3. solutions of sodium iodide and lead nitrate are mixed. i - + pb 2+ pbi 2

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1. Hydrogen sulfide 1. Hydrogen sulfide is bubbled through a is bubbled through a solution of silver solution of silver nitrate. nitrate. H H 2 2 S(g) + AgNO S(g) + AgNO 3 3 (aq) --> (aq) --> HNO HNO 3 3 (aq) + Ag (aq) + Ag 2 2 S(s) S(s) H H 2 2 S + Ag S + Ag + + + NO + NO 3 3 - - --> --> H H + + +NO +NO 3 3 - - + Ag + Ag 2 2 S S H H 2 2 S + Ag S + Ag + + H H + + + + Ag Ag 2 2 S S

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Double Replacement 1. Hydrogen sulfide is bubbled through a solution of silver nitrate. H 2 S(g) + AgNO 3 (aq) --> HNO 3 (aq) + Ag 2 S(s) H 2 S + Ag + + NO 3 - --> H + +NO 3 - + Ag 2 S H 2 S + Ag +  H + + Ag 2 S. - PowerPoint PPT Presentation

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Page 1: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

Double ReplacementDouble Replacement1. Hydrogen sulfide is bubbled 1. Hydrogen sulfide is bubbled

through a solution of silver through a solution of silver nitrate.nitrate.

HH22S(g) + AgNOS(g) + AgNO33(aq) --> (aq) -->

HNOHNO33(aq) + Ag(aq) + Ag22S(s)S(s)

HH22S + AgS + Ag++ + NO + NO33-- --> -->

HH++ +NO +NO33-- + Ag + Ag22SS

HH22S + AgS + Ag++ H H++ ++ AgAg22SS

Page 2: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

2. An excess of sodium 2. An excess of sodium hydroxide solution is added to a hydroxide solution is added to a solution of magnesium nitrate.solution of magnesium nitrate.

OHOH- - + Mg+ Mg2+2+ Mg(OH) Mg(OH)22

Page 3: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

3. Solutions of sodium iodide 3. Solutions of sodium iodide and lead nitrate are mixed.and lead nitrate are mixed.

II-- + Pb + Pb2+ 2+ PbI PbI22

Page 4: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

4. A solution of ammonia is 4. A solution of ammonia is added to a solution of ferric added to a solution of ferric chloride.chloride.NHNH33((gg) + H) + H22O(O(ll) + FeCl) + FeCl33((aqaq) --> ) -->

NHNH44Cl(Cl(aqaq) + Fe(OH)) + Fe(OH)33((ss))

NHNH33 + H + H22O + FeO + Fe3+3+ + Cl + Cl-- NH NH44

++ + Cl + Cl-- + Fe(OH) + Fe(OH)33

NHNH33 + H + H22O + FeO + Fe3+3+ NH NH44

++ + Fe(OH) + Fe(OH)33

Page 5: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

5. Solutions of silver nitrate and 5. Solutions of silver nitrate and sodium chromate are mixed.sodium chromate are mixed.

AgAg++ + CrO + CrO442-2- Ag Ag22CrOCrO44

Page 6: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

6. Excess silver acetate is added 6. Excess silver acetate is added to a solution of trisodium to a solution of trisodium

phosphate.phosphate.

AgAg++ + PO + PO443-3- Ag Ag33POPO44

Page 7: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

7. Manganese(II) nitrate solution 7. Manganese(II) nitrate solution is mixed with sodium hydroxide is mixed with sodium hydroxide

solution.solution.

MnMn2+2+ + OH + OH-- Mn(OH) Mn(OH)22

Page 8: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

8. A saturated solution of 8. A saturated solution of calcium hydroxide is added to a calcium hydroxide is added to a solution of magnesium chloride.solution of magnesium chloride.

MgMg2+2+ + OH + OH- - Mg(OH) Mg(OH)22

Page 9: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

9. Hydrogen sulfide gas is added 9. Hydrogen sulfide gas is added to a solution of cadmium nitrate.to a solution of cadmium nitrate.

HH22S + CdS + Cd2+2+ CdS + H CdS + H++

Page 10: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

10. Dilute sulfuric acid is added 10. Dilute sulfuric acid is added to a solution of barium acetate.to a solution of barium acetate.

HH++ + SO + SO442-2- + Ba + Ba2+2+ + C + C22HH33OO22

- -

BaSO BaSO44 + HC + HC22HH33OO22

Page 11: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

1111. A precipitate is formed when A precipitate is formed when solutions of trisodium phosphate solutions of trisodium phosphate and calcium chloride are and calcium chloride are mixed. mixed.

POPO443-3- + Ca + Ca2+2+ CaCa33(PO(PO44))22

Page 12: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

12. A solution of copper(II) 12. A solution of copper(II) sulfate is added to a solution of sulfate is added to a solution of barium hydroxide.barium hydroxide.

CuCu2+2+ + SO + SO442- 2- + Ba+ Ba2+2+ + OH + OH--

Cu(OH)Cu(OH)22 + BaSO + BaSO44

Page 13: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

1313. Equal volumes of dilute Equal volumes of dilute equimolar solutions of sodium equimolar solutions of sodium carbonate and hydrochloric acid carbonate and hydrochloric acid are mixed. are mixed. NaNa22COCO33((aqaq) + HCl() + HCl(aqaq) -->) -->

NaCl( NaCl(aqaq) + NaHCO) + NaHCO33((aqaq))

2Na2Na++ + CO + CO332-2- + H + H++ +Cl +Cl-- --> -->

NaNa++ + Cl + Cl- - + Na+ Na++ + HCO + HCO33--

HH++ + CO + CO332-2- HCO HCO33--

Page 14: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

14. Solid barium peroxide is 14. Solid barium peroxide is added to cold dilute sulfuric acid.added to cold dilute sulfuric acid.

BaOBaO22((ss) + H) + H22SOSO44((aqaq) --> ) -->

BaSOBaSO44((ss) + H) + H22OO22((ll))

BaOBaO22 +H +H++ + SO + SO442- 2-

BaSOBaSO44 + H + H22OO22

Page 15: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

15. Excess hydrochloric acid 15. Excess hydrochloric acid solution is added to a solution of solution is added to a solution of potassium sulfite.potassium sulfite.HCl(HCl(aqaq) + K) + K22SOSO33((aqaq) --> H) --> H22O(O(ll) )

+ SO+ SO22((gg) + KCl() + KCl(aqaq))

HH++ + Cl + Cl- - + K+ K++ + SO + SO332-2- --> -->

H H22O + SOO + SO22 + K + K++ + Cl + Cl--

HH++ + SO + SO332-2- H H22O + SOO + SO22

Page 16: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

16. Dilute sulfuric acid is added 16. Dilute sulfuric acid is added to a solution of barium chloride.to a solution of barium chloride.

HH22SOSO44((aqaq) + BaCl) + BaCl22((aqaq) --> ) -->

HCl(HCl(aqaq) + BaSO) + BaSO44((ss))

HH++ + SO + SO442-2- + Ba + Ba2+2+ + Cl + Cl-- --> -->

HH++ + Cl + Cl-- + BaSO + BaSO44

SOSO442-2- + Ba + Ba2+2+ BaSO BaSO44

Page 17: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

17. A solution of sodium 17. A solution of sodium hydroxide is added to a solution hydroxide is added to a solution of ammonium chloride.of ammonium chloride.NaOH(NaOH(aqaq) + NH) + NH44Cl(Cl(aqaq) --> ) -->

NaCl(NaCl(aqaq) + NH) + NH33((gg) + H) + H22O(O(ll))

NaNa++ + OH + OH-- + NH + NH44++ + Cl + Cl- - --> -->

NaNa++ + Cl + Cl-- + NH + NH3 3 + H+ H22OO

NHNH44++ + OH + OH-- NH NH33 + H + H22OO

Page 18: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

18. Dilute hydrochloric acid is 18. Dilute hydrochloric acid is added to a solution of potassium added to a solution of potassium carbonate.carbonate.HCl(HCl(aqaq) + K) + K22COCO33((aqaq) --> H) --> H22O(O(ll) )

+ CO+ CO22((gg) + KCl() + KCl(aqaq))

HH+ + + Cl+ Cl-- + K + K++ + CO + CO332-2- --> -->

HH22O + COO + CO22 + K + K++ + Cl + Cl--

HH++ + CO + CO332-2- H H22O + COO + CO22

Page 19: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

19. Gaseous hydrogen sulfide is 19. Gaseous hydrogen sulfide is bubbled through a solution of bubbled through a solution of

nickel(II) nitrate.nickel(II) nitrate.HH22S(g) + Ni(NOS(g) + Ni(NO33))22(aq) --> (aq) -->

HNOHNO33(aq) + NiS(s)(aq) + NiS(s)

HH22S + NiS + Ni2+2+ + NO + NO33-- --> -->

HH++ + NO + NO33-- + NiS + NiS

HH22S + NiS + Ni2+2+ NiS + H NiS + H++

Page 20: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

20. A solution of sodium sulfide 20. A solution of sodium sulfide is added to a solution of zinc is added to a solution of zinc

nitrate.nitrate.NaNa22S(S(aqaq) + Zn(NO) + Zn(NO33))22((aqaq) --> ) -->

NaNONaNO33((aqaq) + ZnS() + ZnS(ss))

NaNa++ + S + S2-2- + Zn + Zn2+2+ + NO + NO33- - --> -->

NaNa++ + NO + NO33-- + ZnS + ZnS

SS2-2- + Zn + Zn2+2+ ZnS ZnS

Page 21: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

21. Concentrated hydrochloric 21. Concentrated hydrochloric acid is added to solid acid is added to solid manganese(II) sulfide.manganese(II) sulfide.

HH++ + MnS + MnS H H22S + MnS + Mn2+2+

Page 22: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

22. Solutions of tri-potassium 22. Solutions of tri-potassium phosphate and zinc nitrate are phosphate and zinc nitrate are mixed.mixed.

POPO443-3- + Zn + Zn2+2+ Zn Zn33(PO(PO44))22

Page 23: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

23. Dilute acetic acid solution is 23. Dilute acetic acid solution is added to solid magnesium added to solid magnesium carbonate.carbonate.

HCHC22HH33OO22 + MgCO + MgCO3 3

H H22O + COO + CO2 2 + Mg+ Mg2+2+ + C + C22HH33OO22--

Page 24: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

24. Gaseous hydrofluoric acid 24. Gaseous hydrofluoric acid reacts with solid silicon dioxide.reacts with solid silicon dioxide.

HF + SiOHF + SiO22 H H22O + SiFO + SiF44

Page 25: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

25. Equimolar amounts of 25. Equimolar amounts of trisodium phosphate and trisodium phosphate and hydrogen chloride, both in hydrogen chloride, both in solution, are mixed.solution, are mixed. POPO44

3-3- + H + H++ HPO HPO442-2-

Page 26: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

26. Ammonium chloride crystals 26. Ammonium chloride crystals are added to a solution of sodium are added to a solution of sodium hydroxide.hydroxide.

NHNH44Cl + OHCl + OH-- NH NH3 3 + H+ H22O + ClO + Cl--

Page 27: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

27. Hydrogen sulfide gas is 27. Hydrogen sulfide gas is bubbled through a solution of bubbled through a solution of lead(II) nitrate.lead(II) nitrate.

HH22S + PbS + Pb2+2+ PbS + H PbS + H++

Page 28: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

28. Solutions of silver nitrate 28. Solutions of silver nitrate and sodium chromate are mixed.and sodium chromate are mixed.

AgAg++ + CrO + CrO442-2- Ag Ag22CrOCrO44

Page 29: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

29. Solutions of sodium fluoride 29. Solutions of sodium fluoride and dilute hydrochloric acid are and dilute hydrochloric acid are mixed.mixed.

FF-- + H + H++ HF HF

Page 30: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

30. A saturated solution of 30. A saturated solution of barium hydroxide is mixed with a barium hydroxide is mixed with a solution of iron(III) sulfate.solution of iron(III) sulfate.

BaBa2+2+ + OH + OH- - + Fe + Fe3+3+ + SO + SO442-2-

BaSOBaSO44 + Fe(OH) + Fe(OH)33

Page 31: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

31. A solution of ammonium 31. A solution of ammonium sulfate is added to a potassium sulfate is added to a potassium hydroxide solution.hydroxide solution.

NHNH44++ + OH + OH-- NH NH33 + H + H22OO

Page 32: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

32. A solution of ammonium 32. A solution of ammonium sulfate is added to a saturated sulfate is added to a saturated solution of barium hydroxide.solution of barium hydroxide.

NHNH44++ + SO + SO44

2-2- + Ba + Ba2+2+ +OH +OH--

NHNH3 3 + H+ H22O + BaSOO + BaSO44

Page 33: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

33. Dilute sulfuric acid is added 33. Dilute sulfuric acid is added to solid calcium fluoride.to solid calcium fluoride.

HH++ + SO + SO442-2- + CaF + CaF22

CaSO CaSO44 + HF + HF

Page 34: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

34. Dilute hydrochloric acid is 34. Dilute hydrochloric acid is added to a dilute solution of added to a dilute solution of mercury(I) nitrate.mercury(I) nitrate.

ClCl-- + Hg + Hg222+2+ Hg Hg22ClCl22

Page 35: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

35. Dilute sulfuric acid is added 35. Dilute sulfuric acid is added to a solution of lithium hydrogen to a solution of lithium hydrogen carbonate.carbonate.

HH++ + HCO + HCO33- - H H22O + COO + CO22

Page 36: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

36. Dilute hydrochloric acid is 36. Dilute hydrochloric acid is added to a solution of potassium added to a solution of potassium sulfite.sulfite.

HH++ + SO + SO332-2- H H22O + SOO + SO22

Page 37: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

3737. Carbon dioxide gas is Carbon dioxide gas is bubbled through water containing bubbled through water containing a suspension of calcium a suspension of calcium carbonate.carbonate.

COCO22 + CaCO + CaCO33 + H + H22O O

HCOHCO33-- + Ca + Ca2+2+

Page 38: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

38. Excess concentrated sulfuric 38. Excess concentrated sulfuric acid is added to solid calcium acid is added to solid calcium phosphate.phosphate.

HH22SOSO4 4 + Ca+ Ca33(PO(PO44))2 2

HH33POPO44 + CaSO + CaSO44

(or Ca(or Ca2+2+ + SO + SO442-2-))

Page 39: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

39. Hydrogen sulfide gas is 39. Hydrogen sulfide gas is bubbled into a solution of bubbled into a solution of mercury(II) chloride.mercury(II) chloride.

HH22S + HgS + Hg2+2+ HgS + H HgS + H++

Page 40: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

40. Solutions of zinc sulfate and sodium phosphate are mixed.

Zn2+ + PO43 - --> Zn3(PO4)2

Page 41: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

41. Solutions of silver nitrate and lithium bromide are mixed.

Ag+ + Br- --> AgBr

Page 42: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

42. Solutions of manganese(II) sulfate and ammonium sulfide are mixed.

Mn2+ + S2- --> MnS

Page 43: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

43. Excess hydrochloric acid solution is added to a solution of potassium sulfite.

H+ + SO32- --> H2O + SO2

Page 44: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

SingleReplacementSingleReplacement1. A piece of aluminum metal is 1. A piece of aluminum metal is added to a solution of silver added to a solution of silver nitrate.nitrate.Al(s) + AgNOAl(s) + AgNO33(aq) --> (aq) -->

Al(NOAl(NO33))33(aq) + Ag(s)(aq) + Ag(s)

Al + Ag+ + NOAl + Ag+ + NO33-- --> -->

AlAl3+3+ + NO + NO33-- + Ag + Ag

Al + AgAl + Ag++ Al Al3+3+ + Ag + Ag

Page 45: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

2. Aluminum metal is added to a 2. Aluminum metal is added to a solution of copper(II) chloride.solution of copper(II) chloride.Al(s) + CuClAl(s) + CuCl22(aq) --> (aq) -->

Cu(s) + AlClCu(s) + AlCl33(aq)(aq)

Al + CuAl + Cu2+2+ + Cl + Cl-- --> --> Cu + AlCu + Al3+3+ + Cl + Cl--

Al + CuAl + Cu2+2+ Al Al3+3+ + Cu + Cu

Page 46: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

3. Hydrogen gas is passed over 3. Hydrogen gas is passed over hot copper(II) oxide.hot copper(II) oxide.

HH22 + CuO + CuO H H22O + CuO + Cu

Page 47: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

4. Small chunks of solid sodium 4. Small chunks of solid sodium are added to water.are added to water.

Na + HNa + H22O O Na Na++ + OH + OH- - + H+ H22

Page 48: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

5. Calcium metal is added to a 5. Calcium metal is added to a dilute solution of hydrochloric dilute solution of hydrochloric acid.acid.

Ca + HCa + H++ Ca Ca2+2+ + H + H22

Page 49: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

6. Magnesium turnings are 6. Magnesium turnings are added to a solution of iron(III) added to a solution of iron(III) chloride.chloride.

Mg + FeMg + Fe3+3+ Mg Mg2+2+ + Fe + Fe

Page 50: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

7. Chlorine gas is bubbled into a 7. Chlorine gas is bubbled into a solution of sodium bromide.solution of sodium bromide.

ClCl22 + Br + Br-- Cl Cl-- + Br + Br22

Page 51: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

8. A strip of magnesium is added 8. A strip of magnesium is added to a solution of silver nitrate.to a solution of silver nitrate.

Mg + AgMg + Ag++ Mg Mg2+2+ + Ag + Ag

Page 52: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

9. Solid calcium is added to 9. Solid calcium is added to warm water.warm water.

Ca + HCa + H22O O Ca Ca2+2+ + OH + OH-- + H + H22

Page 53: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

10. Liquid bromine is added to a 10. Liquid bromine is added to a solution of potassium iodide.solution of potassium iodide.

BrBr22 + I + I- - Br Br-- + I + I22

Page 54: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

11. Chlorine gas is bubbled into 11. Chlorine gas is bubbled into a solution of potassium iodide.a solution of potassium iodide.

ClCl22 + I + I-- Cl Cl-- + I + I22

Page 55: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

12. Lead foil is immersed in 12. Lead foil is immersed in silver nitrate solution.silver nitrate solution.

Pb + AgPb + Ag+ + Pb Pb2+2+ + Ag + Ag

Page 56: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

13. Solid zinc strips are added to 13. Solid zinc strips are added to a solution of copper(II) sulfate.a solution of copper(II) sulfate.

Zn + CuZn + Cu2+2+ Zn Zn2+2+ + Cu + Cu

Page 57: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

14. Sodium metal is added to 14. Sodium metal is added to water.water.

Na + HNa + H22O O Na Na++ + OH + OH-- + H + H22

Page 58: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

15. A bar of zinc metal is 15. A bar of zinc metal is immersed in a solution of immersed in a solution of copper(II) sulfate.copper(II) sulfate.

Zn + CuZn + Cu2+2+ Zn Zn2+2+ + Cu + Cu

Page 59: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

16. A small piece of sodium 16. A small piece of sodium metal is added to distilled water. metal is added to distilled water.

Na + HNa + H22O --> NaO --> Na++ + OH + OH-- + H + H22

Page 60: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

CombustionCombustion

1. Lithium metal is burned in air.1. Lithium metal is burned in air.

Li + OLi + O22 Li Li22OO

Page 61: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

2. The hydrocarbon hexane is 2. The hydrocarbon hexane is burned in excess oxygen.burned in excess oxygen.

CC66HH1414 + O + O22 CO CO22 + H + H22OO

Page 62: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

3. Gaseous diborane, B3. Gaseous diborane, B22HH66, is , is

burned in excess oxygen.burned in excess oxygen.

BB22HH66 + O + O22 B B22OO3 3 + H+ H22OO

Page 63: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

4. A piece of solid bismuth is 4. A piece of solid bismuth is heated strongly in oxygen.heated strongly in oxygen.

Bi + OBi + O22 Bi Bi22OO33

Page 64: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

5. Solid zinc sulfide is heated in 5. Solid zinc sulfide is heated in an excess of oxygen.an excess of oxygen.

ZnS + OZnS + O22 ZnO + SO ZnO + SO22

Page 65: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

6. Propanol is burned completely 6. Propanol is burned completely in air.in air.

CC33HH77OH + OOH + O22 CO CO22 + H + H22OO

Page 66: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

7. Excess oxygen gas is mixed 7. Excess oxygen gas is mixed with ammonia gas in the with ammonia gas in the presence of platinum.presence of platinum.

OO2 2 + NH+ NH33 NO NO2 2 + H+ H22OOPtPt

Page 67: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

8. Gaseous silane, SiH8. Gaseous silane, SiH44, is , is

burned in oxygen.burned in oxygen.

SiHSiH44 + O + O22 SiO SiO2 2 + H+ H22OO

Page 68: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

9. Ethanol is completely burned 9. Ethanol is completely burned in air.in air.

CC22HH55OH + OOH + O22 CO CO22 + H + H22OO

Page 69: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

10. Solid copper(II) sulfide is 10. Solid copper(II) sulfide is heated strongly in oxygen gas.heated strongly in oxygen gas.

CuS + OCuS + O22 CuO + SO CuO + SO22

Page 70: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

11. Ethanol is burned in oxygen.11. Ethanol is burned in oxygen.

CC22HH55OH + OOH + O22 CO CO2 2 + H+ H22OO

Page 71: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

12. Carbon disulfide vapor is 12. Carbon disulfide vapor is burned in excess oxygen.burned in excess oxygen.

CSCS22 + O + O22 --> CO --> CO2 2 + SO+ SO22

Page 72: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

AnhydridesAnhydrides

1. Excess water is added to solid 1. Excess water is added to solid calcium hydride.calcium hydride.

HH22O + CaHO + CaH22

CaCa2+2+ + OH + OH-- or (Ca(OH) or (Ca(OH)22) + H) + H22

Page 73: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

2. Solid lithium hydride is added 2. Solid lithium hydride is added to water.to water.

LiH + HLiH + H22O O Li Li++ + OH + OH- - + H + H22

Page 74: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

3. Liquid phosphorus trichloride 3. Liquid phosphorus trichloride is poured into a large excess of is poured into a large excess of water.water.

PClPCl33 + H + H22O O H H33POPO33 + H + H++ + Cl + Cl--

Page 75: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

4. Solid sodium carbide is added 4. Solid sodium carbide is added to an excess of water.to an excess of water.

NaNa44C + HC + H22O O CC22HH2 2 + Na+ Na++ + OH + OH--

Page 76: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

5. Solid magnesium nitride is 5. Solid magnesium nitride is added to excess deuterium oxide.added to excess deuterium oxide.

MgMg33NN22 + D + D22O O Mg(OD) Mg(OD)22+ ND+ ND33

Page 77: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

6. Water is added to a sample of 6. Water is added to a sample of pure phosphorus tribromide.pure phosphorus tribromide.

HH22O + PBrO + PBr33 H H33POPO33 + H + H++ + Br + Br--

Page 78: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

7. Water is added to a sample of 7. Water is added to a sample of pure sodium hydride.pure sodium hydride.

HH22O + NaH O + NaH Na Na++ + OH + OH- - + H+ H22

Page 79: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

8. Dinitrogen trioxide gas is 8. Dinitrogen trioxide gas is bubbled into water.bubbled into water.

NN22OO33 + H + H22O O HNO HNO22

Page 80: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

9. Solid phosphorus 9. Solid phosphorus pentachloride is added to excess pentachloride is added to excess water.water.

PClPCl55 + H + H22O O H H33POPO4 4 + H + H++ + Cl + Cl--

Page 81: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

10. Solid dinitrogen pentoxide is 10. Solid dinitrogen pentoxide is added to water.added to water.

NN22OO55 + H + H22O O H H++ + NO + NO33--

Page 82: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

11. Sulfur trioxide gas is added 11. Sulfur trioxide gas is added to excess water.to excess water.

SOSO33 + H + H22O O H H++ + SO + SO442-2-

Page 83: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

12. Solid sodium oxide is added 12. Solid sodium oxide is added to water.to water.

NaNa22O + HO + H22O O Na Na++ + OH + OH--

Page 84: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

13. Phosphorus(V) 13. Phosphorus(V) oxytrichloride is added to water.oxytrichloride is added to water.

POClPOCl33 + H + H22O O HH33POPO44+ H+ H++ + Cl + Cl--

Page 85: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

14. Water is added to a sample 14. Water is added to a sample of solid magnesium nitride.of solid magnesium nitride.

HH22O + MgO + Mg33NN22 Mg(OH)Mg(OH)22

+ NH+ NH33

Page 86: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

15. Solid potassium oxide is 15. Solid potassium oxide is added to water.added to water.

KK22O + HO + H22O O K K++ + OH + OH--

Page 87: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

16. Solid sodium cyanide is 16. Solid sodium cyanide is added to water.added to water.

NaCN + HNaCN + H22O O HCN + Na HCN + Na++ + OH + OH--

Page 88: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

17. Trisodium phosphate crystals 17. Trisodium phosphate crystals are added to water.are added to water.

NaNa33POPO44 + H + H22O O

NaNa++ + OH + OH-- + HPO + HPO442-2- ( or H ( or H22POPO44

--))

Page 89: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

18. Solid lithium oxide is added 18. Solid lithium oxide is added to excess water.to excess water.

LiLi22O + HO + H22O O Li Li++ + OH + OH--

Page 90: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

19. Solid barium oxide is added 19. Solid barium oxide is added to distilled water.to distilled water.

BaO + HBaO + H22O O Ba Ba2+2+ + OH + OH--

Page 91: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

2020. Solid calcium hydride is Solid calcium hydride is added to distilled water.added to distilled water.

CaHCaH22+ H+ H22O O CaCa2+2+ + OH + OH- - or (Ca(OH)or (Ca(OH)22)) + H+ H22

Page 92: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

21. Phosphorous(V) oxide powder is sprinkled over distilled water.

P2O5 + H2O --> H3PO4

Page 93: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

RedoxRedox

1. Iron(III) ions are reduced by 1. Iron(III) ions are reduced by iodide ions.iodide ions.

FeFe3+3+ + I + I- - Fe Fe2+2+ + I + I22

Page 94: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

2. Potassium permanganate 2. Potassium permanganate solution is added to concentrated solution is added to concentrated hydrochloric acid.hydrochloric acid.

MnOMnO44-- + H + H++ + Cl + Cl--

MnMn2+2+ + Cl + Cl22 + H + H22OO

Page 95: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

3. Magnesium metal is added to 3. Magnesium metal is added to dilute nitric acid, giving as one dilute nitric acid, giving as one of the products a compound in of the products a compound in which which the oxidation number for the oxidation number for nitrogen is -3.nitrogen is -3.

Mg + HMg + H++ + NO + NO33- -

NHNH44++ + Mg + Mg2+2+ + H + H22OO

Page 96: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

4. A solution of potassium 4. A solution of potassium iodide is electrolyzed.iodide is electrolyzed.

II-- + H + H22O O I I22 + H + H22 + OH + OH--

Page 97: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

5. Potassium dichromate 5. Potassium dichromate solution is added to an acidified solution is added to an acidified solution of sodium sulfite.solution of sodium sulfite.

CrCr22OO772-2- + SO + SO33

2-2- + H + H++

CrCr3+3+ + SO + SO442-2- + H + H22OO

Page 98: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

6. Solutions of potassium iodide, 6. Solutions of potassium iodide, potassium iodate, and dilute potassium iodate, and dilute sulfuric acid are mixed.sulfuric acid are mixed.

II-- + IO + IO33- - + H+ H++ H H22O + IO + I22

Page 99: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

7. A solution of tin(II) sulfate is 7. A solution of tin(II) sulfate is added to a solution of iron(III) added to a solution of iron(III) sulfate.sulfate.

SnSn2+2+ + Fe + Fe3+3+ SnSn4+4+ + Fe + Fe2+2+

Page 100: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

8. Metallic copper is heated with 8. Metallic copper is heated with concentratedconcentrated sulfuric acid. sulfuric acid.

Cu + HCu + H22SOSO44 Cu Cu2+2+ + SO + SO22 + H + H22OO

Page 101: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

9. Manganese(IV) oxide is added 9. Manganese(IV) oxide is added to warm, concentrated to warm, concentrated hydrobromic acid.hydrobromic acid.

MnOMnO22 + H + H++ + Br + Br- -

MnMn2+2+ + Br + Br22 + H + H22OO

Page 102: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

10. Chlorine gas is bubbled into 10. Chlorine gas is bubbled into cold dilute sodium hydroxide.cold dilute sodium hydroxide.

ClCl22 + OH + OH-- ClO ClO-- + Cl + Cl- - + H+ H22OO

Page 103: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

11. Solid iron(III) oxide is heated 11. Solid iron(III) oxide is heated in excess carbon monoxide.in excess carbon monoxide.

FeFe22OO33 + CO + CO Fe + COFe + CO22

Page 104: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

12. Hydrogen peroxide solution 12. Hydrogen peroxide solution is added to acidified potassium is added to acidified potassium iodide solution.iodide solution.

HH22OO22 + H + H++ + I + I-- H H22O + IO + I22

Page 105: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

13. Hydrogen peroxide is added 13. Hydrogen peroxide is added to an acidified solution of to an acidified solution of potassium dichromate.potassium dichromate.

HH22OO22 + H + H++ + Cr + Cr22OO772-2-

HH22O + CrO + Cr3+3+ + O + O22

Page 106: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

14. Sulfur dioxide gas is bubbled 14. Sulfur dioxide gas is bubbled through an acidified solution of through an acidified solution of potassium permanganate.potassium permanganate.

SOSO22 + H + H++ + MnO + MnO44--

MnMn2+2+ + H + H22O + SOO + SO442-2-

Page 107: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

15. A solution containing tin(II) 15. A solution containing tin(II) ions is added to an acidified ions is added to an acidified solution of potassium solution of potassium dichromate.dichromate.

SnSn2+2+ + H + H++ + Cr + Cr22OO772-2-

CrCr3+3+ + Sn + Sn4+4+ + H + H22OO

Page 108: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

16. Solid silver sulfide is 16. Solid silver sulfide is warmed with dilute nitric acid.warmed with dilute nitric acid.

AgAg22S + HS + H++ + NO + NO33- -

AgAg++ + S + NO + S + NO22 + H + H22OO

Page 109: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

17. A dilute solution of sulfuric 17. A dilute solution of sulfuric acid is electrolyzed between acid is electrolyzed between platinum electrodes.platinum electrodes.

HH22O O HH22 + O + O22

Page 110: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

18. Pellets of lead are dropped 18. Pellets of lead are dropped into hot sulfuric acid.into hot sulfuric acid.

Pb + HPb + H++ + SO + SO442-2-

HH22O + SOO + SO22 + Pb + Pb2+2+ (or PbSO (or PbSO44 ) )

Page 111: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

19. Potassium permanganate 19. Potassium permanganate solution is added to a solution of solution is added to a solution of oxalic acid, Hoxalic acid, H22CC22OO44 , acidified , acidified

with a few drops of with a few drops of sulfuric acid.sulfuric acid.

MnOMnO44-- + H + H22CC22OO4 4 + H+ H++

MnMn2+2+ + CO + CO22 + H + H22OO

Page 112: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

20. Powdered iron is added to a 20. Powdered iron is added to a solution of iron(III) sulfate.solution of iron(III) sulfate.

Fe + FeFe + Fe3+3+ Fe Fe2+2+

Page 113: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

21. A concentrated solution of 21. A concentrated solution of hydrochloric acid is added to hydrochloric acid is added to powdered manganese dioxide powdered manganese dioxide and gently heated.and gently heated.

HH++ + Cl + Cl- - + MnO+ MnO22

ClCl22 + Mn + Mn2+2+ + H + H22OO

Page 114: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

22. A strip of copper metal is 22. A strip of copper metal is added to a concentrated solution added to a concentrated solution of sulfuric acid.of sulfuric acid.

Cu + HCu + H++ + SO + SO442-2-

CuCu2+2+ + SO + SO22 + H + H22OO

Page 115: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

23. Copper(II) sulfide is 23. Copper(II) sulfide is oxidized by dilute nitric acid. oxidized by dilute nitric acid.

CuS + HCuS + H++ + NO + NO33--

CuCu2+2+ + NO + H + NO + H22O + SO + S

Page 116: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

24. A solution of copper(II) 24. A solution of copper(II) sulfate is electrolyzed using inert sulfate is electrolyzed using inert electrodes.electrodes.

CuCu2+2+ + H + H22O O O O22 + H + H++ + Cu + Cu

Page 117: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

25. A solution of potassium 25. A solution of potassium iodide is added to an acidified iodide is added to an acidified solution of potassium solution of potassium dichromate.dichromate.

II-- + H + H++ + Cr + Cr22OO772-2-

II22 + Cr + Cr3+3+ + H + H22OO

Page 118: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

26. Hydrogen peroxide solution 26. Hydrogen peroxide solution is added to a solution of iron(II) is added to a solution of iron(II) sulfate.sulfate.

HH22OO22 + Fe + Fe2+ 2+ Fe Fe3+3+ + H + H22OO

Page 119: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

27. Solid silver is added to a 27. Solid silver is added to a dilute nitric acid (6M) solution.dilute nitric acid (6M) solution.

Ag + HAg + H++ +NO +NO33- -

AgAg++ + NO + H + NO + H22OO

Page 120: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

28. A solution of formic acid, 28. A solution of formic acid, HCOOH, is oxidized by an HCOOH, is oxidized by an acidified solution of potassium acidified solution of potassium dichromate.dichromate.

HCOOH + HHCOOH + H++ + Cr + Cr22OO772-2-

HH22O + CrO + Cr3+3+ + CO + CO22

Page 121: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

29. A piece of iron is added to a 29. A piece of iron is added to a solution of iron(III) sulfate.solution of iron(III) sulfate.

Fe + FeFe + Fe3+3+ Fe Fe2+2+

Page 122: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

30. An acidified solution of 30. An acidified solution of potassium permanganate is added potassium permanganate is added to a solution of sodium sulfite.to a solution of sodium sulfite.

HH++ + MnO + MnO44- - + SO+ SO33

2-2-

MnMn2+2+ + SO + SO442- 2- + H+ H22OO

Page 123: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

31. A solution of tin(II) chloride 31. A solution of tin(II) chloride is added to a solution of iron(III) is added to a solution of iron(III) sulfate.sulfate.

SnSn2+2+ + Fe + Fe3+3+ Sn Sn4+ 4+ + Fe+ Fe2+2+

Page 124: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

32. Concentrated hydrochloric 32. Concentrated hydrochloric acid solution is added to solid acid solution is added to solid manganese(IV) oxide and the manganese(IV) oxide and the reactants are heated.reactants are heated.

HH++ + Cl + Cl-- + MnO + MnO22

MnMn2+2+ + Cl + Cl22 + H + H22OO

Page 125: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

34. Potassium permanganate 34. Potassium permanganate solution is added to an acidic solution is added to an acidic solution of hydrogen peroxide.solution of hydrogen peroxide.

MnOMnO44-- + H + H++ + H + H22OO22

MnMn2+2+ + O + O22 + H + H22OO

Page 126: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

35. Solid copper is added to a 35. Solid copper is added to a dilute nitric acid solution.dilute nitric acid solution.

Cu + HCu + H++ + NO + NO33- -

CuCu2+2+ + NO + H + NO + H22OO

Page 127: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

36. Chlorine gas is bubbled into 36. Chlorine gas is bubbled into a cold solution of dilute sodium a cold solution of dilute sodium hydroxide.hydroxide.

ClCl22 + OH + OH-- ClOClO-- + Cl + Cl- - + H+ H22OO

Page 128: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

37. A solution of potassium 37. A solution of potassium permanganate is mixed with an permanganate is mixed with an alkaline solution of sodium alkaline solution of sodium sulfite.sulfite.

MnOMnO44-- + OH + OH- - + SO+ SO33

2- 2-

SOSO442-2- + H + H22O + MnOO + MnO44

2-2- (or MnO (or MnO22))

Page 129: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

38. Solid sodium dichromate is 38. Solid sodium dichromate is added to an acidified solution of added to an acidified solution of sodium iodide.sodium iodide.

NaNa22CrCr22OO77 + H + H++ + I + I--

CrCr3+3+ + I + I22 + H + H22O + NaO + Na++

Page 130: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

39. Hydrogen gas is passed over 39. Hydrogen gas is passed over hot iron(III) oxide.hot iron(III) oxide.

HH22 + Fe + Fe22OO33 Fe + H Fe + H22OO

Page 131: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

40. Solutions of potassium 40. Solutions of potassium iodide and potassium iodate are iodide and potassium iodate are mixed in acid solution.mixed in acid solution.

II-- + IO + IO33- - + H+ H++ I I22 + H + H22OO

Page 132: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

41. Hydrogen peroxide is added 41. Hydrogen peroxide is added to an acidified solution of sodium to an acidified solution of sodium bromide.bromide.

HH22OO22 + H + H++ + Br + Br- - Br Br2 2 + H + H22OO

Page 133: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

4242. Chlorine gas is bubbled into a Chlorine gas is bubbled into a cold, dilute solution of potassium cold, dilute solution of potassium hydroxide.hydroxide.

ClCl22 + OH + OH-- Cl Cl-- + ClO + ClO- - + H+ H22OO

Page 134: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

4343. A solution of iron(II) nitrate A solution of iron(II) nitrate is exposed to air for an extended is exposed to air for an extended period of time.period of time.

FeFe2+2+ + O + O22 Fe Fe22OO33

Page 135: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

44. A stream of chlorine gas is passed through a solution of cold, dilute sodium hydroxide.

ClCl22 + OH + OH-- Cl Cl-- + ClO + ClO- - + H+ H22OO

Page 136: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

45. A solution of tin(II) chloride is added to an acidified solution of potassium permanganate.

Sn2+ + H + + MnO4- -->

Mn2+ + Sn4+ + H2O

Page 137: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

46. A concentrated solution of hydrochloric acid is added to solid potassium permanganate.

H+ + Cl- + MnO4- -->

Cl2 + Mn2+ + H2O

Page 138: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

47. A solution of potassium dichromate is added to an acidified solution of iron(II) chloride.

Cr2O72- + H+ + Fe2+ -->

Cr3+ + Fe3+ + H2O

Page 139: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

Acid-Base NeutralizationsAcid-Base Neutralizations

1. Solutions of ammonia and 1. Solutions of ammonia and hydrofluoric acid are mixed.hydrofluoric acid are mixed.

NHNH33 + H + H22O --> NHO --> NH44++ + OH + OH--

OHOH-- + HF--> H + HF--> H22O + FO + F--

NHNH33 + HF + HF NH NH44++ + F + F--

Page 140: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

2. Hydrogen sulfide gas is 2. Hydrogen sulfide gas is bubbled through a solution of bubbled through a solution of potassium hydroxide.potassium hydroxide.

HH22S + OHS + OH- - H H22O + SO + S2-2-

Page 141: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

3. A solution of sulfuric acid is 3. A solution of sulfuric acid is added to a solution of barium added to a solution of barium hydroxide until the same number hydroxide until the same number of moles of each compound has of moles of each compound has been added.been added.

22HH++ + SO + SO442-2- + Ba + Ba2+2+ + + 22OHOH--

22HH22O + BaSOO + BaSO44

Page 142: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

4. A solution of sodium 4. A solution of sodium hydroxide is added to a solution hydroxide is added to a solution of sodium dihydrogen phosphate of sodium dihydrogen phosphate until the same number of moles until the same number of moles of each compound has been of each compound has been added.added.

OHOH- - + H+ H22POPO44- - HPO HPO44

2-2- + H + H22OO

Page 143: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

5. Dilute nitric acid is added to 5. Dilute nitric acid is added to crystals of pure calcium oxide.crystals of pure calcium oxide.

CaO + HCaO + H22O --> CaO --> Ca2+2+ + 2OH + 2OH--

2H2H++ + 2OH + 2OH-- --> 2H --> 2H22OO

HH++ + CaO + CaO H H22O + CaO + Ca2+2+

Page 144: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

6. Equal volumes of 0.1-molar 6. Equal volumes of 0.1-molar sulfuric acid and 0.1-molar sulfuric acid and 0.1-molar potassium hydroxide are mixed.potassium hydroxide are mixed.

2H2H++ + SO + SO442-2- + K + K++ + OH + OH---->-->

HH22O + HO + H++ + K + K++ + SO + SO442-2-

HH++ +OH +OH- - H H22OO

Page 145: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

7. A solution of ammonia is 7. A solution of ammonia is added to a dilute solution of added to a dilute solution of acetic acid.acetic acid.NHNH33 + H + H22O --> NHO --> NH44

++ + OH + OH--

OHOH-- + HC + HC22HH33OO22 --> -->

HH22O + CO + C22HH33OO22--

NHNH33 + HC + HC22HH33OO22

NHNH44++ + C + C22HH33OO22

--

Page 146: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

8. Excess sulfur dioxide gas is 8. Excess sulfur dioxide gas is bubbled through a dilute solution bubbled through a dilute solution of potassium hydroxide.of potassium hydroxide.

SOSO22 + H + H22O --> HO --> H22SOSO33

HH22SOSO33 + 2OH + 2OH-- --> 2H --> 2H22O + SOO + SO332-2-

SOSO22 + OH + OH-- H H22O + SOO + SO332-2-

Page 147: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

9. Sulfur dioxide gas is bubbled 9. Sulfur dioxide gas is bubbled into an excess of a saturated into an excess of a saturated solution of calcium hydroxide.solution of calcium hydroxide.SOSO22 + H + H22O --> HO --> H22SOSO33

HH22SOSO33 + Ca + Ca2+2+ + 2OH + 2OH-- --> -->

CaSOCaSO33 + 2H + 2H22OO

SOSO22 + Ca + Ca2+2+ + OH + OH--

CaSOCaSO33 + H + H22OO

Page 148: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

10. A solution of sodium 10. A solution of sodium hydroxide is added to a solution hydroxide is added to a solution of calcium hydrogen carbonate of calcium hydrogen carbonate until the number of moles of until the number of moles of sodium hydroxide added is twice sodium hydroxide added is twice the number of moles of the the number of moles of the calcium salt. calcium salt.22OHOH- - +Ca+Ca2+2+ + + 22HCOHCO33

--

22HH22O + CaCOO + CaCO33

Page 149: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

11. Equal volumes of 0.1M 11. Equal volumes of 0.1M hydrochloric acid and 0.1M hydrochloric acid and 0.1M sodium monohydrogen sodium monohydrogen phosphate are mixed.phosphate are mixed.

HH++ + + 22HPOHPO442-2- H H22POPO44

--

Page 150: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

12. Hydrogen sulfide gas is 12. Hydrogen sulfide gas is bubbled through excess bubbled through excess potassium hydroxide solution.potassium hydroxide solution.

HH22S + OHS + OH- - H H22O + SO + S2-2-

Page 151: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

13. Ammonia gas and carbon 13. Ammonia gas and carbon dioxide gas are bubbled into dioxide gas are bubbled into water.water.

NHNH33 + CO + CO22 + 2H + 2H22O --> O -->

NHNH44++ + 2OH + 2OH-- + H + H22COCO33

2OH2OH-- + H + H22COCO33--> H--> H22O + COO + CO332-2-

NHNH33 + CO + CO22 + H + H22O O

NHNH44++ + CO + CO33

2-2-

Page 152: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

14. Carbon dioxide gas is 14. Carbon dioxide gas is bubbled through a concentrated bubbled through a concentrated solution of sodium hydroxide.solution of sodium hydroxide.

COCO22 + H + H22O --> HO --> H22COCO33

HH22COCO33 + 2OH + 2OH-- --> CO --> CO332-2- + 2H + 2H22OO

COCO22 + OH + OH- - CO CO332-2- + H + H22OO

Page 153: 3.  Solutions of sodium iodide and lead nitrate are mixed. I -  + Pb 2+    PbI 2

15. Acetic acid solution is added 15. Acetic acid solution is added to a solution of sodium hydrogen to a solution of sodium hydrogen carbonate.carbonate.

HCHC22HH33OO22 + HCO + HCO33--

HH22O + COO + CO2 2 + C+ C22HH33OO22--

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16. Excess potassium hydroxide 16. Excess potassium hydroxide solution is added to a solution of solution is added to a solution of potassium dihydrogen phosphate.potassium dihydrogen phosphate.

OHOH-- + H + H22POPO44- - H H22O + POO + PO44

3-3-

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17. Carbon dioxide gas is bubbled through a concentrated solution of potassium hydroxide. COCO22 + H + H22O --> HO --> H22COCO33

HH22COCO33 + 2OH + 2OH-- --> CO --> CO332-2- + 2H + 2H22OO

COCO22 + OH + OH- - CO CO332-2- + H + H22OO

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Complex IonsComplex Ions

1. Concentrated (15M) ammonia 1. Concentrated (15M) ammonia solution is added in excess to a solution is added in excess to a solution of copper(II) nitrate.solution of copper(II) nitrate.

NHNH33 + Cu + Cu2+2+ [Cu(NH [Cu(NH33))44]]2+2+

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2. An excess of nitric acid 2. An excess of nitric acid solution is added to a solution of solution is added to a solution of tetraaminecopper(II) sulfate.tetraaminecopper(II) sulfate.

HH++ + [Cu(NH + [Cu(NH33))44]]2+2+

NHNH44++ + Cu + Cu2+2+

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3. Dilute hydrochloric acid is 3. Dilute hydrochloric acid is added to a solution of added to a solution of diamminesilver(I) nitrate.diamminesilver(I) nitrate.

HH++ + Cl + Cl-- + [Ag(NH + [Ag(NH33))22]]++ AgCl + NHAgCl + NH44

++

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4. Solid aluminum nitrate is 4. Solid aluminum nitrate is dissolved in water.dissolved in water.

Al(NOAl(NO33))33 + H + H22O O

[Al(H[Al(H22O)O)66]]+3+3 + NO + NO33--

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5. A suspension of copper(II) 5. A suspension of copper(II) hydroxide is treated with an hydroxide is treated with an excess of ammonia water.excess of ammonia water.

Cu(OH)Cu(OH)22 + NH + NH33

[Cu(NH[Cu(NH33))44]]2+2+ + OH + OH--

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6. A solution of 6. A solution of diamminesilver(I) chloride is diamminesilver(I) chloride is treated with dilute nitric acid.treated with dilute nitric acid.

[Ag(NH[Ag(NH33))22]]++ + Cl + Cl-- + H + H+ +

NHNH44++ + AgCl + AgCl

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7. An excess of concentrated 7. An excess of concentrated ammonia solution is added to ammonia solution is added to freshly precipitated copper(II) freshly precipitated copper(II) hydroxide.hydroxide.

NHNH33 + Cu(OH) + Cu(OH)22

[Cu(NH[Cu(NH33))44]]2+2+ + OH + OH--

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8. Excess dilute nitric acid is 8. Excess dilute nitric acid is added to a solution containing the added to a solution containing the tetraaminecadmium(II) ion.tetraaminecadmium(II) ion.

HH++ + [Cd(NH + [Cd(NH33))44]]2+2+

NHNH44++ + Cd + Cd2+2+

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9. An excess of ammonia is 9. An excess of ammonia is bubbled through a solution bubbled through a solution saturated with silver chloride.saturated with silver chloride.

NHNH33 + Ag + Ag++ [Ag(NH [Ag(NH33))22]]++

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10. Solid aluminum oxide is 10. Solid aluminum oxide is added to a solution of sodium added to a solution of sodium hydroxide.hydroxide.

AlAl22OO33 + OH + OH-- [Al(OH) [Al(OH)44]]--

(may have water as a (may have water as a reactant)reactant)

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11. A concentrated solution of 11. A concentrated solution of ammonia is added to a solution ammonia is added to a solution of zinc iodide.of zinc iodide.

NHNH33 + Zn + Zn2+ 2+ [Zn(NH [Zn(NH33))44]]2+2+

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12. An excess of sodium 12. An excess of sodium hydroxide solution is added to a hydroxide solution is added to a solution of aluminum chloride.solution of aluminum chloride.

OHOH- - + Al+ Al3+3+ [Al(OH) [Al(OH)44]]--

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13. A concentrated solution of 13. A concentrated solution of ammonia is added to a solution ammonia is added to a solution of copper(II) chloride.of copper(II) chloride.

NHNH33 + Cu + Cu2+2+ [Cu(NH [Cu(NH33))44]]2+2+

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14. Excess concentrated sodium 14. Excess concentrated sodium hydroxide solution is added to hydroxide solution is added to solid aluminum hydroxide.solid aluminum hydroxide.

OHOH-- + Al(OH) + Al(OH)33 [Al(OH) [Al(OH)44]]--

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15. Excess concentrated 15. Excess concentrated ammonia solution is added to a ammonia solution is added to a suspension of silver chloride.suspension of silver chloride.

NHNH33 + AgCl + AgCl

[Ag(NH[Ag(NH33))22]]++ + Cl + Cl--

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16. Pellets of aluminum metal 16. Pellets of aluminum metal are added to a solution containing are added to a solution containing an excess of sodium hydroxide.an excess of sodium hydroxide.

Al + OHAl + OH- - [Al(OH) [Al(OH)44]]--

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17. A suspension of zinc 17. A suspension of zinc hydroxide is treated with hydroxide is treated with concentrated sodium hydroxide concentrated sodium hydroxide solution.solution.

Zn(OH)Zn(OH)22 + OH + OH-- [Zn(OH) [Zn(OH)44]]2-2-

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18. Silver chloride is dissolved 18. Silver chloride is dissolved in excess ammonia solution.in excess ammonia solution.

AgCl + NHAgCl + NH33

[Ag(NH [Ag(NH33))22]]++ + Cl + Cl--

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19. Sodium hydroxide solution 19. Sodium hydroxide solution is added to a precipitate of is added to a precipitate of aluminum hydroxide in water.aluminum hydroxide in water.

OHOH- - + Al(OH)+ Al(OH)33 [Al(OH) [Al(OH)44]]--

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20. A drop of potassium 20. A drop of potassium thiocyanate is added to a solution thiocyanate is added to a solution of iron(III) chloride.of iron(III) chloride.

SCNSCN- - + Fe+ Fe3+3+ FeSCN FeSCN2+2+

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21. A concentrated solution of 21. A concentrated solution of ammonia is added to a ammonia is added to a suspension of zinc hydroxide.suspension of zinc hydroxide.

NHNH33 + Zn(OH) + Zn(OH)22

[Zn(NH[Zn(NH33))44]]2+2+ + OH + OH--

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22. Excess concentrated 22. Excess concentrated potassium hydroxide solution is potassium hydroxide solution is added to a precipitate of zinc added to a precipitate of zinc hydroxide. hydroxide.

Zn(OH)Zn(OH)22 + OH + OH-- [Zn(OH) [Zn(OH)44]]2-2-

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23. 23. A solution of ammonium A solution of ammonium thiocyanate is added to a solution thiocyanate is added to a solution of iron(III) chloride.of iron(III) chloride.

SCNSCN- - + Fe+ Fe3+3+ --> FeSCN --> FeSCN2+2+

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2424. . Excess sodium cyanide is Excess sodium cyanide is added to a solution of silver added to a solution of silver nitrate.nitrate. CNCN-- + Ag + Ag++ --> Ag(CN) --> Ag(CN)22

--

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DecompositionDecomposition

1. A solution of hydrogen 1. A solution of hydrogen peroxide is heated.peroxide is heated.

HH22OO22 O O22 + H + H22OO

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2. Solid magnesium carbonate is 2. Solid magnesium carbonate is heated.heated.

MgCOMgCO33 MgO + CO MgO + CO22

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3. A solution of hydrogen 3. A solution of hydrogen peroxide is catalytically peroxide is catalytically decomposed.decomposed.

HH22OO22 H H22O + OO + O22

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4. Solid potassium chlorate is 4. Solid potassium chlorate is heated in the presence of heated in the presence of manganese dioxide as a catalyst.manganese dioxide as a catalyst.

KClOKClO3 3 --> KCl + O--> KCl + O22

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5. Sodium hydrogen carbonate is 5. Sodium hydrogen carbonate is dissolved in water.dissolved in water.

NaHCONaHCO33 Na Na++ + HCO + HCO33--

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6. Solid ammonium carbonate is 6. Solid ammonium carbonate is heated.heated.

(NH(NH44))22COCO33 CO CO22 + NH + NH33 + H + H22OO

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AdditionAddition

1. The gases boron trifluoride 1. The gases boron trifluoride and ammonia are mixed.and ammonia are mixed.

BFBF33 + NH + NH33 F F33BNHBNH33

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2. A mixture of solid calcium 2. A mixture of solid calcium oxide and solid tetraphosphorus oxide and solid tetraphosphorus decaoxide is heated.decaoxide is heated.

CaO + PCaO + P44OO1010 Ca Ca33(PO(PO44))22

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3. Solid calcium oxide is 3. Solid calcium oxide is exposed to a stream of carbon exposed to a stream of carbon dioxide gas.dioxide gas.

CaO + COCaO + CO22 CaCO CaCO33

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4. Solid calcium oxide is heated 4. Solid calcium oxide is heated in the presence of sulfur trioxide in the presence of sulfur trioxide gas.gas.

CaO + SOCaO + SO33 CaSO CaSO44

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5. Calcium metal is heated 5. Calcium metal is heated strongly in nitrogen gas.strongly in nitrogen gas.

Ca + NCa + N2 2 Ca Ca33NN22

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6. Excess chlorine gas is passed 6. Excess chlorine gas is passed over hot iron filings.over hot iron filings.

ClCl22 + Fe + Fe FeCl FeCl33

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7. Powdered magnesium oxide is 7. Powdered magnesium oxide is added to a container of carbon added to a container of carbon dioxide gas.dioxide gas.

MgO + COMgO + CO22 MgCO MgCO33

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8. A piece of lithium metal is 8. A piece of lithium metal is dropped into a container of dropped into a container of nitrogen gas.nitrogen gas.

Li + NLi + N22 Li Li33NN

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9. Magnesium metal is burned in 9. Magnesium metal is burned in nitrogen gas.nitrogen gas.

Mg + NMg + N22 Mg Mg33NN22

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10. Sulfur dioxide gas is passed 10. Sulfur dioxide gas is passed over solid calcium oxide.over solid calcium oxide.

SOSO22 + CaO + CaO CaSO CaSO33

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11. Samples of boron trichloride 11. Samples of boron trichloride gas and ammonia gas are mixed.gas and ammonia gas are mixed.

BClBCl33 + NH + NH33 --> H --> H33NBClNBCl33