advanced cleaning product formulations volume 5
DESCRIPTION
How to formulate, compound, and manufacture industrial detergents. Contains 300 formulas to review and study, along with the author's detailed notes on each oneTRANSCRIPT
ADVANCED CLEANING PRODUCT FORMULATIONS
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ADVANCED CLEANING
PRODUCT
FORM U LATIO NS Volume 4
Ernest W. Flick
NOYES PUBLICATIONS Westwood, New JOrsey, U.S.A.
Copyright 0 19% by Ernest W. Flick No part of this book may be reproduced or utilized in any form or by any means. electronic or mechanical, including photocopying. recording or by any informa- tion storage and retrieval system. without permission in writing from the Publisher.
Library of Congress Catalog C u d Number: 89-30274
Printed in the United States ISBN 0-8155-1396-8
Published in the United States of America by Noyes Publications 369 Fairview Avenue Weshvood, New Jersey 07675
10 9 8 7 6 5 4 3 2 1
Library of Congress Cataloging-in-Publication Data (Revised for vo1.4)
Flick, Ernest W. Advanced cleaning produd formulations
Includes bibliographid references and index. 1. Cleaning compounds. I. Title
TP990.F56 1989 668'1 89-30274 ISBN 0-8155-1186-8 (v. 1) ISBN 0-8155-1346-1 (v. 2) ISBN 0-8155-1382-1 (v. 3) ISBN 0-8155-1396-8 (v. 4)
To
Ernie and Jeanne
and
AIIp and Barbara
and
Chris and Rachel
V
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This book (Volume 4) presents more than 435 up-to-date advanced cleaning product formulations for household, industrial and automotive applications. It is the result of information received from numerous industrial companies and other organizations. The data represent selections made at no cost to, nor influence from, the makers or distributors of these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volumes 1, 2 and 3 published earlier.
Formulation in the cleaning product industry has gradually been undergoing significant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass along these increases. Environmental considerations have also played a part. By changing formulations to improve cost/performance characteristics, manufacturers have been able to control costs but still enhance performance. This book presents manufacturers' suggested formulations which might meet new performance criteria.
The formulations in this book are divided into the following sections and chapters, with the number of formulations indicated in ( ):
I. Household and Industrial Cleaners and Polishes 1. Bathroom Cleaners (26) 2. Dairy, Food and General Industrial Cleaners (15) 3. Degreasers (5) 4. Dishwashing Detergents (47) 5. General Purpose Cleaners (34) 6. Glass Cleaners/Polishes (25) 7. Hard Surface Cleaners (44) 8. Laundry Products (65) 9. Metal Cleaners and Polishes (22)
10. Oven, Grill and Hot Plate Cleaners (3) 11. Polishes, Coatings and Finishes (30) 12. Rinse Aids (4) 13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners (32) 14. Miscellaneous (32)
vii
Preface
viii Preface
11. Transportation Cleaners and Polishes 15. Auto Cleaners and Polishes (14) 16. Car and Truck Wash Compounds (27) 17. Whitewall Tire Cleaners (4) 18. Miscellaneous (8)
Each formula is located in the chapter which is most applicable. The reader, seeking a formula for a specific end use, should check each chapter which could possibly apply. In addition to the above, there are two other sections which will be helpful to the reader.
111. Achemical trademark section where each tradenamed raw material included in the book is listed with a chemical description and the supplier's name. The specifications which each raw material meets are included, if applicable.
IV. Main office addresses of the suppliers of trademarked raw materials.
Each formulation in the book lists the following information, as available, in the manufacturer's own words:
0
Description of end use and most outstanding properties.
The percent by weight or volume of each raw material included in the formula, rounded to a decimal figure.
Key properties of the formula, which are the features that the source considers to be more outstanding than other formulations of the same type. The formula source, which is the company or organization that supplied the formula. The secondary source may be the originating company and/or the primary source's publication title, or both. A formula number is included, if applicable.
0
The table of contents is organized in such a way as to serve as a subject index.
My fullest appreciation is expressed to the companies and organizations who supplied the original starting formulations included in this book. I also thank the suppliers of the raw materials included in these formulations, who furnished information describing their trademarked raw materials.
Newburyport, Massachusetts August 1996
Ernest W. Flick
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NOTICE
To the best of our knowledge the information in this pub- lication is accurate; however, the Publisher does not assume any responsibility or liability for the accuracy or completeness of, or consequences arising from, such information. This book is intended for informational purposes only. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by the Publisher. Final determ- ination of the suitability of any information or product for use contemplated by any user, and the manner of that use, is the sole responsibility of the user. We recommend that anyone in- tending to rely on any recommendation of materials or pro- cedures mentioned in this publication should satisfy himself as to such suitability, and that he can meet all applicable safety and health standards.
X
1 .
Contents and Subject Index
SECl'ION I HOUSEHOLD AND INDU-
CLEANERS AND POLISHES
BATHROOM CLEANERS .............................. 2 Bathtub and Faucet Cleaner ............................ 3 Bathroom Cleaner ................................... 3 Toilet Bowl Cleaner ................................. 3 Tub and Tile Cleaner ................................ 3
Thick Toilet Bowl Cleaner ............................ 4 Foamable Acid Tile Cleaner ........................... 5 Liquid Toilet Bowl Cleaner ............................ 5 Solid Automatic Toilet Bowl Cleaner Formulation . . . . . . . . . . . 6 Acid Toilet Bowl Cleaner ............................. 6 Tub. Tile and Bathroom Cleaner ........................ 6 Tile. Porcelain and Bathroom Cleaner. Acid . . . . . . . . . . . . . . . . 7 Hypochlorite Tub and Tile Cleaner and Mildew Stain
Remover ....................................... 7 Soap Scum RemoverICleaner ........................... 7 Toilet Cleaner
LiquidA ...................................... 8 Liquid B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
Clear Liquid Bowl Cleaner ............................ 4
Medium Viscosity-A ............................. 8 Medium Viscosity-B ............................. 8 Medium Viscosity-A ............................. 9 Medium Viscosity-B ............................. 9 Powder ....................................... 9 Powder-B ..................................... 9
Extruded-A ................................... 10 Extruded-B ................................... 10 Cast-A ...................................... 10 Cast-B ...................................... 10
Toilet Cleaning Block
xi
xii Contents and Subject Index
2 . DAIRY. FOOD AND GENERAL INDUSTRIAL CLEANERS . . . 11
Acid Dilutable Concentrate . . . . . . . . . . . . . . . . . . . . . . . . 12 Low Cost Acid Dilutable Concentrate . . . . . . . . . . . . . . . . 12
Dairy Milkstone Remover
Dairy Pipeline Cleaner-High Alkaline Low Foam
Institutional Stainless Steel Cleaner . . . . . . . . . . . . . . . . . . . . . 13 High Pressure Cleaner for Industrial Use . . . . . . . . . . . . . . . . . 14 Cleaner for Milking Equipment . . . . . . . . . . . . . . . . . . . . . . . . 14 Cleaner for Meat Plants . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 Meat Packaging Plant Cleaner Concentrate . . . . . . . . . . . . . . . . 15 Steam Cleaners
Light Duty . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
Hypochlorite Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Medium Duty . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16 Heavy Duty (for Oily Soils) . . . . . . . . . . . . . . . . . . . . . . . 16 General Purpose . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16 Light Duty for Soft Metals . . . . . . . . . . . . . . . . . . . . . . . . 16 Compound . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
3 . DEGREASERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 d-Limonene Microemulsion Cleanermegreaser . . . . . . . . . . . . . 18 Concentrated d-Limonene Biodegradable Degreaser . . . . . . . . . 18 Solvent Degreasing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
4 . DISHWASHING DETERGENTS . . . . . . . . . . . . . . . . . . . . . . . . . 20 Clear Liquid Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 Non-Chlorinated Machine Dishwashing Compound. Liquid . . . . 21 Clear. Colorless Manual Dish Wash . . . . . . . . . . . . . . . . . . . . . 21
Powder for Automatic Dishwashing Machines . . . . . . . . . . . . . . 23 Dishwashing Detergent
Medium Viscosity
Dish Washing Agent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Basis Marlon A-A . . . . . . . . . . . . . . . . . . . . . . . . . . . 24 Basis Marlon A-B . . . . . . . . . . . . . . . . . . . . . . . . . . . 24 Basis Marlon AS3-A . . . . . . . . . . . . . . . . . . . . . . . . . 24 Basis Marlon AS3-B . . . . . . . . . . . . . . . . . . . . . . . . . 24 Basis Marlon PS-A . . . . . . . . . . . . . . . . . . . . . . . . . . 25 Basis Marlon PS-B . . . . . . . . . . . . . . . . . . . . . . . . . . 25 Basis Marlon Compounds-A ..................... 25 Basis Marlon Compounds-B . . . . . . . . . . . . . . . . . . . . 25
Powdered Spray Mixing Process-A . . . . . . . . . . . . . . . . . . . . . . 26 Spray Mixing Process B . . . . . . . . . . . . . . . . . . . . . . . 26 Phosphate-Free. Spray Mixing. Process A . . . . . . . . . . 26
Contents and Subject Index xiii
Phosphate.Free. Spray Mixing. Process B . . . . . . . . . . 26 40% Solids-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27 40% Solids-B .............................. 27
Hand Dishwashing Liquid ............................ 27 Dish Wash w/Amine Oxide/LABS/SLES . . . . . . . . . . . . . . . . . 28 Dish Wash w/Amine Oxide/LABS/ALES . . . . . . . . . . . . . . . . . 28 Dish Wash w/Amine Oxide/LABS ...................... 28 High-Performance Hand Dish Detergent . . . . . . . . . . . . . . . . . 29 Mild Liquid Hand Dish Detergent ...................... 29 Starting Formulations for Home Machine Dishwashing
Detergents 8.7% Phosphorous(A) ............................ 30 8.7% Phosphorous(l3) ............................ 30 Nonphosphate ................................. 30
Pilot Formula #LDL-010-01 ...................... 31 Pilot Formula #LDL-013-01 ...................... 31 Pilot Formula #LDL-005-01 ...................... 31 Pilot Formula #LDL-O15-01 ...................... 31 Premium Hand Dishwash ......................... 32 Economy Hand Dishwash ......................... 32
Liquid Hand Dish Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . 33 Mechanical Dishwashing Detergent. Chlorinated . . . . . . . . . . . . 34 Mechanical Dishwashing Detergent. Liquid . . . . . . . . . . . . . . . 34 Non-DDBSA Dishwashing Liquid ...................... 35 Starting Formulations for Commercial Machine
Light Duty Liquid Detergents
Dishwashing Detergents Nonchlorine/Noncaustic .......................... 36 Noncaustic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 ChlorineKaustic ................................ 36
5 . GENERAL PURPOSE CLEANERS ....................... 37
Phosphate Free All Purpose Cleaner ..................... 38 Bathroom Tile Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38 All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 Hard-surface Cleaner ............................... 39 All-Purpose Cleaner
Cleaner-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40 Cleaner-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40 With Microbicidal Properties. Liquid-B . . . . . . . . . . . . . . . 40
All Purpose Cleaner ................................ 38
Liquid-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41 Liquid-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41 With Microbicidal Properties. Liquid-A . . . . . . . . . . . . . . . 41
xiv Contents and Subject Index
Pasty-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42
With Soap. High Viscosity-A . . . . . . . . . . . . . . . . . . . . . . 42 With Soap. High Viscosity-B
Pasty-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42
. . . . . . . . . . . . . . . . . . . . . . 42 D-Limonene Emulsifiable Concentrate . . . . . . . . . . . . . . . . . . . 43 D-Limonene All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . 43 General Cleaners
Household . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44 Alkaline Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44 Liquid Hand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44 Germicidal Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44
High-Performance General Purpose Cleaner Concentrate . . . . . . 45 Heavy-Duty Cleaner Powder . . . . . . . . . . . . . . . . . . . . . . . . . . 45 Neutral All-Purpose Cleaner. with Pearlescence Effect
High Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46 High Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46
With Acetic Acid-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46 With Acetic Acid-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 46
Non-Phosphate All Purpose Cleaner .................... 47 Oil Splitting General Purpose Cleaner . . . . . . . . . . . . . . . . . . . 47 Scouring Cleaner
Medium Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 Medium Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 Powder-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 Powder-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48
All-Purpose Cleaner
6 . GLASS CLEANERSD’OLISHES . . . . . . . . . . . . . . . . . . . . . . . . . 49
For Application to Cloth . . . . . . . . . . . . . . . . . . . . . . . . . . 50 For Direct Application to Glass . . . . . . . . . . . . . . . . . . . . . 51
Anti-Fogging. Anti-Static Glass Cleaner . . . . . . . . . . . . . . . . . 52 Ammoniated Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 52 Glass Cleaners
Ammonia . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 Vinegar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53
Antifog Composition
Glassware and Bottle Cleaners Bottle Cleaner
Alkaline-Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54 Acid-Powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54 Acid-Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54 Highly Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54
Household Window Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 55 Premium Household Window Cleaner . . . . . . . . . . . . . . . . . . . 55
Contents and Subject Index xv
Low VOC Antistat/Cleaner for Glass .................... 56 Anti-Fog Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56 Glass Cleaner ..................................... 56 Traditional Consumer Glass Cleaner .................... 57 Consumer Acid Glass Cleaner ......................... 57
7 . HARD SURFACE CLEANERS .......................... 58 Abrasive Cleaner-1 ................................ 59 Abrasive Cleaner-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 Abrasive Cleaner-3 ................................ 59 Concentrated Liquid Household Hard-surface Cleaner . . . . . . . 60 All-Purpose Household Spray Cleaner . . . . . . . . . . . . . . . . . . . 60 Consumer Tile Cleaner .............................. 61 Industrial Strength Chlorine Cleaner ..................... 61 D-Limonene Hard-surface Cleaners .................... 62 d'limonene Spray Cleaner ............................ 63 d'limonene Cleaner Concentrate ....................... 63 General Purpose Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . 64 Alkaline Hard Surface Cleaner ........................ 64 General Purpose Hard-surface Cleaners . . . . . . . . . . . . . . . . . . 65 Unbuilt. High-Sudsing. Hard-surface Cleaner . . . . . . . . . . . . . 65 Hard Surface Cleaner ............................... 66 Non-Abrasive Cleanser .............................. 66 Hard Surface Cleaner ............................... 66 Floor Cleaner Products .............................. 68 Rug Cleaner ...................................... 68 Plastic. Vinyl and Leather Cleaner ...................... 68 Hard Surface Cleaners .............................. 69 Tub and Tile Cleaners ............................... 69 Counter Top/Wall Cleaners
AlIPurposeType ............................... 69 Ammoniated Type .............................. 69
Hard Surface Cleaner w/Amphoteric .................... 70 Hard Surface Cleaner Concentrate
w/d'Limonene ................................. 70 Alkaline All-Purpose Cleaner Concentrate . . . . . . . . . . . . . 71 All-Purpose Alkaline Cleaner for Sponge or Spray
Application ................................. 71 High-Performance. Hard Surface Cleaners . . . . . . . . . . . . . . . . 72 Economical Pine Oil Hard-surface Cleaner . . . . . . . . . . . . . . . 72 Mild Abrasive Hard Surface Cleaner .................... 73 Non-Phosphate Household Hard-surface Cleaner . . . . . . . . . . . 74 Non-Phosphate Concentrated Household Hard-surface
Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74
xvi Contents and Subject Index
Pine Oil Cleaner Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . 75 Liquid Super Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75
8 . LAUNDRY PRODUCTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76 Anionic/Nonionic Heavy-Duty Laundry Detergent . . . . . . . . . . 77 Nonionic/Amphoteric Heavy-Duty Laundry Liquid . . . . . . . . . . 78 Cold Water Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79 Fine Fabric Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79
Process-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80 P~OUXS-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80
Medium Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81 Medium Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81
Medium Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81 Medium Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81
Detergent for Fine Fabrics-1 . . . . . . . . . . . . . . . . . . . . . . . . . . 82 Detergent for Fine Fabrics-2 . . . . . . . . . . . . . . . . . . . . . . . . . . 82 Enzymatic Heavy-Duty Laundry Detergent Non-Phosphate Laundry Powder . . . . . . . . . . . . . . . . . . . . . . . 83 Fabric Pretreatment Spritz . . . . . . . . . . . . . . . . . . . . . . . . . . . . 84 Low VOC Pump Fabric Antistatic Spray Laundry Pre-Spotter and Stain Remover
Detergent for Colored Fabrics. Powder. Spray Mixing
Detergent for Curtains
Manual-Wash Detergent. Foaming
. . . . . . . . . . . . . . . 83
. . . . . . . . . . . . . . . . . 84
. . . . . . . . . . . . . . . . . 84
Process-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 Pr0~ess-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 Process-3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85 Low Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86 Low Viscosity-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86 Concentrate. Low Viscosity-A . . . . . . . . . . . . . . . . . . . . . 86 Concentrate. Low Viscosity-B . . . . . . . . . . . . . . . . . . . . . 86
Spray Mixing Process-A . . . . . . . . . . . . . . . . . . . . . . . . . . 87 Spray Mixing Process-B . . . . . . . . . . . . . . . . . . . . . . . . . . 87 Spray Mixing Process-A . . . . . . . . . . . . . . . . . . . . . . . . . . 88 Spray Mixing Process-B . . . . . . . . . . . . . . . . . . . . . . . . . . 88
Viscosity-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88
Fabric Softener
Heavy-Duty Detergent. Powder
Liquid Heavy-Duty Detergent. Built Type. High
Heavy Duty Liquid Laundry Detergent-Type DN . . . . . . . . . . 89 Built Formulation #1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89 Heavy Duty Liquid Laundry Detergent-Type TA . . . . . . . . . . 90
Heavy Duty Liquid Laundry Detergent-Type WA . . . . . . . . . . 91 Liquid Laundry Detergents . . . . . . . . . . . . . . . . . . . . . . . . . . . 90
Contents and Subject Index xvii
Built Formulation #2 ................................ 91 Liquid Heavy-Duty Detergent
Low Viscosity-A ............................... 92 Low Viscosity-B ............................... 92 Built Type. High Viscosity-B ...................... 92
Light-Duty Detergent. Powder Spray Mixing Process-A .......................... 93 Spray M i n g Process-B .......................... 93
With Incorporated Softener. Low Viscosity-A . . . . . . . . . . 93 Low VisCosity-A ............................... 94 Low Viscosity-B ............................... 94 With Incorporated Softener. Low Viscosity-B .......... 94
Industrial Laundry Two-Part Systems. Uniforms (Petroleum Greases and Oils) ........................ 95
HoteVLinen Supply (Animal and Vegetable Grease) . . . . . . . . . 95 Industrial Laundry Powder. Uniforms .................... 95 Laundry Liquids ................................... 96 "Fine Care" Fabric Detergents
Pilot Formula #LDY-OO3-01 ...................... % Pilot Formula #LDL-003-01 ...................... 96
Pilot Formula #HDL-004-01 ...................... % Pilot Formula #HDL-005-01 ...................... %
Laundry Powder Detergent ........................... 97 Industrial Laundry One-Shot Liquid .................... 97 Liquid Heavy Duty Detergent HDLD .................... 98 Liquid Detergent "FSL" A ............................ 98
Thick Bleach-2 ................................... 99 Wool Detergent
Medium Viscosity-A ........................... 100 Medium Viscosity-B ........................... 100
Liquid Light-Duty Detergent
Heavy Duty Laundry Liquids
Thick Bleach-1 ................................... 99
9 . METAL CLEANERS AND POLISHES . . . . . . . . . . . . . . . . . . . 101 Aluminum CleanerDrightener ........................ 102 Aluminum Smut Cleaner ............................ 102 Aluminum Cleaner Concentrate ....................... 103 Aluminum Wash ................................. 103 Cleaners and Cleaning Solutions ...................... 104 Metal Cleaning
Alkaline .................................... 104 Acid ....................................... 104 Paint Removal ................................ 104
xviii Contents and Subject Index
Rust Removal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104 Copper Cleaning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105
Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105 Brightening . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105
Aluminum Aircraft-Brightener (U.S. Patent 2.687. 346) . . . . . . 105 Electrocleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 106 Moderate Alkalinity. Soil Splitting Soak Cleaner . . . . . . . . . . . 106 High-Foaming Acid Scrubber ........................ 107 Acid Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107 Metal Cleaner and Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . Thickened Clear Degreaser Concentrate . . . . . . . . . . . . . . . . . 108
Cleaner-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109 Cleaner-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109
Liquid-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109 Liquid-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109
Aluminum Cleaning
108
Stainless Steel
Silver Polish
10 . OVEN. GRILL AND HOT PLATE CLEANERS . . . . . . . . . . . . 110 Pump Spray Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 111 Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111 Oven/Grill Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111
11 . POLISHES. COATINGS AND FINISHES . . . . . . . . . . . . . . . . . 112 Aerosol Furniture Polish (Carbon Dioxide Propellant) . . . . . . . 113 General Purpose Liquid Polish (Oil-in-Water Type) . . . . . . . . 113 Aerosol Furniture Polish (Hydrocarbon Propellant) . . . . . . . . . 114 Furniture Paste Wax . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114 Detergent Resistant. Cream Cleaner Polish . . . . . . . . . . . . . . . 115 Non-Abrasive. Detergent Resistant. Glaze Emulsion . . . . . . . . 115 High Gloss. Detergent Resistant. Soft Paste Polish . . . . . . . . . 116 Detergent Resistant Cream Polish ..................... 116
For Clear Coat Finishes . . . . . . . . . . . . . . . . . . . . . . . . . 117 No Solvent . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117 Outer Phase Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 118
Non-Wax Liquid Polish (Oil-in-Water Type) . . . . . . . . . . . . 118 Liquid Furniture Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119 20% Wax Emulsion-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119 20% Was Emulsion-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119 Liquid Water-Based Glaze . . . . . . . . . . . . . . . . . . . . . . . . . . 120 Solvent Wax Glaze . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120 Paste Polish (Oil-in-Water Type) ..................... 121
Liquid Polish
Contents and Subject Index xir
Spray-and-Wipe Polish ............................ 121 Paste Polish
Oil-in-Water Type Type-1 .................................. 122 Type-2 .................................. 122 Type-3 .................................. 123
Outer Phase Oil ............................... 123 Spray-and-Wipe Polish (Pump) ...................... 124 20% Wax Emulsion-1 ............................. 124 20% Wax Emulsion-2 ............................. 124 Spray and Wipe Type
Aerosol or Non-Aerosol (1) ...................... 125
Aerosol or Non-Aerosol (3) ...................... 125 Aerosol or Non-Aerosol (2) ...................... 125
Liquid Wax-Solvent Furniture or Floor Polish . . . . . . . . . . . . 125
12 . RINSE AIDS ....................................... 126
For Hard Water ............................... 127 For Neutral or Soft Water ........................ 127
Rinse Aid ...................................... 128
Automatic Dishwash Rinse Aid
13 . RUG. FJ.DOR, CARPET. UPHOLSTERY SHAMPOOS ANDCLEANERS ................................... 129
Liquid-A .................................... 130 Liquid-B .................................... 130
Liquid-A .................................... 130 Liquid-B .................................... 130
Dry-Foam Cleaner
Basic Floor Cleaner
Floor Cleaner. for Everyday Use
Carpet and Upholstery Cleaners
Liquid-A ................................ 131 Liquid-B ................................. 131 Powder-A ................................ 131 Powder-B ................................. 131
Carpet Shampoo. High Foam ......................... 132 Evaporative (No Rinse) Wax Stripper . . . . . . . . . . . . . . . . . . . 133 Waxed Floor Cleaner .............................. 133 Floor Cleaner .................................... 134 Floor Polish
Mor-Glo 2-457 20% Solids ...................... 135 ML-870-389 20% Solids ........................ 136
Liquid Carpet Cleaner .............................. 137
XT Contents and Subject Index
Carpet Stain Remover-Liquid . . . . . . . . . . . . . . . . . . . . . . . . 137 Carpet Cleaner/Booster.Dry. Destainer . . . . . . . . . . . . . . . . . 137 Low Cost Extraction Carpet Cleaner . . . . . . . . . . . . . . . . . . . 138
Non-Ammoniated Floor Stripper . . . . . . . . . . . . . . . . . . . . . . 139 Quarry Tile Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 140 Low Foam Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 140 Special-Purpose Floor Cleaner
Liquid-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141
Liquid-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141
Medium Cost Steam Extraction Carpet Cleaner . . . . . . . . . . . . 138 Premium. Heavy Duty Steam Extraction Carpet Cleaner . . . . . 138
Liquid-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141 Wash-and-Wax Floor Cleaner
Liquid-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 141
14 . MISCELLANEOUS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 142 Condensate T L Typical Formulations . . . . . . . . . . . . . . . . . . 143 All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143
Dilutable Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143
Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143 Opacified Hand Soap . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143 d'lmonene Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . 144 Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144 Dry Cleaning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145 Dust Control . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 146 Hand and Body Cleanser . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147 Heavy Duty Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 148 Burnishing Compound . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 148
Bubble Bath . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143
Viscous Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143
Corrosion Inhibiting Coating Oil-Emulsifiable . . . . . . . . . . . . 148 Heavy Duty Industrial Spray Metal Cleaner Concentrate . . . . . 149 Low Foam Hypochlorite Cleaner . . . . . . . . . . . . . . . . . . . . . . 149 Metal CleanerBrightener . . . . . . . . . . . . . . . . . . . . . . . . . . . 149
Low Foam Heavy Duty Alkaline Cleaner-A . . . . . . . . . . . . . . 150 Low Foam Heavy Duty Alkaline Cleaner-B . . . . . . . . . . . . . . 150 Paint Brush Cleaners . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 151 Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 152 Heavy Duty Industrial Spray Cleaner Concentrate . . . . . . . . . . 152
Hot Tank Stripper/Cleaner/Derster . . . . . . . . . . . . . . . . . . . . 150
High Solids Alkaline Cleaner . . . . . . . . . . . . . . . . . . . . . . . . 152 Wallpaper Removal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153
Contents and Subject Index m-
SECTION II TRANSPORTATION CLEANERS AND POLISHES
15 . AUTO CLEANERS AND POLISHES .................... 155 Auto Polishlcleanser. Oil in Water Emulsion . . . . . . . . . . . . . 156 Detergent Resistant Auto PolishlCleanser. Paste Wax . . . . . . . 156 Camauba Hotwax ................................. 157 Pressure Spray Truckwash ........................... 157 Detergent Resistant Auto Polish. Oil in Water Emulsion . . . . . 158 High Luster Auto Finish. Paste Wax . . . . . . . . . . . . . . . . . . . 158 High Gloss. Detergent Resistant Polish . . . . . . . . . . . . . . . . . . 159 High Gloss Auto PolishPinish ........................ 159
Spraywax ....................................... 160 Spraywax Ladder of Formulas ........................ 161
Spraywax Concentrate .............................. 160
16 . CAR AND TRUCK WASH COMPOUNDS . . . . . . . . . . . . . . . . 162 Automatic Car Wash Concentrate ..................... 163 General Purpose Car Wash .......................... 163 Auto Shampoo Concentrate .......................... 164 High Foaming Car Wash ............................ 164 Car Wash ....................................... 164 Car Wash Liquid ................................. 165 Car Wash Powder ................................. 165 Economy Truck Wash .............................. 166 Truck Wash Liquid ................................ 166 Foamy Brush Car Wash. Liquid ....................... 167 1:2 Dilutable Car Wash ............................. 167 High Oil Splitting Vehicle
Wash-A .................................... 168 Wash-B .................................... 168
Liquid Car Wash ................................. 169 Spray-On Car Wash Concentrate ...................... 169 Liquid Hi@ Pressure Coocentrate ..................... 170 Tmck Wash w/varamide A-83 ....................... 170 Liquid Tmck Wash ................................ 171 Mild Car Shampoo ................................ 172 Cgrspray CW Concentrate ........................... 172 Automotive "Wash t Wax" ......................... 172 Premium Carspray 500 Concentrate .................... 173 Standard Carspray 500 Concentrate .................... 173 Premium Carspray 700 Concentrate .................... 174 Standard Carspray 700 Concentrate .................... 174
xxii Contents and Subject Index
17 . WHITEWALL TIRE CLEANERS ....................... 175 White Wall Tire Cleaner ............................ 176 Bug Remover Concentrate ........................... 176 Whitewall Tire Cleaner Concentrate .................... 177 Whitewall Tire Cleaner Liquid ....................... 177
18 . MISCELLANEOUS .................................. 178 Automobile Windshield Cleaners ...................... 179 General Purpose Liquid Boat Polish-(l) . . . . . . . . . . . . . . . . . 180 General Purpose Liquid Boat Polish-(2) . . . . . . . . . . . . . . . . . 180 Liquid Aluminum Engine Block Cleaner . . . . . . . . . . . . . . . . 181 Foaming Engine Cleaner ............................ 181
SECTION Ilk TRADE-D RAW MATERIAIS . . . . . . . . . . . 182
SECTION N: SUPPLIERS' ADDRESSES .................... 197
Section I Household and Industrial
Cleaners and Polishes
1
1 Bathroom Cleaners
2
Bathroom Cleaners 3
Bathtub and Faucet Cleaner
I n g r e d i e n t : Percent by We1 q h t
Ammoni um hydrox ide s o l u t i o n 28% 3.2 Ce l l oso l ve so l ven t 5.0 Nonionic s u r f a c t a n t (Neodol 25-9) 6 .0 Water 65.8
L i q u i d C i t r i c Acid-50% (Haarman & Reimer Corp.) 20.0
Fragrance, dye q . s .
Mix t h e L i q u i d C i t r i c Acid-50% w i t h an equal volume o f water. S lowly add t h e ammonium hydrox ide s o l u t i o n . The n e u t r a l i z a t i o n should be done c a u t i o u s l y and under a g i t a t i o n , as t h e r e a c t i o n i s exothermic. Add Ce l l oso l ve , s u r f a c t a n t , remaining water, f ragrance and dye. The formula i s s u i t a b l e f o r a pump spray. Bathtub, s inks , f auce ts and o the r hard sur faces should be sprayed from a d i s tance o f about 10 inches. For maximum e f f e c t - iveness, t h e depos i ted c leaner f l u i d should be e f t a t work f o r a t l e a s t f i v e minutes and then r i n s e d o f f w t h water o r removed w i t h a wet c l o t h o r sponge.
SOURCE: Haarman 81 Reimer Corp.: Suggested Formu
__ Bathroom _ _ _ - ~ Cleaner
Water Sodium C i t r a t e Glucopon 425 CS Propylene Glyco l nButy1 Ether
T o i l e t B o w l Cleaner
Water Phosphoric Ac id Glucopon 425 CS
Tub 8 7 1 l e Cleaner
a t i o n
Water Sodium C i t r a t e STPP Standapol ES-2 Velvetex A0-45 Standamid KD I sop ropy l Alcohol
SOURCE: Henkel Corp., CD D i v i s i o n : S t a r t i n g Formulat ions
\"rtb 79 9 9 3
W t % 79 15 6
W t % 75
4 1
12 4 1 3
4 Advonced Cleoning Roduct Formulotions
Clear Liquid Bowl Cleaner Formula BC-0001
Mi rano l FBS Hydroch lo r ic Ac id (20Be) Water
Wt.% 3.0
20.0 77.0
Procedure
Add t h e Mi rano l FBS. Mix u n t i l un i fo rm.
Phvsi -1 P rooer t i es
Add t h e water. Slowly add t h e hyd roch lo r i c ac id , w i t h mix ing .
Appearance: C lear , l i g h t ye l l ow V i s c o s i t y : <10 cps S p e c i f i c Grav i t y : 1 -03 pH (as i s ) : <1.0
Thick T o i l e t Bowl Cleaner Formula BC-0002
Wt.% M i r a t a i ne TM 5.0 Hydroch lo r ic Ac id (20Be) Water
32.0 Q.S
Prowdu r g
add t h e M i r a t a i n e TM and mix u n t i l un i fo rm.
Phvsi G a l Prooert i es
Add t h e hyd roch lo r i c a c i d t o t h e water, w i t h s t i r r i n g . Slow
Appearance: C1 ear, ye1 1 ow 1 i qui d V i scosi t y : 1.035 cps Speci f i c Gravi t y : 1 ,037 pH (as i s ) : <1.0
Y
SOURCE: Rhone-Poulenc Sur fac tan ts & S p e c i a l t i e s : Formulas
Bathroom Cleaners 5
Foarnable A c i d T i l e Cleaner Hard Foaming Hard Surface Cleaner f o r Soap Scum Removal
I na red i e n t : Dei on i zed Water C i t r i c Ac id (50%) Mazon 98
Wt.% 87.00 10.00 3.00
pH (as i s ) : 2 .0 -2 .5 Appearance: C lear , water-whi te l i q u i d S p e c i f i c G r a v i t y : 1 . 0 1
Procedure:
above. Mix u n t i l c l e a r .
Notes : Th is fo rmula produces a copious, dense foam. It i s s u i t a b l e
f o r c lean ing soap scum from shower s t a l l t i l e s and o the r bath- room and household f i x t u r e s .
To a m ix ing vesse l , charge t h e i n g r e d i e n t s i n t h e order l i s t e d
Formula CH-105
L i a u i d T o i l e t Bowl Cleaner A L i q u i d S t a i n and Rust Remover
I n s r e d i e n t : Deionized Water Phosphoric Ac id (75%) Avanel S-70
pH (as i s ) : t1.5 Appearance: C lear , water -wh i te l i q u i d S p e c i f i c G r a v i t y : 1 .124
Wt.% 66.00 30.00
4 . 0 0
Procedure:
phosphor ic a c i d under a g i t a t i o n . Use c a u t i o n du r ing a c i d add- i t i o n t o avo id s p a t t e r i n g . When a l l o f t h e a c i d i s d isso lved, coo l t o room temperature and add t h e Avanel s u r f a c t a n t .
Notes:
i c u l a r l y e f f e c t i v e i n t h e removal o f sca le bu i l d -up and r u s t s t a i n s .
Th is m a t e r i a l may be marketed i n an approp r ia te squeeze b o t t l e t o f a c i l i t a t e "under t h e r i m " bowl c lean ing by t h e consumer.
Formula CT-101
SOURCE: Mazer Chemicals: Suggested Formulat ions
Charge t h e water t o t h e mix ing vesse l , and s low ly charge t h e
Th is fo rmu la t i on i s designed t o be used "as i s " and i s p a r t -
S o l i d Automat ic T o i l e t Bowl Cleaner Formula t ion
I n g r e d i e n t : Macol DNP 150 Incromide L90 Carbowax PEG 8000 Macol 27 Versa f lex 207 ( d r y ) Water
%- 25.0 25.0 20.0 20.0 5.0 5.0
Procedure: 1 . Me l t t h e Macol 27, Macol DNP 150, and Carbowax PEG 8000, and
2. Main ta in a temperature o f about 70C, and add t h e Incromide
3. Add water and Versa f lex 207 ( d r y ) and mix. 4 . Pour fo rmu la t i on i n t o a mold, and a l l o w t o coo l . SOURCE: Na t iona l S tarch and Chemical Co.: Reference #8069:49
mix toge the r .
L90 w h i l e mix ing .
__ A c i d T o i l e t Bowl Cleaner
Water, D . I . Hyd roch lo r i c Ac id (37%) Rewoteric AM TEG
% bv Weiaht 71 . O 27.0 2.0
B1 endi ng Procedure: Add i n g r e d i e n t s i n o rder shown and d i s s o l v e comple te ly between
each addi t i on. Typ ica l P roper t i es :
V i s c o s i t y , cps: 135 So l i ds : 1.0% pH: 2.8
SOURCE: Witco Corp.: Formula 532
Tub, T i l e and Bathroom Cleaner
Water Sodium Carbonate Tetrasodium EDTA (40%) Phosphoter ic T-C6 Nonoxynol 10
Procedure:
% bv Wei ah t 81.5 5.0 10.0 1.5 2.0
Add i n g r e d i e n t s i n o rder l i s t e d , a l l o w i n g s u f f i c i e n t t ime between a d d i t i o n s .
Th is product may be app l i ed w i t h a t r i g g e r pump o r by aeroso l . Formulat ion P roper t i es :
Phys ica l Appearance: Clear l i q u i d Cloud Po in t : 42C
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulat ion
6 Advanced Cleaning Roabct Formulations
Bathroom Cleaners 7
T i l e , Porcelain and Bathroom Cleaner, Acid
Water. D . 1 % by Weiqht
75.5 Rhodopol 23 0.5 Petro BAF Powder 2.0 Phosphori c Acid, 75% 12.0 Hydroxyacetic Acid, 70% 10.0 Perfume, Dye q . s . B1 endi ng Procedure :
t o mix u n t i l mater ia l th ickens. Add remaining ingredients i n order l i s t e d . If problems develop adding Rhodopol t o water, premix the Rhodopol 23 i n some isopropanol before adding t o water. Formula 529
Add Rhodopol 23 slowly t o water w i t h high speed mixing. Allow
Hypochlor i te Tub and T i l e Cleaner and Mildew S ta in Remover
% by Weiqht Water, D.I. 44.9 Sodium Hydroxide (30%) 1 . o Varox 365 1.5 Sodium Hypochlor i te (5.7%) 52.6 81 endi ng Procedure :
between each addi t i on. Typical Propert ies:
V iscos i ty , cps: 4 Sol ids: 3.8% pH: 13.5
Formula 531
Add ingredients i n order shown and d isso lve completely
Soap Scum Remover/Cleaner
% by Weiaht Water, D.I. q . s . *Bui lder Solut ion 0.20 Tetrasodi um EDTA 0.25 Rewoteric AM V 1 .oo Dowanol EB 0.50 81 ending Procedure:
Blend ingredients i n the order shown, mixing thoroughly between each add i t i on . Typical Proper t i es :
Viscos i ty , cps: 4 Sol ids: 2.0% pH: 11-12
Comments: *Bui lder Solut ion: Sodium Carbonate (Na2C03): 4%
Potassi um Hydroxide (KOH) : 3% DI Water 93%
Formula 544
SOURCE: Witco Corp.: Suggested Formulations
8 Advanced Cleaning Roabct Formulations
T o i l e t Cleaner. L iquid-A
Marl i pa l 01 3/99 Ace t i c ac id* Balance water, f ragrance, dyes tu f f
A c t i v e mat te r : 2.7%
Toi 1 e t Cleaner . L i qui d-B
Marl i pa l 01 3/99 C i t r i c a c i d Balance water, f ragrance, d y e s t u f f
A c t i v e mat te r : 4.5%
To i 1 e t C1 eaner , Medi urn V i scosi t y - A
Mar laz in OL 2 M a r l i p a l 013/99 C i t r i c a c i d Na Cumene sulphonate 40 (approx.) Balance water, f ragrance, d y e s t u f f
A c t i v e mat te r : 2.0%
T o i l e t Cleaner, Medi urn V i scosi tv -B
Mar laz in OL2 Marl i p a l 01 3/99 C i t r i c a c i d Phosphoric ac id , 85% KNA cumene sulphonate 40 (approx.) Balance waser, f ragrance, d y e s t u f f
A c t i v e mat te r : 2.0 * f u r t h e r p roduc ts o f Huls AG
96 3.0 6.0
t o 100
% 5.0 1 .7
t o 100
% 1.5 0 . 5 5.0 1.5
t o 100
% 1.5 0 .5 2.5 7.5 1.3
t o 100
SOURCE: Huls America, I n c . : Baslc Formulat ions o f Detergents and Cleaning Agents f o r Household Purposes
Bathroom Cleaners 9
Toi 1 e t Cleaners, Medi urn V i scosi t y - A
Marlazin 7102 Phosphoric acid, 85% Sodium c h l o r i d e Balance water, fragrance, dyes tu f f
Act ive matter: 4.0%
Toi 1 e t C l eaner . Medi urn V i scosi ty-B
Marlazin OL 2 Mar l i pa l 013/99 Acet ic Acid* KNA cumene sulphonate 40 (approx.) Balance water, fragrance, dyestuf f
Act ive matter: 3.5%
Toi 1 e t Cleaner. Powder
Marlon ARL Amidosulphonic a c i d Magnesium carbonate Sodi um b i sulphate Sodium bicarbonate, fragrance, dyes tu f f
Act ive matter: 4.0%
T o i l e t Cleaner. Powder-B
Marlon A 390 C i t r i c ac id Sodi um sulphate Sodium bicarbonate, fragrance, dyestuf f
Ac t i ve matter: 4.5%
96 4.0 5.0 3.5
t o 100
% 3 . 0 0 .5 6.0 3.1
t o 100
96 5 . 0
20.0 5 . 0
6 0 . 0 t o 100
% 5.0
25.0 55.0
t o 100
SOURCE: Huls America, I nc . : Basic Formulations o f Detergents and Cleaning Agents for Household Purposes
10 Advanced Cleaning Roduct Formulations
T o i l e t Cleaning Block, Extruded-A
Marlon ARL Mar l i pa l 1618/25 powder Marlamid M1618 Vest ino l C* Sodium sulphate, dyes tu f f
Act ive matter: 42.0%
T o i l e t Cleaning Block. Extruded-B
Marlon ARL Marlon A390 Lipoxol 6000* Sodi um tr ipolyphosphate Fragrance Sodium sulphate, dyes tu f f
Act ive matter: 59.0%
T o i l e t Cleanino Block. Cast-A
Marl i n a t 242/70 Marlon A375 Mar l i pa l 1618/25 powder Mar l i pa l 1618/40 Marlamid M 1618 L i poxol 12000* Fragrance Dyestuf f
Act ive matter: 80.8%
T o i l e t Cleaning Block. Cast-B
Marl i pal 01 3/90 Mar l i pa l 1618/40 Mar l i pa l M 1618 L i poxol 12000* Fragrance Dyestuf f
Act ive matter: 79.0% * f u r t h e r products o f Huls Ag
96 40.0
4.0 6.0 4.0
t o 100
ss 40.0 30.0 8.0 1 .o 5.0
t o 100
% 3.0
13.0 30.0 24.0 15.0 10.0 4.0 1 .o
96 12.0 60.0 10.0 13.0 4.0 1 .o
SOURCE: Huls Chemical Co.: Basic Formulations o f Detergents and Cleaning Agents f o r Household Products
2. Dairy, Food and General Industrial Cleaners
11
12 Advanced Cleaning Roduct Formulations
An
Inaredi ent : Deionized Water G lyco l i c Acid (70%) Phosphoric Acid (85%) Avanel S-150
Dai ry Mi 1 kstone Remover Acid D i l u t a b l e Concentrate
Wt.% 53.40 28.60 10.00 8 . 0 0
pH (as i s ) : ~ 2 . 0 Appearance: Clear, water-white t o l i g h t - y e l l o w l i q u i d
Procedure: Charge water t o the mixing vessel and s t a r t ag i ta t i on . Under
a g i t a t i o n , charge the G lyco l i c Acid fo l lowed by the Phosphoric Acid. Charge the Phosphoric Acid s lowly t o avoid s p l a t t e r i n g . Charge t h e Avanel S-150 and cool t o room temperature. F i l l o f f .
Notes :
m i 1 kstone from dai r y equipment . Brush thoroughly, then r i nse . Formula CD-101
This formulat ion i s h igh l y e f f e c t i v e a t removing d a i r y
Use concentrat ion i s 1 /2 t o 1 ounce per ga l l on o f water.
Dairy M i 1 kstone Remover Low Cost Acid D i l u t a b l e Concentrate
Inaredi ent : Dei oni zed Water Phosphoric Acid (85%) Gluconic Acid (50%) Avanel 5-70
pH (as i s ) : < 2 . 0 Appearance: Clear, water-white l i q u i d
Wt.% 55.00 37.50
3 . 5 0 4 . 0 0
Procedure: To mixing vessel, charge the water and s t a r t a g i t a t i o n .
Slowly charge the Phosphoric Acid t o avoid s p l a t t e r i n g . Cool t o room temperature and charge the Gluconic Acid and Avanel S-70.
Notes: A lower cost s u b s t i t u t e f o r PPG/Mazers CD-101 d a i r y cleaner
formulat ion. I t r e t a i n s the general performance a t t r i b u t e s o f t he o r i g i n a l formulat ion.
Use concentrat ion i s 1/2 t o 1 ounce per ga l l on o f water. Brush thoroughly, then r i nse . Formula CD-102
SOURCE: Mazer Chemicals: Suggested Formulations
&ky, Food and General I . . Cleaners 13
D a i r y P i p e l i n e Cleaner H i g h A1 k a l i ne Low Foam Hvpoch lor i t e Cleaner
I n n r e d i en t : Deionized Water Sodium Hydroxide (50%) Avanel S-74 Sodium Cumene Su l fonate (40%) Sodium Hypoch lo r i t e (12.5%)
pH (as i s ) : 12.5-13.5 Appearance: C lea r , 1 igh t -ye1 low 1 i q u i d Speci f i c G r a v i t y : 1 . 1 5
Wt.% 52.00 20.00
2.50 1 .50 24.00
Procedure:
Hydroxide, and coo l t o l e s s than 9OF. Add t h e Avanel 5-74 and Sodium Cumene Su l fonate . Mix u n t i l c l e a r and add t h e Sodium Hypoch lo r i t e .
Notes:
a l k a l i n i t y o f common p i p e l i n e c leaners r e s u l t i n g i n a s i n g l e c lean ing system.
She l f s t a b i l i t y o f h y p o c h l o r i t e c leaners i s dependent on t h e absence o f t r a c e meta ls . Care shou ld be taken t o i n s u r e good q u a l i t y water and hypoch lo r i t e .
Formula may be ad jus ted t o use o the r commercial ly a v a i l a b l e concen t ra t i ons o f Sodium Hypoch lor i te . Absolute concen t ra t i on o f a v a i l a b l e c h l o r i n e i s 3.0%.
SOURCE: Mazer Chemicals: Formula t ion CD-103
Charge water t o mix ing vessel and s t a r t a g i t a t i o n . Add Sodium
Th is fo rmu la t i on combines a c h l o r i n e c leaner w i t h t h e h i g h
I n s t i t u t i o n a l S t a i n l e s s S tee l Cleaner
Components: Water 50% C i t r i c Ac id Burcosperse LP Dequest 2000* Burco NPS 50% 45% KOH
% by Weight 52.75 20.00
5.00 5.00 5.00
12.25
*From Monsanto o r use equ iva len t p roduc t .
Procedure: Add components i n t h e order l i s t e d . Blend u n t i l un i fo rm
between each a d d i t i o n .
SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested Formula t ion
14 Advanced Cleaning Product Formulations
High Pressure Cleaner for I n d u s t r i a l Use L iqu id , t ransparent , a l k a l i n e
Inq red i en ts : A Genapol UD-050
Genapol UD-080 Genopur ASA KOH (85%)
B Water (ca.5OC) C Sodi ummetasi 1 i ca te x 5H20
Manufactur ing: I The components o f A a re mixed. I1 Then B i s added. I11 F i n a l l y t h e components o f C a re added
Aquamoll in 8C Powder h i g h l y conc.
2,50% 2,50% 3,00% 5.00%
67 ,00% 10,00% 10,00%
Cleaner f o r M i 1 k i n a Eaui Dment L i q u i d
Ing red ien ts : A Tetrapotassiumpyrophosphate
Sodi ummetasi 1 i c a t e x 5H20 Sodiumcarbonate
B Water C Genopur ASA
KOH (85%) D Genapol UD - 080 Manufactur ing: I One a f t e r another, t h e components o f A I 1 S t i r one a f t e r another, t h e components I11 A t l a s t D i s added.
7.00% 5,00% 3,00%
70 ,00% 5.00% 5,00% 5,00%
are added t o 8. o f c t o I.
Cleaner f o r Meat P lan ts L i q u i d
Ing red ien ts : A Tetrapotassiumpyrophosphate
B Water C Genopur ASA
KOH (65%) D Hostapur SAS 60
Genapol UD - 080 Solvent GX 5
Manufactur ing: I Add one a f t e r another, t h e components o f A t o I 1 C i s added t o I by con t inu ing s t i r r i n g . I11 A t l a s t t h e components o f D a re added.
Potassium water g las (40 Be) 5,00%
76 ,00% 3,50% 3,50% 5.00% 2,00% 3,00%
2,00%
B.
SOURCE: Hoechst Ak t i engese l l scha f t : Detergents and Cleaning Agents: Guide Formulat ions
he, Food and General Industrial Cleaners 15
Meat Packaaina Plant Cleaner Concentrate An A lka l i ne High Foaming Hypochlor i te Hard Surface Cleaner
w i t h Improved Sa l t Tolerance
Inaredi ent : Oei oni zed Water Hostapur SAS-60 Potassi um Hydroxide Tetrapotassium Pyrophosphate Mazon 98 Sodium Cumene Sul fonate (40%) Sodium Hypochlor i te (12.5%) Oei oni zed Water
Wt.% 59.20 2.50 0.90 2.10 5.00 1.30
10.00 19.00
pH (as i s ) : 12.5-13.5 Appearance: Clear- to- t ranslucent, s l i g h t l y viscous, l i g h t -
Speci f i c Grav i ty : 1 .04
Charge t h e water t o a mixing vessel and s t a r t a g i t a t i o n .
yel low l i q u i d .
Procedure:
Charge t h e Hostapur, fo l lowed by t h e Potassium Hydroxide and the Tetrapotassium Pyrophosphate. Apply cool ing and then add the Mazon 98 and t h e Sodium Cumene Sulfonate. When product i s l ess than 85 degrees F. add the Sodium Hypochlor i te and the balance o f t h e water.
Notes: This formula i s designed t o be d i l u t e d t o 3-6 ounces per
ga l l on i n hot water and t o be appl ied as a foam t o meat packing house w a l l s and other surfaces. A f t e r an appropr iate time, these surfaces should be thoroughly r insed.
Shel f s t a b i l i t y o f ch lo r i ne cleansers i s dependent upon t h e absence o f t race metals. Care should be taken t o insure good q u a l i t y water and Sodium Hypochlor i te.
Revision o f CB-102 t o provide greater s a l t to lerance.
SOURCE: PPG Indust r ies, I n c . : Formula CB-102-A
16 Advanced Cleaning Prodccct Formulations
Steam Cleaners C1 eaner-Li ght Duty
Inaredi ents : Sodi urn Metasi 1 i a te Sodi um T r i po l yphosphate Trisodium Phosphate Aerosol 22 Surfactant T r i t o n CF-10
Inqredi ents: Sodi urn Orthosi 1 i c a t e Sodium Carbonate T r i sodi urn Phosphate Aerosol 22 Surfactant T r i t o n CF-10
C l eaner-Medi urn Duty
% by Weiaht 30.0 58.0 10.0
1 .o 1 .o
% by Wei aht 33.0 20.0 44.0
1.5 1 .5 _ _
Cleaner-Heavy D u t y (For O i l y So i l s ) % by Weiaht Inaredi ents:
Aerosol 22 Surfactant 7.0 ~ ~~~
Sodium Metas i l i ca te Dowanol DE Water
Inaredients : Aerosol 0s Surfactant Soda Ash Sodi urn Hydroxide Sodium Metas i l i ca te (5H20) Sodi um T r i po l yphosphate
Cleaner-General Purpose
Use 0.5 t o 2.0 0 2 . t o 1 aa l l on o f water.
35.0 3.0
55.0
% by Weight 10.0 35.0 15.0 30.0 10.0
_ _ _ Cleaner-Lipht Duty f o r So f t Metals
Ingredients : % by Weiaht Aerosol 0s Surfactant 7.14
~ ~~~
Sodium Sesquicarbonate 92.86
Inpredients : % by Weiaht Cleaner-General Purpose
Sodi um Metasi 1 i cate
Aerosol 22 Surfactant 5.0 Water 73-78
15-20 Aerosol 0s Surfactant 2- 3
Cleaner-Compound Inaredi ents : % by Weiaht Sodi urn Hydroxide 30.0 Borax 30.0
D i sodi um Phosphate 15.0 Aerosol C-61 Surfactant 5.0
Add t h e desired amount o f cleaner t o water which has been preheated t o 140F.
SOURCE: Cytec Indus t r i es I n c . : Suggested Formulations
Soda Ash 20.0
3. Degreasers
17
18 Advanced Cleaning Product Formulations
d-Liaonene Microemulsion Cleaner/Desreaser
Burco TME Burco FAE d-Li monene Water
11 p a r t s 11 p a r t s 16 p a r t s 62 p a r t s
Mix i n order l i s t e d ; add water s lowlv. Product w i l l
No co-solvent i s requi red when mixed i n propror t ions given thicken, then break as water i s added.
above. Produces a c l e a r product. Burco FAE imparts corros ion resistance i n add i t i on t o emulsion cha rac te r i s t i cs .
but r a t i o s o f t he other ac t i ves must remain s i m i l a r t o the above. Exampl e :
To make a more concentrated product, l ess water can be used,
TME FAE d-Limonene Water
22 p a r t s 22 p a r t s 32 p a r t s 24 p a r t s
High a c t i v e products can reach a g e l - l i k e v i scos i t y , but can be t h i nned w i t h Isopropanol and Buty l Propyl sol v.
SOURCE: Bur l ington Chemical Co., I nc . : Suggested Formulation
Concentrated d-Limonene Biodearadable Deareaser A Natural All-Purpose Micro-Emulsion Cleaner o r Concentrate
Inaredi ent : d-Limonene. Grade M Mazclean EP Deionized Water
Wt.% 30.00 20.00 50 .00
pH (as i s ) : 9.0-10.0 Appearance: Clear, l i g h t - y e l l o w l i q u i d Spec i f i c Grav i ty : 0.97 Odor: Sweet Orange
Procedure: Charge t h e d-Limonene and Mazon 245-103 t o an apprDopriate
mixing vessel and s t a r t a g i t a t i o n . Under good ag i ta t i on , s lowly add the water and mix u n t i l s o l u t i o n i s c lea r .
Notes :
duty use, product should be sprayed "as i s " onto the o i l y substrate, fo l lowed by a water r i nse .
SOURCE: PPG Indus t r i es , Inc. : Formulation CS-101
This formulat ion may be used "as i s " o r d i l u t e d . For heavy-
Degreasers 19
Sol vent Deareasi rig
The s o l u b i l i t y o f Aerosol OT Sur fac tan t i s extremely h igh i n a l l so l ven ts used f o r degreasing. I t w i l l d i s s o l v e e a s i l y a t room temperature i n most cases. I f hea t ing i s requ i red f o r s o l u b i l i z a t i o n , t h e s o l u t i o n w i l l be s t a b l e upon r e t u r n t o room temperature.
As an example, Aerosol OT-75% i s so lub le t o over 50% a t room temperature i n carbon t e t r a c h l o r i d e , b u t naphtha so lvent requ i res heat ing . Both a re c l e a r s o l u t i o n s a t room temperature. The presence o f t h e water i n Aerosol OT-75% p o r t i o n i s an a i d i n t h e removal o f any water -so lub le p a r t i c l e s present i n t h e work be ing degreased.
Formulat ions such as: Aerosol GPG o r OT-75% High F lash Naphtha
0.5% 99.5%
can be used f o r l i g h t - d u t y c lean ing , t h e so l ven t removing t h e o i l s , waxes, e t c . and t h e Aerosol OT a i d i n g no t o n l y i n t h e pene t ra t i on o f t h e cover ing ma te r ia l , b u t a l s o i n d r a i n i n g . Th is t ype o f c leaner can be sprayed on, brushed on, o r t h e work can be immersed i n t o i t fo l l owed by a r i n s e .
Heavy-Duty Degreasing: To remove heavy l u b r i c a t i n g and p rese rva t i ve o i l s and
greases, many so l ven ts may be used t o s p e c i f i c needs. Aerosol GPG Sur fac tan t w i l l be found t o be so lub le i n a l l o f these so lvents . A t y p i c a l f o rmu la t i on used i s :
Aerosol GPG o r OT-75% Kerosene
1- 3% 97-99%
Prepara t ion i s by s imple mixing. T r i - o r t e t rach lo roe thy lene , h igh f l a s h naphtha o r o ther s u i t a b l e so l ven ts can be s u b s t i t u t e d f o r t h e kerosene.
Carbonaceous depos i t s can be removed by d i p p i n g i n formula- t i o n s such as:
Kerosene Perchloroethylene Carbon Te t rach lo r i de Cresyl i c Ac id Aerosol GPG o r OT-75%
40% 30% 16% 10%
4%
Normally, 3 g a l l o n s o f t h e above a re added t o 1 g a l l o n of water which, f l o a t i n g on t h e surface, minimizes l o s s o f so l ven t . The work t o be cleaned i s immersed i n t h e so lvent phase f o r t ime per iods o f a few minutes t o several hours, i f requ i red , t o o b t a i n c lean l i ness . Upon removal f rom t h e so lvent l aye r , and a s h o r t r i n s e i n t h e aqueous l a y e r , t h e cleaned a r t i c l e s a re r i nsed , d r i e d o r c a r r i e d on to t h e nex t opera t ion . SOURCE: Cytec I n d u s t r i e s , I nc . : Suggested Formulat ions
4. Dishwashing Detergents
20
Dishwashing Detergents 21
C1 ear L i q u i d D i shwash
W i t c o l a t e AE-3 Witco 1298 S o f t Ac id Sodi um Hydroxide, 50% W i t cona te SXS L i q u i d W i tcami de 51 95 Phosphoric Ac id Water
% by Weiqht 12.5 19.0 5.2
13.5 2.5
q.s. t o pH = 6.4-6.8 q.s. t o 100
Blending Procedure
between each a d d i t i o n .
Formula 108
B1 end i ngred i en ts i n t h e order shown, m i x i ng thorough ly
Non-Chlori na ted Machine D i shwashi na Compound, L i q u i d
% by Weight Water, D.I. 79.5 Sodi um Tr ipo lyphosphate 2.0 Versene 220, Powder 1.0 Sodium Gluconate 1 .o Sodium M e t a s i l i c a t e , Pentahydrate 7 . 0 Caust ic Soda 50% 8 .5 Pet ro ULF L i q u i d 1.0
B lend ing Procedure:
between each a d d i t i o n .
Formula 109
Blend i n g r e d i e n t s i n t h e o rde r shown, m ix ing thorough ly
Clear, Co lo r less Manual D ish Wash
Water, D.I. W i t c o l a t e ES-3 Rewoteric AM 8-14 Ethanol Sodium Ch lo r ide
% by Weiqht 57 .5 31.2
5.0 3.0 3.3
B lend ing Procedure:
between each a d d i t i o n .
Comment :
B1 end i ngredi en ts i n t h e o rde r 1 i sted. D isso lve comple te ly
Rewoteric AM 8-14; Grease c u t t e r and foam booster .
Formula 132
SOURCE: Witco Corp.: Suggested Formulat ions
22 Advanced Cleaning Roduct Formulations
Dish Washi na Agent Clear, l i q u i d , 25% WAS
Alkanesulphonate:ethersulfate=4.1 Ingredients : A Hostapur SAS 60
B Water Genapol ZRO l i q u i d
Preservat ive Dye Perfume Hoe S 3924
Manufacturi ng : One a f t e r another, t h e components o f B are added t o A.
Tests: V i scos i t y (mPas) : 90 Cloud p o i n t : <-5C
33.36% 17.90% 47.50% 0.10% q.s. 0.20% 1.00%
Dish Washin A ent c lea r , l iquid: 2:% WAS
alkanesulphonate:ethersulphate=4.1 Ingredients : A Hostapur SAS 60
B Water Genapol ZRO l i q u i d
Preservat ive We Perfume Hoe S 3924
Manufacturing: One a f t e r another, t he components o f B are added
Tests V iscos i t y (mPas): 410 Cloud po in t : <-5C
33.30% 17.90% 44.50%
0.10% q.s. 0.20% 4.00%
t o A.
Dish Washing Aaent Clear, l i q u i d , 30% WAS
alkanesulphonate:ethersulphate=4.1 Ingredients: A Hostapur SAS 60 40.00%
Genapol ZRO l i q u i d 21.40% B Water 30.30%
Preservat i ve O . \ l O % Dye q.s. Perfume 01.20%
Manufacturing:
Tes ts : One a f t e r another, t h e components o f 0 are added t o A.
V i scos i t y (mPas): 330 Cloud po in t : <-5C
SOURCE: Hoechst Akt iengesel lschaf t : Detergents and Cleaningal Agents: Guide Formulations
Dishwashing Detergents 23
Dish Washi na Agent Clear, l i q u i d , 30% WAS
alkanesulphonate:ethersulphate=4:1
I na red ien ts : A Hostapur SAS 60
Genapol ZRO l i q u i d
8 Water Preserva t ive Dye Perfume Hoe S 3924
Manufactur ing:
Tests:
One a f t e r another, t h e components o f 0 are added
V i s c o s i t y (mPas): 610 Cloud p o i n t : <-5C
Powder f o r Automatic Dishwashina Machines
40.00% 21.40%
34.30% 0.10%
q.s. 0.20% 4.00%
t o A.
I na red ien ts : A Genapol 2908
B Sodiummetasi l icate x 5H20
C Sodiumcarbonate Sodi umdichloroi socyanurate Thermphos NW
Manufactur i no:
1;. 00%
52 .00%
10.00% 2.00%
35.00%
I Spray A on 0 . I1 One a f t e r another, t h e components o f C a re added t o 1.
A p p l i c a t i o n :
SOURCE: Hoechst Ak t i engese l l scha f t : Detergents and Cleaning
1-2 g de tergent /L dishwashing l i q u o r
Agents: Guide Formulat ions
24 Advanced Cleoning Product Formulations
Dishwashing Deteraent. Medium V iscos i t v . Bas is Marlon A-A
% Marlon A 350 30.0 Marl i na t 242/70 5.7 D i o n i l OC 1 .o Na cumene sulphonate 40 1 .o Balance water, f ragrance, dyes tu f f , p rese rva t i ve ,
sodium c h l o r i d e t o 100
A c t i v e mat te r : 20.0%
Dishwashing DeterQent. Medium V iscos i t v . Bas is Marlon A-B
%
Marl i na t 242/70 4.3
sodium c h l o r i d e t o 100
Marlon A 365 18.5
Balance water, f ragrance, d y e s t u f f , p rese rva t i ve ,
A c t i v e mat te r : 15.0%
D i shwashi na Detergent, Medi urn V i m s i t y . B a s i s Marlon AS3-A
% Marlon AS3 10.5 Caust ic soda, 50% (approx.) 2.6 Marl i p a l 01 3/120 2.7 Balance water, f ragrance, dyes tu f f , p rese rva t i ve ,
sodium c h l o r i d e t o 100
A c t i v e mat te r : 14.0%
D i shwashi n Q Detergent, Medi urn V iscos i t y . Bas4 s Marlon AS3-B
% Marlon AS3 4.5 Caust ic soda, 50% (approx.) 1.1 M a r l i n a t 242/70 4.5 Balance water, f ragrance, dyes tu f f , pe rse rva t i ve ,
sodium c h l o r i d e t o 100
A c t i v e mat te r : 8.0%
SOURCE: Hu ls America, I n c . : Bas ic Formulat ions o f Detergents and Cleaning Agents f o r Household Purposes
M w h i n g Detergents 25
D i shwashi nq Detergent, Medi um V i s c o s i t y . Bas is Marlon PS-A
% Marlon PS 65 49.0
Marlamid DF 1218 3.0 Ethanol * 4.0 Balance water, f ragrance, d y e s t u f f , p rese rva t i ve ,
Marl i n a t 242/70 11 .5
sodium c h l o r i d e t o 100
A c t i v e ma t te r : 43.0%
D i shwashi ng Detergent, Medi um V iscos i t y , Bas is Marlon PS-B
% Marlon PF 40 71.3
Balance water, f ragrance, d y e s t u f f , p rese rva t i ve , Marlamid DF 1218 1 . 5
sodium c h l o r i d e t o 100
A c t i v e ma t te r : 30.0% * f u r t h e r p roduc ts o f Hu ls AG
D i shwashi ng Detergent, Medi u m V i scos t y . Bas is Marlon Compounds-A
% Marlon AFO 40 46.3 Marlamid D 1885 1 .5 Balance water, f ragrance, d y e s t u f f , p rese rva t i ve ,
sodium c h l o r i d e t o 100
A c t i v e ma t te r : 20.0%
D i shwashi ng Detergent , Medi um V iscos i t y , Bas is Marlon Compounds-B
% Marlon AFO 50 30 .0 Balance water, f ragrance, d y e s t u f f , p rese rva t i ve ,
sodium c h l o r i d e t o 100
A c t i v e ma t te r : 15.0%
SOURCE: Hu ls America, I n c . : Bas ic Formulat ions o f Detergents and Cleaning Agents for Household Purposes
26 Advanced Cleaning Roduct Formulations
D i shwashi n Q Deteraent . Powdered. SDrav M i x i na Process-A
% Marlox FK 64 1 . o Sodium t r i po l yphospha te 40.0 Sodium m e t a s i l i c a t e pentahydrate 35.0 Sodium carbonate, dehydrated 22.0 Sodium d i ch lo ro i socyanura te 2 .0
A c t i v e ma t te r : 1.0% A p p l i c a t i o n : Use 3-5 g/1 water (depending on water hardness)
D i shwashi ng Detergent, Powdered, Spray M i x i ng Process-I3
Marlox B 24/80 Sodium t r i po l yphospha te Sodium m e t a s i l i c a t e pentahydrate Sodium m e t a s i l i c a t e , dehydrated Sodium carbonate, dehydrated Sodi um d i c h l o r o i socyanurate Phosphonate HEDP, e.g. Sequion 10 Sodi um hydrox ide
A c t i v e ma t te r : 1.0 A p p l i c a t i o n : Use 3-5 g/1 water
Na 2
% 1 . o
25.0 25.0 20.0 15.0 2.0 2.0
10.0
(depending on water hardness)
D i shwashi ng Detergent, Powder, Phosphate-Free, Spray M i x i ng Process-A
Marlox MO 154 Sodi um c i t r a t e d i hydra te Sodium d i s i l i c a t e g ranu la te Po lycarboxy la te , e.g. Sokalan PA 40 g ranu la te Sodium perbora te monohydrate Tetraacetylethylenediami ne (TAED) Enzyme Esperase Sodium sesquicarbonate
A c t i v e ma t te r : 2.5%
% 2.5
35.0 25.0
5 . 0 15.0 4.0 2.0
t o 100
Dishwashing Detergents, Powder, Phosphate-Free, Spray M ix ing Process-I3
Marlox MO 154 Sodium carbonate, dehydrated Po lycarboxy la te , e .g . Permulsin SP Phosphonate HEDP, e .g . Sequion 10 Na 2 Sodi um metasi 1 i c a t e
A c t i v e ma t te r : 2.0%
% 2.0
15.0 10.0
5 . 0 t o 100
SOURCE: Hu ls America, I n c . : Bas ic Formulat ions o f Detergents and Cleaning Agents f o r Household Purposes
Dishwashing Detergents 27
DishwashtnLDeterpent (4096 Sol ids)-A
Witconate 1260 S lu r r y W i t c o l a te LES-6OA W i tcami de 128T Water
% by W e i m 37.0 17.5
4.0 34.0
Blending Procedure:
between each add i t i on . Blend ingredients i n the order shown. mixing thoroughly
Dishwashing Deteraent (40% Sol ids)-8
W i tconate 45LX W i tconate SXS L iqu id Wi tco late LES-6OA W i tcamide 128T Water
% bv Weiqht 59.0
6.0 17.5 4.0
16.5
Blending Procedure:
between each addi t ion.
Formula 105
Blend ingredients i n the order shown. mixing thoroughly
Hand D i shwashi ng L i q u i d
W i tconate AOS Witco late S-1285C Witcamide 128T Water
% by Weiaht 60.0 10.0
4.0 26.0
Blending Procedure:
between each add i t i on .
Formula 106
SOURCE: Witco Corp.: Suggested Formulations
Blend i ngredi ents i n the order shown, m i x i ng thorough1 y
28 Advanced Cleaning R&t Formulations
Dish Wash w/Ami ne Oxi de/LABS/SLES
Water, D . I . Witconate 30DS Varox 1770 W i t c o l a te SE-5
Blending Procedure:
between each add i t i on . Add Ethanol as needed t o Typical Proper t ies:
V iscos i ty , cps: 620 Sol ids: 16.8% pH: 9.12
Formula 117
Add ingredients i n order shown and d i ss l v e
Dish Wash w / h i ne Oxi de/LABS/ALES
Water, 0.1. W i tconate 30DS Varox 1770 Witcolate LES-6OA Ethanol
% by Weiqht 62.9 13.7 5 .3
18.1
ompl e t e l y lower v i s c o s i t y .
% by Weiaht 70.0 13.8 3.1 8.2 5 .0
B1 endi ng Procedure: Add ingredients i n order shown and d isso lve completely
between each add i t i on . A c i d i f y w i t h C i t r i c Acid t o pH = 6.5. Typical Propert ies:
V iscos i ty , cps: 4 Sol ids: 10.1% pH: 6.68
Formula 118
Dish Wash w/Ami ne Oxide/LABS
Water, D . I . W i tconate 30DS Varox 1770 Ethanol
% by Weiaht 69.8 20.3
4.9 5.0
Blending Procedure: Add ingredients i n order shown and d isso lve completely
between each add i t i on . Typical Propert ies:
V iscos i ty , cps: 4 Sol ids: 7.8% pH: 9.16
Formula 119
SOURCE: Witco Corp.: Suggested Formulations
Dishwashing Detergents 29
High-Performance Hand Dish Detergent Formula DW-0013
Water SXS, 40 Caustic Soda, 50% Dodecylbenzene s u l f o n i c Acid Rhodapex NA-61 A 1 kami de DC-212/S Rhodacal A-246/L Rhodasurf 25-9 C i t r i c Acid (50%). t o pH 8 Ethanol SD-3A Preservat i ve Fragrance Dye
Wt.%
3.0 6.6
25.0 8.0 3.0
10.0 6.0 Q.S. 2.0 0.1
To 100
-
Procedure Add the ingredients i n the order l i s t e d w i t h mixing. Mix
u n t i l uni form a f t e r each add i t i on . C i t r i c Acid and Caustic Soda are used f o r pH adjustment. Physical ProDerties
Appearance: Clear go ld l i q u i d , dyed t o preference pH. as i s : 8 V iscos i ty : 400 cps Spec i f i c Grav i ty : 1.05
M i l d L i a u i d Hand Dish Detergent
Water Caustic Soda (50%) Dodecylbenzene s u l f o n i c ac id Miranol CS Conc. A1 kami de DC-212/S Rhodasurf 25-9 Cheel ox BF-13 C i t r i c Acid (50%). t o pH 8 Fragrance Dye
Wt.% To 100
3 12 15 3 3 0.2
Q . S . - - Procedu r e
u n t i l uni form a f t e r each addi t ion. C i t r i c ac id and caus t i c soda are used f o r pH adjustment. Dissolve the dye i n water before add i t i on . Phvsi c a l P roper t i es
Appearance: Clear go ld l i q u i d , dyed t o preference pH. as i s : 8 Spec i f i c Grav i ty : 1.04 V iscos i t y : 150 cps
Add the ingredients i n the order l i s t e d w i t h mixing. Mix
SOURCE: Rhone-Poulenc Surfactants & Spec ia l t i es : Formulas
30 Advanced Cleaning Product Formulations
S t a r t i n g Formula t ions f o r Home Machine Dishwashinq Detergents 8.7% Phosphorous(A)
Compounds: BASF Sur fac tan t * Sodium t r i po l yphospha te B r i t e s i 1 H24 hydrous sodium s i 1 i c a t e * * Sodium s u l f a t e Sodium carbonate Ch lo r ina ted isocyanurate*** Water
8.7% Phosphorous(B1
Coflpounds : BASF Sur fac tan t * B r i t e s i l H24 hydrous sodium s i l i c a t e * * Sodi um s u l f a t e Sodium carbonate Ch lo r ina ted isocynaurate*** Sodium t r i po l yphospha te hexahydrate
Nonphosphate
Compounds2 BASF Sur fac tan t * Sokalan PABOCL B r i t e s i l ti24 hydrous sodium s i l i c a t e * * Ch lo r ina ted t r i s o d i u m phosphate Sodium s u l f a t e Sodium carbonate Sodi um c i t r a t e d i hydra te
?4 b y W S i ¶ h _ t . 3
34 17 15 19
2 10
% -by__W!sh t 3
17 1 4 . 5 20
1 . 5 44
”/._ b Y. W!%lb t 4 . 0 2****
20 1 2 . 5 30
1 . 5 30
*P lu ron ic , P lu ra fac , and I n d u s t r o l s u r f a c t a n t **Other r a t i o s o f Si02 can be used. L i q u i d s i l i c a t e s can a l s o
be used i n p l a c e o f powders. ***Such as ACL-59.
* * * *Ac t ive
M ix ing Procedures:
gent, t h e f o l l o w i n g process i s suggested f o r t h e mix ing of raw mater i a1 s : 1 . Spray a m ix tu re o f t h e s u r f a c t a n t and water ( o r su r fac tan t ,
To achieve maximum c h l o r i n e s t a b i l i t y o f t h e formulated de te r -
water , and l i q u i d s i l i c a t e ) on to t h e phosphate b u i l d e r s , soda ash, o r m ix tu re t h e r e o f . S t i r con t inuous ly w h i l e spray ing .
w i t h s imu l - Th i s process r e s u l t s i n hyd ra t i on o f t h e bu lde rs taneous adsorp t ion o f t h e s u r f a c t a n t .
2. Add t h e ch lo r i ne -con ta in ing compound and any f i l m ix tu re and cont inue mix ing u n t i l t h e e n t i r e m i x homogeneous. A d ry , f r e e - f l o w i n g granu lar produc ob ta ined w i t h t h i s method.
SOURCE: BASF Corp.: Suggested Formulat ions
e r s t o t h e u re i s
should be
-washing Detergents 31
L i g h t Duty L i q u i d Deteraents
L i q u i d de tergents based on P i l o t Ca lso f t , Calsuds and Calfoam s u r f a c t a n t s produce safe, e f f e c t i v e suds w i t h e x c e l l e n t grease- c u t t i n g p r o p e r t i e s f o r hand dishwashing. Detergents con ta in ing Calamide C a re e s p e c i a l l y m i l d t o s e n s i t i v e sk in .
Water C a l s o f t L-60 Ca l fax DB-45 Cal foam EA-603 Calamide C C i t r i c Ac id Perfume
Ammonium Ch lo r ide Dye
Calsuds A Cal foam ES-303 Water* C i t r i c Ac id Perfume and Color
C a l s o f t L-40 Cal foam EA-603 Calamide C P i l o t SXS-40 Water* C i t r i c Ac id Perfume and Color
Calsuds CD-6 Cal foam EA-603 P i l o t SXS-40 Cal s o f t LAS-99 Water* C i t r i c Ac id Perfume and Color
P i l o t Formula #LDL-010-01
% bv Weipht 61 .OO 19.80 9.90 5.00 3.00 0.10 0.10 0.10 1 .oo
P i l o t Formula #LDL-013-01
% by Weiaht 70.00 10.00 20.00
Q.S. pH 7 Q . S .
P i 1 o t Formul a #LDL-005-01
% bv Weiaht 40.00 10.00 6.00
12.50 26.50
Q.S. pH 7 Q . S .
P i 1 o t Formula #LDL-015-01
% bv Weight 25.00 10.00 8.80 6.00
50.20 Q.S. pH 7
Q . S .
*May be o p a c i f i e d by r e p l a c i n g 1% o f water w i t h 1% l a t e x opaci f i e r . Opaci f i e r should be d i 1 u ted w i t h water be fo re a d d i t i o n .
SOURCE: P i 1 o t Chemi c a l Co. : Household C1 eaner Formul a t i on8
32 Advanced Cleaning Promcct Formulations
L i g h t Duty Liauid. Premium Hand Dishwash
Water, D . I . W i t c o l a t e SE-5 W i t cona te 1260 S1 u r r y W i tcami de 128T Pe t ro LEA L i q u i d Sodium S u l f a t e Ethanol Formal i n Perfume, Dye
% by Weight 30.2
36.7 5.0 1 .9 2.6 1 .8 0.1 q . s .
21.7
B lend ing Procedure:
us ing C i t r i c Acid.
Typ ica l P r o p e r t i es :
Blend i n g r e d i e n t s i n t h e order l i s t e d . Ad jus t pH = 6.5-7.0
V i s c o s i t y , cps: 230 Appearance: C lear L i q u i d
Formula 113
L i g h t Duty L i q u i d
Water, D. I. W i t c o l a t e SE-5 Witconate 1260 S l u r r y W i tcami de 128T Pe t ro LEA L i q u i d Sodium S u l f a t e Sodium Ch lo r ide Formal i n Perfume, Dye
Economy Hand D i shwash
% by Weiqht 73.6 8 .3
13.5 1 .9 1 . o 0.6 1 .o 0.1 q . s .
81 ending Procedure:
us ing C i t r i c Ac id .
Typi c a l P r o p e r t i es :
Blend i n g r e d i e n t s i n t h e o rde r l i s t e d . Ad jus t pH = 6.5-7.0
V i s c o s i t y , cps: 180 Appearance: C1 ear L i qu i d
Formula 115
SOURCE: Witco Corp.: Suggested Formula t ions
LXshwashing Detergents 33
Water Caustic Soda (50%)
L i a u i d Hand D ish Detergent Formula DW-0016
Wt.% Wt.% Wt.% To 100 To 100 To 100
2.5 3.3 4.1 Dodecylbenzene sui f o n i c ac id 10 13 Rhodapex NA-61 4.5 4.5 A1 kami de DC 212/S 1 2 Cheelox BF-13 0.5 0.5 C i t r i c Acid (50%), t o pH 8 Q.S. Q . S . Sodium ch lo r i de 1 1 Fragrance - - Dye Opaci f i er (Morton ) - -
- -
16 5 3 0.5 Q.S. 1
Procedu r e Add t h e ingredients i n the order l i s t e d , w i t h mixing. Mix
u n t i l uni form a f t e r each addi t ion. C i t r i c ac id and caus t i c soda are used f o r pH adjustment. Sodium ch lo r i de b u i l d s v i s c o s i t y . Dissolve i t i n water before add i t i on .
Dissolve t h e dye i n water before add i t i on . I f o p a c i f i e r i s used, i t should be d i l u t e d w i t h water before addi t ion. A l l pH adjustments must be completed before t h e o p a c i f i e r i s added.
Phvsical ProDertieg Appearance: L iqu id, colored and opac i f i ed t o preference pH. as i s : 8
V iscos i ty : 200-400 cps Speci f i c Gravi t y : 1 .02+-0.05
pH, 1%: 7.2
SOURCE: Rhone-Poulenc Surfactants & Spec ia l t i es : Formula
34 Advanced Cleaning Product Formulations
Mechanical D i shwashi ng Detergent Chlor inated
Formula DW-0009
Sodium Carbonate ( L t . Density) Antarox BL-330 Sodium Tripolyphosphate. Powder Sodium Metas i l i ca te Pentahydrate Clearon CDB (FMC)
Wt.% 41 . O
2.0 34.0 20.0 3.0
Procedu rQ Add the sodium carbonate t o the mixer. Spray on t h e Antarox
EL 330. Add t h e remaining ingredients i n the order l i s t e d . Mix u n t i 1 uniform.
Phvsi ca l ProDert i eg Appearance: White, f ree- f lowing powder pH (1%): 11.2 Spec i f i c Grav i ty : 0.70
Uechani c a l D i shwashi ng DeterQent L i sui d Formula DW-0010
Igepal CO-730 Gantrez AN-149 Potassium Hydroxide (45% Act ive) Sodium S i l i c a t e (46% Act ive) Antarox BL-330 Tetrapotassium Pyrophosphate (60% Act ive) Water
Wt.% 0.5 1 . o 3.0
17.0 3.0
63.3 12.2
Proctndu r e 1. Add Gantrez AN-149 t o Igepal CO-730/water mix ture and s t i r
a t room temperature u n t i l d issolved. Heat t o 45-50C i f not t o t a l l y i n s o l u t i o n .
2. Maintain heat a t 45C and add r e s t o f ingredients i n d i v i d u a l l y .
Physical P r o m r t i eg pH (as i s ) : 13.2 pH (1%): 10.4 V iscos i t y : 1060 cps Spec i f i c Grav i ty : 1.14
SOURCE: Rhone-Poulenc Spec ia l t i es 6 Surfactants: Formulas
Dishwashing Detergents 35
L i a u i d Formula DW-0008
Rhodacal A-246/L Rhodapex MA-460 Alkamide DC-212/S Sodium Xylene Su l fonate (40%) O p a c i f i e r (Morton) Water C i t r i c Ac id t o pH 6.5-7.5 Perfume and Color
Wt.% 60.0 10.0 5.0 4.0 1.0
20.0 Q . S . P.S.
Procedure 1. Charge water and sodium xylene su l fona te t o vessel equipped
w i t h a g i t a t i o n .
u n t i 1 uni form. 2. Add Rhodacal A-246/L and Rhodapex MA-360 t o vessel and mix
3. Add Alkamide DC-212/S and mix as above. 4. Ad jus t pH 6.5-7.5 w i t h c i t r i c ac id . 5. Add o p a c i f i e r ( o p t i o n a l ) , perfume and co lo ran t , as des i red .
Phys ica l P r o m r t i e s : Appearance: Clear go ld l i q u i d , dye and opac i f y t o preference. pH, as i s : 6.5-7.5 S p e c i f i c Grav i t y : 1.02-1.04 V i s c o s i t y : 200-300 cps
SOURCE: Rhone-Poulenc Sur fac tan ts EL S p e c i a l t i e s : Formula
36 Advanced Cleaning Product Formulations
S t a r t i n a Formulations f o r Commercial Machine Dishwashing Deteraents
Nonchlori ne/Noncaustic
BASF Surfactant* Sodium tr ipolyphosphate Sodium carbonate Sodium s u l f a t e Sodium metas i l i ca te pentahydrate Water
Noncaustic
BASF Surfactant* Sodium tr ipolyphosphate Sodium carbonate Sodium metas i l i ca te pentahydrate Chlor inated isocyanurate** Water
Ch lo r ineKaus t i c
BASF Surfactant* Sodium tr ipolyphosphate Sodium carbonate Sodium metas i l i ca te pentahydrate Chlor inated isocyanurate** Sodium hydroxide (90%) Water
*Pluronic, Plurafac, I ndus t ro l sur factant **Such as ACL-59
% by Weight 3
34 22 11 25
5
% bv Weiaht 3
31.5 20 31.5
1.5 12.5
% bv Weiqht 3
34 18 22.5
2 .5 15 5
M i x i ng Procedures : 1. Thoroughly mix the phosphate and carbonate. 2. I n a separate container, mix the sur factant and water. Next,
spray th'is l i q u i d onto the phosphate/carbonate mixture. Mix cont inuously wh i l e spraying, and continue mixing u n t i l t h e l i q u i d i s completely adsorbed and the mixture i s homogeneous.
3. Add the me tas i l i ca te , su l fa te , and/or caust ic and mix. 4. F i n a l l y , add the ch lo r i na ted cyanurate and mix thoroughly. Note:
maximum ch lo r i ne s t a b i l i t y .
SOURCE: BASF Corp.: Suggested Formulations
The mixing sequence given above i s necessary f o r maintaining
5. General Purpose Cleaners
37
38 Advanced Cleaning Roduct Formulatioiu
A1 1 Purpose Cleaner
Mackam 2CSF Tetrapotassi um Pyrophosphate T r i sodium Polyphosphate KOH (45%) Low Rosin T a l l O i l Fa t t y Acid Dei oni zed Water
Weight.% 10.0 5.0 5.0 4.0
10.0 66.0
Procedure: 1. Dissolve Tetrapotassi um Pyrophosphate and T r i sodi um Po
2. Add KOH. 3. Disperse T a l l O i l Fa t t y Acid. 4. Cool t o 50C and s lowly add Mackam 2CSF.
phosphate a t 70C.
PhosDhate Free A l l PurDose Cleaner
Sodium Metas i l i ca te Pentahydrate Mackami ne C-10 Caustic Soda (50%) Mackam 2CYSF Tetrasodium EDTA (40%) Dei oni zed Water
Y-
Weight .% 22.0 9.0 2.0 4.0 1 . o
62.0
Procedure: 1. Add Sodium Metas i l i ca te and Tetrasodium EOTA t o water and
2. Add Mackamine C-10 and Caustic Soda (50%). 3. Add Mackam 2CYSF and blend u n t i l c l e a r .
heat t o 60C.
Bathroom T i l e Cleaner
Sodium Hypochlor i te (35%) Mackamine LO Tetrasodi um EDTA Dei oni zed Water
Procedure: Add components t o water and blend u n t i l c
SOURCE: McIntyre Qroup Ltd. : Suggested Formu
Wei aht .% 4.7 5 .0 1 .o
89.3
ear.
a t i one
Water Sodi um Carbonate Tetrasodium EDTA, 40% W i t c o l a t e 7031 Sodium Ch lo r ide W i t cona te SXS L i q u i d C i t r i c Acid, 50%
A l l Purgose Cleaner
% bv Weiqht 61.2
5.0 6.0 15.0 10.8 2.0
9 .s . t o pH=11.0-11.5
Blend ing Procedure:
Typ ica l P roper t i es : V i s c o s i t y , cps: Water t h S o l i d s : 25.6% pH, as i s : 11.2
Blend i n g r e d i e n t s i n t h e order l i s t e d .
n
SOURCE: Wi tco Corp.: Formula 518
All-PurDose Cleaner
Eastman E 8 so lven t Na4EDTA* Nonionic s u r f a c t a n t * * I sop ropy l a lcoho l Water
*Tet rasod i um e t h y l enedi ami n e t e t r a c e t a t e **Such as Neodol 23-7 a lcoho l e thoxy la te
N-95 e thoxy la ted nonylphenol (Texaco).
Hard-surface Cleaner
Eastman DB so lven t An ion ic su r fac tan t * * * N a 4 EDT A* * * * Ammonium Hydroxide (28%) Water
2. 2 1
90
39%) S h e l l ) o r Su l fon
% bv Weisht 3.2 7 3 5 3
C
% bv Weiaht 7.0 1 . o 1.25 2.0 88.75
***Such as Rhodapex CO-433 (Rhone-Poulenc) ****Tetrasodium ethylenediaminetetraacetate (39%)
SOURCE: Eastman.Chemica1 Co.: Eastman EB and D0 Solvents f o r Cleaners: Suggested Formulat ions
General Purpose Cleaners 39
40 Advanced Cleaning Product Formulations
A1 1 -Purpose C1 eaner-A
% Marl i p a l 24/90 7.5 Methoxypropanol 6.0 Sodium carbonate 3.0 N i t r i l o t r i a c e t a t e , 40% 0 . 4 Balance water, fragrance, dyestuf f , preservat ive, sodium c h l o r i d e t o 100
Act ive matter: 7.5% V iscos i t y : L iqu id
A11-PUrDOSe C l e a n e r 4
% Mar l i pa l 1012/6 1 .o Mar l i na t 242/28 10.0 Sodium carbonate 3 . 0 Sodium c i t r a t e d ihydrate 1.5 Sodium t a r t r a t e 1.5 Balance water, fragrance, dyestuf f , preservat ive,
sodium ch lo r i de t o 100
Act ive matter: 3.8% Viscos i t y : Low
Al1-PUrDOSe Cleaner. w i t h Y ic rob ic ida l Prooert ies. Liauid-B
Marl i pa l 01 3/99 Warlazin KC 21/50 N i t r i 1 o t r i acetate, 40% Sodium carbonate Balance water, fragrance, dyes tu f f
% 8.0 5.0 0.5 3.0
t o 100
Act ive matter: 9.7%
SOURCE: Huls America, Inc. : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
General Purpose Cleaners 41
A-Jl-Purpose Cleaner, L iquid-A
Marlon PS 65 Marl i pa l 01 3/69 Coconut f a t t y a c i d C i t r i c terpene Methoxypropanol Sodium carbonate Sodium c i t r a t e d ihyd ra te Ethylenediamine te t raace ta te , 40% Balance water, f ragrance, d y e s t u f f , p rese rva t i ve
A c t i v e mat te r : 3.1%
A l l -Pu_rpose C1 eaner , L i qu i d-6
Marl i pa l 01 3/69 C i t r i c terpene Methoxypropanol Sodi um carbonate C i t r i c a c i d N i t r i l o t r i a c e t a t e , 40% KNA cumene sulphonate 40 Balance water, f ragrance, dyes tu f f , p rese rva t i ve
A c t i v e mat te r : 4.5%
% 3.0 1 . o 0.2 2.0 3.0 3.0 3.0 0 . 2
t o 100
'16 5 . 0 0 . 2 5 . 0 3.0 1 . o 0 . 2 1 . o
t o 100
Al l -Purpose CleaKer, w i t h - M i c r o b i c i d a l Proper t ies , L iquid-A
Marl i pa l 01 3/99 N i t r i l o t r i a c e t a t e , 40% Lonzabac 12.30 Sodium carbonate KNA cumene sulphate 40 Balance water, f ragrance, d y e s t u f f
% 7.5 2.0 3.0 3.0 2.0
t o 100
A c t i v e mat te r : 6.8%
SOURCE: Huls America, I n c . : Basic Formulat ions o f Detergents and Cleaning Agents f o r Household Purposes
42 Advanced Cleaning product Formulations
All-Purpose Cleaner, Pastv-A
Marlon AS3 Caust ic soda, 50% (approx.) Marl i nat 242/28 Marl i p a l 01 3/30 Tylose CBR 10000 T i tan ium d i o x i d e Sodium c h l o r i d e (approx.) Balance water, f ragrance, p rese rva t i ve
A c t i v e mat te r : 18.0%
A1 1 -Purpose Cleaner ,
Marlon PF 40 Mi l i p a l 01 3/30 Marlamid DF 1218 Tylose CBR 10000 T i tan ium d i o x i d e Sodium c h l o r i d e (approx.) Balance water, f ragrance, p rese rva t i ve
A c t i v e mat te r : 22.0%
96 10.0 2.6
15.5 3.0 4.0 0.1 2.0
t o 100
Pastv-B
% 45.0
2.0 2.0 4.0 0.1 8.0
t o 100
Al l -Purpose Cleaner, W i t h Soap, High V iscos i ty -A
% Marlon PF 40 5 . 0 O l e i c a c i d 10.0 Caust ic potash, 50%* (approx.) 3.9 Potassium carbonate* 1 .o Ethylenediamine t e t r a a c e t a t e , 40% 0.2 Balance water, f ragrance, d y e s t u f f , p rese rva t i ve t o 100
A c t i v e mat te r : 12.8%
Al l -Purpose Cleaner. W i t h Soap. High V iscos i tv -B
Marl i pa l 24/79 Marl i pa l 242/28 O l e i c Ac id Caust ic potash, 50%* (approx.) Sodi um c i t r a t e d i hydra te Ethylenedi amine te t raace ta te , 40% Ethanol * Balance water, f ragrance, d y e s t u f f , p rese rva t i ve
A c t i v e mat te r : 11.8%
96 2.0 5 .0 8.0 3.1 1.5 0.2 1.5
t o 100
SOURCE: Hu ls America, Inc. : Basic Formulat ions o f Detergents and Cleaning Agents f o r Household Products
General Purpose Cleaners 43
D-Lilnonene Emuls i f iab le Concentrate Formul a HS-0094
Component D-Li monene Rhodacal I PAM Igepal CQ-720 T r i ethanol ami ne
Wt.% 80.0 1 5 . 0
4 . 0 1 .o
Procedure
Phvsical Prooer t i es
Blend ingredients i n order l i s t e d and m i x u n t i l uniform.
Appearance: Clear, yel low l i q u i d Spec i f i c Grav i ty : 0.9 V i scos i t y : t10 cps pH, as i s : 10.0
Note: Product forms mi lky whi te emulsions when d i l u t e d w i t h water.
D-Limonene All-PurDose Cleaner Formula HS-0033
Comoonent: Water Sodium Metasilicate-Pentahydrate Miranol FBS Rhodasurf 91 -6 Cheelox BF-13 A1 kamide DC-212/M D-Li monene
Wt.% 73.5 2.0
10.0 3.5 5.0 3.0 2.0
Procedu r e Blend ingredients i n order l i s t e d and m i x u n t i l uniform.
Phvsicsl Proner t ies Appearance: S l i g h t l y hazy, yel low l i q u i d pH, as i s : 1.25 Spec i f i c Grav i ty : 1.02 V iscos i t y : <I0 cps
SOURCE: Rhone-Poulenc Surfactants 81 Specia l t ies: Formulas
44 Advanced Cleaning Rorluct Formulations
General C1 eaners
Cleaner-Household
Ins red i ents: Tetrapotassium Pyrophosphate Dodecyl benzene Sul fonate T r i ethanol ami ne S a l t Aerosol A-103 Surfactant Laur ic Diethanolamide Sodium Xylene Sul fonate
Mix a l l o f t he above together a t one time.
A1 k a l i ne Cleaner
Ins red i ents: Aerosol 0s Surfactant Sodi um Metasi 1 i cate Caustic Soda Tetrasodi um Pyrophosphate T r i sodi um Phosphate
L i a u i d Hand Cleaner
Insredients : Aerosol A-102 Surfactant Mineral O i l Coconut O i l n-Propanol o r Isopropanol Triethanolamine Germicide Water
% by Weiaht 8 . 0 4.0 4.0 2.0
7 6 . 0
% bv Wei aht 5 . 0
50.0 5.0 7 . 0
3 3 . 0
% by Weiaht 60.0 10.0
5 . 0 5 . 0 0.5 0.1
19.4
Germicidal C1 eaner
Inaredi ents: % bv Weiaht Aerosol 22, Aerosol 0s. Aerosol A-102 Surfactant
o r mix ture 10.0 Tetrapotassium Pyrophosphate 7.0 Dowicide 32 5 . 0 Isopropanol 3 . 0 Water 7 5 . 0
SOURCE: Cytec Indus t r i es Inc. : Suggested Formulations
General Purpose Cleaners 45
Hiph-Performance General Purpose Cleaner Concentrate Formula HS-0038
Water STPP (Anhydrous Granular) Rhodapon UB Rhodapon BOS A1 codet HSC-1000 Butoxyethanol Miranol FBS
Procedu r e Blend ingredients i n order 1
Phvsi ca l P r o D e r t l es Appearance: Clear, l i g h t ye1 pH, as i s : 9 . 4 Spec i f i c Grav i ty : 1.06 Viscos i t y : t10 cps
sted
ow 1
and mix unt
qu id
Heavy-Dutv Cleaner Powder Formula HS-0039
Wt.% 65.0
6.0 13.0 5.0 5.0 4 . 0 2 . 0
1 uniform.
Trisodium Phosphate o r Sodium Carbonate Sodi um S i 1 i cate Rhodacal DS-10 Sodium Su l fa te Fragrance
Procedu r g
uniform.
Physical ProDerti es
Add ingredients i n order l i s t e d t o powder blender
Appearance: Whi te , f ree- f 1 owi ng powder pH, 1% Solut ion: 10.8
Wt.96 40 10 20 30
Q.S
Mix u n t i l
SOURCE: Rhone-Poulenc Surfactants & Specia l t ies: Formulas
46 Advanced Cleaning Pr&t Formulations
Neut ra l A1 1 -PurDose C1 eaner, w i t h Pear l escence High V i scosi t y - A
Marlon PS 65 Marl i nat 242/28 Marlamid DF 1218 Marlamid PG 20 Cellobond HEC l O O O O O A Balance water, f ragrance, dyes tu f f , p rese rva t i ve
A c t i v e mat te r : 7.2%
E f fec t ,
96 7.5 4.5 1 .o 2.0 0.7
t o 100
Neut ra l All-PUrDOSe Cleaner, w i t h Pearlescence E f f e c t . H i ah V i scosi ty-B
M a r l i n a t OFK 30 Marl i na t 242/28 Marlamid DF 1218 Marl i pa l 24/90 Marlamid PG 20 Cellobond HEC l O O O O O A Balance water, f ragrance,
A c t i v e mat te r : 5.0%
96 5.0 2.0 1 .o I .o 1 . o 0.9
dyes tu f f , p rese rva t i ve t o 100
A1l-PUrDOSe Cleaner, w i t h A c e t i c A c i d - A
M a r l i p a l 1012/6 M a r l i n a t 242/28 Sodium c i t r a t e d ihyd ra te Ace t i c ac id * Sodi um c h l o r i d e (approx. ) Balance water, f ragrance, d y e s t u f f
A c t i v e mat te r : 5.7% V i s c o s i t y : low
A11-PUrDOSe Cleaner. w i t h A c e t i c Acid-B
Marlon PS 65 Ace t i c ac id* Balance water, f ragrance, dyes tu f f
A c t i v e mat te r : 3.3% Viscos i t y : 1 i q u i d
* f u r t h e r p roduc ts o f Huls AG
96 1.5
15.0 1 .o 2.0 6.5
to 100
s6 5.0 6.0
t o 100
SOURCE: Hu ls America, Inc. : Bas ic Formulat ions o f Detergents and Cleaning Agents f o r Household Purposes
General Purpose Cleaners 47
Non-PhosDhate A l l PurDose Cleaner
Components: Water 45% KOH Burcosperse AP L iqu id Sodium Xylene Sulfonates 40% Sodi um C i t r a t e Dodecylbenzene Su l fon i c Acid Burco TME Buty l Propasol Varsol o r Mineral S p i r i t s
% by Weight 77.15 0.75 3.00 3.40 1 .oo 1.75 6 . 0 0 6 . 0 0 0.95
Procedure:
between each add i t i on . Add components i n the order l i s t e d . Blend u n t i l uni form
O i l S D l i t t i n s General PurDose Cleaner
Components: Water Sodium Metas i l i ca te Pentahydrate Burco ADS-40 Burco TME Burco LAA-38 Burco EHS
% by Wei Qht 82.5
5.0 2.5 5.0 2.5 2.5
Procedure: Add components i n t h e order l i s t e d . Blend u n t i l f u l l y d iss-
olved between each addi t ion. This i s a use as i s formulat ion f o r heavy duty c leaning. For
l i g h t e r duty appl icat ions, d i l u t i o n w i t h water may be poss ib le . This formulat ion w i l l suspend o i l t o a s s i s t w i t h removal. The suspended o i l w i l l then f l o a t f o r easy removal.
SOURCE: Bu r l ington Chemical Co., I nc . : Suggested Formulations
48 Advanced Cleaning Product Formulations
Scouri ng Cleaner, Medi urn V i scosi tv-A
Marlon PS65 Marl i pal 01 3/30 Sodium sulphate Calcium carbonate, e.g. Durcal 40 Balance water, dyestuf f , fragrance, preservat ive
Act ive matter: 5.5%
Scouring Cleaner. Medi urn V i scosi t y - B
Marlon PS 65 Mar l i pa l 013/30 Marl i nat 242/28 Sodium carbonate Calcium carbonate, e.g. Durcal 40 Balance water, dyes tu f f , fragrance, preservat ive
Act ive matter: 5.8%
Scouring Cl-eaner. Powder-A
Marlon ARL Sodium carbonate, dehydrated Sodi um d i ch lo ro i socyanurate Calc i um carbonate powder (abrasive)
Act ive matter: 4.0%
% 4.3 2.7 1.5
50.0 t o 100
% 3.5 3.0 2 . 0 1.5
5 0 . 0 t o 100
% 5.0 5.0 1 . o
t o 100
Scouring Cleaner, Powder-B
% Marlon ARL 5.0 Sodium carbonate, dehydrated 5.0 Sodium tr ipolyphosphate 2.0 Calcium carbonate powder (abrasive) t o 100
Act ive matter: 4.0%
SOURCE: Huls America, I nc . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
6. Glass Cleaners/Polishes
49
50 Advanced Cleaning Roduct Formulations
A n t i f o g Compositions f o r A p p l i c a t i o n t o C l o t h
Special w ip ing c l o t h s impregnated w i t h Aerosol OT Sur fac tan t a re used t o c lean and t o p revent fogg ing o f eye glasses, b i n - ocu la rs , goggles, eyepieces i n gas masks, and automobile, t r a i n , p lane, and boat windshields. Such w ip ing c l o t h s a re prepared by impregnat ing c o t t o n f l a n n e l w i t h Aerosol OT Sur fac tan t s o l u t i o n s fo l l owed by a run through squeeze r o l l s t o remove t h e excess 1 i quor .
a t 25% s o l i d s and one fo rmu la t i on a t 50% s o l i d s a re as f o l l o w s : Three successful f o rmu la t i ons con ta in ing Aerosol OT Sur fac tan t
Ingred ien ts -1 : Aerosol OT-75% Sur fac tan t ( l b . ) Varsol No. 2 Petroleum Solvent ( g a l . ) I sopropy l Alcohol ( g a l . ) Water ( g a l . )
I na red i ents-2 : Aerosol OT-75% Sur fac tan t ( l b . ) Varsol No. 2 Petroleum Solvent ( g a l . ) I sopropy l Alcohol ( g a l . ) Water ( g a l . )
I n ~ r e d i e n t s - 3 : Aerosol OT-75% Sur fac tan t ( l b . ) Varsol No. 2 Petroleum Solvent ( g a l . ) I sopropy l Alcohol ( g a l . ) Water (ga l . )
Inqred ien ts -4 : Aerosol OT-75% Sur fac tan t ( l b . ) Varsol No. 2 Petroleum Solvent ( g a l . ) I sopropy l Alcohol ( g a l . ) Water ( g a l . )
25% S o l u t i o n 113
15 3
19
25% S o l u t i o n 113
6 6
25
25% S o l u t i o n 113 -
8 29
50% S o l u t i o n 66
2
3 -
The so l ven ts and water a re mixed a t 80F t o 1OOF. The Aerosol OT-75% Sur fac tan t i s added s low ly w i t h cont inued mix ing . A f t e r t h e Aerosol OT has d isso lved, a l l s o l u t i o n s w i l l remain c l e a r and l i q u i d a t temperatures as low as 5OF. No scumming o f t h e sur face w i l l occur because o f evapora t ion d u r i n g a normal run o f c l o t h through t h e ba th . The s o l u t i o n s t h a t a re al lowed t o stand should be covered t o p revent l o s s o f so l ven t .
The optimum amount o f Aerosol OT Sur fac tan t t o be l e f t on t h e c l o t h i s 40-50%, based on t h e weight o f t h e c l o t h . However, a range o f 25-50% w i l l g i v e s a t i s f a c t o r y r e s u l t s .
SOURCE: Cytec I n d u s t r i e s Inc . : Suggested Formulat ions
Glass CleanerslPolishes 51
A n t i f o g Compositions f o r D i r e c t Appl icat ion t o Glass
Aerosol OT Surfactant i s used i n specia l formulat ions t h a t are appl ied d i r e c t l y t o glass surfaces t o prevent fogging under ad- verse weather condi t ions. Some o f these formulat ions g i ve dur- ab le f i l m s t h a t stand up under severe tes ts . An example o f an excel l e n t "Ant i fog" paste i s as fo l lows:
Aerosol OT-75% Surfactant Gum Tragacanth Petrolatum Water
10.7 l b . 2.0 l b . 2 . 0 l b .
85.3 l b .
Heat t h e water t o 18OF and add the Aerosol OT-75% slowly w i t h mixing. S i f t i n powdered gum tragacanth. Continue mixing u n t i l a l l gum i s dispersed, cool t o 105F, and add petrolatum.
Appl icat ion o f An t i f og Paste: Dampen t h e corner of a piece o f c l o t h w i t h paste and rub
over e n t i r e glass surface. Before f i l m becomes dry, p o l i s h we l l w i t h c lean p o r t i o n o f t he c l o t h .
A spray bomb o f An t i f og may be prepared as fo l lows:
Aerosol OT-75% Surfactant Buty l Cel losolve Solvent Propel 1 ant
10 p a r t s 10 p a r t s 80 p a r t s
Aerosol OT Surfactant may a l so be cast i n t o s t i c k form. Softening agents such as g lycer ine o r ethylene g l yco l are incorporated t o s i m p l i f y app l i ca t i on t o the glass surface. Such s t i cks , usual ly two t o fou r inches long and one-half inch i n diameter, are so ld i n k i t s f o r app l i ca t i on t o goggles, w i ndshi e l d w i pes and bthroom m i r r o r s .
SOURCE: Cytec Indus t r i es , Inc. : Suggested Formulations
52 Advonced Cleoning product FormulotiOnr
Water, D . I . Isopropanol Adogen 66 Varox 365 Emcol 4500
Anti-Foggina. An t i -S ta t i c Glass Cleaner
% bv We
Blending Procedure: Combine ingredients i n the order shown and mix thorough
I f product i s hazy, add i t i ona l Isopropanol can be used t o c l a r i f y t he so lu t i on . Gentle heat ing can be used t o f a c i l - i i t a t e mixing o f t h e Emcol 4500.
Use Ins t ruc t i ons :
sht 0.0 9.0 0.1 0.5 0.4
Y.
Apply f i n i s h e d product t o a towe l l e te (Kimwipe, e t c . ) and wipe onto t h e glass. Al low t o dry.
Product Informat Product: Varox 365 Adogen 66 Emcol 4500
This formulat
on : Bene f i t : Wetting agent, degreaser. and detergent A n t i - s t a t i c agent Wetting agent, coupler, and detergent
on presents a t h i n b a r r i e r between the water vapor ( i . e . , fog, steam, e tc . ) and the glass which w i l l prevent fogging. The a b i l i t y t o lower the surface tens ion o f t he water prevents the c l i n g i n g o f i n d i v i d u a l water d rop le ts t o the glass; t he re fo re l i g h t i s not scat tered as much as i t i s when passing through i n d i v i d u a l droplets .
Formula 708
Annoniated Glass Cleaner
Water W i t c o l a te 231 0 Buty l Cel l oso l ve Aqua Ammonia, 26 Be'
% by Weight 94.0 3.0 2.0 2.0
Blending Procedure:
between each add i t i on .
Formula 704
SOURCE: Witco Corp.: Suggested Formulations
Blend ingredients i n the order shown, mixing thoroughly
Glass CleanersfPolbhes 53
Glass C1 eaners Ammon i a
Formula GC-0017
Water Rhodacal DSB Butoxyethanol Ammonium Hydroxide (28%) Dye
Economical Heavy-Duty Wt.% Wt.%
94.60 88.70 ~~
0.15 0.30 5.00 10.00 0.25 1 .oo - -
Procedu rQ Blend ingredients i n order l i s t e d and mix u n t i l uniform.
Phvsi ca 1 Prooer t ies Appearance: Clear l i q u i d , dye t o preference pH (as i s ) : 10.5 pH (1%): 9.0 Spec i f i c Grav i t y : 0.99 V iscos i t y : t10 cps
10.8 9.7 0.99
t10 cps
G1 ass C1 eaners Vinegar
Formula GC-0018
Water Rhodacal DSB Butoxyethanol Acet ic Acid Dye
Economical Heavv-Duty Wt.% Wt.%
94.85 89.70 0.15 0.30 5.00 10.00
To pH=4 To pH=4 - - Procedu rQ
Blend ingredients i n order l i s t e d and mix u n t i l uniform.
Physical Prooer t i eg Appearance: Clear l i q u i d , dye t o preference pH (as i s ) : 4.0 4.0 pH (1%): 3.5 3.5 Speci f i c Grav i ty : 0.99 0.99 V i scosl t y : t10 cps t10 cps
SOURCE: Rhone-Poulenc Surfactants 6 Spec ia l t i e r : Formulas
54 Advanced Cleaning Roduct Formulations
Glassware and B o t t l e Cleaners B o t t l e Cleaner (Alkaline-Powder)
Inaredi ents: Aerosol OT-8 Surfactant Sodium NTA Powder Cyanamer A-100L Polyacrylamide Sodi um Metasi 1 i cate Tetrasodium Pyrophosphate
B o t t l e Cleaner (Acid-Powder)
Inaredients : Aerosol OT-0 Surfactant NTA Acid Sodium Dihydrogen Phosphate Sodium Hydrogen Su l fa te
B o t t l e Cleaner (A1 k a l i ne-Powder)
Inaredients : Aerosol 0s Surfactant Aerosol OT-8 Surfactant Sodium NTA Powder Sodi um Metasi 1 i cate Tetrasodi um Pyrophosphate
% by Weiaht 2.0
2 0 . 0 5.0 8.0
65.0
% by Weiaht 2 . 0
2 0 . 0 58.0 20.0
% bv Weiaht 5-1 0 1- 2
20.0 8.0
60-66
B o t t l e C1 eaner ( A c i d-Li qu i d)
Inaredi ents: Aerosol GPG Surfactant Phosphoric Acid (85%) NTA Acid Water
% by Weiaht 5.0
t o pH 3.0 or l e s s 20.0 75.0
B o t t l e C1 eaner (Acid-Liqui d l
Inaredi ents: Aerosol 0s Surfactant NTA Acid Phosphoric Acid (85%) Water
% bv Weight 10.0 . .
20.0 t o pH 3.0 o r l ess
70.0
B o t t l e Cleaner (Hiahly Alka l ine) % bv Weiaht I naredi ents :
Aerosol 0s Surfactant 10.0 Aerosol 22 Surfactant 2.0 Sodium NTA 20.0 Sodi um Hydroxi de ( 1 0%) 68.0 SOURCE: Cytec Indus t r i es Inc. : Suggested Formulations
Glass CleanerslPolishes 55
Water, D . I . Isopropanol Varox 365 Methyl ene B1 ue
Household Window Cleaner
% by Weight 89.3 10.0 0.7 q . s .
Blending Procedure:
between each addi t ion.
Typical Proper t ies: V iscos i ty , cps: 4 Sol ids: 0.2% pH: 7.4
Add ingredients i n order shown and d isso lve completely
Formula 706
Prerni urn Household W i ndow C1 eaner
Water, D . I . Isopropanol Varox 1770 Methyl ene 81 ue
% by Weight 89.4 10.0
0 . 6 q . s .
Blending Procedure:
between each add i t i on .
Typical Propert ies: V i scos i t y , cps: 4 Sol ids: 0.23% pH: 6.2
Add ingredients i n order shown and d isso lve completely
Formula 707
SOURCE: Witco Corp.: Suggested Formulations
56 Advanced Cleaning Product Formulations
Low VOC An t i s ta t /C leaner f o r Glass
I n q r e d i e n t : Versaf 1 ex 7000 Isopropanol Ammonium Hydroxide (30%) Neodol 25-35 (58%) Water, Fragrance, and Prese rva t i ve
%w/w 1 . o o 5 .00 0.50 0.15
q . s .
Procedure: 1. D isso lve Versa f lex 7000 i n water. 2 . Add ammonium hydrox ide and Neodol 25-35, and mix. 3. Add isopropanol and mix. 4. Add f ragrance and p rese rva t i ve .
SOURCE: Na t iona l S tarch and Chemical Co.: Reference: #8069:32
A n t i -Fog G1 ass C1 g a s
I n q r e d i ents:_ Water Monawet MO-70R I PA
Procedure: Blend i n o rder l i s t e d and package.
% by We- 93.0
2.0 5.0
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formula t ion
G1 ass C1 eaner
Eastman EB so l ven t I sop ropy l a lcoho l Noni on i c s u r f a c t an t * Water
% by We- 3.0 5.0 0.1
91.9
*Such as T e r g i t o l 15-S-7, Cll-C15 secondary a lcoho l e t h o x y l a t e (Union Carbide) o r Genapol 24-L-60 l i n e a r a l coho l e thoxy la te (Hoechst Celanese).
SOURCE: Eastman Chemical Co.: Eastman EB and DB So lvents f o r Cleaners: Suggested Formula t ion
Glass CleaturslPolisks 57
Trad i t i ona l Consumer Glass Cleaner Ammoni ated Anionic Non-Streaki na G1 ass C1 eaner -
Inaredi ent : Wt.% Deionized Water 94.05 2-Butoxyethanol 5.70 Avanel S-70 0.25 C . I . D i r e c t Blue #86 Q.S. Monoethanol ami ne t o pH 10.5-11.5
pH (as i s ) : 10.5-11.5 Appearance: Clear, l i g h t - b l u e l i q u i d Odor: Sweet, ethereal
Charge under a g i t a t i o n most o f t he water, t h e 2-butoxyethanol. Procedure:
and the Avanel S-70 i n t o the mixing vessel. I n a separate vessel, under ag i ta t i on , d isso lve the dye i n the balance of t h e water. Add the dye so lu t i on t o t h e batch. Adjust p H t o 10.5-11.5 w i t h Monoethanolamine. Notes :
This formulat ion incorporates a novel anionic surfactant i n t o a t r a d i t i o n a l ammoniated glass cleaner.
On prolonged storage, g l yco l ethers have been shown t o form peroxy compounds which can adversely a f f e c t t h e dyes normally used i n glass cleaners. Morpholine, Ammonia, o r other v o l a t i l e amines may be used i n place o f t he Monoethanolamine. Formula CG-101
Consumer Aci d G1 ass C1 eaner Acid Anionic Non-Streaking Glass Cleaner
Ins red i ent : Wt.% Dei oni zed Water 89.70 2-Butoxyethanol 10.00 Avanel S-70 0.30 Color Q.S. Acet ic Acid t o p H 3.5-4.0
pH (as i s ) : 3.5-4.0 Appearance: Clear 1 i q u i d Odor: Sweet, ethereal
Charge under a g i t a t i o n most o f the water, t he 2-butoxyethanol, Procedure:
and the Avanel S-70 i n t o the mixing vessel. I n a separate vessel, under ag i ta t i on , d isso lve the dye i n t h e balance o f the water. Add t h e dye so lu t i on t o t h e batch. Adjust p H t o 3.5-4.0 w i t h Acet ic Acid. Notes:
This formulat ion i s p a r t i c u l a r l y e f f e c t i v e a t removing o i l . greases and other atmospheric contaminants from glass surfaces.
On prolonged storage, g l yco l ethers have been shown t o form peroxy compounds which can adversely a f f e c t t h e dyes normally used i n glass cleaners. Dyes should be thoroughly screened f o r s h e l f s t a b i l i t y i n the f i n i s h e d product p r i o r t o adoption i n t o the f i n i shed formulat ion. Formula CG-102
SOURCE: Mazer Chemicals: Suggested Formulations
7. Hard Surface Cleaners
58
Hard swface Cleaners 59
Abrasive Cleaner-1
Ina red ien ts : A Hostapur SAS 60
Genapol UD-030 B Water (40-5OC) C Preserva t ive
D C a l i b r i t e SL Tests:
Perfume
V i s c o s i t y (mPas): 1700 ( B r o o k f i e l d RVT) pH: 1 0 , O
Abrasive C1 eaner-2
1.n q red i en t s : A Hostapur SAS 60
Genapol UD-030 B Water (40-50C) C Preserva t ive
Perfume D C a l i b r i t e SL Tests:
V i s c o s i t y (mPas): 2800 ( B r o o k f i e l d RVT) pH: 1 0 , O
Abrasive C1 eaner-3
Ins red ien ts : A Hostapur SAS 60
Genapol UD-030
B Water (40-5OC)
C Preserva t ive Perfume
D C a l i b r i t e SL
4.50% 5.40%
59.00% 0.10% 0.20%
30.00%
4.50% 5.40%
49.00% 0.10% 0.20%
40.00%
4.50% 5.40%
39.00%
0.10% 0.20%
50.00%
Tests:
Manufactur ing( l ,2,3): I One a f t e r another, t h e components o f A a re added t o 0. I1 A t 30C t h e components o f C a re added t o I. I11 A t l a s t , s t i r D to 11.
any longer . Modern l i q u i d products a re based on ca lc ium carbonate.
SOURCE: Hoechst Ak t i engese l l scha f t : Detergents and Cleaning
V i s c o s i t y (mPas) : 6400 (Brookf i e l d RVT) pH: 1 0 , O O
Abrasive powders, based on s i l i c i u m dioxyde a re no t common
Agents: Guide Formulat ions
60 Advanced Cleaning product Forrnulaiions
Concentrated L i q u i d Household Hard-surface Cleaner P i ne O i 1 A1 1-Purpose D i l u t a b l e Concentrate
Inaredi ent : Dei oni zed Water Macol TD-12 Macol TD-3 Mazamide 80 Macol 40 Pine O i l Tetrapotassium Pyrophosphate Sodium Metas i l i ca te Pentahydrate Sodium Xylene Sul fonate (40%)
Wt.96 79.30 5.00 2.50 0.50 4.00 0.20 3.00 2.00 3.50
pH (as i s ) : 12.5-13.5 Appearance: Clear, l i g h t - y e l l o w l i q u i d Speci f i c Grav i ty : 1 .03
Procedure: Charge the water t o a mixing vessel and s t a r t a g i t a t i o n .
Charge t h e Macol TD-12, Macol TD-3. and Macol 48 and m i x u n t i l product i s c lea r and f r e e o f " f i s h eyes." Charge t h e Pine O i l and mix 5 minutes. Charge t h e remaining ingredients and mix u n t i l c l e a r . Notes:
This i s a concentrated household hard-surface cleaner designed t o be used a t a d i l u t i o n o f 1-3 ounces per ga l lon. Formula CH-103
All-PurDose Household Spray Cleaner Ready t o Use A lka l i ne Hard Surface Spray Cleaner
Ineredi ent : Dei oni zed Water Macol TD-12 Sodi um C i t r a t e Tetrapotassium Pyrophosphate Macol 48
Wt.96 95.15
1 .oo 0.25 0.60 3.00
pH (as i s ) : 9.5-10.5 Appearance: Clear, water-white l i q u i d Spec i f i c Grav i ty : 0.99
Charge the water t o a mixing vessel and s t a r t a g i t a t i o n . Procedure:
Charge t h e Macol TD-12 and mix u n t i l d issolved and f r e e o f " f i s h eyes.'' Charge the remaining ingredients and m i x u n t i l c l e a r . Notes :
This i s an al l -purpose household cleaner designed t o be used "as i s " from a spray b o t t l e . Formula CH-104
SOURCE: Mazer Chemicals: Suggested Formulations
Hard Surface Cleaners 61
Consumer T i 1 e C1 eaner A Hard Surface Hypochlor i te Spray Cleaner
Inpredient : Dei oni zed Water Sodium Hydroxide (50%) Sodium Hypochlor i te (12.5%) Avanel S-70
Wt.% 81 .OO
2.00 18.00 1 .oo
pH (as i s ) : >12.5 Appearance: Clear, water-white t o l i g h t - y e l l o w l i q u i d
Charge t h e ingredients w i t h a g i t a t i o n i n t h e order l i s t e d .
This formula i s s u i t a b l e f o r pump spray app l i ca t i on . I t can
Shel f s t a b i l i t y o f ch lo r i ne cleaners i s dependent on t h e
Formula may be adjusted t o use other commercially ava i l ab le
Procedure:
Notes :
be used on shower t i l e s and l i k e surfaces.
absence o f t race metals. Care should be taken t o insure good q u a l i t y water and Sodium Hypochlor i te.
concentrat ions o f Sodium Hypochlor i te. Absolute concentrat ion o f ava i l ab le c h l o r i n e i s 2.0%. Formula CC-101
I n d u s t r i a l Strenath Chlor ine Cleaner A Hard Surface I n d u s t r i a l Strength Hypochlor i te Spray Cleaner
Inaredient : Deionized Water Sodium Hydroxide (50%) Sodium Hypochlor i te (12.5%) Avanel S-70
Wt.Sb 56 .00
3 . 0 0 40.00
1 .oo
pH (as i s ) : >12.5 Appearance: Clear, water-white t o l i gh t - ye l l ow l i q u i d Odor: Chlor ine
Procedure: Charge t h e ingredients w i t h a g i t a t i o n i n t h e order l i s t e d .
Notes : This formulat ion can be used i n high-pressure spray washing
cleaners, d i l u t e d f o r hard-surface c leaning o r used as i s f o r an enhanced consumer household bleach.
Shel f s t a b i l i t y o f ch lo r i ne cleaners i s dependent on the absence o f t race metals. Care should be taken t o insure good qua1 i t y water and Sodi um Hypochlori t e .
concentrat ions o f Sodium Hypochlorite. Absolute concentrat ion of ava i l ab le ch lo r i ne i s 5.0%. Formula CC-102 SOURCE: Mazer Chemicals: Suggested Formulations
Formula may be adjusted t o use other commercially ava i l ab le
62 Advanced Cleaning Roduct Formulations
D-Limonene Hard-surface Cleaners Formula HS-0093
D-Limonene Concentrate
Component Wt.% D-Li monene 20.0 Alcodet HSC-1000 30.0 Igepa l CO-720 30.0 Mi rano l FBS 19.0 Tr iethanolamine 1 . o Water ---
Al l -Purpose Spray C1 eaner
Type (1 :9 D i l u t i o n )
Wt.% 2.0 3.0 3.0 1.9 0 .1
90.0
Heavy-Duty Degreaser Type (1 :3 D i l u t i o n )
Wt.% 5.0 7.5 7.5 4.75 0.25
75.0
Procedu r e A. Concentrate Blend i n g r e d i e n t s i n o rder l i s t e d and mix
u n t i 1 uni form. B. SDrav Cleaner D i l u t e concent ra te 1:9 w i t h water or charge
"Vessel A" w i t h D-Limonene, Alcodet HSC-1000, and then Igepa l CQ-720. Mix u n t i l uni form. Charge a separate "Vessel B" w i t h water, t r i e thano lamine and M i rano l FBS. Mix u n t i l uni form. F i n a l l y , add t h e conten ts o f "Vessel A" t o "Vessel B" and mix u n t i l un i fo rm.
C.DeQreaSer D i l u t e concent ra te 1:3 w i t h water or b lend i n g r e d i e n t s i n t h e same manner as s p e c i f i e d i n t h e spray c leaner procedure.
Phvsi c a l P r o o e r t i es
Appearance Clear, go ld Clear, l i g h t Clear, Concentrate S w a y Cleaner DegreaSer
l i q u i d ye l l ow l i q u i d ye l l ow l i q u i d S p e c i f i c G r a v i t y 1.02 1 .oo 1 .oo V i s c o s i t y 110 cps <10 cps <10 cps pH. as i s 10.0 9.5 9.5
SOURCE: Rhone-Poulenc Sur fac tan ts & Spec ia l t l ea : Formulas
Hard Surface Cleaners 63
d ' l i aonene SDrav Cleaner
Phase A: Water, D . I . Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e , Anhydrous Pet ro LBA L i q u i d W i t conate AOS
Phase B: DeSonic 9N W i tcami de 128T d ' L i monene*
% bv Weiaht
68.0 6 .0 2.0
10.0 3.0
5.0 3.0 3.0
*Sunkist Growers, I n c . o r Union Camp
Blending Procedure:
speed, add Phase B t o Phase A.
Use D i l u t i o n : use as i s .
Formula 802
Blend Phase A and Phase B separa te ly . W i t h mixer a t h igh
~- d'Lirnonene Cleaner Concentrate
Phase I: Isopropanol O l e i c Ac id Varonic K205 d ' L i monene
Phase 11: Water, D . I . Potassium Hydroxide, 87%
% by Weiaht
10.0 8.8 5.0
12.0
62.2 2.0
Blending Procedure:
I 1 ing red ien ts and mix thoroughly. Whi le mixing, add Phase I t o Phase 11.
Typ ica l P roper t i es : V i scos i t y , cps: 75 So l i ds : 13.8% pH: 10.2
Formula 808
SOURCE: Witco Corp.: Suggested Formulat ions
Combine Phase I ingred ien ts and mix thorough ly . Combine Phase
64 Advanced Cleaning product Formulations
General Purpose Hard Surface Cleaner
This general purpose cleaner i s a v e r s a t i l e product. The combination o f Sandoxylate SX-408 and Sandoxylate SX-424 provide excel lent surface a c t i v i t y and s o i l removal a l lowing i t t o be used i n many app l i ca t i ons .
Inaredi ents: Water Sodi urn S i 1 i cate Sodium Hydroxide (20% Solut ion) Buty l C e l l osol ve Sandoxylate SX-408 Sandoxylate SX-424 Sodium Xylene Sul fonate Drimarine Turquoise XB
% bv W t 79.9
1 .o 0.5 0.5 5.0
11.5 1.5 0.1
Procedure:
i d e (20%), Buty l Cel losolve, Sandoxylate SX-408. Sandoxylate SX-424, Sodium Xylene Sul fonate and Drimarine Turquoise XB.
Charge vessel w i t h water. Add sodium s i l i c a t e , sodium hydrox-
Suggested Use: 4 t o 6 ounces per ga l l on o f water.
SOURCE: Sandoz Chemical s Corp. : Formul a t i on HHG-11
A l k a l i n e Hard Surface Cleaner
Water, D.I. Sodium Metas i l i ca te Varami de A-83 Witconate 30DS W i tconate SXS L iqu id
% by Weiaht 34.0
8.0 12.0 40.0 6.0
Blending Procedure:
each add i t i on .
Typical Propert ies: V iscos i ty , cps: 205 Sol ids: 34.4% pH: 12.5
Add ingredients i n order shown and d isso lve completely between
SOURCE: Wltco Corp.: Formula 5 1 6
Hard swface Cleaners 65
General Puroose Hard-surface Cleaners Formula HS-0034
Comoonent
Water Sodi um Metasi 1 i ca te
Pentahydrate Rhodasurf 91-6 Cheelox BF-13 Mi rano l FBS Rhodaf ac RA-600 Butoxyethanol
Solvent-Free Non-Phosphate
IYPe Wt.% 83.5
2.0 7.5 3.0 4.0 -
Solvent-Free Phosphate m Wt.% 85.5
2.0 7.5 3.0
2.0 - -
Heavy-Duty Sol vent
I Y P S Wt.% 83.0
I . o 6.0 2.0 2.0
6.0 -
Procedure
Phvsi c a l P r o o e r t i 8s
Blend i n g r e d i e n t s i n o rder l i s t e d and mix u n t i l uni form.
Appearance C1 ear, C1 ear, C1 ear,
S p e c i f i c G r a v i t y 1.035 1.012 0.994 V i s c o s i t y <I0 cps <I0 cps <I0 cps pH, as i s 12.3 11.85 12.20
It. ye l l ow water-whi te water-whi te
U n b u i l t . Hiah-Sudsina. Hard-surface Cleaner Formula HS-0036
Comoonent Water C a l s o f t F-90 Mi rano l FBS Sodi um S i 1 i c a t e Igepa l CO-710 A1 kami de DC-212/S M-Pyrol, N-methyl-2-pyrrol idone
Wt.% 79.7
5.3 3.0 5.5 1 .o 2.0 3 .5
Procedure 81 end i n g r e d i e n t s i n o rder l i s t e d and mix u n t i l un i fo rm.
TvDi c a l ProDer t i 88 Appearance: C1 ear, ye1 1 ow 1 i qu id V i s c o s i t y : t 1 0 cps pH, as i s : 9.85 S p e c i f i c Grav i t y : 1.07
SOURCE: Rhone-Poulenc Sur fac tan ts h S p e c i a l t i e s : Formulas
66 Advanced Cleaning Product Formulations
Hard-sur face C leaner
I n q r e d i e n t : L i q u i d C i t r i c Acid-50% (Haarman & Sodium h y d r o x i d e s o l u t i o n 50% N o n i o n i c s u r f a c t a n t (Neodol 25-9) Methy l C a r b i t o l s o l v e n t Sodi um x y l ene s u l f o n a t e Sodium carbonate P i n e o i 1 Water
Percent by Wei q h t Rei mer C o r p l - j 4 . 0
2 . 5 0 . 0 7 . 0 5 .0 3.0 0 . 3
70 .2
M i x t h e L i q u i d C i t r i c Acid-50% s o l u t i o n w i t h an equal volume o f water and n e u t r a l i z e by add ing sodium h y d r o x i d e . The neut - r a l i z a t i o n r e a c t i o n s h o u l d be done s l o w l y and c a u t i o u s l y under a g i t a t i o n , as t h e r e a c t i o n i s h i g h l y exo thermic . B lend t h e neut - r a l i z e d s o l u t i o n w i t h t h e n o n i o n i c s u r f a c t a n t , Methy l C a r b i t o l , sodium x y l e n e s u l f o n a t e and sodium carbonate . Add p i n e o i l l a s t .
M n - A b r a s i v e C l e a n s e r
I n g r ed i en t : L i q u i d C i t r i c Acid-50% (Haarman Sodium h y d r o x i d e s o l u t i o n 50% Xanthan gum Vegetab le gum (Veegum HS) Amphoter ic s u r f a c t a n t Noni o n i c s u r f a c t a n t Calc ium c a r b o n a t e (100 mesh) Water
Percent by Wet q h t & Reimer Corp. ) 6 . 0
3 .7 25.0
2 . 5 3.0 1 . 5
45.0 13.3
-~
Prepare a 1% s o l u t i o n o f xanthan gum w i t h t h e i n c l u s i o n o f a p r e s e r v a t i v e . S l o w l y add t h e v e g e t a b l e gum t o water and s t i r u n t i l t h o r o u g h l y h y d r a t e d . Add t h e c a l c i u m carbonate , f o l l o w e d by t h e amphoter ic s u r f a c t a n t , t h e n o n i o n i c s u r f a c t a n t and t h e xanthan gum s o l u t i o n .
SOURCE: Haarman 8, Reimer Corp . : Suggested F o r m u l a t i o n s
- Hard-Surf ace C leaner
Eastman DB s o l v e n t A n i o n i c s u r f a c t a n t * Na4 EDTA* * Ammoni um h y d r o x i d e (28%) Water
*Such as Rhodapex CO-433 (Rhone-Poulenc) * *Tet rasod ium ethylenediaminetetracetate (39%)
SOURCE: Eastman Chemical Co.: Suggested F o r m u l a t i o n
Yo by W t . 7 . 0 1 . o 1 .25 2 . 0
00.75
Hard swface Cleaners 67
Hard-surface Cleaner Al l -Surface Bathroom Acid Type
Formula BC-0005
M-Pyrol, N-Methyl-2-Pyrrolidone (ISP) Igepal CO-630 Hydroxyethylcel l u lose Phosphori c Acid Water Perfume and co lorants may be added.
W> 3 4 .0 1 .o 0.2 9.5
85.3
Procedure 1 . D i sperse hydroxyethylcel 1 ulose i n water. 2. I n a separate vessel, mix M-pyrol, Igepal CO-630 together.
Add hydroxyethylcellulose/water mixture. 3. Add ac id and mix thoroughly.
Phvsi ca l P r w e r t i gg pH (as i s ) : 2.0 pH (1%): 2.4 V iscos i t y : 30 cps Speci f i c Grav i ty : 1 .02
--Surface Cleaner Al l -Surface Bathroom Type
Formula BC-0006
Wt.% Water 70.5 I gepal CO-630 2.5 Cheel ox NTA-Na3 20.0 Sodi um Xylene Sul fonate 5.5 Sodi um Hydroxide 1.5 Perfume and co lorants added, as desired, rep lac ing water.
Procedure 1 . Dissolve Igepal CO-630 i n water. Add Cheelox NTA-Na3. 2 . Add sodium-xylene su l fonate and sodium hydroxide, mixing we l l
Physical P r w e r t i e s pH, as i s : 12.9 pH (1%): 11.4 V i scos i t y : 10 cps Spec i f i c Grav i ty : 1.05
a f t e r each addi t ion.
SOURCE: Rhone-Poulenc Surfactants 6 Specia l t ies: Formulas
68 Advanced Cleaning Product Formulotiotu
Hard Surface Cleaners
Calsuds, C a l s o f t and Calamide concentrates can be fo rmula ted t o c rea te power fu l , non-corrosive, non - f i lm ing c leaners f o r f l o o r s , woodwork, wa l l s , windows, counter tops, tubs, t i l e and s i m i l a r hard surfaces. Use l e v e l s : 1-4 oz. /gal o f water.
F l o o r Cleaner Products P i 1 o t Formula #HSC-003-01
Water Na4EDTA Ca lso f t F-90 Cal oxy l a t e N-9 B u t y l Ce l l oso l ve
Calsuds 81 TKPP P i l o t SXS-40 Water
Cal foam SLS-30 Calamide C Propyl ene G1 yco l Water
% by Weiaht 81 .OO 10.00 4.00 2.00 3.00
P i l o t Formula #HDC-003-01
% bv Weight 5.00 7.80
10.00 77.20
Rua Cleaner P i l o t Formula #CPT-003-01
% by Weiqht 40.09
4.04 20.11 35.76
P l a s t i c , V i n y l and Leather Cleaner P i l o t Formula #UPC-001-01
Ca loxy la te N-9 Dowanol D (PnB) Propyl ene G1 yco l B u t y l Ce l l oso l ve Water
SOURCE: P i l o t Chemical Co. : Household C1 eaner Formu
by Weight 10.10 5.02 2.56 1.13
81.19
a t i ons
Hard Surface Cleaners 69
Hard Surface Cleaners
Calsuds, C a l s o f t and Calamide concent ra tes can be fo rmula ted t o c r e a t e power fu l , non-corrosive, non - f i lm ing c leaners f o r f l o o r s , woodwork, w a l l s , windows, counter tops , t ubs , t i l e and s i m i l a r hard sur faces . Use l e v e l s : 1 -4 oz . /ga l . o f water.
Tub and T i l e Cleaners P i l o t Formula #APC-004-01
Water Versene 100 Calsuds A I sop ropy l Alcohol Propyl ene G1 yco l Pine O i 1
D-1 i monene Cal imul se PRS Ca loxy la te N-9 Water C a l s o f t L-40 P i l o t sxs-40 Calamide 0
Water TKPP Calsuds 81 P i l o t sxs-40
Water Ammonia (29%) Na4EDTA Bu ty l C e l l osol ve Calsuds 81
P i 1 o t Formula #HDC-006-01
Counter Top/Wall Cleaners P i l o t Formula #HDC-003-01
A l l Purpose Type
P i l o t Formula #HSC-008-01 Ammoniated T-
% bv Weiqht 65.00
1 . o o 25.00
5.00 3.00 1 .oo
?&by Wei a h t 30.00
5.00 5.00
26.50 16.50 10.00
7 . 0 0
% by Weight 77.20
7.80 5.00
10.00
% by Weiaht 86.50 3.00 0.50 5.00 5.00
SOURCE: P i lot Chemical Con : Household C1 eaner Formulat ions
70 Advanced Cleaning Product Formulations
Hard Surface Cleaner w/AmDhoteric
Water, 0.1. Sodium Carbonate Rewoteric AM KSF-40 Oowanol DPM Versene 100 Witconate SXS (40%)
% by Weinht 75.0
4.0 10.0 5.0 2.0 4.0
Blending Procedure:
each add i t i on .
Typi c a l Propert i es :
Add ingredients i n order shown and d isso lve completely between
Viscos i ty , cps: 4 Sol ids: 10.2% pH: 10.8
Formula 507
Hard Surface Cleaner Concentrate w/d'Lilnonene
Phase I: Isopropanol Ole ic Acid Varonic K205 d ' L i monene Phase 11: Water, 0.1. Potassium Hydroxide (87%)
% by Weiciht
10.0 8.8 5.0
12.0
62.2 2.0
B1 endi ng Procedure :
I 1 ingredients and mix thoroughly. While mixing, add Phase I t o Phase 11.
Typical Propert ies: V iscos i ty , cps: 75 Sol ids: 13.8% pn: 10.2
Combine Phase I ingredients and mix thoroughly. Combine Phase
Formula 508
SOURCE: Witco Corp.: Suggested Formulations
Hard Swface Cleaners 71
Hard-surface Cleaner Concentrate A lka l i ne All-Purpose Cleaner Concentrate
Inaredi ent : Deionized Water Sodium Hydroxide (50%) Tetrapotassium Pyrophosphate Sodium Metas i l i ca te Pentahydrate Avanel S-150 Sodium Cumene Sul fonate (40%)
Wt.% 76.00
2.00 12.00 1 .oo 6.00 3.00
pH (as i s ) : 10.5-11.5 Appearance: Clear, l i gh t - ye l l ow l i q u i d Spec i f i c Grav i ty : 1.13
Procedure: Charge the water t o an appropr iate mixing vessel and s t a r t
a a i t a t i o n . I n t h e sequence l i s t e d above, charge the remaining ingredients and mix u n t i l t he so lu t i on i s c lea r . Notes :
This i s a hard-surface cleaner concentrate which i s on many d i f f e r e n t s o i l s and surfaces. For concrete sur use "as i s . " For wal ls , f l o o r s , and other surfaces, d i 1O:l w i t h water. Formula CH-101
Household Hard-surface Cleaner All-Purpose A l k a l i n e Cleaner f o r Sponge o r Spray Apt
Inaredi ent : Deionized Water Sodium Laureth (3) Sul fa te Mazamide 00 Tetrapotassium Pyrophosphate Sodium Metas i l i ca te Pentahydrate Macol 40 Deionized Water, Dye, e tc .
pH (as i s ) : 12.0-13.0 Appearance: Clear, water-white l i q u i d (wi thout dye) Spec i f i c Grav i ty : 1.01
Procedure:
e f f e c t i ve aces, u te
I i ca t i on
Wt.% 80 .00
2.50 0.50 1 .oo 2.00 4.00
Q.S.
Charge the f i r s t p o r t i o n o f water t o a mixing vessel and s t a r t a g i t a t i o n . I f product i s t o be colored, d i sso l ve dye i n the reserved p o r t i o n o f the water i n a separate vessel. Charge a l l remaining ingredients , i nc lud ing t h e dye so lut ion, t o t h e mixing vessel and mix u n t i l c l ea r . Notes :
cleaner. The product may be used w i th a sponge o r may be used i n a spray b o t t l e . Formula CH-102
SOURCE: Mazer Chemicals: Suggested Formulations
This formulat ion i s designed as a general purpose household
72 Advanced Cleaning Roduct Formulations
Hiah-Performance. Hard-surface Cleaners Formula HS-0035
Component
Water Sodi um Metasi 1 i cate
Miranol FBS A1 codet HSC-1 000 Cheelox BF-13 Rhodafac RA-600 Butoxyethanol
Pentahydrate
6 . 0
Solvent-Free Solvent-Free Non-Phosphate Phosphate
IYPe IYIzz Wt.% Wt.% 88.0 87.0
2.0 2.0 3.0 1 . o 4.0 4.0 3.0 3.0 - 3 .0
- -
Heavy-Duty Solvent
TYDe Wt.% 85.0
2 .0 2 . 0 3 .0 2.0 -
Procedu r e
Physical ProDert ies
Blend ingredients i n order l i s t e d and mix u n t i l uniform.
Appearance Clear, l i g h t yel low l i q u i d pH, as i s 12.6 11.5 12.55 V iscos i t y <I0 cps Speci f i c Grav i t y 0.978 1.013 1.016
<I0 cps <10 cps
Econoai c a l P i ne O i 1 Hard-surface C1 eaner Formula HS-0037
Component Pine O i l Rhodasurf 0C-840 Water
Wt.% 5 . 0
10 .0 8 5 . 0
Procedu r e 1 . Add Rhodasurf BC-840 t o p ine o i l . Mix w e l l . Heat t o approx-
imate ly 35-40C t o ob ta in homogeneous so lu t i on . 2. Add water and mix thoroughly.
Physical Prooer t ies Appearance: Clear, water-white l i q u i d pH. as i s : 3.08 Spec i f i c Grav i ty : 0.99 V iscos i t y : <10 cps
SOURCE: Rhone-Poulenc Surfactants & Spec ia l t i es : Formulas
Hard swface Cleaners 73
M i l d Abras ive Hard Sur face Cleaner A m i l d abras ive c leaner f o r consumer use. E f f e c t i v e on
S t a i n l e s s S t e e l , Po rce la in and o the r hard sur faces .
P a r t : I n q r e d i e n t s : A Dei on i zed Water
C a l c i t e ( t100 mesh) Mazox LDA Potass i um C i t r a t e
B C a l s o f t F-90 Deionized Water
Appearance: White pas ty 1 i qu i d p H (as i s ) : 7.0-8.0 S p e c i f i c G r a v i t y : 1.47
Procedure:
charge t h e water and s t a r t a g i t a t i o n . Do no t i n t o t h e p roduc t . Slowly add t h e C a l c i t e f o l Mazox LDA and t h e Potassium C i t r a t e .
To a m ix ing vessel w i t h sweep and scrape
Wt.% 30.00 50.00
6.70 1 .oo
3.30 9 .00
ype a g i t a t i o n , mix a i r owed by t h e
I n a separate vesse l , d i s s o l v e t h e C a l s o f t F-90 i n t h e remaining water. When comple te ly d i sso l ved , add t h e f i r s t p a r t o f t h e mix. Again avo id m ix ing excess a i r i n t o t h e system.
Notes :
I t i s a m i l d abras ive hard su r face c leaner e f f e c t i v e aga ins t mast common s o i l s . I t can be used on s t a i n l e s s s t e e l , p o r c e l a i n and o the r hard surfaces.
I n t h e manufacture o f t h i s p roduc t , ca re should be taken t o avo id m ix ing a i r i n t o t h e f i n i s h e d p roduc t . Being a pas ty l i q u i d , once a i r i s en t ra ined i n t o t h e system, i t i s d i f f i c u l t and t i m e consuming t o remove.
SOURCE: Mazer Chemicals: Formula t ion CH-109
Th is f o r m u l a t i o n i s designed t o be used as i s by t h e consumer.
74 Advanced Cleaning Product Formulations
Non-Phosphate Household Hard-surface Cleaner All-Purpose A l k a l i n e Cleaner f o r Sponge or Spray App l i ca t i on
Inaredi ent : INt.% Dei oni zed Water 79.75 Sodi um Laureth Su l fa te 2.50 Mazamide 80 0.50 Sodi um C i t r a t e 1.25
Macol 40 4.00 Sodium Metas i l i ca te Pentahydrate 2.00
Deionized Water, Dye, e t c . a .s . pH (as i s ) : 12.0-13.0 Appearance: Clear, water-white l i q u i d (wi thout dye) Spec i f i c Grav i ty : 1 . O l
Procedure: Charge the f i r s t p o r t i o n o f water t o a mixing vessel and
s t a r t a g i t a t i o n . I f product i s t o be colored, add the dye t o reserved p o r t i o n o f t he water i n a separate vessel. Charge a l l remaining ingredients , i nc lud ing the dye so lut ion, t o the mixing vessel and mix u n t i l c l ea r . Notes :
This formulat ion i s a non-phosphate version o f formulat ion CH-102. This formulat ion i s designed as a general purpose household c leaner. The product may be used w i t h a sponge or may be used i n a spray vessel. Formula CH-106
Won-Phosphate Concentrated Household Hard-surface Cleaner Concentrated Pine O i l All-Purpose Cleaner
Inqredi ent : Wt.% Dei oni zed Water 78.05 Macol TD-12 5.00 Macol TD-3 2.50 Mazamide 00 0.50 Macol 40 4.50 Pine O i 1 0.20 Sodi um C i t r a t e 3.75 Sodium Metas i l i ca te Pentahydrate 2.00 Sodium Xylene Sul fonate (40%) 3.50
pH (as i s ) : 12.5-13.5 Appearance: Clear, l i g h t yel low l i q u i d Spec i f i c Grav i ty : 1.02
Procedure: Charge the water t o a mixing vessel and s t a r t a g i t a t i o n .
Charge the Macol TD-12, Macol TD-3, Mazamide 80 and Macol 48 and cont inue a g i t a t i o n . Charge the Pine O i l and mix 5 minutes. Charge the remaining ingredients and mix u n t i l c l ea r and f r e e o f "f i sh eyes. I' Notes :
This formulat ion i s a non-phosphate version o f formulat ion CH-103. This i s a concentrated household hard-surface cleaner designed t o be used a t a d i l u t i o n o f 1-3 ounces per ga l lon. Formula CH-107
SOURCE: Mazer Chemicals: Suggested Formulations
Hard Surface Cleaners 75
P i n e O i l C leaner C o n c e n t r a t e
~~ I n g r e d i en.Lsl P i n e 01 I N i n o l 11-CM Makon 12 Ammonyx LO
I s o p r o p a n o l Water, D.I.
B i o - S o f t S-100
% by W t . 20.0
9.0 5 . 0 0 . 5 2 . 0
10 .0 53.5
M i x i n g P rocedure :
w a t e r s l o w l y w h i l e under a g i t a t i o n . M i x u n t i l c l e a r .
P r o p e r t i e s :
Combine p i n e o i l , s u r f a c t a n t s and IPA. M ix u n t i l c l e a r . Add
Appearance: C l e a r y e l l o w l i q u i d Odor: P i n e V i s c o s i t y C 25C, c p s : 50 pH ( a s i s ) : 8 . 1 D e n s i t y l b s / g a l : 8 . 0 6 Freeze/Thaw ( 3 c y c l e s ) : Pass 50C oven ( 1 week): Pass
Use I n s t r u c t i o n s : D i l u t e 1-2 ozs i n t o one g a l l o n
Per formance: Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t :
Above f o r m u l a t i o n : 73.0% s o i l removed f r o m t i l e s Commercial p r o d u c t : 55.5% s o i l removed f r o m t i l e s
SOURCE: Stepan Co.: F o r m u l a t i o n No. 208
L i q u i d Super C o n c e n t r a t e
%_by Wei ght Water, D . I . 30.0 T e t r a p o t a s s i u m Pyrophosphate (60%) 25.0 B u t y l C e l l o s o l v e 5 .0 W i t c o n a t e SXS L i q u i d 10 .0 Varamide A-83 30.0
B l e n d i n g Procedure:
each add1 t i on.
T y p i c a l P r o p e r t i e s : S o l i d s : 49.0%
SOURCE: W i t c o Corp. : Formula 502
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
8. Laundry Products
76
Anionic/Nonionic Heavy-Duty Laundry Deteraent Formula LY-0042
Water Ca lso f t F-90 Rhodasurf 25-7 Rhodacal A-246/L Sodi um C i t r a t e Br ightener Fragrance Dye
Wt.% 63
5 7
15 10
Q.S. Q.S. Q . S .
Procedu rg
a g i t a t i o n . Then, add Rhodasurf A-246/L and Calsof t F-90. Begin coo l i ng and add remaining ingredients s ing l y , w i t h a g i t a t i o n t o ob ta in uni form mixture, before making next add i t i on .
Phveical ProDert 1 ea Appearance: C1 ear 1 i quid, dyed t o preference pH. as i s : 7.4 Spec i f i c Grav i ty : 1.09 V iscos i t y : 200 cps
Heat water t o 60C. Add Rhodasurf 25-7 s lowly, w i t h moderate
Anionic/Nonionic Heavy-Duty Laundry Deteraent Formula LY-0043
Par t A Water Na C i t r a t e Calsof t F-90 l!artJ! Rhodasurf 25-7 MEA sxs Par t C Colorant Perfume Water Procedu rg
Dissolve Sodi um C i t r a t e add Ca lso f t F-90. Mix Part "B" . Add co lorant , perfume
Phvs f ca 1 Prooer t ies pH: 11.0 pH (1% Solut ion) : 9.50 Spec i f i c Grav i ty : 1.120 V iscos i t y : 75 cps
30.0 8 . 0
17.0
8 . 0 2.0 6.0
0.02-1 0.1-0.5
Q . S .
i n water by s t i r r i n g a t 45-50C and
and water. Adjust pH t o 11.0. i n the order l i s t e d . Add "A" t o llgll
SOURCE: Rhone-Poulenc Surfactants 6 Specia l t ies: Formulas
Laundry Products 77
78 Advanced Cleaning Product Formulations
Anionic/Nonionic Heavy-Duty Laundry Deteraent Formula LY-0044
Par t A Water Na C i t r a t e Calsof t F-90
P a r t B Rhodasurf 25-7 MEA sxs
Part C Colorant Perfume Water
Wt.% 30.0 8.0 17.0
8 . 0 2.0 6 . 0
0.02-1 0.1- 0.5
Q . S .
Procedure Dissolve sodium c i t r a t e i n water by s t i r r i n g a t 45C-5OC.
add Ca lso f t F-90. Mix Part "B" i n the order l i s t e d . Add "A" t o "8" . Add co lorant , perfume and water. Adjust pH t o 11.0.
Nonionic/Amphoteric Heavy-Duty Laundry L i q u i d Formula LY-0045
Water G1 ycosi des Miranol FBS MEA Colorant Perf ume '
Wt.% Q.S.
20.0 7 . 0 2 . 0
0.02-1 0.1 -0.5
Procedure
each add i t i on . Adjust pH t o 11.0. Add the ingredients i n the order l i s t e d . M i x wel l a f t e r
Phvsi c a l P r o m r t i eg pH: 11.0 pH (1% Solut ion) : 9.50 Spec i f i c Grav i ty : 1 .lo0 Viscos i ty : 300 cps
SOURCE: Rhone-Poulenc Surfactants & Spec ia l t i es : Formulas
Cold Water Deterpent JFor W o o l and De l i ca te Fabr ics)
Formula LY-0040
Water Miranol CS Conc. Rhodapex ES-2 A1 kami de DC-212 Fluorescent Whitening Agent
Wt.% 55.9 10.0 30.0
4 . 0 0.1
Procedu r Q
c l e a r .
Phvsi c a l Proner t i 8s
Add ingredients i n order l i s t e d . Heat t o 50C and mix u n t i l
Appearance: Clear, yel low l i q u i d pH. as i s : 8.16 Spec i f i c Grav i ty : 1.02 V iscos i t y : 700 cps
F i ne Fabr ic Deterpent Formula LY-0041
Rhodacal DS-10 Sodium Hexametaphosphate Sodium Bicarbonate Opt ica l Br ightener
Wt.% 32.0 30.0 38.0
P.S.
Procedu re
t o t h e blender. Mix f i v e minutes. Add the Rhodacal DS-10 w i t h mixing. Add the o p t i c a l br ightener w i t h mixing. Mix u n t i l uniform.
Phvaical Prooer t i e s
Add the sodium bicarbonate and the sodium hexametaphosphate
Appearance: White, f ree- f lowing powder pH, 1% Solut ion: 8.5
SOURCE: Rhone-Poulenc Surfactants & Specia l t ies: Formulas
Laundry Products 79
80 Advanced Cleaning Product Formulations
Deteraent f o r Colored Fabr ics . Powder, Spray M ix inQ Process-A
Spray Mix : M a r l i p a l 24/939 o r 013/939 Fragrance O p t i c a l b r i g h t e n e r
B u i l d e r Mix : Z e o l i t e A Sodium m e t a s i l i c a t e pen tahyd r i t e Sodium carbonate, dehydrated Carboxymethyl c e l l u lose Po lycarboxy la te , e.g. Sokalan CP 5 powder Sodi um s u l phate 1 i gh t
A c t i v e ma t te r : 9.0%
% 10.0 0.2 0 . 2
35.0 5 . 0
15.0 2.0 4.0
t o 100
Detergent f o r Colored Fabr ics, Powder, Spray M j x i n ~ Pro_cess-B
Spray M i x : M a r l i p a l 24/30 Marl i p a l 24/90 Fragrance O p t i c a l b r i gh tener
B u i l d e r Mix : Marlon ARL Z e o l i t e A Sodium soap powder Sodium m e t a s i l i c a t e pentahydrate Sodium carbonate, dehydrated Po lycarboxy la te , e.g. Sokalan CP 5 powder P o l y v i n y l p y r r o l i d o n e , e.g. Sokalan HP 50 Sodium su lphate l i g h t
% 2.0 4.0 0 . 2 0 . 2
10.0 40.0
4 .0 5.0
15.0 4 . 0 2 . 0
t o 100
A c t i v e ma t te r : 14.0%
SOURCE: Hu ls America, I n c . : Bas ic Formulat ions o f Detergents and Cleaning Agents f o r Household Purposes
Detergent for Cur ta ins , Medium V i s c o s i t v - A
% M a r l i n a t DFK 30 20.0 Marl i pa l 24/70 15.0 Coconut f a t t y ac id , potassium s a l t 5.0 Ethylenedi ami ne t e t r a a c e t a t e 40 0.2 Balance water, f ragrance, d y e s t u f f , o p t i c a l b r i gh tener ,
p reserva t i ve t o 100
A c t i v e ma t te r : 26.0%
Detergent f o r Cur ta ins , Medium V iscos i t v -8
% Marlon PS 65 10.0 Marlox M 606/1 15.0 Ethylenediamine t e t r a a c e t a t e 40 0.2 Balance water, f ragrance, dyes tu f f , o p t i c a l b r i gh tener , p rese rva t i ve t o 100
A c t i v e mat te r : 20.7%
Manual -Wash Detergent, Foaming Medi um V i scos i t y - A
% Marlon PS 65 10.0 M a r l i p a l 013/70 15.0 Marlamid DF 1218 2.5 Na cumene sulphonate, 40% 1 .o Ethanol * 1.5 Balance water, f ragrance, dyes tu f f , p reserva t ive ,
sodium c h l o r i d e t o 100
A c t i v e mat te r : 24.0%
Manual-Wash Detergent. Foaming Medium V iscos i ty -B
%
Marl i na t 242/28 12.0
sodium c h l o r i d e t o 100
Marlon A 365 18.5
Balance water, f ragrance, d y e s t u f f , p rese rva t i ve ,
A c t i v e mat te r : 15.3%
SOURCE: Huls America, I nc . : Basic Formulat ions o f Detergents and Cleaning Agents f o r Household Purposes
Laundry Products 81
82 Advanced Cleaning Product Formulations
Detergent f o r F ine Fabr ics-1 L i q u i d
I n red ien ts : i ? F a t t y a c i d (Cocos + Olein. P r i f a c 7976)
KOH (85%) H20 (40-50C)
B Hostapur SAS 60 Genapol ZRO l i q u i d Genapol UD-080
3.00% 0.60% 41.90%
23.30% 25.00%
6.00%
C C i t r i c a c i d x 1H20 0.20%
Manufactur ing: I One a f t e r another, t h e components o f B a re added t o A . I 1 A t l a s t C i s added.
Deteraent f o r F ine Fabr ics-2
m r e d i e n t s : A F a t t y a c i d (Cocos + O le in , P r i f a c 7976) 4.00%
KOH (85%) 0 . 8 0 % H20 (40-5OC) 63.00%
8 Hostapur SAS 60 Genapol UO-080
a. 00% 24.00%
C C i t r i c a c i d x 1H20 0.20%
Manufactur ing: I One a f t e r another, t h e components o f B a re added t o A. I 1 A t l a s t C i s added.
SOURCE: Hoechst Ak t i engese l l scha f t : Detergents and Cleaning Agents: Guide Formulat ions
Laundry Products 83
Enzymatic Heavy-Duty Laundry Deteraent Formula LY-0046
P a r t A Water C i t r a t e C a l s o f t F-90 P a r t Rhodasurf 25-7 M EA TEA sxs Rhodapex NA 61 P a r t C Na Formate Calcium Ch lo r ide Enzymes Co loran t Perfume Water
Wt.% 10.0
5.0 8.0
6.0 2.0 2.0 3.0 8.0
1.2 0.2 0.4
0.02-1 0.1 - 0 . 8
Q.S.
Procedure
C a l s o f t F-90. Mix Par t "B" i n t h e o r e r l i s t e d . Add "A" t o "B". Add sodium formate and ca lc ium chlOP & e. Cool t o room temper- a tu re . Add t h e enzymes. Add co lo raa t , perfume and water. Ad jus t pH t o 10.0. Phvsi c a l P r o o e r t i
pH: 10.0 pH (1% S o l u t i o n ) : 8.8 Speci f i c G r a v i t y : 1 . l o 0 V i s c o s i t y : 100 cps
D isso lve sodium c i t r a t e i n water by s t i r r i n g a t 45-5OC. add
Won-Phosphate Laundry Powder Formula LY-0048
Sodium Carbonate Igepa l CO-630 Sodi um S i 1 i ca te Sodium S u l f a t e Carboxymethyl c e l l u l ose O p t i c a l Br igh tener
Wt.% 50.0 12.0 12.0 24.5
1 .o 0 .5
Procedu r g Add t h e sodium carbonate t o t h e mixer . Spray t h e Igepa l
02-630 on to t h e sodium carbonate. Add t h e remaining i ng red ien ts i n t h e order l i s t e d . Mix u n t i l a homogeneous, f r e e - f l o w i n g product r e s u l t s . Phvsi c a l P r o m r t 1 os
Appearance: White, f r e e - f l o w i n g powder pH, 1% So lu t i on : 11.0
SOURCE: Rhone-Poulrnc Sur fac tan ta & S p e c i a l t i e s : Formulas
84 Advanced Cleaning product Formulations
Fabr i c Pretreatment S p r i t z
I ng red ien ts : Neodol 25-7 Neodol 25-3 Versa f lex 207 (25%) Sodium Xylene Su l fona te (40%) EDTA, Disodium S a l t Water, Dye, Perfume, and Enzymes
Procedure: 1. Mix me l ted Neodol 25-7 and Neodol 25-3. 2. Add sodium xylene su l fona te and mix. 3. Add water and Versa f lex 207, mix, and coo l . 4. Add EDTA. dye, perfume, and enzymes.
Reference #8069:21
Low VOC Pump F a b r i c Antist-
I ns red ien ts : Versaf 1 ex 2004 (30%) Ethanol Propyl ene G1 yco l Preserva t ive , Water, and Fragrance
9.75 5.25
20.00 15.00
0.50 4.s.
%%. 5.00
10.00 0.50
Q . S .
Procedure: 1. Mix Versa f lex 2004 and water. 2. Add ethanol and mix. 3. Add p ropy l ene g l y c o l , p rese rva t i ve , and fragrance. and mix.
Reference #8069:97
SOURCE: Nat iona l S t rach and Chemical Corp.: Suggested Formula- t i o n s
Laundrv Pre-Spotter and S t a i n Remover
Water Sodium Meta S i l i c a t e (Anhydrous) Detergent Concentrate 840
% by Weiaht 83.0
2.0 15.0
Procedure:
p rese rva t i ve as requ i red.
SOURCE: Mona I n d u s t r i e s , I nc . : Suggested Formulat ion
Blend i n g r e d i e n t s i n o rder l i s t e d . Add c o l o r , f ragrance and
Fabr i c Softener-1
Ing red ien ts : A H20 (50-6OC)
B Prapagen WK
C MgC12 (10% b . w . )
D Perfume Dye
ad 100.00%
6.70%
0.10%
0.20% q . s .
Fabr i c Softener-2
Ing red ien ts : A Genamin S-250
H3P04 (1 M; 9,5% b . w . ) H 2 0 (50-60C)
8 Prapagen WK
C MgClP (10% b . w . )
D Perfume Dye
Fabr i c Softener-3
Inq red ien ts : A Genamin 5-250 0.90%
H3P04 (1 M; 9,5% b . w . ) 0.45% H20 (50-6OC) ad 100.00%
8 Prapagen WK 13.80% Po lyg l yko l 400 3.70%
C MgClZ (10% b . w . 1 1 .OO%
0 Perfume 0.60% Dye q . s .
Manufactur ing: I One a f t e r another, t h e components o f B are added t o A. I 1 A t 40C, a d j u s t t h e v i s c o s i t y w i t h C (ca. 100-150 mPas). I11 A t 30C the-components o f D a re added.
Appl i c a t i on :
SOURCE: Hoechst Ak t i engese l l scha f t : Detergents and C
1.0-2.0 g a c t i v e i ng red ien t / kg t e x t i l e
Agents: Guide Formulat ions
2.00% 1.00%
ad 100.00%
17.30%
3.00%
0.60% Q . S .
eani ng
Laundry Products 85
86 Advanced Cleaning Product Formulatiom
Fabr ic Softener. Low V i scosi tv-A
Mar losof t IQ 90 Balance water, fragrance, dyestuf f
Act ive matter: 5.0%
Fabr ic Softener. Low V i scosi ty-B
Marlosoft IQ 90 Balance water, fragrance, dyes tu f f
Act ive matter: 7.5%
% 5 . 6
t o 100
% 8.3
t o 100
Fabr ic Softener Concentrate. Low Viscosity-A
Marlosoft IQ 90 Calcium chlor ide, 25% (approx.) Balance water, fragrance, dyes tu f f
Act ive matter: 10.0% Formulation A : double concentrate
% 11.1 0.1
t o 100
Fabr ic Softener Concentrate. Low Viscosi ty-B
Mar losof t IQ 90 Calcium ch lo r i de , 25% (approx.) Balance water, fragrance, dyes tu f f
% 16.7
1.1 t o 100
Act ive matter: 15.0% Formulation 8: t r i p l e concentrate
SOURCE: Huls America, I nc . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
Heavy-dutv Detergent, Powder, SDrav Y i x i n a Process-A
Spray Mix: M a r l i p a l 24/70 o r 013/70 O p t i c a l b r i gh tener Ethylenediamine te t raace ta te . 40% Fragrance
% 4.0 0.2 0 . 8 0.2
B u i l d e r M i x : Marlon ARL Sodium soap powder Z e o l i t e A Sodium m e t a s i l i c a t e pentahydrate Sodium perbora te te t rahyd ra te Te t raace ty l e thy lened i ami ne (TAED) Sodium carbonate Polycarboxylate, e.g. Sokalan CP 5 Carboxymethyl c e l l u l o s e Sodium sulphate l i g h t , enzymes
A c t i v e mat te r : 13.2%
powder
8 . 0 2.8
25.0 5.0
20.0 3.0
10.0 4.0 1 .o
t o 100
Heavy-Duty Detergent. Powder, Soray M ix ing Process-8
Spray Mix: M a r l i p a l 24/70 o r 013/70 O p t i c a l b r i gh tener Ethylenediamine te t raace ta te , 40% Fragrance
% 4.0 0.2 0 . 8 0.2
B u i l d e r Mix: Marlon ARL Sodium soap powder Sodium t r i polyphosphate Sodium d i s i l i c a t e Sodi um perbora te te t rahyd ra te Tetraacetyethylenediamine (TAED) Carboxymethyl c e l l u l o s e Sodium sulphate l i g h t , enzymes
8 . 0 3.0
30.0 9.0
20.0 3.0 1 .o
t o 100
A c t i v e mat te r : 13.4%
SOURCE: Huls America, I n c . : Basic Formulat ions o f Detergents and Cleaning Agents f o r Household Purposes
Laundry Products 87
88 Advanced Cleaning Roduct Formulations
Heavy-Duty Deteraent. Powder. Sprav Mix ing Process-A
Spray Mix: Mar l i pa l 013/939 o r 24/939 Fragrance Ethylenediamine te t raacetate. 40% Opt ica l br ightener
Bui lder Mix: Z e o l i t e A Sodium metas i l i ca te pentahydrate Magnesi um s i l i cate Sodium perborate te t rahydrate Tetraacetylethylenedi ami ne (TAED) Sodi um carbonate Carboxymethyl c e l l u l o s e Sodium sulphate l i g h t , enzymes
Act ive matter: 9.0%
E! 10.0 0.2 1 .o 0.2
30.0 5.0 1 .o
25.0 3.0
15.0 1.5
t o 100
Heavy-Duty Deteraent. Powder. Sprav Mix ing Process-8
Spray Mix: Mar l i pa l 013/939 o r 24/939 Fragrance Opt ica l br ightener
Bui lder Mix: Sodium tr ipolyphosphate Sodi um d i s i 1 i cate Magnesi um s i 1 i cate Sodium perborate te t rahydrate Tetraacetylethylenediamine (TAED) Carboxymethyl c e l l u l o s e Sodium sulphate l i g h t , enzymes
Act ive matter: 9.0%
E! 10.0 0.2 0.2
28.0 5.0 1 .o
25.0 3.0 1 .o
t o 100
L i a u i d Heavy-Duty Deteraent. B u i l t Tvoe. Hieh Viscosi ty-A
% Marlon PS 65 10.0 Mar l i pa l 013/30 5.0 1,2-Propylene g l y c o l * 5.0 C i t r i c ac id 2.0 Z e o l i t e A, 50% s l u r r y 45.0 Balance water, fragrance, dyestuf f , o p t i c a l br ightener , enzymes, preservat ive t o 100
Act ive matter: 11.5% + f u r t h e r products o f Huls AG
SOURCE: Hula America, I nc . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
Heavy D u t y L i a u i d Laundry Deterqent Type DN
I n q r e d i en ts : Stepan B i o S o f t D-62 ( a n i o n i c s u r f a c t a n t ) Neodol 25-7 (non ion i c s u r f a c t a n t ) Propyl ene g l y c o l E t h y l a l coho l Sodium C i t r a t e (Haarman & Reimer) Sodium xy lene s u l f o n a t e Sodium bo ra te (borax) T r i ethanol ami ne (TEA) o r sodi um hydrox ide
Par t s by Weiqht 7.0
16.0 7 .0 5.0 5.0
10 .0 1 . o
t o pH 9 .5
D isso lve the Sodium C i t r a t e and sodium bo ra te i n approxim- a t e l y 20 m l water. Apply heat i f necessary t o d i s s o l v e . Combine t h e s u r f a c t a n t s , p ropy lene g l y c o l and e t h y l a l c o h o l . Add t h e Sodium C i t r a t e and sodium bo ra te s o l u t i o n t o t h e s u r f a c t a n t s m ix tu re . Add t h e sodium xy lene s u l f o n a t e . Ad jus t t h e pH t o 9 .5 us ing TEA o r d i l u t e sodium hydroxide. B r i n g t h e volume o f t h e m i x t u r e t o 100 m l us ing water.
I f an enzyme detergent i s des i red , t h e f o l l o w i n g should be added :
Sodium bo ra te (borax) add an a d d i t i o n a l 2 .0 Calcium c h l o r i d e 0.1 Protease 0 . 6 D isso lve t h e Sodium C i t r a t e , sodium bo ra te and ca lc ium ch lo -
r i d e i n water . Apply heat i f necessary t o d i s s o l v e . Combine the s u r f a c t a n t s , p ropy lene g l y c o l and e t h y l a l c o h o l . Add t h e Sodium C i t r a t e , sodium bo ra te and ca lc ium c h l o r i d e s o l u t i o n t o t h i s m ix tu re . Add sodium xy lene su l fona te . Ad jus t t h e pH t o 8.0 w i t h TEA o r d i l u t e sodium hydroxide. Add t h e Protease. B r i n g t h e volume o f t h e m ix tu re t o 100 m l us ing water .
The a d d i t i o n o f f ragrance, dye, o p t i c a l b r i gh tener , a n t i - r e d e p o s i t i o n agent, cor ros ium i n h i b i t o r , e t c . , i s o p t i o n a l .
SOURCE: Haarman & Reimer Corp.: Suggested Formula t ion
B u i l t Formula t ion #1
I n a r e d i en t : Water Na3NTA Na Gluconate 45% KOH 42 S i l i c a t e N G lyco l Ether Non i on i c Sur f a c t an t Amphoteric
Weight .% 68% -
1% 1%
10% 10% 5% 2% '
3%
Both t h e Amphoteric SC and t h e compe t i t i ve im idazo l i ne coupled t h e f o r m u l a t i o n together w i t h 3% o f amphoteric.
SOURCE: Tomah Products, I n c . : Suggested Formul t ion
Laundry Products 89
90 Advanced Cleaning Product Formulations
I nq red Neodol Neodol
Heavy Duty L i q u i d Laundry Detergent Type TA
i en ts : 25-7 (non ion i c s u r f a c t a n t ) 25-35 ( a n i o n i c s u r f a c t a n t )
Sodium l a u r y l s u l f a t e ( a n i o n i c s u r f a c t a n t ) Stepan B i o S o f t D-62 (LAS-anionic s u r f a c t a n t ) T r i ethanolami ne (TEA) Propylene g l y c o l Potassium C i t r a t e (Haarman & Reimer Corp.) E thy l a l coho l Calcium c h l o r i d e Sodium bo ra te (borax) Protease Water q .s
Pa r t s I
t o
a L ! W s h t 5.0
10.0 12.0 8.0 5.0 7.0 6.0 7.0 0 . 1 3 .0 0.6
100 p a r t s
D isso lve the Potassium C i t r a t e , ca lc ium c h l o r de and sodium bo ra te i n approximately 20 m l water. Apply heat f necessary t o d i s s o l v e . Combine t h e su r fac tan ts , TEA, propy ene g l y c o l and e t h y l a l c o h o l . Add t h e Potassium C i t r a t e , ca lc ium c h l o r i d e and sodium bo ra te s o l u t i o n . Ad jus t t h e pH of t h e s o l u t i o n t o 8 . 0 w i t h TEA o r d i l u t e sodium hydrox ide . Add t h e Protease. B r i n g t h e volume o f t h e m ix tu re t o 100 m l us ing water .
The a d d i t i o n o f f ragrance, dye, o p t i c a l b r i g h t e n e r , a n t i - redepos i t i on agent, co r ros ion agent, co r ros ion i n h i b i t o r , e t c . , i s o p t i o n a l .
SOURCE: Haarman & Reimer Corp.: Suggested Formula t ion
!&M d Laundry_ D_etergents
I n Q red j.=ts: Water Glucopon 6OOCSUP (50%) E t hano 1 Tryco l 5963
I n redients.; i a F e r Sodi um C i t r a t e Su l fo tex SXS Glucopon 6OOCSUP (50%) Ethanol S u l f o t e x 6040 S (59%)
We 1 g h t% 72 10
3 15
Weight% 32
5 5
15 5
38
Add i n t h e order l i s t e d , d i s s o l v i n g each i n g r e d i e n t com- p l e t e l y . Use moderate a g i t a t i o n and inco rpo ra te c o l o r s and f ragrances as requ i red .
SOURCE: Henkel Corp.: CD D i v i s i o n : Glucopon Sur fac tan ts : Suggested Formulat ions
Heavv Dutv L i q u i d Laundry Deterqent Type WA
I n a r e d i en ts : _ _ Pa r t s by Weiaht Stepan B i o S o f t D-62 (LAS-anionic s u r f a c t a n t ) 28.0 Neodol 25-7 (non ion i c s u r f a c t a n t ) 7 . 0 Sodium xylene s u l f o n a t e 12.0 T r i ethanolami ne (TEA) 2 .0 Sodium C i t r a t e (Haarman & Reimer Corp . ) 12.0 Water 9 , s . t o 100 p a r t s
D isso lve Sodium C i t r a t e i n approximately 20 m l water. Combine t h e su r fac tan ts , sodium xylene s u l f o n a t e and TEA. Add t h e Sodium C i t r a t e . Ad jus t t h e pH o f t h e s o l u t i o n t o 11 us ing d i l u t e sodium hydrox ide . B r i n g the volume o f t h e m ix tu re t o 100 m l us ing water.
added : I f an enzyme detergent i s des i red , t h e f o l l o w i n g should be
Sodi um bo ra te (borax) 3 . 0 Cal c i um c h l o r i d e 0.1 Propylene g l y c o l 7 . 0 Protease 0 .6 D isso lve t h e sodium bora te , ca lc ium c h l o r i d e and Sodium i
C i t r a t e water. Apply heat i f necessary t o d i s s o l v e . Combine t h e s u r f s t a n t s , sodium xylene su l fona te , TEA and propylene g l y c o l . Add t h e sodium bora te , Sodium C i t r a t e and ca lc ium c h l o r i d e s o l u t i o n t o t h i s m ix tu re . Ad jus t t h e pH t o 8 . 0 w i t h TEA o r d i l u t e sodium hydrox ide . Add t h e Protease. B r i n g t h e volume o f t h e m ix tu re t o 100 m l us ing water.
r e d e p o s i t i o n agent, co r ros ion i n h i b i t o r , e t c . , i s o p t i o n a l .
SOURCE: Haarman & Reimer Corp.: Suggested Formulat ion
The a d d i t i o n of f ragrance, dye, o p t i c a l b r i gh tener , a n t i -
B u i l t Formula t ion #2
I n a r e d i e n t : Water Na M e t a s i l i c a t e pentahydrate STPP Nonionic s u r f a c t a n t Amphoteric s u r f a c t a n t
Weight .% 7 9%
1% 10% 5% 5%
Both t h e Amphoteric SC and t h e compe t i t i ve amphoteric coupled t h e f o r m u l a t i o n together w i t h 5% o f amphoteric.
SOURCE: Tomah Products, I n c . : Suggested Formulat ion
Laundry Products 91
92 Advanced CIeaning Roduct Formulations
L i aui d Heavv-Duty Detergent. Low V i scosi t v - A
Marlon PS 65 Marl i pal 01 3/89 Caustic potash, 50% (approx.)* Coconut f a t t y a c i d T r i ethhnol ami ne R* 1.2-Propylene g l yco l * Ethanol * Phosphonate, e.g. Dequest 2060 S Sodi um formi ate* Balance water, fragrance, dyestuf f , enzymes, preservat ive
Act ive matter: 45.0%
% 20.0 17.2 3.9
10.0 5.0 3.0 8.0 1.5 1 . o
o p t i c a l br ightener , t o 100
L i a u i d Heavy-Dutv Detergent. Low Viscosi tv-B
s6 Marlon PS 65 20.0 Mar l i pa l 013/129 3.9 Marlox FK 64 12.0 Caustic potash, 50% (approx.)* 3.9 Coconut f a t t y ac id 10 .0 Triethanolamine R* 5.0 1,P-Propyl ene g l yco l * 3.0 Ethanol * 8.0 Phosphonate, e.g. Dequest 2060s 1.5 Sodi urn formi ate* 1 .o Balance water, fragrance, dyes tu f f , o p t i c a l br ightener ,
enzymes, preservat ive t o 100
Act ive matter: 45.0%
L i a u i d Heavy-Duty Deteraent. B u i l t Type. H i g h Viscosi tv-B
%
Marl i pa l 01 3/30 5.0 C i t r i c ac id 1 . o Z e o l i t e A, 50% s l u r r y 45.0 Balance water, fragrance, dyestuf f , o p t i c a l br ightener , enzymes, preservat ive t o 100
Marlon PS 65 10.0
Act ive matter: 11.5%
* f u r t h e r products o f Huls AG
SOURCE: Huls America, I nc . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
L igh t -Duty Deterqent. Powder. Spray M i x i n q Process-A
Spray Mix : M a r l i p a l 013/939 o r 24/939 Marlamid DF 1218 Fragrance
% 5.0 1.0 0 . 2
B u i l d e r Mix : Z e o l i t e A Sodi um d i s i 1 i c a t e Carboxymethyl c e l l u lose Sodium su lphate l i g h t
Post Mix: Marlon ARL
A c t i v e ma t te r : 17.5%
40.0 3 . 0 1 .o
34.8
15.0
L i ght-Duty Deterqent ~ Powder, Spray M i x i ng Process-€3
Spray Mix : M a r l i p a l 013/939 o r 24/939 Fragrance
% 3.0 0.2
B u i l d e r Mix : Z e o l i t e A Sodi u m d i s i 1 i c a t e Carboxymethyl c e l l u l o s e Sodium su lphate l i g h t
Post Mix : Marlon ARL
A c t i v e Ma t te r : 17.1%
45.0 5.0 1 . o
22.8
18.0
L i q u i d L igh t -Duty Detergent, w i t h Inco rpo ra ted Softener, Low V i scosi ty-A
Marl i p a l 24/99 Marlox FK 64 Mar loso f t I0 90 Ethanol * Balance water, f ragrance, d y e s t u f f
9b 15.0
5 . 0 5 . 0
10.0 t o 100
A c t i v e Ma t te r : 23.0% * f u r t h e r p roduc ts o f Huls AG
SOURCE: Huls America, I n c . : Bas ic Formulat ions o f Detergents and Cleaning Agents f o r Household Purposes
Laundry Products 93
94 Advanced Cleaning Product Formulations
L i Quid L i ght-Duty Detergent. Low V i scosi t y - A
Marlon PS 65 Marl i nat 242/28 Marlamid DF 1218 Coconut f a t t y a c i d Caustic potash, 50% (approx.)* Ethylenediamine te t raacetate, 40% Balance water, fragrance, dyestuf f , sodium ch lo r i de
Act ive matter: 23.5% Formulation A f o r machine-wash
% 20.0 12.0
3.0 4.0 1.4 0.2
preservat ive, t o 100
L i aui d L i ght-Duty Detergent, Low V i scosi ty-B
% Mar l i na t 242/28 40.0 Marlamid DF 1218 3.0 Marlamid PG 20 3.0 Balance water, fragrance, dyestuf f , preservat ive, sodium c h l o r i d e t o 100
Act ive matter: 16.2% Formulation B f o r manual-wash
L i q u i d Light-Duty Detergent, w i t h Incorporated Softener, Low V i scosi ty-B
Marl i p a l 24/99 Marlox FK 64 Ampholyt JB 130 Marlosoft I Q 90 Balance water, fragrance, dyes tu f f
% 5 . 0 5 . 0
25.0 5.0
t o 100
Act ive matter: 21.5%
* f u r t h e r products o f Huls AG
SOURCE: Huls America, I nc . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
Part A Igepal CO-660 Calsof t F-90 Water
I n d u s t r i a1 Laundry Two-Part Systems Formula LY-0052
Uniforms (Petroleum Greases and O i l s )
2 90
Part B Sodium S i l i c a t e (Si02/Na20 1.6-2.5) 100
Hotel / L i nen SUDD~Y (Ani ma1 and Vegetable Greaser
Part A Igepal CO-660 Calsof t F-90 Water
Par t B Potassi um Hydroxide (45%) STPP, TKPP o r KTPP
Sodium Carbonate Igapal CO-660 Sodi um Tripolyphosphate Sodium Metas i l i ca te Opt ica l B r i ghtener
t o t h mixer. S CO-660. Add t h e remaining ingredients i n t h Mix u n t i l uniform.
Wt.% 10
2 88
85 15
I n d u s t r i a l Laundry Powder Uniforms
Formula LY-0050
Procedure Add t h e sodi um carbona
Wt.% 5 2 . 5 15 20 12
0 . 5
ray on the Igepal order 1 i sted.
Phvsi c a l ProDert i 8s Appearance: White, f ree- f lowing powder pH, 1% Solut ion: 11.4
SOURCE: Rhone-Poulenc Surfactants & Specia l t ies: Formulas
Laundry Products 95
96 Advanced Cleaning Product Formulations
Laundry L iau ids
Calsuds o r C a l s o f t based products remove ground- in d i r t and grease i n heavy f a b r i c s and g e n t l y c lean d e l i c a t e k n i t s i n c o l d water. They i n h i b i t s t a t i c bu i l d -up and p rov ide l u b r i c i t y , f u l l i n g and so f ten ing .
"Fine Care" Fabr i c Detergents P i l o t Formula ULDY-003-01
Calsuds CD-6 Cal foam ES-303 P i l o t SXS-40 Cal s o f t LAS-99 Water
Calsuds CD-6 Cal foam ES-303 P i l o t SXS-40 Cal s o f t LAS-99 Water C i t r i c Ac id Perfume and Color Preserva t ive
Water 50% NaOH D i ethanol ami ne Propylene Glyco l Cal s o f t LAS-99 Cal oxy l a t e N-9
Water 50% NaOH D i ethanol ami ne P i l o t SXS-40 C a l s o f t LAS-99 Cal oxy l a t e N-9
P i l o t Formula ULDL-003-01
Heavy Duty Laundry L iqu ids P i 1 o t Formula #HDL-004-01
P i l o t Formula #HDL-005-01
% bv Weipht 19.90 15.15 10.20 4.96
49.79
% by Weiqht 20.00 15.00 10.00 5.00
50.00 Q.S. pH 7
Q . S . Q.S.
% by Weiqht 36.60
6.40 7.00 5.00
40.00 5.00
% bv Weiqht 30.40
4.60 5.00
25.00 30.00
5.00
SOURCE: P i l o t Chemical Co. : Household C1 eaner Formul a t i ons
Laundry Powder Deteraent Formula LY-0047
Sodium Carbonate Ca lso f t F-90 Rhodapex NA-61 Rhodasurf 25-7 Sodium Metas i l i ca te Pentahydrate Sodi um Su l fa te Zeol i t e Sodi um Perborate Enzymes can be added Dye Perfume
Procedure Add t h e sodium carbonate t o t h e mixer.
pex NA-61 and the Rhodasurf 25-7. Add t h e i n t h e order l i s t e d and mix u n t i l uniform.
Wt.% 44.0 14.0 6.0 2.0 4.0
10.0 18 .0 2.0
Spray on the Rhoda- remai n i ng ingredients
Physical ProDerties Appearance: White, f ree- f lowing powder, dyed t o preference. pH, 1 % Solut ion: 11
I n d u s t r i a l Laundry One-Shot L i a u i d Formula LY-0049
Water Igepal CO-630 Igepal CO-710 Cheelox BF-13 Potassi urn Hydroxide (45%) Miranol FBS
Wt.% 69
3 3
10 10 5
Procedu r e
Phvsi c a l P rove r t i ea
Add t h e ingredients i n the order l i s t e d . Mix u n t i l uniform.
Appearance: Clear l i q u i d pH. as i s : 13.0 pH, 1% so lu t i on : 11.8 Spec i f i c Grav i ty : 1.06 V iscos i t y : <lo cps
SOURCE: Rhone-Poulenc Surfactants a Spec ia l t i es : Formulas
Laundry Products 97
98 Advanced Cleaning Product Formulafions
L i q u i d Heavy Duty Detergent HDLD Soap based
Ingredients : A Genapol OA-080
Fa t t y ac id (2/3 o l e i c , 1/3 COCO) KOH (85%) 1,2 Propyleneglycol
Water (50-6OC)
T r i sodi um-ci t r a t e x 2H20
Savi nase Alcalase Termamyl Parf um Farbs to f f
8 Tinopal CBS-X
C Hostapur SAS 60
D Ethanol
12.00% 14.00% 3.50% 5 .OO% 0.10%
39.40% 17.00% 5.00% 3.00% 0.50% 0.20% 0.30% 0.20% 0.10%
Manufacturing: I Dissolve 8 i n A . 11 One a f t e r another, t he components o f C are added t o I I11 A t 25C, the components o f D t o 11.
L i q u i d Detergent "FSL" A
I ngr ed i ent s I r- Genapol CIA-080 Fa t t y a c i d ( P r i f a c 7976) KOH (85%) T r i ethanolami ne 1.2 Propyleneglycol
8 Tinopal CBS-X Water (50-6OC)
C Hostapur SAS 60 T r i sodi um-ci r a t e x 2H20 Dequest 2066
D Ethanol Savi nase A1 c a l ase Termamyl Perf ume Dye
12.00% 14.00% 2.60% 2.00% 5.00% 0.20%
34.20% 17.00% 5.00% 4.00% 3.00% 0.50% 0.20% 0.30%
q . s . q.s .
Manufacturing: I Dissolve 8 i n A. I 1 One a f t e r another, t he components o f C are added t o I. I11 A t 25C, t h e components o f D t o I.
SOURCE: Hoechst Akt iengesel lschaf t : Detergents and Cleaning Agents: Guide Formulations
Thick Bleach-1 L i qu i d
Ingredients.; A Genaminox MY
Medialan LD NaOH (100%)
B Water
C Sodiumhypochlori te - s o l u t i o n (150 g/L a c t i v e c h l o r i n e )
D Perfume (e.g. Hypofresh)
Manufactur ing: I B i s added t o A. I 1 S t i r C t o I. I11 A t l a s t D i s added.
V i s c o s i t y ( B r o o k f i e l d RVT, sp.4, 22C, mPas): 4800
mgk Bleach-2
Ing red ien ts : A Genaminox MY
Medialan LD NaOH (100%)
B Water
C Sodiumhypochlori te - s o l u t i o n (150 g/L a c t i v e c h l o r i n e )
D Perfume (e.g. Hypofresh)
Manufacturing: I B i s added t o A. I 1 S t i r C t o 1. 111 A t l a s t D i s added.
V i s c o s i t y ( B r o o k f i e l d RVT, sp.4, 22C. mPas): 600
12.000% 2.500% 1 .OOO%
34.475%
50.000%
0.025%
6.000% 1.000% 1.000%
41.975%
50.000%
0.025%
SOURCE: Hoechst Ak t iengese l l scha f t : Detergents and Cleaning Agents: Guide Formulat ions
Laundry Products 99
100 Advanced Cleaning R&ct Formulotions
Wool DeterQent, Medium Viscosity-A
Marlon PS 65 Marl i nat 242/28 Marlamid DF 1218 Balance water. dyestuf f , fragrance, preservat ive.
sodium c h l o r i d e
Act ive matter: 20.5%
Wool Detergent. Medium Viscosi ty-B
Marlon PS 65 Mar l i na t SRN 30 D i o n i l OC Balance water, dyestuf f , fragrance, preservat ive,
sodium ch lo r i de
Act ive matter: 20.0%
Wool Detergent. Medi um V i scosi tv-A
Marlon AS3 Marl i nat 242/28 Ammonium hydroxide, 25% Urea Balance water, fragrance, dyestuf f , preservat ive. sodium c h l o r i d e
Act ive matter: 19.0%
Wool Detergent. Medium Viscosi ty-B
Marlon A 375 Marl i nat 242/28 Marlamid DF 1218 Balance water, fragrance, dyestuf f , preservat ive, sodium c h l o r i d e
Act ive matter: 20.5%
% 18.0 28.0
1 .o
t o 100
% 20.0 20.0
1 .o
t o 100
% 12.0 18.0 3.0 3.0
to 100
% 15.6 28.0
1 . o
t o 100
SOURCE: Huls America, Inc. : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
9. Metal Cleaners and Polishes
101
102 Advanced Cleoning Product Formulations
A l u m i nun C1 eaner/Br i shtener Ac id Cleaner for Aluminum Wheels and T r a i l e r s
Inq red i en t : Deionized Water Phosphoric Ac id (85%) C i t r i c Ac id (50%) N i t r i c Ac id (70%) Avanel S-70
Wt.% 83.00
6.00 8.00 1 .oo 2.00
pH (as i s ) : <2.0 Appearance: Clear, white-water l i q u i d
Charge t h e water t o an appropr ia te mix ing vesse l . Charge
WARNING: Use a l l manufacturer p recaut ionary s a f e t y meas-
Procedure:
remaining i ng red ien ts i n t h e order l i s t e d w h i l e con t inu ing a g i t a t i o n .
ures when hand1 i ng concentrated a c i d s o l u t i o n s .
Formula CM-101
A1 urni num Smut C1 eaner High Temperature D i l u t a b l e Ac id Concentrate
I n s r e d i en t : Dei on i zed Water C i t r i c Ac id (50%) Gluconic Ac id (50%) Avanel N-1525-90 Avanel S-70 Ammoni um B i f 1 u o r i de
Wt.% 19.00 50.00 25.00
3.00 1.50 1.50
pH (as i s ) : <2.0 Appearance: Clear, water-whi te t o l i g h t - y e l l o w l i q u i d S p e c i f i c G r a v i t y : 1 .18
Procedure: Charge t h e water and two ac ids under a g i t a t i o n . Continue
a g i t a t i o n and add t h e Avanel su r fac tan ts ; mix u n t i l d isso lved. Add Ammonium B i f l u o r i d e and mix u n t i l d isso lved.
Use D i r e c t i on8 :
Use temperature o f d i l u t i o n i s normal ly 140-15OF.
Notes: Th is formula was developed t o remove stamping o i l smut from
aluminum cans. Cans should be thorough ly r i n s e d a f t e r c lean ing
Formula CM-104
SOURCE: Mazer Chemicals: SUQQeSted Formulat ions
Use i n pressure wash a t a r a t e o f 2-4 ounces per ga l l on .
Metal Cleaners and Polishes 103
Alumcnum Cleaner Concentrate
Water Sodium M e t a s i l i c a t e (Anhydrous) Tetrapotassium Pyrophosphate (Powder) Mona NF-10
% by Weiqht 75 10 5
10
Procedure:
i n water w i t h mix ing , then add Mona NF-10.
Typ ica l P roper t i es : Appearance: Clear l i q u i d Cloud Po in t : 88C
D isso lve sodium m e t a s i l i c a t e and te t rapotass ium pyrophosphate
Recommended Use D i l u t i o n : 1 t o 4 oz /ga l .
Formula F-498
A1 umi num Wash
Water Sodium M e t a s i l i c a t e (Anhydrous) Tetrasodium Pyrophosphate (Powder) B u t y l Carbi t o 1 Mona NF-10
% by Weight 88
2 3 2 5
Procedure:
i n water, then add Bu ty l C a r b i t o l and Mona NF-10.
Typi c a l Proper t i es :
D isso lve sodium m e t a s i l i c a t e and te t rasod ium pyrophosphate
Appearance: C lear l i q u i d pH: 1 2 . 8
Recommended Use D i l u t i o n : 1 : lO w i t h water
Formula F-499
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulat ions
104 Advanced Cleaning R&t Formulations
Cleaners and Cleanina Solut ionq
Metal Cleani na-A1 k a l i ne
Inaredients : Aerosol 22 Surfactant Sodium Carbonate Sodi um Metasi 1 i cate Sodium Hydroxide
% by Weiaht 10.0 40.0 2 0 . 0 10.0
Grind the powders together and add t h e Aerosol 22 s lowly wh i l e gr ind ing.
Metal C1 eani na-Aci d
Inqredients : Dowanol EB Phosphoric Acid (85%) Aerosol 22 Surfactant Water
Metal C l eani na-Pai n t Removal
I ns red i ents: Aerosol C-61 Surfactant Sodium Carbonate Sodium Metas i l i ca te Sodi um Hydroxide
% by Wei aht 6.0 7 . 0 0 . 3
8 6 . 7
% by Wei aht 20.0 40.0 30.0 10.0
Grind t h e powders together and add t h e Aerosol C-61 slowly wh i l e mixing.
Metal Cleaning-Rust Removal
Ineredi ents: Aerosol 0s Surfactant Sodium B i f l u o r i d e Sodium Tetraphosphate Sodium B i s u l f i t e
% by Weight 10.0 7 5 . 0 10.0 15.0
SOURCE: Cytec Indus t r i es Inc. : Suggested Formulations
Metal Cleaners and Polishes 105
Comer C l eani ng
Inaredients : Aerosol A-102 Surfactant Sodium Chlor ide C i t r i c Acid Eentoni t e Water
Aluminum Cleaning - A c i d
Inaredients : Phosphoric Acid (65%) Hydro f l uo r i c Acid (48%) Glac ia l Acet ic Acid Aerosol 0s Surfactant Water
A1 un i num C1 eani na-Bri ahteni ng
Ingredients : Phosphoric Acid (85%) Aerosol 22 Surfactant Aerosol 0s Surfactant Buty l Cel losolve Water
Aluminum Ai rcraf t -Br ightener (U.S.
Ingredients : Aerosol 0s Surfactant Aerosol 22 Surfactant C i t r i c Acid Arnmoni urn B i f 1 u o r i de Benzenesul f on i c Acid Phosphoric Acid (85%) Water
% bv Weiaht 2.0 5.0 5.0
22.0 66.0
% bv Wei Qht 15.0 2.0 3.0 5.0
75.0
% by Wei Qht 47.2
1 . o 1 . o
16.0 34.8
Patent 2.68Y.3461
% bv Weiaht 3.0 9.0 5.0 3.0
10.0 2.4
26.4-52.6
SOURCE: Cytec Indus t r i es Inc. : Suggested Formulatlons
lo6 Advanced Cleaning Product Formulations
E l e c t r o c l eaner
Components: Water Burco BSGH-400 Burco NPS-225 Burco TME 50% NaOH
% by Weiaht 2-0 1-4
0.75-3 0.25-1
To 100% Tota l
Basic formulat ing guidel ines: 1) Rat io o f Burco NPS-225/Burco TME should be 3/1. 2 ) The l e v e l o f Burco BSGH-400 i s p re fe rab ly equal t o the sum
3 ) The water charge should be equal t o the sum o f Burco BSGH-400,
4) Premix a l l components but NaOH. then add NaOH w i t h s t i r r i n g .
This formulat ion w i l l provide moderate foam l e v e l s and i s s u i t a b l e f o r use as an electrocleaner, food p l a n t cleaner o r o ther app l i ca t i ons where h igh caus t i c concentrates are used. For reduced foam l e v e l s as i n an a l k a l i n e spray cleaner, replace Burco NPS-225 w i t h Burco HCS-50NF.
o f Burco NPS-225 and Burco TME.
Burco NPS-225 and Burco TME.
Moderate A1 k a l i n i t y , Soi 1 So1 i t t i n a Soak Cleaner
ComDonents: Water Sodium Metas i l i ca te (Pentahydrate) Trisodium Phosphate (Crysta ls) Burco ADS-40 Burco EHS Burco TME
% bv Weiaht 70
5 10 5 5 5
Procedure: Add components i n the order l i s t e d . S t i r u n t i l homogeneous
between each addi t ion.
SOURCE: Bur l ington Chemical Co., I n c . : Suggested Formulations
Metal Cleaners and Polirhes 107
Hiah-Foaming Ac id Scrubber* Formula BC-0003
Mi rano l FBS Igepa l CO 630 Sul famic Ac id G1 yco l i c (Hydroxyaceti c ) Ac id (70%) Butoxyethanol Water
Wt.% 5.0 2.0 4.0 4.0 3.0
82.0
Procedure
o lved. Add t h e remaining i ng red ien ts , w i t h mix ing . Mix u n t i l un i fo rm.
Add t h e water, su l famic and g l y c o l i c acids. Mix u n t i l d i s s -
Physical ProDer t ies Appearance: Clear l i q u i d . .
pH, as i s : 1.5 S p e c i f i c Grav i t y : 1 V i s c o s i t y : t10 cps
*Su i tab le f o r appl i c a t
Rhodafac RE-61 0 Igepa l CO-630 Phosphoric Acid, 75% Water
027
ons w i t h a t r i g g e r - t y p e sprayer.
Ac id Cleaner Formula BC-0004
Wt.% 3.0 4.0
10.0 83.0
Procedure Add phosphoric a c i d t o water and heat w i t h a g i t a t i o n t o 50C.
w i t h r a p i d bu t smooth a g i t a t i o n . Slowly b lend i n Rhodafac RE-610 and Igepa l CO-630. Once system i s completely uni form, coo l w i t h s t i r r i n g t o 40-45C, and package.
Phys ica l P r o D e r t i e a Appearance: S l i g h t l y hazy l i q u i d pH, as i s : 1.6 Speci f i c Grav i t y : 1 .03 V i s c o s i t y : 20 cps
SOURCE: Rhone-Poulenc Sur fac tan ts 8 Spec i 'a l t ies : Formulas
108 Advanced Cleaning Product Fotmulations
Metal C1 eaner and Deereaser
InQredi ents: Monoethanolamine Sodium DDBSA, 35% Sandoxylate SX 400 Sodium EDTA Water Ole ic Acid D-Li monene Buty l Cel loso lve
% bv Weight 5.0
12.0 5.0 0.5
50.5 10.0
3.0 6.0
Procedure:
add DDBSA. Mix i n Sandoxylate SX 400, and EDTA. Warm t o 50C, add the o l e i c ac id s lowly, wh i l e increas ing t h e a g i t a t i o n . When t h e o l e i c a c i d has completely reacted, add D-Limonene and Buty l Cel losolve. Cool w i t h s t i r r i n g t o 40C. B o t t l e .
Propert ies:
Charge monoethanolamine and water t o vessel. With s t i r r i n g .
pH (as i s ) : 10.0 V i scos i t y : Approx. 100 cps B rook f i e ld LVT, Spindle #2 @ 12 rpm % Sol ids: 26%
SOURCE: Sandoz Chemicals Corp.: Formulation HHG-10
Thickened Clear Deareaser Concentrate
Water, D . I . DeSonic 9N Varonic DM55 d ' L i monene
% by Weight 42.5 25.0 12 .5 20.0
Blend1 ng Procedure:
each add i t i on .
Typical Propert ies: V i scos i t y , cps: 363 Sol ids: 37.5% pH: 5.9
Add ingredients i n order shown and d isso lve completely between
SOURCE: Witco Corp.: Formula 805
Metal Cleaners and Polishes 109
Stain less Steel Cleaner-A
Mar l i pa l KF Marlophor CS ac id Solvent BG* Balance water, fragrance, dyestuf f , preservat ive
Act ive matter: 1.0 V i scosi t y : 1 i qui d
S ta i n l ess Steel C1 eaner-B
Mar 1 i pa l 01 3/99 Aluminum oxide FPTO Isopara f f i n . e.g. Shel lso l T Balance water, fragrance, dyestuf f , preservat ive
Ac t i ve matter: 5.4 V iscos i t y : medi um Formulation B w i t h abrasive
S i l v e r Pol ish, Liauid-A
Mar l i pa l KF Thiourea Phosphoric acid, 85% Isopropanol* Balance water
Act ive matter: 0.5%
S i l v e r Pol ish. Liauid-B
Marlazin L 10 Marlophor CS ac id Thiourea Phosphoric acid, 85% Balance water
% 1 . o
10.0 5.0
t o 100
% 6.0
25.0 40.0
t o 100
% 0.5 6.0 2.0 3.0
t o 100
% 1.5 5.0 2.5
20.0 t o 100
Act ive matter: 1.5%
SOURCE: Huls America, Inc. : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
10. Oven, Grill and Hot Plate Cleaners
110
Oven, Grill and Hot Plate Cleaners 111
Pump Sprav Oven C leaner
- Ingredient; P a r t A : Vegetab le gum (Veegum T) Xanthan gum Water
-. Percent b v Wei q h t
1 .2 0 . 4
78 .9
P a r t B: L i q u i d C i t r i c Acid--50% (Haarman & Reimer Corp . ) 7 . 0 Sodium h y d r o x i d e s o l u t i o n 50% 4 .5
P a r t C : Amphoter ic s u r f a c t a n t 8 . 0
Prepare P a r t A by s l o w l y add ing v e g e t a b l e gum and xanthan gum t o t h e w a t e r . Cont inue a g i t a t i n g u n t i l smooth d i s p e r s i o n i s o b t a i n e d .
t o a separa te t a n k and n e u t r a l i z i n g i t w i t h t h e sodium h y d r o x i d e s o l u t i o n . The n e u t r a l i z a t i o n s h o u l d be done s l o w l y and c o n t i n - u o u s l y under a g i t a t i o n , as t h e r e a c t i o n i s h i g h l y exo thermic .
Prepare P a r t B ( t r i s o d i u m c i t r a t e ) by add ing t h e c i t r i c a c i d
Add P a r t B t o P a r t A, and f i n a l l y P a r t C . The f o r m u l a t i o n has t h e c o n s i s t e n c y o f a f l u i d g e l . I t may be
used i n e i t h e r warm o r c o l d ovens. The s p r a y i n g s h o u l d be done a t a d i s t a n c e o f f r o m 10 t o 15 inches . Clean by w i p i n g a f t e r a t l e a s t 10 minu tes o f r e a c t i o n t i m e . SOURCE: Haarman & Reimer Corp . : Suggested F o r m u l a t i o n
C a u s t i c Oven C1 eaner
I n g r e d i egt_s_: % b y Weight ( 1 ) K o r t h i x H 2 . 0 ( 2 ) Kelzan 0 .3 ( 3 ) De ion ized Water 8 6 . 7 ( 4 ) Sodium Hydrox ide (50%) 10.0 ( 5 ) Avanel S-74 1 . o Procedure:
Add ( 1 ) t o ( 3 ) and mix a t h i g h speed. A f t e r ( 1 ) i s w e l l d i s - persed, add (2) and ( 5 ) . Reduce speed and add ( 4 ) c a r e f u l l y and s l o w l y .
F o l l o w recommended h a n d l i n g p r a c t i c e s o f t h e s u p p l i e r s of each p r o d u c t used. SOURCE: K a o p o l i t e , I n c . : Suggested F o r m u l a t i o n
O v e n / G r i l l C leaner
Wt% Water 78 Tetrasodium EDTA 2 Sodium Hydrox ide (50%) 15 Glucopon 425 CS 5 SOURCE: Henkel Corp . , CD D i v i s i o n : Suggested F o r m u l a t i o n
11 Polishes, Coatings and Finishes
112
Polishes, Coatings and Finishes 113
Aerosol F u r n i t u r e P o l i s h (Carbon D iox ide Propel l a n t l
Mater i a1 s: Pa r t A: I sopar E Hoechst Wax A 3 CS SF 96 (100) V i s c a s i l (10,000) Span 80 P a r t 8: Water Procedure: 1.) Heat P a r t A t o 85C. 2 . ) Heat Pa r t 8 t o 70C. 3 . ) Add P a r t 8 t o P a r t A w i t h h igh shear mixing. 4.) Cool t o room temperature when homogeneous. Prepara t ion o f Aerosol : Loadi ng : P o l i s h Concentrate Carbon D iox ide
Aerosol Valve: P rec i s ion Valve P a r t Numbers:
*Th is w i l l g i v e a can pressure o f approximately
Button: Pa r t No. 01-5843 (0.020" MBFT RS) Stem: Par t No. 04-1215 (0.016") Gasket: Pa r t No. 05-0310 (BUNA) Body: Pa r t No. 07-1901 (0.080")
5.) Package i n s u i t a b l e conta iners .
Part/Wt(%)
22.5 0.5 2.3 0.5 0 .3
73.9
Part/Wt(%) 97.5
2.5* 105 p s i g .
General Purpose L i auid Pol i sh (Oil-In-Water Type)
Mater i a1 s : Part/Wt (%l P a r t A: SF 96 (350) 2.50
Hoechst Wax E 1.50 O l e i c Ac id 1.50
Par t 8: Water 70.05 Carbopol 934 0.25 Morphol i ne 1.60 Kathon CG 0.10 Par t C: I sopar M 2.00 SF 1706 1.50 P a r t D: Kaopo l i t e SF 8 . 0 0 Procedure: 1 . ) Heat Pa r t A t o 95C. (2 . ) Heat Pa r t B t o 85C. (3.) Add P a r t
A t o Pa r t 8 w i t h h igh shear mix ing . ( 4 . ) When homogeneous, coo l t o 60C and add Par t C w i t h h i g h shear mix ing . ( 5 . ) Add Par t D w i t h moderate mix ing . ( 6 . ) Cool and package i n s u i t a b l e conta iners .
V i s c a s i l (10,000) 1 .oo
Isopar M 10.00
SOURCE: GE Si14cones: Formula FP 3003/Formula AP 1000
114 Advanced Cleaning Roduct Formulatiom
Aerosol F u r n i t u r e P o l i s h IHydrocarbon ProDel lan t )
Ma te r ia l s : Pa r t A: I sopar E Hoechst Wax A3 CS S F 96 (100) V i scasi 1 ( 10,000) Span 80 Tween 81 Par t B: Water Procedure: 1 . ) Heat P a r t A t o 85C. 2 . ) Heat P a r t B t o 70C. 3 . ) Add P a r t B t o Pa r t A w i t h h igh shear mix ing . 4.) Cool t o room temperature when homogeneous. Prepara t ion o f Aerosol : i o a d i ng : P o l i s h Concentrate A 46 P rope l l an t Aerosol Valve : P rec i s i on Valve P a r t Numbers :
But ton : Par t No. 01-5843 (0.020" MBFT RS) Stem: Par t No. 04-1240 (0.024") Gasket: Pa r t No. 05-0310 (BUNA) Body: P a r t No. 07-1901 (0.080")
5. Package i n su i tab1 e conta i ners.
F u r n i t u r e P a s t e m Mater i a1 s : Par t A:
Par t / W t 1%)
14.75 0.50 2.30 0.50 0.25 0.08
81.62
Part/WtC%) 90.0 10.0
V i scasi 1 (30,000) Hoechst Wax E Hoechst Wax F Ross Micro Wax 1135/15# Ross Ozoker i te Wax 77Y Par t B: I sopar L Procedure: 1 . ) Heat Pa r t A t o 1OOC. 2.) Heat Pa r t B t o 9%. 3 . ) Add Par t 8 t o Par t A w i t h g e n t l e mixing. 4.) Cool t o 50-52C w i t h g e n t l e mix ing and pour i n t o conta iners .
A l low con ta ine rs t o coo l be fo re capping. A f l o w o f a i r across sur face o f con ta ine r w i l l improve c o o l i n g process. M u l t i p l e pour cyc les can be used f o r deep conta iners .
A l t e r n a t e Method: 1 . ) Heat P a r t A t o 100C. 2 . ) Add Par t B (unheated) s lowly w h i l e b lend ing . 3 . ) Reheat Pa r t AB u n t i l a c l e a r s o l u t i o n i s obtained. Fo l low
above procedure f rom here.
7.0 7.0 3.0 6 . 0 1 .o
76.0
SOURCE: GE Si l i cones : Formula FP 3002/Formula FP 3004
Polishes, Coatings and Finishes I15
Detergent Res is tan t . Cream Cleaner P o l i s h
I n g r e d i e n t s : % by ( 1 ) Deodori zed Kerosene ( 2 ) Hoechst Wax S (3 ) GP-7104 ( S i l i c o n e F l u i d ) ( 4 ) GP-10-1,000 c s t k (Dimethyl S i l i c o n e F l u i d ) ( 5 ) O l e i c Ac id ( 6 ) S o f t Water ( 7 ) Morphol i ne ( 8 ) S o f t Water ( 9 ) Minera l S p i r i t s (Low Odor) (10)Kaopo l i te SF
Weight 10.0
8 . 0 3 . 0 4.0 1 .o 2.4 0 .8
38.8 20.0 12.0
Procedure: Combine (1 ) through ( 5 ) and heat t o 212F w i t h low t o moderate
m ix ing . Remove heat, inc rease m ix ing and add ( 6 ) through (10) as i n s t r u c t e d below.
Heat (6 ) t o 21OF, s t i r i n ( 7 ) , then pour i n t o t h e ba tch . Heat ( 8 ) t o 210F and add t o t h e ba tch . Add ( 9 ) then (10) s low ly t o t h e batch, a l l o w i n g complete mix ing o f each.
Mix s low ly u n t i l temperature o f ba tch reaches l lOF . Package.
Formula 4-2
Non-Abrasive, Detergent Res is tan t , Glaze Emulsion
I n g r e d i e n t s : % by Weight ( A ) ( 1 ) GP-10-1,000 c s t k (Dimethyl S i l i c o n e F l u i d ) 3.0
(2) GP-7104 ( S i l i c o n e F l u i d ) 3 . 0 ( 3 ) Hoechst Wax S 1.5 ( 4 ) Carnauba Wax #3 1 . o ( 5 ) O l e i c Ac id 1 .5 ( 6 ) Minera l S p i r i t s 4.6
( B ) ( 7 ) S o f t Water (8 ) Carbopol 934 ( 9 ) Tr ie thano lamine 99%
(10) Morphol i ne
83.6 0 . 2 0 .2 1 .4
Procedure: (A) Combine (1 ) through (6 ) and heat t o 150F w i t h mix ing . ( B ) Heat ( 7 ) t o 1OOF. Wi th h i g h shear mix ing add ( 8 ) t o ( 7 ) .
Once (8) i s d i sso l ved add (9 ) and then add (10) . Add ( A ) t o ( B ) s low ly , w i t h h igh shear mix ing . Cont inue m ix ing u n t i l emulsion reaches 70F. Package.
Formula 8-1
SOURCE: Genesee Polymers Corp.: Suggested Formulat ions
I16 Advanced Cleaning Product Formulations
Hi ah G1 oss. Detereent Res is tan t . S o f t Paste Pol i sh
I nq red ien ts : ( A ) ( 1 ) Hoechst Wax OP
(2) Hoechst Wax E (3) Ozokeri t e
% bv Weight 7.0 8.0 1 .5
(B) ( 4 ) GP-7104 ( S i l i c o n e F l u i d ) 3.0 ( 5 ) GP-10-1,000 c s t k (Dimethyl S i l i c o n e F l u i d ) 3.0 (6 ) GP-10-12,500 c s t k (Dimethyl S i l i c o n e F l u i d ) 2.0 (7 ) Minera l S p i r i t s (Low Odor) 36.0 ( 8 ) Deodorized Kerosene 9.5 (9) Kaopo l i t e SF 12.0
(10) Minera l S p i r i t s (Low Odor) 18.0
Procedure: ( A ) Combine ( I ) , (2), and (3), heat t o 230F t o me l t waxes. (B) Separately mix and heat ( 4 ) , ( 5 ) , ( 6 ) , (7 ) , and (8) t o 160F.
Slowly add (B ) t o ( A ) w i t h mix ing . Temperature o f ba tch a f t e r adding (B) t o (A) should be 195F. Add (9 ) then (10) t o ba tch w i t h m ix ing . Remove heat and mix w e l l u n t i l temperature reaches 140F. Package.
Formula 5-2
Detergent Res is tan t Cream P o l i s h
Inq red i en ts : ( 1 ) Witconol 14 (2) GP-10-1,000 c s t k (Dimethyl S i l i c o n e (3) Carnauba Wax #3 (4 ) Isopar L (5) Morphol i ne (6 ) GP-7104 ( S i l i c o n e F l u i d ) (7 ) S o f t Water (8 ) Kaopo l i t e SF
% by Wei ah t 1 .5
F l u i d ) 3.0 10.0 25.0
0.4 3.1
47.1 10.0
Procedure:
t o 195F w i t h m ix ing t o me l t wax. Once wax i s melted, add ( 5 ) w i t h mix ing . Add (6 ) t o m ix tu re fo l l owed by t h e r e s t o f (41, keeping t h e temperature a t 175F. Remove from heat and mix u n t i l temperature reaches 130F. Package.
Formula 3-2
SOURCE: Genesee Polymers Corp.: Suggested FormulatSons
Combine ( I ) , (2), (3). and 50% o f (4) i n a conta iner and heat
Polishes, Coatings and Finishes 117
L i q u i d P o l i s h For C lear Coat F in i shes Mater i a1 _s ; Part/Wt(%) Par t A: SF 96 (350) 3.50 Hoechst Wax S 1 .oo Hoechst Wax E 1.60 O l e i c Ac id 1.50 Isopar M 5.00 Par t 0: Water 77.75 Carbopol 934 0.20 Morphol i ne 1.60 Kathon CG 0.10 Par t C: I sopar M I .oo SF 1706 0.75 Par t D: Kaopol i t e 11 52 6.00 Procedure: 1 . ) Heat P a r t A t o 95C. 2 . ) Heat Pa r t B t o 8%. 3.) Add P a r t A t o Pa r t B w i t h h i g h shear mix ing . 4 . ) When homogeneous, coo l t o 60C and add P a r t C w i t h h igh
5 . ) Add P a r t D w i t h moderate mix ing . 6 . ) Cool and package i n s u i t a b l e conta iners .
Mater i a1 s : Part/Wt(%) Par t A: SF 96 (350) 5.00 Hoechst Wax E 1.50 O l e i c Ac id 1.50 Par t 8: Carbopol 934 0.25 Morphol i ne 1.50 Water 74.15 Kathon CG 0.10 Par t C : SF 96 (100) 2.00 SF 1706 2.00 Par t D: Kaopol i t e 11 52 7.80 Snow F loss 4.20 Procedure: 1 . ) Heat Pa r t A t o 95-IOOC. 2 . ) Heat Par t B t o 85C. 3 . ) Add Par t A t o Pa r t B w i t h h igh shear mix ing . 4 . ) When homogeneous, coo l t o 60-70C and add Par t C w i t h con t in -
5 . ) When homogeneous, reduce mix ing t o medium speed and s low ly
6.) Cool and package i n s u i t a b l e conta iners .
SOURCE: GE S i l i c o n e s : Formula APlOOl/Formula AP1002
shear m i x i ng.
L i q u i d Polish-No Solvent
ued h igh shear mix ing .
b lend i n Par t D.
I18 Advanced Cleaning Product Formulations
L i a u i d Po l i sh (Outer Phase O i l l
Mater ia ls : Par t A: V i scas i l (10,000) W i tcamide 51 1 Tween 81 Hoechst Wax OP Ross Ozoker i te 77Y Isopar M Par t 9: Water Kaopol i t e 11 52 Kaopol i te SF Part C : Isopar L SF 1705 SF 1706 Procedure: 1.) Heat Par t A t o 90-95C. 2 . ) Heat Part B t o 80C. 3 . ) Add Par t B t o Par t A w i t h h igh shear mixing. 4 . ) When homogeneous, cool t o 50-60C and add Par t C
5 . ) Cool and package i n s u i t a b l e containers. Formula AP 1003
continued h igh shear m i x i ng.
Part/Wt (%l
1.50 1 .oo 0.15 1.30 0.20
2 0 . 0 0
55.85 4.50 4.50
6.00 3.00 2.00
w i t h
Non-Wax L i a u i d Po l i sh (Oil-Pn-Water Tvoe)
Mater i a1 s : Par t A:
Part/Wt C%l
SF 96 (350) 4.00 V i scasi 1 (10,000) 1 .oo Isopar L 11 .oo Ole ic A c i d 1.50 Part 0 : Water 65.95 Carbopol 934 0.25 Morpholine 1.70 Kathon CG 0.10 Part C: Isopar M 4.00 SF 1706 1.50 Par t D: Kaopol i t e 11 52 6.00 Snow Floss 3.00 Procedura: 1. ) Add Par t A t o Par t B w i t h h igh shear mixing. 2 . ) When AB i s homogeneous, add Part C. a lso w i th h igh shear
m i x i ng. 3 . ) Add Par t D w i t h moderate mixing u n t i l homogeneous. 4.) Package i n s u i t a b l e containers. Formula AP 1004 SOURCE: BE Sl l lconea: Suggested Formulations
M a t e r i a l s : SM 2133
20% Wax Emulsion Carbopol 934 Tr iethanolamine Water B i o c i de
sm 2135
M a t e r i a l s : P a r t A: Card is 36 Wax Hoechst Wax A3 CS O l e i c Ac id Morphol ine Par t B: Water B i o c i de
Polishes, Coatings and Finishes 119
L i sui d F u r n i t u r e P o l i sh Part/Wt (%I
4.0 2.0 2.5 0 . 2 0.2
91.1 q . s
20% Wax Emulsion-1
20% Wax Emulsion-2 M a t e r i a l s : Pa r t A: Card is 36 Wax Hoechst Wax A3 CS O l e i c Ac id D i e t h y l ami noethanol (DEAE) Par t 8: Water B i oc i de
Part/Wt(%)
10.0 10.0
3.0 4.0
73.0 q . s .
Part/Wt (%)
10.0 10.0
3.0 2.5
74.5 q . s .
Prepara t ion o f Wax Emulsion: 1.) Add Card is 36 wax, Hoechst wax A3 CS, and o l e i c a c i d t o a
2.) When completely melted, add e i t h e r t h e morpholine o r DEAE u n t i l m ix tu re i s homogeneous.
3.) Add P a r t B, preheated t o 95C, s low ly s t i r r i n g t h e wax/soap mix tu re , ma in ta in ing temperature between 93 t o 98C du r ing t h i s a d d i t i o n .
4.) Continue s t i r r i n g u n t i l temperature reaches 45C. 5 . ) Cool t o room temperature. Prepara t ion o f Po l i sh : 1 . ) Add water, b ioc ide , and Carbopol 934 t o a vessel , and
2 . ) Add t r i ethanol ami ne and mix u n t i 1 homogeneous. 3 . ) Add o the r i ng red ien ts . 4 . ) Combine w i t h m i l d mixing, and when homogeneous, package
SOURCE: GE S i l i c o n e s : Formula FP 3000
vessel , and w i t h m i l d s t i r r i n g b r i n g t h e temperature up t o 96-1 OOC.
d i s s o l v e t h e Carbopol w i t h good mix ing . Warm water w i l l improve t h i s process.
i n s u i tab1 e con ta i ners.
120 Advanced Cleaning Roduct Formulatiotu
L i a u i d Water-Based Glaze
Mater i a1 s : Par t A: SF 96 (350) O l e i c Acid Hoechst Wax OP Card is 36 Wax Isopar M
Par t B: Water Carbopol 934 Morphol ine Kathon CG
Par t C: I sopar M SF 1706
Part/Wt(%)
3.50 1.50 1 .oo 1.50 6.00
82.55 0.25 1.60 0.10
1 .so 0.50
Procedure: 1 . ) Heat Pa r t A t o 95-1OOC. 2 . ) Heat P a r t B t o 90-95C. 3 . ) Add Par t A t o Pa r t B w i t h h igh shear mixing. 4.) Cool t o 60-70C and add Par t C w i t h h igh shear mixing. 5 . ) Cool w i t h cont inued moderate mix ing . 6.) Package i n s u i t a b l e conta iners . Formu la AP 1005
Sol vent Wax G l aze
M a t e r i a l s : Pa r t A: SF 96 (1000) Hoechst Wax OM Hoechst Wax F Deodorized Kerosene
Par t B: Odorless Minera l S p i r i t s SR 107
Part/Wt (%l
3.0 0.6 1.4
1 0 . 0
84.0 1 .0
Procedure: 1.) Heat P a r t A to 95C. Be sure a l l wax i s completely melted
2 . ) Add Par t B w i t h moderate mix ing . 3 . ) Continue mix ing and coo l t o room temperature. 4.) Package i n s u i t a b l e conta iners .
Formula AP 1008
SOURCE: GE S i l i c o n e s : Suggested Formulat ions
and d i spersed.
Polishes, Coatings and Finishes 121
Paste Po l i sh (Oil-In-Water Type1
Part/Wt (%l Materi a1 s: Part A: Hoechst Wax S Hoechst Wax OP SF 96 (350) V i scas i l (10,000) Stear ic Acid Isopar M Isopar L Part 0: Water Morpholine Kaopol i t e 11 68 Super Floss Part C: Isopar M SF 1706 Procedure: 1 . ) Heat Part A t o 90-95C. 2.) Heat Part 8 t o 80-85C. 3.) Add Part A to Part B wi th good mixing. 4. ) When homogeneous, cool t o 60C and add Part C w i t h continued
5 . ) Cool t o s u i t a b l e pour temperature (<50C). 6.) Package i n su i tab le containers. Comments :
degree o f cool ing ava i l ab le on the f i l l i n g l i n e . With slow coo l i ng rate, t he coo l i ng cyc le must be done without covers t o prevent condensation i ns ide containers.
mixing.
The pour temperature w i l l depend on equipment and r a t e and
5.0 1 . o 4.5 2.0 1 .o 8 .0
18.0
42.8 0.7 8 .0 2.0
5 .0 2.0
Spray-And-Wipe Po l i sh
Mat e r i a1 s : SM 2109 AF 9020
Part/Wt(%) 8 . 0 0 0.05
Veegum Pro 0 . 8 0 Proxcel GXL 0.15 Kaopol i te SF 5.00 Water 86.00 Procedure: 1 . ) Add water, Proxcel GXL. and Veegum Pro t o a mixing vessel,
2.) Add Kaopol i te SF and continue mixing w i th h igh shear u n t i l
3 . ) Reduce mixing t o low t o moderate and add AF 9020 and
4 . ) Package i n su i tab le sprayable containers.
SOURCE: GE Si l icones: Formula BP 2001/Formula AP 1010
and, using h igh shear, disperse u n t i l uniform.
a uni form f i n e dispersion i s obtained.
SM 2109 emulsions. Do Not Overmix. These mater ia ls e a s i l y disperse i n a very shor t t ime per iod.
122 Advonced Cleaning Product Formulations
Paste P o l i s h (Oi l - In-Water TYDe)-(l)
Ma te r i a1 s : Part/Wt (%) Pa r t A: SF 96 (350) 4.5 V i s c a s i l (10,000) 2.0 Hoechst Wax S 5.0 Hoechst Wax OP 1 . o S t e a r i c Ac id Isopar M Isopar L Par t 0: Water Morphol ine Kaopo l i t e SF Snow F1 oss Kathon CG Par t C: I sopar M SF 1706
Mate r i a1 s : Par t A: SF 96 (350)
1 .o 8 . 0
18.0
42.7 0.7 8.0 2.0 0.1
5.0 2.0
Paste P o l i s h (Oil- In-Water Tyoe)-(Zl
Par t /Wt (%l
4 . 5 v i scas i 1 (i 0, ooo) Hoechst Wax S Hoechst Wax OP S t e a r i c Ac id Isopar M Isopar L Par t 0: Water Morphol ine Kaopo l i t e 1152 Snow F1 oss Kathon CG Par t C: I sopar M SF 1706
2.0 5.0 1 . o 1 .o 8 . 0
18.0
41.7 0.7 7.8 4.2 0.1
4.0 2.0
Procedure: 1.) Heat Par t A t o 90-95C. (2.) Heat Par t B t o 80-8512. 3.) Add Par t A t o Pa r t 0 w i t h good mix ing . (4.) When homogeneous,
6.) Pour i n t o s u i t a b l e con ta ine rs .
Comments : The pour temperature w i l l depend on equipment, r a t e and degree
o f c o o l i n g a v a i l a b l e on the f i l l i n g l i n e . Wi th slow c o o l i n g r a t e , t h e c o o l i n g c y c l e must be done w i thou t covers t o prevent condensation i n s i d e con ta ine rs . SOURCE: GE S i l i c o n e s : Formula AP 1008
coo l t o 60C and add Par t C w i t h cont inued mix ing . ( 5 . ) Cool t o s u i t a b l e pour temperature, e.g., >50C.
Polishes, Coatings and Finishes 123
Paste Pol ish ( O i p Meteri a1 s: Part/Wt t % l Part A: SF 96 (350) 4.5 V i scasi 1 (10,000) 2.0 Hoechst Wax S 5.0 Hoechst Wax OP 1 . o Stear i c Acid 1 . o Isopar M 8 . 0 Isopar L 18.0 Part B: Water 42.7 Morphol i ne 0.7 Kaopol i t e 11 52 7.5 Snow Floss 2 .5 Kathon CG 0 .1 Par t C: Isopar M 5.0 SF 1706 2.0 1 . ) Heat Part A t o 90-95C. 2 . ) Heat Part 8 t o 80-85C. 3 . ) Add Par t A t o Part B w i th good mixing. 4 . ) When homogeneous, cool t o 60C and add Part C w i t h cont-
5 . ) Cool t o su i tab le pour temperature, e.g., >5OC. 6. ) Pour i n to s u i t a b l e contai ners. Comments :
The pour temperature w i l l depend on equipment, r a t e and degree o f cool ing on the f i l l i n g l i n e . With slow cool ing rate, t h e coo l i ng cyc le must be done without covers t o prevent condensation i nsi de contai ners.
Mater ia ls : Part/Wtt%) Par t A: V i scas i l (10,000) 2.50 Hoechst Wax S 1.80 Hoechst Wax E 2.00 Ross Ozokerite 77Y 0.15 Span 80 2.00 Tween 81 0.15 Isopar L 17.00 Isopar M 5.00 Part B: Water 52.40 Kaopol i t e 11 52 6.00 Snow Floss 3.00 Part C : Isopar M 2.00 SF 1705 4.00 SF 1706 2.00 1. Heat Part A t o 95C. ( 2 . ) Heat Part B t o 8OC. ( 3 . ) Add Part
B t o Par t A w i t h h igh shear mixing. (4 . ) Cool t o 60-65C and add Part C w i t h good mixing. (5.) Cool t o 55C and pour i n t o s u i t a b l e containers.
i nued m i x i ng .
Paste Po l i sh (Outer Phase O i l 2
SOURCE: GE S i l icones: Formula AP 1006(3)/AP 1007
124 Advanced Cleaning Product Formulations
Spray-And-Wipe P o l i s h (Pump)
Mater i a1 s 1 SM 2133 SM 2135 20% Wax Emulsion Water B i o c i de
M a t e r i a l s Pa r t A : Card is 36 Wax Hoechst Wax A3 CS O l e i c Ac id Morphol ine
Par t B: Water B i o c i de
20% Wax EmulKion-.(a
Matey ja l s : Par t A: Card is 36 Wax Hoechst Wax A3 CS O l e i c Ac id Diethylaminoethanol (DEAE)
Par t B: Water B i o c i de
Part/Wt(%) 3.0 2 . 0 2 . 5
92.5 q . s .
20% Wax .Emu 1 s i onr--l )
Sartf W t f U
10.0 10 .0
3.0 4 . 0
73.0 q . s
10.0 10.0
3 . 0 2.5
74.5 q . s .
Prepara t ion o f Wax Emulsion: 1 . ) Add Card is 36 wax, Hoechst wax A3 CS, and o l e i c a c i d t o a
vessel and, w i t h m i l d s t i r r i n g , b r i n g temperature up t o 98-1ooc.
2 . ) When comple te ly melted, add e i t h e r t h e morphol ine or DEAE u n t i l m i x t u r e i s homogeneous.
3.) Add Par t B, preheated t o 95C, s low ly s t i r r i n g t h e wax/soap m ix tu re , ma in ta in ing temperature between 93 and 9BC d u r i n g t h e a d d i t i o n .
4 . ) Cont inue s t i r r i n g u n t i l temperature reaches 45C. 5 . ) Cool t o room temperature.
Prepara t ion o f P o l i s h :
package i n s u i t a b l e con ta ine rs .
SOURCE: GE S i l i c o n e s : Formula FP 3001
Blend a l l i n g r e d i e n t s toge the r w i t h m i l d s t i r r i n g , and
Polishes, Coatings and Finishes 125
Spray 8 Wipe Type-Aerosol o r Non-Aerosol(1)
Concord Co-Wax Emulsion, 12% S i 1 i cone (Union Carbide LE-461) D i s t i 11 ed Water
% by Weiaht 4.1 7.0
88.9
Spray 8 Wipe- Type-Aerosol o r Non-Aerosol(E]
Concord Co-Wax Emulsion, 12% S i l i c o n e (Union Carbide LE-461) S i l i c o n e (Union Carbide LE-462) D i s t i 11 ed Water
Weisht 7.5
12.5 2.5
77.5
Spray & Wipe Type-Aerosol o r Non-Aerosol(3)
Concord Co-Wax Emulsion, 12% S i 1 i cone (Union Carbide LE-461) S i l i c o n e (Union Carbide LE-462) T r i ethanol ami ne Laury l S u l f a t e D i s t i 1 l e d Water
% by Weiqht 7.5
12.5 2.5 1 .5
76.0
The formulas l i s t e d above a re suggested formulas. Every e f f o r t has been made t o op t im ize a l l p r o p e r t i e s t o ge t t h e bes t p o l i s h w i t h regard t o s p e c i f i c amounts o f i n g r e d i e n t s . Formula #1 i s t h e bes t a l l around p o l i s h . I t fea tu res e x c e l l e n t g loss , a p p l i c a t i o n ease and economy. Formula #3 i s an example o f l i g h t foam-type p o l i s h , and o f f e r s b e t t e r removal o f s o i l and emuls- i f i c a t i o n o f p r o p e l l e n t s . Formula #2 i l l u s t r a t e s a h igh g loss fo rmula w i t h e x c e l l e n t p r o t e c t i v e q u a l i t i e s .
L i q u i d Wax-Solvent F u r n i t u r e o r F l o o r P o l i s h
Concord Wax #1600 S i l i c o n e General E l e c t r i c SF 96-100 Safety So lvent (Stoddard So lvent )
% by Weight 6.0 1 .o
93.0
Procedure: Me l t wax and s i l i c o n e together a t a temperature o f 195-200F
i n one h a l f o f t h e so l ven t . The balance o f t h e c o l d so l ven t i s then added t o t h i s s o l u t i o n a f t e r t h e waxes a re melted.
SOURCE: Concord Chemical Co., I n c . : Suggested Formulat ions
12. Rinse Aids
126
RinseAids 127
Automatic Dishwash Rinse A i d (For Hard Water1 A c i d Hard Water Tolerant Formulation
Inaredient : Oeioni zed Water Mazawet 36 G lyco l i c Acid (57%) Isopropyl Alcohol
pH, 1%: 2.0-3.0 Appearance: Clear, s l i ght S p r c i f i c Grav i ty : 1.01
y viscous, l i gh t - ye l l ow
Wt.% 30.00 55.00 10.00 5 . 0 0
i qui d
Procedure: Charge the water and Mazawet 36 t o the mixing vessel and
s t a r t a g i t a t i o n . Charge the G lyco l i c Acid and Isopropyl Alcohol and mix u n t i l c l ea r and f r e e o f " f i s h eyes."
Notes : Formulated f o r areas w i t h hard water. Normal use d i l u t i o n i s 100 ppm i n f i n a l r i n s e cyc le . Conc-
en t ra t i ons o f use so lu t i ons may be adjusted t o meet l oca l needs o r va r ta t i ons i n equipment. Formula CR-101
Automatic Dishwash Rinse A i d <For Neutral o r S o f t Water)
Standard Formulation f o r Neutral o r Sof t Water
Ingredient : Mazawet 36 Oeioni zed Water Isopropyl A1 coho1 Sodi um Hydroxide
Wt.% 55 .00 40.00
5 . 0 0 P.S . t o pH 6.0-7.0
pH. 1%: 6.0-7.0 Appearance; Clear, s l i g h t l y viscous, l i gh t - ye l l ow l i q u i d Spec i f i c Grav i ty : 1.01
Procedure:
u n t i l c l ea r and f r e e o f " f i s h eyes."
Notes : Formulated f o r areas w i t h neutra l o r s o f t water. Normal use d i l u t i o n i s 100 ppm i n f i n a l r i n s e cyc le . Conc-
en t ra t i ons o f use so lu t i ons may be adjusted t o meet l o c a l needs o r v a r i a t i o n s i n equipment.
The formulator may adjust t h e c loud-point o f t h i s system by using add i t i ona l a lcohol t o increase i t o r Sodium Hydroxide t o decrease i t . Formula CR-102
SOURCE: Mazer Chemicals: Suggested Formulations
Charge the ingredients i n t h e sequence given above and mix
128 Advanced Cleaning Product Formulations
Rinse A i d Formula DW-0011
Antarox BL-240 Urea Water Dye
Wt.% 50.0
9.0 41 . O
Procedure 1. Dissolve urea i n water. 2. Add Antarox BL-240 t o water/urea so lu t i on . Mix thoroughly.
Physical PrpDertiea pH (as i s ) : 7.5 pH (1%): 8.1 Viscos i ty : 50 cps Spec i f i c Grav i t y : 1.01
Rinse A i d Formula DW-0012
Antarox BL-225 Isopropanol Water Dye
Procedure 1. Dissolve Antarox BL-225 i n water. Mix thoroughly. 2. Add isopropanol.
Physical Proper t ies pH (as i s ) ; 6.1 pH (1%): 8 .3 Viscos i t y : 30 cps Spec i f i c Grav i ty : 0.99
SOURCE: Rhone-Poulenc Surfactants & Specia l t ies: Formulas
Wt.% 70.0 20.0 10 .0 -
13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners
129
130 Advanced Cleaning product Formdations
Basic F loor Cleaner. Liauid-A
Marlon A 360 o r A 365 Marl i pal 01 3/99 Solvent BG* Tetrapotassium pyrophosphate Sodi um metasi 1 i c a t e pentahydrate KNA cumene sulphonate 40 Ammonia, 25% Balance water, fragrance, preservat ive
Act ive matter: 7.0%
Basic F loor C1 eaner, L i aui d-B
Mar l i pa l 013/99 Marl owet 5622 Solvent BG* Tetrapotassium pyrophosphate Ammonia, 25% Balance water, fragrance, preservat ive
Act ive matter: 6.7%
Floor Cleaner. f o r Everyday Use. Liauid-A
Marlon PS 65 L i poxol 12000* Marlamid DF 1218 Isopropanol* Fragrance Balance water, dyes tu f f
Act ive matter: 4.7%
Floor Cleaner. f o r Everyday Use. Liauid-B
Mar l i pa l KF C i t r i c ac id Isopropanol* Fragrance Balance water, dyes tu f f
% 7.0 3.0 3.0 5.0 5.0 10.0 1 .o
t o 100
!% 3.0 4.0 20.0 3.0 1 .o
t o 100
% 5.0 6.0 1.5 20.0
0 . 5 t o 100
!% 3.0 0.2 25.0 0.5
t o 100
Act ive matter: 3.0%
SOURCE: Huls America, I n c . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
&g, Floor, Catpet, Upholstery ShampOchF and Cleaners 131
CarDet and UDhol s t e w C1 eaners Dry-Foam C 1 eaner. L i aui d-A
M a r l i n a t SRN 30 Methacry la te copolymer, e.g. Syntran 6520 N i t r i l o t r i a c e t a t e powder Balance water, f ragrance, p rese rva t i ve
A c t i v e mat te r : 9.0%
Dry-Foam C1 eaner . L i aui d-B
M a r l i n a t SRN 30 N i t r i l o t r i a c e t a t e powder Balance water, f ragrance, p rese rva t i ve
A c t i v e ma t te r : 12.0%
Dry-Foam Cleaner. Powder-A
M a r l i n a t SRN 30 Methoxypropanol Technocell 90 DU Balance water, f ragrance, p rese rva t i ve
A c t i v e mat te r : 1.5%
Dry-Foam Cleaner, Powder-B
M a r l i n a t DFK 30 Methoxypropanol Technocell 90 DU Balance water, f ragrance, p rese rva t i ve
% 3 0 . 0 20.0
1 .o t o 100
% 40.0
0.5 t o 100
% 5 . 0 5 . 0
50.0 t o 100
% 5.0 5.0
50.0 t o 100
A c t i v e mat te r : 1.5%
SOURCE: Hu ls America, I n c . : Bas ic Formulat ions o f Detergents and Cleaning Agents f o r Houaehold Purposes
132 Advanced Cleaning Product Formulations
Carpet Shampoo, Hiah Foam
Water Pe t ro BAF L i q u i d W i t c o l a t e WAC-LA
B lend ing Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d .
%__by Weigh2 10.0 15 .0 75 .0
Pe t ro BAF, i n combinat ion w i t h sodium l a u r y l s u l f a t e , reduces t h e low temperature c loud p o i n t , g i v i n g e x c e l l e n t f reeze/thaw p r o p e r t i e s . The Pet ro BAF combinat ion d r i e s l e s s tacky than sodium l a u r y l s u l f a t e alone.
Formula 911
Carpet. Shampoo, H i &h -Foam
Water Pe t ro BAF L i q u i d W i t c o l a t e WAC-LA
?4 by Weight 78 .3
5 . 0 1 6 . 7
B1 endi ng Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d .
Pe t ro BAF, i n combinat ion w i t h sodium l a u r y l s u l f a t e , reduces t h e low temperature c l o u d p o i n t , g i v i n g e x c e l l e n t f reeze/thaw p r o p e r t i e s . The Pe t ro BAF combinat ion d r i e s l e s s tacky than sodium l a u r y l s u l f a t e alone.
Formula 908
SOURCE: Witco Corp.: Suggested Formulat ions
Rug Floor, Carper, Uphktety Shampoos and Cleaners 133
Evaporative (No Rinse) Wax S t r i ppe r Formula FC-0056
Miranol JEM Concentrate Monoethanol ami ne Butoxyethoxypropanol Isopropanol Water
Procedure
Phvsi c a l ProDerti es
Add t h e ingredients and mix u n t i l uniform.
Appearance: Clear s o l u t i o n pH, as i s : 1 1 . 4 Viscos i ty : t 1 0 cps Spec i f i c Grav i ty : 0.97
Waxed F loo r Cleaner Formula FC-0055
Rhodaf ac RA-600 A1 kami de DC 212/S Tetrapotassium Pyrophosphate (60% Act ive) Water
Wt.% 0.5 6.5 2.5
1 9 . 0 ' 72 .5
Wt.% 5.0 1 . o
25.0 69.0
=Q
a f t e r each add i t i on . Add ingredients one by one, i n order l i s t e d above, mixing wel l
Phvsi c a l ProDerti es pH. as i s : 8.6 pH (1%): 8.6 V i scos i t y : 10 cps Spec i f i c Grav i ty : 1 . 0 4
SOURCE: Rhone-Poulenc Surfactants & Specia l t ies: Formulas
134 Advanced Cleaning product Formulations
F1 oor C l eaner Formula FC-0053
Rhodafac LO-529 Sodi um Tr ipolyphosphate Tetrasodium Pyrophosphate Water
Wt.% 6.0 3.0 3.0
8 8 . 0
Procedure 1. D isso lve s o l i d s i n t h e t o t a l amount o f water. 2. Add Rhodafac LO-529. Mix thorough ly .
Phvsi c a l ProDert i es pH, as i s : 13.9 pH (1%): 8.9 V i s c o s i t y : 60 cps S p e c i f i c G r a v i t y : 1.09
F l o o r Cleaner Formula FC-0054
Wt.% Rhodafac LO-529 5.0 A1 kami de DC-212/S 1 .o Tetrasodium Pyrophosphate (65% Ac t i ve ) 2.0 T r i sodi um Phosphate 1 .o D ie thy lene Glyco l Monoethyl Ether 1 .o Water 90.0 Perfume and Co loran ts added, as des i red , r e p l a c i n g water
Procedu r e 1. D isso lve Tetrasodium Pyrophosphate i n water. Add Tr isodium
2. Add Rhodafac LO-529 and Alkamide DC-212/S. 3. Add so lvent .
Phosphate. D i sso l ve thorough1 y .
1 pH. as i s : 11.0 pH (1%?: 9.0 V i s c o s i t y : 290 cps S p e c i f i c Grav i t y : 1.01
SOURCE: Rhone-Poulenc Sur fac tan ts & S p e c i a l t i e s : Formulas
F l o o r P o l i s h Mor-Glo 2-457 20% S o l i d s
Use w i t h low speed spray b u f f i n g and h igh speed maintenance programs us ing p l u g - i n e l e c t r i c burn ishers and s y n t h e t i c pads. Produces h ighe r i n i t i a l g loss than t h e 442 fo rmu la t i on . Can be burn ished d a i l y o r on an i n t e r m i t t e n t schedule w i thou t p roduc ing excessive amounts o f dus t . M u l t i p l e recoats o f 4-5 coa ts per a p p l i c a t i o n a re recommended w i t h 30-45 min. d r y i n g t ime depending on s o l i d s . Wi th these maintainance procedures a cons is ten t h i g h l e v e l o f appearance can be sus ta ined over an extended p e r i o d o f t ime.
___ Item: 1 2 3 4 5 6 7 8 9
10
Components: Wei Qh t Water D ie thy lene Glyco l Monoethyl Ether T r i bu toxyethy l Phosphate F luorad FC-129 (1% a c t i v e s o l u t i o n ) A n t i foam Emu1 s i on* Proxel GXL Mor-Glo 2 Latex (38%) Morton Conrez 510 (25% s o l u t i o n ) AC-325 An ion ic (35%) E-43 Nonionic (40%)
Percent 47.07
3 .37 2 .95 0 .50 0.02 0 .10
39 9 49 1 .oo 2 .51 2 .19
Procedure: Wi th good a g i t a t i o n add t h e components i n t h e order l i s t e d .
A f t e r t h e a d d i t i o n o f i t e m #6, a l l o w t o mix f o r 30 min. b e f o r e con t inu ing . Add t h e remaining components s low ly .
Formula t ion Constants: Polymer/Resin/Wax Ra t io : 90/0/10 Typ ica l pH: 8 . 5 Formula t ion Dens i ty : 8 .54 l b s . / g a l . S p e c i f i c G r a v i t y : 1.026
TvDi c a l Densi t y Val ues: __- S o l i d s : Pounds/Qal.
2 5% 8.60 20% 8 .54
S p e c i f i c G r a v i t y 1.032 1 .026
15% 8 .49 1.019
*SAG 1010 f rom Union Carbide Corp., o r SWS 211 f rom Wacker S i 1 icones Corp.
SOURCE: Morton I n t e r n a t i o n a l , I n c . : Formula Mor-Glo 2-457 20% Sol i d s
Rug, Floor, Carpet, Upholsfery Shampom and Cleaners 135
136 Advanced Cleaning Roduct Formulations
Floor Po l i sh ML-870-389 20% So l i ds
Use w i t h low speed spray b u f f i n g and high speed maintenance programs. This product maintains a h igh i n i t i a l g loss and can be burnished on an i n t e r m i t t e n t schedule. With these mainten- ance procedures, a consistent h igh l e v e l o f appearance can be sustained over an extended pe r iod o f t ime. Up t o f i v e coats per app l i ca t i on may be appl ied w i th 30-45 min. d ry ing t i m e depending on s o l i d s and condi t ions.
Item: 1 2 3 4 5 6 7 8 9 10 1 1 12
Components: Water Diethylene Glycol Monoethyl Ether T r i butoxyethyl Phosphate D i b u t y l Phthalate Igepal CO 977 F l uorad FC-129 (1% so lu t i on ) Ant i foam* Proxel GXL ML-870 Latex (38%) Morton Conrez 510 (25% so lu t i on ) AC-325 Noni oni c (35%) E-43 Nonionic (40%)
W_ei qht Percent 42.36 4.97 1.24 0.65 0.20 0.60 0.02 0.10 34.89 7.45 4.01 3.51
Procedure:
A f t e r t he add i t i on o f i tem #8, al low t o mix f o r 30 minutes before cont inuing. Add the remaining components s lowly.
Formulation Constants: Polymer/Resin/Wax Rat io: 74/10/16 Typical pH: 8.0 Formulation Density: 8.52 l bs . /ga l . Speci f i c Grav i ty : 1 .023
With good ag i ta t i on , add t h e components i n the order l i s t e d .
Typical Densi ty Values: Sol i ds : Pounds/Gal . Speci f i c Grav i ty 2 5% 8.57 1.029 2 0% 8.52 1.023 15% 8.47 1.017
*SAG 1010 from Union Carbide Corp., o r SWS 211 from Wacker
SOURCE: Morton I n t e r n a t i o n a l : Formulation ML-870-389 20% Sol ids
S i 1 i cones Corp.
Water SXS-40% Sodi um Bicarbonate STPP Burcosperse AP-Liq Burco LAF-6
Water Burcoterge DG-40 Burcosperse AP-Liq Propylene Glycol So rb i to l 70% Burcotase SL-80
Rug, Floor, Carpet, Upholsfery Shampom and Cleaners 137
L i aui d Carpet Cleaner
Carpet S ta in Remover-Liauid
Carpet Cleaner/Booster-Dry Destai ner
Burco LAF-6 Soda Ash FB-Sodi um Percarbonate
% bv We- 72.5 10.0 5.0 5.0 5.0 2.5
% by Weight To 100
40 10 20 15
0.5-1 . o
96 bv Weipht 2.0-6.0 40-60 40-60
Above a l so e l iminates odors such as those caused by pet ur ine.
General ly 5 ounces o f above added t o 5 ga l lons o f detergent Oxidizes s ta ins such as cof fee, wine, j u i ce , e t c .
s o l u t i o n i s s u f f i c i e n t f o r good performance.
SOURCE: Bur l ington Chemical Co., Inc. : Suggested Formulations
138 Advanced Cleaning Product Formulations
Low Cost Ex t rac t i on CarDet Cleaner
Water, D . I . Petro 22 Powder EDTA Powder Perfume
Blending Procedure:
Use D i l u t i o n : 1-2 ot /ga l o f water
Formula 901
Blend ingredients i n the order l i s t e d .
% bv Weight 91 . o
5.0 4.0 Q . S .
Medium Cost Steam Ex t rac t i on Carpet Cleaner
Water, D . I . Petro 22 Powder Sodi um T r i po l yphosphate Sodium S i l i c a t e 42 Be' (Star)* T r i sodi um Phosphate, Crystal DeSonic 9N Perfume
*Pa Corp.
Blend ingredients i n the order l i s t e d 01 end1 ng Procedure:
Use D i l u t i o n : 1-2 oz/gal . o f water
Formula 902
% bv Weight 76.5
3.5 5.0 9.0 2.0 4.0 q . s .
Premium. Heavy Duty Steam Ex t rac t i on Carpet Cleaner
Sodium Tripolyphosphate, L igh t Density Sodium Metas i l i ca te , Pentahydrate Petro 22 Powder Opt ica l Br ightener
01 endi ng Procedure:
Use D i l u t i o n : 1-2 oz/gal
Formula 906
SOURCE: Witco Corp.: Suggested Formulations
Blend ingredients i n the order l i s t e d .
% by Weight 40.0 54.5
5 . 0 0 . 5
Rug, Floor, Carper, Upholstery shonrpocrs and Cleaners 139
Non-Ammaniated F loor S t r i m e r
Water Sodium Metas i l icate, Pentahydrate Monoethanolamine Potassium Hydroxide, 45% Witcamide S-771 Buty l Cel losolve Witconate SXS L i q u i d
%-by Weight 65.44
1 .oo 16.25 3.25 8.00 4.06 2.00
Blending Procedure:
between each add i t i on .
Typical Propert ies: Sol ids: 13.3% pH, as i s : 13.3
Blend ingredients i n the order shown, mixing thoroughly
Formula 924
Non-Ammoniated F loor S t r i m e r
Monoethanolamine Witcamide S-771 Buty l Cel losolve
9b bv Weiaht 40.0 20.0 40.0
81 endi ng Procedure:
between each addi t ion.
Typical Propert ies: Sol ids: 20.0% pH, as i s : 11.4
Blend ingredients i n the order shown, mixing thoroughly
Formula 923
SOURCE: Witco Corp.: Suggested Formulations
I40 Advanced Cleaning R h t FormJatiotu
Quarry T i l e Cleaner
I n q r e d i e n t s : Water Bi o -Sof t S-1 00 Makon 10 Hydroxy A c e t i c Ac id (70%) HC1 (37%)
M i x i ng Procedure :
Typ ica l P roper t i es :
Mix thorough ly i n o rder g iven .
Appearance: L i g h t ye l low, c l e a r l i q u i d p H , as i s : 1.87 S p e c i f i c G r a v i t y , g/ml: 1.01 V i s c o s i t y , @ 25C, cps: 15
S t a b i l i t y : 40F ( 7 days): Pass 75F ( 7 days): Pass 120F ( 7 days) : Pass Freeze/Thaw ( 3 c y c l e s ) : Pass
% bv WeiQht 88.0
4 .0 3.5 3.0 1 . 5
Use I n s t r u c t i o n s :
pour concent ra te d i r e c t l y on. Spread w i t h mop and leave f o r t e n minutes. Scrub and squeegee, r i n s e w i t h water . Dry w i t h c lean mop.
leave f o r f i v e minutes, then scrub, r i n s e , and d ry .
SOURCE: Stepan Co.: Formula t ion No. 582
One t i m e o n l y : Heav i l y s o i l e d f l o o r : wet f l o o r w i t h water and
D a i l y Cleaning: 4 oz/l ga l water d i l u t i o n . Apply w i t h mop and
L o w Foam Floor Cleaner
Water Sodium M e t a s i l i c a t e (Anhydrous) Tetrapotassium Pyrophosphate Mona NF-10
% by Weisht 70
5 14 11
Procedure: Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n .
Typi c a l Proper t i es : Cloud P o i n t : 93C K r a f t P o i n t : C O C
Recommended Use D i l u t i o n : 1 t o 4 o z . / g a l .
SOURCE: Mona I n d u s t r i e s , I n c . : Formula t ion F-545
Rug, Floor, Carpet, Uphoktery Shampoos and Cleaners 141
SDeci a1 -PurDose F loo r C1 eaner . L i aui d-A
Marlon A 365 Marlophor ND-DEA-salt Marlowet T or 5622 Na cumene sulphonate 40 T r i ethanol ami ne* Tetrapotassium pyrophosphate Balance water, fragrance, preservat ive
Act ive matter: 16.5% Formulation A w i t h a n t i s t a t i c p roper t i es
Special-Purpose F loor Cleaner. L iauid-6
Marlon PS 65 Isopropanol* Lonzabac 12.30 N i t r i l o t r i a c e t a t e , 40% Balance water, fragrance, preservat ive
Act ive matter: 3.3% Formulation B w i t h microbic ida l p roper t i es
Wash-and-Wax Floor Cleaner. L i aui d-A
Mar l i pa l 013/79 Marlox FK 64 Marlowet 5622 N i t r i l o t r i a c e t a t e powder C i t r i c a c i d Wax emulsion. 15%. basis Vestowax AW 1060* Balance water, fragrance, preservat ive
Act ive matter: 9.5%
%
5.0 10.0
5.0 10.0 4.0 6.0
t o 100
% 5.0
25.0 3.0 0.5
t o 100
% 5.0 3.0 2.0 0.2 0.3 10.0
t o 100
Wash-and-Wax F1 oor Cleaner, L i aui d-B
% Marl i pa l 01 3/60 8.0 Marlowet 5622 2.0 N i t r i l o t r i a c e t a t e powder 0.2 C i t r i c ac id 0.3 Wax emulsion, 15%, basis Vestowax AW 1060* 10.0 Balance water, fragrance, preservat ive t o 100
Act ive matter: 10.0%
SOURCE: Huls America, I nc . : Basic Formulations o f Detergents and Cleaning Agents f o r Household Purposes
14. Miscellaneous
142
Miscellaneous 143
Condensate TL: Typ ica l Formulat ions
A l l Purpose Cleaner Condensate TL Harco 20% Soap STPP Water
Bubble Bath Diethanolamine Laurel S u l f a t e (35% A c t i v e )
Stepanol DEA Condensate TL Water
D i l u t a b l e Shampoo(l:8) Diethanolamine Laurel S u l f a t e (35% Ac t i ve )
Stepanol DEA Condensate TL
Isopropanol H2S04 (conc.) (TO pH 7.0-7.5)
V i scous F loo r Cleaner Condensate TL TSPP STPP Harco 20% Soap Water
5 . 0 % 50.0%
1-2% To 100%
30.0% 5.0% 65.0%
60.0% 35.0%
1.15% 4%
9.0% 4.0% 4.0%
20.0% 63.0%
Di shwashi ne L i au i d Sodium Xylene Su l fonate 4.0% Dodecylbenzene S u l f o n i c Ac id 12.5% Noni on i c Detergent 6.0% Condensate TL 3.0% 50% Caust ic Soda Ad jus t t o pH o f 7 . 0 + - 0 . 5 SDA 3A Alcohol 2.0 Dye 8 Perfume Water To 100%
ODacif ied Hand SoaD Opaci f i e r Water So lub le Lano l i n Condensate TL Conc. Coconut/Veg. O i l Potash Soap Perfume 8 Dye Water
0.70% 1.25%
12.5% 20.0%
To 100%
SOURCE: Concord Chemical Co., I n c . : Suggested Formulat ions
I44 Advanced Cleaning product Formulations
d' Limonene Waterless Hand Cleaner
Phase I: Water, D.I. T r i sodi um Phosphate Sodium C i t r a t e G1 yce r i ne
Phase 11: d ' L i monene DeSonic 9N Varonic T202
% by Weight
81 .o 1 . o 2.0 2.0
7.0 5.0 2.0
Blending Procedure:
Heat t o 140F. Combine Phase I1 ingredients i n separate vessel and mix thoroughly. Heat t o 140F. While mixing rap id l y , add Phase I1 t o Phase I. Cool qu i ck l y t o s t a b i l i z e emulsion.
Typical Propert ies: Appearance, Room Temp.: Heavy Cream Sol ids: 12.0% pH: 10.4
I n vessel #1 combine Phase I ingredients and mix thoroughly.
Formula 1120
Water1 ess Hand C1 eaner
Emphos PS-220 Kerosene, deodorized Stoddard Solvent, deodorized T r i ethanol ami ne, 99% Water
% by Weight 8.7
37.9 15.4 2.2
35.8
81 ending Procedure:
between each add i t i on .
Formula 1119
SOURCE: Witco Corp.: Suggested Formulations
01 end i ngredi ents i n the order shown, m i x i ng thorough1 y
Miscellaneous 145
D r y Cleanina
By using Aerosol OT-100% Surfactant i n d ry c leaning solvent a t a concentrat ion o f ca. 0.1 oz. /gal . t he soaps used as a ids i n water-soluble s t a i n removal can be replaced i n t h e d ry c leaning indust ry . I n contrast t o many soaps, Aerosol OT does not ox id i ze w i t h consequent development o f undesirable odor upon aging.
Aerosol OT-100% dissolved i n a s u i t a b l e solvent, such as t r i ch lo roe thy lene . naphtha, carbon te t rach lo r i de , or comb- i n a t i o n s o f these, can be used t o remove solvent-soluble s ta ins a f t e r f a b r i c s have become wet w i t h water. The mixture can then be f lushed out w i t h add i t i ona l water.
As a whitener f o r k i d gloves, i t i s recommended t h a t 4 oz. o f Aerosol OT-100% be dissolved i n a ga l l on o f Stoddard solvent, t o which may be added from 4 t o 8 oz. o f z inc s tearate.
A water brushing f o r r e t a i n i n g p lea ts i s made by d i sso l v ing 4 oz. o f Aerosol OT-100% Surfactant i n one-half ga l l on o f Stoddard solvent, t o which i s added one p i n t o f wet spot ter and one-half p i n t o f water. The p leated items should be brushed thoroughly w i t h the mixture, then simply hung i n t h e a i r t o dry, t o e l im ina te water. The i tem should be re-cleaned w i t h solvent t o dispose o f t he other agents present. It w i l l come out wi thout wr ink les o r d is turbed p lea ts .
Sa t i s fac to ry s p o t t i n g mixtures can be made as fo l lows:
To1 uol 3 q t . Perch1 oroethyl ene 1 q t . Water 1/2 p t .
1 . Aerosol MA-80 Surfactant* 1 l b .
* I f Aerosol OT i s used instead o f Aerosol MA, t he mixture becomes t u r b i d when water i s added.
2. Aerosol OT-100% Surfactant 1 l b . Stoddard Solvent 2 ga l . Water 3 p t .
I n order t o increase the wet t ing out (reduce the break t ime) o f except ional ly greasy a r t i c l e s , t he use o f 0.25% to 1.0% of a 10% aqueous s o l u t i o n o f Aerosol OT Surfactant (based upon t h e weight o f t he water) i s resorted t o occasional ly i n laundry pract ices. During except ional ly busy periods, t he use o f 10% aqueous Aerosol OT so lut ions w i l l reduce the treatment t me and thus increase e f f i c i ency , although i t i s t r u e t h a t a k a l i together w i t h hot water over a longer treatment per iod w 11 accomplish the same r e s u l t s . A l k a l i w i t h hot water f i x e s egg albumin whereas Aerosol OT Surfactant does no t .
SOURCE: Cytec Indus t r i es Inc. : Suggested Formulations
146 Advanced Cleaning product Formulations
Dust Cont ro l
Areas o f Use:
o f t a l c o r face powder, m i l l i n g g r a i n and sawing wood are a l l f i r e , exp los ion and/or h e a l t h hazards. Such dus ty cond i t i ons can be a l l e v i a t e d o r c o n t r o l l e d by water sprays con ta in ing small amounts o f Aerosol GPG Sur fac tan t . Reasons f o r Using Aerosol GPO Sur fac tan t :
r a t i o n s o f o n l y 0.01% t o 0.05% o f Aerosol GPG Sur fac tan t i n water p rov ide e f f i c i e n t and economical we t t i ng . Areas t o be Sprayed:
c r e a t i o n o f dus t . Dusty m a t e r i a l s be ing conveyed may a l s o be sprayed. Th is p r a c t i c e no t o n l y minimizes t h e problem o f a i rbo rne dust, b u t s imultaneously reduces product l oss . Spray heads may be l oca ted a t as many l o c a t i o n s as have dust problems because t h e equipment requ i red i s moderate i n cos t and t h e r e i s no hazard t o personnel f rom Aerosol GPG Sur fac tan t .
Dust r e s u l t i n g f rom opera t ions such as mining coa l , p roduc t i on
Most dus ts a re r e s i s t a n t t o w e t t i n g by water alone. Concent-
Work sur faces may be wetted w i t h a f i n e spray t o prevent
Concentrat ions o f Aerosol GPG Sur fac tan t c We1 h t Ino red i en ts : Aerosol GPG Sur fac tan t Ethanol Water Ina red i en ts : Aerosol GPG Sur fac tan t Ethanol Water Ina red ien ts : Aerosol GPG Sur fac tan t Ethanol Water Ing red ien ts : Aerosol GPG Sur fac tan t Ethanol Water Ing red ien ts : Aerosol GPG Sur fac tan t Ethanol Water Procedure:
The s tock s o l u t i o n may stream by a p r o p o r t i o n i n g t h e f i n a l s o l u t i o n may be
- 1% 1.43 none
t o make 100 p a r t s - 5%
7.15
t o make 100 p a r t s - 10%
14.3
t o make 100 Dar t s
10-20
15-20
25% 35.7
10-15 t o make 100 Dar t s
- 50% 7 1 . 5
15-20 t o make 100 p a r t s
be in t roduced i n t o t h e main water DumD o r an eductor. The s t rena th o f . . ad jus ted by changing t h e amount o r
s t r e n g t h o f t h e s tock s o l u t i o n be ing added. The range o f s t reng th concent ra t ions shown i n t h e t a b l e above w i l l a l l o w any o rd ina ry method o f meter ing.
Fu r the r c o n t r o l may be prov ided by use o f ad jus tab le spray heads.
SOURCE: Cytec I n d u s t r i e s Inc . : Suggested Formulat ions
Miscellaneous 147
Hand and Body Cleanser
Phase I: Water, D . I . Witconate AOS Varonic LI-48 Varonic LI-67 Ethylene Glycol Monostearate Varamide ML-1
Phase 11: Glycer ine Lanoquat 50 EDTA Rewoteric AM 8-15
Phase 111: C i t r i c Acid
Phase I V : Sodium Chlor ide
Phase V: Preservat i ve
96 by Weight
67.0 20.0 3.7 1.3 1.6 2 . 5
0.2 0.5 0.1 3.1
q.s.
q.s.
q.s.
Blending Procedure: Heat Phase I water t o 8OC. Blend i n Witconate AOS w i t h good
a g i t a t i o n . When t h i s i s blended completely, add the remaining Phase I ingredients , mel t ing them f i r s t before adding. Cool t o 45C and add Phase 11, i n the order l i s t e d . Cool t o 35C and adjust pH = 7.0-7.7 w i t h c i t r i c acid. Add sodium ch lo r i de t o desired v i scos i t y .
Typical Propert ies: Sol ids: 19.5% pH: 7.3
SOURCE: Witco Corp.: Formula 1125
148 Advanced Cleaning Product Formulations
Heavv Dutv Deareaser
Butoxyethanol Mac kam JS Sodium Metas i l i ca te Pentahydrate Sodi um T r i po l yphosphate T r i sodi urn Phosphate T a l l O i l Fa t t y Acid KOH (45%) EDTA (40%) Deionized Water
Procedure: 1. Add components t o water and heat t o 40C. 2 . Blend u n t i l c l e a r .
Mackamide CD TKPP Glycer in Mackadet 40K
Procedure:
Burni sh i na Colnpound
(Cocami de DEA)
(Potassium Coconut Soap)
Weiqht,% 8 . 0 3.5 3.0 1.5 2.5 2.0 2.1 0.3 77.3
Wei qht .% 93.0 1.5 2.7 2.7
1. Disperse TKPP i n Glycer in and add Mackadet 40K. 2. Then blend i n Mackamide CD.
Remarks :
The product upon d i l u t i o n w i t h water w i l l form a cloudy emulsion which requi res shaking before use.
The f i n a l product w i l l form an almost water c l e a r product.
Corrosion I n h i b i t i n g Coating O i 1 -Emulsi f iable
Wei aht .% Mackazoline 0 (Oleyl Hydroxyethyl Imidazol ine) 16.5 L igh t Mineral O i l 75.0 Glac ia l Acet ic Acid 1.5 Ole ic Acid 7 .0
Procedure: 1. Blend Mackazol i n e 0 and Mineral O i 1. 2. Add Acet ic Acid and Ole ic Acid. 3. Blend u n t i l c l ea r .
SOURCE: McIntyre Group Ltd. : I n d u s t r l a l Formulary
Miscellaneous 149
Heavy D u t y I n d u s t r i a l Spray Metal Cleaner Concentrate
Water Potassi um Hydroxide Sodium M e t a s i l i c a t e (Anhydrous) Sodium Carbonate Mona NF-25
% by Weiaht 65 10 10
5 10
Procedure:
Typ ica l P roper t i es : Cloud P o i n t : 43C K r a f t Po in t : C O C
Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n .
Recommended Use D i l u t i o n : 6 t o 8 o z . / g a l .
Formula t ion F-544
Low Foam Hypoch lo r i t e Cleaner
I n redients;. water Sodium Hypoch lo r i t e (5.25%) Mona NF-10
% bv Wei qh t 79.0 19.0
2 . 0
Procedure: Blend i n g r e d i e n t s i n o rder l i s t e d . Ad jus t pH t o 13-14 w i t h 45%
KOH . Formula t ion F-655
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulat ions
Metal CleanerJBri nhtener
Eastman EB so l ven t C i t r i c a c i d Phosphoric a c i d (85%) Nonionic s u r f a c t a n t * Water
% by WeixhL 4.5 4.0 2.5 3 .0
86.0
*Such as Neodol 91-8 a l coho l e thoxy la te (She l l Chemical Co.) o r Rhodasurf LA-9 a lcoho l e thoxy la te (Rhone-Poulenc).
SOURCE: Eastman Chemical Co.: Eastman EB and DB So lvents f o r Cleaners: Suggested Formula t ion
150 Advanced Cleaning Product Formulations
Hot l a n k - StripperjCleaner/Deruster
Component: Caust ic Potash Crys ta l Anhydrous Sodium M e t a s i l i c a t e Burco BSGH-270 o r BSGH-Crystals Burco ADS-100 Burco TME Dodecylbenzenesulfonate Powder
10.0 15.0
5.0 2.5 5.0
Procedure:
on to m ix tu re and b lend u n t i l f u l l y absorbed. Add 8urco ADS-100, Gluconate o r Glucoheptonate and Dodecylbenzenesulfonate. Blend u n t i 1 un i fo rm.
inc rease p a i n t s t r i p p i n g e f f i c i e n c y prov ided s u f f i c i e n t a l k a l - i n i t y i s present. The Gluconate o r Glucoheptonate p rov ide t h e de rus t i ng . Burco TME and 8urco ADS-100 prov ide removal and d i sp - e r s i o n o f p a r t i c u l a t e s o i l s w h i l e t h e Dodecylbenzenesulfonate adds w e t t i n g and o i l y s o i l detergency. Each component can be ad jus ted according t o t h e improvement needed.
Blend Caust ic Potash and Sodium M e t a s i l i c a t e . Spray Burco TME
Each component has a s p e c i f i c f u n c t i o n . The M e t a s i l i c a t e w i l l
~~ Low Foam _Heavy Duty A1 k a l i ne C l eaner-A
CommDonent: %. bx_Wei.&t Water 58 Sodium M e t a s i l i c a t e , Pentahydrate Burcene 100 Burcosolv TM Burco TME Burcowet TM-LF
5 2
10 20
5
Procedure:
eous between each a d d i t i o n . Add a l l components i n t h e order l i s t e d . S t i r u n t i l homogen-
Formulat ion A i s low foaming a t temperatures above 160F.
Low Foam Heavy-Duty A1 k a l i ne. Cleaner-6
Component: Water Sodium M e t a s i l i c a t e , Pentahydrate Sodi um Xylene Sul fonates 40% Burcosolv TM Burco TME Burco LAF-125
% by Weight 55 5 8.5
10 20
5
Procedure:
between each a d d i t i o n .
SOURCE: B u r l i n g t o n Chemical Co., I nc . : Suggested Formulat ions
Add a l l components i n t h e order l i s t e d . S t i r u n t i l homogeneous
Formulat ion B i s low foaming above 1OOF.
Miscelloneous 151
Pai n t Brush C1 eaners
Aerosol C-61 Surfactant i s a c a t i o n i c reagent t h a t w i l l a c t i v a t e s t rong ly the v o l a t i l e solvents commonly used f o r removing p a i n t . B r i s t l e brushes and r o l l e r s , glass, porce la in , metal, p l a s t i c , and c l o t h i n g have been t rea ted successful ly. A 5 1 0 % s o l u t i o n o f Aerosol C-61 i n a solvent, o r mixed solvents i s recommended.
Extremely rap id sedimentation o f p a i n t pigment has been obtained w i t h t h e fo l l ow ing composition:
Inaredi ents: Aerosol C-61 Surfactant Buty l Cel loso lve Solvent Xyl ene
% by Weight o r Volume
5 5
90
Brushes and r o l l e r s may be cleaned immediately a f t e r use by being suspended i n t h i s mixture. I n a few hours p r a c t i c a l l y a l l o f t he p a i n t pigment s e t t l e s i n a l aye r beneath the b r i s t l e s . The solvent mix ture may be reused repeatedly. When the pigment has s e t t l e d the brush may be removed and hung i n c i r c u l a t i n g a i r t o dry. For best resu l t s , t he brush then should be washed i n soapy water and r insed. I f the brush i s t o be used again immediately, i t may be r insed i n solvent instead o f d ry ing and waterwashi ng.
w i t h hard, dry pa in t , t h e fo l l ow ing formulat ion has proved suc- essf u l .
For renovat ing brushes t h a t have been allowed t o become caked
Ingredients : Aerosol C-61 Surfactant Xyl ene Butanol Mineral Spi r i t s
?4 by Weight o r Volume
10 45
5 40
The brush i s soaked i n the mixture f o r a time, then worked up and down t o a i d the penetrat ion i n t o the caked p a i n t . The soaking and working may be repeated several t imes i f the p a i n t i s very hard and d ry . When the o l d p a i n t has soaked out o f t he brush, t h e brush i s r insed i n clean, warm water and f i n a l l y washed i n soapy water and r i nsed again, then hung up t o d ry . A f t e r being d r i e d t h e b r i s t l e s have the appearance and f e e l of those o f a new brush.
SOURCE: Cytec Indus t r i es Inc. : Suggested Formulations
I52 Advanced Cleaning product Formulations
Steam Cleaner
Water Potassi um Hydroxide Sodium M e t a s i l i c a t e (Anhydrous) Tetrapotassium Pyrophosphate Mona NF-15
% by WeiQht 65
3 10 10 12
Procedure: Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n .
Typ ica l P r o p e r t i es : Cloud P o i n t : 75C K r a f t P o i n t : >OC
Recommended Use D i l u t i o n : 4 t o 6 o z . / g a l .
Formula t ion F-541
Water Sodium Hydroxide (50%) Mona NF-25
Helvy Duty Indus-ray c l e a n e r Concentrate
% by Weigh% 40 50 10
Procedure: Add i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n .
Typ ica l P r o p e r t i e s : Cloud P o i n t : 75C K r a f t P o i n t : >5C
Recommended Use D i l u t i o n : 1 t o 4 o z . / g a l .
Formula t ion F-543
H igh Sol i ds A1 k a l i ne C1 eaner
Water Potassium Hydroxide Sodium M e t a s i l i c a t e (Anhydrous) Tetrapotassium Pyrophosphate Mona NF-25
% bv Weiclht 45.0 10 .0 10 .0 25.0 10.0
Procedure: Mix i n g r e d i e n t s i n t h e order l i s t e d w i t h a g i t a t i o n .
Formula t ion F-555
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested Formulat ions
Miscellaneous 153
Wall DaDer Removal
A s tock s o l u t i o n o f Aerosol OT-75% Sur fac tan t , o r a powder con ta in ing Aerosol OT-B Sur fac tan t can be prepared f o r use as a wal lpaper remover. D i l u t e d w i t h water by t h e user t o a con- c e n t r a t i o n o f 0.025% Aerosol OT, t h e s o l u t i o n i s h i g h l y e f f e c t - i v e i n soaking o f f o l d wal lpaper, and o f t e n renders t h e use of an expensive and bu lky steamer unnecessary.
A t y p i c a l l i q u i d concent ra te wal lpaper remover can be prep- ared as fo l l ows .
I nq red i en ts : Aerosol OT-75% Sur fac tan t I sop ropy l Alcohol Water
% by Weisht 15.0 15.0 70.0
D i r e c t i o n s : Use one tablespoon o f t h e above fo rmu la t i on per g a l l o n o f
warm water. Apply t o a l a r g e sec t i on o f wal lpaper and w a i t a few minutes. I f necessary, apply again.
Aerosol OT-B Sur fac tan t : The f o l l o w i n g powdered concent ra te may be prepared us ing
Inq red ien ts : Sodium S u l f a t e (Powder) Aerosol OT-B Sur fac tan t
% by Weiqht 90.0 10.0
D i r e c t i o n s :
recommended above.
SOURCE: Cytec I n d u s t r i e s , I nc . : Suggested Formulat ions
Use one teaspoonful per g a l l o n o f warm water and apply as
Section II Transportation Cleaners
and Polishes
154
15. Auto Cleaners and Polishes
155
156 Advanced Cleaning Roduct Formulations
Auto Pol i sh/Cl eanser O i l i n Water Emulsion
Phase A: 1 Deionized Water 2 668 P o l i s h i n g Powder 3 Vo lc lay NF-BC Phase 0: 4 PEG-10 Carnauba
6 Montan Wax "S" 7 O l e i c Ac id 8 Morphol ine Phase C: 9 Odorless Minera l S p i r i t s
5 SF96-350
% by Weiqht 40.5 15.0
1 . o
7.0 4.0 2.5 1 .5 1 .o
27.5
Procedure:
hydra te f o r 15 minutes. B r ing temperature up t o 75C. I n a separate vessel , combine Phase B and w h i l e mixing, b r i n g temperature up t o 85C t o me l t t h e waxes. Gent ly heat t h e minera l s p i r i t s t o 65C and add t o Phase 0. Once un i fo rm and a 75C temp- e r a t u r e i s reached, s low ly add t h i s t o Phase A, ma in ta in ing good a g i t a t i o n . Continue mix ing u n t i l emulsion coo ls t o 40C. Pour i n t o app rop r ia te conta iners .
emulsion, w h i l e p rese rv ing t h e s t reng th and i n t e g r i t y o f a n a t u r a l carnauba f i n i sh.
Combine Phase A under a g i t a t i o n and a l l o w t h e Vo lc lay t o
The PEG-10 Carnauba i n t h i s formula he lps t o c rea te a s t a b l e
Detergent Res is tan t Auto Pol i sh/Cleanser Paste Wax
1 Odorless Minera l Spi r i t s 2 787 P o l i s h i n g Alumina P-10 Fe ins t 3 Ozoker i te 170 4 #3 Carnauba 5 Syn the t i c Carnauba 6 SF1706 7 Hexanedi o l Behenyl Beeswax 8 V i s c a s i l 12M
% by WeiQht 57.0 12.0 8.0 6 .0 6.0 5.0 4.0 2.0
Procedure:
8OC. Mix u n t i l homogeneous. Add t h e alumina w h i l e mixing, and coo l t o 35c.
equal p a r t s o f #3 Carnauba and Syn the t i c Carnauba. Th is s u b s t i - t u t i o n has no e f f e c t on t h e f i n i s h e d product and w i l l y i e l d t h e same r e s u l t s . The o n l y d i f f e r e n c e i s a reduc t i on i n cos t .
SOURCE: Koster Keunen I n c . : Suggested Formulat ions
Combine a l l i ng red ien ts , l eav ing ou t t h e alumina, and heat t o
The #1 Yel low Carnauba i n t h i s formula has been replaced by
Auto Cleaners and Polishes 157
Carnauba Hotwax
Carnauba spraywax w i th excel lent performance and s t a b i l i t y i s produced using:
Inaredi ent : Mineral seal o i l Tomah Emu1 s i f i e r Four 9-10 mole ethox. nonionic Ethylene g l yco l monobutyl ether Water (70-9OF) Emulsion C-340
Wei aht% 9.0 6.9 0.3 1.3
67.5 15.0
Add ingredients sequent ia l ly and mix completely p r i o r t o each add i t i on . The carwash w i l l use the "hotwax" by d i l u t i n g 1:lO w i t h water and then i n j e c t i n g 6-8 0 2 . o f the d i l u t e product onto each car. The product w i l l not separate or g e l l .
Pressure Spray Truckwash
Water Sodium Metas i l i ca te Pentahydrate EDTA ( l i q u i d 46%) Tomah Q-17-2 Tomah AO-14-2 Texstim 0741 45% Caustic Potash Tomah A l k a l i Surfactant
Wei aht% 05.7 4.2 1.8 1 . o 1 .o 2.0 2.6 1.7
Texstim 0741 i s a nonionic sur factant which performs as a "sel f -demulsi fy ing" detergent. This i s extremely useful i n truckwash appl icat ions. I n most o i l /wa te r separators, the formulat ion " s p l i t " t he o i l and water i n t o two phases without f u r t h e r treatment. The o i l phase can then be skimmed o f f f o r recovery o r disposal and not be sent t o the sewage treatment p lan t .
SOURCE: Tomah Products, Inc. : Suggested Formulations
158 Advanced Cleaning Product Formulations
D e t e r q e n t R e s i s t a n t A u t o P o l i s h O i l i n Water Emuls ion
% bv Weight Phase A: 1 D e i o n i z e d Water 44.3 2 678 P o l i s h i n g Powder 8.0 3 V o l c l a y NF-BC 1 .o 4 Morpho l ine 0 . 7 Phase B: 5 I s o p a r L 1 8 . 0 6 I s o p a r M 8 . 0 7 PEG-I0 Carnauba 6 .0 8 S i l i c o n y l Beeswax 6 .0 9 SF96-350 3 .0 10 S t e a r i c A c i d 1 . o Phase C : 11 I s o p a r M 5 . 0 12 SF1706 2 .0 Procedure:
Combine Phase A under a g i t a t i o n and b r i n g tempera ture up t o 85C. I n a s e p a r a t e v e s s e l , combine Phase B and w h i l e m i x i n g , b r i n g t h e tempera ture up t o 9OC. Once b o t h phases a r e up t o tempera ture , add Phase B t o Phase A and m a i n t a i n moderate a g i t - a t i o n . S l o w l y c o o l and a t 60C add Phase C .
The S i l i c o n y l Beeswax p e r f o r m s w h i l e a p p l y i n g t h e p o l i s h b y c r e a t i n g a smooth, even c o a t i n g on t h e s u r f a c e o f t h e au tomobi le . The PEG-10 Carnauba t o g e t h e r w i t h t h e amine f u n c t i o n a l s i l i c o n e , g i v e s t h e p o l i s h e d s u r f a c e a deep g l o s s and an e x t r e m e l y d u r a b l e f i n i s h .
H i g h L u s t e r Auto F i n i s h Pas te Wax
1 Odor less M i n e r a l S p i r i t s 2 I s o p a r L 3 I s o p a r M
5 #3 Carnauba 6 S y n t h e t i c Carnauba 7 O z o k e r i t e 170 8 Whi te Beeswax 9 V i s c a s i l 12M
4 SF96-350
% by Weight 49 .0 14.0 10.0 8 . 0 6 .0 6 .0 3 .0 2 .0 2 . 0
Procedure: Combine a l l waxes and s i l i c o n e s . Heat t o 85C. W h i l e m i x i n g ,
s l o w l y add t h e s o l v e n t s . Cont inue m i x i n g and c o o l t o 40C. Equal p a r t s o f #3 Carnauba and S y n t h e t i c Carnauba a r e used
w i t h t h e i n t e n t i o n s o f t h e s e b e i n g a d i r e c t s u b s t i t u t e f o r #1 Y e l l o w Carnauba. The #3 Carnauba and S y n t h e t i c Carnauba w i l l y i e l d t h e same r e s u l t s as #1 Y e l l o w Carnauba, b u t a t a s i g n i f - i c a n t c o s t s a v i n g s .
SOURCE: K o s t e r Keunen I n c . : Suggested F o r m u l a t i o n s
Auto Cleoners ond P o l i s h 159
High Gloss, Detergent Res is tan t P o l i s h
Formula t ion 20-6 i s a wax-free p o l i s h , which p rov ides a h igh- g loss , de tergent r e s i s t a n t f i n i s h on non-porous subs t ra tes . Simple a p p l i c a t i o n , w i thou t hard rubb ing o r b u f f i n g r e s u l t s i n bo th depth o f g loss and de tergent res i s tance f o r extended p r o p e r t i e s .
I ng red ien ts : ( 1 ) GP-121 S i l i c o n e P o l i s h A d d i t i v e ( 2 ) GP-10-1,000 S i l i c o n e F l u i d ( 3 ) Stoddard So lvent ( 4 ) Minera l S p i r i t s (Odor less) ( 5 ) Witcamide 511 (6 ) Kaopo l i t e SF (7) S o f t Water ( 8 ) Giv-Gard DXN
Combine i n o rder shown w i t h h igh shear m ix ing un t i n g occurs. Mix u n t i l homogeneous and package.
Formul a t i on P roper t i es : *Contains no wax *Non-smeari ng *High g loss *Cost e f f i c i e n t *Detergent r e s i s t a n t *Cold b lend (0n ly mix * E a s i l y a p p l i e d *Res is tan t t o wash-o
Formula 20-6
High Gloss Auto P o l i s h f F i n i s h
% by weight 13.0 2.0 5.5
1.4 5.0
67.5 0.1
5.5 ,
1 th i cken -
ng requ i red ) f
Ing red ien ts : ( 1 ) GP-121 ( S i l i c o n e P o l i s h A d d i t i v e ) (2 ) Witcamide 511 (3) Kaopo l i t e SF ( 4 ) S o f t Water ( 5 ) Giv-Gard DXN
% by. Weight 26.0
1.4 5.0
67.5 0.1
Combine i n o rder shown w i t h h igh shear m ix ing u n t i l t h i c k e n i n g occurs. Mix u n t i l homogeneous and package.
Formula t ion P roper t i es : *Contains no wax *High g loss *Detergent r e s i s t a n t *Easi 1 y appl i e d *Non-smeari ng *Cost e f f i c i en t *Cold b lend Only mix ing requ i red
Formula 20-5
SOURCE: Genesee Polymers Corp.: Suggested Formulat ions
160 Advanced Cleaning Roduct Formulations
Spravwax Concentrate
The fo l l ow ing formula should produce a c lea r , s tab le spraywax concentrate.
Comonent: Kerr-McGee Mineral seal o i 1 Emul s i f i er 827 Ethylene g l yco l monobutyl ether Water (70-9OF)
Grams 18.0 15.0
4 . 0 63.0
D i r e c t ions :
monobutyl ether and m i x u n t i l c l ea r . Add water s lowly wh i l e mixing. When water has been added, mix about 5 more minutes. Add dye i f desired. Addi t ion o f a fragrance may requ i re a s l i g h t formulat ion change. The f i n a l product w i l l be c lea r and i s normally packaged i n 5 ga l l on p a i l s . The carwash should d i l u t e 5 ga l lons o f concentrate w i th 50 ga l lons o f water and then i n j e c t about 6 02s. o f the d i l u t e spraywax through a DEMA system onto each ca r .
Charge the mineral seal o i l , Emu ls i f i e r 827, ethylene g l yco l
Spraywax
The fo l l ow ing t y p i c a l formulat ion i s h igh l y e f f e c t i v e , problem f ree, and s tab le i n both concentrate and d i l u t e form.
Inaredi ent : Kerr McGee Mineral Seal O i l Emul s i f i e r Four-HF 9-10 mole ethoxylated nonionic Ethylene g l yco l monobutyl ether Tap Water
Weiaht % 20.0 15.0 1 .o 3.0
61 . O
Di rec t i ons :
nonionic, ethylene g l yco l monobutyl ether and mix u n t i l c l ea r . Add water s lowly wh i l e mixing. When water has been added, mix about 5 more minutes. Add dye i f desired. Addi t ion o f a f rag- rance may requ i re a s l i g h t formulat ion change. The f i n a l product w i l l be c lea r and i s normally packaged i n 5 ga l l on p a i l s . The carwash should d i l u t e 5 ga l lons o f concentrate w i t h 50 ga l lons o f water and then i n j e c t about 6 0 2 s . o f the d i l u t e spraywax through a DEMA system onto each car .
SOURCE: Tomah Products, I n c . : Suggested Formulations
Charge the mineral seal o i 1, Emuls i f ier Four-HF, ethoxylated
Auto Cleaners and Polishes 161
Spravwax Ladder of Formulas
Because mineral seal o i l s d i f f e r i n emu ls i f i ca t i on char- a c t e r i s t i c s , i t i s necessary t o modify the formulat ion t o achieve optimum performance. The best formula can be deter- mined by running a ladder o f formulas. Typical examples are:
Comonent: Mineral seal o i l Emul s i f i er Four-HF 9-10 mole ethoxylated nonionic Ethylene g l y c o l monobutyl ether Water
Component: Mineral seal o i l Emul s i f i er Four-HF 9-10 mole ethoxylated nonionic Ethylene g l yco l monobutyl ether Water
Comoonent: Mineral seal o i l Emu ls i f i e r Four-HF 9-1 0 mole ethoxyl ated noni oni c Ethylene g l yco l monobutyl ether Water
Components: Mineral seal o i l Emul s i f i e r Four-HF 9-10 mole ethoxylated nonionic Ethylene g l yco l monobutyl ether Water
Grams-B 40.0 31 . O
1 .o 6.0
122.0
Grams-C 40.0 30.5
1.5 6 . 0
122.0
Grams-D 40.0 30.0 2.0 6 .0
122.0
Grams-E 40.0 29.5 2.5 6 .0
122.0
Check a l l formulas f o r : 1. 1: lO d i l u t i o n i n water. 2 . 120F s t a b i l i t y (3 hours i n sealed container i n water bath a t
3 . Freeze/thaw-24 hour recovery (sealed conta iner) .
The optimum formula w i 11 : 1. D i l u t e c l e a r and e a s i l y a t 1:lO dT lu t i on . 2. Not c loud at . 120F. 3. Recover completely from freeze/thaw cyc le (wi thout shaking).
SOURCE: Tomah Products, I n c . : Emu ls i f i e r Four-HF: Formulas
120F).
16. Car and Truck Wash Compounds
162
Car and Truck Wash Compounds 163
Automatic Car Wash Concentrate A High A lka l i ne D i l u t a b l e Concentrate
Inaredi ent : Oeioni zed Water Maphos 60-A Potassi um Hydroxide Tetrapotassium Pyrophosphate Sodium Metas i l i ca te , Anhydrous Macol LF-120 Mazamide 80 Sodium Xylene Sul fonate (40%) Macol 48 Oei oni zed Water
pH (as i s ) : 12.5-13.5 Appearance: Clear, l i gh t - ye l l ow l i q u i d Spec i f i c Grav i ty : 1.06
Procedure: Charge the f i r s t water p o r t i o n t o t h e mixing vessel and
s t a r t a g i t a t i o n . Add t h e ingredients i n the given sequence and mix u n t i l c l e a r . Notes :
This i s a h i g h l y a l k a l i n e cleaner designed t o be used i n commercial automatic car washes a t a d i l u t i o n r a t e o f 1-2 ounces per ga l lon. Do not use d i r e c t l y on automotive f i n i shes . Formula CA-102
Wt.% 50 .00
6 . 0 0 3.00 2.00 2.00 2.00 2 .00 3.00 3.00
27.00
General Purtmse Car Wash High Foami ng A1 1 -Purpose D i 1 u tab l e Concentrate
Ineredi ent : Wt.% Deioni zed Water 50.00 Mazon 98 9.50 Macol TD-3 1.50 SLS (Sodi um Lauryl Sul fate) 2.50 Mazamide 80 3.00 Macol 48 1 .oo Triethanolamine (85%) 1.50 Deionized Water 31 .OO
pH (as i s ) : 8.5-9 .5 Appearance: Clear, l i g h t - y e l l o w l i q u i d Spec i f i c Grav i ty : 1.02
Procedure: Charge t h e f i r s t p o r t i o n o f water t o the mixing vessel and
s t a r t slow a g i t a t i o n . Excessive a g i t a t i o n w i 11 produce a foami ng problem. Add the remaining ingredients i n the given sequence and mix u n t i l c l ea r . Notes:
t o be safe on car f i n i shes , yet e f f e c t i v e i n t h e removal o f road grime and other s o i l s .
Formula CA-103
SWRCE: Mazer Chemicals: Supposted Formulations
This i s a copious-foaming, al l -purpose car wash formulated
Use concentrat ion i s 1-2 ounces per ga l l on o f warm water.
164 Advanced Cleaning R h c t Formulations
Auto Shampoo Concentrate
Water, D.I. Rewoteric AM KSF-40 Wi tco late SE-5
% by Weight 80.0 15.0
5.0
Blending Procedure:
between each add i t i on . Typical Propert ies:
V iscos i ty , cps: 4.0 Sol ids: Q.O% pH: 9.5
Add ingredients i n order shown and d isso lve completely
Formula 628
High Foaming Car Wash
Water, D.I. D i ethanol ami ne Witco 1298SA Varox 1770 Buty l Cel losolve Sodi urn Metasi 1 i c a t e Sodium Tripolyphosphate
% by Weight 65.0
5.0 15.0 10.0
1 . o 1 . o 3.0
01 endi ng Procedure:
1298 i n t o so lu t i on . Next, add remai n i ng ingredients a1 lowi ng t o d isso lve completely between addi t ions. Typical Propert i es :
Viscos i ty . cps: 77.0 Sol ids: 27.5% pH: 9.3
Add DEA t o water and mix thoroughly. Slowly d isso lve Witco
Formula 631
Car Wash
Water Wi tco late A W i t c o l a te S-l285C Emcol NA-30 Preservat ive Blending Procedure:
Blend ing red ien ts i n the order l i s t e d . Typi ca l Propert i es :
Sol ids: 28.4% pH: 6.9 V i scos i t y , cps: Gel
Formula 623 SOURCE: Witco Corp.: Suggested Formulations
% by Wei aht 34.9 25.0 25.0 15.0 0.1
Car and l h c k Wash Compowrds 165
Car Wash L i q u i d Formula TR-0023
A1 k y l benzene s u l f o n i c a c i d Sodium xy lene s u l f o n a t e Igepa l CO-710 Tetrapotassium pyrophosphate (60% a c t i v e ) Potassium hydrox ide (45% a c t i v e ) Water
W t .% 6 . 0
11 .5 3 . 0
2 5 . 0 2 . 5
5 2 . 0
-
Procedure 1 . D i sso l ve a1 k y l benzene s u l f o n i c a c i d i n water. 2 . A d d sodium xy lene su l fonate , Igepa l CO-710, t e t rapo tass ium
pyrophosphate and potassium hydroxide, m ix ing w e l l a f t e r each a d d i t i o n .
3. F i l t e r p roduc t .
Phys ica l P r o p e r t i e s pH (as i s ) : 9 . 5 pH (1%): 9.9 V i s c o s i t y : 10 cps S p e c i f i c G r a v i t y : 1 .05
Car Wash Powder Formula TR-0022
Igepa l CO-710 Sodi um t r i po l yphospha te Sodium m e t a s i l i c a t e pentahydrate Sodium carbonate ( L t . d e n s i t y )
W t .% 1 0 . 0 50.0
5 . 0 35 .0
Procedure: 1 . Mix Igepa l CO-710 w i t h sodium t r i po l yphospha te . 2 . Add sodium m e t a s i l i c a t e pentahydrate and sodium carbonate
Phys ica l P roper t i es : Appearance: White, f r e e - f l o w i n g powder pH (1%) : 11 .2 S p e c i f i c G r a v i t y : 0 . 7 3
SOURCE: Rhone-Poulenc Sur fac tan ts & S p e c i a l t i e s : Formulas
166 Advanced Cleaning Product Formulotiom
Igepa l CO-660 Cheel ox BF-13 Sodi um Xylene Sul fonate Water
Procedure 1 . D isso lve sodium xy 2. Add Igepa l CO-660.
Phys ica l Propert i-eg pH (as i s ) : 10.3 DH (1%): 10.1
Economy Truck Wash High-pressure Spray
(Formula TR-0024)
ene s u l fonate Mix thorough ly .
n water . Add Cheelox BF 13.
V i s c o s i t y : 10 cps Speci f i c G r a v i t y : 1 .02
Truck Wash L iqu id Formula TR-0025
Igepa l CO-630 Rhodapex CO-436 A1 kami de DC-212/S Cheelox BF-13 Ethy lene G lyco l Monobutyl Ether Water
W t .% 3.0 1 . o 1 .5
84.5
Procedure 1 . D isso lve s u r f a c t a n t s Igepa l GO-630, Rhodapex CO-436 and
2. Add Cheelox BF-13. Mix w e l l . 3. Add e thy lene g l y c o l monobutyl e the r .
Phys ica l PrQpe-rti 89 pH (as i s ) : 9.9 pH (1%): 9.6 V i s c o s i t y : 10 cps S p e c i f i c G r a v i t y : 1.01
A1 kami de DC-212/5 i n water .
SOURCE: Rhone-Poulenc Sur fac tan ts & S p e c i a l t i e s : Formulas
W t .% 3.0 3.5 2.0 3 .5 3.0
85.0
Gar and h k Wash Compounds 167
Water, D . I . * Caustic Soda, 50% Witco 1298SA Witco late SE-5 Petro BAF L iqu id W i tcami de 128T Formal i n Sodium Chlor ide
Foamy Brush Car Wash. L i q u i d
% by Weight 79.75
1.40 5.00 7.00 3.00 3.00 0.10 0.75
Blending Procedure:
used t o ad just v i s c o s i t y o f t he product.
Typical Propert i es:
Blend ingredients i n the order l i s t e d . Sodium Chlor ide i s
Spec i f i c Grav i ty : 1.015 Wt./Gal. l bs . : 8.46 pH, as i s : 9.8 Viscos i ty , cps: 410
D i l u t i o n Rat io a t Wand = 1:40 * I f unsoftened tap water i s used, add 0.25% l i q u i d EDTA,
40% t o counteract hardness.
Formula 621
1:2 D i l u t a b l e Car Wash
Water Sodium Hydroxide, 50% Witconate SXS (40%) Witco 12988 W i tcami de 128T W i tcami de CDA
Blend4 ng Procedure:
Typi c a l Propert i es :
Blend ingredients i n t h e order l i s t e d .
Sol ids: 54.0% pH. as i s : 8.5 Viscos i ty , as i s , cps: 580 Viscos i ty , 1:2. cps: 440
Formula 622
SOURCE: Witco Corp.: Sugueated Formulations
% by Weight 33.71 5.96
14.90 25.88 16.76 2.79
I68 Advanced Cleaning Product Formulations
High O i l S p l i t t i n g Vehic le Wash-A
Components: Water Sodium Metas i l i ca te Pentahydrate TKPP Sodi um Xylene Sul fonates 40% Burco TME
% by Weiqht 71.5 10.0
2 . 5 6.0
10.0
Add i n t h e order l i s t e d . Blend u n t i l d issolved between each add i t i on .
High O i l S D l i t t i n g Vehic le Wash-B
Components: Water Sodium Metas i l i ca te Pentahydrate Burcosol ADS-40 Glycol Ether Burco TME Burcotrope 1250
% by Weiqht 73.5 10.0
5.0 5.0
10.0 As Required
Add i n t h e order l i s t e d . Blend u n t i l d issolved between each add i t i on .
SOURCE: Bu r l i ng ton Chemical Co., I n c . : Suggested Formulations
Car and Truck Wosh Cornpout& 169
L i aui d Car Wash Formula TR-0020
Rhodapon SB Alcodet SK Rhodasurf 25-9 Tetrapotassium pyrophosphate Sodi um metasi 1 i c a t e Water Perfume Dye
Formula Formula A B
W t T % wtT% 1 8 . 0 18.0 ---- 8 . 0 --- 8 . 0
3.0 3.0 2.0 2.0
69.0 69.0 Q . S . Q . S . Q . S . Q . S .
Procedure
i n water. Add Rhodapon SB. Ag i ta te u n t i l c l ea r . Add Alcodet SK and Rhodasurf 25-9 and mix u n t i l uni form and c lea r . Add perfume and dye, as desired.
Physical ProDertiea
Dissolve tetrapotassium pyrophosphate and sodium metas i l i ca te
Appearance: Clear l i q u i d , dyed t o preference pH: 12.0 Spec i f i c Grav i ty : 1.03 V iscos i t y : t50 cps
Spray-On Car Wash Concentrate "Grease and Grime" Remover
Formula TR-0021
Rhodacal A-246/L Rhodacal 330 Rhodapon BOS Alcodet SK Water
Wt.% 5.0
20.0 3.3 5.0
66.7
Procedure: 1. Charge water t o a vessel equipped w i t h a g i t a t i o n . 2 . Add Rhodacal A-246/L and Rhodapon 00s t o ( 1 ) above. Mix u n t i l
3. Add Rhodacal 330 and Alcodet SK t o (2) above. Mix u n t i l
Phvsi ca 1 Proper t igp Appearance: Viscous, gel -1 i ke 1 i q u i d pH. as i s : 9.0 Spec i f i c Grav i ty : 1.02-1.04 V iscos i t y : t50 cps
uni form (5-10 minutes).
uni form (15-30 minutes).
SOURCE: Rhone-Poulenc Special t iem a Surfactmtm: Formulas
I70 Advanced Cleaning Product Formulotions
L i q u i d Hiah Pressure Concentrate
Water, D.I. Oowanol EB Witconate SXS L iqu id Sodium Benzoate Sodium Metas i l i ca te Tetrapotassium Pyrophosphate Varion AM-KSF-40%
% by Weiaht 46.0
2 . 0 1 .o 1 .o 10.0 20.0 20.0
Blending Procedure:
between each add i t i on .
Typical Propert ies: V i scos i t y , cps: 15 Sol ids: 39.4% pH: 13.4
Formula 605
Add ingredients i n order shown and d isso lve completely
Truck Wash w/Vararide A-83
Water, D . I . Sodium Tripolyphosphate T r i sodi um Phosphate Sodium Metas i l i ca te Varami de A-83 Buty l Ce l l osol ve
% by Weight 81 . o
3.0 3.0 1 .o 9.0 3.0
Blending Procedure:
between each addi t ion.
Typical Propert ies: V iscos i ty , cps: 1 2 Sol ids: 16.0% pH: 11.0
Formula 608
SOURCE: Witco Corp.: Suggested Formulations
Add ingredients i n order shown and d isso lve completely
Car and Truck Wash Compounds 171
L i q u i d Truck Wash Formula TR-0029
Water Mi rano l FBS Igepa l CA-630 Dowanol EB (Dow Chemical ) Potassi um Hydroxide (45%) T a l l O i l Tetrapotassium Pyrophosphate Sodium M e t a s i l i c a t e , Pentahydrate
Wt.% 73.6
6.0 3.0 2.0 4.0 3.4 4.0 4.0
Procedure Premix t h e t a l l o i l and Dowanol EB. Add t h e water t o
t h e mixer . Add t h e sodium m e t a s i l i c a t e , t h e potassium hydroxide and t h e TKPP. Add t h e Mi rano l FBS and Igepa l CA-630. Add t h e t a l l oi l /Dowanol EB premix. Mix u n t i l uni form.
Phys ica l ProDer t ies Appearance: Clear, amber l i q u i d pH, as i s : 12.7 S p e c i f i c G r a v i t y : 1.08 V i s c o s i t y : 6 0 cps
L i q u i d Truck Wash Formula TR-0030
Water Mi rano l FBS Rhodafac RA-600 Igepa l CA-720 Cheel ox BF-13 Tet rapotass i um Pyrophosphate Potassi um Hydroxide (45%) Sodium M e t a s i l i c a t e Pentahydrate Arcosolv PTB
Wt.% 63.0
4 . 0 2.0 2.0
17.5 1 .o 6.0 2.0 2.5
Phvsl c a l P rooer t i es Appearance: C1 ear, ye1 1 ow 1 i qu i d pH, as i s : 12.9 S p e c i f i c Grav i t y : 1.10 V i s c o s i t y : <SO cps
SOURCE: Rhone-Poulenc Sur fac tan ts & Spec
Procedure Add t h e i ng red ien ts i n t h e order l i s t e d and mix u n t i l uniform.
as a1 t i 8s : Formu
172 Advanced Cleaning product Formulations
M i l d Car Shampoo
A m i l d r i c h foaming car shampoo w i t h e x c e l l e n t detergency and sheet ing a c t i o n , I n a r e d i en ts : % ComDosi t o n W / W Sandobet SC 4.5 DDBSA, 60% 10.8 Sandoxylate SX-424 3 .6 Tr ie thano lamine 0 . 8 Dye, Fragrance, P rese rva t i ve , Water Q.S. Procedure:
Charge water t o m ix ing vessel w i t h moderate a g i t a t i o n . Ho ld ou t smal l p o r t i o n o f t h e water t o d i s s o l v e dye. Charge t h e r e - maining components i n sequence, mix ing a f t e r each a d d i t i o n . D isso lve t h e dye w i t h a g i t a t i o n i n t h e water p r e v i o u s l y h e l d ou t and add t o t h e produc t . P roper t i es :
Appearance: C1 ear 1 i qu i d
A p p l i c a t i o n : Use 1 t o 2 oz per 5 g a l l o n bucket SOURCE: Sandoz Chemicals Corp. : Formula t ion HHA-01
pH: 7.0-8.0
Carspray CW Concentrate
% by Weight Water, D . I . 80.0
B lend ing Procedure:
s o l u t i o n i s homogeneous. Typ ica l P roper t i es :
S o l i d s : 11.6% Formula 632
Carspray CW 20 .0
Add Carspray t o water w h i l e mix ing . Continue mix ing u n t i l
Automotive "Wash 8 Wax"
% by Weiqht Witcamine AL42-12 6.9 Isopropanol 1 . o G l a c i a l A c e t i c Ac id 2.1 Water 65.0 Witcamide 5195 25.0 B lend ing Procedure:
Heat t h e m i x t u r e t o 70C and then add Witcamide 5195. Cont inue m ix ing u n t i l s o l u t i o n i s c l e a r .
T h i s f o r m u l a t i o n leaves a water "beading" f i l m on t h e auto- mobi le f i n i s h ,
Formula 636
Mix a l l i n g r e d i e n t s except Witcamide 5195 i n t h e order l i s t e d .
SOURCE: Wi tco Corp.: Suggested Formulat ions
Car and Truck WaFh Compounds I73
Premium CarsDrav 500 Concentrate
Carspray 500 B u t y l C e l l oso l ve Minera l Seal O i l * Water, D . I .
?6 by Weight 20.0
5 . 0 25.0 50.0
*Kermac 600 So lvent : Ker r McGee O i l Co. D i a l a A O i 1 : Shel 1 Chemical I sopar V : Exxon Chemical
B1 endi ng Procedure :
thorough ly . I n a separate vessel weigh i n t h e water. Whi le m ix ing t h e water, pour i n t h e blend. Mix u n t i l s o l u t i o n i s homogeneous.
Use D i l u t i o n :
Combine Carspray, B u t y l Ce l l oso l ve and O i l i n vessel and mix
5 g a l l o n s Concentrate t o 50 g a l l o n s water.
Carspray 500: Beading Agent w i t h s i l i c o n e . Comments:
Formula 687
Standard Carspray 500 Concentrate
Carspray 500 B u t y l Cel l o s o l v e M ine ra l Seal O i l * Water, D . I .
*Kermac 600 So lvent : Ker r McGee O i l Co D i a l a A O i 1 : Shel 1 Chemical I sopar V : Exxon Chemical
% by Weipht 16.0 3.0
20.0 61 .O
81 endi ng Procedure: Combine Carspray, B u t y l Ce l l oso l ve and O i l i n vessel and
mix thorough ly . I n a separate vessel weigh i n t h e water. Whi le m ix ing t h e water, pour i n t h e b lend. Mix u n t i l s o l u t i o n i s homogeneous.
Use D i 1 u t i on :
Comments :
5 g a l l o n s Concentrate t o 50 g a l l o n s water.
Carspray 500: Beading Agent i n s i l i c o n e
Formula 688
SOURCE: Wi tco Corp.: Suggested Formulat ions
174 Advanced Cleaning Product Formulations
Premium Carspray 700 Concentrate
Carspray 700 Minera l Seal O i l * Water, D . I .
*Kermac 600 Solvent: Kerr McGee O i l Co. D i a1 a A O i 1 : She1 1 Chemical Isopar V : Exxon Chemical
%_by Wei qh t 25.0 25.0 50 .0
Blending Procedure:
heat t o l l O F w i t h thorough mix ing . I n vessel #2, weigh i n t h e water and mix u n t i l a vo r tex i s formed. Whi le mix ing t h e water, pour t h e b lend i n t o t h e vo r tex . Mix u n t i l s o l u t i o n i s homo- geneous.
Use D i l u t i o n :
I n vessel #1, combine Carspray 700 and Minera l Seal O i l and
5 ga l l ons Concentrate t o 50 ga l l ons water.
Comments : Carspray 700: Foaming beading agent
Formula 685
Standard Carspray 70-0 Concentrate
Carspray 700 Minera l Seal O i l * Water, D . I .
*Kermac 600 So lvent : Kerr McGee O i l Co. D i a l a A O i l : She l l Chemical Isopar V : Exxon Chemical
% u Y A ! h t 16.0 16.0 68.0
Blending Procedure:
heat t o l l O F w i t h thorough mixing. I n vessel #2, weigh i n t h e water and mix u n t i l a vo r tex i s formed. While mix ing the water, pour t h e b lend i n t o t h e vo r tex . Mix u n t i l s o l u t i o n i s homog- eneous.
Use D i l u t i o n :
I n vessel #1, combine Carspray 700 and Minera l Seal O i l and
5 g a l l o n s Concentrate t o 50 ga l l ons water.
Comments :
Formula 686
SOURCE: Witco Corp.: Suggested Formulat ions
Carspray 700: Foaming beading agent
17. Whitewall Tire Cleaners
175
176 Advanced Cleaning Product Formulations
W h i t e Wal 1 T i r e C leaner
I n g r e d i e n t s : Sodium Metas i 1 i c a t e Sodium T r i p o l y p h o s p h a t e T e t r a p o t a s s i u m Pyrophosphate Sodium L a u r y l E t h e r S u l f a t e S o l i n (35%) Sandopan B Water (warm)
% b y . W t . 2.00 2.00 2.00 4.00 2.30 5.00
83.00
Procedure: Charge t h e w a t e r t o a vesse l w i t h good a g i t a t i o n . Charge t h e
f i r s t t h r e e components and m i x t i l l d i s s o l v e d . Charge t h e remain- i n g p r o d u c t s and m ix t i l l comp e t e l y d i s s o l v e d and f r e e o f g e l p a r t i c l e s .
P h y s i c a l P r o p e r t i e s : Appearance: C l e a r w a t e r whi p H ( a s i s ) : >9.0 T o t a l S o l i d s : 11.0-12.0%
Use L e v e l s :
e t o l i g h t y e l l o w l i q u i d
Fo r f i n a l use, d i l u t e between 4:l and B : l w i t h w a t e r
SOURCE: Sandoz Chemicals C o r p . : F o r m u l a t i o n HHA-03
Bug Remover C o n c e n t r a t e
T r i e thano lami ne (TEA) B u t y l C e l l o s o l v e I s o p r o p a n o l R e w o t e r i c AM 8-15
% by W e i . a 17.14 42.86 17.14 22.86
81 end ing Procedure: B l e n d t h e components i n t h e o r d e r shown. M ix u n t i l homogeneous
D i l u t i o n Ra tes : 1 : 2 E x t r a Heavy Du ty 1 : 4 Heavy Du ty 1 : 16 Medi um Du ty 1 :32 L i g h t Duty
D i 1 u t i on I n s t r u c t i o n s :
m i x i n g u n t i l homogeneous.
Comments:
Add Bug Remover C o n c e n t r a t e t o wa te r w h i l e m
Appearance @ 77F: C r y s t a l c l e a r , y e l l o w l i q u
SOURCE: W i t c o Corp . : Formula 677
Xing; c o n t i n u e
d
Whitewall Ere Cleaners 177
Whitewal l T i r e Cleaner Concentrate Formula TR-0031
Water Mi rano l FBS Sodium M e t a s i l i c a t e , Pentahydrate Potassium Hydroxide (45%) Butoxyethanol
Procedure
Phys ica l ProDer t ies
Add i n g r e d i e n t s i n o rder l i s t e d . Mix u n t i l un i fo rm.
Appearance: Clear, ye l l ow l i q u i d pH, as i s : 12.7 V i s c o s i t y : <50 cps S p e c i f i c G r a v i t y : 1.16
W h i tewa l 1 T i r e C1 eaner L i aui d Formula TR-0027
Igepa l CA-630 Rhodafac RA-600 M-Pyrol N-Methyl-2-Pyrrol idone ( I S P ) Sodium M e t a s i l i c a t e , Anhydrous Sodi um Tr ipolyphosphate Potassi um Hydroxide Water
Wt.% 48.0 22.0 25.0
3.0 2.0
Wt.% 2.0 6.0 2.0 3.0 5.0 1 . 5
8 0 . 5
Procedu PQ 1. D isso lve sodium m e t a s i l i c a t e , anhydrous, sodium t r i p o l y -
phosphate and potassium hydroxide i n t o water. 2. Add Igepa l CA-630, Rhodafac RA-BOO, and M-Pyrol separa te ly ,
m ix ing w e l l a f t e r each a d d i t i o n .
Phys ica l ProDer t iea pH (as i s ) : 13.3 pH (1%): 10.7 V i s c o s i t y : 10 cps S p e c i f i c Grav i t y : 1.03
SOURCE; Rhone-Poulenc Sur fac tan ts a S p e c i a l t i e s : Formulas
18. Miscellaneous
178
Miscellaneous 179
Automobi 1 e W i ndshi e l d Cleaners
Ina red ien ts : Aerosol MA-80 Sur fac tan t Su r fon i c N-95 Isopropanol Water
% by Weiaht 3.5 0.5 51 .o 45.0
The above i s d i l u t e d 5 oz. t o 1 g a l l o n o f water f o r use. I n w in te r t ime , t h e recommended d i l u t i o n i s 10 oz. per ga l l on . Freezi ng i s prevented by t h e i sopropanol . Thi s f o rmu la t i on leaves a small amount o f res idue on t h e unwiped p o r t i o n o f t h e wind- s h i e l d upon d ry ing . There are severa l ways o f p revent ing these v i s i b l e residues.
1 . Use a m ix tu re o f v o l a t i l e so l ven ts w i t h o r w i thou t su r fac tan ts . A suggested fo rmu la t i on i s :
I na red ien ts : 2-Ethyl Hexanol Aerosol OT-75% Sur fac tan t Isopropanol Water
% by Weiaht 5.0 1 . o
47.0 47.0
The above i s d i l u t e d 5-10 0 2 . per g a l l o n o f water, and w i l l n o t f reeze a t t h e h ighe r l e v e l o f concent ra t ion .
2. Using su r fac tan ts , bu t i n c l u d i n g small amounts o f non- v o l a t i l e so l ven ts which g i v e a t ransparent f i l m on t h e g lass w i t h t h e s u r f a c t a n t . Non-vo la t i l e so l ven ts having approximately t h e same r e f r a c t i v e index o f g lass should be se lec ted . A suggested fo rmu la t i on i s :
I nn red ien ts : Aerosol MA-80 Sur fac tan t Aerosol OT-75% Sur fac tan t D ie thy lene Glyco l Isopropanol n-Butyl-p-Hydroxy Benzoate Methyl-p-Hydroxy Benzoate Water
% by Weight 2.5 3.3 4.4
40.0 0 .1 0.1
49.78
The above concent ra te i s used a t 5 02. per g a l l o n (10 02'. per g a l l o n i n w i n t e r ) . The b a c t e r i c i d e s a r e present t o keep t h e window c lean ing s o l u t i o n f r e e o f s l ime and t u r b i d i t y due t o b a c t e r i a . I na red ien ts : % by Weight Aerosol OT-75% Sur fac tan t 3 .5 D i b u t y l ph tha la te 0.5-2.0 Isopropanol 40.0 Water 46-48
The above s o l u t i o n i s d i l u t e d 5-10 02. per g a l l o n o f water and w i l l no t f reeze a t t h e h igher l e v e l o f concent ra t ion .
SOURCE: Cytec I n d u s t r i e s Inc . : Suggested Formulat ions
180 Advanced Cleaning Product Formulations
General PurDose L i q u i d Boat Po l i sh - (1 1
M a t e r i a l s : Pa r t A: SF 96 (350) V i scasi 1 (10,000) O l e i c a c i d Isopar M Hoechst Wax E
Pa r t B: Water Morphol i ne Carbopol 934
Par t C: I sopar M SF 1706
Par t D: Snow Floss Super F loss
General Purpose L i q u i d Boat Po l i sh - (2 )
Mater i a1 s : Pa r t A: SF 96 (350) V i scasi 1 ( 10,000) O l e i c a c i d Isopar M Hoechst Wax E
Pa r t B: Water Morphol i ne Carbopol 934
Par t C : I sopar M SF 1706
Par t D: Kaopol i t e 1 1 68
Part/Wt (%Z
3.50 1 .oo 1.50
10.00 1.50
65.65 1.60 0.25
3.00 2.00
7.50 2.50
Part/Wt(%)
3.50 1 . oo 1.50 10.00 1.50
63.65 1.60 0.25
3.00 2.00
12.00
Procedure: 1.) Heat Par t A t o 90-95C. (2.) Heat Par t B t o 60-85C. 3.) Add Par t A t o Pa r t B w i t h good mix ing . 4 . ) When homogeneous, coo l t o 60-65C and add Par t C w i t h
cont inued h igh shear m ix ing . 5.) Add Par t D w i t h good mix ing . 6.) When un i fo rm, coo l and package i n s u i t a b l e con ta ine rs
SOURCE: GE S i l i c o n e s : Formula BP 2000
Miscellaneous 181
L i a u i d Aluminum Engine B lock Cleaner Formula TR-0032
Water Sodium Metasi 1 i c a t e , Anh Mi rano l FBS M i rano l JEM Conc. A lcodet HSC-1000 D-Limonene
W t .% 82.5
4.5 5 .0 2.0 4.0 2.0
Procedure Completely d i s s o l v e t h e sodium m e t a s i l i c a t e i n t h e water
Add t h e remaining components, w i t h a g i t a t i o n , i n t h e order l i s t e d . Premix t h e 0-Limonene w i t h t h e Alcodet HSC-1000 and add toge the r .
T y p i c a l PropertJ es Appearance: C lea r , ye l l ow t o amber l i q u i d pH, Conc.: 12.75 pH, 10%: 12.15 S p e c i f i c G r a v i t y : 1.04 V i s c o s i t y : t50 cps
Foami ng Engi ne C1 eaner Formula TR-0019
A lcodet 260 Rhodacal 330 Water Isopar " K " (Exxon)
W t .% 2 . 0 8.0
80.0 10.0
Procedure 1. Add A lcodet 260 and Rhodacal 330 t o water a t ambient temp-
e r a t u r e , s t i r u n t i l d i sso l ved (10-15 minu tes) . 2. Add I sopar K a t ambient temperature. S t i r u n t i l d i sso l ved
(30 minutes) . Physi ca l P roeer t i es
Appearance: C lear l i q u i d pH, as i s : 7 . 5 Speci f i c G r a v i t y : 0 .99 V i s c o s i t y : 10 cps
SOURCE: Rhone-Poulenc Sur fac tan ts & S p e c i a l t i e s : Formulas
Section 111 Trademarked Raw Materials
182
Trademarked Raw Materials 183
RAW MATERIALS AC-325 Nonionic
ACL-59
Acrysol ICS-1
Aerosol A-102
Aerosol A-1 03
Aerosol C-61
Aerosol GPG
Aerosol MA-80
Aerosol 0s
Aerosol OT
Aerosol OT-B
Aerosol OT-75%
Aerosol OT-100%
Aerosol 22
AF 9020
Alcodet HSC-1000
Alcodet SK
Alcodet 260
A1 kami de DC-212
A1 kami de DC-212/M
A1 kamide DC-212/S
Aluminum Oxide FPTO
Ammonyx LO
CHEMICAL DESCRIPTION SOURCE Polymer A l l i e d
Ch lo r ina ted isocyanura te Monsanto
Water-soluble a c r y l i c r e s i n Rohm&
Mono-ester su l fosucc i na te Cytec
Mono-ester su l fosucc i na te Cytec
s u r f a c t a n t
s u r f a c t a n t
A1 k y l ami ne-guani d
Sodium d i o c t y l su
Sodium d ihexy l su
A1 k y l naphthalane
Sodium d i o c t y l su
ne e thoxy la te Cytec
fosucc i na te Cytec
fosucc ina te Cyt ec
ox ide su l fona te Cytec
fosucc i na te Cytec
Sodium d i o c t y l su l fosucc ina te Cytec
Sodi um d i o c t y l s u l fosucc i na te( 75%) Cytec
Sodi um d i o c t y l s u l fosucc i na te Cytec
Sul fosucc i namate Cytec
T e r t i a r y t h i o e t h e r su r fac tan t Rhone-
Cleaning s u r f a c t a n t Rhone-
Cleaning s u r f a c t a n t Rhone-
F a t t y a1 kanolamide ISP
F a t t y a1 kanolamide I S P
F a t t y a1 kanolanide ISP
Laurami ne ox ide Stepan
184 Advanced Cleaning Product Formulations
RAW MATERIALS Amphol y t JB130
Antarox BL-225
Antarox BL-240
Antarox BL-330
Aquamoll i n BC Powder
Arcosolv PTB
Avanel N-1525-90
Avanel S-70/5-74/ S-l50/590
BASF Sur fac tan ts
B r i t e s i l H24
Burcene 100
Burco ADS-40
Burco ADS-100
Burco BSGH-270
Burco BSGH-Crystals
Burco BSGH-400
Burco EHS
Burco FAE
Burco LAA-38
Burco LAF-6
Burco LAF-125
Burco NPS-225
CHEMICAL DESCRIPTION Coconut f a t t y a c i d amidopropyl
b e t a i ne
A l i p h a t i c po l ye the r non ion i c
on i c
on i c
A l i p h a t i c po l ye the r non
A l i p h a t i c po l ye the r non
Sol vent
Su r fac tan t
Sodi urn 1 i near a1 k y l po l ye ther su l fona te s u r f a c t a n t
P lu ron ic , P lu ra fac , I n d u s t r o l
Hydrous sodi um s i 1 i ca te
Sur fac tan t
Su r fac tan t
Su r fac tan t
Su r fac tan t
Su r fac tan t
Su r fac tan t
P r o p r i e t a r y t e x t i l e aux
Sur fac tan t
Su r fac tan t
P r o p r i e t a r y t e x t i l e aux
Sur fac tan t
l i a r y
1 i ary
SOURCE Huls
Rhone-
Rhone-
Rhone-
Arco
PPG
P PG
BASF
PQ
B u r l
B u r l
B u r l
ng-
ng-
ng-
Bur1 i ng-
B u r l i ng-
B u r l i ng-
Bur l i ng-
B u r l i ng -
B u r l i ng-
B u r l i ng-
B u r l i ng-
B u r l i ng-
Trademarked Raw Materials 185
RAW MATERIALS Burco NPS 50%
Burcosolv TM
Burcosperse AP
Burcosperse LP
Burcotase SL-80
Burco TM€
Burcotrope 1250
Burcowet TM-LF
Bu ty l Carbit07
Buty l Cel losolve
Buty l Propasol
Calamide C
Calamide 0
Calfax DB-45
Cal foam €A-603
Cal foam ES-303
Cal foam SLS-30
C a l i b r i t e SL
Cal irnul se PRS
Caloxylate N-9
Calsof t F-90
Calsof t L-40
CHEMICAL DESCRIPTION Propr ie tary t e x t i l e a u x i l i a r y
Water so lub le solvent mixture
L iqu id detergent polymer
Propr ie tary detergent polymer
Propr ie tary detergent enzyme
Nonionic th ioe the r sur factant
I ndus t r
I ndus t r
I ndus t r
Surfactant
a7 solvent
a1 solvent
a1 solvent
Foam s tab i 1 i z e r 8 emu1 s i f i er
Super amide
D i sul fonate
L i q u i d detergent
L iqu id detergent
Sodium l a u r y l s u l f a t e 30%
Emu1 s i f i e r
Sodi um 1 i near a1 k y l benzene
Linear sodium dodecylbenzene
su l fonate 90%
sul fonate
SOURCE Bur l i ng-
Bur l i ng-
Bur l i ng-
Bur l i ng-
Bur l i ng-
Bur l i ng-
Bur l i ng-
Bur l ing-
UnCarb
UnCarb
UnCarb
P i 1 o t
P i l o t
P i l o t
P i l o t
P i l o t
P i l o t
P i l o t
P i l o t
P i 1 o t
P i l o t
186 Advanced Cleaning Product Formulationr
R A W MATERIALS CHEMICAL DESCRIPTION C a l s o f t L-60 Sodium alkylbenzene sul fonate(60%)
Cal s o f t LAS-99 Dodecylbenzene s u l f o n i c acid(60%)
Calsuds A L i q u i d de tergent b lend
Calsuds CD-6 Coconut o i 1 amide w/sul fonate
Calsuds 81 Concentrated de tergent b lend
Carbopol 934 A c r y l i c a c i d polymer.MW:3,000,000
Card is 36 Wax Ox id ized m i c r o c r y s t a l l i n e wax
Carspray 500 Beadi ng agent w i t h s i 1 i cone
Carspray 700 Foaming beading agent
Cel lobond HEC 1OOOOOA
Cheel ox BF-13
Cheelox NTA-Na3
Clearon CDB Sodi um d i c h l o r o i socyanurate
Concord Co-Wax Emulsion, 12%
Concord Wax #1600
Condensate TL
Cyanamer A-100L Polyacrylamide
Dequest 20605
Dequest 2066
Desonic 9N
D i a l a A O i l
D ion i c OC
Organophosphorous produc t
Organophosphorous product
Nonionic s u r f a c t a n t
Minera l seal o i l
F a t t y a c i d methanolamide p o l y g l y c o l e the r
SOURCE P i l o t
P i l o t
P i l o t
P i l o t
P i l o t
Goodri ch
P e t r o l - W i t c o
W i t c o
FMC
Concord
Concord
Concord
Cyt ec
Monsan t o
Monsanto
DeSoto
She1 1
n u i s
Trademarked Raw Materials 187
RAW MATERIALS Dowanol D
Dowanol DE
Dowanol DPM
Dowanol EB
Dowanol PnB
Dow Corning EP-1-14
Dowfax 2A-1
Dowicide 32
Durcal 40
Durer Resin 15546
CHEMICAL DESCRIPTION Glyco l e the r
G lyco l e ther
Dipropylene g l y c o l methyl e the r
Ethylene g l y c o l n -bu ty l e ther
G lyco l e the r
An ion ic s u r f a c t a n t
An t im ic rob ia l agent
Cal c i um carbonate
E Sodium s i l i c a t e 40 Be'
E-43 Noni on i c
Emcol NA-30 Surface a c t i v e agent
Emcol 4500 Surface a c t i v e agent
Emersol 213 F a t t y a c i d
Emphos PS-220
Emu1 s i f i e r Four-HF D i a1 k y l quaternary
E m u l s i f i e r 827
E m u l s i o n C-340
F7 uorad FC- 129 F7uorochemica7 surfactant
SOURCE Dow
Dow
Dow
Dow
Dow
DowCorn
Dow
Dow
PQ
W i t c o
W i t c o
Henkel
W i t c o
Tomah
Tomah
Toma h
3 M
I88 Advanced Cleaning product Formulations
RAW MATERIALS CHEMICAL DESCRIPTION Gantrez AN-149 V i n y l e the r polymer
Genagen LAB
Genami n 5-250
Genaminox MY
Genapol OA-80
Genapol UD-030
Genapol UD-050
Genapol UD-080
Genapol ZRO L i q u i d
Genapol 2908
General E l e c t r i c SF96-100 S i 1 i cone
Genopur ASA
Giv-Gard DXN
GP-10-1.000 c s t k Dimethyl s i l i c o n e f
GP-10-12,500 c s t k Dimethyl s i l i c o n e f
GP-121 S i l i c o n e p o l i s h add
GP-7104 S i l i c o n e f l u i d
u i d
u i d
t i v e
SOURCE ISP
Hoechst
Hoechst
Hoechst
Hoechst
Hoechst
Hoechst
Hoechst
Hoec hs t
Hoechst
GESi 1 i - Hoechst
Genesee
Gene see
Genesee
Genesee
Harco 20% Soap
Hoe S 3924
Hoechst Wax A3 CS
Hoechst Wax E
Hoechst Wax F
Hoechst Wax OM
Hoechst
Hoechst
Es ter t y p e wax. Drop po in t :175F Hoechst
Hoechst
Hoechst
nademarked Raw Materials 189
CHEMICAL DESCRIPTION RAW MATERIALS Hoechst Wax OP
Hoechst Wax S
Hostapur SAS 60
Hypof resh Perfume
Igepa l CA-630 A l k y l e thoxy la te non ion ic
Igepa l CA-720 A1 k y l phenol e thoxy l a t e noni oni c
Igepa l C0-630/C0-660/ A lky lpheno l e thoxy la te CO-710
Igepa l CO-977
Isopar E/K/L/M/V
Lanoquat 50
L i poxol
L ipoxo l 6000 & 12000
Lonzabac 12.30
L y t r o n 295 Latex
Kaopo l i t e SF/1152/
Kathon CG
Kel zan
Kermac 600
K o r t h i x Th ixo t rop i c
1168
Agent
Water so lub le s u r f a c t a n t (70%)
I sopara f f i n i c s o l vent
Quaternary product
Po lys ty rene
Anhydrous a
emu1 s i on
umi num s i 1 i ca te
Fungi c i de (B i o c i de)
Xanthan gum
Minera l seal o i l
Ref ined wh i te ben ton i te
SOURCE Hoechst
Hoechst
Hoechst
I S P
I SP
ISP
ISP
Exxon
Henkel
Hul s
Hul s
Lonza
Morton
Kaopol-
Rohm&
Kelco
Kerr-Mc
Kaopol-
190 Advanced Cleaning Product Formulations
RAW MATERIALS Mackadet 40K
Mackam JS
Mackam MEJ
Mackam 2CSF
Mackam 2CYSF
Mackam 35
Mackamide CD
Mackami ne C-10
Mackamine LO
Mackazol i ne 0
Mackstat DM
Macol 48
Macol LF-120
Macol TD-3
Macol TD-12
Maphos 60-A
Marl ami ds
Mar laz i ns
Marl i n a t s
Mar l i p a l s
Marlons
Marlophors
CHEMICAL DESCRIPTION Potassium coconut soap
Low foam s u r f a c t a n t
Amphoteric w e t t i n g agent
Su r fac tan t
Low foaming s u r f a c t a n t
Cocami dopropyl b e t a i ne
Cocamide DEA
Amine ox ide s u r f a c t a n t
Amine ox ide s u r f a c t a n t
01 e y l hydroxyethy l i m i dazol i ne
DMDM hydanto in
B lock p o l y o l
Rinse a i d . MW: 1,000
Nonionic s u r f a c t a n t . HLB: 8 .0
Nonionic s u r f a c t a n t . HLB: 14.1
Phosphate es te r
F a t t y a c i d a1 kanol ami des
F a t t y amine p o l y g l y c o l e the rs
F a t t y a l coho l e the r sulphates
F a t t y a l coho l p o l y g l y c o l e t h e r s
A1 kylbenzenesulphonates, sodium s a l t s
P a r t i a l phosphate e s t e r s
SOURCE M c I n t y r e
McI n t y r e
M c I n t y r e
McI n t y r e
Mc I n t y r e
McI n t y r e
Mc I n t y r e
McI n t y r e
McI n t y r e
McI n t y r e
Mc In ty re
PPG
PPG
PPG
PPG
PPG
Hul s
Hul s
Hul s
Hul s
Hul s
Huls
Trademarked Rmu Materials 191
RAW MATERIALS CHEMICAL DESCRIPTION Mar losof t IQ 90 Quaternary i m i dazol i nes
Mar 1 owets Emu1 s i f i ers
Mar 1 ox I s
Mazamide 80
Mazawet 36
Fa t t y a1 coho1 a1 k y l ene oxide add i t i on products
Speci a1 t y a1 kanol ami de
Surfactant
Mazclean EP
Mazon 98 Propr ie tary sur factant
Medialan LD
Methyl Carb i to l Solvent
Metso Pentabead 20 Sodium metas i l icate, pentahydrate
Miranol CS Conc. Cocoamphopropylsulfonate
Miranol FBS Surfactant
M i ranol JEM Conc. Mixed C8 amphocarboxylate
amphoteric sur factant
amphoteric
M i r a t a i n e TM D i hydroxyethyl t a l l ow g l yc i nate amphoteric sur factant
ML-870 Latex A c r y l i c polymer emulsion
Mon t an Wax "S 'I
Mor-Glo 2 Latex Floor p o l i s h l a t e x (38%)
Morton Conrez 510 Polymer emu1 s i on
M- Py 1-01 N-Methyl-2-Pyrrolidone
SOURCE Huls
Hul s
Hul s
PPG
PPG
PPG
P PG
UnCarb
PQ
M i ranol
M i ranol
M i ranol
M i ranol
Morton
Stroh-
Morton
Morton
I S P
192 Advanced Cleaning Product Formulotions
RAW MATERIALS Neodol 25-3 Ethoxy
Neodol 25-3s
Neodol 25-7 Ethoxy
Neodol 91-8 Ethoxy
Ozokeri t e 170
PEG-10 Carnauba
Permulsin SP
Pe t ro BAF L i q u i d
B e t r o BAF Powder
Pe t ro LBA/ULF/22
Pe t ro SXS-40
Prapagen WK
P r i f a c 7976
Proxel GXL
CHEMICAL DESCRIPTION a t e L inear p r imary a l coho l
E thoxysu l fa te . Sodium c a t i o n
a t e Alcohol e thoxy la te . MW: 519
a t e L inea l p r imary a l c o h o l . MW: 529
Pol ycarboxyl a t e
An ion ic s u r f a c t a n t & d ispersant
An ion ic s u r f a c t a n t & d ispersant
An ion ic s u r f a c t a n t & d i spe rsan t
Sodium xy lene s u l f o n a t e 40%
F a t t y a c i d
Chemical b i o c i de
Ref ined Concord Wax #407
Rewoter ic AM B-15
Rewoter ic AM KSF-40
Rewoter ic AM V
Rhodacal A-246/L
Rhodacal DS-10
Rhodacal DSB
Sur fac tan t
SOURCE Shel 1
Shel 1
Shel 1
Shel 1
Koster
Koster
DeSoto
DeSoto
DeSoto
DeSoto
Unichema
I C I
Concord
w i t C O
w i t c o
w i t c o
Rhone-
Rhone-
Rhone-
Trademarked Rcmt Materials 193
R A W MATERIALS Rhodacal I PAM
Rhodacal 330
Rhodafac LO-529
Rhodafac RA-600
Rhodaf ac RE-61 0
Rhodapex GO-436
Rhodapex ES-2
Rhodapax MA-460
Rhodapex NA-61
Rhodopol 23
Rhodapon BOS
Rhodapon S0
Rhodapon U 0
Rhodasurf 0C-840
Rhodasurf 25-7
Rhodasurf 25-9
Rhodasurf 91 -6
Ross Micro Wax 1133/15W
Ross Ozoker i te Wax 77Y
CHEMICAL DESCRIPTION
Phosphate ester nonioni c
PhosDhate ester an ion ic
SOURCE Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Rhone-
Ethoxylated t r i d e c y l a lcohol Rhone-
Rhone-
Rhone-
Rhone-
Ross
Ross
SAG 1010 S i l i cone a n t i foam UnGarb
Sequi on 1 ONa2 Phosphonate HEDP
SF96(100)/SF96(350)/ Polydimethyl s i l i c o n e f l u i d GESi 1
Shel lso l T I sopara f f i n i c solvent She1 1
SM 2109 GESi 1
SF96(1OOO)/SF 1705/SF 1706
194 Advanced Cleaning Product Formulations
RAW MATERIALS SM 2133/SM 2135
Snow F loss S i l i c a
Sokalan CP 5
Sokalan HP 22
Sokalan HP 50
Sokalan PA 40
Solvent BG
Solvent
Span 80
SR 107
S t a r
Stepano
GX 5
DEA (35%)
Super F loss
Sur fon i c N-95
SWS 211 S i l i c o n e
Syntran 6520
Technocell 90 DU
Texst im 8741
Thermphos NW
T i nopal CBS-X
CHEMICAL DESCRIPTION
Processed diatomaceous s i l i c a
Po lycarboxy la te
P o l y v i n y l p y r r o l i done
Po lycarboxy la te
Sur fac tan t
Sodium s i l i c a t e 42 Be’
D i ethanol ami ne 1 a u r y l s u l f a t e
Minera l f i l l e r
Nonionic s u r f a c t a n t . HLB: 12.9
A n t i foam
Acry l i c emu1 s i on
Nonionic s u r f a c t a n t
F1 uorescent
Tomah A l k a l i Su r fac tan t : Amphoter
Tomah AO-14-2 Ether amine
Tomah A0-728 Special Amine ox ide
wh i ten ing agent
c (35% A c t i v e )
ox ide s u r f a c t a n t
s u r f a c t a n t
SOURCE GESi 1
Manvi 11 e
I C I
PQ
Step n
Manvi 11 e
Texaco
Wac ker
I n t e r -
Tomah
C i ba-
Tomah
Tomah
Tomah
Trademarkmi Raw Materials 195
R A W MATERIALS CHEMICAL DESCRIPTION Tomah E m u l s i f i e r Four D i a l k y l quaternary s u r f a c t a n t
Tomah Q-17-2
Tr iethanolamine R
T r i t o n CF-10 A l k y l a r y l po lye ther non ion ic
Tween 81 Sur fac tan t
Tylose CBR 10000
Ucon
Ucon
Union
Union
1 Propel 1 an t
2 Propel l a n t
Carbide L-45, 100 cs tks . S i l i c o n e
Carbide L-45, 30,000 cs tks . S i l i c o n e
Union Carbide L-46
Union Carbide LE-461
Union Carbide LE-462
Varami de A-83
Varamide ML-1
Var ion AM-KSF-40%
Varonic K205/LI-48/ LI-67
Varox 365
Varox 1770
Varsol 81 Varsol No.2
Veegum Pro
S i 1 i cone
S i 1 i cone
S i 1 i cone
Detergent a1 kanolamide
Detergent a1 kanolamide
Sur fac tan t
Nonionic w e t t i n g agent
Wett ing agent,degreaser,detergent
Amine ox ide
Minera l sp i r i t s
Complex c o l 1 o i da l magnesi urn aluminum s i l i c a t e
SOURCE Tonah
Tomah
UnCarb
I C I
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
UnCarb
W i t c o
W i t c o
W i t c o
W i t c o
W i t c o
W i t c o
Exxon
Vander-
1% Advanced Cleaning Product Formulations
R A W MATERIALS CHEMICAL DESCRIPTION SOURCE Versene 100/220 S o l u t i o n o f te t rasod ium s a l t o f Dow
EDTA
Ves t i no l C Hu ls
Vestowax AW 1060 Wax emulsion, 15% bas is Hul s
V i s c a s i l l O , O O O / S i l i c o n e f l u i d 12,000/30,000
GESi 1
Vol c l ay NF-BC Western b e n t o n i t e AmColl
Wessa l i th P Z e o l i t h A
W i tcami de CDA/ A1 kanol ami de s u r f a c t a n t Wi tco 5-771 /128T/511/5195
Witco 1298 S o f t Ac id W i t c o
W i t c o l a t e A Sodium l a u r y l s u l f a t e . An ion ic W i t c o
W i t c o l a t e AE-3/ S u l f a t e d s u r f a c t a n t s ES-3/LES-60A/S-1285C/SE-5/WAC-LA/2310/7031
W i t conate AOS/ Sul fonate s u r f a c t a n t SXS/3ODS/45LX
Witconate 1260 S l u r r y C-12 LAS (60%)
Witconol 14 Noni on i c
Z e o l i t h A
#3 Carnauba
668 P o l i s h i n g Powder
678 Pol i s h i ng Powder
787 P o l i s h i n g Alumina P-10 F e i n s t
W i t c o
W i t c o
W i t c o
W i t c o
Koster
Whi t tCD
Whi t t C D
Whi t t C D
Section IV Suppliers' Addresses
197
198 Advanced Cleaning Product Formulations
A1 1 i ed-Si gnal I n c . P.O. Box 2332R Morr istown, NJ 07962 (201)-455-2000/(800)-526-0717
American C o l l o i d Co. 1500 W. Shure D r . A r l i n g t o n Heights, I L 60004 (312)-392-4600
Arc0 Chemical Co. 3801 West Chester P ike Newtown Square, PA 19073 (215)-359-2000
BASF Corp. 100 Cherry H i l l Rd. Pars i ppany, NJ 07054 (201)-316-3000/(800)-526-1072
BP O i l I n c . 200 P u b l i c Square Cleveland, OH 44114 (216)-586-6364/(800)-321-8598
B u r l i ngton Chemical Co. , I n c . P.O. Box 111 615 Huffman M i l l Rd. Bu r l i ng ton , NC 27215 (919)-584-0111/(800)-672-5888
Concord Chemical Co. 17 th and Federal S ts . Camden, NJ 08105 (609)-966-1526
Cytec I n d u s t r i e s , I n c . F i v e Gar re t Mountain Plaza West Paterson, N J 07424 (908)-B62-6000/(800)-253-4078
DeSoto, I n c . 1700 S. M t . Prospect Rd. Des P la ines , I L 60018 (312)-391-9000
Dow Chemical Co. Midland, M I 48674 (800)-258-CHEM
Dow Corning Corp. Box 0994 Midland, M I 48686 (51 7)-496-4000
Eastman Chemical Co. P.O. Box 431 K ingspor t , TN 37662 (615)-229-2318/(800)-327-8626
Exxon Chemica? Americas 13501 Katy Frwy Houston, TX 77079 (713)-870-6000/(800)-231-6633
FMC Corp. 2000 Market S t . Ph i l ade lph ia , PA 19103 (215)-299-6000/(800)-526-3649
ISP/GAF Corp. 1361 Alps Road Wayne, NJ 07470
Genesee Polymers Corp. Fenton Rd. P.O. Box 7047 F l i n t , M I 48507
(201)-628-3000/(800)-848-7659
(31 3 ) -238-4966
GE S i 1 icones 260 Hudson R iver Rd. Waterford, NY 12188 (518)-237-3330/(800)-255-8886
BF Goodrich Co. 991 1 Brecksvi 11 e Rd. B r e c k s v i l l e , OH 44141 (216)-447-5000/(800)-332-1144
Haarman & Reimer Corp. P.O. Box 175 70 Diamond Rd. S p r i n g f i e l d , NJ 07081 (201)-467-5600/(800)-422-1559
Suppliers' Addresses 199
Henkel Corp. 5325 S. N i n t h Ave. LaGrange, I L 60525 (708)-530-7300/(800)-543-7370
Hoechst-Celanese Corp. 26 Main S t . Chatham, NJ 07960
Huls America I n c . Turner P1. P i scataway, NJ 08855
In te rpo lymer Corp. 330 Pine S t . Canton, MA 02021
Kaopo l i te , I n c . 2444 M o r r i s Ave. Union, N J 07083
(201)-635-2600/(800)-526-4960
(201)-981-5000/(800)-526-0339
(617)-828-7120/(800)-444-1281
(908)-769-0609
Kelco D iv . Merck & Co., I nc . 8355 Aero D r i v e San Diego, CA 92123
Kerr-McGee Chemical Corp. Kerr-McGee C t r . P.O. Box 25861 Oklahoma C i t y , OK 73125
(619)292-4900/(800)-535-2656
(405)-270-1313/(800)-654-3911
Koster Keunen I n c . P.O. Box 447 90 Bourne B lvd . S a y v i l l e , NY 11782 (51 6)-589-0456
Johns-Manvil le Ken Caryl Ranch Denver, CO 80217
McIn ty re Group L td . 4851 S. S t . Lou is Ave. Chicago, I L 60513 (312)-927-2401
Mi rano l I n c . P.O. Box 436 Dayton, NJ 08810
Mona I n d u s t r i e s I n c . 76 E. 24 S t . P.O. Box 425 Paterson, NJ 07544
Monsanto Chemical Co. 800 N. Lindbergh Blvd. S t . Louis, MO 63167
Morton I n t e r n a t i o n a l I nc . 100 N. R ive rs ide Plaza Chicago, I L 60606
P e t r o l i t e Corp. 6910 E. 14 S t . Tulsa, OK 74112 (918)-838-1601
(201)-329-3900
(201)-345-8220/(800)-553-6662
(314)-694-1000/(800)-325-4330
(312)-807-2000/(800)-367-3318
P i l o t Chemical Co. 11756 Burke S t . Santa Fe Spr ings, CA 90670 (310)-723-0036
PPG Chemical s 3938 P o r e t t D r i v e Gurnee, I L 60031
PQ Corp. P.O. Box 840 Va l l ey Forge, PA 19482
Rhone-Poulenc CN 7500 Prospect P l a i n s Rd. Cranbury, NJ 08512
Rohm & Haas Co. Independence Ma l l West Ph i lade lph ia , PA 19105
(708)-244-3410/(800)-323-0856
(215)-293-7200
(609)-860-4000/(800)-620-2613
(215)-592-3000
200 Advanced Cleaning Product Formulations
Ross Chemical I n c . 303 Da le O r . F o u n t a i n I n n , SC 29644 (803)-862-4474
Sandoz Chemical s Corp. 4000 Monroe Rd. C h a r l o t t e , NC 28205 (704)-331-7078/(800)-631-6077
S h e l l Chemical Co. P . O . Box 2463 Houston, TX 77252 (713)-241-6161
Stepan Co. 22 W . F ron tage Rd. N o r t h f i e l d , I L 60093 (708)-446-7500/(800)-745-7837
Strohmeyer & Arpe Co., I n c . 89 M i 1 b u r n Ave. M i l b u r n , N J 07041 (201)-761-7600
Texaco Chemical Co. 3040 Post Oak B l v d . Houston, TX 77056 (71 3)-961-3711
Tomah Produc ts , I n c . 1012 T e r r a D r i v e M i l t o n , W 1 53563 (608)-868-6811/(800)-441-0708
3M 3M Center S t . Pau l , MN 55144 (612)-733-5454
Unichema Chemicals, I p c . 4650 S. Racine Ave. /'
Chicago, I L 60609 (312)-376-9000/(800)-833-2864
Union Carb ide Corp. 39 O l d Ridgebury R d . Danbury, CT 06817 (203)-794-2000
RT V a n d e r b i l t Co., I n c . P.O. Box 5150 30 W i n f i e l d S t . N o r f o l k , CT 06856
Wacker S i l i c o n e s Corp. 3301 S u t t o n Rd. Adr ian , M I 49221
(203)-853-1400/(800)-243-6064
(517)-264-8500/(800)-246-0063
W h i t t a k e r , C l a r k & D a n i e l s , I n c . 1000 Coo l idge S t . S. P l a i n f i e l d , NJ 07080 (201)-561-6100
W i t c o Chemical Co. 5777 F r a n t z Rd. P.O. Box 646 D u b l i n , OH 43017 (614)-765-6500/(800)-366-6500
Witco Corp. 520 Madison Ave. New York , NY 10022 (212)-605-3941/(800)-634-4010
Other Noyes Arblications
ADVANCED CLEANING
PRODUCT FORMULATIONS
Volume 3
by Ernest W. Flick
This book (Volume 3) presents more than 630 up-to-date advanced cleaning product form- ulations for household, industrial and automotive applications. It istheresultof information received from numerous industrial companies and other organizations. The data represent selections madeatnocostto, norinfluencefrom, themakers or distributors of these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volume 1 published in 1989 and Volume 2 published in 1994.
Formulation in the cleaning product industry has gradually been undergoing significant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass alongthese increases. Environmental con- siderations have also played a part. By changing formulations to improve cost/performance char- acteristics, manufacturers have been able to control costs but still enhance performance. This book presents manufacturers' suggested formu- lations which might meet new performance cri- teria.
The formulations in this book are divided into the following sections and chapters, with the number of formulations indicated in ():
1.
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
Household and Industrial Cleaners and Polishes
Bathroom Cleaners (14)
Dairy Food and General Industrial Cleaners (52)
Degreasers (25)
Dishwashing Detergents (70)
General Purpose Cleaners (29)
Glass CleanarsPolishes (18)
Hard Surface Cleaners (59)
Laundry Products (100)
Metal Cleaners and Polishes (52)
Oven, Grill and Hot Plate Cleaners (1 1)
Polishes, Coatings and Finishes (19)
Rinse Aids (5)
13.
14.
II.
15.
16.
17.
18.
Rug, Floor, Carpet, Upholstery Sham-
Miscellaneous (49)
Transportation Cleaners and Polishes
Auto Cleaners and Polishes (32)
Car and Truck Wash Compounds (34)
Whitewall Tire Cleaners (11)
Miscellaneous
poos and Cleaners (41)
Each formula is located in the chapter which is most applicable. The reader, seeking a formula for aspecific end use, should check each chapter which could possibly apply. In addition to the above, there are two other sections which will be helpful to the reader. 111. A chemical trademark section where
each tradenamed raw material in- cluded in the book is listed with a chemical description andthe supplier's name. The specifications which each raw material meets are included, if applicable.
IV. Main office addresses of the suppliers of trademarked raw materials.
Each formulation in the book lists the following information, as available, in the manufacturets own words:
0 Description of end use and most outstanding properties.
0 The percent by weight orvolume of each raw material included inthe formula, rounded toa decimal figure.
0 Key propertii of the formula, which are the featuresthatthesource considentobemore outstanding than other formulations of the same type.
0 The formula source, which is the company or organization that supplied the formula. The secondary source may be the originating company and/or the primary source's publication title, or both. Aformula number is included, if applicable.
ISBN 0-8155-1382-8 (1995) 6" x9' 280 pages
Other Noyes Publications
ADVANCED CLEANING
PRODUCT FORMULATIONS
Volume 2
by
Ernest W. Flick
This book (volume 2) presents more than 800 up-to-date advanced cleaning product formulations for household, industrial and automotive applications. It is the result of information received from numerous industrial companies and other organizations. The data represent selections made at no cost to, nor influence from, the makers ordistributors of these materials. Only the most recent formulas have been included. All formulations are completely different than those contained in Volume 1, which was published in 1989.
Formulation in the cleaning product in- dustry has gradually been undergoing sig- nificant change during the past years. Raw materials costs have risen and manufacturers have been reluctant to pass along these in- creases. Environmental considerations have also played a part. By changing formulations to improve cost-performance characteristics. manufacturers have been able to control costs but still enhance performance. This book pre- sents supplier's suggested formulations which might meet new performance criteria.
Theformulations inthis bookaredivided into the following sections and chapters, with the number of formulations indicated in ():
1.
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
Household and industrial Cleaners and Polishes (733)
Bathroom Cleaners (29)
Dairy and Food Industry Cleaners (15)
Degreasers (20)
Dishwashing Detergents (67)
DetergentsDisinfectants (36)
General Purpose Cleaners (47)
Hard Surface Cleaners (60)
Laundry Products (217)
Metal Cleaners (87)
Polishes, Coatings and Sealers (32)
Rinse Aids (6)
ISBN 0-8155-1346-1 (1994)
12.
13.
/I.
14.
15.
16.
17.
Rug, Carpet and Upholstery Shampoos
Miscellaneous Cleaners (96)
Transportation Cleaners and Polishes (76)
Auto Cleaners and Polishes (9)
Car and Truck Wash Compounds (38)
Whitewall Tire Cleaners (10)
Miscellaneous (19)
In addition to the above, there are two other
and Cleaners (21)
sections which will be helpful to the reader.
111. A chemical trademark section where each tradenamed raw material included in the book is listed with a chemical description and the sup- plier's name. The specifications which each raw material meets are included, if applicable.
lV. Main office addresses of the suppliers of trademarked raw materials.
Each formulation in the book lists the following information, as available:
1. Description of end use and most outstanding properties.
2. The percent by weight or volume of each raw material included in the formula.
3. Key properties of the formula, which are the features that the source considers to be more outstanding than other formulations of the same type.
4. The formula source, which is the company or organization that supplied the formula. The secondary source maybe theoriginating company and/or the primary source's publication title. or both. A formula number is included, if applicable.
f64 6" x9" 394 pages