8. ghs hazard comm labeling & sds - 1

7/23/2019 8. GHS Hazard Comm Labeling & SDS - 1

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Globally Harmonized System of ClassicationGlobally Harmonized System of ClassicationSystem of Classication and Labelling of ChemicalsSystem of Classication and Labelling of Chemicals

(GHS)(GHS)

Hazard Communication :Hazard Communication :

Labelling and SDS (1)Labelling and SDS (1)



HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 22

One of the objectives of the workOne of the objectives of the work

on the Globally Harmonizedon the Globally HarmonizedSystem (GHS) is the developmentSystem (GHS) is the developmentof aof a harmonized communicationharmonized communication

systemsystem ,, includingincluding abelling! Safetyabelling! Safetydata sheets (S"S)data sheets (S"S) and easilyand easilyunderstandable symbols! based onunderstandable symbols! based on

classification criteria developed forclassification criteria developed forthe GHS#the GHS#




GHSGHSHazard CommunicationHazard Communication : :

LabellingLabelling




Hazard CommunicationHazard CommunicationIn the GHS DocumentIn the GHS Document

Chapter 1.4 -Chapter 1.4 - Hazard Communication :Hazard Communication : LabellingLabelling

• Target audiencesTarget audiences• ComprehensibilityComprehensibility

• Comprehensibility testing methodologyComprehensibility testing methodology• TranslationTranslation• StandardizationStandardization• Use of non-standardized or supplementalUse of non-standardized or supplemental

informationinformation• Updating informationUpdating information• Con dential business information !C"#$Con dential business information !C"#$• TrainingTraining• %abelling procedures%abelling procedures




abellingabellingThe harmo !"e# $%$ em 'or ha"ar# (omm) !(a !o ! (*)#e$The harmo !"e# $%$ em 'or ha"ar# (omm) !(a !o ! (*)#e$

he a++ro+r!a e *a e**! oo*$ o (o .e% ! 'orma !o a o)he a++ro+r!a e *a e**! oo*$ o (o .e% ! 'orma !o a o)ea(h o' he ha"ar# (*a$$e$ a # (a e or!e$ ! he GHS/ea(h o' he ha"ar# (*a$$e$ a # (a e or!e$ ! he GHS/

The )$e o' $%m o*$, $! a* 0or#$ or ha"ar# $ a eme $ o herThe )$e o' $%m o*$, $! a* 0or#$ or ha"ar# $ a eme $ o herha ho$e, 0h!(h ha.e ee a$$! e# o ea(h o' he GHSha ho$e, 0h!(h ha.e ee a$$! e# o ea(h o' he GHS

ha"ar# (*a$$e$ a # (a e or!e$, 0o)*# e (o rar% oha"ar# (*a$$e$ a # (a e or!e$, 0o)*# e (o rar% oharmo !"a !o /harmo !"a !o /

abels communicate the hazard(s) according GHSabels communicate the hazard(s) according GHS

classification to target audiencesclassification to target audiences




abelling $abelling $ %arget audiences%arget audiences

Labels co mmunicate the hazard(s)Labels co mmunicate the hazard(s)according GHS classication to targetaccording GHS classication to targetaudiencesaudiences

&& or +*a(e- Co $)mer$- Emer e (% re$+o #er$- Tra $+or




abelling $abelling $ Tar e a)#!e (e$ 728Tar e a)#!e (e$ 728

-- Consumers Consumers The *a e* ! mo$ (a$e$ !$ *! e*% o eThe *a e* ! mo$ (a$e$ !$ *! e*% o e

he $o*e $o)r(e o' ! 'orma !o rea#!*%he $o*e $o)r(e o' ! 'orma !o rea#!*% a.a!*a *e o he (o $)mer/a.a!*a *e o he (o $)mer/

The *a e*, here'ore, 0!** ee# o eThe *a e*, here'ore, 0!** ee# o e$)''!(!e *% #e a!*e# a # re*e.a o$)''!(!e *% #e a!*e# a # re*e.a o

he )$e o' he +ro#)( /he )$e o' he +ro#)( /




abelling $ %arget audiences ( )abelling $ %arget audiences ( )

-- Emergency respondersEmergency responders Emer e (% re$+o #er$ ee# ! 'orma !oEmer e (% re$+o #er$ ee# ! 'orma !o

o a ra e o' *e.e*$/o a ra e o' *e.e*$/

To 'a(!*! a e !mme#!a e re$+o $e$, he%To 'a(!*! a e !mme#!a e re$+o $e$, he%ee# a(()ra e, #e a!*e# a # $)''!(!e *%ee# a(()ra e, #e a!*e# a # $)''!(!e *%

(*ear ! 'orma !o / Th!$ a++*!e$ ! he(*ear ! 'orma !o / Th!$ a++*!e$ ! hee.e o' a a((!#e #)r! ra $+or a !o ,e.e o' a a((!#e #)r! ra $+or a !o ,! $ ora e 'a(!*! !e$ or a 0or +*a(e$/! $ ora e 'a(!*! !e$ or a 0or +*a(e$/



HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS :;:;

abelling $ %arget audiences ( )abelling $ %arget audiences ( )

-- Transport Transport The UN Re(omme #a !o $ o heThe UN Re(omme #a !o $ o he

Tra $+or o' Da ero)$ Goo#$, Mo#e*Tra $+or o' Da ero)$ Goo#$, Mo#e*re )*a !o $, (a er 'or a 0!#e ra e o're )*a !o $, (a er 'or a 0!#e ra e o'

ar e a)#!e (e$ a* ho) h ra $+orar e a)#!e (e$ a* ho) h ra $+or0or er$ a # emer e (% re$+o #er$ are0or er$ a # emer e (% re$+o #er$ are

he +r! (!+a* o e$/ O her$ ! (*)#ehe +r! (!+a* o e$/ O her$ ! (*)#eem+*o%er$, ho$e 0ho o''er or a((e+em+*o%er$, ho$e 0ho o''er or a((e+#a ero)$ oo#$ 'or ra $+or or *oa# or#a ero)$ oo#$ 'or ra $+or or *oa# or) *oa# +a( a e$ o' #a ero)$ oo#$) *oa# +a( a e$ o' #a ero)$ oo#$! o or 'rom ra $+or .eh!(*e$, or 're! h! o or 'rom ra $+or .eh!(*e$, or 're! h(o a! er$/(o a! er$/



HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS ::::

%arget audiences needs have been identified%arget audiences needs have been identified

Workplace -Workplace - Em+*o%er$ a # 0or er$ ee# o o0 he ha"ar#$ $+e(!'!( o heEm+*o%er$ a # 0or er$ ee# o o0 he ha"ar#$ $+e(!'!( o he

(hem!(a*$ )$e# a # or ha #*e# ! he 0or +*a(e, a$ 0e** a$ ! 'orma !o a o)(hem!(a*$ )$e# a # or ha #*e# ! he 0or +*a(e, a$ 0e** a$ ! 'orma !o a o)he $+e(!'!( +ro e( !.e mea$)re$ re )!re# o a.o!# he a#.er$e e''e( $ hahe $+e(!'!( +ro e( !.e mea$)re$ re )!re# o a.o!# he a#.er$e e''e( $ ham! h e (a)$e# % ho$e ha"ar#$/m! h e (a)$e# % ho$e ha"ar#$/

Consumers -Consumers - The *a e* ! mo$ (a$e$ !$ *! e*% o e he $o*e $o)r(e o'The *a e* ! mo$ (a$e$ !$ *! e*% o e he $o*e $o)r(e o'! 'orma !o rea#!*% a.a!*a *e o he (o $)mer/ The *a e*, here'ore, 0!** ee# o! 'orma !o rea#!*% a.a!*a *e o he (o $)mer/ The *a e*, here'ore, 0!** ee# o

e $)''!(!e *% #e a!*e# a # re*e.a o he )$e o' he +ro#)( /e $)''!(!e *% #e a!*e# a # re*e.a o he )$e o' he +ro#)( /

Emergency responders - labels, placards :Emergency responders - labels, placards : Emer e (% re$+o #er$ ee#Emer e (% re$+o #er$ ee#! 'orma !o o a ra e o' *e.e*$/ To 'a(!*! a e !mme#!a e re$+o $e$, he% ee#! 'orma !o o a ra e o' *e.e*$/ To 'a(!*! a e !mme#!a e re$+o $e$, he% ee#a(()ra e, #e a!*e# a # $)''!(!e *% (*ear ! 'orma !o / Th!$ a++*!e$ ! he e.ea(()ra e, #e a!*e# a # $)''!(!e *% (*ear ! 'orma !o / Th!$ a++*!e$ ! he e.eo' a a((!#e #)r! ra $+or a !o , ! $ ora e 'a(!*! !e$ or a 0or +*a(e$/o' a a((!#e #)r! ra $+or a !o , ! $ ora e 'a(!*! !e$ or a 0or +*a(e$/

Transport - labels, placards, transport documents :Transport - labels, placards, transport documents : TThe UNhe UNRe(omme #a !o $ o he Tra $+or o' Da ero)$ Goo#$, Mo#e* Re )*a !o $,Re(omme #a !o $ o he Tra $+or o' Da ero)$ Goo#$, Mo#e* Re )*a !o $,(a er 'or a 0!#e ra e o' ar e a)#!e (e$ a* ho) h ra $+or 0or er$ a #(a er 'or a 0!#e ra e o' ar e a)#!e (e$ a* ho) h ra $+or 0or er$ a #emer e (% re$+o #er$ are he +r! (!+a* o e$/ O her$ ! (*)#e em+*o%er$,emer e (% re$+o #er$ are he +r! (!+a* o e$/ O her$ ! (*)#e em+*o%er$,

ho$e 0ho o''er or a((e+ #a ero)$ oo#$ 'or ra $+or or *oa# or ) *oa#ho$e 0ho o''er or a((e+ #a ero)$ oo#$ 'or ra $+or or *oa# or ) *oa#+a( a e$ o' #a ero)$ oo#$ ! o or 'rom ra $+or .eh!(*e$, or 're! h+a( a e$ o' #a ero)$ oo#$ ! o or 'rom ra $+or .eh!(*e$, or 're! h(o a! er$/(o a! er$/



HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS :2:2

La e**! <ro(e#)re$La e**! <ro(e#)re$*llocation of abel elements*llocation of abel elements+eproduction of the symbol+eproduction of the symbol+eproduction of the Hazard ,ictograms+eproduction of the Hazard ,ictogramsSignal -ordsSignal -ords

Hazard StatementsHazard Statements,recautionary statements and pictograms,recautionary statements and pictograms,roduct and supplier identification,roduct and supplier identification.ultiple hazards and precedence of information.ultiple hazards and precedence of information

*rrangements for presenting the GHS label*rrangements for presenting the GHS labelelementselementsSpecial labelling arrangementsSpecial labelling arrangements




La e* E*eme $La e* E*eme $ <!( o ram$<!( o ram$

,ictogram for flammable li/uidin the 01 .odel +egulations(Symbol$ 2lame$ 3lack or -hite43ackground#

,ictograms prescribed by the GHSshould have a black symbol on awhite background with a red framesufficiently wide to be clearlyvisible#

GHS <!( o ram UN RTDG <!( o ramGHS <!( o ram UN RTDG <!( o ram




La e**!La e**! <!( o ram$<!( o ram$ :: Convey health, physical &Convey health, physical &

environmental hazard information.environmental hazard information.



HAZARD COMMUNICATION -LABELLING & SDS :5

Oxidizers Organic Peroxides

Flammables Self Reactives Pyrophorics Self-Heating Emits Flammable

Gas

Explosives Self Reactives Organic Peroxides

Acute Toxicity (severe) Corrosives Gases underpressure

Carcinogen Respiratory Sensitizer Reproductive Target Organ Toxicity Mutagenicity

Environmental Toxicity

Iriitant Dermal Sensitizer Acute To xicity

(harmful )

GHS Pictograms




UN Dangerous Goods Transport Labelling

Class 1Explosives

Class 1Div. 4

Class 1Div. 5

Class 1Div. 6

Class 2, Div. 2.1Flammable gases

Class 2Div. 2.2, Non

ammablenon toxic g as

Class 2Div. 2.3Toxic g ases

Class 3 Flammable liquids

Class 4 ,Div.4.1Flammable

solids

Class4,Div.4.2Spontaneouscombustion

Class 4, Div. 4.3Emit ammable gasesin contact with water

Class 5 ,Div.5.1Oxidizingsubstances

Class 5 ,Div.5.2Organicperoxides

Class 6 ,Div.6.1Toxicsubstances

Class 8Corrosivesubstances



HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS ::

La e**!La e**!

Signal Words:Signal Words: ““ Danger”Danger” oror “Warning”“Warning”

are used to emphasis h azard andare used to emphasis h azard andindicate the relative of severity of theindicate the relative of severity of thehazard.hazard.




La e**!La e**!

Hazard Statements:Hazard Statements: Standard phrased assigned to a hazard class a ndStandard phrased assigned to a hazard class a ndcategory to specied the nature of the hazard.category to specied the nature of the hazard.

Example : Acute Toxicity OralExample : Acute Toxicity Oral

= (a e or% :(a e or% :“ “ Fatal if swallowed “ Fatal if swallowed “

= Ca e or% 2Ca e or% 2“ “ Fatal if swallowed ” Fatal if swallowed ”

= Ca e or% 3Ca e or% 3“ “ Toxic if swallowed” Toxic if swallowed”

= Ca e or% 4Ca e or% 4 “ “ Harmful if swallowed” Harmful if swallowed”

= Ca e or% 5Ca e or% 5

“ “ Maybe harmful if swallowed” Maybe harmful if swallowed”




Label elements Example Acute toxicity,oral)

(GHS Recommendation Annex )

Ca e or%:

Ca e or%2

Ca e or%3

Ca e or%4

Ca e or%5

Da er

>a a* !'$0a**o0e#

Da er

>a a* !'$0a**o0e#

Da er

To?!( !'$0a**o0e#

ar !

Harm')* !' S0a**o0e#

NoS%m o*

ar !

Ma% eharm')* !'

$0a**o0e#

Signal &ord

'ictograms

Hazard

statements



HAZARD COMMUNICATION -LABELLING & SDS 2;

Label elements ExampleCarcinogenicity)


Ca e or% :A Ca e or% :B Ca e or% 2

Da er

Ma% (a)$e (a (er 7state route of

exposure if it isconclusively proventhat no other routesof exposure causethe hazard )

Da er

Ma% (a)$e (a (er 7state route of


ar !

S)$+e( e# o' (a)$!(a (er 7 state route of




HAZARD COMMUNICATION -LABELLING & SDS 2:

Label elements Example 3 Aquatic toxicity,acute)


Ca e or% : Ca e or% 2 Ca e or% 3

ar !

@er% o?!( o a )a !(

*!'e

No $%m o*

No $! a* 0or#

To?!( o a )a !( *!'e

No $%m o*

No $! a* 0or#

Harm')* o a )a !( *!'e




La e**!La e**!

Precautionary S tatementsPrecautionary Statements

GHS label should include appropriateprecautionary information

GHS document contains e5amples ofprecautionary statements which can be used

%he intent is to harmonize precautionarystatements in the future as *nne5 to6,urple book7



HAZARD COMMUNICATION -HAZARD COMMUNICATION -

LABELLING & SDSLABELLING & SDS 2323

abellingabellingPrecautionary statements:Precautionary statements:

Measures to minimize or prevent adverseMeasures to minimize or prevent adverseeffects.effects.

Example : (GHS Recommendation Annex 3)Example : (GHS Recommendation Annex 3)

* # # #* # # # *ccident caused by ingestion*ccident caused by ingestion

8f swallowed! seek medical advice immediately8f swallowed! seek medical advice immediatelyand show this container or label#and show this container or label#

8f swallowed! rinse mouth with water (only if the8f swallowed! rinse mouth with water (only if the person is conscious)#person is conscious)#

8f swallowed! and the victim is conscious and8f swallowed! and the victim is conscious andalert! induce vomiting immediately! as directedalert! induce vomiting immediately! as directed

by medical personnel#by medical personnel#

S b&9ommittee of :5perts on the Globall Harmoni ed S stem of 9lassification and abelling of 9hemicals



HAZARD COMMUNICATION -LABELLING & SDS 24

*90%: %O;898%< & O+* 9H*,%:+ #')

Hazard 9ategory Signal -ord Hazard Statement : Da er >a a* !' $0a**o0e#

2 Da er >a a* !' $0a**o0e#

'recautionary Statements

're(ention )esponse Storage *isposal )eference

+ ,eep out ofreach of

children.

+ *o not eatdrin or smo e&hen using thisproduct.

+ /ash handsthoroughly

after handling.

0(oid allcontact .

# S/0%%2/3*:#mmediately call a'2#S2 C2 T)2%C3 T3)5 doctor/physician .

Sho&container5label5Safety *ata Sheet&hen possible.

#nduce (omiting !ifconscious$.- if knowledge of thechemical indicatesthisaction is notcontraindicated.

6i(e &ater5nothingtodrin .

6i(e a slurry ofacti(ated charcoal- if ingestion of a

+ Store locked up# "ispose of thismaterial and itscontainer to ### #/// ! a((or#a (e 0! h*o(a*re !o a* a !o a*! er a !o a*re )*a !o 8/

+ if likely to be usedby the generalpublic#

== +ead directions>label>Safety "ata Sheetbefore use#

Specific treatment isurgent (see ### on thislabel)/// re'ere (e oS)++*eme a* >!r$ A!#I $ r)( !o /!' !mme#!a e a#m! !$ ra !oo' a !#o e !$ re )!re#/

== if likely to be usedcommercially /

Symbol S ull andcrossbones

Sub&9ommittee of :5perts on the Globally Harmonized System of 9lassification and abelling of 9hemicals(?@@ >A)

":B: O,.:1% O2 G08"*19: 2O+ 8., :.:1%*%8O1 ,recautionary Statements (,S) Draft !





abellingabelling

Product IdentierProduct Identier

1ame or number used for a hazardousproduct on a label or in the S"S#

0ni/ue means by which the substance ormi5ture can be identified within theparticular use setting

01 proper shipping name also to be usedon the package when substance or mi5turecovered by the 01 +%"G





La e**!La e**!

Supplier Identication:Supplier Identication: The name, address an d telephone sh ould beThe name, address an d telephone sh ould beprovided on the label.provided on the label.

Supplemental Information:Supplemental Information:non-harmonized informationnon-harmonized information ..




La e* e?am+*eLa e* e?am+*e




Precedence for the allocation of symbolsPrecedence for the allocation of symbols(1)(1)

For substances an d mixtures co veredFor substances and mixtures coveredbyby the UN Recommendations on thethe UN Recommendations on the

Transport of Dangerous Goods, ModelTransport of Dangerous Goods, ModelRegulationsRegulations ,, the p recedence ofthe p recedence ofsymbols for physical hazards shouldsymbols for physical hazards should

follow the rules offollow the rules of the UN Modelthe UN ModelRegulationsRegulations ..





For health hazards the following principles ofFor health hazards the following principles ofprecedence a pply:precedence a pply:(a) if the (a) if the Skull and crossbonesSkull and crossbones applies,applies,

thethe Exclamation markExclamation mark should not appear;should not appear;

(b) if the (b) if the Corrosive symbolCorrosive symbol applies,applies,thethe Exclamation markExclamation mark should not appearshould not appearwhere it is used for skin or eye irritation;where it is used for skin or eye irritation;

(c) if the (c) if the Health hazard symbolHealth hazard symbol appears forappears forrespiratory sensitisation, therespiratory sensitisation, the ExclamationExclamation

markmark should not appear where it is u sedshould not appear where it is u sedfor skin sensitisation or for skin or eyefor skin sensitisation or for skin or eyeirri tation.irri tation.



HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 3;3;


Precedence for allocation of signalPrecedence for allocation of signalwords If the signal wordwords If the signal word ‘‘DangerDanger ’’

applies, the signal wordapplies, the signal word ‘‘WarningWarning ’’ should not appear.should not appear.



HAZARD COMMUNICATION -HAZARD COMMUNICATION -LABELLING & SDSLABELLING & SDS 3:3:

Precedence for the allocation of symbolsPrecedence for the allocation of symbols

Skin>:ye irritationSkin>:ye irritation

Skin sensitization!Skin sensitization! Skin>:ye irritationSkin>:ye irritation

"*1G:+"*1G:+ -*+181G-*+181G



HAZARD COMMUNICATION -LABELLING & SDS 32

6lobal Haze7y

6lobalethylene( !Hazanol

C"S #o$ ! !

*anger

Hazard statements Combustible li%uid

Harm&ul i& s'allo'ed o ic in contact 'ith s*inCause serious s*in burns and eye

irritationCause serious eye irritation

Supplier: +nited #ations Corp$ Ltd$ 1!1, -eace ".e$ ene.a, S'itzerland 0L: 1 213 44 444 5"6: 1 213 44

444

6HS%abel

'roduct

identi er

'ictograms

Hazardstatements

Signal&ord

Supplieridenti cation





ContinueContinue



Globally Harmonized System of ClassicationGlobally Harmonized System of ClassicationSystem of Classication and Labelling of ChemicalsSystem of Classication and Labelling of Chemicals

(GHS)(GHS)

Hazard Communication :Hazard Communication :Labelling and SDS ( )Labelling and SDS ( )

GHS ,+*9%89* %+*8181G &GHS ,+*9%89* %+*8181G & * %echnical *ssistance for * %echnical *ssistance for C1&+98 membersC1&+98 membersDakarta! .arch ? E ?A! ?@@FDakarta! .arch ? E ?A! ?@@F





Sa&ety Data Sheet (SDS)Sa&ety Data Sheet (SDS)

d h




Hazard Communication in the GHSHazard Communication in the GHSDocumentDocument

Chapter 1.5, Hazard communication :Chapter 1.5, Hazard communication : Safety dataSafety datasheets (SDS)sheets (SDS)

Role of the SDS in the GHSRole of the SDS in the GHS

Criteria for determining whether an SDSCriteria for determining whether an SDS

should be producedshould be produced

GG eneral guidance for compiling a S DSeneral guidance for compiling a S DSSDSSDS formatformat

SDSSDS contentcontent




Role of the SDS in the GHSRole of the SDS in the GHS

SDS $ho)*# +ro.!#e (om+rehe $!.eSDS $ho)*# +ro.!#e (om+rehe $!.e! 'orma !o a o) a (hem!(a* $) $ a (e or! 'orma !o a o) a (hem!(a* $) $ a (e orm!? )re 'or )$e ! 0or +*a(e/m!? )re 'or )$e ! 0or +*a(e/

Bo hBo h employersemployers a #a # workersworkers )$e ! a$ a)$e ! a$ a$o)r(e o' $o)r(e o' ! 'orma !o a o)! 'orma !o a o) ha"ar#$ha"ar#$ ,,! (*)#! e .!ro me a* ha"ar#$, a # o! (*)#! e .!ro me a* ha"ar#$, a # oo a! a#.!(e oo a! a#.!(e o $a'e % +re(a) !o $/$a'e % +re(a) !o $/




SDSSDS Target AudiencesTarget Audiences

SDS +ro.!#e$ a !m+or a $o)r(e o'SDS +ro.!#e$ a !m+or a $o)r(e o'! 'orma !o 'or ar e a)#!e (e$ ! 'orma !o 'or ar e a)#!e (e$

- or +*a(e 7em+*o%er a # 0or er8or +*a(e 7em+*o%er a # 0or er8- Co $)mer$Co $)mer$- Emer e (% re$+o #er$ 7! (*)#! <o!$o Ce re$8Emer e (% re$+o #er$ 7! (*)#! <o!$o Ce re$8- Tra $+or er$ = TREM (ar#Tra $+or er$ = TREM (ar#- Tho$e ! .o*.e# ! he +ro'e$$!o a* )$e o' <e$ !(!#e$Tho$e ! .o*.e# ! he +ro'e$$!o a* )$e o' <e$ !(!#e$




T)38 Card




Criteria for determining whether aCriteria for determining whether aSDS should be producedSDS should be produced

SDS $ho)*# e +ro#)(e# 'or a** $) $ a (e$SDS $ho)*# e +ro#)(e# 'or a** $) $ a (e$a # m!? )re$ 0h!(h mee he harmo !"e#a # m!? )re$ 0h!(h mee he harmo !"e#(r! er!a 'or +h%$!(a*, hea* h or e .!ro me a*(r! er!a 'or +h%$!(a*, hea* h or e .!ro me a*ha"ar#$ ) #er he GHS a # 'or a** m!? )re$ha"ar#$ ) #er he GHS a # 'or a** m!? )re$0h!(h (o a! $) $ a (e$ ha mee he0h!(h (o a! $) $ a (e$ ha mee he(r! er!a 'or (ar(! o e !(, o?!( o re+ro#)( !o(r! er!a 'or (ar(! o e !(, o?!( o re+ro#)( !o

or $+e(!'!( ar e or a $%$ em!( o?!(! % !or $+e(!'!( ar e or a $%$ em!( o?!(! % !(o (e ra !o $ e?(ee#! he () -o'' *!m! $ 'or(o (e ra !o $ e?(ee#! he () -o'' *!m! $ 'orSDS $+e(!'!e# % he (r! er!a 'or m!? )re$/SDS $+e(!'!e# % he (r! er!a 'or m!? )re$/



When is a S DS required?When is a S DS required?

SDS should be produced for allSDS should be produced for allsubstancessubstances and and mixturesmixtures which meetwhich meet

the harmonized criteria under the GHSthe harmonized criteria under the GHSand for all mixtures which containand for all mixtures which containsubstances t hat meet the GHS criteriasubstances t hat meet the GHS criteriaexceeding theexceeding the c ut-off limitscut-off limits 'or ea(h'or ea(hha"ar# (*a$$/ha"ar# (*a$$/




General guidance for compiling a S DSGeneral guidance for compiling a S DS

:/5/3/: C) -o'' .a*)e$ (o (e ra !o *!m! $:/5/3/: C) -o'' .a*)e$ (o (e ra !o *!m! $SDS $ho)*# e +ro.!#e# a$e# o he e er!(SDS $ho)*# e +ro.!#e# a$e# o he e er!(

() -o'' .a*)e$ (o (e ra !o *!m! $ ! #!(a e#() -o'' .a*)e$ (o (e ra !o *!m! $ ! #!(a e#

! Ta *e :/5/: ! Ta *e :/5/:




9ut&off values>9oncentration limits for each health andenvironmental hazard class

Hazard 9lassHazard 9lass

9ut&off value >9ut&off value >

9oncentration imit9oncentration imit A() e To?!(! % A() e To?!(! % ≧ ≧ :/;:/;

S ! Corro$!o Irr! a !oS ! Corro$!o Irr! a !o ≧ ≧ :/;:/;

Ser!o)$ #ama e o e%e$ e%e !rr! a !oSer!o)$ #ama e o e%e$ e%e !rr! a !o ≧ ≧ :/;:/;

Re$+!ra or% S ! Se $! !"a !oRe$+!ra or% S ! Se $! !"a !o ≧ ≧ :/;:/;

.utagenicity$ 9ategory '.utagenicity$ 9ategory ' 7 7 @#'@#'

M) a e !(! % Ca e or% 2M) a e !(! % Ca e or% 2 ≧ ≧ :/;:/;

9arcinogenicity9arcinogenicity ≧ ≧

@#'@#'

+eproductive %o5icity+eproductive %o5icity ≧ ≧ @#'@#'

S+e(!'!( Tar e Or a S%$ em!( To?!(! %S+e(!'!( Tar e Or a S%$ em!( To?!(! %7S! *e E?+o$)re 7S! *e E?+o$)re +epeat :5posure)+epeat :5posure)

≧ ≧ :/;:/;

Ha"ar#o)$ o he A )a !( E .!ro meHa"ar#o)$ o he A )a !( E .!ro me ≧ ≧ :/;:/;




Safety Data SheetsSafety Data Sheets,rimarily workplace use,rimarily workplace use

'A heading format agreed! similar to the 8 O and'A heading format agreed! similar to the 8 O and8SO format! but8SO format! but sections ? and reversedsections ? and reversed

.inimum additional information specified! where.inimum additional information specified! whereapplicable or available! under the relevantapplicable or available! under the relevant

headingsheadings




S"S format (')S"S format (')%he information in the S"S should be presented using the%he information in the S"S should be presented using the

following 'A headings in the order following 'A headings in the order !.e e*o0 !.e e*o0

:/:/ I#e !'!(a !oI#e !'!(a !o2/2/ Ha"ar#7$8 !#e !'!(a !oHa"ar#7$8 !#e !'!(a !o3/3/ Com+o$! !o ! 'orma !o o ! re#!e $Com+o$! !o ! 'orma !o o ! re#!e $4/4/ >!r$ -a!# mea$)re$>!r$ -a!# mea$)re$5/ >!re-'! h ! mea$)re$5/ >!re-'! h ! mea$)re$

1/ A((!#e a* re*ea$e mea$)re$1/ A((!#e a* re*ea$e mea$)re$/ Ha #*! a # $ ora e/ Ha #*! a # $ ora e

6/ E?+o$)re (o ro*$ +er$o a* +ro e( !o6/ E?+o$)re (o ro*$ +er$o a* +ro e( !o




SDS format (2)SDS format (2)

# ,hysical and chemical properties# ,hysical and chemical properties

'@# Stability and reactivity'@# Stability and reactivity ''# %o5icological information''# %o5icological information '?# :cological information'?# :cological information ' # "isposal considerations' # "isposal considerations ' # %ransport information' # %ransport information ' # +egulatory information' # +egulatory information 'A# Other information'A# Other information

* S"S is not a fi5ed length document# %he length of the S"S should* S"S is not a fi5ed length document# %he length of the S"S shouldbe commensurate with the hazard of the material and thebe commensurate with the hazard of the material and theinformation available#information available#

MinimuminformationforaSDScontent( 1)MinimuminformationforaSDScontent( 1)




Minimum information for a SDS content ( 1)Minimum information for a SDS content ( 1)

:: Identication of the

substance o r mixture

and of the supplier

GHS +ro#)( !#e !'!er/O her mea $ o' !#e !'!(a !o /Re(omme #e# )$e o' he (hem!(a*

a # re$ r!( !o $ o )$e/S)++*!er $ #e a!*$ 7! (*)#! ame,

a##re$$, +ho e )m er e (8/Emer e (% +ho e )m er/

2 Hazards identication GHS classification o' he $) $ a (e m!? )re a # a % a !o a* or re !o a* ! 'orma !o /

GHS label elements , ! (*)#! +re(a) !o ar% $ a eme $/

O her ha"ar#$ 0h!(h #o o re$)* ! (*a$$!'!(a !o or are o (o.ere#

% he GHS/






3 Composition/

information on

ingredients

NOTE >or ! 'orma !o o

! re#!e $, he (om+e ea) hor! % r)*e$ 'or CBI a e+r!or! % o.er he r)*e$ 'or+ro#)( !#e !'!(a !o /

SubstanceChem!(a* !#e ! %/Commo ame, $% o %m$, e (/CAS )m er, EC )m er, e (/Im+)r! !e$ a # $ a !*!"! a##! !.e$

0h!(h are hem$e*.e$ (*a$$!'!e#a # 0h!(h (o r! ) e o he

(*a$$!'!(a !o o' he $) $ a (e/

.i5ture%he chemical identity and

concentration or concentration ranges of all ingredients which

are hazardous within themeaning of the GHS and are

present above their cut&off levels#






4 First aid measures De$(r!+ !o o' e(e$$ar% mea$)re$, $) #!.!#e# a((or#! o he

#!''ere ro) e$ o' e?+o$)re, !/e/! ha*a !o , $ ! a # e%e (o a(a # ! e$ !o /

Mo$ !m+or a $%m+ om$ e''e( $, a() e a # #e*a%e#/

I #!(a !o o' !mme#!a e me#!(a* a e !o a # $+e(!a* rea me ee#e#, !' e(e$$ar%/

5 Fire-ghting measures S)! a *e 7a # ) $)! a *e8 e? ! )!$h! me#!a/

S+e(!'!( ha"ar#$ ar!$! 'rom he

(hem!(a* 7e/ / a )re o' a % ha"ar#o)$ (om )$ !o +ro#)( $8/

S+e(!a* +ro e( !.e e )!+me a # +re(a) !o $ 'or '!re'! h er$/






1 Accidental releasemeasures

<er$o a* +re(a) !o $, +ro e( !.e e )!+me a # emer e (%

+ro(e#)re$/E .!ro me a* +re(a) !o $/Me ho#$ a # ma er!a*$ 'or

(o a! me a # (*ea ! )+

Handling and storage <re(a) !o $ 'or $a'e ha #*! /

Co #! !o $ 'or $a'e $ ora e,! (*)#! a % ! (om+a ! !*! !e$/

6 Exposure

controls/personal

protection /

Co ro* +arame er$ e/ /o(()+a !o a* e?+o$)re *!m! .a*)e$

or !o*o !(a* *!m! .a*)e$/ A++ro+r!a e e ! eer! (o ro*$/I #!.!#)a* +ro e( !o mea$)re$,$)(h a$ +er$o a* +ro e( !.ee )!+me /






9 Physical and chemicalproperties

A++eara (e 7+h%$!(a* $ a e, (o*o)r8/O#o)r/O#o)r hre$ho*#/

+H/Me* ! +o! 'ree"! +o! /I ! !a* o!*! +o! a # o!*! ra e/>*a$h +o! /E.a+ora !o ra e/>*amma !*! % 7$o*!#, a$8/U++er *o0er '*amma !*! % or

e?+*o$!.e *!m! $/@a+o)r +re$$)re/@a+o)r #e $! %/Re*a !.e #e $! %/So*) !*! %7!e$8/<ar ! !o (oe''!(!e -o( a o* 0a er/

A) o-! ! !o em+era )re/De(om+o$! !o em+era )re/





Minimum information for a SDS content ( 6)Minimum information for a SDS content ( 6):; Stability and reactivity Chem!(a* $ a !*! %/

<o$$! !*! % o' ha"ar#o)$ rea( !o $/Co #! !o $ o a.o!# 7e/ / $ a !(

#!$(har e, $ho( or .! ra !o 8/I (om+a ! *e ma er!a*$/Ha"ar#o)$ #e(om+o$! !o

+ro#)( $/

:: Toxicologicalinformation

! 'orma !o o he *! e*% ro) e$ o' e?+o$)re 7! ha*a !o , ! e$ !o ,$ ! a # e%e (o a( 8S%m+ om$ re*a e# o he +h%$!(a*,

(hem!(a* a # o?!(o*o !(a*

(hara( er!$ !($De*a%e# a # !mme#!a e e''e( $ a # a*$o (hro !( e''e( $ 'rom

$hor - a # *o - erm e?+o$)reN)mer!(a* mea$)re$ o' o?!(! %

7$)(h a$ a() e o?!(! % e$ !ma e$8/





Minimum information for a SDS content ( 7)Minimum information for a SDS content ( 7):2 Ecological information E(o o?!(! % 7a )a !( a #

erre$ r!a*, 0here a.a!*a *e8/

<er$!$ e (e a # #e ra#a !*! %/B!oa(()m)*a !.e +o e !a*/Mo !*! % ! $o!*/O her a#.er$e e''e( $/

:3 Disposalconsiderations

De$(r!+ !o o' 0a$ e re$!#)e$a # ! 'orma !o o he!r

$a'e ha #*! a # me ho#$ o'

#!$+o$a*, ! (*)#! he #!$+o$a* o'

a % (o am! a e# +a( a ! /

MinimuminformationforaSDScontent(8)MinimuminformationforaSDScontent(8)




Minimum information for a SDS content (8)Minimum information for a SDS content (8):4 Transport information UN )m er/

01 ,roper shipping name //Tra $+or Ha"ar# (*a$$7e$8/<a( ! ro)+, !' a++*!(a *e/Mar! e +o**) a 7Fe$ No8/S+e(!a* +re(a) !o $ 0h!(h a )$er

ee#$ o e a0are o' or ee#$ o (om+*% 0! h ! (o e( !o 0! h ra $+or or (o .e%a (e e! her

0! h! or o) $!#e he!r +rem!$e$/

:5 Regulatoryinformation

Sa'e %, hea* h a # e .!ro me a* re )*a !o $ $+e(!'!( 'or he +ro#)(

! )e$ !o /:1 Other information

Including informationon preparation and

revision of the SDS

Re'ere (e$, e (/

A425OhifiiA425Othif tii t




A4.2.5 Other information requirementsA4.2.5 Other information requirements

I a##! !o o he m! !m)m ! 'orma !oI a##! !o o he m! !m)m ! 'orma !o

re )!reme $ 7$ee A4/2/4/28, he SDS ma% a*$ore )!reme $ 7$ee A4/2/4/28, he SDS ma% a*$o(o a! a##! !o a* ! 'orma !o / here a ma er!a*(o a! a##! !o a* ! 'orma !o / here a ma er!a*ha$ a##! !o a* re*e.a a # a.a!*a *e ! 'orma !oha$ a##! !o a* re*e.a a # a.a!*a *e ! 'orma !oa o) ! $ a )re a # or )$e, ha ! 'orma !oa o) ! $ a )re a # or )$e, ha ! 'orma !o$ho)*# e ! (*)#e# ! he SDS 7$ee A4/3/:1 'or$ho)*# e ! (*)#e# ! he SDS 7$ee A4/3/:1 'or')r her a#.!(e o a##! !o a* ! 'orma !o')r her a#.!(e o a##! !o a* ! 'orma !ore )!reme $8/re )!reme $8/




UnitsUnits

N)m er$ a # )a ! !e$ $ho)*# eN)m er$ a # )a ! !e$ $ho)*# ee?+re$$e# ! ) ! $ a++ro+r!a e o he re !oe?+re$$e# ! ) ! $ a++ro+r!a e o he re !o! o 0h!(h he +ro#)( !$ e! $)++*!e#/ I! o 0h!(h he +ro#)( !$ e! $)++*!e#/ I

e era*,e era*, hehe I er a !o a* S%$ em o' U ! $I er a !o a* S%$ em o' U ! $7SI8 $ho)*# e )$e#/7SI8 $ho)*# e )$e#/




Internationally-recognisedInternationally-recognisedstandards for SDSstandards for SDS ILO Recommendation 177ILO Recommendation 177 19901990 EU SDS Directive 91/155/EECEU SDS Directive 91/155/EEC 19911991

USA Standard ANSI Z 400.1USA Standard ANSI Z 400.1 19931993ISO SDS Standard 11014-1ISO SDS Standard 11014-1 19941994

Guidance on the preparation of SDS is availableGuidance on the preparation of SDS is availableas Annex 4 toas Annex 4 to “GHS Purple book”“GHS Purple book”

GHS S"S (S*2 %< "*%* SH %)GHS S"S (S*2:%< "*%* SH::%)




GHS S"S (S*2:%< "*%* SH::%)GHS S"S (S*2:%< "*%* SH::%)2O+.*%2O+.*%

'#'# 8dentity of manufacturers> suppliers8dentity of manufacturers> suppliers?#?# Hazard (s) identificationHazard (s) identification

## 9omposition>information on ingredients9omposition>information on ingredients## 2irst aid measures2irst aid measures## 2ire fighting measures2ire fighting measures

A#A# *ccidental release measures*ccidental release measures

I#I# Handling and storageHandling and storageF#F# :5posure control>personal protection:5posure control>personal protection

## ,hysical and chemical properties,hysical and chemical properties'@#'@# Stability and reactivityStability and reactivity''#''# %o5icological information%o5icological information

'?#'?# :cological information:cological information' #' # "isposal consideration"isposal consideration' #' # %ransport information%ransport information' #' # +egulatory information+egulatory information'A#'A# Other informationOther information



A A CO CA OHAZARD COMMUNICATION

GHSGHSHazard CommunicationHazard Communication

Thank youThank you

8. ghs hazard comm labeling & sds - 1

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