akzo nobel general catalog

S U R FA C E C H E M I S T R YG E N E R A L C ATA L O G

I N T R O D U C T I O N . . . . . . . . . . . . . . . . 1

P R O D U C T A P P L I C AT I O N S . . . . . . . . . . 2

FAT T Y A M I N E C H E M I S T R Y O V E R V I E W . . 3

L I S T I N G O F N I T R O G E N D E R I VAT I V E S . . 10AMINES Armeen® Amines

Primary Amines

Dialkyl Secondary Amines

Alkyl Dimethyl Tertiary Amines

Dialkyl Methyl Tertiary Amines

Trialkyl Tertiary Amines

Duomeen® N-Alkyl Propane DiaminesTriameen® and Tetrameen® N-Alkyl Higher AminesEthomeen® Ethoxylated AminesEthoduomeen® Ethoxylated DiaminesPropomeen® Propoxylated Amines

AMINE SALTSArmac® Amine Acetates

QUATERNARY AMMONIUM SALTSArquad® Quaternary Salts

Alkyltrimethyl Quaternary Salts

Dialkyldimethyl Quaternary Salts

Trialkylmethyl Quaternary Salts

Benzylalkyl Quaternary Salts

Ethoquad® Ethoxylated Quaternary SaltsDuoquad® Diquaternary Salts

AMINE OXIDESAromox® Amine Oxides

Alkyl Dimethyl Amine Oxides

Bis(2-hydroxethyl) Alkyl Amine Oxides

AMIDESArmid® AmidesEthomid® Ethoxylated Amides

NITRILESArneel® OD

CORROSION INHIBITORSArmohib® Products

A N I O N I C C H E M I S T R Y O V E R V I E W . . . . . . 2 2

L I S T I N G O F A N I O N I C S U R FA C TA N TS . . . . 2 4SULFONIC ACIDS AND SULFONATESPetro® Alkyl Naphthalene SulfonatesWitconate™ Alpha Olefin SulfonatesWitconate™ Alkylbenzene SulfonatesWitconate™ Aryl/Alkyl Aryl Sulfonic Acids

SULFATESWitcolate™ Alkyl/Alkyl Ether/Alkyl Aryl Ether Sulfates

PHOSPHATE ESTERS Phospholan™ Alcohol PhosphatesPhospholan™ Alcohol Ethoxylate PhosphatesPhospholan™ Phenol/Alkyl Phenol Ethoxylate PhosphatesPhospholan™ Alkyl Amine Phosphate

CARBOXYLATES Emcol® Ethoxylated Carboxylate

SULFOSUCCINATES Lankropol™ Sulfosuccinates

N O N I O N I C C H E M I S T R Y O V E R V I E W . . . . . 3 4

L I S T I N G O F N O N I O N I C S U R FA C TA N TS . . . 3 6Amadol® AlkanolamidesEmulpon™ Castor Oil EthoxylatesEthofat® Ethoxylated Fatty AcidsEthylan™ Linear and Branched Alcohol AlkoxylatesWitconol™ Alkyl Phenol AlkoxylatesWitconol™ Polyols/Polyol EstersWitconol™ Resin Alkoxylates

A P P E N D I C E S . . . . . . . . . . . . . . . . . . . 4 2Solubility of Armeen AminesSolubility of Ethoxylated ProductsSolubility of Arquad Quaternary Ammonium Compounds

C U S TO M E R S E RV I C E & S U P P O RT . . . . . . . 4 7

T R A D E M A R K E D P R O D U CTS N OT L I S T E D . . . 4 8

C O N T E N TS

I N T R O D U C T I O N This catalog contains information about specialty chemicals offered by Akzo Nobel

Surface Chemistry LLC. Among these are fatty amines, amine salts, quaternary

ammonium compounds, amine oxides and amides. Naphthalene and alpha olefin

sulfonates, alkyl and alkyl ether sulfates, alcohol and phenol-derived alkoxylates,

polyols, phosphate esters, sulfosuccinates and alkanolamides are also offered.

The majority of these compounds are surface active agents,

used in hundreds of commercial applications.

Our product portfolio, with the acquisition of the Industrial Specialties division of

Crompton Corporation, has expanded to include nitrogen-based cationic, anionic

and nonionic surfactants. We now offer the formulator and chemical investigator a

robust portfolio of surface-active agents and intermediates from which to choose.

Our chemical technology expertise, efficient manufacturing facilities, research and

development support and commitment to providing quality products help fulfill

our promise to be your responsive partner in rheology and surface

chemistry wherever you are.

This catalog lists our product range, specifications, typical properties and

applications. Minimum order quantities may be required for some of the chemicals

in this catalog. Should you require additional information or wish to inquire

about the availability of related products, please contact our Customer Service or

Technical Service personnel at 1-800-906-9977, email [email protected] or

via our website at http://surface.akzonobelusa.com. We will be pleased to help you.

INTRODUCTION 1

2 FATTY AMINE CHEMISTRY OVERVIEW

Agricultural Chemicals• inert ingredients Ethomeen, Arquad, Petro chemicals

(under Title 40 CFR 180.1001) Ethoquad, Armeen• adjuvants • emulsifiers Armac chemicals• anticaking • dispersing

Antistatic Agents• textiles • polymers Arquad, Ethoquad, Phospholan chemicals• electronics • paper Ethomeen, Armac chemicals• electrostatic spraying

Bitumen Chemicals Arquad, Duomeen, Duoquad chemicals

Corrosion Inhibitors• acid • metal working Armeen, Arquad, Ethomeen, Phospholan chemicals Amadol chemicals• petroleum • water treatment Duomeen chemicals

Armohib® chemicals

Demulsifiers• paper • pharmaceuticals Arquad, Ethomeen, • petroleum Propomeen chemicals

Detergents• fabric softeners • thickeners Arquad, Ethoquad, Aromox, Witcolate, Witconate, Witconol, Ethylan chemicals• cleaners Armosoft chemicals Phospholan chemicals

Dishwashing Liquids Aromox chemicals Witcolate, Witconate chemicals Witconol, Ethylan, Amadol chemicals

Dispersing Agents• pigments • paints Arquad, Armeen, Armac, Duomeen, Petro, Phospholan, Witconol, Ethylan chemicals• inks Duomac, Triameen chemicals Lankropol chemicals

Emulsifiers• oil • wax polish Arquad, Ethomeen, Phospholan chemicals Witconol, Ethylan, Amadol • leather treatment • solvent cleaners Duoquad, Ethoquad, chemicals• silicones • triglycerides Ethomid chemicals

Foaming Agents Arquad, Aromox chemicals Witconic, Witcolate, Witconate, Petro, Phospholan chemicals

Metal Working• cutting fluids • metal cleaning Armeen, Ethomeen, Phospholan chemicals• lubricants Duomeen chemicals

Mineral Processing• anticaking agents • flotation agents Armeen, Armac, Lilamin®, Petro chemicals• flocculating aids Armoflo® chemicals

Organoclays Arquad chemicals

Paper Manufacture• deinking • printing aids Armid, Ethofat, Lankropol, Petro, • coatings • absorbency Ethomeen chemicals Phospholan chemicals• softening/debonding/pulping

Personal Care/Cosmetics• hair conditioners • resin neutralizers Arquad, Ethoquad chemicals, Witcolate, Witconate, Lankropol, Amadol chemicals• shampoo cosurfactants Armeen, Ethomeen chemicals, Phospholan chemicals• thickeners Ampholak, Aromox chemicals

Petroleum Production• thickened fracturing fluids Ethoquad, Aromox chemicals, Petro, Witconate chemicals,• diesel oil emulsions Armac, Duomeen, Arquad chemicals, Witconate chemicals• antiswelling agents Arquad chemicals, • corrosion inhibition/water Duomac, Arquad, Armeen • demulsifiers chemicals• paraffin control

Petroleum Refined Products• corrosion inhibition/lubricants Armeen, Ethomeen, Aromox, Armid,

Duomeen, Arquad chemicals

Pigment Producing Additives• filler dispersants Duomeen, Triameen chemicals Petro, Witconate chemicals• stabilizer intermediates Arquad, Ethomeen chemicals• mold release agents Armeen chemicals

Armid, Arneel chemicals

Sugar Refining Additives Arquad chemicals

Textile Auxiliaries• dyeing assistants Arquad, Armeen, Ethomeen, Petro chemicals, Witconic, Amadol chemicals• lubricants/scrooping Ethoquad chemicals, Witconate, Witcolate, Phospholan, Witconol chemicals• scouring Ethomid chemicals Lankropol, Emcol chemicals

Vehicle Cleaning Formulations Arquad, Ethomeen chemicals Witcolate, Witconate, Petro chemicals Witconol chemicals

Water Treatment Chemicals• filming amines Armeen, Armac chemicals• flocculants Arquad chemicals• corrosion inhibitors Arquad, Duomeen chemicals

APPLICATION NITROGEN DERIVATIVES ANIONICS NONIONICS

Many applications are made possible using the cationic, anionic and nonionic products presented in this catalog. Their versatility is illustrated by the following list of industrial,detergent and personal care applications with examples of Akzo Nobel products to be used.

R E C O M M E N D E D P R O D U C TS

FAT T Y A M I N E C H E M I S T R Y O V E R V I E W

FATTY AMINE CHEMISTRY OVERVIEW 3

FIGURE 1. AKZO NOBEL SURFACE CHEMISTRY PROCESS OVERVIEW

Raw Materials

Finished Products

Kortacid®Nouracid® Armid

ArmacDuomac

ArquadDuoquadEthoquadArmosoft®Redicote

ArmeenDuomeenTriameenRedicote®Berol®

EthomeenEthomidEthofatRedicoteBerolElfacos®Bermodol®

AromoxEthylene Oxide

Bermocoll®Ampholak®Berol

Animal Based FatsVegetable Based Oils

CelluloseAlcohols

Glucose

Amidation

Neutralization

Alkylation

Oxidation

Alkoxylation

HydrogenationNitrilation

Glycerine

Distillation

Fat/OilHydrolysis

Esterification Quaternization


This review describes the chemistry of fatty amines and relatednitrogen derivatives offered by Akzo Nobel Surface ChemistryLLC. These products are produced at three plants in NorthAmerica. This output, when combined with the production ofour European, Brazilian and Japanese plants, makes AkzoNobel the world's leading supplier of fatty amines and theirderivatives. The combined research programs of our group areextensive and ensure that Akzo Nobel will maintain its foremostposition in fatty amine technology.

The basic building blocks of the products are the primary,secondary and tertiary amines and diamines described in thisbrochure. These are based on alkyl groups ranging from C8 toC22, with C12 to C18 most predominant. In most cases, theproducts are derived from natural feedstocks. Table 1 displaysthe alkyl percent distributions for the various fattyalkyl groupsused in the manufacture of our products.

By protonation, alkylation or ethoxylation, the product group isextended in order to form a range of surfactants offering a widespectrum of melting point, solubility and cationic activity. Therange of derivatives is sufficiently extensive to meet the needsof almost all Cationic Surfactant users

• as chemical intermediates• as essential processing aids, and• as functional ingredients in many formulations.

Figure 1 gives an overview of the interconnecting process stepsto produce these derivatives. Our major trademarks are givenfor the finished products.

Many applications are made possible using fattyalkyl aminesurfactants because of one or more of the three functionsdescribed in the next section. Their versatility can be illustratedby the following list of industrial, detergent and personal careapplications with examples of Akzo Nobel products used: (see chart on page 2)

TABLE 1. APPROXIMATE ALKYL PERCENT DISTRIBUTION FOR FATTYALKYL AMINES

hexa

decy

l-

octa

decy

l-

oley

l

coco

soya

tallo

w

hydr

ogen

ated

tallo

w

dode

cyl-

Alk

ylCo

mpo

sitio

n

hydr

ogen

ated

rape

seed

S AT U R AT E D

U N S AT U R AT E D

C8 6C10 0.5 7C12 99 0.5 51 0.5C14 0.5 0.5 1.5 19 1.0 3 3.5 0.5C15 0.5 0.5C16 97 2.5 4 9 16 29 31 3.5C17 0.5 1 1C18 2.5 96.5 8-14 2 15 20 61 38C20 0.5 8C22 50

C14’ 0.5 0.5C16’ 4 1.0 2C18’ 0.5 70-74 6 49.5 44 3C18” 5 13

* Composition is that of base acids from which amines were derived.

I n t r o d u c t i o n

swap in hi res

Ethylene

F u n c t i o n a l P r o p e r t i e s o f F a t t y A m i n e s a n d D e r i v a t i v e s


The molecular structure of fatty amines and derivatives is characterized by one or more C8 to C22 aliphatic alkyl groups, R,with one or more amine or quaternary ammonium functionalities:Because of the number of carbon atoms in the alkyl group, this group

is strongly hydrophobic, that is, it is repelled by water. On the otherhand, the nitrogen atom is hydrophilic or water loving, particularlywhen it is protonated, alkoxylated or quaternized. Substances whichcontain groups in the same molecule with such opposite functions arereferred to as amphiphilic. When dissolved or dispersed in water ornon-aqueous solvents, one portion of the molecule is strongly repelledby its surrounding solvent. Because of this repelling force, thesemolecules tend to orient themselves at surfaces and interfaces, or form micelles (aggregates of oriented molecules), as shown in Figure 2.Such orientation/aggregation phenomena are called surface activityand materials that exhibit it are surface active agents, often referredto as surfactants.

Surfactants are classified by the nature of their hydrophilic moiety,which carries a negative ionic charge in anionic surfactants, or apositive ionic charge in cationic surfactants. The hydrophilic moiety innon-ionic surfactants is usually a neutral polyoxyalkylene group. Incationic surfactants the positive charge may be derived from severalchemical functional groups, such as sulphoxonium, oxonium,phosphonium, iodonium, etc. Commercially, however, it is usuallyassociated with a nitrogen atom contained in an amine or quaternaryammonium group. The cationic nature of fatty amines and derivativeshas given rise to a wide variety of uses in many applications. These functions may be recognized as being derived from three basic properties:

A. Surface Activity

B. Substantivity

C. Reactivity

1. The surface active properties of many fatty amines and derivativesrelate to the amphiphilic molecular structure, which leads to orientationat interfaces (see figure 2). As a result, interfacial tension is affected and a number of surfactant functions can be seen:

• emulsification • foaming• wetting • thickening

2. The term substantivity refers to the adsorptive properties ofcationic surfactants and related nitrogen derivatives. Adsorption,particularly onto solid surfaces, results from the attraction between the positive charge on the nitrogen atom and the negative chargecharacteristic of most surfaces. Consequently, substantivity leads tosurface modification and to the following functions:

• softening • corrosion inhibition• anti-static properties • adhesion• lubrication • hydrophobation

3. Reactive properties of cationic surfactants can be identified inseveral uses, in particular when complexes are formed with anionicspecies on a molecular level, governed by stoichiometry. Frequently,such complexes show very low solubility in water, so that the following functions can be found in such areas as water treatment,sugar refining, and the production of organo clays:

• flocculation • ion exchange• decolorization

F I G U R E 2 . O R I E N TAT I O N O F S U R FA C TA N T I N S E V E R A L S Y S T E M S

orientation in water

orientation in non-polar solvent

orientation at air/water interface

orientation at air/oil interface

The following properties of fatty amines and derivatives may beused as guideposts in their selection in a variety of applications.

SolubilitySolubility of surfactants is a primary criterion for their selection.Tables 1, 2 and 3 in the Appendices summarize the solubilitybehavior in various solvents for fatty amines and their ethoxylatedand quaternary derivatives, respectively.

A. Solubility in waterAlkylamines of C8-C22 chain length are only slightly protonated at neutral pH and thus are insoluble in water:

In acidic media, protonation is proportional to the strength of theprotonating acid and the resulting amine salt is much more soluble:

In general, one protonated amino group is sufficiently hydrophilicto solubilize an alkyl chain containing up to twelve methylenegroups. Solubilization of an octadecyl (C18) alkyl group requirestwo protonated amino groups as provided in Duomeen® T at low

pH, for example. The increased aqueous solubility associated withprotonation comes with a considerable increase in positive charge. This is also achievable by alkylation of the nitrogen atom, formingquaternary ammonium compounds. Monoalkyl trimethylammonium chlorides are soluble in water up to a concentrationrange of 30% (for C18) to 40% (for C12). Above this concentrationlevel, the surfactant forms a liquid crystalline phase. For dialkyldimethyl ammonium chlorides, literature states that this solubilitylimit is found at much lower levels, as low as 0.001% fordi(hydrogenated tallowalkyl) ammonium chloride, Arquad® 2HT.This quaternary salt, however, can form stable dispersions as aresult of molecular aggregation into vesicles. These consist ofbilayers spaced by aqueous layers arranged in concentric circles.Water solubility also is increased by the introduction of neutralhydrophilic groups such as polyoxyethylene groups, in which casethere is no increase in charge on the nitrogen atoms. Ethoxylationof aliphatic amines yields the Ethomeen® series. Solubility ofEthomeen compounds is dependent upon the degree ofethoxylation (see Table 2 in Appendices). Ethomeen C/12, forexample, contains two oxyethylene units per molecule and isinsoluble in water, whereas Ethomeen C/25 contains fifteenoxyethylene units per molecule and is water soluble.

Factors which affect water solubility are summarized in Table 2.

S e l e c t i o n C r i t e r i a f o r F a t t y A m i n e s a n d D e r i v a t i v e s

TA B L E 2 . FA C TO R S A F F E C T I N G WAT E R S O L U B I L I T Y

WATER SOLUBILITY INCREASES:

a. influence of alkyl chain

• by decrease in chain length (or molecular mass)

• by increase in unsaturation

b. influence of nitrogen moiety

• by increase in number of functional groups

• by increase in degree of ethoxylation

• by formation of salts

• by quaternization

c. influence of medium

• by decreasing pH


B. Solubility in non-aqueous mediaFatty amines and derivatives generally show appreciable solubilities in polar organic solvents such as methanol, ethanol andisopropanol, and in non-polar solvents. In hydrocarbons, solubilitydepends on the alkyl chain length, on the degree of unsaturationand on the cationic character of the nitrogen moiety.

C. Solubility in two-phase systemsWhen a surfactant is dissolved in a two-phase system consisting ofwater and, for example, a hydrocarbon such as n-heptane, itdistributes itself in the two phases. The relative solubility isdependent on the nature of the surfactant and on the nature of thesystem, and can be expressed by the so-called partition coefficient.The effect of pH on partitioning may be dramatic as in the case ofamines that can be protonated and consequently have apreference for the aqueous phase at low pH. This is illustrated inFigure 3, showing the partition of Armeen® C (a primary amine)between n-heptane and water as a function of the pH of theaqueous phase.

Hydrophile-Lipophile BalanceThe orientation of surfactant molecules at a water/solvent interface,as shown in Figure 2, leads to important performance properties ofthe surfactant such as emulsification. A classification of surfactantsthat can help in selecting an appropriate emulsifier is theHydrophile-Lipophile Balance (HLB) value. The HLB valueindicates where the relative hydrophilicity of a particular surfactantlies. Higher HLB values correspond to stronger hydrophiliccharacter of the surfactant. Akzo Nobel Surface Chemistry uses the Davies scale of 0-40 to classify its surfactants. These values are found in the product description section of this catalog.

Emulsions may be classified as oil in water, in which hydrophobicmaterial is dispersed in water, or as water in oil, in which water isdispersed in hydrophobic material. Formation of oil in water (O/W)emulsions is favored by emulsifiers having a high HLB value. Thus,ethoxylated amines such as Ethomeen C/15 and Ethomeen C/25are used in applications where O/W emulsions are desired. Insimilar applications but at high pH, the corresponding Ethoquad®ethoxylated quaternary salt might be preferred, due to increasedsolubility derived from the quaternized amine group. For water inoil (W/O) emulsions, low HLB surfactants are more effective. Lower ethoxylates of higher molecular weight alkylamines would be considered for such applications, including Ethomeen S/12and Ethomeen T/12.

F I G U R E 3 . PA R T I T I O N O F C O C O A M I N E [ A R M E E N C ] I N N - H E P TA N E / WAT E R .


Surface tensionSurfactants exhibit both adsorption phenomena and the ability toform micelles. Due to adsorption at the air/water interface, adecrease of surface tension is observed with increasing surfactantconcentration (see Figure 4). At a rather distinct surfactantconcentration, the Critical Micelle Concentration (CMC), theformation of micelles starts and thereafter the free surfactantconcentration remains constant, as does the surface tension, γc.

F I G U R E 4 . S U R FA C E T E N S I O N A S A F U N C T I O N O F S U R FA C TA N T C O N C E N T R AT I O N

Table 3 shows typical values of the surface tension forrepresentative fatty amine derivatives.

γc DYNES/CMSURFACTANT (WATER, 20ºC)

Armeen 12D (at pH 4, neutralized with HCl) 27

Aromox C/12-W 31

Arquad 16-50 34

Ethomeen S/12 32

Ethomeen T/15 33

Ethomeen C/25 41

Ethoquad 18/25 50

Other surfactant characteristicsIn order to select the appropriate fatty amine or derivative, the determination of the following surface active properties can be helpful:

• foaming characteristics (e.g., according to Ross-Miles)

• Kraft point• Cloud point

Other physical and chemical propertiesDuring processing, properties such as melting point, boiling pointand flash point are important. Some properties are affected by thedegree of unsaturation; for example, the melting point increaseswith increasing removal of double bonds (by hydrogenation) in the alkyl chain. Solubility is also influenced. Unsaturation may play arole in applications where chemical reactivity has an influence.


TA B L E 3 . T Y P I C A L S U R FA C E T E N S I O N VA L U E S

R e p r e s e n t a t i v e E x a m p l e s o f N i t r o g e n D e r i v a t i v e s O f f e r e d b y A k z o N o b e l

C H E M I C A L T R A D E F O R M U L AT Y P E N A M E

C H E M I C A L T R A D E F O R M U L AT Y P E N A M E


10 NITROGEN DERIVATIVES

N I T R O G E N D E R I VAT I V E S

Prim

ary

Am

ine,

%

Am

ine

Num

ber

Gar

dner

Col

or

Moi

stur

e %

Equi

vale

nt W

eigh

t**

Mel

ting

Poin

t,ºC

Prim

ary

Am

ine,

%

Am

ine

Num

ber

Iodi

ne V

alue

HLB

Dav

ies

Scal

e

NITROGEN DERIVATIVES 11

PRODUCT COMMON NAME* TSCA NUMBER

SPECIFICATIONS

Min. Min. Max.

ARMEEN 12D*** Dodecylamine 124-22-1 98 297 1 0.5 186 24 99.5 303 0.5 10.7

ARMEEN 16D Hexadecylamine 143-27-1 98 228 1 0.5 243 48 99 231 1 8.6

ARMEEN 18D Octadecylamine 124-30-1 98 204 1 0.5 270 55 99 208 2 8

ARMEEN C Cocoalkylamines 61788-46-3 97 272 3 0.5 204 16 98 275 9 10.3

ARMEEN CD Cocoalkylamines 61788-46-3 98 275 1 0.5 200 16 100 281 9 10.3

ARMEEN HR Hydrogenated

rapeseedalkylamines 125328-43-0 93 178 12 1.0 3.5 48 95 181 6 6

ARMEEN HT Hydrogenated

tallowalkylamines 61788-45-2 97 207 3 0.5 271 55 98 207 3 8.2

ARMEEN HTD Hydrogenated

tallowalkylamines 61788-45-2 98 209 1 0.5 263 55 100 213 3 8.2

ARMEEN O Oleylamine 112-90-3 97 205 3 0.5 266 24 98 211 89 8

ARMEEN OD Oleylamine 112-90-3 98 207 1 0.5 265 23 99 212 89 8

ARMEEN OL Oleylamine 112-90-3 95 202 4 0.5 273 20 97 206 89 8

ARMEEN OLD Oleylamine 112-90-3 98 207 1 0.5 265 19 99 212 90 8

ARMEEN R Rapeseedalkylamines 125328-46-3 95 180 12 1.5 306 18 97 183 83 6

ARMEEN S Soyaalkylamines 61790-18-9 97 206 4 0.5 273 29 97 206 92 8

ARMEEN SD Soyaalkylamines 61790-18-9 98 208 2 0.5 264 29 100 213 92 8

ARMEEN T Tallowalkylamines 61790-33-8 97 208 3 0.5 267 40 98 210 46 8.2

ARMEEN TD Tallowalkylamines 61790-33-8 98 210 1 0.5 262 40 100 214 46 8.2

P r i m a r y A m i n e s

App

aren

t Se

cond

ary

Prim

ary

Am

ine,

%

Am

ine

Num

ber

Gar

dner

Col

or

Equi

vale

nt W

eigh

t**

Mel

ting

Poin

t,ºC

Seco

ndar

y A

min

e, %

Am

ine

Num

ber

Iodi

ne V

alue

HLB

Dav

ies

Scal

e


SPECIFICATIONS****

* Common name may be different from the name listed by TSCA.** Equivalent Weight = 56,110/Amine Number.

*** D = Distilled**** All secondary amines meet moisture specifications of 0.5% max.

Min. Max. Max. Max. Max.

ARMEEN 2C Dicocoalkylamines 61789-76-2 93 6 155 2 401 43 94 145 8 4.2

ARMEEN 2HT Ditallowalkylamines 61789-79-5 90 5 116 2 510 62 91 112 3 1

S e c o n d a r y A m i n e s R NH2Secondary Amines

A M I N E S

S E C O N D A R Y A M I N E S

TYPICAL PROPERTIES

Some products may be subject to minimum quantity orders.

P R I M A R Y A M I N E S

TYPICAL PROPERTIES

Tert

iary

Am

ine,

%

Am

ine

Num

ber

Gar

dner

Col

or

Equi

vale

nt W

eigh

t

Mel

ting

Poin

t,ºC

Am

ine

Num

ber

Tert

iary

Am

ine,

%

HLB

Dav

ies

Scal

e

PRODUCT COMMON NAME*** TSCA NUMBER

SPECIFICATIONS**

* Additional tertiary amines are listed under “EthoxylatedAmines.”

** All tertiary amines meet moisture specifications of 0.5% max.

*** Common name may be different from the name listed by TSCA.

Min. Min. Max.

ARMEEN DM12D Dodecyl-dimethylamine 112-18-5 95 250 1 219 -19 258 98 9.8

ARMEEN DM16D Hexadecyl-dimethylamine 112-69-6 95 198 1 276 8 203 98 7.7

ARMEEN DM18D Octadecyl-dimethylamine 124-28-7 95 180 1 303 20 185 98 7.1

ARMEEN DMCD Cocoalkyl-dimethylamines 61788-93-0 95 234 1 236 -22 239 98 9.4

ARMEEN DMHTD Hydrogenated tallowalkyl-

dimethylamines 61788-95-2 95 184 2 292 18 192 98 7.3

ARMEEN DMOD Oleyl-dimethylamine 28061-69-0 95 183 1 295 -10 190 98 7.1

ARMEEN DMSD Soyaalkyl-dimethylamines 61788-91-8 95 183 2 297 -10 189 98 7.3

ARMEEN DMTD Tallowalkyl-dimethylamines 68814-69-7 95 184 1 291 5 193 98 7.3

Te r t i a r y A m i n e s – M o n o a l k y l *

Tert

iary

Am

ine,

%

Am

ine

Num

ber

Gar

dner

Col

or

Equi

vale

nt W

eigh

t

Mel

ting

Poin

t,ºC

Am

ine

Num

ber

Tert

iary

Am

ine,

%

HLB

Dav

ies

Scal

e


SPECIFICATIONS**

Min. Min. Max.

ARMEEN M2C Dicocoalkyl-methylamines 61788-62-3 97 137 2 395 -2 142 99 3.7

ARMEEN M2HT Dihydrogenated

tallowalkyl-methylamines 61788-63-4 97 105 1 524 38 107 99 1

Te r t i a r y A m i n e s – D i a l k y l * Tertiary AminesDialkyl

Tert

iary

Am

ine,

%

Am

ine

Num

ber

Gar

dner

Col

or

Equi

vale

nt W

eigh

t

Mel

ting

Poin

t,ºC

Am

ine

Num

ber

Tert

iary

Am

ine,

%

HLB

Dav

ies

Scal

e


Min. Min. Max.

ARMEEN 312 Tridodecylamine 102-87-4 95 102 1 540 -9 104 96 <1

ARMEEN 316 Trihexadecylamine 67701-00-2 98 82 3 668 38 84 99 <1

ARMEEN 380 Tri(octyl/decyl)amine 68814-95-9 95 2 385 96 <1

Te r t i a r y A m i n e s – Tr i a l k y l * Tertiary AminesTrialkyl

A M I N E S


T E R T I A R Y A M I N E S - M O N O A L K Y L - D I M E T H Y L A M I N E S

T E R T I A R Y A M I N E S - D I A L K Y L - M E T H Y L A M I N E S

T E R T I A R Y A M I N E S - T R I A L K Y L A M I N E S

TYPICAL PROPERTIES

TYPICAL PROPERTIES


TYPICAL PROPERTIESSPECIFICATIONS**


Min. Max. Min. Max.

DUOMEEN C N-coco-1,3-

diaminopropane 61791-63-7 409 3 – 1.0 133 Liquid 422 17.5

DUOMEEN CD N-coco-1,3-

diaminopropane 61791-63-7 409 2 – 1.0 130 Liquid 432 17.5

DUOMEEN O N-oleyl-1,3-

diaminopropane 7173-62-8 320 5 60 1.0 163 Liquid 344 15.2

DUOMEEN OL N-oleyl-1,3-

diaminopropane 7173-62-8 320 5 70 1.0 163 Liquid 344 15.2

DUOMEEN T N-tallow-1,3-

diaminopropane 61791-55-7 334 7 32 1.0 161 Paste 348 15.6

DUOMEEN TTM N.N.N’-trimethyl-N’-

tallow-1,3-diaminopropane 68783-25-5 271 6 – 1.0 199 Liquid 282 14.2

DUOMEEN S N-soya-1,3-

diaminopropane 61791-67-1 303 6 68 1.0 160 Paste 320 15.6

Po l y a m i n e s — D i a m i n e s DiaminesDiamines

A M I N E S


Am

ine

Num

ber

Gar

dner

Col

or

Iodi

ne V

alue

Moi

stur

e %

Equi

vale

nt W

eigh

t

App

eara

nce@

25ºC

Am

ine

Num

ber

HLB

Dav

ies

Scal

e

P O LYA M I N E S — D I A M I N E S

SPECIFICATIONS TYPICAL PROPERTIES

* Common name may be different from the name listed by TSCA.


Min. Max. Min. Max.

TETRAMEEN T N-tallowalkyl

dipropylene tetramines 68911-79-5 475 6 25 0.5 114 37 492 –

TRIAMEEN T N-tallowalkyl

tripropylene triamines 61791-57-9 413 8 – 0.5 133 34 422 32.4

TRIAMEEN YT N-(3-Aminopropyl)-N-

tallowalkyl trimethylene

diamines 85632-63-9 390 12 – – – 20 403 32.4

Po l y a m i n e s — H i g h e r A m i n e s

Am

ine

Num

ber

Gar

dner

Col

or

Iodi

ne V

alue

Moi

stur

e %

Equi

vale

nt W

eigh

t

Mel

ting

Poin

t

Am

ine

Num

ber

HLB

Dav

ies

Scal

eP O LYA M I N E S — H I G H E R A M I N E S



A M I N E S


Equi

vale

nt W

eigh

t

Gar

dner

Col

or

Prim

ary

plus

Seco

ndar

y Am

ine,

%

Am

ine

Num

ber

Appe

aran

ce @

25º

C

HLB

Dav

ies

Scal

e


Min. Max. Max.

ETHOMEEN 18/12 Ethoxylated (2)

octadecylamine 10213-78-2 350 374 2 3 155 Solid 9.8


octadecylamine 26635-92-7 480 505 8 2 114 Solid 10.9


octadecylamine 26635-92-7 900 960 8 1 60 Liquid to Paste 14.4


octadecylamine 26635-92-7 2370 2570 10 0.5 23 Paste to Solid 26.6

ETHOMEEN C/12 Ethoxylated (2)

cocoalkylamines 61791-31-9 280 300 4 3 193 Liquid 12.2





ETHOMEEN O/12 Ethoxylated (2)

oleylamines 13127-82-7 343 363 8 3 160 Liquid 9.7

ETHOMEEN S/12 Ethoxylated (2)

soyaalkylamines 73246-96-5 342 362 6 3 159 Liquid 10.0





ETHOMEEN T/12 Ethoxylated (2)

tallowalkylamines 61791-44-4 340 360 6 3 160 Paste 10.1


tallowalkylamines 61791-26-2 470 495 7 2 116 Liquid to Paste 11.2


tallowalkylamines 61791-26-2 690 752 12 0.4 78 Liquid 13.0


tallowalkylamines 61791-26-2 890 950 8 1 61 Liquid to Paste 14.7


tallowalkylamines 61791-26-2 1250 1300 12 1 44 Liquid 17.0

E t h o x y l a t e d A m i n e s *

(CH2CH2O)xH

(CH2CH2O)yH

X + Y = 2, 5, 10, 15, 50

R-N

* Base amines can be offered as propoxylated derivatives.** The ethoxylated amines and diamines all meet moisture specifications of 1.0% max.*** Common name may be different from name listed by TSCA.

E T H O X Y L AT E D A M I N E S *


SPECIFICATIONS** TYPICAL PROPERTIES

A M I N E S


Equi

vale

nt W

eigh

t

Prim

ary

plus

Seco

ndar

y Am

ine,

%

Am

ine

Num

ber

Appe

aran

ce @

25º

C

HLB

Dav

ies

Scal

e


Min. Max. Max.

ETHODUOMEEN T/13 Ethoxylated (3) N-tallow-1,

3-diaminopropane 61790-85-0 220 250 2 239 Liquid 19.0

ETHODUOMEEN T/13N Ethoxylated (3) N-tallow-1,

3-diaminopropane Proprietary blend 265 272 2 209 Liquid





Po l y a m i n e s — E t h o x y l a t e d D i a m i n e s *

(CH2CH2O)yH(CH2CH2O)xH

(CH2CH2O)zH

X + Y + Z = 3, 10, 15Ethoxylated Diamines

R-NCH2CH2CH2N

* Base amines can be offered as propoxylated derivatives.** The ethoxylated amines and diamines all meet moisture specifications of 1.0% max.*** Common name may be different from name listed by TSCA.

Equi

vale

nt W

eigh

t

Gard

ner

Colo

r

Tert

iary

Am

ine,

%

Amin

e N

umbe

r

Appe

aran

ce @

25º

C

HLB

Dav

ies

Scal

e

PRODUCT COMMON NAME TSCA NUMBER

Min. Max. Max.

PROPOMEEN O/12 N-oleyl-1,

1’-iminobis-2-propanol 65086-71-7 371 391 6 97 147 Clear Liquid 8.9

PROPOMEEN T/12 N-tallowalkyl-1,

1’-iminobis-2-propanol 68951-72-4 368 388 6 97 148 Clear Liquid 9.2

P r o p o x y l a t e d A m i n e s

CH3

CH2CHOH

Propoxylated Amines

R-N 2

* All propoxylated amines meet moisture specifications of 1.0% max.

P O LYA M I N E S — E T H O X Y L AT E D D I A M I N E S

P R O P O X Y L AT E D A M I N E S


SPECIFICATIONS** TYPICAL PROPERTIES

SPECIFICATIONS* TYPICAL PROPERTIES

A M I N E S A LTS


Neu

tral

izat

ion

Equi

vale

nt

Gar

dner

Col

or

Am

ine

Num

ber

App

eara

nce

@ 2

5ºC

HLB

Dav

ies

Scal

e


A m i n e A c e t a t e s a n d D i a m i n e S a l t s

RNH2 • CH3CO2HAmine Salts

RNHCH2CH2CH2NH2 • 2R'CO2HDiamine Salts

** Common name may be different from the name listed by TSCA.*** Only flaked forms available.(a) 80% in mineral spirits

Min. Max. Max. Min. Max.

ARMAC 18D-40*** Octadecylamine acetate 2190-04-7

and octadecyl amine 124-30-1 38 42 11 190 200 Flake** 7.5

ARMAC HT*** Hydrogenated tallowalkyl

amine acetates 61790-59-8 95 102 10 165 – Flake** 6.8

ARMAC T Tallowalkylamine

acetates 61790-60-1 – – 10 165 – Solid 6.8

DUOMEEN TDO N-tallow-1,3-

diaminopropane ditallates 61791-53-5 98 104 10 120 130 Liquid to Paste 6.4

DUOMEEN TDO-IHF N-tallow-1,3-(a)

diaminopropane ditallates Mixture 98 104 10 94 107 Viscous Liquid 6.4

A M I N E A C E TAT E S A N D D I A M I N E S A LTS



Q U AT E R N A R Y A M M O N I U M S A LTS


Qua

tern

ary

Salt,

%**

*

Free

Am

ine

plus

Am

ine

Salt,

%

pH Gar

dner

Col

or

PMCC

Fla

sh

Poin

t, º

C

App

eara

nce

@

25ºC

HLB

Dav

ies

Scal

e

PRODUCT COMMON NAME** TSCA NUMBER

A l k y l t r i m e t h y l

RN+(CH3)3 CI–

AlkyltrimethylQuaternary

Ammonium Salts

* Prepared in aqueous isopropanol or water (W). Can be prepared in other solvents.** Common name may be different fromthe name listed by TSCA.

*** In many cases, activity (concentration) can be changed to suit your needs.**** Setaflash

Min. Max. Max. Max.

ARQUAD 12-37W Dodecyl– 112-00-5 35 39 1 6.5-9 2 Non-Flammable Liquid 23.3

ARQUAD 12-50 Dodecyl– 112-00-5 49 52 2 6-9 1 19 Liquid 23.3

ARQUAD 16-29 Hexadecyl– 112-02-7 27 30 2 6-9 3 Non-Flammable Liquid 21.2

ARQUAD 16-50 Hexadecyl– 112-02-7 49 52 2 6-9 3 17 Liquid 21.2

ARQUAD 18-50 Octadecyl– 112-03-8 49 52 2 6-9 3 18**** Liquid 20.5

ARQUAD C-33W Cocoalkyl– 61789-18-2 32 35 2 6-9 4 Non-Flammable Liquid 22.9

ARQUAD C-50 Cocoalkyl 61789-18-2 49 52 2 6-9 4 20 Liquid 22.9

ARQUAD S-50 Soyaalkyl 61790-41-8 49 52 2 6-9 5 16 Liquid 20.8

ARQUAD T-27W Tallowalkyl 8030-78-2 26 29 2 6-9 3 Non-Flammable Liquid 20.8

ARQUAD T-50 Tallowalkyl 8030-78-2 49 52 2 6-9 4 16 Liquid 20.8

Qua

tern

ary

Salt,

%**

*

Free

Am

ine

plus

Am

ine

Salt,

%

pH Gar

dner

Col

or

PMCC

Fla

sh

Poin

t, º

C

App

eara

nce

@

25ºC

HLB

Dav

ies

Scal

e


D i a l k y l d i m e t h y lR2 N+ (CH3)2 (X)–

(X) = CI, NO2, OSO2OCH3

* Can be prepared in other solvents.** Common name may be different from the name listed by TSCA.*** In many cases, activity (concentration) can be changed to suit your needs.

(a) Propylene glycol(b) Nitrite(c) Methyl Sulfate Anion

Min. Max. Max. Max.

ARQUAD2C-70 Nitrite Dicocoalkyl–(b) 71487-01-9 68 72 – 6-8.5 14 23 Liquid 17.3ARQUAD 2C-70 PG Dicocoalkyl– 61789-77-3 68 72 2 6-9 4 107 Liquid 17.3

ARQUAD 2C-75 Dicocoalkyl– 61789-77-3 74 77 1.5 6-9 3 23 Liquid 17.3

ARQUAD 2HT-75 Di(hydrogenated

tallowalkyl)– 61789-80-8 74 77 1.5 6-9 2 25 Paste 13.2

ARQUAD 2HT-75 PG Di(hydrogenated

tallowalkyl)–(a) 61789-80-8 74 77 1.5 6-9 3 107 Paste 13.2

ARQUAD HTL8 MS 2-Ethylhexyl

hydrogenated Non-

tallowalkyl–(c) EPA Listed 81.5 84.5 4 6-8 5 Flammable Liquid 17.5

SPECIFICATIONS

TYPICAL PROPERTIES

D I A L K Y L D I M E T H Y L A M M O N I U M C H L O R I D E S * *

TYPICAL PROPERTIES


A L K Y LT R I M E T H Y L A M M O N I U M C H L O R I D E S

SPECIFICATIONS



Qua

tern

ary

Salt,

%**

*

Free

Am

ine

plus

Am

ine

Salt,

%

pH Gar

dner

Col

or

PMCC

Fla

sh

Poin

t, º

C

App

eara

nce

@

25ºC

HLB

Dav

ies

Scal

e

COMMON NAME** TSCA NUMBER

Tr i a l k y l m e t h y l R3 N+ CH3 CI–

** Common name may be different from the name listed by TSCA.Q

uate

rnar

y Sa

lt,%

***

Free

Am

ine

plus

Am

ine

Salt,

%

pH Gar

dner

Col

or

PMCC

Fla

sh

Poin

t, º

C

App

eara

nce

@

25ºC

HLB

Dav

ies

Scal

e


B e n z y l a l k y lR2 N+ CH2 C6 H5 CI–

CH3

RN+ CH2 C6 H5 CI–

CH3

CH3

* Prepared in aqueous isopropanol. Can be prepared in other solvents. ** Common name may be different from the name listed by TSCA.

Min. Max. Max. Max.

ARQUAD DMCB-80 Benzyldimethyl–

cocoalkyl– 61789-71-7 79 82 1.5 6-8 4 27 Liquid 20.1

ARQUAD DMHTB-75 Benzyldimethyl–

(hydrogenated

tallowalkyl) 61789-72-8 75 80 2 7-9 4 23 Solid 18.0

ARQUAD M2HTB Benzylmethyl–

di(hydrogenated

tallowalkyl) 61789-73-9 82 84 2 7-9 3 23 Solid 10.4

ETHOQUAD C/12B Benzylcocoalkyl

[ethoxylated (2)]– 61789-68-2 73 77 2 6-9 12 26 Liquid 23.7

Min. Max. Max. Max.

ARQUAD 316(W) Trihexadecylmethyl 52467-63-7 86 90 2 6-8 4 Non-Flammable Solid 7.6

ammonium chloride

[in water (W)]

TYPICAL PROPERTIES

T R I A L K Y L M E T H Y L

PRODUCT


A M M O N I U M C H L O R I D E S


SPECIFICATIONS



* Common name may be different from the name listed by TSCA.** Setaflash

(PG) Propylene glycol

Qua

tern

ary

Salt,

%

Free

Am

ine

plus

Am

ine

Salt,

%

pH Gar

dner

Col

or

Flas

h Po

int,

ºC

App

eara

nce

@ 2

5ºC

HLB

Dav

ies

Scal

e


E t h ox y l a t e d Q u a t e r n a r y S a l t s — M o n o a l k y l E t h ox y l a t e s

RN+ (CH2 CH2 OH)2 CH3 CO2–

Ethoxylated Monoalkyl Quaternary Acetates

Min. Max. Max.

ETHOQUAD 18/12 Octadecylmethyl

[ethoxylated (2)]– 3010-24-0 70 2 7-9 7 22** Paste 23.4

ETHOQUAD 18/25 Octadecylmethyl

[ethoxylated (15)]– 28724-32-5 95 2 7-9 11 149 Liquid 28.0

ETHOQUAD C/12-75 Cocoalkylmethyl


ETHOQUAD C/12 Cocoalkylmethyl

NITRATE [ethoxylated (2)]–

ammonium nitrate 71487-00-8 59 – 6.5-7.5 8 20 Liquid 25.8

ETHOQUAD C/25 Cocoalkylmethyl


ETHOQUAD O/12 PG Oleylmethyl


ETHOQUAD T/13-27W Tris(2-hydroxyethyl)

tallowalkyl ammonium

acetates 91080-64-7 27 1.5 6-8 5 63 Liquid 26.0

ETHOQUAD T/25 Tallowalkylmethyl

[ethoxylated (15)]– 64755-05-1 95 – 7-9 12 93 Liquid 28.3

* Prepared in aqueous isopropanol. Can also be prepared in other solvents. ** Common name may be different from the name listed by TSCA.

Qua

tern

ary

Salt,

%**

*

Free

Am

ine

plus

Am

ine

Salt,

%

pH Gar

dner

Col

or

PMCC

Fla

sh P

oint

,ºC

App

eara

nce

@ 2

5ºC


A l k y l D i a m m o n i u m Pe n ta m e t hy l C h l o r i d e s

Min. Max. Max. Max.

DUOQUAD T-50 N,N,N’,N’,N’-pentamethyl-

N-tallow-1,3-propane

diammonium dichloride 68607-29-4 48 52 2 6-9 7 15 Liquid

Alkyl Diammonium Pentamethyl Chlorides

R N+ CH2 CH2 CH2 N+ (CH3)3 2CI–

CH3

CH3

MONOALKYLMETHYL [ETHOXYLATED (N)]-AMMONIUM CHLORIDES [NITRATES] [ACETATES]

TYPICAL PROPERTIES

ALKYL DIAMMONIUM PENTAMETHYL CHLORIDES



SPECIFICATIONS

RN + CH3

[CH2CH2O]zH

[CH2CH2O]yH

[X] – Z + Y = 2 or 15[X] = CI or NO3

Ethoxylated Monoalkyl Quaternary Salts

A M I N E O X I D E S / A M I D E S

* Prepared in diethylene glycol. ** Common name may be different from the name listed by TSCA.

Am

ine

Oxi

de, %

Am

ine,

%

Gar

dner

Col

or

Pero

xide

, %

Flas

h Po

int,

ºC

HLB

at

pH3

Dav

is S

cale


A m i n e O x i d e s

Min. Max. Max. Max.

AROMOX C /12 Bis(2-hydroxyethyl)-

cocoalkylamine oxides 61791-47-7 49 2.5 6 0.34 22 24.7

AROMOX C /12W Bis(2-hydroxyethyl)-

cocoalkylamine oxides 61791-47-7 30 1.0 6 0.34 >100 24.7

AROMOX DMC Dimethylcoco-

alkylamine oxides 61788-90-7 39 1.5 – 0.34 21 22

AROMOX DM16 Dimethylhexadecyl-

amine oxide 7128-91-8 39 1.5 1 0.34 26 20.3

AROMOX DMHT Dimethylhydrogenated

tallowalkylamine oxides 68390-99-8 24 1.5 2 0.34 20 19.8

AROMOX T/12 DEG* Dimethyl

tallowalkylamine oxides 68390-99-8 24 1.5 2 0.34 20 19.8

R N O

CH2CH2OH

CH2CH2OH

R N O

CH3

CH3


Am

ide,

%

Free

Fat

ty A

cid,

%

Gar

dner

Col

or

Iodi

ne V

alue

Mel

ting

Poin

t,ºC

Phys

ical

For

m

HLB

Dav

is S

cale


A m i d e s

Min. Min. Max.

ARMID HT Hydrogenated

tallowalkylamides 61790-31-6 90 5 7 3 98 Flakes <1

ARMID O Oleamide 301-02-0 90 3.5 7 85 71 Flakes <1

RCONH2


A M I N E O X I D E S

AMIDES




E T H O X Y L AT E D A M I D E S / N I T R I L E S / C O R R O S I O N I N H I B I TO R S


* Common name may be different from the name listed by TSCA.G

ardn

er C

olor

Free

Am

ide,

%

Mol

es E

O

Hyd

roxy

l Val

ue

Appe

aran

ce a

t 25º

C

HLB

Dav

is S

cale

COMMON NAME* TSCA NUMBER

E t h o x y l a t e d A m i d e s

Max. Max.

ETHOMID O/17 Ethoxylated (7) oleamide 26027-37-2 8 15 7 110 Liquid 10.5

ETHOMID HT/23 Ethoxylated (13)

hydrogenated

tallowalkylamides 68155-24-8 9 15 13 105 Solid 13.5

X = 7 or 13RCONH(CH2CH2O)XH

Sapo

nific

atio

n Va

lue

Acid

Val

ue

Gar

dner

Col

or

Iodi

ne V

alue

Mel

ting

Poin

t, ºC

Flas

h Po

int,

ºC


N i t r i l e s

Min. Max. Max. Max. Min.

ARNEEL OD Oleonitrile 112-91-4 195 203 1.2 3 85 5 >149

RCN

E T H O X Y L AT E D A M I D E S

TYPICAL PROPERTIES

N I T R I L E S



SPECIFICATIONS


Neu

tral

izat

ion

Equi

vale

nt

Moi

stur

e

App

eara

nce

@25

C

Visc

osity

cps

Pour

Poi

nt, º

C


C o r r o s i o n I n h i b i t o r s

Min. Max. Max. %

ARMOHIB 28 Proprietary Blend Inhibit hydrochloric

and hydrofluoric acids 750 800 4.5 Liquid 11

ARMOHIB 31 Proprietary Blend Inhibit sulfuric, sulfamic

phosphoric, citric acids 2.0 Liquid 0

ARMOHIB 209 Tall Oil

Imidazoline Intermediate 68442-97-7 208 222 0.2 Liquid 200 <0

ARMOHIB 210 Tall Oil

Amido Amine Intermediate 61790-69-0 187 200 1.0 Solid 32

TYPICAL PROPERTIES

C O R R O S I O N I N H I B I TO R S


USE

E T H O X Y L AT E D A M I D E S

PRODUCT

SPECIFICATIONS

22 ANIONIC SURFACTANTS

A N I O N I C S U R FA C TA N TS

ANIONIC SURFACTANTS 23

A n i o n i c S u r f a c t a n t sAnionic surfactants can be structurally described as an organichydrophobe (water-insoluble) that contains one or more negativelycharged substituents (anions). Akzo Nobel Surface Chemistry offersanionic surfactants having sulfonate, sulfonic acid, sulfate, phosphateor carboxylic acid groups, which bear the negative (anionic) charge.

Figure 1 shows the variety of hydrophobes we use to make ouranionic surfactant products. The hydrophobes are reacted with anappropriate reactant to form the anionic surfactant species listed inthe right-hand column.

Below are listed the trademarks we use to identify the anionicsurfactants we market.

Trademark Surfactant Type

EMCOL® Ethoxylated Carboxylic Acid (terminated)

LANKROPOL™ Sulfosuccinates

PETRO® Alkyl Naphthalene Sulfonates

UDET™ Detergent Surfactant Blend

PHOSPHOLAN™ Phosphate Esters

WITCOLATE™ Alkyl Sulfates; Alkyl Ether/Alkylaryl Ether Sulfates

WITCONATE™ Alkylaryl and ∝ – Olefin Sulfonates (Air/SO3)

WITCONIC™ Sulfonic Acids

FIGURE 1

Alkylbenzenes

Alkylnaphthalenes

Olefins

Alcohols

Alcohol Ethers

Alkylphenols

Alkylphenol Ethers

Fatty Acids

Sulfonic Acids

Sulfates

Ether Sulfates

Sulfonates

EthoxylatedCarboxylates

Sulfosuccinates

Phosphate Esters

NaphthaleneSulfonates

SO3

H2SO4

NaHSO3

Na2SO3

NaOAcCI

P2O5

(H3PO4)x

Anionic Process Chemicals

Anionic surfactants are important for their dispersing and detergencyproperties in aqueous media. By choosing the appropriatehydrophobe and anion combination, the formulator can achieve the desired surfactant effect for their formulations.

Listed below are the examples of the types of properties that can be optimized with anionic surfactants from Akzo Nobel Surface Chemistry:

• Water solubility• pH stability• Thermal stability• Cloud point• Detergency• Dispersancy• Hard water tolerance

Recommendations of the surfactant type for various applications are found on page 2. Advice for specific products for individualrequirements can be obtained by contacting our Technical Service at 1-877-565-8432.


Petro® alkyl naphthalene sulfonates are regarded as surface-active hydrotropes.

They exhibit characteristics such as wetting, foaming, detergency and surface

tension reduction. They have excellent rinseability, acid and base stability,

hard-water tolerance and high-temperature stability. These versatile surfactants

are used in a variety of applications including carpet cleaners, transportation

cleaners, rinse aids, metal cleaners, rust removers and hard surface cleaners.

A l k y l N a p h t h a l e n e S u l f o n a t e s

A L K Y L N A P H T H A L E N E S U L F O N AT E S

PETRO 11 LIQUID Sodium Alkyl Naphthalene Sulfonate Liquid 50

PETRO 11 POWDER Sodium Alkyl Naphthalene Sulfonate Powder 95


PETRO 22 POWDER Sodium Alkyl Naphthalene Sulfonate Powder 95


PETRO AA LIQUID Sodium Alkyl Naphthalene Sulfonate Liquid 50

PETRO AA POWDER Sodium Alkyl Naphthalene Sulfonate Powder 95

PETRO AG SPECIAL Sodium Alkyl Naphthalene Sulfonate Liquid 50

PETRO AG SPECIAL Sodium Alkyl Naphthalene Sulfonate Powder 95

PETRO AGS-SUPERFINE Sodium Alkyl Naphthalene Sulfonate Powder 95

PETRO BA LIQUID Sodium Alkyl Naphthalene Sulfonate Liquid 50

PETRO BA POWDER Sodium Alkyl Naphthalene Sulfonate Powder 95

PETRO BAF LIQUID Sodium Alkyl Naphthalene Sulfonate Liquid 50

PETRO BAF POWDER Sodium Alkyl Naphthalene Sulfonate Powder 95

PETRO BP POWDER Sodium Alkyl Naphthalene Sulfonate Powder 95

PETRO D-425 LIQUID Sodium Naphthalene Sulfonate Condensate Liquid 43

PETRO D-425 POWDER Sodium Naphthalene Sulfonate Condensate Powder 88

PETRO DISPERSANT 98 Sodium Naphthalene Sulfonate Liquid 95

PETRO LBA LIQUID Sodium Alkyl Naphthalene Sulfonate Liquid 50

PETRO LBA POWDER Sodium Alkyl Naphthalene Sulfonate Liquid 95

PETRO LBAF LIQUID Sodium Alkyl Naphthalene Sulfonate Liquid 50

PETRO LULF LIQUID Sodium Alkyl Naphthalene Sulfonate Liquid 50

PETRO P LIQUID Sodium Alkyl Naphthalene Sulfonate Powder 95

PETRO P POWDER Sodium Alkyl Naphthalene Sulfonate Powder 95

UDET 950 POWDER Sodium Alkyl Naphthalene Sulfonate Powder 95

PETRO ULF LIQUID Sodium Alkyl Naphthalene Sulfonate Liquid 50

PETRO X-3158 LIQUID Sodium Alkyl Naphthalene Sulfonate Liquid 70

PRODUCT DESCRIPTION APPEARANCE TYPICAL ACTIVITY,%


Ant

icak

ing

Coup

ling

Det

erge

ncy

Dis

pers

ion

Foam

ing

Hyd

rotr

opin

g

Wet

ting

HI &

I

Laun

dry

Det

erge

nts

Food

Pro

cess

ing

Clea

ners

Tran

spor

taio

n Cl

eane

rs


• • • M • • • •

• • • M • • • •

• L • • • • •

• L • • • • •

• • •

• • • M • • • •

• • • M • • • •

• • • • • •

• • • • • •

• • • • • •

• • • M • • • •

• • • M • • • •

• H • • • • •

• H • • • • •

• •

• •

• •

• • • •

• • • M • • • •

• • • M • • • •

• H • • • •

• • • • • •

• M/H •

• M/H •

• H • • • •

• • L • • •

• • •



KEY

(H) High

(M) Moderate

(L) Low


FUNCTIONALITY MARKETS


Witconic™ sulfonic acids are the base acids used to make detergent sulfonates.

They can be neutralized in situ to produce the anionic surfactant desired. Witconate™

anionic surfactants include alkylaryl sulfonates, olefin sulfonates, alkane sulfonates and

specialty sulfonates. These products are workhorse surfactants in numerous Household

and Industrial & Institutional cleaning applications.

S u l f o n a t e s

S U L F O N AT E S

WITCONATE 1223H Sodium Dodecylbenzene Sulfonate, Branched Liquid 21-23 7.5-8.5 (g) 120 (K)WITCONATE 1223L Sodium Dodecylbenzene Sulfonate, Linear Liquid 22-23 7.5-8.5 (g) 75 (K)WITCONATE 1223SK Potassium Dodecylbenzene Sulfonate, Linear Liquid 20.5-21.5 7.5-8.5 (g) 100 (K)WITCONATE 1238 Slurry Sodium Dodecylbenzene Sulfonate, Linear Light slurry 38-40 7.5-9 (e) 90 (K)WITCONATE 1840X Fatty Acid Sulfonate Clear-slightly hazy liquid 48-52 (s) 6.5-7.5 (b)WITCONATE 3203 Specialty Sulfonate Dark amber liquid 48-52 (s) 7-8 (e)WITCONATE 4133 Isopropylamine salt of 1298S in IPA Clear amber liquid 74-76 3-4 * 6 (G)WITCONATE 605 A Calcium Salt of DDBSA (Branched) in Aromatic 150 Dark viscous Liquid 59.5-60.5 5-7 (d)WITCONATE 60T TEA-Dodecylbenzene Sulfonate Liquid 57-58 5.5-7 (e) 350 (K)WITCONATE 79S TEA-Dodecylbenzene Sulfonate Clear yellow liquid 51.3-53.1 6.5-8 ( c) 6 (G)WITCONATE 90 Flake Sodium Dodecylbenzene Sulfonate Cream colored flake 90-91 6.5-8.7 (e) 200 (K) in 10% aqWITCONATE 93S Isopropylamine Dodecylbenzene Sulfonate Clear amber liquid 90-93 4-5 (g) 7 (G)WITCONATE 96A Sodium C14-16 Alpha Olefin Sulfonate Light liquid 38-40 6.5-8.5 (e) 120 (K)WITCONATE AOK Sodium C14-16 Alpha Olefin Sulfonate Cream colored flake 90 7-10 (e) 275 (K) in 10% aqWITCONATE AOS Sodium C14-16 Alpha Olefin Sulfonate Clear yellow liquid 38 - 40 8-10 (f) 120 (K) in 12.8% aqWITCONATE AOS-12 Sodium C14-16 Alpha Olefin Sulfonate Clear amber liquid 40 (s) 8-10 (b) 400 (K)WITCONATE AOS-EP Sodium C14-16 Alpha Olefin Sulfonate Clear yellow liquid 38-40 7.5-8.5 (f) 100 (K)WITCONATE AOS-PC Sodium C14-16 Alpha Olefin Sulfonate Liquid 38-40 6.5-8.5 (f) 70 (K)WITCONATE DS Dense Linear Sodium Alkylbenzene Sulfonate Cream colored flake 90 6.5-8.7 (e) 200 (K) WITCONATE DS Flake Linear Sodium Alkylbenzene Sulfonate Off-white flakes 90 1.5-7 (e) 120 (K) in 10% aqWITCONATE K Dense Sodium Dodecylbenzene Sulfonate Cream colored flake 90 6.5-8.7 (e) 200 (K) in 10% aq

WITCONATE LX Flake Sodium Dodecylbenzene Flake 91Sulfonate / Sodium Xylene sulfonate

WITCONATE LX Powder Sodium Dodecylbenzene Powder 91Sulfonate / Sodium Xylene sulfonate

WITCONATE NAS-8 Sodium Octane Sulfonate Clear-slightly hazy liquid 37 6-7 (a) 2 (G)WITCONATE NAS-8W Sodium Octane Sulfonate-Winterized Clear-slightly hazy liquid 38 6-7 (a) 2 (G)WITCONATE P-1059 Isopropylamine Dodecylbenzene Sulfonate Clear amber liquid 90 4.5-5.5 (f) 7 (G)WITCONATE P-1220 Calcium Salt of DDBSA, Branched Clear amber liquid 60 5-7 ( c ) 12 (G)WITCONATE P-1220 Bust Calcium Salt of DDBSA, Branched Dark amber liquid 70 5-7 ( c ) 12 (G)WITCONATE P-1220EH Calcium Salt of DDBSA (Branched) in 2-Ethylhexanol Clear amber liquid 60 5-7 ( c ) 12 (G)WITCONATE P-1220S Calcium Salt of DDBSA (Branched) in 2-EH/PG Clear amber liquid 54 5-7 ( c ) 12 (G)WITCONATE P-1860 Calcium Salt of DDBSA (Branched) in Octanol Dark brown liquid 60 5-7 ( c )

WITCONATE SK Flake Sodium Dodecylbenzene Cream colored powder 40 8.5-8.5 (e) 180 (K)Sulfonate / Sodium Xylene sulfonate

WITCONATE SXS Sodium Xylene Sulfonate Liquid 40-42 7-9 (a) 50 (K)

PETRO IPSA Liquid Diisopropyl Naphthalene Sulfonic Acid Black liquid 50WITCONIC1298 Hard acid Dodecylbenzene Sulfonic Acid, Branched Dark brown liquid 94-97 400 (K)WITCONIC 1298 Soft acid Dodecylbenzene Sulfonic Acid, Linear Dark amber liquid 97 150 (K)WITCONIC 1398 Soft acid Alkylaryl Sulfonic Acid, Linear Dark amber liquid 96-97 150 (K)WITCONIC AN Acid Methyl Naphthalene Sulfonic Acid Dark brown liquid 92WITCONIC TX Acid Toluene Sulfonic Acid, Modified Dark visc. Liquid 94-96 150 (K)

PRODUCT DESCRIPTION APPEARANCETYPICALACTIVITY,% pH COLOR, MAX

S U L F O N I C A C I D S

S U L F O N AT E S

Coup

ling

Def

oam

ing

Det

erge

ncy

Dem

ulsi

fier

Dis

pers

ion

Emul

sifie

r O

/W

Foam

Sta

biliz

er

Foam

ing

Wet

ting

Elec

trol

yte

Tole

rant

Emul

sion

Pol

ymer

izatio

n

Fire

Fig

htin

g

Wal

lboa

rd/C

emen

t Foa

mer

Text

ile


• • • •• • • •• • • •• • • •

• •1 • • •• • •

• • •• • • •• • • •• • • • •• • • •

• • • • •• • • • • •• • • • • •• • • • • •• • • • • •• • • • • • •• • • • • •• • • •• • • •• • • •

• • • •

• • • •

• • L •• • L •• • • • • •

• •• •• •• •• •

• • • •

• •

• • • • • •• • • • •• • • • •• • • • •

•• •

S U L F O N AT E S

KEY

1. In acidic solution

* 1% aq

(a) as is

(b) 5% aq solution

(c) 5% in 25% IPA solution

(d) 5% in 75 % IPA solution

(e) 10 % aq solution

(f) 12.8% aq solution

(g) 20% aq solution

(G) Gardner

(h) 20% in 25% IPA solution

(K) Klett

(L) Low Foam

(m) % moisture

(s) % solid

S U L F O N AT E S S U L F O N I C A C I D S




Witcolate™ sulfates, alkyl ether sulfates and alkylaryl ether sulfates are

available with a variety of hydrophobe structures, ethylene oxide content

and cations. Ether sulfates exhibit flash foam and have lower irritation

properties than the corresponding alkyl sulfates. These anionic surfactants

provide detergency, foaming, and wetting to many products such as liquid

hand dishwash, transportation cleaners, hard-surface cleaners and a variety

of industrial and institutional products.

S u l f a t e s

S U L FAT E S

WITCOLATE 1300 Surfactant Blend Clear amber liquid 53-57 (s) 8-9 (b)

WITCOLATE 3220 Surfactant Blend Liquid 31.5-33 8-9.6 (b)

WITCOLATE 7259 Sodium C8-10 Sulfate Liquid 37-39 10-11 ( c ) 3 (G)

WITCOLATE A POWDER Sodium Lauryl Sulfate Off-white powder 92.5 7-10 ( c )

WITCOLATE C* Sodium Lauryl Sulfate Off-white powder 90.6 60 min (T%)

WITCOLATE D-510 Sodium 2-Ethylhexyl Sulfate Liquid 38.5-40.5 9-10.5 ( c ) 4 (G)

WITCOLATE EP DEA Lauryl Sulfate Liquid 31.8-34.7 7.5-8.5 ( c ) 55 min (T%)

WITCOLATE LCP Sodium Lauryl Sulfate Liquid 28-30 7-8.5 ( a ) 100 (A)

WITCOLATE ME DRY Sodium Lauryl Sulfate Off-white powder 60 60 min (T%)

WITCOLATE NH Ammonium Lauryl Sulfate Liquid 28-30 6.3-6.8 ( c ) 200 (A)

WITCOLATE NHK Ammonium Lauryl Sulfate Liquid 28-30 6.3-6.8 ( c ) 200 (A)

WITCOLATE NHP Ammonium Lauryl Sulfate Liquid 28-30 6.3-6.8 ( c ) 200 (A)

WITCOLATE SL-EP Sodium C10-16 Sulfate Liquid 29-30 7.5-8.5 ( c ) 50 (K)

WITCOLATE TLS-500 TEA-Lauryl Sulfate Liquid 40-42 6.5-7.5 ( c ) 150 (PCC)

WITCOLATE WA PASTE Sodium Lauryl Sulfate White paste 19-20 7.5-8.5 ( c ) 85 min (T%)

WITCOLATE WAC LA Sodium Lauryl Sulfate Liquid 28-30 8-8.5 ( c ) 100 (A)

WITCOLATE WAQ Sodium Lauryl Sulfate Liquid 19-20 7.5-8.5 ( c ) 65-100 (T%)

WITCOLATE WAQE Sodium Lauryl Sulfate Clear yellow liquid 19.2-20.2 7.5-8.5 ( c ) 60 min (T%)

WITCOLATE 1050 Sodium C12-15 Pareth Sulfate (1 EO) Clear yellow liquid 38-40 8.5-11 ( c ) 220 (K)

WITCOLATE 1247HF Ammonium C6-10 Alcohol Ether Sulfate (3 EO) Clear yellow liquid 64-66 7-8.5 (b) 50 (K)

WITCOLATE 1247H Ammonium C6-10 Alcohol Ether Sulfate (3 EO) Clear yellow liquid 64-66 7-8.5 (b) 50 (K)

WITCOLATE 1259 C6-10 Alcohol Ether Sulfate (3 EO), IPA Salt Liquid 80 7-8 (b) 100 (K)

WITCOLATE 1259FS C6-10 Alcohol Ether Sulfate (3 EO), IPA Salt Clear amber liquid 88.5 7-8.5 (b) 100 (K)

WITCOLATE 1276 Ammonium C10-12 Alcohol Ether Sulfate (3 EO) Clear yellow liquid 52.5-53.5 7-8 (b) 30 (K)

WITCOLATE 7093 Sodium C6-10 Alcohol Ether Sulfate (3 EO) Liquid 38-39 7-8.5 (a) 300 (K)

WITCOLATE LES-60A Ammonium Lauryl Ether Sulfate (3 EO) Light liquid 58-62 7-7.5 ( c ) 50 (K) in 5% aq

WITCOLATE LES-60C Sodium Lauryl Ether Sulfate (3 EO) Light liquid 60 7.5-9 ( c ) 1 (G)

WITCOLATE D-51-51 Sodium Nonylphenol Ethoxylate Sulfate (4 EO) Liquid 28-30 7.5-8.5 (b) 4 (G)

WITCOLATE D-51-53 Sodium Nonylphenol Ethoxylate Sulfate (10 EO) Liquid 28-30 7.5-8.5 (b)

PRODUCT DESCRIPTION APPEARANCETYPICALACTIVITY,% pH

COLOR, MAX

A L K Y L S U L FAT E S

A L K Y L E T H E R S U L FAT E S

A L K Y L A R Y L E T H E R S U L FAT E S

Coup

ling

Det

erge

ncy

Emul

sifie

r O

/W

Foam

ing

Wet

ting

Elec

trol

yte

Tole

rant

Emul

sion

Pol

ymer

izatio

n

Fire

Fig

htin

g

Wal

lboa

rd/C

emen

t Foa

mer

Text

ile


• •

• • S • •

• • • • M

3 • • • •

3.5 • • • •

• L • M • •

3.5

1.3 • • • •

3.5 • • • •

1-1.8 • • • •

1.8 • • • •

1-1.8 • • • •

0.7 • • • •

• • • •

1.8-2.3 • • • •

1.3 • • •

1.8-2.3 • • • • •

1.3 • • • •

1.7 • • • • M

• • • • S • •

• • • • S • •

• • • • • S •

• • • • • S •

• • • M • • •

2 • • • S •

• • • M

• • • M

4 • • • M •

• • • M • •

S U L FAT E S

ACID # to pH 5.5

A L K Y L S U L FAT E S A L K Y L E T H E R S U L FAT E S A L K Y L A R Y L E T H E R S U L FAT E S

KEY

(M) Moderate

(S) Superior

(L) Low

(a) As is

(b) 5% aq solution

(c) 10 % aq solution

(A) APHA

(G) Gardner

(K) Klett

(PCC)Platinum Cobolt Color

(T%) % transmittance



Phospholan™ organic phosphate esters are derived from ethoxylated

alcohols, alkyl phenols or phenols and are composed of mixtures of

mono- and diesters. Most of these surfactants are supplied as free

acids that can be converted to salts by the addition of bases. Excellent

compatibility, detergency, coupling, emulsification and low to moderate

foaming can be attained by the proper selection from the Phospholan

phosphate esters listed below.

P h o s p h a t e E s t e r s

P H O S P H AT E E S T E R S

PHOSPHOLAN NBAP N-Butyl Mono/DiPhosphate Liquid 96-99 1 4 (G) 300-320

PHOSPHOLAN PS-400 C6-10 Alkyl Phosphate Ester Liquid 96-99 0.5 1 (G) 213-224

PHOSPHOLAN 5AP C8-10 Alcohol Ethoxylate Phosphate Ester Liquid 96-99 1 2 (G) -

PHOSPHOLAN PS-131 Tridecyl Alcohol Ethoxylate Phosphate Ester Liquid 96-99 1 2 (G) 75-85

PHOSPHOLAN PS-220 C10-14 Alcohol Ethoxylate Phosphate Ester Liquid 96-99 1 8 (G) 104-109

PHOSPHOLAN PS-222 C12-15 Alcohol Ethoxylate Phosphate Ester Clear-slightly hazy liquid 96-99 1 1 (G) 101-109

PHOSPHOLAN PS-236 C10-14 Alcohol Ethoxylate Phosphate Ester Liquid 96-99 2 2 (G) 90-93

PHOSPHOLAN PS-331 C12-14 Sec. Alcohol Ethoxylate Phosphate Ester Amber liquid 90 1 1 (G) 140-143

PHOSPHOLAN PS-413 Butyl Cellosolve Phosphate Ester Liquid 77-82 0.5 12 (G) 342-348

PHOSPHOLAN PS-810 Oleyl Alcohol Ethoxylate Phosphate Ester Clear-slightly hazy liquid 96-99 1 1 (G) 84-90

PHOSPHOLAN PS-900 Tridecyl Alcohol Phosphate Ester Liquid 96-99 1.5 - 2.0 3 (G) 151-163

PHOSPHOLAN 9NP Nonylphenol Ethoxylate Phosphate Ester Yellow viscous liquid 96-99 1 2 (G) -

PHOSPHOLAN CS-121 Nonylphenol Ethoxylate Phosphate Ester Liquid 96-99 1 3 (G) 92-98

PHOSPHOLAN CS-131 Nonylphenol Ethoxylate Phosphate Ester Liquid 96-99 0.4 1 (G) 93-101

PHOSPHOLAN CS-1361 Nonylphenol Ethoxylate Phosphate Ester, Sodium Salt Liquid 90 9.5/10.5 100 (A) 25-35 (AV)

PHOSPHOLAN CS-141 Nonylphenol Ethoxylate Phosphate Ester Liquid 96-99 1 100 (A) 63-67

PHOSPHOLAN CS-147 Nonylphenol Ethoxylate Phosphate Ester Liquid 96-99 1.5 4 (G) 86-90

PHOSPHOLAN CS-151 Nonylphenol Ethoxylate Phosphate Ester Liquid 96-99 0.5 200 (A) 50-56

PHOSPHOLAN CS-341 Dinonylphenol Ethoxylate Phosphate Ester Liquid 96-99 1 6 (G) 61-63

PHOSPHOLAN TS-210 Phenol Ethoxylate Phosphate Ester Liquid 96-99 1 4 (G) 154-160

PHOSPHOLAN TS-211 Phenol Ethoxylate Phosphate Ester Liquid 83-87 1 7 (G) 230-260

PHOSPHOLAN TS-230 Phenol Ethoxylate Phosphate Ester Liquid 96-99 1 - 2 8 (G) 84-90

PHOSPHOLAN TEAP Triethylammonium Phosphate Liquid 43 50 (A) 1.85-2.03 (TA)

PRODUCT DESCRIPTION APPEARANCETYPICALACTIVITY,%

MOISTURE%, MAX

COLOR, MAX

ACID # to pH 5.5

A L K Y L P H E N O L E T H O X Y L AT E P H O S P H AT E

A L C O H O L E T H O X Y L AT E P H O S P H AT E

P H E N O L E T H O X Y L AT E P H O S P H AT E

A L K Y L A M I N E P H O S P H AT E

A L C O H O L P H O S P H AT E


Ant

ista

t

Hyd

rotr

opin

g

Corr

osio

n In

hibi

tor

Coup

ling

Def

oam

ing

Det

erge

ncy

Dis

pers

ion

Emul

sifie

r

Foam

ing

Lubr

icat

ion

Visc

osity

Mod

ifier

Wet

ting

Lubr

ican

ts

Text

ile

Emul

sion

Pol

ymer

izatio

n

Plas

tic/A

ntis

tat

Pape

r

Pers

onal

Car

e

Met

al C

lean

ing


FREE PHOSPHORIC ACID, MAX

4 •

3 • • • • L • • G • • •

- • • L M • •

2 • • • M/L M • • •

2 • • • • M/L • M • • •

1.5 • • • • L • G • •

- • • • • • M/L • M • • •

12 • • • • M M • •

17.5 - 22.5 • • • • L •

2 • • • • • L • L • • • •

3 • • • • M • •

- • • M M • • •

2.5 • • • • M • •

3 • • • • M/L M • • •

1 • • • • • M • • G • • • •

- • • • • M • M • • • •

1 • • • • M/L • M • • • •

1.5 • M/H M • • •

1.5 • • L • • •

3 • • • • • •

17 • • • • • •

3 • • • • • •

- • • • •

P H O S P H AT E E S T E R S


A L C O H O L E T H O X Y L AT E P H O S P H AT E

A L K Y L P H E N O L E T H O X Y L AT E P H O S P H AT E

P H E N O L E T H O X Y L AT E P H O S P H AT E

A L K Y L A M I N E P H O S P H AT E

KEY(A) APHA(G) Gardner for color

or Good for other(H) High(M) Moderate(L) Low(AV) acid value


MARKETSFUNCTIONALITY


Lankropol® sulfosuccinates are well-known as mild anionics and are used

where mildness and foaming are key considerations in formulating liquid

hand soaps and light duty liquids.

S u l f o s u c c i n a t e s

S U L F O S U C C I N AT E S

LANKROPOL 4161L Disodium Oleamido MIPA-Sulfosuccinate Clear amber liquid 33-36 61-64 6 (G) 6.5-7.5*

LANKROPOL 4500 Sodium Dioctyl Sulfosuccinate Clear-slightly hazy liquid 70 21.5 35 (A) 6*

LANKROPOL 4560 Blend Liquid 70 1 200 (A) 4-5.5**

LANKROPOL K-8300 Disodium Oleamido MIPA-Sulfosuccinate Clear amber liquid 38 62.5 9 (G) 6.5-7.5***


MOISTURE%, MAX

COLOR, MAX pH


Emcol® carboxylated ethoxylates are mild surfactants suitable for

personal care cleansing applications with good emulsification and

hydrotroping properties.

C a r b o x y l a t e d E t h o x y l a t e s

EMCOL CNP-110 Carboxylated Nonylphenol + 9 EO Liquid 80 9-11 3 (G) 1.5-3.5***


MOISTURE%, MAX

COLOR, MAX pH


Cond

ition

ing

& E

mol

lienc

y

Coup

ling

Dis

pers

ion

Det

erge

ncy

& C

lean

ing

Emul

sifie

r O

/W

Foam

ing

Wet

ting

Elec

trol

yte

Tole

rant

Emul

sion

Pol

ymer

izatio

n

Text

ile


• • • • •

• • • • • • • •

• • • • • •

• • • • • • •

C A R B O X Y L AT E D E T H O X Y L AT E S

KEY

* 1% aq solution

** 3% aq solution

*** 5% aq solution

**** 10% aq solution

Cond

ition

ing

& E

mol

lienc

y

Coup

ling

Corr

osio

n In

hibi

tor

Def

oam

ing

Dis

pers

ion

Det

erge

ncy

& C

lean

ing

Emul

sifie

r O

/W

Foam

ing

Visc

osity

Mod

ifier

Wet

ting

Elec

trol

yte

Tole

rant

Emul

sion

Pol

ymer

izatio

n

Fire

Fig

htin

g

• • • • • •

S U L F O S U C C I N AT E S

C A R B O X Y L AT E D E T H O X Y L AT E S

KEY

* 1% aq solution

** 3% aq solution

*** 5% aq solution





34 NONIONIC SURFACTANTS

N O N I O N I C S U R FA C TA N TS

N o n i o n i c S u r f a c t a n t sNonionic surfactants by definition contain no functionality that has a formal charge. Surface activity derives from a balance ofhydrophobic and hydrophilic structures contained in the surfactantmolecule. Altering the balance toward more hydrophobic or morehydrophilic influences the surfactant’s functional properties to achieve a desired effect.

Akzo Nobel Surface Chemistry’s nonionic surfactant offerings usehydrophobic structures represented by fatty alcohols/acids/esters,alkyl-substituted phenols and blocks of polypropylene oxide.Hydrophilic character is imparted using ethylene oxide and itspolymers, alkanolamines and sugar polyols. Figure 1 illustrates the process chemistries we employ.

Below are listed the trademarks we use to identify the nonionicsurfactants we market.

Trademark Surfactant Type

AMADOL® Alkanolamides

ARMOTAN® Sorbitan Ester Ethoxylates

EMULPON™ Castor Oil Ethoxylates

ETHOFAT® Fatty Acid Ethoxylates

ETHYLAN™ Linear and Branched Alcohol Alkoxylates

WITCONOL™ Alkyl Phenol Alkoxylates; Block Copolymers; PEG Esters

Nonionic surfactants have attributes that make their useadvantageous over other surfactant types. With their lack of charge,nonionic surfactants are compatible with both cationic and anionicsurfactants. In mixed surfactant systems the properties of each

surfactant influence performance at the surface or interface.Detergency, emulsification and hard surface cleaning are applicationswhere the use of nonionic surfactants is indicated. Further, theirinverse relationship of solubility and temperature in water isparticularly useful in cleaning formulations.

Listed below are the examples of the types of functions that can be optimized with nonionic surfactants from Akzo Nobel Surface Chemistry:

• Detergency• Wetting• Emulsification• Foam stabilization• Defoaming• Viscosifying• Solubilization

The table on page 2 shows our recommendations of the surfactanttype for various applications. Advice for specific products forindividual requirements can be obtained by contacting our Technical Service at 1-877-565-8432.

AlkoxylatesEthoxylated AlcoholAlkyl Phenol EthoxylatesEO-PO Co-polymerEthoxylated Castor Oil

PEG-Esters

Alkanolamides

Amine Ethoxylates

Sorbitan Esters

EO

PO

Acids

CH2O

Alcohols

Alkylphenols

Polyols

Glycol Ethers

Fatty Acids

Sorbitol

Amines

Castor Oil

Methyl Esters

Glycerides

Nonionic Process Chemicals

NONIONIC SURFACTANTS 35

FIGURE 1


Ethylan™ linear and branched alcohol ethoxylates, Witconol™ alkyl phenol

ethoxylates, polyols and PEG esters offer the formulator nonionic surfactants

for a wide variety of industrial cleaners and household detergents, including

applications requiring low foaming. PEG esters are low-irritation viscosity

modifiers when added to many anionic surfactants. Emulpon™ castor oil

ethoxylates are co-emulsifiers used to balance the hydrophilic-lipophilic

balance (HLB).

N o n i o n i c s

N O N I O N I C S

WITCONOL 9N Nonyl Phenol (9 EO) Ethoxylate Liquid 100 0.2 5-7*** 100 (A)

WITCONOL NIO Dodecyl Phenol (6 EO) Ethoxylate Clear yellow liquid 100 0.3 7-8.5 (d) 4 (G)

WITCONOL NIW Dodecyl Phenol (11 EO) Ethoxylate Clear yellow liquid 92 8 7-8.5 (h) 6 (G)

WITCONOL NP-100 Nonyl Phenol (10 EO) Ethoxylate Liquid 99 0.3 5-8 (a) 100 (A)

WITCONOL NP-120 Nonyl Phenol (12 EO) Ethoxylate Light liquid 99 0.3 5-8 (a) 100 (A)

WITCONOL NP-15 Nonyl Phenol (1.5 EO) Ethoxylate Liquid 99 0.2 6-7.5 (f)

WITCONOL NP-200 Nonyl Phenol (20 EO) Ethoxylate White solid 99 0.5 6-7.5*** 1 (G)

WITCONOL NP-300 Nonyl Phenol (30 EO) Ethoxylate White solid 99 0.5 6-7.5 (b) 100 (A)

WITCONOL NP-330 Nonyl Phenol Ethoxylate/Propoxylate Light liquid 99 0.5 6-8 (b) 3 (G)

WITCONOL NP-40 Nonyl Phenol (4 EO) Ethoxylate Liquid 99 0.5 5-8 (a) 2 (G)

WITCONOL NP-400 Nonyl Phenol (40 EO) Ethoxylate White solid 99 0.5 6-7.5 (b) 1 (G)

WITCONOL NP-507 Nonyl Phenol (50 EO) Ethoxylate Viscous liquid 70 30 6-8*** 1 (G)

WITCONOL NP-60 Nonyl Phenol (6 EO) Ethoxylate Liquid 99 0.2 5-8 (a) 200 (A)

WITCONOL NP-90 Nonyl Phenol (9 EO) Ethoxylate Liquid 99 0.3 5-8**** 1 (G)

WITCONOL NS-108LQ Nonyl Phenol Ethoxylate/Propoxylate Liquid 99 0.2 6-7 (e)

WITCONOL S-100 Octyl Phenol (10 EO) Ethoxylate Liquid 100 0.5 5-7* 100 (A)

ETHYLAN 1204 C12-14 Alcohol (4 EO) Ethoxylate Liquid 99 0.2 6-7*** 100 (A)

ETHYLAN 1206 C10-12 Alcohol Ethoxylate/Propoxylate Liquid 99 0.5 6-8 (b) 6 (G)

ETHYLAN 4061 Butanol EO/PO Copolymer in PG Light liquid 70 0.5 6-8

ETHYLAN 25-3 C12-15 Alcohol (3 EO) Ethoxylate Liquid 100 0.1 5.5-7.5* 50 (A)

ETHYLAN DA-4 Isodecyl Alcohol (4 EO) Ethoxylate Clear-hazy liquid 100 0.5 5-7 (b) 100 (A)

ETHYLAN DA-9 Isodecyl Alcohol (9 EO) Ethoxylate Clear-hazy liquid 100 0.2 6-7***

ETHYLAN LA-230 C12-15 Alcohol (23 EO) Ethoxylate Solid 100 0.1 5-7* 200 (A)

ETHYLAN NS-500LQ Butanol Ethoxylate/Propoxylate Hazy liquid 99 0.2 6.5-7.5 (b) 3 (G)

ETHYLAN OLA-200 Oleyl Alcohol (20 EO) Ethoxylate Light amber solid 100 0.2 6.5-7.5*** 2 (G)

ETHYLAN PT-750 Glycerin (13 PO) Propoxylate Clear liquid 100 0.5 5-7*

ETHYLAN SN-120 C10-12 Alcohol (10 EO) Ethoxylate Light liquid 100 0.2 6-8* 1 (G)

ETHYLAN SN-70 C10-12 Alcohol (5 EO) Ethoxylate Clear-Hazy pale yellow liquid 100 0.2 6-7*

ETHYLAN SN-90 C10-12 Alcohol (7 EO) Ethoxylate Light liquid 100 0.5 6-8* 1 (G)

ETHYLAN TD-100 Tridecyl Alcohol (10 EO) Ethoxylate Clear liquid 100 0.2 6.5-7.5***

ETHYLAN TD-1407 Tridecyl Alcohol (14 EO) Ethoxylate Clear liquid 75 24-25 6.5-8.5***

ETHYLAN TD-60 Tridecyl Alcohol (6 EO) Ethoxylate Pale yellow liquid 100 0.5 6-8* 200 (A)


MOISTURE%, MAX

COLOR, MAXpH

A L K O X Y L AT E D A L K Y L P H E N O L S

A L K O X Y L AT E D A L C O H O L S

Coup

ling

Corr

osio

n In

hibi

tor

Def

oam

er

Dis

pers

ion

Det

erge

ncy

& C

lean

ing

Emul

sifie

r O

/W

Foam

ing

Visc

osity

Mod

ifier

Wet

ting

Lubr

ican

tion

Emul

sion

Pol

ymer

izatio

n

Pers

onal

Car

e

Text

ile

Met

al C

lean

ing


CLOUD PT. °F

12.6 • • • • • • •

9 • • • • • • •

120-130 12.6 • • • •

52-61 °C 13.1 • • • • • • •

168-180 14.1 • • •

4.6 •

160-164 16 • • • •

165-170 17.2 • • • • •

142-152 • • • • •

8.9 • • W/O • •

175-180 17.8 • • •

18.2 • •

10.9 • • • • • •

124-133 13 • • • • • • •

170-185 • • •

62-68 °C 13.4 • • • • • • •

62-66 °C • W/O •

88-92 9.5 • • L • • •

• •

8 W/O •

65-75 10.5 • • • • •

• • • • • •

17 • • • • •

45-55 °C • • • • • •

15.6 • • • • • • • •

• •

85-91.7 °C 14.3 • • • •

36.7-38.9 °C 12 • • • •

58.3-60 12.9 • • • •

13.7 • • • • • • •

• • •

32-40 °C 11.4 • • • • L • • •

N O N I O N I C S

KEY

* 1% aq

** 3%aq

*** 5% aq

**** 10% aq

(a) 1% in 62.5% IPA

(b) 5% in 25% IPA

(c) 1% in 25% IPA

(d) 5% in 50% IPA

(e) 1% in 50% IPA

(f) 5% in 75% IPA

(g) 1% in 75% IPA

(h) 5% in 50% Ethanol

(A) APNA

(G) Gardner

(L) Low Foam

W/O Water-in-oil

HLB

A L K O X Y L AT E D A L K Y L P H E N O L S A L K O X Y L AT E D A L C O H O L S




N O N I O N I C S c o n t i n u e d

WITCONOL 324 EO/PO Copolymer Paste 100 0.2 6-8 (f)

WITCONOL 324D Witconol 324 in Butyl Cellosolve/Water Liquid 51-53 13.5 5-7 (b)

WITCONOL PEG-400 Polyethylene Glycol 400 Liquid 100 0.5 6.5*

WITCONOL PD-2000 Polypropylene Glycol 2000 clear amber liquid 100 0.5 12 typical (g)

ARMOTAN AL-69-66 Sorbitol Tallate (30 EO) Ethoxylate Liquid 100 0.5

EMULPON CO-100 Castor Oil (10 EO) Ethoxylate Liquid 99 0.5 6-7 (b) 6 (G)

EMULPON CO-200 Castor Oil (20 EO) Ethoxylate Liquid 99 0.5 6-7 (b) 6 (G)

EMULPON CO-360 Castor Oil (36 EO) Ethoxylate Paste 99 0.2 6.5-7.5 (b)

EMULPON CO-550 Castor Oil (50 EO) Ethoxylate Paste 99 0.5 6-8

ETHOFAT 242/25 Tall Oil Fatty Acid (15 EO) Ethoxylate Liquid 99 3 6 12 (G)

WITCONOL 14 Polyglycerol Oleate Liquid 100 0.2 8-9.5** 10 (G)

WITCONOL H-31A PEG 400 Monooleate Clear amber liquid 100 0.5 3-4** 3 (G)

WITCONOL H-32 PEG 600 Ditallate Clear amber liquid 100 0.5 6-7** 8 (G)

WITCONOL H-33 PEG 400 Ditallate Amber liquid 100 0.5 5-8*** 8 (G)

WITCONOL NS-98 Resin Alkoxylate Hazy viscous liquid 94 0.2

WITCONOL NS-145 Resin Ethoxylate/Propoxylate Dark amber lizuid 99 0.3

WITCONOL NS-179 Resin Propoxylate Amber liquid 99 0.3


MOISTURE%, MAX

COLOR, MAXpH

P O LYO L S

A L K O X Y L AT E D R E S I N S

P O LYO L E S T E R S

Coup

ling

Corr

osio

n In

hibi

tor

Def

oam

er

Dis

pers

ion

Det

erge

ncy

& C

lean

ing

Emul

sifie

r O

/W

Foam

ing

Visc

osity

Mod

ifier

Wet

ting

Lubr

ican

tion

Emul

sion

Pol

ymer

izatio

n

Pers

onal

Car

e

Text

ile

Met

al C

lean

ing


CLOUD PT. °F

158-164 8.0 • • • •

• • •

• •

• • •

• • •

6.3 •

10.2 •

166-176 13.5 •

138-142 14.4 •

12.2 • • • •

6 • • • • • •

12.5 • • • • •

10 • • • •

8.4 • • • •

•

•

•

c o n t i n u e d N O N I O N I C S

HLB

P O LYO L S

KEY

* 1% aq

** 3%aq

*** 5% aq

**** 10% aq

(a) 1% in 62.5% IPA

(b) 5% in 25% IPA

(c) 1% in 25% IPA

(d) 5% in 50% IPA

(e) 1% in 50% IPA

(f) 5% in 75% IPA

(g) 1% in 75% IPA

(h) 5% in 50% Ethanol

(G) Gardner




A L K A N O L A M I D E S

AMADOL 1017 Modified Cocamide DEA Clear amber liquid 95 0.5 8-10*** 160 (K)

AMADOL 128 T Cocamide DEA (1:1) Clear amber liquid 90 0.5 9-10.5* 5 (G)

AMADOL 272 Modified Cocamide DEA Liquid 90 9.5-10.5 6.8-8.8* 14 (G)

AMADOL 511 Fatty Alkanolamide Clear-hazy amber liquid 98 0.3 9-11** 11 (G)

AMADOL 511H Fatty Alkanolamide Clear amber liquid 90 0.5 8-10** 10 (G)

AMADOL 512 Blend Dark liquid 47 20-25 8-9*

AMADOL 5130 Modified Cocamide DEA Clear amber liquid 95 2 8* (typical) 14 (G)

AMADOL 5133 Cocamide DEA (2:1) Clear amber liquid 95 0.5 9-12.5* 8 (G)

AMADOL 5138 Fatty Alkanolamide Clear tan liquid 90 1 9.2-9.7*** 10 (G)

AMADOL 5195 Lauramide DEA Clear yellow liquid 92 0.5 9-11* 2 (G)

AMADOL 61 Oleamide MIPA Paste (yellow-light tan) >90 0.5 8-9.5*

AMADOL CDA Modified Cocamide DEA Clear amber liquid >90 0.5 8-10* 7 (G)

AMADOL WE Fatty Alkanolamide Clear-hazy amber liquid 99 0.3 9-10** 11 (G)


MOISTURE%, MAX

COLOR, MAXpH

Amadol® alkanolamides are reaction products of various fatty acids and

short chain amines in 1:1 or 2:1 ratios. These perform as foam boosters

and viscosity control agents for detergents, cleaners and hand soaps.

A l k a n o l a m i d e s


Cond

ition

ing

& E

mol

lienc

y

Coup

ling

Corr

osio

n In

hibi

tor

Def

oam

ing

Dis

pers

ion

Det

erge

ncy

& C

lean

ing

Emul

sifie

r O

/W

Foam

Boo

stin

g

Visc

osity

Mod

ifier

Wet

ting

Elec

trol

yte

Tole

rant

Emul

sion

Pol

ymer

izatio

n

Fire

Fig

htin

g

Text

ile

Pape

r / M

etal

Wor

king

/ In

k




KEY

* 1% aq solution

** 3% aq solution

*** 5% aq solution


(a) 5% in 25% IPA

(b) 5% in 75% IPA

(G) Gardner

(A) APHA

(K) Klett

(PCC) Platinum Cobolt Color

(s) % solid

(W/O) Water-in-Oil

• • • • •

• • • • • •

• • • W/O • • • •

• • • • W/O • • •

• • • • W/O • •

• • • • • •

• • • • • • • • •

• • • • • • • •

• • • • •

• • • • •

• • • • • •

• • • • • • • •

• • • • •



42 APPENDICES

A P P E N D I C E S

All temperatures are in degrees Centigrade. Solubilities are in g amine per 100 g/solvent.

Ta b l e 1 : S o l u b i l i t y D a t a f o r F a t t y A l k y l A m i n e s

NO. OFCARBON ATOMS INAMINES TEMPERATURE

B E N Z E N E

10.0° 20.0° 30.0° 40.0° 50.0°10 395 ∞ ∞ ∞ ∞12 72 277 ∞ ∞ ∞14 26.4 83 302 ∞ ∞16 10.0 30.7 98 388 ∞18 4.2 14.8 52 173 1000

C Y C L O H E X A N E

10.0° 20.0° 30.0° 40.0° 50.0°10 318 ∞ ∞ ∞ ∞12 57 230 ∞ ∞ ∞14 19.9 68 268 ∞ ∞16 7.4 26.6 86 360 ∞18 2.8 13.2 42.9 144 940

T E T R A C H L O R O M E T H A N E

-20° 0.0° 20.0° 30.0° 40.0° 50.0°10 10.5 57 ∞ ∞ ∞ ∞12 5.5 19.8 148 ∞ ∞ ∞14 2.3 7.7 56 235 ∞ ∞16 0.5 3.2 21.2 73 335 ∞18 <0.1 0.6 7.7 27.9 120 835

T R I C H L O R O M E T H A N E

-40.0° -20.0° 0.0° 20.0° 30.0° 40.0° 50.0°10 17.7 43.0 148 ∞ ∞ ∞ ∞12 9.2 20.0 56 315 ∞ ∞ ∞14 4.5 11.2 29.5 110 308 ∞ ∞16 2.4 6.6 17.0 56 117 378 ∞18 1.2 3.3 9.4 31.9 63 149 845

E T H Y L E T H E R

-40.0° -20.0° 0.0° 20.0° 30.0° 34.5°10 1.4 12.1 86 ∞ ∞ ∞12 0.2 3.4 22.6 275 ∞ ∞14 0.2 5.8 71 273 705

16 0.2 18.5 72 135

18 4.4 22.7 46.8

E T H Y L A C E TAT E

-20.0° 0.0° 20.0° 30.0° 40.0° 50.0°10 14.8 69 ∞ ∞ ∞ ∞12 4.7 18.6 211 ∞ ∞ ∞14 1.7 7.8 57 233 ∞ ∞16 0.3 3.2 19.7 63 295 ∞18 0.9 9.5 27.0 100 845

NO. OFCARBON ATOMS INAMINES TEMPERATURE

M E T H A N O L

-40.0° -20.0° 0.0° 20.0° 30.0° 40.0° 50.0°10 31.0 172 550 ∞ ∞ ∞ ∞12 4.8 29.7 196 930 ∞ ∞ ∞14 0.2 2.8 62 292 770 ∞ ∞16 0,2 6.1 116 256 785 ∞18 0.6 15.6 95 256 1440

B U T Y L A C E TAT E

-20.0° 0.0° 20.0° 30.0° 40.0° 50.0°10 13.3 69 ∞ ∞ ∞ ∞12 4.4 23.0 221 ∞ ∞ ∞14 1.4 9.7 62 233 ∞ ∞16 0.2 3.5 23.9 64 295 ∞18 1.0 11.4 30.4 100 845

A C E T O N E

-20.0° 0.0° 20.0° 30.0° 40.0° 50.0°10 6.6 54 ∞ ∞ ∞ ∞12 0.3 8.1 266 ∞ ∞ ∞14 0.1 15.5 228 ∞ ∞16 <0.1 4.7 445 ∞18 <0.1 3.7 17.0

2 - B U TA N O N E

-20.0° 0.0° 20.0° 30.0° 40.0° 50.0°10 13.3 69 ∞ ∞ ∞ ∞12 4.4 23.0 221 ∞ ∞ ∞14 1.4 9.7 62 233 ∞ ∞16 0.2 3.5 23.9 64 295 ∞18 1.0 11.4 30.4 100 845

E T H A N O L

-40.0° -20.0° 0.0° 20.0° 30.0° 40.0° 50.0°10 8.5 91 350 ∞ ∞ ∞ ∞12 2.0 14.1 115 660 ∞ ∞ ∞14 1.5 30.2 218 660 ∞ ∞16 3.0 83 239 770 ∞18 0.1 7.2 75 280 1630

I S O P R O PA N O L

-40.0° -20.0° 0.0° 20.0° 30.0° 40.0° 50.0°10 11.1 49.0 228 ∞ ∞ ∞ ∞12 4.7 15.0 75 492 ∞ ∞ ∞14 0.6 3.7 25.1 154 458 ∞ ∞16 0.4 7.3 68 169 580 ∞18 0.5 30.0 86 228 1330

n – B U TA N O L

-40.0° -20.0° 0.0° 20.0° 30.0° 40.0° 50.0°10 9.5 30.8 182 ∞ ∞ ∞ ∞12 2.4 8.5 57 430 ∞ ∞ ∞14 0.2 2.4 16.5 130 405 ∞ ∞16 <0.1 3.9 55 148 515 ∞18 0.4 22.7 75 208 1240

A C E T O N I T R I L E

-20.0° 0.0° 20.0° 30.0° 40.0° 50.0°10 2.8 12.7 ∞ ∞ ∞ ∞12 0.2 27.7 ∞ ∞ ∞14 1.8 14.9 ∞ ∞16 0.2 1.3 14.8 ∞18 0.3 1.9 10.5

APPENDICES 43

44 APPENDICES

At room temperatures (g/100 g solution at 25˚C/77˚F).

Ta b l e 2 : S o l u b i l i t y C h a r a c t e r i s t i c s o f E t h o x y l a t e d ® P r o d u c t s

PRODUCT ACETONE

0 25 50 75 100

ISOPROPANOL

0 25 50 75 100

CARBON TETRACHLORIDE

0 25 50 75 100

ETHOFAT 242/25

ETHOMEEN® C/12

ETHOMEEN C/15

ETHOMEEN C/20

ETHOMEEN C/25

ETHOMEEN 18/12

ETHOMEEN 18/15

ETHOMEEN 18/60

ETHOMEEN T/12

ETHOMEEN T/15

ETHOMEEN T/25

ETHOMEEN S/12

ETHOMEEN S/15

ETHOMEEN S/20

ETHOMEEN S/25

ETHOMID® HT/23

ETHOMID HT/60

ETHOMID O/17

ETHOQUAD® C/12

ETHOQUAD C/25

ETHOQUAD 18/12

ETHOQUAD 18/25

ETHOQUAD 0/12

cloudy

cloudy

cloudy

cloudy

cloudy

sl. cloudy very cloudy

cloudy

cloudy

cloudy

cloudy

fluid paste

paste

cloudy

paste

cloudy

pastevery cloudy fluid paste

paste

APPENDICES 45

DIOXANE

0 25 50 75 100

STODDARD SOLVNET

0 25 50 75 100

BENZENE

0 25 50 75 100

WATER

0 25 50 75 100

KEY Gel

Insoluble

Solution

Dispersion

viscous

viscous

viscous

fluidfluid pastepastepaste stifffluid paste

pastepastepastepaste

cloudy paste

cloudy

cloudy

cloudycloudypaste sl. cloudy

cloudy

cloudyvery cloudy

cloudypastecloudy cloudy

pastepastepaste

QUATERNARY METHANOL/AMMONIUM ETHANOL/ N-HEXANE/ CARBON HEXYLENE (1,2) MINERALSALT** WATER ISOPROPANOL ACETONE BENZENE CYCLOHEXANE CHLOROFORM TETRACHLORIDE GLYCOL OIL

Arquad XX XX NA O O XX XX NA NAAlkyltrimethyl

Arquad D XX X XX NA XX XX NA NADialkyldimethyl

Arquad XX XX XX X NA NA NA NA NABenzylalkyl

Duoquad XX XX NA O O XX XX NA NAAlkylDiquaternary

Ethoquad XX XX XX XX NA NA XX XX OEthoxylatedQuaternary

Propoquad XX XX XX XX NA NA XX XX NAPropoxylatedQuaternary

Ta b l e 3 : S o l u b i l i t y D a t a F o r Q u a t e r n a r y A m m o n i u m C o m p o u n d s a t 2 5 º C

* Solubility generally decreases in a given solvent with increasing chain length of alkyl substituents.** Most quaternary ammonium salts are soluble in hot ethyl acetate.

KEY

XX Very Soluble (≥5% by weight)X Slightly Soluble (between 1 and 5% by weight)D DispersibleO Insoluble (<0.5% by weight)

46 APPENDICES

C U S TO M E R S E R V I C E & T E C H N I C A L S U P P O R T

CUSTOMER SERVICE & TECHNICAL SUPPORT 47

48 CUSTOMER SERVICE AND TECHNICAL SUPPORT

Tr a d e m a r k e d P r o d u c t s N o t L i s t e d i n C a t a l o gThis catalog provides information on those products which have a broad range of industrial applications. However, Akzo Nobel Surface Chemistry

LLC markets many more that are directed toward specific applications or markets. To facilitate obtaining information on these products, their

trademarks are listed below alphabetically with their main application area identified. For more information on any products using these

trademarks, please contact Customer or Technical Service.

Trademark Responsible Marketing Function

ADSEE® Agro Applications

AGTM Cleaning Applications

AMADOL® Mining Applications

ARDEFOAMTM Industrial Applications

ARMACFLOT® Mining Applications

ARMIXTM Agro Applications

ARMOCARE® Personal Care

ARMOFLOTM Mining Applications

ARMOGLOSS® Cleaning Applications

ARMOLUBE® Cleaning Applications

ARMOSOFT® Fabric Care

ARMULTM Agro Applications

BALAB® Industrial Applications

BEROL SPIN® Viscose

BEROL VISCOTM Viscose

BEROL® Cleaning Applications

DUOMAC® Mining Applications

ELFACOS® Personal Care

ELFAN® Personal Care

EMPHOSTM Agro Applications

Trademark Responsible Marketing Function

EMULPONTM Agro Applications

ETHOPROPOMEENTM Agro Applications

FLO MO® Agro Applications

KETJENLUBE® Oilfield Applications

KETJEN-OX® Oilfield Applications

LASARTM Agro Applications

LILAMINTM Mining Applications

MORWET® Agro Applications

PCTM Oilfield Applications

PROPODUOMEENTM Asphalt Applications

REDICOTE® Asphalt Applications

SPONTO® Agro Applications

WETFIX® Asphalt Applications

WITBREAKTM Oilfield Applications

WITCAMINETM Oilfield Applications

WITCODETTM Cleaning Applications

WITCOMULTM Oilfield Applications

WITCORTM Oilfield Applications

WITFLOWTM Industrial Applications

©2004 Akzo Nobel Surface Chemistry LLC, all rights reserved Publication SC04-10

All information concerning these products and/or all suggestions for handling and use contained herein are offered in good faith and believed to bereliable. Akzo Nobel Surface Chemistry LLC and its affiliates, however, make no warranty as to the accuracy and/or sufficiency of such information and/orsuggestions, as to the products’ merchantability or fitness for any particular purpose, or that any suggested use will not infringe any patent. Nothingcontained herein shall be construed as granting or extending any license under any patent. Buyer must determine for himself, by preliminary tests orotherwise, the suitability of these products for his purposes. The information contained herein supersedes all previously issued bulletins on the subjectmatter covered. The user may forward, distribute and/or photocopy this document only if unaltered and complete, including all of its headers andfooters, and should refrain from any unauthorized use. You may not copy this document to a website.

C u s t o m e r S e r v i c e a n d Te c h n i c a l S u p p o r t

N o r t h A m e r i c aAkzo Nobel Surface Chemistry LLC525 W. Van Buren StreetChicago, IL 60607-3823United States

R e g i o n a l O f f i c e s

A s i a / A u s t r a l i aAkzo Nobel Chemicals Pte. Ltd 41, Science Park Road# 03-03 & 12 The GeminiSingapore Science Park IISG-117610 Singapore

Tel: +65 773 8488Fax: +65 773 8484

www.surfactantsasia.akzonobel.com

Europe/Midd le East /Afr i caAkzo Nobel Surface Chemistry ABSE-444 85 StenungsundSweden

Tel: +46 303 85000Fax: +46 303 770578

www.se.akzonobel.comOR: www.surface.akzonobel.com

Te c h n i c a l S u p p o r tTel: (877) 565-8432

(312) 544-7139Fax: (312) 544-7410

C u s t o m e r S e r v i c eTel: (800) 906-9977

(312) 544-7000Fax: (312) 544-7159

[email protected]://surface.akzonobelusa.com

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Tel: +55 11 4591 8800Fax: +55 11 4591 1495

www.akzonobel.com.br

Akzo Nobel, based in the Netherlands, serves customers throughout the world with healthcare products, coatings and chemicals.

The Company currently employs approximately 64,000 people in more than 80 countries.

Surface Chemistry

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