1 1 coolants tom birch jim halderman. 2 introductions: tom birch retired instructor from yuba...
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11
Coolants
Tom Birch
Jim Halderman
2
Introductions: Tom Birch
• Retired instructor from Yuba College, Marysville, CA.
• Author of many automotive textbooks
• Former officer in CAT and NACAT Board Member
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Jim Halderman
Former flat-rate technician and instructor and a business owner. Author of many automotive books and lives in Dayton, Ohio.http://jameshalderman.com
4
Topics to be Discussed
Engine coolants- Purpose and function Water (1/2 of the coolant)Coolant TypesCooling system testingCooling system service
55
What is Coolant?
Coolant is a mixture of: 1. Water (50%)
2. Anti-Freeze (ethylene glycol-about 93%)
3. Corrosion inhibitors (additives)
Water: 50%
Ethylene Glycol: 47%
Additives: About 3%
Coolant
Need to know
66
Water
Water is the principal ingredient and:
1. Is inexpensive 2. Is a very efficient heat exchange fluid 3. Has excellent thermal conductivity 4. Has a good specific heat 5. Freezes at 32°F (0°C) 6. Boils at 212°F (100°C)The water used in coolant must be clean &
pure.
Need to know
77
Good Water
The American Society for Testing and Materials (ASTM) standards for water quality include:
Chloride <40 ppm Sulfate <100
ppm Calcium <100 ppm Magnesium <100 ppm Total Hardness <170 ppm pH Range: 5.5—9.0 Iron <1 ppm
Nice to know
88
Freeze and Boil
Pure Water 50/50 Anti-Freeze/Water
70/30 Anti-Freeze/Water
Freezing Point
0° C (32° F) -37° C (-35° F) -55° C (-67° F)
Boiling Point 100° C (212° F) 106° C (223° F) 113° C (235° F)
Need to know
9
Ethylene Glycol (EG)
Ethylene glycol is the base antifreeze used in every OEM factory fill. The additive package will vary.
Need to know
10
Propylene Glycol (PG)
• Only sold to the aftermarket
• Not recommended for use by vehicle manufacturers
• More expensive than EG, Increased cost is $/gallon
• Still toxic but is not as sweet as EG
Need to know
11
Embittered Coolant
Embittered = tastes awful
Embittering agent is required (denatonium benzoate, 30 ppm) Required in California and Oregon since 2004 but not included on the label.Need to know
Bittered States
At this time, 7/20/10, 12 states require antifreeze with a bittering agent: dentonium benzoate. They are:
4 states: Illinois, Massachusetts, New Hampshire, and Ohio are working on a similar rule.
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OAT=DEX-COOL is one brand
Nice to know
14
HOAT=Red; Pink; Yellow or Blue
Nice to know
15
Replacement Antifreeze
The best choice is to follow the vehicle manufacturer’s recommendations.
OR, you can follow the recommendations of reliable antifreeze manufacturers (next slide).
Need to know
16
Coolant Summary • Ethylene glycol - Most ethylene glycol coolant is any color and contains about 93% ethylene glycol
plus water and additives.
• Propylene glycol - less harmful to pets and animals because it is not sweet tasting, although it is still harmful if swallowed.
• Organic acid technology (OAT) antifreeze coolant – This type is ethylene glycol based but it does not contain silicates or phosphates. It is usually orange. DEXCOOL is an OAT coolant.
• • Hybrid organic acid technology (HOAT) – This orange, green, red, blue or yellow coolant is an
ethylene glycol based coolant similar to the OAT- type antifreeze as it uses additives (a low amount of silicate)
• VW/Audi pink - Most of these coolants are HOAT (ethylene glycol-based with some silicate and contain an organic acid) and are phosphate free.
• Asian red – This coolant is ethylene glycol-based and is silicate-free, yet contains phosphate.
• Mercedes and Ford yellow – This conventional ethylene glycol coolant has low amounts of silicate and no phosphates.
• Mercedes Lifetime – Very expensive, can be drained, filtered and reused.• Korean or European blue – This conventional ethylene glycol coolant has low amounts of silicate
and no phosphates.
Nice to know
17
pH Tests
pH can be measure using test strips or a meter.
Fairly accurate and costs pennies/test.
Need to know
18
Metal Corrosion
This iron tube has been ruined by rust.
Need to know
19
Diesel Wet Sleeve Cavitation
The sleeve can vibrate during the combustion stroke producing the pressure drop, bubbles, and metal erosion. Heavy duty coolants contain supplemental coolant additives (SCA) to help prevent this.
Need to know
20
Bi-Metal Corrosion
Ions move from more active metals to less active metal through the coolant which acts like the electrolyteNice to know
21
Radiator Voltage
Connect the negative voltmeter lead to a good ground (this radiator has a plastic filler neck), and immerse the positive lead into the coolant. A reading of 0.300 V or greater indicates corrosion is probably occurring.
Need to know
22
Refractometer Image
The image will show the amount of freeze protection and is read at the scale at the bottom edge of the shadow. This unit can check EG and PG antifreeze freeze protection and battery specific gravity.
Shadow
Read Here
Need to know
23
Universal Coolant
• Arctic Blend
• Recycool
•Prestone Prime
coolants that have been formulated to be used in any vehicle
Nice to know
2424
Additives
The major additives:
1. Reduce corrosion
2. Buffer (control) pH
3. Add color (dye)
Need to know
25Need to
know 25
IAT
Inorganic Additive Technology (IAT) is the traditional green coolant used in most older vehicles. This solution offers fast-acting corrosion protection, but the additives are quickly consumed, exposing the cooling system to possible corrosion problems if not changed regularly.
2626
IAT (Usually Green in Color)
Inorganic Additive Technology (IAT) antifreeze can contain:
• Silicates (possible abrasive dropouts)
• Phosphates• Borates
Need to know
IAT is considered obsolete and can cause early failure of ceramic-phenolic seals used in newer water pumps.
2727
OAT (Usually Orange)
The downside of OAT is it is not compatible with other types of coolant (IAT and HOAT). In fact, Ford, Chrysler and others say to not use this type of coolant in their newer models.
Organic Acid Technology (OAT) is the formula found in DEX-COOL®, and is usually the antifreeze/coolant of choice for GM, VW, and many Japanese/Asian vehicles. This formula is engineered to offer long-life corrosion protection.
Need to know
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OAT-continued
NAPS=nitrates, amines, phosphate and silicate free
Nice to know
29
OAT=DEX-COOL is one brand
Nice to know
30
DEX-COOL Concerns
• Root cause= air entering system
• Check cap replace cap
• Air causes ‘Brown Gunk’
• Rust then causes blockages
Need to know
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Rust in Engine
• DEX-COOL + Air= rust orDEX-COOL + core sand = Brown gunk
Need to know
32
GM DEX-COOL Problems
Class action suit; GM may have to pay for intake gaskets on V-6s (V-8s still being determined)
Brown Gunk on radiator cap
Need to know
33
DEX-COOL’s Unique Formulation
• DEX-COOL uses Ethylhexanoic Acid (2-EH) as a corrosive inhibitor
• 2-EH is prone to damage plastics like Nylon 6.6 used in intake manifold gaskets and radiators
• G30 OAT and Peak Global OAT do NOT use 2-EH
Nice to know
3434
HOAT (Many colors)
Hybrid Organic Acid Technology (HOAT) is found in newer Ford, Chrysler and Mercedes vehicles. Said to use the very best aspects of both IAT and OAT, HOAT is a very protective, long-life coolant.
Need to know
35
HOAT=Red; Pink; Yellow or Blue
Nice to know
POAT Coolant
• Phosphated Organic Acid Technology (POAT)
• Dark Green in color• Used in Mazda-based
Fords (2008+)• same as Mazda FL-
22 • $34.95 per gallon
Ford Motor Company & E-OAT
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The E = European, low silicate and phosphate free
•Ford of Europe has validated Dex-Cool and uses it with no problems.
•Ford of U.S. has reengineered all of their new engines (No- Cavitation water pumps and no-silicone rubber or Nylon 66) to work with this formula.
Ford/Mercury Coolant
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The 1999—2001 Cougar used a OAT Dex-Cool clone, but had issues with water pump cavitation.
Pre 1999 99—01 2002 2003 2004
Dex-Cool & OAT that meets GM Spec.
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Prestone markets an OAT antifreeze (Extended Life)
“compatible with ANY antifreeze/ coolant”) that meets the GM Dex-Cool spec.
it is less expensive than Dex-Cool-labeled products because of no-royalty cost.
40
Passivation
• Passivation= is a chemical reaction the takes place between coolant additives and the metal that it protects
• Takes a few days or few weeks • It creates barrier between the metal and corrosion• Each chemical package does its own passivation • if you change chemical packages, passivation has to
start over • It boils down to: DO NOT CHANGE PACKAGES.
Nice to know
41
“G” Designations
• G= Glysantin –trade name of BASF. Valvoline (Zerex) in the US.
• G30, G33, G34= non-silicate and phosphate free (DEX-COOL replacement)
• G05 = Phosphate free-low silicates (Asian formula and Chrysler HOAT)
Nice to know
42
“G” Designations-continued
• G11=Blue VW used before 1997
• G12=Pink/Red VW 1997+
• G12=Purple VW 2003+
• HOAT formulation; phosphate free
?
43
“G” Designations-continued
• G48=Low Silicate and Phosphate free
• Blue Color
• NAP =nitrates, amines, phosphate free
• BMW
?
44
Replacement Antifreeze
The best choice is to follow the vehicle manufacturer’s recommendations.
OR, you can follow the recommendations of reliable antifreeze manufacturers (next slide).
Need to know
4545
Color
The color helps us identify a coolant leak. It also helps us identify the additive package.
Should not be used as an indicator what to use-some Chrysler vehicles used HOAT coolant that was green
Need to know
46
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Coolant Summary • Ethylene glycol - Most ethylene glycol coolant is any color and contains about 93% ethylene glycol
plus water and additives.
• Propylene glycol - less harmful to pets and animals because it is not sweet tasting, although it is still harmful if swallowed.
• Organic acid technology (OAT) antifreeze coolant – This type is ethylene glycol based but it does not contain silicates or phosphates. It is usually orange. DEXCOOL is an OAT coolant.
• • Hybrid organic acid technology (HOAT) – This orange, green, red, blue or yellow coolant is an
ethylene glycol based coolant similar to the OAT- type antifreeze as it uses additives (a low amount of silicate)
• VW/Audi pink - Most of these coolants are HOAT (ethylene glycol-based with some silicate and contain an organic acid) and are phosphate free.
• Asian red – This coolant is ethylene glycol-based and is silicate-free, yet contains phosphate.
• Mercedes and Ford yellow – This conventional ethylene glycol coolant has low amounts of silicate and no phosphates.
• Mercedes Lifetime – Very expensive, can be drained, filtered and reused.• Korean or European blue – This conventional ethylene glycol coolant has low amounts of silicate
and no phosphates.
Nice to know
48
Depletion Rate of Additives
Need to know
4949
pH
Substance pH
Hydrochloric acid -1.0
Battery acid 0.5
Lemon juice 2.4
Cola 2.5
Vinegar 2.9
Orange or Apple juice 3.5
Acid Rain <5.0
Tea or healthy skin 5.5
Milk 6.5
Pure water 7.0
Healthy human saliva 6.5 – 7.4
Blood 7.34 – 7.45
Sea water 7.7 – 8.3
Hand soap 9.0 – 10.0
Household ammonia 11.5
Bleach 12.5
Household lye 13.5
Caustic Soda 13.9
pH is a measure of acidity or alkalinity of a solution. Less than 7 is considered acidic. Greater than 7 is considered alkaline.
Alkaline
Acid
Nice to know
5050
pH Effects
Fresh antifreeze pH= 9 and 11
Used coolant pH= 7.5 and 10
It can also increase electrolysis
( the dissimilar metals in contact with an electrolyte can produce a simple battery)
Need to know
51
pH of various coolants
• IAT= 9.0-10.5 new
• OAT= 7.5-8.5 new (G30 and G34 designation)
• HOAT= 7.5-8.5 new (G05,G48,G11 or G12 designation)
Need to know
52
Desired pH
Need to know
53
pH Tests
pH can be measure using test strips or a meter.
Fairly accurate and costs pennies/test.
Need to know
54
pH Meter
This Milwaukee is probably more accurate and cost $30.00.
Need to know
5555
Corrosion
Corrosion is the “decomposition of metal”
(called rust or aluminum oxide, the whitish material that forms on aluminum components)
Oxide formation:
1. eats away at the parent material from the outside
2. forms an insulating barrier for heat transfer
Need to know
56
Metal Corrosion
This iron tube has been ruined by rust.
Need to know
5757
Corrosion
aluminum oxide, often found on coolant outlet/stat cover
Need to know
58
Corroded Water Pump
One of the reasons for the removal of silicates from coolant
Need to know
59
Corroded pump can cause:
• reduced coolant flowand an overheating
condition
Need to know
6060
Cavitation
Cavitation is the sudden formation and collapse of low-pressure bubbles. With gasoline engines, the pressure drop can occur at the inlet of the water pump. These bubbles produce a pitting of the solid metal .
Cavitation
Need to know
61
Cavitation Damage
The very low pressure can produce gas bubbles that implode next to a metal surface. The implosion blasts particles from the surface.
Need to know
62
Diesel Wet Sleeve Cavitation
The sleeve can vibrate during the combustion stroke producing the pressure drop, bubbles, and metal erosion. Heavy duty coolants contain supplemental coolant additives (SCA) to help prevent this.
Need to know
63
Galvanic action
• Galvanic activity does not require an outside source of voltage
• The higher the conductivity of the coolant, the greater the amount of corrosion
Need to know
64
Metals
Nice to know
65
Bi-Metal Corrosion
Ions move from more active metals to less active metal through the coolant which acts like the electrolyteNice to know
6666
Electrolysis
Electrolysis requires the use of an outside voltage source.
•When electrical ions move from metal to the coolant, they can take metal atoms with them
• This metal transfer can eat holes in a heater core or radiator.
•Electrolysis holes will usually start from the inside and have a dark coloration. Need to know
67
Testing Coolant with a Voltmeter
• This test gives variable and questionable results depending on many factors
• Galvanic=less than 200 mV
• Electrolysis= (engine running and accessories switched on and off)=less than 300 mV. This check can locate faulty ground connections
Need to know
68
Radiator Voltage
Connect the negative voltmeter lead to a good ground (this radiator has a plastic filler neck), and immerse the positive lead into the coolant. A reading of 0.300 V or greater indicates corrosion is probably occurring.
Need to know
69
Coolant Condition
This “green” antifreeze has a clean, bright appearance. The other types will have a different color but should also appear clean and bright.
A muddy brown or rust-reddish color indicates that corrosion is occurring.
Need to know
70
Freeze Protection, Refractometer
A few drops of coolant are placed under the sample window. The technician then holds the unit up to light and looks through the eye piece (right end).
Sample Window
Eye Piece
Need to know
71
Refractometer Image
The image will show the amount of freeze protection and is read at the scale at the bottom edge of the shadow. This unit can check EG and PG antifreeze freeze protection and battery specific gravity.
Shadow
Read Here
Need to know
7272
Freeze Protection, Test Strips
Test strips will change color when they are dipped into the coolant, and the color change is compared to the container.
Test strips are fairly accurate, easy to use, and inexpensive.
Need to know
73
Coolant Corrosion Protection
The new test strip color is compared to the color pads on the container to determine the amount of freeze protection and corrosion protection.
Need to know
74
Coolant Replacement
1. 15 to 20% remains in the system after it has been drained
2. Fill system with antifreeze first and top off with water
3. Be sure to use the specified coolant
(GM warns not to reuse coolant drained from the system)
(Mercedes has a lifetime coolant, drain, filter, & reuse)
Need to know
75
Coolant Replacement-#2
• Check the pressure cap and radiator for faults• Check all hoses and always use coolant hose
Need to know
76
Universal Coolant • Universal Gold =HOAT, extended life, low-
silicate, phosphate-free antifreeze/coolant.
• This product meets Ford WSS M97B51-A1 and Chrysler MS 9769 and other "global antifreeze" type specifications, as well as ASTM D3306, D4985 and D6210/11
Nice to know
77
Universal Coolant
• Arctic Blend
• Recycool
•Prestone Prime
coolants that have been formulated to be used in any vehicle
Nice to know
78
Coolant Recovery and Storage
Some shops recycle used antifreeze
Should be stored until picked up for recycling
Notice double containers to help avoid spills
Need to know
79
Flushing a Dirty System
1. Drain system 2. Fill system with clean water & chemical 3. Run system to operating temp. (Heater on) 4. Drain system & fill with clean water 5. Repeat until drain water runs clear Any remaining flush agent will upset pH. 6. Fill system with 50/50 antifreeze/water mix 7. Run system to operating temp. (Heater on) 8. Adjust coolant level
Need to know
Caution: If flushing a really dirty system, be prepared to repair some leaks.
80
Flushing
Some communities permit draining into sewer. EG and PG will biodegrade. There is a problem however if coolant is spilled on open ground.
Need to know
81
Be sure to clean the overflow/surge tank
It should empty if you start draining with the cap in place.
Need to know
82
Mix Coolant 50/50 or use premix
?
83
Coolant Exchange Machine
Most shops use machines like this.
Coolant drains have become fragile and hard to find.
Need to know
TECH TIP
• Check the freezing Point after service
• Should be -34 degrees F (proper 50/50 mix)
• If higher (i.e. -20 F) this means that there is too much water.
• If lower (i.e. -40 F) this means that there is too much antifreeze
85
Always check or replace the radiator pressure cap
The cap can be located on
1. the radiator
2. The coolant recovery reservoir
3. The upper radiator hose
Note the pressure.
Need to know
86
Cap has two seals
What will happen if the upper seal fails? What will happen if the lower seal fails?
Upper Seal
Filler Neck
Lower Seal
To CRR
Need to know
87
Never open when hot!
What can happen if the cap is removed from a hot system?
Need to know
1 psi will increase the coolant boiling point 2.7oF. A 15 lb. Cap will increase the BP 40.5oF.
88
Proper Fill
All of the air must be removed from the cooling system by one of these methods:
• Bleeder screw: lets air escape• Air Lift: evacuates system before fill• Spill-Free Funnel: Lisle #22150• Fluid Exchange: requires special equipment
Need to know
89
Bleeder Valves
• Use a clear hose attached to the bleeder valve and the other end in a “suitable” container
• Prevents coolant from getting on the engine and gives the technician a visual clue as to color of coolant
Need to know
90
Leak Detection
A good system holds pressure
Tracer dye and some antifreezes glow under UV light
Need to know
91
What should Technician's do?
• Check service information for the designated coolant and replacement interval
• Check the coolant appearance and level at every service
• Check the pressure cap appearance at every service• Check the appearance and pH for signs that the
coolant should be replaced before the regular service interval
• Check Freeze Point, pH, and Galvanic/Electrolysis
Need to know
92
Typical Questions/Answers
1. Are all green antifreezes the same?A. No-Chrysler used HOAT coolant that was green like IAT coolant
2. Can DEX-COOL be replaced with conventional green coolant?A. Yes, but then the coolant has be replaced every 24 months or 24,000 miles
93
Questions/Answers
3. Can coolants be mixed?A. No
4. Is DEX-COOL propylene glycol ?A. No. DEX-COOL and all other coolants are ethylene glycol except one labeled propylene glycol and is never used from the factory
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Summary
• Not all coolants are the same• Not all tap water is OK to use• Premixed coolant usually produces good
results• Check the coolant freezing/boiling point• Check the coolant pH • Always check or replace the pressure cap,
especially on DEX-COOL vehicles
95
Resource materials
96
Contact Information
Tom Birchhttp://tombirch.com
Jim Halderman- jim@jameshalderman.com
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