agrosimplex application guide

AGROSIMPLEX FORMULA -‐ 4 AND AGROSIMPLEX FORMULA -‐ 17

Application Guide for the Use of AgroSimplex Formula -‐ 4 and AgroSimplex Formula -‐ 17 in the treatment of diseases in agricultural crops. Please read all the information and follow the instructions as detailed in this guide. MANUFACTURERS DISCLAIMER: The information contained herein is, to the best of the manufacturer’s knowledge and belief, accurate and reliable as of the date of preparation of this document. However, no warranty or guarantee, express or implied, is made as to the accuracy or reliability, and the manufacturer shall not be liable for any loss or damage arising out of the use thereof. No authorisation is given or implied to use any patented invention without a license. In addition the manufacturer shall not be liable for any damage or injury resulting from


abnormal use, from any failure to adhere to recommended practises or from any hazards inherent in the nature of the product.

This guide is intended for the use of AgroSimplex Formula -‐ 4 and AgroSimplex Formula -‐ 17 in the control of diseases in crops.

AgroSimplex Formula -‐ 4 is a general fungicide and pesticide that is used to prevent and control the spread of pathogens in crops, it is also effective against many soft bodied pests. However it is an oxidising agent and care must be taken during handling and application.

Please read MSDS and all Standard Operating Procedures BEFORE using this product.

AgroSimplex Formula -‐ 17 is a plant growth enhancer that will help crops to recover after stress induced events and potentially produce a bigger healthier crop than expected. There are no known hazards associated with this product.

Please read MSDS and all Standard Operating Procedures BEFORE using this product.

WARNING: AgroSimplex Formula -‐ 4 contains hydrogen peroxide a chemical which is available commercially. However the AgroSimplex Formula -‐ 4 supplied by AgroSimplex is a specially formulated and stabilised product for agricultural use only and allows dilution with lower grade waters such as potable supplies without compromising the efficiency. AgroSimplex will not take responsibility for any plant damage caused by products not purchased through our certified agents.


APPLICATION GUIDE

STANDARD OPERATING PROCEDURE FOR MIXING AND APPLICATION OF AGROSIMPLEX FORMULA -‐ 4 (SOP)

General

2 People to be present at all times

No food or drinks to be consumed whilst carrying out procedures

All safety equipment to be worn at all times

All safety procedures to be adhered to at all times

Access to cellphone/landline available at all times

Access to Eyewash station available at all times

Access to First Aid station at all times

Before beginning process it is necessary to ensure:

All equipment required is correct and fully functional

All safety equipment/clothing is present including safety glasses, protective clothing and gloves

All ingredients required are present

Labels to be checked to ensure date compliance

All instructions regarding mixing/dosage and disposal of product are adhered to

SOLUTION PREPARATION AgroSimplex Formula -‐ 4 solution should not be combined or mixed with any other pesticide or fertilizer.

AgroSimplex Formula -‐ 4 is a strong oxidizing agent and may react with residues of metal-‐based fungicides or supplements. Care should be used when applying AgroSimplex Formula -‐ 4 as a foliar spray immediately following foliar applications of metal-‐based products.

AgroSimplex Formula -‐ 4 is a strong oxidizing agent and may react with residues of metal-‐based fungicides or supplements. Care should be used when applying AgroSimplex Formula -‐ 4 as a foliar spray immediately following foliar applications of metal-‐based products.

Use a dilution of 1 fl oz per gallon of clean water (30mls per 4 litres). Diluted product cannot be stored, make fresh daily. Gloves and eye protection must be worn during preparation and application of this product.


1. Ensure tanks and all measuring utensils are clean and the solution is not mixed or combined with any other pesticide or fertilizer as this may cause an adverse reaction when combined with AgroSimplex Formula -‐ 4. It is advisable to keep dedicated materials for use with AgroSimplex Formula -‐ 4 only.

2. Product works best when diluted with water containing low levels of organic or inorganic materials and having a neutral pH. Tap water is okay. It is recommended that mixing tanks are kept separately for sole use with AgroSimplex Formula -‐ 4. This will avoid the AgroSimplex Formula -‐ 4 solution being mixed with any previously used products which may cause a reaction. AgroSimplex Formula -‐ 4 mixes readily with clean, neutral water and does not require agitation.

3. AgroSimplex Formula -‐ 4 is a strong oxidising agent and may react with residues of metal based fungicides or supplements. Care must be used when applying AgroSimplex Formula -‐ 4 as a foliar spray immediately following foliar applications of metal-‐based products.

4. Surfactant may be added to AgroSimplex Formula -‐ 17 if needed for treatment of plants with difficult to reach surfaces or for plants having waxy or hairy surfaces. Surfactant should be added last. APPLICATION OF AGROSIMPLEX FORMULA -‐ 4 1. Add 1 gallon (4 litres) of water into clean spray tank. 2. Add 1fl.oz 30 mls of AgroSimplex Formula -‐ 4 3. Mix solution thoroughly before starting spray pump

Thoroughly wet all surfaces of plant including upper and lower foliage, stems, branches and stalks to ensure full contact with plant tissue.

4. Work from the back of the area identified through to front to avoid brushing against plants/trees which have just been treated with AgroSimplex Formula -‐ 4.

5. Spray product in a wide circle around the base of each plant/tree. This is to avoid spores being dispersed into the surrounding area whist treating the affected plants.

6. Spray the soil within the circle around the base of the plant. 7. Work from bottom of plant to top to ensure product does not drip onto clothing or

skin during application. Always wear eye protection to avoid accidental spray or drift into the eyes.

8. For diseases such as coffee rust which affects the underside of the leaves it is necessary to spray underneath the leaves to ensure contact with spores. Spray the topside of leaves for treatment of all diseases which affect the top surface of the plant.

9. Spray stem and overhanging leaves. 10. Clean hands with disinfectant wipes after removing gloves to ensure there is no

transfer of spores to non-‐ infected areas.


11. For optimal results it is recommended that initially crops should be treated with AgroSimplex Formula -‐ 4 3 times. AgroSimplex Formula -‐ 4 can be reapplied as soon as the previous application has dried. Depending on climatic conditions, altitude, etc it is possible to complete 3 applications on the same day. However, effective treatment can be obtained with only 1 spay (60-‐ 80%) to be followed up with regular spraying of AgroSimplex Formula -‐ 4 as part of the normal spraying protocol. i.e. If at present, spraying is undertaken every 2 weeks for control of disease, then AgroSimplex Formula -‐ 4 should be sprayed liberally every 2 weeks to ensure that the disease is efficiently controlled and to prevent spread of spores to areas which are not infected.

12. AgroSimplex Formula -‐ 17 should be sprayed over the top of the plant and leaves. This can be done anytime after as the AgroSimplex Formula -‐ 4 has dried.

AgroSimplex Formula -‐ 17 is an integral part of the protocol in control and recovery of affected crops and for optimum results should be applied within days of spraying AgroSimplex Formula -‐ 4.

APPLICATION OF AGROSIMPLEX FORMULA -‐ 17 1. Add 1 gallon (4 litres) of water into clean spray tank 2. Add 1fl.oz (30mls) of AgroSimplex Formula -‐ 17 3. Mix solution thoroughly before starting spray pump 4. Work from the back of the area to be treated through to front to avoid brushing

against plants/trees which have just been treated with AgroSimplex Formula -‐ 17 . 5. Always spray over the top of plant, include all leaf surfaces and the soil underneath. 6. Diluted product can be stored maximum 1 week.

It is possible to add fertilisers or other adjuvants to AgroSimplex Formula -‐ 17, however where this is done it is always recommended that the other additives are diluted prior to adding concentrated AgroSimplex Formula -‐ 17 at the same dosage as above. Mix well before spraying.

THE AGROSIMPLEX FORMULA -‐ 4/AGROSIMPLEX FORMULA -‐ 17 REGIME SHOULD BE CARRIED OUT EVERY 2-‐3 WEEKS TO ENSURE EFFECTIVE CONTROL OF INFECTIONS. THIS REGIME WILL ALSO MAXIMISE PLANT RECOVERY AND REGROWTH .


Material Safety Data Sheet

Product Name: AgroSimplex Formula -‐ 4 Product description: Liquid

Product Use: Agriculture

Supplier’s Name: AgroSimplex

Address: 1313 Ross Road, North Vancouver, B.C, Canada

Emergency Telephone: +001 778-‐835-‐5251

Emergency Contact: Tyler Mackay

Section 1: Product Information Product Name: Chemical Name: DOT Shipping Name: CAS Registry: Chemical Family: Chemical Formula: Formula Weight: ACGIH: OSHA:

AgroSimplex Formula - 4 1 Hydrogen Peroxide 34% & stabilising agents (Trade Secret) UN 2014, Hydrogen Peroxide, Aqueous Solutions, 5.1 (8) PG II 7722-84-1 Inorganic Peroxide H202 34.02 TLV 1 ppm STEL None PEL 1 ppm STEL None


Section 2: Health Data Eye Contact: Exposure to the vapors, mists, or liquids can cause severe eye irritation or burns. Flush eyes with a directed stream of water for at least 15 minutes. Forcibly hold eyelids apart to ensure complete irrigation of all eyelid tissue. Get immediate attention if irritation occurs. Contact lenses should not be worn when working with this chemical.

Skin Contact: Exposure can cause severe skin irritation or burns. Immediately flush skin with water. If the chemical penetrates clothing, immediately remove the clothing and flush the skin with water. Get prompt medical attention if irritation occurs. Wash clothing before reuse. Ingestion: Can cause severe irritation or burns to the entire gastrointestinal tract. Ingestions of large amounts may be fatal. If person is conscious, immediately administer large quantities of water.

Never give anything by mouth to an unconscious person. Do not induce vomiting. GET IMMEDIATE MEDICAL ATTENTION. Inhalation: Move the exposed person to fresh air at once. If breathing stops, give artificial respiration. If breathing is difficult, administer oxygen. Seek medical attention if irritation persists. Note to Physician: Direct contact with the eye is likely to cause corneal damage, especially if not washed away immediately. Careful ophthalmologic evaluation is recommended, and the possibility of local corticosteroid therapy should be considered. Attempts at evacuating the stomach via emesis induction or gastric lavage should be avoided. In the event of severe distension of the stomach or esophagus due to gas formation, insertion of a gastric tube may be required. Effects of Overexposure: Contact of the skin with hydrogen peroxide may cause severe skin irritation. Contact of eye may cause eye irritation with tearing or blurring vision and possible blindness. Inhalation may include irritation of the upper respiratory passages, nausea, headache or weakness. Ingestion may include irritation of the gastrointestinal internal tract and abdominal pain or red blood cell destruction.


Toxicity: Laboratory Animals: Acute Oral Toxicity: LD50 for different species are in the

range of 700mg/kg (90% H202) 9,200mg/kg (70% H202). LC50 for rat is greater than 200mb/m3 (75% H202)

Acute Dermal Toxicity Non - Toxic (Rabbit): Primary Skin Irritation Mildly irritating (Rabbit): Primary Eye Irritation Extreme irritation (Rabbit): Carcinogenicity: Non identified NTP: No IARC: No ACGIH: No OSHA: No


Section 3: Fire and Explosion Hazard Data Extinguishing Media: Use water only to fight fire where hydrogen peroxide is involved. Special Fire Fighting Procedure and Personal Protection: Avoid all bodily contact. Wear self-contained breathing apparatus and appropriate protective equipment. In case of external fire, cool hydrogen peroxide and surrounding containers with plenty of water. Unusual Fire and Explosive Hazards: Spontaneous combustion can occur if allowed to remain in contact with oxidizable materials. Drying product in clothing or combustible material may cause fire. Do not heat solution to concentrations of 74% or greater. Do not allow temperature of storage tank to rise above 100° F (38° C). Mixtures with combustible material may be explosive. Flashpoint: Non-Flammable

Hazardous Reactivity

Stability: Unstable when heated or contaminated with heavy metals, reducing agents, rust, dirt or organic materials. Incompatibility: Incompatible with cyanides, iron, copper and its alloys, hexavalent, chromium compounds, nitric acid, potassium permanganate, reducing agents and other flammables and combustibles.

Hazardous Products of Decomposition: Contamination from any source may cause rapid decomposition, oxygen gas release, and dangerous pressures. Polymerization: Will not occur.

Section 4: Handling and Storage Precautions: Store in a properly vented container or in approved bulk storage facilities. Do not block vent. Store drums on flame retardant pallets. Do not store where contact with incompatible materials could occur, even with a spill. Have water source available for diluting. Keep containers out of sun and away from heat, sparks, and flames. Do not add any other product to container. Never return any unused product to container. Rinse empty containers thoroughly with clean water before discarding.

Section 5: Environmental Protection Procedure in case of spill or release: Obtain full protective equipment, including respiratory protection. Review fire and explosion hazards and safety precautions before proceeding with clean up. Dilute with a large volume of water, and contain runoff until hydrogen peroxide decomposes. Do not allow to escape into sewers or natural watercourses before decomposition. May be destroyed with sodium metabisulfite or sodium sulfite (1.7lbs SO2 equivalent per lb of hydrogen peroxide) after diluting to 5-10% hydrogen peroxide. Care must be exercised because of temperature rise. Waste disposal method: After decomposition, consult with local, state and federal officials, and, subject to their approval, discharge into suitable treatment system. If product is released prior to decomposition, it is termed hazardous waste as defined by 40 CFR261 and would have the following EPA hazardous waste: D001.

Section 6: Regulatory Status Sara Title III Section 311/312 classifies hydrogen peroxide as an immediate health hazard and a fire hazard. The minimum threshold quantity for reporting is 10,000 pounds.

Extremely Hazardous Substance: No CERCLA Hazardous Substance: No SARA Title III Section 313 Toxic Chemicals: No TSCA Inventory: Yes Process Safety Management: No RISK Management Program: No

Section 7: Transportation Data UN 2014, Hydrogen Peroxide, Aqueous Solutions, 5.1 (8) PG II Hydrogen peroxide above 8% concentration is classified as an "oxidizer and corrosive" by the DOT and must be labeled accordingly.

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Document prepared by Dr. H.E. Keenan 30th July 2014

MATERIAL SAFETY DATA SHEET (MSDS)

Date MSDS Prepared 26/1/2014 24 Hour Emergency Contacts

Revision Number 1: Revised July 2014 Tyler Mackay +001 778-‐835-‐5251

MSDS Prepared By: Dr H Keenan Cchem Csci MRSC

Phone Number +4407944706642

SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: AgroSimplex Formula -‐ 17 Product description: Mixture Product Use: Plant Stimulant

Manufacturer’s Name: AgroSimplex Supplier’s Name: AgroSimplex

Address: 1313 Ross Road, North Vancouver, BC, Canada Emergency Telephone: +001 778-‐835-‐5251

SECTION 2 — COMPOSITION / INFORMATION ON INGREDIENTS

Product Description : Liquid Mixture This Mixture is claimed as a Trade Secret and as such the composition is withheld.

Registered as International Class 001- Substances for regulating plant growth.

However it is disclosed that the mixture is a combination of several chemicals at different concentrations.

Active Ingredients

INGREDIENT Quantity

Volume % OSHA PEL ACGIH TLV

1 <10% 3ppm, 6 mg/m3 3ppm

2 <10% Not Listed Not Listed

3 20-40% Not Listed Not Listed



6 <10% Not Listed Not Listed

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SECTION 3 — HAZARDS IDENTIFICATION

Potential Health Effects

OSHA regulatory Status: This mixture is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200)

SECTION 4 — FIRST AID MEASURES

Skin Contact:

Take off contaminated clothing. Rinse skin immediately with plenty of water. Call a Poison Control Centre or Doctor for further treatment advice.

Eye Contact:

Hold eye open and rinse slowly and gently with water for 15-20mins. Remove contact lenses, if present after first 5 minutes then continue rinsing the eye. Call a Poison Control Centre or Doctor for further treatment advice.

Inhalation:

Move to Fresh air. If person not breathing call emergency doctor or ambulance, then give artificial respiration (mouth to mouth if possible) until assistance arrives. Call a Poison Control Centre or Doctor for further treatment advice.

Ingestion:

Have person sip a glass of water if able to swallow. Do NOT induce vomiting. Do not give anything by mouth to an unconcious person. Call a Poison Control Centre or Doctor for further treatment advice.

SECTION 5 — FIRE FIGHTING MEASURES

Flammable

❐Yes ☑ No

If yes, under which conditions?

Means of Extinction

Water spray, carbon dioxide, fine-earth or sand. Flashpoint (° C) and Method

Not Determined

Upper Flammable Limit (% by volume)

Not Determined

Lower Flammable Limit (% by volume)

Not Determined

Autoignition Temperature (°C)

Not Determined

Explosion Data — Sensitivity to Impact

Not Determined

Explosion Data — Sensitivity to Static Discharge

Not Determined Hazardous Combustion Products

Not Determined

SECTION 6 — ACCIDENTAL RELEASE MEASURES

General Procedures: Extinguish all ignition sources. Flush area with water.

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If checked, please specify type

Safety Glasses with side shield are recommended when handling undiluted Product. Disposable gloves. Overall or apron.

SECTION 7 — HANDLING AND STORAGE

General Procedures: Rinse all equipment after use. All rinse water can be applied as product.

Handling: Wear Safety Goggles and Gloves when working with undiluted product. Wash hands with water after handling product.

Storage: Store in a cool dry area in closed container. Keep in original container, do not reuse container for consumables. KEEP OUT OF REACH OF CHILDREN.

Diluted product is safe for handling without personal protective equipment.

SECTION 8 — EXPOSURE CONTROL / PERSONAL PROTECTION Exposure Limits: ACGIH TLV Applies to pure chemical. This product is a mix in which <10% is present therefore it is unlikely TLV will be exceeded.

☑ ACGIH TLV ❐ OSHA PEL ❐ Other (specify)

Specific Engineering Controls (such as ventilation, enclosed process)

Ensure adequate ventilation during dilution.

Personal Protective Equipment ☑ Gloves ❐ Respirator ☑ Eye ❐ Footwear ☑ Clothing ❐ Other

SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES Physical State

Liquid

Odour and Appearance

Alcohol/amine smell, slightly viscous green/yellow liquid

Odour Threshold (ppm)

Not Determined Specific Gravity 1.03-1.05

Not Determined

Vapour Density (air = 1)

Not Determined

Vapour Pressure (mmHg)

Not Determined Evaporation Rate

Not Determined

Boiling Point (° C)

Not Determined

Freezing Point (° C)

Not Determined pH 9.9-10.2 Coefficient of Water/Oil Distribution

Not Determined

[Solubility in Water]

100%

SECTION 10 — STABILITY AND REACTIVITY Stability: Stable

Reactivity, and under what conditions? Not Determined.

Hazardous Decomposition Products: None

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SECTION 11 — TOXICOLOGICAL INFORMATION The Toxicological information is based on the individual ingredients in the product. The dilution effect must be taken into consideration when considering the toxicology of the mixture that is AgroSimplex Formula - 17 . Carcinogenicity: IARC: No NTP: No OSHA: No This product contains Ingredient 1 at a concentration of <10%. This chemical has a stated occupational exposure limit (ACGIH, OSHA) of 3ppm or 6 mg/m3. However the volatility and effect of this chemical is much reduced by dilution, and therefore the stated level would be difficult to achieve. This product (AgroSimplex Formula - 17) should also be diluted prior to use and the final concentration of AgroSimplex Formula - 17 is < 0.5% when diluted at recommended rates.

SECTION 12 — ECOLOGICAL INFORMATION [Aquatic Toxicity]

The active ingredients 1,2 & 5 were all considered below criteria for persistence, bioaccumulation and toxicity. i.e. they are non persistent, non bioaccumulative & non toxic. (http://www.pbtprofiler.net/default.asp see

http://www.pbtprofiler.net/Details.asp for criteria)

Ingredient 3 cannot be modelled due to insolubility, it is however a naturally derived ingredient. The MSDS supplied with the chemical shows no toxicity (all values >1000mg/l fish & daphnia) and states that it is readily biodegradeable.

Ingredient 4 cannot be modelled as it has no entry in database, however the MSDS shows no toxicity and states that it is readily biodegradable.

This product (AgroSimplex Formula - 17 ) is highly beneficial to plant life and there are no known adverse effects on aquatic life.

A Full Ecological Assessment is available on request.

SECTION 13 — DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Waste disposal must be in accordance with Federal, state, and local regulations. Be aware that the waste owner has responsibility for final disposal. Regulations may also apply to empty containers. This material can be safely disposed to drain, flush with plenty of water. SECTION 14 — TRANSPORT INFORMATION

This product is non hazardous by the OSHA classification as set out in document https://www.osha.gov/dsg/hazcom/ghs.html#3.0

Not DOT/ ICAA/ IMDG regulated.

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SECTION 15 — REGULATORY INFORMATION

NA

Fire:No Pressure Generating:No Reactivity:No Acute:No Chronic:No SECTION 16 — OTHER INFORMATION REVISION SUMMARY: Revised July 2014 New MSDS