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Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

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Page 1: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

Alex StoneWashington Department of

EcologyNAHMMA Meeting

2 June 2015

Alternatives Assessment: The Search for Safer Substitutes

Page 2: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

Contents Definitions

Explain why we care

Summarize recent activities in Alternatives Assessment

Page 3: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

Definitions

Page 4: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

Regrettable Substitution• Definition: Replacement of toxic chemical with chemical

of equal or greater toxicity

• Historically occurred when chemical banned with no review of toxicity of replacement

• Ex: Replacing chlorinated solvents- CA banned use of many chlorinated solvents- Manufacturers replaced products containing chlorinated solvents with hexane- Few years after switch, employees started having neurological problems- Hexane identified as neurotoxic in 1960’s- Replaced with n-propyl bromide, another neurotoxicant

Page 5: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

Phase out hazardous chemicals yes! But how can one avoid regrettable substitutions?

Page 6: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

Alternatives AssessmentDefinition:– The objective of an alternatives assessment is to replace

chemicals of concern in products or processes with inherently safer alternatives, thereby protecting and enhancing human health and the environment.

Principles– Reduce risk by reducing hazard– Transparency– Flexibility– Life-cycle Thinking– Opportunities for Green Chemistry and Continuous

Improvement– Consider Uncertainties

Page 7: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

Alternative Assessment Objective

Replace toxic chemicals with safer alternatives

If a safer alternative to a toxic chemical exists that completes the function of the product at a cost effective price, NO justification for continued use of toxic chemical

Money is saved by not using toxic chemicals including cost savings associated with:

– Manufacture, transport and potential spills– Release during use and end-of-life– Cleanup of contaminated sites– Regulatory costs of managing both chemicals and

dangerous waste

Major US and International companies require alternatives assessment because of these benefits

Page 8: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

Chemical Hazard AssessmentDefinition:– A process for identifying, comparing and selecting safer chemical alternatives

to replace hazardous chemicals based on the inherent characteristics of the chemical impacting public health and the environment

Numerous tools available– Pharos Database– ChemHat– Interstate Chemicals Clearinghouse CHA Database– GreenScreen and GreenScreen Store– OECD Toolbox– Quick Chemical Assessment Tool (QCAT)

Page 9: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

Why We Care!

Page 10: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

Why conduct an Alternatives Assessment?

– Desire to get off toxic treadmill and stop regrettable substitutions from occurring

– Increased interest by State Legislatures in AA process along with chemical bans

– Two states currently have authority to require alternatives assessments

• California• Maine

– Increased industry interest and requests for assistance

– Health Impacts

Page 11: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

The true burden of environmentally induced cancer has been grossly underestimated. With nearly 80,000 chemicals on the market in the United States, many of which are used by millions of Americans in their daily lives and are understudied and largely unregulated, exposure to environmental carcinogens is widespread.

Pres. Obama’s Cancer Panel (2010)

Page 12: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

• Only 10 percent of breast cancers can be attributed to genetic mutations.

• Compelling scientific evidence points to some of 50,000 synthetic chemicals in use today as contributing to development of breast cancer, either by altering hormone function or gene expression.

Preventing Breast Cancer?

Page 13: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

Additional Concerns

Page 14: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

Autism Concerns (cont.)

Recent data (2014) from the Centers for Disease Control and Prevention

Page 15: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

Oooh-Look Donald Duck!

Golly-There’s Pluto too!

Non-hazardous to children or adults, to pets or cloth. Certified to be absolutely safe for home use. Tested and recommended by Parents’ Magazine.

Page 16: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

Chemical Hazard Assessment-Business

Perspective (HP)1

Faster, Easier to complete– Narrow, well-defined endpoints– Science-based– Facilitates relative quick assessments

Increasingly used by regulatory bodies

– Useful as an indicator of future restriction

– Aligns business with regulatory process

1 Information from a presentation at a Green Materials symposium made by Helen Holder of Hewlett-Packard on 23 March 2011

Page 17: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

RA Concerns-Business Perspective (HP)1

• Not comparative– Not in a useful format for comparative

decisions– Chemists consider function when designing

formulations– Alternatives must be shown in relation to

other chemicals of the same function1 Information from a presentation at a Green Materials symposium made by Helen Holder of Hewlett-Packard on 23 March 2011

Is Risk Assessment the right tool for comparing alternatives to restricted substances in electronics?• Overwhelming to most decision-makers

– Most decision makers are procurement engineers– Overwhelmed by information out of their field– Can’t effectively incorporate into existing procurement process

Page 18: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

Recent Activities in Alternatives Assessment

Page 19: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

IC2 AA Guide

– Released IC2 Guide in Jan. 2014

– Guide detailed and complicated

– Based upon concept that an AA cannot be done using just one method

– Includes flexibility to meet wide range of needs

– States to adapt IC2 Guide to suit individual needs

– Ecology created Washington specific AA Guide

Page 20: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

IC2 AA Guide

http://theic2.org/article/download-pdf/file_name/IC2_AA_Guide_Version_1.0.pdf

Page 21: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

Guide Components

1. Identify COCs

2. Initial Evaluation

3. Scoping– Stakeholder– Decision Framework

4. Identification of Alternatives

5. Assess Alternatives– Hazard– Performance– Cost & Availability– Exposure– Materials Mgt– Social Impact– Life cycle

AA consists of five distinct steps

Page 22: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

Other Frameworks– National Academy of Sciences (NAS) released an

alternatives assessment framework document in October 2014

– NAS framework based upon existing frameworks and is in agreement with the IC2 AA Guide

– Provides less concrete guidance than other frameworks

– Leaves many of the decisions to assessor or external parties• Ex: Less defined hazard assessment

Page 23: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

OECD Toolbox– Organization for Economic Cooperation and

Development (OECD) recently released AA Toolbox– Assist users with AA

Page 24: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

Summary– Although AA techniques still developing,

considerable activity occurring

– Resources made available to a wide range of potential users

– Training becoming more available• GreenScreen• Quick Chemical Assessment Tool (QCAT)

Page 25: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes
Page 26: Alex Stone Washington Department of Ecology NAHMMA Meeting 2 June 2015 Alternatives Assessment: The Search for Safer Substitutes

ContactsAlex StoneWashington Department of EcologySafer Chemical Alternative Chemist(360) [email protected]

Ken ZarkerWashington Department of EcologyPollution Prevention and Regulatory

Assistance(360) [email protected]