advanced oatings - metalor...use of any product in a manner, process or formula not designed by...

4
ADVANCED COATINGS PRECIOUS METAL POWDERS AND FLAKES THE ADVANCED COATINGS BUSINESS UNIT DISCLAIMER This data sheet provides information concerning the properties, composition and use of Metalor’s products. The information is provided solely as a convenience to customers. Neither this data nor any advice concerning the selection and/or use of any product shall consti- tute a warranty of any type, whether express or implied. ALL WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE AND NON-INFRINGEMENT ARE EXPRESSLY DISCLAIMED. Nothing in this data sheet or in other information pro- vided by Metalor shall be construed as a recommendation or inducement toproduce or use any process or product in a manner that infringes any existing or future patents. All sales are made expressly subject to Metalor’s standard terms and conditions which are printed on the reverse side of each invoice. Metalor shall not be responsible for any liability arising out of the processing or use of any product in a manner, process or formula not designed by Metalor. JAPAN Metalor Technologies (Japan) Corporation 9F, Shinagawa East One Tower 2-16-1, Kohnan, Minato-Ku Tokyo 108-0075 Phone +81 3 6863 3385 Fax +81 3 6863 3565 Numazu Plant 678 Ipponmatsu, Numazu-City Shizuoka-Prefecture 410-0314 Phone +81 55 966 1080 Fax +81 55 967 2544 Mitomo Semicon Engineering Co. Ltd. Tsukuba Plant 25-3, Koshindiara,Bando-City Ibaraki-Prefecture 306-0608 Phone +81 297 36 8800 Fax +81 297 36 8802 KOREA Metalor Coatings (Korea) Corporation 5F Suwon venture Plaza Samsung-ro 168-48 (Maetan-dong 413-3) Yongtong-gu, Suwon-si, Gyeonggi-do 443-803 Phone +82 2 3453 4264 Fax +82 2 3453 4147 NETHERLANDS Metalor Technologies (UK) Ltd. Netherlands Branch Weegschaalstraat 3 NL-5632CW Eindhoven Phone +31 40 291 1265 Fax +31 40 291 1266 [email protected] SINGAPORE Metalor Technologies (Singapore) Pte. Ltd. Surface Engineering Hub 8 Buroh Street #01-06 Singapore 627563 Phone +65 6586 3333 [email protected] SPAIN Metalor Technologies (Ibérica) S.A. C/ Albasanz, 14 bis, 1°G E-28037 Madrid Phone +34 91 375 7480 Fax +34 91 304 4142 [email protected] SWEDEN Metalor Technologies (Sweden) AB Sagagatan 22 S-506 35 Boras Phone +46 33 444 250 Fax +46 33 444 260 [email protected] CHINA Metalor Technologies (Suzhou) Ltd. B building, 48 Dong Fu Road Suzhou Industrial Park Jiangsu Province P.R. China 215123 Phone +86 512 6593 6181 Fax +86 512 6593 6171 [email protected] Dongguan Branch Office Unit B213, Wanbao Cheng Dezheng E. Road, Changan Dongguan, Guangdong Province P.R. China 523856 Phone +86 769 8544 3938 Fax +86 769 8544 3933 Metalor Coatings (Shanghai) Co. Ltd. No. 3 Building, 800 Shenfu Road Xinzhuang Industry Park, Minhang District Shanghai P.R. China 201108 Phone +86 21 5442 7450 Fax +86 21 5442 7451 Phone +86 21 5442 3060 Fax +86 21 5442 0790 FRANCE Metalor Technologies (France) S.A.S. 11, Rue Louis Aulagne F-69600 Oullins Phone +33 4 72 66 32 10 Fax +33 4 72 66 37 20 [email protected] HONG KONG Metalor Technologies (Hong Kong) Ltd. Suite 1705-9 The Metropolis Tower 10 Metropolis Drive Hunghom, Kowloon Hong Kong – China Phone +852 2521 4131-5 Fax +852 2845 1791 [email protected] ITALY Metalor Technologies (Italia) S.r.l. Via G. Di Vittorio, 28 I-20068 Peschiera Borromeo (Milano) Phone +39 02 5165 181 Fax +39 02 5530 1021 [email protected] SWITZERLAND Metalor Technologies SA Rue des Perveuils 8 CH-2074 Marin Phone +41 32 720 6111 Fax +41 32 720 6612 [email protected] TAIWAN Metalor Technologies (Hong Kong) Ltd. Taiwan Branch 6F, 101 Rei-Hu Street Nei-Hu Taipei, Taiwan R.O.C. Phone +886 2 7720 7775 Fax +886 2 7720 0303 [email protected] Metalor Coatings (Taiwan) Corporation 16 East 7th Street Nan-Tze Export Processing Zone Kaohsiung, Taiwan R.O.C. Phone +886 7 368 0560 Fax +886 7 365 3174 THAILAND Metalor Technologies (Singapore) Pte. Ltd. Bangkok Representative Office 335/43, 7th Floor, Prime State Office Sirnakarin Road, Nongborn, Pravej District TH-Bangkok 10250 Phone +66 2366 0719 Fax +66 2366 0720 [email protected] UNITED KINGDOM Metalor Technologies (UK) Ltd. 74, Warstone Lane UK-Birmingham B18 6NG Phone +44 121 262 3088 Fax +44 121 236 3568 [email protected] USA Metalor Technologies USA Corporation 52 Gardner Street USA-Attleboro, MA 02703 Phone +1 508 226 4470 Fax +1 508 695 4180 [email protected] 255 John Dietsch Boulevard USA-North Attleboro, MA 02763 Phone +1 508 699 8800 Fax +1 508 695 4828 1640 Thomas Street USA-Port Huron, MI 48061 Phone +1 508 699 8800 Fax +1 810 985 5132 MTPF01-EN/07.14 Metalor Technologies SA Avenue du Vignoble, Case postale 9, CH-2009 Neuchâtel Tel. +41 (0) 32 720 61 11, Fax +41 (0) 32 720 61 12 [email protected], www.metalor.com © Metalor 2014 All rights reserved LBMA Good Delivery Referee LPPM Good Delivery Referee

Upload: others

Post on 07-Jun-2020

3 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: AdvAnced oAtings - Metalor...use of any product in a manner, process or formula not designed by Metalor. JA pAn Metalor Technologies (Japan) Corporation 9F, Shinagawa East One Tower

AdvAnced coAtings

precious Metalpowders and flakes

the AdvAnced coAtings Business unit

DISCLAIMERThis data sheet provides information concerning the properties, composition and use of Metalor’s products. The information is provided solely as a convenience to customers. Neither this data nor any advice concerning the selection and/or use of any product shall consti-tute a warranty of any type, whether express or implied. ALL WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE AND NON-INFRINGEMENT ARE EXPRESSLY DISCLAIMED. Nothing in this data sheet or in other information pro-vided by Metalor shall be construed as a recommendation or inducement toproduce or use any process or product in a manner that infringes any existing or future patents. All sales are made expressly subject to Metalor’s standard terms and conditions which are printed on the reverse side of each invoice. Metalor shall not be responsible for any liability arising out of the processing or use of any product in a manner, process or formula not designed by Metalor.

JApAnMetalor Technologies (Japan) Corporation9F, Shinagawa East One Tower2-16-1, Kohnan, Minato-KuTokyo 108-0075Phone +81 3 6863 3385Fax +81 3 6863 3565

Numazu Plant 678 Ipponmatsu, Numazu-CityShizuoka-Prefecture 410-0314 Phone +81 55 966 1080 Fax +81 55 967 2544

Mitomo Semicon Engineering Co. Ltd.Tsukuba Plant 25-3, Koshindiara,Bando-CityIbaraki-Prefecture 306-0608 Phone +81 297 36 8800 Fax +81 297 36 8802

KoreAMetalor Coatings (Korea) Corporation5F Suwon venture PlazaSamsung-ro 168-48 (Maetan-dong 413-3)Yongtong-gu, Suwon-si, Gyeonggi-do 443-803Phone +82 2 3453 4264Fax +82 2 3453 4147

netherlAndsMetalor Technologies (UK) Ltd.Netherlands BranchWeegschaalstraat 3NL-5632CW EindhovenPhone +31 40 291 1265Fax +31 40 291 [email protected]

singAporeMetalor Technologies (Singapore) Pte. Ltd.Surface Engineering Hub 8 Buroh Street #01-06 Singapore 627563Phone +65 6586 [email protected]

spAin Metalor Technologies (Ibérica) S.A.C/ Albasanz, 14 bis, 1°GE-28037 MadridPhone +34 91 375 7480Fax +34 91 304 [email protected]

sweden Metalor Technologies (Sweden) ABSagagatan 22S-506 35 BorasPhone +46 33 444 250Fax +46 33 444 [email protected]

chinAMetalor Technologies (Suzhou) Ltd.B building, 48 Dong Fu RoadSuzhou Industrial ParkJiangsu ProvinceP.R. China 215123Phone +86 512 6593 6181Fax +86 512 6593 [email protected]

Dongguan Branch Office Unit B213, Wanbao Cheng Dezheng E. Road, ChanganDongguan, Guangdong ProvinceP.R. China 523856 Phone +86 769 8544 3938 Fax +86 769 8544 3933

Metalor Coatings (Shanghai) Co. Ltd.No. 3 Building, 800 Shenfu RoadXinzhuang Industry Park, Minhang District Shanghai P.R. China 201108 Phone +86 21 5442 7450 Fax +86 21 5442 7451Phone +86 21 5442 3060 Fax +86 21 5442 0790

FrAnceMetalor Technologies (France) S.A.S.11, Rue Louis AulagneF-69600 OullinsPhone +33 4 72 66 32 10Fax +33 4 72 66 37 [email protected]

hong KongMetalor Technologies (Hong Kong) Ltd.Suite 1705-9 The Metropolis Tower10 Metropolis DriveHunghom, KowloonHong Kong – ChinaPhone +852 2521 4131-5Fax +852 2845 [email protected]

itAlyMetalor Technologies (Italia) S.r.l.Via G. Di Vittorio, 28I-20068 Peschiera Borromeo (Milano)Phone +39 02 5165 181Fax +39 02 5530 [email protected]

switzerlAndMetalor Technologies SARue des Perveuils 8CH-2074 MarinPhone +41 32 720 6111Fax +41 32 720 [email protected]

tAiwAn Metalor Technologies (Hong Kong) Ltd.Taiwan Branch6F, 101 Rei-Hu StreetNei-HuTaipei, Taiwan R.O.C.Phone +886 2 7720 7775Fax +886 2 7720 [email protected]

Metalor Coatings (Taiwan) Corporation16 East 7th StreetNan-Tze Export Processing ZoneKaohsiung, Taiwan R.O.C.Phone +886 7 368 0560Fax +886 7 365 3174

thAilAnd Metalor Technologies (Singapore) Pte. Ltd.Bangkok Representative Office335/43, 7th Floor, Prime State OfficeSirnakarin Road, Nongborn, Pravej DistrictTH-Bangkok 10250Phone +66 2366 0719Fax +66 2366 [email protected]

united Kingdom Metalor Technologies (UK) Ltd.74, Warstone LaneUK-Birmingham B18 6NGPhone +44 121 262 3088Fax +44 121 236 [email protected]

usAMetalor Technologies USA Corporation52 Gardner StreetUSA-Attleboro, MA 02703Phone +1 508 226 4470Fax +1 508 695 [email protected]

255 John Dietsch BoulevardUSA-North Attleboro, MA 02763Phone +1 508 699 8800Fax +1 508 695 4828

1640 Thomas StreetUSA-Port Huron, MI 48061Phone +1 508 699 8800Fax +1 810 985 5132

MTP

F01-

EN

/07.

14

Metalor Technologies SAAvenue du Vignoble, Case postale 9, CH-2009 NeuchâtelTel. +41 (0) 32 720 61 11, Fax +41 (0) 32 720 61 [email protected], www.metalor.com

© Metalor 2014 All rights reserved

LBMAGood Delivery

Referee

LPPMGood Delivery

Referee

Page 2: AdvAnced oAtings - Metalor...use of any product in a manner, process or formula not designed by Metalor. JA pAn Metalor Technologies (Japan) Corporation 9F, Shinagawa East One Tower

These are typical values obtained in our laboratory and do not represent any specification

PUPD4326PUPD4216 PUPD13710 μm SEM 2 μm SEM 2 μm SEM PUPT5061PUAU114 PUAU59420 μm SEM SEM 4 μm 2 μm SEM

Product Name

Description Tap Density

Surface Area

Particle Size Distribution (μm)

Application PDS

(g/cm3) (m2/g) 10 50 90

plAtinum powdersPUPT511 Deagglomerated powder 4.9 0.80 1.1 3.2 7.0

Fuel cells, gas sensors, compo-nent electrodes, termination inks

0393

PUPT514 Amorphous powder 1.7 24 0.74 2.0 7.9 Fuel cells and gas sensors 0394

PUPT551 Controlled porosity powder 3.7 25 Sensors, medical 0397

PUPT5061 Agglomerated spheres 2.1 0.80 0.80 1.5 3.5 General purpose, 3D printing 0400

PUPT5071 Flaked powder 5.8 0.80 1.0 1.8 3.3Fuel cells, gas sensors, compo-nent electrodes, termination inks

0401

gold powders And FlAKes PUAU114 Very high surface area, doped gold 1.2 4.8 Gas sensors 0760

PUAU458Dendritic, designed for high conduction with low charge

3.9 0.35 1.2 1.9 3.1 Adhesive pastes 0408

PUAU468Dendritic, designed for high conduction with low charge, deagglomeration treated

5.9 0.26 1.1 1.7 2.7 Adhesive pastes 0896

PUAU593Spheres flakes mix, deagglomeration treated

9.2 0.16 1.3 2.7 6.3 Thickfilm inks 0410

PUAU594Spheres flakes mix, deagglomeration treated

10 0.13 1.9 4.1 11 Thickfilm inks 0411

PUAU3335 Fine spheres, designed for compact firing 10 0.20 0.8 1.5 2.7 Thickfilm inks 0413

WA0400 Flaked powder 8.9 0.29 1.2 2.8 6.4 Adhesive pastes 0416

Product Name

Description Tap Density

Surface Area

Particle Size Distribution (μm)

Application PDS

(g/cm3) (m2/g) 10 50 90

pAllAdium powders PUPD184 Spherical powder 1.2 1.2 General purpose 0379

PUPD137 Spherical powder, retarded oxidation 2.8 0.40 1.6 4.4 12 High fire, MLCC 0385

PUPD186 Spherical powder 1.5 3.0 0.75 1.5 3.0 General purpose 1069

pAllAdium silver powders PUPD451

Amorphous, coprecipitated Pd/Ag ratio 56/44

1.6 1.5 1.1 2.6 6.2MLCC, components, thickfilm, resistors

0435

PUPD4216Coprecipitated, flaked and alloyed Pd/Ag ratio 20/80

1.8 1.3 1.2 2.4 6.7MLCC, components, thickfilm, resistors

0437

PUPD4326Deagglomerated, coprecipitated and alloyed Pd/Ag ratio 30/70

1.2 4.0 0.8 1.7 3.6MLCC, components, thickfilm, resistors

1210

PUPD4722Amorphous, coprecipitated Pd/Ag ratio 70/30

1.2 3.0 0.8 1.5 3.7MLCC, components, thickfilm, resistors

0441

Page 3: AdvAnced oAtings - Metalor...use of any product in a manner, process or formula not designed by Metalor. JA pAn Metalor Technologies (Japan) Corporation 9F, Shinagawa East One Tower

AB-0222

These are typical values obtained in our laboratory and do not represent any specification

D-0138AB-5895 D-34435 μm SEM 5 μm SEM 5 μm SEM (A)P582-2C-0083P K-1081PSEM 5 μm 5 μm SEM SEM 5 μm

Product Name

Description Tap Density

Surface Area

Particle Size Distribution (μm)

Application PDS

(g/cm3) (m2/g) 10 50 90 100

silver processed powders D-2466P Ionically pure spherical ultra fine powder 5.1 0.35 1.9 4.0 7.6 13 Thickfilm 0806

C-1284PExcellent sintering behaviour to form highly dense, highly conductive deposits

2.3 1.51 0.5 0.8 1.5 4 Thickfilm 0794

C-0083PExcellent sintering behaviour. Excellent rheology modifier to increase thixotropy

2.5 1.62 0.5 0.9 1.6 5 Thickfilm 0735

(A)P582-2Processed powder with “G” coating, produced using caustic input powders

5.0 0.45 1.4 3.4 6.0 10.5 Thickfilm 1301

silver sphericAl powders K-0082P

Excellent sintering behaviour to form highly dense, highly conductive deposits

5.3 0.9 0.8 1.5 2.5 7.0 Thickfilm 0369

K-1081PHigh photovoltaic and low temperature ink applica-tions, excellent sintering behaviour

4.5 0.65 1.0 1.8 3.3 9.0 Thickfilm 0739

K-1321PPhotovoltaic and high temperature fired applications, excellent sintering behaviour

4.7 1.61 0.6 1.1 1.7 5.0 Thickfilm 0370

K-1322PHigh and low temperature applications, excellent sintering behaviour

4.5 2.1 0.6 0.9 1.7 3.0 Thickfilm 0740

K-1631PHigh temperature fired applications, excellent sintering behaviour

3.8 1.15 0.7 1.3 2.4 6.0 Thickfilm 0371

K-2081PHigh temperature fired and die attach applications, excellent sintering behaviour

4.6 0.64 1.0 1.8 3.2 9.0 Thickfilm 0753

P554-19 High and low temperature applications 4.2 0.52 0.9 1.4 2.1 4.0 Thickfilm 1316

Product Name

Description Tap Density

Surface Area

Particle Size Distribution (μm)

Application PDS

(g/cm3) (m2/g) fsss 10 50 90 100

silver FlAKes SA-0201

Designed for die attach, high and low tempera-ture PTF conductive paste applications

4.7 0.83 0.9 2.6 6.7 21 Adhesives 0375

MB-5891Flake with “J” coating, produced using caustic input powders

3.6 0.9 1.82 5.83 14.6 38.3 Adhesives 1299

EA-0295Designed for high and low temperature PTF conductive paste applications

4.3 0.56 1.7 5.8 14.2 32 Adhesives 0365

AB-5895Flake with “A” coating, produced using caustic input powders

3.4 0.55 4.8 14.1 27.3 65 Thickfilm 1298

AB-5894Flake with “A” coating, produced using caustic input powders

3.9 1.19 1.5 4.9 12.7 26 Thickfilm 1297

AA-4703Bi-modal, neutralized flake. For low tempera-ture conductive ink and die attach applications

3.5 1.01 1.2 4.4 12.2 28 Adhesives 0454

silver powdersD-3443

Mid-range particle size, agglomerated, amorphous powder

1.6 0.43 1.7General purpose

0804

D-0138Mid-range particle size, low surface area, agglomerated, amorphous powder

1.4 0.22 5.1General purpose

0803

D-0001Mid-range particle size, low surface area, agglomerated, amorphous powder

1.0 0.38 2.62General purpose

0801

C-0017Excellent sintering behaviour to form highly dense, highly conductive deposits

1.0 2.3General purpose

1300

C-0002Excellent sintering behaviour to form highly dense, highly conductive deposits

1.1 0.96 1.02General purpose

0667

Page 4: AdvAnced oAtings - Metalor...use of any product in a manner, process or formula not designed by Metalor. JA pAn Metalor Technologies (Japan) Corporation 9F, Shinagawa East One Tower

These are typical values obtained in our laboratory and do not represent any specification

P668-2 P620-22(A)P665-25 μm SEM 5 μm SEM 1 μm SEM Ag-V03 Ag-R0220 nm TEM 20 nm TEM20 nm TEM Ag-D02

Product Name

Description Tap Density

Surface Area

Particle Size Distribution (μm)

Application PDS

(g/cm3) (m2/g) 10 50 90 100

Fine silver FlAKes AC-4048

Ultra-fine flake, specifically designed for PV, die attach, high and low temperature fine line printing

2.9 2.0 0.5 0.9 1.6 5.0 Thickfilm 1156

(A)P665-2Highly conductive, low aspect ratio and medium particle size flake with “V” coating

3.9 1.55 0.7 1.0 1.7 4.0 Thickfilm 1305

(G)P668-2High aspect ratio and medium particle size flake with “G” coating

3.8 1.6 0.59 1.08 2.0 4.4 Thickfilm 1317

(G)P683-2High aspect ratio and medium particle size flake with “G” coating

3.6 1.69 0.71 1.5 3.13 7.0 Thickfilm 1306

suB-micron silver powders P620-2 Sub-micron spherical powder with “A” coating 2.65 2.5 0.1 0.2 0.5 1.2 Thickfilm 1307

P620-7 Sub-micron spherical powder with “A” coating 2.65 4.0 0.1 0.2 0.5 1.0 Thickfilm 1311

P620-12 Sub-micron spherical powder with “A” coating 2.25 6.5 0.05 0.1 0.3 0.5 Thickfilm 1309

P554-3 Sub-micron spherical silver powder 2.6 1.5 0.4 0.7 1.1 1.9 Thickfilm 1310

Product Name

Provided as

Product available in following solvents

Description Composition Particle Size (nm)

Ag Content (%) in dry product

PDSAg

Content (%)Solvent

Content (%)

metnAno silver

Ag-V03 Ink additiveWaterEthanolEthylene glycol

Very well-dispersed solu-tions, low viscosity (<100 mPa.s at 50 % silver loa-ding in ethylene glycol)

10 - 70 30 - 90 13 - 201 92 - 95 1360

Ag-V03 Paste

Terpineol Butyl carbitolTexanolDipropylene glycol n-butyl ether

Very well dispersed solutions to paste

40 - 70 30 - 50 13 - 201 92 - 95 1364

Ag-V03 can be used as an additive or as a stand-alone product for low sintering applications. Provided mainly in ink formulation for inkjet and roll-to-roll printing. 1 9 % of particles have a diameter of 130 nm.

Ag-D02 PasteUndecane Terpineol

Paste with decantation1 74 - 88 5 - 20 2 - 20 93 1347

Ag-R02 Paste

Carbitol acetateCarduraTerpineol2-Butoxyethyl ether acetate

Paste with decantation1,2 76 - 85 5 - 20 5 - 15 90 1359

Ag-D02 and Ag-R02 can be used as additives or stand-alone products for low sintering applications. They are provided in paste form only. 1 Low dust: product is a suspension/paste. No emission of nano Ag powder to be expected.2 After reception at customer: the material must be redispersed using high speed mixer or ultrasonication.On request other solvents can be tested to disperse these nanoparticles.