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Bottle / Blow Moulding Adherend ADMER ® PP-type Grades PREFACE ADMER ® PP type grades are designed for multi-layer films, bottles or sheets composed of poly- propylene (PP) and EVOH or PA. These grades are based on PP. As a result of our advanced anhydride grafting technology, these grades create superb adhesion to EVOH and PA, while maintaining an excellent processability and a thermal stability equivalent to that of common PP. CHARACTERISTICS Homopolymer-PP based grades: QB510E: Standard grade for Bottle, Sheet and Blown Film. QB520E: Advanced grade for Bottle and Sheet. QF300E: Standard grade for Cast Film with PA. Copolymer-PP based grade QF551E: Advanced grade for Film. ADMER ® GRADE LINE-UP IN EUROPE – PP TYPE Sheet Blown Film Cast Film EVOH PA QB510E QB520E QB510E QB520E QB510E QF551E QF551E QB510E QB510E QB510E QF300E

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Bottle /Blow MouldingAdherend

ADMER® PP-type Grades

PREFACE

ADMER® PP type grades are designed for multi-layer films, bottles or sheets composed of poly-propylene (PP) and EVOH or PA.These grades are based on PP. As a result of our advanced anhydride grafting technology, thesegrades create superb adhesion to EVOH and PA, while maintaining an excellent processability anda thermal stability equivalent to that of common PP.

CHARACTERISTICS

Homopolymer-PP based grades:QB510E: Standard grade for Bottle, Sheet and Blown Film.QB520E: Advanced grade for Bottle and Sheet.QF300E: Standard grade for Cast Film with PA.

Copolymer-PP based gradeQF551E: Advanced grade for Film.

ADMER® GRADE LINE-UP IN EUROPE – PP TYPE

Sheet Blown Film Cast Film

EVOH

PA

QB510EQB520E

QB510EQB520E

QB510EQF551E

QF551E

QB510E QB510E QB510E QF300E

PHYSICAL PROPERTIES AND ADHESION PERFORMANCE

*1) T-Peel method: Speed=300mm/minExperimental conditions are followed, although the real production conditions should be optimized by customer's line.

*2) Processing Temperature: PA=250 °C, ADMER=230 °C, PP=230 °C. Die land length = 45mm. Blow up ratio=3,5.Bottle Shape = 400 ml cylindrical bottle

*3) Processing Temperature: PA=250 °C, ADMER & PP=240 °C, Die=260 °C, Die lip Distance = 0,5 mm*4) Processing Temperature: EVOH=210 °C, ADMER=200 °C, PP=220 °C. Die land length=45mm. Blow up ratio=3.5,

Bottle Shape=400 ml cylindrical bottle.*5) Processing Temperature: EVOH=210 °C, ADMER=230 °C, PP=230 °C. DIE=210 °C. Die lip distance=0,5 mm

ASTMItem Test Unit QF300E QB510E QB520E QF551E

Method

MFR (230 °C) D1238 g/10min 6.2 3.0 1.8 5.2

Density D1505 g/cm3 0.91 0.90 0.90 0.89

Tensile strength at yield D638 MPa 30 24 21 17

Tensile strength at break D638 MPa 31 29 16 17

Elongation at break D638 % >500 >500 >500 >500

Izod impact strength D256 J/m 90 380 470 No Break

Shore hardness D2240 D scale 68 65 64 59

Vicat softening point D1525 °C 146 142 140 120

Melting point D3418 °C 160 160 160 147

Adhesion Strength of Bottle *1)

PP/AD/EVOH/AD/PP *4) N/15mm

=350/50/50/50/350 µm – 34 35 40

PP/AD/PA/AD/PP *2)

=350/50/50/50/350 µm – Unpeelable Unpeelable –

Adhesive Strength of Cast Film *1) Speed

EVOH/AD/PP =40/40/160 µm *5) 5m/min N/15mm – 12 13 18

EVOH/AD/PP =20/10/40 µm *5) 20m/min – 1.2 2.5 4.5

PA/AD/PP =40/40/160 µm *3) 5m/min 11 Unpeelable Unpeelable –

PA/AD/PP =20/10/40 µm *3) 20m/min 7.5 8.5 10 –

ADMER®

PP-type Grades

1) EC: Monomers and additives are listed as authorized monomers/additives in the EUplastics directive 2002/72/EC and/or its amendment 2004/1/EC, 2004/19/EC, 2005/79/EC,2007/19/EC and 2008/39/EC. Status: 06th March 2008It is the responsibility of end-users to check by appropriate migration test on the final materialor articles the suitability for contact with different food types and various end-use conditions.

2) USA: All ADMER® grades conform to FDA 21CFR, §175.105 (Adhesives) for indirect foodcontact. Some grades are also suitable for direct food contact. Status: 1st April 2007

Please contact your sales representatives for further details.

FOOD STATUS

GRADE SELECTIONAdhesionPe

rform

ance

Low

High

1 2 3 4 5 6 7

MFR at 230 °C (g/10min)

Homo-PP based

Copolymer-PP basedQF551 E

QF300 E

QB510E

QB520E

Mitsui Chemicals Europe GmbHOststraße 10 · 40211 Duesseldorf · Germany

Telephone: (49)211-17332-0 · Facsimile: (49)211-1719960 · http://eu.mitsuichem.com

Mitsui Chemicals America, Inc.800 Westchester Avenue · Suite N607 · Rye Brook · NY 10573 · USA

Telephone: (1)914-251-4239 · Facsimile: (1)914-253-8553 · http://www.mitsuichemicals.com

Mitsui Chemicals, Inc., Automotive & Industrial Materials DivisionShiodome City Center · 1-5-2, Higashi-Shimbashi · Minato-ku · Tokyo 105-7117 · Japan

Telephone: (81)3-6253-3454 · Facsimile: (81)3-6253-4218 · http://www.mitsuichem.com

Mitsui Chemicals (Shanghai) CO., LTD.Room 2309 · Bank of China Tower 200 · Yin Cheng Road Central Pudong · New Area, Shanghai 200120 · China

Telephone: 86-21-5888-6336 · Facsimile: 86-21-5888-6337

The information and numerical results are for information only and are given in good faith. In view of numerous factors of which we areunaware and which are beyond our control regarding the use of our products, we cannot guarantee that this information covers all possibleaspects of the subject. Moreover, we cannot accept any responsibility with regard to patents for applications and processes described.

11/2008

For further details please refer to www.admer.de