無 機 化 學 (ㄧ)無 機 化 學 (ㄧ) 2009 化學系 黃建和. 1-1 what is inorganic chemistry...
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無 機 化 學 ( ㄧ )
2009 化學系 黃建和
1-1 What is Inorganic Chemistry
limitless area
1-2 Contracts with Organic Chemistry
delta bond
bridging H and alkyl group
higher coordination numbers
aromatic ring-metal bond
carbon in metal cluster cpds
fullerene
1-3 Genesis of the elements and formation of the earth: the big bang theory
hydrogen burning
helium burning
the carbon-nitrogen cycle
1-4 Nuclear reaction and radioactivity
fission of U and Pu
fusion of H
• 1-5 Distribution of elements on earth according to the solubility in water and
magma
• 1-6 The history of inorganic chemistry before alchemy alchemy radioactivity Werner, Ziegler biological activity
Chap. 2
• 2.1 Historical development of atomic theory
2.2.1 The periodic table
2.2.2 discovery of subatomic particles and the Bohr atom
hydrogen emission spectrum quantum number Heisenberg’s uncertainty principle
Chapter 2 p17
Chapter 2 p20
Chap. 2
• 2.2 The Schrodinger equation
2.2.1 the particle in a box
2.2.2 quantum numbers and atomic wave functions
2.2.3 the Aufbau principle
2.2.4 Shielding: Slater rule
Chapter 2 p23
Chapter 2 p26
Chapter 2 p26
Chapter 2 p27
Chapter 2 p31
Chapter 2 p31
Chapter 2 p35
Chap. 2
• 2.3 periodic properties of atoms
2.3.1 ionization energy
2.3.2 electron affinity
2.3.3 covalent and ionic radii
Chap. 3
• 3.1 Lewis electron-dot diagrams
3.1.1 resonance
3.1.2 expanded shells
3.1.3 formal charge
3.1.4 multiple bonds in Be and B compounds
Chapter 3 p55
Chapter 3 p56
Chap. 3
• 3.2 valence shell electron pair repulsion theory
3.2.1 lone pair repulsion
3.2.2 multiple bonds
3.2.3 electronegativity and atomic size effects
3.2.4 ligand close-packing
Chapter 3 p58
Chapter 3 p61
Chapter 3 p64
Chap. 3
• 3.3 polar molecules
dipole moment
dispersion forces
Chap. 3
• 3.4 Hydrogen bonding
ammonia
clathrates
Chapter 3 p70
Chapter 3 p71
Chapter 4
• 4.1 symmetry elements and operations
identity
rotation
reflection
inversion
improper rotation
Chapter 4 p81
Chapter 4
• 4.2 point groups
the point group assignment method
4.2.1 group of low and high symmetry
4.2.2 other groups
Chapter 4 p84
Chapter 4
• 4.3 properties and representations of groups
4.3.1 matrices
4.3.2 representation of point groups
4.3.3 character tables
Chapter 4
• 4.4 examples and applications of symmetry
4.4.1 chirality
4.4.2 molecular vibrations
water and cis-ML2(CO)2
Chapter 4 p102
Chapter 4 p103
Chapter 4 p103
Chapter 5
• 5.1 formation of molecular orbitals from atomic orbitals
5.1.1 molecular orbitals from s orbitals
5.1.2 molecular orbitals from p orbitals
5.1.3 molecular orbitals from d orbitals
Chapter 5 p118
Chapter 5
• 5.2 homonuclear diatomic molecules
5.2.1 molecular orbitals
5.2.2 orbital mixing
5.2.3 homonuclear diatomic molecules
5.2.4 photoelectron spectroscopy
5.2.5 correlation diagrams
Chapter 5 p123
Chapter 5
• 5.3 heteronuclear diatomic molecules
5.3.1 polar bonds
5.3.2 ionic compounds and molecular orbitals
Chapter 5 p135
Chapter 5
• 5.4 molecular orbitals for larger molecules
FHF-
CO2
H2O
NH3
BF3
Chapter 5 p144
Chapter 5 p147
Chapter 5 p148
Chapter 5 p151
Chapter 5 p152
Chapter 5
• 5.5 expanded shells and molecular orbitals
Chapter 5 p161
Chapter 6
• 6.1 acid-base concepts and organizing concepts
6.1.1 history
from the concept of sour-bitter taste
to Table 6-1
Chapter 6
• 6.2 major acid-base concepts
6.2.1 Arrhenius concept 6.2.2 Brønsted-Lowry concept 6.2.3 Solvent system concept 6.2.4 Lewis concept 6.2.5 frontier orbitals and acid-base reactions 6.2.6 hydrogen bonding 6.2.7 electronic spectra
Chapter 6 p179
Chapter 6
• 6.3 hard and soft acids and bases
6.3.1 theory of hard and soft acids and bases
class (a) is hard class (b) is soft 6.3.2 quantitative measures Drago and Wayland system
Chapter 6 p183
Chapter 6 p184
Chapter 6 p185
Chapter 6 p191
Chapter 6• 6.4 acid and base strength
6.4.1 measurement of acid-base interactions 6.4.2 thermodynamic measurements 6.4.3 proton affinity 6.4.4 acidity and basicity of binary hydrogen compounds 6.4.5 inductive effects 6.4.6 strength of oxyacids 6.4.7 acidity of cations in aqueous solution 6.4.8 steric effects 6.4.9 solvation and acid-base strength 6.4.10 nonaqueous solvents and acid-base strength 6.4.11 superacids
Chapter 6 p202
Chapter 6 p203
Chapter 7
• 7.1 formulas and structures
7.1.1 simple structures
cubic, body-centered cubic,
close-packed structures,
metallic crystals, properties of metals,
diamond
Chapter 7
• 7.1.2 structures of binary compounds sodium chloride cesium chloride zinc blend wurtzite fluorite NiAs rutile
Chapter 7 p214
Chapter 7 p214
Chapter 7 p216
Chapter 7 p216
Chapter 7 p216
Chapter 7 p216
Chapter 7 p217
Chapter 7 p217
Chapter 7
• 7.1.3 more complex compounds
• 7.1.4 radius ratio
Table 7-1 radius ratio limiting values
0.414
0.732
1.00
Chapter 7
• 7.2 thermodynamics of ionic crystal formation
7.2.1 lattice energy and Madelung constant
7.2.2 solubility, ion size, and HSAB
Chapter 7 p221
Chapter 7
• 7.3 molecular orbitals and band structure
p- and n-type semiconductors
7.3.1 diodes, the photovoltaic effect, and light-emitting diodes (LED)
Chapter 7 p223
Chapter 7 p225
Chapter 7
• 7.4 superconductivity
7.4.1 low-temperature superconducting alloys
7.4.2 the theory of superconductivity
(Cooper pairs)
7.4.3 high-temperature superconductors
Chapter 7 p228
Chapter 7 p230
Chapter 7
• 7.5 bonding in ionic crystals
• 7.6 imperfections in solids
vacancies and self-interstitials
substitutions
dislocations
Chapter 7
• 7.7 silicates
silica: quartz, tridymite, and cristobalite
silicate: chain, double chain, ring, sheet, and 3-D array
Chapter 7 p237
Chapter 8
• 8.1 general trends in main group chem.
8.1.1 physical properties
8.1.2 electronegativity
8.1.3 ionization energy
8.1.4 chemical properties
redox reactions
Chapter 8 p241
Chapter 8 p243
Chapter 8
• 8.2 hydrogen
Table 8-2
hydrogen, deuterium, and tritium
Chapter 8
• 8.3 group 1: the alkali metals
8.3.1 the elements
8.3.2 chemical properties
crown ether
Chapter 8 p251
Chapter 8 p253
Chapter 8 p253
Chapter 8
• 8.4 group 2: alkaline earths
8.4.1 the elements
8.4.2 chemical properties
BeCl2 Grignart reagent
Chapter 8
• 8.5 group 13
8.5.1 the elements boron diborane 8.5.2 other chemistry of the group 13 ele
ments inorganic benzene
Chapter 8 p258
Chapter 8 p261
Chapter 8
• 8.6 group 14
8.6.1 the elements
8.6.2 compounds
Chapter 8 p264
Chapter 8 p268
Chapter 8
• 8.7 group 15
8.7.1 the elements
8.7.2 compounds
hydrides
nitrogen oxides and oxyions
Chapter 8 p277
Chapter 8
• 8.8 group 16
8.8.1 the elements
the viscosity of sulfur is due to the tendency of S-S bonds to break and to reform at high temperature
Chapter 8 p283
Chapter 8
• 8.9 group 17
8.9.1 the elements
Table8-14
polyatomic ions
interhalogens
pseudohalogens
Chapter 8
• 8.10 group 18
8.10.1 the elements
8.10.2 chemistry
clathrates
xenon compounds
Chapter 8 p293
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