022 0 0 0 0 0 0 0 0 0 0 0 023 0 0 0 0 0 0 0 0 0 0 0 024 0 0 0 0 0 0 0 0 0 0 0 025 0 0 0 88,200 0 0 50,400 0 0 0 0 026 0 0 0 88,200 0 0 63,000 0 0 0 0 027 0 0 0 0 0 0 0 0 0 0 0 028 0 0 0 0 0 0 0 0 0 0 0 029 0 0 0 0 0 0 0 0 0 0 0 030 0 0 0 0 0 0 0 0 0 0 031 0 0 0 0 0 0 0

Total 0 100,800 0 315,000 604,800 0 390,600 0 0 226,800 100,800 176,400


185,942 Gal/Acre


JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC1 0 0 0 0 0 0 0 0 0 0 0 02 0 0 0 0 0 0 0 0 0 0 0 03 0 0 0 0 0 0 0 0 0 0 0 04 0 0 0 0 0 0 0 0 0 0 0 05 0 0 0 0 0 0 0 0 0 0 0 06 0 0 0 0 0 0 0 0 0 0 50,400 75,6007 0 0 0 0 0 0 0 0 0 0 0 100,8008 0 0 0 0 0 0 0 0 0 0 0 09 0 0 0 0 0 0 0 0 0 0 0 0

10 0 0 0 0 0 0 0 0 0 0 0 011 0 0 0 0 0 0 0 0 0 0 0 012 0 0 0 0 0 0 0 0 0 151,200 0 013 0 0 0 0 0 0 0 0 0 0 0 014 0 0 0 0 0 0 0 0 0 0 0 015 0 0 0 0 0 0 0 0 0 0 0 016 0 0 0 0 0 0 0 0 0 0 0 017 0 0 0 0 0 0 0 0 0 0 0 018 0 0 0 0 0 0 0 0 0 0 0 019 0 0 0 0 0 0 0 0 0 0 0 020 0 0 0 0 0 0 0 0 0 0 0 021 0 0 0 0 0 0 0 0 0 0 0 022 0 0 0 0 0 0 0 0 0 0 0 023 0 0 0 0 0 0 0 0 0 0 0 024 0 0 0 0 0 0 0 0 0 0 0 025 0 0 0 0 0 0 0 0 0 0 0 026 0 0 0 0 0 0 0 0 0 0 0 027 0 0 0 0 0 0 0 0 0 0 0 028 0 0 0 0 0 0 0 0 0 0 0 029 0 0 0 0 0 0 0 0 0 0 0 030 0 0 0 0 0 0 0 0 0 0 031 0 0 0 0 0 0 0

Total 0 0 0 0 0 0 0 0 0 151,200 50,400 176,400

Total, 2012 378,000 Gallons2.3 Acres

164,348 Gal/Acre




APPENDIX C

Land Application Nutrients, PAN, Metals, and Cover Crop

Application Calculations (1/1/2012 ‐ 12/31/2012)

ADEQ Permit No.: 3778‐WR‐5 Permitee: Pet Solutions, LLC







Actual Loading Rate

(lbs/acre/yr)Arsenic 13.18 mg/kg 1.7E‐02 1.3E‐02Cadimium 0.59 mg/kg 7.8E‐04 5.9E‐04Chromium 11.76 mg/kg 1.6E‐02 1.2E‐02Copper 23.53 mg/kg 3.1E‐02 2.3E‐02Lead 17.65 mg/kg 2.3E‐02 1.8E‐02Mercury 0.24 mg/kg 3.1E‐04 2.3E‐04Molybdenum 35.29 mg/kg 4.7E‐02 3.5E‐02Nickel 11.76 mg/kg 1.6E‐02 1.2E‐02Selenium 58.82 mg/kg 7.8E‐02 5.9E‐02Zinc 17.65 mg/kg 2.3E‐02 1.8E‐02Total Solids 0.09 %BOD 673.75 mg/L 1,052.21 790.33 NO3 26.05 mg/L 40.68 30.56 NO2 20.60 mg/L 32.17 24.16 Ammonia 323.50 mg/L 505.22 379.48 TKN 269.15 mg/L 420.34 315.72 Total P 70.25 mg/L 109.71 82.41 Total K 76.80 mg/L 119.94 90.09 pH 7.65 S.U.O&G 13.80 mg/L 21.55 16.19





(mg/kg)Within Permit







Arsenic 1.3E‐02 lb/acre 1.3E‐02 lb/acre 37 YesCadmium 5.9E‐04 lb/acre 5.9E‐04 lb/acre 35 YesCopper 2.3E‐02 lb/acre 2.3E‐02 lb/acre 1,350 YesLead 1.8E‐02 lb/acre 1.8E‐02 lb/acre 270 YesMercury 2.3E‐04 lb/acre 2.3E‐04 lb/acre 15 YesMolybdenum 3.5E‐02 lb/acre 3.5E‐02 lb/acre N/A YesNickel 1.2E‐02 lb/acre 1.2E‐02 lb/acre 378 YesSelenium 5.9E‐02 lb/acre 5.9E‐02 lb/acre 90 YesZinc 1.8E‐02 lb/acre 1.8E‐02 lb/acre 2,520 Yes


Data

Inputs from LandApplication Records


Inputs from Waste AnalysisInputs from Permit








Actual Loading Rate

(lbs/acre/yr)Arsenic 13.18 mg/kg 1.7E‐02 1.7E‐02Cadimium 0.59 mg/kg 7.8E‐04 7.8E‐04Chromium 11.76 mg/kg 1.6E‐02 1.6E‐02Copper 23.53 mg/kg 3.1E‐02 3.1E‐02Lead 17.65 mg/kg 2.3E‐02 2.3E‐02Mercury 0.24 mg/kg 3.1E‐04 3.1E‐04Molybdenum 35.29 mg/kg 4.7E‐02 4.7E‐02Nickel 11.76 mg/kg 1.6E‐02 1.6E‐02Selenium 58.82 mg/kg 7.8E‐02 7.8E‐02Zinc 17.65 mg/kg 2.3E‐02 2.3E‐02Total Solids 0.09 %BOD 673.75 mg/L 1,052.21 1,044.82 NO3 26.05 mg/L 40.68 40.40 NO2 20.60 mg/L 32.17 31.95 Ammonia 323.50 mg/LTKN 269.15 mg/L 420.34 417.39 Total P 70.25 mg/L 109.71 108.94 Total K 76.80 mg/L 119.94 119.10 pH 7.65 S.U.O&G 13.80 mg/L 21.55 21.40





(mg/L)Within Permit







Arsenic 1.7E‐02 lb/acre 1.7E‐02 lb/acre 37 YesCadmium 7.8E‐04 lb/acre 7.8E‐04 lb/acre 35 YesChromium 1.6E‐02 lb/acre 1.6E‐02 lb/acre 1,350 YesCopper 3.1E‐02 lb/acre 3.1E‐02 lb/acre 270 YesLead 2.3E‐02 lb/acre 2.3E‐02 lb/acre 15 YesMercury 3.1E‐04 lb/acre 3.1E‐04 lb/acre N/A YesMolybdenum 4.7E‐02 lb/acre 4.7E‐02 lb/acre 378 YesNickel 1.6E‐02 lb/acre 1.6E‐02 lb/acre 90 YesSelenium 7.8E‐02 lb/acre 7.8E‐02 lb/acre 2,520 YesZinc 2.3E‐02 lb/acre 2.3E‐02 lb/acre



Data

Inputs from Waste AnalysisInputs from PermitInputs from Land

Application Records




Acreage: 2.3Max N Application(lbs N): 690.00 Nitrogen Per Gal (lbs N/gal) 0.0016 Max Application Rate per acre for Nitrogen (gal/acre): 187,257

Gallons Applied: 378,000.00 gallons Land Application Controlled By:Gal/Acre/Yr Applied: 164,347.83



Actual Loading Rate

(lbs/acre/yr)Arsenic 13.18 mg/kg 1.7E‐02 1.5E‐02Cadimium 0.59 mg/kg 7.8E‐04 6.9E‐04Chromium 11.76 mg/kg 1.6E‐02 1.4E‐02Copper 23.53 mg/kg 3.1E‐02 2.7E‐02Lead 17.65 mg/kg 2.3E‐02 2.1E‐02Mercury 0.24 mg/kg 3.1E‐04 2.7E‐04Molybdenum 35.29 mg/kg 4.7E‐02 4.1E‐02Nickel 11.76 mg/kg 1.6E‐02 1.4E‐02Selenium 58.82 mg/kg 7.8E‐02 6.9E‐02Zinc 17.65 mg/kg 2.3E‐02 2.1E‐02Total Solids 0.09 %BOD 673.75 mg/L 1,052.21 923.48 NO3 26.05 mg/L 40.68 35.71 NO2 20.60 mg/L 32.17 28.24 Ammonia 323.50 mg/LTKN 269.15 mg/L 420.34 368.91 Total P 70.25 mg/L 109.71 96.29 Total K 76.80 mg/L 119.94 105.27 pH 7.65 S.U.O&G 13.80 mg/L 21.55 18.92





(mg/L)Within Permit







Arsenic 1.5E‐02 lb/acre 1.5E‐02 lb/acre 37 YesCadmium 6.9E‐04 lb/acre 6.9E‐04 lb/acre 35 YesChromium 1.4E‐02 lb/acre 1.4E‐02 lb/acreCopper 2.7E‐02 lb/acre 2.7E‐02 lb/acre 1,350 YesLead 2.1E‐02 lb/acre 2.1E‐02 lb/acre 270 YesMercury 2.7E‐04 lb/acre 2.7E‐04 lb/acre 15 YesMolybdenum 4.1E‐02 lb/acre 4.1E‐02 lb/acre N/A YesNickel 1.4E‐02 lb/acre 1.4E‐02 lb/acre 378 YesSelenium 6.9E‐02 lb/acre 6.9E‐02 lb/acre 90 YesZinc 2.1E‐02 lb/acre 2.1E‐02 lb/acre 2,520 Yes


Data

Inputs from PermitInputs from Land

Application Records

Inputs from Waste Analysis





APPENDIX D

Analytical Data Wastewater and Soils Data

Pet Solutions LLC


10511 Gauge Rd.

Bryan Posey

17 April 2012


Lab Number:


Sample Matrix:

4/10/12 9:00

ANALYTICAL RESULTS

Sample Name: Lagoon #3

1204100-01

Water


Nitrate as N mg/L 51.6 A204118 300.0/9056A4/10/12 18:21

Nitrite as N mg/L 40.7 A204118 300.0/9056A4/10/12 18:21


Arsenic mg/L 0.0112 A204119 200.74/11/12 13:13

mg/L < 0.000500Cadmium A204119 200.74/11/12 13:13mg/L < 0.0100Chromium A204119 200.74/11/12 13:13mg/L < 0.0200Copper A204119 200.74/11/12 13:13mg/L < 0.0150Lead A204119 200.74/11/12 13:13mg/L < 0.000200Mercury A204141 245.1/7470A4/11/12 16:22mg/L < 0.0300Molybdenum A204119 200.74/11/12 13:13mg/L < 0.0100Nickel A204119 200.74/11/12 13:13

Potassium mg/L 76.8 A204119 200.74/11/12 13:13

mg/L < 0.0500Selenium A204119 200.74/11/12 13:13Zinc mg/L 0.0150 A204119 200.74/11/12 13:13


% Volatile Solids % by WT 35.9 A204161 160.44/12/12 15:13

Ammonia as N mg/L 92.0 A204151 4500-NH3D4/12/12 10:26

BOD-5 mg/L 37.5 A204204 5210B4/12/12 8:40

mg/L < 2.6Oil and Grease A204127 1664A4/11/12 9:00pH S.U. 7.25 A204125 150.2/9040C4/10/12 15:05E2

TKN mg/L 58.3 A204173 4500-Norg C4/13/12 9:29

Total Phosphorus mg/L 34.5 A204191 4500-P B5,E4/16/12 11:38

Total Solids % by WT 0.0850 A204160 2540 B4/12/12 15:13


Pet Solutions LLC


10511 Gauge Rd.

Bryan Posey

17 April 2012


CHAIN OF CUSTODY FORM(S)


Pet Solutions LLC


10511 Gauge Rd.

Dan Craig

12 July 2012


Lab Number:


Sample Matrix:

7/4/12 6:00

ANALYTICAL RESULTS

Sample Name: Pond 3 Affluent Mid-Pond

1207033-04

Water


Chloride mg/L 368 A207063 300.0/9056A7/6/12 4:46ETmg/L < 0.500Nitrate as N A207063 300.0/9056A7/5/12 14:43ET

mg/L < 0.500Nitrite as N A207063 300.0/9056A7/5/12 14:43ET

Units Result Date/Time Analyzed BatchDissolved Sulfide MethodQualifier(s)

mg/L < 0.100Sulfide A207118 4500S2-D7/10/12 15:51E20, ET

Units Result Date/Time Analyzed BatchDissolved Sulfite MethodQualifier(s)

mg/L < 4.00Sulfite A207083 4500-SO3 B7/6/12 13:30E2, ET


Ammonia as N mg/L 555 A207101 4500-NH3D7/10/12 10:03E3, ETBOD-5 mg/L 1310 A207108 5210B7/10/12 11:32ET

Dissolved Oxygen mg/L 0.0600 A207069 4500-O-G7/5/12 13:20E2mg/L < 25Oil and Grease A207100 1664A7/11/12 9:39E3, ET

pH S.U. 8.05 A207086 150.2/9040C7/6/12 15:00E2Sulfide mg/L 0.172 A207111 4500S2-D7/10/12 9:45E20, E3, ET

TDS mg/L 1800 A207096 2540C7/9/12 12:52ETTKN mg/L 480 A207097 4500-Norg C7/9/12 10:18E3, ET

Total Alkalinity mg/L 1820 A207106 2320 B7/10/12 10:58ETTotal Phosphorus mg/L 106 A207123 4500-P B5,E7/11/12 15:23E3, ET

TSS mg/L 380 A207098 2540D7/9/12 10:43ETCBOD mg/L 258 A207108 5210B7/10/12 11:32B-01, ET


Pet Solutions LLC


10511 Gauge Rd.

Dan Craig

12 July 2012




Pet Solutions LLC


10511 Gauge Rd.

Bryan Posey

28 December 2011


Lab Number:


Sample Matrix:

12/21/11 10:15

ANALYTICAL RESULTS


1112289-01

Soil




CEC meq/100 g 3.45 A112305 9081 mod.12/27/11 15:21






Lead mg/kg dry 17.1 A112306 6010C12/27/11 16:28

Magnesium mg/kg dry 612 A112306 6010C12/27/11 16:28E20mg/kg dry < 0.020Mercury A112330 7471B12/28/11 11:03mg/kg dry < 2.10Molybdenum A112306 6010C12/27/11 16:28


Phosphorus mg/kg dry 553 A112306 6010C12/27/11 16:28E20Potassium mg/kg dry 805 A112306 6010C12/27/11 16:28

mg/kg dry < 5.26Selenium A112306 6010C12/27/11 16:28Zinc mg/kg dry 34.6 A112306 6010C12/27/11 16:28




Pet Solutions LLC


10511 Gauge Rd.

Bryan Posey

28 December 2011


Lab Number:


Sample Matrix:

12/21/11 10:31

ANALYTICAL RESULTS


1112289-02

Soil




CEC meq/100 g 2.11 A112305 9081 mod.12/27/11 15:21

Units Result Date/Time Analyzed BatchTotal Metals MethodQualifier(s)mg/kg dry < 2.99Arsenic A112306 6010C12/27/11 16:40mg/kg dry < 0.299Cadmium A112306 6010C12/27/11 16:40



Lead mg/kg dry 9.42 A112306 6010C12/27/11 16:40






Zinc mg/kg dry 24.0 A112306 6010C12/27/11 16:40




Pet Solutions LLC


10511 Gauge Rd.

Bryan Posey

28 December 2011


Lab Number:


Sample Matrix:

12/21/11 10:46

ANALYTICAL RESULTS


1112289-03

Soil




CEC meq/100 g 2.16 A112305 9081 mod.12/27/11 15:21






Lead mg/kg dry 15.3 A112306 6010C12/27/11 16:44





Zinc mg/kg dry 35.5 A112306 6010C12/27/11 16:44




Pet Solutions LLC


10511 Gauge Rd.

Bryan Posey

28 December 2011


Lab Number:


Sample Matrix:

12/21/11 10:53

ANALYTICAL RESULTS


1112289-04

Soil




CEC meq/100 g 4.39 A112305 9081 mod.12/27/11 15:21






Lead mg/kg dry 18.3 A112306 6010C12/27/11 16:48






Zinc mg/kg dry 61.5 A112306 6010C12/27/11 16:48




Pet Solutions LLC


10511 Gauge Rd.

Bryan Posey

28 December 2011


Lab Number:


Sample Matrix:

12/21/11 11:02

ANALYTICAL RESULTS


1112289-05

Soil




CEC meq/100 g 4.71 A112305 9081 mod.12/27/11 15:21






Lead mg/kg dry 20.1 A112306 6010C12/27/11 16:52






Zinc mg/kg dry 59.4 A112306 6010C12/27/11 16:52




Pet Solutions LLC


10511 Gauge Rd.

Bryan Posey

28 December 2011


Lab Number:


Sample Matrix:

12/21/11 11:07

ANALYTICAL RESULTS


1112289-06

Soil


Chloride mg/kg 3.01 A112307 9056A12/22/11 11:35

mg/kg < 5.00Nitrate as N A112307 9056A12/22/11 11:35


CEC meq/100 g 4.07 A112305 9081 mod.12/27/11 15:21






Lead mg/kg dry 15.6 A112306 6010C12/27/11 17:14





Zinc mg/kg dry 35.1 A112306 6010C12/27/11 17:14




Pet Solutions LLC


10511 Gauge Rd.

Bryan Posey

28 December 2011




Soil Sample pH readings 12/21/11

Sample #1 – 6.55 @ 10:15 AM (Area 2)

Sample #2 – 5.30 @ 10:31 AM (Area 3)

Sample #3 – 5.25 @ 10:46 AM (Area 4)

Sample #4 – 5.83 @ 10:53 AM (Area 5)

Sample #5 – 6.15 @ 11:02 AM (Area 1)

Sample #6 – 6.43 @ 11:07 AM (Area 1)

Calculation Summary - Pet Solutions - 2012.pdf

Tract 2- Calc

Tract 3- Calc

Volume Summaries - Nebo - 2012.pdf

LH-3 App

RW-1 App

RW-2 App

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2012 annual report · 4/30/2013 · 2012 annual report april 2013 pet solutions, llc permit no....

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