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    RATES OF REACTIONThe rate of a chemical reaction is determined by HOW FASTa reaction occurs (this is the rate of

    reaction):

    TYPES OF REACTION :VERY FAST an explosion e.g. dynamite

    FAST group 1 metals + water

    SLOW zinc + acidVERY SLOW rusting

    FACTORS AFFECTING RATE :TEMPERATURE: each atom will then have a higher kinetic energy, which increases the number of collisions(as the particles are moving faster and crazier), and bigger and faster collisions

    CONCENTRATION: a higher concentration means more atoms and molecules which will then increase theprobability of collision, which increases the efficiency of a reaction

    SURFACE AREA: the larger the surface area, the more reactions can take place on that certain substance,which increases the efficiency of the reaction

    CATALYST: lowers the ACTIVATION ENERGY allowing the substance to react at a lower temperature, whichdecreases the amount of energy needed, allowing it to react faster

    PRESSURE: the increase in pressure for gases is the same as increasing concentration for liquids; it meansthat there are more of that certain atom, which therefore increases the likelihood of collision

    CATALYSTSThey are mainly used in industrial processes, as they manage to speed up the rate of reaction. They do this

    by lowering the activation energy, which means that they can use less energy to complete the reaction. This

    reduces costs, and is therefore very useful to the companies.

    ENZYMESEnzymes are complex molecules which act as a biological catalyst in leaving systems, such as humans

    (amylase, protease etc.). They are very sensitive to temperature and pH.

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    Catalysts Enzymes

    Manganese Dioxide Making O2 from hydrogen

    peroxideAmylase

    Platinum, Rhodium & Palladium used in car

    exhaust pipesProtease

    Nickel - making margarine Lipase

    ATOMIC STRUCTURE &

    CHEMICAL BONDING

    Electrons:

    relative charge: -1

    relative mass: 11836

    Protons

    relative charge: +1 relative mass: 1

    Neutrons

    relative charge: 0 relative mass: 1

    Electrons found in a shell

    around the nucleus

    Nucleus has protons andneutrons

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    POTASSIUMS ELECTRONIC STRUCTURE

    Atoms transfer electrons in chemical bonds to try and achieve a full outer shell as it is MORE STABLE.

    IONSIons are electrically atoms or groups of atoms. They are formed by the loss or gain of electrons

    Type of Ion Charge

    Metal Atoms&Ions Positively Charged (+)

    Non-Metal Ion Negatively Charged (-)

    COMMON IONS

    SODIUM:Na+ MAGNESIUM:Mg

    2+

    AMMONIUM:NH4 + OXIDE:O2- CHLORIDE:Cl-

    IONIC BONDINGIonic bonding includes the gain or loss of one or more electrons from an atom

    -to obtain a FULL OUTER SHELL

    Ionic Bonding only occurs between: METALSANDNON-METALS (1metal+1non-metal)

    K2,8,8,1

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    EXAMPLES:

    ClNa

    Na Cl

    NaCl

    OMg

    Mg O

    MgO

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    LATTICE STRUCTUREA way of displaying regular patterns within atoms of oppositely charged ions is used a lattice structure:

    IONIC SUBSTANCES THEY HAVE HIGH METING POINTS: strong electrostatic bonds between each ion (and these have to

    break)o The greater the charge on the ions the higher the melting and boiling point.

    COVALENT BONDINGDEFINITION :Covalent bonding is the sharing of a pair of electrons between two atoms. Covalent bonds are only

    formed between NON-METALS + NON-METALS.

    FAl

    Al F

    AlF3

    Lattice of NaCl+

    ++

    ++ +

    ++ --

    --

    -

    --

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    FORMATION

    METALLIC BONDING

    DEFINITIONA metallic bond is a giant structure of positive (metal) ions, surrounded by a sea of delocalised (free)electrons.

    Cl ClH H H Cl

    O O

    H

    O

    H H

    C

    H

    H

    N

    H

    H

    O O O

    Positive metal ions

    Sea of negative ions

    +

    + ++ +

    +

    +

    +

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    STRUCTURECARBON DIOXIDE :

    Double bonds Structured in a line It is stable (has a full outer shell)

    DIAMOND

    Single covalent Bonds All bonds are strong No weak Bonds Tetrahedron of Carbon atoms

    GRAPHITE Hexagonal shape of c atoms Only 3 covalent bonds It is formed in layers Weak bonds between layers

    C O C

    C

    C

    C C

    C

    C

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    THE STRUCTURE DIAGRAM

    SIMPLE MOLECULAR SUBSTANCESThey normally have low boiling and melting points because the forces of attraction are typically

    weaker, and therefore they are easier to break.

    They dont conduct electricity, because they are all COVALENT bonds, and therefore share electrons which

    UTILISES all of them, which means there are no free electrons.

    DIAMOND and GRAPHITE have many strong covalent bonds making their melting and boiling points veryhigh.

    HOWEVER

    DIAMOND has no free electrons within its structure which means that it cannot conduct electricity.

    GRAPHITEdoes have free electrons between layers of carbon atoms, and can therefore conductelectricity. It also has layers of carbon atoms connected by weak bonds making them slippery.

    Giant Structure Molecular Structure

    Substances made up ofhuge numbersof atoms, or

    ions

    Substances that are made up of a mixed number of

    atoms shown by the molecular formula (eg. H2O or

    C6H12O6

    The number of particles is not fixed, but are usually

    arranged in a regular pattern(lattice)

    Generally the atoms are joined by covalent bonds.

    The molecules are usually very small but can be

    large in some cases

    Includes:

    Giant Metallic - all metals and alloys Giant ionic all ionic substances

    Giant Covalent in diamond, graphite andsilicon

    Includes Simple Structures:

    Monatomic like He, Ne, Ar etc. Simple Molecules like H2, H2O, CO2

    Structure

    Sim leGiant

    Gra hiteDiamond

    Silicon

    Carbon

    All

    Metals

    Anything

    Ionic Almost all

    covalent

    substances

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    MACROMOLECULEA macromolecule is an extremely large molecule containing a very large number of atoms.

    REACTIVITY SERIES

    DISPLACEMENTExample:

    OXIDE:The removal of electrons from a substance, or the addition of oxygen

    REDUCTION:The addition of electrons from a substance, or the removal of oxygen

    REDOX:a reaction in which reduction and oxidation is both occurring

    OXIDISING AGENT:A substance that is capable of oxidising another substance

    REDUCING AGENT:A substance that is capable of reducing another substance

    Element Cold water/steam Dilute Acid

    Potassium

    React very vigorously with cold water

    to form a solution of the metalhydroxide + hydrogen

    Reacts vigorously to form a

    metal salt + hydrogenSodium

    Lithium

    Calcium

    Decreasing vigour as scaledecreases (forms metal salt +

    hydrogen)

    Magnesium Reacts very slowly with cold water, but

    burns with steam MgO + H2

    Aluminium Does not react with cold waterhowever reacts with steam without

    burning, to form metal oxide +hydrogen

    Zinc

    Iron

    Tin

    Does not react with steam or water

    Lead

    Copper

    Does not reactSilver

    Gold

    Platinum

    More Take Salt

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    EXAMPLES2Na+O Na2O

    Mg + OMgO

    2K + 2H2O H2+2KOH

    Ca + 2H2O Ca(OH)2 + H2

    3AgNO3 + Fe 3Ag + Fe(NO3)3

    MgSO4 + Cu CuSO4 + Mg

    RUSTINGFe2 + 3O2 Fe2O3

    A REDOX reaction will occur and the iron will be oxidised. Rusting normally occurs in moisture-prone areas.

    EXTRACTION &USES OF METALSMost metals found recently are higher up in the reactivity series. This is because as technology progresses

    we are able to find more reactive substances, which could not have been found previously, and so are now

    founded.

    As the reactivity series increases the extraction methods become more extravagant and expensive.

    If the substance is low down it is safer and can therefore be used in consumer products.

    QUALITATIVE ANALYSISQualitative: what is present?

    Quantative: how much?

    IONSAn ion is a charged atom or molecule: Cations are POSITIVE: Li+, Na+, K+, and NH4

    Anions are NEGATIVE: F-, Cl-, Br-, and OH-

    Ions can have more than one chargehowever.

    Group 1 2 3 4 5 6 7

    Charge +1 +2 +3 -3 -2 -1

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    Positive Ions Negative Ions

    Hydrogen ion H+ Magnesium Mg2+ Aluminium Al3+ Chloride Cl- Oxide O2-

    Lithium Li+ Calcium Ca2+ Iron(III) Fe3+ Bromide Br- Co32-

    Sodium Na+ Barium Ba2+ Iodide I- Sulfate SO42-

    Potassium K+ Manganese (II) Mn2+ Hydroxide OH-

    Ammonium NH4+ Iron (II) Fe2+ Nitrate NO3-

    Copper (II) Cu2+

    Zinc Zn2+

    TESTING FOR CATIONS1. Flame test: some metals burn with a distinctive colour2. Dissolve the unknown substance in concentrated Hydrochloric Acid (HCl)3. Dip this solution on a piece of sterile wire4. Hold in a hot flame

    Metal Ion Flame Colour

    Li+ (Lithium) Red scarlet

    Na+ (Sodium) Orange yellow

    K+ (Potassium) Lilac

    Ca2+ (Calcium) Brick-red

    Ba2+ (Barium) Apple-Green

    Or

    1. Sodium Hydroxide test: adding sodium hydroxide to Cations produces a precipitate2. Aqueous metal salt + aqueous sodium hydroxide precipitate

    Metal Ion Precipitate

    Al3+, Mg2+, Ca2+ White precipitate

    Al(OH)3Re-dissolves sodium

    hydroxide

    Cu2+ Pale blue

    Fe2+ Dirty green

    Fe3+ Rusty brown

    SYMBOLEQUATION: CaCl2 (aq)+2NaOH(aq)Ca(OH)2 (s)+2NaCl(aq)

    IONICEQUATION: Ca2+(aq) + 2OH-(aq) Ca(OH)2 (s)

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    TESTING FOR IONSThe anions are only the halides (group 7 metals Cl, Br, I), the sulphates, carbonates, and nitrates.

    HALIDES:You can test for them using DILUTE NITRIC ACID AND SILVER NITRATE forms an insoluble silver iodide

    precipitate.

    1. Make a solution of suspected halide2. Add enough nitric acid to make it acidic3. Then add some silver nitrate solution (AgNO3(aq))

    White precipitate: AgCl

    Pale Green: AgBr

    Yellow: AgI

    Equations

    Ag

    +

    (aq) + X

    -

    (aq) AgX (s)Ag+(aq) + Cl

    -(aq) AgCl (s)

    AgNO3(aq) + NaBr(aq) AgBr NaNO3 (s)As the precipitates are similar colours you can do a further test to make sure that you know what is what.

    The test is the SOLUBILITY IN AMMONIA SOLUTION.

    Halide Solubility in Dilute Ammonia In Concentrated Ammonia

    Silver Chloride Silver Bromide Silver Iodide

    FURTHER ATOMIC STRUCTURE

    A Single

    Atom

    2 Separate

    Atoms

    2 Chemically

    Joined Atoms

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    GENERAL STRUCTURE

    Isotope: atoms with different numbers of neutrons however, are the same element.

    Relative atomic mass: the weighted average mass of the isotopes of an element relative to an atom of

    Carbon-12

    We use the weighted average mass because there ARENT EQUAL AMOUNTS OF ISOTOPES of eachelement.

    To find out the Relative Formula Mass (Mr) of Chlorines isotopes, we need to know its isotopes and their

    relative atomic mass:

    Eg1. The isotopes of chlorine are: 75% 35Cl, and 25% 37Cl.

    When we add these two together, we get 35.5, this means the RFM (Mr) is 35.5 (35.5Cl)

    Relative Formula Mass: the relative formula mass of a compound is the sum of relative atomic masses (Ar)

    of the atoms in the numbers shown in the formula.

    Eg2. MgCO3= 1Mg 1C 3O

    ( )

    23

    11 Na

    Mass Number protons and

    neutrons

    Atomic Number Protons (and

    neutrons if it isnt an isoto e

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    Mass

    MrMole

    THE MOLEThe mole is a measurement of a substance, a mole of carbon; a mole of water.

    For example: Ar of C=12 . . . So 1 mole of C is 12g

    Mr of H2O is 18, so 1 mole of H2O is 18g

    The molar mass = mass of 1 mole

    = same as Mr

    QUESTIONS

    Whats the mass of 1 mole of Mg?

    Ar=24.3, 1 mole=24.3g

    What is the mass of 1 mole of NaOH?

    Mr=40, 1 mole=40g

    What is the mass of 0.2 moles of CaCO3?

    Mr=100, 0.2x100=20g

    How many Moles in 54g of H2O?

    Mr=18,

    18 moles

    AVOGADROS NUMBER One mole of something always contains the same number of molecules (or atoms if its an element) That number is 3 So 1 mole of carbon has a mass of 12g and contains 3 atoms of Carbon-12 But 1 mole of water has a mass of 18g and also contains 3 of water molecules

    KEY CONCEPTSRadicals Formula Valency

    Ammonium NH4- 1

    Hydroxide OH-

    1Nitrate NO3

    - 1

    Carbonate CO32- 2

    Sulfate SO42- 2

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    The reaction ratio is called the STOICHIOMETRY

    GENERAL FORMULAS

    CALCULATIONSWHAT MASS OF MGO IS FORMED WHEN 4.8G OF MG IS OXIDISED?

    1. Balance Equation:

    2. Stoichiometry:

    3. Work something out:

    4. Mr of MgO = 40

    PERCENTAGE YIELD

    EMPIRICAL FORMULA1. Calculate moles of each element2. Divide by smallest = ratio

    Eg1. Mg O Eg2. H O

    =0.1

    1

    1

    8

    16

    0.1

    MgO H2O

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    AVOGADROS LAW That 1 mole of any gas will OCCUPY 24DM3 1Litre = 1dm3 = 1000cm3 1 Mole of Ammonium will occupy 24000cm3

    CALCULATING THE VOLUME OF GASCALCULATE THE VOLUME OF 0.01G OF HYDROGEN:

    3

    CALCULATE THE VOLUME OF CARBON DIOXIDE PRODUCED AT ROOM TEMPERATURE WHEN DILUTE

    HCL IS ADDED TO 1.00G OF CACO3

    3

    CALCULATING THE CONCENTRATIONThis is the number of moles in a litre (of water or another solvent)

    1mole in litre has a concentration of 1mol/dm3 (1moldm-3)

    Also 1M = 1 molar solution

    Volume in dm3

    3

    3

    CRITICAL EQUATIONS:

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    CHEMISTRY OF THE ELEMENTSIMPORTANT GROUPS:

    Group 1LITHIUM, SODIUM, POTASSIUM Group 7CHLORINE, BROMINE, IODINE Group 0 noble gases; HELIUM, NEON, ARGON (full outer shell)

    GROUP 1In group 1, the elements get INCREASINGLY REACTIVE due to the distance between the first shell and last

    shell, in order for a reaction to take place, these shells must be broken, and so the more that need to be

    broken, the more reactive they are.

    GROUP 7Chlorine a yellow/green GAS at room temperature

    Bromine a brown LIQUID at room temperature

    Iodine a black SOLID at room temperature

    ORGANIC CHEMISTRYTerm Definition

    Homologous seriesA series of organic compounds that have the same general formula,similar chemical reactions and where each member differs from the

    next by a Ch2- group

    Hydrocarbon A compound only containing the elements hydrogen and carbon

    Saturated An organic compound in which all bonds are single bonds

    Unsaturated An organic compound that contains carbon-carbon double bonds

    General FormulaA formula that states the ratio of atoms of each element in the

    formula of every compound in a particular homologous series

    IsomerismCompounds that have the same molecular formula but differentdisplayed formulae are said to exhibit isomerism; the different

    compounds are called isomers

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    ALKANES

    This is a homologous series that has the general formula:CnH2n+2. these are the first five terms in theseries:

    Molecular Formula Name

    CH4 Methane

    C2H6 Ethane

    C3H8 Propane

    C4H10 Butane

    C5H12 Pentane

    Displayed Formula

    ReactionsCombustion: the alkanes burn when heated in air or oxygen. If there is a plentiful supply of air/oxygen the

    products are carbon dioxide and water.

    () () () ()

    38 () () () ()

    Methane Ethane Propane Butane

    DimethylpropaneMethylbutaneMethylpropanePentane

    Both butane and pentane have isomers: Methylpropane is an

    isomer of butane; and Methylbutane and Dimethylpropane

    are isomers of pentane

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    If there is insufficient oxygen:

    () () () ()

    With Bromine: Methane and bromine react together in the presence of UV radiation to form

    bromomethane.

    () () 3() ()

    ALKENES

    This is a homologous series that has the general formula:CnH2n. these are the first five terms in the series:

    Molecular Formula Name

    C2H4 Ethene

    C3H6 Propene

    C4H8 Butene

    C5H10 Pentene

    Reactions of the AlkenesAlkenes undergo addition reactions with halogens. For example, a bromine molecule will add across the

    double bond of ethene to form 1,2-dibromoethane:

    1,2-dibromoethane is colourless, so when

    bromine or bromine water is shaken with ethene

    the BROMINE WILL DECOLOURISE. All alkenes will

    decolourise bromine. This is the TEST FOR

    UNSATURATION (c=c double bonds).

    Ethene Propene But-1-ene

    Meth l ro eneMethane Ethane Propane Butane

    But-2-aneMethane Ethane Propane Butane

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    ETHANOLEthanol is manufactured by two different processes: fermentation and direct hydration of ethane.

    Fermentation Dissolve sugar or starch in water and add yeast Leave the mixture to ferment at 25-40C for several days in the absence of air Filter off the excess yeast to obtain a dilute solution of ethanol

    If the ethanol content in the mixture rises to around 15%, the yeast is now killed. If a moreconcentrated solution of ethanol is required, the mixture is fractionally distilled.

    Whatever the starting point, sugar or starch, the enzymes in the yeast produce glucose, C6H12O6. Theenzymes in yeast then convert the glucose into ethanol:

    616() () ()

    Direct Hydration of Ethane A mixture of ethene and steam is passed over a phosphoric acid catalyst at a temperature of 300C

    and 60-70 atmosphere pressure:

    () () () The ethanol is condensed as a liquid The ethene required for this reaction is obtained from crude oil

    Comparing the Two Methods

    EXTRACTION OF ALUMINIUMThe method of extraction of metals relates to their reactivity, the higher the reactivity, the more difficult the

    extraction process.

    Fermentation Hydration

    Raw materials USE RENEWABLE SOURCESUses NON-RENEWABLE resources

    once all the crude oil is used up

    there will not be any more

    Type of process BATCH process CONTINUOUS process

    Rate of reaction Very SLOW, several days FAST

    Quality of product

    Produces a DILUTE solution of

    ethanol that needs further

    processing if pure ethanol is

    required

    Produces PURE ETHANOL

    Reaction conditions LOWTEMPERATURES requiredHigh temperature and pressures

    required, increasing the COSTS

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    ELECTROLYSIS

    The positive and negative electrodes are made of graphite (Carbon). The electrolyte is a solution of aluminium oxide dissolved in molten cryolite. The main ore of aluminium is bauxite. The bauxite is first purified to produce aluminium oxide, Al2O3 Aluminium oxide has a very high melting point and hence it is dissolved in cryolite to make the

    electrolyte. This mixture has a much lower melting point and is also a much better conductor ofelectricity than molten aluminium oxide.

    At the negative electrode:3

    The aluminium melts and collects at the bottom of the cell and is then tapped off.

    At the positive electrode:

    Some of the oxygen produced at the positive electrode then reacts with

    graphite to produce carbon dioxide gas:

    () () ()

    This means that the positive electrode slowly burns away and needs to be regularly replaced.

    +

    -

    Positive electrode

    Negative

    electrode

    Insulation

    Electrolyte

    Tapping hole

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    EXTRACTION OF IRONBLAST FURNACE

    The raw materials are iron ore (haematite), coke (carbon), limestone (calcium carbonate) and air Iron ore, coke and limestone are mixed up together and fed into the top of the blast furnace Hot air is blasted into the bottom of the furnace

    Iron ore mixed with

    limestone and coke

    Waste

    gases

    Waste

    gases

    Blast of

    hot air

    Molten slag

    Molten iron

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    THE REACTIONS

    Oxygen in the air reacts with the coke to form CARBON DIOXIDE:() ()

    Carbon dioxide reacts with coke to form CARBON MONOXIDE:() () ()

    Carbon monoxide REDUCES IRON (III) OXIDE in the iron ore:3() ()

    The iron melts and collects at the bottom of the furnace, where it is tapped off The calcium carbonate in the limestone decomposes to form CALCIUM OXIDE:

    3() () ()

    The calcium core reacts with silicon dioxide, which is an impurity in the iron ore, to form CALCIUM

    SILICATE:

    () () 3()

    The calcium silicate melts and collects as a molten slag on top of the molten iron, which is thentapped off separately

    USES OF ALUMINIUM AND IRON

    Aluminium

    Iron

    Use Most important property

    Aeroplane body high strength-to-weight ratio

    Overhead power cable Good conductor of electricity

    Saucepans Good Conductor of heat

    Food cans Non-toxic

    Window frames Resists corrosion

    Use Most important property

    Car Bodies Strong (withstand collisions)

    Iron Nails Strong

    Ships, Girders & Bridges Strong

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    CRUDE OILWHAT IS IT?Crude oil is a thick, sticky, black liquid that is found under the ground and under the sea in certain

    parts of the world such as the Middle East and Texas (USA). It is a mixture of hydrocarbons, MOSTLY

    ALKANES.

    REFINING CRUDE OILCrude oil, as such, has no direct use. It has to BE REFINED before it is of any use. The first step in the

    refining of crude oil is FRACTIONAL DISTILLATION.

    Fractional distillation is carried out in fractioning columns. The column is hot at the bottom and gradually

    becomes cooler towards the top.

    The crude oil is split into various fractions

    as described below. A fraction is a mixture

    of hydrocarbons with very similar boiling

    points.

    Crude oil is heated to convert it intoVAPOUR and is then fed into the

    bottom of the column

    The hydrocarbons with very highboiling points (fuel oil and bitumen)IMMEDIATELY TURN INTO LIQUIDS

    and are tapped off at the bottom ofthe column

    The hydrocarbons that have boilingpoints lower than 400oC remain as

    gases and RISE UP THE COLUMN,AS THEY DO THEY COOL DOWN.

    The different fractions willcondense at different heights

    according to their different boilingpoints. When they condense theyare tapped off as liquids

    The fraction with the lowest boilingpoint (refinery gas) REMAINS AS AGAS and comes out the top.

    Refinery

    Gasoline (petrol)

    Kerosene

    Diesel Gas (gas oil)

    Fuel Oil

    Bitumen

    Crude Oil

    40oC

    400oC

    Fractioning

    Column

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    PROPERTIES

    USES

    HOW DOES CRACKING WORK?Alkane is a long-chain hydrocarbon, and these molecules are passed over a catalyst (silica or aluminium

    oxide) and heated to about 600oC. They then start to break down into a short-chained alkane, and at least

    one alkene.

    Eg. Cracking of Decane (C10H22) to produce octane (C8H18) and ethene (C2H4).

    1() 818() ()

    INCOMPLETE COMBUSTION can create carbon monoxide, which reduces the bloods ability to carryoxygen.

    Fraction

    Number of

    Carbon AtomsBoiling Point Thickness

    Refinery Gases

    INCREASES INCREASES INCREASES

    Gasoline

    Kerosene

    Diesel Oil

    Fuel Oil

    Bitumen

    Fraction Uses

    Refinery Gases Bottled Gas For Camping

    Gasoline Petrol for Cars

    Kerosene Fuel for planes; oil for central heating; paraffin for small heaters

    Diesel Oil Diesel fuel for buses, lorries, trains and cars

    Fuel Oil Fuel for ships and for industrial heating

    Bitumen Road surfaces and covering flat roofs of buildings

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    OXYGEN AND OXIDESCOMPOSITION OF GASES IN CLEAN UNPOLLUTED AIR :

    HOW TO SHOW THAT AIR CONTAINS1

    OF OXYGEN:H

    Using Copper

    This apparatus can be used to find the percentage of oxygen in air:

    Set up the apparatus with 100cm3 of air in one gas syringe Heat the copper at one end of the silica tube using a blue Bunsen burner Pass the air backwards and forwards over the copper As the volume of gas decreases, move the Bunsen flame along the tube so it heats fresh copper Stop heating when the volume of gas has stopped decreasing The copper has reacted with the oxygen to form black copper oxide:

    () () ()

    The final volume will be around 78-79cm3 which shows that 21cm3 has reacted with the copper sothat says that 21% of oxygen is in the air.

    Gas Percentage in Air

    Nitrogen 78

    Oxygen 21

    Argon 0.9

    Carbon dioxide 0.04

    Originally 100cm3 of airSilica tube packed with copper

    Gas syringeHeat

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    Using IronPlace wet iron filings in the end of a burette and set up the apparatus as shown in the diagram.

    Over several days the water will rise up the burette and reach a constant level. This is because

    the iron reacts with the oxygen in the air. Take the initial and final readings of the water level

    in the burette.

    ( )

    ( )

    ( )

    LABORATORY PREPARATION OF OXYGENHydrogen peroxide (H2O2), decomposes slowly to form water and oxygen. The speed of decomposition is

    increased by adding a catalyst: MnO2, manganese dioxide. The oxygen can be collected over water. Since

    oxygen is not very soluble in water, very little is lost. An aqueous solution of hydrogen peroxide is used.

    () () ()

    Manganese (IV) Oxide

    Oxygen

    Hydrogen Peroxide

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    REACTIONS OF OXYGEN

    Magnesium oxide is a basic oxide, and is very slightly soluble in water and when saturated will have a pH of

    about 10. It reacts with water to form magnesium hydroxide:

    () () ()()

    CARBON DIOXIDELAB PREPARATION: 3

    The reaction between any metal carbonate and an acid will produce carbon dioxide. Calcium carbonate is

    the most commonly used carbonate in the laboratory preparation of carbon dioxide. The most convenient

    form of calcium is in marble chips. They are very easy to handle and the reaction is not too fast so the

    Element Observations Equation

    MagnesiumBurns with bright, white flame to

    form a white powder

    Carbon

    Burns with a yellow-orange flame

    to form a colourless gas

    SulphurBurns with a blue flame to form a

    colourless gas

    Calcium carbonate

    Carbon Dioxide

    Dilute Hydrochloric acid

    Water