ferries - mhisafety msds book 2015...safety data sheet (sds) date prepared/revised: 1/9/2015 version...
Post on 21-Feb-2021
2 Views
Preview:
TRANSCRIPT
Ferries
2015 MSDS Collection
Ferry Crew Index 2015
Manufacturer Product Name Revision Date
Aervoe Industries Aervoe 860 Glass & Surface Cleaner – Aerosol
January 09, 2015
Amteco Inc. White Zero Rust Aerosol March 01, 2014 Boss Lubricants. Hi-Performance Synthetic
Engine Oil 10W-30 August 28, 2012
Calument Lubricants Co. Calumet Lantern Fuel February 28, 2014
Chatterson Janitoria C-THRU Liquid Glass Cleaner
February 03, 2014
Co-op Refineries D-MO November 13, 2012
Co-op Refineries Diesel Distillate December 18, 2012 Co-op Refineries HD7 October 02, 2012
Co-op Refineries Industrial Hydraulic Oil July 31, 2012 Co-op Refineries Sonic 2 Cycle Oil January 08, 2015
Co-op Refineries Sonic ATF August 22, 2012
Co-op Refineries Sonic Blue Guard May 20, 2014 Co-op Refineries Sonic Industrial Gear Oil May 20, 2014
Co-op Refineries Trans Hydraulic Fluid January 08, 2015 Degil Safety Products
Canada Croc Bloc Heavy Duty
Insect Repellent Aerosol January 29, 2015
Degil Safety Products Canada
Croc Bloc Insect Repellent Foam
January 29, 2015
Degil Safety Products Canada
Croc Bloc SPF30 Spray Lotion
January 29, 2015
Dow Corning Corp. Do Coming 732 Multi- Purpose Sealant-Clear
April 05, 2013
Energizer Battery Manufacturing Inc.
Eveready Energizer Battery
January 01, 2014
Ferrellgas Propane November 01, 2014
General Paint Corp 70-052R Breeze Exterior October 03, 2012
Gojo Industries Purell Instant Hand Sanitizer
April 29, 2013
Grime Eater (Tm) Gel With Pumice Hand Cleanser
January 01, 2014
Gunk. hydraulic jack oil J132C July 11, 2013
Henkel USA Corp Loctite 592 Thread August 29, 2014
Sealant.
Imperial Oil Products Hydraul 56 August 28, 2014
Imperial Oil Products Middle Distillate November 26, 2014
Imperial Oil Products Unirex EP 0 November 10, 2014
Imperial Oil Products Unirex EP 2 November 29, 2012 Imperial Oil Products Unleaded Gasoline February 23, 2015
Imperial Oil Products Block Grease S-100 September 10, 2012
Imperial Oil Products Commercial Propane June 07, 2013
Jelmar. CLR – Calcium Lime & Rust
October 01, 2012
KIK Custom Products. Glass Cleaner October 07, 2014
Kleen-Flo Tumbler Industries Ltd.
Silicone Gasket Maker (Clear) (472)
January 02, 2015
Kleen-Flo Tumbler Industries Ltd.
ACE Starting Fluid (735) January 02, 2015
Kleen-Flo Tumbler Industries Ltd.
Brake & Parts Kleen (313) January 02, 2015
Kleen-Flo Tumbler Industries Ltd.
Dot 3 Super Heavy Duty Brake Fluid 525 -527-528-
529-530
January 02, 2015
Kleen-Flo Tumbler Industries Ltd.
Kleen-Start Starting Fluid (730)
January 02, 2015
Lawson Products Inc. Moly Coat May 01, 2013
Nemco Resources Ltd. SR-1 Antifreeze and Coolant
October 01, 2013
NeoChem Enercon Water treatment Ltd. ChemTronic
March 01, 2013
Oatey Co All-purpose cement September 12, 2012
Permatex Canada Inc. PC Fast Orange lotion with Pumice 443 ml
March 31, 2015
Permatex Inc. Fast Orange Pumice Lotion
May 17, 2013
Permatex Inc. Fast Orange Smooth Lotion.
May 16, 2013
Permatex Inc. Spray Nine. March 25, 2014
Radiator Speciality Co. Motor Flush July 18, 2013
Rechochem Inc Universal Gas Line Antifreeze
April 02, 2013
Rechochem Inc 60-40 Premixed Universal Antifreeze Coolant
May 01, 2013
Rechochem Inc Paint Thinner November 24, 2014
Rechochem Inc Solvent November 24, 2014
Rust Check Corp. Rust Inhibitor Aerosol (1043)
April 10, 2015
Rust-Oleum Corp. Enamel 1-Gl 2Pk Flat White
August 14, 2014
Rust-Oleum Corp. Enamel 1-Gl 2Pk High Gloss White
August 15, 2014
Rust-Oleum Corp. Enamel 1-Gl 2Pk Semigl White SemiGloss
September 17, 2014
Rust-Oleum Corp. Enamel 5-Gl High Gloss Black
August 13, 2014
Rust-Oleum Corp Enamel Qt 4Pk Gloss White
August 07, 2012
Rust-Oleum Corp Enamel Qt 4Pk Gloss Safety Orange
August 07, 2012
Rust-Oleum Corp. Enamel 5-Gl High Gloss White
August 14, 2014
S.C. Johnson and Son OFF! Deep Woods 3 Insect Repellent
September 14, 2012
S.C. Johnson and Son Raid Max Wasp & Hornet Foam Bug Killer
November 21, 2014
S.C. Johnson and Son Windex December 05, 2012
Merck Consumer Care Products Canada
Muskol Aerosol, 23.5% DEET
March 11, 2014
Texas Refinery Corp Power Cleanse November 15, 2013
The Procter & Gamble Co. Mr. Clean Antibacterial Multi-Surfaces
Disinfectant Multi-Surfaces Liquid
March 11, 2013
Univar Canad Ltd. Sulphuric Acid 98% January 13, 2014
WD-40 Products Ltd. WD-40 Aerosol March 27, 2014
ZEP Inc. Reach NPE Free February 12, 2014
Discontinued or Out of Date
Manufacturer Product Name Last Revision Date
Boss Lubricants Hi-Performance Synthetic Engine Oil 10W-30
January 01, 2012
Co-op Refineries Ltd. Gasoline – Ethanol Blended
July 19, 2012
Co-op Refineries Ltd.
Kerosene July 07, 2012
Co-op Refineries Ltd. Solvent July 12, 2012
Esso Imperial Oil Products Gear Oil GX Extra 75W-90 April 01, 2009 General Paint Corp. 06-134 Q.D. Shop Primer
– Red February 27, 2012
General Paint Corp 06-154 Anti- Corrosive Primer-Red
February 27, 2012
General Paint Corp 10-010 Marine Enamel – White
June 17, 2010
General Paint Corp 10-122 Marine Rust - White
June 17, 2010
General Paint Corp 10-134 Marine Rust Mild Blue
October 06, 2010
General Paint Corp 11-890 Low Sheen Non-slip En. Q.D.Grey
June 17, 2010
General Paint Corp 32-001 Exterior Allkyd Primer
June 17, 2010
Imperial Oil Products. Heavy Duty Antifreeze 60-40
May 18, 2012
Imperial Oil Products. XD-3 Extra Engine Oil 10W-30
May 03, 2011
Kemsol Products Ltd. San-I-Can Porcelain Cleaner
June 01, 2012
Momentive Performance Silicone Moldmaking Material
June 13, 2008
Permatex Canada Inc. PC Fast Orange Pumice Cream 400GR
October 28, 2010
R.B. Howes & Co. Inc. Howes Lubricator Diesel Treat
July 05, 2012
Rust oleum Corp. Enamel 5-GL Flat Black April 02, 2012
S.C. Johnson and Son OFF! Deep Woods Pump Spray Insect Repellent 4
June 08, 2012
Safety Data Sheet (SDS) Date Prepared/Revised: 1/9/2015 Version no.: 01 Supersedes: (-) Product identifier: Aervoe Glass & Surface Cleaner - Aerosol Product name: 860 Glass & Surface Cleaner Relevant identified uses of the substance: Use to clean all glass and baked enamel objects, auto windshields, porcelain,vinyl, Plexiglas, laminated surfaces, chrome, stainless steel, tile, and bumpers. Uses advised against: Poorly ventilated areas CAS No: Not Applicable (mixture) EC No: Not Applicable (mixture) Index No: Not Applicable (mixture) Manufacturer/Supplier: Aervoe Industries Incorporated Street address/P.O. Box: 1100 Mark Circle Country ID/Postcode/Place Gardnerville, Nevada 89410 Telephone number: 001 (0) 1-775-782-0100 e-mail: mailbox@aervoe.com National contact: Aervoe industries Incorporated For Product Information: 001 (0) 1-800-227-0196 Emergency telephone number: 001 (0) 1-800-424-9300 (CHEMTREC – 24 hrs) English Language Service
Classifications Physical Hazards: Aerosol - Category 2 Flam. Gas. 1 Press. Gas Flam Liq 2 Health Hazards: Acute Tox 4 Carc. 1B Muta. 1B Eye Irrit. 2 STOT SE 3 Environmental Hazards: N/AV Labeling Signal Word: Danger
1.) Identification of the Mixture and of the Company
2. Hazards identification
Safety Data Sheet (SDS) Date Prepared/Revised: 1/9/2015 Version no.: 01 Supersedes: (-) Hazard Statements: H220 – Extremely flammable gas H223 – Flammable aerosol H225 – Highly flammable liquid and vapour. H229 - Pressurized container: may burst if heated H312 – Harmful in contact with skin. H319 – Causes serious eye irritation. H332 – Harmful if inhaled. H336 – May cause drowsiness or dizziness. H340 – May cause genetic defects H350 – May cause cancer Precautionary Statements: P101 - If medical advice is needed, have product container or label at hand P102 - Keep out of reach of children P103 - Read label before use
P210 - Keep away from heat/sparks/open flames/hot surfaces - no smoking
P211 - Do not spray on an open flame or other ignition source P251 - Pressurized container: Do not pierce or burn, even after use P261 - Avoid breathing dust/fume/gas/mist/vapours/spray P262 - Do not get in eyes, on skin, or on clothing P264 - Wash … thoroughly after handling P280 - Wear protective gloves/eye protection/face protection P303+P361+P353 - If on skin or hair, remove/takeoff immediately all contaminated clothing. Rinse skin with water/shower.
P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50ºC/122ºF
P501 - Dispose of contents/container in accordance with local/regional/national/international regulation
Symbols/Pictograms:
3. Composition / Information on Ingredients
Safety Data Sheet (SDS) Date Prepared/Revised: 1/9/2015 Version no.: 01 Supersedes: (-) Composition Chemical Synonyms CAS Number EINECS
Number Weight Percent
Hazard Category H-Code
Hydrocarbon Propellant
LPG 68476-86-8 270-705-8 1-5% Press. Gas Flam. Gas 1 Carc. 1B Muta. 1B
H220 H350 H340
Isopropanol Isopropyl Alcohol
67-63-0 200-661-7 1-5% Flam. Liq. 2 Eye Irrit. 2 STOT SE 3
H225 H319 H336
2-Butoxyethyl Acetate
Butyl Glycol Acetate
112-07-2 203-933-3 1-5% Acute Tox. 4 * Acute Tox. 4 *
H332 H312
Ethanol Ethyl Alcohol
64-17-5 200-578-6 1-5% Flam. Liq. 2 H225
Other Product Information Chemical Identity: Mixture
General Advice: If symptoms persist, always call a doctor. Inhalation First Aid: Remove victim to fresh air and provide oxygen if breathing is difficult. If not breathing, give artificial respiration, preferably mouth to mouth. Get medical attention immediately. Skin Contact First Aid: Wash with soap and water. Remove contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Eye Contact First Aid: If contact with eyes, immediately flush eyes with plenty of water for at least 15 minutes, while holding eyelids open. Get medical attention immediately. Ingestion First Aid: If swallowed, wash out mouth with water provided the person is conscious. Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately. Most Important Symptoms/Effects: Exposure may cause slight irritation to the skin, eyes, and respiratory tract.
Excessive exposure may cause central nervous system effects.
Flammable Properties: Aerosol Auto Ignition Temperature: Not Available Suitable extinguishing media: Carbon dioxide, dry chemical, water spray. Unsuitable extinguishing media: None known Special hazards arising from the
4.) First Aid Measures
5. Fire Fighting Measures
Safety Data Sheet (SDS) Date Prepared/Revised: 1/9/2015 Version no.: 01 Supersedes: (-) substance or mixture: None known Hazardous combustion products: Carbon dioxide, Carbon monoxide Fire & Explosion Hazards: Closed Containers may rupture due to the buildup of pressure from extreme temperatures. Precautions for fire-fighters: Use water spray to cool containers exposed to heat or fire to prevent pressure build up. In the event of a fire, wear full protective clothing and NIOSH- approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.
PERSONAL PRECAUTIONARY MEASURES: 1) Follow personal protective equipment recommendations found in section 8. 2) Maintain adequate ventilation. SPILL CLEAN-UP PROCEDURES: 1.) Evacuate unprotected personnel from the area. 2.) Remove sources of ignition if safe to do so. 3.) Pickup spilled materials using non-sparking tools and place in an appropriate container for disposal. 4.) Contain spill to prevent material from entering sewage or ground water systems. 5.) Always dispose of waste materials in accordance with all EU, National and Local Regulations.
Handling: Flammable Aerosol, use in a well ventilated area.
Do not use near sources of ignition. Do not to eat, drink and smoke while working with this material. Wash hands after use.
Conditions for safe storage, including any incompatibilities: Store out of direct sunlight. Storage Temperature: 32° to 120°F (0° to 49°C). No known incompatibilities.
Appropriate engineering controls: Ensure adequate ventilation. A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Keep away from sources of ignition. Take precautionary measures against static discharge. Personal Protection: Eye & face protection devices such as safety glasses, safety goggles or face shield are recommended.
6. Accidental Release Measures
7. Handling and Storage
8. Exposure Controls / Personal Protection
Safety Data Sheet (SDS) Date Prepared/Revised: 1/9/2015 Version no.: 01 Supersedes: (-) Skin protection Wear the appropriate protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Respiratory protection: Use only in an adequately ventilated area. For unknown vapor concentrations use a positive-pressure, pressure-demand, self-contained breathing apparatus (SCBA). Hazardous Ingredient CAS
Number ACGIH TLV (TWA)
ACGIH TLV (STEL)
OSHA PEL (TWA)
OSHA PEL (STEL)
Hydrocarbon Propellant 68476-86-8
N/AV N/AV N/AV N/AV
Isopropanol 67-63-0 200ppm 400ppm 400ppm N/AV 2-Butoxyethyl Acetate 112-07-2 20ppm N/AV N/AV N/AV Ethanol 64-17-5 N/AV N/AV N/AV N/AV *Values are based on the 2014 Guide to Occupational Exposure Values by ACGIH
Appearance: Clear Odor: Bouquet Odor Threshold: N/AV pH: Not Applicable (solvent Base) Melting Point: N/AV Freezing Point: N/AV Initial Boiling Point: N/AV Boiling Point Range: N/AV Flash Point: <0° F (-18° C) Evaporation Rate: Slower than n-Butyl
Acetate Flammability Solid/Gas: Flammable gas LEL: N/AV UEL: N/AV Vapor Pressure: N/AV Vapor Density: Heavier Than Air Relative Density: N/AV Solubility: Negligible Partition Coefficient: n-octanol/ water: N/AV
Auto-ignition Temperature: N/AV
Decomposition Temperature: N/AV Viscosity: N/AV Explosive Properties: N/AV Oxidizing Properties: N/AV
Possibility of hazardous reactions: Hazardous polymerization will not occur under normal conditions Chemical stability: Stable under normal conditions Conditions to avoid: Heat and ignition sources Incompatible materials: Strong Oxidizing Agents Hazardous decomposition products: Will not occur
Reports have associated repeated and prolonged overexposure to solvents with permanent brain and
9. Information on Basic Physical and Chemical Properties
10. Stability & Reactivity
11. Toxicological Information
Safety Data Sheet (SDS) Date Prepared/Revised: 1/9/2015 Version no.: 01 Supersedes: (-) nervous system damage. Repeated overexposure can also damage kidneys, lungs, liver, heart and blood Routes of exposure: Eyes, skin, ingestion, and/or inhalation Acute toxicological data: (2-Butoxyethyl Acetate)CD50: 2400mg/kg
(Rat-Oral) (2-Butoxyethyl Acetate) LC50:450ppm,4h (Rat-Oral)
Eye irritation data: N/AV Skin irritation/sensitization/absorption data: N/AV Reproductive toxicity data: N/AV Mutagenicity data: Muta 1B Symptoms associated with physical contact: N/AV Acute/chronic effects from short/long term exposure: Irritating to skin. Prolonged/repeated contact may cause defatting of the skin which can lead to dermatitis. Not expected to be a skin sensitizer. Known reportable carcinogens via the following agencies: NTP: N/AV IARC: N/AV OSHA: N/AV * Petroleum distillates may contain chemical carcinogens in limited quantities (< 0.01%). These quantities are determined by the supplier/fraction/purity of the distillate during the manufacturing process. Chemicals that may be present within distillates are listed on California’s prop 65 list such as ETHYLBENZENE, BENZENE, and TOLUENE.
Ecotoxicity: No Data Available Persistence and degradability: No Data Available Bioaccumulative potential: No Data Available Mobility in soil: No Data Available Results of PBT and vPvB assessment: No Data Available Other adverse effects: No Data Available
12. Ecological Information
Safety Data Sheet (SDS) Date Prepared/Revised: 1/9/2015 Version no.: 01 Supersedes: (-)
Waste Disposal: Dispose of material in accordance with EU, national and local requirements. For proper disposal of used material, an assessment must be completed to determine the proper and permissible waste management options permitted under applicable rules, regulations and/or laws governing your location. Product / Packaging disposal: Dispose of packaging in accordance with federal, state and local requirements, regulations and/or laws governing your location.
US DOT UN Number
Proper Shipping Name Hazard Class
Packing Group
Marine Pollutant
Special Provisions
UN1950 Aerosols 2.1 Not Applicable
Not Applicable
Reference 49 CFR 172.101
IMDG UN Number
Proper Shipping Name Hazard Class
Packing Group
Marine Pollutant
Special Provisions
UN1950 Aerosols 2.1 Not Applicable
Not Applicable
Reference IMDG code part 3
IATA: UN Number
Proper Shipping Name Hazard Class
Packing Group
Marine Pollutant
Special Provisions
UN1950 Aerosols, Flammable 2.1 Not Applicable
Not Applicable
Reference IATA Dangerous Goods Regulation
Workplace classification: This product is considered hazardous under the OSHA Hazard Communication Standard (29 CFR 1910.1200). The Occupational Safety and Health Administration's interpretation of the product's hazard to workers. SARA Title 3: Section 311/312 Categorizations (40 CFR 372): This product is a hazardous chemical under 29 CFR 1910.1200, and is categorized as an immediate and delayed health, and flammability physical hazard. Superfund Amendment and Reauthorization Act (SARA) category. SARA requires reporting any spill of any hazardous substance. TSCA status: All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory.
13. Disposal Considerations
14. Transportation Information
15. Regulatory Information
Safety Data Sheet (SDS) Date Prepared/Revised: 1/9/2015 Version no.: 01 Supersedes: (-) WHMIS: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the (M)SDS contains all of the information required by the CPR. PROP 65 (CA): WARNING: This product may contain chemicals know to the state of California to cause cancer, birth defects or other reproductive harm.
This SDS has been completed in accordance with GHS Rev04 (2011): U.S OSHA, CMA, ANSI, Canadian WHMIS standards, and European Directives. Date of Preparation/Revision 1/9/2015 Supersedes: (-) To the best of our knowledge, the information contained herein is believed to be accurate. However, the above data does not imply any guarantee or warranty of any kind, expressed or implied. The final determination of the suitability of any material is the sole responsibility of the user. All materials made present un-known hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee these are the only hazards existing.
16. Other Information
M A T E R I A L S A F E T Y D A T A S H E E T
Page: 1 Date Printed: 1/3/2014
Product Code: Product Name:
24-hour Emergency Phone:
HMIS RATING: H-2 F-4 R-0
WHITE ZERO RUST AEROSOL 67SP
Manufacture : AMTECO, INC., P.O. BOX 9, 1100 JEFFERSON ST, PACIFIC, MO. 63069
1-800-424-9300
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
(See top of page)
2. COMPOSITION/INFORMATION ON INGREDIENTS
3. HAZARDS IDENTIFICATION
This product is classified as hazardous under OSHA regulations. FLAMMABLE
liquid and vapor. Harmful if inhaled. Overexposure may cause nervous system
effects. Harmful or fatal if swallowed. Can cause eye and skin irritation.
Causes respiratory tract irritation. May cause serious heart rhythm
disturbances.
ROUTES OF EXPOSURE: Exposure may be by INHALATION and/or SKIN or EYE contact,
depending on conditions of use. To minimize exposure, follow recommendations for
proper use, ventilation, and personal protective equipment.
EFFECTS OF OVEREXPOSURE: Irritation of eyes, skin and upper respiratory system.
May cause nervous system depression. Extreme overexposure may result in
unconsciousness and possibly death. SIGNS AND SYMPTOMS OF OVEREXPOSURE:
Headache, dizziness, nausea, and loss of coordination are indications of
excessive exposure to vapors or spray mists. Redness and itching or burning
sensation may indicate eye or excessive skin exposure.
AGGRAVATED MEDICAL CONDITION:
The following diseases or disorders may be aggravated by exposure to this
product: Skin, Eye, Liver, Kidney, Nervous system, Respiratory system, Lung
(asthma-like conditions).
REPRODUCTION INFORMATION: This material (or a component) may be harmful to
the human fetus based on positive results with laboratory animal.
CARCINOGENICITY: This product could contain trace amounts of ethyl benzene,
which has been shown to cause cancer in lab animals by inhalation and is
listed as a suspect carcinogen by IARC.
CAS No. Ingredient Wt% MAX ACGIH TLV <STEL> OSHA PEL <STEL> Vapor Pressure (mm
Hg 20C)
74-98-6 Propane 16 2500 ppm 1000 ppm 760
106-97-8 Butane 7 800 ppm 800 ppm 760
75-28-5 Isobutane 5 NE NE 760
108-88-3 Toluene 9 50 ppm 100 ppm <150 ppm> 22
67-64-1 Acetone 22 500 ppm <750 ppm> 1000 ppm 180
108-65-6 PM Acetate 4 NE NE 3.8 @ 77F
64742-95-6
Solvent Naptha Light Aromatic 5 200 ppm 200 ppm 4.8@ 100F
123-86-4 n-Butyl Acetate 3 150 ppm <200 ppm> 150 ppm <200 ppm> 8.4
107-87-9 Methyl Propyl Ketone 3 200 ppm 200 ppm 26.9
M A T E R I A L S A F E T Y D A T A S H E E T
Page: 2 Date Printed: 1/3/2014
Product Code: Product Name:
24-hour Emergency Phone:
WHITE ZERO RUST AEROSOL 67SP
Manufacture : AMTECO, INC., P.O. BOX 9, 1100 JEFFERSON ST, PACIFIC, MO. 63069 1-800-424-9300
4. FIRST AID MEASURES
EYES: Move individual away from exposure and into fresh air. Flush eyes
gently with water for 15 minutes while holding eyelids apart. If symptoms
persist or there is any visual difficulty, seek medical attention immediately.
SKIN: Remove contaminated clothing. Rinse exposed areas with large amounts
of water. If skin is damaged or symptoms persist, seek medical attention.
Launder clothing before reuse.
INGESTION: Seek medical attention immediately! Never give anything by mouth to
a drowsy or unconscious person. Do not induce vomiting. If possible, do not
leave individual unattended.
INHALATION: Immediately move individual away from exposure and into fresh air.
Seek immediate medical attention. Keep person warm and quiet. If not
breathing, begin artificial respiration. If breathing is difficult,
administer oxygen.
NOTE TO PHYSICIANS: Inhalation of high concentrations could occur in enclosed
spaces or during deliberate abuse could cause cardiac arrhythmias. This
material is an aspiration hazard.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES: FLASH POINT: <0 F Method: TCC Tag Closed Cup
FLAMMABLE LIMITS: ND Upper ND
HAZARDOUS COMBUSTION PRODUCTS: Formation of toxic gases is possible during
heating or in case of fire.
EXTINGUISHING MEDIA: Foam, Carbon Dioxide (CO2), Dry Chemical, Sand
FIREFIGHTING INSTRUCTIONS: Wear self contained breathing apparatus.
Containers may explode if heated above 120F. Water may be used to keep
containers cool. During emergency conditions overexposure to decomposition
products may cause a health hazard.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS: Eliminate all ignition sources (flares, flames including
pilot lights, electrical sparks). Person not wearing protective equipment
should be excluded from area of spill until clean-up has been completed. Stop
spill at the source. Prevent from entering drains, sewers, streams or other
bodies of water. Prevent from spreading. If runoff occurs, notify authorities
as required. Remove with inert absorbent. Use only non sparking tools for
clean up.
7. HANDLING AND STORAGE
HANDLING AND STORAGE: Keep out of reach of children. Keep away from heat,
sparks and flames. Vapors will accumulate readily and may ignite explosively.
During use and until all vapors are gone – Keep area well ventilated – Do Not
Smoke – Extinguish all flames, pilot lights and heaters – Turn off stoves,
electrical tools and appliances, and any other source of ignition. Consult
NFPA Code. Use approved bonding and grounding procedures.
M A T E R I A L S A F E T Y D A T A S H E E T
Page: 3 Date Printed: 1/3/2014
Product Code: Product Name:
24-hour Emergency Phone:
WHITE ZERO RUST AEROSOL 67SP
Manufacture: AMTECO, INC., P.O. BOX 9, 1100 JEFFERSON ST, PACIFIC, MO. 63069 1-800-424-9300
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
GENERAL ADVICE: These recommendations provide general guidance for handling
this product. Personal protective equipment should be selected for
individual applications and should consider factors which affect exposure
potential, such as handling practices, chemical concentrations and
ventilation. It is ultimately the responsibility of the applicator to follow
regulatory guidelines established by local authorities.
ENGINEERING CONTROLS: Local exhaust preferable. General exhaust acceptable if
the exposure to materials in Section 2 is maintained below applicable exposure
limits.
RESPIRATORY PROTECTION: If personal exposure cannot be controlled to below
applicable limits by ventilation, war a properly fitter organic
vapor/particulate respirator approved by NIOSH/MSHA for protection against
materials in Section 2. When sanding or abrading the dried film, wear a
dust/mist respirator approved by NIOSH/MSHA for dust that may be generated by
this product, underlying paint or adhesive.
SKIN PROTECTION AND BODY PROTECTION: Wear impermeable chemical resistant
gloves such as neoprene coated gloves to prevent repeated or prolonged skin
contact. Liquid may penetrate clothes, shoes and leather causing delayed
irritation. Remove immediately if product gets insides. Then wash thoroughly
with soap and water and put on clean clothing or shoes. User should remove
personnel protective equipment immediately after handling this product. Wash
the outside the outside of gloves before removing.
EYE PROTECTION: Use safety eye ware with side-shields to protect against
chemical splash of liquids and spray mist.
WORK/HYGIENIC PRACTICES: Wash hands before and after eating, smoking and using
the bathroom.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: LIQUID/GAS VAPOR DENSITY: HEAVIER THAN AIR SOLUBILITY IN WATER: INSOLUBLE SPECIFIC GRAVITY: 0.757 EVAPORATION RATE: SLOWER THAN ETHER ODOR: STRONG SOLVENT ODOR
Contents under pressure. Do not puncture, incinerate or expose to
temperatures above 120F. Heat from sunlight, radiators, stoves, hot water
and other heat sources could cause containers to burst. Do not take
internally. Category – NFPA 30B Level 2 Aerosol
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY (CONDITIONS TO AVOID): STABLE
CONDITIONS TO AVOID: DO NOT EXPOSE TO TEMPERATURES ABOVE 120F
MATERIALS TO AVOID: STRONG ACIDS, OXIDIZING AGENTS HAZARDOUS DECOMPOSITION PRODUCTS: Carbon dioxide, Carbon monoxide, Oxides of
Nitrogen.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
M A T E R I A L S A F E T Y D A T A S H E E T
Page: 4 Date Printed: 1/3/2014
Product Code: Product Name:
24-hour Emergency Phone:
WHITE ZERO RUST AEROSOL 67SP
MANUFACTURE : AMTECO, INC., P.O. BOX 9, 1100 JEFFERSON ST, PACIFIC, MO. 63069 1-800-424-9300
11. TOXICOLOGICAL INFORMATION
CHRONIC/CARCINOGENICITY: This product may contain trace amounts of ethyl
benzene which has been shown to cause cancer in lab animals by inhalation and
is listed as a suspect carcinogen by IARC. Overexposure may cause adverse
effects of the liver, urinary and flood forming systems. Reports have
associated repeated and prolonged overexposure to solvents with permanent
brain and nervous system damage.
12. ECOLOGICAL INFORMATION
ECOLOGY WARNING: Hazardous for water. Do not allow product to reach ground
water, water course or sewage system. Danger to drinking water if even small
quantities leak into the ground.
13. DISPOSAL CONSIDERATIONS
Dispose of according to Federal, State and Local regulations. Must not be
disposed of together with household garbage. Do not allow product to reach
sewage system. Do not incinerate. Depressurize container. Waste from this
product may be hazardous as defined under the Resource Conservation and
Recovery Act (RCRA) 40 CFR 261.
14. TRANSPORT INFORMATION (Not meant to be all inclusive)
DOT GROUND CONSUMER COMMODITY ORM-D
IATA AEROSOLS, FLAMMABLE, UN1950, 2.1
IMDG AEROSOLS, FLAMMABLE, UN1950, 2.1
15. REGULATORY Information(Not meant to be all inclusive - selected regulations
represented) U.S. FEDERAL REGULATIONS:
CERCLA: SARA HAZARD CATEGORY: SECTION 313: *Xylene * Indicates toxic chemical(s) subject to the reporting requirements of
Section 313 of Title III and of 40 CFR 372.
16. DISCLAIMER
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, AMTECO DOES NOT ASSUME ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR
COMPLETENESS OF THE INFORMATION CONTAINED HEREIN. FINAL DETERMINATION OF THE
SUITABILITY OF ANY MATERIAL IS THE SOLE RESPONSIBILITY O THE USER.
1 | P a g e
MATERIAL SAFETY DATA SHEET
*** SECTION 1: PRODUCT AND COMPANY IDENTIFICATION ***
PRODUCT NAME: BOSS HI-PERFORMANCE 5000 ENGINE OIL
Includes Grades 5W-20, 5W-30, 10W-30, 10W-40, 20W-50
SYNONYMS:
Petroleum oil; Lube oil; Petroleum hydrocarbon; Lubricant.
PRODUCT CODE:
Prefix 21
PRODUCT USE: For lubricating passenger car motors.
If these products are used in combination with other products, refer to the Material Safety Data
Sheet for those products.
SUPPLIER: BOSS Lubricants
6303 30 Street SE
Suite 112
Calgary, AB T2C 1R4
1-800-844-9457
www.bosslubricants.com
TECHNICAL INFORMATION: 1-800-844-9457
ISSUE: August 28, 2012
ORIGINAL ISSUE: October 31, 1998 SUPERSEDES: November 1, 2010
*** SECTION 2: HAZARDS IDENTIFICATION ***
EMERGENCY OVERVIEW
APPEARANCE
Liquid, amber, petroleum odor.
CAUTION!
HEALTH HAZARDS
May irritate eyes and skin.
May be harmful if swallowed.
2 | P a g e
OSHA Regulated Chemicals
No information is available.
POTENTIAL HEALTH EFFECTS
INHALATION
(BREATHING):
EYES:
SKIN:
These products are not likely to present an inhalation hazard at normal temperatures and pressures.
However, when aerosolizing, misting, or heating these products, high concentrations of generated vapor
or mist may irritate the respiratory tract (nose, throat, and lungs).
May cause irritation.
May cause irritation. Not likely to be absorbed through the skin in harmful amounts.
INGESTION
(SWALLOWING):
May be harmful if swallowed. May cause throat irritation, nausea, vomiting, and diarrhea.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Individuals with pre-existing respiratory tract (nose,
throat, and lungs), eye, and/or skin disorders may have increased susceptibility to the effects of exposure.
CHRONIC: Prolonged or repeated inhalation of oil mist may cause oil pneumonia, lung tissue inflammation,
and/or fibrous tissue formation. Prolonged or repeated eye contact may cause inflammation of the
membrane lining the eyelids and covering the eyeball (conjunctivitis). Prolonged or repeated skin
contact may cause drying, cracking, redness, itching, and/or swelling (dermatitis).
CANCER
INFORMATION:
No known carcinogenicity. For more information, see SECTION 11: CARCINOGENICITY.
Also see SECTION 15: CALIFORNIA.
POTENTIAL ENVIRONMENTAL EFFECTS
Not available. Also see SECTION 12: ECOLOGICAL INFORMATION.
*** SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS ***
AS # Component Synonym Wt. Percent*
64742-58-1 Lubricating oils, petroleum,
hydrotreated spent
Hydrotreated paraffinic base oil 56-85
Trade Secret Mineral oil Trade Secret 0-35
64742-01-4 Residual oils (petroleum), solvent Bright Stock 0-25
Mixture** Base oil, mixture Not Available 0-25
64742-62-7 Residual oils (petroleum), solvent
dewaxed
Bright Stock 0-25
72623-83-7 Lubricating oils, (petroleum), C>25,
hydrotreated bright stock
Bright Stock 0-25
3 | P a g e
72623-86-0 Neutral oil Not Available 0-25
Trade Secret Acrylic copolymer Not Available 0-25
64742-54-7 Petroleum distillates, heavy paraffinic,
C20-C50
Not Available 0-25
64742-55-8 Petroleum distillates, light paraffinic,
C15-C30
Not Available 0-25
68649-42-3 Phosphorodithioic acid, O,O-di-C114-
alkyl esters, zinc salts
Dialkyl (C1-C14) dithiophosphoric acid,
zinc salt
0-6
Component Related Regulatory Information This product may be regulated, have exposure limits or other information identified as the following: Oil mist, mineral (8012-95-1). *Even though
the concentration range does not fall under the ranges prescribed by WHMIS, this is the actual range which varies with each batch of the product. **The base oil may be a mixture of the following CAS#s: 8042-47-5, 64742-46-7, 64742-47-8, 64742-52-5, 64742-54-7, 72623-84-8, 72623-85-9,
72623-86-0, 72623-87-1, 178603-64-0, 178603-66-2, 17603-65-1, and 445411-73-4
*** SECTION 4: FIRST AID MEASURES ***
INHALATION
(BREATHING):
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Oxygen should only be administered by qualified personnel. Someone should stay with
victim. Get medical attention if breathing difficulty persists.
EYES: If irritation or redness from exposure to vapor develops, move away from exposure into fresh air.
Upon contact, immediately flush eyes with plenty of lukewarm water, holding eyelids apart, for 15
minutes. Get medical attention.
SKIN: Remove affected clothing and shoes. Wash skin thoroughly with soap and water. Get medical
attention if irritation or pain develops or persists. If product is injected under pressure into or
under the skin, or into any part of the body, regardless of the appearance of the wound or its size, a
physician should immediately evaluate the individual as a medical emergency.
INGESTION
(SWALLOWING):
Do NOT induce vomiting. Immediately get medical attention. Call 1-800-844-9457 for additional
information. If spontaneous vomiting occurs, keep head below hips to avoid breathing the product
into the lungs. Never give anything by mouth to an unconscious person.
NOTE TO
PHYSICIANS:
Treat symptomatically and supportively. Treatment may vary with condition of victim and
specifics of incident. Call 1-800-844-9457 for additional information.
4 | P a g e
*** SECTION 5: FIRE FIGHTING MEASURES ***
*** SECTION 6: ACCIDENTAL RELEASE MEASURES ***
Remove all ignition sources. Do not touch or walk through spilled product. Stop leak if you can do it without risk. Wear
protective equipment and provide engineering controls as specified in SECTION 8: EXPOSURE
CONTROLS/PERSONAL PROTECTION. Isolate hazard area. Keep unnecessary and unprotected personnel from entering.
Ventilate area and avoid breathing vapor or mist. Contain spill away from surface water and sewers. Contain spill as a liquid
for possible recovery, or absorb with compatible sorbent material and shovel with a clean, sparkproof tool into a sealable
container for disposal.
Additionally, for large spills: Dike far ahead of liquid spill for collection and later disposal.
HAZARDOUS COMBUSTION
PRODUCTS:
Decomposition and combustion materials may be toxic. Burning may produce
aldehydes, hydrogen sulfide, alkyl mercaptans, sulfides, carbon monoxide, and
oxides of sulfur, calcium and zinc and other unidentified organic compounds.
CONDITIONS OF FLAMMABILITY: Sparks, or flame. Product may burn, but does not ignite readily.
PROTECTIVE EQUIPMENT FOR
FIREFIGHTERS:
A positive-pressure, self-contained breathing apparatus (SCBA) and full-body
protective equipment are required for fire emergencies.
EXTINGUISHING MEDIA: Carbon dioxide, regular foam, dry chemical, water spray, or water fog. Water or
foam may cause frothing.
NFPA 704
HAZARD IDENTIFICATION:
This information is intended solely for the use by individuals trained in this
system.
1 0
1
REACTIVITY
(YELLOW)
HEALTH HAZARD
( BLUE)
SPECIFIC
HAZARD
(WHITE)
FIRE
HAZARD
(RED)
5 | P a g e
*** SECTION 7: HANDLING AND STORAGE ***
HANDLING: Keep away from sparks or flame. Where flammable mixtures may be present, equipment safe for
such locations should be used. Use clean tools. These products have a low vapor pressure and are
not expected to present an inhalation hazard under normal temperatures and pressures. However,
when aerosolizing, misting, or heating these products, do not breathe vapor or mist. Use in a well-
ventilated area. Avoid contact with eyes, skin, clothing, and shoes.
SHIPPING AND
STORING:
Keep container tightly closed when not in use and during transport. Store containers in a cool, dry
place. Do not pressurize, cut, weld, braze, solder, drill, or grind containers. Keep containers away
from flame, sparks, static electricity, or other sources of ignition. Empty product containers may
retain product residue and can be dangerous.
*** SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ***
EXPOSURE GUIDELINES: Component
Exposure Limits
Lubricating oils, petroleum, hydrotreated spent (64742-58-1)
ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist, mineral)
10 mg/m3 STEL (sampled by method that does not collect vapor) (related to Oil mist, mineral)
OSHA Final: 5 mg/m3 TWA (related to Oil mist, mineral) OSHA
Vacated: 5 mg/m3 TWA (related to Oil mist, mineral)
NIOSH: 5 mg/m3 TWA (related to Oil mist, mineral)
10 mg/m3 STEL (related to Oil mist, mineral)
Mineral oil (Not Available)
ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist, mineral)
10 mg/m3 STEL (sampled by method that does not collect vapor) (related to Oil mist, mineral)
OSHA Final: 5 mg/m3 TWA (related to Oil mist, mineral) OSHA
Vacated: 5 mg/m3 TWA (related to Oil mist, mineral)
NIOSH: 5 mg/m3 TWA (related to Oil mist, mineral)
10 mg/m3 STEL (related to Oil mist, mineral)
Lubricating oils, (petroleum), C>25, hydrotreated brightstock (72623-83-7)
ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist,
mineral)
10 mg/m3 STEL (related to Oil mist, mineral)
FIRE FIGHTING INSTRUCTIONS: Keep storage containers cool with water spray.
FIRE AND EXPLOSION HAZARDS:
Heated containers may rupture. "Empty"
containers may retain residue and can be
dangerous. Products are not sensitive to mechanical
impact or static discharge.
6 | P a g e
OSHA: 5 mg/m3 TWA (related to Oil mist, mineral)
NIOSH: 5 mg/m3 TWA (related to Oil mist (mineral)
10 mg/m3 STEL (related to Oil mist (mineral)
Residual oils (petroleum), hydrotreated (64742-54-7)
ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist,
mineral)
10 mg/m3 STEL (related to Oil mist, mineral)
OSHA: 5 mg/m3 TWA (related to Oil mist, mineral)
NIOSH: 5 mg/m3 TWA (related to Oil mist (mineral)
10 mg/m3 STEL (related to Oil mist (mineral) Neutral oil
(72623-86-0)
ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist,
mineral)
10 mg/m3 STEL (related to Oil mist, mineral)
OSHA: 5 mg/m3 TWA (related to Oil mist, mineral)
NIOSH: 5 mg/m3 TWA (related to Oil mist (mineral))
10 mg/m3 STEL (related to Oil mist (mineral)
Residual oils (petroleum), solvent dewaxed (64742-62-7)
ACGIH: 5 mg/m3 TWA (sampled by method that does not collect vapor) (related to Oil mist, mineral) 10
mg/m3 STEL (related to Oil mist, mineral)
OSHA: 5 mg/m3 TWA (related to Oil mist, mineral)
NIOSH: 5 mg/m3 TWA (related to Oil mist (mineral))
10 mg/m3 STEL (related to Oil mist (mineral)
ENGINEERING
CONTROLS:
Provide general ventilation needed to maintain concentration of vapor or mist below applicable
exposure limits. Where adequate general ventilation is unavailable, use process enclosures, local
exhaust ventilation, or other engineering controls to control airborne levels below applicable
exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY
PROTECTION:
Not normally needed. Use NIOSH-certified P- or R- series particulate filter and organic vapor
cartridges when concentration of vapor or mist exceeds applicable exposure limits. Protection
provided by air purifying respirators is limited. Do not use N-rated respirators. Selection and use of
respiratory protective equipment should be in accordance in the USA with OSHA General Industry
Standard 29 CFR 1910.134; or in Canada with CSA Standard Z94.4.
EYE
PROTECTION:
Where eye contact is likely, wear chemical goggles; contact lens use is not recommended.
7 | P a g e
SKIN
PROTECTION:
Where skin contact is likely, wear neoprene, nitrile or equivalent protective gloves; use of natural
rubber or equivalent gloves is not recommended.
When products are heated and skin contact is likely, wear heat-insulating, gloves, boots, and other
protective clothing.
To avoid prolonged or repeated contact where spills and splashes are likely, wear appropriate
chemical-resistant faceshield, boots, apron, coveralls, long sleeve shirts, or other protective clothing.
PERSONAL
HYGIENE:
Use good personal hygiene. Wash thoroughly with soap and water after handling product and before
eating, drinking, or using tobacco products. Clean affected clothing, shoes, and protective equipment
before reuse. Discard leather articles, such as shoes, saturated with these products.
OTHER
PROTECTIVE
EQUIPMENT:
Where spills and splashes are likely, facilities storing or using these products should be equipped with
an emergency eyewash and shower, both equipped with clean water, in the immediate work area.
*** SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES ***
PHYSICAL STATE,
APPEARANCE, AND ODOR: Liquid, amber, petroleum odor.
ODOR THRESHOLD: Not available
MOLECULAR WEIGHT: Not applicable
SPECIFIC GRAVITY: 0.88 (water = 1) (approximately)
DENSITY: 7.3 LB/US gal (880 g/l) (approximately)
VAPOR DENSITY: Not available
VAPOR PRESSURE: less than 0.1 mmHg at 68ºF (20ºC)
BOILING POINT: 475ºF (246ºC) (minimum)
FREEZING/MELTING POINT: Not available [pour point 0ºF (-18ºC) (maximum)].
pH: Not available.
EVAPORATION RATE: Not available
SOLUBILITY IN WATER: Insoluble
FLASH POINT: 383ºF (195ºC) (minimum) Cleveland Open Cup
FLAMMABLE LIMITS IN AIR:
LOWER: Not available UPPER: Not available
AUTOIGNITION TEMPERATURE: Not available
*** SECTION 10: STABILITY AND REACTIVITY ***
STABILITY: Stable under normal temperatures and pressures.
CONDITIONS TO
AVOID:
Avoid sparks or flame when not in use.
INCOMPATIBILITY: Avoid oxidizing agents, acids and reactive halogens.
8 | P a g e
REACTIVITY: Polymerization is not known to occur under normal temperature and pressures. Not reactive
with water.
HAZARDOUS
DECOMPOSITION
PRODUCTS:
None under normal temperatures and pressures. See also SECTION 5:
HAZARDOUS COMBUSTION PRODUCTS.
*** SECTION 11: TOXICOLOGICAL INFORMATION ***
TOXICITY DATA:
Component Analysis - LD50/LC50
Lubricating oils, petroleum, hydrotreated spent (64742-58-1)
Oral LD50 Rat >2000 mg/kg
Dermal LD50 Rat >2000 mg/kg
Dermal LD50 Rabbit >4480 mg/kg
Residual oils (petroleum), solvent dewaxed (64742-62-7)
Inhalation LC50 Rat: 2.18 mg/L/4H
Oral LD50 Rat:>5000 mg/kg
Dermal LD50 Rabbit:>2000 mg/kg
Lubricating oils (petroleum), C>25, hydrotreated bright stock (72623-83-7) Oral LD50
Rat:>5000 mg/kg
Residual oils (petroleum), hydrotreated (64742-54-7)
Inhalation LC50 Rat: 2.18 mg/L/4H
Oral LD50 Rat: >2000 mg/kg
Dermal LD50 Rabbit: >2000 mg/kg
Lubricating oils, petroleum, C15-30, hydrotreated neutral oil-based (72623-86-0)
Inhalation LC50 Rat: 2.18 mg/L/4H
Oral LD50 Rat: >5000 mg/kg
Dermal LD50 Rabbit: >2000 mg/kg
Residual oils (petroleum), solvent refined (64742-01-4)
Inhalation LC50 Rat: 2.18 mg/L/4H
Oral LD50 Rat:>5000 mg/kg
Dermal LD50 Rabbit:>2000 mg/kg
Mineral oil (Not Available)
Oral LD50 Mouse 22 g/kg (related to Oil mist, mineral)
ACUTE EFFECTS: These products are not likely to present an inhalation hazard at normal
temperatures and pressures. However, when aerosolizing, misting, or heating
these products, high concentrations of generated vapor or mist may irritate the
respiratory tract (nose, throat, and lungs). May cause eye and skin irritation. Not
likely to be absorbed through the skin in harmful amounts. May be harmful if
swallowed. May cause throat irritation, nausea, vomiting, and diarrhea.
9 | P a g e
REPEATED DOSE EFFECTS: Prolonged or repeated inhalation of oil mist may cause oil pneumonia, lung tissue
inflammation, and/or fibrous tissue formation. Prolonged or repeated eye contact
may cause inflammation of the membrane lining the eyelids and covering the
eyeball (conjunctivitis). Prolonged or repeated skin contact may cause drying,
cracking, redness, itching, and/or swelling (dermatitis).
Experimental evidence suggests that these products do not cause mutagenesis.
Based on best current information, there is no known sensitization, reproductive
toxicity, or teratogenicity associated with these products.
CARCINOGENICITY: Based on best current information, there is no known carcinogenicity as
categorized by ACGIH A1 or A2 substances; as categorized by IARC Group 1,
Group 2A, or Group 2B agents; or as listed by NTP as either known
carcinogens or substances for which there is limited evidence of
carcinogenicity in humans or sufficient evidence of carcinogenicity in
experimental animals.
Also see SECTION 15: CALIFORNIA.
TARGET ORGAN EFFECTS: Prolonged or repeated inhalation of oil mist may cause oil pneumonia, lung
tissue inflammation, and/or fibrous tissue formation.
*** SECTION 12: ECOLOGICAL INFORMATION ***
ECOTOXICITY: No information available for the product.
Component Analysis - Ecotoxicity - Aquatic Toxicity
Lubricating oils, petroleum, hydrotreated spent (64742-58-1)
Test & Species Results Conditions
96 Hr LC50 Brachydanio rerio 79.6 mg/L semi-static
96 Hr LC50 Pimephales promelas 3.2 mg/L semi-static
Lubricating oils, petroleum, C20-50, hydrotreated neutral oil-based (72623-87-1)
Test & Species Results Conditions
96 Hr LC50 Oncorhynchus mykiss >5000 mg/L
Residual oils (petroleum), solvent dewaxed (64742-62-7)
Test & Species Results Conditions
96 Hr LC50 Pimephales promelas >5000 mg/L
Lubricating oils, petroleum, C>25. hydrotreated bright stock (72623-83-7)
Test & Species Conditions
96 Hr LC50 Lepomis macrochirus >10000 mg/L
Lubricating oils, petroleum, C15-30, hydrotreated neutral oil-based (72623-86-0)
Test & Species Results Conditions
96 Hr LC50 Oncorhynchus mykill >5000 mg/L
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3)
10 | P a g e
Test & Species Results Conditions
96 Hr LC50 Pimephales promelas 1-5 mg/L static
Residual oils (petroleum), solvent refined (64742-01-4)
Test & Species Results Conditions
96 Hr LC50 Oncorhynchus >5000 mg/L mykiss
Petroleum distillates, hydrotreated heavy paraffinic (64742-54-7)
Test & Species Results Conditions
96 Hr LC50 Pimephales promelas >5000
PERSISTENCE/ DEGRADABILITY:
No information available.
BIOACCUMULATION/ ACCUMULATION:
No information available.
MOBILITY IN
ENVIRONMENTAL MEDIA: No information available.
OTHER ADVERSE EFFECTS: Not available.
OCTANOL/WATER Not available PARTITION COEFFICIENT:
VOLATILE ORGANIC Negligible.
COMPOUNDS:
*** SECTION 13: DISPOSAL CONSIDERATIONS ***
DISPOSAL: Dispose in accordance with federal, state, provincial, and local regulations. Regulations may also
apply to empty containers. The responsibility for proper waste disposal lies with the owner of the
waste. Contact Safety-Kleen regarding proper recycling or disposal.
USEPA WASTE
CODE(S):
These products, if discarded, are not expected to be a characteristic or listed hazardous waste. If
recycled in the USA, they must be managed in accordance with 40 CFR Part 279. Processing, use, or
contamination by the user may change the waste code(s) applicable to the disposal of these products.
*** SECTION 14: TRANSPORT INFORMATION ***
DOT: Shipping Name: Not regulated
TDG: Shipping Name: Not regulated
EMERGENCY RESPONSE GUIDE Not applicable.
NUMBER: Reference North American Emergency Response Guidebook
*** SECTION 15: REGULATORY INFORMATION ***
USA REGULATIONS
11 | P a g e
OSHA OSHA Regulated Chemicals
No information is available.
SARA SECTIONS 302
AND 304:
Based on the ingredient listed in SECTION 3, this product does not contain any
"extremely hazardous substances" listed pursuant to Title III of the Superfund
Amendments and Reauthorization Act of 1986 (SARA) Section 302 or Section 304 as identified
in 40 CFR Part 355, Appendix A and B.
SARA SECTIONS 311
AND 312:
These products pose the following health hazard(s) as defined in 40 CFR Part 370 and are subject
to the requirements of sections 311 and 312 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 (SARA):
Immediate (Acute) Health Hazard
Delayed (Chronic) Health Hazard
SARA SECTION 313: These products contain "toxic" chemical(s) subject to the requirements of section 313 of Title III
of the Superfund Amendments and Reauthorization Act of 1986 (SARA) and 40 CFR Part 372.
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-4203)
1.0% de minimis concentration (Chemical Category N982) (related to Zinc compounds)
CERCLA: Based on the ingredient(s) listed in SECTION 3, this product does not contain any "hazardous
substances" listed pursuant to the Comprehensive Environmental Response, Compensation and
Liability Act of 1980 (CERCLA) in 40 CFR Part 302, Table 302.4.
TSCA: All the components of this product are listed on, or are exempted from the requirement to be
listed on, the TSCA Inventory.
CALIFORNIA: This product does not contain detectable amounts of any chemical known to the State of
California to cause cancer.
This product does not contain detectable amounts of any chemical known to the state of
California to cause birth defects or other reproductive harm.
CANADIAN REGULATIONS
These products have been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all information required by the CPR.
CANADIAN The components of this product are listed on, or are exempted from the requirements to
ENVIRONMENTAL be listed on, the Canadian Domestic Substances List (DSL).
PROTECTION ACT
(CEPA):
12 | P a g e
*** SECTION 16. OTHER INFORMATION ***
REVISION INFORMATION: This MSDS has been revised in the following sections:
Section 1, (Address, Date); Section 7 (Handling)
LABEL/OTHER INFORMATION: Not available
User assumes all risks incident to the use of this (these) product(s). To the best of our knowledge, the information contained herein is accurate. However,
BOSS Lubricants assumes no liability whatsoever for the accuracy or completeness of the information contained herein. No representations or warranties,
either express or implied, or merchantability, fitness for a particular purpose or of any other nature are made hereunder with respect to information or the
product to which information refers. The data contained on this sheet apply to the product(s) as supplied to the user.
Calumet Lantern Fuel
0170-00-V
Petrochemical industry: Petroleum refining. Solvent.
Calumet Specialty Products Partners, L.P.2780 Waterfront Pkwy E. Dr.Suite 200Indianapolis, Indiana 46214 USATechnical Services: 317-328-5660
24hr. CHEMTREC 1-800-424-9300 / International 1-703-527-3887
Material Safety Data Sheet
Product name
Supplier
Material uses
Product code
Validation date
In case of emergency
1. Product and company identification
Calumet Lantern Fuel
:
:
:
:
:
:
Product type : Liquid.
2/28/2014.
Version : 1
Signal word
2. Hazards identification
Routes of entry
Potential acute health effects
Can cause central nervous system (CNS) depression. Irritating to respiratory system.
Irritating to eyes.
Can cause central nervous system (CNS) depression. Aspiration hazard if swallowed.Can enter lungs and cause damage.
Irritating to skin.
Eyes
Skin
Inhalation
Ingestion
Physical state Liquid. [Mobile liquid.]
See toxicological information (Section 11)
DANGER!
EXTREMELY FLAMMABLE LIQUID AND VAPOR. FLAMMABLE. VAPOR MAY CAUSE FLASH FIRE. INHALATION CAUSES HEADACHES, DIZZINESS,DROWSINESS AND NAUSEA AND MAY LEAD TO UNCONSCIOUSNESS. CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. HARMFUL OR FATAL IF SWALLOWED. CAN ENTER LUNGS AND CAUSE DAMAGE. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.
:
:
:
:
:
:
:
Odor : Characteristic. Hydrocarbon.
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Color : Clear. Colorless to light yellow.
Emergency overview
Hazard statements :
Precautionary measures : Do not breathe vapor or mist. Use only with adequate ventilation. Do not eat, drink or smoke when using this product. Avoid contact with eyes, skin and clothing. Keep away from heat, sparks and flame. Keep container tightly closed. Wash thoroughly after handling.
Eyes, Skin, Ingestion, Inhalation
1/102/28/2014. 0170-00-V
Calumet Lantern Fuel
Distillates (petroleum), light distillate hydrotreating process, low-boiling 68410-97-9 60 - 70isopentane 78-78-4 5 - 10pentane 109-66-0 5 - 10cyclohexane 110-82-7 5 - 10Distillates (petroleum), hydrotreated light 64742-47-8 1 - 5
3. Composition/information on ingredients
Name CAS number % by weight
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately.
Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.
4. First aid measuresEye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Use dry chemical, CO₂, water spray (fog) or foam.
5. Fire-fighting measures
Extinguishing media
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.
Extremely flammable liquid. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Runoff to sewer may create fire or explosion hazard.
Special protective equipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
Special exposure hazards :
Do not use water jet.
Suitable :
Not suitable :
Hazardous thermal decomposition products
: Decomposition products may include the following materials:carbon dioxidecarbon monoxide
Flammability of the product :
2/102/28/2014. 0170-00-V
Calumet Lantern Fuel
No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8).
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
Environmental precautions
6. Accidental release measures
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Personal precautions :
Large spill :
Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods for cleaning up
Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination.
Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking.Remove contaminated clothing and protective equipment before entering eating areas.Do not breathe vapor or mist. Do not swallow. Avoid contact with eyes, skin and clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparking tools.Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Empty containers retain product residue and can be hazardous. Do not reuse container.
7. Handling and storageHandling
Storage
:
:
8. Exposure controls/personal protection
3/102/28/2014. 0170-00-V
Calumet Lantern Fuel
8. Exposure controls/personal protection
Distillates (petroleum), light distillate hydrotreating process, low-boiling
ACGIH TLV (United States). TWA: 200 ppm 8 hours.
isopentane ACGIH TLV (United States, 3/2012). TWA: 600 ppm 8 hours.
pentane ACGIH TLV (United States, 3/2012). TWA: 600 ppm 8 hours.OSHA PEL (United States, 6/2010). TWA: 1000 ppm 8 hours. TWA: 2950 mg/m³ 8 hours.
cyclohexane ACGIH TLV (United States, 3/2012). TWA: 100 ppm 8 hours.OSHA PEL (United States, 6/2010). TWA: 300 ppm 8 hours. TWA: 1050 mg/m³ 8 hours.
Distillates (petroleum), hydrotreated light ACGIH TLV (United States). TWA: 200 ppm 8 hours.
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.When there is a risk of ignition from static electricity, wear anti-static protective clothing.For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves.
Personal protection
Eyes
Skin
Respiratory
:
:
:
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Hands :
Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas,vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Recommended monitoring procedures
: If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to appropriate monitoring standards.Reference to national guidance documents for methods for the determination of hazardous substances will also be required.
Ingredient Exposure limits
4/102/28/2014. 0170-00-V
Calumet Lantern Fuel
8. Exposure controls/personal protectionEnvironmental exposure controls
: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
37.778 to 176.67°C (100 to 350°F)
Liquid. [Mobile liquid.]
0.715
Insoluble in the following materials: cold water and hot water.
Characteristic. Hydrocarbon.
Clear. Colorless to light yellow.
Boiling/condensation point
Kinematic (40°C (104°F)): <0.1 cm2/s (<10 cSt)
9. Physical and chemical propertiesPhysical state
Relative density
Viscosity
Solubility
Odor
Color
:
:
:
:
:
:
:
Flash point : Closed cup: <-18°C (<-0.4°F) [Tagliabue.]
66.3:API Gravity @60°F
The product is stable.
Highly reactive or incompatible with the following materials:oxidizing materials
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition.
10. Stability and reactivityChemical stability
Conditions to avoid
Incompatible materials
Hazardous decomposition products
:
:
:
:
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
11. Toxicological informationAcute toxicity
Distillates (petroleum), light distillate hydrotreating process, low-boiling
LC50 Inhalation Vapor Rat >7.63 mg/l 4 hours
LD50 Dermal Rabbit >2000 mg/kg -LD50 Oral Rat 5170 mg/kg -
isopentane LC50 Inhalation Vapor Rat 280000 mg/m³ 4 hourspentane LC50 Inhalation Vapor Rat 364 g/m³ 4 hoursDistillates (petroleum),hydrotreated light
LD50 Dermal Rabbit >2000 mg/kg -
LD50 Oral Rat >5000 mg/kg -cyclohexane LD50 Dermal Rabbit >180000 mg/kg -
LD50 Oral Rat 6240 mg/kg -
Product/ingredient name Result Species Dose Exposure
Conclusion/Summary : Not available.
Chronic toxicity
Conclusion/Summary : Not available.
Carcinogenicity
Conclusion/Summary : Not available.
Mutagenicity
Conclusion/Summary : Not available.
5/102/28/2014. 0170-00-V
Calumet Lantern Fuel
11. Toxicological informationTeratogenicity
Conclusion/Summary : Not available.
Reproductive toxicity
Conclusion/Summary : Not available.
12. Ecological informationEcotoxicity : No known significant effects or critical hazards.
Aquatic ecotoxicity
cyclohexane Acute LC50 4530 µg/l Fresh water Fish - Pimephales promelas 96 hours
Product/ingredient name SpeciesResult Exposure
Conclusion/Summary : Not available.
Persistence/degradability
Conclusion/Summary : Not available.
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues.Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Waste disposal
13. Disposal considerations
Disposal should be in accordance with applicable regional, national and local laws and regulations.
:
RCRA classification : D001 [Flammable]
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees.
14. Transport informationRegulatory information
UN number Proper shipping name
Classes PG* Label Additional information
6/102/28/2014. 0170-00-V
Calumet Lantern Fuel
14. Transport information3 Reportable quantity
11086.5 lbs / 5033.3 kg [1859.6 gal / 7039.5 L]Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity)transportation requirements.
Limited quantityYes.
Packaging instructionPassenger aircraftQuantity limitation: 5 L
Cargo aircraftQuantity limitation: 60 L
Special provisions144, IB2, T7, TP1,TP8, TP28
DOT Classification Petroleum distillates,n.o.s. RQ(Cyclohexane)
II
IMDG Class PETROLEUM DISTILLATES, N.O.S.
3 II
Petroleum distillates,n.o.s.
UN1268IATA-DGR Class 3 II
UN1268 Emergency schedules (EmS)F-E, S-E
Passenger and Cargo AircraftQuantity limitation: 5 LPackaging instructions: 353Cargo Aircraft OnlyQuantity limitation: 60 LPackaging instructions: 364Limited Quantities -Passenger AircraftQuantity limitation: 1 LPackaging instructions: Y341
UN1268
PG* : Packing group
7/102/28/2014. 0170-00-V
Calumet Lantern Fuel
Flammable liquidIrritating materialTarget organ effects
HCS Classification
15. Regulatory information
U.S. Federal regulations
The following components are listed: CYCLOHEXANE; ISOPENTANE; PENTANE
WARNING: This product contains less than 0.1% of a chemical known to the State of California to cause cancer.WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm.
Clean Water Act (CWA) 307: benzene
Clean Water Act (CWA) 311: cyclohexane; benzene
Clean Air Act (CAA) 112 regulated flammable substances: isopentane; pentane
Massachusetts
SARA 302/304: No products were found.SARA 311/312 Hazards identification: Fire hazard, Immediate (acute) health hazard,Delayed (chronic) health hazard
:
:
SARA 313
:
Product name CAS number Concentration
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
benzene Yes. Yes. 6.4 µg/day (ingestion)13 µg/day (inhalation)
24 µg/day (ingestion)49 µg/day (inhalation)
Ingredient name Cancer Reproductive No significant risk level
Maximum acceptable dosage level
cyclohexane 110-82-7 5 - 10
cyclohexane 110-82-7 5 - 10
Form R - Reporting requirements
Supplier notification
California Prop. 65
Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)
: Not listed
Clean Air Act Section 602 Class I Substances
: Not listed
Clean Air Act Section 602 Class II Substances
: Not listed
DEA List I Chemicals (Precursor Chemicals)
: Not listed
DEA List II Chemicals (Essential Chemicals)
: Not listed
New York : The following components are listed: Cyclohexane; Benzene, hexahydro-
New Jersey : The following components are listed: CYCLOHEXANE; ISOPENTANE; BUTANE,2-METHYL-; PENTANE
Pennsylvania : The following components are listed: CYCLOHEXANE; BUTANE, 2-METHYL-;PENTANE
State regulations
TSCA 8(a) PAIR: pentane
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): All components are listed or exempted.
8/102/28/2014. 0170-00-V
Calumet Lantern Fuel
15. Regulatory information
The following components are listed: Cyclohexane; Pentane (all isomers); Pentane (all isomers); Hydrotreated light distillate
Australia inventory (AICS): All components are listed or exempted.China inventory (IECSC): All components are listed or exempted.Japan inventory: Not determined.Korea inventory: All components are listed or exempted.Malaysia Inventory (EHS Register): Not determined.New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted.Philippines inventory (PICCS): All components are listed or exempted.Taiwan inventory (CSNN): Not determined.
WHMIS (Canada) Class B-2: Flammable liquidClass D-2B: Material causing other toxic effects (Toxic).
International regulations
International lists :
Canada
Canadian NPRI
CANADA INVENTORY (DSL)
: All components are listed or exempted.
Chemical Weapons Convention List Schedule I Chemicals
: Not listed
Chemical Weapons Convention List Schedule II Chemicals
: Not listed
Chemical Weapons Convention List Schedule III Chemicals
: Not listed
CEPA Toxic substances None of the components are listed.
Canadian lists
Europe inventory (EINECS)
: All components are listed or exempted.
16. Other information
Hazardous Material Information System (U.S.A.)
2
3
0
Health
Flammability
Physical hazards
EXTREMELY FLAMMABLE LIQUID AND VAPOR. FLAMMABLE. VAPOR MAY CAUSE FLASH FIRE. INHALATION CAUSES HEADACHES, DIZZINESS,DROWSINESS AND NAUSEA AND MAY LEAD TO UNCONSCIOUSNESS. CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. HARMFUL OR FATAL IF SWALLOWED. CAN ENTER LUNGS AND CAUSE DAMAGE. CONTAINS MATERIAL THAT CAN CAUSE TARGET ORGAN DAMAGE.
Label requirements :
Date of issue :
:
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
2/28/2014.
9/102/28/2014. 0170-00-V
Calumet Lantern Fuel
16. Other information
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Date of previous issue
Version :
:
Indicates information that has changed from previously issued version.
No previous validation.
1
Prepared by : Technical Department
10/102/28/2014. 0170-00-V
Material Safety Data Sheet
Section 1 Product Information
Product Name/Identifier: C-THRU Liquid Glass Cleaner Concentrate
Manufactured For: Chatterson Janitorial Supplies, 2810 Dewdney, Regina, SK. S4T 0X7
Product Use: Glass, mirror, countertops, and enamelled surface cleaner
Section 2 Hazardous Ingredients
Chemical Name Concentration % CAS and Product ID
Number50 50LD LC
Methyl Alcohol 7 - 15 67-56-1 Oral (Rat) 6200 mg/kg
Not available
Isopropyl Alcohol 3 - 15 67-63-0 Oral (Rat) 4720 mg/kg
Not available
Section 3 Physical Data
Physical State: Liquid Odour and Appearance: Clear blue liquid, scented
Odour threshold: Not Available Specific Gravity: 0.970 @ 25º C Water = 1
Vapour Pressure: Not Available Vapour Density (Air=1): Not Available
Evaporation Rate(Water=1):
Not Available Boiling Point: 100º C Melting Point: N/A
pH: 7.5 (basic) Coefficient of Water/Oil Distribution: Not Available
Section 4 Fire and Explosion Hazard
Flammability: Yes Means of Extinction: Water, Fog, Foam, Dry Chemical
Flash Point (°C)and Method of Determination: 55 COC
Upper Flammable Limit (% byvolume):
Not Available Lower Flammable Limit (% byvolume):
Not Available
Auto Ignition Temperature (0ºC): Not Available Hazardous Combustion Products: Not Available
Explosion Data-Sensitivity to Mechanical Impact: Not Available
Sensitivity to Static Discharge: Not Available
Section 5 Reactivity Data
Chemical Stability: This product is stable Compatibility to Other Substances: Not Available
Conditions of Reactivity: Not available Hazardous Decomposition Products: Not available
NOTICEChatterson Janitorial Supplies and the manufacturer expressly disclaims any injury, damage or death because of theimproper use of this product. The proper use of this product is described on the label of the container.
ChattersonJANITORIAL SUPPLIES
Section 6 Toxicological Properties
Route of Entry: / Skin Contact: Slight irritant / Skin Absorption: Not Applicable
/ Eye Contact: Slight Irritant / Inhalation: Not Applicable
/ Ingestion: Slightly toxic
Exposure Limits: Not Available Irritancy of Products: Slight
Sensitization to Product: Not Available Synergistic Products: Not Available
Carcinogenicity, Reproductive Toxicity, Teratogenicity, Mutagenicity: Not Available
Section 7 Preventative Measures
Personal Protective / Gloves: No / Respiratory: No
Equipment : / Eyes: No / Clothing: No
/ Footwear: No
Engineering Controls: General ventilation normally adequate
Leak and Spill
Procedure:Mop up spillage. Rinse spill area with water and allow to dry.
Waste Disposal: Flush with water into waste systems in accordance with municipal, provincial, and federalregulations.
Storage and HandlingRequirements:
Normal handling processes. Inside storage at 1-40º C recommended.
Special ShippingInformation:
Not Regulated
Section 8 First Aid Measures
Eyes: Flush with water. If irritation persists, call a physician.
Skin: Flush with water. If irritation persists, call a physician.
Inhalation: Not applicable.
Ingestion: Do not induce vomiting. Drink 3 - 4 glasses of milk or water. Call a physician immediately.
Section 9 Preparation Information
Prepared by: A. Taylor Telephone: 306 - 525 - 3568 Date: February 03, 2014
NOTICEChatterson Janitorial Supplies and the manufacturer expressly disclaims any injury, damage or death because of theimproper use of this product. The proper use of this product is described on the label of the container.
MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Material name D-MO
Version # 02
Issue date 01-04-2012
Revision date 11-13-2012
Supersedes date 01-04-2012
CAS # Mixture
Product code 189
Product use Lubrication oil.
Synonym(s) SAE 10W, 20W-20, 30, 40, 50, Sonic D-MO
Manufacturer information
Manufacturer Consumers' Co-operative Refineries Limited
Address P.O. Box 260; 9th Avenue North
Regina, SK S4P 3A1 Canada
Telephone (306) 721-5353
Supplier Federated Co-operatives Limited
Address P.O. Box 1050, 401 - 22nd Street East
Saskatoon SK S7K 3M9 Canada
Telephone (306) 244-3447
24 Hour Emergency
Telephone
(613) 996-6666 - Canutec
2. Hazards Identification
Physical state Liquid.
Appearance Oily liquid.
Emergency overview WARNING
Causes skin and eye irritation.
OSHA regulatory status This product is hazardous according to OSHA 29 CFR 1910.1200.
Potential health effects
Routes of exposure Eye contact. Skin contact. Ingestion. Inhalation.
Eyes Causes eye irritation.
Skin Causes skin irritation.
Inhalation May cause respiratory tract irritation.
Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.
Chronic effects No data available.
Potential environmental effects No special environmental precautions required.
Components CAS # Percent
3. Composition / Information on Ingredients
68649-42-3 1-5Zinc Alkyldithiophosphate
4. First Aid Measures
First aid procedures
Eye contact Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least20 minutes, occasionally lifting the upper and lower eyelids. Get medical attention if symptomsoccur.
CPH MSDS NA
1 / 5
D-MO CPH MSDS NA
906163 Version #: 02 Revision date: 11-13-2012 Issue date: 01-04-2012
Skin contact In case of contact, flush skin with plenty of water for at least 20 minutes, while removingcontaminated shoes and clothes. Wash contaminated skin with soap and water. Washcontaminated clothing before reuse. Thoroughly clean shoes before reuse. Get medical attentionif irritation develops and persists.
Inhalation If fumes or combustion products are inhaled move victim to fresh air. Get medical attention if anydiscomfort occurs.
Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medicalattention if any discomfort occurs.
Notes to physician Treat symptomatically.
General advice If you feel unwell, seek medical advice (show the label where possible).
5. Fire Fighting Measures
Extinguishing media
Suitable extinguishing
mediaExtinguish with water spray, carbon dioxide, dry chemical or material appropriate for thesurrounding fire.
Unsuitable extinguishing
mediaNone.
Protection of firefighters
Specific hazards arising
from the chemicalBy heating and fire, toxic vapors/gases may be formed.
Fire fighting
equipment/instructionsFirefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
Hazardous combustion
productsNo data available.
6. Accidental Release Measures
Personal precautions In case of spills, beware of slippery floors and surfaces. Wear suitable protective clothing andgloves.
Environmental precautions Avoid discharge into drains, water courses or onto the ground. Prevent spreading over a widearea (e.g. by containment or oil barriers).
Methods for containment Collect and dispose of spillage as indicated in Section 13 of the MSDS.
Methods for cleaning up Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
Other information Clean up in accordance with all applicable regulations.
7. Handling and Storage
Handling Observe good industrial hygiene practices. Use appropriate Personal Protective Equipment.
Storage Store in original tightly closed container. Keep in a cool, well-ventilated place.
8. Exposure Controls / Personal Protection
Occupational exposure limits No exposure limits noted for ingredient(s).
Engineering controls General ventilation is normally adequate.
Personal protective equipment
Eye / face protection Wear approved safety glasses or goggles.
Skin protection Wear appropriate clothing to prevent repeated or prolonged skin contact. Wear protective gloves.Neoprene or nitrile gloves are recommended.
Respiratory protection No personal respiratory protective equipment normally required.
General hygiene
considerationsHandle in accordance with good industrial hygiene and safety practices.
9. Physical & Chemical Properties
Appearance Oily liquid.
Physical state Liquid.
Form Liquid.
Color Brown.
Odor Mild.
Odor threshold Not available.
CPH MSDS NA
2 / 5
D-MO CPH MSDS NA
906163 Version #: 02 Revision date: 11-13-2012 Issue date: 01-04-2012
pH Not available.
Vapor pressure Not available.
Vapor density Not available.
Boiling point Not available.
Melting point/Freezing point -4 °F (-20 °C)
Solubility (water) Slight
Specific gravity 0.88 - 0.89
Flash point > 296.6 °F (> 147 °C) Open Cup
Flammability limits in air,
upper, % by volume
Not available.
Flammability limits in air,
lower, % by volume
Not available.
Auto-ignition temperature 775.4 °F (413 °C)
10. Chemical Stability & Reactivity Information
Chemical stability Material is stable under normal conditions.
Conditions to avoid Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition
productsNone expected under normal conditions of use.
Possibility of hazardous
reactionsWill not occur.
11. Toxicological Information
Sensitization No data available.
Acute effects Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.
Local effects Causes skin and eye irritation.
Chronic effects Chronic effects are not expected when this product is used as intended.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Mutagenicity Not expected to be mutagenic.
Neurological effects No data available.
Reproductive effects Contains no ingredient listed as toxic to reproduction.
Teratogenicity Not classified.
12. Ecological Information
Ecotoxicity No data on possible environmental effects have been found.
Environmental effects The product components are not classified as environmentally hazardous. However, this does notexclude the possibility that large or frequent spills can have a harmful or damaging effect on theenvironment.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulation /
AccumulationNot available.
13. Disposal Considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose inaccordance with all applicable regulations.
Waste from residues / unused
productsDispose of waste and residues in accordance with local authority requirements.
Contaminated packaging Since emptied containers retain product residue, follow label warnings even after container isemptied.
14. Transport Information
DOT
Not regulated as a hazardous material by DOT.
CPH MSDS NA
3 / 5
D-MO CPH MSDS NA
906163 Version #: 02 Revision date: 11-13-2012 Issue date: 01-04-2012
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
TDG
Not regulated as dangerous goods.
15. Regulatory Information
US federal regulations This product is hazardous according to OSHA 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration
Zinc Alkyldithiophosphate (CAS 68649-42-3) 1.0 % N982
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Zinc Alkyldithiophosphate (CAS 68649-42-3) N982 Listed.
CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)
None
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - NoDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
Section 302 extremely
hazardous substance (40
CFR 355, Appendix A)
No
Section 311/312 (40 CFR
370)No
Drug Enforcement
Administration (DEA) (21 CFR
1308.11-15)
Not controlled
Canadian regulations Canadian NPRI: The following components are listed: Zinc.
WHMIS status Controlled
WHMIS classification D2B - Other Toxic Effects-TOXIC
WHMIS labeling
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial ChemicalSubstances (EINECS)
YesEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Existing Chemicals List (ECL) YesKorea
CPH MSDS NA
4 / 5
D-MO CPH MSDS NA
906163 Version #: 02 Revision date: 11-13-2012 Issue date: 01-04-2012
Country(s) or region Inventory name On inventory (yes/no)*
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances(PICCS)
YesPhilippines
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s)
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
State regulations
US - California Hazardous Substances (Director's): Listed substance
Zinc Alkyldithiophosphate (CAS 68649-42-3) Listed.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
US - New Jersey RTK - Substances: Listed substance
Zinc Alkyldithiophosphate (CAS 68649-42-3) Listed.
US. Massachusetts RTK - Substance List
Not regulated.
US. New Jersey Worker and Community Right-to-Know Act
Zinc Alkyldithiophosphate (CAS 68649-42-3) 500 LBS
US. Pennsylvania RTK - Hazardous Substances
Not regulated.
16. Other Information
Further information HMIS® is a registered trade and service mark of the NPCA.
HMIS® ratings Health: 2Flammability: 1Physical hazard: 0Personal protection: X
NFPA ratings Health: 2Flammability: 1Instability: 0
Disclaimer The information in the sheet was written based on the best knowledge and experience currentlyavailable.
CPH MSDS NA
5 / 5
D-MO CPH MSDS NA
906163 Version #: 02 Revision date: 11-13-2012 Issue date: 01-04-2012
MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Material name Diesel/Bio-diesel/Distillate
Version # 04
Issue date 07-29-2010
Revision date 12-18-2012
Supersedes date 12-14-2012
CAS # Mixture
Product code 2181
Product use Fuel. Refinery feedstock.
Synonym(s) Premium Diesel, EP 3000, Railroad Diesel, Seasonal Diesel, Premium Mine Diesel, Mine Diesel,Summer Diesel, Winter Diesel, Dyed (Purple) Diesel, Export Diesel, Electric Generating Diesel,ARDS Light Distillate, ARDS Heavy Distillate/Diesel, Crude Straight run Diesel, MDUUnifinate/Diesel, CAT light Cycle oil, Low Pour Distillate, High Pour Diesel, #2 Fuel Oil.
Manufacturer information
Manufacturer Consumers' Co-operative Refineries Limited
Address P.O. Box 260; 9th Avenue North
Regina, SK S4P 3A1 Canada
Telephone (306) 721-5353
Supplier Federated Co-operatives Limited
Address P.O. Box 1050, 401 - 22nd Street East
Saskatoon SK S7K 3M9 Canada
Telephone (306) 244-3447
24 Hour Emergency
Telephone
(613) 996-6666 - Canutec
Telephone Number: (306) 244-3447
Emergency telephone (613) 996-6666
Federated Co-operatives Ltd.Supplier
P.O. Box 1050
401 - 22nd Street East
Saskatoon
S7K 3M9
CA
2. Hazards Identification
Physical state Liquid.
Emergency overview WARNING! Combustible liquid and vapor. Aspiration hazard: Harmful if swallowed - may enterlungs if swallowed or vomited. High vapor concentrations may cause drowsiness and irritation ofthe eyes or respiratory tract. Prolonged or repeated skin contact may cause drying, cracking, orirritation. Toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.
OSHA regulatory status This product is hazardous according to OSHA 29 CFR 1910.1200.
Potential health effects
Routes of exposure Ingestion. Eye contact. Inhalation. Skin contact.
Eyes May cause eye irritation. Contact may cause irritation with redness, tearing, pain, and/or blurredvision.
Skin Prolonged or repeated contact may dry skin and cause irritation.
Inhalation Vapors may cause headache, fatigue, dizziness and nausea. May cause central nervous systemeffects.
Ingestion Ingestion may result in vomiting; aspiration (breathing) of vomitus into lungs must be avoided aseven small quantities may result in aspiration pneumonitis.
Potential environmental effects Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
CPH MSDS NA
1 / 7
Diesel/Bio-diesel/Distillate CPH MSDS NA
4379 Version #: 04 Revision date: 12-18-2012 Issue date: 07-29-2010
Components CAS # Percent
3. Composition / Information on Ingredients
68334-30-5 95 - 100Fuels, diesel
129828-16-6 0 - 5Canola Oil - Fatty Acid Methyl Ester
73891-99-3 0 - 5Rapeseed Oil - Fatty Acid Methyl Ester
67784-80-9 0 - 5Soy Methyl Esters from Vegetable Oil
4. First Aid Measures
First aid procedures
Eye contact Immediately flush with plenty of water for at least 15 minutes. Remove any contact lenses. Getmedical attention immediately.
Skin contact Remove contaminated clothing. Wash with soap and water. Get medical attention if irritationdevelops and persists. Wash contaminated clothing before reuse. Destroy or thoroughly cleancontaminated shoes.
Inhalation Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.Get medical attention immediately!
Ingestion Rinse mouth thoroughly with water and give large amounts of milk or water to people notunconscious. DO NOT induce vomiting because of danger of aspirating liquid into lungs. Call aphysician or poison control center. If vomiting occurs naturally, have victim lean forward to reducerisk of aspiration. Never give anything by mouth to an unconscious person.
Notes to physician Treat symptomatically. The effects might be delayed.
General advice Get medical attention if any discomfort develops.
5. Fire Fighting Measures
Flammable properties The product is combustible, and heating may generate vapors which may form explosive vapor/airmixtures. Material will float and can be re-ignited on surface of water.
Extinguishing media
Suitable extinguishing
mediaCarbon dioxide, regular foam, dry chemical, water spray, or water fog.
Unsuitable extinguishing
mediaDo not use water jet as an extinguisher, as this will spread the fire.
Protection of firefighters
Specific hazards arising
from the chemicalVapors may form explosive mixtures with air. Vapors are heavier than air and may travel along thefloor and in the bottom of containers. Vapors may be ignited by a spark, a hot surface or anember.
Protective equipment and
precautions for firefightersSelf-contained breathing apparatus and full protective clothing must be worn in case of fire.
Fire fighting
equipment/instructionsMove containers from fire area if you can do it without risk. Use water spray to cool unopenedcontainers. Cool containers with flooding quantities of water until well after fire is out.
Hazardous combustion
productsCarbon monoxide and carbon dioxide.
6. Accidental Release Measures
Personal precautions Stay upwind. Ventilate closed spaces before entering them. Wear suitable protective clothing,gloves and eye/face protection. For personal protection, see section 8 of the MSDS.
Environmental precautions Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. bycontainment or oil barriers). Do not contaminate water. Contact local authorities in case of spillageto drain/aquatic environment.
Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop theflow of material, if this is without risk. Dike the spilled material, where this is possible. Prevententry into waterways, sewer, basements or confined areas.
CPH MSDS NA
2 / 7
Diesel/Bio-diesel/Distillate CPH MSDS NA
4379 Version #: 04 Revision date: 12-18-2012 Issue date: 07-29-2010
Methods for cleaning up Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible.
Small Spills: Absorb spillage with non-combustible, absorbent material.
Large Spills: Remove with vacuum trucks or pump to storage/salvage vessels. Use anon-combustible material like vermiculite, sand or earth to soak up the product and place into acontainer for later disposal. Wash area with soap and water. Ensure that waste and contaminatedmaterials are collected and removed from the work area as soon as possible in a suitably labeledcontainer.
7. Handling and Storage
Handling Access to work area should be restricted to people handling the product only. Should be handledin closed systems, if possible. Avoid contact with eyes, skin, and clothing. Avoid inhalation ofvapors. Wear appropriate personal protective equipment. Ground container and transferequipment to eliminate static electric sparks. The product is a combustible liquid. Take thenecessary precautionary measures. Vapors are heavier than air and may travel along the floorand in the bottom of containers. Immediately change contaminated clothes. Do not eat, drink orsmoke when using the product. Be aware of potential for surfaces to become slippery. Observegood industrial hygiene practices.
Storage Keep away from heat, sparks and open flame. Keep in a cool, well-ventilated place. Keep awayfrom food, drink and animal feeding stuffs. Store away from incompatible materials.
8. Exposure Controls / Personal Protection
Occupational exposure limits
US. ACGIH Threshold Limit Values
ValueType FormComponents
TWA 100 mg/m3 Inhalable fraction andvapor.
Fuels, diesel (CAS68334-30-5)
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
ValueTypeComponents
TWA 100 mg/m3Fuels, diesel (CAS68334-30-5)
Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and
Safety Regulation 296/97, as amended)
ValueType FormComponents
TWA 100 mg/m3 Vapor and aerosol.Fuels, diesel (CAS68334-30-5)
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)
ValueType FormComponents
TWA 100 mg/m3 Inhalable fraction andvapor.
Fuels, diesel (CAS68334-30-5)
Engineering controls Provide adequate ventilation and minimize the risk of inhalation of vapors and oil mist. Provideeasy access to water supply and eye wash facilities. Use explosion-proof equipment.
Personal protective equipment
Eye / face protection Wear approved safety goggles.
Skin protection Wear chemical-resistant gloves, footwear and protective clothing appropriate for risk of exposure.Contact glove manufacturer for specific information.
Respiratory protection Do not breathe mist or vapor. In case of inadequate ventilation or risk of inhalation of vapors, usesuitable respiratory equipment. Wear NIOSH approved respirator appropriate for airborneexposure at the point of use.
General hygiene
considerationsDo not eat, drink or smoke when using the product. Wash hands after handling. Laundercontaminated clothing before reuse. Handle in accordance with good industrial hygiene and safetypractices.
9. Physical & Chemical Properties
Appearance Not available.
Physical state Liquid.
Form Not available.
CPH MSDS NA
3 / 7
Diesel/Bio-diesel/Distillate CPH MSDS NA
4379 Version #: 04 Revision date: 12-18-2012 Issue date: 07-29-2010
Color Straw.
Odor Hydrocarbon-like.
Odor threshold Not available.
pH Not Applicable
Vapor pressure < 2 psia
Vapor density Not available.
Boiling point 300.2 - 752 °F (149 - 400 °C)
Melting point/Freezing point Not Applicable
Solubility (water) Insoluble
Specific gravity 0.839 - 0.887 @ 15.6 °C
Flash point > 104 °F (> 40 °C) Pensky-Martens Closed Cup
Flammability limits in air,
upper, % by volume
7.6 %
Flammability limits in air,
lower, % by volume
0.6 %
Auto-ignition temperature Not available.
Viscosity 1 - 10 cSt @ 40 °C
Other data
Flash point class Combustible II
Structural formula ( Water = 1)
10. Chemical Stability & Reactivity Information
Chemical stability Stable under normal storage and handling conditions.
Conditions to avoid Heat, sparks, flames, elevated temperatures. Contact with incompatible materials. Do notpressurize, cut, weld, braze, solder, drill, grind or expose empty containers to heat, flame, sparks,static electricity, or other sources of ignition; they may explode and cause injury or death.
Incompatible materials Strong acids. Strong oxidizing agents.
Hazardous decomposition
productsThermal decomposition or combustion may liberate carbon oxides and other toxic gases orvapors.
Possibility of hazardous
reactionsPolymerization will not occur. No dangerous reaction known under conditions of normal use.
11. Toxicological Information
Sensitization May cause eczema-like skin disorders (dermatitis).
Acute effects Swallowing or vomiting of the liquid may result in aspiration into the lungs. Breathing of highconcentrations may cause dizziness, light-headedness, headache, nausea and loss ofcoordination. Continued inhalation may result in unconsciousness.
Local effects Prolonged or repeated contact may dry skin and cause irritation.
US. ACGIH Threshold Limit Values
Fuels, diesel (CAS 68334-30-5) Can be absorbed through the skin.
Chronic effects Prolonged or repeated contact with skin may cause redness, itching, irritation, eczema/chappingand oil acne.
Carcinogenicity IARC, NTP and OSHA: Not listed.
ACGIH Carcinogens
Fuels, diesel (CAS 68334-30-5) A3 Confirmed animal carcinogen with unknown relevance tohumans.
Epidemiology Pre-existing skin conditions including dermatitis might be aggravated by exposure to this product.
Mutagenicity Knowledge about mutagenicity is incomplete.
Reproductive effects Knowledge about reproductive effects is incomplete.
Further information Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.
12. Ecological Information
Ecotoxicity Oil spills are generally hazardous to the environment.
CPH MSDS NA
4 / 7
Diesel/Bio-diesel/Distillate CPH MSDS NA
4379 Version #: 04 Revision date: 12-18-2012 Issue date: 07-29-2010
Environmental effects The product contains volatile organic compounds which have a photochemical ozone creationpotential.
Persistence and degradability The degradability of the product has not been stated.
Bioaccumulation /
AccumulationNo data available on bioaccumulation.
Mobility in environmental
mediaThe product is insoluble in water. It will spread on the water surface while some of thecomponents will eventually sediment in water systems. The volatile components of the product willspread in the atmosphere.
13. Disposal Considerations
Disposal instructions Disposal of this product, solutions, or containers must at all times comply with the requirements ofthe environmental protection and waste disposal legislation and any regional local authorityrequirements.
Waste from residues / unused
productsThe generation of waste should be avoided or minimized wherever possible. Empty containers orliners may retain some product residues. This material and its container must be disposed of in asafe manner (see: Disposal instructions).
14. Transport Information
DOT
UN1202UN number
Basic shipping requirements:
Diesel FuelProper shipping name
Combustible LiquidHazard class
IIIPacking group
144, B1, IB3, T2, TP1Special provisions
Additional information:
150Packaging exceptions
203Packaging non bulk
242Packaging bulk
IATA
UN1202UN number
Diesel FuelUN proper shipping name
3Transport hazard class(es)
IIIPacking group
3LERG code
IMDG
UN1202UN number
Diesel FuelUN proper shipping name
3Transport hazard class(es)
IIIPacking group
F-E, S-EEmS
TDG
Diesel FuelProper shipping name
3Hazard class
UN1202UN number
IIIPacking group
15. Regulatory Information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)
None
CPH MSDS NA
5 / 7
Diesel/Bio-diesel/Distillate CPH MSDS NA
4379 Version #: 04 Revision date: 12-18-2012 Issue date: 07-29-2010
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - NoDelayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No
Section 302 extremely
hazardous substance (40
CFR 355, Appendix A)
No
Section 311/312 (40 CFR
370)No
Drug Enforcement
Administration (DEA) (21 CFR
1308.11-15)
Not controlled
Canadian regulations This product has been classified in accordance with the hazard criteria of the CPR and the MSDScontains all the information required by the CPR.
WHMIS status Controlled
WHMIS classification B3 - Combustible LiquidsD2B - Other Toxic Effects-TOXIC
WHMIS labeling
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) NoAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial ChemicalSubstances (EINECS)
NoEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Existing Chemicals List (ECL) NoKorea
New Zealand Inventory NoNew Zealand
Philippine Inventory of Chemicals and Chemical Substances(PICCS)
NoPhilippines
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s)
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
State regulations
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
US. Massachusetts RTK - Substance List
Not regulated.
US. New Jersey Worker and Community Right-to-Know Act
Not regulated.
US. Pennsylvania RTK - Hazardous Substances
Fuels, diesel (CAS 68334-30-5) Listed.
16. Other Information
HMIS® ratings Health: 2Flammability: 2Physical hazard: 0
NFPA ratings Health: 2Flammability: 2Instability: 0
CPH MSDS NA
6 / 7
Diesel/Bio-diesel/Distillate CPH MSDS NA
4379 Version #: 04 Revision date: 12-18-2012 Issue date: 07-29-2010
Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither theabove named supplier nor any of its subsidiaries assumes any liability whatsoever forcompleteness of the information contained herein. Final determination of suitability of any materialis the sole responsibility of the user. All materials may present unknown hazards and should beused with caution. Although certain hazards are described herein, we cannot guarantee that theseare the only hazards that exist.
CPH MSDS NA
7 / 7
Diesel/Bio-diesel/Distillate CPH MSDS NA
4379 Version #: 04 Revision date: 12-18-2012 Issue date: 07-29-2010
HD7SAE 10W30; 5W30; 10W; 20W20; 30; 40; 50
185
Product nameSynonym
Code
In case of emergency
Product and company identification
Responsible name Atrion Regulatory Services, Inc.:::
::
1 .
Conforms to ANSI Z400.5-2004 Standard (Canada).
CANUTEC (613) 996-6666
SupplierFederated Co-operatives LimitedP. O. Box 1050; 401 - 22nd StreetEastSaskatoon, SK S7K 3M9 Canada(306) 244-3447
:Supplier/ManufacturerMaterial uses : Lubrication oil.
Material Safety Data SheetHD7
ManufacturerConsumers' Co-operative Refineries LimitedP.O. Box 260; 9th Avenue NorthRegina, SK S4P 3A1 Canada(306) 721-5353
Dermal contact. Eye contact. Inhalation. Ingestion.
Emergency overview
Hazards identification
Routes of entryPotential acute health effects
No known significant effects or critical hazards.
Zinc C1-C14 Alkydithiophosphate is an eye irritant at concentration of 5% or greater.
Low oral toxicity; vomiting may present an aspiration hazard. Vomiting may result inaspiration into lungs causing chemical pneumonitis.No known significant effects or critical hazards.
EyesSkin
InhalationIngestion
Physical state Liquid. [Oily liquid.]
NOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHENTHE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED.No known significant effects or critical hazards. Avoid prolonged contact with eyes, skinand clothing.
:
:
:
::
::
Odor : Mild.
2 .
Potential chronic health effects
Carcinogenicity : There is no data to indicate any component present at greater than 0.1% that maypresent a carcinogenic risk.
Mutagenicity : There are no ingredients present which, within the current knowledge of the supplier andin the concentrations applicable, are classified as hazardous to health or theenvironment and hence require reporting in this section.
Teratogenicity : There are no ingredients present which, within the current knowledge of the supplier andin the concentrations applicable, are classified as hazardous to health or theenvironment and hence require reporting in this section.
Developmental effects : There are no ingredients present which, within the current knowledge of the supplier andin the concentrations applicable, are classified as hazardous to health or theenvironment and hence require reporting in this section.
Chronic effects : May cause skin irritation, especially under repeated or prolonged contact or whenmoisture is present.
Fertility effects : No known significant effects or critical hazards.Over-exposure signs/symptoms
Ingestion : No specific data.Skin : No specific data.Eyes : No specific data.
Inhalation : No specific data.
Date of issue : 07/23/2009 Page: 1/610/02/2012
HD7
Hazards identification2 .
See toxicological information (section 11)
Medical conditionsaggravated by over-exposure
None known.:
Composition/information on ingredients3 .
There are no ingredients present which, within the current knowledge of the supplier and in the concentrationsapplicable, are classified as hazardous to health or the environment and hence require reporting in this section.
No hazardous ingredient
Name
First aid measures
No specific treatment. Treat symptomatically. Contact poison treatment specialistimmediately if large quantities have been ingested or inhaled.
Notes to physician :
4 .
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.
Eye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
Check for and remove any contact lenses. Immediately flush eyes with plenty of waterfor at least 20 minutes, occasionally lifting the upper and lower eyelids. Get medicalattention if symptoms occur.In case of contact, immediately flush skin with plenty of water for at least 20 minuteswhile removing contaminated clothing and shoes. Wash contaminated skin with soapand water. Wash clothing before reuse. Clean shoes thoroughly before reuse. Getmedical attention if symptoms occur.Move exposed person to fresh air. If not breathing, if breathing is irregular or ifrespiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.Loosen tight clothing such as a collar, tie, belt or waistband. Seek medical attention.Wash out mouth with water. Give 1/2 glass of milk./Give two glasses of water to drink.Never give anything by mouth to an unconscious person. Do not induce vomiting unlessdirected to do so by medical personnel. If spontaneous vomiting occurs, have victimlean forward so that their head is between their knees. Vomiting may result in aspirationinto lungs causing chemical pneumonitis. Keep victim at rest. Seek medical attention.
Use an extinguishing agent suitable for the surrounding fire. Carbon dioxide, water sprayor fog, dry chemical or foam. Cool closed containers exposed to fire with water. Movecontainers from fire area if this can be done without risk.
Fire-fighting measures
Extinguishing media
Special protectiveequipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
5 .
Do not spray water directly into containers due to the danger of slop over.
Suitable :
Not suitable :Hazardous thermaldecomposition products
: Incomplete combustion may produce: Calcium, nitrogen oxides, carbon oxides, sulfuroxides, phosphorus oxides, magnesium, sodium and zinc.
May form combustible mixtures with air at temperatures at or above the flashpoint. Heator contact with oxidizing materials will greatly increase fire and explosion hazards.Vapors may accumulate in low or confined areas or travel a considerable distance to asource of ignition and flash back.
:Flammability of the product
Date of issue : 07/23/2009 Page: 2/610/02/2012
HD7
No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Avoid all possible sources of ignition (spark or flame). Do not touch or walkthrough spilled material. Avoid breathing vapor or mist. Wear appropriate respiratorwhen ventilation is inadequate. Provide adequate ventilation. Put on appropriatepersonal protective equipment (see section 8). Wear protective equipment includingrubber boots.
Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Prevent entry into sewers, water courses, basements or confined areas. Washspillages into an effluent treatment plant or proceed as follows. Contain and collectspillage with non-combustible, absorbent material e.g. sand, earth, vermiculite ordiatomaceous earth and place in container for disposal according to local regulations(see section 13). Dispose of via a licensed waste disposal contractor. Contaminatedabsorbent material may pose the same hazard as the spilled product. Note: see section1 for emergency contact information and section 13 for waste disposal.
Environmental precautions
Accidental release measures
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air).
Personal precautions :
Large spill :
6 .
Stop leak if without risk. Move containers from spill area. Pump up using an explosion-proof pump. Absorb with an inert material and place in an appropriate waste disposalcontainer. Dispose of via a licensed waste disposal contractor.
Small spill :Methods for cleaning up
Store in accordance with local regulations. Store in original container protected fromdirect sunlight in a dry, cool and well-ventilated area, away from incompatible materials(see section 10) and food and drink. Keep container tightly closed and sealed until readyfor use. Containers that have been opened must be carefully resealed and kept uprightto prevent leakage. Do not store in unlabeled containers. Use appropriate containmentto avoid environmental contamination.
Put on appropriate personal protective equipment (see section 8). Eating, drinking andsmoking should be prohibited in areas where this material is handled, stored andprocessed. Workers should wash hands and face before eating, drinking and smoking.Do not ingest. Avoid contact with eyes, skin and clothing. Wear chemical resistantclothing if prolonged skin contact is likely. Chemical splash goggles. Avoid breathingvapor or mist. Wear appropriate respirator when ventilation is inadequate. Use withadequate ventilation. Wash thoroughly after handling. Launder contaminated clothingbefore reuse. Keep in the original container or an approved alternative made from acompatible material, kept tightly closed when not in use. Empty containers retainproduct residue and can be hazardous. Do not reuse container.
Handling and storageHandling
Storage
:
:
7 .
Exposure controls/personal protectionConsult local authorities for acceptable exposure limits.
8 .
Engineering measures : No special ventilation requirements. Good general ventilation should be sufficient tocontrol worker exposure to airborne contaminants. If this product contains ingredientswith exposure limits, use process enclosures, local exhaust ventilation or otherengineering controls to keep worker exposure below any recommended or statutorylimits. Use of mechanical ventilation is recommended.
Recommended monitoringprocedures
: If this product contains ingredients with exposure limits, personal, workplace atmosphereor biological monitoring may be required to determine the effectiveness of the ventilationor other control measures and/or the necessity to use respiratory protective equipment.
Date of issue : 07/23/2009 Page: 3/610/02/2012
HD7
Exposure controls/personal protection8 .
Personal protection
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period. Appropriatetechniques should be used to remove potentially contaminated clothing. Washcontaminated clothing before reusing. Ensure that eyewash stations and safety showersare close to the workstation location.
Environmental exposurecontrols
: Emissions from ventilation or work process equipment should be checked to ensure theycomply with the requirements of environmental protection legislation. In some cases,fume scrubbers, filters or engineering modifications to the process equipment will benecessary to reduce emissions to acceptable levels.
Eyes
Personal protectiveequipment (Pictograms)
:
Wear chemical resistant clothing if prolonged skin contact is likely.
Neoprene gloves./ Nitrile gloves.
A respirator is not needed under normal and intended conditions of product use. Wearan appropriate NIOSH approved respirator if concentration levels exceed the safeexposure limits.
Splash goggles. Safety glasses with side shields.
:
SkinRespiratory
:::
Hands
HMIS Code/Personalprotective equipment
: x
Liquid. [Oily liquid.]
-18°C (-0.4°F)0.88Partially soluble in the following materials: cold water and hot water.
Mild.Brown.
Melting/freezing point
Physical and chemical propertiesPhysical state
Specific gravitySolubility
OdorColor
:
:::::
Flash point : Open cup: >147°C (>296.6°F)413°C (775.4°F):Auto-ignition temperature
9 .
The product is stable.Under normal conditions of storage and use, hazardous polymerization will not occur.
Under normal conditions of storage and use, hazardous decomposition products shouldnot be produced.
Heat or contact with oxidizing materials will greatly increase fire and explosion hazards.
Stability and reactivityStability
Conditions to avoid
Hazardous decompositionproducts
Hazardous polymerization:
:
:
:
10 .
:Materials to avoid Reactive or incompatible with the following materials: oxidizing materials.
Toxicological information11 .Acute toxicity
Inhalation No known significant effects or critical hazards.Low oral toxicity; vomiting may present an aspiration hazard. Vomiting may result inaspiration into lungs causing chemical pneumonitis.
No known significant effects or critical hazards.Skin
Ingestion
:
::
Date of issue : 07/23/2009 Page: 4/610/02/2012
HD7
Toxicological information11 .Zinc C1-C14 Alkydithiophosphate is an eye irritant at concentration of 5% or greater.Eyes :
Ecological informationEnvironmental effects : No known significant effects or critical hazards.
12 .
The generation of waste should be avoided or minimized wherever possible. Emptycontainers or liners may retain some product residues. This material and its containermust be disposed of in a safe way. Dispose of surplus and non-recyclable products viaa licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protectionand waste disposal legislation and any regional local authority requirements. Avoiddispersal of spilled material and runoff and contact with soil, waterways, drains andsewers.
Waste disposal
Disposal considerations
Disposal should be in accordance with applicable regional, national and local laws and regulations.
:
13 .
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTIONfor additional handling information and protection of employees.
Transport information14 .AERG
IATA :TDG / IMDG/ Not regulated.
: Not applicable.Regulatory information
Regulatory information
CEPA Toxic substances: None of the components are listed.Canadian ARET: None of the components are listed.Canadian NPRI: None of the components are listed.Alberta Designated Substances: None of the components are listed.Ontario Designated Substances: None of the components are listed.Quebec Designated Substances: None of the components are listed.
WHMIS (Canada) Not controlled under WHMIS (Canada).
International regulationsInternational lists
:
:
Canada
15 .
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulationsand the MSDS contains all the information required by the Controlled Products Regulations.
Canadian lists :
Canada inventory(DSL/NDSL)
: Canada inventory: All components are listed or exempted.
This product, (and its ingredients) is (are) listed on national inventories, or is (are)exempted from being listed, in Australia (AICS), in Europe (EINECS/ELINCS), in Korea(TCCL), in Japan (METI), in the Philippines (RA6969).
Other informationNOT EXPECTED TO PRODUCE SIGNIFICANT ADVERSE HEALTH EFFECTS WHENTHE RECOMMENDED INSTRUCTIONS FOR USE ARE FOLLOWED.
Label requirements :
16 .
Date of issue : 07/23/2009 Page: 5/610/02/2012
HD7
Other information16 .
References
Hazardous MaterialInformation System (U.S.A.)
01
0
National Fire ProtectionAssociation (U.S.A.)
Health
Special
Instability
Flammability
:
:
:The customer is responsible for determining the PPE code for this material.
4- Extreme3- Serious
2- Moderate1- Slight
0- MinimalSee section 8 for more detailed
information on personal protection.
HAZARD RATINGS
Health
Physical Hazard
0
1Fire hazard
x
0
Health
Personal protection
Date of issueDate of previous issueVersion :
::
07/23/200905/15/20082
Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above namedsupplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein. Final determination of suitability of any material is the sole responsibility of theuser. All materials may present unknown hazards and should be used with caution. Although certain hazards aredescribed herein, we cannot guarantee that these are the only hazards that exist.
ANSI Z400.1, MSDS Standard, 2004. - Manufacturer's Material Safety Data Sheet. -Canada Gazette Part II, Vol. 122, No. 2. Registration SOR/88-64, 31 December 1987.Hazardous Products Act "Ingredient Disclosure List" - Canadian Transport of DangerousGoods, Regulations and Schedules, Clear Language version 2005.
Date of issue : 07/23/2009 Page: 6/610/02/2012
10/02/201207/23/200903
MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Material name INDUSTRIAL HYDRAULIC OIL
Version # 02
Issue date 07-31-2012
Revision date 07-31-2012
Supersedes date 07-31-2012
CAS # Mixture
Product code 184
Product use Hydraulic oil.
Synonym(s) ISO GRADES 22, 32, 46, 68, 100, 150, MV22, HVI 36
Manufacturer information
Manufacturer Consumers' Co-operative Refineries Limited
Address P.O. Box 260; 9th Avenue North
Regina, SK S4P 3A1 Canada
Telephone (306) 721-5353
Supplier Federated Co-operatives Limited
Address P.O. Box 1050, 401 - 22nd Street East
Saskatoon SK S7K 3M9 Canada
Telephone (306) 244-3447
24 Hour Emergency
Telephone
(613) 996-6666 - Canutec
2. Hazards Identification
Physical state Liquid.
Appearance Oily liquid.
Emergency overview Low hazard for usual industrial or commercial handling by trained personnel.
OSHA regulatory status This product is not hazardous according to OSHA 29CFR 1910.1200.
Potential health effects
Routes of exposure Eye contact. Skin contact. Ingestion. Inhalation.
Eyes Direct contact with eyes may cause temporary irritation.
Skin Prolonged skin contact may cause temporary irritation.
Inhalation May cause respiratory tract irritation.
Ingestion Under normal conditions of intended use, this material does not pose a risk to health.
Chronic effects No data available.
Potential environmental effects No special environmental precautions required.
3. Composition / Information on Ingredients
The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR 1910.1200.
4. First Aid Measures
First aid procedures
Eye contact Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least20 minutes, occasionally lifting the upper and lower eyelids. Get medical attention if symptomsoccur.
Skin contact In case of contact, flush skin with plenty of water for at least 20 minutes, while removingcontaminated shoes and clothes. Wash contaminated skin with soap and water. Washcontaminated clothing before reuse. Thoroughly clean shoes before reuse. Get medical attentionif irritation develops and persists.
Inhalation If fumes or combustion products are inhaled move victim to fresh air. Get medical attention if anydiscomfort occurs.
CPH MSDS NA
1 / 5
INDUSTRIAL HYDRAULIC OIL CPH MSDS NA
909875 Version #: 02 Revision date: 07-31-2012 Issue date: 07-31-2012
Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medicalattention if any discomfort occurs.
Notes to physician Treat symptomatically.
General advice If you feel unwell, seek medical advice (show the label where possible).
5. Fire Fighting Measures
Extinguishing media
Suitable extinguishing
mediaExtinguish with water spray, carbon dioxide, dry chemical or material appropriate for thesurrounding fire.
Unsuitable extinguishing
mediaNone.
Protection of firefighters
Specific hazards arising
from the chemicalBy heating and fire, toxic vapors/gases may be formed.
Fire fighting
equipment/instructionsFirefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
Hazardous combustion
productsNo data available.
6. Accidental Release Measures
Personal precautions In case of spills, beware of slippery floors and surfaces. Wear suitable protective clothing andgloves.
Environmental precautions Avoid discharge into drains, water courses or onto the ground. Prevent spreading over a widearea (e.g. by containment or oil barriers).
Methods for containment Collect and dispose of spillage as indicated in Section 13 of the MSDS.
Methods for cleaning up Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
Other information Clean up in accordance with all applicable regulations.
7. Handling and Storage
Handling Observe good industrial hygiene practices. Use appropriate Personal Protective Equipment.
Storage Store in original tightly closed container. Keep in a cool, well-ventilated place.
8. Exposure Controls / Personal Protection
Occupational exposure limits No exposure limits noted for ingredient(s).
Engineering controls General ventilation is normally adequate.
Personal protective equipment
Eye / face protection Wear approved safety glasses or goggles.
Skin protection Wear appropriate clothing to prevent repeated or prolonged skin contact. Wear protective gloves.Neoprene or nitrile gloves are recommended.
Respiratory protection No personal respiratory protective equipment normally required.
General hygiene
considerationsHandle in accordance with good industrial hygiene and safety practices.
9. Physical & Chemical Properties
Appearance Oily liquid.
Physical state Liquid.
Form Liquid.
Color Brown.
Odor Mild.
Odor threshold Not available.
pH Not available.
Vapor pressure Not available.
Vapor density Not available.
Boiling point Not available.
CPH MSDS NA
2 / 5
INDUSTRIAL HYDRAULIC OIL CPH MSDS NA
909875 Version #: 02 Revision date: 07-31-2012 Issue date: 07-31-2012
Melting point/Freezing point 14 °F (-10 °C)
Solubility (water) Partially soluble in cold and hot water.
Specific gravity 0.86
Flash point > 296.6 °F (> 147 °C) Open Cup
Flammability limits in air,
upper, % by volume
Not available.
Flammability limits in air,
lower, % by volume
Not available.
Auto-ignition temperature 775.4 °F (413 °C)
10. Chemical Stability & Reactivity Information
Chemical stability Material is stable under normal conditions.
Conditions to avoid No data available.
Incompatible materials None known.
Hazardous decomposition
productsNone expected under normal conditions of use.
Possibility of hazardous
reactionsWill not occur.
11. Toxicological Information
Sensitization No data available.
Acute effects No data available.
Local effects None known.
Chronic effects Chronic effects are not expected when this product is used as intended.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Mutagenicity Not expected to be mutagenic.
Neurological effects No data available.
Reproductive effects Contains no ingredient listed as toxic to reproduction.
Teratogenicity Not classified.
12. Ecological Information
Ecotoxicity No data on possible environmental effects have been found.
Environmental effects The product components are not classified as environmentally hazardous. However, this does notexclude the possibility that large or frequent spills can have a harmful or damaging effect on theenvironment.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulation /
AccumulationNot available.
13. Disposal Considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose inaccordance with all applicable regulations.
Waste from residues / unused
productsDispose of waste and residues in accordance with local authority requirements.
Contaminated packaging Since emptied containers retain product residue, follow label warnings even after container isemptied.
14. Transport Information
DOT
Not regulated as a hazardous material by DOT.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
CPH MSDS NA
3 / 5
INDUSTRIAL HYDRAULIC OIL CPH MSDS NA
909875 Version #: 02 Revision date: 07-31-2012 Issue date: 07-31-2012
TDG
Not regulated as dangerous goods.
15. Regulatory Information
US federal regulations This product is not hazardous according to OSHA 29CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)
None
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - NoDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
Section 302 extremely
hazardous substance (40
CFR 355, Appendix A)
No
Section 311/312 (40 CFR
370)No
Drug Enforcement
Administration (DEA) (21 CFR
1308.11-15)
Not controlled
WHMIS status Non-controlled
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) NoChina
European Inventory of Existing Commercial ChemicalSubstances (EINECS)
YesEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) YesJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory NoNew Zealand
Philippine Inventory of Chemicals and Chemical Substances(PICCS)
YesPhilippines
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s)
Toxic Substances Control Act (TSCA) Inventory NoUnited States & Puerto Rico
State regulations
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
US. Massachusetts RTK - Substance List
Not regulated.
US. New Jersey Worker and Community Right-to-Know Act
Not regulated.
US. Pennsylvania RTK - Hazardous Substances
Not regulated.
CPH MSDS NA
4 / 5
INDUSTRIAL HYDRAULIC OIL CPH MSDS NA
909875 Version #: 02 Revision date: 07-31-2012 Issue date: 07-31-2012
16. Other Information
Further information HMIS® is a registered trade and service mark of the NPCA.
HMIS® ratings Health: 0Flammability: 1Physical hazard: 0
NFPA ratings Health: 0Flammability: 1Instability: 0
Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither theabove named supplier nor any of its subsidiaries assumes any liability whatsoever forcompleteness of the information contained herein. Final determination of suitability of any materialis the sole responsibility of the user. All materials may present unknown hazards and should beused with caution. Although certain hazards are described herein, we cannot guarantee that theseare the only hazards that exist.
CPH MSDS NA
5 / 5
INDUSTRIAL HYDRAULIC OIL CPH MSDS NA
909875 Version #: 02 Revision date: 07-31-2012 Issue date: 07-31-2012
MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Material name PROPANE- LIQUEFIED PETROLEUM GAS
Version # 01
Issue date 07-19-2012
Revision date -
Supersedes date -
CAS # Mixture
Product code 127
Product use Various.
Synonym(s) Unstenched Propane * Stenched Propane * HD-5 Propane * Standard Propane
Manufacturer information
Manufacturer Consumers' Co-operative Refineries Limited
Address P.O. Box 260; 9th Avenue North
Regina, SK S4P 3A1 Canada
Telephone (306) 721-5353
Supplier Federated Co-operatives Limited
Address P.O. Box 1050, 401 - 22nd Street East
Saskatoon SK S7K 3M9 Canada
Telephone (306) 244-3447
24 Hour Emergency
Telephone
(613) 996-6666 - Canutec
2. Hazards Identification
Physical state Gas.
Appearance Colorless liquefied gas.
Emergency overview DANGER
Extremely flammable gas. High pressure gas. Gas reduces oxygen available for breathing.
Contact with liquefied gas might cause frostbites, in some cases with tissue damage. In a fire or ifheated, a pressure increase will occur and the container may burst or explode.Static accumulating flammable materials can become electrostatically charged even in bondedand grounded equipment. Sparks may ignite material and vapor may cause flash fire (orexplosion).
OSHA regulatory status This product is hazardous according to OSHA 29 CFR 1910.1200.
Potential health effects
Routes of exposure Inhalation. Eyes. Skin.
Eyes Exposure to rapidly expanding gas or vaporizing liquid may cause frostbite ("cold burn").
Skin Exposure to rapidly expanding gas or vaporizing liquid may cause frostbite ("cold burn").
Inhalation Suffocation (asphyxiant) hazard - if allowed to accumulate to concentrations that reduce oxygenbelow safe breathing levels. Nasal and respiratory tract irritation, central nervous system effectsincluding excitation, euphoria, contracted eye pupils, dizziness, drowsiness, blurred vision,fatigue, nausea, headache, loss of reflexes, tremors, convulsions, seizures, loss ofconsciousness, coma, respiratory arrest and sudden death could occur as a result of long termand/or high concentration exposure to vapors. May also cause anemia and irregular heart rhythm.
Ingestion This material is a gas under normal atmospheric conditions and ingestion is unlikely.
Target organs Respiratory tract. Eyes. Central nervous system.
Chronic effects May cause central nervous system effects. Components have been shown to be weak cardiacsensitizers which can result in cardiac arrhythmia and ventricular fibrillation.
Potential environmental effects Not expected to be harmful to aquatic organisms.
CPH MSDS NA
1 / 6
PROPANE- LIQUEFIED PETROLEUM GAS CPH MSDS NA
909445 Version #: 01 Revision date: - Issue date: 07-19-2012
Components CAS # Percent
3. Composition / Information on Ingredients
74-98-6 100Propane
75-08-1 0.005Ethanethiol
4. First Aid Measures
First aid procedures
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention immediately.
Skin contact Wash frost-bitten areas with plenty of water. Do not remove clothing. Get medical attentionimmediately.
Inhalation Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.Call a physician or poison control center immediately.
Ingestion Ingestion is not a typical route of exposure for gases or liquefied gases.
Notes to physician Treat symptomatically.
5. Fire Fighting Measures
Flammable properties Extremely flammable gas. Gas forms mixtures with air which can catch fire and burn withexplosive violence. Vapors are heavier than air and invisible mixture spreads easily and mayaccumulate in low or confined areas, travel considerable distance to source of ignition and flashback. Runoff to sewer may create fire or explosion hazard.
Extinguishing media
Suitable extinguishing
mediaDry chemical, CO2, water spray, fog, or foam.
Fire fighting
equipment/instructionsSelf-contained breathing apparatus, operated in positive pressure mode and full protectiveclothing must be worn in case of fire.
Move container from fire area if it can be done without risk.
Do not extinguish fires unless gas flow can be stopped safely; explosive re-ignition may occur.Promptly isolate the scene by removing all persons from the vicinity of the incident. No actionshall be taken involving any personal risk or without suitable training. For fires involving thismaterial, do not enter any enclosed or confined fire space without proper protective equipment,including self-contained breathing apparatus. Stop flow of material. Use water to keep fireexposed containers cool and to protect personnel effecting shutoff. If a leak or spill has notignited, use water spray to disperse the vapors and to protect personnel attempting to stop leak.Prevent runoff from fire control or dilution from entering streams, sewers or drinking water supply.
Hazardous combustion
productsCarbon oxides.
6. Accidental Release Measures
Personal precautions Evacuate the area promptly. No action shall be taken involving any personal risk or withoutsuitable training. Keep unnecessary personnel away.
Ensure adequate ventilation. In case of inadequate ventilation, use respiratory protection. Wearappropriate personal protective equipment (See Section 8).
Environmental precautions Should not be released into the environment. Prevent further leakage or spillage if safe to do so.Prevent from entering into soil, ditches, sanitary sewers, waterways and/or groundwater.
Methods for cleaning up Ventilate well, stop flow of gas or liquid if possible. Immediately contact emergency personnel.
7. Handling and Storage
Handling Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and equipment.These alone may be insufficient to remove static electricity.Wear appropriate personal protective equipment (See Section 8). Eating, drinking, and smokingshould be prohibited in areas where this material is handled, stored, and processed. Do notbreathe gas. Do not get in eyes, on skin, on clothing. Use only with adequate ventilation.
Storage Store in accordance with local, regional, national, and international regulations. Secure cylindersin an upright position at all times, close all valves when not in use. Store in a cool, dry,well-ventilated place. Keep container tightly closed and sealed until ready for use. Protectcylinders from damage.
CPH MSDS NA
2 / 6
PROPANE- LIQUEFIED PETROLEUM GAS CPH MSDS NA
909445 Version #: 01 Revision date: - Issue date: 07-19-2012
8. Exposure Controls / Personal Protection
Occupational exposure limits
US. ACGIH Threshold Limit Values
ValueTypeComponents
TWAPropane (CAS 74-98-6) 1000 ppm
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueTypeComponents
PELPropane (CAS 74-98-6) 1800 mg/m3
1000 ppm
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
ValueTypeComponents
TWAPropane (CAS 74-98-6) 1000 ppm
Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and
Safety Regulation 296/97, as amended)
ValueTypeComponents
TWAPropane (CAS 74-98-6) 1000 ppm
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)
ValueTypeComponents
TWAPropane (CAS 74-98-6) 1000 ppm
Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)
ValueTypeComponents
TWAPropane (CAS 74-98-6) 1800 mg/m3
1000 ppm
Engineering controls Use process enclosures, local exhaust ventilation, or other engineering controls to controlairborne levels below recommended exposure limits. The engineering controls also need to keepgas, vapor, or dust concentrations below any lower explosive limits.
Personal protective equipment
Eye / face protection Wear approved safety glasses or goggles.
Skin protection Wear protective clothing appropriate for the risk of exposure.
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposurelimits (where applicable) or to an acceptable level (in countries where exposure limits have notbeen established), an approved respirator must be worn.
General hygiene
considerationsDo not eat, drink or smoke when using the product. Wash thoroughly after handling. Provideeyewash station and safety shower. Handle in accordance with good industrial hygiene and safetypractices.
9. Physical & Chemical Properties
Appearance Colorless liquefied gas.
Physical state Gas.
Form Compressed liquefied gas.
Color Colorless
Odor Boiling cabbage if stenched.
Odor threshold 4800 ppm
pH Not available.
Vapor pressure 1034.1 - 1241 kPa
Vapor density 1.6
Boiling point -43.6 °F (-42 °C)
Melting point/Freezing point -292 °F (-180 °C) / -302.6 °F (-185.89 °C)
Solubility (water) 6.5 % v/v (20 °C)
Specific gravity 0.58
Flash point -150 °F (-101.1 °C) Pensky-Martens Closed Cup
Flammability limits in air,
upper, % by volume
9.5 %
CPH MSDS NA
3 / 6
PROPANE- LIQUEFIED PETROLEUM GAS CPH MSDS NA
909445 Version #: 01 Revision date: - Issue date: 07-19-2012
Flammability limits in air,
lower, % by volume
2.2 %
Auto-ignition temperature 809.6 °F (432 °C)
VOC 100 %
Evaporation rate > 1 (Ether (anhydrous)=1)
Molecular weight 44.11 g/mol
Molecular formula C3-H8
Other data
Critical temperature 205.9 °F (96.6 °C)
10. Chemical Stability & Reactivity Information
Chemical stability Stable under normal temperature conditions and recommended use.
Conditions to avoid In a fire or if heated, a pressure increase will occur and the container may burst or explode.
Incompatible materials Oxidizing agents. Reducing agents. Acids. Alkalis.
Hazardous decomposition
productsNone known.
Possibility of hazardous
reactionsPolymerization will not occur.
11. Toxicological Information
Test Results
Toxicological data
Components Species
Propane (CAS 74-98-6)
LC50 Rat
Inhalation
Acute
> 1442.847 mg/l, 15 Minutes
Sensitization Not available.
Acute effects Suffocation (asphyxiant) hazard - if allowed to accumulate to concentrations that reduce oxygenbelow safe breathing levels. Exposure to rapidly expanding gas or vaporizing liquid may causefrostbite ("cold burn").
Chronic effects May cause central nervous system effects.
12. Ecological Information
Ecotoxicity Not expected to be harmful to aquatic organisms.
Persistence and degradability Not available.
Bioaccumulation /
AccumulationNot available.
Partition coefficient
Propane 2.36
13. Disposal Considerations
Waste codes D001: Waste Flammable material with a flash point <140 °F
Disposal instructions Dispose in accordance with all applicable regulations. Empty containers may contain productresidues. Do not puncture or incinerate even when empty. This material and/or its container mustbe disposed of as hazardous waste. Return the empty cylinder to the supplier.
14. Transport Information
DOT
UN1978UN number
Basic shipping requirements:
PropaneProper shipping name
2.1Hazard class
19, T50Special provisions
Additional information:
306Packaging exceptions
CPH MSDS NA
4 / 6
PROPANE- LIQUEFIED PETROLEUM GAS CPH MSDS NA
909445 Version #: 01 Revision date: - Issue date: 07-19-2012
304Packaging non bulk
314, 315Packaging bulk
100Reportable quantity
IATA
UN1978UN number
PropaneUN proper shipping name
2.1Transport hazard class(es)
10LERG code
IMDG
UN1978UN number
PROPANEUN proper shipping name
2.1Transport hazard class(es)
F-D, S-UEmS No.
TDG
PROPANEProper shipping name
2.1Hazard class
UN1978UN number
NoMarine pollutant
15. Regulatory Information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)
Propane: 100
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - YesDelayed Hazard - NoFire Hazard - YesPressure Hazard - YesReactivity Hazard - No
Section 302 extremely
hazardous substance (40
CFR 355, Appendix A)
Yes
Section 311/312 (40 CFR
370)Yes
Clean Water Act (CWA) Section
112(r) (40 CFR 68.130)Hazardous substance
Drug Enforcement
Administration (DEA) (21 CFR
1308.11-15)
Not controlled
Canadian regulations This product has been classified in accordance with the hazard criteria of the CPR and the MSDScontains all the information required by the CPR.
WHMIS status Controlled
WHMIS classification A - Compressed GasB1 - Flammable Gases
WHMIS labeling
CPH MSDS NA
5 / 6
PROPANE- LIQUEFIED PETROLEUM GAS CPH MSDS NA
909445 Version #: 01 Revision date: - Issue date: 07-19-2012
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial ChemicalSubstances (EINECS)
YesEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) YesJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances(PICCS)
YesPhilippines
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s)
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
State regulations
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
US - New Jersey RTK - Substances: Listed substance
Propane (CAS 74-98-6) Listed.
US. Massachusetts RTK - Substance List
Propane (CAS 74-98-6) Listed.
US. New Jersey Worker and Community Right-to-Know Act
Propane (CAS 74-98-6) 500 LBS
US. Pennsylvania RTK - Hazardous Substances
Propane (CAS 74-98-6) Listed.
16. Other Information
Further information HMIS® is a registered trade and service mark of the NPCA.
HMIS® ratings Health: 1Flammability: 4Physical hazard: 0
NFPA ratings Health: 1Flammability: 4Instability: 0
Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither theabove named supplier nor any of its subsidiaries assumes any liability whatsoever forcompleteness of the information contained herein. Final determination of suitability of any materialis the sole responsibility of the user. All materials may present unknown hazards and should beused with caution. Although certain hazards are described herein, we cannot guarantee that theseare the only hazards that exist.
CPH MSDS NA
6 / 6
PROPANE- LIQUEFIED PETROLEUM GAS CPH MSDS NA
909445 Version #: 01 Revision date: - Issue date: 07-19-2012
MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Material name SONIC 2 CYCLE OIL
Version # 02
Issue date 13-December-2011
Revision date 08-January-2015
Supersedes date 13-December-2011
CAS # Mixture
Product code 111
Product use 2 cycle lubricant.
Manufacturer information
Manufacturer Consumers' Co-operative Refineries Limited
Address P.O. Box 260; 9th Avenue North
Regina, SK S4P 3A1 Canada
Telephone (306) 721-5353/(306) 719-4353
Supplier Federated Co-operatives Limited
Address P.O. Box 1050, 401 - 22nd Street East
Saskatoon SK S7K 3M9 Canada
Telephone (306) 244-3447
24 Hour Emergency
Telephone
(613) 996-6666 - Canutec
2. Hazards Identification
Physical state Liquid.
Appearance Oily liquid.
Emergency overview WARNING! Combustible liquid and vapor. Harmful if swallowed - may enter lungs if swallowed orvomited. May cause skin irritation. May cause central nervous system effects. May cause damageto the kidneys.
OSHA regulatory status This product is hazardous according to OSHA 29 CFR 1910.1200.
Potential health effects
Routes of exposure Inhalation. Skin contact. Ingestion.
Eyes Direct contact with eyes may cause temporary irritation.
Skin Prolonged or repeated contact may dry skin and cause irritation.
Inhalation Overexposure to mists/vapors of this product may cause headache, dizziness, nausea, andrespiratory tract irritation.
Ingestion Swallowing or vomiting of the liquid may result in aspiration into the lungs.
Target organs Contains material which causes damage to the following organs: kidneys, liver, upper respiratorytract, skin, central nervous system (CNS), eye, lens or cornea. Health studies have shown thatmany petroleum hydrocarbons pose potential human health risks which may vary from person toperson. As a precaution, exposure should be minimized.
Chronic effects Exposure over a long period of time may cause central nervous system effects. Symptoms may bedelayed.
Carcinogenicity, Mutagenicity and Teragenocity: There is no data to indicate that any componentpresent at greater than 0.1% may present a risk.
Signs and symptoms Overexposure to mists/vapors of this product may cause headache, dizziness, nausea, andrespiratory tract irritation. Prolonged or repeated contact may dry skin and cause irritation. Dropletsof the product aspirated into the lungs through ingestion or vomiting may cause a serious chemicalpneumonia.
Potential environmental effects Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
SONIC 2 CYCLE OIL CPH MSDS NA
906157 Version #: 02 Revision date: 08-January-2015 Issue date: 13-December-2011 1 / 7
Components CAS # Percent
3. Composition / Information on Ingredients
8052-41-3 10-30Stoddard solvent
Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are inpercent by volume.
4. First Aid Measures
First aid procedures
Inhalation If symptomatic, move to fresh air. Get medical attention if symptoms persist.
Skin contact Wash area with soap and water. Get medical attention if irritation develops or persists.
Eye contact Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least20 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately.
Ingestion Call a physician or poison control center immediately. DO NOT induce vomiting. If victim is fullyconscious, give a cupful of water. Never give anything by mouth to an unconscious person. Ifvomiting occurs, keep head lower than the hips to help prevent aspiration. Never give anything bymouth to an unconscious person.
Notes to physician Treat symptomatically.
5. Fire Fighting Measures
Flammable properties Combustible liquid and vapor. Material will float and may ignite on surface of water. Containersmay explode when heated.
Extinguishing media
Suitable extinguishing
media
Carbon dioxide (CO2). Foam. Dry chemical. Water fog.
Unsuitable extinguishing
media
Do not use water jet as an extinguisher, as this will spread the fire.
Fire fighting
equipment/instructions
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Specific methods Cool containers exposed to heat with water spray and remove container, if no risk is involved.
Hazardous combustion
products
Carbon oxides.
6. Accidental Release Measures
Personal precautions Ensure adequate ventilation. Wear suitable protective clothing. See Section 8 of the MSDS forPersonal Protective Equipment.
Environmental precautions Collect and dispose of spillage as indicated in Section 13 of the MSDS.
Methods for containment Eliminate all ignition sources. Dike the spilled material, where this is possible. Prevent entry intowaterways, sewer, basements or confined areas.
Methods for cleaning up Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Use a non-combustiblematerial like vermiculite, sand or earth to soak up the product and place into a container for laterdisposal.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece).
Never return spills to original containers for re-use. Following product recovery, flush area withwater. Clean surface thoroughly to remove residual contamination.
Other information Absorb spill with vermiculite or other inert material, then place in a container for chemical waste.
7. Handling and Storage
Handling Use only with adequate ventilation. Wash thoroughly after handling. Observe good industrialhygiene practices.
Storage Keep container tightly closed and in a well-ventilated place. Store in closed original container atroom temperature. Store away from incompatible materials.
SONIC 2 CYCLE OIL CPH MSDS NA
906157 Version #: 02 Revision date: 08-January-2015 Issue date: 13-December-2011 2 / 7
8. Exposure Controls / Personal Protection
Occupational exposure limits
US. ACGIH Threshold Limit Values
ValueTypeComponents
TWA 100 ppmStoddard solvent (CAS8052-41-3)
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueTypeComponents
PEL 2900 mg/m3Stoddard solvent (CAS8052-41-3)
500 ppm
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
ValueTypeComponents
TWA 572 mg/m3Stoddard solvent (CAS8052-41-3)
100 ppm
Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and
Safety Regulation 296/97, as amended)
ValueTypeComponents
STEL 580 mg/m3Stoddard solvent (CAS8052-41-3)
TWA 290 mg/m3
Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act)
ValueTypeComponents
TWA 100 ppmStoddard solvent (CAS8052-41-3)
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)
ValueTypeComponents
TWA 100 ppmStoddard solvent (CAS8052-41-3)
Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)
ValueTypeComponents
TWA 525 mg/m3Stoddard solvent (CAS8052-41-3)
100 ppm
Mexico. Occupational Exposure Limit Values
ValueTypeComponents
STEL 1050 mg/m3Stoddard solvent (CAS8052-41-3)
200 ppm
TWA 523 mg/m3
100 ppm
Biological limit values No biological exposure limits noted for the ingredient(s).
Engineering controls Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk ofinhalation of vapors.
Personal protective equipment
Eye / face protection Use approved safety goggles or face shield.
Skin protection Wear appropriate chemical resistant clothing to prevent any possibility of skin contact.
Respiratory protection In case of inadequate ventilation, use respiratory protection.
Hand protection Wear appropriate chemical resistant gloves. Butyl rubber gloves are recommended, but be awarethat the liquid may penetrate the gloves. Frequent change is advisable.
SONIC 2 CYCLE OIL CPH MSDS NA
906157 Version #: 02 Revision date: 08-January-2015 Issue date: 13-December-2011 3 / 7
General hygiene
considerations
Always observe good personal hygiene measures, such as washing after handling the materialand before eating, drinking, and/or smoking. Routinely wash work clothing and protectiveequipment to remove contaminants.
9. Physical & Chemical Properties
Appearance Oily liquid.
Physical state Liquid.
Form Liquid.
Color Blue.
Odor Solvent.
Odor threshold Not available.
pH Not available.
Vapor pressure Not available.
Vapor density > 1 ( Air=1)
Boiling point Not available.
Melting point/Freezing point -22 °F (-30 °C)
Solubility (water) Slight
Specific gravity 0.87
Flash point 109.0 °F (42.8 °C) Closed Cup
Flammability limits in air,
upper, % by volume
Not available.
Flammability limits in air,
lower, % by volume
Not available.
Auto-ignition temperature Not available.
10. Chemical Stability & Reactivity Information
Chemical stability Material is stable under normal conditions.
Conditions to avoid Heat, sparks, flames. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition
products
No hazardous decomposition products are known.
Possibility of hazardous
reactions
Will not occur.
11. Toxicological Information
Sensitization None known.
Acute effects Harmful if swallowed - may enter lungs if swallowed or vomited. Prolonged or repeated contactmay dry skin and cause irritation. Overexposure to mists/vapors of this product may causeheadache, dizziness, nausea, and respiratory tract irritation.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.There is no data to indicate that any component present at greater than 0.1% may present a risk.
IARC Monographs. Overall Evaluation of Carcinogenicity
Stoddard solvent (CAS 8052-41-3) 3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Mutagenicity There is no data to indicate that any component present at greater than 0.1% may present a risk.
Teratogenicity There is no data to indicate that any component present at greater than 0.1% may present a risk.
12. Ecological Information
Ecotoxicity Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Persistence and degradability No data available.
Bioaccumulation /
accumulation
No data available.
SONIC 2 CYCLE OIL CPH MSDS NA
906157 Version #: 02 Revision date: 08-January-2015 Issue date: 13-December-2011 4 / 7
Bioaccumulative potential
Octanol/water partition coefficient log Kow
Stoddard solvent (CAS 8052-41-3) 3.16 - 7.15
Mobility in environmental
media
No data available.
13. Disposal Considerations
Waste codes D001: Waste Flammable material with a flash point <140 °F
Disposal instructions Must be incinerated in a suitable incineration plant holding a permit delivered by the competentauthorities. Do not allow this material to drain into sewers/water supplies. Do not contaminateponds, waterways or ditches with chemical or used container. When this product as supplied is tobe discarded as waste, it may meet the definition of a RCRA waste under 40 CFR 261.
Waste from residues / unused
products
Dispose of waste and residues in accordance with local authority requirements.
Contaminated packaging Since emptied containers retain product residue, follow label warnings even after container isemptied.
14. Transport Information
DOT
UN1993UN number
Basic shipping requirements:
Flammable liquids, n.o.s. (Stoddard solvent)Proper shipping name
3Hazard class
3Labels required
IIIPacking group
NoMarine pollutant
Environmental hazards
B1, B52, IB3, T4, TP1, TP29Special provisions
Additional information:
150Packaging exceptions
203Packaging non bulk
242Packaging bulk
IATA
UN1993UN number
Flammable liquid, n.o.s. (Stoddard solvent)UN proper shipping name
3Transport hazard class(es)
IIIPacking group
NoEnvironmental hazards
3LERG code
IMDG
UN1993UN number
FLAMMABLE LIQUID, N.O.S. (Stoddard solvent)UN proper shipping name
3Transport hazard class(es)
IIIPacking group
NoMarine pollutant
Environmental hazards
F-E, S-EEmS
TDG
UN1993UN number
FLAMMABLE LIQUID, N.O.S. (Stoddard solvent)Proper shipping name
3Hazard class
IIIPacking group
NoMarine pollutant
15. Regulatory Information
US federal regulations This product is hazardous according to OSHA 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
SONIC 2 CYCLE OIL CPH MSDS NA
906157 Version #: 02 Revision date: 08-January-2015 Issue date: 13-December-2011 5 / 7
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)
None
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - YesDelayed Hazard - YesFire Hazard - YesPressure Hazard - NoReactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
Yes
Drug Enforcement
Administration (DEA) (21 CFR
1308.11-15)
Not controlled
Canadian regulations This product has been classified in accordance with the hazard criteria of the CPR and the MSDScontains all the information required by the CPR.
WHMIS status Controlled
WHMIS classification B3 - Combustible LiquidsD2B - Other Toxic Effects-TOXIC
WHMIS labeling
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial ChemicalSubstances (EINECS)
YesEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) YesJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances(PICCS)
YesPhilippines
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
State regulations This product does not contain a chemical known to the State of California to cause cancer, birthdefects or other reproductive harm.
US - California Hazardous Substances (Director's): Listed substance
Stoddard solvent (CAS 8052-41-3) Listed.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
US. Massachusetts RTK - Substance List
Stoddard solvent (CAS 8052-41-3) Listed.
US. New Jersey Worker and Community Right-to-Know Act
Stoddard solvent (CAS 8052-41-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Stoddard solvent (CAS 8052-41-3)
SONIC 2 CYCLE OIL CPH MSDS NA
906157 Version #: 02 Revision date: 08-January-2015 Issue date: 13-December-2011 6 / 7
16. Other Information
HMIS® ratings Health: 2*Flammability: 2Physical hazard: 0Personal protection: X
NFPA ratings
02
2
Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither theabove named supplier nor any of its subsidiaries assumes any liability whatsoever forcompleteness of the information contained herein. Final determination of suitability of any materialis the sole responsibility of the user. All materials may present unknown hazards and should beused with caution. Although certain hazards are described herein, we cannot guarantee that theseare the only hazards that exist.
Prepared by Not available.
SONIC 2 CYCLE OIL CPH MSDS NA
906157 Version #: 02 Revision date: 08-January-2015 Issue date: 13-December-2011 7 / 7
MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Material name SONIC ATF
Version # 01
Issue date 08-22-2012
Revision date -
Supersedes date -
CAS # Mixture
Product code 1221
Product use Automatic Transmission Fluid.
Synonym(s) SONIC ATF DEXRON III/MERCON; SONIC ATF DEX III
Manufacturer information
Manufacturer CHS Inc.
Address P.O. Box 64089 - Mail station 525
St. Paul, MN 55164-0089
Telephone (651) 424-8438
Supplier Federated Co-operatives Limited
Address P. O. Box 1050; 401 - 22nd Street East
Saskatoon, SK S7K 3M9 Canada
Telephone (306) 244-3447
24 Hour Emergency
Telephone
(613) 996-6666 - Canutec
2. Hazards Identification
Physical state Liquid.
Appearance Liquid.
Emergency overview Low hazard for usual industrial or commercial handling by trained personnel.
OSHA regulatory status This product is not hazardous according to OSHA 29CFR 1910.1200.
Potential health effects
Routes of exposure Eye contact. Skin contact. Ingestion. Inhalation.
Eyes Direct contact with eyes may cause temporary irritation.
Skin Prolonged skin contact may cause temporary irritation.
Inhalation May cause respiratory tract irritation.
Ingestion Under normal conditions of intended use, this material does not pose a risk to health.
Chronic effects No data available.
Potential environmental effects No special environmental precautions required.
Components CAS # Percent
3. Composition / Information on Ingredients
64742-65-0 60-100Distillates (petroleum), solvent-dewaxed heavy paraffinic
4. First Aid Measures
First aid procedures
Eye contact Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least20 minutes, occasionally lifting the upper and lower eyelids. Get medical attention if symptomsoccur.
Skin contact In case of contact, flush skin with plenty of water for at least 20 minutes, while removingcontaminated shoes and clothes. Wash contaminated skin with soap and water. Washcontaminated clothing before reuse. Thoroughly clean shoes before reuse. Get medical attentionif irritation develops and persists.
CPH MSDS NA
1 / 5
SONIC ATF CPH MSDS NA
910066 Version #: 01 Revision date: - Issue date: 08-22-2012
Inhalation If fumes or combustion products are inhaled move victim to fresh air. Get medical attention if anydiscomfort occurs.
Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medicalattention if any discomfort occurs.
Notes to physician Treat symptomatically.
General advice If you feel unwell, seek medical advice (show the label where possible).
5. Fire Fighting Measures
Extinguishing media
Suitable extinguishing
mediaExtinguish with water spray, carbon dioxide, dry chemical or material appropriate for thesurrounding fire.
Unsuitable extinguishing
mediaNone.
Protection of firefighters
Specific hazards arising
from the chemicalBy heating and fire, toxic vapors/gases may be formed.
Fire fighting
equipment/instructionsFirefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
Hazardous combustion
productsNo data available.
6. Accidental Release Measures
Personal precautions In case of spills, beware of slippery floors and surfaces. Wear suitable protective clothing andgloves.
Environmental precautions Avoid discharge into drains, water courses or onto the ground. Prevent spreading over a widearea (e.g. by containment or oil barriers).
Methods for containment Collect and dispose of spillage as indicated in Section 13 of the MSDS.
Methods for cleaning up Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
Other information Clean up in accordance with all applicable regulations.
7. Handling and Storage
Handling Observe good industrial hygiene practices. Use appropriate Personal Protective Equipment.
Storage Store in original tightly closed container. Keep in a cool, well-ventilated place.
8. Exposure Controls / Personal Protection
Occupational exposure limits
US. ACGIH Threshold Limit Values
ValueType FormComponents
TWA 5 mg/m3 Inhalable fraction.Distillate s (petroleum ),solvent-de waxed heavyparaffinic (CAS 64742-65-0)
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueType FormComponents
PEL 5 mg/m3 Mist.Distillate s (petroleum ),solvent-de waxed heavyparaffinic (CAS 64742-65-0)
Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)
ValueType FormComponents
STEL 10 mg/m3 Mist.Distillate s (petroleum ),solvent-de waxed heavyparaffinic (CAS 64742-65-0)
TWA 5 mg/m3 Mist.
CPH MSDS NA
2 / 5
SONIC ATF CPH MSDS NA
910066 Version #: 01 Revision date: - Issue date: 08-22-2012
Mexico. Occupational Exposure Limit Values
ValueType FormComponents
STEL 10 mg/m3 Mist.Distillate s (petroleum ),solvent-de waxed heavyparaffinic (CAS 64742-65-0)
TWA 5 mg/m3 Mist.
Engineering controls General ventilation is normally adequate.
Personal protective equipment
Eye / face protection Wear approved safety glasses or goggles.
Skin protection Wear appropriate clothing to prevent repeated or prolonged skin contact. Wear protective gloves.Neoprene or nitrile gloves are recommended.
Respiratory protection No personal respiratory protective equipment normally required.
General hygiene
considerationsHandle in accordance with good industrial hygiene and safety practices.
9. Physical & Chemical Properties
Appearance Liquid.
Physical state Liquid.
Form Liquid.
Color Red / yellow.
Odor Mild.
Odor threshold Not available.
pH Not available.
Vapor pressure < 0.13 kPa
Vapor density > 1 ( Air=1)
Boiling point Not available.
Melting point/Freezing point 5 °F (-15 °C)
Solubility (water) Partially soluble in cold and hot water.
Specific gravity 0.85 - 0.88
Flash point > 379.4 °F (> 193 °C) Closed Cup
Flammability limits in air,
upper, % by volume
Not available.
Flammability limits in air,
lower, % by volume
Not available.
Auto-ignition temperature > 500 °F (> 260 °C)
Evaporation rate < 1 (ether (anhydrous) = 1)
10. Chemical Stability & Reactivity Information
Chemical stability Material is stable under normal conditions. Handling temperatures should not exceed 175ºF (80ºC). Storage temperatures should not exceed 212º F (45º C).
Conditions to avoid No data available.
Incompatible materials None known.
Hazardous decomposition
productsNone expected under normal conditions of use.
Possibility of hazardous
reactionsUnder normal conditions of storage and use, hazardous polymerization will not occur.
11. Toxicological Information
Sensitization No data available.
Acute effects No data available.
Local effects None known.
Chronic effects Chronic effects are not expected when this product is used as intended.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
CPH MSDS NA
3 / 5
SONIC ATF CPH MSDS NA
910066 Version #: 01 Revision date: - Issue date: 08-22-2012
Mutagenicity Not expected to be mutagenic.
Neurological effects No data available.
Reproductive effects Contains no ingredient listed as toxic to reproduction.
Teratogenicity Not classified.
12. Ecological Information
Ecotoxicity No data on possible environmental effects have been found.
Environmental effects The product components are not classified as environmentally hazardous. However, this does notexclude the possibility that large or frequent spills can have a harmful or damaging effect on theenvironment.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulation /
AccumulationNot available.
13. Disposal Considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose inaccordance with all applicable regulations.
Waste from residues / unused
productsDispose of waste and residues in accordance with local authority requirements.
Contaminated packaging Since emptied containers retain product residue, follow label warnings even after container isemptied.
14. Transport Information
DOT
Not regulated as a hazardous material by DOT.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
TDG
Not regulated as dangerous goods.
15. Regulatory Information
US federal regulations This product is not hazardous according to OSHA 29CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)
None
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - NoDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
Section 302 extremely
hazardous substance (40
CFR 355, Appendix A)
No
Section 311/312 (40 CFR
370)No
Drug Enforcement
Administration (DEA) (21 CFR
1308.11-15)
Not controlled
WHMIS status Non-controlled
CPH MSDS NA
4 / 5
SONIC ATF CPH MSDS NA
910066 Version #: 01 Revision date: - Issue date: 08-22-2012
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) NoChina
European Inventory of Existing Commercial ChemicalSubstances (EINECS)
YesEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) YesJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory NoNew Zealand
Philippine Inventory of Chemicals and Chemical Substances(PICCS)
YesPhilippines
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s)
Toxic Substances Control Act (TSCA) Inventory NoUnited States & Puerto Rico
State regulations
US - California Hazardous Substances (Director's): Listed substance
Distillates (petroleum), solvent-dewaxed heavy paraffinic (CAS 64742-65-0)
Listed.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
US - New Jersey RTK - Substances: Listed substance
Distillates (petroleum), solvent-dewaxed heavy paraffinic (CAS 64742-65-0)
Listed.
US. Massachusetts RTK - Substance List
Distillates (petroleum), solvent-dewaxed heavy paraffinic (CAS 64742-65-0)
Listed.
US. New Jersey Worker and Community Right-to-Know Act
Not regulated.
US. Pennsylvania RTK - Hazardous Substances
Not regulated.
16. Other Information
Further information HMIS® is a registered trade and service mark of the NPCA.
HMIS® ratings Health: 1Flammability: 1Physical hazard: 0
NFPA ratings Health: 1Flammability: 1Instability: 0
Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither theabove named supplier nor any of its subsidiaries assumes any liability whatsoever forcompleteness of the information contained herein. Final determination of suitability of any materialis the sole responsibility of the user. All materials may present unknown hazards and should beused with caution. Although certain hazards are described herein, we cannot guarantee that theseare the only hazards that exist.
CPH MSDS NA
5 / 5
SONIC ATF CPH MSDS NA
910066 Version #: 01 Revision date: - Issue date: 08-22-2012
MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Material name SONIC BLUE GUARD
Version # 02
Issue date 19-September-2011
Revision date 20-May-2014
Supersedes date 19-September-2011
CAS # Mixture
Product code 1696
Product use Multi-purpose grease
Synonym(s) GREASE, MULTIPURPOSE
Manufacturer information
Manufacturer CHS Inc.
Address P.O. Box 64089, Mail station 525
St. Paul, MN 55164-0089
Telephone (651) 355-8438
Supplier Federated Co-operatives Limited
Address P.O. Box 1050, 401 - 22nd Street
East Saskatoon SK S7K 3M9 Canada
Telephone (306) 244-3447
24 Hour Emergency
Telephone
(613) 996-6666 - Canutec
2. Hazards Identification
Physical state Solid.
Appearance Gel-like solid.
Emergency overview Low hazard for usual industrial or commercial handling by trained personnel.
OSHA regulatory status This product is hazardous according to OSHA 29 CFR 1910.1200.
Potential health effects
Routes of exposure Eye contact. Skin contact.
Eyes Direct contact with eyes may cause temporary irritation.
Skin Prolonged skin contact may cause temporary irritation.
Inhalation May cause respiratory tract irritation.
Ingestion Under normal conditions of intended use, this material does not pose a risk to health.
Chronic effects No data available.
Potential environmental effects The product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.
Components CAS # Percent
3. Composition / Information on Ingredients
64742-52-5 60-100Distillates (petroleum), hydrotreated heavy naphthenic
Composition comments * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are inpercent by volume.
4. First Aid Measures
First aid procedures
Eye contact Immediately rinse with water for several minutes.
Skin contact Wash area with soap and water. Get medical attention if irritation develops or persists.
Inhalation If fumes or combustion products are inhaled move victim to fresh air. Get medical attention if anydiscomfort occurs.
SONIC BLUE GUARD CPH MSDS NA
904292 Version #: 02 Revision date: 20-May-2014 Issue date: 19-September-2011 1 / 6
Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medicalattention if any discomfort occurs.
Notes to physician Treat symptomatically.
General advice If you feel unwell, seek medical advice (show the label where possible).
5. Fire Fighting Measures
Extinguishing media
Suitable extinguishing
media
Extinguish with water spray, carbon dioxide, dry chemical or material appropriate for thesurrounding fire.
Unsuitable extinguishing
media
None.
Protection of firefighters
Specific hazards arising
from the chemical
By heating and fire, toxic vapors/gases may be formed.
Fire fighting
equipment/instructions
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
Hazardous combustion
products
No data available.
6. Accidental Release Measures
Personal precautions In case of spills, beware of slippery floors and surfaces. Wear suitable protective clothing andgloves.
Environmental precautions Avoid discharge into drains, water courses or onto the ground. Prevent spreading over a wide area(e.g. by containment or oil barriers).
Methods for containment Collect and dispose of spillage as indicated in Section 13 of the MSDS.
Methods for cleaning up Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
Other information Clean up in accordance with all applicable regulations.
7. Handling and Storage
Handling Observe good industrial hygiene practices. Use appropriate Personal Protective Equipment.
Storage Store in original tightly closed container. Keep in a cool, well-ventilated place.
8. Exposure Controls / Personal Protection
Occupational exposure limits
US. ACGIH Threshold Limit Values
ValueType FormComponents
TWA 5 mg/m3 Inhalable fraction.Distillates (petroleum),hydrotreated heavynaphthenic (CAS64742-52-5)
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueType FormComponents
PEL 5 mg/m3 Mist.Distillates (petroleum),hydrotreated heavynaphthenic (CAS64742-52-5)
2000 mg/m3
500 ppm
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
ValueType FormComponents
STEL 10 mg/m3 Mist.Distillates (petroleum),hydrotreated heavynaphthenic (CAS64742-52-5)
TWA 5 mg/m3 Mist.
SONIC BLUE GUARD CPH MSDS NA
904292 Version #: 02 Revision date: 20-May-2014 Issue date: 19-September-2011 2 / 6
Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act)
ValueType FormComponents
TWA 5 mg/m3 Inhalable fraction.Distillates (petroleum),hydrotreated heavynaphthenic (CAS64742-52-5)
Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)
ValueType FormComponents
STEL 10 mg/m3 Mist.Distillates (petroleum),hydrotreated heavynaphthenic (CAS64742-52-5)
TWA 5 mg/m3 Mist.
Mexico. Occupational Exposure Limit Values
ValueType FormComponents
STEL 10 mg/m3 Mist.Distillates (petroleum),hydrotreated heavynaphthenic (CAS64742-52-5)
TWA 5 mg/m3 Mist.
Engineering controls General ventilation is normally adequate.
Personal protective equipment
Eye / face protection Wear approved safety glasses or goggles.
Skin protection Wear appropriate clothing to prevent repeated or prolonged skin contact. Wear protective gloves.
Respiratory protection No personal respiratory protective equipment normally required.
General hygiene
considerations
Handle in accordance with good industrial hygiene and safety practices.
9. Physical & Chemical Properties
Appearance Gel-like solid.
Physical state Solid.
Form Gel.
Color Blue.
Odor Slight petroleum odor.
Odor threshold Not available.
pH Not available.
Vapor pressure < 0.13 kPa (< 1mm Hg)
Vapor density > 1 (Air = 1)
Boiling point > 600.8 °F (> 316 °C)
Melting point/Freezing point > 500 °F (> 260 °C)
Solubility (water) Partially soluble in cold and hot water.
Specific gravity 0.91
Flash point > 399.2 °F (> 204.0 °C) Pensky-Martens Closed Cup
Flammability limits in air,
upper, % by volume
Not available.
Flammability limits in air,
lower, % by volume
Not available.
Auto-ignition temperature Not available.
Evaporation rate < 1 (Ether = 1.0)
10. Chemical Stability & Reactivity Information
Chemical stability Material is stable under normal conditions.
Conditions to avoid Prolonged excessive heat may cause product decomposition.
SONIC BLUE GUARD CPH MSDS NA
904292 Version #: 02 Revision date: 20-May-2014 Issue date: 19-September-2011 3 / 6
Incompatible materials Strong oxidizing agents.
Hazardous decomposition
products
None expected under normal conditions of use.
Possibility of hazardous
reactions
Will not occur.
11. Toxicological Information
Sensitization Not a skin or respiratory sensitizer.
Acute effects May be harmful if swallowed.
Local effects None known.
Chronic effects Chronic effects are not expected when this product is used as intended.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
ACGIH Carcinogens
Distillates (petroleum), hydrotreated heavy naphthenic(CAS 64742-52-5)
A4 Not classifiable as a human carcinogen.
IARC Monographs. Overall Evaluation of Carcinogenicity
Distillates (petroleum), hydrotreated heavy naphthenic(CAS 64742-52-5)
3 Not classifiable as to carcinogenicity to humans.
Mutagenicity Not expected to be mutagenic.
Neurological effects No data available.
Reproductive effects Not classified.
Teratogenicity Not classified.
12. Ecological Information
Ecotoxicity No data on possible environmental effects have been found.
Environmental effects The product components are not classified as environmentally hazardous. However, this does notexclude the possibility that large or frequent spills can have a harmful or damaging effect on theenvironment.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulation /
Accumulation
Not available.
13. Disposal Considerations
Waste codes Not regulated.
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose inaccordance with all applicable regulations.
Waste from residues / unused
products
Dispose of waste and residues in accordance with local authority requirements.
Contaminated packaging Since emptied containers retain product residue, follow label warnings even after container isemptied.
14. Transport Information
DOT
Not regulated as a hazardous material by DOT.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
TDG
Not regulated as dangerous goods.
15. Regulatory Information
US federal regulations This product is hazardous according to OSHA 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
SONIC BLUE GUARD CPH MSDS NA
904292 Version #: 02 Revision date: 20-May-2014 Issue date: 19-September-2011 4 / 6
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)
None
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - YesDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
Yes
Drug Enforcement
Administration (DEA) (21 CFR
1308.11-15)
Not controlled
WHMIS status Non-controlled
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial ChemicalSubstances (EINECS)
YesEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances(PICCS)
YesPhilippines
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
State regulations This product does not contain a chemical known to the State of California to cause cancer, birthdefects or other reproductive harm.
US - California Hazardous Substances (Director's): Listed substance
Distillates (petroleum), hydrotreated heavy naphthenic(CAS 64742-52-5)
Listed.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
US. Massachusetts RTK - Substance List
Distillates (petroleum), hydrotreated heavy naphthenic(CAS 64742-52-5)
Listed.
US. New Jersey Worker and Community Right-to-Know Act
Not listed.
US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.
16. Other Information
Further information The classification for health and environmental hazards is derived by a combination of calculationmethods and test data, if available.
SONIC BLUE GUARD CPH MSDS NA
904292 Version #: 02 Revision date: 20-May-2014 Issue date: 19-September-2011 5 / 6
NFPA Ratings
0
1
1
Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither theabove named supplier nor any of its subsidiaries assumes any liability whatsoever forcompleteness of the information contained herein. Final determination of suitability of any materialis the sole responsibility of the user. All materials may present unknown hazards and should beused with caution. Although certain hazards are described herein, we cannot guarantee that theseare the only hazards that exist.
SONIC BLUE GUARD CPH MSDS NA
904292 Version #: 02 Revision date: 20-May-2014 Issue date: 19-September-2011 6 / 6
MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Material name SONIC INDUSTRIAL GEAR OIL
Version # 02
Issue date 19-September-2011
Revision date 20-May-2014
Supersedes date 19-September-2011
CAS # -
Product code 182
Product use Gear lubricant
Synonym(s) ISO GRADES 100, 150, 220, 320, 460
Manufacturer information
Manufacturer Consumers' Co-operative Refineries Limited
Address P.O. Box 260; 9th Avenue North
Regina, SK S4P 3A1 Canada
Telephone (306) 721-5353
Supplier Federated Co-operatives Limited
Address P.O. Box 1050, 401 - 22nd Street East
Saskatoon SK S7K 3M9 Canada
Telephone (306) 244-3447
24 Hour Emergency
Telephone
(613) 996-6666 - Canutec
2. Hazards Identification
Physical state Liquid.
Appearance Dark viscous liquid.
Emergency overview Low hazard for usual industrial or commercial handling by trained personnel.
OSHA regulatory status This product is hazardous according to OSHA 29 CFR 1910.1200.
Potential health effects
Routes of exposure Eye contact. Skin contact. Ingestion.
Eyes Direct contact with eyes may cause temporary irritation.
Skin Prolonged skin contact may cause temporary irritation.
Inhalation May cause respiratory tract irritation.
Ingestion Under normal conditions of intended use, this material does not pose a risk to health.
Chronic effects No data available.
Potential environmental effects The product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.
Components CAS # Percent
3. Composition / Information on Ingredients
64742-62-7 100Residual oils (petroleum), solvent-dewaxed
4. First Aid Measures
First aid procedures
Eye contact Immediately rinse with water for several minutes.
Skin contact Wash area with soap and water. Get medical attention if irritation develops or persists.
Inhalation If fumes or combustion products are inhaled move victim to fresh air. Get medical attention if anydiscomfort occurs.
Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medicalattention if any discomfort occurs.
SONIC INDUSTRIAL GEAR OIL CPH MSDS NA
904240 Version #: 02 Revision date: 20-May-2014 Issue date: 19-September-2011 1 / 5
Notes to physician Treat symptomatically.
General advice If you feel unwell, seek medical advice (show the label where possible).
5. Fire Fighting Measures
Extinguishing media
Suitable extinguishing
media
Extinguish with water spray, carbon dioxide, dry chemical or material appropriate for thesurrounding fire.
Unsuitable extinguishing
media
None.
Protection of firefighters
Specific hazards arising
from the chemical
By heating and fire, toxic vapors/gases may be formed.
Fire fighting
equipment/instructions
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
Hazardous combustion
products
No data available.
6. Accidental Release Measures
Personal precautions In case of spills, beware of slippery floors and surfaces. Wear suitable protective clothing andgloves.
Environmental precautions Avoid discharge into drains, water courses or onto the ground. Prevent spreading over a wide area(e.g. by containment or oil barriers).
Methods for containment Collect and dispose of spillage as indicated in Section 13 of the MSDS.
Methods for cleaning up Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
Other information Clean up in accordance with all applicable regulations.
7. Handling and Storage
Handling Observe good industrial hygiene practices. Use appropriate Personal Protective Equipment.
Storage Store in original tightly closed container. Keep in a cool, well-ventilated place.
8. Exposure Controls / Personal Protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueType FormComponents
PEL 5 mg/m3 Mist.Residual oils (petroleum),solvent-dewaxed (CAS64742-62-7)
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
ValueType FormComponents
STEL 10 mg/m3 Mist.Residual oils (petroleum),solvent-dewaxed (CAS64742-62-7)
TWA 5 mg/m3 Mist.
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)
ValueType FormComponents
STEL 10 mg/m3 Mist.Residual oils (petroleum),solvent-dewaxed (CAS64742-62-7)
TWA 5 mg/m3 Mist.
Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)
ValueType FormComponents
STEL 10 mg/m3 Mist.Residual oils (petroleum),solvent-dewaxed (CAS64742-62-7)
TWA 5 mg/m3 Mist.
SONIC INDUSTRIAL GEAR OIL CPH MSDS NA
904240 Version #: 02 Revision date: 20-May-2014 Issue date: 19-September-2011 2 / 5
Mexico. Occupational Exposure Limit Values
ValueType FormComponents
STEL 10 mg/m3 Mist.Residual oils (petroleum),solvent-dewaxed (CAS64742-62-7)
TWA 5 mg/m3 Mist.
Engineering controls General ventilation is normally adequate.
Personal protective equipment
Eye / face protection Wear approved safety glasses or goggles.
Skin protection Wear appropriate clothing to prevent repeated or prolonged skin contact. Wear protective gloves.
Respiratory protection No personal respiratory protective equipment normally required.
General hygiene
considerations
Handle in accordance with good industrial hygiene and safety practices.
9. Physical & Chemical Properties
Appearance Dark viscous liquid.
Physical state Liquid.
Form Liquid.
Color Dark.
Odor Slight.
Odor threshold Not available.
pH Not available.
Vapor pressure < 0 mm Hg (20 °C)
Vapor density Not available.
Boiling point Not available.
Solubility (water) Nil in water.
Specific gravity 0.89
Flash point > 294.0 °F (> 145.6 °C)
Flammability limits in air,
upper, % by volume
Not available.
Flammability limits in air,
lower, % by volume
Not available.
Auto-ignition temperature 755 °F (401.67 °C)
VOC Nil.
Viscosity 2636 SUS (100 °F)
491.4 cSt (40 °C)
Pour point 15.8 °F (-9 °C)
Bulk density 7.42 lb/gal
Molecular weight 690 g/mol
10. Chemical Stability & Reactivity Information
Chemical stability Material is stable under normal conditions.
Conditions to avoid Prolonged excessive heat may cause product decomposition.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition
products
None expected under normal conditions of use.
Possibility of hazardous
reactions
Will not occur.
11. Toxicological Information
Sensitization Not a skin or respiratory sensitizer.
Acute effects May be harmful if swallowed.
Local effects None known.
SONIC INDUSTRIAL GEAR OIL CPH MSDS NA
904240 Version #: 02 Revision date: 20-May-2014 Issue date: 19-September-2011 3 / 5
Chronic effects Chronic effects are not expected when this product is used as intended.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Mutagenicity Not expected to be mutagenic.
Neurological effects No data available.
Reproductive effects Not classified.
Teratogenicity Not classified.
12. Ecological Information
Ecotoxicity No data on possible environmental effects have been found.
Environmental effects The product components are not classified as environmentally hazardous. However, this does notexclude the possibility that large or frequent spills can have a harmful or damaging effect on theenvironment.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulation /
Accumulation
Not available.
13. Disposal Considerations
Waste codes Not regulated.
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose inaccordance with all applicable regulations.
Waste from residues / unused
products
Dispose of waste and residues in accordance with local authority requirements.
Contaminated packaging Since emptied containers retain product residue, follow label warnings even after container isemptied.
14. Transport Information
DOT
Not regulated as a hazardous material by DOT.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
TDG
Not regulated as dangerous goods.
15. Regulatory Information
US federal regulations This product is hazardous according to OSHA 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)
None
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - YesDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
Yes
Drug Enforcement
Administration (DEA) (21 CFR
1308.11-15)
Not controlled
SONIC INDUSTRIAL GEAR OIL CPH MSDS NA
904240 Version #: 02 Revision date: 20-May-2014 Issue date: 19-September-2011 4 / 5
WHMIS status Non-controlled
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial ChemicalSubstances (EINECS)
YesEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances(PICCS)
YesPhilippines
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
State regulations This product does not contain a chemical known to the State of California to cause cancer, birthdefects or other reproductive harm.
US - California Hazardous Substances (Director's): Listed substance
Residual oils (petroleum), solvent-dewaxed (CAS64742-62-7)
Listed.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
US. Massachusetts RTK - Substance List
Residual oils (petroleum), solvent-dewaxed (CAS64742-62-7)
Listed.
US. New Jersey Worker and Community Right-to-Know Act
Residual oils (petroleum), solvent-dewaxed (CAS 64742-62-7)
US. Pennsylvania Worker and Community Right-to-Know Law
Residual oils (petroleum), solvent-dewaxed (CAS 64742-62-7)
16. Other Information
Further information The classification for health and environmental hazards is derived by a combination of calculationmethods and test data, if available.
NFPA Ratings
0
1
1
Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither theabove named supplier nor any of its subsidiaries assumes any liability whatsoever forcompleteness of the information contained herein. Final determination of suitability of any materialis the sole responsibility of the user. All materials may present unknown hazards and should beused with caution. Although certain hazards are described herein, we cannot guarantee that theseare the only hazards that exist.
SONIC INDUSTRIAL GEAR OIL CPH MSDS NA
904240 Version #: 02 Revision date: 20-May-2014 Issue date: 19-September-2011 5 / 5
MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Material name TRANS HYDRAULIC FLUID
Version # 02
Issue date 04-January-2012
Revision date 08-January-2015
Supersedes date 04-January-2012
CAS # Mixture
Product code 62
Product use Transmission and hydraulic oil.
Synonym(s) (NO DYE)
Manufacturer information
Manufacturer Consumers' Co-operative Refineries Limited
Address P.O. Box 260; 9th Avenue North
Regina, SK S4P 3A1 Canada
Telephone (306) 721-5353/(306) 719-4353
Supplier Federated Co-operatives Limited
Address P.O. Box 1050, 401 - 22nd Street East
Saskatoon SK S7K 3M9 Canada
Telephone (306) 244-3447
24 Hour Emergency
Telephone
(613) 996-6666 - Canutec
2. Hazards Identification
Physical state Liquid.
Appearance Oily liquid.
Emergency overview WARNING
Causes skin and eye irritation.
OSHA regulatory status This product is hazardous according to OSHA 29 CFR 1910.1200.
Potential health effects
Routes of exposure Eye contact. Skin contact. Ingestion. Inhalation.
Eyes Causes eye irritation.
Skin Causes skin irritation.
Inhalation May cause respiratory tract irritation.
Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.
Chronic effects No data available.
Potential environmental effects No special environmental precautions required.
Components CAS # Percent
3. Composition / Information on Ingredients
68649-42-3 1-5Zinc Alkyldithiophosphate
4. First Aid Measures
First aid procedures
Inhalation If fumes or combustion products are inhaled move victim to fresh air. Get medical attention if anydiscomfort occurs.
Skin contact In case of contact, flush skin with plenty of water for at least 20 minutes, while removingcontaminated shoes and clothes. Wash contaminated skin with soap and water. Washcontaminated clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention ifirritation develops and persists.
TRANS HYDRAULIC FLUID CPH MSDS NA
906148 Version #: 02 Revision date: 08-January-2015 Issue date: 04-January-2012 1 / 5
Eye contact Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least20 minutes, occasionally lifting the upper and lower eyelids. Get medical attention if symptomsoccur.
Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medicalattention if any discomfort occurs.
Notes to physician Treat symptomatically.
General advice If you feel unwell, seek medical advice (show the label where possible).
5. Fire Fighting Measures
Extinguishing media
Suitable extinguishing
media
Extinguish with water spray, carbon dioxide, dry chemical or material appropriate for thesurrounding fire.
Unsuitable extinguishing
media
None.
Protection of firefighters
Specific hazards arising
from the chemical
By heating and fire, toxic vapors/gases may be formed.
Fire fighting
equipment/instructions
Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
Hazardous combustion
products
No data available.
6. Accidental Release Measures
Personal precautions In case of spills, beware of slippery floors and surfaces. Wear suitable protective clothing andgloves.
Environmental precautions Avoid discharge into drains, water courses or onto the ground. Prevent spreading over a wide area(e.g. by containment or oil barriers).
Methods for containment Collect and dispose of spillage as indicated in Section 13 of the MSDS.
Methods for cleaning up Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
Other information Clean up in accordance with all applicable regulations.
7. Handling and Storage
Handling Observe good industrial hygiene practices. Use appropriate Personal Protective Equipment.
Storage Store in original tightly closed container. Keep in a cool, well-ventilated place.
8. Exposure Controls / Personal Protection
Occupational exposure limits No exposure limits noted for ingredient(s).
Biological limit values No biological exposure limits noted for the ingredient(s).
Engineering controls General ventilation is normally adequate.
Personal protective equipment
Eye / face protection Wear approved safety glasses or goggles.
Skin protection Wear appropriate clothing to prevent repeated or prolonged skin contact. Wear protective gloves.Neoprene or nitrile gloves are recommended.
Respiratory protection No personal respiratory protective equipment normally required.
Hand protection Wash hands after handling.
General hygiene
considerations
Handle in accordance with good industrial hygiene and safety practices.
9. Physical & Chemical Properties
Appearance Oily liquid.
Physical state Liquid.
Form Liquid.
Color Brown.
Odor Mild.
Odor threshold Not available.
TRANS HYDRAULIC FLUID CPH MSDS NA
906148 Version #: 02 Revision date: 08-January-2015 Issue date: 04-January-2012 2 / 5
pH Not available.
Vapor pressure Not available.
Vapor density Not available.
Boiling point Not available.
Melting point/Freezing point -40 °F (-40 °C)
Solubility (water) Sligthly soluble in cold and hot water
Specific gravity 0.88
Flash point > 298.4 °F (> 148.0 °C) Open Cup
Flammability limits in air,
upper, % by volume
Not available.
Flammability limits in air,
lower, % by volume
Not available.
Auto-ignition temperature 775.4 °F (413 °C)
10. Chemical Stability & Reactivity Information
Chemical stability Material is stable under normal conditions.
Conditions to avoid Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition
products
None expected under normal conditions of use.
Possibility of hazardous
reactions
Will not occur.
11. Toxicological Information
Sensitization No data available.
Acute effects Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.
Local effects Causes skin and eye irritation.
Chronic effects Chronic effects are not expected when this product is used as intended.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Mutagenicity Not expected to be mutagenic.
Neurological effects No data available.
Reproductive effects Contains no ingredient listed as toxic to reproduction.
Teratogenicity Not classified.
12. Ecological Information
Ecotoxicity No data on possible environmental effects have been found.
Environmental effects The product components are not classified as environmentally hazardous. However, this does notexclude the possibility that large or frequent spills can have a harmful or damaging effect on theenvironment.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulation /
accumulation
Not available.
13. Disposal Considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose inaccordance with all applicable regulations.
Waste from residues / unused
products
Dispose of waste and residues in accordance with local authority requirements.
Contaminated packaging Since emptied containers retain product residue, follow label warnings even after container isemptied.
TRANS HYDRAULIC FLUID CPH MSDS NA
906148 Version #: 02 Revision date: 08-January-2015 Issue date: 04-January-2012 3 / 5
14. Transport Information
DOT
Not regulated as a hazardous material by DOT.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
TDG
Not regulated as dangerous goods.
15. Regulatory Information
US federal regulations This product is hazardous according to OSHA 29 CFR 1910.1200.All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration
Zinc Alkyldithiophosphate (CAS 68649-42-3) 1.0 % N982
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Zinc Alkyldithiophosphate (CAS 68649-42-3) N982 Listed.
CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)
None
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - NoDelayed Hazard - NoFire Hazard - NoPressure Hazard - NoReactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
No
Drug Enforcement
Administration (DEA) (21 CFR
1308.11-15)
Not controlled
WHMIS status Controlled
WHMIS classification D2B - Other Toxic Effects-TOXIC
WHMIS labeling
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) YesChina
European Inventory of Existing Commercial ChemicalSubstances (EINECS)
YesEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
TRANS HYDRAULIC FLUID CPH MSDS NA
906148 Version #: 02 Revision date: 08-January-2015 Issue date: 04-January-2012 4 / 5
Country(s) or region Inventory name On inventory (yes/no)*
Philippine Inventory of Chemicals and Chemical Substances(PICCS)
YesPhilippines
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).
Toxic Substances Control Act (TSCA) Inventory YesUnited States & Puerto Rico
State regulations
US - California Hazardous Substances (Director's): Listed substance
Zinc Alkyldithiophosphate (CAS 68649-42-3) Listed.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
US. Massachusetts RTK - Substance List
Not regulated.
US. New Jersey Worker and Community Right-to-Know Act
Zinc Alkyldithiophosphate (CAS 68649-42-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.
16. Other Information
Further information HMIS® is a registered trade and service mark of the NPCA.
HMIS® ratings Health: 2Flammability: 1Physical hazard: 0Personal protection: X
NFPA ratings
02
1
Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither theabove named supplier nor any of its subsidiaries assumes any liability whatsoever forcompleteness of the information contained herein. Final determination of suitability of any materialis the sole responsibility of the user. All materials may present unknown hazards and should beused with caution. Although certain hazards are described herein, we cannot guarantee that theseare the only hazards that exist.
Prepared by Not available.
TRANS HYDRAULIC FLUID CPH MSDS NA
906148 Version #: 02 Revision date: 08-January-2015 Issue date: 04-January-2012 5 / 5
MATERIAL SAFETY DATA SHEET 12435 INSECT REPELLENT HD AEROSOL 1 of 2
DEGIL SAFETY PRODUCTS 200 ZENWAY BLVD. UNIT 1 PH. 905-856-1511
www.degilsafety.com VAUGHAN, ON CANADA L4H 0L6 FAX. 905-856-1694SECTION ONE PRODUCT IDENTIFICATIONTRADE NAME CROC BLOC HEAVY DUTY INSECT REPELLENT AEROSOL UPC CODECHEMICAL FAMILY N,N-DIETHYL m-TOLUAMIDE (DEET)PRODUCT USE PackagingMOLECULAR WEIGHT NOT APPLICABLE 24 CANS / CASEFORMULA NOT APPLICABLECNFC SECTION 3 3.5 LEVEL 3NFPA CODE 30B LEVEL 3T.D.G. CLASS ORM-D CONSUMER COMMODITY (AEROSOLS, UN1950, CLASS 2.1)WHMIS CLASSIFICATION NOT APPLICABLEHMIS RATING: FLAMMABILITY 4 SEVERE HAZARDHMIS RATING: HEALTH 2 MODERATE HAZARDHMIS RATING: REACTIVITY 0 MINIMAL HAZARDSECTION TWO COMPOSITION / INFORMATION INGREDIENTSHazardous Ingredients % T.L.V. C.A.S. # LD/50, Route, Species LC/50, Route, Species
N,N-DIETHYL m-TOLUAMIDE 28.5 N/A 134-62-3 2000 mg/kg ORAL - RAT 5950 mg/kg INHAL - RAT
ETHANOL 30 - 60 1000ppm 64-17-5 7060mg/kg ORAL - RAT 31623ppm (4hr) INHAL - RAT
ISOBUTANE 10 - 30 1000ppm 75-28-5 NOT AVAILABLE 142500 ppm (4hr) INHAL - RAT
PROPANE 1 - 5 1000ppm 74-98-6 >5000mg/kg DERMAL-RABBITS NOT AVAILABLESECTION THREE PHYSICAL DATAPHYSICAL STATE AEROSOLAPPEARANCE CLEAR - COLOURLESSODOR FRAGRANTODOR THRESHOLD NOT AVAILABLEBOILING POINT (° C)(CONC) 78.5°CEVAPORATION RATE GREATER THAN 1VAPOUR PRESSURE (PSIG) AEROSOL 40 - 50 @ 20° CVAPOUR DENSITY (AIR=1) GREATER THAN 1AEROSOL % VOC (w/w) 79 - 80AEROSOL % VOLATILE 79 - 80SOLUBILITY IN WATER NOT AVAILABLEpH NOT APPLICABLESPECIFIC GRAVITY (LIQUID) 0.83 - 0.87SPECIFIC GRAVITY (AEROSOL) 0.75 - 0.79COEFFICIENT OF WATER/OIL DIST NOT AVAILABLEFREEZING POINT: (° C) NOT AVAILABLESECTION FOURAEROSOL FLAME PROJECTION > 15cm BUT < 100cmFLASHBACK NOT APPLICABLEFLAMMABILITY EXTREMELY FLAMMABLEIF YES, UNDER WHICH CONDITIONS EXCESSIVE HEAT, SPARKS AND OPEN FLAMEAUTO IGNITION TEMPERATURE (° C) LOWEST KNOWN VALUE IS 422°C (ETHANOL)EXTINGUISHING MEDIA CARBON DIOXIDE, DRY CHEMICAL, FOAMUPPER FLAMMABLE LIMIT 19.0 (% BY VOLUME)LOWER FLAMMABLE LIMIT 3.3 (% BY VOLUME)EXPLOSION DATA SENSITIVITY TO STATIC DISCHARGE NOT APPLICABLE SENSITIVITY TO IMPACT NOT APPLICABLEHAZARDOUS COMBUSTIONPRODUCTS HYDROCARBON FUMES AND SMOKE, CARBON MONOXIDE WHERE
COMBUSTION IS INCOMPLETE.FLASH POINT (° C) TAG CLOSED CUP - LOWEST KNOWN VALUE IS ETHANOL @ 13°C(CONCENTRATE)SPECIAL PROCEDURES WATER FROM FOGGING NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS
TO PREVENT BUILD UP IF EXPOSED TO EXTREME TEMPERATURES. FULLPROTECTIVE EQUIPMENT INCLUDING SELF CONTAINED BREATHING APPARATUSSHOULD BE WORN IN A FIRE INVOLVING THIS MATERIAL.
INSECTICIDE
FIRE & EXPLOSION HAZARD DATA
Reviewed On: 1/29/201511:22 AM ITEM# 12435 DEGIL SAFETY PRODUCTS
MATERIAL SAFETY DATA SHEET 12435 INSECT REPELLENT HD AEROSOL 2 of 2
SECTION FIVE STABILITY AND REACTIVITYHAZARDOUS PRODUCTS OFDECOMPOSITION HYDROCARBON FUMES AND SMOKE. CARBON MONOXIDE WHERE
COMBUSTION IS INCOMPLETECHEMICAL STABILITY YES
UNDER NORMAL CONDITIONSCOMPATABILITY WITH OTHERSUBSTANCES - NO, WHICH ONES? STRONG OXIDIZING AGENTSREACTIVITY CONDITIONS? NOT APPLICABLESECTION SIX HEALTH DATAROUTE OF ENTRYINGESTION MAY CAUSE HEADACHE, NAUSEA, VOMITING & WEAKNESSINHALATION INHALATION OF SOLVENTS MAY CAUSE IRRITATION. PROPELLENT IS SIMPLE ASPHYXIANTEYE CONTACT MAY CAUSE IRRITATIONSKIN CONTACT MAY CAUSE IRRITATIONEFFECTS OF ACUTE EXPOSURE DIZZINESS, NAUSEA, IRRITATION TO SKIN & EYESEFFECTS OF CHRONIC EXPOSURE SOLVENTS MAY CAUSE DEFATTING DERMATITISEXPOSURE LIMIT OF MATERIAL SEE SECTION TWOCARCINOGENICITY OF MATERIAL THE INGREDIENTS OF THIS PRODUCT ARE NOT LISTED AS
CARCINOGENS BY NTP, (NATIONAL TOXICOLOGY PROGRAM), NOTREGULATED AS CARCINOGENS BY OSHA, (OCCUPATIONAL SAFETYAND HEALTH ADMINISTRATION), AND HAVE NOT BEEN EVALUATED BYIARC, (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER), NOR BYACGIH (AMERICAN CONFERENCE OF GOVERNMENTALINDUSTRIAL HYGIENISTS).
REPRODUCTIVE EFFECTS NO INFORMATION IS AVAILABLE AND NO ADVERSE RESPRODUCTIVEEFFECTS ARE ANTICIPATED.
IRRITANCY OF MATERIAL SLIGHTTERATOGENICITY NO INFORMATION IS AVAILABLE AND NO ADVERSE TERATOGENICITY
EFFECTS ARE ANTICIPATED.MUTAGENICITY NO INFORMATION IS AVAILABLE AND NO ADVERSE MUTAGENIC
EFFECTS ARE ANTICIPATED.SYNERGISTIC MATERIALS NONE KNOWNSECTION SEVEN EXPOSURE CONTROLS/PERSONAL PROTECTIONGLOVES CHEMICAL RESISTANT GLOVESRESPIRATORY IF USED INDOORS ON A CONTINUOUS BASIS, USE OF A CARTRIDGE TYPE
RESPIRATOR (NIOSH/MSHA TC-23C OR EQUIVALENT) IS RECOMMENDED.EYE SAFETY GLASSESENGINEERING CONTROLS VENTILATION - LOCAL (MECHANICAL IF INDOORS ON A CONTINUOUS BASIS)FOOTWEAR NOT NORMALLY REQUIREDOTHER NOT REQUIREDSECTION EIGHTLEAK / SPILL REMOVE ALL SOURCES OF IGNITION, USE AN INERT ABSORBENT MATERIAL AND NON -
SPARKING TOOLS. VENTILATE AREA. PREVENT FROM ENTERING A WATERCOURSESTORAGE NEEDS KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAMSHANDLING PROCEDURES AND STORE IN A COOL, WELL VENTILATED AREA NOT TO EXCEED 50 DEG C.EQUIPMENTSHIPPING INSTRUCTIONS SEE SECTION ONE TDG CLASSIFICATIONWASTE DISPOSAL DO NOT PUNCTURE OR INCINERATE PACKAGES EVEN WHEN EMPTY. DISPOSE OF IN
ACCORDANCE WITH LOCAL, PROVINCIAL AND FEDERAL REGULATIONSSECTION NINEEMERGENCY FIRST AID PROCEDURE
SECTION TEN ADDITIONAL INFORMATIONThis document has been prepared using data from sources considered technically reliable.It does not constitute a warranty, express or implied, as to the accuracy of the informationcontained herein. Actual conditions of use and handling are beyond seller's control.User is responsible to evaluate all available information when using product for anyparticular use and to comply with all Federal, State, Provincial and local laws andregulations.
Prepared By: Maureen Kayum 1-800-332-1810 REVIEWED ON: JANUARY 29/2015
INHALATION OF VAPOUR OR SPRAY MIST, REMOVE TO FRESH AIR. IF SWALLOWED; DO NOT INDUCE VOMITING, GET MEDICAL ATTENTION.
HANDLING AND STORAGE
FIRST AID MEASURES IN CASE OF EYE CONTACT, FLUSH IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION. FOR SKIN, WASH THOROUGHLY WITH SOAP AND WATER. IF AFFECTED BY
Reviewed On: 1/29/201511:22 AM ITEM# 12435 DEGIL SAFETY PRODUCTS
MATERIAL SAFETY DATA SHEET 12415 INSECT REPELLENT FOAM 1 of 2
1/29/201510:57 AM ITEM# 12415 DEGIL SAFETY PRODUCTS
DEGIL SAFETY PRODUCTS 200 ZENWAY BLVD. UNIT 1 PH. 905-856-1511
www.degilsafety.com VAUGHAN, ON CANADA L4H 0L6 FAX. 905-856-1694SECTION ONE PRODUCT IDENTIFICATIONTRADE NAME CROC BLOC INSECT REPELLENT FOAM UPC CODECHEMICAL FAMILY N,N-DIETHYL m-TOLUAMIDE (DEET)PRODUCT USE PackagingMOLECULAR WEIGHT NOT APPLICABLE 48 CANS / CASEFORMULA NOT APPLICABLECNFC SECTION 3 3.5 LEVEL 1NFPA CODE 30B LEVEL 1T.D.G. CLASS ORM-D CONSUMER COMMODITYWHMIS CLASSIFICATION NOT APPLICABLEHMIS RATING: FLAMMABILITY 1 SLIGHT HAZARDHMIS RATING: HEALTH 2 MODERATE HAZARDHMIS RATING: REACTIVITY 0 MINIMAL HAZARDSECTION TWO COMPOSITION / INFORMATION INGREDIENTSHazardous Ingredients % T.L.V. C.A.S. # LD/50, Route, Species LC/50, Route, Species
N,N-DIETHYL m-TOLUAMIDE 9.50 N/A 134-62-3 2000 mg/kg ORAL - RAT 5950 mg/kg INHAL - RAT
ISOPROPYL MYRISTATE 1.5 N/A 110-27-0 NOT AVAILABLE NOT AVAILABLE INHAL - RAT
ISOBUTANE 3 - 7 N/A 75-28-5 NOT AVAILABLE 142500 ppm (4hr) INHAL - MOUSE
PROPANE 1 - 5 1000ppm 74-98-6 NOT AVAILABLE NOT AVAILABLESECTION THREE PHYSICAL DATAPHYSICAL STATE AEROSOLAPPEARANCE OFF-WHITE LIQUIDODOR INSECTICIDEODOR THRESHOLD NOT AVAILABLEBOILING POINT (° C)(CONC) 100EVAPORATION RATE LESS THAN 1VAPOUR PRESSURE (PSIG) AEROSOL 55 - 65 @ 20° CVAPOUR DENSITY (AIR=1) GREATER THAN 1AEROSOL % VOC (w/w) 24.25AEROSOL % VOLATILE NOT AVAILABLESOLUBILITY IN WATER SOLUBLEpH 7.3 - 8.3SPECIFIC GRAVITY (LIQUID) 0.98 - 1.02SPECIFIC GRAVITY (AEROSOL) 0.90 - 0.94COEFFICIENT OF WATER/OIL DIST NOT AVAILABLEFREEZING POINT: (° C) NOT AVAILABLESECTION FOURAEROSOL FLAME PROJECTION CLASSIFIED AS 0 CmFLASHBACK NOT APPLICABLEFLAMMABILITY NOT A FLAMMABLE PRODUCT (AS PER CANADIAN AEROSOL REGULATIONS)IF YES, UNDER WHICH CONDITIONS EXCESSIVE HEAT, SPARKS AND OPEN FLAMEAUTO IGNITION TEMPERATURE (° C) NOT AVAILABLEEXTINGUISHING MEDIA CARBON DIOXIDE, DRY CHEMICAL, FOAMUPPER FLAMMABLE LIMIT 9.5 (% BY VOLUME)LOWER FLAMMABLE LIMIT 0.8 (% BY VOLUME)EXPLOSION DATA SENSITIVITY TO STATIC DISCHARGE NOT APPLICABLE SENSITIVITY TO IMPACT NOT APPLICABLEHAZARDOUS COMBUSTIONPRODUCTS HYDROCARBON FUMES AND SMOKE, CARBON MONOXIDE WHERE
COMBUSTION IS INCOMPLETE.FLASH POINT (° C) NOT AVAILABLE(CONCENTRATE)SECTION FIVE STABILITY AND REACTIVITYHAZARDOUS PRODUCTS OFDECOMPOSITION HYDROCARBON FUMES AND SMOKE. CARBON MONOXIDE WHERE
COMBUSTION IS INCOMPLETECHEMICAL STABILITY YES
UNDER NORMAL CONDITIONSCOMPATABILITY WITH OTHERSUBSTANCES - NO, WHICH ONES? STRONG OXIDIZING AGENTSREACTIVITY CONDITIONS? NOT APPLICABLE
INSECTICIDE
FIRE & EXPLOSION HAZARD DATA
MATERIAL SAFETY DATA SHEET 12415 INSECT REPELLENT FOAM 2 of 2
1/29/201510:57 AM ITEM# 12415 DEGIL SAFETY PRODUCTS
SECTION SIX HEALTH DATAROUTE OF ENTRYINGESTION MAY CAUSE HEADACHE, NAUSEA, VOMITING & WEAKNESSINHALATION INHALATION OF SOLVENTS MAY CAUSE IRRITATION. PROPELLENT IS SIMPLE ASPHYXIANTEYE CONTACT VAPOURS MAY IRRITATESKIN CONTACT MAY CAUSE IRRITATIONEFFECTS OF ACUTE EXPOSURE DIZZINESS, NAUSEA, IRRITATION TO SKIN & EYESEFFECTS OF CHRONIC EXPOSURE SOLVENTS MAY CAUSE DEFATTING DERMATITISEXPOSURE LIMIT OF MATERIAL SEE SECTION TWOCARCINOGENICITY OF MATERIAL THE INGREDIENTS OF THIS PRODUCT ARE NOT LISTED AS
CARCINOGENS BY NTP, (NATIONAL TOXICOLOGY PROGRAM), NOTREGULATED AS CARCINOGENS BY OSHA, (OCCUPATIONAL SAFETYAND HEALTH ADMINISTRATION), AND HAVE NOT BEEN EVALUATED BYIARC, (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER), NOR BYACGIH (AMERICAN CONFERENCE OF GOVERNMENTALINDUSTRIAL HYGIENISTS).
REPRODUCTIVE EFFECTS NO INFORMATION IS AVAILABLE AND NO ADVERSE RESPRODUCTIVEEFFECTS ARE ANTICIPATED.
IRRITANCY OF MATERIAL SLIGHTTERATOGENICITY NO INFORMATION IS AVAILABLE AND NO ADVERSE TERATOGENICITY
EFFECTS ARE ANTICIPATED.MUTAGENICITY NO INFORMATION IS AVAILABLE AND NO ADVERSE MUTAGENIC
EFFECTS ARE ANTICIPATED.SYNERGISTIC MATERIALS NONE KNOWNSECTION SEVEN EXPOSURE CONTROLS/PERSONAL PROTECTIONGLOVES CHEMICAL RESISTANT GLOVESRESPIRATORY IF USED INDOORS ON A CONTINUOUS BASIS, USE OF A CARTRIDGE TYPE
RESPIRATOR (NIOSH/MSHA TC-23C OR EQUIVALENT) IS RECOMMENDED.EYE SAFETY GLASSESENGINEERING CONTROLS VENTILATION - LOCAL (MECHANICAL IF INDOORS ON A CONTINUOUS BASIS)FOOTWEAR NOT NORMALLY REQUIREDOTHER NOT REQUIREDSECTION EIGHTLEAK / SPILL REMOVE ALL SOURCES OF IGNITION, USE AN INERT ABSORBENT MATERIAL AND NON -
SPARKING TOOLS. AVOID BREATHING FUMES, VENTILATE AREASTORAGE NEEDS KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAMSHANDLING PROCEDURES AND STORE IN A COOL, WELL VENTILATED AREA NOT TO EXCEED 50 DEG C.EQUIPMENTSHIPPING INSTRUCTIONS SEE SECTION ONE TDG CLASSIFICATIONWASTE DISPOSAL DO NOT PUNCTURE OR INCINERATE PACKAGES EVEN WHEN EMPTY. DISPOSE OF IN
ACCORDANCE WITH LOCAL, PROVINCIAL AND FEDERAL REGULATIONSSECTION NINEEMERGENCY FIRST AID PROCEDURE
SECTION TEN ADDITIONAL INFORMATIONThis document has been prepared using data from sources considered technically reliable.It does not constitute a warranty, express or implied, as to the accuracy of the informationcontained herein. Actual conditions of use and handling are beyond seller's control.User is responsible to evaluate all available information when using product for anyparticular use and to comply with all Federal, State, Provincial and local laws andregulations.
Prepared By: Maureen Kayum 1-800-332-1810 REVIEWED JANUARY 29/2015
INHALATION OF VAPOUR OR SPRAY MIST, REMOVE TO FRESH AIR. IF SWALLOWED; DO NOT INDUCE VOMITING, GET MEDICAL ATTENTION.
HANDLING AND STORAGE
FIRST AID MEASURES IN CASE OF EYE CONTACT, FLUSH IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION. FOR SKIN, WASH THOROUGHLY WITH SOAP AND WATER. IF AFFECTED BY
M A T E R I A L S A F E T Y D A T A S H E E T
Original Date: 3/28/13 Revision Date: 1/29/15
S e c t i o n 1 - I d e n t i f i c a t i o n
PRODUCT NAME: Croc Bloc SPF30 Spray Lotion Broad Spectrum
FORMULA: 12330-10 Proprietary Cosmetic Mixture Containing Active Ingredients: Octinoxate, Octisalate, Avobenzone,
Octocrylene, and Benzophenone-3
PRODUCT USE DESCRIPTION: Sunscreen MANUFACTURER: Croc Bloc Products Inc. 200 Zenway Blvd. Unit #1 Vaughan, ON, Canada L4H 0L6 Phone 800 332 1810 EMERGENCY (24 HOUR) PHONE: Emergency Chemical Response 800 535 5053
S e c t i o n 2 – H a z a r d ( s ) I d e n t i f i c a t i o n NFPA Hazard Classification Health: 0 Fire: 0 Reactivity: 0 Specific Hazard: None ACUTE INHALATION: Low volatility makes vapor inhalation unlikely. ACUTE SKIN CONTACT: Product assumed to be practically non-irritating to minimally irritating ACUTE EYE CONTACT: Product assumed to be minimally to slightly irritating INGESTION: Product assumed to be practically non-toxic CHRONIC OVEREXPOSURE: N. Av.
RESPONSE: INHALATION: Not expected route of exposure. If vapors or mist cause irritation or distress, remove subject to fresh air. Give oxygen or
artificial respiration if needed. SKIN CONTACT: Remove contaminated clothing and wash contact area with soap and fresh water. EYE CONTACT: Flush eyes with plenty of water for at least 15 minutes. If eye irritation persists, seek medical attention. INGESTION: No harmful affects expected. Drink water or milk to calm stomach.
S e c t i o n 3 – C o m p o s i t i o n / I n f o r m a t i o n o n I n g r e d i e n t s APPEARANCE:
White to Off-White Uniform Spray Lotion
PH: 6.5 to 7.5 SPEC. GRAVITY: 1.020 +/- 0.020 @ 25C FREEZING POINT: N. Av. VAPOR PRESSURE: N. Av. BOILING POINT: 100 C + VAPOR DENSITY: N. Av. WATER SOLUBILITY: Partly Miscible EVAP. RATE: N. Av.
S e c t i o n 4 – F i r s t - A i d M e a s u r e s INHALATION:
Not expected route of exposure. If vapors or mist cause irritation or distress, remove subject to fresh air. Give oxygen or artificial respiration if needed.
SKIN CONTACT: Remove contaminated clothing and wash contact area with soap and fresh water.
EYE CONTACT: Flush eyes with plenty of water for at least 15 minutes. If eye irritation persists, seek medical attention.
INGESTION: No harmful affects expected. Drink water or milk to calm stomach.
S e c t i o n 5 – F i r e - F i g h t i n g M e a s u r e s
FLASH POINT: >200 F A.I. TEMPERATURE: N. Av. EXTINGUISHING MEDIA: Use water spray, foam, CO2, or dry chemical extinguishing media SPECIAL FIRE FIGHTING PROCEDURES: None UNUSUAL HAZARDS: None
S e c t i o n 6 – A c c i d e n t a l R e l e a s e M e a s u r e s
GENERAL: Spills should be contained. Absorb with inert material and collect for disposal. Flush area with water. Prevent
washing from entering waterways.
WASTE DISPOSAL: Dispose in accordance with Local, State, and Federal regulations.
CONTAINER DISPOSAL: Dispose in accordance with Local, State, and Federal regulations.
S e c t i o n 7 – H a n d l i n g a n d S t o r a g e GENERAL: Store in a cool dry place. Keep containers tightly closed when not in use. Avoid contact with eyes. Avoid freezing and localized overheating. OTHER PRECAUTIONS: None known
S e c t i o n 8 – E x p o s u r e C o n t r o l s / P e r s o n a l P r o t e c t i o n CLOTHING: Gloves, coveralls, aprons, boots as necessary to minimize contact
EYES: Chemical goggles, full face shield
RESPIRATION: If vapors or mist are generated, wear an approved respirator
VENTILATION: Use adequate exhaust to control vapor/mist
EXPLOSION PROOFING: None required
S e c t i o n 9 – P h y s i c a l a n d C h e m i c a l P r o p e r t i e s Appearance: White to Off-White Uniform Spray Lotion Odor: Matches Standard Odor Threshold: N.Av. Vapor Pressure: N.Av. Vapor Density: N.Av. pH: 6.5 to 7.5 Relative Density: 1.020 +/- 0.020 @25C Melting Point/Freezing Point: N.Av. Solubility(ies): Partly Miscible in water Initial Boiling Point and Boiling Range: 100C+ Flash Point: >200F Evaporation Rate: N.Av. Flammability (solid, gas): N.Av. Upper/Lower Flammability or Explosive Limits: N.Av. Auto-ignition Temp: N.Av. Partition Coefficient:(n-octanol/water) N.Av. Decomposition Temp: N.Av. Viscosity: SP #2 @10rpm: 50 to 2000
S e c t i o n 1 0 – S t a b i l i t y a n d R e a c t i v i t y STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID: None INCOMPATIBILITY: None HAZARDOUS DECOMPOSITION PRODUCTS: None
S e c t i o n 1 1 – T o x i c o l o g i c a l I n f o r m a t i o n No data is available on the mixture.
S e c t i o n 1 2 – E c o l o g i c a l I n f o r m a t i o n No data is available on the mixture.
S e c t i o n 1 3 – D i s p o s a l C o n s i d e r a t i o n s WASTE DISPOSAL:
Dispose in accordance with Local, State, and Federal regulations.
CONTAINER DISPOSAL: Dispose in accordance with Local, State, and Federal regulations.
S e c t i o n 1 4 – T r a n s p o r t I n f o r m a t i o n DOT Hazard Class: Non-Regulated DOT Shipping Name: N/A
S e c t i o n 1 5 - R e g u l a t o r y I n f o r m a t i o n We certify that all components of this mixture are listed on the TSCA inventory.
S e c t i o n 1 6 – O t h e r I n f o r m a t i o n The information herein is given in good faith but no warranty is expressed or implied. History: Original. Rev 1: Changed Formula Number Rev 2: Changed Formula Number End of Report
MATERIAL SAFETY DATA SHEET 12435A INSECT REPELLENT LIQUID SPRAY 1 of 2
DEGIL SAFETY PRODUCTS 200 ZENWAY BLVD. UNIT 1 PH. 905-856-1511
www.degilsafety.com VAUGHAN, ON CANADA L4H 0L6 FAX. 905-856-1694SECTION ONE PRODUCT IDENTIFICATIONTRADE NAME CROC BLOC INSECT REPELLENT LIQUID PUMP SPRAY UPC CODECHEMICAL FAMILY N,N-DIETHYL m-TOLUAMIDE (DEET) 7 76285 12455 6PRODUCT USE PackagingMOLECULAR WEIGHT NOT APPLICABLE 12 BOTTLES / BOXFORMULA MIXTURET.D.G. CLASSIFICATION ISOPROPANOL SOLUTION, CLASS 3, UN 1219, PACKING GROUP IIWHMIS CLASSIFICATION NOT REGULATEDHMIS RATING: HEALTH 2 MODERATE HAZARDHMIS RATING: FLAMMABILITY 2 MODERATE HAZARDHMIS RATING: REACTIVITY 0 MINIMAL HAZARDSECTION TWO COMPOSITION / INFORMATION INGREDIENTSHazardous Ingredients % T.L.V. C.A.S. # LD/50, Route, Species LC/50, Route, Species
ISOPROPANOL 30 - 60 400 ppm 67-63-0 >4720 mg/kg ORAL - RAT 12000 ppm (8hr) INHAL - RAT
N,N-DIETHYL m-TOLUAMIDE 30 N/A 134-62-3 2000 mg/kg ORAL - RAT 5950 mg/kg INHAL - RAT
SECTION THREE HAZARDOUS IDENTIFICATIONROUTE OF ENTRYINGESTION MAY CAUSE HEADACHE, NAUSEA, VOMITING AND WEAKNESSINHALATION INHALATION OF SOLVENTS MAY CAUSE IRRITATIONEYE CONTACT MAY CAUSE IRRITATIONSKIN CONTACT MAY CAUSE IRRITATIONEFFECTS OF ACUTE EXPOSURE DIZZINESS, NAUSEA, IRRITATION TO SKIN & EYESEFFECTS OF CHRONIC EXPOSURE SOLVENTS MAY CAUSE DEFATTING DERMATITISEXPOSURE LIMIT OF MATERIAL SEE SECTION TWOSECTION FOUREMERGENCY FIRST AID PROCEDURE
SECTION FIVEAUTO IGNITION TEMPERATURE (° C) 399SPECIAL PROCEDURES WATER FROM FOGGING NOZZLES MAY BE USED TO COOL CLOSED
CONTAINERS TO PREVENT BUILD-UP IF EXPOSED TO EXTREMETEMPERATURES. FULL PROTECTIVE EQUIPMENT INCLUDING SELFCONTAINED BREATHING APPARATUS SHOULD BE WORN IN A FIREINVOLVING THIS MATERIAL.
FLAMMABILITY CAUTION-FLAMMABLEIF YES, UNDER WHICH CONDITIONS EXCESSIVE HEAT, SPARKS AND OPEN FLAMEEXTINGUISHING MEDIA WATER, CARBON DIOXIDE, DRY CHEMICAL, FOAMUPPER FLAMMABLE LIMIT 12 % BY VOLUME.LOWER FLAMMABLE LIMIT 2.0 % BY VOLUME.EXPLOSION DATA SENSITIVITY TO STATIC DISCHARGE NOT APPLICABLE SENSITIVITY TO IMPACT NOT APPLICABLEHAZARDOUS COMBUSTIONPRODUCTS HYDROCARBON FUMES AND SMOKE, CARBON MONOXIDE WHERE
COMBUSTION IS INCOMPLETE.FLASH POINT ( C ), TAG CLOSED-CUP >14(CONCENTRATE)SECTION SIX ACCIDENTAL RELEASE MEASURESLEAK/SPILL REMOVE ALL SOURCES OF IGNITION. USE AN INERT ABSORBENT MATERIAL,
AND NON-SPARKING TOOLS. VENTILATE AREA. PREVENT FROM ENTERING A WATERCOURSE
SECTION SEVENSTORAGE NEEDS KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAMSENGINEERING CONTROLS VENTILATION - LOCAL (MECHANICAL IF USED INDOORS ON A CONTINUOUS BASIS)HANDLING PROCEDURES ANDEQUIPMENT STORE IN A COOL, WELL VENTILATED AREA NOT TO EXCEED 50 DEG C.SYNERGISTIC MATERIALS NONE KNOWNWASTE DISPOSAL DISPOSE OF IN ACCORDANCE WITH LOCAL, PROVINCIAL AND FEDERAL REGULATIONS
INHALATION OF VAPOUR OR SPRAY MIST, REMOVE TO FRESH AIR. IF SWALLOWED; DO NOT INDUCE VOMITING, GET MEDICAL ATTENTION.
HANDLING AND STORAGE
INSECT REPELLENT
FIRE FIGHTING MEASURES
FIRST AID MEASURES IN CASE OF EYE CONTACT, FLUSH IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION. FOR SKIN, WASH THOROUGHLY WITH SOAP AND WATER. IF AFFECTED BY
1/29/201511:24 AM ITEM# 12435A DEGIL SAFETY PRODUCTS
MATERIAL SAFETY DATA SHEET 12435A INSECT REPELLENT LIQUID SPRAY 2 of 2
SECTION EIGHT EXPOSURE CONTROLS/PERSONAL PROTECTIONGLOVES NOT NORMALLY REQUIREDRESPIRATORY NOT NORMALLY REQUIREDEYE SAFETY GLASSESFOOTWEAR NOT NORMALLY REQUIREDOTHER NOT REQUIRED
SECTION NINE PHYSICAL AND CHEMICAL PROPERTIESPHYSICAL STATE LIQUIDAPPEARANCE CLEAR, PALE YELLOW LIQUIDODOR FRAGRANTODOR THRESHOLD NOT AVAILABLEBOILING POINT (° C)(CONC) 83EVAPORATION RATE LESS THAN 1n-BUTYL ACETATE = 1VAPOUR DENSITY (AIR=1) GREATER THAN 1(BY WEIGHT)SOLUBILITY IN WATER g/L (20°C) NOT AVAILABLEpH NOT APPLICABLESPECIFIC GRAVITY (LIQUID) 0.88 - 0.92COEFFICIENT OF WATER/OIL DIST NOT AVAILABLEFREEZING POINT: (° C) NOT AVAILABLEAEROSOL PERCENT VOLATILE 69 - 70(BY WEIGHT)SECTION TEN STABILITY AND REACTIVITYHAZARDOUS PRODUCTS OFDECOMPOSITION HYDROCARBON FUMES AND SMOKE. CARBON MONOXIDE WHERE
COMBUSTION IS INCOMPLETECHEMICAL STABILITYYES UNDER NORMAL CONDITIONSNO, WHICH ONES? NOT APPLICABLECOMPATABILITY WITH OTHERSUBSTANCES - NO, WHICH ONES? STRONG OXIDIZING AGENTSREACTIVITY CONDITIONS? NOT APPLICABLESECTION ELEVEN TOXICOLOGICAL INFORMATIONREPRODUCTIVE EFFECTS NO INFORMATION IS AVAILABLE AND NO ADVERSE RESPRODUCTIVE
EFFECTS ARE ANTICIPATED.IRRITANCY OF MATERIAL SKIN/EYE IRRITANTSENSITIZING CAPABILITY OF MATERIAL UNKNOWNCARCINOGENICITY OF MATERIAL THE INGREDIENTS OF THIS PRODUCT ARE NOT LISTED AS
CARCINOGENS BY NTP, (NATIONAL TOXICOLOGY PROGRAM), NOTREGULATED AS CARCINOGENS BY OSHA, (OCCUPATIONAL SAFETYAND HEALTH ADMINISTRATION), AND HAVE NOT BEEN EVALUATED BYIARC, (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER), NOR BYACGIH (AMERICAN CONFERENCE OF GOVERNMENTALINDUSTRIAL HYGIENISTS).
TERATOGENICITY NO INFORMATION IS AVAILABLE AND NO ADVERSE TERATOGENICITYEFFECTS ARE ANTICIPATED.
MUTAGENICITY NO INFORMATION IS AVAILABLE AND NO ADVERSE MUTAGENICEFFECTS ARE ANTICIPATED.
SECTION SIXTEEN ADDITIONAL INFORMATIONThis document has been prepared using data from sources considered technically reliable.It does not constitute a warranty, express or implied, as to the accuracy of the informationcontained herein. Actual conditions of use and handling are beyond seller's control.User is responsible to evaluate all available information when using product for anyparticular use and to comply with all Federal, State, Provincial and local laws andregulations.
Prepared By: Maureen Kayum 1-800-332-1810 REVIEWED JANUARY 29/2015
1/29/201511:24 AM ITEM# 12435A DEGIL SAFETY PRODUCTS
Date Printed: 4/2/2012
Material Safety Data Sheet
24 Hour Assistance:
1-847-367-7700
Rust-Oleum Corp.
www.rustoleum.com
1. Identification
4/2/2012Product Name: ENAMEL 5-GL SAFETY ORANGE Revision Date:
Identification Number: 956300
Product Use/Class: Topcoat/Alkyd
Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA
Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA
Supplier: Manufacturer:
Preparer: Regulatory Department
2. Hazard Identification
EMERGENCY OVERVIEW: Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and respiratory tract. Combustible liquid and vapor. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. May cause headaches and dizziness. High vapor concentrations are irritating to the eyes, nose, throat and lungs.
EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause damage.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. IARC lists Ethylbenzene as a possible human carcinogen (group 2B).
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
3. Composition/Information On Ingredients
Chemical Name CAS-No.Weight %Less Than
ACGIH TLV-TWA
ACGIH TLV-STEL
OSHA PEL-TWAOSHA PEL-CEILING
Stoddard Solvents 8052-41-3 35.0 100 ppm N.E. 500 ppm N.E.Mineral Spirits 64742-88-7 15.0 100 ppm N.E. 100 ppm N.E.Xylene 1330-20-7 1.0 100 ppm 150 ppm 100 ppm N.E.Ethylbenzene 100-41-4 1.0 100 ppm 125 ppm 100 ppm N.E.
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash with soap and water. Get medical attention if irritation develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation.
FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention.
Page 1 / 4
Date Printed: 4/2/2012
5. Fire-fighting Measures
Flash Point, °F 104 (Setaflash)
EXTINGUISHING MEDIA: Dry Chemical, Foam, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Evacuate area and fight fire from a safe distance.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing vapor or mist. Avoid contact with eyes.
STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Keep away from heat, sparks, flame and sources of ignition. Keep container closed when not in use.
8. Exposure Controls/Personal Protection
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.
Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or in any other circumstances where air purifying respirators may not provide adequate protection.
SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking.
9. Physical and Chemical Properties
Vapor Density HEAVIER THAN AIR Odor: Solvent Like
Appearance: Liquid Evaporation Rate: Slower than Ether
Solubility in Water: Slight Freeze Point: N.D.
Specific Gravity: 0.933 pH: N.A.
Physical State: Liquid
(See section 16 for abbreviation legend)
10. Stability and Reactivity
Page 2 / 4
Date Printed: 4/2/2012
CONDITIONS TO AVOID: Avoid all possible sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological Information
Chemical Name LD50 LC50
Stoddard Solvents >5000 mg/kg (Rat, Oral) N.E.
Mineral Spirits >5000 mg/kg (Rat, Oral) >1400 ppm (Rat, Inhalation, 4Hr)
Xylene 4300 mg/kg (Rat, Oral) 5000 ppm (Rat, Inhalation, 4Hr)
Ethylbenzene 3500 mg/kg (Rat, Oral) N.E.
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow to enter storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) Air (IATA)International (IMDG)
Proper Shipping Name: Not Regulated Paint Paint
Hazard Class: N.A. 3 3
UN Number: N.A. UN1263 UN1263
Packing Group: N.A. III III
Limited Quantity: No No No
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of theSuperfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, tomeet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
SARA SECTION 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of theSuperfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported fromthe United States:
Page 3 / 4
Date Printed: 4/2/2012
No TSCA 12(b)components exist in this product.
International Regulations:
CANADIAN WHMIS:
This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
Canadian WHMIS Class: B3 D2A
16. Other Information
HMIS Ratings:
Health: 2* Flammability: 2 Physical Hazard: 0 Personal Protection: X
NFPA Ratings:
Health: 2 Flammability: 2 Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L: 445
REASON FOR REVISION: Regulatory Update
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to beaccurate and reliable as of the date of this material safety data sheet. However, because the conditions of handling, use, andstorage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damageincurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracyor reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used withcaution. The information and recommendations in this material safety data sheet are offered for the users’ consideration andexamination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicableinternational, federal, state, and local laws and regulations.
Page 4 / 4
DOW CORNING CORPORATION Material Safety Data Sheet
Page: 1 of 8 Version: 1.10
Revision Date: 2013/04/05 DOW CORNING(R) 732 MULTI -PURPOSE SEALANT CLEAR
1. PRODUCT AND COMPANY IDENTIFICATION Dow Corning Corporation South Saginaw Road Midland, Michigan 48686
24 Hour Emergency Telephone:
Customer Service: Product Disposal Information:
CHEMTREC:
(989) 496-5900 (989) 496-6000 (989) 496-6315 (800) 424-9300
MSDS No.: 01890573
Revision Date: 2013/04/05
Generic Description: Silicone elastomer Physical Form: Paste
Color: Colorless Odor: Acetic acid odor
NFPA Profile:
Health 1 Flammability 1 Instability/Reactivity 0
Note: NFPA = National Fire Protection Association 2. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
Acute Effects Eye:
Direct contact may cause mild irritation.
Skin:
May cause mild irritation.
Inhalation:
No significant effects expected from a single short-term exposure.
Oral:
Low ingestion hazard in normal use.
Prolonged/Repeated Exposure Effects Skin:
No known applicable information.
Inhalation:
No known applicable information.
Oral:
No known applicable information.
Signs and Symptoms of Overexposure
No known applicable information.
Medical Conditions Aggravated by Exposure
No known applicable information.
DOW CORNING CORPORATION Material Safety Data Sheet
Page: 2 of 8 Version: 1.10
Revision Date: 2013/04/05 DOW CORNING(R) 732 MULTI -PURPOSE SEALANT CLEAR
The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions, component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology information.
3. COMPOSITION/INFORMATION ON INGREDIENTS
CAS Number Wt % Component Name
17689-77-9 1.0 - 5.0 Ethyltriacetoxysilane
4253-34-3 1.0 - 5.0 Methyltriacetoxysilane
The above components are hazardous as defined in 29 CFR 1910.1200.
4. FIRST AID MEASURES Eye:
Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes while holding the eyelid(s) open. Obtain medical attention.
Skin: No health effects expected. If irritation does occur flush with lukewarm, gently flowing water for 5 minutes. If irritation persists, obtain medical advice.
Inhalation: If symptoms are experienced remove source of contamination or move victim to fresh air. If irritation persists, obtain medical advice.
Oral: If irritation or discomfort occur, obtain medical advice.
Notes to Physician: Treat according to person's condition and specifics of exposure.
5. FIRE FIGHTING MEASURES Flash Point:
Not applicable. Not applicable.
Autoignition Temperature:
Not determined.
Flammability Limits in Air:
Not determined.
Extinguishing Media:
On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide (CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.
Fire Fighting Measures:
Self-contained breathing apparatus and protective clothing should be worn in fighting large fires involving chemicals. Determine the need to evacuate or isolate the area according to your local emergency plan. Use water spray to keep fire exposed containers cool.
DOW CORNING CORPORATION Material Safety Data Sheet
Page: 3 of 8 Version: 1.10
Revision Date: 2013/04/05 DOW CORNING(R) 732 MULTI -PURPOSE SEALANT CLEAR
Unusual Fire Hazards:
None.
6. ACCIDENTAL RELEASE MEASURES Containment/Clean up:
Observe all personal protection equipment recommendations described in Sections 5 and 8. Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since spilled materials, even in small quantities, may present a slip hazard. Final cleaning may require use of steam, solvents or detergents. Dispose of saturated absorbant or cleaning materials appropriately, since spontaneous heating may occur. Local, state and federal laws and regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which federal, state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide information regarding certain federal and state requirements.
Note: See Section 8 for Personal Protective Equipment for Spills. Call (989) 496-5900, if additional information is required.
7. HANDLING AND STORAGE Use with adequate ventilation. Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation during use to control HOAc within exposure guidelines or use respiratory protection. Avoid eye contact. Avoid skin contact. Keep container closed and store away from water or moisture.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION Component Exposure Limits CAS Number Component Name
Exposure Limits
17689-77-9 Ethyltriacetoxysilane
See acetic acid comments.
4253-34-3 Methyltriacetoxysilane
See acetic acid comments.
Acetic acid is formed upon contact with water or humid air. Provide adequate ventilation to control exposures within guidelines of OSHA PEL: TWA 10 ppm and ACGIH TLV: TWA 10 ppm, STEL 15 ppm.
Engineering Controls Local Ventilation: None should be needed. General Ventilation: Recommended.
Personal Protective Equipment for Routine Handling
DOW CORNING CORPORATION Material Safety Data Sheet
Page: 4 of 8 Version: 1.10
Revision Date: 2013/04/05 DOW CORNING(R) 732 MULTI -PURPOSE SEALANT CLEAR
Eyes:
Use proper protection - safety glasses as a minimum.
Skin:
Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are recommended.
Suitable Gloves:
Handle in accordance with good industrial hygiene and safety practices.
Inhalation:
No respiratory protection should be needed.
Suitable Respirator:
None should be needed.
Personal Protective Equipment for Spills Eyes:
Use proper protection - safety glasses as a minimum.
Skin:
Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are recommended.
Inhalation/Suitable Respirator:
No respiratory protection should be needed.
Precautionary Measures: Avoid eye contact. Avoid skin contact. Use reasonable care.
Comments: Product evolves acetic acid (HOAc) when exposed to water or humid air. Provide ventilation during use to control HOAc within exposure guidelines or use respiratory protection.
Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may require added precautions.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical Form:
Paste
Color: Colorless Odor: Acetic acid odor
Specific Gravity @ 25°C: 1.04 Viscosity: Not determined.
Freezing/Melting Point: Not determined. Boiling Point: Not determined.
Vapor Pressure @ 25°C: Not determined. Vapor Density: Not determined.
Solubility in Water: Not determined. pH: Not determined.
Volatile Content: Not determined. Flash Point: Not applicable. Not applicable.
Autoignition Temperature: Not determined. Flammability Limits in Air: Not determined.
DOW CORNING CORPORATION Material Safety Data Sheet
Page: 5 of 8 Version: 1.10
Revision Date: 2013/04/05 DOW CORNING(R) 732 MULTI -PURPOSE SEALANT CLEAR
Note: The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing specifications.
10. STABILITY AND REACTIVITY Chemical Stability:
Stable.
Hazardous Polymerization:
Hazardous polymerization will not occur.
Conditions to Avoid:
None.
Materials to Avoid:
Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous vapors to form as described in Section 8.
Hazardous Decomposition Products Thermal breakdown of this product during fire or very high heat conditions may evolve the following decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Formaldehyde.
11. TOXICOLOGICAL INFORMATION Special Hazard Information on Components
No known applicable information.
12. ECOLOGICAL INFORMATION Environmental Fate and Distribution
Complete information is not yet available.
Environmental Effects
Complete information is not yet available.
Fate and Effects in Waste Water Treatment Plants
Complete information is not yet available.
Ecotoxicity Classification Criteria Hazard Parameters (LC50 or EC50) High Medium Low Acute Aquatic Toxicity (mg/L) <=1 >1 and <=100 >100 Acute Terrestrial Toxicity <=100 >100 and <= 2000 >2000 This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993.
DOW CORNING CORPORATION Material Safety Data Sheet
Page: 6 of 8 Version: 1.10
Revision Date: 2013/04/05 DOW CORNING(R) 732 MULTI -PURPOSE SEALANT CLEAR
This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the section concerning the overall ecological safety of this material.
13. DISPOSAL CONSIDERATIONS RCRA Hazard Class (40 CFR 261) When a decision is made to discard this material, as received, is it classified as a hazardous waste? No State or local laws may impose additional regulatory requirements regarding disposal. Call (989) 496-6315, if additional information is required.
14. TRANSPORT INFORMATION DOT Road Shipment Information (49 CFR 172.101) Not subject to DOT. Ocean Shipment (IMDG) Not subject to IMDG code. Air Shipment (IATA) Not subject to IATA regulations. Call Dow Corning Transportation, (989) 496-8577, if additional information is required.
15. REGULATORY INFORMATION Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200. TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA
Inventory of Chemical Substances.
EPA SARA Title III Chemical Listings Section 302 Extremely Hazardous Substances (40 CFR 355): None. Section 304 CERCLA Hazardous Substances (40 CFR 302):
None.
Section 311/312 Hazard Class (40 CFR 370):
Acute: No Chronic: No
DOW CORNING CORPORATION Material Safety Data Sheet
Page: 7 of 8 Version: 1.10
Revision Date: 2013/04/05 DOW CORNING(R) 732 MULTI -PURPOSE SEALANT CLEAR
Fire: No Pressure: No Reactive: No
Section 313 Toxic Chemicals (40 CFR 372):
None present or none present in regulated quantities. Note: Chemicals are listed under the 313 Toxic Chemicals section only if they meet or exceed a reporting threshold. Supplemental State Compliance Information California
Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other reproductive harm.
None known. New Jersey
CAS Number
Wt %
Component Name
70131-67-8 70.0 - 90.0 Dimethyl siloxane, hydroxy-terminated
7631-86-9 7.0 - 13.0 Silicon dioxide
17689-77-9 1.0 - 5.0 Ethyltriacetoxysilane
4253-34-3 1.0 - 5.0 Methyltriacetoxysilane
Pennsylvania CAS Number
Wt %
Component Name
70131-67-8 70.0 - 90.0 Dimethyl siloxane, hydroxy-terminated
7631-86-9 7.0 - 13.0 Silicon dioxide
DOW CORNING CORPORATION Material Safety Data Sheet
Page: 8 of 8 Version: 1.10
Revision Date: 2013/04/05 DOW CORNING(R) 732 MULTI -PURPOSE SEALANT CLEAR
16. OTHER INFORMATION Prepared by: Dow Corning Corporation These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate.
(R) indicates Registered Trademark
Page 1 of 4
Alkaline Batteries January 2014
©2014 Energizer
PRODUCT SAFETY DATA SHEET
PRODUCT NAME: Eveready / Energizer Battery Type No.: Volts: TRADE NAMES: ENERGIZER, ENERGIZER e², INDUSTRIAL ZMA, HERCULES, EVEREADY, WONDER
Approximate Weight:
CHEMICAL SYSTEM: Alkaline Manganese Dioxide-Zinc Designed for Recharge: No
SECTION 1 - MANUFACTURER INFORMATION
Energizer Battery Manufacturing, Inc. Telephone Number for Information: 25225 Detroit Rd. Westlake, OH 44145
800-383-7323 (USA / CANADA)
Date Prepared: January 2014
SECTION 2 – HAZARDS IDENTIFICATION
Under normal conditions of use, the battery is hermetically sealed.
Ingestion: Swallowing a battery can be harmful. Contents of an open battery can cause serious chemical burns of mouth, esophagus, and gastrointestinal tract. Inhalation: Contents of an open battery can cause respiratory irritation. Skin Contact: Contents of an open battery can cause skin irritation and/or chemical burns. Eye Contact: Contents of an open battery can cause severe irritation and chemical burns.
SECTION 3 - INGREDIENTS
IMPORTANT NOTE: The battery should not be opened or burned. Exposure to the ingredients contained within or their combustion products could be harmful.
MATERIAL OR INGREDIENT PEL (OSHA) TLV (ACGIH) %/wt.
Graphite (CAS# 7782-42-5)
15 mg/m3 TWA (total dust) 5 mg/m3 TWA (respirable fraction)
2 mg/m3 TWA (respirable fraction)
2-6
Manganese Dioxide (CAS# 1313-13-9)
5 mg/m3 Ceiling (as Mn) 0.2 mg/m3 TWA (as Mn) 30-45
Potassium Hydroxide (CAS# 1310-58-3)
None established 2 mg/m3 Ceiling 4-8
Zinc (CAS# 7440-66-6)
15 mg/m3 TWA PNOR* (total dust) 5 mg/m3 TWA PNOR* (respirable fraction)
10 mg/m3 TWA PNOC** (inhalable particulate) 3 mg/m3 TWA PNOC** (respirable particulate)
12-25
Non-Hazardous Components Steel (iron CAS# 7439-89-6) Water, Paper, Plastic and Other
None established None established
None established None established
18-22 Balance
* PNOR: Particulates not otherwise regulated **PNOC: Particulates not otherwise classified
Page 2 of 4
Alkaline Batteries January 2014
©2014 Energizer
SECTION 4 – FIRST AID MEASURES
Ingestion: Do not induce vomiting or give food or drink. Seek medical attention immediately. CALL NATIONAL BATTERY INGESTION HOTLINE for advice and follow-up (202-625-3333) collect day or night. Inhalation: Provide fresh air and seek medical attention. Skin Contact: Remove contaminated clothing and wash skin with soap and water. If a chemical burn occurs or if irritation persists, seek medical attention. Eye Contact: Immediately flush eyes thoroughly with water for at least 15 minutes, lifting upper and lower lids, until no evidence of the chemical remains. Seek medical attention.
SECTION 5 - FIRE FIGHTING MEASURES
In case of fire, it is permissible to use any class of extinguishing medium on these batteries or their packing material. Cool exterior of batteries if exposed to fire to prevent rupture. Fire fighters should wear self-contained breathing apparatus.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
To cleanup leaking batteries:
Ventilation Requirements: Room ventilation may be required in areas where there are open or leaking batteries.
Eye Protection: Wear safety glasses with side shields if handling an open or leaking battery. Gloves: Use neoprene or natural rubber gloves if handling an open or leaking battery. Battery materials should be collected in a leak-proof container.
SECTION 7 - HANDLING AND STORAGE
Storage: Store in a cool, well ventilated area. Elevated temperatures can result in shortened battery life.
Mechanical Containment: If potting or sealing the battery in an airtight or watertight container is required, consult your Energizer Battery Manufacturing, Inc. representative for precautionary suggestions. Batteries normally evolve hydrogen which, when combined with oxygen from the air, can produce a combustible or explosive mixture unless vented. If such a mixture is present, short circuits, high temperature, or static sparks can cause an ignition.
Do not obstruct safety release vents on batteries. Encapsulation (potting) of batteries will not allow cell venting and can cause high pressure rupture.
Handling: Accidental short circuit for a few seconds will not seriously affect the battery. Prolonged short circuit will cause the battery to lose energy, and can cause the safety release vent to open. Sources of short circuits include jumbled batteries in bulk containers, metal jewelry, metal covered tables or metal belts used for assembly of batteries into devices.
If soldering or welding to the battery is required, consult your Energizer Battery Manufacturing, Inc. representative for proper precautions to prevent seal damage or short circuit.
Charging: This battery is manufactured in a charged state. It is not designed for recharging. Recharging can cause battery leakage or, in some cases, high pressure rupture. Inadvertent charging can occur if a battery is installed backwards.
Labeling: If the Eveready / Energizer Battery label or package warnings are not visible, it is important to provide a package and/or device label stating:
WARNING: do not install backwards, charge, put in fire, or mix with other battery types. May explode or leak causing injury. Replace all batteries at the same time.
Where accidental ingestion of small batteries is possible, the label should include:
Keep away from small children. If swallowed, promptly see doctor; have doctor phone (202) 625-3333 collect.
Page 3 of 4
Alkaline Batteries January 2014
©2014 Energizer
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation Requirements: Not necessary under normal conditions. Respiratory Protection: Not necessary under normal conditions.
Eye Protection: Not necessary under normal conditions. Gloves: Not necessary under normal conditions.
SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point @ 760 mm Hg (°C) Not applicable for an Article
Vapor Pressure (mm Hg @ 25°C) Not applicable for an Article
Vapor Density (Air = 1) Not applicable for an Article
Density (g/cm3) 2.0 – 3.0
Percent Volatile by Volume (%) Not applicable for an Article
Evaporation Rate (Butyl Acetate = 1) Not applicable for an Article
Physical State Solid
Solubility in Water (% by weight) Not applicable for an Article
pH Not applicable for an Article
Appearance and Odor Solid object / no odor
SECTION 10 – STABILITY AND REACTIVITY
Alkaline batteries do not meet any of the criteria established in 40 CFR 261.2 for reactivity.
SECTION 11 – TOXICOLOGICAL INFORMATION
Alkaline batteries are not hazardous waste. Under normal conditions of use, alkaline batteries are non-toxic.
SECTION 12 – ECOLOGICAL INFORMATION
Issues such as ecotoxicity, persistence and bioaccumulation are not applicable for articles.
SECTION 13 – DISPOSAL CONSIDERATIONS
Dispose of in accordance with all applicable federal, state and local regulations. Appropriate disposal technologies include incineration and land filling.
Page 4 of 4
Alkaline Batteries January 2014
©2014 Energizer
SECTION 14 – TRANSPORT INFORMATION
In general, all batteries in all forms of transportation (ground, air, or ocean) must be packaged in a safe and responsible manner. Regulatory concerns from all agencies for safe packaging require that batteries be packaged in a manner that prevents short circuits and be contained in “strong outer packaging” that prevents spillage of contents. All original packaging for Energizer alkaline batteries has been designed to be compliant with these regulatory concerns. Alkaline batteries (sometimes referred to as “Dry cell” batteries) are not listed as dangerous goods under the ADR European Agreement Concerning the International Carriage of Dangerous Goods by Road, the IMDG International Maritime Dangerous Goods Code, UN Dangerous Good Regulations, IATA Dangerous Goods Regulations, ICAO Technical Instructions and the U.S. hazardous materials regulations (49 CFR). These batteries are not subject to the dangerous goods regulations provided they meet the requirements contained in the following special provisions.
Regulatory Body Special Provisions
ADR Not regulated
IMDG Not regulated
UN Not regulated
US DOT 49 CFR 172.102 Provision 130
IATA A123
ICAO Not regulated
All Energizer alkaline batteries are packed in such a way to prevent short circuits or the generation dangerous quantities of heat and meet the special provisions listed above. In addition, the IATA Dangerous Goods Regulations and ICAO Technical Instructions require the words “not restricted” and the Special Provision number A123 be provided on the air waybill, when an air waybill is issued.
SECTION 15 - REGULATORY INFORMATION
Batteries marketed by Energizer Battery Manufacturing, Inc. are not classified as dangerous goods by the US Department of Transportation or the major international regulatory bodies and are therefore not regulated. SARA/TITLE III - As an article, this battery and its contents are not subject to the requirements of the Emergency Planning and Community Right-To-Know Act.
SECTION 16 - OTHER INFORMATION
None. Energizer has prepared copyrighted Product Safety Datasheets to provide information on the different Eveready/Energizer battery systems. As defined in OSHA Hazard Communication Standard, Section 1910.1200 (c), Eveready/Energizer batteries are manufactured articles, which do not result in exposure to a hazardous chemical under normal conditions of use. The information and recommendations set forth herein are made in good faith, for information only, and are believed to be accurate as of the date of preparation. However, ENERGIZER BATTERY MANUFACTURING, INC., MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, WITH RESPECT TO THIS INFORMATION AND DISCLAIMS ALL LIABILITY FROM REFERENCE ON IT.
1
BOSS LUBRICANTS: MATERIAL SAFETY DATA SHEET
Date Issued: 01/01/2012
PRODUCT INFORMATION
Product Trade Name: BOSS HI-PERFORMANCE SYNTHETIC ENGINE OIL 10W-30
Product Use: Lubricating oil
COMPOSITION/INFORMATION ON INGREDIENTS
OSHA Hazardous Components (29 CFR 1910.1200)
1-Decene, Homopolymer, Hydrogenated Base,
CAS # Mixture, 85-95%
HAZARDS IDENTIFICATION
Potential health effects: Minor eye, inhalation and skin irritant.
FIRST AID MEASURES
EYE: Flush with water for 15-20 minutes.
Seek medical attention if irritation develops.
SKIN: Wash immediately with soap and water.
Remove contaminated clothing and launder before reuse.
Discard shoes and leather articles saturated with the product.
Obtain medical advice if irritation occurs.
INHALATION: Remove exposed person to fresh air.
If breathing is labored give oxygen. If breathing has stopped apply artificial
respiration.
Get immediate medical attention.
INGESTION: DO NOT INDUCE VOMITING.
If conscious, give 2 glasses of water. If vomiting does occur, keep head below
hips to reduce risk of aspiration. Get immediate medical attention.
FIRE FIGHTING MEASURES
FLAMMABILITY PROPERTIES:
Flash Point 236ºC
Method COC ASTM-D-92
LFL/IFL Not determined
Auto-ignition Temperature Not determined
BOSS HI-PERFORMANCE SYNTHETIC ENGINE OIL 10W-30
2
BOSS LUBRICANTS: MATERIAL SAFETY DATA SHEET
EXTINGUISHING MEDIA
Carbon dioxide, dry chemical, and alcohol foam.
FIREFIGHTING EQUIPMENT
Full bunker gear recommended including a positive pressure self-contained
breathing apparatus.
ACCIDENTAL RELEASE MEASURES
Isolate spill area. Provide adequate ventilation. Wear appropriate personal protection. Recover
free product for recycle and/or disposal. Add sand, earth or other suitable to spill area.
Prevent entry into sewers and waterways. Check under Transportation and Labeling
(DOT/CERCLA) and other Regulator Information Section (SARA) for hazardous substances to
determine regulatory reporting requirements for spill.
HANDLING AND STORAGE
HANDLING: Keep containers closed.
Avoid contact with eyes, skin or clothing.
Wash hands after handling.
Empty container may retain product residue, which may exhibit
hazards of product.
STORAGE: Keep away from heat or flame.
EXPOSURE CONTROLS/PERSONAL PROTECTION
VENTILATION: Use adequate general or local exhaust ventilation to keep
airborne concentrations below exposure limits.
RESPIRATORY: Use a NIOSH approved respirator when necessary.
SKIN: Use Viton or Nitrile gloves to avoid prolonged or repeated
skin contact.
EYE: Use splash goggles or face shield where splashing is expected
or can occur.
EXPOSURE LIMITS: The Threshold Limit Value (TLV) of 5 mg/m is suggested
For oil mist.
BOSS HI-PERFORMANCE SYNTHETIC ENGINE OIL 10W-30
3
BOSS LUBRICANTS: MATERIAL SAFETY DATA SHEET
PHYSICAL AND CHEMICAL PROPERTIES
Physical State Liquid
Boiling point Not Determined
Vapor Pressure Not Determined
Vapor Density (Air=1) Negligible
Evaporation Rate Not Determined
Solubility in Water Negligible
Specific Gravity (Water=1) 0.8686
Volatility (Volume) Negligible
VOC Unknown
pH Essentially Neutral
Coefficient of Water/Oil Distribution Not Determined
Odor Mild, Bland, Hydrocarbon Odor
Odor Threshold Not Determined
Appearance Amber Transparent Colored Liquid
Viscosity, cST @ 100ºC 10.70
Viscosity, cST @ 40ºC 62.30
Viscosity Index 161
Refractive Index 1.4664
Fire Point 250ºC
Pour Point -42ºC
STABILITY AND REACTIVITY
STABLILITY: Stable under moderately elevated temperatures and
Pressures.
INCOMPATABILITY: Avoid contact with strong oxidants.
HAZARDOUS POLYMERIZATION: Will not occur.
HAZARDOUS DECOMPOSITION: Toxic oxides of carbon, aldehydes and other products
Of PRODUCT of incomplete combustion.
TOXICOLOGICAL INFORMATION
EYE IRRITATION: Moderate to strong eye irritation. Based on data from components
or similar material.
BOSS HI-PERFORMANCE SYNTHETIC ENGINE OIL 10W-30
4
BOSS LUBRICANTS: MATERIAL SAFETY DATA SHEET
TOXICOLOGICAL INFORMATION (CONT’D)
SKIN IRRITATION: Not expected to be a primary skin irritant. Based on data from
Components or similar material. Prolonged or repeated skin contact as
from clothing wet with material may cause dermatitis. Symptoms may
include redness, edema, drying, defatting, and cracking of the skin.
RESPIRATORY If material is misted or if vapors are generated from heating, exposure
IRRITATION: may cause irritation of mucous membranes and the upper respiratory
tract similar to that observed with mineral oil. Based on data from
components or similar materials. Under good industrial hygiene
practices where all exposure limits are observed, respiratory irritation
should not be a problem.
CHRONIC EXPOSURE
CHRONIC TOXICITY: No data available to indicate product present at greater than 1.0%
are chronic health hazards.
CARCINOGENICITY: No data available to indicate product present at greater than 1.0%
are a carcinogenic.
MUTAGENICITY: No data available to indicate product present at greater than 1.0%
present a mutagenic or genotoxic hazard.
REPRODUCTIVE No data available to indicate product present at greater than 1.0%
TOXICITY: present a reproductive hazard.
TERATOGENICITY: No data available to indicate product present at greater than 1.0%
Present a teratogenic hazards.
ADDITIONAL INFORMATION
EXPOSURE LIMITS: Under conditions which may generate mists, observe the OSHA PEL
mg 5 mg per cubic meter.
ECOLOGICAL INFORMATION
No data available on the adverse effects of this product on the environment.
BOSS HI-PERFORMANCE SYNTHETIC ENGINE OIL 10W-30
5
BOSS LUBRICANTS: MATERIAL SAFETY DATA SHEET
DISPOSAL CONSIDERATIONS
If this product as supplied becomes a waste, it does not meet the criteria of a hazardous waste as
defined under the Resource Conservation and Recovery Act 9RCRA) 40 CFR 261.
TRANSPORT INFORMATION
This product is not classified as hazardous material for DOT shipping. For further information
relative to spills resulting from transportation incidents, refer to the latest DOT Emergency
Response Guidebook for Hazardous Materials.
REGULATORY INFORMATION
U.S. Federal Regulations
OSHA Table Z Synthetic Base Stock (mist)
TSCA Not Applicable
CERCLA 40 CFR 302.4 Zinc compounds @ 1.30 – 2.58% RQ 1 lb
SARA Title III
Section 311/312
Fire Hazard Yes
Reactive Hazard No
Release of Pressure No
Acute Health Hazard Yes
Chronic Health Hazard No
Section 313 Toxic Chemical Not Applicable
U.S. State Regulations
California (Prop 65)
Does not contain chemicals known to the state of California to cause cancer.
International Regulations
WHMIS All components listed
OTHER INFORMATION
The information contained herein is based on data considered accurate, to the best of BOSS
LUBRICANTS’S knowledge, however, no warranty is expressed or implied regarding the accuracy of
these data or the results to be obtained from the use thereof. Vendor assumes no responsibility for injury
or third person proximately caused by the material if reasonable safety procedures are not adhered to as
stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to vendee or third
person proximatley caused by abnormal use of the material even if reasonable safety procedures are
followed. Furthermore, vendee assumes the risk in his use of the material.
BOSS HI-PERFORMANCE SYNTHETIC ENGINE OIL 10W-30
MATERIAL SAFETY DATA SHEET
1. Product and Company Identification
Material name GASOLINE - ETHANOL BLENDED
Version # 01
Issue date 07-19-2012
Revision date -
Supersedes date -
CAS # Mixture
Product code 2738
Product use Motor fuels.
Synonym(s) Unleaded Gasoline * Gasoline * Regular Gasoline * Premium Gasoline * Premium UnleadedGasoline * Mid Grade Gasoline * Gasoline (Export) * Petroleum Naphtha * Alkylate
Manufacturer information
Manufacturer Consumers' Co-operative Refineries Limited
Address P.O. Box 260; 9th Avenue North
Regina, SK S4P 3A1 Canada
Telephone (306) 721-5353
Supplier Federated Co-operatives Limited
Address P.O. Box 1050, 401 - 22nd Street East
Saskatoon SK S7K 3M9 Canada
Telephone (306) 244-3447
24 Hour Emergency
Telephone
(613) 996-6666 - Canutec
2. Hazards Identification
Physical state Liquid.
Appearance Amber liquid.
Emergency overview DANGER!Extremely flammable liquid and vapor - vapor may cause flash fire or explosion. Staticaccumulating flammable liquid can become electrostatically charged even in bonded andgrounded equipment.
Harmful if inhaled, absorbed through skin, or swallowed. Aspiration may cause lung damage.Irritating to eyes, respiratory system and skin. In high concentrations, vapors and spray mists arenarcotic and may cause headache, fatigue, dizziness and nausea. Cancer hazard. May causeheritable genetic damage. Toxic to aquatic organisms. May cause long-term adverse effects in theaquatic environment.
OSHA regulatory status This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).
Potential health effects
Routes of exposure Inhalation. Ingestion. Skin contact. Eye contact.
Eyes Contact may irritate or burn eyes. Eye contact may result in corneal injury.
Skin Harmful if absorbed through skin. Irritating to skin. Frequent or prolonged contact may defat anddry the skin, leading to discomfort and dermatitis.
Inhalation Harmful if inhaled. Irritating to respiratory system. In high concentrations, vapors and spray mistsare narcotic and may cause headache, fatigue, dizziness and nausea. May cause breathingdisorders and lung damage. May cause cancer by inhalation. Prolonged inhalation may beharmful.
Ingestion Harmful if swallowed. Ingestion may result in vomiting; aspiration (breathing) of vomitus into lungsmust be avoided as even small quantities may result in aspiration pneumonitis. Irritating to mouth,throat, and stomach.
Target organs Blood. Eyes. Liver. Respiratory system. Skin. Kidneys. Central nervous system.
CPH MSDS NA
1 / 9
GASOLINE - ETHANOL BLENDED CPH MSDS NA
909438 Version #: 01 Revision date: - Issue date: 07-19-2012
Chronic effects Cancer hazard. Contains material which may have reproductive toxicity, teratogenetic ormutagenic effects. Liver injury may occur. Kidney injury may occur. May cause central nervoussystem disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue, mentalconfusion and blurred vision) and/or damage. Frequent or prolonged contact may defat and drythe skin, leading to discomfort and dermatitis.
Signs and symptoms Irritation of nose and throat. Irritation of eyes and mucous membranes. Skin irritation.Unconsciousness. Corneal damage. Narcosis. Cyanosis (blue tissue condition, nails, lips, and/orskin). Decrease in motor functions. Behavioral changes. Edema. Liver enlargement. Jaundice.Conjunctivitis. Proteinuria. Defatting of the skin. Rash.
Potential environmental effects Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
Components CAS # Percent
3. Composition / Information on Ingredients
86290-81-5 60-100Gasoline
64-17-5 5-10Ethanol
71-43-2 1-5Benzene
Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are inpercent by volume.
4. First Aid Measures
First aid procedures
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention.
Skin contact Remove contaminated clothing and shoes. Wash off immediately with soap and plenty of water.Get medical attention if irritation develops or persists. Wash clothing separately before reuse.Destroy or thoroughly clean contaminated shoes.
Inhalation Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.Get medical attention if discomfort develops or persists.
Ingestion Rinse mouth thoroughly. Do not induce vomiting without advice from poison control center. Ifvomiting occurs, keep head low so that stomach content does not get into the lungs. Get medicalattention immediately.
Notes to physician In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation.Symptoms may be delayed.
General advice If exposed or concerned: get medical attention/advice. Ensure that medical personnel are awareof the material(s) involved, and take precautions to protect themselves. Show this safety datasheet to the doctor in attendance. Wash contaminated clothing before re-use.
5. Fire Fighting Measures
Flammable properties Extremely flammable liquid and vapor - vapor may cause flash fire.
Extinguishing media
Suitable extinguishing
mediaWater. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing
mediaDo not use a solid water stream as it may scatter and spread fire.
Protection of firefighters
Specific hazards arising
from the chemicalVapor may cause flash fire. Vapors can flow along surfaces to distant ignition source and flashback. Sensitive to static discharge.
Protective equipment and
precautions for firefightersWear full protective clothing, including helmet, self-contained positive pressure or pressuredemand breathing apparatus, protective clothing and face mask.
Fire fighting
equipment/instructionsWear full protective clothing, including helmet, self-contained positive pressure or pressuredemand breathing apparatus, protective clothing and face mask. Withdraw immediately in case ofrising sound from venting safety devices or any discoloration of tanks due to fire. Fight fire frommaximum distance or use unmanned hose holders or monitor nozzles. Move containers from firearea if you can do it without risk. In the event of fire, cool tanks with water spray. Cool containersexposed to flames with water until well after the fire is out. For massive fire, use unmanned hoseholders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Vapors mayform explosive air mixtures even at room temperature. Prevent buildup of vapors or gases toexplosive concentrations. Some of these materials, if spilled, may evaporate leaving a flammableresidue. Water runoff can cause environmental damage.
CPH MSDS NA
2 / 9
GASOLINE - ETHANOL BLENDED CPH MSDS NA
909438 Version #: 01 Revision date: - Issue date: 07-19-2012
Specific methods In the event of fire and/or explosion do not breathe fumes. Use water spray to cool unopenedcontainers.
Hazardous combustion
productsCarbon monoxide. Carbon Dioxide. Sulfur oxides. Nitrogen oxides (NOx). Hydrocarbons.
6. Accidental Release Measures
Personal precautions Keep unnecessary personnel away. Local authorities should be advised if significant spillagescannot be contained. Keep upwind. Keep out of low areas. Ventilate closed spaces beforeentering. Do not touch damaged containers or spilled material unless wearing appropriateprotective clothing. See Section 8 of the MSDS for Personal Protective Equipment.
Environmental precautions If facility or operation has an "oil or hazardous substance contingency plan", activate itsprocedures. Stay upwind and away from spill. Wear appropriate protective equipment includingrespiratory protection as conditions warrant. Do not enter or stay in area unless monitoringindicates that it is safe to do so. Isolate hazard area and restrict entry to emergency crew.Flammable. Review Firefighting Measures, Section 5, before proceeding with clean up. Keep allsources of ignition (flames , smoking, flares, etc.) and hot surfaces away from release. Containspill in smallest possible area. Recover as much product as possible (e.g. by vacuuming). Stopleak if it can be done without risk. Use water spray to disperse vapors. Spilled material may beabsorbed by an appropriate absorbent, and then handled in accordance with environmentalregulations. Prevent spilled material from entering sewers, storm drains, other unauthorizedtreatment or drainage systems and natural waterways. Contact fire authorities and appropriatefederal, state and local agencies. If spill of any amount is made into or upon navigable waters, thecontiguous zone, or adjoining shorelines, contact the National Response Center at1-800-424-8802. For highway or railways spills, contact Chemtrec at 1-800-424-9300.
Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leakif you can do so without risk. This material is a water pollutant and should be prevented fromcontaminating soil or from entering sewage and drainage systems and bodies of water. Dike thespilled material, where this is possible. Prevent entry into waterways, sewers, basements orconfined areas.
Methods for cleaning up Small Spills: Absorb spill with vermiculite or other inert material, then place in a container forchemical waste. Clean surface thoroughly to remove residual contamination. This material and itscontainer must be disposed of as hazardous waste.
Large Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the productand place into a container for later disposal. Prevent product from entering drains. Do not allowmaterial to contaminate ground water system. Should not be released into the environment.
Other information Clean up in accordance with all applicable regulations.
7. Handling and Storage
Handling Wear personal protective equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Avoidcontact with eyes, skin, and clothing. Do not taste or swallow. Avoid prolonged exposure. Useonly with adequate ventilation. Wash thoroughly after handling. The product is flammable, andheating may generate vapors which may form explosive vapor/air mixtures. DO NOT handle, storeor open near an open flame, sources of heat or sources of ignition. Protect material from directsunlight. Take precautionary measures against static discharges. All equipment used whenhandling the product must be grounded. Use non-sparking tools and explosion-proof equipment.When using, do not eat, drink or smoke. Avoid release to the environment.
Storage Flammable liquid storage. Do not handle or store near an open flame, heat or other sources ofignition. This material can accumulate static charge which may cause spark and become anignition source. The pressure in sealed containers can increase under the influence of heat. Keepcontainer tightly closed in a cool, well-ventilated place. Keep away from food, drink and animalfeedingstuffs. Keep out of the reach of children.
8. Exposure Controls / Personal Protection
Occupational exposure limits
US. ACGIH Threshold Limit Values
ValueTypeComponents
STELBenzene (CAS 71-43-2) 2.5 ppm
TWA 0.5 ppm
STELEthanol (CAS 64-17-5) 1000 ppm
STELGasoline (CAS 86290-81-5) 500 ppm
TWA 300 ppm
CPH MSDS NA
3 / 9
GASOLINE - ETHANOL BLENDED CPH MSDS NA
909438 Version #: 01 Revision date: - Issue date: 07-19-2012
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
ValueTypeComponents
STELBenzene (CAS 71-43-2) 5 ppm
TWA 1 ppm
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueTypeComponents
PELEthanol (CAS 64-17-5) 1900 mg/m3
1000 ppm
US. OSHA Table Z-2 (29 CFR 1910.1000)
ValueTypeComponents
CeilingBenzene (CAS 71-43-2) 25 ppm
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
ValueTypeComponents
STELBenzene (CAS 71-43-2) 8 mg/m3
2.5 ppm
TWA 1.6 mg/m3
0.5 ppm
TWAEthanol (CAS 64-17-5) 1880 mg/m3
1000 ppm
STELGasoline (CAS 86290-81-5) 500 ppm
TWA 300 ppm
Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and
Safety Regulation 296/97, as amended)
ValueTypeComponents
STELBenzene (CAS 71-43-2) 2.5 ppm
TWA 0.5 ppm
STELEthanol (CAS 64-17-5) 1000 ppm
STELGasoline (CAS 86290-81-5) 500 ppm
TWA 300 ppm
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)
ValueTypeComponents
STELBenzene (CAS 71-43-2) 2.5 ppm
TWA 0.5 ppm
STELEthanol (CAS 64-17-5) 1000 ppm
STELGasoline (CAS 86290-81-5) 500 ppm
TWA 300 ppm
Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)
ValueTypeComponents
STELBenzene (CAS 71-43-2) 15.5 mg/m3
5 ppm
TWA 3 mg/m3
1 ppm
TWAEthanol (CAS 64-17-5) 1880 mg/m3
1000 ppm
Mexico. Occupational Exposure Limit Values
ValueTypeComponents
STELBenzene (CAS 71-43-2) 16 mg/m3
5 ppm
TWA 3.2 mg/m3
1 ppm
TWAEthanol (CAS 64-17-5) 1900 mg/m3
1000 ppm
Engineering controls Provide adequate general and local exhaust ventilation. Use process enclosures, local exhaustventilation, or other engineering controls to control airborne levels below recommended exposurelimits. Use explosion-proof equipment.
Personal protective equipment
Eye / face protection Wear safety glasses. If splash potential exists, wear full face shield or chemical goggles.
Skin protection Wear chemical-resistant, impervious gloves. Full body suit and boots are recommended whenhandling large volumes or in emergency situations. Flame retardant protective clothing isrecommended.
CPH MSDS NA
4 / 9
GASOLINE - ETHANOL BLENDED CPH MSDS NA
909438 Version #: 01 Revision date: - Issue date: 07-19-2012
Respiratory protection Wear a NIOSH-approved (or equivalent) full-facepiece airline respirator in the positive pressuremode with emergency escape provisions.
General hygiene
considerationsAvoid contact with skin. Keep away from food and drink. Provide eyewash station and safetyshower. Handle in accordance with good industrial hygiene and safety practice.
9. Physical & Chemical Properties
Appearance Amber liquid.
Physical state Liquid.
Form Liquid.
Color Amber.
Odor Gasoline-like.
Odor threshold < 0.25 ppm
pH Not available.
Vapor pressure > 1 (Air=1)
Vapor density 3 - 4 ( Air=1)
Boiling point 77 - 392 °F (25 - 200 °C)
Melting point/Freezing point Not available.
Solubility (water) Insoluble
Specific gravity 0.69 - 0.75
Flash point < -40 °F (< -40 °C) Closed Cup
Flammability limits in air,
upper, % by volume
7.1 %
Flammability limits in air,
lower, % by volume
1.2 %
Auto-ignition temperature 842 °F (450 °C)
VOC 100 %
Evaporation rate 4 (Butyl acetate = 1)
10. Chemical Stability & Reactivity Information
Chemical stability Stable under normal temperature conditions and recommended use.
Conditions to avoid Heat, flames and sparks. Ignition sources. Contact with incompatible materials. Do not pressurize,cut, weld, braze, solder, drill, grind or expose empty containers to heat, flame, sparks, staticelectricity, or other sources of ignition; they may explode and cause injury or death.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition
productsCarbon monoxide. Carbon dioxide. Sulfur oxides. Hydrocarbons.
Possibility of hazardous
reactionsHazardous polymerization does not occur.
11. Toxicological Information
Test Results
Toxicological data
Components Species
Ethanol (CAS 64-17-5)
LC50 Rat
Inhalation
Acute
20000 mg/l, 10 Hours
LD50 Rat
Oral
7060 mg/kg
Sensitization This substance may have a potential for sensitization which may provoke an allergic reactionamong sensitive individuals.
Acute effects Harmful if inhaled, absorbed through skin, or swallowed. Harmful: may cause lung damage ifswallowed. Irritating to eyes, respiratory system and skin. In high concentrations, vapors andspray mists are narcotic and may cause headache, fatigue, dizziness and nausea.
CPH MSDS NA
5 / 9
GASOLINE - ETHANOL BLENDED CPH MSDS NA
909438 Version #: 01 Revision date: - Issue date: 07-19-2012
Local effects
US. ACGIH Threshold Limit Values
Benzene (CAS 71-43-2) Can be absorbed through the skin.
Chronic effects Prolonged and repeated exposure to benzene may cause serious injury to blood forming organsand is associated with anemia and to the later development of acute myelogenous leukemia(AML). Danger of serious damage to health by prolonged exposure. Prolonged or repeatedoverexposure may cause central nervous system, kidney, liver, and lung damage.
Subchronic effects Subchronic inhalation of benzene by rats produced decreased white blood cell counts, decreasedbone marrow cell activity, increased red blood cell activity and cataracts. Blood disorders mayoccur after prolonged inhalation, prolonged skin contact and/or ingestion. Liver and kidneydamage may occur after prolonged and repeated exposure.
Carcinogenicity Cancer hazard. Contains benzene, a classified IARC 1 chemical (Known Human Carcinogen).
ACGIH Carcinogens
Benzene (CAS 71-43-2) A1 Confirmed human carcinogen.
Ethanol (CAS 64-17-5) A3 Confirmed animal carcinogen with unknown relevance tohumans.
Gasoline (CAS 86290-81-5) A3 Confirmed animal carcinogen with unknown relevance tohumans.
IARC Monographs. Overall Evaluation of Carcinogenicity
Benzene (CAS 71-43-2) 1 Carcinogenic to humans.
Gasoline (CAS 86290-81-5) 2B Possibly carcinogenic to humans.
US NTP Report on Carcinogens: Known carcinogen
Benzene (CAS 71-43-2) Known To Be Human Carcinogen.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Benzene (CAS 71-43-2) Cancer hazard.
Epidemiology Contains benzene. Human epidemiology studies indicate that prolonged and/or repeatedoverexposure to benzene may cause damage to the blood-producing system and serious blooddisorders, including leukemia. Animal tests suggest that prolonged and/or repeated overexposureto benzene may damage the embryo/fetus. The relevance of these animal studies to humans hasnot been fully established.
Mutagenicity May cause heritable genetic damage.
Neurological effects Central and/or peripheral nervous system damage. May cause central nervous system disorder(e.g., narcosis involving a loss of coordination, weakness, fatigue) and/or damage.
Reproductive effects Animal studies of benzene have shown testicular effects, alterations in reproductive cycles,chromosomal aberrations and embryo/fetotoxicity. May damage fertility or the unborn child. Cancause adverse reproductive effects - such as birth defects, miscarriages, or infertility. Avoidexposure to women during early pregnancy. Avoid contact during pregnancy/while nursing.
Further information Symptoms may be delayed.
12. Ecological Information
Ecotoxicological data
Components Test ResultsSpecies
Benzene (CAS 71-43-2)
Aquatic
EC50Crustacea 8.76 - 15.6 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish 5.3 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)
Ethanol (CAS 64-17-5)
Aquatic
EC50Crustacea 7.7 - 11.2 mg/l, 48 hoursWater flea (Daphnia magna)
LC50Fish > 100 mg/l, 96 hoursFathead minnow (Pimephales promelas)
Ecotoxicity Contains a substance which causes risk of hazardous effects to the environment.
Environmental effects The product contains a substance which is toxic to aquatic organisms and which may causelong-term adverse effects in the aquatic environment.
Aquatic toxicity Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
Persistence and degradability Not available.
CPH MSDS NA
6 / 9
GASOLINE - ETHANOL BLENDED CPH MSDS NA
909438 Version #: 01 Revision date: - Issue date: 07-19-2012
Bioaccumulation /
AccumulationNot available.
Partition coefficient
Ethanol -0.31
Benzene 2.13
13. Disposal Considerations
Waste codes D001: Waste Flammable material with a flash point <140 °FD018: Waste Benzene
Disposal instructions Dispose in accordance with all applicable regulations. Dispose of this material and its container tohazardous or special waste collection point. Incinerate the material under controlled conditions inan approved incinerator. Do not allow this material to drain into sewers/water supplies. Do notcontaminate ponds, waterways or ditches with chemical or used container.
14. Transport Information
DOT
UN1203UN number
Basic shipping requirements:
Gasoline, MARINE POLLUTANTProper shipping name
3Hazard class
IIPacking group
YesMarine pollutant
Environmental hazards
144, 177, B1, B33, IB2, T4, TP1 Special provisions
Additional information:
150Packaging exceptions
202Packaging non bulk
242Packaging bulk
IATA
UN1203UN number
GasolineUN proper shipping name
3Transport hazard class(es)
IIPacking group
YesEnvironmental hazards
3HERG code
IMDG
UN1203UN number
GASOLINE, MARINE POLLUTANTUN proper shipping name
3Transport hazard class(es)
IIPacking group
YesMarine pollutant
Environmental hazards
F-E, S-EEmS No.
TDG
GASOLINE, MARINE POLLUTANTProper shipping name
3Hazard class
UN1203UN number
IIPacking group
YesMarine pollutant
17, 82, 88Special provisions
15. Regulatory Information
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Benzene (CAS 71-43-2)
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration
Benzene (CAS 71-43-2) 0.1 %
CPH MSDS NA
7 / 9
GASOLINE - ETHANOL BLENDED CPH MSDS NA
909438 Version #: 01 Revision date: - Issue date: 07-19-2012
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Benzene (CAS 71-43-2) Listed.
CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)
Gasoline: 100Benzene: 10
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - YesDelayed Hazard - YesFire Hazard - YesPressure Hazard - NoReactivity Hazard - No
Section 302 extremely
hazardous substance (40
CFR 355, Appendix A)
No
Section 311/312 (40 CFR
370)Yes
Drug Enforcement
Administration (DEA) (21 CFR
1308.11-15)
Not controlled
WHMIS status Controlled
WHMIS classification B2 - Flammable LiquidsD1A - Immediate/Serious-VERY TOXICD2A - Other Toxic Effects-VERY TOXICD2B - Other Toxic Effects-TOXIC
WHMIS labeling
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Australian Inventory of Chemical Substances (AICS) YesAustralia
Domestic Substances List (DSL) YesCanada
Non-Domestic Substances List (NDSL) NoCanada
Inventory of Existing Chemical Substances in China (IECSC) NoChina
European Inventory of Existing Commercial ChemicalSubstances (EINECS)
YesEurope
European List of Notified Chemical Substances (ELINCS) NoEurope
Inventory of Existing and New Chemical Substances (ENCS) NoJapan
Existing Chemicals List (ECL) YesKorea
New Zealand Inventory YesNew Zealand
Philippine Inventory of Chemicals and Chemical Substances(PICCS)
YesPhilippines
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s)
Toxic Substances Control Act (TSCA) Inventory NoUnited States & Puerto Rico
State regulations
US - California Hazardous Substances (Director's): Listed substance
Benzene (CAS 71-43-2) Listed.
Ethanol (CAS 64-17-5) Listed.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Benzene (CAS 71-43-2) Listed.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
Benzene (CAS 71-43-2) Listed: February 27, 1987 Carcinogenic.
US - California Proposition 65 - CRT: Listed date/Developmental toxin
Benzene (CAS 71-43-2) Listed: December 26, 1997 Developmental toxin.
CPH MSDS NA
8 / 9
GASOLINE - ETHANOL BLENDED CPH MSDS NA
909438 Version #: 01 Revision date: - Issue date: 07-19-2012
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
Benzene (CAS 71-43-2) Listed: December 26, 1997 Male reproductive toxin.
US - New Jersey RTK - Substances: Listed substance
Benzene (CAS 71-43-2) Listed.
Ethanol (CAS 64-17-5) Listed.
US - Pennsylvania RTK - Hazardous Substances: Special hazard
Benzene (CAS 71-43-2) Special hazard.
US. Massachusetts RTK - Substance List
Benzene (CAS 71-43-2) Listed.
Ethanol (CAS 64-17-5) Listed.
US. New Jersey Worker and Community Right-to-Know Act
Benzene (CAS 71-43-2) 500 LBS
US. Pennsylvania RTK - Hazardous Substances
Benzene (CAS 71-43-2) Listed.
Ethanol (CAS 64-17-5) Listed.
Gasoline (CAS 86290-81-5) Listed.
16. Other Information
Further information HMIS® is a registered trade and service mark of the NPCA.
HMIS® ratings Health: 2*Flammability: 4Physical hazard: 0
NFPA ratings Health: 2Flammability: 4Instability: 0
Disclaimer To the best of our knowledge, the information contained herein is accurate. However, neither theabove named supplier nor any of its subsidiaries assumes any liability whatsoever forcompleteness of the information contained herein. Final determination of suitability of any materialis the sole responsibility of the user. All materials may present unknown hazards and should beused with caution. Although certain hazards are described herein, we cannot guarantee that theseare the only hazards that exist.
CPH MSDS NA
9 / 9
GASOLINE - ETHANOL BLENDED CPH MSDS NA
909438 Version #: 01 Revision date: - Issue date: 07-19-2012
MATERIAL SAFETY DATA SHEET
1. Product and Company IdentificationMaterial name KeroseneRevision date 10-25-2011Version # 01Product code 106Product use Heating and illuminating oil.Synonym(s) VARSOL 3139 SOLVENT
(613) 996-6666 - Canutec(306) 244-3447
Federated Co-operative Limited(416) 968-4415Toronto, ON M5W 1K3111 ST. Clair Avenue WestImperial Oil; Chemical Division
24 Hour EmergencyTelephone
Telephone
AddressSupplierTelephone
AddressManufacturer
P.O. Box 1050, 401 - 22nd StreetEast Saskatoon SK S7K 3M9 Canada
2. Hazards IdentificationPhysical state Liquid.Appearance Clear liquid.Emergency overview WARNING! Combustible liquid and vapor. Harmful if swallowed - may enter lungs if swallowed or
vomited. May cause skin irritation. May cause central nervous system effects. May cause damageto the kidneys.
OSHA regulatory status This product is hazardous according to OSHA 29 CFR 1910.1200.Potential health effects
Routes of exposure Inhalation. Skin contact. Ingestion.Eyes Direct contact with eyes may cause temporary irritation.Skin Prolonged or repeated contact may dry skin and cause irritation.Inhalation Overexposure to mists/vapours of this product may cause headache, dizziness, nausea, and
respiratory tract irritation.Ingestion Swallowing or vomiting of the liquid may result in aspiration into the lungs.
Chronic effects Exposure over a long period of time may cause central nervous system effects. Symptoms maybe delayed.
Signs and symptoms Overexposure to mists/vapours of this product may cause headache, dizziness, nausea, andrespiratory tract irritation. Prolonged or repeated contact may dry skin and cause irritation.Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.
Potential environmental effects Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Components CAS # Percent
3. Composition / Information on Ingredients
8052-41-3 60-100Stoddard solvent
64742-47-8 30-60Distillates, (petroleum), Hydrotreated Light
95-63-6 1-51,2,4-Trimethylbenze ne
100-41-4 0.1-1Ethylbenzene
91-20-3 0.1-1Naphthalene
1330-20-7 0.1-1Xylene
Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are inpercent by volume.
CPH MSDS NA
1 / 9Kerosene904858 Version #: 01 Revision date: 10-25-2011 Print date: 10-25-2011
07-12-2012
Contact supplier for current manufacturer.
07-12-201207-12-2012
4. First Aid MeasuresFirst aid procedures
Eye contact Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least20 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately.
Skin contact Wash area with soap and water. Get medical attention if irritation develops or persists.Inhalation If symptomatic, move to fresh air. Get medical attention if symptoms persist.Ingestion Call a physician or poison control center immediately. DO NOT induce vomiting. If victim is fully
conscious, give a cupful of water. Never give anything by mouth to an unconscious person. Ifvomiting occurs, keep head lower than the hips to help prevent aspiration. Never give anything bymouth to an unconscious person.
Notes to physician Treat symptomatically.
5. Fire Fighting MeasuresFlammable properties Combustible liquid and vapor. Material will float and may ignite on surface of water. Containers
may explode when heated.Extinguishing media
Suitable extinguishingmedia
Carbon dioxide (CO2). Foam. Dry chemical. Water fog.
Unsuitable extinguishingmedia
None known.
Fire fightingequipment/instructions
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Specific methods Cool containers exposed to heat with water spray and remove container, if no risk is involved.Hazardous combustionproducts
Carbon oxides.
6. Accidental Release MeasuresPersonal precautions Ensure adequate ventilation. Wear suitable protective clothing. See Section 8 of the MSDS for
Personal Protective Equipment.Environmental precautions Collect and dispose of spillage as indicated in Section 13 of the MSDS.Methods for containment Eliminate all ignition sources. Dike the spilled material, where this is possible. Prevent entry into
waterways, sewer, basements or confined areas.Methods for cleaning up Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Use a non-combustible
material like vermiculite, sand or earth to soak up the product and place into a container for laterdisposal.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece).
Never return spills to original containers for re-use. Following product recovery, flush area withwater. Clean surface thoroughly to remove residual contamination.
Other information Absorb spill with vermiculite or other inert material, then place in a container for chemical waste.
7. Handling and StorageHandling Use only with adequate ventilation. Wash thoroughly after handling. Observe good industrial
hygiene practices.Storage Keep container tightly closed and in a well-ventilated place. Store in closed original container at
room temperature. Store away from incompatible materials.
8. Exposure Controls / Personal ProtectionOccupational exposure limits
US. ACGIH Threshold Limit ValuesValueTypeComponents
1,2,4-Trim ethyl benze ne (95-63-6)
TWA 25 ppm
Ethylbenze ne (100-41-4) TWA 20 ppmNaphthalen e (91-20-3) STEL 15 ppm
TWA 10 ppmStoddard solvent (8052-41-3)
TWA 100 ppm
CPH MSDS NA
2 / 9Kerosene904858 Version #: 01 Revision date: 10-25-2011 Print date: 10-25-201107-12-2012 07-12-2012
US. ACGIH Threshold Limit ValuesValueTypeComponents
Xylene (1330-20-7) STEL 150 ppmTWA 100 ppm
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)ValueTypeComponents
Ethylbenze ne (100-41-4) PEL 435 mg/m3100 ppm
Naphthalen e (91-20-3) PEL 50 mg/m310 ppm
Stoddard solvent (8052-41-3)
PEL 2900 mg/m3
500 ppmXylene (1330-20-7) PEL 435 mg/m3
100 ppmCanada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
FormValueTypeComponents1,2,4-Trim ethyl benze ne (95-63-6)
TWA 123 mg/m3
25 ppmDistillate s, (petroleum ),Hydrotreat ed Light (64742-47-8)
TWA 200 mg/m3 Vapor.
Ethylbenze ne (100-41-4) STEL 543 mg/m3125 ppm
TWA 434 mg/m3100 ppm
Naphthalen e (91-20-3) STEL 79 mg/m315 ppm
TWA 52 mg/m310 ppm
Stoddard solvent (8052-41-3)
TWA 572 mg/m3
100 ppmCanada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health andSafety Regulation 296/97, as amended)
FormValueTypeComponents1,2,4-Trim ethyl benze ne (95-63-6)
TWA 25 ppm
Distillate s, (petroleum ),Hydrotreat ed Light (64742-47-8)
TWA 200 mg/m3 Non-aerosol.
Ethylbenze ne (100-41-4) STEL 125 ppmTWA 100 ppm
Naphthalen e (91-20-3) STEL 15 ppmTWA 10 ppm
Stoddard solvent (8052-41-3)
STEL 580 mg/m3
TWA 290 mg/m3Xylene (1330-20-7) STEL 150 ppm
TWA 100 ppmCanada. Ontario OELs. (Ministry of Labor - Control of Exposure to Biological or Chemical Agents)
ValueTypeComponents1,2,4-Trim ethyl benze ne (95-63-6)
TWA 123 mg/m3
25 ppmEthylbenze ne (100-41-4) STEL 540 mg/m3
125 ppmTWA 435 mg/m3
100 ppm
CPH MSDS NA
3 / 9Kerosene904858 Version #: 01 Revision date: 10-25-2011 Print date: 10-25-201107-12-2012 07-12-2012
Canada. Ontario OELs. (Ministry of Labor - Control of Exposure to Biological or Chemical Agents)ValueTypeComponents
Naphthalen e (91-20-3) STEL 78 mg/m315 ppm
TWA 52 mg/m310 ppm
Stoddard solvent (8052-41-3)
TWA 525 mg/m3
Xylene (1330-20-7) STEL 650 mg/m3150 ppm
TWA 435 mg/m3100 ppm
Canada. Quebec OELS. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)ValueTypeComponents
1,2,4-Trim ethyl benze ne (95-63-6)
TWA 123 mg/m3
25 ppmEthylbenze ne (100-41-4) STEL 543 mg/m3
125 ppmTWA 434 mg/m3
100 ppmNaphthalen e (91-20-3) STEL 79 mg/m3
15 ppmTWA 52 mg/m3
10 ppmStoddard solvent (8052-41-3)
TWA 525 mg/m3
100 ppmXylene (1330-20-7) STEL 651 mg/m3
150 ppmTWA 434 mg/m3
100 ppmMexico. Occupational Exposure Limit Values
ValueTypeComponents1,2,4-Trim ethyl benze ne (95-63-6)
STEL 170 mg/m3
35 ppmTWA 125 mg/m3
25 ppmEthylbenze ne (100-41-4) STEL 545 mg/m3
125 ppmTWA 435 mg/m3
100 ppmNaphthalen e (91-20-3) STEL 75 mg/m3
15 ppmTWA 50 mg/m3
10 ppmStoddard solvent (8052-41-3)
STEL 1050 mg/m3
200 ppmTWA 523 mg/m3
100 ppmXylene (1330-20-7) STEL 655 mg/m3
150 ppmTWA 435 mg/m3
100 ppmEngineering controls Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk of
inhalation of vapors.Personal protective equipment
Eye / face protection Use approved safety goggles or face shield.Skin protection Wear appropriate chemical resistant clothing to prevent any possibility of skin contact.Respiratory protection In case of inadequate ventilation, use respiratory protection.
CPH MSDS NA
4 / 9Kerosene904858 Version #: 01 Revision date: 10-25-2011 Print date: 10-25-201107-12-2012 07-12-2012
General hygieneconsiderations
Always observe good personal hygiene measures, such as washing after handling the materialand before eating, drinking, and/or smoking. Routinely wash work clothing and protectiveequipment to remove contaminants.
9. Physical & Chemical PropertiesAppearance Clear liquid.
Color Clear, colorless.
Odor Mild. Petroleum.
Odor threshold Not available.
Physical state Liquid.
Form Liquid.
pH Not applicable.
Melting point < -65.2 °F (< -54 °C)
Freezing point < -65.2 °F (< -54 °C)
Boiling point 327.2 - 397.4 °F (164 - 203 °C)
Flash point 116.6 °F (47 °C) Closed Cup
Evaporation rate 0.01 (Butyl acetate = 1)
Flammability limits in air, upper,% by volume
6 %
Flammability limits in air, lower,% by volume
1.1 %
Vapor pressure 0.03 kPa
Vapor density 5
Specific gravity 0.8 (15.5°C)
Solubility (water) Very slightly soluble in the following materials: cold water and hot water.
Partition coefficient(n-octanol/water)
Not available.
Auto-ignition temperature 440.6 °F (227 °C)
Decomposition temperature Not available.
VOC 0.81 % w/w
Percent volatile 100 % w/w
10. Chemical Stability & Reactivity InformationChemical stability Material is stable under normal conditions.Conditions to avoid Heat, sparks, flames. Contact with incompatible materials.Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts
No hazardous decomposition products are known.
Possibility of hazardousreactions
Will not occur.
Toxicological data
11. Toxicological Information
Product Test Results
Acute Dermal LD50 Rabbit: 471.476 g/kg estimatedKerosene
Acute Dermal LD50 Rat: 4714.7574 g/kg estimatedAcute Inhalation LC50 Rat: 86434.1588 ppm estimatedAcute Inhalation LC50 Rat: 86434.1588 mg/l estimatedAcute Other LD50 Mouse: 22579.9501 mg/kg estimated
Components Test Results
Acute Dermal LD50 Rabbit: > 5000 mg/kgEthylbenzene (100-41-4)
Acute Oral LD50 Rat: 5.46 g/kg
CPH MSDS NA
5 / 9Kerosene904858 Version #: 01 Revision date: 10-25-2011 Print date: 10-25-201107-12-201207-12-2012
Components Test Results
Acute Oral LD50 Rat: 4300 mg/kgXylene (1330-20-7)
Acute Dermal LD50 Rabbit: > 2 g/kgNaphthalene (91-20-3)
Acute Oral LD50 Rat: 490 mg/kgAcute Dermal LD50 Rabbit: > 3160 mg/kg1,2,4-Trimethylbenzene (95-63-6)
Acute Inhalation LC50 Rat: 18000 mg/m3 4 hoursAcute effects Harmful if swallowed - may enter lungs if swallowed or vomited. Prolonged or repeated contact
may dry skin and cause irritation. Overexposure to mists/vapours of this product may causeheadache, dizziness, nausea, and respiratory tract irritation.
Local effectsUS ACGIH Threshold Limit Values: Skin designation
Naphthalene (CAS 91-20-3) Can be absorbed through the skin.Sensitization None known.Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
ACGIH CarcinogensEthylbenzene (CAS 100-41-4) A3 Confirmed animal carcinogen with unknown relevance to
humans.Naphthalene (CAS 91-20-3) A4 Not classifiable as a human carcinogen.Xylene (CAS 1330-20-7) A4 Not classifiable as a human carcinogen.
IARC Monographs. Overall Evaluation of CarcinogenicityEthylbenzene (CAS 100-41-4) 2B Possibly carcinogenic to humans.Naphthalene (CAS 91-20-3) 2B Possibly carcinogenic to humans.Stoddard solvent (CAS 8052-41-3) 3 Not classifiable as to carcinogenicity to humans.Xylene (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans.
US NTP Report on Carcinogens: Anticipated carcinogenNaphthalene (CAS 91-20-3) Anticipated carcinogen.
Ecotoxicological data
12. Ecological Information
Product Test Results
EC50 Daphnia: 267.4925 mg/l 48 hours estimatedKeroseneComponents Test Results
EC50 Water flea (Daphnia magna): 1 - 4 mg/l 48 hoursEthylbenzene (100-41-4)LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss): 4mg/l 96 hoursLC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss): 8mg/l 96 Hours
Xylene (1330-20-7)
EC50 Water flea (Daphnia magna): 1.09 - 3.4 mg/l 48 hoursNaphthalene (91-20-3)LC50 Rainbow trout,donaldson trout (Oncorhynchus mykiss):0.91 - 2.82 mg/l 96 hoursLC50 Fathead minnow (Pimephales promelas): 7.19 - 8.28 mg/l96 hours
1,2,4-Trimethylbenzene (95-63-6)
Ecotoxicity Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Persistence anddegradability
No data available.
Bioaccumulation /Accumulation
No data available.
Partition coefficient(n-octanol/water)
Not available.
Mobility in environmentalmedia
No data available.
CPH MSDS NA
6 / 9Kerosene904858 Version #: 01 Revision date: 10-25-2011 Print date: 10-25-201107-12-2012 07-12-2012
13. Disposal ConsiderationsWaste codes D001: Waste Flammable material with a flash point <140 °FDisposal instructions Must be incinerated in a suitable incineration plant holding a permit delivered by the competent
authorities. Do not allow this material to drain into sewers/water supplies. Do not contaminateponds, waterways or ditches with chemical or used container. When this product as supplied is tobe discarded as waste, it may meet the definition of a RCRA waste under 40 CFR 261.
Waste from residues / unusedproducts
Dispose of waste and residues in accordance with local authority requirements.
Contaminated packaging Since emptied containers retain product residue, follow label warnings even after container isemptied.
14. Transport InformationDOT
Basic shipping requirements:UN1268UN numberPetroleum distillates, n.o.s.Proper shipping nameCombustible LiquidHazard classIIIPacking group3Labels required
Additional information:144, T11, TP1, TP8Special provisions150Packaging exceptions201Packaging non bulk243Packaging bulk128ERG number
IATABasic shipping requirements:
1268UN numberPetroleum distillates, n.o.s. (Stoddard solvent)Proper shipping name3Hazard classIIIPacking group
Additional information:3HERG code
IMDGBasic shipping requirements:
1268UN numberPETROLEUM DISTILLATES, N.O.S. (Stoddard solvent)Proper shipping name3Hazard classIIIPacking groupF-E, S-EEmS No.
TDGBasic shipping requirements:
PETROLEUM DISTILLATES, N.O.S. (Stoddard solvent)Proper shipping name3Hazard classUN1268UN numberIIIPacking group·Marine pollutant
15. Regulatory InformationUS federal regulations This product is hazardous according to OSHA 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.TSCA Section 12(b) Export Notification(40 CFR 707, Subpt. D)
Not regulated.US CAA Section 112 Hazardous Air Pollutants (HAPs) List
ETHYLBENZENE (CAS 100-41-4)M-XYLENES (CAS 1330-20-7)NAPHTHALENE (CAS 91-20-3)
CPH MSDS NA
7 / 9Kerosene904858 Version #: 01 Revision date: 10-25-2011 Print date: 10-25-201107-12-201207-12-2012
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration1,2,4-Trimethylbenzene (CAS 95-63-6) 1.0 %Ethylbenzene (CAS 100-41-4) 0.1 %Naphthalene (CAS 91-20-3) 0.1 %Xylene (CAS 1330-20-7) 1.0 %
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance1,2,4-Trimethylbenzene (CAS 95-63-6) Listed.Ethylbenzene (CAS 100-41-4) Listed.Naphthalene (CAS 91-20-3) Listed.Xylene (CAS 1330-20-7) Listed.
CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)Ethylbenze ne: 1000Naph thalene: 100Xylen e: 100
Superfund Amendments and Reauthorization Act of 1986 (SARA)Hazard categories Immediate Hazard - Yes
Delayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No
Section 302 extremelyhazardous substance (40CRF 355, Appendix A)
No
Section 311/312 (40 CFR370)
No
Drug EnforcementAdministration (DEA) (21 CFR1308.11-15)
Not controlled
Canadian regulations This product has been classified in accordance with the hazard criteria of the CPR and the MSDScontains all the information required by the CPR.
WHMIS status ControlledWHMIS classification B3 - Flammable/Combustible
D2A - Other Toxic Effects-VERY TOXICD2B - Other Toxic Effects-TOXIC
WHMIS labeling
Inventory statusCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
State regulations WARNING: This product contains chemicals known to the State of California to cause cancer.
CPH MSDS NA
8 / 9Kerosene904858 Version #: 01 Revision date: 10-25-2011 Print date: 10-25-201107-12-201207-12-2012
US - California Hazardous Substances (Director's): Listed substance1,2,4-Trimethylbenzene (CAS 95-63-6) Listed.Ethylbenzene (CAS 100-41-4) Listed.Naphthalene (CAS 91-20-3) Listed.Stoddard solvent (CAS 8052-41-3) Listed.Xylene (CAS 1330-20-7) Listed.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substanceEthylbenzene (CAS 100-41-4) Listed.Naphthalene (CAS 91-20-3) Listed.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substanceEthylbenzene (CAS 100-41-4) Listed: June 11, 2004 Carcinogenic.Naphthalene (CAS 91-20-3) Listed: April 19, 2002 Carcinogenic.
US - Massachusetts RTK - Substance: Listed substance1,2,4-Trimethylbenzene (CAS 95-63-6) Listed.Distillates, (petroleum), Hydrotreated Light (CAS64742-47-8)
Listed.
Ethylbenzene (CAS 100-41-4) Listed.Naphthalene (CAS 91-20-3) Listed.Stoddard solvent (CAS 8052-41-3) Listed.
US - New Jersey Community RTK (EHS Survey): Reportable threshold1,2,4-Trimethylbenzene (CAS 95-63-6) 500 LBSDistillates, (petroleum), Hydrotreated Light (CAS64742-47-8)
10000 LBS
Ethylbenzene (CAS 100-41-4) 500 LBSNaphthalene (CAS 91-20-3) 500 LBSXylene (CAS 1330-20-7) 500 LBS
US - New Jersey RTK - Substances: Listed substance1,2,4-Trimethylbenzene (CAS 95-63-6) Listed.Ethylbenzene (CAS 100-41-4) Listed.Naphthalene (CAS 91-20-3) Listed.Stoddard solvent (CAS 8052-41-3) Listed.Xylene (CAS 1330-20-7) Listed.
US - Pennsylvania RTK - Hazardous Substances: Listed substance1,2,4-Trimethylbenzene (CAS 95-63-6) Listed.Distillates, (petroleum), Hydrotreated Light (CAS64742-47-8)
Listed.
Ethylbenzene (CAS 100-41-4) Listed.Naphthalene (CAS 91-20-3) Listed.Stoddard solvent (CAS 8052-41-3) Listed.Xylene (CAS 1330-20-7) Listed.
16. Other InformationHMIS® ratings Health: 2
Flammability: 2Physical hazard: 0
NFPA ratings Health: 2Flammability: 2Instability: 0
Disclaimer The information in the sheet was written based on the best knowledge and experience currentlyavailable.
Issue date 10-25-2011
CPH MSDS NA
9 / 9Kerosene904858 Version #: 01 Revision date: 10-25-2011 Print date: 10-25-201107-12-201207-12-2012
07-12-2012
MATERIAL SAFETY DATA SHEET
1. Product and Company IdentificationMaterial name SOLVENTRevision date 09-16-2011Version # 01CAS # 8052-41-3Product code 2183Product use Solvent. Fuel. Diluter Feedstock.Synonym(s) VARSOL 3139 SOLVENT
(613) 996-6666 - Canutec(306) 244-3447
Federated Co-operative Limited-Richmond, BC V6X 1W5 Canada9800 Van Home WayUnivar Canada Ltd.
24 Hour EmergencyTelephone
Telephone
AddressSupplierTelephone
AddressManufacturer
P.O. Box 1050, 401 - 22nd StreetEast Saskatoon SK S7K 3M9 Canada
2. Hazards IdentificationPhysical state Liquid.Appearance Clear liquid.Emergency overview WARNING! Combustible liquid and vapor. Harmful if swallowed - may enter lungs if swallowed or
vomited. May cause skin irritation. May cause central nervous system effects. May cause damageto the kidneys.
OSHA regulatory status This product is hazardous according to OSHA 29 CFR 1910.1200.Potential health effects
Routes of exposure Inhalation. Skin contact. Ingestion.Eyes Direct contact with eyes may cause temporary irritation.Skin Prolonged or repeated contact may dry skin and cause irritation.Inhalation Overexposure to mists/vapours of this product may cause headache, dizziness, nausea, and
respiratory tract irritation.Ingestion Swallowing or vomiting of the liquid may result in aspiration into the lungs.
Chronic effects Exposure over a long period of time may cause central nervous system effects. Symptoms maybe delayed.
Signs and symptoms Overexposure to mists/vapours of this product may cause headache, dizziness, nausea, andrespiratory tract irritation. Prolonged or repeated contact may dry skin and cause irritation.Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.
Potential environmental effects Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Components CAS # Percent
3. Composition / Information on Ingredients
8052-41-3 60-100Stoddart solvent
Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are inpercent by volume.
4. First Aid MeasuresFirst aid procedures
Eye contact Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least20 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately.
CPH MSDS NA
1 / 6SOLVENT904346 Version #: 01 Revision date: 09-16-2011 Print date: 09-19-2011
Contact supplier for current manufacturer.
07-12-2012
07-12-2012 07-12-2012
Skin contact Wash area with soap and water. Get medical attention if irritation develops or persists.Inhalation If symptomatic, move to fresh air. Get medical attention if symptoms persist.Ingestion Call a physician or poison control center immediately. DO NOT induce vomiting. If victim is fully
conscious, give a cupful of water. Never give anything by mouth to an unconscious person. Ifvomiting occurs, keep head lower than the hips to help prevent aspiration. Never give anything bymouth to an unconscious person.
Notes to physician Treat symptomatically.
5. Fire Fighting MeasuresFlammable properties Combustible liquid and vapor. Material will float and may ignite on surface of water. Containers
may explode when heated.Extinguishing media
Suitable extinguishingmedia
Carbon dioxide (CO2). Foam. Dry chemical. Water fog.
Unsuitable extinguishingmedia
None known.
Fire fightingequipment/instructions
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Specific methods Cool containers exposed to heat with water spray and remove container, if no risk is involved.Hazardous combustionproducts
Carbon oxides.
6. Accidental Release MeasuresPersonal precautions Ensure adequate ventilation. Wear suitable protective clothing. See Section 8 of the MSDS for
Personal Protective Equipment.Environmental precautions Collect and dispose of spillage as indicated in Section 13 of the MSDS.Methods for containment Eliminate all ignition sources. Dike the spilled material, where this is possible. Prevent entry into
waterways, sewer, basements or confined areas.Methods for cleaning up Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Use a non-combustible
material like vermiculite, sand or earth to soak up the product and place into a container for laterdisposal.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece).
Never return spills to original containers for re-use. Following product recovery, flush area withwater. Clean surface thoroughly to remove residual contamination.
Other information Absorb spill with vermiculite or other inert material, then place in a container for chemical waste.
7. Handling and StorageHandling Use only with adequate ventilation. Wash thoroughly after handling. Observe good industrial
hygiene practices.Storage Keep container tightly closed and in a well-ventilated place. Store in closed original container at
room temperature. Store away from incompatible materials.
8. Exposure Controls / Personal ProtectionOccupational exposure limits
US. ACGIH Threshold Limit ValuesValueTypeMaterial
Stoddart solvent (8052-41-3)
TWA 100 ppm
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)ValueTypeMaterial
Stoddart solvent (8052-41-3)
PEL 2900 mg/m3
500 ppmCanada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
ValueTypeMaterialStoddart solvent (8052-41-3)
TWA 100 ppm
CPH MSDS NA
2 / 6SOLVENT904346 Version #: 01 Revision date: 09-16-2011 Print date: 09-19-201107-12-2012 07-12-2012
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)ValueTypeMaterial572 mg/m3
Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health andSafety Regulation 296/97, as amended)
ValueTypeMaterialStoddart solvent (8052-41-3)
TWA 290 mg/m3
STEL 580 mg/m3Canada. Ontario OELs. (Ministry of Labor - Control of Exposure to Biological or Chemical Agents)
ValueTypeMaterialStoddart solvent (8052-41-3)
TWA 525 mg/m3
Canada. Quebec OELS. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)ValueTypeMaterial
Stoddart solvent (8052-41-3)
TWA 100 ppm
525 mg/m3Mexico. Occupational Exposure Limit Values
ValueTypeMaterialStoddart solvent (8052-41-3)
TWA 100 ppm
STEL 1050 mg/m3200 ppm
TWA 523 mg/m3Engineering controls Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk of
inhalation of vapors.Personal protective equipment
Eye / face protection Use approved safety goggles or face shield.Skin protection Wear appropriate chemical resistant clothing to prevent any possibility of skin contact.Respiratory protection In case of inadequate ventilation, use respiratory protection.General hygieneconsiderations
Always observe good personal hygiene measures, such as washing after handling the materialand before eating, drinking, and/or smoking. Routinely wash work clothing and protectiveequipment to remove contaminants.
9. Physical & Chemical PropertiesAppearance Clear liquid.
Color Clear, colorless.
Odor Mild. Petroleum.
Odor threshold Not available.
Physical state Liquid.
Form Liquid.
pH Not applicable.
Melting point -72.4 °F (-58 °C)
Freezing point Not available.
Boiling point 316.4 - 383 °F (158 - 195 °C)
Flash point 109.4 °F (43 °C) Closed Cup
Evaporation rate 0.1 (Butyl acetate = 1)
Flammability limits in air, upper,% by volume
13.3 %
Flammability limits in air, lower,% by volume
1 %
Vapor pressure 0.04 kPa
Vapor density 5
Specific gravity 0.79 (15.5°C)
CPH MSDS NA
3 / 6SOLVENT904346 Version #: 01 Revision date: 09-16-2011 Print date: 09-19-201107-12-201207-12-2012
Solubility (water) Not available.
Partition coefficient(n-octanol/water)
Not available.
Auto-ignition temperature 444.2 °F (229 °C)
Decomposition temperature Not available.
VOC 100 %
10. Chemical Stability & Reactivity InformationChemical stability Material is stable under normal conditions.Conditions to avoid Heat, sparks, flames. Contact with incompatible materials.Incompatible materials Strong oxidizing agents.Hazardous decompositionproducts
No hazardous decomposition products are known.
Possibility of hazardousreactions
Will not occur.
11. Toxicological InformationAcute effects Harmful if swallowed - may enter lungs if swallowed or vomited. Prolonged or repeated contact
may dry skin and cause irritation. Overexposure to mists/vapours of this product may causeheadache, dizziness, nausea, and respiratory tract irritation.
Sensitization None known.Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of CarcinogenicityStoddart solvent (CAS 8052-41-3) 3 Not classifiable as to carcinogenicity to humans.
12. Ecological InformationEcotoxicity Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Persistence anddegradability
No data available.
Bioaccumulation /Accumulation
No data available.
Partition coefficient(n-octanol/water)
Not available.
Mobility in environmentalmedia
No data available.
13. Disposal ConsiderationsWaste codes D001: Waste Flammable material with a flash point <140 °FDisposal instructions Must be incinerated in a suitable incineration plant holding a permit delivered by the competent
authorities. Do not allow this material to drain into sewers/water supplies. Do not contaminateponds, waterways or ditches with chemical or used container. When this product as supplied is tobe discarded as waste, it may meet the definition of a RCRA waste under 40 CFR 261.
Waste from residues / unusedproducts
Dispose of waste and residues in accordance with local authority requirements.
Contaminated packaging Since emptied containers retain product residue, follow label warnings even after container isemptied.
14. Transport InformationProduct Specific Note: This product meets the limited quantities exception as follows:
IMDG: Limited quantities up to 5 liters.Otherwise, the above descriptions apply.
DOTBasic shipping requirements:
UN1268UN numberPetroleum distillates, n.o.s. or Petroleum products, n.o.s. (Solvant Stoddard)Proper shipping name3Hazard classIIIPacking group
CPH MSDS NA
4 / 6SOLVENT904346 Version #: 01 Revision date: 09-16-2011 Print date: 09-19-201107-12-2012 07-12-2012
3Labels requiredAdditional information:
144, B1, IB3, T4, TP1, TP29Special provisions150Packaging exceptions203Packaging non bulk242Packaging bulk128ERG number
IATABasic shipping requirements:
UN1268UN numberPetroleum distillates, n.o.s. or Petroleum products, n.o.s. (Solvant Stoddard)Proper shipping name3Hazard classIIIPacking group3Labels required
Additional information:150Packaging exceptions203Packaging non bulk242Packaging bulk
IMDGBasic shipping requirements:
1268UN numberPETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. (Solvant Stoddard)Proper shipping name3Hazard classIIIPacking groupF-E, S-EEmS No.
TDGBasic shipping requirements:
Petroleum distillates, n.o.s. or Petroleum products, n.o.s. (Solvant Stoddard)Proper shipping name3Hazard classUN1268UN numberIIIPacking group
Additional information:144, B1, IB3, T4, TP1, TP29Special provisions
Basic shipping requirements:3Labels required
Additional information:150Packaging exceptions203Packaging non bulk242Packaging bulk
15. Regulatory InformationUS federal regulations This product is hazardous according to OSHA 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.TSCA Section 12(b) Export Notification(40 CFR 707, Subpt. D)
Not regulated.CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)
NoneSuperfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - YesDelayed Hazard - NoFire Hazard - YesPressure Hazard - NoReactivity Hazard - No
Section 302 extremelyhazardous substance (40CRF 355, Appendix A)
No
Section 311/312 (40 CFR370)
No
CPH MSDS NA
5 / 6SOLVENT904346 Version #: 01 Revision date: 09-16-2011 Print date: 09-19-201107-12-2012 07-12-2012
Drug EnforcementAdministration (DEA) (21 CFR1308.11-15)
Not controlled
Canadian regulations This product has been classified in accordance with the hazard criteria of the CPR and the MSDScontains all the information required by the CPR.
WHMIS status ControlledWHMIS classification B3 - Flammable/Combustible
D2B - Other Toxic Effects-TOXICWHMIS labeling
Inventory statusCountry(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)YesCanada Domestic Substances List (DSL)NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)NoEurope European List of Notified Chemical Substances (ELINCS)
YesJapan Inventory of Existing and New Chemical Substances (ENCS)YesKorea Existing Chemicals List (ECL)YesNew Zealand New Zealand InventoryYesPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
State regulations This product does not contain a chemical known to the State of California to cause cancer, birthdefects or other reproductive harm.
US - California Hazardous Substances (Director's): Listed substanceStoddart solvent (CAS 8052-41-3) Listed.
US - Massachusetts RTK - Substance: Listed substanceStoddart solvent (CAS 8052-41-3) Listed.
US - New Jersey RTK - Substances: Listed substanceStoddart solvent (CAS 8052-41-3) Listed.
US - Pennsylvania RTK - Hazardous Substances: Listed substanceStoddart solvent (CAS 8052-41-3) Listed.
16. Other InformationHMIS® ratings Health: 2
Flammability: 2Physical hazard: 0
NFPA ratings Health: 1Flammability: 2Instability: 0
Disclaimer The information in the sheet was written based on the best knowledge and experience currentlyavailable.
Issue date 09-16-2011
CPH MSDS NA
6 / 6SOLVENT904346 Version #: 01 Revision date: 09-16-2011 Print date: 09-19-201107-12-2012 07-12-2012
07-12-2012
*Trademarks of Imperial Oil Limited. Imperial Oil, Licensee. Lubricants and Specialties, Marketing Technical Services ™Trademark of Exxon Corporation. Imperial Oil, Licensee. Helplines: 1-800-268-3183
Esso Gear Oil GX Extra is an API GL-6 quality oil specifically designed for severe service with shock loading ♦ Esso Gear Oil GX Extra is a premium
multi-service, extreme pressure, sulphur-phosphorus type gear oil recommended for the high performance requirements of API service classification GL-5 and GL-6.
♦ A synthetic blended product available in 75W-90, and 80W-140 grades
Primary Applications Esso Gear Oil GX Extra is a multi-service, non-corrosive type hypoid gear lubricant recommended for API service GL-5 and the more severe API service GL-6 (now obsolete). GL-6 is defined by the American Petroleum Institute as designating those lubricants suitable for the lubrication of gears, particularly hypoid gears, in passenger cars, trucks and other equipment operating under high speed, severe shock loaded; high speed, low torque; and low speed, high torque conditions. Esso Gear Oil GX Extra is recommended for most manual transmissions, reducers, differentials, and final drives used in passenger cars, trucks, construction and mining equipment, farm tractors and industrial equipment requiring API GL-5 orGL-6 performance levels. Esso Gear Oil GX Extra 75W-90 is suitable as an all-season lubricant for manual transmissions and differentials in most passenger car and light duty vehicles - including Ford high off-set hypoid gears. The exceptions include those differentials which require limited slip performance for which Esso Gear Oil LS 80W-90 is recommended and manual transmissions and transaxles for which specific OEM or API service GL-4 lubricants are specified. Esso Gear Oil GX Extra is recommended for most equipment in severe service, particularly in the differentials and planetary gears in mining and woodland trucks, where maximum protection is required.
ESSO GEAR OIL GX EXTRA
AUTOMOTIVE GEAR OILS
April 2009
ESSO GEAR OIL GX EXTRA
AUTOMOTIVE GEAR OILS
April 2009
*Trademarks of Imperial Oil Limited. Imperial Oil, Licensee. Lubricants and Specialties, Marketing Technical Services ™Trademark of Exxon Corporation. Imperial Oil, Licensee. Helplines: 1-800-268-3183
Esso Gear Oil GX Extra is recommended for Mack GO-F specification. For Mack Trucks specifying GO-H or GO-J oils, use Esso Gear Oil GX 80W-90 or 85W-140. Esso Gear Oil GX Extra is also suitable for worm gear drives and axles. Performance Features Anti-Score Protection Esso Gear Oil GX Extra meets API service level GL-6 score levels. This provides excellent gear tooth wear protection in high off-set hypoid and shock loaded conditions. Multi-Temperature Service Esso Gear Oil GX Extra 80W-140 offers both good low temperature performance and protection at high operating temperatures. For extreme low temperature operating conditions, Esso Gear Oil GX Extra 75W-90 is recommended. This high quality synthetic blend offers improved low temperature flow characteristics without sacrificing performance at high operating temperatures. Under low temperature start-up conditions, the channel point and viscosity are important, since lubricants should flow readily between contacting surfaces. The temperature at which the lubricant reaches a viscosity of 1500 Poise is used to define low temperature properties, and is
based on a series of tests in a specific rear axle design. These tests have shown that pinion bearing failure has occurred at Brookfield viscosity higher than 1500 Poise. Other axle designs may tolerate higher viscosities, and the typical properties of Esso Gear Oil GX Extra should be used only as a guide. Corrosion Protection, Filterability, Foam Protection, Seal Compatibility, Oil Compatibility and Storage Stability properties are similar to those of Esso Gear Oil GX. Precautions Esso Gear Oil GX Extra is manufactured from quality petroleum base stocks, blended with selected additives. As with all petroleum products, good personal hygiene and careful handling should always be practiced. Avoid prolonged contact with the skin, splashing into the eyes, ingestion, or vapour inhalation. Please refer to the Esso Material Safety Data Sheet for further information. Note: This product is NOT controlled under the Canadian WHMIS legislation.
Typical Properties Esso Gear Oil GX Extra 75W-90 80W-140 Density @ 15 °C 903 894 Flash, COC, °C 150 160 Kinematic Viscosity cSt @ 40 °C 93 268 cSt @ 100 °C 15.9 27.4 Viscosity Index 182 134 Brookfield Viscosity, cP @ -40°C 90,000 @ -26°C 130,000 Pour Point, °C -48 -33 Channel Point, °C <-45 <-36 Colour 1.0 1.0 The values shown above are representative of current production. Some are controlled by manufacturing and performance specifications while others are not. All may vary within modest ranges.
SECTION 1 - PRODUCT INFORMATION
Product Identifier: 06-134 Q.D. SHOP PRIMER - RED
Product Use: Protective Coating
Manufacturer's Name: General Paint Corp. Supplier's Name: General Paint Corp.
Street Address: 950 Raymur Ave Street Address: 950 Raymur Ave
City: Vancouver Province: BC City: Vancouver Province: BC
Postal Code: V6A 3L5
Emergency Phone: (604) 253-4022
Postal Code: V6A 3L5
Emergency Phone: (604) 253-4022
SECTION 2 - HAZARDOUS INGREDIENTS
Hazardous Ingredients(Specific)
% CAS Number
LD 50 of Ingredient(Specify
species,route)
LC 50 of Ingredient(Specify
species)
ETHYLBENZENE 0.27 - 0.73 100-41-4 3500 MG/KG(ORAL, RAT)
4000 PPM(VAPOR, RAT)
TOLUENE 12 - 13 108-88-3 2600 MG/KG(ORAL, RAT)
8800 PPM(VAPOR, RAT)
IRON OXIDE FUME 7 1309-37-1 NOT AVAILABLE NOT AVAILABLE
XYLENE (MIXED ISOMERS)
14 - 15 1330-20-7 5400 MG/KG(ORAL, RAT)
6350 PPM(VAPOR, RAT)
LOW FLASH NAPTHA ALIPHATIC
7 - 11 64742-89-8 NOT AVAILABLE NOT AVAILABLE
SECTION 3 - PHYSICAL DATA
Physical State: Liquid
Odour and Appearance: liquid with a solvent smell
Coating VOC(gm/l): 498
Odour Threshold(ppm): Not Available
Specific Gravity: 1.25
Vapor Density(air=1): Not Available
Vapor Pressure(mmHg): Not Available
Evaporation Rate: Not Available
Boiling Point(º C ): Not Available
Freezing Point(º C ): Not Available
pH: Not Applicable
Coefficient of Water/Oil Distribution:
Not Available
SECTION 4 - FIRE AND EXPLOSION DATA
Flammability:Yes If yes, Under which Conditions?Flammable Liquid
Means of Extinction: Alcohol foam, Carbon dioxide, Dry chemical powder, Polymer foam
Flashpoint and Method: 9 °C Closed Cup
Upper Flammable Lt (% by Volume):Not Available
Lower Flammable Lt (% by Volume):Not Available
Autoignition Temperature: Not Available
Explosion Data - Sensitivity to Impact: No
Explosion Data - Sensitivity to Static discharges: No
Hazardous Combustion Pdts:carbon monoxide, carbon dioxide, calcium oxide, aldehydes, magnesium oxide, formaldehyde, nitrogen oxides
SECTION 5 - REACTIVITY DATA
Chemical Stability:Stable If Yes, Under which Conditions?Not Applicable
Incompatibility with other substances:Yes
If yes, which ones? Strong Acids Strong Oxidizing agents
Reactivity, and under what conditions?heat, ignition sources, nitric acid, sulfuric acid, sulfur dichloride, tetranitromethane, dichlorohydrantion, heat, sparks, or other ignition sources, generation of dust
Hazardous Decomposition Products:carbon dioxide
SECTION 6 - TOXICOLOGICAL PROPERTIES
Route of Entry
Skin Contact: Yes Absorption: Yes
Eye Contact: Yes
Inhalation: Yes Ingestion: Yes
Effects to Acute exposure to Product: ETHYLBENZENE has been known to cause HEADACHES, MEMORY LOSS, FATIGUE and DERMATITIS. TOLUENE has been known to cause FATIGE, WEAKNESS, INCOORDINATION, HEADACHE and DIZZINESS. XYLENE (MIXED ISOMERS) has been known to cause CENTRAL NERVOUS SYSTEM DEPPRESSION, HEADACHE, DEPRESSION, DROWSINESS, INCOORDINATION and SKIN AND EYE IRRITATION. LOW FLASH NAPTHA ALIPHATIC has been known to cause NAUSEA, HEADACHE, VOMITING and EUPHORIA.
Effects to Chronic exposure to Product: ETHYLBENZENE has been known to cause CENTRAL NERVOUS SYSTEM DPRESSION. TOLUENE has been known to cause IMPARED MEMORY, IMPARED SPEECH, IMPARED VISION, IMPARED HEARING, DERMATITIS. XYLENE (MIXED ISOMERS) has been known to cause LIVER DAMAGE, KIDNEY DAMAGE, DERMATITIS. LOW FLASH NAPTHA ALIPHATIC has been known to cause DERMATITIS, LIVER DAMAGE, KIDNEY DAMAGE, SNS, CENTRAL NERVOUS SYSTEM DAMAGE.
Exposure Limits (Value,Units,By) ETHYLBENZENE: 100 ppm ACGIH TOLUENE: 150 ppm OSHA IRON OXIDE FUME: 5 mg/m3 ACGIH XYLENE (MIXED ISOMERS): 100 ppm ACGIH LOW FLASH NAPTHA ALIPHATIC: N/A
Irritancy (if yes, explain) ETHYLBENZENE is a skin and eye irritant. (MODERATE SKIN AND EYE IRRITANT) TOLUENE is a skin and eye irritant. (MODERATE SKIN IRRITANT) XYLENE (MIXED ISOMERS) is a skin and eye irritant.
Sensitization (if yes, explain) Carcinogenicity (if yes, explain) ETHYLBENZENE is considered to be a Animal carcinogen. The agent is not likely to cause cancer
in humans except under uncommon or unlikely routes or levels of exposure(A3) by ACGHI. ETHYLBENZENE is possibly carcinogenic to humans(2B) by IARC.
Reproductive Toxicity (if yes, explain) LOW FLASH NAPTHA ALIPHATIC may damage the reproductive system.
Teratogenicity (if yes, explain) TOLUENE may cause birth defects. (REDUCED FETAL WEIGHT AND BEHAVIOURAL EFFECTS) XYLENE (MIXED ISOMERS) may cause birth defects.
Mutagenicity (if yes, explain) Synergistic Products (if yes, explain)
SECTION 7 - PREVENTIVE MEASURES
Personal Protective Equipment
Gloves: Yes
Respirator: Yes
Eye: Yes Footwear: No
Clothing: No
Other: No
If checked, specify type: Gloves: BUTYL RUBBER Respirator: NIOSH APPROVED Eye: SPLASH RESISTANT
Engineering controls (specify such as ventilation, enclosed process): Use mechanical ventilation to reduce exposure.
Leak and Spill Procedure: Wear adequate protective equipment and eliminate all ignition sources. Contain spill with absorbant material and place in a suitable covered and labeled container for disposal.
Waste Disposal: Check with Federal, Provincial and local government regulations and requirements for disposal.
Handling Procedures and Equipment: Use in a well ventilated area. Do not use with incompatible substances.
Storage Requirements: Store in a cool, well ventilated area out of direct sunlight.
Special Shipping Information: TDG Shipping Name: PAINT Classification: 3.2 Packing Group: II Identification Number: UN1263
SECTION 8 - FIRST AID MEASURES
Inhalation: Remove to fresh air. Get medical help if there is any breathing difficulty.
Ingestion: Do not induce vomiting unless directed by a physician. If conscious and alert, give two glasses of water. Seek medical attention immediately.
Skin Contact: Remove Contaminated clothing (including shoes) and wash before reuse. Flush with large amounts of soap and water. If irritation persists, seek medical attention.
Eye Contact: Flush eyes with large amounts of lukewarm water for 20 minutes, while holding eyelids open or until irritation subsides. If irritation persist, get medical attention.
SECTION 9 - PREPARATION INFORMATION
Prepared by: General Paint Technical Dept
Phone: (604) 253-3131
Preparation Date: Feb 27, 2012
SECTION 1 - PRODUCT INFORMATION
Product Identifier: 06-154 ANTI-CORROSIVE PRIMER - RED
Product Use: Protective Coating
Manufacturer's Name: General Paint Corp. Supplier's Name: General Paint Corp.
Street Address: 950 Raymur Ave Street Address: 950 Raymur Ave
City: Vancouver Province: BC City: Vancouver Province: BC
Postal Code: V6A 3L5
Emergency Phone: (604) 253-4022
Postal Code: V6A 3L5
Emergency Phone: (604) 253-4022
SECTION 2 - HAZARDOUS INGREDIENTS
Hazardous Ingredients(Specific)
% CAS Number
LD 50 of Ingredient(Specify
species,route)
LC 50 of Ingredient(Specify
species)
ETHYLBENZENE 1 - 5 100-41-4 3500 MG/KG(ORAL, RAT)
4000 PPM(VAPOR, RAT)
TOLUENE 6 108-88-3 2600 MG/KG(ORAL, RAT)
8800 PPM(VAPOR, RAT)
IRON OXIDE FUME 7 1309-37-1 NOT AVAILABLE NOT AVAILABLE
XYLENE (MIXED ISOMERS)
18 - 21 1330-20-7 5400 MG/KG(ORAL, RAT)
6350 PPM(VAPOR, RAT)
LOW FLASH NAPTHA ALIPHATIC
2.22 - 3.7 64742-89-8 NOT AVAILABLE NOT AVAILABLE
NAPHTHA, VM & P 3.16 - 3.49 8032-32-4 NOT AVAILABLE 3400 PPM(VAPOR, RAT)
N-DIBUTYL PHTHALATE 1.17 84-74-2 8000 MG/KG(ORAL, RAT)
25 PPM(VAPOR, MOUSE)
SECTION 3 - PHYSICAL DATA
Physical State: Liquid
Odour and Appearance: liquid with a solvent smell
Coating VOC(gm/l): 476
Odour Threshold(ppm): Not Available
Specific Gravity: 1.33
Vapor Density(air=1): Not Available
Vapor Pressure(mmHg): Not Available
Evaporation Rate: Not Available
Boiling Point(º C ): Not Available
Freezing Point(º C ): Not Available
pH: Not Applicable
Coefficient of Water/Oil Distribution:
Not Available
SECTION 4 - FIRE AND EXPLOSION DATA
Flammability:Yes If yes, Under which Conditions?Flammable Liquid
Means of Extinction: Alcohol foam, Carbon dioxide, Dry chemical powder, Polymer foam
Flashpoint and Method: 23 °C Closed Cup
Upper Flammable Lt (% by Volume):Not Available
Lower Flammable Lt (% by Volume):Not Available
Autoignition Temperature: Not Available
Explosion Data - Sensitivity to Impact: No
Explosion Data - Sensitivity to Static discharges: No
Hazardous Combustion Pdts:carbon monoxide, carbon dioxide, calcium oxide, aldehydes, magnesium oxide, formaldehyde, phthalic anhydride, nitrogen oxides
SECTION 5 - REACTIVITY DATA
Chemical Stability:Stable If Yes, Under which Conditions?Not Applicable
Incompatibility with other substances:Yes
If yes, which ones? Strong Acids Strong Oxidizing agents Strong Bases
Reactivity, and under what conditions?heat, ignition sources, nitric acid, sulfuric acid, sulfur dichloride, tetranitromethane, dichlorohydrantion, heat, sparks, or other ignition sources, generation of dust, igniton sources
Hazardous Decomposition Products:carbon dioxide
SECTION 6 - TOXICOLOGICAL PROPERTIES
Route of Entry
Skin Contact: Yes Absorption: Yes
Eye Contact: Yes
Inhalation: Yes Ingestion: Yes
Effects to Acute exposure to Product:ETHYLBENZENE has been known to cause HEADACHES, MEMORY LOSS, FATIGUE and DERMATITIS. TOLUENE has been known to cause FATIGE, WEAKNESS, INCOORDINATION, HEADACHE and DIZZINESS. XYLENE (MIXED ISOMERS) has been known to cause CENTRAL NERVOUS SYSTEM DEPPRESSION, HEADACHE, DEPRESSION, DROWSINESS, INCOORDINATION and SKIN AND EYE IRRITATION. LOW FLASH NAPTHA ALIPHATIC has been known to cause NAUSEA, HEADACHE, VOMITING and EUPHORIA. N-DIBUTYL PHTHALATE has been known to cause EYE IRRITATION, STOMACH IRRITATION and UPPER RESPITORY TRACT IRRITATION.
Effects to Chronic exposure to Product:ETHYLBENZENE has been known to cause CENTRAL NERVOUS SYSTEM DEPRESSION. TOLUENE has been known to cause IMPARED MEMORY, IMPARED SPEECH, IMPARED VISION, IMPARED HEARING, DERMATITIS. XYLENE (MIXED ISOMERS) has been known to cause LIVER DAMAGE, KIDNEY DAMAGE, DERMATITIS. LOW FLASH NAPTHA ALIPHATIC has been known to cause DERMATITIS, LIVER DAMAGE, KIDNEY DAMAGE, SNS, CENTRAL NERVOUS SYSTEM DAMAGE. NAPHTHA, VM & P has been known to cause DERMATITIS.
Exposure Limits (Value,Units,By) ETHYLBENZENE: 100 ppm ACGIH TOLUENE: 150 ppm OSHA IRON OXIDE FUME: 5 mg/m3 ACGIH XYLENE (MIXED ISOMERS): 100 ppm ACGIH LOW FLASH NAPTHA ALIPHATIC: N/A NAPHTHA, VM & P: 300 ppm ACGIH N-DIBUTYL PHTHALATE: 5 mg/m3 ACGIH
Irritancy (if yes, explain)ETHYLBENZENE is a skin and eye irritant. (MODERATE SKIN AND EYE IRRITANT) TOLUENE is a skin and eye irritant. (MODERATE SKIN IRRITANT) XYLENE (MIXED ISOMERS) is a skin and eye irritant. NAPHTHA, VM & P is a skin and eye irritant.
Sensitization (if yes, explain) Carcinogenicity (if yes, explain) ETHYLBENZENE is considered to be a Animal carcinogen. The agent is not likely to cause cancer in humans except under uncommon or unlikely routes or levels of exposure(A3) by ACGHI. ETHYLBENZENE is possibly carcinogenic to humans(2B) by IARC. NAPHTHA, VM & P is considered to be a Animal carcinogen. The agent is not likely to cause cancer in humans except under uncommon or unlikely routes or levels of exposure(A3) by ACGHI.
Reproductive Toxicity (if yes, explain) LOW FLASH NAPTHA ALIPHATIC may damage the reproductive system. N-DIBUTYL PHTHALATE may damage the reproductive system.
Teratogenicity (if yes, explain) TOLUENE may cause birth defects. (REDUCED FETAL WEIGHT AND BEHAVIOURAL EFFECTS) XYLENE (MIXED ISOMERS) may cause birth defects. N-DIBUTYL PHTHALATE may cause birth defects.
Mutagenicity (if yes, explain) Synergistic Products (if yes, explain)
SECTION 7 - PREVENTIVE MEASURES
Personal Protective Equipment
Gloves: Yes
Respirator: Yes
Eye: Yes Footwear: No
Clothing: No
Other: No
If checked, specify type: Gloves: BUTYL RUBBER Respirator: NIOSH APPROVED Eye: SPLASH RESISTANT
Engineering controls (specify such as ventilation, enclosed process): Use mechanical ventilation to reduce exposure.
Leak and Spill Procedure: Wear adequate protective equipment and eliminate all ignition sources. Contain spill with absorbant material and place in a suitable covered and labeled container for disposal.
Waste Disposal: Check with Federal, Provincial and local government regulations and requirements for disposal.
Handling Procedures and Equipment: Use in a well ventilated area. Do not use with incompatible substances.
Storage Requirements: Store in a cool, well ventilated area out of direct sunlight.
Special Shipping Information: TDG Shipping Name: PAINT Classification: 3.2 Packing Group: II Identification Number: UN1263
SECTION 8 - FIRST AID MEASURES
Inhalation: Remove to fresh air. Get medical help if there is any breathing difficulty.
Ingestion: Do not induce vomiting unless directed by a physician. If conscious and alert, give two glasses of water. Seek medical attention immediately.
Skin Contact: Remove Contaminated clothing (including shoes) and wash before reuse. Flush with large amounts of soap and water. If irritation persists, seek medical attention.
Eye Contact: Flush eyes with large amounts of lukewarm water for 20 minutes, while holding eyelids open or until irritation subsides. If irritation persist, get medical attention.
SECTION 9 - PREPARATION INFORMATION
Prepared by: General Paint Technical Dept
Phone: (604) 253-3131
Preparation Date: Feb 27, 2012
MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT INFORMATION
Product Identifier:10-010 LOW ODOR ALKYD INT GLO
Product Use: Protective Coating
Manufacturer's Name: General Paint Corp. Supplier's Name: General Paint Corp.
Street Address: 950 Raymur Ave Street Address: 950 Raymur Ave
City: Vancouver Province: BC City: Vancouver Province: BC
Postal Code:V6A 3L5
Emergency Phone:(604) 253-4022
Postal Code:V6A 3L5
EmergencyPhone:(604) 253-4022
SECTION 2 - HAZARDOUS INGREDIENTS
HazardousIngredients(Specific)
% CASNumber
LD 50 ofIngredient(Specify
species,route)
LC 50 ofIngredient(Specify
species)
TITANIUM DIOXIDE 19 - 23 13463-67-7 NOT AVAILABLE NOT AVAILABLE
HEAVY NAPTHA(HYDROTREATED)
13 64742-48-9 NOT AVAILABLE NOT AVAILABLE
MINERAL SPIRITS 24 - 25 8052-41-3 5000 MG/KG(ORAL,RAT)
5500 PPM(VAPOR,RAT)
SECTION 3 - PHYSICAL DATA
PhysicalState:Liquid
Odour andAppearance:liquid with a solventsmell
Coating VOC(gm/l):417
OdourThreshold(ppm):Not Available
SpecificGravity:1.1
VaporDensity(air=1):Not Available
VaporPressure(mmHg):Not Available
Evaporation Rate:Not Available
Boiling Point(C ):Not Available
Freezing Point( C ):Not Available
pH:Not Applicable
Coefficient ofWater/OilDistribution:
Not Available
SECTION 4 - FIRE AND EXPLOSION DATA
Flammability:YesIf yes, Under which Conditions?Flammable Liquid
Means of Extinction: Alcohol foam, Carbon dioxide, Dry chemical powder, Polymer foam
Flashpoint and Method:45 C Closed Cup
Upper Flammable Lt (%by Volume):Not Available
Lower Flammable Lt (%by Volume):Not Available
Autoignition Temperature:Not Available
Explosion Data -Sensitivity to Impact: No
Explosion Data -Sensitivity to Staticdischarges: No
Hazardous Combustion Pdts:carbon monoxide, carbon dioxide, aldehydes, nitrogen oxides, sulfuroxides
SECTION 5 - REACTIVITY DATA
Chemical Stability:Stable If Yes, Under which Conditions?Not Applicable
Incompatibility with othersubstances:Yes
If yes, which ones?Strong AcidsStrong Oxidizing agents
Reactivity, and under what conditions?heat, ignition sources, generation of dust, flame,sparks, other ignition sources, nitric acid, dichlorohydrantion, heat, sparks, or other ignition sources
Hazardous Decomposition Products:
SECTION 6 - TOXICOLOGICAL PROPERTIES
Route ofEntry
Skin Contact:Yes
Absorption:Yes
Eye Contact:Yes
Inhalation:Yes
Ingestion:Yes
Effects to Acute exposure to Product:HEAVY NAPTHA (HYDROTREATED) has been known to cause HEADACHE, DIZZINESS andOTHER CENTRAL NERVOUS SYSTEM EFFECTS. MINERAL SPIRITS has been known to causeEYE IRRITANT, NOSE IRRITANT, THROAT IRRITANT, DIZZINESS and DERMATITIS.
Effects to Chronic exposure to Product:MINERAL SPIRITS has been known to cause NARCOSIS, CENTRAL NERVOUS SYSTEMDEPRESSION.
Exposure Limits (Value,Units,By)TITANIUM DIOXIDE: 10 mg/m3 ACGIH
HEAVY NAPTHA (HYDROTREATED): 1200 mg/m3 Manufacturer (ESSO)MINERAL SPIRITS: 100 PPM ACGIH
Irritancy (if yes, explain)MINERAL SPIRITS is a skin and eye irritant. (MILD)
Sensitization (if yes, explain) Carcinogenicity (if yes, explain)TITANIUM DIOXIDE is possibly carcinogenic tohumans(2B) by IARC.
Reproductive Toxicity (if yes, explain) Teratogenicity (if yes, explain)
Mutagenicity (if yes, explain) Synergistic Products (if yes, explain)
SECTION 7 - PREVENTIVE MEASURES
PersonalProtectiveEquipment
Gloves:Yes
Respirator:Yes
Eye: Yes Footwear:No
Clothing:No
Other: No
If checked, specify type:Respirator: NIOSH APPROVED Gloves: BUTYL RUBBER Eye: SPLASH RESISTANT
Engineering controls (specify such as ventilation, enclosed process):Use mechanical ventilation to reduce exposure.
Leak and Spill Procedure:Wear adequate protective equipment and eliminate all ignition sources. Contain spill withabsorbant material and place in a suitable covered and labeled container for disposal.
Waste Disposal:Check with Federal, Provincial and local government regulations and requirements fordisposal.
Handling Procedures and Equipment:Use in a well ventilated area. Do not use with incompatible substances.
Storage Requirements:Store in a cool, well ventilated area out of direct sunlight.
Special Shipping Information:TDG Shipping Name: PAINT Classification: 3.3 Packing Group: III Identification Number:UN1263
SECTION 8 - FIRST AID MEASURES
Inhalation: Remove to fresh air. Get medical help if there is any breathing difficulty.
Ingestion: Do not induce vomiting unless directed by a physician. If conscious and alert,give two glasses of water. Seek medical attention immediately.
Skin Contact: Remove Contaminated clothing (including shoes) and wash before reuse.Flush with large amounts of soap and water. If irritation persists, seek medical attention.
Eye Contact: Flush eyes with large amounts of lukewarm water for 20 minutes, whileholding eyelids open or until irritation subsides. If irritation persist, get medical attention.
SECTION 9 - PREPARATION INFORMATION
Prepared by:General Paint Technical Dept
Phone:(604) 253-3131
Preparation Date:Jun 17, 2010
MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT INFORMATION
Product Identifier:10-122 CO-OP RUST - GLOSS WHI
Product Use: Protective Coating
Manufacturer's Name: General Paint Corp. Supplier's Name: General Paint Corp.
Street Address: 950 Raymur Ave Street Address: 950 Raymur Ave
City: Vancouver Province: BC City: Vancouver Province: BC
Postal Code:V6A 3L5
Emergency Phone:(604) 253-4022
Postal Code:V6A 3L5
EmergencyPhone:(604) 253-4022
SECTION 2 - HAZARDOUS INGREDIENTS
HazardousIngredients(Specific)
% CASNumber
LD 50 ofIngredient(Specify
species,route)
LC 50 ofIngredient(Specify
species)
ETHYLBENZENE 0.11 -0.22
100-41-4 3500 MG/KG(ORAL,RAT)
4000 PPM(VAPOR,RAT)
XYLENE (MIXEDISOMERS)
0.55 -1.1
1330-20-7 5400 MG/KG(ORAL,RAT)
6350 PPM(VAPOR,RAT)
TITANIUM DIOXIDE 19 - 24 13463-67-7 NOT AVAILABLE NOT AVAILABLE
MINERAL SPIRITS 17 64742-88-7 5000 MG/KG(ORAL,RAT)
5500 PPM(VAPOR,RAT)
MINERAL SPIRITS 23 - 24 8052-41-3 5000 MG/KG(ORAL,RAT)
5500 PPM(VAPOR,RAT)
SECTION 3 - PHYSICAL DATA
Physical Odour and Coating VOC(gm/l): Odour
State:Liquid
Appearance:liquid with a solventsmell
440 Threshold(ppm):Not Available
SpecificGravity:1.12
VaporDensity(air=1):Not Available
VaporPressure(mmHg):Not Available
Evaporation Rate:Not Available
Boiling Point(C ):Not Available
Freezing Point( C ):Not Available
pH:Not Applicable
Coefficient ofWater/OilDistribution:
Not Available
SECTION 4 - FIRE AND EXPLOSION DATA
Flammability:YesIf yes, Under which Conditions?Flammable Liquid
Means of Extinction: Alcohol foam, Carbon dioxide, Dry chemical powder, Polymer foam
Flashpoint and Method:45 C Closed Cup
Upper Flammable Lt (%by Volume):Not Available
Lower Flammable Lt (%by Volume):Not Available
Autoignition Temperature:Not Available
Explosion Data -Sensitivity to Impact: No
Explosion Data -Sensitivity to Staticdischarges: No
Hazardous Combustion Pdts:carbon monoxide, carbon dioxide, aldehydes, nitrogen oxides, sulfuroxides
SECTION 5 - REACTIVITY DATA
Chemical Stability:Stable If Yes, Under which Conditions?Not Applicable
Incompatibility with othersubstances:Yes
If yes, which ones?Strong AcidsStrong Oxidizing agentsStrong Bases
Reactivity, and under what conditions?heat, ignition sources, potassium t-butoxide, nitric acid,sulfuric acid, sulfur dichloride, tetranitromethane, generation of dust, dichlorohydrantion, heat, sparks,or other ignition sources
Hazardous Decomposition Products:
SECTION 6 - TOXICOLOGICAL PROPERTIES
Route ofEntry
Skin Contact:Yes
Absorption:Yes
Eye Contact:Yes
Inhalation:Yes
Ingestion:Yes
Effects to Acute exposure to Product:ETHYLBENZENE has been known to cause HEADACHES, MEMORY LOSS, FATIGUE and
DERMATITIS. XYLENE (MIXED ISOMERS) has been known to cause CENTRAL NERVOUSSYSTEM DEPPRESSION, HEADACHE, DEPRESSION, DROWSINESS, INCOORDINATION andSKIN AND EYE IRRITATION. MINERAL SPIRITS has been known to cause CONJUNCTIVITIS,CORNEAL DAMAGE, NAUSEA, VOMITING, DIARRHEA, HEADACHE and DIZZINESS. MINERALSPIRITS has been known to cause EYE IRRITANT, NOSE IRRITANT, THROAT IRRITANT,DIZZINESS and DERMATITIS.
Effects to Chronic exposure to Product:ETHYLBENZENE has been known to cause CENTRAL NERVOUS SYSTEM DPRESSION. XYLENE(MIXED ISOMERS) has been known to cause LIVER DAMAGE, KIDNEY DAMAGE, DERMATITIS.MINERAL SPIRITS has been known to cause DERMATITIS. MINERAL SPIRITS has been knownto cause NARCOSIS, CENTRAL NERVOUS SYSTEM DEPRESSION.
Exposure Limits (Value,Units,By)ETHYLBENZENE: 100 ppm ACGIHXYLENE (MIXED ISOMERS): 100 ppm ACGIHTITANIUM DIOXIDE: 10 mg/m3 ACGIHMINERAL SPIRITS: 100 mg/m3 ACGIHMINERAL SPIRITS: 100 PPM ACGIH
Irritancy (if yes, explain)ETHYLBENZENE is a skin and eye irritant. (MODERATE SKIN AND EYE IRRITANT) XYLENE(MIXED ISOMERS) is a skin and eye irritant. MINERAL SPIRITS is a skin and eye irritant.(MILD)
Sensitization (if yes, explain) Carcinogenicity (if yes, explain)ETHYLBENZENE is considered to be a Animalcarcinogen. The agent is not likely to causecancer in humans except under uncommon orunlikely routes or levels of exposure(A3) byACGHI. ETHYLBENZENE is possiblycarcinogenic to humans(2B) by IARC.TITANIUM DIOXIDE is possibly carcinogenic tohumans(2B) by IARC.
Reproductive Toxicity (if yes, explain) Teratogenicity (if yes, explain)XYLENE (MIXED ISOMERS) may cause birthdefects.
Mutagenicity (if yes, explain) Synergistic Products (if yes, explain)
SECTION 7 - PREVENTIVE MEASURES
PersonalProtectiveEquipment
Gloves:Yes
Respirator:Yes
Eye: Yes Footwear:No
Clothing:No
Other: No
If checked, specify type:Gloves: BUTYL RUBBER Respirator: NIOSH APPROVED Eye: SPLASH RESISTANT
Engineering controls (specify such as ventilation, enclosed process):Use mechanical ventilation to reduce exposure.
Leak and Spill Procedure:Wear adequate protective equipment and eliminate all ignition sources. Contain spill withabsorbant material and place in a suitable covered and labeled container for disposal.
Waste Disposal:Check with Federal, Provincial and local government regulations and requirements fordisposal.
Handling Procedures and Equipment:Use in a well ventilated area. Do not use with incompatible substances.
Storage Requirements:Store in a cool, well ventilated area out of direct sunlight.
Special Shipping Information:TDG Shipping Name: PAINT Classification: 3.3 Packing Group: III Identification Number:UN1263
SECTION 8 - FIRST AID MEASURES
Inhalation: Remove to fresh air. Get medical help if there is any breathing difficulty.
Ingestion: Do not induce vomiting unless directed by a physician. If conscious and alert,give two glasses of water. Seek medical attention immediately.
Skin Contact: Remove Contaminated clothing (including shoes) and wash before reuse.Flush with large amounts of soap and water. If irritation persists, seek medical attention.
Eye Contact: Flush eyes with large amounts of lukewarm water for 20 minutes, whileholding eyelids open or until irritation subsides. If irritation persist, get medical attention.
SECTION 9 - PREPARATION INFORMATION
Prepared by:General Paint Technical Dept
Phone:(604) 253-3131
Preparation Date:Jun 17, 2010
SECTION 1 - PRODUCT INFORMATION
Product Identifier: 10-134 MARINE RUST MID BLUE
Product Use: Protective Coating
Manufacturer's Name: General Paint Corp. Supplier's Name: General Paint Corp.
Street Address: 950 Raymur Ave Street Address: 950 Raymur Ave
City: Vancouver Province: BC City: Vancouver Province: BC
Postal Code: V6A 3L5
Emergency Phone: (604) 253-4022
Postal Code: V6A 3L5
Emergency Phone: (604) 253-4022
SECTION 2 - HAZARDOUS INGREDIENTS
Hazardous Ingredients(Specific) % CAS Number LD 50 of Ingredient(Specify
species,route)
LC 50 of Ingredient(Specify species)
ETHYLBENZENE 0.18 - 0.33 100-41-4 3500 MG/KG(ORAL, RAT) 4000 PPM(VAPOR, RAT)
XYLENE (MIXED ISOMERS) 0.5 - 1.5 1330-20-7 5400 MG/KG(ORAL, RAT) 6350 PPM(VAPOR, RAT)
TITANIUM DIOXIDE 2.79 - 3.49 13463-67-7 NOT AVAILABLE NOT AVAILABLE
MINERAL SPIRITS 18 - 19 64742-88-7 5000 MG/KG(ORAL, RAT) 5500 PPM(VAPOR, RAT)
MINERAL SPIRITS 29 - 31 8052-41-3 5000 MG/KG(ORAL, RAT) 5500 PPM(VAPOR, RAT)
SECTION 3 - PHYSICAL DATA
Physical State: Liquid
Odour and Appearance: liquid with a solvent smell
Coating VOC(gm/l): 454
Odour Threshold(ppm): Not Available
Specific Gravity: 0.95
Vapor Density(air=1): Not Available
Vapor Pressure(mmHg): Not Available
Evaporation Rate: Not Available
Boiling Point(º C ): Not Available
Freezing Point(º C ): Not Available
pH: Not Applicable
Coefficient of Water/Oil Distribution:
Not Available
SECTION 4 - FIRE AND EXPLOSION DATA
Flammability:Yes If yes, Under which Conditions?Flammable Liquid
Means of Extinction: Alcohol foam, Carbon dioxide, Dry chemical powder, Polymer foam
Flashpoint and Method: 43 °C Closed Cup
Upper Flammable Lt (% by Volume):Not Available
Lower Flammable Lt (% by Volume):Not Available
Autoignition Temperature: Not Available
Explosion Data - Sensitivity to Impact: No Explosion Data - Sensitivity to Static discharges: No
Hazardous Combustion Pdts:carbon monoxide, carbon dioxide, aldehydes, nitrogen oxides, sulfur oxides, isobutylene
SECTION 5 - REACTIVITY DATA
Chemical Stability:Stable If Yes, Under which Conditions?Not Applicable
Incompatibility with other substances:Yes If yes, which ones? Strong Acids Strong Oxidizing agents Strong Bases
Reactivity, and under what conditions?heat, ignition sources, potassium t-butoxide, nitric acid, sulfuric acid, sulfur dichloride, tetranitromethane, generation of dust, dichlorohydrantion, heat, sparks, or other ignition sources, heat (temperatures above 194°c)
Hazardous Decomposition Products:
SECTION 6 - TOXICOLOGICAL PROPERTIES
Route of Entry Skin Contact: Yes Absorption: Yes Eye Contact: Yes Inhalation: Yes Ingestion: Yes
Effects to Acute exposure to Product: ETHYLBENZENE has been known to cause HEADACHES, MEMORY LOSS, FATIGUE and DERMATITIS. XYLENE (MIXED ISOMERS) has been known to cause CENTRAL NERVOUS SYSTEM DEPPRESSION, HEADACHE, DEPRESSION, DROWSINESS, INCOORDINATION and SKIN AND EYE IRRITATION. MINERAL SPIRITS has been known to cause CONJUNCTIVITIS, CORNEAL DAMAGE, NAUSEA, VOMITING, DIARRHEA, HEADACHE and DIZZINESS. MINERAL SPIRITS has been known to cause EYE IRRITANT, NOSE IRRITANT, THROAT IRRITANT, DIZZINESS and DERMATITIS.
Effects to Chronic exposure to Product: ETHYLBENZENE has been known to cause CENTRAL NERVOUS SYSTEM DPRESSION. XYLENE (MIXED ISOMERS) has been known to cause LIVER DAMAGE, KIDNEY DAMAGE, DERMATITIS. MINERAL SPIRITS has been known to cause DERMATITIS. MINERAL SPIRITS has been known to cause NARCOSIS, CENTRAL NERVOUS SYSTEM DEPRESSION.
Exposure Limits (Value,Units,By) ETHYLBENZENE: 100 ppm ACGIH XYLENE (MIXED ISOMERS): 100 ppm ACGIH TITANIUM DIOXIDE: 10 mg/m3 ACGIH MINERAL SPIRITS: 100 mg/m3 ACGIH MINERAL SPIRITS: 100 PPM ACGIH
Irritancy (if yes, explain) ETHYLBENZENE is a skin and eye irritant. (MODERATE SKIN AND EYE IRRITANT) XYLENE (MIXED ISOMERS) is a skin and eye irritant. MINERAL SPIRITS is a skin and eye irritant. (MILD)
Sensitization (if yes, explain) Carcinogenicity (if yes, explain) ETHYLBENZENE is considered to be a Animal carcinogen. The agent is not likely to cause cancer in humans except under uncommon or unlikely routes or levels of exposure(A3) by ACGHI. ETHYLBENZENE is possibly carcinogenic to humans(2B) by IARC. TITANIUM DIOXIDE is possibly carcinogenic to humans(2B) by IARC.
Reproductive Toxicity (if yes, explain) Teratogenicity (if yes, explain) XYLENE (MIXED ISOMERS) may cause birth defects.
Mutagenicity (if yes, explain) Synergistic Products (if yes, explain)
SECTION 7 - PREVENTIVE MEASURES
Personal Protective Equipment
Gloves: Yes Respirator: Yes Eye: Yes Footwear: No Clothing: No Other: No
If checked, specify type: Gloves: BUTYL RUBBER Respirator: NIOSH APPROVED Eye: SPLASH RESISTANT
Engineering controls (specify such as ventilation, enclosed process): Use mechanical ventilation to reduce exposure.
Leak and Spill Procedure: Wear adequate protective equipment and eliminate all ignition sources. Contain spill with absorbant material and place in a suitable covered and labeled container for disposal.
Waste Disposal: Check with Federal, Provincial and local government regulations and requirements for disposal.
Handling Procedures and Equipment: Use in a well ventilated area. Do not use with incompatible substances.
Storage Requirements: Store in a cool, well ventilated area out of direct sunlight.
Special Shipping Information: TDG Shipping Name: PAINT Classification: 3.3 Packing Group: III Identification Number: UN1263
SECTION 8 - FIRST AID MEASURES
Inhalation: Remove to fresh air. Get medical help if there is any breathing difficulty.
Ingestion: Do not induce vomiting unless directed by a physician. If conscious and alert, give two glasses of water. Seek medical attention immediately.
Skin Contact: Remove Contaminated clothing (including shoes) and wash before reuse. Flush with large amounts of soap and water. If irritation persists, seek medical attention.
Eye Contact: Flush eyes with large amounts of lukewarm water for 20 minutes, while holding eyelids open or until irritation subsides. If irritation persist, get medical attention.
SECTION 9 - PREPARATION INFORMATION
Prepared by: General Paint Technical Dept
Phone: (604) 253-3131
Preparation Date: Oct 06, 2010
MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT INFORMATION
Product Identifier:11-890 LOW SHEEN NON-SLIP EN.-Q.D.GREY
Product Use: Protective Coating
Manufacturer's Name: General Paint Corp. Supplier's Name: General Paint Corp.
Street Address: 950 Raymur Ave Street Address: 950 Raymur Ave
City: Vancouver Province: BC City: Vancouver Province: BC
Postal Code:V6A 3L5
Emergency Phone:(604) 253-4022
Postal Code:V6A 3L5
EmergencyPhone:(604) 253-4022
SECTION 2 - HAZARDOUS INGREDIENTS
HazardousIngredients(Specific)
% CASNumber
LD 50 ofIngredient(Specify
species,route)
LC 50 ofIngredient(Specify
species)
ETHYLBENZENE 2.11 -2.81
100-41-4 3500 MG/KG(ORAL,RAT)
4000 PPM(VAPOR,RAT)
TOLUENE 8 108-88-3 2600 MG/KG(ORAL,RAT)
8800 PPM(VAPOR,RAT)
XYLENE (MIXEDISOMERS)
8 1330-20-7 5400 MG/KG(ORAL,RAT)
6350 PPM(VAPOR,RAT)
TITANIUM DIOXIDE 2.92 -3.64
13463-67-7 NOT AVAILABLE NOT AVAILABLE
LOW FLASH NAPTHAALIPHATIC
2.28 -3.09
64742-89-8 NOT AVAILABLE NOT AVAILABLE
SECTION 3 - PHYSICAL DATA
PhysicalState:Liquid
Odour andAppearance:liquid with a solventsmell
Coating VOC(gm/l):375
OdourThreshold(ppm):Not Available
SpecificGravity:1.36
VaporDensity(air=1):Not Available
VaporPressure(mmHg):Not Available
Evaporation Rate:Not Available
Boiling Point(C ):Not Available
Freezing Point( C ):Not Available
pH:Not Applicable
Coefficient ofWater/OilDistribution:
Not Available
SECTION 4 - FIRE AND EXPLOSION DATA
Flammability:YesIf yes, Under which Conditions?Flammable Liquid
Means of Extinction: Alcohol foam, Carbon dioxide, Dry chemical powder, Polymer foam
Flashpoint and Method:40 C Closed Cup
Upper Flammable Lt (%by Volume):Not Available
Lower Flammable Lt (%by Volume):Not Available
Autoignition Temperature:Not Available
Explosion Data -Sensitivity to Impact: No
Explosion Data -Sensitivity to Staticdischarges: No
Hazardous Combustion Pdts:carbon monoxide, carbon dioxide, aldehydes, nitrogen oxides, sulfuroxides
SECTION 5 - REACTIVITY DATA
Chemical Stability:Stable If Yes, Under which Conditions?Not Applicable
Incompatibility with othersubstances:Yes
If yes, which ones?Strong AcidsStrong Oxidizing agentsStrong Bases
Reactivity, and under what conditions?heat, ignition sources, nitric acid, sulfuric acid, sulfurdichloride, tetranitromethane, generation of dust, dichlorohydrantion, heat, sparks, or other ignitionsources
Hazardous Decomposition Products:
SECTION 6 - TOXICOLOGICAL PROPERTIES
Route ofEntry
Skin Contact:Yes
Absorption:Yes
Eye Contact:Yes
Inhalation:Yes
Ingestion:Yes
Effects to Acute exposure to Product:ETHYLBENZENE has been known to cause HEADACHES, MEMORY LOSS, FATIGUE andDERMATITIS. TOLUENE has been known to cause FATIGE, WEAKNESS, INCOORDINATION,HEADACHE and DIZZINESS. XYLENE (MIXED ISOMERS) has been known to cause CENTRALNERVOUS SYSTEM DEPPRESSION, HEADACHE, DEPRESSION, DROWSINESS,INCOORDINATION and SKIN AND EYE IRRITATION. LOW FLASH NAPTHA ALIPHATIC has beenknown to cause NAUSEA, HEADACHE, VOMITING and EUPHORIA.
Effects to Chronic exposure to Product:ETHYLBENZENE has been known to cause CENTRAL NERVOUS SYSTEM DPRESSION.TOLUENE has been known to cause IMPARED MEMORY, IMPARED SPEECH, IMPARED VISION,IMPARED HEARING, DERMATITIS. XYLENE (MIXED ISOMERS) has been known to causeLIVER DAMAGE, KIDNEY DAMAGE, DERMATITIS. LOW FLASH NAPTHA ALIPHATIC has beenknown to cause DERMATITIS, LIVER DAMAGE, KIDNEY DAMAGE, SNS, CENTRAL NERVOUSSYSTEM DAMAGE.
Exposure Limits (Value,Units,By)ETHYLBENZENE: 100 ppm ACGIHTOLUENE: 150 ppm OSHAXYLENE (MIXED ISOMERS): 100 ppm ACGIHTITANIUM DIOXIDE: 10 mg/m3 ACGIHLOW FLASH NAPTHA ALIPHATIC: N/A
Irritancy (if yes, explain)ETHYLBENZENE is a skin and eye irritant. (MODERATE SKIN AND EYE IRRITANT) TOLUENE isa skin and eye irritant. (MODERATE SKIN IRRITANT) XYLENE (MIXED ISOMERS) is a skin andeye irritant.
Sensitization (if yes, explain) Carcinogenicity (if yes, explain)ETHYLBENZENE is considered to be a Animalcarcinogen. The agent is not likely to causecancer in humans except under uncommon orunlikely routes or levels of exposure(A3) byACGHI. ETHYLBENZENE is possiblycarcinogenic to humans(2B) by IARC.TITANIUM DIOXIDE is possibly carcinogenic tohumans(2B) by IARC.
Reproductive Toxicity (if yes, explain)LOW FLASH NAPTHA ALIPHATIC may damagethe reproductive system.
Teratogenicity (if yes, explain)TOLUENE may cause birth defects. (REDUCEDFETAL WEIGHT AND BEHAVIOURAL EFFECTS)XYLENE (MIXED ISOMERS) may cause birthdefects.
Mutagenicity (if yes, explain) Synergistic Products (if yes, explain)
SECTION 7 - PREVENTIVE MEASURES
PersonalProtectiveEquipment
Gloves:Yes
Respirator:Yes
Eye: Yes Footwear:No
Clothing:No
Other: No
If checked, specify type:Gloves: BUTYL RUBBER Respirator: NIOSH APPROVED Eye: SPLASH RESISTANT
Engineering controls (specify such as ventilation, enclosed process):Use mechanical ventilation to reduce exposure.
Leak and Spill Procedure:Wear adequate protective equipment and eliminate all ignition sources. Contain spill withabsorbant material and place in a suitable covered and labeled container for disposal.
Waste Disposal:Check with Federal, Provincial and local government regulations and requirements fordisposal.
Handling Procedures and Equipment:Use in a well ventilated area. Do not use with incompatible substances.
Storage Requirements:Store in a cool, well ventilated area out of direct sunlight.
Special Shipping Information:TDG Shipping Name: PAINT Classification: 3.3 Packing Group: III Identification Number:UN1263
SECTION 8 - FIRST AID MEASURES
Inhalation: Remove to fresh air. Get medical help if there is any breathing difficulty.
Ingestion: Do not induce vomiting unless directed by a physician. If conscious and alert,give two glasses of water. Seek medical attention immediately.
Skin Contact: Remove Contaminated clothing (including shoes) and wash before reuse.Flush with large amounts of soap and water. If irritation persists, seek medical attention.
Eye Contact: Flush eyes with large amounts of lukewarm water for 20 minutes, whileholding eyelids open or until irritation subsides. If irritation persist, get medical attention.
SECTION 9 - PREPARATION INFORMATION
Prepared by:General Paint Technical Dept
Phone:(604) 253-3131
Preparation Date:Jun 17, 2010
MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT INFORMATION
Product Identifier:32-001 EXTERIOR ALKYD PRIMER
Product Use: Protective Coating
Manufacturer's Name: General Paint Corp. Supplier's Name: General Paint Corp.
Street Address: 950 Raymur Ave Street Address: 950 Raymur Ave
City: Vancouver Province: BC City: Vancouver Province: BC
Postal Code:V6A 3L5
Emergency Phone:(604) 253-4022
Postal Code:V6A 3L5
EmergencyPhone:(604) 253-4022
SECTION 2 - HAZARDOUS INGREDIENTS
HazardousIngredients(Specific)
% CASNumber
LD 50 ofIngredient(Specify
species,route)
LC 50 ofIngredient(Specify
species)
ETHYLBENZENE 0.1 - 1 100-41-4 3500 MG/KG(ORAL,RAT)
4000 PPM(VAPOR,RAT)
XYLENE (MIXEDISOMERS)
0.33 -0.66
1330-20-7 5400 MG/KG(ORAL,RAT)
6350 PPM(VAPOR,RAT)
TITANIUM DIOXIDE 9 - 11 13463-67-7 NOT AVAILABLE NOT AVAILABLE
NAPTHA PETROLIUM,LIGHT ALKYLATE
6 64741-66-8 NOT AVAILABLE NOT AVAILABLE
MINERAL SPIRITS 13 64742-88-7 5000 MG/KG(ORAL,RAT)
5500 PPM(VAPOR,RAT)
MINERAL SPIRITS 13 - 14 8052-41-3 5000 MG/KG(ORAL,RAT)
5500 PPM(VAPOR,RAT)
SECTION 3 - PHYSICAL DATA
PhysicalState:Liquid
Odour andAppearance:liquid with a solventsmell
Coating VOC(gm/l):410
OdourThreshold(ppm):Not Available
SpecificGravity:1.33
VaporDensity(air=1):Not Available
VaporPressure(mmHg):Not Available
Evaporation Rate:Not Available
Boiling Point(C ):Not Available
Freezing Point( C ):Not Available
pH:Not Applicable
Coefficient ofWater/OilDistribution:
Not Available
SECTION 4 - FIRE AND EXPLOSION DATA
Flammability:YesIf yes, Under which Conditions?Flammable Liquid
Means of Extinction: Alcohol foam, Carbon dioxide, Dry chemical powder, Polymer foam
Flashpoint and Method:45 C Closed Cup
Upper Flammable Lt (%by Volume):Not Available
Lower Flammable Lt (%by Volume):Not Available
Autoignition Temperature:Not Available
Explosion Data -Sensitivity to Impact: No
Explosion Data -Sensitivity to Staticdischarges: No
Hazardous Combustion Pdts:oxides of sulfur, aluminum oxide, carbon monoxide, carbon dioxide,calcium oxide, aldehydes, nitrogen oxides, sulfur oxides, magnesium oxide
SECTION 5 - REACTIVITY DATA
Chemical Stability:Stable If Yes, Under which Conditions?Not Applicable
Incompatibility with othersubstances:Yes
If yes, which ones?Strong AcidsStrong Oxidizing agentsStrong Bases
Reactivity, and under what conditions?heat, ignition sources, nitric acid, sulfuric acid, sulfurdichloride, tetranitromethane, generation of dust, dichlorohydrantion, heat, sparks, or other ignitionsources
Hazardous Decomposition Products:carbon dioxide
SECTION 6 - TOXICOLOGICAL PROPERTIES
Route ofEntry
Skin Contact:Yes
Absorption:Yes
Eye Contact:Yes
Inhalation:Yes
Ingestion:Yes
Effects to Acute exposure to Product:ETHYLBENZENE has been known to cause HEADACHES, MEMORY LOSS, FATIGUE andDERMATITIS. XYLENE (MIXED ISOMERS) has been known to cause CENTRAL NERVOUSSYSTEM DEPPRESSION, HEADACHE, DEPRESSION, DROWSINESS, INCOORDINATION andSKIN AND EYE IRRITATION. MINERAL SPIRITS has been known to cause CONJUNCTIVITIS,CORNEAL DAMAGE, NAUSEA, VOMITING, DIARRHEA, HEADACHE and DIZZINESS. MINERALSPIRITS has been known to cause EYE IRRITANT, NOSE IRRITANT, THROAT IRRITANT,DIZZINESS and DERMATITIS.
Effects to Chronic exposure to Product:ETHYLBENZENE has been known to cause CENTRAL NERVOUS SYSTEM DPRESSION. XYLENE(MIXED ISOMERS) has been known to cause LIVER DAMAGE, KIDNEY DAMAGE, DERMATITIS.MINERAL SPIRITS has been known to cause DERMATITIS. MINERAL SPIRITS has been knownto cause NARCOSIS, CENTRAL NERVOUS SYSTEM DEPRESSION.
Exposure Limits (Value,Units,By)ETHYLBENZENE: 100 ppm ACGIHXYLENE (MIXED ISOMERS): 100 ppm ACGIHTITANIUM DIOXIDE: 10 mg/m3 ACGIHNAPTHA PETROLIUM, LIGHT ALKYLATE: 1400 mg/m3 Imperial Oil (manufacturer)MINERAL SPIRITS: 100 mg/m3 ACGIHMINERAL SPIRITS: 100 PPM ACGIH
Irritancy (if yes, explain)ETHYLBENZENE is a skin and eye irritant. (MODERATE SKIN AND EYE IRRITANT) XYLENE(MIXED ISOMERS) is a skin and eye irritant. MINERAL SPIRITS is a skin and eye irritant.(MILD)
Sensitization (if yes, explain) Carcinogenicity (if yes, explain)ETHYLBENZENE is considered to be a Animalcarcinogen. The agent is not likely to causecancer in humans except under uncommon orunlikely routes or levels of exposure(A3) byACGHI. ETHYLBENZENE is possiblycarcinogenic to humans(2B) by IARC.TITANIUM DIOXIDE is possibly carcinogenic tohumans(2B) by IARC.
Reproductive Toxicity (if yes, explain) Teratogenicity (if yes, explain)XYLENE (MIXED ISOMERS) may cause birthdefects.
Mutagenicity (if yes, explain) Synergistic Products (if yes, explain)
SECTION 7 - PREVENTIVE MEASURES
PersonalProtectiveEquipment
Gloves:Yes
Respirator:Yes
Eye: Yes Footwear:No
Clothing:No
Other: No
If checked, specify type:Gloves: BUTYL RUBBER Respirator: NIOSH APPROVED Eye: SPLASH RESISTANT
Engineering controls (specify such as ventilation, enclosed process):Use mechanical ventilation to reduce exposure.
Leak and Spill Procedure:Wear adequate protective equipment and eliminate all ignition sources. Contain spill withabsorbant material and place in a suitable covered and labeled container for disposal.
Waste Disposal:Check with Federal, Provincial and local government regulations and requirements fordisposal.
Handling Procedures and Equipment:Use in a well ventilated area. Do not use with incompatible substances.
Storage Requirements:Store in a cool, well ventilated area out of direct sunlight.
Special Shipping Information:TDG Shipping Name: PAINT Classification: 3.3 Packing Group: III Identification Number:UN1263
SECTION 8 - FIRST AID MEASURES
Inhalation: Remove to fresh air. Get medical help if there is any breathing difficulty.
Ingestion: Do not induce vomiting unless directed by a physician. If conscious and alert,give two glasses of water. Seek medical attention immediately.
Skin Contact: Remove Contaminated clothing (including shoes) and wash before reuse.Flush with large amounts of soap and water. If irritation persists, seek medical attention.
Eye Contact: Flush eyes with large amounts of lukewarm water for 20 minutes, whileholding eyelids open or until irritation subsides. If irritation persist, get medical attention.
SECTION 9 - PREPARATION INFORMATION
Prepared by:General Paint Technical Dept
Phone:(604) 253-3131
Preparation Date:Jun 17, 2010
Product Name: HEAVY DUTY ANTIFREEZE 60/40 PREMIX
Revision Date: 18 May 2012 Page 1 of 10
______________________________________________________________________________________________________________________
MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT
Product Name: HEAVY DUTY ANTIFREEZE 60/40 PREMIX Product Description: Glycol MSDS Number: 8514 Product Code: 35101010A0H7 Intended Use: Antifreeze/coolant
COMPANY IDENTIFICATION
Supplier: Imperial Oil Products Division 240 4th Avenue Calgary, ALBERTA. T2P 3M9 Canada
24 Hour Environmental / Health Emergency Telephone
1-866-232-9563
Transportation Emergency Phone Number 1-866-232-9563 Product Technical Information 1-800-268-3183 Supplier General Contact 1-800-567-3776
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# Concentration* Acute Toxicity ETHYLENE GLYCOL 107-21-1 55 - 65% Dermal Lethality: LD50 9.53
g/kg (Rabbit); Inhalation Lethality: LC50 4300 ppm (Rat); Oral Lethality: LD50 4.70 g/kg (Rat)
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 3 HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).
HEALTH EFFECTS
May cause harm to the unborn child. Ingestion may cause serious adverse effects and may be fatal. May cause kidney failure and central nervous system effects. Prolonged exposure to elevated concentrations of mist or liquid may cause irritation of the skin, eyes, and respiratory tract. High-pressure injection under skin may cause serious damage.
NFPA Hazard ID: Health: 1 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 2* Flammability: 1 Reactivity: 0
Product Name: HEAVY DUTY ANTIFREEZE 60/40 PREMIX
Revision Date: 18 May 2012 Page 2 of 10
______________________________________________________________________________________________________________________
NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.
SKIN CONTACT
Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION
Seek immediate medical attention. NOTE TO PHYSICIAN
This product contains ethylene glycol and/or diethylene glycol which, if ingested, are metabolized to toxic metabolites by the enzyme alcohol dehydrogenase, for which ethanol and 4-methylpyrazole {U.S. drug name Fomepizole, trade name Antizol} are antagonists. Administration of oral or intravenous ethanol or intravenous 4-methylpyrazole may arrest further metabolism of this material and thereby ameliorate the toxicity. Use of ethanol or 4-methylpyrazole does not affect toxic metabolites that are already present and is not a substitute for hemodialysis.
SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, alcohol-resistant foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water or standard foam
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Hazardous material. Firefighters should consider protective equipment indicated in Section 8.
Product Name: HEAVY DUTY ANTIFREEZE 60/40 PREMIX
Revision Date: 18 May 2012 Page 3 of 10
______________________________________________________________________________________________________________________
Hazardous Combustion Products: Smoke, Fume, Aldehydes, Incomplete combustion products, Oxides of carbon
FLAMMABILITY PROPERTIES
Flash Point [Method]: 116°C (240°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 3.2 UEL: 15.3 Autoignition Temperature: 40°C (104°F)
SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
PROTECTIVE MEASURES
Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Do not touch or walk through spilled material. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Consult an expert. Warn other shipping. Material will sink. Remove material, as much as possible, using mechanical equipment. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Remove debris in path of spill and remove contaminated debris from shoreline and water surface. Dispose of according to local regulations. Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7 HANDLING AND STORAGE HANDLING
Avoid breathing mists or vapour. Avoid contact with skin. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator.
STORAGE
Do not store in open or unlabelled containers. Keep away from incompatible materials.
Product Name: HEAVY DUTY ANTIFREEZE 60/40 PREMIX
Revision Date: 18 May 2012 Page 4 of 10
______________________________________________________________________________________________________________________
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Substance Name Form Limit/Standard Note Source ETHYLENE GLYCOL Aerosol. Ceiling 100 mg/m3 ACGIH
NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.
PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:
If prolonged or repeated contact is likely, chemical-resistant gloves are recommended. If contact with forearms is likely, wear gauntlet-style gloves.
Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:
If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping.
Product Name: HEAVY DUTY ANTIFREEZE 60/40 PREMIX
Revision Date: 18 May 2012 Page 5 of 10
______________________________________________________________________________________________________________________
ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION
Physical State: Liquid Colour: Violet Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density: > 1 Flash Point [Method]: 116°C (240°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 3.2 UEL: 15.3 Autoignition Temperature: 40°C (104°F) Boiling Point / Range: N/D Vapour Density (Air = 1): 2.1 at 101 kPa Vapour Pressure: 0.008 kPa (0.06 mm Hg) at 20ºC Evaporation Rate (n-butyl acetate = 1): 0.01 pH: 9 - 11 Log Pow (n-Octanol/Water Partition Coefficient): < 2 Solubility in Water: Complete Viscosity: [N/D at 40°C] Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
Freezing Point: N/D Melting Point: N/D Pour Point: -52°C (-62°F)
SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers, Acids, Alkalies HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks
Product Name: HEAVY DUTY ANTIFREEZE 60/40 PREMIX
Revision Date: 18 May 2012 Page 6 of 10
______________________________________________________________________________________________________________________
Inhalation Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on test data for structurally similar
materials. Irritation: Data available. Negligible hazard at ambient/normal handling temperatures.
Based on test data for structurally similar materials.
Ingestion Toxicity (Rat): LDLo 100 ml Moderately toxic. Based on test data for structurally similar
materials.
Skin Toxicity (Rabbit): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials. Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on test
data for structurally similar materials.
Eye Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test
data for structurally similar materials. CHRONIC/OTHER EFFECTS
Contains: ETHYLENE GLYCOL (EG): Repeated high oral exposure has caused kidney damage, neurological effects, degeneration of the liver and changes in blood chemistry and circulating blood cells in laboratory animals. Repeated overexposure has the potential to cause similar toxic effects in humans. EG causes developmental and reproductive effects at high dose levels in laboratory animals. The relevance of these findings to humans is uncertain. However, as a precaution, avoid exposure during pregnancy.
Additional information is available by request. CMR Status: None. Chemical Name CAS Number List Citations ETHYLENE GLYCOL 107-21-1 4
--REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Material -- Expected to remain in water or migrate through soil. PERSISTENCE AND DEGRADABILITY Biodegradation: Material -- Expected to be readily biodegradable.
Product Name: HEAVY DUTY ANTIFREEZE 60/40 PREMIX
Revision Date: 18 May 2012 Page 7 of 10
______________________________________________________________________________________________________________________
Atmospheric Oxidation: Material -- Expected to degrade rapidly in air BIOACCUMULATION POTENTIAL Material -- Potential to bioaccumulate is low.
SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS
Even though this product is readily biodegradable, it must not be indiscriminately discarded into the environment. Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products.
REGULATORY DISPOSAL INFORMATION Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION LAND (TDG): Not Regulated for Land Transport
LAND (DOT)
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Ethylene Glycol ) Hazard Class & Division: 9 ID Number: 3082 Packing Group: III Product RQ: 7692.31 LBS - ETHYLENE GLYCOL ERG Number: 171 Label(s): 9 Transport Document Name: UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S. (Ethylene Glycol), 9, PG III, RQ
SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code
AIR (IATA): Not Regulated for Air Transport
Product Name: HEAVY DUTY ANTIFREEZE 60/40 PREMIX
Revision Date: 18 May 2012 Page 8 of 10
______________________________________________________________________________________________________________________
SECTION 15 REGULATORY INFORMATION WHMIS Classification: Class D, Division 2, Subdivision A: Very Toxic Material This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Complies with the following national/regional chemical inventory requirements: AICS, DSL, EINECS, ENCS, IECSC, KECI, PICCS, TSCA The Following Ingredients are Cited on the Lists Below: None. Chemical Name CAS Number List Citations ETHYLENE GLYCOL 107-21-1 6
--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 04: First Aid Eye - Header was modified. Section 04: First Aid Ingestion - Header was modified. Section 06: Protective Measures was modified. Section 06: Notification Procedures - Header was modified. Section 11: Acute Toxicity Table Header was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Colour was modified. Section 11: Inhalation - Header was modified. Section 09: Evaporation Rate - Header was modified. Section 08: Comply with applicable regulations phrase was modified. Section 09: Vapour Pressure - Header was modified. Section 09: Vapour Pressure was modified. Hazard Identification: Health Hazards was modified. Section 11: Inhalation Lethality Test Data was modified. Section 06: Accidental Release-Spill Management-Land was modified. Section 06: Accidental Release- Spill Management- Water was modified. Section 09: Flash Point C(F) was modified.
Product Name: HEAVY DUTY ANTIFREEZE 60/40 PREMIX
Revision Date: 18 May 2012 Page 9 of 10
______________________________________________________________________________________________________________________
Section 14: Sea (IMDG) - Header was modified. Section 14: Air (IATA) - Header was modified. Section 14: LAND (TDG) - Header was modified. Section 14: LAND (TDG) Default was modified. Section 14: Sea (IMDG) - Default was modified. Section 14: Air (IATA) - Default was modified. Section 15: National Chemical Inventory Listing - Header was modified. Section 15: National Chemical Inventory Listing was modified. Hazard Identification: Hazards Note was modified. Composition: Component table was modified. Section 16: Health Hazards was modified. Section 16: Health Hazards - Header was modified. Section 16: CA Prepared by - Header was modified. Section 08: Exposure Limits Table was modified. Section 16: Land Spill was modified. Section 16: First Aid Inhalation - Header was modified. Section 16: Precautionary Label Text - Header was modified. Section 09: Oxidizing Properties was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 11: Tox List Cited Table was modified. Section 13: Regulatory Disposal Information - Header was modified. Section 14: Product RQ - Header was added. Section 14: Product RQ was added. Section 15: Canadian List Citations Table was added. Section 15: Chemical Name - Header was added. Section 15: CAS Number - Header was added. Section 15: List Citations -Header was added. Section 01: Product Code was added. Section 01: Product Code - Header was added. ----------------------------------------------------------------------------------------------------------------------------------------------------- PRECAUTIONARY LABEL TEXT: WHMIS Classification: Class D, Division 2, Subdivision A: Very Toxic Material HEALTH HAZARDS May cause harm to the unborn child. PRECAUTIONS Avoid breathing mists or vapour. Avoid contact with skin. FIRST AID Inhalation: Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Eye: Flush thoroughly with water. If irritation occurs, get medical assistance. Oral: Seek immediate medical attention. Skin: Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.
Product Name: HEAVY DUTY ANTIFREEZE 60/40 PREMIX
Revision Date: 18 May 2012 Page 10 of 10
______________________________________________________________________________________________________________________
FIRE FIGHTING MEDIA Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPILL/LEAK Land Spill: Stop leak if you can do so without risk. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Recover by pumping or with suitable absorbent. Do not touch or walk through spilled material. Water Spill: Stop leak if you can do so without risk. Report spills as required to appropriate authorities. Material will sink. ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 5007472 (1011905) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety
Product Name: EXXON XD-3 EXTRA ENGINE OIL 10W-30
Revision Date: 03 Mar 2011 Page 1 of 9
______________________________________________________________________________________________________________________
MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT
Product Name: EXXON XD-3 EXTRA ENGINE OIL 10W-30 Product Description: Base Oil and Additives MSDS Number: 15932 Intended Use: Engine oil
COMPANY IDENTIFICATION
Supplier: Imperial Oil Products Division 240 4th Avenue Calgary, ALBERTA. T2P 3M9 Canada
24 Hour Environmental / Health Emergency Telephone
519-339-2145
Transportation Emergency Phone Number 519-339-2145 Product Technical Information 1-800-268-3183 Supplier General Contact 1-800-567-3776
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 3 HAZARDS IDENTIFICATION This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH EFFECTS
Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
Product Name: EXXON XD-3 EXTRA ENGINE OIL 10W-30
Revision Date: 03 Mar 2011 Page 2 of 9
______________________________________________________________________________________________________________________ immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.
SKIN CONTACT
Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION
First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulphur oxides, Incomplete combustion products, Oxides of carbon
FLAMMABILITY PROPERTIES
Flash Point [Method]: 230C (446F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: 315°C (599°F)
SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
PROTECTIVE MEASURES
Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending
Product Name: EXXON XD-3 EXTRA ENGINE OIL 10W-30
Revision Date: 03 Mar 2011 Page 3 of 9
______________________________________________________________________________________________________________________ on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7 HANDLING AND STORAGE HANDLING
Avoid contact with used product. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present (e.g., during switch-loading operations). Use proper bonding and/or earthing procedures. However, bonding and earthing may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator.
STORAGE
The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers.
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL.
Product Name: EXXON XD-3 EXTRA ENGINE OIL 10W-30
Revision Date: 03 Mar 2011 Page 4 of 9
______________________________________________________________________________________________________________________ NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.
PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:
No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping.
ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional data.
Product Name: EXXON XD-3 EXTRA ENGINE OIL 10W-30
Revision Date: 03 Mar 2011 Page 5 of 9
______________________________________________________________________________________________________________________ GENERAL INFORMATION
Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 C): 0.863 Flash Point [Method]: 230C (446F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: 315°C (599°F) Boiling Point / Range: > 316C (600F) Vapour Density (Air = 1): > 2 at 101 kPa Vapour Pressure: [N/D at 20°C] | < 1 kPa (7.5 mm Hg) at 38C Evaporation Rate (n-butyl acetate = 1): < 0.1 pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: [N/D at 40°C] | 12 cSt (12 mm2/sec) at 100C Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
Freezing Point: N/D Melting Point: N/A Pour Point: -30°C (-22°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt
SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation
Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on test data for structurally similar materials.
Irritation: No end point data. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Ingestion
Toxicity (Rat): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar materials.
Skin
Product Name: EXXON XD-3 EXTRA ENGINE OIL 10W-30
Revision Date: 03 Mar 2011 Page 6 of 9
______________________________________________________________________________________________________________________ Toxicity (Rabbit): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials. Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on test
data for structurally similar materials.
Eye Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test
data for structurally similar materials. CHRONIC/OTHER EFFECTS For the product itself:
Diesel engine oils: Not carcinogenic in animals tests. Used and unused diesel engine oils did not produce any carcinogenic effects in chronic mouse skin painting studies. Oils that are used in gasoline engines may become hazardous and display the following properties: Carcinogenic in animal tests. Caused mutations in vitro. Possible allergen and photoallergen. Contains polycyclic aromatic compounds (PAC) from combustion products of gasoline and/or thermal degradation products. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
Additional information is available by request. CMR Status: None.
--REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to
partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may
reduce the bioconcentration or limit bioavailability.
Product Name: EXXON XD-3 EXTRA ENGINE OIL 10W-30
Revision Date: 03 Mar 2011 Page 7 of 9
______________________________________________________________________________________________________________________ SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants.
REGULATORY DISPOSAL INFORMATION Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION LAND (TDG): Not Regulated for Land Transport
LAND (DOT): Not Regulated for Land Transport
SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code
AIR (IATA): Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION WHMIS Classification: Not controlled This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Complies with the following national/regional chemical inventory requirements: AICS, TSCA, DSL, PICCS, IECSC, KECI Special Cases:
Inventory Status ELINCS Restrictions Apply ENCS Restrictions Apply
Product Name: EXXON XD-3 EXTRA ENGINE OIL 10W-30
Revision Date: 03 Mar 2011 Page 8 of 9
______________________________________________________________________________________________________________________ The Following Ingredients are Cited on the Lists Below: Chemical Name CAS Number List Citations ZINC DITHIOPHOSPHATE 68649-42-3 6
--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 04: First Aid Eye - Header was modified. Section 04: First Aid Ingestion - Header was modified. Section 06: Notification Procedures - Header was modified. Section 13: Disposal Considerations - Disposal Recommendations was modified. Section 11: Acute Toxicity Table Header was modified. Section 09: Colour was modified. Section 11: Inhalation - Header was modified. Section 09: Evaporation Rate - Header was modified. Section 09: Vapour Pressure - Header was modified. Section 07: Handling and Storage-Handling was modified. Section 07: Handling and Storage-Storage Phrases was modified. Section 11: Inhalation Lethality Test Data was modified. Section 05: Hazardous Combustion Products was modified. Section 06: Accidental Release- Spill Management- Water was modified. Section 09: Flash Point C(F) was modified. Section 09 Viscosity was modified. Section 14: Sea (IMDG) - Header was modified. Section 14: Air (IATA) - Header was modified. Section 14: LAND (TDG) - Header was modified. Section 14: LAND (DOT) - Header was modified. Section 14: LAND (DOT) - Default was modified. Section 14: LAND (TDG) Default was modified. Section 14: Sea (IMDG) - Default was modified. Section 14: Air (IATA) - Default was modified. Section 15: National Chemical Inventory Listing - Header was modified. Section 15: National Chemical Inventory Listing was modified. Section 09: Relative Density was modified. Hazard Identification: Hazards Note was modified. Section 16: CA Prepared by - Header was modified. Section 09: Oxidizing Properties was modified. Section 15: List Citation Table - Header was modified.
Product Name: EXXON XD-3 EXTRA ENGINE OIL 10W-30
Revision Date: 03 Mar 2011 Page 9 of 9
______________________________________________________________________________________________________________________
Section 13: Regulatory Disposal Information - Header was modified. Section 06: Protective Measures was added. Section 06: Accidental Release - Protective Measures - Header was added. Section 15: Canadian List Citations Table was added. Section 15: Chemical Name - Header was added. Section 15: CAS Number - Header was added. Section 15: List Citations -Header was added. ----------------------------------------------------------------------------------------------------------------------------------------------------- WHMIS Classification: Not controlled ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 5014229 (543611) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety
MATERIAL SAFETY DATA SHEET
==================================================
SECTION I - PRODUCT IDENTIFICATION ==================================================
==================================================
SECTION II – HAZARDOUS INGREDIENTS ==================================================
Ingredients CAS# Wt% ACGIH-TLV LC50 LD50 Alcohols, C9-11, ethoxylated 68439-46-3 1 - 5 Not available Not available 1200 mg/kg oral, rat Hydrogen chloride 7647-01-0 1 - 5 5 ppm Ceiling 935 ppm 4 h, mouse 900 mg/kg oral, rabbit
==================================================
SECTION III - PHYSICAL DATA ==================================================
Boiling Point (°C): Not available Specific Gravity (H2O = 1): 1.05
Vapour Pressure (mm Hg): Not available Evaporation Rate (Ether = 1): Not available
Vapour Density (Air = 1): Not available pH (100%): 0.5
Solubility in Water: Emulsifiable Viscosity: Water thin
Physical State: Liquid
Appearance; Odour: Opaque green; floral
==================================================
SECTION IV - FIRE AND EXPLOSION DATA ==================================================
Flammability: Not flammable by WHMIS criteria.
Flash Point (oC, TCC): None LEL: Not applicable UEL: Not applicable
Hazardous Combustion Products: May include and are not limited to oxides of carbon, hydrogen chloride, oxides of nitrogen, ammonia, chlorine.
Autoignition Temperature (oC): Not applicable
Means of Extinction: Treat for surrounding material.
Special Fire Hazards: Firefighters should wear self-contained breathing apparatus. ==================================================
SECTION V - REACTIVITY DATA ==================================================
Conditions for Chemical Instability: Stable.
Incompatible Materials: Oxidizers, aluminum, caustics, reducers.
Reactivity, and Under What Conditions: Reacts vigorously with alkaline material or metals. Reacts with soft metals producing flammable hydrogen gas.
Hazardous Decomposition Products: May include and are not limited to oxides of carbon, hydrogen chloride, oxides of nitrogen, ammonia, chlorine when heated to decomposition.
Product Name:
SAN-I-CAN PORCELAIN CLEANER (1L)
Product Use:
Bathroom Care
WHMIS Class:
Class E - Corrosive Material
TDG Classification: HYDROCHLORIC ACID, SOLUTION; Class 8; UN1789; PG II
Manufacturer/Supplier: Kemsol Products Ltd.
Address:
1120 McDonald St. Regina, SK S4N 4X3
Telephone: (306) 569-0636
HEALTH
3
FLAMMABILITY
0
REACTIVITY
0
PERSONAL
PROTECTION
B
SAN-I-CAN POPRCELAIN CLEANER (1L)
==================================================
SECTION VI - TOXICOLOGICAL PROPERTIES ==================================================
Route of Entry: Eye, Skin contact, Inhalation, Ingestion.
EFFECTS OF ACUTE EXPOSURE:
Eye: May cause chemical burns. May cause blindness.
Skin: May cause chemical burns.
Inhalation (mists): Harmful. May cause respiratory tract irritation or chemical burns.
Ingestion: Harmful if swallowed. May cause chemical burns to mouth, throat and stomach.
EFFECTS OF CHRONIC EXPOSURE:
Skin: May cause chemical burns.
Irritancy: Corrosive by WHMIS criteria.
Respiratory Tract Sensitization: No data available.
Carcinogenicity: Non-hazardous by WHMIS criteria.
Teratogenicity, Mutagenicity, Reproductive Effects: No data available.
==================================================
SECTION VII- PREVENTATIVE MEASURES ==================================================
Gloves: Rubber gloves. Confirm with a reputable supplier first.
Eye Protection: Chemical splash goggles.
Respiratory Protection: Not normally required if good ventilation is maintained.
Other Protective Equipment: As required by employer code.
Engineering Controls: General ventilation normally adequate.
Leak and Spill Procedure: Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice.
Waste Disposal: Review federal, provincial, and local government requirements prior to disposal.
Storage and Handling Requirements: Keep out of reach of children. Store in a closed container away from incompatible materials.
==================================================
SECTION VIII - FIRST AID ==================================================
Eye: Immediately flush with cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes. Obtain medical attention immediately.
Skin: Immediately flush with cool water for 15 minutes while removing contaminated clothing and shoes. Discard or wash well before reuse. Obtain medical attention if irritation persists.
Inhalation: Move victim to fresh air. If symptoms persist, obtain medical attention.
Ingestion: Do not induce vomiting. Rinse mouth with water then drink one or two glasses of water. Obtain medical attention. Never give anything by mouth if victim is unconscious, or is convulsing.
=================================================
SECTION IX - PREPARATION INFORMATION =================================================
Date: 06/01/12 MSDS Prepared by: Kemsol Products Ltd.
Telephone: (306) 569-0636 ================================================== Disclaimer
Information for this material safety data sheet was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the mandatory requirements of WHMIS. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this form. If user requires independent information on ingredients in this or any other material, we recommend contact with the Canadian Centre for Occupational Health and Safety (CCOHS) in Hamilton, Ontario (1-905-572-4400) or CSST in Montreal, Quebec (514-873-3990).
2
Material Safety Data SheetVersion: 1.5
05/13/2008
RTV630 001-KIT(1.0 Lbs-0.454 Kg) Silicone Moldmaking Material - Component A
Page 1/7
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufactured By: Waterford Plant 260 Hudson River Rd Waterford NY 12188
Revised: 05/13/2008 Preparer: PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS CHEMTREC 1-800-424-9300 Chemical Family/Use: Silicone Elastomer Formula: Mixture HMIS Flammability: 1 Reactivity: 0 Health: 0 NFPA Flammability: 1 Reactivity: 0 Health: 1
2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CAUTION! May cause skin, eye, and respiratory tract irritation. May generate formaldehyde at temperatures greater than 150 C (300 F). See Section 10 of MSDS for details. Attention: Not for injection into humans.
Form: Liquid Color: beige Odor: Slight POTENTIAL HEALTH EFFECTS INGESTION
None known. Not an anticipated route of exposure. SKIN
Skin contact may cause irritation. INHALATION
Inhalation of vapors may cause irritation of the respiratory tract. EYES
May cause eye irritation. MEDICAL CONDITIONS AGGRAVATED
None known. SUBCHRONIC (TARGET ORGAN )
None known. CHRONIC EFFECTS / CARCINOGENICITY
No data available
Material Safety Data SheetVersion: 1.5
05/13/2008
RTV630 001-KIT(1.0 Lbs-0.454 Kg) Silicone Moldmaking Material - Component A
Page 2/7
ROUTES OF EXPOSURE
Inhalation
3. COMPOSITION / INFORMATION ON INGREDIENTS
PRODUCT COMPOSITION CAS REG NO. WGT. %
A. HAZARDOUS B. NON-HAZARDOUS polyvinylsiloxane 68083-19-2 30 - 60 %
Polyalkylalkenylsiloxane 68584-83-8 10 - 30 %
Limestone 471-34-1 1 - 5 %
4. FIRST AID MEASURES INGESTION
Do not induce vomiting. If victim is conscious, give 1-3 glasses of water to drink. Never give anything by mouth to an unconscious person. Get medical attention if irritation persists.
SKIN
Wash with soap and water. Get medical attention if irritation or symptoms from Section 3 develop.
INHALATION
If inhaled, remove to fresh air. If not breathing give artificial respiration using a barrier device. If breathing is difficult give oxygen. Get medical attention.
EYES
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists.
NOTE TO PHYSICIAN
Treatment is symptomatic and supportive.
5. FIRE-FIGHTING MEASURES FLASH POINT: > 100 °C; 212 °F
Material Safety Data SheetVersion: 1.5
05/13/2008
RTV630 001-KIT(1.0 Lbs-0.454 Kg) Silicone Moldmaking Material - Component A
Page 3/7
IGNITION TEMPERATURE: Not applicable FLAMMABLE LIMITS IN AIR - LOWER (%): No data available FLAMMABLE LIMITS IN AIR - UPPER (%): No data available SENSITIVITY TO MECHANICAL IMPACT: No SENSITIVITY TO STATIC DISCHARGE
Sensitivity to static discharge is not expected. EXTINGUISHING MEDIA
All standard extinguishing agents are suitable. SPECIAL FIRE FIGHTING PROCEDURES
Firefighters must wear NIOSH/MSHA approved positive pressure self-contained breathing apparatus with full face mask and full protective clothing.
FURTHER INFORMATION
Standard procedure for chemical fires.
6. ACCIDENTAL RELEASE MEASURES ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Wipe, scrape or soak up in an inert material and put in a container for disposal. Wash walking surfaces with detergent and water to reduce slipping hazard. Wear proper protective equipment as specified in the protective equipment section.
7. HANDLING AND STORAGE PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Keep container closed when not in use. Avoid contact with skin, eyes and clothing. Keep away from children.
STORAGE
Keep container closed. Store away from heat, sources of ignition, and incompatibles.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS
Eyewash stations; Showers; Exhaust ventilation RESPIRATORY PROTECTION
If exposure limits are exceeded or respiratory irritation is experienced, NIOSH/MSHA approved
Material Safety Data SheetVersion: 1.5
05/13/2008
RTV630 001-KIT(1.0 Lbs-0.454 Kg) Silicone Moldmaking Material - Component A
Page 4/7
respiratory protection should be worn. Supplied air respirators may be required for non-routine or emergency situations. Respiratory protection must be provided in accordance with OSHA regulations (see 29CFR 1910.134).
PROTECTIVE GLOVES
Rubber gloves EYE AND FACE PROTECTION
Safety glasses with side-shields OTHER PROTECTIVE EQUIPMENT
Wear suitable protective clothing and eye/face protection. Exposure Guidelines
Component CAS RN Source Value
Absence of values indicates none found PEL - OSHA Permissible Exposure Limit; TLV - ACGIH Threshold Limit Value; TWA - Time Weighted Average; INTL REL - Internal Recommended Exposure Limit OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 11th Circuit Court of Appeals decision (AFL-CIO v. OSHA) effective June 30, 1993. See 29 CFR 1910.1000 (58 FR 35338).
9. PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT - C & F: >260 °C; 500 °F VAPOR PRESSURE (20 C) (MM HG): Negligible VAPOR DENSITY (AIR=1): 1.0 FREEZING POINT: Not applicable MELTING POINT: Not applicable PHYSICAL STATE: Liquid ODOR: Slight COLOR: beige EVAPORATION RATE (BUTYL ACETATE=1): < 1 SPECIFIC GRAVITY (WATER=1): ca. 1.28 DENSITY: ca. 1.28 g/cm3 ACID / ALKALINITY (MEQ/G): Unknown pH: No data available VOLATILE ORGANIC CONTENT (VOL): No data available SOLUBILITY IN WATER (20 C): Insoluble SOLUBILITY IN ORGANIC SOLVENT (STATE SOLVENT):
Toluene
VOC EXCL. H2O & EXEMPTS (G/L): ca. 1
Material Safety Data SheetVersion: 1.5
05/13/2008
RTV630 001-KIT(1.0 Lbs-0.454 Kg) Silicone Moldmaking Material - Component A
Page 5/7
10. STABILITY AND REACTIVITY STABILITY
Stable HAZARDOUS POLYMERIZATION
Will not occur HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS
Carbon monoxide; Carbon dioxide (CO2); Silicon dioxide.; Formaldehyde; This product contains methylpolysiloxanes which can generate formaldehyde at approximately 300 degrees Fahrenheit (150'C) and above, in atmospheres which contain oxygen. Formaldehyde is a skin and respiratory sensitizer, eye and throat irritant, acute toxicant, and potential cancer hazard. A MSDS for formaldehyde is available from Momentive.
INCOMPATIBILITY (MATERIALS TO AVOID)
None known. CONDITIONS TO AVOID
None known.
11. TOXICOLOGICAL INFORMATION ACUTE ORAL
Remarks: Unknown ACUTE DERMAL
Remarks: Unknown ACUTE INHALATION
Remarks: Unknown OTHER
None. SENSITIZATION
No data available SKIN IRRITATION
No data available EYE IRRITATION
No data available MUTAGENICITY
Unknown
Material Safety Data SheetVersion: 1.5
05/13/2008
RTV630 001-KIT(1.0 Lbs-0.454 Kg) Silicone Moldmaking Material - Component A
Page 6/7
12. ECOLOGICAL INFORMATION ECOTOXICITY
No data available
DISTRIBUTION
No data available CHEMICAL FATE
No data available
13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD
Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORT INFORMATION
Further Information: This product is not regarded as dangerous goods according to the
national and international regulations on the transport of dangerous goods.
15. REGULATORY INFORMATION
Inventories
Canada DSL Inventory y (Positive listing) Japan Inventory of Existing & New Chemical Substances (ENCS)
y (Positive listing)
Korea Existing Chemicals Inventory (KECI)
y (Positive listing)
China Inventory of Existing Chemical Substances
y (Positive listing)
Australia Inventory of Chemical Substances (AICS)
y (Positive listing)
Philippines Inventory of Chemicals and Chemical Substances (PICCS)
y (Positive listing)
TSCA list y (Positive listing) On TSCA Inventory
Material Safety Data SheetVersion: 1.5
05/13/2008
RTV630 001-KIT(1.0 Lbs-0.454 Kg) Silicone Moldmaking Material - Component A
Page 7/7
EU list of existing chemical substances
y (Positive listing)
For inventories that are marked as quantity restricted or special cases, please contact Momentive.
US Regulatory Information SARA (311,312) HAZARD CLASS
No SARA HazardsAcute Health Hazard; Chronic Health Hazard SARA (313) CHEMICALS
CALIFORNIA PROPOSITION 65
WARNING! This product contains a chemical known in the State of California to cause cancer. 100-41-4, Ethylbenzene. 71-43-2, Benzene. 108-88-3, Toluene.
Canadian Regulatory Information WHMIS HAZARD CLASS
Non-controlled. Other SCHDLE B/HTSUS: 3910.00 Silicones in Primary Form ECCN: EAR99
16. OTHER INFORMATION OTHER
These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied, is made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate., C = ceiling limit NEGL = negligible EST = estimated NF = none found NA = not applicable UNKN = unknown NE = none established REC = recommended ND = none determined V = recommended by vendor SKN = skin TS = trade secret R = recommended MST = mist NT = not tested STEL = short term exposure limit ppm = parts per million ppb = parts per billion By-product= reaction by-product, TSCA inventory status not required under 40 CFR part 720.30(h-2).
Material Safety Data SheetVersion: 1.4
05/13/2008
RTV630 001-KIT(1.0 Lbs-0.454 Kg) Silicone Moldmaking Material - Component B
Page 1/7
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Manufactured By: Waterford Plant 260 Hudson River Rd Waterford NY 12188
Revised: 05/13/2008 Preparer: PRODUCT STEWARDSHIP COMPLIANCE AND STANDARDS CHEMTREC 1-800-424-9300 Chemical Family/Use: Silicone Rubber Formula: Mixture HMIS Flammability: 1 Reactivity: 1 Health: 0 NFPA Flammability: 1 Reactivity: 1 Health: 1
2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CAUTION! Product generates flammable gas on contact with acids, bases or oxidizing substances. May cause irritation of skin and eyes.
Form: Liquid Color: Blue Odor: Slight POTENTIAL HEALTH EFFECTS INGESTION
None known. SKIN
May cause mild skin irritation. INHALATION
None known. EYES
May cause mild eye irritation. MEDICAL CONDITIONS AGGRAVATED
None known. SUBCHRONIC (TARGET ORGAN )
None known. CHRONIC EFFECTS / CARCINOGENICITY
This product or one of its ingredients present at 0.1% or more is NOT listed as a carcinogen or suspected carcinogen by NTP, IARC, or OSHA.
Material Safety Data SheetVersion: 1.4
05/13/2008
RTV630 001-KIT(1.0 Lbs-0.454 Kg) Silicone Moldmaking Material - Component B
Page 2/7
ROUTES OF EXPOSURE
None known.
3. COMPOSITION / INFORMATION ON INGREDIENTS
PRODUCT COMPOSITION CAS REG NO. WGT. %
A. HAZARDOUS B. NON-HAZARDOUS METHYLHYDROGENPOLYSILOXANE
68988-57-8 30 - 60 %
polyvinylsiloxane 68083-19-2 30 - 60 %
Polyalkylalkenylsiloxane 68584-83-8 10 - 30 %
4. FIRST AID MEASURES INGESTION
Rinse mouth with water several times. Obtain medical attention. SKIN
After contact with skin, remove product mechanically. Wash off with soap and water. INHALATION
None known. EYES
Immediately flush eye(s) with plenty of water. If eye irritation persists, consult a specialist. NOTE TO PHYSICIAN
None known.
5. FIRE-FIGHTING MEASURES FLASH POINT: > 100 °C; 212 °F FLAMMABLE LIMITS IN AIR - LOWER (%): Not applicable FLAMMABLE LIMITS IN AIR - UPPER (%): Not applicable SENSITIVITY TO MECHANICAL IMPACT: No
Material Safety Data SheetVersion: 1.4
05/13/2008
RTV630 001-KIT(1.0 Lbs-0.454 Kg) Silicone Moldmaking Material - Component B
Page 3/7
EXTINGUISHING MEDIA
Carbon dioxide (CO2), Foam, Water spray, Dry powder SPECIAL FIRE FIGHTING PROCEDURES
Firefighters must wear NIOSH/MSHA approved positive pressure self-contained breathing apparatus with full face mask and full protective clothing.
FURTHER INFORMATION
Standard procedure for chemical fires.
6. ACCIDENTAL RELEASE MEASURES ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Wipe, scrape or soak up in an inert material and put in a container for disposal. Wear proper protective equipment as specified in the protective equipment section.
7. HANDLING AND STORAGE PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
Use personal protective equipment. Avoid contact with skin, eyes and clothing. Keep container closed when not in use to prevent contact with acidic, basic, or oxidizing materials, and metallic catalysts like tin soaps and noble metals (Pt, Rh, etc.).
STORAGE
Store away from heat, sources of ignition, and incompatibles.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS
Eyewash stations RESPIRATORY PROTECTION
If exposure limits are exceeded or respiratory irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Supplied air respirators may be required for non-routine or emergency situations. Respiratory protection must be provided in accordance with OSHA regulations (see 29CFR 1910.134).
PROTECTIVE GLOVES
Protective gloves
Material Safety Data SheetVersion: 1.4
05/13/2008
RTV630 001-KIT(1.0 Lbs-0.454 Kg) Silicone Moldmaking Material - Component B
Page 4/7
EYE AND FACE PROTECTION Safety glasses with side-shields
OTHER PROTECTIVE EQUIPMENT
Lightweight protective clothing Exposure Guidelines
Component CAS RN Source Value
Absence of values indicates none found PEL - OSHA Permissible Exposure Limit; TLV - ACGIH Threshold Limit Value; TWA - Time Weighted Average; INTL REL - Internal Recommended Exposure Limit OSHA revoked the Final Rule Limits of January 19, 1989 in response to the 11th Circuit Court of Appeals decision (AFL-CIO v. OSHA) effective June 30, 1993. See 29 CFR 1910.1000 (58 FR 35338).
9. PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT - C & F: >300 °C; 572 °F VAPOR PRESSURE (20 C) (MM HG): No data available VAPOR DENSITY (AIR=1): No data available FREEZING POINT: No data available MELTING POINT: No data available PHYSICAL STATE: Liquid ODOR: Slight COLOR: Blue EVAPORATION RATE (BUTYL ACETATE=1): Unknown SPECIFIC GRAVITY (WATER=1): ca. 1.02 DENSITY: ca. 1.02 g/cm3 ACID / ALKALINITY (MEQ/G): No data available pH: N/A VOLATILE ORGANIC CONTENT (VOL): No data available SOLUBILITY IN WATER (20 C): Insoluble SOLUBILITY IN ORGANIC SOLVENT (STATE SOLVENT):
Soluble in toluene
VOC EXCL. H2O & EXEMPTS (G/L): ca. 5
10. STABILITY AND REACTIVITY STABILITY
Stable HAZARDOUS POLYMERIZATION
Will not occur
Material Safety Data SheetVersion: 1.4
05/13/2008
RTV630 001-KIT(1.0 Lbs-0.454 Kg) Silicone Moldmaking Material - Component B
Page 5/7
HAZARDOUS THERMAL DECOMPOSITION / COMBUSTION PRODUCTS Flammable hydrogen gas.; Carbon dioxide (CO2); Carbon monoxide; Formaldehyde; Silicon dioxide.; This product contains methylpolysiloxanes which can generate formaldehyde at approximately 300 degrees Fahrenheit (150'C) and above, in atmospheres which contain oxygen. Formaldehyde is a skin and respiratory sensitizer, eye and throat irritant, acute toxicant, and potential cancer hazard. A MSDS for formaldehyde is available from Momentive.
INCOMPATIBILITY (MATERIALS TO AVOID)
Avoid contact with acidic, basic, or oxidizing agents, and metallic catalysts like tin soaps and noble metals (Pt, Rh, etc.).
CONDITIONS TO AVOID
Avoid contact with acids, bases, or oxidizing agents. Product generates flammable gas on contact with acids, bases or oxidizing substances.
11. TOXICOLOGICAL INFORMATION ACUTE ORAL
Remarks: None known. ACUTE DERMAL
Remarks: None known. ACUTE INHALATION
Remarks: Unknown OTHER
None. MUTAGENICITY
Unknown
12. ECOLOGICAL INFORMATION CHEMICAL FATE
No data available
13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD
Disposal should be made in accordance with federal, state and local regulations.
Material Safety Data SheetVersion: 1.4
05/13/2008
RTV630 001-KIT(1.0 Lbs-0.454 Kg) Silicone Moldmaking Material - Component B
Page 6/7
14. TRANSPORT INFORMATION
Further Information: This product is not regarded as dangerous goods according to the
national and international regulations on the transport of dangerous goods.
15. REGULATORY INFORMATION
Inventories
Canada DSL Inventory y (Positive listing) Japan Inventory of Existing & New Chemical Substances (ENCS)
y (Positive listing)
Korea Existing Chemicals Inventory (KECI)
y (Positive listing)
China Inventory of Existing Chemical Substances
y (Positive listing)
Australia Inventory of Chemical Substances (AICS)
y (Positive listing)
Philippines Inventory of Chemicals and Chemical Substances (PICCS)
y (Positive listing)
TSCA list y (Positive listing) On TSCA Inventory EU list of existing chemical substances
y (Positive listing)
Canada NDSL Inventory n (Negative listing) For inventories that are marked as quantity restricted or special cases, please contact Momentive.
US Regulatory Information SARA (311,312) HAZARD CLASS
No SARA Hazards SARA (313) CHEMICALS
CALIFORNIA PROPOSITION 65
Warning! This product contains a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. 71-43-2, Benzene. 108-88-3, Toluene.
Canadian Regulatory Information
Material Safety Data SheetVersion: 1.4
05/13/2008
RTV630 001-KIT(1.0 Lbs-0.454 Kg) Silicone Moldmaking Material - Component B
Page 7/7
WHMIS HAZARD CLASS
D2A VERY TOXIC MATERIALS
Other SCHDLE B/HTSUS: 3910.00 Silicones in Primary Form ECCN: EAR99
16. OTHER INFORMATION OTHER
These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied, is made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate., C = ceiling limit NEGL = negligible EST = estimated NF = none found NA = not applicable UNKN = unknown NE = none established REC = recommended ND = none determined V = recommended by vendor SKN = skin TS = trade secret R = recommended MST = mist NT = not tested STEL = short term exposure limit ppm = parts per million ppb = parts per billion By-product= reaction by-product, TSCA inventory status not required under 40 CFR part 720.30(h-2).
Canadian Workplace Hazardous Materials Information SystemMaterial Safety Data Sheet
I. PRODUCT IDENTIFICATIONProduct Name: PC FAST ORANGE PUMICE CREAM 400GRItem No: 20864Product Type: Waterless hand cleaner
II. COMPOSITION/INFORMATION ON INGREDIENTSComponent Weight% LD50/oral/rat LC50/inhalation/rat ACGIH; TLV-TWA
WATER7732-18-5
70-80 not available not available
PUMICE1332-09-8
5-15 not available not available 10 mg/m3 (inhal); 3 mg/m3
(resp) ACGIHD-LIMONENE5989-27-5
5-15 4400 mg/kg not available
ETHOXYLATED C11-C16 ALCOHOL127036-24-2
<3 oral rat: >500 mg/kg not available
CASTOR OIL8001-79-4
<3 not available not available
PROPYLENE GLYCOL57-55-6
<3 20 g/kg not available
III. PHYSICAL DATAPhysical State/Appearance: White cream with pumiceOdour & Odour Threshold: Citrus odourSpecific Gravity: 1.02Evaporation Rate: <1 (butyl acetate = 1)Vapour Pressure: Not determinedVapour Density: Heavier than airFreezing Point: Not determinedpH: 6.5-7.5Octanol/Water Coefficient: Not determinedBoiling Point: Not determined
IV. FIRE AND EXPLOSIVE DATARecommended Extinguishing Media: Water, Dry chemical, Carbon dioxide, FoamHazardous Combustion Products: None knownSensitivity to Static Discharge: Sensitivity to static discharge is not expected.Conditions of Flammability: None anticipated.Flash Point/Range: >95°C COCAutoignition Temperature: Not determinedUpper Explosive Limit: Not determinedLower Explosive Limit: Not determined
V. REACTIVITY DATAConditions Causing Chemical Instability: NoneMaterials to avoid: None reasonably foreseeableConditions of Reactivity: NoneHazardous Decomposition Products: None anticipated
VI. HAZARDS IDENTIFICATIONPrimary Routes of Exposure: Eye and skin contact, ingestion, inhalationToxicity Information: (See Effects of Acute Exposure to Product)Effects of Acute Exposure: None under normal conditions of use.
1 of 2
Permatex Canada, Inc.8450 Lawson Road, Unit 1Milton, ON Canada L9T 0A4Telephone: 1-87-Permatex(877) 376-2839Urgence: 800-255-3924 (ChemTel)
VI. HAZARDS IDENTIFICATIONEffects of Chronic Exposure: Estimated oral LD50 is greater than 5000 mg/kg. Primary irritation tests show that this product is not a
primary irritant..Irritancy of Product: None under normal conditions of use.Sensitization to Product: (See Effects of Acute Exposure to Product)Carcinogenicity: (See Effects of Chronic Exposure to Product)Reproductive Toxicity: (See Effects of Chronic Exposure to Product)Teratogenicity: (See Effects of Chronic Exposure to Product)Mutagenicity: (See Effects of Chronic Exposure to Product)Toxicologically Synergistic Products: None knownWHMIS Hazard Class: Non-controlled
VII. PREVENTATIVE MEASURESPersonal ProtectionEyes: Not required.Skin: Not necessary.Ventilation: None needed.Engineering Controls: No special precautions requiredSpill Procedures: Rinse away with water or wipe up with a towel.Protection of Man and Environment: Follow Canadian and local regulations for disposal.Handling Procedures and Equipment:No special precautions required.Special Handling Information: Hand cleaners should be stored at temperatures between 5 degrees C. and 37 degrees C.
VIII. FIRST AID MEASURESIngestion: If swallowed, DO NOT induce vomiting. Keep individual calm. Obtain medical attention.Inhalation: None reasonably foreseeable.Skin Contact: Flush with water.Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical
attention if irritation persists.
IX. SHIPPING INFORMATIONCanadian Transportation of Dangerous Goods
Proper Shipping Name: Not regulatedHazard Class: NoneUN/ID No: None
IATAProper Shipping Name: Not regulatedClass or Division: NoneUN/ID Number: None
IMDGProper Shipping: Not regulatedHazard Class: NoneUN Number: None
X. PREPARATION INFORMATIONEstimated HMIS Classification: HEALTH 1, FLAMMABILITY 1, PHYSICAL HAZARD 0HMIS is a registered trademark of the National Paint and Coatings Assn.
Estimated NFPA Rating: HEALTH 1, FLAMMABILITY 1 , REACTIVITY 0NFPA is a registered trademark of the National Fire Protection Assn.
Prepared By: Denise Boyd, Manager-Environmental, Health & SafetyRevision Date: October 28, 2010
Company:Permatex Canada, Inc. 8450 Lawson Rd. Unit 1, Milton, ON L9T 0A4
Revision Number: 6Telephone No.: 1-87-Permatex (877) 376-2839
2 of 2
Product Name: Item No: 20864PC FAST ORANGE PUMICE CREAM400GR
R.B. Howes & Co., Inc., 60 Ocean State Drive, North Kingstown, RI 02852, Tel: 1-800-438-9080 or 1-401-294-5500
U.S. SAFETY DATA SHEET
Howes Lubricator Diesel Treat Page 1 of 6
Section 1. PRODUCT AND COMPANY IDENTIFICATION
Product Name: Howes Lubricator Diesel Treat Part Number(s): 103060, 103061, 103062, 103064,
103065, 103066, 103068, 103070 Company Identification: R.B. Howes & Co., Inc. 60 Ocean State Drive North Kingstown, RI 02852 Tel: 800-438-9080 or 401-294-5500 Emergency Telephone Number: Chemtrec 1-800-424-9300 or 703-527-3887 (24 hours)
Section 2. HAZARDS IDENTIFICATION
Emergency Overview Combustible. Light amber oil-like liquid with distinctive odor. Prolonged or repeated skin contact may cause skin irritation. Ingestion harmful or fatal if not treated. Prolonged exposure to heavy concentrations of vapors may cause irritation to mucus membranes and airway. Respiratory diseases such as asthma and skin conditions such as rashes, cuts or similar skin diseases are generally aggravated by exposure. Do not handle near excessive heat, sparks, flame or strong oxidants. Incompatible with (material to avoid) strong oxidants like liquid chlorine or concentrated oxygen. This material could be a slipping hazard if spilled. OSHA Regulatory Status This product contains components that are considered to be hazardous under OSHA’s Hazard Communication Standard (29 CFR 1900.1200). Potential Health Effects Eye Contact: May cause redness and mild irritation. Skin Contact: Prolonged contact may cause mild irritation. Ingestion: Can cause cramps and nausea. Inhalation: Prolonged exposure may irritate the respiratory tract. Carcinogen: OSHA: no IARC: Ethylbenzene & Vinyl Acetate, Group 2B, possible human carcinogenic NTP: no
R.B. Howes & Co., Inc., 60 Ocean State Drive, North Kingstown, RI 02852, Tel: 1-800-438-9080 or 1-401-294-5500
U.S. SAFETY DATA SHEET
Howes Lubricator Diesel Treat Page 2 of 6
Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS # % by Volume Petroleum Distillates 64742-46-7 1.00 – 70.0 Aliphatic Hydrocarbon 8052-41-3 1.00 – 50.0 1,2,4 Trimethylbenzene 95-63-6 0.50 – 1.50 1,3,5 Trimethylbenzene 108-67-8 0.01 – 0.60 Trimethylbenzene 25551-13-7 0.01 – 0.30 Ethylbenzene 100-41-4 0.01 – 0.05 Vinyl Acetate 108-05-4 0.01 – 0.05
Section 4. FIRST AID MEASURES
Eye contact: Flush eyes with plenty of water for several minutes. Get medical attention if irritation persists. Skin contact: Wash skin with plenty of soap and water for several minutes. Get medical attention if irritation persists. Ingestion: Do not induce vomiting. Water may be given slowly. Contact physician immediately. Inhalation: If irritation or headache occurs, remove to fresh air. If signs/symptoms continue, get medical attention. Additionally: In all cases, if symptoms persist, contact physician.
Section 5. FIRE FIGHTING MEASURES
Flash point: 150°F / 65.5°C (Rapid Flash Point Closed-Cup, ASTM D3243) Autoignition temperature: Data not available. Upper flammable limit: Data not available. Lower flammable limit: Data not available. Extinguishing media: Foam, CO2, water fog or spray.
R.B. Howes & Co., Inc., 60 Ocean State Drive, North Kingstown, RI 02852, Tel: 1-800-438-9080 or 1-401-294-5500
U.S. SAFETY DATA SHEET
Howes Lubricator Diesel Treat Page 3 of 6
Fire fighting equipment: Recommend wearing self contained breathing apparatus. Avoid breathing vapors or fumes. Cool exposed containers with water spray. Unusual fire and explosion hazard: Combustible liquid. May form combustible mixtures at or above the flash point. Empty product containers may contain product residue. Do not pressurize, cut, heat, weld or expose containers to flame or other sources of ignition. National Fire Protection Association (NFPA) Flammability (red): 2 Health (blue): 1 Reactivity (yellow): 0 Special (white):
Section 6. ACCIDENTAL RELEASE MEASURES
Use appropriate personal protective equipment (PPE). (see section 8) Soak up the spill with oil absorbents, sand or other non-combustible material. Place residue in suitable, covered and properly labeled container. Dispose in accordance with federal, state and local laws.
Section 7. HANDLING AND STORAGE
Keep away from sources of ignition. Keep container closed when not in use.
Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
OSHA Permissible Exposure Limits (PEL’s); 8-hour Time Weighted Averages (TWA) Petroleum Distillates TWA: 2000 ppm Aliphatic Hydrocarbon TWA: 500 ppm
1,2,4 Trimethylbenzene TWA: 25 ppm 1,3,5 Trimethylbenzene TWA: 25 ppm Trimethylbenzene TWA: 25 ppm Ethylbenzene TWA: 100 ppm Vinyl Acetate TWA: 10 ppm
Engineering Controls Good general ventilation should be sufficient to control airborne levels.
R.B. Howes & Co., Inc., 60 Ocean State Drive, North Kingstown, RI 02852, Tel: 1-800-438-9080 or 1-401-294-5500
U.S. SAFETY DATA SHEET
Howes Lubricator Diesel Treat Page 4 of 6
Respiratory Protection Respirator use is not expected to be necessary under normal conditions of use. If application creates mist, wear a NIOSH approved respirator. Skin Protection For brief contact, no precautions other than wearing long sleeves should be needed. Use chemical resistant gloves such as neoprene. Eye/Face Protection Safety glasses with side shield, anti-splash goggles or face shield. Hygiene Recommendations Avoid breathing mist or vapor. Avoid contact with skin and eyes. Keep an eyewash kit available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse.
Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Light amber Odor: Distinctive Physical State: Liquid Flash: 150°F / 65.5°C (Rapid Flash Point Closed-Cup, ASTM D3243) VOC: 823 (g/l) pH: Not determined Vapor Pressure: <.1mm Hg Vapor Density: >1 (air = 1) Boiling Point: 327°F / 164°C Freezing Point: Not determined Solubility in Water: Insoluble Specific Gravity: <.9 (H2O = 1)
Section 10. STABILITY AND REACTIVITY
Chemical Stability: Stable under normal ambient temperature (70°F / 21°C) and pressure
(14.7 psi / 760 mmHg). Conditions to Avoid: Combustible when exposed to excessive heat, sparks, flames or strong
oxidants. Incompatible Materials: Contact with strong oxidizers like chlorine or concentrated oxygen. Hazardous Decomposition Products: Under fire conditions: Carbon oxides (CO, CO2) Hazardous Polymerization: Hazardous polymerization will not occur.
R.B. Howes & Co., Inc., 60 Ocean State Drive, North Kingstown, RI 02852, Tel: 1-800-438-9080 or 1-401-294-5500
U.S. SAFETY DATA SHEET
Howes Lubricator Diesel Treat Page 5 of 6
Section 11. TOXICOLOGICAL INFORMATION
Oral (rat) LD50 Dermal (rabbit) LD50 Inhalation (rat) LC50 Petroleum Distillates 5,000 mg/kg 3,000 mg/kg Aliphatic Hydrocarbon 5,000 mg/kg 3,000 mg/kg 5,500 mg/m3 1,2,4 Trimethylbenzene 5,000 mg/kg 3160 mg/kg 18,000 mg/m3 1,3,5 Trimethylbenzene 23,000 mg/kg 24,000 mg/m3 Trimethylbenzene 8,970 mg/kg Ethylbenzene 3,500 mg/kg 17,800 mg/kg 55,000 mg/m3 Vinyl Acetate 2,900 mg/kg 2,335 mg/kg 11,400 mg/m3
Section 12. ECOLOGICAL INFORMATION
No ecotoxicological studies have been conducted on this product.
Section 13. DISPOSAL CONSIDERATIONS
Waste management should be in compliance with federal, state and local laws.
Section 14. TRANSPORT INFORMATION
The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties and mode of transportation. 49 CFR §173.150(f) Exceptions for Class 3 flammable and combustible liquids. Howes part number(s): 103060, 103061, 103062, 103064, 103065, 103066, 103068, 103070 Non-bulk packaging (≤ 119 gal. liquid; ≤ 882 lbs. solid):
This product is non hazardous when packaged in non-bulk packaging. Howes part number(s): N/A
Bulk packaging (> 119 gal. liquid; > 882 lbs. solid): This product is hazardous when packaged in bulk packaging and the Proper Shipping Name would be:
Proper Shipping Name: Petroleum distillates, n.o.s. UN Identification Number: UN1268 Hazard Class – Primary: 3 Packing Group: III Flash Point: 150°F / 65.5°C
R.B. Howes & Co., Inc., 60 Ocean State Drive, North Kingstown, RI 02852, Tel: 1-800-438-9080 or 1-401-294-5500
U.S. SAFETY DATA SHEET
Howes Lubricator Diesel Treat Page 6 of 6
49 CFR §172.101 (Appendix B) List of Marine Pollutants This product is not a marine pollutant as defined in 49 CFR §171.8.
Section 15. REGULATORY INFORMATION
U.S. Regulations: Clean Air Act (CAA) 112(r) Accidental Release Prevention Substances: Vinyl Acetate. Clean Water Act (CWA) 307 Priority Pollutants: Ethylbenzene. Clean Water Act (CWA) 311 Hazardous Substances: Ethylbenzene, Vinyl Acetate. CERCLA 302 Hazardous Substances: Ethylbenzene RQ 1,000 lbs. Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986: (Known to cause cancer) Ethylbenzene. SARA 302/304 Emergency Planning and Notification Substances: No products were found. SARA 313 Toxic Chemical Notification: Ethylbenzene, 1,2,4 Trimethylbenzene, Vinyl Acetate. TSCA Inventory Status: All components are included or are exempted from listing on the US Toxic Substances Control Act Inventory.
Section 16. OTHER INFORMATION
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS) Health (Blue) 1 Flammability (Red) 2 Reactivity (Yellow) 0 Personal Protection (White) B SDS PREPARATION Prepared By: VP of Logistics Issue Date: July 5, 2012 Supersedes Date: August 26, 2011 The recommendations and data presented herein are based on sources considered to be reliable. Any use inconsistent with our recommendations may affect the risk characterization. However, no warranty is expressed or implied regarding the accuracy of the data or the results obtained from the use of this information or the use of the product. R.B. Howes & Co., Inc. expressly disclaims all liability for loss or damage, including consequential loss, or injury to persons (including death) arising directly or indirectly from reliance upon the information or misuse of the material.
Date Printed: 4/2/2012
Material Safety Data Sheet
24 Hour Assistance:
1-847-367-7700
Rust-Oleum Corp.
www.rustoleum.com
1. Identification
4/2/2012Product Name: ENAMEL 5-GL FLAT BLACK Revision Date:
Identification Number: 412300
Product Use/Class: Topcoat/Alkyd
Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA
Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA
Supplier: Manufacturer:
Preparer: Regulatory Department
2. Hazard Identification
EMERGENCY OVERVIEW: Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and respiratory tract. Combustible liquid and vapor. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. May cause headaches and dizziness. High vapor concentrations are irritating to the eyes, nose, throat and lungs.
EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause damage.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. Contains carbon black. Chronic inflammation, lung fibrosis, and lung tumors have been observed in some rats experimentally exposed for long periods of time to excessive concentrations of carbon black and several insoluble fine dust particles. Tumors have not been observed in other animal species (i.e., mouse and hamster) under similar circumstances and study conditions. Epidemiological studies of North American workers show no evidence of clinically significant adverse health effects due to occupational exposure to carbon black.
Carbon black is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC and is proposed to be listed as A4- "not classified as a human carcinogen" by the American Conference of Governmental Industrial Hygienists. Significant exposure is not anticipated during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of carbon black in the formula.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
3. Composition/Information On Ingredients
Chemical Name CAS-No.Weight %Less Than
ACGIH TLV-TWA
ACGIH TLV-STEL
OSHA PEL-TWAOSHA PEL-CEILING
Limestone 1317-65-3 50.03 mg/m3(Respirable)
N.E.5 mg/m3(Respirable)
N.E.
Stoddard Solvents 8052-41-3 20.0 100 ppm N.E. 500 ppm N.E.Mineral Spirits 64742-88-7 15.0 100 ppm N.E. 100 ppm N.E.Carbon Black 1333-86-4 5.0 3.5 mg/m3 N.E. 3.5 mg/m3 N.E.Xylene 1330-20-7 1.0 100 ppm 150 ppm 100 ppm N.E.
Page 1 / 4
Date Printed: 4/2/2012
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash with soap and water. Get medical attention if irritation develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation.
FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention.
5. Fire-fighting Measures
Flash Point, °F 104 (Setaflash)
EXTINGUISHING MEDIA: Dry Chemical, Foam, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Evacuate area and fight fire from a safe distance.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing vapor or mist. Avoid contact with eyes.
STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Keep away from heat, sparks, flame and sources of ignition. Keep container closed when not in use.
8. Exposure Controls/Personal Protection
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.
Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or in any other circumstances where air purifying respirators may not provide adequate protection.
SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking.
Page 2 / 4
Date Printed: 4/2/2012
9. Physical and Chemical Properties
Vapor Density HEAVIER THAN AIR Odor: Solvent Like
Appearance: Liquid Evaporation Rate: Slower than Ether
Solubility in Water: Slight Freeze Point: N.D.
Specific Gravity: 1.323 pH: N.A.
Physical State: Liquid
(See section 16 for abbreviation legend)
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid all possible sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological Information
Chemical Name LD50 LC50
Limestone N.E. N.E.
Stoddard Solvents >5000 mg/kg (Rat, Oral) N.E.
Mineral Spirits >5000 mg/kg (Rat, Oral) >1400 ppm (Rat, Inhalation, 4Hr)
Carbon Black >8000 mg/kg (Rat, Oral) N.E.
Xylene 4300 mg/kg (Rat, Oral) 5000 ppm (Rat, Inhalation, 4Hr)
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow to enter storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) Air (IATA)International (IMDG)
Proper Shipping Name: Not Regulated Paint Paint
Hazard Class: N.A. 3 3
UN Number: N.A. UN1263 UN1263
Packing Group: N.A. III III
Limited Quantity: No No No
15. Regulatory Information
Page 3 / 4
Date Printed: 4/2/2012
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of theSuperfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, tomeet the following categories:
Fire Hazard, Chronic Health Hazard
SARA SECTION 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of theSuperfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported fromthe United States:
No TSCA 12(b)components exist in this product.
International Regulations:
CANADIAN WHMIS:
This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
Canadian WHMIS Class: B3 D2A
16. Other Information
HMIS Ratings:
Health: 2* Flammability: 2 Physical Hazard: 0 Personal Protection: X
NFPA Ratings:
Health: 2 Flammability: 2 Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L: 404
REASON FOR REVISION: Regulatory Update
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to beaccurate and reliable as of the date of this material safety data sheet. However, because the conditions of handling, use, andstorage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damageincurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracyor reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used withcaution. The information and recommendations in this material safety data sheet are offered for the users’ consideration andexamination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicableinternational, federal, state, and local laws and regulations.
Page 4 / 4
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
RAID MOSQUITO COILS (REG NO 22672 P.C.P. ACT)
Version 1.1 Print Date 10/17/2011
Revision Date 09/01/2011 MSDS Number 350000004239 SITE_FORM Number 30000000000000003564.001
1/5
1. PRODUCT AND COMPANY IDENTIFICATION
Product information
Trade name : RAID MOSQUITO COILS (REG NO 22672 P.C.P. ACT)
Use of the Substance/Mixture
: Insect Repellent
Company : S.C. Johnson and Son, Limited 1 Webster Street Brantford ON N3T 5R1
Emergency telephone number
: 24 Hour Transport & Medical Emergency Phone (866) 231-5406 24 Hour International Emergency Phone (952) 852-4647 24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666
2. HAZARDS IDENTIFICATION
Emergency Overview Appearance / Odor : blue / solid / mild pleasant
Immediate Concerns
:
Potential Health Effects
3. COMPOSITION/INFORMATION ON INGREDIENTS
This product does not contain hazardous chemicals at or above a reportable level as defined by OSHA 29 CFR 1910.1200 or Canadian Controlled Products Regulations. For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES
5. FIREFIGHTING MEASURES
Flash point : Note: no data available
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
RAID MOSQUITO COILS (REG NO 22672 P.C.P. ACT)
Version 1.1 Print Date 10/17/2011
Revision Date 09/01/2011 MSDS Number 350000004239 SITE_FORM Number 30000000000000003564.001
2/5
Lower explosion limit : Note: no data available
Upper explosion limit : Note: no data available
6. ACCIDENTAL RELEASE MEASURES
7. HANDLING AND STORAGE
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
9. PHYSICAL AND CHEMICAL PROPERTIES
Form : solid
Color : blue
Odor : mild pleasant
pH : not applicable
Boiling point : not applicable
Freezing point : not applicable
Flash point : no data available
Evaporation rate : not applicable
Autoignition temperature : not applicable
Lower explosion limit : no data available
Upper explosion limit : no data available
Vapour pressure : not applicable
Density : no data available Water solubility : not applicable
Partition coefficient: n-octanol/water
: not applicable
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
RAID MOSQUITO COILS (REG NO 22672 P.C.P. ACT)
Version 1.1 Print Date 10/17/2011
Revision Date 09/01/2011 MSDS Number 350000004239 SITE_FORM Number 30000000000000003564.001
3/5
Volatile Organic Compounds Total VOC (wt. %)*
: 0 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations
10. STABILITY AND REACTIVITY
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity : LD50 > 5,000 mg/kg
Acute inhalation toxicity : LC50 > 1.1 mg/l
Acute dermal toxicity : LD50 > 2,000 mg/kg
Chronic effects Carcinogenicity : no data available
Mutagenicity : None Anticipated Reproductive effects : no data available
Teratogenicity : no data available
Sensitisation : no data available
12. ECOLOGICAL INFORMATION
Ecotoxicity effects : no data available 13. DISPOSAL CONSIDERATIONS
14. TRANSPORT INFORMATION
Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
RAID MOSQUITO COILS (REG NO 22672 P.C.P. ACT)
Version 1.1 Print Date 10/17/2011
Revision Date 09/01/2011 MSDS Number 350000004239 SITE_FORM Number 30000000000000003564.001
4/5
15. REGULATORY INFORMATION
Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA).
: This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.
16. OTHER INFORMATION
HMIS Ratings Health 1
Flammability 1
Reactivity 0
NFPA Ratings Health 1
Fire 1
Reactivity 0
Special -
Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by: SC Johnson Global Safety Assessment &
Regulatory Affairs (GSARA)
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
RAID MOSQUITO COILS (REG NO 22672 P.C.P. ACT)
Version 1.1 Print Date 10/17/2011
Revision Date 09/01/2011 MSDS Number 350000004239 SITE_FORM Number 30000000000000003564.001
5/5
MSDS: CALCIUM LIME AND RUST REMOVER Page 1 of 2 Revision Date: 3/06/12
MATERIAL SAFETY DATA SHEET from STEARNS PACKAGING CORPORATION
SECTION I—PRODUCT/MANUFACTURER’S IDENTITY
HAZARD RATING 4 = Extreme
0 Flammability 3 = High
2 Health 2 = Moderate
0 Reactivity 1 = Slight
None Special Hazard 0 = Insignificant
IDENTITY (As Used On Label and List): Calcium, Lime & Rust Remover SYNONYMS: ST-1257 FORMULA ID NUMBER: AM10 EPA REG #: None NSF CERTIFIED: None
COMPANY: STEARNS PACKAGING CORPORATION ADDRESS: 4200 Sycamore Ave. (53714), PO Box 3216 Madison, Wisconsin (WI) 53704-0216 PHONE: 1 (608) 246–5150 FAX: 1 (608) 246–5149 INTERNET: www.stearnspkg.com EMAIL: stearns@stearnspkg.com
For Transportation Emergency Involving Hazardous Materials Contact: CHEM-TEL 1 (800) 255–3924 Shipping Information: DOT SHIPPING NAME: NA1760, Compounds, cleaning liquid, (containing phosphoric acid), 8, PG III, Ltd Qty. Item 48580, Sub 3, Class 55 DOT SHIPPING NUMBER: NA1760 HAZARD LABEL: NA1760, Compounds, cleaning liquid, (containing phosphoric acid), 8, PG III, Ltd Qty. No diamond required for PG III, Ltd Qty HAZARD CLASS: 8, Corrosive
SECTION II—HAZARDOUS INGREDIENTS OR IDENTITY INFORMATION HAZARDOUS CHEMICAL IDENTITY &
CAS# HAZARD OSHA PEL ACGIH TLV OTHER LIMITS % (OPTIONAL)
▶ Phosphoric acid 7664-38-2
Corrosive 1 mg/cu m 1 mg/cu m 3 mg/cu m (STEL) 42.25
SARA SECTION 313 TITLE III NOTIFICATION REQUIRED: No; CHEMICAL IN PRODUCT: N/A; CAS#: N/A; WEIGHT % OF CHEM: N/A
SECTION III—PHYSICAL/CHEMICAL CHARACTERISTICS
BOILING POINT: 111ºC VAPOR PRESSURE (mm Hg): 0.03 mm Hg @20ºC SPECIFIC GRAVITY (WATER=1): 1.279 VAPOR DENSITY (AIR=1): Not Determined MELTING POINT: Not Applicable EVAPORATION RATE: Not Determined
SOLUBILITY IN WATER: Infinite pH (CONCENTRATE): 0.5 APPEARANCE AND ODOR: Light orange, clear liquid,
Slight acid odor pH (1% SOLUTION): 1.65 – 1.74
SECTION IV—FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (METHOD USED): Non-combustible, >200ºF
EXTINGUISHING MEDIA: CO2, water, dry chemical
FLAMMABLE LIMITS: LEL: Not Applicable UEL: Not Applicable
SPECIAL FIRE FIGHTING PROCEDURES:
Use full protective clothing and self-contained breathing apparatus. Thermal decomposition emits toxic fumes of oxides of phosphorous.
FIRE & EXPLOSION HAZARDS: None
SECTION V—REACTIVITY DATA
STABILITY: Stable INCOMPATIBILITY (MATERIALS TO AVOID):
None known
HAZARDOUS DECOMPOSITION OR BYPRODUCTS: None known CONDITIONS TO AVOID: Freezing and extremes of heat HAZARDOUS POLYMERIZATION: Will not occur
MSDS: CALCIUM LIME AND RUST REMOVER Page 2 of 2 Revision Date: 3/06/12
SECTION VI—HEALTH HAZARD DATA/FIRST AID PROCEDURES
HEALTH HAZARDS (ACUTE AND CHRONIC): Irritation or corrosion may occur to exposed tissues, especially eyes, skin, throat, nasal cavities and other mucous membranes from contact with the product, its use solutions, or mists and vapors generated by the product. Eye contact may cause blindness. Ingestion may be harmful or fatal.
CARCINOGENICITY: NTP: No IARC Monographs: No OSHA Regulated: No SIGNS AND SYMPTOMS OF OVEREXPOSURE: Irritation of exposed tissues. Chronic exposure causes burns. Eyes, skin and mucous membranes may
be simultaneously irritated or burned if exposed to mists of phosphoric acid solutions. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: No data available. EMERGENCY AND FIRST AID PROCEDURES: Eyes: If contact with eyes occurs, flush with plenty of cool water for 15 minutes. Consult a physician. Skin: May be irritating to skin. If contact occurs, flush with water and wear gloves in the future to minimize exposure. Wash hands
thoroughly after handling. Discontinue use if irritation persists and consult a physician. Inhalation: Remove from exposure. Obtain medical attention immediately. Ingestion: May be harmful if swallowed. If ingested, drink large amounts of water or milk. DO NOT induce vomiting. Get medical attention
immediately. Avoid contamination of foods. Note to Physician: Extremely corrosive agent which will burn any exposed tissues upon other than very brief contact. Eyes, skin, and mucous
membranes should be flushed thoroughly with water, and ophthalmologic consultation should be obtained for any corneal burns. In case of ingestion, immediate dilution with water, milk or demulcent liquids is worthwhile, but attempts to neutralize with a base should be avoided because of excessive base and heat formation, which may increase the threat of esophagogastric perforation. Vomiting and diarrhea (laxative effect of phosphates) are to be expected with large doses. Parenteral fluid administration may be needed if losses therefrom are severe, or if shock ensues. Supportive care may be needed for such other complications as glottal edema, hematemesis and perforation (unlikely). Induced vomiting should be avoided because local tissue injury may be aggravated, but the patient should be watched hyperphospatemia and hypocalcemia. Milk or other demulcent liquids may be worthwhile for gastric irritation.
SECTION VII—PRECAUTIONS FOR SAFE HANDLING AND USE
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Wear acid-resistant suit and complete protective equipment including rubber gloves, boots, chemical goggles and faceshield. Small spills: mop up and dispose of in DOT-approved waste containers. Large spills: Contain by diking with soil or other absorbent material and carefully neutralize with soda ash or lime. If soda ash is used, provide adequate ventilation to dissipate carbon dioxide gas. Keep unneutralized material out of sewers, storm drains, surface waters, and soil.
WASTE DISPOSAL METHOD: Waste disposal must be done in accordance with all local, city or municipality, county, state, and federal regulations. Consult your state department of natural resources or the EPA for specific questions not answerable through other sources. Wastewater should never enter a fresh water body without treatment. If material cannot be salvaged, an acceptable method of disposal is neutralization followed by discharge into treatment system with large amounts of water..
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store in a dry, well-ventilated place above 50ºF. Store away from all other chemicals and potential sources of contamination. Do not use pressure to empty container. Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing.
OTHER PRECAUTIONS: Empty containers may have residues, gases, and mists, and are subject to proper waste disposal, as above. Always obey hazard warnings and handle empty containers as if they were full. Always keep product out of the reach of children.
SECTION VIII—OTHER REGULATORY INFORMATION
California Safe Drinking Water and Toxic Enforcement Act of 1986: Ethylene oxide 75-21-8 1,4 Dioxane 123-91-1 TSCA Inventory Status: All ingredients used in Calcium, Lime and Rust Remover are listed on the TSCA inventory.
SECTION IX—CONTROL MEASURES
RESPIRATORY PROTECTION: In general, respirators are not needed if the product is used in a well-ventilated area. However, use of a NIOSH/MSHA respirator may be a good common sense approach to working with products where dusts and mists are known to cause irritation of the eyes and/or mucous membranes.
VENTILATION: Local Exhaust: Recommended to control below TLV of 1 ppm for phosphoric acid.
Mechanical (General): Recommended to control below TLV of 1 ppm for phosphoric acid.
SKIN PROTECTION: Neoprene, rubber, or other chemical resistant gloves. Wear protective clothing to prevent repeated or prolonged contact.
EYE PROTECTION: Splash goggles, or safety glasses if splashing is not a concern. WORK/HYGIENIC PRACTICES: As good hygiene dictates.
Stearns Packaging Corporation makes no warranty, representation or guarantee as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of this product. Since actual use by others is beyond our control, no warranty, expressed or implied, is made by Stearns Packaging Corporation as to the effects of such use, the results to be obtained or the safety and toxicity of this product, nor does Stearns Packaging Corporation assume any liability arising out of the use by others of this product referred to herein. The data in this MSDS relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Stearns Packaging Corporation does not recommend blending this product with any other chemicals. All information, recommendations and data contained herein concerning this product are based upon information available at the time of writing from recognized technical sources.
The Clorox Company 1221 Broadway Oakland, CA 94612 Tel. (510) 271-7000
Material Safety Data Sheet
I Product: ORIGINAL PINE-SOL BRAND CLEANER
Description: CLEAR AMBER LIQUID WITH CHARACTERISTIC PINE ODOR
Other Designations Distributor Emergency Telephone Nos.
EPA Reg. No. 5813-54 Clorox Sales Company
1221 Broadway Oakland, CA 94612
For Medical Emergencies, call 1-800-446-1014
For Transportation Emergencies, call
Chemtrec 1-800-424-9300
II Health Hazard Data III Hazardous Ingredients Eye irritant. May cause skin irritation. Avoid contact with food. No medical conditions are known to be aggravated by exposure to this product. FIRST AID: EYE CONTACT: Immediately flush eyes with plenty of water. If irritation persists, call a physician. INGESTION: Do not induce vomiting. Promptly drink a large amount of milk or water. Call a physician. SKIN CONTACT: Wash skin with water. If irritation persists, call a physician. INHALATION: Remove to fresh air. If breathing problems develop, call a physician.
Ingredient Concentration Worker Exposure Limit Pine oil 10 - 20% Not established. CAS # 8002-09-3
Isopropyl alcohol 4 - 7% 400 ppm - TLV-TWAa CAS #67-63-0 400 ppm - PELb 500 ppm - TLV-STELc Alkyl alcohol ethoxylates 2 - 6% Not established. CAS # 66455-15-0
aTLV-TWA = ACGIH Threshold Limit Value - Time Weighted Average bPEL = OSHA Permissible Exposure Limit - Time Weighted Average cTLV-STEL = ACGIH Threshold Limit Value - Short Term Exposure Limit None of the materials in this product are on the IARC, OSHA, or NTP carcinogen lists.
IV Special Protection and Precautions V Transportation and Regulatory Data Hygienic Practices: Wash hands after direct contact. Do not wear product-contaminated clothing for prolonged periods. Engineering Controls: Use local exhaust to minimize exposure to product mist. Personal Protective Equipment: Wear safety glasses. Wear rubber or neoprene gloves if there is the potential for repeated or prolonged skin contact.
DOT: Not restricted per 49 CFR 173.120(a)(3) and Appendix H.
IMDG: Not restricted per IMDG Code Page 0016 Paragraph 5.1.3.1.1.
IATA: Not restricted per IATA D.G.R. Sections 3.3.1.2 and 3.3.5.
EPA - SARA Title III/CERCLA: This product is regulated under Sections 311/312. This product contains no chemicals which are regulated under Section 313 and contains sodium dodecylbenzenesulfonate (CAS #25155-30-0, <4%), ammonium hydroxide (CAS #1336-21-6, <1%), benzoic acid (CAS #65-85-0, <1%) and glycol ethers (<1%) which are regulated under Section 304/CERCLA.
VI Spill Procedures/Waste Disposal VII Reactivity Data Spill Procedures: Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material. Waste Disposal: Dispose of in accordance with all applicable federal, state, and local regulations.
Stable under normal use and storage conditions.
VIII Fire and Explosion Data IX Physical Data Flash Point: 105° F (Setaflash closed cup).
Fire Extinguishing Agents: Dry chemical, carbon dioxide (CO2), foam, or water spray.
pH...................................................................................................... 3.0 - 4.0
Specific gravity......................................................................................... ~1.0
Solubility in water .................................................................................Soluble
1963, 1991 THE CLOROX COMPANY DATA SUPPLIED IS FOR USE ONLY IN CONNECTION WITH OCCUPATIONAL SAFETY AND HEALTH DATE PREPARED 4/01
Safety Data Sheet
Propane
Synonyms: Dimethylmethane, Liquefied Petroleum Gas (LPG), Sales Propane, Commercial Propane, Refinery Propane, Product Propane (non-odorized)
____________________________________________________________
GHS Classification:
Signal Word
Danger Hazard Statements
Precautionary Statements
Chemical Name:
Section 1 - Chemical Product and Company Identification
Section 2 - Hazards Identification
Company Information Product Information Product: Propane (odorized)Chemical Name: Propane Chemical Family: Liquified Petroleum Gas (Paraffinic Hydrocarbons) Chemical Formula: C3H8
GHS LABEL ELEMENTS Pictogram(s)
H220 - Extremely flammable gas. H280 - Contains gas under pressure, may explode if heated.
Prevention P210 - Keep away from heat/sparks/open flames/hot surfaces. No smokingResponseP376 - Stop leak if safe to do so.P377 - Leaking gas fire: Do not extinguish, unless leak can be stopped safely.P381 - Eliminate all ignition sources if safe to do so.Storage P403 - Store in a well-ventilated place.P405 - Store locked up.P410 - Protect from sunlight.Disposal P501 - Dispose of contents/container in accordance with local/regional/national/international regulations.
Flammable Gas - Category 1 Gases Under Pressure - Liquefied Gas
Ferrellgas (Blue Rhino) One Liberty Plaza Liberty, MO 64068 Emergency # 800-424-9300 (CHEMTREC)General SDS assistance # 855-738-9178 (Ferrellgas Safety Department)
Page 1 of 8 Revision Date 11/2014
Safety Data Sheet
Material Name: Propane
____________________________________________________________
First Aid: Eyes
First Aid: Skin
Remove contaminated clothing. In case of blistering, frostbite or freeze burns seek immediate medical attention. First Aid: Ingestion
Risk of ingestion is extremely low. However, if oral exposure occurs, seek immediate medical assistance. First Aid: Inhalation
Remove person to fresh air. If person is not breathing, provide artificial respiration. If necessary, provide additional oxygen once breathing is restored if trained to do so. Seek medical attention immediately.
General Fire Hazards See Section 9 for Flammability Properties. Liquid releases flammable vapors at well below ambient temperatures and readily forms a flammable mixture with air. Dangerous fire and explosion hazard when exposed to heat, sparks or flame. Vapors are heavier than air and may travel long distances to a point of ignition and flash back.
Hazardous Combustion Products Carbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke).
Extinguishing Media Use extinguishing media suitable for the surrounding material, preferably or, any extinguisher suitable for Class B fires, dry chemical, fire fighting foam, CO2, and other gaseous agents. However, fire should not be extinguished unless flow of gas can be immediately stopped.
Unsuitable Extinguishing Media None
Section 3 - Composition / Information on Ingredients
Section 4 - First Aid Measures
Direct contact with liquid propane can result in eye burns.
Cover eyes to protect from light. Seek immediate medical attention. In case of contact with eyes, hold eyelids open to allow liquid to evaporate and gently flush with lukewarm water.
Direct contact with liquid propane can result in skin burns (frostbite).
This product is classified as a simple asphyxiant. High vapor concentrations may produce a reversiblecentral nervous system depression (anesthesia) and asphyxiation.
Section 5 - Fire Fighting Measures
Page 2 of 8 Revision Date 11/2014
CAS # Component Percent74-98-6 Propane 85 - 100 106-97-8 Butane and heavier 0 - 2.5 74-84-0 Ethane 0 - 5 115-07-1 Propylene 0 - 10 75-08-1 Ethyl Mercaptan 0 - 0.0025
Safety Data Sheet
Material Name: Propane Fire Fighting Equipment/Instructions
Gas fires should not be extinguished unless flow of gas can be immediately stopped. Shut off gas source and allow gas to burn out. If spill or leak has not ignited, determine if water spray may assist in dispersing gas or vapor to protect personnel attempting to stop leak. Use water to cool equipment, surfaces and containers exposed to fire and excessive heat. For large fire the use of unmanned hose holders or monitor nozzles may be advantageous to further minimize personnel exposure. Isolate area, particularly around ends of storage vessels. Let vessel, tank car or container burn unless leak can be stopped. Withdraw immediately in the event of a rising sound from a venting safety device. Large fires typically require specially trained personnel and equipment to isolate and extinguish the fire. Firefighting activities that may result in potential exposure to high heat, smoke or toxic by-products of combustion should require NIOSH- approved pressure-demand self-contained breathing apparatus with full facepiece and full protective clothing.
Recovery and Neutralization Stop the source of the release, if safe to do so.
Materials and Methods for Clean-Up Do not flush down sewer or drainage systems. Do not touch spilled liquid (frostbite/freeze burn hazard!). Consider the use of water spray to disperse vapors. Isolate the area until gas has dispersed. Ventilate and gas test area before entering.
Emergency Measures Evacuate nonessential personnel and secure all ignition sources. No road flares, smoking or flames in hazard area. Consider wind direction, stay upwind and uphill, if possible. Evaluate the direction of product travel. Vapor cloud may be white, but color will dissipate as cloud disperses - fire and explosion hazard is still present!
Personal Precautions and Protective Equipment Do not touch spilled liquid (frostbite/freeze burn hazard!).
Environmental Precautions Do not flush down sewer or drainage systems.
Prevention of Secondary Hazards None
Handling Procedures
Storage Procedures
Incompatibilities Keep away from strong oxidizers, ignition sources and heat. Explosion hazard when exposed to chlorine dioxide. Heating barium peroxide with propane causes violent exothermic reaction. Heated chlorine-propane mixtures are explosive under some conditions.
Section 6 - Accidental Release Measures
Section 7 - Handling and Storage
Keep away from flame, sparks, ingnition sources and excessive temperatures. Use only in well ventilated areas.
Store only in approved containers. Keep away from flame, sparks, excessive temperatures and open flame. Keep containers closed and clearly labeled. Empty product containers or vessels may contain explosive vapors. Do not pressurize, cut, heat, weld or expose such containers to sources of ignition.
____________________________________________________________ Page 3 of 8 Revision Date 11/2014
Safety Data Sheet
Material Name: Propane
____________________________________________________________
Component Exposure Limits Propane (74-98-6)
ACGIH: 1000 ppm TWA (listed under Aliphatic hydrocarbon gases: Alkane C1-4) OSHA: 1000 ppm TWA; 1800 mg/m3 TWA
NIOSH: 1000 ppm TWA; 1800 mg/m3 TWA Ethane (74-84-0)
ACGIH: 1000 ppm TWA (listed under Aliphatic hydrocarbon gases: Alkane C1-4) Propylene (115-07-1)
ACGIH: 500 ppm TWA
Engineering Measures Use adequate ventilation to keep gas and vapor concentrations of this product below occupational exposure and flammability limits, particularly in confined spaces. Use explosion-proof equipment and lighting in classified/controlled areas.
Personal Protective Equipment: Respiratory Use a NIOSH approved positive-pressure, supplied air respirator with escape bottle or self-contained breathing apparatus (SCBA) for gas concentrations above occupational exposure limits, for potential for uncontrolled release, if exposure levels are not known, or in an oxygen-deficient atmosphere. CAUTION: Flammability limits (i.e., explosion hazard) should be considered when assessing the need to expose personnel to concentrations requiring respiratory protection.
Personal Protective Equipment: Hands Use cold-impervious, insulating gloves where contact with liquid may occur.
Personal Protective Equipment: Eyes
Personal Protective Equipment: Skin and Body Where contact with liquid may occur, wear apron and faceshield.
Appearance: Colorless Odor: Odorless
Physical State: Gas pH: ND
Solubility (H2O): Specific Gravity:
Section 8 - Exposure Controls / Personal Protection
Section 9 - Physical & Chemical Properties
1.52 (Air = 1) -43.8°F (-42.1°C) Molecular Weight:Boiling Point: 44.096slight (0.1 to 1.0%)
Expansion Ratio: 1 to 270 (from liquid to gas @ 14.7 psia)
Where there is a possibility of liquid contact, wear splash-proof safety glasses and faceshield.
208 psig @ 100 °F (37.8 °C) 1.56 @ 32°F (0°C) Max Vapor Pressure: Vapor Density:
Burning Rate: ND Evaporation Rate: ND VOC: ND
Octanol/H2O Coeff.: ND Flash Point: -156°F (-104 °C) Flash Point Method: PMCC Auto Ignition: 842°F (450°C)
Upper Flammability Limit (UFL): 9.6%Lower Flammability Limit (LFL): 2.15%
Page 4 of 8 Revision Date 11/2014
Safety Data Sheet
Material Name: Propane
Chemical Stability This is a stable material.
Will not occur. Conditions to Avoid
Keep away from strong oxidizers, ignition sources and heat. Incompatible Products
Explosion hazard when exposed to chlorine dioxide. Heating barium peroxide with propane causes violent exothermic reaction. Heated chlorine-propane mixtures are explosive under some conditions.
Hazardous Decomposition Products
Acute Toxicity A: General Product Information
Propane exhibits some degree of anesthetic action and is mildly irritating to the mucous membranes. At high concentrations propane acts as a simple asphyxiant without other significant physiological effects. High concentrations may cause death due to oxygen depletion.
Potential Health Effects: Skin Corrosion Property/Stimulativeness Vapors are not irritating. Direct contact to skin or mucous membranes with liquefied product or cold vapor may cause freeze burns and frostbite. Contact to mucous membranes with liquefied product may cause frostbite and freeze burns. Signs of frostbite include a change in the color of the skin to gray or white, possibly followed by blistering. Skin may become inflamed and painful.
Potential Health Effects: Eye Critical Damage/ Stimulativeness Vapors are not irritating. However, contact with liquid or cold vapor may cause frostbite, freeze burns, and permanent eye damage.
Potential Health Effects: Ingestion Ingestion is unlikely. Contact with mucous membranes with liquefied product may cause frostbite and freeze burns.
Section 10 - Chemical Stability & Reactivity Information
Section 11 - Toxicological InformationCarbon monoxide, carbon dioxide and non-combusted hydrocarbons (smoke) may be formed during combustion.
Hazardous Polymerization
Potential Health Effects: Inhalation This product is considered to be non-toxic by inhalation. Inhalation of high concentrations may cause central nervous system depression such as dizziness, drowsiness, headache, and similar narcotic symptoms, but no long-term effects. Numbness, a "chilly" feeling, and vomiting have been reported from accidental exposures to high concentrations. This product is a simple asphyxiant. In high concentrations it will displace oxygen from the breathing atmosphere, particularly in confined spaces. Signs of asphyxiation will be noticed when oxygen is reduced to below 16%, and may occur in several stages. Symptoms may include rapid breathing and pulse rate, headache, dizziness, visual disturbances, mental confusion, incoordination, mood changes, muscular weakness, tremors, cyanosis, narcosis and numbness of the extremities. Unconsciousness leading to central nervous system injury and possibly death will occur when the atmospheric oxygen concentration is reduced to about 6% to 8% or less. WARNING: The burning of any hydrocarbon as a fuel in an area without adequate ventilation may result in hazardous levels of combustion products, including carbon monoxide, and inadequate oxygen levels, which may cause unconsciousness, suffocation, and death.
____________________________________________________________ Page 5 of 8 Revision Date 11/2014
Safety Data Sheet
Material Name: Propane Respiratory Organs Sensitization/Skin Sensitization
This product is not reported to have any skin sensitization effects. Generative Cell Mutagenicity
This product is not reported to have any mutagenic effects. Carcinogenicity A: General Product Information
This product is not reported to have any carcinogenic effects.
Reproductive Toxicity This product is not reported to have any reproductive toxicity effects.
Specified Target Organ General Toxicity: Repeated Exposure This product is not reported to have any specific target organ repeat effects.
Aspiration Respiratory Organs Hazard This product is not reported to have any aspiration hazard effects.
Ecotoxicity A: General Product Information
Liquid release is only expected to cause localized, non-persistent environmental damage, such as freezing. Biodegradation of this product may occur in soil and water. Volatilization is expected to be the most important removal process in soil and water. This product is expected to exist entirely in the vapor phase in ambient air.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Section 12 - Ecological Information
No ecotoxicity data is available for this product's components.
Persistence/Degradability No information available.
Bioaccumulation No information available.
Mobility in Soil No information available.
Waste Disposal Instructions See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations.
Disposal of Contaminated Containers or Packaging Dispose of contents/container in accordance with local/regional/national/international regulations.
____________________________________________________________
Section 13 - Disposal Considerations
DOT Information
Section 14 - Transportation Information
UN #: 1075 or 1978 Hazard Class: 2.1 Shipping Name: Petroleum Gases, Liquefied Placard:
Page 6 of 8 Revision Date 11/2014
Safety Data Sheet
Regulatory Information
Component Analysis This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4). Propylene (115-07-1)
SARA 313: 1.0 % de minimis concentration SARA Section 311/312 – Hazard Classes
Acute Health Chronic Health Fire Sudden Release of Pressure Reactive -- -- X X --
SARA SECTION 313 - SUPPLIER NOTIFICATION This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372:
INGREDIENT NAME (CAS NUMBER) CONCENTRATION PERCENT BY VOLUME Propylene (115-07-1) 30 max
State Regulations
Propylene 115-07-1 Yes DSL EINECS Ethane 74-84-0 Yes DSL
Yes DSL
Component Analysis - Inventory
Additional Regulatory Information No components are listed in the WHMIS IDL.
Component Analysis - WHMIS IDL
The following components appear on one or more of the following state hazardous substances lists:
Component Analysis - State
Material Name: Propane
Section 15 - Regulatory Information
Component CAS CA MA MN NJ PA RI
____________________________________________________________ Page 7 of 8 Revision Date 11/2014
Component CAS # TSCA CAN EUEINECS
Propane 74-98-6 EINECS
Propane 74-98-6 No Yes Yes Yes Yes YesEthane 74-84-0 No Yes Yes Yes Yes YesPropylene 115-07-1 Yes Yes Yes Yes Yes Yes
Safety Data Sheet
Material Name: Propane
____________________________________________________________
* * * Section 16 - Other Information * * * NFPA® Hazard Rating Health 2
Fire 4 Reactivity 0
HMIS® Hazard Rating Health 2 Moderate Fire
hysical 4
Severe P 0 Minimal
4
Key/Legend
Literature References None
Other Information Information presented herein has been compiled from sources considered to be dependable, and is accurate and reliable to the best of our knowledge and belief, but is not guaranteed to be so. Since conditions of use are beyond our control, we make no warranties, expressed or implied, except those that may be contained in our
ritten contract of sale or acknowledgment. wVendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if
Issue Information
reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material, even if reasonable safety procedures are followed. Furthermore, vendee assumes the risk in their use of the material.
FerrellgasOne Liberty PlazaLiberty, MO 64068
This Safety Data Sheet supersedes all previous editions.
2 0
Page 8 of 8 Revision Date 11/2014
Issued: November, 2014Issued by: Ferrellgas Safety Department
EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration., NJTSR = New Jersey Trade Secret Registry; TSCA = Toxic Substance Control Act; EU = European Union; CAN = Canada
SECTION 1 - PRODUCT INFORMATION
Product Identifier: 70-052 BREEZE EXTERIOR FLAT-ACCENT BASE
Product Use: Protective Coating
Manufacturer's Name: General Paint Corp. Supplier's Name: General Paint Corp.
Street Address: 950 Raymur Ave Street Address: 950 Raymur Ave
City: Vancouver Province: BC City: Vancouver Province: BC
Postal Code: V6A 3L5
Emergency Phone: (604) 253-4022
Postal Code: V6A 3L5
Emergency Phone: (604) 253-4022
SECTION 2 - HAZARDOUS INGREDIENTS
Hazardous Ingredients(Specific)
% CAS Number
LD 50 of Ingredient(Specify
species,route)
LC 50 of Ingredient(Specify
species)
TITANIUM DIOXIDE 1.63 - 1.86 13463-67-7 NOT AVAILABLE NOT AVAILABLE
PROPYLENE GLYCOL 1.68 - 1.7 57-55-6 20000 MG/KG(ORAL, RAT)
NOT AVAILABLE
SECTION 3 - PHYSICAL DATA
Physical State: Liquid
Odour and Appearance: liquid with a slight ammonia smell
Coating VOC(gm/l): 96
Odour Threshold(ppm): Not Available
Specific Gravity: 1.32
Vapor Density(air=1): Not Available
Vapor Pressure(mmHg): Not Available
Evaporation Rate: Not Available
Boiling Point(º C ): Greater than 100°C
Freezing Point(º C ): Less than 0°C
pH: 8.5-9.5
Coefficient of Water/Oil Distribution: Not Available
SECTION 4 - FIRE AND EXPLOSION DATA
Flammability:No If yes, Under which Conditions?Not Applicable
Means of Extinction: Alcohol foam, Carbon dioxide, Dry chemical powder, Polymer foam
Flashpoint and Method: "Not Applicable
Upper Flammable Lt (% by Volume):Not Applicable
Lower Flammable Lt (% by Volume):Not Applicable
Autoignition Temperature: Not Applicable
Explosion Data - Sensitivity to Impact: No
Explosion Data - Sensitivity to Static discharges: No
Hazardous Combustion Pdts:nitrogen oxides, carbon dioxide, carbon monoxide
SECTION 5 - REACTIVITY DATA
Chemical Stability:Stable If Yes, Under which Conditions?Not Applicable
Incompatibility with other substances:Yes
If yes, which ones? Strong Acids Strong Oxidizing agents Strong Bases
Reactivity, and under what conditions?heat, generation of dust, temperatures above 320°c
Hazardous Decomposition Products:oxides of nitrogen, ammonia, aldehydes
SECTION 6 - TOXICOLOGICAL PROPERTIES
Route of Entry
Skin Contact: Yes Absorption: Yes
Eye Contact: Yes
Inhalation: Yes Ingestion: Yes
Effects to Acute exposure to Product: Insufficient Data
Effects to Chronic exposure to Product: PROPYLENE GLYCOL has been known to cause LACTIC ACIDOSIS.
Exposure Limits (Value,Units,By) TITANIUM DIOXIDE: 10 mg/m3 ACGIH PROPYLENE GLYCOL: 10 mg/m3 AIHA
Irritancy (if yes, explain)
Sensitization (if yes, explain) Carcinogenicity (if yes, explain) TITANIUM DIOXIDE is possibly carcinogenic to humans(2B) by IARC.
Reproductive Toxicity (if yes, explain) Teratogenicity (if yes, explain)
Mutagenicity (if yes, explain) Synergistic Products (if yes, explain)
SECTION 7 - PREVENTIVE MEASURES
Personal Protective Equipment
Gloves: No Respirator: Yes
Eye: No Footwear: No
Clothing: No
Other: No
If checked, specify type: Respirator: NIOSH APPROVED
Engineering controls (specify such as ventilation, enclosed process): Use mechanical ventilation to reduce exposure, ground all equipment and avoid exposure to open flames or sparks.
Leak and Spill Procedure: Wear adequate protective equipment and eliminate all ignition sources. Contain spill with absorbant material and place in a suitable covered and labeled container for disposal.
Waste Disposal: Check with Federal, Provincial and local government regulations and requirements for disposal.
Handling Procedures and Equipment: Use in a well ventilated area. Do not use with incompatible substances and keep away from heat and all ignition sources. Use grounded and non-sparking equipment only.
Storage Requirements: Store in a cool, well ventilated area out of direct sunlight. Store away from heat and all ignition sources. Storage facility should be manufactured out of fire resistant materials.
Special Shipping Information: None Required
SECTION 8 - FIRST AID MEASURES
Inhalation: Remove to fresh air. Get medical help if there is any breathing difficulty.
Ingestion: Do not induce vomiting unless directed by a physician. If conscious and alert, give two glasses of water. Seek medical attention immediately.
Skin Contact: Remove Contaminated clothing (including shoes) and wash before reuse. Flush with large amounts of soap and water. If irritation persists, seek medical attention.
Eye Contact: Flush eyes with large amounts of lukewarm water for 20 minutes, while holding eyelids open or until irritation subsides. If irritation persist, get medical attention.
SECTION 9 - PREPARATION INFORMATION
Prepared by: General Paint Technical Dept
Phone: (604) 253-3131
Preparation Date: Oct 03, 2012
Date: 29 April 2013 Supercedes: 4 May 2010
MATERIAL SAFETY DATA SHEET
IN CASE OF EMERGENCY CALL CHEMTREC AT 1-800-424-9300
1. PRODUCT IDENTIFICATION AND COMPANY IDENTIFICATION:
Product Name: PURELL® INSTANT HAND SANITIZER
Company Name & Address:
GOJO Industries, Inc. One GOJO Plaza, Suite 500 Akron, OH 44311
Emergency Phone: 1-800-424-9300 CHEMTREC
Non-Emergency Phone: (330) 255-6000 MSDS Request Phone: (330) 255-6000 x8804
2. INFORMATION ON INGREDIENTS:
HAZARDOUS INGREDIENTS CAS NUMBER OSHA PEL ACGIH TLV % RANGE
Ethyl Alcohol 64-17-5 1000 ppm 1000 ppm 62 Isopropanol 67-63-0 400 ppm 200 ppm <5
Other ingredient(s) with notification requirements: CAS NUMBER List
Ethyl Alcohol 64-17-5 MA 1; NJ 1S; PA 1; CN 2 Isopropanol 67-63-0 MA 1; NJ 1S; PA; CN 1
3. HAZARDS IDENTIFICATION:
EMERGENCY OVERVIEW When used according to instructions, the product applicable to this MSDS is safe and presents no immediate or long-term health hazard. However, abnormal entry routes, such as gross ingestion, may require immediate medical attention.
Potential Health Effects:
HMIS: Health 2 Flammability 3 Reactivity 0 Personal Protection None
Eye Contact: May cause eye irritation. Skin Contact: No irritation or reaction expected. Inhalation: Not applicable. Ingestion: May cause upset stomach, nausea (Abnormal entry route). Carcinogenicity: Not listed as a carcinogen by NTP, IARC, OSHA or ACGIH.
4. FIRST AID MEASURES:
Eye Contact: Do not rub eyes. Flush eyes thoroughly with water for 15 minutes. If condition worsens or irritation persists, contact physician.
Skin Contact: Not applicable. Inhalation: Not applicable. Ingestion: Do not induce vomiting. Contact a physician or Poison Control Center.
PURELL® INSTANT HAND SANITIZER Page 2 of 2
Document#: 9652-521
5. FIRE FIGHTING MEASURES:
NFPA: Health 2 Fire 3 Reactivity 0 Flashpoint °F/°C (PMCC method): 77°F/25°C Unusual Fire and Explosion Hazards: Product is flammable due to alcohol content. Special Fire Fighting Procedures: None known. Extinguishing Media: X Water Fog X Alcohol Foam X CO2 X Dry Chemical Other
6. ACCIDENTAL RELEASE MEASURES:
Avoid contact with ignition sources since product is flammable. Absorb onto inert material and dispose in appropriate manner. Water clean up and rinse. CAUTION – WILL CAUSE SLIPPERY SURFACES.
7. HANDLING AND STORAGE:
Keep away from fire or flame. Store at normal room temperature away from reach of small children. Keep containers sealed. Use older containers first. Avoid freezing conditions.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION:
Eye Protection: None required under normal conditions. Skin Protection: None required under normal conditions. Respiratory Protection: None required under normal conditions. Ventilation: None required under normal conditions. Protective Equipment or Clothing: None required under normal conditions.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Appearance and Odor Clear liquid, citrus fragrance pH (undiluted): 6.0 – 9.2 VOC , %: 65
10. STABILITY AND REACTIVITY:
Stable/Non reactive product. Avoid ignition sources. 11. TOXICOLOGICAL INFORMATION:
No acute or chronic toxic effects expected when used according to directions. 12. ECOLOGICAL CONSIDERATIONS:
No ecological or special considerations when used according to directions. Not considered environmentally harmful from normal dilution, expected usage and typical drainage to sewers, septic systems and treatment plants.
13. DISPOSAL CONSIDERATIONS:
Characteristic hazardous waste-flammable liquid. Dispose according to local, state and Federal regulations. 14. TRANSPORT INFORMATION:
Hazardous by transport regulations. When transported by ground modes in the U.S., this product typically is typically shipped as Consumer Commodity ORM-D. When transported by water, this product is typically shipped as a UN1170 in Limited Quantities. Refer to all current transport regulations for exact requirements.
15. REGULATORY AND OTHER INFORMATION:
TSCA: All ingredients are listed or exempt per reference 15 USC 2602 (2)(B)(vi).
Complies with current FDA regulations for cosmetic and/or over-the-counter drug products.
This formula meets the FDA Food Code Hand Antiseptics (Sanitizers) criteria (Section 2-301.16).
WHMIS: Exempt under the Food and Drug Act Notice: The information herein is based on data considered to be accurate as of the date of preparation of this material safety data sheet. However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and safety information. The user assumes all liability for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices or from any hazards inherent in the nature of the product.
GRIME EATER PRODUCTS LIMITED Date : 2014-01-01
4140 B Sladeview Crescent Units # 1 & 2
Mississauga, Ontario, Canada, L5L 6A1
1-905-820-2255
MATERIAL SAFETY DATA SHEET
1 PRODUCT IDENTIFICATION
Product Name : GRIME EATER ™ GEL WITH PUMICE HAND CLEANSER
Product Type : HAND CLEANSER - WATERLESS
2 INFORMATION ON INGREDIENTS
INGREDIENTS WITH REPORTING REQUIREMENTS
CAS # % RANGE OSHA PEL ACGIH TLV LD50 / LC50
112-80-1 3% - 7%
102-71-6 1% - 5% 5mg/m3 TWA
Products are notified cosmetics under the Food & Drug Act
3 HAZARDS IDENTIFICATION
These products when used as instructed are safe and pose no short or long term health hazards.
Incorrect or abnormal use ie : ingestion may require medical attention.
HAZARD RATING
Eye contact May cause eye irritation HEALTH 0
Skin contact No irritation under normal conditions FLAMMABILITY 0
Inhalation Not applicable REACTIVITY 0
Ingestion May cause upset stomach PERSONAL PROTECTION 0
0 = INSIGNIFICANT 1 = SLIGHT 2 = MODERATE 3 = HIGH 4 = EXTREME
4 FIRST AID MEASURES
Eye contact Flush eyes thoroughly with potable water for 15 minutes. DO NOT RUB EYES UNDER ANY CIRCUMSTANCES.
Skin contact Not applicable
Inhalation Not applicable
Ingestion DO NOT induce vomiting. Drink plenty of water. Get medical attention.
OLEIC ACID
TRIETHANOLAMINE
Page 1 of 3
GRIME EATER ™ GEL WITH PUMICE HAND CLEANSER
5 FIRE FIGHTING MEASURES
Flash Point N/E
Recommended extinguishing media Carbon Dioxide, Dry Chemical
Special Fire Fighting Procedures None
Unusual Fire Explosion Hazards None
Hazardous Products Formed by Fire None anticipated
6 ACCIDENTAL RELEASE MEASURES
No special requirements. Rinse with water, mop up or wipe up with towel.
May cause slippery surfaces - exercise caution.
7 HANDLING AND STORAGE
Store at room temperature. Keep from extreme heat and freezing.
Keep out of reach of Children.
8 EXPOSURE CONTROL / PERSONAL PROTECTION
Eyes Not required
Skin Not required
Respiratory Not required
Ventilation Not required
Protective equipment Not required
9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance Green
Odor honey almond ( synthetic - allergy safe )
pH 8.0 - 9.0
Specific Gravity 0.985
VOC Content N/E
Viscosity N/E
Solubility in water yes
Page 2 of 3
GRIME EATER ™ GEL WITH PUMICE HAND CLEANSER
10 STABILITY AND REACTIVITY
Stable / Non reactive product
Avoid strong oxidizing agents
11 TOXICOLOGICAL INFORMATION
No acute or chronic toxic effects when used as directed.
12 ECOLOGICAL CONSIDERATIONS
No ecological / environmental issues with this product, when used in normal dilutions ( with water )
No concerns for typical usage / drainage to sewers, septic systems and treatment plants.
13 DISPOSAL CONSIDERATIONS
Dispose through a sanitary sewer in accordance with local, state / provincial and federal regulations.
14 TRANSPORT INFORMATION
Non Hazardous / Non flammable - No shipping restrictions
15 REGULATORY INFORMATION
Canada - These products have been classified in accordance with the hazard criteria of the CPR / IDL and the MSDS contains all
of the information required by the CPR. All ingredients listed on the DSL.
California Proposition 65 No California Prop 65 chemicals are known to exist at or above the No Significant Risk Level.
TSCA inventory status All ingredients listed
16 OTHER INFORMATION
Products are notified cosmetics under the Food & Drug Act
This MSDS is registered with Canadian Centre for Occupational Health & Safety ( CCOHS ) www.ccohs.ca PH 905-572-2981
DISCLAIMER
The information contained on this MSDS is based on available testing and data as supplied to Grime Eater Products Limited and is
believed to be correct and reliable, however no guarantee for it's accuracy or completeness is offered by Grime Eater.
Grime Eater assumes no responsibility or liability from loss or damage due to improper use, incompatibility of these products with
other products and failure to follow directions on the product label and MSDS.
Prepared By : Chemical Department
Company : Grime Eater Products Limited N/E = NOT ESTABLISHED
Telephone : 1-888-424-2976 / 905-820-2255 DNA = DOES NOT APPLY
Revision Date : 2014-01-01
Supercedes Date: 2012-11-01
Page 3 of 3
JACK OIL J132C
Page 1 of 6 MSDS Revision Date (mm/dd/yyyy): 07/11/2013
MATERIAL SAFETY DATA SHEET
: JACK OIL Product identifier
SECTION 1: IDENTIFICATION
Hydraulic oil : Product Use
: Mixture. Chemical Family
J132C : Manufacturer part no.
Refer to Supplier
Manufacturer’s name and address: Supplier’s name and address:
Radiator Specialty Co., of Canada 1711 Aimco Blvd. Mississauga, ON, Canada L4W 1H7
(905) 625-9117 (Monday - Friday, 8 AM - 4 PM) : Information Telephone #
613-996-6666 (CANUTEC) : 24 Hr. Emergency Tel #
SECTION 2 - HAZARDS IDENTIFICATION
Classification : WHMIS information: This product is not a WHMIS controlled product in Canada. It does not meet any of the criteria for a controlled product provided in Part IV of the Controlled Products Regulations (CPR).
Emergency Overview Clear amber liquid. Petroleum odour. Fumes from heated product or mists may irritate respiratory tract. May cause mild eye irritation. Prolonged or repeated skin contact may cause drying and irritation.
:
POTENTIAL HEALTH EFFECTS:
:
Signs and symptoms of short-term (acute) exposure
If product is heated or mists are formed, inhalation may cause irritation to the nose, throat and respiratory tract.
Inhalation
: Skin Direct skin contact may result in little or no irritation.
: Eyes May cause mild transient irritation.
May cause irritation of mouth, throat, and stomach. May cause nausea, vomiting, and diarrhea. Ingestion :
Prolonged skin contact may cause dermatitis (rash), characterized by red, dry, itching skin.
Effects of long-term (chronic) exposure
:
See TOXICOLOGICAL INFORMATION, Section 11. : Carcinogenic status
Additional health hazards : See TOXICOLOGICAL INFORMATION, Section 11.
See ECOLOGICAL INFORMATION, Section 12. :
Potential environmental effects
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients CAS # Wt.%
64742-52-5 Distillates (petroleum), hydrotreated heavy naphthenic
60.00 - 100.00
*N/Av Zinc compounds < 0.3
*Note:: The specific identity of this component is considered proprietary information.
If inhaled, move to fresh air. If breathing has stopped, give artificial respiration. Consult a physician.
: Inhalation
SECTION 4 - FIRST AID MEASURES
JACK OIL J132C
Page 2 of 6 MSDS Revision Date (mm/dd/yyyy): 07/11/2013
Remove contaminated clothing. Wash off with soap and plenty of water. If irritation persists, seek prompt medical attention.
Skin contact :
Immediately flush eyes with plenty of water for at least 15 minutes. If irritation persists, seek prompt medical attention.
Eye contact :
Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention.
:
Treat symptomatically. : Notes For Physician
Fire hazards/conditions of flammability
SECTION 5 - FIRE FIGHTING MEASURES
Not flammable under normal conditions of use. However, may ignite if exposed to extreme heat and flame. Product may float, and be re-ignited at the water's surface. Closed containers may rupture if exposed to excess heat or flame due to a build-up of internal pressure. Vapours are heavier than air and collect in confined and low-lying areas.
:
None known. : Oxidizing properties
: Not expected to be sensitive to mechanical impact or static discharge.
Explosion data: Sensitivity to mechanical impact / static discharge
Dry chemical, foam, carbon dioxide and water fog. Do not use water jet, as this may spread burning material.
: Suitable extinguishing media
Special fire-fighting procedures/equipment
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full face piece operated in positive pressure mode. Move containers from fire area if safe to do so. Water spray may be useful in cooling equipment exposed to heat and flame.
:
Hazardous combustion products
: Carbon oxides; Phosphorus compounds; Nitrogen oxides (NOx); Polycyclic aromatic hydrocarbons; Sulphur oxides; Other unidentified organic compounds.
All persons dealing with the clean-up should wear the appropriate chemically protective equipment. Keep all other personnel upwind and away from the spill/release. Restrict access to area until completion of clean-up. Refer to protective measures listed in sections 7 and 8.
Personal precautions :
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Ensure spilled product does not enter drains, sewers, waterways, or confined spaces. For large spills, dike the area to prevent spreading.
Environmental precautions :
Spill response/cleanup Ventilate area of release. Remove all sources of ignition. Contain and absorb spilled liquid with non-combustible, inert absorbent material (e.g. sand), then place absorbent material into a container for later disposal (see Section 13). Notify the appropriate authorities as required.
:
: Prohibited materials Do not use combustible absorbents, such as sawdust.
Use with adequate ventilation. Wear suitable protective equipment during handling. Avoid breathing vapours. Avoid contact with skin, eyes and clothing. Keep away from extreme heat and flame. Avoid contact with incompatible materials. Wash thoroughly after handling. Keep container tightly closed when not in use.
Safe Handling procedures :
SECTION 7 - HANDLING AND STORAGE
Store in a cool, dry, well-ventilated area. Storage area should be clearly identified, clear of obstruction and accessible only to trained and authorized personnel. Inspect periodically for damage or leaks.
Storage requirements :
Incompatible materials : Strong oxidizing agents.
Special packaging materials : Always keep in containers made of the same materials as the supply container.
Exposure Limits
ACGIH TLV OSHA PEL
STEL TWA STEL PEL Ingredients
5 mg/m³ (As 'Oil
mist, mineral') N/Av 5 mg/m³ (As 'Oil mist,
mineral') N/Av Distillates (petroleum), hydrotreated
heavy naphthenic
N/Av N/Av N/Av N/Av Zinc compounds
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
JACK OIL J132C
Page 3 of 6 MSDS Revision Date (mm/dd/yyyy): 07/11/2013
Ventilation and engineering measures
Use in a well-ventilated area. Use general or local exhaust ventilation to maintain air concentrations below recommended exposure limits.
:
Respiratory protection : If the TLV is exceeded, a NIOSH/MSHA-approved respirator is advised. Advice should be sought from respiratory protection specialists.
Skin protection : Gloves impervious to the material are recommended. Advice should be sought from glove suppliers. Depending on conditions of use, an impervious apron should be worn.
Eye / face protection : Safety glasses with side-shields or chemical splash goggles.
An eyewash station and safety shower should be made available in the immediate working area.
: Other protective equipment
General hygiene considerations
: Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink, smoke or use cosmetics while working with this product. Remove and wash contaminated clothing before re-use. Wash thoroughly after handling.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical state liquid : Appearance Light amber liquid. :
Odour Petroleum odour. : Odour threshold N/Av :
pH N/Av :
Boiling point 0.895 @ 20°C : Specific gravity : 240.5°C
Melting/Freezing point N/Av :
N/Av :
Coefficient of water/oil distribution
Vapour pressure (mmHg @ 20° C / 68° F)
0.008 :
Solubility in water Insoluble. :
Vapour density (Air = 1) 4.3 : Evaporation rate (n-Butyl acetate = 1)
: < 1
Volatile organic Compounds (VOC's)
N/Av :
Volatiles (% by weight) : N/Av
Flash point 160°C :
Flash point Method Not available. : Auto-ignition temperature Cleveland Open Cup :
Lower flammable limit (% by vol.) Upper flammable limit (% by vol.)
: : N/Av N/Av
Flame Projection Length Flashback observed : : N/Ap N/Ap
Absolute pressure of container
: N/Ap
Viscosity : N/Av
No additional information. : General Informatioln
Section 10: STABILITY AND REACTIVITY
Stability and reactivity Stable under the recommended storage and handling conditions prescribed. :
Hazardous polymerization Hazardous polymerization does not occur. :
Conditions to avoid : Avoid heat and open flame.
Materials To Avoid And Incompatibility
: See Section 7 (Handling and Storage) for further details.
Hazardous decomposition products None known, refer to hazardous combustion products in Section 5. :
Eyes, skin, respiratory system and digestive system. Target organs :
SECTION 11 - TOXICOLOGICAL INFORMATION
Routes of exposure Inhalation: Skin Absorption: Skin & Eyes: Ingestion: YES YES NO YES :
: May be mildly irritating to eyes and skin. Irritancy
There is no available data for the product itself, only for the ingredients. See below for individual ingredient acute toxicity data.
: Toxicological data
LD50 LC50(4hr)
inh, rat Ingredients (Rabbit, dermal) (Oral, rat)
Distillates (petroleum),
hydrotreated heavy naphthenic
> 5 mg/L (mist) > 5000 mg/kg > 2000 mg/kg
JACK OIL J132C
Page 4 of 6 MSDS Revision Date (mm/dd/yyyy): 07/11/2013
Zinc compounds N/Av N/Av N/Av
Carcinogenic status No components are listed as carcinogens by ACGIH, IARC, OSHA or NTP. Use caution when pouring this material. This product can generate a complex mixture of airbourne material during heating or in a fire. This combustion material can include carcinogenic polycyclic aromatic hydrocarbons.
:
: Not expected to have other reproductive effects. Reproductive effects
: Teratogenicity Not expected to be a teratogen.
: Mutagenicity Not expected to be mutagenic in humans.
: Epidemiology None known or reported by the manufacturer.
Sensitization to material : Not expected to be a skin or respiratory sensitizer.
: Synergistic materials None known or reported by the manufacturer.
None known or reported by the manufacturer. other important hazards :
Conditions aggravated by overexposure
Pre-existing skin and respiratory disorders. :
Ecotoxicity : The ecological characteristics of this product have not been fully investigated. The product should not be allowed to enter drains or water courses, or be deposited where it can affect ground or surface waters. See the following tables for individual ingredient ecotoxicity data.
SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity data:
NOEC / 21 day LC50 / 96h M Factor
Toxicity to Fish CAS No Ingredients
Distillates (petroleum),
hydrotreated heavy naphthenic
> 5000 mg/L (Rainbow
trout)
64742-52-5 N/Av None.
Zinc compounds N/Av *N/Av N/Av None.
CAS No Ingredients Toxicity to Daphnia
EC50 / 48h NOEC / 21 day M Factor
64742-52-5 None. N/Av > 1000 mg/L [Daphnia magna (Water flea)]
Distillates (petroleum),
hydrotreated heavy naphthenic
*N/Av None. N/Av N/Av Zinc compounds
CAS No Ingredients Toxicity to Algae
EC50 / 96h or 72h NOEC / 96h or 72h M Factor
64742-52-5 Distillates (petroleum),
hydrotreated heavy naphthenic
> 1000 mg/L/96hr (Green
algae) N/Av None.
*N/Av Zinc compounds N/Av N/Av None.
Mobility No data is available on the product itself. :
Persistence No data is available on the product itself. Contains: Distillates (petroleum), hydrotreated heavy naphthenic. Distillates (petroleum), hydrotreated heavy naphthenic is not considered readily biodegradable and is insoluble in water. The substance may persist in the environment.
:
Bioaccumulation potential No data is available on the product itself. :
Other Adverse Environmental effects
No data is available on the product itself. :
JACK OIL J132C
Page 5 of 6 MSDS Revision Date (mm/dd/yyyy): 07/11/2013
Handle waste according to recommendations in Section 7. : Handling for Disposal
SECTION 13 - DISPOSAL CONSIDERATIONS
Dispose of in accordance with federal, provincial and local hazardous waste laws. : Methods of Disposal
SECTION 14: TRANPORT INFORMATION
Regulatory Information UN Number Shipping Name Class
Packing Group Label
Not regulated. not regulated TDG None none
None.
Additional information
TDG
SECTION 15 - REGULATORY INFORMATION
Labelling:
This product is not a WHMIS controlled product in Canada. As such, this product does not require a WHMIS Supplier label.
Canadian Environmental Protection Act (CEPA) information: All ingredients listed appear on the Domestic Substances List (DSL). WHMIS information: Refer to Section 2 for a WHMIS Classification for this product.
Canadian Information:
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the
information required by the CPR.
TSCA: All listed ingredients appear on the Toxic Substances Control Act (TSCA) inventory.
US Federal Information:
SECTION 16 - OTHER INFORMATION
: ACGIH: American Conference of Governmental Industrial Hygienists CAS: Chemical Abstract Services HSDB: Hazardous Substances Data Bank IARC: International Agency for Research on Cancer Inh: Inhalation LC: Lethal Concentration LD: Lethal Dose MSHA: Mine Safety and Health Administration N/Ap: Not Applicable N/Av: Not Available NIOSH: National Institute of Occupational Safety and Health NOEC: No observable effect concentration NTP: National Toxicology Program OECD: Organisation for Economic Co-operation and Development OSHA: Occupational Safety and Health Administration PEL: Permissible exposure limit RTECS: Registry of Toxic Effects of Chemical Substances STEL: Short Term Exposure Limit TDG: Canadian Transportation of Dangerous Goods Act & Regulations TLV: Threshold Limit Values TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Identification System .
Legend
JACK OIL J132C
Page 6 of 6 MSDS Revision Date (mm/dd/yyyy): 07/11/2013
1. ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents & Biological Exposure Indices for 2013. 2. International Agency for Research on Cancer Monographs, searched 2013. 3. Canadian Centre for Occupational Health and Safety, CCInfoWeb databases, 2013 (Chempendium, HSDB and RTECs). 4. Material Safety Data Sheets from manufacturer. 5. OECD - The Global Portal to Information on Chemical Substances - eChemPortal, 2013
References :
Prepared for:
Radiator Specialty Co. of Canada 1711 Aimco Blvd. Mississauga, ON, Canada, L4W 1H7 Telephone: 905-625-9117 (Mon. - Fri., 8 AM - 4 PM) Please direct all enquiries to Radiator Specialty.
Prepared by:
ICC The Compliance Center Inc. http://www.thecompliancecenter.com
DISCLAIMER OF LIABILITY
This Material Safety Data Sheet was prepared by ICC The Compliance Center Inc. using information provided by Radiator Specialty Co. of Canada and CCOHS’ Web Information Service. The information in the Material Safety Data Sheet is offered for your consideration and guidance when exposed to this product. ICC The Compliance Center Inc and Radiator Specialty Co. of Canada expressly disclaim all expressed or implied warranties and assume no responsibilities for the accuracy or completeness of the data contained herein. The data in this MSDS does not apply to use with any other product or in any other process. This Material Safety Data Sheet may not be changed, or altered in any way without the expressed knowledge and permission of ICC The Compliance Center Inc. and Radiator Specialty Co. of Canada.
:
MSDS Preparation Date (mm/dd/yyyy)
07/26/2007
MSDS Revision Date (mm/dd/yyyy)
: 07/11/2013
Revision No. 3 :
(M)SDS sections updated: 12. ECOLOGICAL INFORMATION.
: Revision Information
END OF DOCUMENT
Safety Data Sheet
Revision Number: 004.0 Issue date: 08/29/2014
IDH number: 88567 Product name: PST® 592 Pipe Sealant With PTFE Page 1 of 7
1. PRODUCT AND COMPANY IDENTIFICATION Product name: PST® 592 Pipe Sealant With PTFE IDH number: 88567 Product type: Anaerobic Sealant Item number: 59214 Restriction of Use: None identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067
Telephone: (860) 571-5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING: CAUSES SKIN AND EYE IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2B
SKIN SENSITIZATION 1
PICTOGRAM(S)
Precautionary Statements
Prevention: Avoid breathing dust or fumes. Wash thoroughly after handling. Contaminated work clothing
should not be allowed out of the workplace. Wear protective gloves. Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing.
Storage: Not prescribed Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).
See Section 11 for additional toxicological information.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous Component(s) CAS Number Percentage*
Mica 12001-26-2 10 - 30
Polyglycol dimethacrylate Proprietary 10 - 30
IDH number: 88567 Product name: PST® 592 Pipe Sealant With PTFE Page 2 of 7
Polyglycoldioctanoate Proprietary 10 - 30
Octan-1-ol 111-87-5 10 - 30
Ethene, tetrafluoro-, homopolymer 9002-84-0 5 - 10
Silica, amorphous, treated 68909-20-6 1 - 5
Titanium dioxide 13463-67-7 1 - 5
Propane-1,2-diol 57-55-6 1 - 5
Cumene hydroperoxide 80-15-9 0.1 - 1
Benzaldehyde 100-52-7 0.1 - 1
Cumene 98-82-8 0.1 - 1
* Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections.
4. FIRST AID MEASURES
Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove
contaminated clothing and footwear. Wash clothing before reuse. Get medical attention.
Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Get medical attention.
Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Symptoms: See Section 11.
5. FIRE FIGHTING MEASURES
Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.
Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In case of fire, keep containers cool with water spray.
Unusual fire or explosion hazards: Uncontrolled polymerization may occur at high temperatures resulting in
explosions or rupture of storage containers.
Hazardous combustion products: Oxides of carbon. Toxic fluorine compounds. Irritating organic vapours.
6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel.
Environmental precautions: Do not allow product to enter sewer or waterways.
Clean-up methods: Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to
prevent entry into water system; wear full protective equipment during clean-up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape up as much material as possible. Store in a partly filled, closed container until disposal. Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up.
IDH number: 88567 Product name: PST® 592 Pipe Sealant With PTFE Page 3 of 7
7. HANDLING AND STORAGE
Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Keep container closed. Refer to Section 8.
Storage: For safe storage, store at or below 38 °C (100.4 °F)
Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use.
For information on product shelf life contact Henkel Customer Service at (800) 243-4874.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed.
Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER
Mica 3 mg/m3 TWA
Respirable fraction. 20 MPPCF TWA None None
Polyglycol dimethacrylate None None None None
Polyglycoldioctanoate None None None None
Octan-1-ol None None 50 ppm (265 mg/m3)
TWA None
Ethene, tetrafluoro-, homopolymer None None None
10 mg/m3 TWA Total dust.
5 mg/m3 TWA Respirable fraction.
Silica, amorphous, treated 10 mg/m3 TWA Inhalable dust.
6 mg/m3 TWA None None
Titanium dioxide 10 mg/m3 TWA 15 mg/m3 PEL Total
dust. None None
Propane-1,2-diol None None 10 mg/m3 TWA
Aerosol. None
Cumene hydroperoxide None None 1 ppm (6 mg/m3)
TWA (SKIN)
None
Benzaldehyde None None
4 ppm (17.4 mg/m3) STEL
2 ppm (8.7 mg/m3) TWA (Skin sensitizer)
None
Cumene 50 ppm TWA 50 ppm (245 mg/m3)
PEL (SKIN)
None None
Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below
exposure limits.
Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s).
Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available.
Skin protection: Use chemical resistant, impermeable clothing including gloves and either an
apron or body suit to prevent skin contact. Neoprene, Butyl-rubber, or nitrile-rubber gloves.
IDH number: 88567 Product name: PST® 592 Pipe Sealant With PTFE Page 4 of 7
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Paste Color: White Odor: Mild Odor threshold: Not available. pH: Not applicable Vapor pressure: < 10 mm hg (27 °C (80.6 °F)) Boiling point/range: > 149 °C (> 300.2 °F) Melting point/ range: Not available. Specific gravity: 1.21 Vapor density: Not available. Flash point: > 93.3 °C (> 199.94 °F) Tagliabue closed cup Flammable/Explosive limits - lower: Not available. Flammable/Explosive limits - upper: Not available. Autoignition temperature: Not available. Evaporation rate: Not available. Solubility in water: Slight Partition coefficient (n-octanol/water): Not available. VOC content: 0.72 %; 6.86 g/l Viscosity: Not available. Decomposition temperature: Not available.
10. STABILITY AND REACTIVITY
Stability: Stable under normal conditions of storage and use.
Hazardous reactions: None under normal processing. Polymerization may occur at elevated temperature or in the presence of incompatible materials.
Hazardous decomposition products:
Oxides of carbon. Toxic fluorine compounds. Irritating organic vapours.
Incompatible materials: Strong oxidizing agents.
Reactivity: Not available.
Conditions to avoid: Elevated temperatures. Heat, flames, sparks and other sources of ignition. Store away from
incompatible materials.
11. TOXICOLOGICAL INFORMATION
Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion
IDH number: 88567 Product name: PST® 592 Pipe Sealant With PTFE Page 5 of 7
Potential Health Effects/Symptoms
Inhalation: Inhalation of vapors or mists of the product may be irritating to the respiratory system. Vapors may cause headaches, nausea, dizziness and respiratory tract irritation.
Skin contact: Causes skin irritation. May cause allergic skin reaction. Eye contact: Causes eye irritation. Ingestion: May cause gastrointestinal tract irritation if swallowed.
Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Mica None Lung Polyglycol dimethacrylate None Allergen, Irritant Polyglycoldioctanoate None Irritant
Octan-1-ol Oral LD50 (RAT) = > 5 g/kg
Dermal LD50 (RABBIT) = > 5 g/kg Central nervous system, Irritant
Ethene, tetrafluoro-, homopolymer None No Target Organs Silica, amorphous, treated None No Target Organs
Titanium dioxide None Irritant, Respiratory, Some evidence of
carcinogenicity
Propane-1,2-diol Oral LD50 (RABBIT) = 18 g/kg
Oral LD50 (RAT) = 30 g/kg Irritant
Cumene hydroperoxide None Allergen, Central nervous system, Corrosive,
Irritant, Mutagen
Benzaldehyde Oral LD50 (RAT) = 1,300 mg/kg
Dermal LD50 (RABBIT) = > 1,250 mg/kg Allergen, Central nervous system, Irritant
Cumene Oral LD50 (RAT) = 2.91 g/kg
Oral LD50 (RAT) = 1,400 mg/kg Inhalation LC50 (RAT, 4 h) = 8000 ppm
Central nervous system, Irritant, Lung
Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen
(Specifically Regulated)
Mica No No No
Polyglycol dimethacrylate No No No
Polyglycoldioctanoate No No No
Octan-1-ol No No No
Ethene, tetrafluoro-, homopolymer No No No
Silica, amorphous, treated No No No
Titanium dioxide No Group 2B No
Propane-1,2-diol No No No
Cumene hydroperoxide No No No
Benzaldehyde No No No
Cumene No Group 2B No
12. ECOLOGICAL INFORMATION
Ecological information: Not available.
IDH number: 88567 Product name: PST® 592 Pipe Sealant With PTFE Page 6 of 7
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.
Hazardous waste number: D018: Benzene.
14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR)
Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None
International Air Transportation (ICAO/IATA)
Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None
Water Transportation (IMO/IMDG)
Proper shipping name: Not regulated Hazard class or division: None Identification number: None Packing group: None
15. REGULATORY INFORMATION United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
TSCA 12 (b) Export Notification: Ethene, tetrafluoro-, homopolymer (CAS# 9002-84-0).
CERCLA/SARA Section 302 EHS: None above reporting de minimis CERCLA/SARA Section 311/312: Immediate Health, Delayed Health CERCLA/SARA Section 313: None above reporting de minimis CERCLA Reportable quantity: Cumene hydroperoxide (CAS# 80-15-9) 10 lbs. (4.54 kg)
California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other reproductive harm.
Canada Regulatory Information
CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List.
16. OTHER INFORMATION
This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format.
Prepared by: Sheila Gines, Regulatory Affairs Specialist
Issue date: 08/29/2014
IDH number: 88567 Product name: PST® 592 Pipe Sealant With PTFE Page 7 of 7
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits.
Product Name: MOBIL HYDRAUL 56
Revision Date: 28 Aug 2014 Page 1 of 9
______________________________________________________________________________________________________________________
MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT
Product Name: MOBIL HYDRAUL 56 Product Description: Base Oil and Additives MSDS Number: 20777 Product Code: 20152050B510 Intended Use: Hydraulic fluid
COMPANY IDENTIFICATION
Supplier: Imperial Oil Downstream 240 4th Avenue Calgary, ALBERTA. T2P 3M9 Canada
24 Hour Environmental / Health Emergency Telephone
1-866-232-9563
Transportation Emergency Phone Number 1-866-232-9563 Product Technical Information 1-800-268-3183 Supplier General Contact 1-800-567-3776
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 3 HAZARDS IDENTIFICATION This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH EFFECTS
Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use
Product Name: MOBIL HYDRAUL 56
Revision Date: 28 Aug 2014 Page 2 of 9
______________________________________________________________________________________________________________________
adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.
SKIN CONTACT
Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION
First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Pressurised mists may form a flammable mixture. Hazardous Combustion Products: Aldehydes, Incomplete combustion products, Smoke, Fume, Oxides of carbon, Sulphur oxides
FLAMMABILITY PROPERTIES
Flash Point [Method]: >198°C (389°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D
SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
PROTECTIVE MEASURES
Product Name: MOBIL HYDRAUL 56
Revision Date: 28 Aug 2014 Page 3 of 9
______________________________________________________________________________________________________________________
Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended.
SPILL MANAGEMENT Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7 HANDLING AND STORAGE HANDLING
Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present (e.g., during switch-loading operations). Use proper bonding and/or earthing procedures. However, bonding and earthing may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator.
STORAGE
The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers. Keep away from incompatible materials.
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Product Name: MOBIL HYDRAUL 56
Revision Date: 28 Aug 2014 Page 4 of 9
______________________________________________________________________________________________________________________
Substance Name Form Limit/Standard Note Source HYDROTREATED MIDDLE DISTILLATE (PETROLEUM)
Inhalable fraction.
TWA 5 mg/m3 ACGIH
Exposure limits/standards for materials that can be formed when handling this product: When mists/aerosols can occur the following is recommended: 5 mg/m³ - ACGIH TLV (inhalable fraction). NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.
PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:
No protection is ordinarily required under normal conditions of use. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping.
Product Name: MOBIL HYDRAUL 56
Revision Date: 28 Aug 2014 Page 5 of 9
______________________________________________________________________________________________________________________
ENVIRONMENTAL CONTROLS Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION
Physical State: Liquid Colour: Amber Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 °C): 0.884 Flash Point [Method]: >198°C (389°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: N/D Boiling Point / Range: > 316°C (600°F) [Estimated] Vapour Density (Air = 1): > 2 at 101 kPa [Estimated] Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20ºC [Estimated] Evaporation Rate (n-butyl acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 [Estimated] Solubility in Water: Negligible Viscosity: 55 cSt (55 mm2/sec) at 40ºC | 9.6 cSt (9.6 mm2/sec) at 100°C Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
Freezing Point: N/D Melting Point: N/A Pour Point: -36°C (-33°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt Decomposition Temperature: N/D
SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION
Product Name: MOBIL HYDRAUL 56
Revision Date: 28 Aug 2014 Page 6 of 9
______________________________________________________________________________________________________________________
ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation
Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures.
Ingestion Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components.
Skin Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on
assessment of the components.
Eye Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on
assessment of the components. CHRONIC/OTHER EFFECTS
Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals. MIDDLE DISTILLATES: Carcinogenic in animal tests. Lifetime skin painting tests produced tumours, but the mechanism is due to repeated cycles of skin damage and restorative hyperplasia. This mechanism is considered unlikely in humans where such prolonged skin irritation would not be tolerated. Did not cause mutations in-vitro. Inhalation of vapours did not result in reproductive or developmental effects in laboratory animals. Inhalation of high concentrations in animals resulted in respiratory tract irritation, lung changes and some reduction in lung function. Non-sensitising in test animals.
CMR Status: None. Chemical Name CAS Number List Citations HYDROTREATED MIDDLE DISTILLATE (PETROLEUM)
64742-46-7 4
--REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land.
Product Name: MOBIL HYDRAUL 56
Revision Date: 28 Aug 2014 Page 7 of 9
______________________________________________________________________________________________________________________
Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may
reduce the bioconcentration or limit bioavailability.
SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products. Protect the environment. Dispose of used oil at designated sites. Minimize skin contact. Do not mix used oils with solvents, brake fluids or coolants.
REGULATORY DISPOSAL INFORMATION Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION LAND (TDG): Not Regulated for Land Transport
LAND (DOT): Not Regulated for Land Transport
SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code
AIR (IATA): Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION
Product Name: MOBIL HYDRAUL 56
Revision Date: 28 Aug 2014 Page 8 of 9
______________________________________________________________________________________________________________________
WHMIS Classification: Not controlled This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Complies with the following national/regional chemical inventory requirements AICS, DSL, ENCS, KECI, PICCS, TSCA The Following Ingredients are Cited on the Lists Below: Chemical Name CAS Number List Citations ZINC ALKYLDITHIOPHOSPHATE 68649-42-3 6
--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 13: Disposal Considerations - Disposal Recommendations information was modified. Section 09: Boiling Point C(F) information was modified. Section 09: Pour Point C(F) information was modified. Section 09: Flash Point C(F) information was modified. Section 09: n-Octanol/Water Partition Coefficient information was modified. Section 05: Hazardous Combustion Products information was modified. Section 09: Flash Point C(F) information was modified. Section 09: Autoignition Temperature information was modified. Section 09 Viscosity information was modified. Section 09 Viscosity information was modified. Section 15: National Chemical Inventory Listing information was modified. Section 09: Relative Density information was modified. Section 16: MSN,MAT ID information was modified. Section 11: Chronic Tox - Component - WHMIS information was modified. Section 08: Exposure Limits Table information was added. Section 11: Chemical Name - Header information was added. Section 11: CAS Number - Header information was added. Section 11: List Citation - Header information was added. Section 11: Tox List Cited Table information was added. Section 08: OEL Table - Substance Name Column - Header information was added.
Product Name: MOBIL HYDRAUL 56
Revision Date: 28 Aug 2014 Page 9 of 9
______________________________________________________________________________________________________________________
Section 08: OEL Table - Form Column - Header information was added. Section 08: OEL Table - Limit Column - Header information was added. Section 08: OEL Table - Notation Column - Header information was added. Section 08: OEL Table - Source Column - Header information was added. Section 09: Vapour Pressure information was added. Section 15: Special Cases - Header information was deleted. Section 15: Special Cases Table information was deleted. Section 15: Inventory - Header information was deleted. Section 15: Status - Header information was deleted. Section 09: Vapour Pressure information was deleted. ----------------------------------------------------------------------------------------------------------------------------------------------------- WHMIS Classification: Not controlled ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 7105047 (538859) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety
Product Name: LIGHT DISTILLATE
Revision Date: 09 Apr 2013 Page 1 of 12
______________________________________________________________________________________________________________________
MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT
Product Name: (see Section 16 for Synonyms) LIGHT DISTILLATE Product Description: Petroleum Distillates MSDS Number: 8529 Product Code: 10102015 Intended Use: Fuel/solvent/blend stock
COMPANY IDENTIFICATION
Supplier: Imperial Oil Products Division 240 4th Avenue Calgary, ALBERTA. T2P 3M9 Canada
24 Hour Environmental / Health Emergency Telephone
1-866-232-9563
Transportation Emergency Phone Number 1-866-232-9563 Product Technical Information 1-800-268-3183 Supplier General Contact 1-800-567-3776
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# Concentration* Acute Toxicity KEROSENE, STRAIGHT RUN 8008-20-6 0 - 100% None LIGHT ATMOSPHERIC GAS OIL 64741-44-2 0 - 100% None LIGHT HYDROCRACKED DISTILLATE (PETROLEUM) 64741-77-1 0 - 100% None Hazardous Constituent(s) Contained in Complex Substance(s) Name CAS# Concentration* Acute Toxicity NAPHTHALENE 91-20-3 < 1% Dermal Lethality: LD50 >
2500 mg/kg (Rat); Inhalation Lethality: LC50 > 0.4 mg/l (Rat); Oral Lethality: LD50 622 mg/kg (Mouse)
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 3 HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). PHYSICAL/CHEMICAL EFFECTS
Combustible. Material can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited. Material can accumulate static charges which may cause an ignition.
HEALTH EFFECTS
Irritating to skin. If swallowed, may be aspirated and cause lung damage. May be irritating to the eyes, nose, throat, and lungs. Breathing of high vapour concentrations may cause dizziness, light-headedness, headache,
Product Name: LIGHT DISTILLATE
Revision Date: 09 Apr 2013 Page 2 of 12
______________________________________________________________________________________________________________________
nausea and loss of co-ordination. Continued inhalation may result in unconsciousness. High-pressure injection under skin may cause serious damage. Target Organs: Skin |
NFPA Hazard ID: Health: 2 Flammability: 2 Reactivity: 0 HMIS Hazard ID: Health: 2* Flammability: 2 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.
SKIN CONTACT
Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION
Seek immediate medical attention. Do not induce vomiting. NOTE TO PHYSICIAN
If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately. PRE-EXISTING MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE
Contains hydrocarbon solvent/petroleum hydrocarbons; skin contact may aggravate an existing dermatitis.
SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to
Product Name: LIGHT DISTILLATE
Revision Date: 09 Apr 2013 Page 3 of 12
______________________________________________________________________________________________________________________
protect personnel. Unusual Fire Hazards: Combustible. Vapour is flammable and heavier than air. Vapour may travel across the ground and reach remote ignition sources, causing a flashback fire danger. Hazardous material. Firefighters should consider protective equipment indicated in Section 8. Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulphur oxides, Incomplete combustion products, Oxides of carbon
FLAMMABILITY PROPERTIES
Flash Point [Method]: 40°C (104°F) [ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D
SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
PROTECTIVE MEASURES
Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders.
SPILL MANAGEMENT Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed material. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills: Water spray may reduce vapour, but may not prevent ignition in enclosed spaces. Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. Warn other shipping. If the Flash Point exceeds the Ambient Temperature by 10 deg C or more, use containment booms and remove from the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed the Ambient Air Temperature by at least 10C, use booms as a barrier to protect shorelines and allow material to evaporate. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
Product Name: LIGHT DISTILLATE
Revision Date: 09 Apr 2013 Page 4 of 12
______________________________________________________________________________________________________________________
SECTION 7 HANDLING AND STORAGE HANDLING
Avoid all personal contact. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Loading/Unloading Temperature: ND Transport Temperature: N/D Transport Pressure: N/D Static Accumulator: This material is a static accumulator.
STORAGE
The container choice, for example storage vessel, may effect static accumulation and dissipation. Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated area. Storage containers should be earthed and bonded. Fixed storage containers, transfer containers and associated equipment should be grounded and bonded to prevent accumulation of static charge. Storage Temperature: N/D Storage Pressure: N/D
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Substance Name Form Limit/Standard Note Source KEROSENE, STRAIGHT RUN Stable
Aerosol. TWA 5 mg/m3 Supplier
KEROSENE, STRAIGHT RUN Vapour. TWA 200 mg/m3 Supplier KEROSENE, STRAIGHT RUN [as total hydrocarbon vapor]
Non-Aerosol TWA 200 mg/m3 Skin ACGIH
LIGHT ATMOSPHERIC GAS OIL Stable Aerosol.
TWA 5 mg/m3 Supplier
LIGHT ATMOSPHERIC GAS OIL Vapour. TWA 200 mg/m3 Supplier LIGHT HYDROCRACKED DISTILLATE (PETROLEUM)
Stable Aerosol.
TWA 5 mg/m3 Supplier
LIGHT HYDROCRACKED DISTILLATE (PETROLEUM)
Vapour. TWA 200 mg/m3 Supplier
NAPHTHALENE STEL 15 ppm Skin ACGIH NAPHTHALENE TWA 10 ppm Skin ACGIH
NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS
Product Name: LIGHT DISTILLATE
Revision Date: 09 Apr 2013 Page 5 of 12
______________________________________________________________________________________________________________________
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:
Use explosion-proof ventilation equipment to stay below exposure limits.
PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:
Chemical resistant gloves are recommended. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:
Chemical/oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping.
ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION
Physical State: Liquid Colour: Pale Yellow Odour: Petroleum/Solvent
Product Name: LIGHT DISTILLATE
Revision Date: 09 Apr 2013 Page 6 of 12
______________________________________________________________________________________________________________________
Odour Threshold: N/D IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 °C): 0.85 Flash Point [Method]: 40°C (104°F) [ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D Boiling Point / Range: 180°C (356°F) - 320°C (608°F) [Estimated] Vapour Density (Air = 1): N/D Vapour Pressure: [N/D at 20 °C] | < 1 kPa (7.5 mm Hg) at 38°C Evaporation Rate (n-butyl acetate = 1): < 1 pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): N/D Solubility in Water: Negligible Viscosity: 1.7 cSt (1.7 mm2/sec) at 40ºC Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
Freezing Point: N/D Melting Point: N/A Pour Point: -39°C (-38°F) Decomposition Temperature: N/D
SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation
Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on test data for structurally similar materials.
Irritation: No end point data for material. Elevated temperatures or mechanical action may form vapours, mist, or fumes which may be irritating to the eyes, nose, throat, or lungs. Based on assessment of the components.
Ingestion
Toxicity (Rat): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar materials.
Skin
Toxicity (Rabbit): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar materials.
Product Name: LIGHT DISTILLATE
Revision Date: 09 Apr 2013 Page 7 of 12
______________________________________________________________________________________________________________________
Irritation (Rabbit): Data available. Moderately irritating to skin with prolonged exposure. Based on test data for structurally similar materials.
Eye
Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself:
Vapour/aerosol concentrations above recommended exposure levels are irritating to the eyes and respiratory tract, may cause headaches, dizziness, anaesthesia, drowsiness, unconsciousness and other central nervous system effects including death. Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Contains: KEROSENE: Carcinogenic in animal tests. Lifetime skin painting tests produced tumours, but the mechanism is due to repeated cycles of skin damage and restorative hyperplasia. This mechanism is considered unlikely in humans where such prolonged skin irritation would not be tolerated. Did not cause mutations in-vitro. Inhalation of vapours did not result in reproductive or developmental effects in laboratory animals. Inhalation of high concentrations in animals resulted in respiratory tract irritation, lung changes and some reduction in lung function. Non-sensitizing in animal tests. MIDDLE DISTILLATES WITH CRACKED STOCKS: Carcinogenic in animal tests. Caused mutations in-vitro. Repeated dermal exposures to high concentrations in test animals resulted in reduced litter size and litter weight, and increased fetal resorptions at maternally toxic doses. Dermal exposure to high concentrations resulted in severe skin irritation with weight loss and some mortality. Inhalation exposure to high concentrations resulted in respiratory tract irritation, lung changes/infiltration/accumulation, and reduction in lung function. NAPHTHALENE: Exposure to high concentrations of naphthalene may cause destruction of red blood cells, anemia, and cataracts. Naphthalene caused cancer in laboratory animal studies, but the relevance of these findings to humans is uncertain.
CMR Status: Chemical Name CAS Number List Citations KEROSENE, STRAIGHT RUN 8008-20-6 4 NAPHTHALENE 91-20-3 3, 4
--REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic
environment. MOBILITY More volatile component -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment and
wastewater solids.
Product Name: LIGHT DISTILLATE
Revision Date: 09 Apr 2013 Page 8 of 12
______________________________________________________________________________________________________________________
High molecular wt. component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids.
PERSISTENCE AND DEGRADABILITY Biodegradation: Majority of components -- Expected to be inherently biodegradable Atmospheric Oxidation: More volatile component -- Expected to degrade rapidly in air BIOACCUMULATION POTENTIAL Majority of components -- Has the potential to bioaccumulate, however metabolism or physical properties may
reduce the bioconcentration or limit bioavailability.
SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products.
REGULATORY DISPOSAL INFORMATION Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION LAND (TDG)
Proper Shipping Name: FUEL OIL (Kerosene) Hazard Class & Division: 3 UN Number: 1202 Packing Group: III Marine Pollutant: Yes Footnote: Marine Pollutant designation is applicable only if shipped over water.
LAND (DOT)
Proper Shipping Name: DIESEL FUEL Hazard Class & Division: 3 ID Number: 1993
Product Name: LIGHT DISTILLATE
Revision Date: 09 Apr 2013 Page 9 of 12
______________________________________________________________________________________________________________________
Packing Group: III ERG Number: 128 Label(s): None Transport Document Name: UN1993, DIESEL FUEL, 3, PG III Footnote: The flash point of this material is greater than 38ºC/100ºF. Regulatory classification of this material varies. DOT: Flammable liquid or combustible liquid. OSHA: Combustible liquid. IATA/IMO: Flammable liquid. This material is not regulated under 49 CFR in a container of 450 litre/119 gallon capacity or less when transported solely by land, as long as the material is not a hazardous waste, a marine pollutant, or specifically listed as a hazardous substance.
SEA (IMDG)
Proper Shipping Name: HEATING OIL, LIGHT Hazard Class & Division: 3 EMS Number: F-E, S-E UN Number: 1202 Packing Group: III Marine Pollutant: Yes Label(s): 3 Transport Document Name: UN1202, HEATING OIL, LIGHT, 3, PG III, (40°C c.c.), MARINE POLLUTANT
AIR (IATA)
Proper Shipping Name: HEATING OIL, LIGHT Hazard Class & Division: 3 UN Number: 1202 Packing Group: III Label(s) / Mark(s): 3 Transport Document Name: UN1202, HEATING OIL, LIGHT, 3, PG III
SECTION 15 REGULATORY INFORMATION WHMIS Classification: Class B, Division 3: Combustible Liquids Class D, Division 2, Subdivision B: Toxic Material This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Complies with the following national/regional chemical inventory requirements DSL, TSCA Special Cases:
Inventory Status AICS Not determined ENCS Not determined IECSC Not determined KECI Not determined PICCS Not determined
Product Name: LIGHT DISTILLATE
Revision Date: 09 Apr 2013 Page 10 of 12
______________________________________________________________________________________________________________________
The Following Ingredients are Cited on the Lists Below: Chemical Name CAS Number List Citations NAPHTHALENE 91-20-3 5
--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Protective Measures was modified. Section 09: Phys/Chem Properties Note was modified. Section 09: Boiling Point C(F) was modified. Section 09: Pour Point C(F) was modified. Section 08: Comply with applicable regulations phrase was modified. Section 09: VAPOUR PRESSURE was modified. Section 09: Vapour Pressure was modified. Section 11: Inhalation Irritation Test Data was modified. Section 06: Accidental Release-Spill Management-Land was modified. Section 06: Accidental Release- Spill Management- Water was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09 Viscosity was modified. Section 04: First Aid Pre-existing Medical Conditions was modified. Section 08: Respiratory Protection was modified. Section 14: Transport Document Name was modified. Section 14: Label(s) was modified. Section 15: National Chemical Inventory Listing - Header was modified. Section 11: Additional Health Information was modified. Section 14: DOT Footnote was modified. Section 15: Special Cases Table was modified. Composition: Component table was modified. Composition: Component table was modified. Section 08: Exposure Limits Table was modified. Section 16: Land Spill was modified. Section 16: Water Spill was modified. Section 15: Canadian List Citations Table was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 11: Tox List Cited Table was modified. Section 09: Decomposition Temperature was added. Section 09: Decomposition Temp - Header was added. Section 01: Product Code was added. Section 01: Product Code - Header was added. SYNONYMS: AUTOMOTIVE (ON-ROAD) DIESEL FUEL, DIESEL ARCTIC, DIESEL FUEL, DIESEL LOW SULPHUR
Product Name: LIGHT DISTILLATE
Revision Date: 09 Apr 2013 Page 11 of 12
______________________________________________________________________________________________________________________
LIGHT, DIESEL LOW SULPHUR LIGHT DYED, DIESEL LOW SULPHUR LIGHT RAIL, DIESEL REGULAR SULPHUR LIGHT DYED, FURNACE FUEL LIGHT, FURNACE FUEL LIGHT DYED, MC SOLVENT, STOVE OIL, STOVE OIL DYED ----------------------------------------------------------------------------------------------------------------------------------------------------- PRECAUTIONARY LABEL TEXT: WHMIS Classification: Class B, Division 3: Combustible Liquids Class D, Division 2, Subdivision B: Toxic Material HEALTH HAZARDS Irritating to skin. If swallowed, may be aspirated and cause lung damage. Target Organs: Skin | PHYSICAL HAZARDS Combustible. In use, may form flammable/explosive vapour-air mixture. Material can accumulate static charges which may cause an ignition. PRECAUTIONS Avoid all personal contact. Use proper bonding and/or earthing procedures.However, bonding and earthing may not eliminate the hazard from static accumulation. FIRST AID Eye: Flush thoroughly with water. If irritation occurs, get medical assistance. Oral: Seek immediate medical attention. Do not induce vomiting. Skin: Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. FIRE FIGHTING MEDIA Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPILL/LEAK Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. Warn other shipping. Report spills as required to appropriate authorities. If the Flash Point exceeds the Ambient Temperature by 10 deg C or more, use containment booms and remove from the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed the Ambient Air Temperature by at least 10C, use booms as a barrier to protect shorelines and allow material to evaporate. Seek the advice of a specialist before using dispersants. ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy
Product Name: LIGHT DISTILLATE
Revision Date: 09 Apr 2013 Page 12 of 12
______________________________________________________________________________________________________________________
itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 5007490 (552455) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety
Product Name: MIDDLE DISTILLATE
Revision Date: 26 Nov 2014 Page 1 of 11
______________________________________________________________________________________________________________________
MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT
Product Name: (see Section 16 for Synonyms) MIDDLE DISTILLATE Product Description: Hydrocarbons and Additives MSDS Number: 826 Intended Use: Fuel
COMPANY IDENTIFICATION
Supplier: Imperial Oil Downstream 240 4th Avenue Calgary, ALBERTA. T2P 3M9 Canada
24 Hour Environmental / Health Emergency Telephone
1-866-232-9563
Transportation Emergency Phone Number 1-866-232-9563 Product Technical Information 1-800-268-3183 Supplier General Contact 1-800-567-3776
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# Concentration* Acute Toxicity FUEL OIL NO. 2 68476-30-2 > 99 % None Hazardous Constituent(s) Contained in Complex Substance(s) Name CAS# Concentration* Acute Toxicity NAPHTHALENE 91-20-3 < 1% Inhalation Lethality: LC50 >
0.4 mg/l (Rat); Oral Lethality: LD50 710 mg/kg (Mouse); Oral Lethality: LD50 533 mg/kg (Mouse)
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 3 HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). PHYSICAL/CHEMICAL EFFECTS
Combustible. In use, may form flammable/explosive vapour-air mixture. Material can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited. Material can accumulate static charges which may cause an ignition.
HEALTH EFFECTS
Irritating to skin. If swallowed, may be aspirated and cause lung damage. Under conditions of poor personal hygiene and prolonged repeated contact, some polycyclic aromatic compounds (PACs) have been suspected as a cause of skin cancer in humans. May be irritating to the eyes, nose, throat, and lungs. High-pressure
Product Name: MIDDLE DISTILLATE
Revision Date: 26 Nov 2014 Page 2 of 11
______________________________________________________________________________________________________________________
injection under skin may cause serious damage. Target Organs: Skin |
NFPA Hazard ID: Health: 1 Flammability: 2 Reactivity: 0 HMIS Hazard ID: Health: 1 Flammability: 2 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.
SKIN CONTACT
Remove contaminated clothing. Dry wipe exposed skin and cleanse with waterless hand cleaner and follow by washing thoroughly with soap and water. For those providing assistance, avoid further skin contact to yourself or others. Wear impervious gloves. Launder contaminated clothing separately before reuse. Discard contaminated articles that cannot be laundered. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION
Seek immediate medical attention. Do not induce vomiting. NOTE TO PHYSICIAN
If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately. PRE-EXISTING MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE
Contains hydrocarbon solvent/petroleum hydrocarbons; skin contact may aggravate an existing dermatitis.
SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering
Product Name: MIDDLE DISTILLATE
Revision Date: 26 Nov 2014 Page 3 of 11
______________________________________________________________________________________________________________________
streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Combustible. Vapour is flammable and heavier than air. Vapour may travel across the ground and reach remote ignition sources, causing a flashback fire danger. Static discharge: material can accumulate static charges which may cause an incendiary electrical discharge. Hazardous material. Firefighters should consider protective equipment indicated in Section 8. Hazardous Combustion Products: Sulphur oxides, Smoke, Fume, Aldehydes, Oxides of carbon, Incomplete combustion products
FLAMMABILITY PROPERTIES
Flash Point [Method]: >40°C (104°F) [ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: 0.7 UEL: 6.5 Autoignition Temperature: N/D
SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
PROTECTIVE MEASURES
Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders.
SPILL MANAGEMENT Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed material. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills: Water spray may reduce vapour, but may not prevent ignition in enclosed spaces. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Eliminate sources of ignition. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
Product Name: MIDDLE DISTILLATE
Revision Date: 26 Nov 2014 Page 4 of 11
______________________________________________________________________________________________________________________
SECTION 7 HANDLING AND STORAGE HANDLING
Avoid breathing mists or vapour. Avoid contact with skin. Do not siphon by mouth. It is dangerous and/or unlawful to put petrol into unapproved containers. Do not fill container while it is in or on a vehicle. Static electricity may ignite vapour and cause fire. Place container on ground when filling and keep nozzle in contact with container. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. A liquid is typically considered a nonconductive, static accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens per meter) and is considered a semiconductive, static accumulator if its conductivity is below 10,000 pS/m. Whether a liquid is nonconductive or semiconductive, the precautions are the same. A number of factors, for example liquid temperature, presence of contaminants, anti-static additives and filtration can greatly influence the conductivity of a liquid.
STORAGE
The container choice, for example storage vessel, may effect static accumulation and dissipation. Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated area. Storage containers should be earthed and bonded. Fixed storage containers, transfer containers and associated equipment should be grounded and bonded to prevent accumulation of static charge.
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Substance Name Form Limit/Standard Note Source FUEL OIL NO. 2 Stable
Aerosol. TWA 5 mg/m3 Supplier
FUEL OIL NO. 2 Vapour. TWA 200 mg/m3 Supplier FUEL OIL NO. 2 [total hydrocarb, vapor&aerosol]
Inhalable fraction and vapour
TWA 100 mg/m3 Skin ACGIH
NAPHTHALENE TWA 10 ppm Skin ACGIH NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:
Adequate ventilation should be provided so that exposure limits are not exceeded.
PERSONAL PROTECTION
Product Name: MIDDLE DISTILLATE
Revision Date: 26 Nov 2014 Page 5 of 11
______________________________________________________________________________________________________________________
Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:
If prolonged or repeated contact is likely, chemical-resistant gloves are recommended. If contact with forearms is likely, wear gauntlet-style gloves.
Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:
If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping.
ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION
Physical State: Liquid Colour: Clear (May Be Dyed) Odour: Petroleum/Solvent Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15.5 °C): 0.82 - 0.9
Product Name: MIDDLE DISTILLATE
Revision Date: 26 Nov 2014 Page 6 of 11
______________________________________________________________________________________________________________________
Flash Point [Method]: >40°C (104°F) [ASTM D-93] Flammable Limits (Approximate volume % in air): LEL: 0.7 UEL: 6.5 Autoignition Temperature: N/D Boiling Point / Range: 150°C (302°F) - 370°C (698°F) Vapour Density (Air = 1): 4 at 101 kPa Vapour Pressure: [N/D at 20°C] | 4 kPa (30 mm Hg) at 38°C Evaporation Rate (n-butyl acetate = 1): < 1 pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): N/D Solubility in Water: Negligible Viscosity: 1.3 cSt (1.3 mm2/sec) at 40ºC - 11 cSt (11 mm2/sec) at 40ºC Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
Freezing Point: N/D Melting Point: N/A Pour Point: -4°C (25°F) - -39°C (-38°F) Decomposition Temperature: N/D
SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation
Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures.
Based on assessment of the components.
Ingestion Toxicity (Rat): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials.
Skin Toxicity (Rabbit): LD50 > 2000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials. Irritation: Data available. Moderately irritating to skin with prolonged exposure.
Eye Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on
assessment of the components.
Product Name: MIDDLE DISTILLATE
Revision Date: 26 Nov 2014 Page 7 of 11
______________________________________________________________________________________________________________________
CHRONIC/OTHER EFFECTS For the product itself:
Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Diesel exhaust fumes: Carcinogenic in animal tests. Inhalation exposures to exhaust for 2 years in test animals resulted in lung tumours and lymphoma. Extract of particulate produced skin tumours in test animals. Caused mutations in-vitro. Diesel fuel: Carcinogenic in animal tests. Caused mutations in-vitro. Repeated dermal exposures to high concentrations in test animals resulted in reduced litter size and litter weight, and increased fetal resorptions at maternally toxic doses. Dermal exposure to high concentrations resulted in severe skin irritation with weight loss and some mortality. Inhalation exposure to high concentrations resulted in respiratory tract irritation, lung changes/infiltration/accumulation, and reduction in lung function. Contains: NAPHTHALENE: Exposure to high concentrations of naphthalene may cause destruction of red blood cells, anemia, and cataracts. Naphthalene caused cancer in laboratory animal studies, but the relevance of these findings to humans is uncertain.
CMR Status: Chemical Name CAS Number List Citations FUEL OIL NO. 2 68476-30-2 4 NAPHTHALENE 91-20-3 3, 4
--REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic
environment. MOBILITY More volatile component -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment
and wastewater solids. High molecular wt. component -- Low solubility and floats and is expected to migrate from water to the
land. Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Hydrocarbon component -- Expected to be inherently biodegradable Atmospheric Oxidation: More volatile component -- Expected to degrade rapidly in air BIOACCUMULATION POTENTIAL
Product Name: MIDDLE DISTILLATE
Revision Date: 26 Nov 2014 Page 8 of 11
______________________________________________________________________________________________________________________
Hydrocarbon component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.
SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products.
REGULATORY DISPOSAL INFORMATION Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION LAND (TDG)
Proper Shipping Name: FUEL OIL Hazard Class & Division: 3 UN Number: 1202 Packing Group: III
LAND (DOT)
Proper Shipping Name: HEATING OIL, LIGHT Hazard Class & Division: 3 ID Number: 1202 Packing Group: III ERG Number: 128 Label(s): 3 Transport Document Name: UN1202, HEATING OIL, LIGHT, 3, PG III Footnote: The flash point of this material is greater than 38ºC/100ºF. Regulatory classification of this material varies. DOT: Flammable liquid or combustible liquid. OSHA: Combustible liquid. IATA/IMO: Flammable liquid.
SEA (IMDG)
Proper Shipping Name: HEATING OIL, LIGHT Hazard Class & Division: 3 EMS Number: F-E, S-E
Product Name: MIDDLE DISTILLATE
Revision Date: 26 Nov 2014 Page 9 of 11
______________________________________________________________________________________________________________________
UN Number: 1202 Packing Group: III Label(s): 3 Transport Document Name:
AIR (IATA)
Proper Shipping Name: HEATING OIL, LIGHT Hazard Class & Division: 3 UN Number: 1202 Packing Group: III Label(s) / Mark(s): 3 Transport Document Name:
SECTION 15 REGULATORY INFORMATION WHMIS Classification: Class B, Division 3: Combustible Liquids Class D, Division 2, Subdivision B: Toxic Material This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Listed or exempt from listing/notification on the following chemical inventories: DSL, TSCA The Following Ingredients are Cited on the Lists Below: Chemical Name CAS Number List Citations NAPHTHALENE 91-20-3 5
--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 05: Hazardous Combustion Products information was modified. Section 15: National Chemical Inventory Listing - Header information was modified. Section 08: Exposure Limits Table information was modified. SYNONYMS: DIESEL REGULAR SULPHUR RAIL #3, ULTRA LOW SULPHUR DIESEL, DIESEL MARINE,
Product Name: MIDDLE DISTILLATE
Revision Date: 26 Nov 2014 Page 10 of 11
______________________________________________________________________________________________________________________
DIESEL LOW SULPHUR RAIL, DIESEL LOW SULPHUR, DIESEL LOW SULPHUR DYED, DIESEL MARINE GAS OIL, DIESEL REGULAR SULPHUR, DIESEL REGULAR SULPHUR RAIL, DIESEL REGULAR SULPHUR DYED, ESSO DIESEL FUEL, DIESEL REGULAR SULPHUR RAIL DYED, ESSO HEATING OIL, FURNACE FUEL DYED, FURNACE FUEL, ISO 8217 DMA, ISO 8217 DMB, NO. 2 FUEL OIL, REGULAR SULPHUR DIESEL FUEL, DIESEL MARINE DYED, DIESEL MARINE GAS OIL INTERNATIONAL, DIESEL MARINE GAS OIL DYED, DIESEL FUEL, AUTOMOTIVE (ON-ROAD) DIESEL FUEL, FURNACE LOW S DYED, FURNACE LOW S, DIESEL MARINE - NLA DYED, DIESEL LOW SULPHUR RAIL DYED, DIESEL MARINE CGSB-3.11, DIESEL MARINE CGSB DYED, NAVAL DISTILLATE FUEL ----------------------------------------------------------------------------------------------------------------------------------------------------- PRECAUTIONARY LABEL TEXT: WHMIS Classification: Class B, Division 3: Combustible Liquids Class D, Division 2, Subdivision B: Toxic Material HEALTH HAZARDS Irritating to skin. If swallowed, may be aspirated and cause lung damage. Target Organs: Skin | PHYSICAL HAZARDS In use, may form flammable/explosive vapour-air mixture. Combustible. Material can accumulate static charges which may cause an ignition. PRECAUTIONS Avoid contact with skin. Do not siphon by mouth. Use proper bonding and/or earthing procedures.However, bonding and earthing may not eliminate the hazard from static accumulation. FIRST AID Eye: Flush thoroughly with water. If irritation occurs, get medical assistance. Oral: Seek immediate medical attention. Do not induce vomiting. Skin: Remove contaminated clothing. Dry wipe exposed skin and cleanse with waterless hand cleaner and follow by washing thoroughly with soap and water. For those providing assistance, avoid further skin contact to yourself or others. Wear impervious gloves. Launder contaminated clothing separately before reuse. Discard contaminated articles that cannot be laundered. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. FIRE FIGHTING MEDIA Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPILL/LEAK Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Eliminate sources of ignition. Remove from the surface by skimming or with suitable absorbents. Report spills as required to appropriate authorities. Seek the advice of a specialist before using dispersants.
Product Name: MIDDLE DISTILLATE
Revision Date: 26 Nov 2014 Page 11 of 11
______________________________________________________________________________________________________________________
----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 5000908 (1004214) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety
Product Name: UNIREX EP 0
Revision Date: 10 Nov 2014 Page 1 of 8
______________________________________________________________________________________________________________________
MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT
Product Name: UNIREX EP 0 Product Description: Base Oil and Additives MSDS Number: 8386 Product Code: 2015A020W020 Intended Use: Grease
COMPANY IDENTIFICATION
Supplier: Imperial Oil Downstream 240 4th Avenue Calgary, ALBERTA. T2P 3M9 Canada
24 Hour Environmental / Health Emergency Telephone
1-866-232-9563
Transportation Emergency Phone Number 1-866-232-9563 Product Technical Information 1-800-268-3183 Supplier General Contact 1-800-567-3776
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 3 HAZARDS IDENTIFICATION This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH EFFECTS
Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
NFPA Hazard ID: Health: 2 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 2 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION
Under normal conditions of intended use, this material is not expected to be an inhalation hazard.
Product Name: UNIREX EP 0
Revision Date: 10 Nov 2014 Page 2 of 8
______________________________________________________________________________________________________________________
SKIN CONTACT
Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION
First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Aldehydes, Oxides of carbon, Smoke, Fume, Sulphur oxides, Incomplete combustion products
FLAMMABILITY PROPERTIES
Flash Point [Method]: 174°C (345°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: >260°C (500°F)
SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
PROTECTIVE MEASURES
Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders.
Product Name: UNIREX EP 0
Revision Date: 10 Nov 2014 Page 3 of 8
______________________________________________________________________________________________________________________
For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended.
SPILL MANAGEMENT Land Spill: Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Skim from surface Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7 HANDLING AND STORAGE HANDLING
Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator.
STORAGE
Do not store in open or unlabelled containers. Keep away from incompatible materials. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.
PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use
Product Name: UNIREX EP 0
Revision Date: 10 Nov 2014 Page 4 of 8
______________________________________________________________________________________________________________________
with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:
Chemical resistant gloves are recommended. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:
Chemical/oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping.
ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION
Physical State: Solid Form: Semi-fluid Colour: Dark Green Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density: 0.93 Flash Point [Method]: 174°C (345°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0 Autoignition Temperature: >260°C (500°F)
Product Name: UNIREX EP 0
Revision Date: 10 Nov 2014 Page 5 of 8
______________________________________________________________________________________________________________________
Boiling Point / Range: 293°C (559°F) Vapour Density (Air = 1): > 5 at 101 kPa Vapour Pressure: < 0.01 kPa (0.08 mm Hg) at 20ºC Evaporation Rate (n-butyl acetate = 1): < 0.01 pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: >20 cSt (20 mm2/sec) at 40ºC Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
Freezing Point: N/D Melting Point: N/D DMSO Extract (mineral oil only), IP-346: < 3 %wt Decomposition Temperature: N/D NOTE: Most physical properties above are for the oil component in the material.
SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation
Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures.
Ingestion Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components.
Skin Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on
assessment of the components.
Eye Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on
assessment of the components. CHRONIC/OTHER EFFECTS For the product itself:
Product Name: UNIREX EP 0
Revision Date: 10 Nov 2014 Page 6 of 8
______________________________________________________________________________________________________________________
An ingredient or ingredients that are classified as a skin sensitizer. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
CMR Status: None.
--REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land.
Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may
reduce the bioconcentration or limit bioavailability.
SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS
Suitable routes of disposal are supervised incineration, preferentially with energy recovery, or appropriate recycling methods in accordance with applicable regulations and material characteristics at the time of disposal .
Product Name: UNIREX EP 0
Revision Date: 10 Nov 2014 Page 7 of 8
______________________________________________________________________________________________________________________
REGULATORY DISPOSAL INFORMATION Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION LAND (TDG): Not Regulated for Land Transport
LAND (DOT): Not Regulated for Land Transport
SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code
AIR (IATA): Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION WHMIS Classification: Not controlled This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, IECSC, TSCA The Following Ingredients are Cited on the Lists Below: Chemical Name CAS Number List Citations ZINC DITHIOPHOSPHATE 68649-42-3 6
--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION
Product Name: UNIREX EP 0
Revision Date: 10 Nov 2014 Page 8 of 8
______________________________________________________________________________________________________________________
N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 16: Not determined, Not applicable information was modified. Section 09: Vapour Pressure information was modified. Hazard Identification: NFPA Health information was modified. Hazard Identification: HMIS Health information was modified. Section 05: Hazardous Combustion Products information was modified. Section 15: National Chemical Inventory Listing - Header information was modified. Section 15: National Chemical Inventory Listing information was modified. Section 12: Ecological Information - Acute Aquatic Toxicity information was added. Section 12: Ecological Information - Acute Aquatic Toxicity information was added. Section 12: Ecological Information - Acute Aquatic Toxicity information was deleted. Section 12: Ecological Information - Acute Aquatic Toxicity information was deleted. ----------------------------------------------------------------------------------------------------------------------------------------------------- WHMIS Classification: Not controlled ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 5007339 (1011757) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety
Product Name: UNIREX EP 2
Revision Date: 29 Nov 2012 Page 1 of 9
______________________________________________________________________________________________________________________
MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT
Product Name: (see Section 16 for Synonyms) UNIREX EP 2 Product Description: Base Oil and Additives MSDS Number: 20444 Product Code: 2015A0207210 Intended Use: Grease
COMPANY IDENTIFICATION
Supplier: Imperial Oil Products Division 240 4th Avenue Calgary, ALBERTA. T2P 3M9 Canada
24 Hour Environmental / Health Emergency Telephone
1-866-232-9563
Transportation Emergency Phone Number 1-866-232-9563 Product Technical Information 1-800-268-3183 Supplier General Contact 1-800-567-3776
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS No Reportable Hazardous Substance(s) or Complex Substance(s). SECTION 3 HAZARDS IDENTIFICATION This material is not considered to be hazardous according to regulatory guidelines see Section 15.
HEALTH EFFECTS
Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
NFPA Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 0 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION
Under normal conditions of intended use, this material is not expected to be an inhalation hazard.
Product Name: UNIREX EP 2
Revision Date: 29 Nov 2012 Page 2 of 9
______________________________________________________________________________________________________________________
SKIN CONTACT
Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION
First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulphur oxides, Incomplete combustion products, Oxides of carbon
FLAMMABILITY PROPERTIES
Flash Point [Method]: >200°C (392°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: N/D
SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
PROTECTIVE MEASURES
Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders.
Product Name: UNIREX EP 2
Revision Date: 29 Nov 2012 Page 3 of 9
______________________________________________________________________________________________________________________
For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended.
SPILL MANAGEMENT Land Spill: Allow spilled material to solidify and shovel it up into a suitable container for recycle or disposal. Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Skim from surface Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7 HANDLING AND STORAGE HANDLING
Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator.
STORAGE
Do not store in open or unlabelled containers. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.
PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications,
Product Name: UNIREX EP 2
Revision Date: 29 Nov 2012 Page 4 of 9
______________________________________________________________________________________________________________________
handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:
Chemical resistant gloves are recommended. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:
Chemical/oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping.
ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION
Physical State: Solid Form: Semi-fluid Colour: Green Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density: 0.89 Flash Point [Method]: >200°C (392°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D
Product Name: UNIREX EP 2
Revision Date: 29 Nov 2012 Page 5 of 9
______________________________________________________________________________________________________________________
Autoignition Temperature: N/D Boiling Point / Range: N/D Vapour Density (Air = 1): N/D Vapour Pressure: < 0.01 kPa (0.08 mm Hg) at 20ºC Evaporation Rate (n-butyl acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 Solubility in Water: Negligible Viscosity: 220 cSt (220 mm2/sec) at 40ºC | 18.5 cSt (18.5 mm2/sec) at 100°C Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
Freezing Point: N/D Melting Point: >260°C (500°F) DMSO Extract (mineral oil only), IP-346: < 3 %wt NOTE: Most physical properties above are for the oil component in the material.
SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation
Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Not determined. Based on assessment of the components.
Ingestion Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components.
Skin Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Negligible irritation to skin at ambient temperatures. Based on
assessment of the components.
Eye Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on
assessment of the components. CHRONIC/OTHER EFFECTS For the product itself:
Product Name: UNIREX EP 2
Revision Date: 29 Nov 2012 Page 6 of 9
______________________________________________________________________________________________________________________
An ingredient or ingredients that are classified as a skin sensitizer. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
Additional information is available by request. CMR Status: None.
--REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to
partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may
reduce the bioconcentration or limit bioavailability.
SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products.
REGULATORY DISPOSAL INFORMATION Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain
Product Name: UNIREX EP 2
Revision Date: 29 Nov 2012 Page 7 of 9
______________________________________________________________________________________________________________________
residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION LAND (TDG): Not Regulated for Land Transport
LAND (DOT): Not Regulated for Land Transport
SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code
AIR (IATA): Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION WHMIS Classification: Not controlled This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Complies with the following national/regional chemical inventory requirements: AICS, DSL, IECSC, TSCA The Following Ingredients are Cited on the Lists Below: Chemical Name CAS Number List Citations ZINC DITHIOPHOSPHATE 68649-42-3 6
--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable
Product Name: UNIREX EP 2
Revision Date: 29 Nov 2012 Page 8 of 9
______________________________________________________________________________________________________________________
THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 09: Vapour Pressure was modified. Section 15: Canadian List Citations Table was modified. Section 04: First Aid Skin was modified. Section 11: Other Health Effects Header was modified. Section 13: Disposal Considerations - Disposal Recommendations was modified. Section 06: Accidental Release - Protective Measures - Header was added. Hazard Identification: Health Hazards was modified. Section 11: Dermal Lethality Test Data was modified. Section 11: Dermal Lethality Test Comment was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Inhalation Lethality Test Data was modified. Section 11: Dermal Irritation Test Data was modified. Section 11: Eye Irritation Test Data was modified. Section 11: Oral Lethality Test Comment was modified. Section 09: Flash Point C(F) was modified. Section 09 Viscosity was modified. Section 09 Viscosity was modified. Section 08: Hand Protection was modified. Section 08: Skin and Body Protection was modified. Section 11: Skin Irritation Conclusion was modified. Section 09: Melting Point C(F) was modified. Section 11: Other Health Effects was added. Section 12: Ecological Information - Acute Aquatic Toxicity was added. Section 12: Ecological Information - Acute Aquatic Toxicity was deleted. Section 12: Ecological Information - Acute Aquatic Toxicity was added. Section 12: Ecological Information - Acute Aquatic Toxicity was deleted. Section 01: Company Contact Methods Sorted by Priority was modified. Section 06: Protective Measures was modified. SYNONYMS: Unirex EP 2 Electroluber ----------------------------------------------------------------------------------------------------------------------------------------------------- WHMIS Classification: Not controlled ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 7091356 (1015501) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety
Product Name: UNIREX EP 2
Revision Date: 29 Nov 2012 Page 9 of 9
______________________________________________________________________________________________________________________
Product Name: UNLEADED GASOLINE
Revision Date: 23 Feb 2015 Page 1 of 13
______________________________________________________________________________________________________________________
MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT
Product Name: (see Section 16 for Synonyms) UNLEADED GASOLINE Product Description: Hydrocarbons and Additives MSDS Number: 8522 Intended Use: Fuel
COMPANY IDENTIFICATION
Supplier: Imperial Oil Downstream 240 4th Avenue Calgary, ALBERTA. T2P 3M9 Canada
24 Hour Environmental / Health Emergency Telephone
1-866-232-9563
Transportation Emergency Phone Number 1-866-232-9563 Product Technical Information 1-800-268-3183 Supplier General Contact 1-800-567-3776
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# Concentration* Acute Toxicity ETHYL ALCOHOL 64-17-5 0 - 1% None GASOLINE 86290-81-5 > 99 % None METHYL-TERT-BUTYL ETHER 1634-04-4 0 - 1% Oral Lethality: LD50 4000
mg/kg (Rat) Hazardous Constituent(s) Contained in Complex Substance(s) Name CAS# Concentration* Acute Toxicity BENZENE 71-43-2 0 - 1.5% None CUMENE 98-82-8 0 - 1% None CYCLOHEXANE 110-82-7 0 - 1.5% None ETHYL BENZENE 100-41-4 0 - 3.5% Inhalation Lethality: LC50
17.8 mg/l (Rat); Oral Lethality: LD50 3.5 g/kg (Rat)
n-Hexane 110-54-3 0 - 5% None NAPHTHALENE 91-20-3 0 - 1% Inhalation Lethality: LC50 >
0.4 mg/l (Rat); Oral Lethality: LD50 710 mg/kg (Mouse); Oral Lethality: LD50 533 mg/kg (Mouse)
TOLUENE 108-88-3 0 - 20% None XYLENES 1330-20-7 0 - 20% None * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
Product Name: UNLEADED GASOLINE
Revision Date: 23 Feb 2015 Page 2 of 13
______________________________________________________________________________________________________________________
NOTE: The concentration of the components shown above may vary substantially. In certain countries, benzene content may be limited to lower levels. Oxygenates such as tertiary-amyl-methyl ether, ethanol, di-isopropyl ether, and ethyl-tertiary-butyl ether may be present. Because of volatility considerations, gasoline vapor may have concentrations of components very different from those of liquid gasoline. The major components of gasoline vapor are: butane, isobutane, pentane, and isopentane. The reportable component percentages, shown in the composition/information on ingredients section, are based on API's evaluation of a typical gasoline mixture. SECTION 3 HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). PHYSICAL/CHEMICAL EFFECTS
FLAMMABLE. Material can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited. Material can accumulate static charges which may cause an ignition.
HEALTH EFFECTS
May cause cancer. Repeated exposure may cause skin dryness or cracking. If swallowed, may be aspirated and cause lung damage. May be irritating to the eyes, nose, throat, and lungs. May cause central nervous system depression. High-pressure injection under skin may cause serious damage. Exposure to benzene is associated with cancer (acute myeloid leukaemia and myelodysplastic syndrome), damage to the blood-producing system, and serious blood disorders (see Section 11).
NFPA Hazard ID: Health: 1 Flammability: 3 Reactivity: 0 HMIS Hazard ID: Health: 1* Flammability: 3 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.
SKIN CONTACT
Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION
Seek immediate medical attention. Do not induce vomiting. NOTE TO PHYSICIAN
If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately.
Product Name: UNLEADED GASOLINE
Revision Date: 23 Feb 2015 Page 3 of 13
______________________________________________________________________________________________________________________
This light hydrocarbon material, or a component, may be associated with cardiac sensitisation following very high exposures (well above occupational exposure limits) or with concurrent exposure to high stress levels or heart-stimulating substances like epinephrine. Administration of such substances should be avoided.
SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. If a leak or spill has not ignited, use water spray to disperse the vapours and to protect personnel attempting to stop a leak. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Extremely Flammable. Vapour is flammable and heavier than air. Vapour may travel across the ground and reach remote ignition sources, causing a flashback fire danger. Hazardous Combustion Products: Sulphur oxides, Aldehydes, Oxides of carbon, Incomplete combustion products, Smoke, Fume
FLAMMABILITY PROPERTIES
Flash Point [Method]: -40°C (-40°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 1.4 UEL: 7.6 Autoignition Temperature: >250°C (482°F)
SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
PROTECTIVE MEASURES
Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: half-face or full-face respirator with filter(s) for organic vapor and, when applicable, H2S, or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to aromatic hydrocarbons are recommended. Note: gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills:
Product Name: UNLEADED GASOLINE
Revision Date: 23 Feb 2015 Page 4 of 13
______________________________________________________________________________________________________________________
full body suit of chemical resistant, antistatic material is recommended.
SPILL MANAGEMENT Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed material. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills: Water spray may reduce vapour, but may not prevent ignition in enclosed spaces. Water Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. Do not confine in area of spill. Advise occupants and shipping in downwind areas of fire and explosion hazard and warn them to stay clear. Allow liquid to evaporate from the surface. Seek the advice of a specialist before using dispersants. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7 HANDLING AND STORAGE HANDLING
Avoid breathing mists or vapour. Avoid all personal contact. Prevent exposure to ignition sources, for example use non-sparking tools and explosion-proof equipment. Potentially toxic/irritating fumes/vapour may be evolved from heated or agitated material. Do not siphon by mouth. Use only with adequate ventilation. Do not use as a cleaning solvent or other non-motor fuel uses. For use as a motor fuel only. It is dangerous and/or unlawful to put petrol into unapproved containers. Do not fill container while it is in or on a vehicle. Static electricity may ignite vapour and cause fire. Place container on ground when filling and keep nozzle in contact with container. Do not use electronic devices (including but not limited to cellular phones, computers, calculators, pagers or other electronic devices etc) in or around any fuelling operation or storage area unless the devices are certified intrinsically safe by an approved national testing agency and to the safety standards required by national and/or local laws and regulations. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity). Static Accumulator: This material is a static accumulator. A liquid is typically considered a nonconductive, static accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens per meter) and is considered a semiconductive, static accumulator if its conductivity is below 10,000 pS/m. Whether a liquid is nonconductive or semiconductive, the precautions are the same. A number of factors, for example liquid temperature, presence of contaminants, anti-static additives and filtration can greatly influence the conductivity of a liquid.
STORAGE
Ample fire water supply should be available. A fixed sprinkler/deluge system is recommended. The container
Product Name: UNLEADED GASOLINE
Revision Date: 23 Feb 2015 Page 5 of 13
______________________________________________________________________________________________________________________
choice, for example storage vessel, may effect static accumulation and dissipation. Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated area. Outside or detached storage preferred. Storage containers should be earthed and bonded. Fixed storage containers, transfer containers and associated equipment should be grounded and bonded to prevent accumulation of static charge.
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Substance Name Form Limit/Standard Note Source BENZENE STEL 1 ppm Supplier BENZENE TWA 0.5 ppm Supplier BENZENE STEL 2.5 ppm Skin ACGIH BENZENE TWA 0.5 ppm Skin ACGIH CUMENE TWA 50 ppm ACGIH CYCLOHEXANE TWA 100 ppm ACGIH ETHYL ALCOHOL STEL 1000 ppm ACGIH ETHYL BENZENE TWA 20 ppm ACGIH GASOLINE STEL 200 ppm Supplier GASOLINE TWA 100 ppm Supplier GASOLINE Vapour. TWA 300 mg/m3 100 ppm Supplier GASOLINE STEL 500 ppm ACGIH GASOLINE TWA 300 ppm ACGIH METHYL-TERT-BUTYL ETHER TWA 50 ppm ACGIH n-Hexane TWA 50 ppm Skin ACGIH NAPHTHALENE TWA 10 ppm Skin ACGIH TOLUENE TWA 20 ppm ACGIH XYLENES STEL 150 ppm ACGIH XYLENES TWA 100 ppm ACGIH
NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:
Use explosion-proof ventilation equipment to stay below exposure limits.
PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
No protection is ordinarily required under normal conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Product Name: UNLEADED GASOLINE
Revision Date: 23 Feb 2015 Page 6 of 13
______________________________________________________________________________________________________________________
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:
Chemical resistant gloves are recommended. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:
Chemical/oil resistant clothing is recommended. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping.
ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION
Physical State: Liquid Colour: Clear (May Be Dyed) Odour: Petroleum/Solvent Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 °C): 0.74 Flash Point [Method]: -40°C (-40°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 1.4 UEL: 7.6 Autoignition Temperature: >250°C (482°F) Boiling Point / Range: > 20°C (68°F) - 225°C (437°F) Vapour Density (Air = 1): 3.2 at 101 kPa Vapour Pressure: > 26.6 kPa (200 mm Hg) at 20ºC | 76 kPa (570 mm Hg) at 38 °C - 103 kPa (772.5 mm Hg) at 38°C Evaporation Rate (n-butyl acetate = 1): > 10 pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3 Solubility in Water: Negligible Viscosity: <1 cSt (1 mm2/sec) at 40ºC Oxidizing Properties: See Hazards Identification Section.
Product Name: UNLEADED GASOLINE
Revision Date: 23 Feb 2015 Page 7 of 13
______________________________________________________________________________________________________________________
OTHER INFORMATION
Freezing Point: N/D Melting Point: N/A Decomposition Temperature: N/D
SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources. MATERIALS TO AVOID: Halogens, Strong Acids, Alkalies, Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation
Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Elevated temperatures or mechanical action may form vapours,
mist, or fumes which may be irritating to the eyes, nose, throat, or lungs.
Ingestion
Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components.
Skin Toxicity: No end point data for material. Minimally Toxic. Based on assessment of the components. Irritation: No end point data for material. Mildly irritating to skin with prolonged exposure. Based on
assessment of the components.
Eye Irritation: No end point data for material. May cause mild, short-lasting discomfort to eyes. Based on
assessment of the components. CHRONIC/OTHER EFFECTS For the product itself:
Laboratory animal studies have shown that prolonged and repeated inhalation exposure to light hydrocarbon vapours in the same boiling range as this product can produce adverse kidney effects in male rats. However, these effects were not observed in similar studies with female rats, male and female mice, or in limited studies with other animal species. Additionally, in a number of human studies, there was no clinical evidence of such effects at normal occupational levels. In 1991, The U.S. EPA determined that the male rat kidney is not useful for assessing human risk. Vapour concentrations above recommended exposure levels are irritating to the eyes and the respiratory tract, may cause headaches and dizziness, are anaesthetic and may have other central nervous system effects. Small amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or pulmonary edema. Very high exposure (confined spaces / abuse) to light hydrocarbons may result in abnormal heart rhythm (arrhythmias). Concurrent high stress levels and/or co-exposure to high levels of hydrocarbons (above occupational exposure limits), and to
Product Name: UNLEADED GASOLINE
Revision Date: 23 Feb 2015 Page 8 of 13
______________________________________________________________________________________________________________________
heart-stimulating substances like epinephrine, nasal decongestants, asthma drugs, or cardiovascular drugs may initiate arrhythmias. Contains: BENZENE: Caused cancer (acute myeloid leukemia and myelodysplastic syndrome), damage to the blood-producing system, and serious blood disorders in human studies. Caused genetic effects and effects on the immune system in laboratory animal and some human studies. Caused toxicity to the fetus and cancer in laboratory animal studies. CUMENE: Repeated inhalation exposure of cumene vapour produced damage in the kidney of male rats only. These effects are believed to be species specific and are not relevant to humans. ETHANOL: Prolonged or repeated exposure to high concentrations of ethanol vapour or overexposure by ingestion may produce adverse effects to brain, kidney, liver, and reproductive organs, birth defects in offspring, and developmental toxicity in offspring. GASOLINE UNLEADED: Carcinogenic in animal tests. Chronic inhalation studies resulted in liver tumours in female mice and kidney tumours in male rats. Neither result considered significant for human health risk assessment by the United States EPA and others. Did not cause mutations in-vitro or in-vivo. Negative in inhalation developmental studies and reproductive tox studies. Inhalation of high concentrations in animals resulted in reversible central nervous system depression, but no persistent toxic effect on the nervous system. Non-sensitizing in test animals. Caused nerve damage in humans from abusive use (sniffing). METHYL TERTIARY BUTYL ETHER (MTBE): Carcinogenic in animal tests. Inhalation exposure to high concentrations resulted in higher than expected mortality in male mice due to urinary tract obstructions and female mice displayed benign liver tumours. Inhalation exposure to high concentrations resulted in higher than expected mortality in male rats due to progressive kidney damage as well as increased benign and malignant kidney tumours, and benign testicular tumours. Did not cause mutations in-vitro or in-vivo. Rabbits exposed to high vapour concentrations did not have any offspring with adverse developmental effects. Mice exposed to high vapour concentrations (maternally toxic) had offspring with embryo/fetal toxicity and birth defects. Rats exposed to high vapour concentrations did not display any treatment-related effects in a two generation reproduction study.The significance of the animal findings at high exposures are not believed to be directly related to potential human health hazards in the workplace. NAPHTHALENE: Exposure to high concentrations of naphthalene may cause destruction of red blood cells, anemia, and cataracts. Naphthalene caused cancer in laboratory animal studies, but the relevance of these findings to humans is uncertain. N-HEXANE: Prolonged and/or repeated exposures to n-Hexane can cause progressive and potentially irreversible damage to the peripheral nervous system (e.g. fingers, feet, arms, legs, etc.). Simultaneous exposure to Methyl Ethyl Ketone (MEK) or Methyl Isobutyl Ketone (MIBK) and n-Hexane can potentiate the risk of adverse effects from n-Hexane on the peripheral nervous system. n-Hexane has been shown to cause testicular damage at high doses in male rats. The relevance of this effect for humans is unknown. TOLUENE : Concentrated, prolonged or deliberate inhalation may cause brain and nervous system damage. Prolonged and repeated exposure of pregnant animals (> 1500 ppm) have been reported to cause adverse fetal developmental effects. ETHYLBENZENE: Caused cancer in laboratory animal studies. The relevance of these findings to humans is uncertain. XYLENES: High exposures to xylenes in some animal studies have been reported to cause health effects on the developing embryo/fetus. These effects were often at levels toxic to the mother. The significance of these findings to humans has not been determined.
CMR Status: Chemical Name CAS Number List Citations BENZENE 71-43-2 1, 4, 5 CUMENE 98-82-8 3, 4 CYCLOHEXANE 110-82-7 4 ETHYL ALCOHOL 64-17-5 4 ETHYL BENZENE 100-41-4 3, 4 GASOLINE 86290-81-5 3, 4
Product Name: UNLEADED GASOLINE
Revision Date: 23 Feb 2015 Page 9 of 13
______________________________________________________________________________________________________________________
METHYL-TERT-BUTYL ETHER 1634-04-4 4 n-Hexane 110-54-3 4 NAPHTHALENE 91-20-3 3, 4 TOLUENE 108-88-3 4 XYLENES 1330-20-7 4
--REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic
environment. MOBILITY More volatile component -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment
and wastewater solids. Less volatile component -- Low solubility and floats and is expected to migrate from water to the land.
Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Majority of components -- Expected to be inherently biodegradable Atmospheric Oxidation: More volatile component -- Expected to degrade rapidly in air BIOACCUMULATION POTENTIAL Majority of components -- Has the potential to bioaccumulate, however metabolism or physical properties
may reduce the bioconcentration or limit bioavailability.
SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products.
Product Name: UNLEADED GASOLINE
Revision Date: 23 Feb 2015 Page 10 of 13
______________________________________________________________________________________________________________________
REGULATORY DISPOSAL INFORMATION Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION LAND (TDG)
Proper Shipping Name: GASOLINE Hazard Class & Division: 3 UN Number: 1203 Packing Group: II Marine Pollutant: Yes Special Provisions: 17 Footnote: Marine Pollutant designation is applicable only if shipped over water.
LAND (DOT)
Proper Shipping Name: GASOLINE Hazard Class & Division: 3 ID Number: 1203 Packing Group: II ERG Number: 128 Label(s): 3 Transport Document Name: UN1203, GASOLINE, 3, PG II
SEA (IMDG)
Proper Shipping Name: MOTOR SPIRIT or GASOLINE or PETROL Hazard Class & Division: 3 EMS Number: F-E, S-E UN Number: 1203 Packing Group: II Label(s): 3 Transport Document Name: UN1203, MOTOR SPIRIT or GASOLINE or PETROL, 3, PG II, (-40°C c.c.)
AIR (IATA)
Proper Shipping Name: MOTOR SPIRIT or GASOLINE or PETROL Hazard Class & Division: 3 UN Number: 1203 Packing Group: II Label(s) / Mark(s): 3 Transport Document Name: UN1203, GASOLINE, 3, PG II
SECTION 15 REGULATORY INFORMATION WHMIS Classification: Class B, Division 2: Flammable Liquids Class D, Division 2, Subdivision A: Very Toxic Material
Product Name: UNLEADED GASOLINE
Revision Date: 23 Feb 2015 Page 11 of 13
______________________________________________________________________________________________________________________
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Listed or exempt from listing/notification on the following chemical inventories: AICS, DSL, ENCS, KECI, PICCS, TSCA The Following Ingredients are Cited on the Lists Below: Chemical Name CAS Number List Citations BENZENE 71-43-2 6 CUMENE 98-82-8 6 CYCLOHEXANE 110-82-7 6 ETHYL BENZENE 100-41-4 6 METHYL-TERT-BUTYL ETHER 1634-04-4 6 n-Hexane 110-54-3 6 NAPHTHALENE 91-20-3 6 TOLUENE 108-88-3 6 XYLENES 1330-20-7 6
--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 05: Hazardous Combustion Products information was modified. Section 15: National Chemical Inventory Listing - Header information was modified. Composition: Component table information was modified. Composition: Component table information was modified. Section 08: Exposure Limits Table information was modified. SYNONYMS: GASOLINE REGULAR UNLEADED RUL87 DCA DYED, GASOLINE PREMIUM UNLEADED PUL91 DCA, GASOLINE PREMIUM UNLEADED PUL91 LDCA, GASOLINE PREMIUM UNLEADED PUL91 LDCA DYED, ISOOCTANE, AUTOMOTIVE GASOLINE, ESSO SUPREME GASOLINE, GASOLINE REGULAR UNLEADED RUL87 LDCA DYED, ESSO EXTRA GASOLINE, GASOLINE REGULAR UNLEADED RUL87 LDCA, EXXON MIDGRADE GASOLINE, ESSO PREMIUM GASOLINE, ESSO MIDGRADE GASOLINE, ESSO REGULAR GASOLINE, GASOLINE MIDGRADE UNLEADED MUL89 DCA, EXXON REGULAR GASOLINE, GASOLINE MIDGRADE UNLEADED MUL89, EXXON PREMIUM GASOLINE, GASOLINE REGULAR UNLEADED RUL87 DYED, GASOLINE MIDGRADE
Product Name: UNLEADED GASOLINE
Revision Date: 23 Feb 2015 Page 12 of 13
______________________________________________________________________________________________________________________
UNLEADED MUL89 DCA DYED, GASOLINE REGULAR UNLEADED RUL87, GASOLINE PREMIUM UNLEADED PUL91, GASOLINE RBOB BLENDSTOCK P91, GASOLINE RBOB BLENDSTOCK R87, GASOLINE MIDGRADE UNLEADED MUL89 LDCA, GASOLINE MIDGRADE UNLEADED MUL89 LDCA DYED, GASOLINE REGULAR UNLEADED RUL87 DCA, GASOLINE PREMIUM UNLEADED PUL91 DCA DYED ----------------------------------------------------------------------------------------------------------------------------------------------------- PRECAUTIONARY LABEL TEXT: WHMIS Classification: Class B, Division 2: Flammable Liquids Class D, Division 2, Subdivision A: Very Toxic Material HEALTH HAZARDS May cause cancer. Repeated exposure may cause skin dryness or cracking. If swallowed, may be aspirated and cause lung damage. May cause central nervous system depression. PHYSICAL HAZARDS FLAMMABLE. Material can accumulate static charges which may cause an ignition. Material can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited. PRECAUTIONS Avoid breathing mists or vapour. Avoid all personal contact. Prevent exposure to ignition sources, for example use non-sparking tools and explosion-proof equipment. Potentially toxic/irritating fumes/vapour may be evolved from heated or agitated material. Do not siphon by mouth. Use only with adequate ventilation. Use proper bonding and/or earthing procedures.However, bonding and earthing may not eliminate the hazard from static accumulation. FIRST AID Inhalation: Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Eye: Flush thoroughly with water. If irritation occurs, get medical assistance. Oral: Seek immediate medical attention. Do not induce vomiting. Skin: Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. FIRE FIGHTING MEDIA Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPILL/LEAK Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Water Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. Do not confine in area of spill. Advise occupants and shipping in downwind areas of fire and explosion hazard and warn them to stay clear. Allow liquid to evaporate from the surface. Seek the advice of a specialist before using dispersants.
Product Name: UNLEADED GASOLINE
Revision Date: 23 Feb 2015 Page 13 of 13
______________________________________________________________________________________________________________________
----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 5007481 (1006754) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety
Product Name: BLOCK GREASE S-100
Revision Date: 10 Sep 2012 Page 1 of 9
______________________________________________________________________________________________________________________
MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT
Product Name: BLOCK GREASE S-100 Product Description: Base Oil and Additives MSDS Number: 8363 Product Code: 2015A020R010 Intended Use: Grease
COMPANY IDENTIFICATION
Supplier: Imperial Oil Products Division 240 4th Avenue Calgary, ALBERTA. T2P 3M9 Canada
24 Hour Environmental / Health Emergency Telephone
1-866-232-9563
Transportation Emergency Phone Number 1-866-232-9563 Product Technical Information 1-800-268-3183 Supplier General Contact 1-800-567-3776
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# Concentration* Acute Toxicity ASPHALT (PETROLEUM) 8052-42-4 5 - 15% None ROSIN (PINE ROSIN, COLOPHONY) 8050-09-7 5 - 15% None SODIUM STEARATE 822-16-2 10 - 20% None * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 3 HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15).
HEALTH EFFECTS
May cause sensitisation by skin contact. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.
NFPA Hazard ID: Health: 2 Flammability: 1 Reactivity: 0 HMIS Hazard ID: Health: 2 Flammability: 1 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary
Product Name: BLOCK GREASE S-100
Revision Date: 10 Sep 2012 Page 2 of 9
______________________________________________________________________________________________________________________
from person to person. SECTION 4 FIRST AID MEASURES INHALATION
Under normal conditions of intended use, this material is not expected to be an inhalation hazard. SKIN CONTACT
Wash contact areas with soap and water. Remove contaminated clothing. Wash carefully behind ears, under nails and in skin folds. Get medical assistance. For those providing assistance, avoid further skin contact to yourself or others. Wear impervious gloves. Launder contaminated clothing separately before reuse. Discard contaminated articles that cannot be laundered. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.
EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance. INGESTION
First aid is normally not required. Seek medical attention if discomfort occurs.
SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water
FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Hazardous material. Firefighters should consider protective equipment indicated in Section 8. Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulphur oxides, Incomplete combustion products, Oxides of carbon
FLAMMABILITY PROPERTIES
Flash Point [Method]: 182°C (360°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: 204°C (400°F)
SECTION 6 ACCIDENTAL RELEASE MEASURES
Product Name: BLOCK GREASE S-100
Revision Date: 10 Sep 2012 Page 3 of 9
______________________________________________________________________________________________________________________
NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
PROTECTIVE MEASURES
Avoid contact with spilled material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: respiratory protection will be necessary only in special cases, e.g., formation of mists. Half-face or full-face respirator with filter(s) for dust/organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant to hydrocarbons are recommended. Gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body suit of chemical resistant, antistatic material is recommended.
SPILL MANAGEMENT Land Spill: Scrape up spilled material with shovels into a suitable container for recycle or disposal. Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Skim from surface Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7 HANDLING AND STORAGE HANDLING
Avoid contact with skin. Prevent small spills and leakage to avoid slip hazard. Static Accumulator: This material is not a static accumulator.
STORAGE
Do not store in open or unlabelled containers. Keep away from incompatible materials. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Substance Name Form Limit/Standard Note Source ASPHALT (PETROLEUM) [benzene solubles]
Inhalable fraction.
TWA 0.5 mg/m3 ACGIH
SODIUM STEARATE TWA 10 mg/m3 ACGIH
Product Name: BLOCK GREASE S-100
Revision Date: 10 Sep 2012 Page 4 of 9
______________________________________________________________________________________________________________________
NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:
No special requirements under ordinary conditions of use and with adequate ventilation.
PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:
Chemical resistant gloves are recommended. Eye Protection: If contact is likely, safety glasses with side shields are recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:
Chemical / oil resistant clothing if contact with material is likely. Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping.
ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Product Name: BLOCK GREASE S-100
Revision Date: 10 Sep 2012 Page 5 of 9
______________________________________________________________________________________________________________________
Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION
Physical State: Solid Form: Semi-fluid Colour: Brown Odour: Characteristic Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 °C): 0.9 Flash Point [Method]: 182°C (360°F) [EST. FOR OIL, ASTM D-92 (COC)] Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/D Autoignition Temperature: 204°C (400°F) Boiling Point / Range: 371°C (700°F) [Estimated] Vapour Density (Air = 1): > 2 at 101 kPa [Estimated] Vapour Pressure: < 0.013 kPa (0.1 mm Hg) at 20ºC [Estimated] Evaporation Rate (n-butyl acetate = 1): N/D pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): > 3.5 [Estimated] Solubility in Water: Negligible Viscosity: [N/D at 40°C] | 10.3 cSt (10.3 mm2/sec) at 100°C Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
Freezing Point: N/D Melting Point: N/D DMSO Extract (mineral oil only), IP-346: < 3 %wt Decomposition Temperature: N/D
SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation
Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on test data for structurally similar materials.
Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Product Name: BLOCK GREASE S-100
Revision Date: 10 Sep 2012 Page 6 of 9
______________________________________________________________________________________________________________________
Ingestion
Toxicity (Rat): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar materials.
Skin
Toxicity (Rabbit): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar materials.
Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.
Eye
Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.
CHRONIC/OTHER EFFECTS For the product itself:
Sensitisation: Allergic dermatitis in humans. The study was conducted on structurally similar material. Contains: Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
Additional information is available by request. CMR Status: None. Chemical Name CAS Number List Citations ASPHALT (PETROLEUM) 8052-42-4 4 SODIUM STEARATE 822-16-2 4
--REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Base oil component -- Low solubility and floats and is expected to migrate from water to the land.
Expected to partition to sediment and wastewater solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Base oil component -- Expected to be inherently biodegradable
Product Name: BLOCK GREASE S-100
Revision Date: 10 Sep 2012 Page 7 of 9
______________________________________________________________________________________________________________________
BIOACCUMULATION POTENTIAL Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may
reduce the bioconcentration or limit bioavailability.
SECTION 13 DISPOSAL CONSIDERATIONS Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS
If Regulated, dispose of waste in a secure hazardous waste landfill. If not regulated, dispose of as normal refuse.
REGULATORY DISPOSAL INFORMATION Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION LAND (TDG): Not Regulated for Land Transport
LAND (DOT): Not Regulated for Land Transport
SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code
AIR (IATA): Not Regulated for Air Transport
SECTION 15 REGULATORY INFORMATION WHMIS Classification: Class D, Division 2, Subdivision B: Toxic Material This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or
Product Name: BLOCK GREASE S-100
Revision Date: 10 Sep 2012 Page 8 of 9
______________________________________________________________________________________________________________________
have been notified under CEPA. Complies with the following national/regional chemical inventory requirements: AICS, DSL, ENCS, IECSC, KECI, PICCS, TSCA The Following Ingredients are Cited on the Lists Below: None.
--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATION N/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 11: Inhalation Irritation Test Data was modified. Section 14: LAND (TDG) - Header was modified. Section 15: National Chemical Inventory Listing was modified. ----------------------------------------------------------------------------------------------------------------------------------------------------- PRECAUTIONARY LABEL TEXT: WHMIS Classification: Class D, Division 2, Subdivision B: Toxic Material HEALTH HAZARDS May cause sensitisation by skin contact. PRECAUTIONS Avoid contact with skin. FIRST AID Eye: Flush thoroughly with water. If irritation occurs, get medical assistance. Skin: Wash contact areas with soap and water. Remove contaminated clothing. Wash carefully behind ears, under nails and in skin folds. Get medical assistance. For those providing assistance, avoid further skin contact to yourself or others. Wear impervious gloves. Launder contaminated clothing separately before reuse. Discard contaminated articles that cannot be laundered. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. FIRE FIGHTING MEDIA Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPILL/LEAK Land Spill: Scrape up spilled material with shovels into a suitable container for recycle or disposal.
Product Name: BLOCK GREASE S-100
Revision Date: 10 Sep 2012 Page 9 of 9
______________________________________________________________________________________________________________________
Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Report spills as required to appropriate authorities. Skim from surface Use Not intended or suitable for use in or around a household or dwelling. ----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 5007315 (1017155) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety
Product Name: COMMERCIAL PROPANE (ODORIZED)
Revision Date: 07 Jun 2013 Page 1 of 11
______________________________________________________________________________________________________________________
MATERIAL SAFETY DATA SHEET SECTION 1 PRODUCT AND COMPANY IDENTIFICATION PRODUCT
Product Name: COMMERCIAL PROPANE (ODORIZED) Product Description: Liquefied Hydrocarbon Gas, Gas or Liquefied Gas MSDS Number: 8515 Intended Use: Fuel gas
COMPANY IDENTIFICATION
Supplier: Imperial Oil Products Division 240 4th Avenue Calgary, ALBERTA. T2P 3M9 Canada
24 Hour Environmental / Health Emergency Telephone
1-866-232-9563
Transportation Emergency Phone Number 1-866-232-9563 Product Technical Information 1-800-268-3183 Supplier General Contact 1-800-567-3776
SECTION 2 COMPOSITION / INFORMATION ON INGREDIENTS Reportable Hazardous Substance(s) or Complex Substance(s) Name CAS# Concentration* Acute Toxicity ALKANES, C4 68513-65-5 0 - 2.5% None ETHANE 74-84-0 0 - 5% None ISOBUTANE 75-28-5 0 - 2.5% Inhalation Lethality: LC50 >
13000 ppm (Rat) PROPANE 74-98-6 90 - 99% None PROPYLENE 115-07-1 1 - 10% None * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. SECTION 3 HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). PHYSICAL/CHEMICAL EFFECTS
Flammable Gas. Material can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited. Frostbite hazard - rapidly expanding gas or liquid may cause frostbite. Material can accumulate static charges which may cause an ignition.
HEALTH EFFECTS
Continued exposure to odorised gas may reduce or eliminate ability to smell the odorant. People with impaired ability to detect odour due to colds, allergies, injuries etc must be especially cautious. Odour must not be used exclusively as a safety measure. Proper respiratory protection and fire/explosion precautions should be utilised when odour is first detected. Inert gas and/or simple asphyxiant. Reduces oxygen available for breathing. Exposure to concentrations above 10% of the LEL may cause a general central nervous system
Product Name: COMMERCIAL PROPANE (ODORIZED)
Revision Date: 07 Jun 2013 Page 2 of 11
______________________________________________________________________________________________________________________
(CNS) depression typical of anesthetic gases or intoxicants. Aliphatic hydrocarbon gases may build up in confined spaces and may cause dizziness, light-headedness, headache, nausea and loss of co-ordination. Continued inhalation may result in narcosis, unconsciousness, and possibly lead to death. High-pressure injection under skin may cause serious damage.
NFPA Hazard ID: Health: 1 Flammability: 4 Reactivity: 0 HMIS Hazard ID: Health: 1 Flammability: 4 Reactivity: 0 NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person. SECTION 4 FIRST AID MEASURES INHALATION
Immediately remove from further exposure. Get immediate medical assistance. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. Give supplemental oxygen, if available. If breathing has stopped, assist ventilation with a mechanical device.
SKIN CONTACT
If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. If frostbite occurs, immerse involved area in water at body temperature. Keep immersed for 20 to 40 minutes. Seek medical assistance.
EYE CONTACT
Flush thoroughly with water for at least 15 minutes. Get medical assistance. INGESTION
Not Applicable NOTE TO PHYSICIAN
This light hydrocarbon material, or a component, may be associated with cardiac sensitisation following very high exposures (well above occupational exposure limits) or with concurrent exposure to high stress levels or heart-stimulating substances like epinephrine. Administration of such substances should be avoided.
SECTION 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, dry chemical or carbon dioxide (CO2) to extinguish flames. Inappropriate Extinguishing Media: Straight streams of water
FIRE FIGHTING
Fire Fighting Instructions: Allow the fire to burn under controlled conditions. Stop leak if you can do so without risk. Evacuate area. If a leak or spill has not ignited, use water spray to disperse the vapours and to protect personnel attempting to stop a leak. Prevent run-off from fire control or dilution from entering streams,
Product Name: COMMERCIAL PROPANE (ODORIZED)
Revision Date: 07 Jun 2013 Page 3 of 11
______________________________________________________________________________________________________________________
sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel. Unusual Fire Hazards: Flammable Gas. Vapour is flammable and heavier than air. Vapour may travel across the ground and reach remote ignition sources, causing a flashback fire danger. Hazardous material. Firefighters should consider protective equipment indicated in Section 8. Hazardous Combustion Products: Incomplete combustion products, Oxides of carbon
FLAMMABILITY PROPERTIES
Flash Point [Method]: -103°C (-153°F) [ASTM D-92] Flammable Limits (Approximate volume % in air): LEL: 2.4 UEL: 9.5 Autoignition Temperature: 432°C (810°F)
SECTION 6 ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.
PROTECTIVE MEASURES
Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for advice on the minimum requirements for personal protective equipment. Additional protective measures may be necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders. For emergency responders: Respiratory protection: half-face or full-face respirator with filter(s) for organic vapor or Self Contained Breathing Apparatus (SCBA) can be used depending on the size of the spill and potential level of exposure. If the exposure cannot be completely characterized or an oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that provide chemical resistance and, when necessary, heat-resistance and/or thermal insulation are recommended. Note: gloves made of polyvinyl acetate (PVA) are not water-resistant and are not suitable for emergency use. Small spills: normal work clothes are usually adequate. Large spills: full body suit of chemical and thermal resistant material is recommended. Chemical goggles and face shield are recommended if contact with liquefied gas is possible.
SPILL MANAGEMENT Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. CAUTION: When in contact with refrigerated/cryogenic liquids, many materials become brittle and are likely to break without warning. Allow liquid to evaporate from the surface. All equipment used when handling the product must be grounded. Do not direct water at spill or source of leak. Do not touch or walk through spilled material. If possible, turn leaking containers so that gas escapes rather than liquid. Isolate area until gas has dispersed. Prevent spreading of vapour through sewers, ventilation systems and confined areas. Use water spray to reduce vapour or divert vapour cloud drift. Avoid allowing water run-off to contact spilled material. Water Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Allow liquid to evaporate from the surface. See Land Spill section of the SDS for advice on gases. Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
Product Name: COMMERCIAL PROPANE (ODORIZED)
Revision Date: 07 Jun 2013 Page 4 of 11
______________________________________________________________________________________________________________________
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS
Prevent entry into waterways, sewers, basements or confined areas.
SECTION 7 HANDLING AND STORAGE HANDLING
Prevent exposure to ignition sources, for example use non-sparking tools and explosion-proof equipment. Ethyl mercaptan is added to gas as an odorant to aid in the detection of the gas in case of leak or accidental discharge. Since ethyl mercaptan is reactive, a reduction in its effectiveness may occur during transport and storage of the odorised gas. Therefore, odour must not be used exclusively as a safety measure. Handle gas with strict adherence to established safety procedures. Use proper bonding and/or earthing procedures.However, bonding and earthing may not eliminate the hazard from static accumulation. Material can accumulate static charges which may cause an electrical spark (ignition source). Static Accumulator: This material is a static accumulator.
STORAGE
Ample fire water supply should be available. A fixed sprinkler/deluge system is recommended. The container choice, for example storage vessel, may effect static accumulation and dissipation. Keep container closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated area. Outside or detached storage preferred. Storage containers should be earthed and bonded.
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Substance Name Form Limit/Standard Note Source ISOBUTANE STEL 1000 ppm ACGIH PROPYLENE TWA 500 ppm ACGIH
NOTE: Limits/standards shown for guidance only. Follow applicable regulations. ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:
Use explosion-proof ventilation equipment to stay below exposure limits.
PERSONAL PROTECTION Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage. Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
Product Name: COMMERCIAL PROPANE (ODORIZED)
Revision Date: 07 Jun 2013 Page 5 of 11
______________________________________________________________________________________________________________________
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:
No special requirements under ordinary conditions of use and with adequate ventilation. For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded. Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:
If product is hot, thermally protective, chemical resistant gloves are recommended. If contact with forearms is likely, wear gauntlet style gloves. Thermally protective, chemical resistant gloves are recommended. If contact with forearms is likely, wear gauntlet-style gloves.
Eye Protection: If contact is likely, safety glasses with side shields are recommended. Face shield is recommended. Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:
No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact. Thermally protective and chemical resistant apron and long sleeves are recommended when volume of material is significant.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping.
ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and soil. Protect the environment by applying appropriate control measures to prevent or limit emissions.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Note: Physical and chemical properties are provided for safety, health and environmental considerations only and may not fully represent product specifications. Contact the Supplier for additional information. GENERAL INFORMATION
Physical State: Gas Form: Liquefied Colour: Colourless Odour: Mercaptan Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION
Relative Density (at 15 °C): 0.51 Flash Point [Method]: -103°C (-153°F) [ASTM D-92]
Product Name: COMMERCIAL PROPANE (ODORIZED)
Revision Date: 07 Jun 2013 Page 6 of 11
______________________________________________________________________________________________________________________
Flammable Limits (Approximate volume % in air): LEL: 2.4 UEL: 9.5 Autoignition Temperature: 432°C (810°F) Boiling Point / Range: -42°C (-44°F) Vapour Density (Air = 1): 1.5 at 101 kPa Vapour Pressure: 850 kPa (6375 mm Hg) at 20ºC Evaporation Rate (n-butyl acetate = 1): > 1 pH: N/A Log Pow (n-Octanol/Water Partition Coefficient): N/A Solubility in Water: Negligible Viscosity: [N/D at 40 °C] | 0.5 cSt (0.5 mm2/sec) at 15°C Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION
Freezing Point: N/D Melting Point: >-187°C (-305°F)
SECTION 10 STABILITY AND REACTIVITY STABILITY: Material is stable under normal conditions. CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources. MATERIALS TO AVOID: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY Route of Exposure Conclusion / Remarks Inhalation
Toxicity (Rat): LC50 > 5000 mg/m3 Minimally Toxic. Based on test data for structurally similar materials.
Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.
Ingestion
Toxicity: No end point data for material. Not applicable.
Skin Toxicity: No end point data for material. Not applicable. Irritation (Rabbit): Data available. Negligible irritation to skin at ambient temperatures. Based on test
data for structurally similar materials.
Eye Irritation (Rabbit): Data available. May cause mild, short-lasting discomfort to eyes. Based on test
data for structurally similar materials. CHRONIC/OTHER EFFECTS For the product itself:
May cause central nervous system disorder (e.g., narcosis involving a loss of coordination, weakness, fatigue,
Product Name: COMMERCIAL PROPANE (ODORIZED)
Revision Date: 07 Jun 2013 Page 7 of 11
______________________________________________________________________________________________________________________
mental confusion and blurred vision) and/or damage. Exposure to rapidly expanding gas or vaporizing liquid may cause frostbite (cold burn). Very high exposure (confined spaces / abuse) to light hydrocarbons may result in abnormal heart rhythm (arrhythmias). Concurrent high stress levels and/or co-exposure to high levels of hydrocarbons (above occupational exposure limits), and to heart-stimulating substances like epinephrine, nasal decongestants, asthma drugs, or cardiovascular drugs may initiate arrhythmias. Simple asphyxiant: Acts by displacing oxygen in the lungs thereby diminishing the supply of oxygen available to the blood and tissues. Symptoms include shortness of breath, rapid heart rate, incoordination, lethargy, headaches, nausea, vomiting, and disorientation. Continued lack of oxygen may result in convulsions, loss of consciousness and death. Since exercise increases the tissue need for oxygen, symptoms will occur more quickly during exertion in an oxygen-deficient environment. Oxygen in enclosed spaces should be maintained at 21 percent by volume.
CMR Status: None. Chemical Name CAS Number List Citations ISOBUTANE 75-28-5 4 PROPYLENE 115-07-1 4
--REGULATORY LISTS SEARCHED-- 1 = IARC 1 3 = IARC 2B 5 = ACGIH A1 2 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2 SECTION 12 ECOLOGICAL INFORMATION The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITY Material -- Not expected to be harmful to aquatic organisms. MOBILITY Material -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment and wastewater
solids. PERSISTENCE AND DEGRADABILITY Biodegradation: Material -- Expected to be inherently biodegradable Atmospheric Oxidation: Material -- Expected to degrade at a moderate rate in air BIOACCUMULATION POTENTIAL Material -- Potential to bioaccumulate is low.
SECTION 13 DISPOSAL CONSIDERATIONS
Product Name: COMMERCIAL PROPANE (ODORIZED)
Revision Date: 07 Jun 2013 Page 8 of 11
______________________________________________________________________________________________________________________
Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products.
REGULATORY DISPOSAL INFORMATION Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.
SECTION 14 TRANSPORT INFORMATION LAND (TDG)
Proper Shipping Name: LIQUEFIED PETROLEUM GASES Hazard Class & Division: 2.1 UN Number: 1075 Packing Group: (N/A)
LAND (DOT)
Proper Shipping Name: PETROLEUM GASES, LIQUEFIED Hazard Class & Division: 2.1 ID Number: 1075 Packing Group: (N/A) ERG Number: 115 Label(s): 2.1 Transport Document Name: UN1075, PETROLEUM GASES, LIQUEFIED, 2.1
SEA (IMDG)
Proper Shipping Name: PETROLEUM GASES, LIQUEFIED Hazard Class & Division: 2.1 EMS Number: F-D, S-U UN Number: 1075 Packing Group: (N/A) Label(s): 2.1 Transport Document Name: UN1075, PETROLEUM GASES, LIQUEFIED, 2.1 (-103°C c.c.)
AIR (IATA)
Proper Shipping Name: PETROLEUM GASES, LIQUEFIED Hazard Class & Division: 2.1 UN Number: 1075 Packing Group: (N/A) Label(s) / Mark(s): 2.1 Transportation Limitations: CARGO AIRCRAFT ONLY Transport Document Name: UN1075, PETROLEUM GASES, LIQUEFIED, 2.1
Product Name: COMMERCIAL PROPANE (ODORIZED)
Revision Date: 07 Jun 2013 Page 9 of 11
______________________________________________________________________________________________________________________
SECTION 15 REGULATORY INFORMATION WHMIS Classification: Class A: Compressed Gas Class B, Division 1: Flammable Gases This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations. CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA. Complies with the following national/regional chemical inventory requirements AICS, DSL, ENCS, IECSC, KECI, PICCS, TSCA The Following Ingredients are Cited on the Lists Below: Chemical Name CAS Number List Citations PROPYLENE 115-07-1 6
--REGULATORY LISTS SEARCHED-- 1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b 2 = TSCA 5a2 4 = TSCA 6 6 = NPRI SECTION 16 OTHER INFORMATIONN/D = Not determined, N/A = Not applicable THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS: Revision Changes: Section 06: Protective Measures was modified. Section 09: Boiling Point C(F) was modified. Section 08: Comply with applicable regulations phrase was modified. Section 09: Vapour Pressure was modified. Section 11: Dermal Lethality Test Data was modified. Section 11: Oral Lethality Test Data was modified. Section 11: Inhalation Irritation Test Data was modified. Section 09: Relative Density - Header was modified. Section 09: Flash Point C(F) was modified. Section 09: Autoignition Temperature was modified. Section 09 Viscosity was modified. Section 09 Viscosity was modified. Section 14: Transport Document Name was modified. Section 15: National Chemical Inventory Listing - Header was modified. Section 15: National Chemical Inventory Listing was modified. Section 11: Additional Health Information was modified. Section 16: MSN,MAT ID was modified.
Product Name: COMMERCIAL PROPANE (ODORIZED)
Revision Date: 07 Jun 2013 Page 10 of 11
______________________________________________________________________________________________________________________
Section 09: Melting Point C(F) was modified. Composition: Component table was modified. Section 16: CA Contains was modified. Section 08: Exposure Limits Table was modified. Section 15: Canadian List Citations Table was modified. Section 01: Company Contact Methods Sorted by Priority was modified. Section 11: Tox List Cited Table was modified. ----------------------------------------------------------------------------------------------------------------------------------------------------- PRECAUTIONARY LABEL TEXT: Contains: ALKANES, C4; ISOBUTANE; PROPYLENE; ETHANE; PROPANE WHMIS Classification: Class A: Compressed Gas Class B, Division 1: Flammable Gases HEALTH HAZARDS May cause central nervous system depression. PHYSICAL HAZARDS Flammable Gas. In use, may form flammable/explosive vapour-air mixture. Suffocation (asphyxiant) hazard - if allowed to accumulate to concentrations that reduce oxygen below safe breathing levels. Frostbite hazard - rapidly expanding gas or liquid may cause frostbite. Material can accumulate static charges which may cause an ignition. PRECAUTIONS Prevent exposure to ignition sources, for example use non-sparking tools and explosion-proof equipment. Use proper bonding and/or earthing procedures.However, bonding and earthing may not eliminate the hazard from static accumulation. FIRST AID Inhalation: Immediately remove from further exposure. Get immediate medical assistance. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. Give supplemental oxygen, if available. If breathing has stopped, assist ventilation with a mechanical device. Eye: Flush thoroughly with water for at least 15 minutes. Get medical assistance. Skin: If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury. If frostbite occurs, immerse involved area in water at body temperature. Keep immersed for 20 to 40 minutes. Seek medical assistance. FIRE FIGHTING MEDIA Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. SPILL/LEAK Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. CAUTION: When in contact with refrigerated/cryogenic liquids, many materials become brittle and are likely to break without warning. Allow liquid to evaporate from the surface. Do not direct water at spill or source of leak. If possible, turn leaking containers so that gas escapes rather than liquid. Isolate area until gas has dispersed. Prevent spreading of vapour through sewers, ventilation systems and confined areas. Use water spray to reduce vapour or divert vapour cloud drift. Avoid allowing water run-off to contact spilled material. Water Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Allow liquid to evaporate from the surface. Report spills as required to appropriate authorities. See Land Spill section of the SDS for advice on gases.
Product Name: COMMERCIAL PROPANE (ODORIZED)
Revision Date: 07 Jun 2013 Page 11 of 11
______________________________________________________________________________________________________________________
----------------------------------------------------------------------------------------------------------------------------------------------------- The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. ----------------------------------------------------------------------------------------------------------------------------------------------------- DGN: 5007473 (1010550) ----------------------------------------------------------------------------------------------------------------------------------------------------- Copyright 2002 Imperial Oil Limited, All rights reserved Prepared by: Imperial Oil Limited, IH and Product Safety
MATERIAL SAFETY DATA SHEET
CLR CALCIUM, LIME & RUST REMOVER
521012 Page 1 of 6 Date issued 01-October-2012
1 - PRODUCT AND COMPANY IDENTIFICATION SDS ID: 521012 Product Name CLR Calcium, Lime & Rust Remover Product Use Aqueous Acidic Cleaner for Removal of Calcium, Lime, and Rust from Hard
Surfaces Retail Package: [28 fl. oz., 42 fl. oz., and 128 fl. oz. (one gallon)} CAS# Proprietary Mixture Restrictions on Use Incompatible with strong oxidizing agents, metals (except stainless steel, chrome), acids, bases, and bleach. Manufacturer: Jelmar, LLC Emergency Phone Number: 1(800) 323-5497 (USA) Address: 5550 W. Touhy Ave. Monday – Friday 8:30 A.M. – 4:30 P.M. CST Skokie, IL 60077 Emergency 24 hour Contact: Chemtrec 1(800) 424-9300
2 – HAZARDS IDENTIFICATION Emergency Overview: WARNING: EYE IRRITATANT. GHS Toxicity Category 2A Causes eye irritation
and possible SKIN IRRITATANT GHS Category 3 – on sensitive skin.DO NOT get in eyes, on skin or clothing. DO NOT mix with bleach or other household chemicals as harmful fumes may result. DO NOT ingest. DO NOT breathe vapor or mist. Use in well ventilated areas. Keep container closed when not in use.
KEEP OUT OF REACH OF CHILDREN
Potential Short Term Health Effects Routes of Exposure Eyes, Skin, Inhalation, Ingestion. Eyes Irritant
Avoid eye contact Effects may vary depending on length of exposure, solution concentration
Skin Irritant. Prolonged contact may cause dermatitis, and itching. Inhalation No adverse effects expected under typical use conditions. Ingestion Oral burns, vomiting, and gastrointestinal disturbance. Target organs Eyes. Skin.
SECTION 3 - COMPOSITION /INFORMATION ON INGREDIENTS Component CAS# OSHA HAZARD % by Weight 1. Lactic Acid 79-33-4 YES 12.00-18.00 2. Gluconic Acid 526-95-4 YES 2.50-3.75 3. Lauramine Oxide 1643-20-5 YES 1.50-3.25
MATERIAL SAFETY DATA SHEET
CLR CALCIUM, LIME & RUST REMOVER
521012 Page 2 of 6 Date issued 01-October-2012
SECTION 4 – FIRST AID MEASURES EYE CONTACT: In case of eye contact, immediately rinse eye thoroughly with plenty of water. Remove contact lenses, and continue rinsing for at least 15 minutes. If irritation persists, get medical attention. SKIN CONTACT: Can be irritating to skin, prolonged contact can be more severe, no adverse effects during normal usage. In case of skin contact, rinse area for at least 15 minutes. Remove contaminated clothing and shoes, wash thoroughly before reuse. If irritation persists get medical attention. INHALATION: Not a significant route of exposure. Remove to fresh air. If breathing is difficult, GET MEDICAL ATTENTION IMMEDIATELY. INGESTION: DO NOT induce vomiting. If fully conscious, drink 16 ounces of water. CALL A PHYSCIAN OR POISON CONTROL CENTER IMMEDIATELY. NEVER give an unconscious person anything to ingest.
SECTION 5 – FIRE FIGHTING MEASURES FLAMMABILTY: Not flammable FLASH POINT: None; Method: ASTM D-56 EXPLOSIVE LIMITS IN AIR: Not available EXTINGUISHING MEDIA: Not flammable. Use appropriate media for area. Use water spray, dry chemical, alcohol foam or carbon dioxide. FIRE FIGHTING METHODS: Evacuate area of personnel. Wear protective NIOSH-approved self-contained breathing apparatus. Remain upwind of fire to avoid hazardous vapors and decomposition products. Use water spray to cool fire-exposed containers. Run-off of large quantities of product from fire control may cause pollution. Contact appropriate agencies. HAZARDOUS COMBUSTION PRODUCTS: Carbon Monoxide. Thermal decomposition can lead to irritating gases and vapors. FIRE AND EXPLOSION HAZARDS: None known.
SECTION 6 – ACCIDENTAL RELEASES MEASURES Steps to be taken in Case Material is Released or Spilled: Avoid contact with skin and eyes Small Spill: No special clean-up procedure is necessary for small (less than 1 gallon) spills. Flush spill area with water. Wear rubber gloves. Large Spill: Use personal protection recommended in Section 8. Isolate area, and deny entry to unnecessary and unprotected personnel. Dam spill, and absorb with earth, sand or similar material. Place in non-leaking containers. Dispose of collected material according to local, state, and federal regulations. Flush residue with large amount of water. Avoid direct discharge to sewers and surface waters.
SECTION 7- HANDLING AND STORAGE STORAGE: Store in cool, well-ventilated area, away from heat. Keep containers tightly closed. Avoid contact with combustible materials, wood, and organic materials. Store in original container in a secure area away from children and pets. HANDLING: Avoid contact with eyes, skin or clothing. May be harmful or if swallowed. Use with adequate ventilation. Avoid breathing vapors or mist. Do not eat, drink, or smoke in work area. Wash hand thoroughly after use. Consumer size containers (28, and 42 fluid ounces and gallon containers), should be rinsed and recycled. DO NOT PRESSURIZE, CUT OR EXPOSE THESE CONTAINERS TO HEAT, FLAME,
MATERIAL SAFETY DATA SHEET
CLR CALCIUM, LIME & RUST REMOVER
521012 Page 3 of 6 Date issued 01-October-2012
SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY. DO NOT MIX WITH BLEACH, OR ANY OTHER PRODUCTS AS TOXIC FUMES MAY RESULT. KEEP OUT OF REACH OF CHILDREN.
SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION VENTILATION REQUIREMENT: Avoid prolonged breathing mists or dusts of this product. Use with adequate ventilation. Do not use in closed or confined spaces. RESPIRATORY PROTECTION: None required during normal household use. EYE PROTECTION: Not required during normal household usage. Do not wear contact lenses. Emergency responders should wear full eye and face protection. SKIN PROTECTION: Rubber gloves with protective cuff. Emergency responders should wear impermeable gloves. OTHER PROTECTION: Emergency responders should wear chemical type (impermeable) protective clothing and footwear where direct contact with chemicals in this product is possible. WORK/HYGIENIC PRACTICES: Wash thoroughly with soap and water after use or handling. EXPOSURE GUIDELINES: OSHA ACGIH COMPONENT PEL STEL/C TWA STEL/C 1. Lactic Acid N.E N.E. N.E. N.E. 2. Gluconic Acid N.E. N.E. N.E. N.E. 3. Lauramine Oxide N.E. N.E. N.E. N.E.
SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES Boiling point: 99ºC / 210º F Specific Gravity @20ºC: 1.04 – 1.06 Vapor Pressure: N.D. Percent Volatiles: ~77.2% (Calculated) Freezing Point: N.D. Evaporation Rate: N.D. (nBuAc=1) Melting Point: N.D. Total VOC (wt. %): 0% - does not include any Vapor Density (mm Hg): N.D. (Volatile Organic Compounds/ CARB applicable pH: @20ºC 2.10-2.30 California Air Resource Board) exemptions Solubility in Water: 100%
SECTION 10 – STABILITY AND REACTIVITY STABILITY: Stable under normal conditions. CONDITIONS TO AVOID: Avoid elevated temperatures. INCOMPATIBLE MATERIALS: Strong oxidizing agents, metals (except stainless steel and chrome), acids, and bases. HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition can lead to release of irritating gases, vapors and carbon oxides. POSSIBILITY OF HAZARDOUS REACTIONS: No data.
SECTION 11 – TOXICOLOGICAL INFORMATION LD50 ACUTE EYE IRRITATION: OPPTS 8740.2400 Toxicity - Irritant; GHS Toxicity Category 2A - Irritant LD50 ACUTE DERMAL IRRATION - RABBITS: OPPTS 870.2500 Toxicity Category IV – Mild or Slight Skin Irritation; GHS Category 3 – Mild Skin Irritation. LD50ACUTE ORAL TOXICITY – RATS: OPPTS 870.1100 Toxicity Category IV >5,000 mg/kg; GHS Category 5 >5,000 mg/kg - Not Toxic
MATERIAL SAFETY DATA SHEET
CLR CALCIUM, LIME & RUST REMOVER
521012 Page 4 of 6 Date issued 01-October-2012
LD50ACUTE DERMAL TOXICITY - RABBITTS: OPPTS 870-1200 Toxicity Category IV >5 g/kg; GHS Category 5 >5,000 mg/kg – Not Toxic LD50 ACUTE INHALATION TOXICITY – RATS: OPPTS 870.1300 Toxicity Category IV - Not toxic by inhalation; GHS Category 5 - Not toxic by inhalation
SECTION 12- ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION: LACTIC ACID: Persistence / degradability
Readily biodegradable, according to appropriate OECD test. Biochemical oxygen demand (BOD)5 = 0.45 mg O2 /mg Biochemical oxygen demand (BOD)20= 0.60 mg O2/mg Chemical oxygen demand (COD) =0.90 mg O2 /mg
Bioaccumulation None.
Ecotoxicity EC50/48h/Daphnia = 240mg/l LC50/48h/Fish = 320 mg/l EC50/Algae = 3500 mg/l(neutral) No data available.
GLUCONIC ACID: Fish 96-h LC50 > 1000.0 mg/L Daphnid 48-h LC50 > 1000.0 mg/L Green algal 96-h EC50 > 1000.0 mg/L Fish Chronic Value (ChV) > 100.0 mg/L Daphnid ChV > 100.0 mg/L Algal ChV > 100.0 mg/L Biological Fate: No bioconcentration in aquatic organisms and rapid biodegradation/disappearance in the environment, i.e. 40% in 5 days.
LAURAMINE OXIDE: Acute Aquatic Toxicity Reviewed Category ≤1 mg/L Algae IC50 0.01 mg/L Invertebrate EC50 1.01 mg/L Fish LC50 2.6 mg/L Biodegradation: % degraded in 28 days ≥60% ThOD/ThCO2 (≥70% DOC) DOWANOL DPNB: Movement & Partitioning
Bioconcentration potential is low (BCF less than 100 or log Pow less than 3). Potential for mobility in soil is very high (Koc between 0 and 50).
MATERIAL SAFETY DATA SHEET
CLR CALCIUM, LIME & RUST REMOVER
521012 Page 5 of 6 Date issued 01-October-2012
Henry’s Law Constant (H): 3.78E-07 atm*m3/mole; 25 °C Estimated. Partition coefficient, n-octanol/water (log Pow): 1.13 Estimated. Partition coefficient, soil organic carbon/water (Koc): 10 - 21 Estimated. Persistence and Degradability Material is readily biodegradable. Passes OECD test(s) for ready biodegradability. Material is ultimately biodegradable (reaches > 70% mineralization in OECD test(s) for inherent biodegradability). Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method
4.97E-11 cm3/s 2.6 h Estimated. OECD Biodegradation Tests: Biodegradation Exposure Time Method 91 % 28 d OECD 301E Test 96 % 28 d OECD 302B Test Theoretical Oxygen Demand: 2.35 mg/mg ECOTOXICITY Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested). Fish Acute & Prolonged Toxicity LC50, guppy (Poecilia reticulata), static, 96 h: 841 mg/l Aquatic Invertebrate Acute Toxicity LC50, water flea Daphnia magna, static, 48 h, immobilization: > 1,000 mg/l
CLR CHEMICAL FATE INFORMATION: 28-day biodegradation. The matter is readily biodegradable. OECD 301D
SECTION 13 – DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Rinse empty bottles and recycle. Dispose of unused product in a permitted hazardous waste management facility following all local, state, and federal regulations. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. Follow label warnings, since containers may retain some reside of the product. Processing, use or contamination of this product may change the waste management options. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. State and local disposal regulations may differ from federal disposal regulations.
SECTION 14 - TRANSPORTATION INFORMATION DOT (Department of Transportation Proper Shipping Name): Not regulated by DOT. Identification Number: N.A. Packaging Group: N.A.
MATERIAL SAFETY DATA SHEET
CLR CALCIUM, LIME & RUST REMOVER
521012 Page 6 of 6 Date issued 01-October-2012
UN Number: N.A. TDG Classification: Not Regulated IMDG Classification: Not Regulated IATA Classification: Passenger – Not Regulated WHIMS (Canada): This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by CPR.
SECTION 15 – REGULATORY INFORMATION FEDERAL REGULATIONS: TSCA INVENTORY STATUS: All components of this product are listed on the TSCA Inventory or are exempt from TSCA Inventory requirements. SARA TITTLE III SECTION 311/312 CATEGORY: IMMEDIATE (ACUTE) HEALTH HAZARARD: YES DELAYED (CHRONIC) HEALTH HAZARD: NO FIRE HAZARD: NO SUDDEN RELEASE OF PRESSURE: NO REACTIVE HAZARD: NO SARA SECTIONS 302/304/313/HAP: NO INTERNATIONAL CHEMICAL INVENTORY STATUS: EUROPEAN UNION (EINECS) YES JAPAN (METI) YES AUSTRALIA (ACIS) YES KOREA (KECL) YES CANADA (DSL) YES CANADA (NDSL) NO PHILIPPINES YES STATES RIGHT TO KNOW: California, New Jersey, Pennsylvania, Minnesota, Massachusetts, and Wisconsin. Complies with listed States Right to Know Act. The following statement is made in order to comply with the California State Drinking Water Act. California Proposition 65: This product does not contain any chemicals known to the State of California to cause cancer and/or to cause birth defects and other reproductive harm.
SECTION 16 – OTHER INFORMATION Precautions to be taken in Handling and Storing: Avoid exposure to excess heat, and prevent from freezing. Other Precautions: None required. MSDS ABBREVIATIONS: N. A.: Not Applicable HAP: Hazardous Air Pollutant VOC: Volatile Organic Compound N. D.: Not Determined N.E.: Not Established
MATERIAL SAFETY DATA SHEET
CLR CALCIUM, LIME & RUST REMOVER
521012 Page 7 of 6 Date issued 01-October-2012
C: Ceiling Limit HAP: Hazardous Air Pollutant VOC: Volatile Organic Compound Revision: New Formula, GHS Format October 2012 R. A. Gaudreault Although the information and recommendations set forth herein are presented in good faith and believed to be correct as of the date hereof, JELMAR offers no representations as to the completeness or accuracy thereof. Information is provided upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. In no event will JELMAR be responsible for damages of any nature whatsoever resulting from use of or reliance upon said information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION HEREIN REFERS.
KIK
CUSTOM PRODUCTS Page 1 of 2
Material Safety Data Sheet
Section 1. Chemical Product and Company Identification
Product Name/Trade Name Glass Cleaner
Ref# 40000263
Manufacturer: KIK CUSTOM PRODUCTS
2921 Corder Street
Houston, TX USA 77054
Contact Number:
24 Hour Emergency Contact:
Prepared By:
Date Last Revised:
Replaces Date:
Tel: 905-660-0444
Tel: 1-800-255-3924
KIK CUSTOM PRODUCTS
October 7, 2014
October 18, 2011
Section 2. Hazardous Ingredients Name % CAS# LD50/LC50
Aqua Ammonia ≤1.0 7664-41-7 43 mg/kg (oral) /30,000 ppm (1hr)
Section 3. Physical Data
State Liquid pH 10.5 – 12.5
Appearance Blue % Volatile 99.9 %
Odour Ammonia Boiling Point N Av.
Specific Gravity 1.000-1.010 Vapour Pressure N Av.
Solubility 100% in water Freezing Point Approx. 0°C
Section 4. Fire & Explosion
Flammable: YES NO X
Means of Extinction: As per surrounding fire
Special Procedures: As per surrounding fire.
Flash Point: & Method: > 200°F TCC
Hazardous Combustion Products: N. Av.
Section 5. Reactivity Data
Chemical Stability: YES X NO
Conditions: N App.
Incompatibility: YES NO X
What Substances:
Reactivity / Conditions: None reactive
Hazardous Decomposition Products: N Av.
KIK
CUSTOM PRODUCTS Page 2 of 2
Section 6. Toxicological Properties Route of Entry
Skin Contact X Skin Absorption Eye Contact X
Inhalation Acute X Inhalation Chronic Ingestion X
Effects of Acute Exposure: Inhalation of vapours will irritate breathing passages. Contact with eyes may
cause mild irritation. Ingestion may cause very mild sensation in mouth, throat and stomach.
Effects of chronic exposure: Prolonged and repeated exposure to skin will cause irritation, drying and
dermatitis
Carcinogenicity, Reproductive Effects, Teratogenicity, Mutagenicity: No known effects
Section 7. Preventative Measures
Protective Equipment
Gloves: Recommended for prolonged exposure. Eyes: Not normally required
Respiratory: Not normally required. Footwear: Not Applicable
Leak & Spill Procedure: Rinse with water mop up dispose of in accordance with local,
state/provincial and federal regulations
Section 8. First Aid Measures
Skin: Wash with soap and water
Eyes: Flush eyes with cool running water holding eyelids apart to ensure thorough rinsing for 15 minutes.
Remove contact lenses.
Inhalation: Move to fresh air and restore breathing, if required.
Ingestion: DO NOT INDUCE VOMITING! Drink large amounts of water. Do not give anything by mouth
to a convulsing or unconscious person. See a doctor immediately.
General Advice: If irritation occurs, see a doctor immediately.
Section 9. Regulatory Information
TRANSPORTATION: Not Restricted
WHIMIS Controlled Product: No
Health 1
Flammability 0
Reactivity 0
As the handling and use of products under user's conditions are beyond our control, no warranty, expressed or implied, is made concerning this product. The information contained herein is offered only as a guide to the handling of this specific material and is not intended to be all-inclusive in the manner and conditions of use and handling. The user assumes all risks of use or handling, whether or not in accordance with any directions or suggestions of the manufacturer. Manufacturer shall not be liable to purchaser or any other person for loss or damages directly or indirectly arising from the use of our product.
KLEEN-FLO TUMBLER INDUSTRIES LIMITED MATERIAL SAFETY DATA SHEET PAGE 1
SECTION I-MATERIAL IDENTIFICATION AND USE
Material Name/Identifier: Silicone Gasket Maker (Clear) Stock No. 472
Manufacturer's Name: Kleen-Flo Tumbler Industries Ltd Street Address: 75 Advance Blvd.
City: Brampton Province: Ontario
Postal Code: L6T 4N1 Emergency Phone #: CANUTEC:- 613-996-6666 (24HR)
Chemical Name: N. Ap (mixture) Chemical Family: Silicone rubber sealant
Chemical Formula: N. Ap (mixture) Trade Names & Synonyms: None
Material Use: Sealer Molecular Weight: N/Ap.
SECTION II-HAZARDOUS INGREDIENTS OF MATERIAL
Hazardous Approximate LD50 LC50
Ingredients C.A.S. Concentration Species & Route Species & Route
Amorphous silica 7631-86-9 7 - 13 % 3160 mg/kg rat-oral >0.139mg/L(4hr) rat-inhal
Methyltriacetoxysilane 4253-34-3 1 - 5% 1600 mg/kg rat-oral N/Av.
Ethyl Triacetoxysilane 17689-77-9 1 - 5 % 1460mg/kg rat-oral N/Av.
Octamethylcyclotetrasiloxane 556-67-2 0.1 - 1% 1540mg/kg rat-oral 36mg/L(4hr) rat - inhal
SECTION III-PHYSICAL DATA FOR MATERIAL
Physical State: Paste Odour/Appearance: Acetic acid odour/ thixotropic sealant
Specific Gravity: 1.01 Odour Threshold(p.p.m.): N/Av.
Boiling Point: N/Av. Evaporation Rate: N/Av.
Freezing Point: N/Av. Solubility in Water: insoluble
% Volatile(by volume): N/Av. Vapour Pressure(mm)Hg: N/Av.
Vapour Density(Air=1): N/Av. Coefficient of Water/Oil Distribut: N/Av.
pH N/Ap.
SECTION IV-FIRE AND EXPLOSION HAZARD OF MATERIAL
Flammability Yes/No No If yes under which conditions?: N.Ap.
Auto Ignition Temperature: N/Av. Means of Extinction: Dry chemical, foam, waterspray, carbon dioxide
carbon dioxide, carbon monoxide, formaldehyde
Upper Flammable limit (%vol) None Lower Flammable Limit(% by volume): None
Explosion Data: Sensitivity to Mech. Impact: N. Ap Sensitivity to Static Discharge: N.Ap.
SECTION V-REACTIVITY DATA
Chemical Stability Yes/No: Yes If NO under which conditions? N.Ap.
Incompatibility to Other Substances Yes/No: yes If so which ones? : Strong oxidizers or electrophiles
(e.g Ferric chloride) strong Acid and Base
Reactivity and under what conditions? Heat, open flames, fire. Moisture and incompatible material
Hazardous Decomposition Products: Carbon oxides, Carbon monoxide, formaldehyde, silicon dioxide, metal oxide.
N/E: not established N.Ap.: not applicable N/Av.: not available
Material Name/Identifier: Silicone Gasket Maker (Clear) Stock No. 472 PAGE 2
SECTION VI-TOXICOLOGICAL PROPERTIES OF PRODUCT
Route of Entry: ALL Routes --SKIN CONTACT --SKIN ABSORPTION --EYE CONTACT --INHALATION --INGESTION
Effects of Acute Exposure: Uncured product contact will irritate skin, lips, gums and tongue. May cause mild respiratory irritation.
Effects of Chronic Exposure: No known chronic health effects, but should avoid unnecessary exposure to product
LD 50 of Product: N/Av. LC 50 of Product: N/Av.
Irritancy of Product: Skin, eye irritant Exposure Limits of Product: N/Av.
Sensitization of Product: Allergic skin sensitization possible through repeated direct contact with the ketoxime in uncured product.
--CARCINOGENICITY --REPRODUCTIVE EFFECTS --TERATOGENICITY --MUTAGENICITY None known
SECTION VII-PREVENTIVE MEASURES
Personal Protective Equipment to be used:
Gloves(specify): Nitril, neoprene, Eye(specify): Safety glasses
Respiratory(specify): Mask with filter for free acidic vapour Clothing: Not required
Respiratory Protection: If used indoors or on a continuous basis, use of NIOSH approved cartridge type respirator is recommended
Engineering Controls: Local and mechanical ventilation required.
Leak and Spill Procedure: Wipe, scrape or soak up in an inert mateiral and put in a container for disposal
Surface may become slippery, cleaning may required steam, solvent or detergent.
Waste Disposal: Standard methods approved in your region.
Storage Requirements: Store at room temperature between 10 and 25ºC. keep in well ventilated area. Keep lid closed when not in use.
Handling Procedures and Acetic acid is released during application and curing. Provide adequate ventilation to control
Equipment: exposures within guidelines of OSHA.
TDG Classification: non-regulated.
WHMIS Classification: Consumer commodity/ CCCR label Complies with CCCR 2001
SECTION VIII-FIRST AID MEASURES
Eye: Rinse thoroughly with water for 10-15 minutes. Consult a physician immediately.
Skin: Remove contaminated clothing. Wash with soap and water. Consult doctor if irritation, rashes persist.
Inhalation: Move patient to fresh air and restore breathing if requiredseek medical help if discomfort persist.
Ingestion: DO NOT INDUCE VOMITING. Call a physician immediately.
SECTION IX-PREPARATION DATE OF M.S.D.S.
Additional Info/Comments: Sources Used: Supplier's data
Phone Number: (905) 793-4311 Prepared By: Quality Control Laboratory
Date Prepared: January 2, 2015 Kleen-Flo Tumbler Industries Limited
THIS SHEET SUPERSEDES ANY OTHER M.S.D.S. PREVIOUSLY PREPARED
N/Av.: not available N/Ap.: not applicable N/E: not established
KLEEN-FLO TUMBLER INDUSTRIES LIMITED MATERIAL SAFETY DATA SHEET PAGE 1
SECTION I-MATERIAL IDENTIFICATION AND USE
Material Name/Identifier: ACE-Start Starting Fluid Stock No. 735
Manufacturer's Name: Kleen-Flo Tumbler Industries Ltd Street Address: 75 Advance Blvd.
City: Brampton Province: Ontario
Postal Code: L6T 4N1 Emergency Phone #: CANUTEC:- 613-996-6666 (24HR)
Chemical Name: N.Ap. (Mixture) Chemical Family: N/Av. (Mixture)
Chemical Formula: N.Ap. (Mixture) Trade Names & Synonyms: Kleen-Start
Material Use: Engine Starting Fluid Molecular Weight: N/Av. (Mixture)
SECTION II-HAZARDOUS INGREDIENTS OF MATERIAL
Hazardous Approximate LD50 LC50
Ingredients C.A.S. % Concentration Species & Route Species & Route
Diethyl ether 60-29-7 40-70 1215mg/kg rat-oral 73000 ppm(150 min.) rat-inhal.
Heptane 142-82-5 30-60 4420-5840mg/kg rat-oral 14000 ppm (4 hr) rat-inhl.
Carbon dioxide 124-38-9 5-10 N/Ap. N/Av.
SECTION III-PHYSICAL DATA FOR MATERIAL
Physical State: Aerosol Odour/Appearance: ether-like odour/ colorless liquid
Specific Gravity: 0.713 Odour Threshold(p.p.m.): N/Av.
Boiling Point: 35.5ºC Evaporation Rate: >1 (Butyl-acetate=1)
Freezing Point: N/E Solubility in Water: Negligible
% Volatile(by volume): 100 Vapour Pressure, psig 80 -90
Vapour Density(Air=1): >1 Coefficient of Water/Oil Distribut: N/Av.
pH N/Ap.
SECTION IV-FIRE AND EXPLOSION HAZARD OF MATERIAL
Flammability Yes/No: Yes, extremely If yes under which conditions?: Excessive heat, open flame or sparksAuto Ignition Temperature: N/Av. Means of Extinction: carbon dioxide, dry chemical, foam
Flashpoint and Method: -45ºC Hazardous Combustion Products: Hydrocarbon fumes, smoke,
Carbon dioxide, carbon monoxide.
Flame Extension: >45 cm but <100 cm Flashback yes.
Upper Flammable limit (%vol) 36 Lower Flammable Limit(% by volume): 1
Explosion Data: Sensitivity to Mechanical Impact: N.Ap Sensitivity to Static Discharge: N.Ap.
SECTION V-REACTIVITY DATA
Chemical Stability Yes/No: No If NO under which conditions? above 35.5ºC
Incompatibility to Other Substances Yes/No: Yes If so which ones? Strong oxidizing agents, Nitric acid
Reactivity and under what conditions? N/Av. Sulfuric acid, Amines.
Hazardous Decomposition Products: Carbon monoxide & carbon dioxides.
N/E: not established N.Ap.: not applicable N/Av.: not available
Material Name/Identifier: ACE-Start Starting Fluid Stock No. 735 PAGE 2
SECTION VI-TOXICOLOGICAL PROPERTIES OF PRODUCT
Route of Entry: ALL Routes --SKIN CONTACT --SKIN ABSORPTION --EYE CONTACT --INHALATION --INGESTION
Effects of Acute Exposure: May cause defatting and drying of skin and eye irritation. May irritate mucous membranes of respiratory tract.
Overexposure may cause central nervous system depression. Headache or nausea.
Effects of Chronic Exposure: Continuous inhalation of spray may harmful or fatal.
LD 50 of Product: N/Av. LC 50 of Product: N/Av.
Irritancy of Product: Skin & Eye Irritant Exposure Limits of Product: N/Av.
Sensitization of Product: N/Av. Toxicologically Synergistic Materials: N/Av.
--CARCINOGENICITY --REPRODUCTIVE EFFECTS --TERATOGENICITY --MUTAGENICITY
Diethyl ether has caused birth defects and toxicity to the fetus in animal tests.
SECTION VII-PREVENTIVE MEASURES
Personal Protective Equipment to be used:
Gloves(specify): Solvent resistant gloves Eye(specify): Safety Glasses
Respiratory(specify): NOISH approved organic vapor mask Clothing: Not required
Respiratory Protection: If used indoors or on a continuous basis, use of NIOSH approved respirator is recommended
Engineering Controls: Local or mechanical ventilation required to keep exposure limit below 400 ppm (diethyl ether).Leak and Spill Procedure: Absorb with inert non reactive absorbant. Use non sparking tool. Remove all ignition sources.
Waste Disposal: Do not puncture or incinerate, even when can is empty. Dispose as per local, provincial regulation.
Storage Requirements: Store in cool, well ventilayed area at room temperature. Do not expose under direct sunlight for prolonged period.
Handling Procedure & Keep away from open flame and spark excessive heat. Do not store above 30ºC for a long period of time.
Equipment: Keep away from reach of children. Do not inhale or ingest.
NFPA30B/CNFC3.3.5 Level 3
IATA (air transport) Prohibited. (Passanger Aircraft)
Marine (IMDG) Limited Quantity, Aerosol, UN1950, Class 2.1
DSL listing: All components are listed in the inventory.
TDG Classification: Consumer Commodity
WHMIS Classification: Consumer Commodity - exempt from WHMIS labeling requirement. Complies with CCCR 2001
SECTION VIII-FIRST AID MEASURES
Eye: Flush with plenty of water for at least 15 minutes. If irritation persists, seek medical help immediately.
Skin: Remove contaminated clothing. Wash with soap and water. If rash, irritation persists contact a physician.
Inhalation: Move patient to fresh air and restore breathing if required. If discomfort persist see a doctor.
Ingestion: DO NOT INDUCE VOMITING. Seek medical help immedaitely.
SECTION IX-PREPARATION DATE OF M.S.D.S.
Additional Info/Comments: Sources Used: Supplier's data
Phone Number: (905) 793-4311 Prepared By: Quality Control Laboratory
Date Prepared: Janaury 2, 2015. Kleen-Flo Tumbler Industries Limited
THIS SHEET SUPERSEDES ANY OTHER M.S.D.S. PREVIOUSLY PREPARED
N/E: not established N.Ap.: not applicable N/Av.: not available
KLEEN-FLO TUMBLER INDUSTRIES LIMITED MATERIAL SAFETY DATA SHEET PAGE 1
SECTION I-MATERIAL IDENTIFICATION AND USE
Material Name/Identifier: Brake & Parts Kleen(Non Chlorinated) Stock No. 313
Manufacturer's Name: Kleen-Flo Tumbler Industries Ltd Street Address: 75 Advance Blvd.
City: Brampton Province: Ontario
Postal Code: L6T 4N1 Emergency Phone #: CANUTEC:- 613-996-6666 (24HR)
Chemical Name: N.Ap. Chemical Family: N/Ap. ( mixture)
Chemical Formula: N.Ap. ( mixture) Trade Names & Synonyms: none
Material Use: Cleaner Molecular Weight: N.Ap. ( mixture)
SECTION II-HAZARDOUS INGREDIENTS OF MATERIAL
Hazardous Approximate LD50 LC50
Ingredients C.A.S. Conc. %wt. Species & Route Species & Route
Heptane 142-82-5 60-100 >15000 mg/kg rat-oral 103g/m3 (4hr) rat-inhal
Isopropyl alcohol 67-63-0 10 -30 >4720 mg/kg rat-oral 12000 ppm rat- (8 hr) inhl.
Carbon dioxide 124-38-9 3 -7 N/Ap N/Av.
SECTION III-PHYSICAL DATA FOR MATERIAL
Physical State: aerosol Odour/Appearance: Solvent-like, clear, colorless
Specific Gravity: 0.7 Odour Threshold(p.p.m.): N/E
Boiling Point: (on conc.) 80 -100 °C Evaporation Rate: > 1 (water=1)
Freezing Point: N/Av. Solubility in Water: partial soluble
% Volatile(by volume): 100% Vapour Pressure(mm)Hg: N/E
Vapour Density(Air=1): >1 Coefficient of Water/Oil Distribut: N/E
pH N.Ap.
SECTION IV-FIRE AND EXPLOSION HAZARD OF MATERIAL
Flammability Yes/No Yes, Highly flammable If yes under which conditions?: Open flame, Spark, Excessive heat
Auto Ignition Temperature: 204-399 °C Means of Extinction: Water fog, Dry Chemical, Foam
Flashpoint (Concentrate): Lowest known Heptane -7 ºC, T.C.C. Hazardous Combustion Products: hydrocarbon fumes and
Flame extension >45 cm smoke, carbon monoxide where combustio stion is incomplete.
Upper Flammable limit (%vol) 12 Lower Flammable Limit(% by volume): 1.2
Explosion Data: Sensitivity to Mechanical Impact: N.Av. Sensitivity to Static Discharge: N/E
SECTION V-REACTIVITY DATA
Chemical Stability Yes/No: Yes If NO under which conditions? N.Ap.
Incompatibility to Other Substances Yes/No: Yes If so which ones? Strong oxidizing agents
Reactivity and under what conditions? Excessive heat, open flame, spark
Hazardous Decomposition Products: Hydrocarbon fumes and smoke, carbon monoxide where combustion is incomplete
N/E: not established N.Ap.: not applicable N/Av.: not available
Material Name/Identifier: Brake & Parts Kleen(Non Chlorinated) Stock No. 313 PAGE 2
SECTION VI-TOXICOLOGICAL PROPERTIES OF PRODUCT
Route of Entry: ALL Routes --SKIN CONTACT --SKIN ABSORPTION --EYE CONTACT --INHALATION --INGESTION
Effects of Acute Exposure: May cause Dizziness, nausea, vomiting, weekness, eye and skin irritation.
Effects of Chronic Exposure: Solvents may cause defatting dermatitis.
LD 50 of Product: N/E LC 50 of Product: N/E
Irritancy of Product: Skin and eye irritant Exposure Limits of Product: N/E
Sensitization of Product: N/E Toxicologically Synergistic Materials: N/E
--CARCINOGENICITY --REPRODUCTIVE EFFECTS --TERATOGENICITY --MUTAGENICITY none known
SECTION VII-PREVENTIVE MEASURES
Personal Protective Equipment to be used:
Gloves(specify): Nitrile, vinyl or chemical resistant gloves Eye(specify): Wear eye/face protection
Respiratory(specify): Wear cartridge type respirator Clothing: Not required
Respiratory Protection: If used indoors or on a continuous basis, use of NIOSH approved cartridge type respirator is recommended
Engineering Controls: Use adequate ventilation.
Leak and Spill Procedure: Use inert absorbent material, non sparking tools to contain spills. Ventilate area.
Prevent from entering sewage or waterways.
Waste Disposal: Do not puncture or incinerate, even when can is empty. Dispose as per local, provincial regulation.
Storage Requirements: Store in a cool, well ventilated area where temperature not to exceed 50ºC
Handling Procedures and Use with adequate ventilation. Contents under pressure. Keep away from heat, sparks, flame and other
Equipment: sources of ignition. Keep away from children. Do not inhale or ingest.
DSL All ingredients are in the Domestic substance listing.
NFPA 30B/CNFC 3.3.5 Level 3
TDG Classification: Consumer Commodity
WHMIS Classification: A, B5, D2-B
SECTION VIII-FIRST AID MEASURES
Eye: Flush immediately with fresh water for at least 15 minutes. See a doctor immediately.
Skin: Wash with soap and water, consult a doctor if irritation or rashes persist.
Inhalation: Move patient to fresh air and restore breathing if required. Call a physician if discomfort persist.
Ingestion: DO NOT INDUCE VOMITING. Get medical attention immediately.
SECTION IX-PREPARATION DATE OF M.S.D.S.
Additional Info/Comments: Source used: Supplier's data
Phone Number: (905) 793-4311 Prepared By: Quality Control Laboratory
Date Prepared: January 2, 2015 Kleen-Flo Tumbler Industries Limited
THIS SHEET SUPERSEDES ANY OTHER M.S.D.S. PREVIOUSLY PREPARED
N/Av.: not available N/Ap: not applicable N/E: not established
KLEEN-FLO TUMBLER INDUSTRIES LIMITED MATERIAL SAFETY DATA SHEET PAGE 1
SECTION I-MATERIAL IDENTIFICATION AND USE
Material Name/Identifier: Kleen-Start Starting Fluid Stock No. 730
Manufacturer's Name: Kleen-Flo Tumbler Industries Ltd Street Address: 75 Advance Blvd.
City: Brampton Province: Ontario
Postal Code: L6T 4N1 Emergency Phone #: CANUTEC:- 613-996-6666 (24HR)
Chemical Name: N.Ap. (Mixture) Chemical Family: N/Av. (Mixture)
Chemical Formula: N.Ap. (Mixture) Trade Names & Synonyms: Kleen-Start
Material Use: Engine Starting Fluid Molecular Weight: N/Av. (Mixture)
SECTION II-HAZARDOUS INGREDIENTS OF MATERIAL
Hazardous Approximate LD50 LC50
Ingredients C.A.S. % Concentration Species & Route Species & Route
Diethyl ether 60-29-7 40-70 1215mg/kg rat-oral 73000 ppm(150 min.) rat-inhal.
Heptane 142-82-5 30-60 4420-5840mg/kg rat-oral 14000 ppm (4 hr) rat-inhl.
Carbon dioxide 124-38-9 5-10 N/Ap. N/Av.
SECTION III-PHYSICAL DATA FOR MATERIAL
Physical State: Aerosol Odour/Appearance: ether-like odour/ colorless liquid
Specific Gravity: 0.713 Odour Threshold(p.p.m.): N/Av.
Boiling Point: 35.5ºC Evaporation Rate: >1 (Butyl-acetate=1)
Freezing Point: N/E Solubility in Water: Negligible
% Volatile(by volume): 100 Vapour Pressure, psig 80 -90
Vapour Density(Air=1): >1 Coefficient of Water/Oil Distribut: N/Av.
pH N/Ap.
SECTION IV-FIRE AND EXPLOSION HAZARD OF MATERIAL
Flammability Yes/No: Yes, extremely If yes under which conditions?: Excessive heat, open flame or sparksAuto Ignition Temperature: N/Av. Means of Extinction: carbon dioxide, dry chemical, foam
Flashpoint and Method: -45ºC Hazardous Combustion Products: Hydrocarbon fumes, smoke,
Carbon dioxide, carbon monoxide.
Flame Extension: >45 cm but <100 cm Flashback yes.
Upper Flammable limit (%vol) 36 Lower Flammable Limit(% by volume): 1
Explosion Data: Sensitivity to Mechanical Impact: N.Ap Sensitivity to Static Discharge: N.Ap.
SECTION V-REACTIVITY DATA
Chemical Stability Yes/No: No If NO under which conditions? above 35.5ºC
Incompatibility to Other Substances Yes/No: Yes If so which ones? Strong oxidizing agents, Nitric acid
Reactivity and under what conditions? N/Av. Sulfuric acid, Amines.
Hazardous Decomposition Products: Carbon monoxide & carbon dioxides.
N/E: not established N.Ap.: not applicable N/Av.: not available
Material Name/Identifier: Kleen-Start Starting Fluid Stock No. 730 PAGE 2
SECTION VI-TOXICOLOGICAL PROPERTIES OF PRODUCT
Route of Entry: ALL Routes --SKIN CONTACT --SKIN ABSORPTION --EYE CONTACT --INHALATION --INGESTION
Effects of Acute Exposure: May cause defatting and drying of skin and eye irritation. May irritate mucous membranes of respiratory tract.
Overexposure may cause central nervous system depression. Headache or nausea.
Effects of Chronic Exposure: Continuous inhalation of spray may harmful or fatal.
LD 50 of Product: N/Av. LC 50 of Product: N/Av.
Irritancy of Product: Skin & Eye Irritant Exposure Limits of Product: N/Av.
Sensitization of Product: N/Av. Toxicologically Synergistic Materials: N/Av.
--CARCINOGENICITY --REPRODUCTIVE EFFECTS --TERATOGENICITY --MUTAGENICITY
Diethyl ether has caused birth defects and toxicity to the fetus in animal tests.
SECTION VII-PREVENTIVE MEASURES
Personal Protective Equipment to be used:
Gloves(specify): Solvent resistant gloves Eye(specify): Safety Glasses
Respiratory(specify): NOISH approved organic vapor mask Clothing: Not required
Respiratory Protection: If used indoors or on a continuous basis, use of NIOSH approved respirator is recommended
Engineering Controls: Local or mechanical ventilation required to keep exposure limit below 400 ppm (diethyl ether).Leak and Spill Procedure: Absorb with inert non reactive absorbant. Use non sparking tool. Remove all ignition sources.
Waste Disposal: Do not puncture or incinerate, even when can is empty. Dispose as per local, provincial regulation.
Storage Requirements: Store in cool, well ventilayed area at room temperature. Do not expose under direct sunlight for prolonged period.
Handling Procedure & Keep away from open flame and spark excessive heat. Do not store above 30ºC for a long period of time.
Equipment: Keep away from reach of children. Do not inhale or ingest.
NFPA30B/CNFC3.3.5 Level 3
IATA (air transport) Prohibited. (Passanger Aircraft)
Marine (IMDG) Limited Quantity, Aerosol, UN1950, Class 2.1
DSL listing: All components are listed in the inventory.
TDG Classification: Consumer Commodity
WHMIS Classification: Consumer Commodity - exempt from WHMIS labeling requirement. Complies with CCCR 2001
SECTION VIII-FIRST AID MEASURES
Eye: Flush with plenty of water for at least 15 minutes. If irritation persists, seek medical help immediately.
Skin: Remove contaminated clothing. Wash with soap and water. If rash, irritation persists contact a physician.
Inhalation: Move patient to fresh air and restore breathing if required. If discomfort persist see a doctor.
Ingestion: DO NOT INDUCE VOMITING. Seek medical help immedaitely.
SECTION IX-PREPARATION DATE OF M.S.D.S.
Additional Info/Comments: Sources Used: Supplier's data
Phone Number: (905) 793-4311 Prepared By: Quality Control Laboratory
Date Prepared: Janaury 2, 2015. Kleen-Flo Tumbler Industries Limited
THIS SHEET SUPERSEDES ANY OTHER M.S.D.S. PREVIOUSLY PREPARED
N/E: not established N.Ap.: not applicable N/Av.: not available
Material Safety Data Sheet_______________________________________________
Revision Date 01-May-2013
1. CHEMICAL PRODUCT AND COMPANYINFORMATION
Product code 92964
Product name Moly Coat
Recommended Use Lubricant
Supplier Lawson Products, Inc.8770 W.Bryn Mawr Ave.- Suite 900Chicago, IL 606311-866-529-7664
Emergency telephone number (888) 426-4851
2. HAZARDS IDENTIFICATION
Aggravated Medical ConditionsNone Known
Principal Routes of ExposureEyes. Skin contact. Inhalation. Ingestion.
Potential health effects
Eyes May cause the following effects:. Irritation. Pain.Tearing. Reddening. Swelling. Stinging sensation.Feeling like that of fine dust in the eye.
Skin Repeated or prolonged exposure may cause:. SkinIrritation. Defatting. Dermatitis. Chronic exposurecauses drying effect on the skin .
Inhalation Harmful by inhalation. Avoid breathing vapors ormists. Repeated or prolonged exposure may causethe following effects:. Headaches. Dizziness.Nausea. Decreased blood pressure. Changes inheart rate. Cyanosis. Central nervous systemdamage. Lung damage. Kidney damage. Liverdamage.
Ingestion No hazard under normal industrial and institutionaluse. Harmful or fatal if swallowed. Can burn mouth,throat, and stomach.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name CAS-No Weight %
Propane/Isobutane/N-Butane
68476-86-8 40-50
2-Propanone 67-64-1 20-30
Dimethylbenzene 1330-20-7 10-20
Isopropyl Alcohol 67-63-0 1-10
Ethylbenzene 100-41-4 1-10
Molybdenum sulfide 1317-33-5 1-10
4. FIRST AID MEASURES
Eye contact Flush eyes immediately with large amounts ofwater. Seek medical attention if irritation persists.
Skin contact Wash off immediately with soap and plenty ofwater. Seek medical attention if irritation persists.
Ingestion Seek medical attention immediately. Do not inducevomiting. Give victim a glass of water or milk.Contact physician or poison control centerimmediately. Do not give anything by mouth to anunconscious person.
Inhalation Move to fresh air. If not breathing, give artificialrespiration. If breathing is difficult, give oxygen.Immediate medical attention is required.
5. FIRE FIGHTING MEASURES
Flash point °C -96.11
Flash point °F -141
Method Pensky-Martens C.C.
Autoignition temperature °C No data available
Autoignition temperature °F No data available
Flammability Limits (% in Air)Upper 12.8
Lower 0.8
Specific Information for Aerosol Products
Flame extension Unknown
Flashback Unknown
Suitable extinguishing mediaAlcohol foam. Carbon dioxide (CO2). Dry chemical powder. Foam. Waterfog.
Special protective equipment for firefightersAs in any fire, wear self-contained breathing apparatus pressure-demand,MSHA/NIOSH (approved or equivalent) and full protective gear.
Fire and Explosion HazardsContainers may vent or burst under extreme or prolonged fire conditions.Vapors are heavier than air and may travel along the ground to an ignitionsource distant from material handling area. Possible ignition sourcesinclude pilot lights, flames, lighted cigarettes, heating elements, electricmotors, sparks from electrical switches. Empty containers contain residueand/or vapors. Do not weld, cut, pressurize, braze, solder, drill, grind, orexpose such containers to heat, sparks, flame, static electricity, or othersources of ignition. They may explode and cause injury or death.
Sensitivity to shockNo information available.
_______________________________________________
Page 1 / 4
Emergency OverviewVapors may be irritating to eyes, nose, throat, and lungs. Vapors may
cause flash fire or explosion.
_______________________________________________
Sensitivity to static dischargeNo information available.
6. ACCIDENTAL RELEASE MEASURES
Methods for cleaning upSoak up with noncombustible inert absorbent material. Place in suitablecontainer for disposal as hazardous waste.
7. HANDLING AND STORAGE
HandlingThoroughly wash hands and exposed skin after handling. Wash handswith soap and water before eating, drinking, smoking, or using toiletfacilities. Control airborne concentration below exposure level. Use onlyaccording to label directions. Handle empty containers as if they were full.Avoid breathing vapors. Do not get on skin or in eyes.
StorageKeep away from heat. Keep away from open flames, hot surfaces andsources of ignition. Do not freeze.
NFPA Storage CodeStore as Level 3 Aerosol (NFPA 30B)
8. EXPOSURE CONTROLS / PERSONALPROTECTION
ChemicalName
OSHA PEL(TWA)
OSHA PEL(Ceiling)
ACGIH OEL(TWA)
ACGIH OEL(STEL)
Propane/Isobutane/N-Butane
- - - -
2-Propanone 1000 ppm2400 mg/m3
- 500 ppm 750 ppm
Dimethylbenzene
100 ppm435 mg/m3
- 100 ppm 150 ppm
IsopropylAlcohol
400 ppm980 mg/m3
- 200 ppm 400 ppm
Ethylbenzene 100 ppm435 mg/m3
- 20 ppm -
Molybdenumsulfide
- - - -
Ventilation and Environmental ControlsUse enough ventilation, local exhaust at the work area, general, or both,to keep below the TLV's in the worker's breathing zone and the generalarea.
Hygiene measuresHandle in accordance with good industrial hygiene and safety practice.
Other precautionsAvoid contact with skin, eyes and clothing.
Respiratory protectionIf the exposure limits are exceeded, a NIOSH/MSHA approved respiratoris recommended. Protection provided by air purifying respirators islimited. Use a positive pressure supplied air respirator. if there is anypotential for an uncontrolled release:. where exposure levels are notknown. or other circumstances where an air purifying respirator (P100)may not provide adequate protection . Seek professional advise prior torespirator selection and use.
Hand ProtectionChemical resistant gloves. Consult glove manufacturer to determine theproper type for a specific operation.
Eye protectionWear safety glasses with side shields.
Skin and body protectionWear appropriate clothing to minimize skin contact.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form Aerosol
Color Black - Green
Odor Solvent
Odor Threshold No information available
pH Not Applicable
Specific Gravity 0.6752
Vapor pressure No data available
Vapor density heavier than air
Evaporation Rate Is faster than Butyl Acetate
Water solubility Negligible
VOC Content 68.6%; 369 gm/liter; 3.08 lbs/gal
Partition Coefficient (n-octanol/water)
No data available
Boiling point/range °C -30.6 - 175
Boiling point/range °F -23 - 284
Melting point/range °C No data available
Melting point/range °F No data available
Flash point °C -96.11
Flash point °F -141
10. STABILITY AND REACTIVITY
StabilityStable under normal conditions.
Conditions to avoidContact with ignition sources, hot-glowing surfaces, electrical arcs,sparks, and open flame. Do not use near welding arcs.
IncompatabilityStrong acids. Alkalies. Oxidizers.
_______________________________________________
Page 2 / 4
Product code 92964 Product name Moly Coat
_______________________________________________
Hazardous Decomposition ProductsCarbon oxides.
PolymerizationWill not occur.
11. TOXICOLOGICAL INFORMATION
Component Information
Chemical Name LD50(oral,rat
)
LD50(dermal,rat/rab
bit)
LC50 (inhalation,rat)
Propane/Isobutane/N-Butane68476-86-8
- - -
2-Propanone67-64-1
5800mg/kg
- -
Dimethylbenzene1330-20-7
4300mg/kg
1700mg/kg
47635 mg/L5000 ppm
Isopropyl Alcohol67-63-0
4396mg/kg
12800mg/kg12870mg/kg
72.6 mg/L
Ethylbenzene100-41-4
3500mg/kg
15354mg/kg
17.2 mg/L
Molybdenumsulfide1317-33-5
- - 2820 mg/m3
Synergistic Products None known
Potential health effects
Sensitization None known
Chronic toxicity Possible risks of irreversible effects .Prolonged exposure may causechronic effects .
Mutagenic effects None known
Teratogenic effects None known
Reproductive toxicity None known
Target Organ Effects Long term exposure to vapor maycause lung damage. Long termexposure to vapor may cause kidneydamage. Central nervous system.
Carcinogenic effects See table below
ChemicalName
ACGIHOEL -
Carcinogens
IARC NTP -Known
Carcinogens
NTP -Suspected
HumanCarcinoge
ns
OSHARTK
Carcinogens
Propane/Isobutane/N-Butane
Not Listed Not Listed Not Listed Not Listed Not Listed
2-Propanone A4 Not Listed Not Listed Not Listed Not Listed
Dimethylbenzene
A4 Not Listed Not Listed Not Listed Not Listed
IsopropylAlcohol
A4 Not Listed Not Listed Not Listed Not Listed
Ethylbenzene A3 Group 2B Not Listed Not Listed Listed
Molybdenumsulfide
Not Listed Not Listed Not Listed Not Listed Not Listed
12. ECOLOGICAL INFORMATION
13. DISPOSAL CONSIDERATIONS
Disposal InformationDispose in accordance with federal, state, and local regulations.
14. TRANSPORTATION INFORMATION
DOTConsumer commodity, ORM-D
TDGConsumer commodity, ORM-D
15. REGULATORY INFORMATION
Chemical Name US EPA SARA 313 Emission Reporting
Dimethylbenzene Listed
Isopropyl Alcohol Listed
Ethylbenzene Listed
State Regulations
_______________________________________________
Page 3 / 4
Microtox DataPhotobacterium phosphoreum EC50=9.68 mg/L (30 min)Nitrosomonas EC50=96 mg/L (24 h)
Product name Moly Coat
Water Flea DataDaphnia magna EC501.8 - 2.4 mg/L (48 h)
Microtox DataPhotobacterium phosphoreum EC50=0.0084 mg/L (24 h)
Microtox DataPhotobacterium phosphoreum EC50=14500 mg/L (15 min)
Water Flea Datawater flea hEC50 48 (3.82 mg/L)Gammarus lacustris hLC50 48 (0.6 mg/L)water flea hEC50 48 (3.82 mg/L)
Isopropyl Alcohol
Product code 92964
Microtox DataPhotobacterium phosphoreum EC50=35390 mg/L (5 min)
Water Flea DataDaphnia magna EC5010294 - 17704 mg/L (48 h)Daphnia magna EC5012600 - 12700 mg/L (48 h)
Water Flea DataDaphnia magna EC50=13299 mg/L (48 h)
2-Propanone
Ethylbenzene
Dimethylbenzene
_______________________________________________
Chemical Name New Jersey -RTK
Pennsylvania- RTK
CaliforniaProp. 65
Propane/Isobutane/N-Butane
Not Listed Not Listed Not Listed
2-Propanone Not Listed Listed Not Listed
Dimethylbenzene Not Listed Listed Not Listed
Isopropyl Alcohol Not Listed Listed Not Listed
Ethylbenzene Not Listed Listed Carcinogen
Molybdenum sulfide Not Listed Not Listed Not Listed
WARNING: This product contains a chemical(s) known to the state ofCalifornia to cause cancer and birth defects or other reproductive harm
International Inventories
Chemical Name EINECS DSL NDSL TSCA
Propane/Isobutane/N-Butane
X X - X
2-Propanone X X - X
Dimethylbenzene X X - X
Isopropyl Alcohol X X - X
Ethylbenzene X X - X
Molybdenum sulfide X X - X
CPRThis product has been classified in accordance with the hazard criteria ofthe Controlled Product Regulations and the MSDS contains all of theinformation required by the Controlled Product Regulations.
16. OTHER INFORMATION
HMIS
Health - 2Flammability - 4Physical Hazard - 0
Prepared By V. Shargorodsky, Regulatory AffairsEngineer
The information accumulated herein is believed to be accurate, but is notwarranted to be, whether originating with the company or not. Recipientsare advised to confirm in advance of need that the information is current,applicable, and suitable to their circumstances.
_______________________________________________
Page 4 / 4
Product code 92964 Product name Moly Coat
MSD Consumer Care, Inc.3535 Trans-CanadaPointe Claire, QuebecCanada H9R 1B4
MATERIAL SAFETY DATA SHEET
MSD Consumer Care, Inc. urges each user or recipient of this MSDS to read the entire data sheet to become aware of the hazards associated with thismaterial.
SECTION 1. IDENTIFICATION OF SUBSTANCE AND CONTACT INFORMATION
MSDS NAME: Muskol Aerosol, 23.5% DEET
SYNONYM(S): Muskol Insect Repellent Aerosol
MSDS NUMBER: SP001588
EMERGENCY NUMBER(S): (908) 423-6000 (24/7/36) English Only
Transportation Emergencies - CANUTEC: (613) 996-6666 (Canada)
INFORMATION: Merck Consumer Care Products CanadaCustomer Service (English): 1-800-361-6550Service à la clientèle (French): 1-800-361-2431
MERCK MSDS HELPLINE: (908) 473-3371 (Worldwide)Monday to Friday, 9am to 5pm (US Eastern Time)
SECTION 2. HAZARDS IDENTIFICATION
Consumers: Refer to the package insert or product label for appropriate consumer-specific information about this product when used according tomanufacturer's directions.
POTENTIAL HEALTH EFFECTS:
The following summary is based upon available information about the individual ingredients of the mixture, or of the expected properties of the mixture.
May be harmful to fish and aquatic organisms.
Alcohol odor
Aerosol
Flammable.
EMERGENCY OVERVIEW
May be severely irritating to the eyes.May be harmful by inhalation.Absorbed through the skin.Harmful if swallowed or absorbed through the skin in large amounts.
May cause effects to:nervous systemcardiovascular systemliverkidney
Clear, Light yellow
DEET is a common insect repellent which is applied directly to the skin. DEET may cause stinging and slight to moderate eye and mucous membraneirritation. DEET may cause contact dermatitis or excerbation of pre-existing skin disease in sensitive individuals. DEET is efficiently absorbed from theskin or gut. If large amounts of DEET are inhaled, ingested, or applied dermally (especially areas of skin that are occluded), the potential for severetoxicity exists. However, compared to the widespread use of the product, there are relatively few cases of toxicity. Reported acute or chronic effectsfrom overexposure to DEET were restlessness, drowsiness, irritability, weakness, headaches, incoordination, slurred speech, confusion, insomnia,tremor, flexing or extending of extremities, decreases in blood pressure, decreased heartbeat, skin effects (rashes, bullous eruptions and necrosis),pyschosis, seizures, prolonged disability, coma, or anaphylactic reaction. Death has been reported when large amounts of DEET were ingested.
Ethanol (ethyl alcohol) is an eye, nose, and mucous membrane irritant. It may cause skin irritation or sensitization after prolonged exposure. Acuteeffects of ethanol may include headache, dizziness, nausea, sensations of warmth and cold, numbness, fatigue, breathing difficulty, cough, tearing,vision impairment, incoordination, decreased reaction time, alteration of mood and personality, slurred speech, coma and respiratory depression.Chronic effects may include concentration difficulty, sleepiness, kidney and liver damage, and cardiac effects. Chronic ingestion of ethanol may causecancer of the oral cavity, pharynx, larynx, esophagus, and liver. Oral ingestion of alcohol during pregnancy may cause Fetal Alcohol Syndrome (FAS)including joint, limb, and cardiac abnormalities and behavioral and learning impairment. There have been no reports of FAS as a result of occupationalhandling of ethanol.
Isobutane and propane are simple asphixiant gases (displaces oxygen from the breathing atmosphere), anesthetics, and central nervous systemdepressants. Inhalation exposure to high concentrations may cause fatigue, vomiting, nausea dizziness, decreased vision, mood disturbances,numbness of extremities (e.g. fingers), headache, confusion, decreased coordination and judgment, breathing difficulties, irregular heartbeat, cyanosis,convulsions, or coma. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. Direct contact with liquefiedisobutane or propane may cause frostbite or burns to the eyes or following prolonged skin contact.
LISTED CARCINOGENS
INGREDIENT CAS NUMBER OSHA IARC NTP ACGIH
Ethyl Alcohol 64-17-5 K A3
Ethanol (ethyl alcohol): IARC (International Agency for Research on Cancer) has classified Alcoholic Beverages as Group 1 (indicating in theirevaluation that the agent is carcinogenic to humans). However, occupational handling or manufacturer's specified use of this product is not expected toresult in relevant exposures. K (NTP): NTP - Known Human Carcinogen A3 (ACGIH): ACGIH A3 - Confirmed Animal Carcinogen with UnknownRelevance to Humans
SECTION 3. COMPOSITION AND INFORMATION ON INGREDIENTS
PRODUCT USE: Consumer product
CHEMICAL FORMULA: Mixture.
The formulation for this product is proprietary information. Only hazardous ingredients in concentrations of 1% or greater and/or carcinogenic ingredientsin concentrations of 0.1% or greater are listed in the Chemical Composition table. Active ingredients in any concentration are listed.
CHEMICAL COMPOSITION
INGREDIENT CAS NUMBER PERCENT
Isobutane 75-28-5 1-5
Ethyl Alcohol 64-17-5 30-60
Diethyltoluamide (DEET) 134-62-3 23.5
Propane 74-98-6 10-30
ADDITIONAL INFORMATION: This MSDS is written to provide health and safety information for individuals who will be handling the finalproduct formulation during research, manufacturing, and distribution. For health and safety information forindividual ingredients used during manufacturing, refer to the appropriate MSDS for each ingredient. Referto the package insert or product label for handling guidance for the consumer.
SECTION 4. FIRST AID MEASURES
INHALATION: Remove to fresh air. If any trouble breathing, get immediate medical attention. Administer artificialrespiration if breathing has ceased. If irritation or symptoms occur or persist, consult a physician.
SKIN CONTACT: In case of skin contact, while wearing protective gloves, carefully remove any contaminated clothing,including shoes, and wash skin thoroughly with soap and water. If irritation or symptoms occur or persist,consult a physician.
MSDS NUMBER: SP001588MSDS NAME: Muskol Aerosol, 23.5% DEET
Latest Revision Date: 11-Mar-2014 Page 2 of 8
SECTION 4. FIRST AID MEASURESEYE CONTACT: In case of eye contact, IMMEDIATELY rinse eyes thoroughly with plenty of water. If wearing contact
lenses, remove only after initial rinse, and continue rinsing eyes for at least 15 minutes. Get IMMEDIATEmedical attention.
INGESTION: Rinse mouth and drink a glass of water. Do not induce vomiting unless under the direction of a qualifiedmedical professional or Poison Control Center. If symptoms persist, consult a physician.
SECTION 5. FIRE FIGHTING MEASURES
FLAMMABILITY DATA:
Flash Point: Concentrate (Similar Product Formulation): 13 deg C (55.4 deg F) Method: Tagliabue closed cup (TCC)Ethanol (50%): 24 deg C ( 79 deg F) Method: Close cupPropellant:: -84.4 deg C (-120 deg F)
Classification: Flammable (US OSHA Criteria)Flammable (Canada WHMIS Criteria)
Autoignition Temperature: Concentrate: 422 deg C ( 791.6 deg F )
SPECIAL FIRE FIGHTING PROCEDURES:Wear full protective clothing and self-contained breathing apparatus (SCBA).
SUITABLE EXTINGUISHING MEDIA:Carbon dioxide (CO2), extinguishing powder or water spray.
See Section 9 for Physical and Chemical Properties.
SECTION 6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS:Wear appropriate personal protective equipment as specified in Section 8. Keep personnel away from the clean-up area.
SPILL RESPONSE / CLEANUP:All spills should be handled according to site requirements and based on precautions cited in the MSDS. In the case of liquids, use proper absorbentmaterials. For laboratories and small-scale operations, incidental spills within a hood or enclosure should be cleaned by using a HEPA filtered vacuum orwet cleaning methods as appropriate. For large dry or liquid spills or those spills outside enclosure or hood, appropriate emergency response personnelshould be notified. In manufacturing and large-scale operations, HEPA vacuuming prior to wet mopping or cleaning is required.
See Sections 9 and 10 for additional physical, chemical, and hazard information.
SECTION 7. HANDLING AND STORAGE
HANDLING:Keep containers adequately sealed during material transfer, transport, or when not in use. Wash face, hands, and any exposed skin after handling. Donot eat, drink, or smoke when using this substance or mixture.
Appropriate handling of this material is dependent on many factors, including physical form, duration and frequency of process or task, and effectivenessof engineering controls. Site-specific risk assessments should be conducted to determine the feasibility and the appropriateness of all exposure controlmeasures. See Section 8 (Exposure Controls) for additional guidance.
STORAGE:Store in a cool, dry, well ventilated area. Keep away from heat, sparks, open flames, and direct sunlight.
See Section 8 for exposure controls and additional safe handling information.
MSDS NUMBER: SP001588MSDS NAME: Muskol Aerosol, 23.5% DEET
Latest Revision Date: 11-Mar-2014 Page 3 of 8
SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
EXPOSURE CONTROLSThe health hazard risks of handling this material are dependent on many factors, including physical form, duration and frequency of process or task, andeffectiveness of engineering controls. Site-specific risk assessments should be conducted to determine the feasibility and the appropriateness of allexposure control measures. Exposure controls for normal operating or routine procedures follow a tiered strategy. Engineering controls are thepreferred means of long-term or permanent exposure control. If engineering controls are not feasible, appropriate use of personal protective equipment(PPE) may be considered as alternative control measures. Exposure controls for non-routine operations must be evaluated and addressed as part ofthe site-specific risk assessment.
RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT (PPE):
Respiratory Protection: None required for consumer use of this product.
Respiratory protective equipment (RPE) may be required for certain laboratory and large-scalemanufacturing tasks if potential airborne breathing zone concentrations of substances exceed the relevantexposure limit(s). Workplace risk assessment should be completed before specifying and implementingRPE usage. Potential exposure points and pathways, task duration and frequency, potential employeecontact with the substance, and the ability of the substance to be rendered airborne during specific tasksshould be evaluated. Initial and ongoing strategies of quantitative exposure measurement should beobtained as required by the workplace risk assessment. All RPE must conform to local and regionalspecifications for efficacy and performance. Consult your site or corporate health and safety professionalfor additional guidance.
Skin Protection: None required for consumer use of this product.
Gloves that provide an appropriate barrier to the skin are recommended if there is potential for contact withthis material. Consult your site safety staff for guidance.
Eye Protection: None required for consumer use of this product.
Safety glasses with side shields. Use of goggles or full face protection is required if there is potential forcontact with this material. Consult your site safety staff for guidance.
Body Protection: None required for consumer use of this product.
In small-scale or laboratory operations, lab coats or equivalent protection is required. Disposable Tyvek orother dust impermeable suit should be considered based on procedure or level of exposure. Use ofadditional PPE such as shoe coverings, gauntlets, hood, or head covering may be necessary. Consultyour site safety staff for guidance.
In large-scale or manufacturing operations, disposable Tyvek or other dust impermeable suit isrecommended and based on level of exposure. Use of additional PPE such as shoe coverings, gauntlets,hood, or head covering may be necessary. Consult your site safety staff for guidance.
EXPOSURE LIMIT VALUES
INGREDIENT CAS NUMBER ACGIH TLV (TWA) OSHA PEL (TWA)
Isobutane 75-28-5 1000 ppm
Ethyl Alcohol 64-17-5 1000 ppm1900 mg/m3
Propane 74-98-6 1000 ppm 1000 ppm1800 mg/m3
INGREDIENT CAS NUMBER ACGIH TLV (STEL/ SKIN)
ACGIH TLV(CEIL)
OSHA PEL(STEL / SKIN)
OSHA PEL(CEIL)
Ethyl Alcohol 64-17-5 1000 ppm
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
FORM: Aerosol
COLOR: Clear, Light yellow
ODOR: Alcohol odor
BOILING POINT / RANGE: 79-100 deg C
VAPOR PRESSURE: 45-55 psi @ 20 deg C
VAPOR DENSITY: >1
MSDS NUMBER: SP001588MSDS NAME: Muskol Aerosol, 23.5% DEET
Latest Revision Date: 11-Mar-2014 Page 4 of 8
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIESSPECIFIC GRAVITY: Aerosol: 0.75-0.79
Concentrate: 0.85-0.89
SOLUBILITY:
Water: Not determined
EVAPORATION RATE: >1
See Section 5 for flammability/explosivity information.
SECTION 10. STABILITY AND REACTIVITY
STABILITY/ REACTIVITY:Stable under normal conditions.
INCOMPATIBLE MATERIALS / CONDITIONS TO AVOID:Oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS / REACTIONS:No dangerous decomposition is expected if used according to manufacturer's specifications.
SECTION 11. TOXICOLOGICAL INFORMATION
There are no data available specifically for this formulation. The data shown below pertains to the following individual ingredients in the formulation, orare from studies conducted using similar formulas containing the same active and/or hazardous ingredients found in this product.
ACUTE TOXICITY DATA
INHALATION:Deet: LC50: 5.95 mg/L
Ethanol: Inhalation LC50 (10hr): 20,000ppmEthanol caused dose dependent effects following inhalation exposure in rats on the central nervous system including drowsiness, incoordination,narcosis and excitation.
Propane caused irregular breathing, tremors, stupor, and CNS depression in guinea pigs exposed to 2.2 to 5.5% (24,000 to 55,000 ppm). Effects wererapidly reversible upon cessation of exposure. In cats, 89% propane caused a decrease in blood pressure, and in dogs, 1% to 3.3% causedhemodynamic changes, decreases in mean arotic pressure, stroke volume, and cardiac output, increase in pulmonary vascular resistance, anddecreases in the contractility of the heart muscle. Weak cardiac sensitization was observed in mice and dogs exposed to 10 to 15% propane.Respiratory depression was observed in non-human primates exposed to 20% propane.
Isobutane caused CNS depression, rapid and shallow respiration, and apnea in mice exposed to high concentrations. In dogs, 45% isobutane causedanesthetic effects.
SKIN:Similiar product formulations were shown to be slightly irritating to animals.
DEET caused minimal to moderate transient dermal irritation in animals, which cleared by day 7.
Ethanol was mildly to moderately irritating to the skin of rabbits.
Propane is a moderate irritant.
EYE:Similar product formulations were shown to be moderate to severe eye irritants to animals.
Ethanol (95%) was irritating to the eyes of rabbits.
ORAL:Clinical signs of toxicity noted in animals treated with DEET at 50 to 500 mg/kg included piloerection, increased vocalization and decreased activity. Atlethal doses, animals showed signs of lacrimation, depression, prostration, tremors, asphyxial convulsions or respiratory failure usually preceding cardiacfailure.
Ethanol: Oral LD50: 6.2 to 17.8 g/kg (rat); 5.5 to 6.6 g/kg (dog)
DERMAL AND RESPIRATORY SENSITIZATION:Ethanol has been shown to be a weak sensitizer in a human patch test. Ethanol was negative in the mouse ear sensitization assay.
MSDS NUMBER: SP001588MSDS NAME: Muskol Aerosol, 23.5% DEET
Latest Revision Date: 11-Mar-2014 Page 5 of 8
REPEAT DOSE TOXICITY DATA
SUBCHRONIC / CHRONIC TOXICITY:Subchronic (56 to 90 days) to chronic (2-year) oral studies with DEET were conducted in animals. Effects noted at dosages ranging from 8.4 to 10,000mg/kg/day included decreases in food consumption and weight, salivation, tremors, elevated liver and kidney weights and cholesterol, and death (highdose groups only). Microscopic findings were observed in the kidneys, testis, epidiymides, and uterus. NOELs ranged from 61 to 100 mg/kg/day acrossspecies.
Repeated oral and inhalation exposure to high concentrations of ethanol has caused kidney and liver damage in animals.
REPRODUCTIVE / DEVELOPMENTAL TOXICITY:DEET caused no effects on reproduction or development in animals administered oral doses up to 1,000 mg/kg/day. Maternal toxicity was observed atthe higher dosages and was consisted with that seen in acute, subchronic and chronic studies. The reproductive and developmental NOEL was 250mg/kg/day.
Ethanol: Exposure to large doses during gestation is reported to cause effects on reproduction, including fetotoxicity and growth retardation in mice,rats, and rabbits. However, no teratogenic effects were reported.
MUTAGENICITY / GENOTOXICITY:DEET was negative in a bacterial mutagenicity study (Ames), a chromosome aberration study, a dominant lethal test, and in an unscheduled DNAsynthesis assay. DEET was negative in a mouse lymphoma assay without metabolic activation but positive with metabolic activation.
Ethanol was positive in a bacterial mutagenicity study (Ames) and negative in a mammalian mutagenicity study (mouse lymphoma).
Propane was negative in a bacterial mutagenicity study.
Isobutane was negative in a bacterial mutagenicity study (Ames).
CARCINOGENICITY:This material or product has not been evaluated for carcinogenicity.
There was no evidence of carcinogenicity in mice or rats treated with DEET at dosages up to 1000 mg/kg/day for 78 weeks and 2 years, respectively.
Rats given 25 to 50% ethanol by oral gavage or in the drinking water for one to two years did not show a significant increase in tumors compared to thecontrol groups. Mice given 43% ethanol in drinking water for three years showed an increase in papillomas of the forestomach, malignant lymphomasand lung adenomas. Ethanol was an effective promoter of liver tumors in rats given a single intraperitoneal dose of diethylnitrosamine followed bytreatment of ethanol in the drinking water for 12 to 18 months.
SECTION 12. ECOLOGICAL INFORMATION
There are no data for the final product or its formulation(s). The information presented below pertains to the following ingredient(s).
ECOTOXICITY DATA
INGREDIENT ECOTOXICITY Deet: 96-hr LC50 (rainbow trout): 75 mg/LDeet: 48-hr EC50 (daphnid): 75 mg/LDeet: Avian Oral LD50 (quail): 1375 mg/kg
Ethanol: 96-hr (static) LC50 (rainbow trout): 13 g/LEthanol: 96-hr (flow-through) LC50 (fathead minnow): 12.9-15.3 g/L
ENVIRONMENTAL DATA
OTHER INGREDIENT ENVIRONMENTAL DATA: DEET: n-Octanol/Water Partition Coefficient (log Pow): 2.02DEET will be stable to hydrolysis at pH levels 5 to 9.
SECTION 13. DISPOSAL CONSIDERATIONS
MATERIAL WASTE:Disposal must be in accordance with applicable federal, state/provincial, and/or local regulations. Incineration is not the preferred method of disposal.Operations that involve the crushing or shredding of waste materials or returned goods must be handled to meet the recommended exposure limit(s).
PACKAGING AND CONTAINERS:Disposal must be in accordance with applicable federal, state/provincial, and/or local regulations.
MSDS NUMBER: SP001588MSDS NAME: Muskol Aerosol, 23.5% DEET
Latest Revision Date: 11-Mar-2014 Page 6 of 8
SECTION 14. TRANSPORT INFORMATION
Refer to site-specific procedures and requirements for additional guidance.
DOT CLASSIFICATION:
Proper Shipping Name: AerosolsHazard Class: 2.1UN Number: UN 1950Packing Group: None
IATA/ICAO CLASSIFICATION:
Proper Shipping Name: Aerosols, flammableHazard Class: 2.1UN Number: UN 1950Packing Group: None
ADR CLASSIFICATION:
Proper Shipping Name: AerosolsHazard Class: 2.1UN Number: UN 1950Packing Group: None
IMDG/IMO CLASSIFICATION:
Proper Shipping Name: AerosolsHazard Class: 2UN Number: UN 1950Packing Group: None
SECTION 15. REGULATORY INFORMATION
WHMIS CLASSIFICATIONS:
This product has been classified in accordance with the hazard criteria on the Controlled Products Regulations and the MSDS contains all theinformation required by the Controlled Products Regulations. The final packaged product is not subject to WHMIS classification. The followingclassification applies to the bulk formulation handled in the workplace.
Controlled Product Class: B5: Flammable AerosolD1B: ToxicD2B: Toxic
TSCA LISTING
INGREDIENT TSCA
Isobutane X
Ethyl Alcohol X
Diethyltoluamide (DEET) X
Propane X
SECTION 16. OTHER INFORMATION
Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracyor completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intendedpurposes or for the consequence of its use. Each individual should make a determination as to the suitability of the information for their particularpurpose(s).
MSDS NUMBER: SP001588
Latest Revision Date: 11-Mar-2014 Page 7 of 8
MSDS NAME: Muskol Aerosol, 23.5% DEET
DEPARTMENT ISSUING MSDS: Global Safety & the EnvironmentMerck & Co., Inc.One Merck DriveWhitehouse Station, NJ 08889
MERCK MSDS HELPLINE: (800) 770-8878 (US and Canada)(908) 473-3371 (Worldwide)Monday to Friday, 9am to 5pm (US Eastern Time)
MSDS CREATION DATE: 24-Oct-2002
SUPERSEDES DATE: 03-Mar-2011
SECTIONS CHANGED (CAN SUBFORMAT): 1, 16
SIGNIFICANT CHANGES (CAN SUBFORMAT): Phone Number(s)
MSDS NUMBER: SP001588MSDS NAME: Muskol Aerosol, 23.5% DEET
Latest Revision Date: 11-Mar-2014 Page 8 of 8
NEMCO RESOURCES LTD. Page 1 of 13 SR-1 Antifreeze & Coolant Pure
Date of issue: October, 2013. www.NEMCO.ca Emergency Number: 1-204-788-1030 CANUTEC : 1-613-996-6666
MATERIAL SAFETY DATA SHEET
1. Product and company identification
PRODUCT NAME : SR-1 Antifreeze & Coolant Pure
PRODUCT CODE : 0696
SUPPLIER : NEMCO RESOURCES LTD.
25 Midland Street
Winnipeg, Manitoba
R3E 3J6 Canada
Date Issued : October, 2013
Emergency (call collect) : 204-788-1030
CANUTEC : 613-996-6666
2. Hazards identification
EMERGENCY OVERVIEW
Slight odor.
May be fatal if swallowed.
Vapors can cause eye irritation.
Lowest Known LD50 (Oral) 107-21-1 >5000 mg/kg (Rats)
Lowest Known LD50 (Skin) 107-21-1 >8000 mg/kg (Rabbits)
HAZARD RATING SYSTEM
NFPA: HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0
HMIS: HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0
KEY: 0 – Minimal 1 – Slight 2 - Moderate 3 - Serious 4 - Severe
POTENTIAL ACUTE HEALTH EFFECTS
Inhalation : At room temperature, exposures to vapors are minimal due to physical properties; higher temperatures may generate vapor levels sufficient to cause adverse effects.
Ingestion : Single dose oral toxicity is considered to be moderate. Excessive exposure may cause central nervous system effects, cardiopulmonary effects (metabolic acidosis), and kidney failure. Small amounts swallowed incidental to normal handling operations are not likely to cause injury; however, swallowing amounts larger than that may cause serious injury, even death
NEMCO RESOURCES LTD. Page 2 of 13 SR-1 Antifreeze & Coolant Pure
Date of issue: October, 2013. www.NEMCO.ca Emergency Number: 1-204-788-1030 CANUTEC : 1-613-996-6666
Eye : May cause slight transient (temporary) eye irritation. Corneal injury is unlikely. Vapors or mists may cause eye irritation.
2. Hazards identification
Skin : Prolonged or repeated exposure not likely to cause significant skin irritation. A single prolonged exposure is not likely to result in the material being absorbed through skin in harmful amounts. Repeated skin exposure may result in absorption of harmful amounts. Massive contact with damaged skin or of material sufficiently hot to burn skin may result in absorption of potential lethal amounts.
Systemic (Other Target Organ) Effects
: The signs and symptoms in ethylene glycol poisoning are those of metabolic acidosis, central nervous system depression and kidney injury. Clinical chemistry may reveal anion-gap metabolic acidosis and uremia. Treatment with ethanol to inhibit the metabolism of glycol to oxalate.Early administration of ethanol may counter the toxic effects of ethylene glycol (cardiopulmonary effects attributed to metabolic acidosis and renal damage). Hemodialysis or peritoneal dialysis have been of benefit. Pre-existing respiratory and skin disorders may be aggravated by over-exposure to this product. Treat symptomatically and supportively.
Cancer Information : Based on data from long-term animal studies, ethylene glycol is not believed to pose a carcinogenic risk to man.
Teratology (Birth Defects) : Exposure to ethylene glycol has caused birth defects in laboratory animals only at doses toxic to the mother.
Reproductive Effects : Ethylene glycol has not interfered with reproduction in animal studies except at very high doses.
CHRONIC, PROLONGED OR REPEATED OVEREXPOSURE
Effects of Repeated Overexposure
: Repeated inhalation of ethylene glycol mist may produce signs of central nervous system involvement, particularly dizziness and nystagmus.
Other Effects of Overexposure : repeated skin contact with ethylene glycol may, in a very small proportion of cases, cause sensitization with the development of allergic contact dermatitis. The incidence is significantly less than 1% with the undiluted material.
3. COMPOSITION/INFORMATION ON INGREDIENTS Material CAS# % by Wt PEL (OSHA) TLV (ACGIH) Ethylene Glycol 107-21-1 >95 50 ppm 50 ppm
4. FIRST AID MEASURES
EYE CONTACT : Immediately flush eyes with large amounts of water for 15 minutes, lifting lower and upper lids. Get medical attention as soon as possible. Contact lenses should never be worn when working with this chemical.
SKIN CONTACT : Flush area of skin contact immediately with large amounts of water for at least 15 minutes while removing contaminated clothing. If irritation persists after flushing, get medical attention promptly. Wash clothing before re-use.
INHALATION : If inhaled, immediately remove victim to fresh air and call emergency medical care. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
INGESTION : Obtain medical attention immediately. If patient is fully conscious, give two glasses of water. Do not induce vomiting. If medical advice is delayed, and if the person has swallowed a moderate volume of material (a few ounces), then give three to four ounces of hard liquor, such as whisky. For children, give proportionally less liquor, according to weight.
NEMCO RESOURCES LTD. Page 3 of 13 SR-1 Antifreeze & Coolant Pure
Date of issue: October, 2013. www.NEMCO.ca Emergency Number: 1-204-788-1030 CANUTEC : 1-613-996-6666
4. FIRST AID MEASURES Notes to physician : It is estimated that the lethal oral dose to adults is of the order of 1.0 ml/kg. Ethylene glycol is
metabolized by alcohol dehydrogenate to various metabolites including glyceraldehydes, glycolic acid and oxalic acid which cause an elevated anion-gap metabolic acidosis and renal tubular injury. The signs and symptoms in ethylene glycol poisoning are those of metabolic acidosis, CNS depression, and kidney injury. Urinalysis may show albuminuria, hematuria and oxaluria. Clinical chemistry may reveal anion-gap metabolic acidosis and uremia. The currently recommended medical management of ethylene glycol poisoning includes elimination of ethylene glycol and metabolites, correction of metabolic acidosis and prevention of kidney injury. It is essential to have immediate and follow up urinalysis and clinical chemistry. There should be particular emphasis on acid-base balance and renal function tests. A continuous infusion of 5% sodium bicarbonate with frequent monitoring of electrolytes and fluid balance is used to achieve correction of metabolic acidosis and forced diuresis. As a competitive substrate for alcohol dehydrogenase, ethanol is antidotal. Given in the early stages of intoxication, it blocks the formulation of nephrotoxic metabolites. A therapeutically effective blood concentration of ethanol is in the range 100-150 mg/dl, and should be achieved by a rapid loading dose and maintained by intravenous infusion. For severe and/or deteriorating cases, hemodialysis may be required. Dialysis should be considered for patients who are symptomatic, have severe metabolic acidosis, a blood ethylene glycol concentration greater than 25 md/dl, or compromise of renal functions. A more effective intravenous antidote for physician use is 4-methylpyrazole, a potent inhibitor of alcohol dehydrogenases, which effectively blocks the formation of toxic metabolites of ethylene glycol. It has been used to decrease the metabolic consequences of ethylene glycol poisoning before metabolic acidosis coma, seizures, and renal failure have occurred. A generally recommended protocol is a loading dose of 15 mg/kg followed by 10 mg/kg every 12 hours for 4 doses and then 15 mg/kg every 12 hours until ethylene glycol concentrations are below 20 mg/100 ml. Slow intravenous infusion is required. Since 4-methyplyrozole is dialyzable, increased dosage may be necessary during hemodialysis. Additional therapeutic measures may include the administration of cofactors involved in the metabolism of ethylene glycol. Thiamine (100 mg) and pyridoxine (50 mg) should be given every six hours. Pulmonary edema with hypoxemia has been described in a number of patients following poisoning with ethylene glycol. The mechanism of production has not been elucidated, but it appears to be non-cardiogenic in origin in several cases. Respiratory support with mechanical ventilation and positive end expiratory pressure may be required. There may be cranial nerve involvement in the late stages of toxicity from swallowed ethylene glycol. In particular, effects have been reported involving the seventh, eighth and ninth cranial nerves, presenting with bilateral facial paralysis, diminished hearing and dysphasia..
NEMCO RESOURCES LTD. Page 4 of 13 SR-1 Antifreeze & Coolant Pure
Date of issue: October, 2013. www.NEMCO.ca Emergency Number: 1-204-788-1030 CANUTEC : 1-613-996-6666
5. FIRE FIGHTING MEASURES
Flammable Properties : Flash Point: None, since % of water is over 20. Autoignition Temperature: Autoignition temperature for 100% ethylene glycol is 398C (748F).
Flammability Limits : % of vapor concentration at which product can ignite in presence of spark. Lower Flammability Limit: Not determined Upper Flammability Limit: Not determined
Flammability limits are not determined on this product because the solution consists of 50% water. If and when the water evaporates and 100% glycol is left, the upper and lower flammability limits would be 3.2% and 15.3% (the same as concentrated Ethylene glycol).
HAZARDOUS PRODUCTS OF COMBUSTION
: Hazardous combustion products may include and are not limited to carbon monoxide, carbon dioxide and trace amounts of aldehydes and organic acids. When available oxygen is limited, as in a fire or when heated to very high temperatures by a hot wire or plate, carbon monoxide and other hazardous compounds such as aldehydes might be generated.
EXTINGUISH MEDIA : Water fog or fine spray. Alcohol resistant foams (ATC type) are preferred if available. General purpose synthetic foams (including AFFF) or protein foams may function, but much less effectively. Carbon dioxide. Dry chemical. Do not use direct water stream. May spread fire.
FIRE FIGHTING INSTRUCTIONS : No fire and explosion hazards expected under normal storage and handling conditions (i.e. ambient temperatures). However, ethylene glycol or solutions of ethylene glycol and water can form flammable vapors with air if heated sufficiently. Keep people away. Isolate fire area and deny unnecessary entry.
PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS
: Wear positive-pressure, self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire-fighting helmet, coat, pants, boots and gloves).
6. ACCIDENTAL RELEASE MEASURES
PROTECT PEOPLE : Material is moderately toxic when ingested. Take adequate precautions to keep people, especially children away from spill site. PVC-coated rubber gloves and monogoggles or face shield can be used during cleanup of spill site. Product on surfaces can cause slippery conditions. Practice reasonable care and cleanliness. Avoid breathing spray mists if generated. Keep out of reach of children. Product may become a solid at temperatures below -18oC (0oF). Do not store near food, foodstuffs, drugs or potable water supplies.
PROTECT ENVIRONMENT : Do not dump used product or diluted material into sewers, on the ground, or into any body of water. .
CLEANUP : Small spills: Soak up with absorbent material. Large spills: Dike and pump into suitable containers for disposal. Ensure compliance with all applicable statues that require notification of appropriate government officials
NEMCO RESOURCES LTD. Page 5 of 13 SR-1 Antifreeze & Coolant Pure
Date of issue: October, 2013. www.NEMCO.ca Emergency Number: 1-204-788-1030 CANUTEC : 1-613-996-6666
7. HANDLING AND STORAGE HANDLING : Put on appropriate personal protective equipment (see section 8). Eating,
drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.
STORAGE : Keep container closed when not in use. Store away from heat or open flame. Product on surfaces can cause slippery conditions. Practice reasonable care and cleanliness. Avoid breathing spray mists if generated. Keep out of reach of children. Product may become a solid at temperatures below -37oC (-34oF). Do not store near food, foodstuffs, drugs or potable water supplies.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS : Use general or local exhaust ventilation to meet TLV requirements.
RESPIRATORY PROTECTION : Respiratory protection is required if airborne concentration exceeds TLV. At any detectable concentration any self-contained breathing apparatus with a full face piece and operated in a pressure-demand or other positive pressure mode or any supplied-air respirator with a full face piece and operated in a pressure-demand or other positive pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive pressure mode..
EYE PROTECTION : Safety goggles and face shield. Emergency eyewash should be available. Contact lenses should not be worn when working with this chemical.
SKIN PROTECTION : Protective gloves recommended when prolonged skin contact cannot be avoided. Polyethylene; Neoprene; Nitrile; Polyvinyl alcohol; Natural Rubber, Butyl Rubber. Safety shower should be available.
HAND PROTECTION : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. >8 hours (breakthrough time): nitrile rubber
EXPOSURE LIMITS Component Exposure Limits Skin Form Ethylene glycol 100 mg/m3 CEILING ACGIH Aerosol Ethylene glycol 125 mg/m3 CEILING OSHA-vacated 50 ppm CEILING OSHA – vacated 100 mg/m3 CEILING UCC Aerosol and Vapor Diethylene glycol 50 ppm TWA8 AIHA WEEL Aerosol and Vapor Diethylene glycol 10 mg/m3 TWA8 AIHA WEEL Aerosol In the Exposure Limits Chart above, if there is no specific qualifier (i.e., Aerosol) listed in the Form Column for a particular limit, the listed limit includes all airborne forms of the substance that can be inhaled. A “blank” in the Skin column indicates that exposure by the cutaneous (skin) route is not a potential significant contributor to overall exposure.
NEMCO RESOURCES LTD. Page 6 of 13 SR-1 Antifreeze & Coolant Pure
Date of issue: October, 2013. www.NEMCO.ca Emergency Number: 1-204-788-1030 CANUTEC : 1-613-996-6666
9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE : Clear viscous liquid
ODOR THRESHOLD-ppm : Odorless.
pH : 7.5-11
BOILING POINT C (F) : 107°C (226°F)
FREEDZING POINT C (F) : -37°C (-34°F)
FLASH POINT C (F) : Not Established
FLAMMABILITY : Not Established
WATER SOLUBILITY : Complete Soluble in water
VOC CONTENT : Not Established
VAPOR PRESSURE -mmHg 20 C
: <0.1
VAPOR DENSITY: : Not Established
EVAPORATION RATE : Nil
FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING EPRESENTATIVE
10. STABILITY AND REACTIVITY STABILITY (THERMAL, LIGHT, ETC.)
: Stable
CONDITION OF INSTABILITY : Keep away from flame
INCOMPATIBILITY (MATERIALS TO AVOID)
: Strong acid or oxidizing agents
HAZARDOUS DECOMPOSITION PRODUCTS
: Incomplete combustion may produce CO gas.
HAZARDOUS POLYMERIZATION
: Will not occur
NEMCO RESOURCES LTD. Page 7 of 13 SR-1 Antifreeze & Coolant Pure
Date of issue: October, 2013. www.NEMCO.ca Emergency Number: 1-204-788-1030 CANUTEC : 1-613-996-6666
11. TOXICOLOGICAL DATA Skin: The dermal LD50 has not been determined. Ingestion: The lethal dose in humans is estimated to be 100 ml (3 ozs.). The oral LD50 for rats is in the 6000-13,000-mg/kg range. Hydrated Inorganic Acid Sodium Salt: The lowest dose of a similar compound reported to produce death in humans was estimated to be 709 mg/kg body weight for a person weighing 150 pounds, this would be equivalent to swallowing about one-tenth (.1) of a pound of the dry material in a short period of time. Acute oral LD50s for a similar compound = 2,650 mg/kg (rats) 2,000 mg/kg (mice) Mutagenicity (The Effects on Genetic Material): In vitro mutagenicity studies were negative. Animal mutagenicity studies were negative. Significant Data with Possible Relevance to Humans: Ethylene glycol has been shown to produce dose-related teratogenic effects in rats and mice when given by gavage or in drinking water at high concentrations or doses. The no-effect doses for developmental toxicity for ethylene glycol given by gavage over the period of organogenesis has been shown to be 150 mg/kg/day for the mouse and 500 mg/kg/day for the rat. Also, in a preliminary study to asses the effects of exposure of pregnant rats and made to aerosis at concentrations of 150, 1000 and 25000 mg/m3 for 6 hours a day throughout the period of organogenesis, teratogenic effects were produced at the highest concentration, but only in mice. The conditions of these latter experiments did not allow a conclusion as to whether the developmental toxicity was mediated by inhalation of aerosol percutaneous absorption of ethylene glycol from contaminated skin, or swallowing ethylene glycol as a result of grooming the wetted coat. In a further study, comparing effects from high aerosol concentration by whole-body or nose-only exposure, it was shown that nose-only exposure resulted in maternal toxicity (1000 and 25000 mg/m3) and developmental toxicity with minimal evidence of teratogenicity (2500 mg/m3). The no-effects concentration (based on maternal toxicity) was 500 mg/m3. In a further study in mice, no teratogenic effects could be produced when ethylene glycol was applied to skin of pregnant mice over the period of organogenesis. The above observations suggest that ethylene glycol is to be regarded as an animal teratogen. There is currently no available information to suggest that ethylene glycol has caused birth defects in humans. Cutaneous application of ethylene glycol is ineffective in producing developmental toxicity. Exposure to high aerosol concentrations is only minimally effective in producing developmental toxicity. The major route for producing developmental toxicity is perorally. Two chronic feeding studies, using rats and mice, have not produced any evidence that ethylene glycol causes dose-related increases in tumor incidence or a different pattern of tumors compared with untreated controls. The absence of carcinogenic potential for ethylene glycol has been supported by numerous in vitro genotoxicity studies showing that it does not produce mutagenic or clastogenic effects. A chronic dietary feeding study of diethylene glycol with rats showed mild kidney injury at 1%, while concentrations of 2% and 4% caused more marked kidney injury. In addition, at 2% and 4% of diethylene glycol in the diet, some rats developed benign papillary tumors in the urinary bladder. These have been attributed to the presence of urinary bladder calcium oxalate stones. No evidence for carcinogenicity was found with a chronic skin-painting study with diethylene glycol in mice. The absence of a direct chemical carcinogenic effect addords with the results in vitro genotoxicity studies that show that it does not produce mutagenic or clastogenic effects. A feeding study employing up to 5.0% diethylene glycol in the diet failed to produce any teratogenic effects. In a mouse continuous breeding study with large doses of diethylene glycol in drinking water, there was evidence for reproductive toxicity at 3.5% (equivalent to 6.1 g/kg/day) as reduced number of litter, live pups per litter and live pup weight. No such effects were seen at 1.75% (approximately 3.05 g/kg/day). The relevance of these very high dosages to human health is uncertain. Pregnant rats receiving undiluted diethylene glycol by gavage over the period of organogenesis had toxic effects at 4.0 and 8.0 ml/kg/day as mortality, decreased body weight, decreased food consumption increased water consumption and increased liver and kidney weights. Fetotoxicity was seen only at these maternally toxic dosages. Decreased fetal body weight occurred at 8.0 ml/kg/day, and increased skeletal variants at 4.0 and 8.0 ml/kg/day. No embryotixic or teratogenic effects were seen. Neither maternal toxicity nor fetotoxicity occurred at 1.0 ml/kg/day. In a study with mice also receiving undiluted diethylene glycol over the period of organogenesis, maternal toxicity occurred at 2.5 and 10.0 ml/kg/day, but not at 0.5 ml/kg/day. Definitive developmental toxicity was not seen in this species. ACUTE TOXICITY Peroral: The lethal dose in humans is estimated to be 3 oz. or 100 ml. Rat: LD50 (6000 – 13000) mg/kg
NEMCO RESOURCES LTD. Page 8 of 13 SR-1 Antifreeze & Coolant Pure
Date of issue: October, 2013. www.NEMCO.ca Emergency Number: 1-204-788-1030 CANUTEC : 1-613-996-6666
Percutaneous: Rabbit: LD50 = >22270 mg/kg; 24 h occluded Inhalation: Rat: 8-hour exposure, substantially saturated vapor studies, dynamic generation method Mortality: 0/6 Inhalation: Mist/vapor study, rat, at 170C, 8-hour exposure = 2.2 mg/l Mortality: 0/6 Inhalation: Rat: 8-hour exposure, fog = 10000 ppm; 65 - 70C Mortality: 0/6 IRRITATION Skin: Rabbit: 24-hour occluded contact, 0.5 ml Results: Minor erythema and edema Skin: Human: Primary irritation patch test, 48-hour occluded, 0.2 ml Results: Evidence of irritation Eye: Rabbit: 0.1 ml Results: Minor transient iritis, conjunctival irritation with discharge REPEATED EXPOSURE In a 7-day dietary study with rats, a significant increase in kidney weights in females was observed at 5.0 gm/kg. The NOEL was 2.5 gm/kg. In a 24-month dietary study with rats, increased mortality in males was observed at the highest dose, 1.0 gm/kg/day. There were multiple signs: mineralization of several organs, including the cardiac vessels, cardiac muscle, vas deferens, stomach and pulmonary vessels; cellular hyperplasia of the parathyroids, hemosiderosis of the spleen, myocardial fibrosis, portal fibrosis of the liver, bile duct hyperplasia and hydronephrosis and oxylate nephrosis of the kidneys. Ethylene glycol was not oncogenic. In a 90-day dietary study with dogs, repeated exposures to 2.5 gm/kg resulted in acute renal failure and deaths. The NOAEL was 1.0 gm/kg. SENSITIZATION (ANIMAL AND HUMAN STUDIES) Repeated skin contact with ethylene glycol may, in a very small proportion of cases, cause sensitization with the development of allergic contact dermatitis. The incidence is significantly less than 1% with the undiluted material. REPRODUCTIVE TOXICITY A three-generation study indicated that ethylene glycol did not affect reproductive parameters at dietary concentrations up to 1.0 gm/kg/day in any generation. CHRONIC TOXICITY AND CARCINOGENICITY Two chronic feeding studies, using rats and mice, have not produced any evidence that ethylene glycol causes dose-related increases in
NEMCO RESOURCES LTD. Page 9 of 13 SR-1 Antifreeze & Coolant Pure
Date of issue: October, 2013. www.NEMCO.ca Emergency Number: 1-204-788-1030 CANUTEC : 1-613-996-6666
tumor incidence or a different pattern of tumors compared with untreated controls. The absence of a carcinogenic potential for ethylene glycol has been supported by numerous in vitro genotoxicity studies showing that it does not produce mutagenic or clastogenic effects. GENETIC TOXICOLOGY In Vitro: Ethylene glycol was devoid of genotoxic activity in an Ames test, forward gene mutation and sister chromatid exchange (SCE) studies in Chinese Hamster Ovary (CHO) cells and an in vitro cytogenetics study. In Vivo: Ethylene glycol by three different routes (intravenous, peroral and percutaneous) demonstrates apparent first-order pharmacokinetic behavior for the disposition in and the elimination from the plasma. Dose-dependent changes occur for the elimination of metabolites in the urine and as 14CO2 after single doses for the intravenous and peroral, but not the percutaneous route. The hypothesis from literature sources exists that developmental toxicity is caused by a metabolite of ethylene glycol, called glycolic acid, and not parent ethylene glycol. Under most conditions of ethylene glycol exposure, the glycolic acid metabolite is present in the blood in very low levels. However, it can become the major metabolite following large doses of ethylene glycol due to saturation of glycolic acid oxidation and/or elimination. When levels of this acidic metabolite exceed the capacity of maternal blood buffers to neutralize it, a maternal metabolic acidosis ensues, which has been hypothesized to be the true agent responsible for ethylene glycol induced developmental toxicity. Research suggests that ethylene glycol developmental toxicity is due to a dose-rate dependent toxicokinetic shift leading to glycolate accumulation and metabolic acidosis. ADDITIONAL STUDIES Ethylene glycol has been shown to produce dose-related teratogenic effects in rats and mice when given by gavage or in drinking water at high concentrations or doses. The no-effect doses for developmental toxicity for ethylene glycol given by gavage over the period of organogenesis has been shown to be 150 mg/kg/day for the mouse and 500 mg/kg/day for the rat. Also, in a preliminary study to assess the effects of exposure of pregnant rats and mice to aerosols at concentrations of 150, 1000 and 2500 mg/m3 for 6 hours a day throughout the period of organogenesis, teratogenic effects were produced at the highest concentration, but only in mice. The conditions of these latter experiments did not allow a conclusion as to whether the developmental toxicity was mediated by inhalation of aerosol, percutaneous absorption of ethylene glycol from contaminated skin, or swallowing of ethylene glycol as a result of grooming the wetted coat. In a further study, comparing effects from high aerosol concentration by whole-body or nose-only exposure, it was shown that nose-only exposure resulted in maternal toxicity (1000 and 2500 mg/m3) and developmental toxicity with minimal evidence of teratogenicity (2500 mg/m3). The no-effects concentration (based on maternal toxicity) was 500 mg/m3. In a further study in mice, no teratogenic effects could be produced when ethylene glycol was applied to the skin of pregnant mice over the period of organogenesis. The above observations suggest that ethylene glycol is to be regarded as an animal teratogen. There is currently no available information to suggest that ethylene glycol has caused birth defects in humans. Cutaneous application of ethylene glycol is ineffective in producing developmental toxicity. Exposure to high aerosol concentrations is only minimally effective in producing developmental toxicity.
NEMCO RESOURCES LTD. Page 10 of 13 SR-1 Antifreeze & Coolant Pure
Date of issue: October, 2013. www.NEMCO.ca Emergency Number: 1-204-788-1030 CANUTEC : 1-613-996-6666
12. ECOLOGICAL INFORMATION (Concentrated Ethylene Glycol)
13. DISPOSAL CONSIDERATIONS DO NOT discharge to sewer. Wear appropriate personal protection. Take up with sand, vermiculite, or similar inert material. Dispose in accordance with federal, state and local regulations.
NEMCO RESOURCES LTD. Page 11 of 13 SR-1 Antifreeze & Coolant Pure
Date of issue: October, 2013. www.NEMCO.ca Emergency Number: 1-204-788-1030 CANUTEC : 1-613-996-6666
14. TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION Non-Bulk Not regulated by the US D.O.T. (in quantities under 5,000 lbs in any one inner package) Bulk Proper Shipping Name: Environmentally Hazardous Substance, LIQUID N.O.S. (ETHYLENE GLYCOL) Technical Name: ETHYLENE GLYCOL ID Number: UN 3082 Hazard Class: 9 Packing Group: PG III Reportable Quantity: 5,000 lb. IATA Non-Bulk Not Regulated by IATA IMDG Non-Bulk Not regulated by IMDG (in quantities under 5,000 lbs in any one inner package)
15. REGULATORY INFORMATION
THIS PRODUCT CONTAINS COMPONENT(S) CITED ON THE FOLLOWING REGULATIONS.
Chemical Name Cas Number Ethylene Glycol 107-21-1
United States - TSCA Inventory: Listed Water Standards: No data available Atmospheric Standards: Clean Air Act (1990) - List of Hazardous Air Contaminants: listed CERCLA: Reportable Quantity (RQ): 5,000 pounds (532 gallons) OSHA Hazard Communication Standard: This product is a “hazardous chemical” as defined by the OSHA
Hazard Communication Standard, 29 CFR 1910.1200.
NEMCO RESOURCES LTD. Page 12 of 13 SR-1 Antifreeze & Coolant Pure
Date of issue: October, 2013. www.NEMCO.ca Emergency Number: 1-204-788-1030 CANUTEC : 1-613-996-6666
15. REGULATORY INFORMATION SARA Title III: Section 311/312 - Categories: Acute hazard; chronic hazard
Section 312 - Inventory Reporting: Ethylene glycol is subject to Tier I and/or Tier II annual inventory reporting. Section 313 - Emission Reporting: Ethylene glycol is subject to Form R reporting requirements. Section 302 - Extremely Hazardous Substances: Ethylene glycol is not listed.
State Right-To-Know:
California - Exposure Limits - Ceilings: vapor-50 ppm ceiling; 125 mg/m3 ceiling Director's List of Hazardous Substances: listed Florida - Hazardous Substances List: listed Massachusetts - Right-to-Know List: listed Minnesota - Haz. Subs. List: listed (particulate and vapor) New Jersey - Right-to-Know List (Total): Present greater than 1.0% Pennsylvania Right-to-Know List: environmental hazard
Canadian Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required. WHMIS Information: D2A - material has potential toxic effects. Refer elsewhere in the MSDS for specific warnings and safe handling information. Refer to the employer's workplace education program. California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986): The normal consumer use of this product does not result in exposure to chemicals known to the state of California to cause Cancer and/or reproductive harm above the significant risk level for carcinogens or the maximum allowable dose levels for reproductive toxins. Warnings are not required for consumer packaging. However, industrial or other occupational use of this product at higher frequency and using larger quantities of this product may result in exposures exceeding these levels and are labeled accordingly. California SCAQMD Rule 443.1 (South Coast Air Quality Management District Rule 443.1, Labeling of Materials Containing Organic Solvents): VOC: Vapor pressure 0.06 mmHg at 20°C 1113.38 g/l
NEMCO RESOURCES LTD. Page 13 of 13 SR-1 Antifreeze & Coolant Pure
Date of issue: October, 2013. www.NEMCO.ca Emergency Number: 1-204-788-1030 CANUTEC : 1-613-996-6666
16. OTHER INFORMATION ********************************************************************** Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control. All risks of use of the product are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND AND NATURE, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a recommendation for uses, which infringe valid patents, or as extending license under valid patents. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted. Nemco assumes no responsibility for accuracy of information unless the document is the most current available from an official Nemco distribution system. Nemco neither represents nor warrants that the format, content or product formulas contained in this document comply with the laws of any country except Canada. ********************************************************************** FOR FURTHER INFORMATION, CONTACT: Date of printing : October, 2013
Date of issue : October, 2013
Supplier : Nemco Resources Ltd
Address : 25 Midland Street Winnipeg, Manitoba R3E 3J6 CANADA
Telephone : 204-788-1030
Fax : 204-788-1593
NeoChem Div. of ENERCON WATER TREATMENT LTD. 3606 – 6 Avenue North, Lethbridge, AB T1H 5C4
Phone: (403) 328-9730 * Toll Free: 1-800-248-1195 * Fax: (403) 327-4375 Website: www.neochem.ca * Email: ewt@enerconwt.com
EMERGENCY PHONE NUMBER (CANUTEC): (613) 906-6666
ChemTronic (Aerosol)
Section 01: Identification Product Name: ChemTronic Recommended Use: Demoisturing Lubricant (See Technical Data Sheet) Section 02: Hazards Identification/Emergency Overview Physical State: Aerosol WHMIS Classification: A, D1 Colour: Brown Odour: Solvent Hazard Statement: Do not puncture or incinerate container, even when empty.
Section 03: Composition/Information on Ingredients Ingredient % Conc. C.A.S. # Ingredient % Conc. C.A.S. # Methylene Chloride 30 - 60 75-09-2 Perchloroethylene (Tetrachloroethylene) 30 - 60 127-18-4 Diethylene Glycol Monobutyl Ether 1 - 5 112-34-5 Sodium Sulfonate 3 - 7 Not Available Carbon Dioxide 1 – 5 124-38-9 Section 04: First Aid Measures Skin: Flush skin thoroughly for at least 15 minutes. Remove contaminated clothing if necessary. Seek medical attention if irritation occurs or persists. Eyes: Flush eyes with running water for at least 15 minutes. Forcibly hold eyelids apart to ensure complete irrigation of eye tissue. Seek medical attention immediately. Inhalation: Assist difficult breathing by removing casualty to fresh air. Administer oxygen to casualty experiencing breathing difficulty. Perform artificial respiration if breathing stops. Seek medical attention if irritation or breathing difficulties persist. Ingestion: If swallowed, DO NOT induce vomiting. Never give anything by mouth to an unconscious person. Seek medical attention immediately. Section 05: Fire Fighting Measures Flammable: Non-Flammable. If yes, under what conditions: Not Applicable Means of extinction: Standard procedure for chemical fires. Cool containers / tanks with water spray. Hazardous combustion products: Possible phosgene over 250° C, chlorine gas, hydrochloric acid. Hydrocarbon fumes and smoke. Carbon monoxide (where combustion is incomplete). Special protective equipment and precautions for firefighters: Standard equipment for chemical fires. Section 06: Accidental Release Measures Personal precautions, protective equipment and emergency procedures: See Section 8. Environment precautions: Avoid entry of product into the sewage system or water streams. Methods and materials for containment and disposal: Do not puncture or incinerate containers, even when empty. Dispose of in accordance with local, provincial and federal regulations. Section 07: Handling and Storage Precautions for safe handling: Open and handle container with care, ensure the spray nozzle will direct the spray toward the intended target rather than the user. Do not eat, drink or smoke in the presence of open container. Follow routine safe-handling procedures. Storage requirements: When not in use, keep container tightly closed in a dry, cool, well-ventilated area. Avoid contact with incompatible materials listed in Section 10. Product should be stored away from food, drink and ignition sources. Empty containers can retain product residue and may be hazardous. Section 08: Exposure Controls/Personal Protection Note: These recommendations provide general guidelines for handling this product. Personal protective equipment should be selected according to individual application of the material, safe handling practices to consider include: exposure potential, chemical concentration and ventilation. Methylene Chloride vapours can readily accumulate in poorly ventilated areas and can cause unconsciousness. It is ultimately the responsibility of the employer to follow regulatory guidelines established by local, provincial and federal authorities. Recommended Personal Protective Equipment: Gloves: PVC or Nitrile Rubber Respiratory: NIOSH approved respirator (when fumes are present) Eye: Chemical goggles or face shield Footwear: Chemical resistant footwear
Clothing: Cover exposed skin Engineering controls: Local mechanical exhaust ventilation Other: Eyewash station and safety shower are proximal to workstation
Section 09: Physical and Chemical Properties Physical State: Aerosol Appearance: Brown Liquid Odour: Solvent Odour threshold: Not Available pH: Not Applicable Melting point / Freezing point (°C): Not Available Initial boiling point and boiling range (°C): >260° C Flash point (°C): Not Available Evaporation rate: >1 Flammability: Non-Flammable
Upper / Lower flammability or explosive limits: Not Available Vapour pressure (psig): 70 – 80 @ 20° C Vapour density (Air=1): >1 Relative density: Not Available Solubility in Water: Negligible Partition coefficient: n-octanol/water: Not Available Auto-ignition temperature (°C): 556° C Decomposition temperature: Not Available Specific Gravity (Liquid): 0.84 – 0.88
ChemTronic (Aerosol) Section 10: Stability and Reactivity Chemical stability under normal conditions: Stable. If no, under what conditions: Avoid moisture and elevated temperatures. Possibility of hazardous reactions: Normally stable. Incompatible materials: Avoid contact with strong oxidizing agents. Reactivity and under what conditions: Normally stable. Hazardous decomposition products: Possible phosgene over 250° C, chlorine gas, hydrochloric acid. Hydrocarbon fumes and smoke. Carbon monoxide (where combustion is incomplete). Section 11: Toxicological Information Hazardous Ingredients (Section 3): LD50, (Oral) LD50, (Dermal) LC50, (Inhalation) Methylene Chloride 2100 mg/kg (Rat) Not Available 88000 mg/m3 (1/2h) (Rat) Perchloroethylene (Tetrachloroethylene) 2629 mg/kg (Rat) Not Available 5200 ppm (4h) (Mouse) Diethylene Glycol Monobutyl Ether 6560 mg/kg (Rat) Not Available Not Available Sodium Sulfonate Not Available Not Available Not Available Carbon Dioxide Not Applicable Not Available Not Available Effects of acute exposure Skin Contact: Irritant. Skin Absorption: Not Applicable Eye: Irritant. Inhalation: Irritation (where mist or fumes are accumulated). Propellant is simple asphyxiant. Ingestion: Moderately Toxic. Effects of chronic exposure Chronic Exposure Overview: Chronic effects include allergic reactions (headaches, difficulty breathing, rapid heart rate and anaphylaxis) in susceptible individuals. Prolonged and repeated exposure can cause pneumonitis. Solvents may cause defatting dermatitis. Methylene Chloride has moderate toxicity if ingested. If aspirated, Methylene Chloride may be rapidly absorbed through the lungs and result in injury to other body systems. Skin Contact: Irritant. Methylene Chloride overexposure may have central nervous system effects. Solvents may cause defatting dermatitis. Skin Absorption: Not Applicable Eye: Irritation. Inhalation: Methylene Chloride overexposure may lead to central nervous system depression and cardiac sensitization and may cause headache, vomiting, nausea and weakness. Ingestion: Irritation. Methylene Chloride has moderate toxicity if ingested. Teratogenicity: Not Available Reproductive toxicity: Not Available Mutagenicity: Not Available Carcinogenicity: Methylene Chloride and Perchloroethylene have been listed as potential carcinogens by the International Agency for Research on Cancer (IARC). Section 12: Ecological Consideration Ecotoxicity (aquatic and terrestrial): Not Available Persistence and degradability: Not Available Bioaccummulative potential: Not Available
Mobility in soil: Not Available Other adverse effects: Not Available
Section 13: Disposal Considerations Waste Disposal: Dispose of this material and its container in accordance with local, provincial and federal regulations. Section 14: Transport Information UN Number: Not Applicable Shipping Name: Consumer Commodity
Packing Group: Not Applicable Special Shipping Information: Not Applicable
Section 15: Regulatory Information This safety data sheet has been prepared in accordance with the WHMIS standards. All materials used appear on the Canadian DSL. Materials not listed are either non-hazardous or in concentrations of less than 0.1%. Section 16: Other Information Responsibility Statement The information contained herein is provided as a guide to the handling of this product. It is our belief that the information provided in this safety data sheet is reliable. This product should not be used by any person who is not familiar with the contents of this safety data sheet, the recommendation found on the label or technical data sheet. No warranty of any kind is given or implied and Enercon Water Treatment Ltd. assumes no responsibility for damages, losses, injuries or events resulting from damages incurred from its use. The information on this material safety data sheet relates only to the specific material designated herein and does not relate to material use in combination with any other material or in any process. Prepared By: Technical Services Preparation Date: March 1, 2013 Expiry Date: March 1, 2016
Page: 1 of 5
MATERIAL SAFETY DATA SHEET
MSDS Number: 1106C
Section 1 PRODUCT AND COMPANY IDENTIFICATION
Trade Name: OATEY CANADIAN ALL PURPOSE CEMENT
Product Nos.: Milky - 31575, 31576, 31577, 31578, 31579
Product Use: Cement for PVC, CPVC and ABS pipe
Formula: PVC and CPVC Resin in Solvent Solution
Synonyms: None
Firm Name &
Address:
Oatey Company 4700 West 160th Street, Cleveland, Ohio 44135
www.oatey.com
Firm Phone No: (216) 267-7100
Emergency Phone
Nos.:
For Emergency First Aid call 1-877-740-5015. For chemical transportation
emergencies ONLY, call Chemtrec at 1-800-424-9300. Outside the U.S. 1-
703-527-3887.
Prepared by: Technical Department
Preparation Date: 09/11/2012
Section 2 HAZARDS IDENTIFICATION
Emergency Overview:
Milky
liquid with an ether-like odor. Extremely flammable liquid and vapor. Vapors may cause flash
fire. May cause eye and skin irritation. Inhalation of vapors or mist may cause respiratory
irritation and central nervous system effects. Swallowing may cause irritation, nausea,
vomiting, diarrhea and kidney or liver disorders. Aspiration hazard. May be fatal if
swallowed. Symptoms may be delayed.
Section 3 COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENTS: %wt/wt : CAS NUMBER: ACGIH TLV TWA: OSHA PEL TWA OTHER:
Tetrahydrofuran 30 - 45% 109-99-9 50 ppm(skin) 200 ppm 25 ppm (Mfg)
100 ppm STEL
Methyl Ethyl Ketone 7 - 13% 78-93-3 200 ppm 200 ppm None
300 ppm STEL
Acetone 10 – 20% 67-64-1 500 ppm 1000 ppm None
750 ppm STEL
PVC Resin 7 – 13% 9002-86-2 10 mg/m3 15 mg/m3 None
(Non-hazardous)
CPVC Resin 3 – 7% 68648-82-8 10 mg/m3 None None
(Non-hazardous) Established
Cyclohexanone 10 – 20% 108-94-1 20 ppm(skin) 50 ppm None
50 ppm STEL
Amorphous Fumed Silica 1 - 5% 112945-52-5 10 mg/m3 None None
(Non-hazardous) Established a
OSHA Hazard Classification: Flammable, irritant, organ effects
Section 4 FIRST AID MEASURES
Skin: Remove contaminated clothing immediately. Wash all exposed areas with soap and
water. Get medical attention if irritation develops. Remove dried cement with
Oatey Plumber's Hand Cleaner or baby oil.
Eyes: If material gets into eyes or if fumes cause irritation, immediately flush eyes
with plenty of water until chemical is removed. If irritation persists, get
Page: 2 of 5
medical attention immediately.
Inhalation: If symptoms of exposure develop, remove to fresh air. If breathing becomes
difficult, administer oxygen. Administer artificial respiration if breathing
has stopped. Seek immediate medical attention.
Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything by mouth to
a person who is unconscious or drowsy. Get immediate medical attention by
calling a Poison Control Center, or hospital emergency room. If medical advice
cannot be obtained, then take the person and product to the nearest medical
emergency treatment center or hospital.
Section 5 FIRE FIGHTING MEASURES
Flashpoint /
Method:
14 - 23 Degrees F. (-10 to -5 Degrees C) / CCCFP
Flammability: LEL = 1.8 % Volume, UEL = 11.8 % Volume
Extinguishing
Media:
Use dry chemical, CO2, or foam to extinguish fire. Cool fire exposed container
with water. Water may be ineffective as an extinguishing agent.
Special Fire
Fighting
Procedure:
Firefighters should wear positive pressure self-contained breathing apparatus
and full protective clothing for fires in areas where chemicals are used or
stored
Unusual Fire
And Explosion
Hazards:
Extremely flammable liquid. Keep away from heat and all sources of ignition
including sparks, flames, lighted cigarettes and pilot lights. Containers may
rupture or explode in the heat of a fire. Vapors are heavier than air and may
travel to a remote ignition source and flash back. This product contains
tetrahydrofuran that may form explosive organic peroxide when exposed to air or
light or with age.
Hazardous
Decomposition
Products:
Combustion will produce toxic and irritating vapors including carbon monoxide,
carbon dioxide and hydrogen chloride.
Section 6 ACCIDENTAL RELEASE MEASURES
Spill or Leak
Procedures:
Remove all sources of ignition and ventilate area. Stop leak if it can be done
without risk. Personnel cleaning up the spill should wear appropriate personal
protective equipment, including respirators if vapor concentrations are high.
Soak up spill with an inert absorbent such as sand, earth or other non-
combusting material. Put absorbent material in covered, labeled metal
containers. Prevent liquid from entering watercourses, sewers and natural
waterways. Report releases to authorities as required. See Section 13 for
disposal information.
Section 7 HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists.
Use with adequate ventilation (equivalent to outdoors). Wash thoroughly after
handling. Do not eat, drink or smoke in the work area. Keep product away from
heat, sparks, flames and all other sources of ignition. No smoking in storage
or use areas. Keep containers closed when not in use.
Storage: Store in a cool, dry, well-ventilated area away from incompatible materials.
Keep containers closed when not in use.
Other: "Empty" containers retain product residue and can be hazardous. Follow all MSDS
precautions in handling empty containers. Do not cut or weld on or near empty
or full containers.
Section 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation: Open doors & windows. Provide ventilation capable of maintaining emissions at
the point of use below recommended exposure limits. If used in enclosed area,
use exhaust fans. Exhaust fans should be explosion-proof or set up in a way
that flammable concentrations of solvent vapors are not exposed to electrical
fixtures or hot surfaces.
Respiratory
Protection:
For operations where the exposure limit may be exceeded, a NIOSH approved
organic vapor respirator or supplied air respirator is recommended. Equipment
selection depends on contaminant type and concentration, select in accordance
with 29 CFR 1910.134 and good industrial hygiene practice. For firefighting,
use self-contained breathing apparatus.
Skin Rubber gloves are suitable for normal use of the product. For long exposures
Page: 3 of 5
Protection: chemical resistant gloves may be required such as 4H(tm) or Silver Shield(tm)
to avoid prolonged skin contact.
Eye
Protection:
Safety glasses with side shields or safety goggles.
Section 9 PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point: 151 Degrees F / 66 Degrees C
Melting Point: Not applicable
Vapor Pressure: 145 mmHg @ 20 Degrees C
Vapor Density: (Air = 1) 2.5
Volatile Components: 80-84%
Solubility In Water: Negligible
pH: Not applicable
Specific Gravity: 0.94 +/- 0.02 @ 20 Degrees C
Evaporation Rate: (BUAC = 1) = 5.5 - 8.0
Appearance: Milky Liquid
Odor: Ether-Like
Will Dissolve In: Tetrahydrofuran
Material Is: Liquid
Section 10 STABILITY AND REACTIVITY
Stability: Stable.
Conditions To
Avoid:
Avoid heat, sparks, flames and other sources of ignition.
Hazardous
Decomposition
Products:
Combustion will produce toxic and irritating vapors including carbon
monoxide, carbon dioxide and hydrogen chloride.
Incompatibility/
Materials To
Avoid:
Oxidizing agents, alkalis, amines, ammonia, acids, chlorine compounds,
chlorinated inorganics (potassium, calcium and sodium hypochlorite) and
hydrogen peroxides. May attack plastic, resins and rubber.
Hazardous
Polymerization:
Will not occur.
Section 11 TOXICOLOGICAL INFORMATION
Inhalation: Vapors or mists may cause mucous membrane and respiratory irritation,
coughing, headache, dizziness, dullness, nausea, shortness of breath and
vomiting. High concentrations may cause central nervous system depression,
narcosis and unconsciousness. May cause kidney, liver and lung damage.
Skin: May cause irritation with redness, itching and pain. Methyl ethyl ketone and
cyclohexanone may be absorbed through the skin causing effects similar to
those listed under inhalation.
Eye: Vapors may cause irritation. Direct contact may cause irritation with
redness, stinging and tearing of the eyes. May cause eye damage.
Ingestion: Swallowing may cause abdominal pain, nausea, vomiting and diarrhea.
Aspiration during swallowing or vomiting can cause chemical pneumonia and
lung damage. May cause kidney and liver damage.
Chronic
Toxicity:
Prolonged or repeated overexposure cause dermatitis and damage to the
kidney, liver, lungs and central nervous system.
Toxicity Data: Acetone: Oral rat LD50: 5,800 mg/kg
Inhalation rat LC50: 50,100 mg/m3/8 hours
Cyclohexanone: Oral rat LD50: 1,620 mg/kg
Inhalation rat LC50: 8,000 ppm/4 hours
Skin rabbit LD50: 1 mL/kg
Tetrahydrofuran: Oral rat LD50: 1,650 mg/kg
Inhalation rat LC50: 21,000 ppm/3 hours
Methyl Ethyl Ketone: Oral rat LD50: 2,737 mg/kg
Inhalation rat LC50: 23,500 mg/m3/8 hours
Skin rabbit LD50: 6,480 mg/kg
Sensitization: None of the components are known to cause sensitization.
Carcinogenicity: None of the components are listed as a carcinogen or suspect carcinogen by
Page: 4 of 5
NTP, IARC or OSHA. The National Toxicology Program has reported that
exposure of mice and rats to tetrahydrofuran (THF) vapor levels up to 1800
ppm 6 hr/day, 5 days/week for their lifetime caused an increased incidence
of kidney tumors in male rats and liver tumors in female mice. The
significance of these findings for human health is unclear at this time, and
may be related to "species specific" effects. Elevated incidences of tumors
in humans have not been reported for THF. ACGIH has classified
cyclohexanone (CYH) and tetrahydrofuran as “A3,” Confirmed Animal
Carcinogens with Unknown Relevance to Humans.
Mutagenicity: Cyclohexanone has been positive in bacterial and mammalian assays. Acetone,
methyl ethyl ketone and tetrahydrofuran are generally thought not to be
mutagenic.
Reproductive
Toxicity:
Methyl ethyl ketone and cyclohexanone have been shown to cause embryofetal
toxicity and birth defects in laboratory animals. Acetone and
tetrahydrofuran has been found to cause adverse developmental effects only
when exposure levels cause other toxic effects to the mother.
Medical
Conditions
Aggravated By
Exposure:
Persons with pre-existing skin, lung, kidney or liver disorders may be at
increased risk from exposure to this product.
Section 12 ECOLOGICAL INFORMATION
This product is not expected to be toxic to aquatic organisms.
Cyclohexanone: 96 hour LC50 values for fish is over 100 mg/l.
Tetrahydrofuran: 96 hour LC50 fathead minnow: 2160 mg/L.
Acetone: 96 hour LC50 for fish is greater than 100 mg/L.
Methyl Ethyl Ketone: 96 hour LC50 for fish is greater than 100 mg/L.
VOC
Information:
This product emits VOC’s (volatile organic compounds) in its use. Make sure
that use of this product complies with local VOC emission regulations, where
they exist.
VOC Level: Maximum 510 g/L per SCAQMD Test Method 316A.
Section 13 DISPOSAL CONSIDERATIONS
Waste Disposal: Dispose in accordance with current local, state and federal
regulations.
RCRA Hazardous Waste
Number:
U002, U057, U159, U213
EPA Hazardous Waste
ID Number:
D001, D035, F003, F0005
EPA Hazard Waste
Number:
Ignitable Waste. Toxic Waste (Methyl Ethyl Ketone content)
Section 14 TRANSPORT INFORMATION
DOT Less than 1 Liter (0.3
gal)
Greater than 1 Liter (0.3
gal)
UN/NA Number: None UN1133
Proper Shipping Name: Consumer Commodity Adhesives
Hazard Class: ORM-D 3
Packing Group: None PGII
Hazard Labels: None Flammable Liquid
IMDG
UN Number: UN1133 UN1133
Proper Shipping Name: Adhesives Adhesives
Hazard Class: 3 3
Packing Group: II II
Label: None (Limited Quantities
are expected from
labeling)
Class 3 (Flammable Liquid)
Flashpoint (deg C) -10 to -5 Degrees C -10 to -5 Degrees C
Page: 5 of 5
2008 North American Emercency Response Guidebook Number: 127
Section 15 REGULATORY INFORMATION
Hazard Category for
Section 311/312:
Acute Health, Chronic Health, Flammable
Section 302
Extremely Hazardous
Substances (TPQ):
This product does not contain chemicals regulated under SARA Section 302.
Section 313 Toxic
Chemicals:
This product does not contain chemicals subject to SARA Title III Section
313 Reporting requirements.
CERCLA 103
Reportable
Quantity:
Spills of this product over the RQ (reportable quantity) must be reported
to the National Response Center. The RQ for the product, based on the RQ
for Tetrahydrofuran (45% maximum) of 1,000 lbs, is 2,222 lbs.
Many states have more stringent release reporting requirements. Report
spills required under federal, state and local regulations.
California
Proposition 65:
This product contains trace amounts of chemicals known to the State of
California to cause cancer. Under normal use conditions, exposure to
these chemicals at levels above the State of California “No Significant
Risk Level” (NSRL) are unlikely. The use of proper personal protective
equipment (PPE) and ventilation guidelines noted in Section 8 will
minimize exposure to these chemicals.
TSCA Inventory All of the components of this product are listed on the TSCA inventory.
Canadian WHIMS
Classification:
Class B, Division 2; Class D, Division 2, Subdivision B; Class D,
Division 2, Subdivision A. This product has been classified in accordance
with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all the information required by the CPR.
Section 16 OTHER INFORMATION
NFPA and HMIS:
NFPA Hazard Signal: Health: 2 Flammability: 3 Reactivity: 1 Special: None
HMIS Hazard Signal: Health: 2* Flammability: 3 Reactivity: 1 PPE: G
Disclaimer:
The information herein has been compiled from sources believed to be reliable, up-to-date, and
is accurate to the best of our knowledge. However, we cannot give any guarantees regarding
information from other sources, and expressly do not make warranties, nor assume any liability
for its use.
Template: tmpl-cn-e1
Canadian Workplace Hazardous Materials Information SystemMaterial Safety Data Sheet
I. PRODUCT IDENTIFICATIONProduct Name: PC FAST ORANGE LOTION WITH PUMICE 443 MLItem No: 25117Product Type: Waterless hand cleaner
II. COMPOSITION/INFORMATION ON INGREDIENTSComponent: Weight% LD50/oral/rat LC50/inhalation/rat ACGIH; TLV-TWA
WATER7732-18-5
>75 not available not available
PUMICE1332-09-8
<10 not available not available 10 mg/m3 (inhal); 3 mg/m3
(resp) ACGIH
ETHOXYLATED C11-C16 ALCOHOL127036-24-2
<5 oral rat: >500 mg/kg not available
D-LIMONENE5989-27-5
0.1-1.0 4400 mg/kg not available
III. PHYSICAL DATAPhysical State/Appearance: White lotion with pumice
Odour & Odour Threshold: Orange odour
Specific Gravity: 1.06
Evaporation Rate: <1 (Butyl acetate = 1)
Vapour Pressure: Not determined
Vapour Density: Heavier than air
Freezing Point: Not determined
pH: 6.0-8.0
Octanol/Water Coefficient: Not determined
Boiling Point: 100°C (212°F)
IV. FIRE AND EXPLOSIVE DATARecommended Extinguishing Media: Carbon dioxide, Water, dry chemical
Hazardous Combustion Products: Not applicable
Sensitivity to Static Discharge: Sensitivity to static discharge is not expected.
Conditions of Flammability: None anticipated.
Flash Point/Range: >100°C.
Autoignition Temperature: Not determined
Upper Explosive Limit: Not determined
Lower Explosive Limit: Not determined
V. REACTIVITY DATAConditions Causing Chemical Instability: None
Materials to avoid: None reasonably foreseeable
Conditions of Reactivity: None.
Hazardous Decomposition Products: None anticipated
VI. HAZARDS IDENTIFICATIONPrimary Routes of Exposure: Eye and skin contact, ingestion, inhalation
Existing Conditions Aggravated byExposure:
None known
Toxicity Information: (See Effects of Acute Exposure to Product)
Effects of Acute Exposure: None under normal conditions of use.
Effects of Chronic Exposure: May cause an allergic skin reaction.
Irritancy of Product: Possible eye irritation.
Sensitization to Product: (See Effects of Acute Exposure to Product)Carcinogenicity: (See Effects of Chronic Exposure to Product)
1 of 2
ITW Permatex Canada35 Brownridge Road, Unit 1Halton Hills, ON Canada L7G 0C6Telephone: (800) 924-6994Urgence: 800-255-3924 (ChemTel)
VI. HAZARDS IDENTIFICATIONReproductive Toxicity: (See Effects of Chronic Exposure to Product)Teratogenicity: (See Effects of Chronic Exposure to Product)Mutagenicity: (See Effects of Chronic Exposure to Product)Toxicologically Synergistic Products: None known
WHMIS Hazard Class: Non-controlled
VII. PREVENTATIVE MEASURESPersonal ProtectionEyes: Not required.
Skin: Not required.
Ventilation: Not required under normal use.
Engineering Controls: No special provisions are required under normal conditions.
Spill Procedures: Rinse away with water or wipe up with a towel.
Protection of Man and Environment: Follow Canadian and local regulations for disposal.
Handling Procedures and Equipment:Protect from freezing.
Special Handling Information: Avoid contact with eyes.
VIII. FIRST AID MEASURESIngestion: If swallowed, do not induce vomiting - seek medical advice.
Inhalation: Immediate medical attention is not required.
Skin Contact: Flush with water.
Eye Contact: Flush with water. If eye irritation persists, get medical attention.
IX. SHIPPING INFORMATIONCanadian Transportation of Dangerous Goods
Proper Shipping Name: Not regulated
Hazard Class: None
UN/ID No: None
IATA (Air)Proper Shipping Name: Not regulated
Class or Division: None
UN/ID Number: None
IMDG (Vessel)Proper Shipping Name: Not regulated
Hazard Class: None
UN Number: None
X. PREPARATION INFORMATIONEstimated HMIS Classification: HEALTH 1, FLAMMABILITY 1, PHYSICAL HAZARD 0
(HMIS is a registered trademark of the National Paint and Coatings Association)
Estimated NFPA Rating: HEALTH 1, FLAMMABILITY 1 , REACTIVITY 0
(NFPA is a registered trademark of the National Fire Protection Association)
Prepared By: Denise Boyd, Manager-Environmental, Health & SafetyRevision Date: March 31, 2015
Company: ITW Permatex Canada. 35 Brownridge Rd. Unit 1, Halton Hills, ON L76 0C6Revision Number: 3
Telephone No.: 1-800-924-6994
2 of 2
Canadian Workplace Hazardous Materials Information SystemMaterial Safety Data Sheet
I. PRODUCT IDENTIFICATIONProduct Name: FAST ORANGE PUMICE LOTION 1 GALItem No: 25218Product Type: Waterless hand cleaner
II. COMPOSITION/INFORMATION ON INGREDIENTSComponent Weight% LD50/oral/rat LC50/inhalation/rat ACGIH; TLV-TWA
WATER7732-18-5
>75 not available not available
PUMICE1332-09-8
<10 not available not available 10 mg/m3 (inhal); 3 mg/m3
(resp) ACGIH
ETHOXYLATED C11-C16 ALCOHOL127036-24-2
<5 oral rat: >500 mg/kg not available
D-LIMONENE5989-27-5
0.1-1.0 4400 mg/kg not available
III. PHYSICAL DATAPhysical State/Appearance: White lotion with pumice
Odour & Odour Threshold: Orange odour
Specific Gravity: 1.06
Evaporation Rate: <1 (Butyl acetate = 1)
Vapour Pressure: Not determined
Vapour Density: Heavier than air
Freezing Point: Not determined
pH: 6.0-8.0
Octanol/Water Coefficient: Not determined
Boiling Point: 100°C (212°F)
IV. FIRE AND EXPLOSIVE DATARecommended Extinguishing Media: Carbon dioxide, Water, dry chemical
Hazardous Combustion Products: Not applicable.
Sensitivity to Static Discharge: Sensitivity to static discharge is not expected.
Conditions of Flammability: None anticipated.
Flash Point/Range: >95°C COC
Autoignition Temperature: Not determined
Upper Explosive Limit: Not determined
Lower Explosive Limit: Not determined
V. REACTIVITY DATAConditions Causing Chemical Instability: None
Materials to avoid: None reasonably foreseeable
Conditions of Reactivity: None.
Hazardous Decomposition Products: None anticipated
VI. HAZARDS IDENTIFICATIONPrimary Routes of Exposure: Eye and skin contact, ingestion, inhalation
Existing Conditions Aggravated byExposure:
None known
Toxicity Information: (See Effects of Acute Exposure to Product)
Effects of Acute Exposure: None under normal conditions of use.
Effects of Chronic Exposure: May cause an allergic skin reaction.
Irritancy of Product: Possible eye irritation.
1 of 2
ITW Permatex Canada35 Brownridge Road, Unit 1Halton Hills, ON Canada L7G 0C6Telephone: (800) 924-6994Urgence: 800-255-3924 (ChemTel)
VI. HAZARDS IDENTIFICATIONSensitization to Product: (See Effects of Acute Exposure to Product)Carcinogenicity: (See Effects of Chronic Exposure to Product)Reproductive Toxicity: (See Effects of Chronic Exposure to Product)Teratogenicity: (See Effects of Chronic Exposure to Product)Mutagenicity: (See Effects of Chronic Exposure to Product)Toxicologically Synergistic Products: None known
WHMIS Hazard Class: Non-controlled
VII. PREVENTATIVE MEASURESPersonal ProtectionEyes: Not required.
Skin: Not required.
Ventilation: Not required under normal use.
Engineering Controls: No special provisions are required under normal conditions.
Spill Procedures: Rinse away with water or wipe up with a towel.
Protection of Man and Environment: Follow Canadian and local regulations for disposal.
Handling Procedures and Equipment:Protect from freezing.
Special Handling Information: Avoid contact with eyes.
VIII. FIRST AID MEASURESIngestion: If swallowed, do not induce vomiting - seek medical advice.
Inhalation: Immediate medical attention is not required.
Skin Contact: Flush with water.
Eye Contact: Flush with water. If eye irritation persists, get medical attention.
IX. SHIPPING INFORMATIONCanadian Transportation of Dangerous Goods
Proper Shipping Name: Not regulated
Hazard Class: None
UN/ID No: None
IATA (Air)Proper Shipping Name: Not regulated
Class or Division: None
UN/ID Number: None
IMDG (Vessel)Proper Shipping Name: Not regulated
Hazard Class: None
UN Number: None
X. PREPARATION INFORMATIONEstimated HMIS Classification: HEALTH 1, FLAMMABILITY 1, PHYSICAL HAZARD 0
(HMIS is a registered trademark of the National Paint and Coatings Association)
Estimated NFPA Rating: HEALTH 1, FLAMMABILITY 1 , REACTIVITY 0
(NFPA is a registered trademark of the National Fire Protection Association)
Prepared By: Denise Boyd, Manager-Environmental, Health & SafetyRevision Date: May 17, 2013
Company: ITW Permatex Canada. 35 Brownridge Rd. Unit 1, Halton Hills, ON L76 0C6Revision Number: 1
Telephone No.: 1-800-924-6994
2 of 2
Canadian Workplace Hazardous Materials Information SystemMaterial Safety Data Sheet
I. PRODUCT IDENTIFICATIONProduct Name: PC FAST ORANGE SMOOTH LOTION 1.89 LItem No: 25520Product Type: Waterless hand cleaner
II. COMPOSITION/INFORMATION ON INGREDIENTSComponent Weight% LD50/oral/rat LC50/inhalation/rat ACGIH; TLV-TWA
WATER7732-18-5
>80 not available not available
POLYMER EMULSION(PROPRIETARY)_
<3 not available not available
ETHOXYLATED C11-C16 ALCOHOL127036-24-2
<3 oral rat: >500 mg/kg not available
D-LIMONENE5989-27-5
0.1-1.0 4400 mg/kg not available
III. PHYSICAL DATAPhysical State/Appearance: White lotion
Odour & Odour Threshold: Orange odour
Specific Gravity: 0.96
Evaporation Rate: <1 (Butyl acetate = 1)
Vapour Pressure: Not determined
Vapour Density: Heavier than air
Freezing Point: Not determined
pH: 6.0-8.0
Octanol/Water Coefficient: Not determined
Boiling Point: 100°C (212°F)
IV. FIRE AND EXPLOSIVE DATARecommended Extinguishing Media: Water, Carbon dioxide, Dry chemical, Foam
Hazardous Combustion Products: Not applicable.
Sensitivity to Static Discharge: Sensitivity to static discharge is not expected.
Conditions of Flammability: None anticipated.
Flash Point/Range: >95°C COC
Autoignition Temperature: Not determined
Upper Explosive Limit: Not determined
Lower Explosive Limit: Not determined
V. REACTIVITY DATAConditions Causing Chemical Instability: None
Materials to avoid: None reasonably foreseeable
Conditions of Reactivity: None.
Hazardous Decomposition Products: None anticipated
VI. HAZARDS IDENTIFICATIONPrimary Routes of Exposure: Eye and skin contact, ingestion, inhalation
Existing Conditions Aggravated byExposure:
None known
Toxicity Information: (See Effects of Acute Exposure to Product)
Effects of Acute Exposure: None under normal conditions of use.
Effects of Chronic Exposure: May cause an allergic skin reaction.
1 of 2
ITW Permatex Canada35 Brownridge Road, Unit 1Halton Hills, ON Canada L7G 0C6Telephone: (800) 924-6994Urgence: 800-255-3924 (ChemTel)
VI. HAZARDS IDENTIFICATIONIrritancy of Product: Possible eye irritation.
Sensitization to Product: (See Effects of Acute Exposure to Product)Carcinogenicity: (See Effects of Chronic Exposure to Product)Reproductive Toxicity: (See Effects of Chronic Exposure to Product)Teratogenicity: (See Effects of Chronic Exposure to Product)Mutagenicity: (See Effects of Chronic Exposure to Product)Toxicologically Synergistic Products: None known
WHMIS Hazard Class: Non-controlled
VII. PREVENTATIVE MEASURESPersonal ProtectionEyes: Not required.
Skin: Not required.
Ventilation: Not required under normal use.
Engineering Controls: No special provisions are required under normal conditions.
Spill Procedures: Rinse away with water or wipe up with a towel.
Protection of Man and Environment: Follow Canadian and local regulations for disposal.
Handling Procedures and Equipment:Protect from freezing.
Special Handling Information: Avoid contact with eyes.
VIII. FIRST AID MEASURESIngestion: If swallowed, do not induce vomiting - seek medical advice.
Inhalation: Immediate medical attention is not required.
Skin Contact: Flush with water.
Eye Contact: Flush with water. If eye irritation persists, get medical attention.
IX. SHIPPING INFORMATIONCanadian Transportation of Dangerous Goods
Proper Shipping Name: Not regulated
Hazard Class: None
UN/ID No: None
IATA (Air)Proper Shipping Name: Not regulated
Class or Division: None
UN/ID Number: None
IMDG (Vessel)Proper Shipping Name: Not regulated
Hazard Class: None
UN Number: None
X. PREPARATION INFORMATIONEstimated HMIS Classification: HEALTH 1, FLAMMABILITY 1, PHYSICAL HAZARD 0
(HMIS is a registered trademark of the National Paint and Coatings Association)
Estimated NFPA Rating: HEALTH 1, FLAMMABILITY 1 , REACTIVITY 0
(NFPA is a registered trademark of the National Fire Protection Association)
Prepared By: Denise Boyd, Manager-Environmental, Health & SafetyRevision Date: May 16, 2013
Company: ITW Permatex Canada. 35 Brownridge Rd. Unit 1, Halton Hills, ON L76 0C6Revision Number: 1
Telephone No.: 1-800-924-6994
2 of 2
Material Safety Data Sheet
1. PRODUCT IDENTIFICATIONProduct Name: Spray Nine® 32 fl.oz
Item No: 26832Product Type: Multi-Purpose Cleaner
2. COMPOSITION/INFORMATION ON INGREDIENTSComponent: Weight% ACGIH; TLV-TWA OSHA PEL
WATER7732-18-5
>80 Not listed Not listed
ETHOXYLATED C9-C11 ALCOHOLS68439-46-3
1-5 Not listed Not listed
DIPROPYLENE GLYCOLMONONBUTYL ETHER29911-28-2
1-5 Not listed Not listed
3. HAZARDS IDENTIFICATIONToxicity: Product may cause reversible eye and skin irritation.. May irritate respiratory system upon frequent or
prolonged use. Oral LD50 greater than 5000 mg/kg.
Primary Routes of Entry: Eye and skin contact, ingestion, inhalation
Signs and Symptoms of Exposure: Overexposure may cause eye and skin redness. May cause inflammation of mucous membranes andirritation. Ingestion may cause nausea and vomiting.
Aggravated Medical Condition: Preexisting eye, skin and respiratory disorders may be aggravated by overexposure to this product.
WHMIS Hazard Class: Non-controlled
4. FIRST AID MEASURESIngestion: If swallowed, do not induce vomiting - seek medical advice. Never give anything by mouth to an
unconscious person.
Inhalation: Move to fresh air in case of accidental inhalation of vapours. If symptoms persist, call a physician.
Skin Contact: Wash off with soap and water. If skin irritation persists, call a physician.
Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medicalattention if irritation persists.
5. FIRE FIGHTING MEASURESFlash Point °F(C°): 182°F/83°C TCC
Recommended Extinguishing Media: Carbon dioxide, Dry chemical, Foam
Special Fire-Fighting Procedures: Wear suitable protective equipment. Use water spray to cool exposedcontainers.
Hazardous Products of Combustion: Oxides of carbon, Oxides of nitrogen
Unusual Fire/Explosion Hazards: Does not sustain combustion (ASTM D4206).
Lower Explosive Limit: Not determined
Upper Explosive Limit: Not determined
6. ACCIDENTAL RELEASE MEASURESSpill Procedures: Maintain good ventilation. Take up with an inert absorbent. Store in a closed waste container until disposal.
Clean up spills thoroughly as residue is slippery.
1 of 3
ITW Permatex Canada35 Brownridge Road, Unit 1Halton Hills, ON Canada L7G 0C6Telephone: (800) 924-6994Urgence: 800-255-3924 (ChemTel)
ITW PermatexSpray Nine Brands10 Columbus Blvd.Hartford, CT 06106 USATelephone: 1-87-Permatex(877) 376-2839Emergency: 800-255-3924 (ChemTel)International Emergency: +01-813-248-0585
7. HANDLING AND STORAGEStorage: Keep containers tightly closed in a cool, well-ventilated place. Store below 100°F. Do not allow freezing.
Handling: Use in a well ventilated area. Avoid contact with skin and eyes. Wash thoroughly after handling. Productmay cause surfaces to become slippery.
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONEyes: Safety glasses.
Skin: Neoprene or nitrile gloves recommended.
Ventilation: Where reasonably practicable this should be achieved by the use of local exhaust ventilation and goodgeneral extraction.
Respiratory Protection: Not required under normal use.
9. PHYSICAL AND CHEMICAL PROPERTIESAppearance: Clear liquid
Odor: Citrus
Boiling Point: ~212°F (100°C)
pH: ~12.4
Solubility in Water: Soluble
Specific Gravity: 1.02 g/ml
VOC(Wt.%): 0
Vapor Pressure: 18 mm Hg
Vapor Density (Air=1): >1
Evaporation Rate: <1 (butyl acetate=1)
10. STABILITY AND REACTIVITYChemical Stability: Stable
Hazardous Polymerization: Will not occur
Incompatabilities: Strong oxidizers
Conditions to Avoid: Freezing
Hazardous Products of Combustion: Oxides of carbon, Oxides of nitrogen
11. TOXICOLOGICAL INFORMATIONOral LD50 (rat) >5,000 mg/kgDermal LD50 (rabbit) >5,000 mg/kgInhalation LD50 (rat) >200 g/LEye irritation: Draize = 27.3 of 110 (reversible in 10 days)Skin irritation: Draize 2.5 of 10 (reversible in 14 days)
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONSRecommended Method of Disposal: Disposal should be made in accordance with federal, state and local regulations
US EPA Waste Number: NH - Not a RCRA Hazardous Waste Material
14. TRANSPORTATION INFORMATIONDOT (49CFR 172)U.S. Department of Transportation - DOT - 49 CFR (Ground)
DOT Shipping Name: Not regulated
Hazard Class: None
UN/ID Number: None
IATA (Air)Proper Shipping Name: Not regulated
Class or Division: None
UN/ID Number: None
IMDG (Vessel)Proper Shipping Name: Not regulated
Hazard Class: None
UN Number: None
Item No. 26832Spray Nine® 32 fl.ozProduct Name:
Marine Pollutant: None
SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical.
None
California Proposition 65: No California Prop 65 chemicals are known to be present.
TSCA Inventory Status: All components of this product are listed (or exempt) on the EPA TSCA inventory.
16. OTHER INFORMATIONEstimated NFPA Rating: HEALTH 1, FLAMMABILITY 1 , REACTIVITY 0.
Estimated HMIS Classification: HEALTH 1, FLAMMABILITY 1, PHYSICAL HAZARD 0
(NFPA is a registered trademark of the National Fire Protection Association)(HMIS is a registered trademark of the National Paint and Coatings Association)
Item No. 26832
Company: ITW Permatex 10 Columbus Blvd. Hartford, CT USA 06106
Spray Nine® 32 fl.oz
Revision Number: 3
Telephone No.: 1-87-Permatex (877) 376-2839
Prepared By: Denise Boyd, Manager-Environmental, Health & Safety
Product Name:
Revision Date: March 25, 2014
MOTOR FLUSH MF2C, MF12C, MF2/6C
Page 1 of 7 MSDS Revision Date (mm/dd/yyyy): 07/18/2013
MATERIAL SAFETY DATA SHEET
: MOTOR FLUSH Product identifier
SECTION 1: IDENTIFICATION
Internal Engine Cleaner. : Product Use
: Mixture. Chemical Family
MF2C, MF12C, MF2/6C : Manufacturer part no.
Refer to Supplier
Manufacturer’s name and address: Supplier’s name and address:
Radiator Specialty Co., of Canada 1711 Aimco Blvd. Mississauga, ON, Canada L4W 1H7
(905) 625-9117 (Monday - Friday, 8 AM - 4 PM) : Information Telephone #
613-996-6666 (CANUTEC) : 24 Hr. Emergency Tel #
SECTION 2 - HAZARDS IDENTIFICATION
Classification : WHMIS information: This product is a WHMIS Controlled Product. It meets one or more of the criteria for a controlled product provided in Part IV of the Canadian Controlled Products Regulations (CPR). WHMIS classification: Class B3 (Combustible Liquids); Class D2A (Materials Causing Other Toxic Effects, Very Toxic Material); Class D2B (Materials Causing Other Toxic Effects, Toxic Material). Labelling: Phrases recommended to appear on a supplier label, can be found in Section 15. WHMIS symbols required on a supplier label:
Emergency Overview Light amber liquid. Petroleum odour. WARNING! Combustible liquid and vapour. Harmful if inhaled. May cause respiratory irritation. May cause nausea, vomiting, headache and other central nervous system effects. Harmful or fatal if swallowed. May be an aspiration hazard. Can enter the lungs and cause damage. May cause eye irritation. Prolonged or repeated skin contact may cause drying and irritation. Contains material which
may cause cancer, based on animal data.
:
POTENTIAL HEALTH EFFECTS:
:
Signs and symptoms of short-term (acute) exposure
May cause irritation to the nose, throat and upper respiratory tract. Symptoms may include pain, headache, nausea, vomiting, dizziness, drowsiness and other central nervous system effects.
Inhalation
: Skin May cause mild skin irritation. May cause redness and itching or burning sensation. Prolonged contact, such as when trapped against the skin under clothing or jewelry, may be more irritating. May be absorbed and cause symptoms similar to those for inhalation.
: Eyes May cause mild to moderate irritation.
May cause irritation of mouth, throat, and stomach. Symptoms may include pain, headache, nausea, vomiting, dizziness, drowsiness and other central nervous system effects. May be an aspiration hazard. Aspiration into the lungs during swallowing or subsequent vomiting may cause chemical pneumonitis, which can be fatal.
Ingestion :
Prolonged skin contact may cause dermatitis (rash), characterized by red, dry, itching skin.
Effects of long-term (chronic) exposure
:
Possible cancer hazard. See TOXICOLOGICAL INFORMATION, Section 11. : Carcinogenic status
Additional health hazards : See TOXICOLOGICAL INFORMATION, Section 11.
See ECOLOGICAL INFORMATION, Section 12. :
Potential environmental effects
MOTOR FLUSH MF2C, MF12C, MF2/6C
Page 2 of 7 MSDS Revision Date (mm/dd/yyyy): 07/18/2013
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients CAS # Wt.%
68476-34-6 Petroleum distillates 60.00 - 100.00 64742-52-5 Distillates (petroleum), hydrotreated heavy
naphthenic 7.00 - 13.00
78330-12-8 Petroleum sulfonate 0.10 - 1.00
If inhaled, move to fresh air. If breathing has stopped, give artificial respiration. If breathing is difficult, give oxygen by qualified medical personnel only. Get medical attention.
: Inhalation
SECTION 4 - FIRST AID MEASURES
Remove/Take off immediately all contaminated clothing. Wash exposed area thoroughly with soap and water for at least 15 minutes. If irritation persists, seek prompt medical attention.
Skin contact :
Immediately flush eyes with plenty of water for at least 15 minutes. If irritation persists, seek prompt medical attention.
Eye contact :
Ingestion Seek immediate medical attention/advice. Do not induce vomiting. Never give anything by mouth to an unconscious person.
:
Treat symptomatically. : Notes For Physician
Fire hazards/conditions of flammability
SECTION 5 - FIRE FIGHTING MEASURES
Combustible liquid and vapour. Will ignite when exposed to heat, flame and other sources of ignition. Product may float, and be re-ignited at the water's surface. Closed containers may rupture if exposed to excess heat or flame due to a build-up of internal pressure. Vapours may be heavier than air and may collect in confined and low-lying areas.
:
None known. : Oxidizing properties
: Not expected to be sensitive to mechanical impact. May be sensitive to static discharge.
Explosion data: Sensitivity to mechanical impact / static discharge
Dry chemical, foam, carbon dioxide and water fog. Do not use water jet, as this may spread burning material.
: Suitable extinguishing media
Special fire-fighting procedures/equipment
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full face piece operated in positive pressure mode. Move containers from fire area if safe to do so. Water spray may be useful in cooling equipment exposed to heat and flame.
:
Hazardous combustion products
: Carbon oxides; Sulphur oxides; Phosphorus compounds; Nitrogen oxides (NOx); Polycyclic aromatic hydrocarbons; Other unidentified organic compounds.
All persons dealing with the clean-up should wear the appropriate personal protective equipment. Keep all other personnel upwind and away from the spill/release. Restrict access to area until completion of clean-up.
Personal precautions :
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Ensure spilled product does not enter drains, sewers, waterways, or confined spaces. For large spills, dike the area to prevent spreading.
Environmental precautions :
Spill response/cleanup Ventilate area of release. Remove all sources of ignition. Use only non-sparking tools and equipment in the clean-up process. Contain and absorb spilled liquid with non-combustible, inert absorbent material (e.g. sand), then place absorbent material into a container for later disposal (see Section 13). Notify the appropriate authorities as required.
:
: Prohibited materials Do not use combustible absorbents, such as sawdust.
MOTOR FLUSH MF2C, MF12C, MF2/6C
Page 3 of 7 MSDS Revision Date (mm/dd/yyyy): 07/18/2013
Use in a well-ventilated area. Wear suitable protective equipment during handling. Avoid breathing vapours. Avoid contact with skin, eyes and clothing. Keep away from heat, sparks, and open flames. No sparking tools should be used. Avoid contact with incompatible materials. Wash thoroughly after handling.
Safe Handling procedures :
SECTION 7 - HANDLING AND STORAGE
Store in a cool, dry, well-ventilated area. Keep away from direct sunlight. Storage area should be clearly identified, clear of obstruction and accessible only to trained and authorized personnel. Inspect periodically for damage or leaks. No smoking in the area.
Storage requirements :
Incompatible materials : Strong oxidizing agents; Acids.
Special packaging materials : Always keep in containers made of the same materials as the supply container.
Exposure Limits
ACGIH TLV OSHA PEL
STEL TWA STEL PEL Ingredients
N/Av N/Av 100 mg/m³ (vapor and aerosol, as total
hydrocarbons) (skin)
N/Av Petroleum distillates
5 mg/m³ (As 'Oil
mist, mineral') N/Av 5 mg/m³ (As 'Oil mist,
mineral') N/Av Distillates (petroleum), hydrotreated
heavy naphthenic
N/Av N/Av N/Av N/Av Petroleum sulfonate
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
Ventilation and engineering measures
Use in a well-ventilated area. Use general or local exhaust ventilation to maintain air concentrations below recommended exposure limits.
:
Respiratory protection : If the TLV is exceeded, a NIOSH/MSHA-approved respirator is advised. Advice should be sought from respiratory protection specialists.
Skin protection : Impervious gloves must be worn when using this product. Advice should be sought from glove suppliers. Depending on conditions of use, an impervious apron should be worn.
Eye / face protection : Chemical splash goggles are recommended.
An eyewash station and safety shower should be made available in the immediate working area.
: Other protective equipment
General hygiene considerations
: Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink, smoke or use cosmetics while working with this product. Remove and wash contaminated clothing before re-use. Wash thoroughly after handling.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical state liquid : Appearance Light amber liquid. :
Odour Petroleum odour. : Odour threshold N/Av :
pH N/Av :
Boiling point 0.86 @ 20°C : Specific gravity : 79.4°C
Melting/Freezing point N/Av :
N/Av :
Coefficient of water/oil distribution
Vapour pressure (mmHg @ 20° C / 68° F)
N/Av :
Solubility in water Insoluble. :
Vapour density (Air = 1) N/Av : Evaporation rate (n-Butyl acetate = 1)
: N/Av
Volatile organic Compounds (VOC's)
N/Av :
Volatiles (% by weight) : N/Av
Flash point 71.1°C :
Flash point Method N/Av : Auto-ignition temperature TCC :
Lower flammable limit (% by vol.) Upper flammable limit (% by vol.)
: : N/Av N/Av
Flame Projection Length Flashback observed : : N/Ap N/Ap
MOTOR FLUSH MF2C, MF12C, MF2/6C
Page 4 of 7 MSDS Revision Date (mm/dd/yyyy): 07/18/2013
Absolute pressure of container
: N/Ap
Viscosity : < 10 cSt @ 40°C
No additional information. : General Informatioln
Section 10: STABILITY AND REACTIVITY
Stability and reactivity Stable under the recommended storage and handling conditions prescribed. :
Hazardous polymerization Hazardous polymerization does not occur. :
Conditions to avoid : Avoid heat and open flame. Keep away from direct sunlight. Do not use in areas without adequate ventilation. Avoid contact with incompatible materials.
Materials To Avoid And Incompatibility
: Strong oxidizing agents; Acids.
Hazardous decomposition products None known, refer to hazardous combustion products in Section 5. :
Eyes, skin, respiratory system, digestive system, central nervous system. Target organs :
SECTION 11 - TOXICOLOGICAL INFORMATION
Routes of exposure Inhalation: Skin Absorption: Skin & Eyes: Ingestion: YES YES YES YES :
: Mild to moderate eye irritant. Mild skin irritant.. Irritancy
There is no available data for the product itself, only for the ingredients. See below for individual ingredient acute toxicity data.
: Toxicological data
LD50 LC50(4hr)
inh, rat Ingredients (Rabbit, dermal) (Oral, rat)
Petroleum distillates N/Av N/Av N/Av
Distillates (petroleum),
hydrotreated heavy naphthenic
> 5 mg/L (mist) > 5000 mg/kg > 2000 mg/kg
Petroleum sulfonate N/Av > 2000 mg/kg > 2000 mg/kg
Carcinogenic status Contains the following chemicals listed as confirmed animal carcinogens (A3) by ACGIH: Petroleum distillates.
:
: Not expected to have other reproductive effects. Reproductive effects
: Teratogenicity Not expected to be a teratogen.
: Mutagenicity Not expected to be mutagenic in humans.
: Epidemiology None known or reported by the manufacturer.
Sensitization to material : Not expected to be a skin or respiratory sensitizer.
: Synergistic materials None known or reported by the manufacturer.
CNS depression may result from extreme exposures. other important hazards :
Conditions aggravated by overexposure
None known or reported by the manufacturer. :
Ecotoxicity : The ecological characteristics of this product have not been fully investigated. The product should not be allowed to enter drains or water courses, or be deposited where it can affect ground or surface waters. See the following tables for individual ingredient ecotoxicity data.
SECTION 12 - ECOLOGICAL INFORMATION
Ecotoxicity data:
NOEC / 21 day LC50 / 96h M Factor
Toxicity to Fish CAS No Ingredients
Petroleum distillates 21 mg/L (Rainbow trout) 68476-34-6 N/Av None.
Distillates (petroleum), hydrotreated heavy naphthenic
> 5000 mg/L (Rainbow trout)
64742-52-5 N/Av None.
Petroleum sulfonate N/Av 78330-12-8 N/Av None.
MOTOR FLUSH MF2C, MF12C, MF2/6C
Page 5 of 7 MSDS Revision Date (mm/dd/yyyy): 07/18/2013
CAS No Ingredients Toxicity to Daphnia
EC50 / 48h NOEC / 21 day M Factor
68476-34-6 None. N/Av 49 - 94 mg/L (Daphnia
magna) Petroleum distillates
64742-52-5 None. N/Av > 1000 mg/L [Daphnia
magna (Water flea)] Distillates (petroleum),
hydrotreated heavy naphthenic
78330-12-8 None. N/Av N/Av Petroleum sulfonate
CAS No Ingredients Toxicity to Algae
EC50 / 96h or 72h NOEC / 96h or 72h M Factor
68476-34-6 Petroleum distillates 10 mg/L/72hr (Green algae) 3 mg/L (NOEL) None.
64742-52-5 Distillates (petroleum),
hydrotreated heavy naphthenic
> 1000 mg/L/96hr (Green
algae) N/Av None.
78330-12-8 Petroleum sulfonate N/Av N/Av None.
Mobility No data is available on the product itself. :
Persistence No data is available on the product itself. Contains: Petroleum distillates. Petroleum distillates are not considered to be readily biodegradable.
:
Bioaccumulation potential No data is available on the product itself. :
Other Adverse Environmental effects
No data is available on the product itself. :
Handle waste according to recommendations in Section 7. Empty containers retain residue (liquid and/or vapour) and can be dangerous.
: Handling for Disposal
SECTION 13 - DISPOSAL CONSIDERATIONS
Dispose of in accordance with federal, provincial and local hazardous waste laws. : Methods of Disposal
SECTION 14: TRANPORT INFORMATION
Regulatory Information UN Number Shipping Name Class
Packing
Group Label
Not regulated. not regulated TDG None none
None.
Additional information
TDG
SECTION 15 - REGULATORY INFORMATION
Labelling:
WARNING! Combustible liquid and vapour. Harmful if inhaled. May cause respiratory irritation. May cause nausea, vomiting, headache and other central nervous system effects. Harmful or fatal if swallowed. May be an aspiration hazard. Can enter the lungs and cause damage. May cause eye irritation. Prolonged or repeated skin contact may cause drying and irritation. Contains material which may cause cancer, based on animal data.
Precautions: Use in a well-ventilated area. Wear suitable protective equipment during handling. Avoid breathing vapours. Avoid contact with skin, eyes and clothing. Keep away from heat, sparks, and open flames. No sparking tools should be used. Avoid contact with incompatible materials. Wash thoroughly after handling. Store in a cool, dry, well ventilated area, away from heat and ignition sources.
MOTOR FLUSH MF2C, MF12C, MF2/6C
Page 6 of 7 MSDS Revision Date (mm/dd/yyyy): 07/18/2013
FIRST AID: If inhaled, move to fresh air. If breathing stopped, begin artificial respiration. If breathing is difficult, give oxygen by qualified medical personnel only. Get medical attention. For skin contact, immediately remove contaminated clothing then wash thoroughly with soap and water for at least 15 minutes. If irritation persists, seek prompt medical attention. For eye contact, flush with running water for at least 15 minutes. If irritation persists, seek prompt medical attention. If ingested, do not induce vomiting. Never give anything by mouth to an unconscious person. Seek immediate medical attention/advice. Refer To Material Safety Data Sheet for further information.
Canadian Environmental Protection Act (CEPA) information: All ingredients listed appear on the Domestic Substances List (DSL). WHMIS information: Refer to Section 2 for a WHMIS Classification for this product.
Canadian Information:
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR.
TSCA: All listed ingredients appear on the Toxic Substances Control Act (TSCA) inventory.
US Federal Information:
SECTION 16 - OTHER INFORMATION
: ACGIH: American Conference of Governmental Industrial Hygienists CAS: Chemical Abstract Services HSDB: Hazardous Substances Data Bank IARC: International Agency for Research on Cancer Inh: Inhalation LC: Lethal Concentration LD: Lethal Dose MSHA: Mine Safety and Health Administration N/Ap: Not Applicable N/Av: Not Available NIOSH: National Institute of Occupational Safety and Health NOEC: No observable effect concentration NTP: National Toxicology Program OECD: Organisation for Economic Co-operation and Development OSHA: Occupational Safety and Health Administration PEL: Permissible exposure limit RTECS: Registry of Toxic Effects of Chemical Substances STEL: Short Term Exposure Limit TCC: Tagliabue Closed Cup TDG: Canadian Transportation of Dangerous Goods Act & Regulations TLV: Threshold Limit Values TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Identification System
Legend
1. ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents & Biological Exposure Indices for 2013. 2. International Agency for Research on Cancer Monographs, searched 2013. 3. Canadian Centre for Occupational Health and Safety, CCInfoWeb databases, 2013 (Chempendium, HSDB and RTECs). 4. Material Safety Data Sheets from manufacturer. 5. OECD - The Global Portal to Information on Chemical Substances - eChemPortal, 2013
References :
MOTOR FLUSH MF2C, MF12C, MF2/6C
Page 7 of 7 MSDS Revision Date (mm/dd/yyyy): 07/18/2013
Prepared for:
Radiator Specialty Co. of Canada 1711 Aimco Blvd. Mississauga, ON, Canada, L4W 1H7 Telephone: 905-625-9117 (Mon. - Fri., 8 AM - 4 PM) Please direct all enquiries to Radiator Specialty.
Prepared by:
ICC The Compliance Center Inc. http://www.thecompliancecenter.com
DISCLAIMER OF LIABILITY
This Material Safety Data Sheet was prepared by ICC The Compliance Center Inc. using information provided by Radiator Specialty Co. of Canada and CCOHS’ Web Information Service. The information in the Material Safety Data Sheet is offered for your consideration and guidance when exposed to this product. ICC The Compliance Center Inc and Radiator Specialty Co. of Canada expressly disclaim all expressed or implied warranties and assume no responsibilities for the accuracy or completeness of the data contained herein. The data in this MSDS does not apply to use with any other product or in any other process. This Material Safety Data Sheet may not be changed, or altered in any way without the expressed knowledge and permission of ICC The Compliance Center Inc. and Radiator Specialty Co. of Canada.
:
MSDS Preparation Date (mm/dd/yyyy)
07/26/2007
MSDS Revision Date (mm/dd/yyyy)
: 07/18/2013
Revision No. 3 :
(M)SDS sections updated: 9. PHYSICAL AND CHEMICAL PROPERTIES (Viscosity); 12. ECOLOGICAL INFORMATION.
: Revision Information
END OF DOCUMENT
Methanol Products
Not available.
CH3OH
Alcohol. (Solvent.)
67-56-1
Not available.
Not available.
Recochem Inc.Communications and Regulatory AffairsDepartment(905) 878-5544
Recochem Inc.850 Montee de LiesseMontreal, Quebec514-341-3550
Class B-2: Flammable liquidClass D-1B: Material causing immediate and serious toxic effects (Toxic).Class D-2A: Material causing other toxic effects (Very toxic).Class D-2B: Material causing other toxic effects (Toxic).
Material Safety Data SheetWHMIS (Pictograms) WHMIS (Classification) Personal protective equipment
Section 1. Product and Company IdentificationProduct name/ Trade name
Synonym
Chemical family
Chemical formula
Manufacturer/Supplier
Material uses
AssociatedProduct’s ItemCode
CAS #
In case ofemergency
Print date
Validation date 2013-04-02.
2013-04-04.
Extremely hazardous by the following route of exposure: of ingestion. Hazardous by the following route of exposure: ofinhalation. Slightly hazardous by the following route of exposure: of skin contact (irritant, permeator), of eye contact(irritant). Non-sensitizer to skin. Severe over-exposure can result in death.
Acute exposure to methanol, either through ingestion or breathing high airborne concentrations can result in symptomsappearing between 40 minutes and 72 hours after exposure. Symptoms and signs are usually limited to CNS, eyes andgastrointestinal tract. Because of the initial CNS’s effects of headache, vertigo, lethargy and confusion, there may be animpression of ethanol intoxication. Blurred vision, decreased acuity and photophobia are common complaints.Treatment with ipecac or lavage is indicated in any patient presenting within two hours of ingestion. A profoundmetabolic acidosis occurs in severe poisoning and serum bicarbonate levels are a more accurate measure of severitythan serum methanol levels. Treatment protocols are available from most major hospitals and early collaboration withappropriate hospitals is recommended.
Section 2. Hazards identification
Potential Acute HealthEffects
Note to Physician
Emergency Overview
Flammable liquid. Keep away from heat, sparks and flame. Avoid breathing vapor or mist. Avoid contact with skin andclothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use.
WARNING!FLAMMABLE LIQUID AND VAPOR. MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.
See section 11 for more detailed information on health effects and symptoms.
Section 3. Composition, information on ingredients
Canada
Name CAS number Conc. (% w/w)
Methanol 67-56-1 100
Continued on next page
Methanol ProductsPage: 2/8Validated on 2013-04-02.
There are no other ingredients present which, within the current knowledge of the supplier and in theconcentrations applicable, are classified as hazardous to health or the environment and hence requirereporting in this section.
Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anythingby mouth to an unconscious person. Get medical attention immediately.
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 30 minutes,occasionally lifting the upper and lower eyelids. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 30 minutes while removing contaminatedclothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attentionimmediately.
Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificialrespiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medicalattention immediately.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
Notes to physician No specific treatment. Treat symptomatically. Contact poison treatment specialistimmediately if large quantities have been ingested or inhaled.
Decomposition products may include the following materials:carbon dioxidecarbon monoxide
Use dry chemical, CO2, water spray (fog) or foam.
Explosive in the form of vapor when exposed to heat or flame. Vapor may travel a considerable distance to source ofignition and flash back. Emits acrid smoke and irritating fumes when heated to decomposition.
Highly flammable liquid and vapor.
Section 5. Fire-fighting measures
Products of combustion
Fire-fighting media andinstructions
Fire Hazards
Explosion Hazards
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, orif water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows.Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceousearth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools andexplosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent materialmay pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section13 for waste disposal.
Section 6. Accidental release measures
Small spill and leak
Large spill and leak
Continued on next page
Methanol ProductsPage: 3/8Validated on 2013-04-02.
Store in accordance with local regulations. Store in a segregated and approved area. Store in original containerprotected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10)and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed andsealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to preventleakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited inareas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Useonly with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areasand confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from acompatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any otherignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparkingtools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate staticelectricity during transfer by grounding and bonding containers and equipment before transferring material. Emptycontainers retain product residue and can be hazardous. Do not reuse container.
Section 7. Handling and Storage
Handling
Storage
Section 8. Exposure controls/personal protection
Engineering controls
Personal protectionEyes
Body
Respiratory
Hands
Product name Exposure limits
United States
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits. The engineering controls also need to keep gas, vaporor dust concentrations below any lower explosive limits. Use explosion-proof ventilationequipment.
Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts. Recommended: splash gogglesPossible: face shield
Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.Possible: safety apron coveralls boots.
Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection must bebased on known or anticipated exposure levels, the hazards of the product and the safeworking limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this inecessary. >8 hours (breakthrough time): nitrile rubber
Continued on next page
Methanol ProductsPage: 4/8Validated on 2013-04-02.
Canada
Methanol ACGIH TLV (United States, 1/2008). Absorbed through skin. TWA: 200 ppm 8 hour(s). TWA: 262 mg/m³ 8 hour(s). STEL: 250 ppm 15 minute(s). STEL: 328 mg/m³ 15 minute(s).OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. TWA: 200 ppm 8 hour(s). TWA: 260 mg/m³ 8 hour(s). STEL: 250 ppm 15 minute(s). STEL: 325 mg/m³ 15 minute(s).NIOSH REL (United States, 6/2008). Absorbed through skin. TWA: 200 ppm 10 hour(s). TWA: 260 mg/m³ 10 hour(s). STEL: 250 ppm 15 minute(s). STEL: 325 mg/m³ 15 minute(s).OSHA PEL (United States, 11/2006). TWA: 200 ppm 8 hour(s). TWA: 260 mg/m³ 8 hour(s).OSHA (United States, 2003). TWA: 200 ppm 8 hour(s). TWA: 260 mg/m³ 8 hour(s).
[1]Absorbed through skin.
Methanol US ACGIH 1/2008 200 262 - 250 328 - - - - [1]AB 6/2008 200 262 - 250 328 - - - - [1]BC 6/2008 200 - - 250 - - - - - [1]ON 6/2008 200 260 - 250 325 - - - - [1]QC 6/2008 200 262 - 250 328 - - - - [1]
Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations
CeilingSTEL (15 mins)TWA (8 hours)Occupational exposure limits
64.5°C (148.1°F)Boiling/condensation point
Liquid.
100% (v/v)
7
-98°C (-144°F)
0.79
1.11 [Air = 1]
12.8 kPa (96 mm Hg)
Easily soluble in the following materials: cold water, hotwater and diethyl ether.
2000 ppm
32.04 g/mole
Alcohol. [Slight]
Not available.
Colorless.
5.9 (Butyl acetate. = 1)
Not available.
Section 9. Physical and chemical properties
Physical State andAppearance
Molecular weight
pH
Odour
Taste
Colour
Relative density
Vapor pressure
Vapour Density
Volatility
OdourThreshold
Viscosity
Solubility
Evaporationrate
Melting/freezing point
Continued on next page
Methanol ProductsPage: 5/8Validated on 2013-04-02.
Lower: 6%Upper: 36%
CLOSED CUP: 11°C (51.8°F). (Tagliabue.)
385°C (725°F)
Flammable.
Highly flammable in the presence of the following materials or conditions: open flames, sparks and static discharge andheat.Non-flammable in the presence of the following materials or conditions: shocks and mechanical impacts.Explosive in the form of vapor when exposed to heat or flame. Vapor may travel a considerable distance to source ofignition and flash back. Emits acrid smoke and irritating fumes when heated to decomposition.
The product is:
Auto-ignition temperature
Flash point
Flammable limits
Fire hazards in thepresence of varioussubstances
VOC content OtherProperties
Not available.100 % (w/w)
The product is stable.
Slightly reactive or incompatible with the following materials: oxidizing materials, acids and alkalis.
Not available.
Section 10. Stability and reactivity
Stability
Conditions of instability
Incompatibility withvarious substancesHazardous decompositionproducts
Under normal conditions of storage and use, hazardous decomposition products shouldnot be produced.
Acute toxicity
Chronic toxicity
Carcinogenicity
Classification
Product/ingredient name ACGIH EPA NIOSH NTPIARC OSHA
Section 11. Toxicological Information
Canada
Methanol LC50 Inhalation Gas. Rat 64000 ppm 4 hoursLD50 Dermal Rabbit 15800 mg/kg -LD50 Dermal Rabbit 15840 mg/kg -LD50 Oral Rat 5600 mg/kg -LD50 Oral Rat 5600 mg/kg -
Methanol A5 4 - - - None.
Conclusion/Summary Not available.
Conclusion/Summary Not available.
Conclusion/Summary May be fatal or cause blindness if swallowed.Chronic Exposure Effects can include one or all of the following: Acute poisoning,headaches, nausea, vomiting, unconsciousness, kidney and liver damage.Exposure can cause dermatitis.
Continued on next page
Methanol ProductsPage: 6/8Validated on 2013-04-02.
Mutagenicity
Conclusion/Summary :
Teratogenicity
Conclusion/Summary :
Reproductive Toxicity
Conclusion/Summary :
Not available.
Not available.
Not available.
Section 12. Ecological informationFor accidental discharges into the environment, see Section 6:"Accidental Release Measures" for suggestedinstructions.
Canada
:
Aquatic ecotoxicity
Conclusion/Summary :
Biodegradability
Conclusion/Summary : No additional remark.
Product/ingredient name Result Species ExposureMethanol Acute LC50 2500000 ug/L Marine water Crustaceans - Crangon crangon -
Adult48 hours
Acute LC50 3289 to 4395 mg/L Freshwater
Daphnia - Daphnia magna -Neonate - <24 hours
48 hours
Acute LC50 >100000 ug/L Fresh water Fish - Pimephales promelas -Juvenile (Fledgling, Hatchling,Weanling) - 0.2 to 0.5 g
96 hours
Not available.
Ecotoxicity Readily biodegradable
The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-productsshould at all times comply with the requirements of environmental protection and waste disposal legislation and anyregional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways,drains and sewers.
Waste information
Section 13. Disposal considerations
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Continued on next page
Methanol ProductsPage: 7/8Validated on 2013-04-02.
In containers of 1 L (1Kg) capacity or less this product is classifiedas a "Limited Quantities""Consumer Commodity" under TDGregulations.
Class
Not a pollutant.
Section 14. Transport information
Proper Shipping Name(Canada) TDG
Special provisions
Class 3: Flammable liquid.
Special provisions In containers of 1 L (1Kg) this product is qualified as a "consumercommodity" ORM-D under DOT
Proper Shipping Name(United States) DOT
Methanol
Class 3: Flammable liquid.
Methanol
Marine pollutant
Proper Shipping NameIMDG
No placard (handling and hazard label) requi red.
Special provisions RemarksIn containers of 1 L (1Kg) capacity or less this product is classifiedas a "Limited Quantity" under IMDG regulations
Class 6.1: Toxic substance.Subsidiary class
Class 6.1: Toxic substance.Subsidiary class
International AirTransport Association(IATA)
Class 3: Flammable liquid.
Class 6.1: Toxic substance.ClassSubsidiary class
For air shipment classification and associated regulations, please refer to the latest edition ofIATA Dangerous Goods Regulations.
Class
United States DOT (Classification)
IMDG Classification
Canada TDG Classification
Methanol
UN 1230II
UN numberPacking Group
IIUN 1230UN number
Packing Group
UN 1230
II
UN numberPacking Group
Continued on next page
Methanol ProductsPage: 8/8Validated on 2013-04-02.
130B
03
1
Flammable liquidTarget organ effects
U.S.A. Regulatory Lists
Section 15. Regulatory information
HCS Classification(U.S.A.)
Hazardous MaterialInformation System(U.S.A.)
National FireProtectionAssociation(U.S.A.)
Health
Specific hazard
Reactivity
FlammabilityHealth
Flammability
Reactivity
Personal protection
Class B-2: Flammable liquidClass D-1B: Material causing immediate and serious toxic effects(Toxic).Class D-2A: Material causing other toxic effects (Very toxic).Class D-2B: Material causing other toxic effects (Toxic).
WHMIS Classification(Canada)
This product and/ or all of its components are on the TSCA inventory list.
This product and/ or all of its components are on the DSL.Canada DomesticSubstances List (DSL)Status
Section 16. Other information
Validated and verified by Compliance and Technical Information Manager on 2013-04-02 ph.#905-878-5544.
Printed 2013-04-04.
Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever forthe accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certainhazards are described herein, we cannot guarantee that these are the only hazards that exist.
MSDS are available at www.recochem.com
Universal Fully Formulated Antifreeze/Coolant Premix 60/40
Not available.
CH2OHCH2OH
Not available.
Not available.
WIP-15240-60
Industrial applications: Coolant and antifreeze formulations.
Recochem Inc.Communications and Regulatory AffairsDepartment(905) 878-5544
Recochem Inc.850 Montee de LiesseMontreal, QuebecH4T 1P4(514) 341-3550www.recochem.com
Class D-1B: Material causing immediate and serious toxic effects(Toxic).Class D-2A: Material causing other toxic effects (Very toxic).
Material Safety Data SheetWHMIS (Pictograms) WHMIS (Classification) Personal protective equipment
Section 1. Product and Company IdentificationProduct name/ Trade name
Synonym
Chemical family
Chemical formula
Manufacturer/Supplier
Material uses
AssociatedProduct’s ItemCode
CAS #
In case ofemergency
Print date
Validation date 2013-04-23.
2013-05-01.
Toxic by ingestion. May cause abdominal discomfort or pain, nausea, vomiting, dizziness, central nervous system effectsand coma. Cardiac failure, pulmonary edema and severe kidney damage may develop. May cause mild eye irritation.May cause mild skin irritation. Unlikely to be inhaled because of physical characteristics, however, heated material mayproduce vapours, which may cause irritation to lungs if inhaled excessively. Inhalation, particularly of mist, may causeirritation of the nose and throat with headache. High vapour concentrations may produce nausea, vomiting, headache,dizziness and irregular eye movement..
The signs and symptoms in ethylene glycol poisoning are those of metabolic acidosis, central nervous systemdepression and kidney injury. Clinical chemistry may reveal anion-gap metabolic acidosis and uremia. Treatment withethanol to inhibit the metabolism of glycol to oxalate.Early administration of ethanol may counter the toxic effects ofethylene glycol (cardiopulmonary effects attributed to metabolic acidosis and renal damage).Hemodialysis or peritoneal dialysis have been of benefit.Pre-existing respiratory and skin disorders may be aggravated by over-exposure to this product.Treat symptomatically and supportively.
Section 2. Hazards identification
Potential Acute HealthEffects
Note to Physician
Emergency Overview
Harmful by inhalation. Do not breathe vapor or mist. Avoid contact with eyes, skin and clothing. May cause target organdamage, based on animal data. Use only with adequate ventilation. Keep container tightly closed and sealed until readyfor use.
WARNING!MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.
See section 11 for more detailed information on health effects and symptoms.
Continued on next page
Universal Fully FormulatedAntifreeze/ Coolant Premix 60/40
Page: 2/8Validated on 2013-04-23.
Section 3. Composition, information on ingredients
There are no other ingredients present which, within the current knowledge of the supplier and in theconcentrations applicable, are classified as hazardous to health or the environment and hence requirereporting in this section.
Canada
Name CAS number Conc. (% w/w)
Ethylene glyco 107-21-1 60
Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anythingby mouth to an unconscious person. Get medical attention immediately.
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 30 minutes,occasionally lifting the upper and lower eyelids. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 30 minutes while removing contaminatedclothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attentionimmediately.
Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificialrespiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medicalattention immediately.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
Notes to physician See section 2 Treat symptomatically. Contact poison treatment specialist immediately if largequantities have been ingested or inhaled.
Decomposition products may include the following materials:carbon dioxidecarbon monoxide
Use an extinguishing agent suitable for the surrounding fire.
Emits acrid smoke and irritating fumes when heated to decomposition.May be combustible at high temperature.
Not a product presenting risks of explosion.
Section 5. Fire-fighting measures
Products of combustion
Fire-fighting media andinstructions
Fire Hazards
Explosion Hazards
Continued on next page
Universal Fully FormulatedAntifreeze/ Coolant Premix 60/40
Page: 3/8Validated on 2013-04-23.
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, orif water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of viaa licensed waste disposal contractor.
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows.Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceousearth and place in container for disposal according to local regulations (see section 13). Dispose of via a licensedwaste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note:see section 1 for emergency contact information and section 13 for waste disposal.
Section 6. Accidental release measures
Small spill and leak
Large spill and leak
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool andwell-ventilated area, away from incompatible materials (see section 10) and food and drink. Keep container tightly closedand sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to preventleakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited inareas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep inthe original container or an approved alternative made from a compatible material, kept tightly closed when not in use.Empty containers retain product residue and can be hazardous. Do not reuse container.
Section 7. Handling and Storage
Handling
Storage
Section 8. Exposure controls/personal protection
Engineering controls
Personal protectionEyes
Body
Respiratory
Hands
United States
No special ventilation requirements. Good general ventilation should be sufficient tocontrol worker exposure to airborne contaminants. If this product contains ingredientswith exposure limits, use process enclosures, local exhaust ventilation or otheengineering controls to keep worker exposure below any recommended or statutorylimits.
Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts. Recommended: splash goggles
Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.
Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection must bebased on known or anticipated exposure levels, the hazards of the product and the safeworking limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this inecessary. >8 hours (breakthrough time): nitrile rubber
Continued on next page
Universal Fully FormulatedAntifreeze/ Coolant Premix 60/40
Page: 4/8Validated on 2013-04-23.
Product name Exposure limits
Canada
Ethylene glycol OSHA PEL 1989 (United States, 3/1989). CEIL: 50 ppm CEIL: 125 mg/m³ACGIH TLV (United States, 1/2008). C: 100 mg/m³ Form: Aerosol
Form: [a]Aerosol [b]aerosol [c]Particulate [d]Vapour [e]vapour and mist
Ethylene glycol US ACGIH 1/2008 - - - - - - - 100 - [a]AB 6/2008 - - - - - - - 100 - [b]BC 6/2008 - - - - 100 - - - - [a]
- 10 - - 20 - - - - [c]- - - 50 - - - - - [d]
ON 6/2008 - - - - - - - 100 -QC 6/2008 - - - 50 127 - - - - [e]
Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations
CeilingSTEL (15 mins)TWA (8 hours)Occupational exposure limits
132°C (269.6°F)Boiling/condensation point
Clear viscous liquid.
Not available.
7
-52°C (-61.6°F)
1.08 to 1.12
2.1 [Air = 1]
0.008 kPa (0.06 mm Hg)
Soluble in water, methanol, diethyl ether.
25 ppm
Not available.
Odorless.
Sweet.
Green.
Not available.
Not applicable.
Not available.
May be combustible at high temperature.
Non-flammable in the presence of the following materials or conditions: open flames, sparks and static discharge, heatand shocks and mechanical impacts
0.01 (Butyl acetate. = 1)
Dynamic: 21 mPa·s (21 cP)
Section 9. Physical and chemical properties
Physical State andAppearance
Molecular weight
pH
Odour
Taste
Colour
Relative density
Vapor pressure
Vapour Density
Volatility
OdourThreshold
Viscosity
Solubility
The product is:
Auto-ignition temperature
Flash point
Flammable limits
Fire hazards in thepresence of varioussubstances
Evaporationrate
Melting/freezing point
VOC content OtherProperties
Not available.101.4 % (w/w) [ISO 11890-1]
Continued on next page
Universal Fully FormulatedAntifreeze/ Coolant Premix 60/40
Page: 5/8Validated on 2013-04-23.
The product is stable.
Reactive or incompatible with the following materials: oxidizing materials, acids and alkalis.Avoid contamination with reactive substances.
Not available.
Section 10. Stability and reactivity
Stability
Conditions of instability
Incompatibility withvarious substancesHazardous decompositionproducts
Under normal conditions of storage and use, hazardous decomposition products shouldnot be produced.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Chronic toxicity
Carcinogenicity
Classification
Product/ingredient name ACGIH EPA NIOSH NTPIARC OSHA
Section 11. Toxicological Information
Canada
Ethylene glycol LC50 Inhalation Dusts andmists
Rat 2725 mg/m³ 4 hours
LD50 Dermal Rabbit 9500 mg/kg -LD50 Dermal Rabbit 9500 mg/kg -LD50 Dermal Rabbit 9530 uL/kg -LD50 Intraperitoneal Mouse 5614 mg/kg -LD50 Intraperitoneal Rat 5010 mg/kg -LD50 Intravenous Rat 3260 mg/kg -LD50 Oral Cat 1650 mg/kg -LD50 Oral Dog 5500 mg/kg -LD50 Oral Mouse 5500 mg/kg -LD50 Oral Rat 4000 mg/kg -LD50 Oral Rat 4700 mg/kg -LD50 Oral Rat 5000 mg/kg -LD50 Subcutaneous Rat 2800 mg/kg -LD50 Unreported Mouse 8050 mg/kg -LD50 Unreported Rabbit 5017 mg/kg -LD50 Unreported Rat 13 g/kg -
Ethylene glycol A4 - - - - -
Conclusion/Summary (Ethylene glycol) The most common effects seen from ingestion of ethylene glycol arecentral nervous system (CNS) depression (muscular incoordination, lethargy, coma) andharmful effects on the kidneys including inflammation, degeneration, tissue death(necrosis), tubule dilation and oxalate crystal or stone deposition.
Conclusion/Summary Not available.
Conclusion/Summary Exposure can cause dermatitis.
Continued on next page
Universal Fully FormulatedAntifreeze/ Coolant Premix 60/40
Page: 6/8Validated on 2013-04-23.
Mutagenicity
Conclusion/Summary :
Teratogenicity
Conclusion/Summary :
Reproductive Toxicity
Conclusion/Summary :
Not available.
(Ethylene Glycol) Embryotoxicity (late resorptions), fetotoxicity (reduced fetal bodyweight) and teratogenicity (external, soft tissue and skeletal defects) have been observedin rats and mice exposed to at high oral doses that caused no or minimal maternaltoxicity. The US National Toxicology Program-Center for the Evaluation of Risks toHuman Reproduction (NTP-CERHR) has also concluded that oral exposure to high dosesof ethylene glycol causes developmental toxicity in rats and mice.
Not available.
Section 12. Ecological information
For accidental discharges into the environment, see Section 6:"Accidental Release Measures" for suggestedinstructions.
Canada
:
Aquatic ecotoxicity
Conclusion/Summary :
Biodegradability
Conclusion/Summary : Not available.
Product/ingredient name Result Species ExposureEthylene glycol Acute EC50 >100 mg/L Daphnia 4 hours
Acute EC50 >100 mg/L Daphnia 4 hoursAcute IC50 >100 mg/L Algae 1 hoursAcute IC50 >100 mg/L Algae 1 hoursAcute LC50 >100000 ug/L Marine water Crustaceans - Crangon crangon -
Adult48 hours
Acute LC50 6900000 to 8800000 ug/LFresh water
Daphnia - Ceriodaphnia dubia -Neonate
48 hours
Acute LC50 >100 mg/L Fish 24 hoursAcute LC50 >100 mg/L Fish 24 hoursAcute LC50 8050000 ug/L Fresh water Fish - Pimephales promelas - <=7
days96 hours
Chronic NOEC 11610000 ug/L Freshwater
Daphnia - Ceriodaphnia dubia -<=24 hours
48 hours
Chronic NOEC 6090000 ug/L Freshwater
Fish - Pimephales promelas - <=7days
96 hours
Not available.
Ecotoxicity This product shows a low bioaccumulation potential.
Continued on next page
Universal Fully FormulatedAntifreeze/ Coolant Premix 60/40
Page: 7/8Validated on 2013-04-23.
The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-productsshould at all times comply with the requirements of environmental protection and waste disposal legislation and anyregional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways,drains and sewers.
Waste information
Section 13. Disposal considerations
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Not applicable.
Class
Not a pollutant.
No placard (handling and hazard label) requi red.
Section 14. Transport information
Proper Shipping Name(Canada) TDG
Special provisions
Class 9: Miscellaneous hazardous material.
Proper Shipping Name(United States) DOT
Environmentally hazardous substance, liquid, n.o.s. (Ethylene glycol)
Not controlled under IMDG.
Not applicable.
Marine pollutant
Proper Shipping NameIMDG
No placard (handling and hazard label) requi red.
No placard (handling and hazard label) requi red.
Special provisions Not applicable.
Not applicable.Subsidiary class
-Subsidiary class
Not a TDG-controlled material.
-ClassSubsidiary class
Class
United States DOT (Classification)
IMDG Classification
Canada TDG Classification
Not applicable.
Not applicable.Not applicable.
UN numberPacking Group
Not applicable.Not applicable.UN number
Packing Group
UN 3082
IIIUN numberPacking Group
Continued on next page
Universal Fully FormulatedAntifreeze/ Coolant Premix 60/40
Page: 8/8Validated on 2013-04-23.
Special provisions In single containers of 5000 lbs capacity or less this product isexempt from DOT regulations (not regulated). Does not requirelabel or placards.Reportable Quantity (RQ)= 5000 lbs (2268 kg) (as ethylene glycolFor bulk shipments equal to or greater than Reportable Quantity(RQ), please adhere to classification as outlined in DOTClassification section.
International AirTransport Association(IATA)
For air shipment classification and associated regulations, please refer to the latest edition ofIATA Dangerous Goods Regulations.
200B
00
2
Target organ effects
U.S.A. Regulatory Lists
Section 15. Regulatory information
HCS Classification(U.S.A.)
Hazardous MaterialInformation System(U.S.A.)
National FireProtectionAssociation(U.S.A.)
Health
Specific hazard
Reactivity
FlammabilityHealth
Flammability
Reactivity
Personal protection
Class D-1B: Material causing immediate and serious toxic effects(Toxic).Class D-2A: Material causing other toxic effects (Very toxic).
WHMIS Classification(Canada)
This product and/ or all of its components are on the TSCA inventory list.
This product and/ or all of its components are on the DSL.Canada DomesticSubstances List (DSL)Status
Section 16. Other information
Validated and verified by Compliance and Technical Information Manager on 2013-04-23 ph.#905-878-5544.
Printed 2013-05-01.
Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever forthe accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certainhazards are described herein, we cannot guarantee that these are the only hazards that exist.
MSDS are available at www.recochem.com
Solvent 3139 (Petroleum Distillat)
dry cleaning safety solvent; mineral spirits; varnoline; naphtha safetysolvent; white spirits
C9~C11 paraffin(85%) + aromatics(15%)
Solvent.
8052-41-3
SOLVENT 3139
Consumer products: Various.Other non-specified industry: DRY CLEANING; SPOT AND STAINREMOVAL.
Recochem Inc.Communications and Regulatory AffairsDepartment(905) 791-1788
Recochem Inc.850 Montee de LiesseMontreal, QuebecH4T 1P4(514) 341-3550www.recochem.com
Class B-3: Combustible liquid with a flash point between 37.8°C(100°F) and 93.3°C (200°F).Class D-2B: Material causing other toxic effects (Toxic).
Material Safety Data SheetWHMIS (Pictograms) WHMIS (Classification) Personal protective equipment
Section 1. Product and Company IdentificationProduct name/ Trade name
Synonym
Chemical family
Chemical formula
Manufacturer/Supplier
Material uses
AssociatedProduct’s ItemCode
CAS #
In case ofemergency
Print date
Validation date 2014-11-20.
2014-11-24.
This product may cause mild irritatation to eyes and skin upon contact.Prolonged and repeated contact with skin can cause drying of the skin resulting in irritation and dermatitis.Inflammation of the eye is characterized by mild redness, watering, and itching.Skin inflammation is characterized by mild itching, scaling, reddening.Ingestion can cause burning sensation, vomiting, drowsiness and in severe cases pulmonary edema.Inhalation of excessive amounts may result in impairment, such as drowsiness, lack of coordination, headache andnausea.
Aspiration hazard if swallowed. Can enter lungs and cause damage. Small amounts of liquid aspirated into therespiratory system during ingestion or from vomiting may cause mild to severe pulmonary injury and possible death.
Section 2. Hazards identification
Potential Acute HealthEffects
Note to Physician
Emergency Overview
Combustible liquid and vapor. Keep away from heat, sparks and flame. Avoid breathing vapor or mist. Avoid contactwith skin and clothing. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use.
WARNING!COMBUSTIBLE LIQUID AND VAPOR.
See section 11 for more detailed information on health effects and symptoms.
Continued on next page
Solvent 3139 (Petroleum Distillat)Page: 2/7Validated on 2014-11-20.
Section 3. Composition, information on ingredients
There are no other ingredients present which, within the current knowledge of the supplier and in theconcentrations applicable, are classified as hazardous to health or the environment and hence requirereporting in this section.
Canada
Name CAS number Conc. (% w/w)
Stoddard solvent 8052-41-3 100
Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anythingby mouth to an unconscious person. Get medical attention immediately.
Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 20 minutes,occasionally lifting the upper and lower eyelids. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 20 minutes while removing contaminatedclothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attentionimmediately.
Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificialrespiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medicalattention immediately.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
Notes to physician No specific treatment. Treat symptomatically. Contact poison treatment specialistimmediately if large quantities have been ingested or inhaled.
Decomposition products may include the following materials:carbon dioxidecarbon monoxide
Use dry chemical, CO2, water spray (fog) or foam.
Container explosion may occur under fire conditions or when heated. Vapor may travel a considerable distance tosource of ignition and flash back. Vigorously supports combustion. Combustible when exposed to heat or flame.
Vapor may travel a considerable distance to source of ignition and flash back.
Section 5. Fire-fighting measures
Products of combustion
Fire-fighting media andinstructions
Fire Hazards
Explosion Hazards
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, orif water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Use spark-proof tools and explosion-proof equipment. Dispose of via a licensed waste disposal contractor.
Section 6. Accidental release measures
Small spill and leak
Continued on next page
Solvent 3139 (Petroleum Distillat)Page: 3/7Validated on 2014-11-20.
Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows.Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceousearth and place in container for disposal according to local regulations (see section 13). Use spark-proof tools andexplosion-proof equipment. Dispose of via a licensed waste disposal contractor. Contaminated absorbent materialmay pose the same hazard as the spilled product. Note: see section 1 for emergency contact information and section13 for waste disposal.
Large spill and leak
Do not store above the following temperature: 43°C (109.4°F). Store in accordance with local regulations. Store in asegregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food and drink. Eliminate all ignition sources.Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that havebeen opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Useappropriate containment to avoid environmental contamination.
Put on appropriate personal protective equipment (see section 8). Eating, drinking and smoking should be prohibited inareas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Useonly with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areasand confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from acompatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any otherignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use non-sparkingtools. Take precautionary measures against electrostatic discharges. To avoid fire or explosion, dissipate staticelectricity during transfer by grounding and bonding containers and equipment before transferring material. Emptycontainers retain product residue and can be hazardous. Do not reuse container.
Section 7. Handling and Storage
Handling
Storage
Section 8. Exposure controls/personal protection
Engineering controls
Personal protectionEyes
Body
Respiratory
Hands
United States
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits. The engineering controls also need to keep gas, vaporor dust concentrations below any lower explosive limits. Use explosion-proof ventilationequipment.
Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts. Recommended: splash goggles
Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.
Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection must bebased on known or anticipated exposure levels, the hazards of the product and the safeworking limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this inecessary. >8 hours (breakthrough time): nitrile rubber
Continued on next page
Solvent 3139 (Petroleum Distillat)Page: 4/7Validated on 2014-11-20.
Product name Exposure limits
Canada
Stoddard solvent ACGIH TLV (United States, 1/2008). TWA: 100 ppm 8 hour(s). TWA: 525 mg/m³ 8 hour(s).OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hour(s). TWA: 525 mg/m³ 8 hour(s).NIOSH REL (United States, 6/2008). TWA: 350 mg/m³ 10 hour(s). CEIL: 1800 mg/m³ 15 minute(s).OSHA PEL (United States, 11/2006). TWA: 500 ppm 8 hour(s). TWA: 2900 mg/m³ 8 hour(s).
No exposure limit value known.
Occupational exposure limits
153.9 to 202.2°C (309 to 396°F)Boiling/condensation point
Liquid.
100% (v/v), 100% (w/w)
Not available.
-58°C (-72.4°F)
0.78
5 [Air = 1]
0.29 kPa (2.2 mm Hg)
Easily soluble in the following materials: diethyl ether, n-octanol.Insoluble in the following materials: water.
Not available.
Not available.
KEROSENE-LIKE [Slight]
Not available.
Colorless.
Lower: 1%Upper: 13.3%
Closed cup: 38.85 to 42.85°C (101.9 to 109.1°F) [Tagliabue. (ASTM D56)]
232.22°C (450°F)
Combustible.
0.1 (Butyl acetate. = 1)
Kinematic: 0.0114 cm2/s (1.14 cSt)
Section 9. Physical and chemical properties
Physical State andAppearance
Molecular weight
pH
Odour
Taste
Colour
Relative density
Vapor pressure
Vapour Density
Volatility
OdourThreshold
Viscosity
Solubility
The product is:
Auto-ignition temperature
Flash point
Flammable limits
Evaporationrate
Melting/freezing point
VOC content OtherProperties
Not available.101.3 % (w/w) [ISO 11890-1]
Continued on next page
Solvent 3139 (Petroleum Distillat)Page: 5/7Validated on 2014-11-20.
Flammable in the presence of open flames, sparks and static discharge. This product is combustible if exposed to heator when in involved in a fire and in contact with combustible materials which may act as a wick.
Fire hazards in thepresence of varioussubstances
The product is stable.
Reactive with oxidizing agents.
Not available.
Section 10. Stability and reactivity
Stability
Conditions of instability
Incompatibility withvarious substancesHazardous decompositionproducts
Under normal conditions of storage and use, hazardous decomposition products shouldnot be produced.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Chronic toxicity
Carcinogenicity
Mutagenicity
Conclusion/Summary :
Teratogenicity
Conclusion/Summary :
Reproductive Toxicity
Conclusion/Summary :
IDLH :
Section 11. Toxicological Information
Canada
Not available.
Not available.
Not available.
20000 mg/m³
Conclusion/Summary Not available.
Conclusion/Summary Not available.
Conclusion/Summary Not available.
Section 12. Ecological information
For accidental discharges into the environment, see Section 6:"Accidental Release Measures" for suggestedinstructions.
Canada
:
Aquatic ecotoxicity
Ecotoxicity No known significant effects or critical hazards.
Continued on next page
Solvent 3139 (Petroleum Distillat)Page: 6/7Validated on 2014-11-20.
Conclusion/Summary :
Biodegradability
Conclusion/Summary : Not available.
Not available.
The generation of waste should be avoided or minimized wherever possible. Empty containers or liners may retainsome product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any by-productsshould at all times comply with the requirements of environmental protection and waste disposal legislation and anyregional local authority requirements. Avoid dispersal of spilled material and runoff and contact with soil, waterways,drains and sewers.
Waste information
Section 13. Disposal considerations
Disposal should be in accordance with applicable regional, national and local laws and regulations.
In containers of 450L or less this product is not classified as aDangerous Goods according to TDG exemption 1.33
Class
Not a pollutant.
Section 14. Transport information
Proper Shipping Name(Canada) TDG
Special provisions
Class 3: Flammable liquid.
PETROLEUM DISTILLATES, N.O.S.
Marine pollutant
Proper Shipping NameIMDG
No placard (handling and hazard label) requi red.
Special provisions In containers of 5 L (5Kg) capacity or less this product is classifiedas a "Consumer Commodity" under IMDG regulations.
-Subsidiary class
Class 3: Flammable liquid.
-ClassSubsidiary class
United States DOT (Classification)
IMDG Classification
Canada TDG Classification
PETROLEUM DISTILLATES, N.O.S.
UN 1268III
UN numberPacking Group
IIIUN 1268UN number
Packing Group
Continued on next page
Solvent 3139 (Petroleum Distillat)Page: 7/7Validated on 2014-11-20.
Combustible liquid.
Special provisions In containers of 450 L capacity or less this product is exempt fromDOT regulations (non regulated).
Proper Shipping Name(United States) DOT
PETROLEUM DISTILLATES, N.O.S.
-Subsidiary class
International AirTransport Association(IATA)
For air shipment classification and associated regulations, please refer to the latest edition ofIATA Dangerous Goods Regulations.
Class
UN 1268
III
UN numberPacking Group
120G
02
1
Combustible liquidTarget organ effects
U.S.A. Regulatory Lists
Section 15. Regulatory information
HCS Classification(U.S.A.)
Hazardous MaterialInformation System(U.S.A.)
National FireProtectionAssociation(U.S.A.)
Health
Specific hazard
Reactivity
FlammabilityHealth
Flammability
Reactivity
Personal protection
Class B-3: Combustible liquid with a flash point between 37.8°C(100°F) and 93.3°C (200°F).Class D-2B: Material causing other toxic effects (Toxic).
WHMIS Classification(Canada)
This product and/ or all of its components are on the TSCA inventory list.
This product and/ or all of its components are on the DSL.Canada DomesticSubstances List (DSL)Status
Section 16. Other information
Validated and verified by Compliance and Technical Information Manager on 2014-11-20 ph.#905-878-5544.
Printed 2014-11-24.
Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever forthe accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certainhazards are described herein, we cannot guarantee that these are the only hazards that exist.
MSDS are available at www.recochem.com
Material Safety Data Sheet
Synonyms
Chemical Name
Chemical Formula
Chemical Family
Material Uses
Rust Inhibitor Aerosol (1043)
Rust Inhibitor (1043)
Not applicable.
Chemical mixture.
Hydrocarbons.
Multi-purpose rust inhibitor and lubricant.
WHMIS Protective Clothing TDG Road / Rail
Section I. Product Identification and Uses
Not available.
Not available.
Not applicable.
1043
Molecular Weight Not applicable.
Supplier Emergency Number CANUTEC ( 24 HR )(613)996-6666
Rust Check Corporation6175 Danville Road, Mississauga, Ontario L5T 2H7(905) 670-5411
CI#
DSL
CAS #
Code
Product Name
Section 2. Hazardous Ingredients
1) Petroleum Distillates, Light 8052-41-3 1-5 INHALE (LD50) ppm/kg: Acute: >1400 (Rat).2) Petroleum Distillates, Heavy 8008-20-6
64742-81-03-7 ORAL (LD50) mg/kg: Acute: >5000 (Rat).
3) Petroleum Distillates, Heavy 64742-54-764742-52-5
3-7 Not available.
4) Petroleum Distillates, Light 64742-53-6 3-7 Not available.5) Propane 74-98-6 5-15 Not available.6) Isobutane 75-28-5 5-10 GAS (LC50): Acute: 142500 ppm 4 hour(s) [Rat].
Name CAS # % by Weight LC50/LD50
Physical State andAppearance
Volatility
pH (1% Soln/Water)
Odor
Color
Melting Point
Boiling Point
Taste
Vapor Pressure
Odor Threshold
Density
Vapor Density
LogKow
Ionicity (Surface ActiveAgent)
Liquid (Aerosol Concentrate).
Not available.
Aerosol Portion: Not applicable.Liquid Portion: Not available.
Red.
Not available.
Aerosol Portion: -42.1 to -0.5°C.Liquid Portion: Not available.
0.850 - 0.875 @ 20°C (Water = 1).
Greater than1.0 (Air = 1.0)
The highest known value is 7 mm of Hg (@ 20°C) (Petroleum distillate).
Not available.
Not available.
Characteristic.
Not available.
Propane: 22,000 mg/m3
Critical Temperature Not available.
Instability Temperature Not available.
Section 3. Physical Data
Evaporation Rate Aerosol Portion: faster than butyl acetate;Immediate at temperatures above -35°C.Liquid Portion: slower than butyl acetate.
Continued on Next Page
Rust Inhibitor (1043) Page Number: 2
WHMIS Protective Clothing TDG Road / Rail
A B-5 D-2B CONSUMER COMMODITY.
Dispersion Properties
Solubility
Not available.
Not available.
Conditions of Instability No additional remark.
The Product is:
Auto-ignitionTemperature
Products of Combustion
Flash Points
Extinguishing Media
Flammable Limits
Flammability
Not available.
Extremely Flammable Aerosol
These products are carbon oxides (CO, CO2), sulfur and other irritating gases.
Not available.
Not available.
SMALL FIRE: Use DRY chemicals, carbon dioxide or foam.LARGE FIRE: Use foam or water fog.Cool containing vessels with water spray in order to prevent pressure build-up, autoignition or explosion. Avoidspreading burning liquid with water used to cool containers.Self-contained respiratory protection should be provided for firefighters.
The flammability of an aerosol by WHMIS definition is determined by its flame-extension or its flashback. Theflame-extension of this product is greater than 45 cm. FIRE CODE: Level 3 Aerosol (as per NFPA 30B).Do not use in the presence of open flame or spark.Do not place in hot water or near radiators, stoves or other sources of heat.
Risks of Explosion Risk of explosion of the product in presence of mechanical impact: Do not subject aerosol cans to impact.Risk of explosion of the product in the presence of static discharge: Aerosol spray may be sensitive to staticdischarge due to flammable concentrate and flammable propellant. Vapours of this product may form aflammable/explosive mixture with air in enclosed areas and come into contact with open flames, sparks or staticdischarge.Do NOT expose aerosol containers to open flames, heat or ignition sources.Container may explode if heated.
Section 4. Fire and Explosion Data
Hazardous DecompositionProducts
Stability
Corrosivity
Products of Degradation
Reactivity
Degradability
The product is stable.
These products are carbon oxides (CO, CO2), sulfur and other irritating gases.
Not available.
Not available.
No specific information is available in our database regarding the corrosivity of this product in presence of variousmaterials.
Avoid contact with strong oxidizing agents, strong acids and strong alkalies.Keep away from heat, sparks, open flame and all possible ignition sources.
Section 5. Reactivity
Not available.
No additional remark.Conditions of Instability
Not available.Instability Temperature
Continued on Next Page
Rust Inhibitor (1043) Page Number: 3
WHMIS Protective Clothing TDG Road / Rail
A B-5 D-2B CONSUMER COMMODITY.
Toxicity to Animals
Acute Effects onHumans
Routes of Entry
Chronic Effects onHumans
Ingestion. Inhalation. Skin contact. Eye contact.
WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE.Acute oral toxicity (LD50): >8000 mg/kg [Rat]. (Petroleum distillate).Acute toxicity of the gas (LC50): 142500 ppm 4 hour(s) [Rat]. (Isobutane).Acute toxicity of the vapor (LC50): >5900 ppm 4 hour(s) [Rat]. (Petroleum distillate).
EYE CONTACT: May cause redness.SKIN CONTACT: Prolonged or repeated contact may cause irritation.INHALATION: May cause chemical pneumonitis if sprayed and mist is inhaled into lungs.INGESTION: May cause gastrointestinal irritation, nausea, vomiting and diarrhea. Aspiration of material into thelungs may cause chemical pneumonitis, which can be fatal.Can be fatal if inhaled or ingested. This product may irritate eyes and skin upon contact.
Prolonged or repeated skin contact may lead to dermatitis.
TLV Petroleum distillateTWA: 300 (ppm) from ACGIH (TLV)
PropaneSimple asphyxiant.
Consult local authorities for acceptable exposure limits.
Section 6. Toxicological Properties
Synergetic Products(Toxicologically)
Not available.
Irritation/Corrosivity Not available.
Sensitization None known.
Carcinogenic Effects No ingredients listed as carcinogens by IARC OR ACGIH.
Toxic Effects onReproduction
DEVELOPMENTAL TOXICITY: Not available.
Teratogenic Effects TERATOGENIC EFFECTS: Not available.
Mutagenic Effects MUTAGENIC EFFECTS: Not available.
Storage
Precautions
Small Spill and Leak
Large Spill and Leak
Protective Clothing
Store in a cool, dry place. Do not place in hot water or near radiators, stoves or other sources of heat. Do notpuncture or incinerate container or store at temperatures over 50°C or in direct sunlight.
Ventilate area and eliminate all sources of ignition. Keep away from heat. Absorb with an inert DRY material andplace in an appropriate waste disposal container.
Not applicable for aerosol containers.
Not applicable for aerosol containers.
Contents under pressure. Container may explode if heated. Direct inhalation of spray may be harmful. Keep out ofreach of children.
Section 7. Preventive Measures
Recommend Safety glasses, chemical resistant gloves and NIOSHApproved respirator for organic mists and vapours.
Engineering Controls Use under well-ventilated conditions.
Personal ProtectiveEquipment
Continued on Next Page
Rust Inhibitor (1043) Page Number: 4
WHMIS Protective Clothing TDG Road / Rail
A B-5 D-2B CONSUMER COMMODITY.
Waste Disposal Recycle to process, if possible. Consult your local or regional authorities. Do not dispose in sewers. When containeris empty, press button to release all pressure, then dispose of in garbage can.
Handling Do not use in the presence of open flame, sparks or ignition sources. Keep away from heat. Avoid breathing vapoursor spray mists. If ingested, seek medical advice immediately and show the container or the label. Avoid contact withskin and eyes. After handling, always wash hands thoroughly with soap and water.
Not available.Special ShippingInformation
No additional information.
No additional information.
Flush eyes with plenty of running water for at least 15 minutes, lifting upper and lower lids, occasionally. Get medicalattention.
Remove affected person to fresh air. If breathing is difficult, administer oxygen. If breathing stops give artificialrespiration. Get medical attention.
No additional information.
If swallowed, call physician or poison control centre immediately. DO NOT induce vomiting. Rinse mouth with water.Aspiration of material into lungs due to vomiting may cause chemical pneumonitis which can be fatal.
Eye Contact
Skin Contact
Hazardous Inhalation
Slight Inhalation
Slight Ingestion
Hazardous Ingestion
Wash thoroughly with soap and water. If irritation persists, get medical attention. Remove contaminated clothing andwash before reuse.
Section 8. First Aid
Hazardous SkinContact
Section 9. MSDS PreparationReferences Not available.
Validated by Regulatory Affairs Dept. on April 10, 2015
Emergency Phone: (905) 670-5411 , (613)996-6666 , 1-800-265-0790
No additional remark.
CONSUMER COMMODITY.
WHMIS WHMIS CLASS A: Compressed gas.WHMIS CLASS B-5: Flammable aerosol.WHMIS CLASS D-2B: Material causing other toxic effects (TOXIC).
Not applicable.
TDG Road /Rail
Classification
ResponsableName/Telephone No.
Continued on Next Page
Rust Inhibitor (1043) Page Number: 5
WHMIS Protective Clothing TDG Road / Rail
A B-5 D-2B CONSUMER COMMODITY.
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any ofits subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Finaldetermination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards andshould be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazardsthat exist.
Date Printed: 8/14/2014
Safety Data Sheet* Trusted Quality Since 1921 *
www.rustoleum.com
1. Identification
Product Name: ENAMEL 1-GL 2PK FLAT WHITE Revision Date: 8/14/2014
Product Identifier: 2764402 Supercedes Date: 8/13/2014
Product Use/Class: Topcoat/Alkyd
Supplier: Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA
Manufacturer: Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA
Preparer: Regulatory Department
24 Hour Hotline: 847-367-7700Emergency Telephone:
2. Hazard Identification
EMERGENCY OVERVIEW: Harmful if inhaled. Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and respiratory tract. Combustible liquid and vapor. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN.
Classification
Symbol(s) of Product
Signal Word
Danger
GHS HAZARD STATEMENTSFlammable liquid, category 4 H227 Combustible liquid
Organic Peroxide, categories C, D H242 Heating may cause a fire.
Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.
Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2B H320 Causes eye irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.
STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.
GHS PRECAUTIONARY STATEMENTSP102 Keep out of reach of children.
P103 Read label before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P220 Keep/Store away from clothing/…/combustible materials.
P234 Keep only in original container.
Page 1 / 6
Date Printed: 8/14/2014
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable forbreathing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P321 Specific treatment (see … on this label).
P332+P313 If skin irritation occurs: Get medical advice/attention.
P351 Rinse cautiously with water for several minutes.
P352 Wash with plenty of soap and water.
P362 Take off contaminated clothing and wash before reuse.
P374 Fight fire with normal precautions from a reasonable distance.
P402 Store in a dry place.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/ 122°F.
P411+P235 Store at temperatures not exceeding …°C/…°F. Keep cool.
P420 Store away from other materials.
P501 Dispose of contents/container to …
3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%Range
GHS Symbols GHS Statements
Limestone 10-251317-65-3
Stoddard Solvents 10-25 GHS02 H2248052-41-3
Titanium Dioxide 10-2513463-67-7
Mineral Spirits 10-25 GHS06 H33164742-88-7
The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: If swallowed, get medical attention.
5. Fire-fighting Measures
EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode when exposed to extreme heat due to buildup of steam. Keep containers tightly closed. Combustible liquid and vapor. No unusual fire or explosion hazards noted.
Page 2 / 6
Date Printed: 8/14/2014
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Evacuate area and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing. Avoid contact with eyes.
STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class II combustible liquids. Keep away from heat, sparks, flame and sources of ignition. Keep container closed when not in use. Avoid excess heat.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.Weight %Less Than
ACGIH TLV-TWA
ACGIH TLV-STEL
OSHA PEL-TWAOSHA PEL-
CEILING
Limestone 1317-65-3 20.0 N.E. N.E.15 mg/m3 [Total
Dust]N.E.
Stoddard Solvents 8052-41-3 20.0 100 ppm N.E. 500 ppm N.E.
Titanium Dioxide 13463-67-7 15.0 10 mg/m3 N.E.15 mg/m3 [Total
Dust]N.E.
Mineral Spirits 64742-88-7 15.0 100 ppm N.E. 100 ppm N.E.
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.
Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or in any other circumstances where air purifying respirators may not provide adequate protection.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications. Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.
Page 3 / 6
Date Printed: 8/14/2014
9. Physical and Chemical Properties
Appearance: Liquid Physical State: Liquid
Odor: Solvent Like Odor Threshold: N.E.
Relative Density: 1.359 pH: N.A.
Freeze Point, °C: N.D. Viscosity: N.D.
Solubility in Water: Negligible Partition Coefficient, n-octanol/water: No Information
Decompostion Temp., °C: No Information
Boiling Range, °C: 212 - 400 Explosive Limits, vol%: 0.7 - 8.9
Flammability: Supports Combustion Flash Point, °C: 40
Evaporation Rate: Slower than Ether Auto-ignition Temp., °C: No Information
Vapor Density: Heavier than Air Vapor Pressure: N.D.
(See "Other information" Section for abbreviation legend)
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid temperatures above 120 ° F. Avoid contact with strong acid and strong bases. Avoid all possible sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation. Substance causes moderate eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. May cause skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. May cause headaches and dizziness. High vapor concentrations are irritating to the eyes, nose, throat and lungs. Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Irritating to the nose, throat and respiratory tract. Harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause damage.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Contains Titanium Dioxide. Titanium Dioxide is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound to other materials, such as in paints during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUESThe acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I. N.I.64742-88-7 Mineral Spirits >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat
N.I. - No Information
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow to enter waterways, wastewater, soil, storm drains or sewer systems.
Page 4 / 6
Date Printed: 8/14/2014
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 1263 1263 N.A.
Proper Shipping Name: Not Regulated Paint Paint Not Regulated
Hazard Class: N.A. 3 3 N.A.
Packing Group: N.A. III III N.A.
Limited Quantity: No Yes, >5L No Yes, >5L No No
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of theSuperfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, tomeet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of theSuperfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported fromthe United States:
No TSCA components exist in this product.
Inventory Information
Country ValueUSA (TSCA) No InformationCanada (DSL) No InformationMexico(INSQ) No InformationEurope (EINECS) No InformationJapan (ENCS) No InformationPhilippines (PICCS) No InformationChina (IECSC) No InformationAustralia (AICS) No InformationKorea (KECI) No InformationNew Zealand (NZIOC) No Information
No Information
CALIFORNIA PROPOSITION 65:
Warning: This products contains a substance known to the State of California to cause cancer.
Chemical Name CAS-No.
Titanium Dioxide 13463-67-7
Page 5 / 6
Date Printed: 8/14/2014
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
Warning: This product contains a substance known to the State of California to cause birth defects or other reproductiveharm.
No Proposition 65 Reproductive Toxins exist in this product.
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 2 Physical Hazard: 0 Personal Protection: X
CANADIAN WHMIS CLASS: B3 D2A
NFPA RATINGS
Health: 2 Flammability: 2 Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L: 410
MSDS REVISION DATE: 8/14/2014
REASON FOR REVISION: No Information
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H224 Extremely flammable liquid and vapour.H331 Toxic if inhaled.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS02
GHS06
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.
Page 6 / 6
Date Printed: 8/15/2014
Safety Data Sheet* Trusted Quality Since 1921 *
www.rustoleum.com
1. Identification
Product Name: ENAMEL 1-GL 2PK HIGH GLOSS WHITE Revision Date: 8/15/2014
Product Identifier: 2766402 Supercedes Date: 8/13/2014
Product Use/Class: Topcoat/Alkyd
Supplier: Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA
Manufacturer: Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA
Preparer: Regulatory Department
24 Hour Hotline: 847-367-7700Emergency Telephone:
2. Hazard Identification
EMERGENCY OVERVIEW: Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and respiratory tract. Combustible liquid and vapor. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaled. Use ventilation necessary to keep exposures below recommended exposure limits, if any.
Classification
Symbol(s) of Product
Signal Word
Danger
GHS HAZARD STATEMENTSFlammable liquid, category 4 H227 Combustible liquid
Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.
STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.
Organic Peroxide, categories C, D H242 Heating may cause a fire.
Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.
Eye Irritation, category 2B H320 Causes eye irritation.
GHS PRECAUTIONARY STATEMENTSP102 Keep out of reach of children.
P103 Read label before use.
P202 Do not handle until all safety precautions have been read and understood.
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
Page 1 / 7
Date Printed: 8/15/2014
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P351 Rinse cautiously with water for several minutes.
P374 Fight fire with normal precautions from a reasonable distance.
P402 Store in a dry place.
P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/ 122°F.
P321 Specific treatment (see … on this label).
P352 Wash with plenty of soap and water.
P362 Take off contaminated clothing and wash before reuse.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable forbreathing.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to …
P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P220 Keep/Store away from clothing/…/combustible materials.
P420 Store away from other materials.
P411+P235 Store at temperatures not exceeding …°C/…°F. Keep cool.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%Range
GHS Symbols GHS Statements
Stoddard Solvents 25-50 GHS02 H2248052-41-3
Titanium Dioxide 10-2513463-67-7
Mineral Spirits 10-25 GHS06 H33164742-88-7
Ethylbenzene 0.1-1.0 GHS02-GHS07 H225-332100-41-4
The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: If swallowed, get medical attention.
5. Fire-fighting Measures
EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. No unusual fire or explosion hazards noted. Closed containers may explode when exposed to extreme heat due to buildup of steam. Combustible liquid and vapor.
Page 2 / 7
Date Printed: 8/15/2014
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Evacuate area and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Avoid contact with eyes, skin and clothing.
STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Keep away from heat, sparks, flame and sources of ignition. Keep container closed when not in use. Store in a dry, well ventilated place. Keep container tightly closed when not in use. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class II combustible liquids. Avoid excess heat.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.Weight %Less Than
ACGIH TLV-TWA
ACGIH TLV-STEL
OSHA PEL-TWAOSHA PEL-
CEILING
Stoddard Solvents 8052-41-3 30.0 100 ppm N.E. 500 ppm N.E.
Titanium Dioxide 13463-67-7 20.0 10 mg/m3 N.E.15 mg/m3 [Total
Dust]N.E.
Mineral Spirits 64742-88-7 15.0 100 ppm N.E. 100 ppm N.E.Ethylbenzene 100-41-4 1.0 20 ppm 125 ppm 100 ppm N.E.
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.
Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or in any other circumstances where air purifying respirators may not provide adequate protection.
SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection. Use gloves to prevent prolonged skin contact.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application. Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.
Page 3 / 7
Date Printed: 8/15/2014
9. Physical and Chemical Properties
Appearance: Liquid Physical State: Liquid
Odor: Solvent Like Odor Threshold: N.E.
Relative Density: 1.066 pH: N.D.
Freeze Point, °C: N.D. Viscosity: N.D.
Solubility in Water: Slight Partition Coefficient, n-octanol/water: No Information
Decompostion Temp., °C: No Information
Boiling Range, °C: 212 - 415 Explosive Limits, vol%: 0.7 - 8.9
Flammability: Does not Support Combustion Flash Point, °C: 40
Evaporation Rate: Slower than Ether Auto-ignition Temp., °C: No Information
Vapor Density: Heavier than Air Vapor Pressure: N.D.
(See "Other information" Section for abbreviation legend)
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid all possible sources of ignition. Avoid temperatures above 120 ° F. Avoid contact with strong acid and strong bases.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation. Substance causes moderate eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. Substance may cause slight skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. May cause headaches and dizziness. High vapor concentrations are irritating to the eyes, nose, throat and lungs. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Aspiration hazard if swallowed; can enter lungs and cause damage. Irritating to the nose, throat and respiratory tract. Harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: IARC lists Ethylbenzene as a possible human carcinogen (group 2B). Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Contains Titanium Dioxide. Titanium Dioxide is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound to other materials, such as in paints during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUESThe acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I. N.I.64742-88-7 Mineral Spirits >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat100-41-4 Ethylbenzene 3500 mg/kg Rat 15354 mg/kg Rabbit 17.2 mg/L Rat
N.I. - No Information
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow to enter waterways, wastewater, soil, storm drains or sewer systems.
Page 4 / 7
Date Printed: 8/15/2014
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 1263 1263 N.A.
Proper Shipping Name: Not Regulated Paint Paint Not Regulated
Hazard Class: N.A. 3 3 N.A.
Packing Group: N.A. III III N.A.
Limited Quantity: No Yes, >5L No Yes, >5L No No
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of theSuperfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, tomeet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of theSuperfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
Ethylbenzene 100-41-4
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported fromthe United States:
No TSCA components exist in this product.
Inventory Information
Country ValueUSA (TSCA) No InformationCanada (DSL) No InformationMexico(INSQ) No InformationEurope (EINECS) No InformationJapan (ENCS) No InformationPhilippines (PICCS) No InformationChina (IECSC) No InformationAustralia (AICS) No InformationKorea (KECI) No InformationNew Zealand (NZIOC) No Information
No Information
CALIFORNIA PROPOSITION 65:
Warning: This products contains a substance known to the State of California to cause cancer.
Chemical Name CAS-No.
Titanium Dioxide 13463-67-7Ethylbenzene 100-41-4
Page 5 / 7
Date Printed: 8/15/2014
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
Warning: This product contains a substance known to the State of California to cause birth defects or other reproductiveharm.
No Proposition 65 Reproductive Toxins exist in this product.
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 2 Physical Hazard: 0 Personal Protection: X
CANADIAN WHMIS CLASS: B3 D2A
NFPA RATINGS
Health: 2 Flammability: 2 Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L: 448
MSDS REVISION DATE: 8/15/2014
REASON FOR REVISION: No Information
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H224 Extremely flammable liquid and vapour.H225 Highly flammable liquid and vapour.H331 Toxic if inhaled.H332 Harmful if inhaled.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS02
GHS06
GHS07
Page 6 / 7
Date Printed: 8/15/2014
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.
Page 7 / 7
Date Printed: 9/17/2014
Safety Data Sheetwww.toughandeasyfloors.com
1. Identification
Product Name: ENAMEL 1-GL 2PK SEMIGL WHITESEMIGLOSS
Revision Date: 9/17/2014
Product Identifier: 7290402 Supercedes Date: 8/13/2014
Product Use/Class: Topcoat/Alkyd
Supplier: Rust-Oleum Industrial Flooring11 Hawthorn ParkwayVernon Hills, IL 60061USA
Manufacturer: Rust-Oleum Industrial Flooring11 Hawthorn ParkwayVernon Hills, IL 60061USA
Preparer: Regulatory Department
24 Hour Hotline: 847-367-7700Emergency Telephone:
2. Hazard Identification
EMERGENCY OVERVIEW: Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and respiratory tract. Combustible liquid and vapor. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaled. Flammable liquid and vapor. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Vapor Harmful. Causes Eye, Skin, Nose, and Throat Irritation.
Classification
Symbol(s) of Product
Signal Word
Danger
GHS HAZARD STATEMENTSFlammable Liquid, category 2 H225 Highly flammable liquid and vapour.
Acute Toxicity, Oral, category 5 H303 May be harmful if swallowed.
Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.
STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.
Organic Peroxide, categories C, D H242 Heating may cause a fire.
Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.
Eye Irritation, category 2B H320 Causes eye irritation.
GHS PRECAUTIONARY STATEMENTSP102 Keep out of reach of children.
P103 Read label before use.
P202 Do not handle until all safety precautions have been read and understood.
Page 1 / 7
Date Printed: 9/17/2014
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P351 Rinse cautiously with water for several minutes.
P374 Fight fire with normal precautions from a reasonable distance.
P402 Store in a dry place.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/ equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skinwith water/shower.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container to …
P321 Specific treatment (see … on this label).
P352 Wash with plenty of soap and water.
P362 Take off contaminated clothing and wash before reuse.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable forbreathing.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P220 Keep/Store away from clothing/…/combustible materials.
P410 Protect from sunlight.
P420 Store away from other materials.
P411+P235 Store at temperatures not exceeding …°C/…°F. Keep cool.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%Range
GHS Symbols GHS Statements
Stoddard Solvent 25-50 GHS02 H2248052-41-3
Titanium Dioxide 10-2513463-67-7
Limestone 10-251317-65-3
Mineral Spirits 10-25 GHS06 H33164742-88-7
Talc 2.5-1014807-96-6
Ethylbenzene 0.1-1.0 GHS02-GHS07 H225-332100-41-4
The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
Page 2 / 7
Date Printed: 9/17/2014
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.
5. Fire-fighting Measures
EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. No unusual fire or explosion hazards noted. Closed containers may explode when exposed to extreme heat due to buildup of steam. Isolate from heat, electrical equipment, sparks and open flame.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Evacuate area and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Ventilate area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Avoid contact with eyes, skin and clothing.
STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Keep away from heat, sparks, flame and sources of ignition. Keep container closed when not in use. Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign materials. Store in a dry, well ventilated place. Keep container tightly closed when not in use. Avoid excess heat. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class II combustible liquids.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.Weight %Less Than
ACGIH TLV-TWA
ACGIH TLV-STEL
OSHA PEL-TWAOSHA PEL-
CEILING
Stoddard Solvent 8052-41-3 30.0 100 ppm N.E. 500 ppm N.E.
Titanium Dioxide 13463-67-7 20.0 10 mg/m3 N.E.15 mg/m3 [Total
Dust]N.E.
Limestone 1317-65-3 15.05 mg/m3(NIOSH,
Respirable Dust)N.E.
15 mg/m3 [TotalDust]
N.E.
Mineral Spirits 64742-88-7 15.0 100 ppm N.E. 100 ppm N.E.
Talc 14807-96-6 5.0 2 mg/m3 N.E.0.1 mg/m3
[Respirable]N.E.
Ethylbenzene 100-41-4 1.0 20 ppm 125 ppm 100 ppm N.E.
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.
Page 3 / 7
Date Printed: 9/17/2014
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.
Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or in any other circumstances where air purifying respirators may not provide adequate protection.
SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection. Use gloves to prevent prolonged skin contact.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application. Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.
9. Physical and Chemical Properties
Appearance: Liquid Physical State: Liquid
Odor: Solvent Like Odor Threshold: N.E.
Relative Density: 1.194 pH: N.A.
Freeze Point, °C: N.D. Viscosity: N.D.
Solubility in Water: Negligible Partition Coefficient, n-octanol/water: No Information
Decompostion Temp., °C: No Information
Boiling Range, °C: 212 - 400 Explosive Limits, vol%: 0.7 - 8.9
Flammability: Supports Combustion Flash Point, °C: 40
Evaporation Rate: Slower than Ether Auto-ignition Temp., °C: No Information
Vapor Density: Heavier than air Vapor Pressure: N.D.
(See "Other information" Section for abbreviation legend)
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid all possible sources of ignition. Avoid temperatures above 120 ° F. Avoid contact with strong acid and strong bases.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. Causes skin irritation. Allergic reactions are possible.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. May cause headaches and dizziness. High vapor concentrations are irritating to the eyes, nose, throat and lungs. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Aspiration hazard if swallowed; can enter lungs and cause damage. Harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: IARC lists Ethylbenzene as a possible human carcinogen (group 2B). Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Contains Titanium Dioxide. Titanium Dioxide is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound to other materials, such as in paints during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
Page 4 / 7
Date Printed: 9/17/2014
ACUTE TOXICITY VALUESThe acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I. N.I.64742-88-7 Mineral Spirits >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat100-41-4 Ethylbenzene 3500 mg/kg Rat 15354 mg/kg Rabbit 17.2 mg/L Rat
N.I. - No Information
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow to enter waterways, wastewater, soil, storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 1263 1263 N.A.
Proper Shipping Name:Paint Products inLimited Quantities
Paint PaintPaint Products inLimited Quantities
Hazard Class: N.A. 3 3 N.A.
Packing Group: N.A. III III N.A.
Limited Quantity: Yes Yes Yes Yes
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of theSuperfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, tomeet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of theSuperfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
Ethylbenzene 100-41-4
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported fromthe United States:
No TSCA components exist in this product.
Page 5 / 7
Date Printed: 9/17/2014
Inventory Information
Country ValueUSA (TSCA) No InformationCanada (DSL) No InformationMexico(INSQ) No InformationEurope (EINECS) No InformationJapan (ENCS) No InformationPhilippines (PICCS) No InformationChina (IECSC) No InformationAustralia (AICS) No InformationKorea (KECI) No InformationNew Zealand (NZIOC) No Information
No Information
CALIFORNIA PROPOSITION 65:
Warning: This products contains a substance known to the State of California to cause cancer.
Chemical Name CAS-No.
Titanium Dioxide 13463-67-7Ethylbenzene 100-41-4
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
Warning: This product contains a substance known to the State of California to cause birth defects or other reproductiveharm.
No Proposition 65 Reproductive Toxins exist in this product.
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 3 Physical Hazard: 0 Personal Protection: X
CANADIAN WHMIS CLASS: B2 D2A
NFPA RATINGS
Health: 2 Flammability: 3 Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L: 440
MSDS REVISION DATE: 9/17/2014
REASON FOR REVISION: No Information
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Page 6 / 7
Date Printed: 9/17/2014
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H224 Extremely flammable liquid and vapour.H225 Highly flammable liquid and vapour.H331 Toxic if inhaled.H332 Harmful if inhaled.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS02
GHS06
GHS07
Rust-Oleum Industrial Flooring believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Industrial Flooring makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.
Page 7 / 7
Date Printed: 8/13/2014
Safety Data Sheet* Trusted Quality Since 1921 *
www.rustoleum.com
1. Identification
Product Name: ENAMEL 5-GL HIGH GLOSS BLACK Revision Date: 8/13/2014
Product Identifier: 634300 Supercedes Date: New SDS
Product Use/Class: Topcoat/Alkyd
Supplier: Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA
Manufacturer: Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA
Preparer: Regulatory Department
24 Hour Hotline: 847-367-7700Emergency Telephone:
2. Hazard Identification
EMERGENCY OVERVIEW: Harmful if inhaled. Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and respiratory tract. Combustible liquid and vapor. Flammable liquid and vapor. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. Vapor Harmful. Causes Eye, Skin, Nose, and Throat Irritation. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN.
Classification
Symbol(s) of Product
Signal Word
Danger
GHS HAZARD STATEMENTSFlammable Liquid, category 2 H225 Highly flammable liquid and vapour.
Organic Peroxide, categories C, D H242 Heating may cause a fire.
Acute Toxicity, Oral, category 5 H303 May be harmful if swallowed.
Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.
Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Eye Irritation, category 2B H320 Causes eye irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.
STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.
GHS PRECAUTIONARY STATEMENTSP102 Keep out of reach of children.
P103 Read label before use.
P202 Do not handle until all safety precautions have been read and understood.
Page 1 / 7
Date Printed: 8/13/2014
P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P220 Keep/Store away from clothing/…/combustible materials.
P234 Keep only in original container.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/ equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skinwith water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable forbreathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P321 Specific treatment (see … on this label).
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P351 Rinse cautiously with water for several minutes.
P352 Wash with plenty of soap and water.
P362 Take off contaminated clothing and wash before reuse.
P370+P378 In case of fire: Use … for extinction.
P374 Fight fire with normal precautions from a reasonable distance.
P402 Store in a dry place.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P410 Protect from sunlight.
P411+P235 Store at temperatures not exceeding …°C/…°F. Keep cool.
P420 Store away from other materials.
P501 Dispose of contents/container to …
3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%Range
GHS Symbols GHS Statements
Stoddard Solvents 25-50 GHS02 H2248052-41-3
Mineral Spirits 10-25 GHS06 H33164742-88-7
Carbon Black 1.0-2.5 GHS02 H2511333-86-4
Ethylbenzene 0.1-1.0 GHS02-GHS07 H225-332100-41-4
The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed.
Page 2 / 7
Date Printed: 8/13/2014
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.
5. Fire-fighting Measures
EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode when exposed to extreme heat due to buildup of steam. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. No unusual fire or explosion hazards noted.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Evacuate area and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Ventilate area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing. Avoid contact with eyes.
STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class II combustible liquids. Keep away from heat, sparks, flame and sources of ignition. Keep container closed when not in use. Avoid excess heat. Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign materials.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.Weight %Less Than
ACGIH TLV-TWA
ACGIH TLV-STEL
OSHA PEL-TWAOSHA PEL-
CEILING
Stoddard Solvents 8052-41-3 40.0 100 ppm N.E. 500 ppm N.E.Mineral Spirits 64742-88-7 15.0 100 ppm N.E. 100 ppm N.E.Carbon Black 1333-86-4 5.0 3 mg/m3 N.E. 3.5 mg/m3 N.E.Ethylbenzene 100-41-4 1.0 20 ppm 125 ppm 100 ppm N.E.
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.
Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or in any other circumstances where air purifying respirators may not provide adequate protection.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
Page 3 / 7
Date Printed: 8/13/2014
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications. Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.
9. Physical and Chemical Properties
Appearance: Liquid Physical State: Liquid
Odor: Solvent Like Odor Threshold: N.E.
Relative Density: 0.911 pH: N.A.
Freeze Point, °C: N.D. Viscosity: N.D.
Solubility in Water: Negligible Partition Coefficient, n-octanol/water: No Information
Decompostion Temp., °C: No Information
Boiling Range, °C: 212 - 415 Explosive Limits, vol%: 0.7 - 8.9
Flammability: Supports Combustion Flash Point, °C: 37
Evaporation Rate: Slower than Ether Auto-ignition Temp., °C: No Information
Vapor Density: Heavier than Air Vapor Pressure: N.D.
(See "Other information" Section for abbreviation legend)
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid temperatures above 120 ° F. Avoid contact with strong acid and strong bases. Avoid all possible sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. Causes skin irritation. Allergic reactions are possible.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. May cause headaches and dizziness. High vapor concentrations are irritating to the eyes, nose, throat and lungs. Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause damage.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Contains carbon black. Chronic inflammation, lung fibrosis, and lung tumors have been observed in some rats experimentally exposed for long periods of time to excessive concentrations of carbon black and several insoluble fine dust particles. Tumors have not been observed in other animal species (i.e., mouse and hamster) under similar circumstances and study conditions. Epidemiological studies of North American workers show no evidence of clinically significant adverse health effects due to occupational exposure to carbon black.
Carbon black is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC and is proposed to be listed as A4- "not classified as a human carcinogen" by the American Conference of Governmental Industrial Hygienists. Significant exposure is not anticipated during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of carbon black in the formula. IARC lists Ethylbenzene as a possible human carcinogen (group 2B).
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUESThe acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
64742-88-7 Mineral Spirits >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat100-41-4 Ethylbenzene 3500 mg/kg Rat 15354 mg/kg Rabbit 17.2 mg/L Rat
Page 4 / 7
Date Printed: 8/13/2014
N.I. - No Information
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow to enter waterways, wastewater, soil, storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: 1263 1263 1263 1263
Proper Shipping Name: Paint Paint Paint Paint
Hazard Class: 3 3 3 3
Packing Group: III III III III
Limited Quantity: No No No No
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of theSuperfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, tomeet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of theSuperfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
Ethylbenzene 100-41-4
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported fromthe United States:
No TSCA components exist in this product.
Page 5 / 7
Date Printed: 8/13/2014
Inventory Information
Country ValueUSA (TSCA) No InformationCanada (DSL) No InformationMexico(INSQ) No InformationEurope (EINECS) No InformationJapan (ENCS) No InformationPhilippines (PICCS) No InformationChina (IECSC) No InformationAustralia (AICS) No InformationKorea (KECI) No InformationNew Zealand (NZIOC) No Information
No Information
CALIFORNIA PROPOSITION 65:
Warning: This products contains a substance known to the State of California to cause cancer.
Chemical Name CAS-No.
Carbon Black 1333-86-4Ethylbenzene 100-41-4
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
Warning: This product contains a substance known to the State of California to cause birth defects or other reproductiveharm.
No Proposition 65 Reproductive Toxins exist in this product.
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 3 Physical Hazard: 0 Personal Protection: X
CANADIAN WHMIS CLASS: B2 D2A
NFPA RATINGS
Health: 2 Flammability: 3 Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L: 450
MSDS REVISION DATE: 8/13/2014
REASON FOR REVISION: No Information
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Page 6 / 7
Date Printed: 8/13/2014
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H224 Extremely flammable liquid and vapour.H225 Highly flammable liquid and vapour.H251 Self-heating: may catch fire.H331 Toxic if inhaled.H332 Harmful if inhaled.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS02
GHS06
GHS07
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.
Page 7 / 7
Date Printed: 8/14/2014
Safety Data Sheet* Trusted Quality Since 1921 *
www.rustoleum.com
1. Identification
Product Name: ENAMEL 5-GL HIGH GLOSS WHITE Revision Date: 8/14/2014
Product Identifier: 2766300 Supercedes Date: New SDS
Product Use/Class: Topcoat/Alkyd
Supplier: Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA
Manufacturer: Rust-Oleum Corporation11 Hawthorn ParkwayVernon Hills, IL 60061USA
Preparer: Regulatory Department
24 Hour Hotline: 847-367-7700Emergency Telephone:
2. Hazard Identification
EMERGENCY OVERVIEW: Harmful if inhaled. Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and respiratory tract. Combustible liquid and vapor. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN.
Classification
Symbol(s) of Product
Signal Word
Danger
GHS HAZARD STATEMENTSFlammable liquid, category 4 H227 Combustible liquid
Organic Peroxide, categories C, D H242 Heating may cause a fire.
Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.
Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2B H320 Causes eye irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.
STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.
GHS PRECAUTIONARY STATEMENTSP102 Keep out of reach of children.
P103 Read label before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P220 Keep/Store away from clothing/…/combustible materials.
P234 Keep only in original container.
Page 1 / 7
Date Printed: 8/14/2014
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable forbreathing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P321 Specific treatment (see … on this label).
P332+P313 If skin irritation occurs: Get medical advice/attention.
P351 Rinse cautiously with water for several minutes.
P352 Wash with plenty of soap and water.
P362 Take off contaminated clothing and wash before reuse.
P374 Fight fire with normal precautions from a reasonable distance.
P402 Store in a dry place.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/ 122°F.
P411+P235 Store at temperatures not exceeding …°C/…°F. Keep cool.
P420 Store away from other materials.
P501 Dispose of contents/container to …
3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%Range
GHS Symbols GHS Statements
Stoddard Solvents 25-50 GHS02 H2248052-41-3
Titanium Dioxide 10-2513463-67-7
Mineral Spirits 10-25 GHS06 H33164742-88-7
Ethylbenzene 0.1-1.0 GHS02-GHS07 H225-332100-41-4
The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: If swallowed, get medical attention.
5. Fire-fighting Measures
EXTINGUISHING MEDIA: Dry Chemical, Dry Sand, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode when exposed to extreme heat due to buildup of steam. Keep containers tightly closed. Combustible liquid and vapor. No unusual fire or explosion hazards noted.
Page 2 / 7
Date Printed: 8/14/2014
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Evacuate area and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing. Avoid contact with eyes.
STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class II combustible liquids. Keep away from heat, sparks, flame and sources of ignition. Keep container closed when not in use. Avoid excess heat.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.Weight %Less Than
ACGIH TLV-TWA
ACGIH TLV-STEL
OSHA PEL-TWAOSHA PEL-
CEILING
Stoddard Solvents 8052-41-3 30.0 100 ppm N.E. 500 ppm N.E.
Titanium Dioxide 13463-67-7 20.0 10 mg/m3 N.E.15 mg/m3 [Total
Dust]N.E.
Mineral Spirits 64742-88-7 15.0 100 ppm N.E. 100 ppm N.E.Ethylbenzene 100-41-4 1.0 20 ppm 125 ppm 100 ppm N.E.
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.
Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or in any other circumstances where air purifying respirators may not provide adequate protection.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications. Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.
Page 3 / 7
Date Printed: 8/14/2014
9. Physical and Chemical Properties
Appearance: Liquid Physical State: Liquid
Odor: Solvent Like Odor Threshold: N.E.
Relative Density: 1.066 pH: N.A.
Freeze Point, °C: N.D. Viscosity: N.D.
Solubility in Water: Negligible Partition Coefficient, n-octanol/water: No Information
Decompostion Temp., °C: No Information
Boiling Range, °C: 212 - 415 Explosive Limits, vol%: 0.7 - 8.9
Flammability: Supports Combustion Flash Point, °C: 39
Evaporation Rate: Slower than Ether Auto-ignition Temp., °C: No Information
Vapor Density: Heavier than Air Vapor Pressure: N.D.
(See "Other information" Section for abbreviation legend)
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid temperatures above 120 ° F. Avoid contact with strong acid and strong bases. Avoid all possible sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation. Substance causes moderate eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. May cause skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. May cause headaches and dizziness. High vapor concentrations are irritating to the eyes, nose, throat and lungs. Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Irritating to the nose, throat and respiratory tract. Harmful if swallowed. Aspiration hazard if swallowed; can enter lungs and cause damage.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. IARC lists Ethylbenzene as a possible human carcinogen (group 2B). Contains Titanium Dioxide. Titanium Dioxide is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound to other materials, such as in paints during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUESThe acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I. N.I.64742-88-7 Mineral Spirits >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat100-41-4 Ethylbenzene 3500 mg/kg Rat 15354 mg/kg Rabbit 17.2 mg/L Rat
N.I. - No Information
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow to enter waterways, wastewater, soil, storm drains or sewer systems.
Page 4 / 7
Date Printed: 8/14/2014
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 1263 1263 N.A.
Proper Shipping Name: Not Regulated Paint Paint Not Regulated
Hazard Class: N.A. 3 3 N.A.
Packing Group: N.A. III III N.A.
Limited Quantity: No Yes, >5L No Yes, >5L No No
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of theSuperfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, tomeet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of theSuperfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
Ethylbenzene 100-41-4
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported fromthe United States:
No TSCA components exist in this product.
Inventory Information
Country ValueUSA (TSCA) No InformationCanada (DSL) No InformationMexico(INSQ) No InformationEurope (EINECS) No InformationJapan (ENCS) No InformationPhilippines (PICCS) No InformationChina (IECSC) No InformationAustralia (AICS) No InformationKorea (KECI) No InformationNew Zealand (NZIOC) No Information
No Information
CALIFORNIA PROPOSITION 65:
Warning: This products contains a substance known to the State of California to cause cancer.
Chemical Name CAS-No.
Titanium Dioxide 13463-67-7Ethylbenzene 100-41-4
Page 5 / 7
Date Printed: 8/14/2014
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
Warning: This product contains a substance known to the State of California to cause birth defects or other reproductiveharm.
No Proposition 65 Reproductive Toxins exist in this product.
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 2 Physical Hazard: 0 Personal Protection: X
CANADIAN WHMIS CLASS: B3 D2A
NFPA RATINGS
Health: 2 Flammability: 2 Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L: 448
MSDS REVISION DATE: 8/14/2014
REASON FOR REVISION: No Information
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H224 Extremely flammable liquid and vapour.H225 Highly flammable liquid and vapour.H331 Toxic if inhaled.H332 Harmful if inhaled.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS02
GHS06
GHS07
Page 6 / 7
Date Printed: 8/14/2014
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.
Page 7 / 7
Date Printed: 8/7/2012
Material Safety Data Sheet
24 Hour Assistance:
1-847-367-7700
Rust-Oleum Corp.
www.rustoleum.com
1. Identification
8/7/2012Product Name: ENAMEL QT 4PK GLOSS WHITE Revision Date:
Identification Number: 2766504
Product Use/Class: Topcoat/Alkyd
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
Supplier: Manufacturer:
Preparer: Regulatory Department
2. Hazard Identification
EMERGENCY OVERVIEW: Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and respiratory tract.
Combustible liquid and vapor. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. May cause headaches and dizziness. High vapor
concentrations are irritating to the eyes, nose, throat and lungs.
EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed. Aspiration hazard if swallowed; can
enter lungs and cause damage.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational
overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has
been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in
humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. IARC lists
Ethylbenzene as a possible human carcinogen (group 2B). Contains Titanium Dioxide. Titanium Dioxide is listed as a Group
2B-"Possibly carcinogenic to humans" by IARC. Significant exposure is not anticipated during brush application or drying. Risk of
overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual
concentration of Titanium Dioxide in the formula.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
3. Composition/Information On Ingredients
Chemical Name CAS-No.Weight %
Less Than
ACGIH TLV-
TWA
ACGIH TLV-
STELOSHA PEL-TWA
OSHA PEL-
CEILING
Stoddard Solvents 8052-41-3 45.0 100 ppm N.E. 500 ppm N.E.
Titanium Dioxide 13463-67-7 20.0 10 mg/m3 N.E.15 mg/m3 [Total
Dust]N.E.
Xylene 1330-20-7 1.0 100 ppm 150 ppm 100 ppm N.E.
Ethylbenzene 100-41-4 1.0 20 ppm 125 ppm 100 ppm N.E.
Amorphous Silica 7631-86-9 1.0 N.E. N.E. 0.8 mg/m3 N.E.
Page 1 / 4
Date Printed: 8/7/2012
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash with soap and water. Get medical attention if irritation develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
immediate medical attention. Do NOT use mouth-to-mouth resuscitation.
FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the
lungs and cause severe lung damage. Get immediate medical attention.
5. Fire-fighting Measures
Flash Point, °F 104 (Setaflash)
EXTINGUISHING MEDIA: Dry Chemical, Foam, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible
autoignition or explosion. Evacuate area and fight fire from a safe distance.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate
closed containers.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Follow all MSDS/label precautions even after container is
emptied because it may retain product residues. Avoid breathing vapor or mist. Avoid contact with eyes.
STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Keep away from heat,
sparks, flame and sources of ignition. Keep container closed when not in use.
8. Exposure Controls/Personal Protection
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must
be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an
organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to
exceed exposure limits.
Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an
uncontrolled release, exposure levels are not known, or in any other circumstances where air purifying respirators may not provide
adequate protection.
SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or
Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal
protective equipment and its application.
Page 2 / 4
Date Printed: 8/7/2012
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking.
9. Physical and Chemical Properties
Vapor Density Heavier than Air Odor: Solvent Like
Appearance: Liquid Evaporation Rate: Slower than Ether
Solubility in Water: Slight Freeze Point: N.D.
Specific Gravity: 1.071 pH: N.D.
Physical State: Liquid
(See section 16 for abbreviation legend)
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid all possible sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits
acrid smoke and irritating fumes.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological Information
Chemical Name LD50 LC50
Stoddard Solvents >5000 mg/kg (Rat, Oral) N.E.
Titanium Dioxide >7500 mg/kg (Rat, Oral) N.E.
Xylene 4300 mg/kg (Rat, Oral) 5000 ppm (Rat, Inhalation, 4Hr)
Ethylbenzene 3500 mg/kg (Rat, Oral) N.E.
Amorphous Silica >7500 mg/kg (Rat) >250 mg/m3 (Rat, 6Hr)
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow
to enter storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) Air (IATA)International (IMDG)
Proper Shipping Name: Paint Paint Paint
Hazard Class: 3 3 3
UN Number: UN1263 UN1263 UN1263
Packing Group: III III III
Limited Quantity: No Yes Yes
15. Regulatory Information
Page 3 / 4
Date Printed: 8/7/2012
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Fire Hazard, Acute Health Hazard
SARA SECTION 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund
Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
No TSCA 12(b)components exist in this product.
International Regulations:
CANADIAN WHMIS:
This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
Canadian WHMIS Class: B3 D2A D2B
16. Other Information
HMIS Ratings:
Health: 2* Flammability: 3 Physical Hazard: 0 Personal Protection: X
NFPA Ratings:
Health: 2 Flammability: 2 Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L: 450
REASON FOR REVISION: Regulatory Update
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to beaccurate and reliable as of the date of this material safety data sheet. However, because the conditions of handling, use, andstorage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damageincurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracyor reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used withcaution. The information and recommendations in this material safety data sheet are offered for the users’ consideration andexamination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicableinternational, federal, state, and local laws and regulations.
Page 4 / 4
Date Printed: 8/7/2012
Material Safety Data Sheet
24 Hour Assistance:
1-847-367-7700
Rust-Oleum Corp.
www.rustoleum.com
1. Identification
8/7/2012Product Name: ENAMEL QT 4PK GLOSS SAFETY ORANGE Revision Date:
Identification Number: 956504
Product Use/Class: Topcoat/Alkyd
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
Supplier: Manufacturer:
Preparer: Regulatory Department
2. Hazard Identification
EMERGENCY OVERVIEW: Suspect cancer hazard. Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and
respiratory tract. Combustible liquid and vapor. Harmful if inhaled. May affect the brain or nervous system causing dizziness,
headache or nausea.
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. May cause headaches and dizziness. High vapor
concentrations are irritating to the eyes, nose, throat and lungs.
EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed. Aspiration hazard if swallowed; can
enter lungs and cause damage.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational
overexposure to solvents with permanent brain and nervous system damage. Overexposure to xylene in laboratory animals has
been associated with liver abnormalities, kidney, lung, spleen, eye and blood damage as well as reproductive disorders. Effects in
humans, due to chronic overexposure, have included liver, cardiac abnormalities and nervous system damage. IARC lists
Ethylbenzene as a possible human carcinogen (group 2B). Contains Titanium Dioxide. Titanium Dioxide is listed as a Group
2B-"Possibly carcinogenic to humans" by IARC. Significant exposure is not anticipated during brush application or drying. Risk of
overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual
concentration of Titanium Dioxide in the formula. Suspect cancer hazard--contains material which may cause cancer.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
3. Composition/Information On Ingredients
Chemical Name CAS-No.Weight %
Less Than
ACGIH TLV-
TWA
ACGIH TLV-
STELOSHA PEL-TWA
OSHA PEL-
CEILING
Stoddard Solvents 8052-41-3 35.0 100 ppm N.E. 500 ppm N.E.
Mineral Spirits 64742-88-7 15.0 100 ppm N.E. 100 ppm N.E.
Pigment Orange 5 3468-63-1 5.0 N.E. N.E.5 mg/m3
(Respirable Dust)N.E.
Xylene 1330-20-7 1.0 100 ppm 150 ppm 100 ppm N.E.
Ethylbenzene 100-41-4 1.0 20 ppm 125 ppm 100 ppm N.E.
Titanium Dioxide 13463-67-7 1.0 10 mg/m3 N.E.15 mg/m3 [Total
Dust]N.E.
Page 1 / 4
Date Printed: 8/7/2012
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash with soap and water. Get medical attention if irritation develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
immediate medical attention. Do NOT use mouth-to-mouth resuscitation.
FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the
lungs and cause severe lung damage. Get immediate medical attention.
5. Fire-fighting Measures
Flash Point, °F 104 (Setaflash)
EXTINGUISHING MEDIA: Dry Chemical, Foam, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible
autoignition or explosion. Evacuate area and fight fire from a safe distance.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate
closed containers.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Follow all MSDS/label precautions even after container is
emptied because it may retain product residues. Avoid breathing vapor or mist. Avoid contact with eyes.
STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Keep away from heat,
sparks, flame and sources of ignition. Keep container closed when not in use.
8. Exposure Controls/Personal Protection
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must
be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an
organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to
exceed exposure limits.
Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an
uncontrolled release, exposure levels are not known, or in any other circumstances where air purifying respirators may not provide
adequate protection.
SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or
Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal
protective equipment and its application.
Page 2 / 4
Date Printed: 8/7/2012
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking.
9. Physical and Chemical Properties
Vapor Density Heavier than Air Odor: Solvent Like
Appearance: Liquid Evaporation Rate: Slower than Ether
Solubility in Water: Slight Freeze Point: N.D.
Specific Gravity: 0.933 pH: N.A.
Physical State: Liquid
(See section 16 for abbreviation legend)
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid all possible sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits
acrid smoke and irritating fumes.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological Information
Chemical Name LD50 LC50
Stoddard Solvents >5000 mg/kg (Rat, Oral) N.E.
Mineral Spirits >5000 mg/kg (Rat, Oral) >1400 ppm (Rat, Inhalation, 4Hr)
Pigment Orange 5 >10,000 mg/kg (Rat, Oral) N.E.
Xylene 4300 mg/kg (Rat, Oral) 5000 ppm (Rat, Inhalation, 4Hr)
Ethylbenzene 3500 mg/kg (Rat, Oral) N.E.
Titanium Dioxide >7500 mg/kg (Rat, Oral) N.E.
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow
to enter storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) Air (IATA)International (IMDG)
Proper Shipping Name: Not Regulated Paint Paint
Hazard Class: N.A. 3 3
UN Number: N.A. UN1263 UN1263
Packing Group: N.A. III III
Limited Quantity: No Yes Yes
Page 3 / 4
Date Printed: 8/7/2012
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
SARA SECTION 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund
Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
No TSCA 12(b)components exist in this product.
International Regulations:
CANADIAN WHMIS:
This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
Canadian WHMIS Class: B3 D2B
16. Other Information
HMIS Ratings:
Health: 2* Flammability: 2 Physical Hazard: 0 Personal Protection: X
NFPA Ratings:
Health: 2 Flammability: 2 Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L: 445
REASON FOR REVISION: Regulatory Update
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to beaccurate and reliable as of the date of this material safety data sheet. However, because the conditions of handling, use, andstorage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damageincurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracyor reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used withcaution. The information and recommendations in this material safety data sheet are offered for the users’ consideration andexamination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicableinternational, federal, state, and local laws and regulations.
Page 4 / 4
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® PUMP SPRAY INSECT REPELLENT FOR SPORTSMEN (REG NO 28340 P.C.P. ACT)
Version 2.0 Print Date 06/08/2012
Revision Date 03/12/2012 MSDS Number 350000012371 SITE_FORM Number 30000000000000009857.001
1/9
1. PRODUCT AND COMPANY IDENTIFICATION
Product information
Trade name : OFF!® DEEP WOODS® PUMP SPRAY INSECT REPELLENT FOR SPORTSMEN (REG NO 28340 P.C.P. ACT)
Use of the Substance/Mixture
: Insect Repellent
Company : S.C. Johnson and Son, Limited 1 Webster Street Brantford ON N3T 5R1
Emergency telephone number
: 24 Hour Transport & Medical Emergency Phone (866) 231-5406 24 Hour International Emergency Phone (952) 852-4647 24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666
2. HAZARDS IDENTIFICATION
Emergency Overview Appearance / Odor : yellow / liquid / pleasant
Immediate Concerns
: Caution FLAMMABLE: CAUSES EYE IRRITATION. Keep away from heat, sparks and flame. Avoid contact with eyes and lips.
Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion.
Eyes : Causes:
Moderate eye irritation
Skin : May cause skin reactions in rare cases. Prolonged or repeated contact may dry skin and cause irritation.
Inhalation : May cause nose, throat, and lung irritation. Inhalation may cause central nervous system effects.
Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort. Causes headache, drowsiness or other effects to the central
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® PUMP SPRAY INSECT REPELLENT FOR SPORTSMEN (REG NO 28340 P.C.P. ACT)
Version 2.0 Print Date 06/08/2012
Revision Date 03/12/2012 MSDS Number 350000012371 SITE_FORM Number 30000000000000009857.001
2/9
nervous system.
Aggravated Medical Condition
: Persons with pre-existing skin disorders may be more susceptible to irritating effects. Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc. may be more susceptible to irritating effects Do not apply to cuts or irritated skin.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table:
Chemical Name CAS-No. Weight percent
Ethyl alcohol 64-17-5 30.00 - 60.00
N,N-Diethyl-m-toluamide 134-62-3 10.00 - 30.00
For additional information on product ingredients, see www.whatsinsidescjohnson.com.
4. FIRST AID MEASURES
Eye contact : Remove contact lenses. Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention if irritation develops and persists.
Skin contact : Wash off immediately with plenty of water. Get medical attention if irritation develops and persists. If you suspect a reaction to this product, discontinue use and remove contaminated clothing.
Inhalation : Remove to fresh air.
Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately.
5. FIREFIGHTING MEASURES
Suitable extinguishing media
: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® PUMP SPRAY INSECT REPELLENT FOR SPORTSMEN (REG NO 28340 P.C.P. ACT)
Version 2.0 Print Date 06/08/2012
Revision Date 03/12/2012 MSDS Number 350000012371 SITE_FORM Number 30000000000000009857.001
3/9
Specific hazards during firefighting
: Flammable liquid. Vapors are heavier than air and may travel to a source of ignition and flash back. Liquid run-off to sewers may create fire/explosion hazard. Burns with colourless flame. Container may melt and leak in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses.
Further information : Fight fire from maximum distance or protected area. Cool and
use caution when approaching or handling fire-exposed containers. For large quantities of flammable liquids, consider containment to prevent the spread of fire. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes.
Flash point : 25 °C
77 °F Method: Tag Closed Cup (TCC)
Lower explosion limit : Note: no data available
Upper explosion limit : Note: no data available
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Wear personal protective equipment.
Environmental precautions : Do not flush into surface water or sanitary sewer system. Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment.
Methods for cleaning up : Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site.
7. HANDLING AND STORAGE
Handling
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® PUMP SPRAY INSECT REPELLENT FOR SPORTSMEN (REG NO 28340 P.C.P. ACT)
Version 2.0 Print Date 06/08/2012
Revision Date 03/12/2012 MSDS Number 350000012371 SITE_FORM Number 30000000000000009857.001
4/9
Advice on safe handling : Avoid contact with eyes and lips. Avoid breathing vapors, mist or gas. For personal protection see section 8. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS.
Advice on protection against fire and explosion
: Keep away from heat and sources of ignition. Take measures to prevent the build up of electrostatic charge.
Storage
Requirements for storage areas and containers
: Keep away from food, drink and animal feedingstuffs. Keep container closed when not in use. Keep in a dry, cool and well-ventilated place.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
Components CAS-No. mg/m3
ppm
Non-standard
units
Basis
Ethyl alcohol 64-17-5 -
1,000 ppm
-
ACGIH STEL
Personal protective equipment
Respiratory protection
Use only with adequate ventilation. Do not spray in enclosed areas.
Hand protection
: No special requirements.
Eye protection
Safety glasses with side-shields
Skin and body protection
: No special requirements.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form : liquid
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® PUMP SPRAY INSECT REPELLENT FOR SPORTSMEN (REG NO 28340 P.C.P. ACT)
Version 2.0 Print Date 06/08/2012
Revision Date 03/12/2012 MSDS Number 350000012371 SITE_FORM Number 30000000000000009857.001
5/9
Color : yellow
Odor : pleasant
pH : 7.5
Boiling point : 75 °C
Boiling point : 167 °F
Freezing point : no data available
Flash point : 25 °C 77 °F Method: Tag Closed Cup (TCC)
Evaporation rate : no data available
Autoignition temperature : no data available
Lower explosion limit : no data available
Upper explosion limit : no data available
Vapour pressure : no data available
Density : 0.930 g/cm3 at 21 °C
Water solubility : dispersible
Partition coefficient: n-octanol/water
: no data available
10. STABILITY AND REACTIVITY
Conditions to avoid : Heat, flames and sparks.
Materials to avoid : Do not mix with oxidizing agents. Avoid contact with: Oxidizing agents Natural Rubber Plastic Aluminium
Hazardous decomposition products
: Thermal decomposition can lead to release of irritating gases and vapours.
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® PUMP SPRAY INSECT REPELLENT FOR SPORTSMEN (REG NO 28340 P.C.P. ACT)
Version 2.0 Print Date 06/08/2012
Revision Date 03/12/2012 MSDS Number 350000012371 SITE_FORM Number 30000000000000009857.001
6/9
Hazardous reactions : Stable under recommended storage conditions.
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity : LD50 estimated > 2,000 mg/kg
Acute inhalation toxicity : LC50
estimated > 2.07 mg/l
Acute dermal toxicity : LD50
estimated > 5,000 mg/kg
Chronic effects Carcinogenicity : no data available
Mutagenicity : no data available
Reproductive effects : no data available
Teratogenicity : no data available
Sensitisation : Substances is not a sensitizer.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects : no data available
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® PUMP SPRAY INSECT REPELLENT FOR SPORTSMEN (REG NO 28340 P.C.P. ACT)
Version 2.0 Print Date 06/08/2012
Revision Date 03/12/2012 MSDS Number 350000012371 SITE_FORM Number 30000000000000009857.001
7/9
13. DISPOSAL CONSIDERATIONS
PESTICIDAL WASTE: Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist.
RCRA waste class : D001 (Ignitable Waste)
14. TRANSPORT INFORMATION
Land transport
U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name UN 1993 Flammable liquids, n.o.s.
Class: 3
UN number 1993 Packaging group: II Note: Limited quantities derogation may be applicable to this product,
please check transport documents.
Sea transport
IMDG: Proper shipping name UN 1993 Flammable liquids, n.o.s. Class: 3 UN number: 1993 Packaging group: II EmS: F-E, S-E Note: Limited quantities derogation may be applicable to this product,
please check transport documents.
Air transport
ICAO/IATA:
Proper shipping name UN 1993 Flammable liquids, n.o.s. Class: 3 UN/ID No.: UN 1993 Packaging group: II Note: SC Johnson typically does not ship products via air. Refer to
IATA/ICAO Dangerous Goods Regulations for detailed instructions when shipping this item by air.
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® PUMP SPRAY INSECT REPELLENT FOR SPORTSMEN (REG NO 28340 P.C.P. ACT)
Version 2.0 Print Date 06/08/2012
Revision Date 03/12/2012 MSDS Number 350000012371 SITE_FORM Number 30000000000000009857.001
8/9
15. REGULATORY INFORMATION
Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA).
California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65.
Canada Regulations : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.
16. OTHER INFORMATION
HMIS Ratings
Health 2
Flammability 3
Reactivity 0
NFPA Ratings
Health 2
Fire 3
Reactivity 0
Special -
Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.
Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® PUMP SPRAY INSECT REPELLENT FOR SPORTSMEN (REG NO 28340 P.C.P. ACT)
Version 2.0 Print Date 06/08/2012
Revision Date 03/12/2012 MSDS Number 350000012371 SITE_FORM Number 30000000000000009857.001
9/9
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® 3 INSECT REPELLENT (REG NO. 24723 P.C.P. ACT)
Version 2.0 Print Date 09/14/2012
Revision Date 09/07/2012 MSDS Number 350000004807 SITE_FORM Number 30000000000000004116.004
1/10
1. PRODUCT AND COMPANY IDENTIFICATION
Product information
Trade name : OFF!® DEEP WOODS® 3 INSECT REPELLENT (REG NO. 24723 P.C.P. ACT)
Use of the Substance/Mixture
: Insect Repellent
Company : S.C. Johnson and Son, Limited 1 Webster Street Brantford ON N3T 5R1
Emergency telephone number
: 24 Hour Transport & Medical Emergency Phone (866) 231-5406 24 Hour International Emergency Phone (952) 852-4647 24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666
2. HAZARDS IDENTIFICATION
Emergency Overview Appearance / Odor : clear / aerosol / Alcohol Odor
Immediate Concerns
: Caution FLAMMABLE: CAUSES EYE IRRITATION. Harmful if swallowed. Keep away from heat, sparks and flame. Do not puncture or incinerate. Do not store at temperatures above 120 Deg. F (50 Deg C), as container may burst. Avoid contact with eyes and lips. Contents under pressure.
Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion.
Eyes : Causes: Moderate eye irritation
Skin : May cause skin reactions in rare cases.
Inhalation : May cause nose, throat, and lung irritation. Inhalation may cause central nervous system effects.
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® 3 INSECT REPELLENT (REG NO. 24723 P.C.P. ACT)
Version 2.0 Print Date 09/14/2012
Revision Date 09/07/2012 MSDS Number 350000004807 SITE_FORM Number 30000000000000004116.004
2/10
Ingestion : Harmful if swallowed.
Causes headache, drowsiness or other effects to the central nervous system.
Aggravated Medical Condition
: Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc. may be more susceptible to irritating effects Do not apply to cuts or irritated skin.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table:
Chemical Name CAS-No. Weight percent
Ethyl alcohol 64-17-5 30.00 - 60.00
N,N-Diethyl-m-toluamide 134-62-3 10.00 - 30.00
Butane 106-97-8 1.00 - 5.00
Propane 74-98-6 1.00 - 5.00
Isobutane 75-28-5 1.00 - 5.00
For additional information on product ingredients, see www.whatsinsidescjohnson.com.
4. FIRST AID MEASURES
Eye contact : Remove contact lenses. Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention if irritation develops and persists.
Skin contact : Wash off immediately with plenty of water. Get medical attention if irritation develops and persists. If you suspect a reaction to this product, discontinue use and remove contaminated clothing.
Inhalation : Remove to fresh air. If breathing is affected, get medical attention.
Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® 3 INSECT REPELLENT (REG NO. 24723 P.C.P. ACT)
Version 2.0 Print Date 09/14/2012
Revision Date 09/07/2012 MSDS Number 350000004807 SITE_FORM Number 30000000000000004116.004
3/10
5. FIREFIGHTING MEASURES
Suitable extinguishing media
: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Specific hazards during firefighting
: Burns with colourless flame. Aerosol Product - Containers may rocket or explode in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses.
Further information : Fight fire from maximum distance or protected area. Cool and
use caution when approaching or handling fire-exposed containers. For large quantities of flammable liquids, consider containment to prevent the spread of fire. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes.
Flash point : -7 °C
19.4 °F
Lower explosion limit : Note: no data available
Upper explosion limit : Note: no data available
NFPA Classification : NFPA Level 2 Aerosol
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Remove all sources of ignition. Wear personal protective equipment.
Environmental precautions : Do not flush into surface water or sanitary sewer system. Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment.
Methods for cleaning up : If damage occurs to aerosol can: Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site.
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® 3 INSECT REPELLENT (REG NO. 24723 P.C.P. ACT)
Version 2.0 Print Date 09/14/2012
Revision Date 09/07/2012 MSDS Number 350000004807 SITE_FORM Number 30000000000000004116.004
4/10
7. HANDLING AND STORAGE
Handling
Advice on safe handling : Do not puncture or incinerate. Avoid contact with eyes and lips. Avoid breathing vapors, mist or gas. For personal protection see section 8. Do not spray toward face. Do not use in areas without adequate ventilation. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Smoking, eating and drinking should be prohibited in the application area.
Advice on protection against fire and explosion
: Keep away from heat and sources of ignition. Take measures to prevent the build up of electrostatic charge.
Storage
Requirements for storage areas and containers
: Keep away from food, drink and animal feedingstuffs. Do not store at temperatures above 120 Deg. F (50 Deg C), as container may burst. Keep in a dry, cool and well-ventilated place.
Other data : Stable under recommended storage conditions.
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® 3 INSECT REPELLENT (REG NO. 24723 P.C.P. ACT)
Version 2.0 Print Date 09/14/2012
Revision Date 09/07/2012 MSDS Number 350000004807 SITE_FORM Number 30000000000000004116.004
5/10
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
Components CAS-No. mg/m3
ppm
Non-standard
units
Basis
Ethyl alcohol 64-17-5 -
1,000 ppm
-
ACGIH STEL
Butane 106-97-8 -
1,000 ppm
-
ACGIH TWA
Propane 74-98-6 -
1,000 ppm
-
ACGIH TWA
Isobutane 75-28-5 -
1,000 ppm
-
ACGIH TWA
Personal protective equipment
Respiratory protection
Use only with adequate ventilation. Do not spray in enclosed areas.
Hand protection
: No special requirements.
Eye protection
Safety glasses with side-shields
Skin and body protection
: No special requirements.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Smoking, eating and drinking should be prohibited in the application area.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form : aerosol
Color : clear
Odor : Alcohol Odor
pH : no data available
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® 3 INSECT REPELLENT (REG NO. 24723 P.C.P. ACT)
Version 2.0 Print Date 09/14/2012
Revision Date 09/07/2012 MSDS Number 350000004807 SITE_FORM Number 30000000000000004116.004
6/10
Boiling point : no data available
Freezing point : no data available
Flash point : -7 °C
19.4 °F
Evaporation rate : no data available
Flammability (solid, gas) : no data available
Auto-ignition temperature : no data available
Lower explosion limit : no data available
Upper explosion limit : no data available
Vapour pressure : no data available
Density : no data available
Water solubility : slightly soluble
Partition coefficient: n-octanol/water
: no data available
Viscosity, dynamic : no data available
Viscosity, kinematic : no data available
Relative vapor density : no data available
Volatile Organic Compounds Total VOC (wt. %)*
: 64.2 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations
10. STABILITY AND REACTIVITY
Conditions to avoid : Heat, flames and sparks.
Materials to avoid : Strong oxidizing agents
Hazardous decomposition products
: Thermal decomposition can lead to release of irritating gases and vapours.
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® 3 INSECT REPELLENT (REG NO. 24723 P.C.P. ACT)
Version 2.0 Print Date 09/14/2012
Revision Date 09/07/2012 MSDS Number 350000004807 SITE_FORM Number 30000000000000004116.004
7/10
Thermal decomposition : Note: no data available
Hazardous reactions : Stable under recommended storage conditions.
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity : LD50 Measured 3,735 mg/kg
Acute inhalation toxicity : LC50
Measured > 2.18 mg/l
Acute dermal toxicity : LD50
Measured > 2,000 mg/kg
Chronic effects Carcinogenicity : no data available
Mutagenicity : None Anticipated Reproductive effects : no data available
Teratogenicity : no data available
Sensitisation : Substances is not a sensitizer.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects : no data available
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® 3 INSECT REPELLENT (REG NO. 24723 P.C.P. ACT)
Version 2.0 Print Date 09/14/2012
Revision Date 09/07/2012 MSDS Number 350000004807 SITE_FORM Number 30000000000000004116.004
8/10
13. DISPOSAL CONSIDERATIONS
PESTICIDAL WASTE: Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist.
14. TRANSPORT INFORMATION
Land transport
U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name UN 1950 AEROSOLS, Flammable, 2.1
Class: 2.1
UN number 1950 Packaging group: None. Note: Limited quantities derogation may be applicable to this product,
please check transport documents.
Sea transport
IMDG: Proper shipping name UN 1950 AEROSOLS, Flammable, 2.1 Class: 2 UN number: 1950 Packaging group: None. EmS: F-D, S-U Note: Limited quantities derogation may be applicable to this product,
please check transport documents.
Air transport
ICAO/IATA: Proper shipping name UN 1950 AEROSOLS, Flammable, 2.1 Class: 2.1 UN/ID No.: UN 1950 Packaging group: None. Note: SC Johnson typically does not ship products via air. Refer to
IATA/ICAO Dangerous Goods Regulations for detailed instructions when shipping this item by air.
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® 3 INSECT REPELLENT (REG NO. 24723 P.C.P. ACT)
Version 2.0 Print Date 09/14/2012
Revision Date 09/07/2012 MSDS Number 350000004807 SITE_FORM Number 30000000000000004116.004
9/10
15. REGULATORY INFORMATION
Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA).
California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65.
Canada Regulations : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.
16. OTHER INFORMATION
HMIS Ratings
Health 2
Flammability 4
Reactivity 0
NFPA Ratings
Health 2
Fire 4
Reactivity 0
Special -
Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.
Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
OFF!® DEEP WOODS® 3 INSECT REPELLENT (REG NO. 24723 P.C.P. ACT)
Version 2.0 Print Date 09/14/2012
Revision Date 09/07/2012 MSDS Number 350000004807 SITE_FORM Number 30000000000000004116.004
10/10
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
RAID MAX® WASP & HORNET FOAM BUG KILLER (REG NO 25303 P.C.P. ACT)
Version 3.0 Print Date 11/21/2014
Revision Date 10/07/2014 MSDS Number 350000004124
1. PRODUCT AND COMPANY IDENTIFICATION
Product information
Trade name : RAID MAX® WASP & HORNET FOAM BUG KILLER (REG NO 25303 P.C.P. ACT)
Use of the Substance/Mixture
: Insecticide
Company : S.C. Johnson and Son, Limited 1 Webster Street Brantford ON N3T 5R1
Emergency telephone number
: 24 Hour Transport & Medical Emergency Phone (866) 231-5406 24 Hour International Emergency Phone (952) 852-4647 24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666
2. HAZARDS IDENTIFICATION
Emergency OverviewAppearance / Odor : off-white / aerosol / characteristic
Immediate Concerns
: Warning Avoid contact with skin, eyes and clothing. Avoid breathing vapours, mist or gas. Keep away from heat, sparks and flame. Harmful if absorbed through skin. Toxic by inhalation. Contents under pressure. Do not puncture or incinerate. Do not store at temperatures above 120 Deg. F (50 Deg C), as container may burst. May be harmful if swallowed.
Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion.
Eyes : May cause:
Mild eye irritation
Skin : May cause skin reactions in rare cases. Harmful if absorbed through skin. May cause systemic effects.
Inhalation : Excessive exposures may affect human health, as follows:
1/9
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
RAID MAX® WASP & HORNET FOAM BUG KILLER (REG NO 25303 P.C.P. ACT)
Version 3.0 Print Date 11/21/2014
Revision Date 10/07/2014 MSDS Number 350000004124
Harmful if inhaled. May cause systemic effects. Inhalation may cause central nervous system effects.
Ingestion : Aspiration hazard if swallowed - can enter lungs and cause damage. Causes headache, drowsiness or other effects to the central nervous system.
Aggravated Medical Condition
: None known.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table:
Chemical Name CAS-No. Weight percent Ethyl alcohol 64-17-5 10.00 - 30.00 Isobutane 75-28-5 5.00 - 10.00 Propane 74-98-6 5.00 - 10.00 n-Octyl bicycloheptene dicarboximide
113-48-4 0.10 - 1.00
Permethrin 52645-53-1 0.10 - 1.00 d-(Cis/Trans) Allethrin 584-79-2 0.0001 - 0.10
For additional information on product ingredients, see www.whatsinsidescjohnson.com. 4. FIRST AID MEASURES
Eye contact : Rinse with plenty of water. Get medical attention if irritation develops and persists.
Skin contact : Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention immediately. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Inhalation : Remove to fresh air. If breathing is affected, get medical attention. If not breathing, give artificial respiration. Get medical attention immediately.
Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately.
2/9
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
RAID MAX® WASP & HORNET FOAM BUG KILLER (REG NO 25303 P.C.P. ACT)
Version 3.0 Print Date 11/21/2014
Revision Date 10/07/2014 MSDS Number 350000004124
5. FIREFIGHTING MEASURES
Suitable extinguishing media
: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Specific hazards during firefighting
: Aerosol Product - Containers may rocket or explode in heat of fire. Container may melt and leak in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses. Burns with colourless flame.
Further information : Fight fire from maximum distance or protected area. Cool and
use caution when approaching or handling fire-exposed containers. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes.
Flash point : < -7 °C
< 19.4 °F Method: Tag Closed Cup (TCC) Note: Propellant
Lower explosion limit : Note: No data available
Upper explosion limit : Note: No data available
NFPA Classification : NFPA Level 1 Aerosol 6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Remove all sources of ignition. Wear personal protective equipment.
Environmental precautions : Do not flush into surface water or sanitary sewer system. Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment.
Methods for cleaning up : Soak up with inert absorbent material. If damage occurs to aerosol can: Sweep up and shovel into suitable containers for disposal. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Dike large spills. Clean residue from spill site.
3/9
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
RAID MAX® WASP & HORNET FOAM BUG KILLER (REG NO 25303 P.C.P. ACT)
Version 3.0 Print Date 11/21/2014
Revision Date 10/07/2014 MSDS Number 350000004124
7. HANDLING AND STORAGE
Handling
Advice on safe handling : Do not puncture or incinerate. Do not enter places where used or stored until adequately ventilated. Avoid breathing vapours, mist or gas. Do not spray toward face. Do not use in areas without adequate ventilation. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Smoking, eating and drinking should be prohibited in the application area.
Advice on protection against fire and explosion
: Keep away from heat and sources of ignition.
Storage
Requirements for storage areas and containers
: Do not store at temperatures above 120 Deg. F (50 Deg C), as container may burst. Keep away from food, drink and animal feedingstuffs. Keep in a dry, cool and well-ventilated place.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
Components CAS-No. mg/m3
ppm
Non-standard
units
Basis
Ethyl alcohol 64-17-5 -
1,000 ppm
-
ACGIH STEL
Isobutane 75-28-5 -
1,000 ppm
-
ACGIH STEL
Propane 74-98-6 -
1,000 ppm
-
ACGIH TWA
Personal protective equipment
Respiratory protection
Substantial amounts of mist/vapors can be controlled with local exhaust ventilation or respiratory protection. Do not spray in enclosed areas.
4/9
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
RAID MAX® WASP & HORNET FOAM BUG KILLER (REG NO 25303 P.C.P. ACT)
Version 3.0 Print Date 11/21/2014
Revision Date 10/07/2014 MSDS Number 350000004124
Hand protection
: Rubber gloves
Eye protection
No special requirements.
Skin and body protection
: No special requirements.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Smoking, eating and drinking should be prohibited in the application area.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form : aerosol
Color : off-white
Odor : characteristic
pH : 8.6 - 9.5
Melting point : No data available
Boiling point : 78 - 100 °C
Freezing point : No data available
Flash point : < -7 °C < 19.4 °F Method: Tag Closed Cup (TCC) Propellant
Evaporation rate : No data available
Auto-ignition temperature : No data available
Lower explosion limit : No data available
Upper explosion limit : No data available
Vapour pressure : estimated86.66 hPa
Density : 0.88 - 0.92 g/cm3
Water solubility : negligible
Partition coefficient: n-octanol/water
: No data available
5/9
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
RAID MAX® WASP & HORNET FOAM BUG KILLER (REG NO 25303 P.C.P. ACT)
Version 3.0 Print Date 11/21/2014
Revision Date 10/07/2014 MSDS Number 350000004124
Volatile Organic Compounds Total VOC (wt. %)*
: 28.5 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations
10. STABILITY AND REACTIVITY
Conditions to avoid : Heat, flames and sparks.
Materials to avoid : Strong acids Do not mix with oxidizing agents.
Materials to avoid : Strong oxidizing agents Do not mix with bleach or any other household cleaners. Strong bases
Hazardous decomposition products
: Thermal decomposition can lead to release of irritating gases and vapours.
Hazardous reactions : Stable under recommended storage conditions.
Hazardous reactions : If accidental mixing occurs and toxic gas is formed, exit area
immediately. Do not return until well ventilated.
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity : LD50 estimated 500 - 5,000 mg/kg
Acute inhalation toxicity : No data available
Acute dermal toxicity : No data available
Chronic effects Carcinogenicity : None Anticipated Mutagenicity : None Anticipated Reproductive effects : None Anticipated
6/9
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
RAID MAX® WASP & HORNET FOAM BUG KILLER (REG NO 25303 P.C.P. ACT)
Version 3.0 Print Date 11/21/2014
Revision Date 10/07/2014 MSDS Number 350000004124
Teratogenicity : None Anticipated
Sensitisation : No data available
12. ECOLOGICAL INFORMATION
Ecotoxicity effects : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
13. DISPOSAL CONSIDERATIONS
PESTICIDAL WASTE: Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist.
14. TRANSPORT INFORMATION
Land transport
U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name AEROSOLS, Flammable, 2.1 Class: 2.1 UN number 1950 Packaging group: None. Note: SC Johnson ships this product as "Limited Quantity" when the
container quantity value is 1 Liter or less.
Sea transport
IMDG: Proper shipping name AEROSOLS, Flammable, 2.1 Class: 2 UN number: 1950 Packaging group: None. EmS: F-D, S-U Note: SC Johnson ships this product as "Limited Quantity" when the
container quantity value is 1 Liter or less.
Air transport
ICAO/IATA:
7/9
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
RAID MAX® WASP & HORNET FOAM BUG KILLER (REG NO 25303 P.C.P. ACT)
Version 3.0 Print Date 11/21/2014
Revision Date 10/07/2014 MSDS Number 350000004124
Proper shipping name AEROSOLS, Flammable, 2.1 Class: 2.1 UN/ID No.: UN 1950 Packaging group: None. Note: SC Johnson typically does not ship products via air. Refer to
IATA/ICAO Dangerous Goods Regulations for detailed instructions when shipping this item by air.
15. REGULATORY INFORMATION
Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA).
California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65.
Canada Regulations : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.
16. OTHER INFORMATION
HMIS Ratings Health 2
Flammability 4
Reactivity 0
NFPA Ratings Health 2
Fire 4
Reactivity 0
Special -
This information is being provided in accordance with Occupational Safety and Health Administration (OSHA) and Canada’s Workplace Hazard Material Information System (WHMIS) regulations. The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use. Further information
8/9
Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
RAID MAX® WASP & HORNET FOAM BUG KILLER (REG NO 25303 P.C.P. ACT)
Version 3.0 Print Date 11/21/2014
Revision Date 10/07/2014 MSDS Number 350000004124
This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by SC Johnson Global Safety Assessment &
Regulatory Affairs (GSARA)
9/9
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
WINDEX® ORIGINAL GLASS CLEANER
Version 1.1 Print Date 12/05/2012
Revision Date 12/05/2012 MSDS Number 350000014153
1/7
1. PRODUCT AND COMPANY IDENTIFICATION
Product information
Trade name : WINDEX® ORIGINAL GLASS CLEANER
Use of the Substance/Mixture
: Hard Surface Cleaner
Company : S.C. Johnson and Son, Limited 1 Webster Street Brantford ON N3T 5R1
Emergency telephone number
: 24 Hour Transport & Medical Emergency Phone (866) 231-5406 24 Hour International Emergency Phone (952) 852-4647 24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666
2. HAZARDS IDENTIFICATION
Emergency Overview Appearance / Odor : blue / liquid / pleasant
Immediate Concerns
: Avoid contact with skin, eyes and clothing.
Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion.
Eyes : May cause:
Mild eye irritation
Skin : Prolonged or repeated contact may dry skin and cause irritation.
Inhalation : No adverse effects expected when used as directed.
Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort.
Aggravated Medical Condition
: Persons with pre-existing skin disorders may be more susceptible to irritating effects.
3. COMPOSITION/INFORMATION ON INGREDIENTS
This product does not contain hazardous chemicals at or above a reportable level as defined by OSHA 29 CFR 1910.1200 or Canadian Controlled Products Regulations.
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
WINDEX® ORIGINAL GLASS CLEANER
Version 1.1 Print Date 12/05/2012
Revision Date 12/05/2012 MSDS Number 350000014153
2/7
For additional information on product ingredients, see www.whatsinsidescjohnson.com.
4. FIRST AID MEASURES
Eye contact : Rinse with plenty of water. Get medical attention if irritation develops and persists.
Skin contact : Rinse with plenty of water. Get medical attention if irritation develops and persists.
Inhalation : No special requirements
Ingestion : Rinse mouth with water.
5. FIREFIGHTING MEASURES
Suitable extinguishing media
: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Specific hazards during firefighting
: Container may melt and leak in heat of fire.
Further information : Although this product has a flash point below 200 Deg F, it is
an aqueous solution containing an alcohol and does not sustain combustion. Fight fire with normal precautions from a reasonable distance. Standard procedure for chemical fires. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes.
Flash point : 85 °C
185 °F Method: ASTM D 56
Lower explosion limit : Note: no data available
Upper explosion limit : Note: no data available
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : No special precautions required.
Environmental precautions : Outside of normal use, avoid release to the environment.
Methods for cleaning up : Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Dike large spills.
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
WINDEX® ORIGINAL GLASS CLEANER
Version 1.1 Print Date 12/05/2012
Revision Date 12/05/2012 MSDS Number 350000014153
3/7
Clean residue from spill site.
7. HANDLING AND STORAGE
Handling
Advice on safe handling : Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS.
Advice on protection against fire and explosion
: Normal measures for preventive fire protection.
Storage
Requirements for storage areas and containers
: Keep container closed when not in use. Keep in a dry, cool and well-ventilated place.
Other data : Stable under normal conditions.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
ACGIH or OSHA exposure limits have not been established for this product or reportable ingredients unless noted in the table above.
Personal protective equipment
Respiratory protection
No personal respiratory protective equipment normally required.
Hand protection
: No special requirements.
Eye protection
No special requirements.
Skin and body protection
: No special requirements.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form : liquid
Color : blue
Odor : pleasant
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
WINDEX® ORIGINAL GLASS CLEANER
Version 1.1 Print Date 12/05/2012
Revision Date 12/05/2012 MSDS Number 350000014153
4/7
pH : 10.7
Boiling point : no data available
Freezing point : no data available
Flash point : 85 °C 185 °F Method: ASTM D 56
Evaporation rate : no data available
Flammability (solid, gas) : Does not sustain combustion.
Auto-ignition temperature : no data available
Lower explosion limit : no data available
Upper explosion limit : no data available
Vapour pressure : no data available
Density : 0.997 g/cm3 at 20 °C
Water solubility : soluble
Viscosity, dynamic : no data available
Viscosity, kinematic : no data available
Volatile Organic Compounds Total VOC (wt. %)*
: 0.5 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations
10. STABILITY AND REACTIVITY
Conditions to avoid : Direct sources of heat.
Materials to avoid : Strong oxidizing agents
Hazardous decomposition products
: Thermal decomposition can lead to release of irritating gases and vapours.
Hazardous reactions : Stable under recommended storage conditions.
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity : LD50
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
WINDEX® ORIGINAL GLASS CLEANER
Version 1.1 Print Date 12/05/2012
Revision Date 12/05/2012 MSDS Number 350000014153
5/7
estimated > 5,000 mg/kg
Acute inhalation toxicity : LC50
estimated > 2.58 mg/l
Acute dermal toxicity : LD50
estimated > 5,000 mg/kg
Chronic effects Carcinogenicity : no data available
Mutagenicity : no data available
Reproductive effects : no data available
Teratogenicity : no data available
Sensitisation : Not known to be a sensitizer.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects : no data available
13. DISPOSAL CONSIDERATIONS
Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist.
14. TRANSPORT INFORMATION
Land transport
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
WINDEX® ORIGINAL GLASS CLEANER
Version 1.1 Print Date 12/05/2012
Revision Date 12/05/2012 MSDS Number 350000014153
6/7
U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Sea transport
IMDG: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Air transport
ICAO/IATA:
Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None.
15. REGULATORY INFORMATION
Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA).
California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Canada Regulations : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.
16. OTHER INFORMATION
HMIS Ratings
Health 1
Flammability 2
Reactivity 0
NFPA Ratings
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
WINDEX® ORIGINAL GLASS CLEANER
Version 1.1 Print Date 12/05/2012
Revision Date 12/05/2012 MSDS Number 350000014153
7/7
Health 1
Fire 2
Reactivity 0
Special -
Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.
Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)
3306
SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Power Cleanse PRODUCT IDENTIFIER CODE(S): 3306/3307 PRODUCT RECOMMENDED/INTENDED USE: Industrial-Grade Hand Cleaner MANUFACTURER/SUPPLIER: TEXAS REFINERY CORP. ADDRESS: 840 N. MAIN STREET FORT WORTH, TX 76164 GENERAL INFORMATION: 817-332-1161 24 HR. EMERGENCY PHONE NUMBER: CHEMTREC 1-800-424-9300
SECTION 2 HAZARDS IDENTIFICATION This material is not considered to be hazardous according to regulatory guidelines (See Section 15.)
SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS
Component CAS Number Weight %
Petroleum Distillate 64742-15-0 35-50
Amyl Acetate 628-63-7 < 2.0
Isopropanol 67-63-0 < 2.0
Triethanolamine 102-71-6 < 1.0
Nonylphenol ethoxylate 26027-38-3 < 3.0
Petroleum Hydrocarbon Oil 64741-89-5 10-20
(See Section 8 for Exposure Limits)
SECTION 4 FIRST AID MEASURES PRINCIPAL ROUTES OF EXPOSURE: Eyes and Ingestion EFFECTS OF OVEREXPOSURE: May cause mild, transient irritation to eyes. If ingested may cause abdominal pain, nausea, vomiting and/or diarrhea. EYE: Rinse cautiously with water for several minutes. If irritation persists get medical attention. SKIN: N/A. This product is an industrial-grade hand cleaner. INGESTION: Do NOT induce vomiting. Get medical attention. INHALATION: N/A. No inhalation hazards expected from this product under normal conditions of use and storage. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Unknown. NOTES TO PHYSICIAN: None.
SECTION 5 FIRE FIGHTING MEASURES FIRE CLASSIFICATION: GHS Non-flammable. Non-Combustible. NFPA RATINGS: HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0 FLASH POINT (°F/C): > 212/100 LOWER EXPLOSION LIMIT/UPPER EXPLOSION LIMIT: Not established. OSHA FLAMMABILITY CLASSIFICATION: Non-flammable. Non-combustible. SUITABLE EXTINGUISHING MEDIA: If a fire occurs in which this product is involved or is in the vicinity, use an NFPA Class B extinguisher (carbon dioxide or foam) for Class III B Liquid Fires for extinction.
3306
FIREFIGHTING PROCEDURES: Water spray may be used to cool exposed containers. Use fog nozzles and self-contained breathing apparatus (SCBA). PROTECTION OF FIRE FIGHTERS: Chemical fire- wear self-contained breathing apparatus (SCBA). UNUSUAL FIRE AND EXPLOSION HAZARDS: None. COMBUSTION PRODUCTS: Oxides of carbon and nitrogen.
SECTION 6 ACCIDENTAL RELEASE MEASURES PERSONAL PROTECTION: Wear appropriate personal protective equipment when cleaning up spills (See Section 8). Keep unnecessary people away; isolate hazard area and deny entry. PROCEDURES: Mop up with absorbent material and dispose of in approved containers in accordance with local, State and Federal pollution control regulations.
SECTION 7 HANDLING AND STORAGE HANDLING: Avoid contact with eyes. For industrial use only. STORAGE: Store away from strong oxidizers and at temperatures not exceeding 120°F (49°C). Keep out of reach of children. Do not flame cut, weld or braze on or around open containers.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: Not required under normal conditions of use. PERSONAL PROTECTIVE EQUIPMENT: Not required under normal conditions of use. EYE/FACE PROTECTION: Not required under normal conditions of use. SKIN PROTECTION: Not required under normal conditions of use. RESPIRATORY PROTECTION: Not required under normal conditions of use. OCCUPATIONAL EXPOSURE LIMITS:
Component PEL TLV
Petroleum Distillate 400 ppm 300 ppm
Amyl Acetate 100 ppm 100 ppm
Isopropanol 400 ppm 400 ppm
Triethanolamine Not established 100 ppm
Nonylphenol ethoxylate Not established Not established
Petroleum hydrocarbon oil 5 mg/m3 5 mg/m3
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE (Color and physical state): Thick creamy pink liquid ODOR: Banana odor. pH: Not determined. MELTING POINT/FREEZING POINT: Not determined. BOILING POINT (OF/C): 212/100 FLASH POINT (OF/C): > 212/100 EVAPORATION RATE (Butyl Acetate =1): < 1.0 FLAMMABILITY: Non-flammable. Non-combustible. UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: Not established. VAPOR PRESSURE (mm Hg): 15.8 VAPOR DENSITY (Air=1): 5.0 SOLUBILITY (ies) in water: Dispersable.
3306
SPECIFIC GRAVITY (H2O=1): 0.871 PERCENT VOLATILE BY VOLUME: Not established.
SECTION 10 STABILITY AND REACTIVITY CHEMICAL STABILITY: This material is considered stable under specified conditions of storage, shipment and/or use. INCOMPATIBILITY WITH OTHER MATERIALS: Strong oxidizers. CONDITIONS TO AVOID: None known. HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of carbon and nitrogen. HAZARDOUS REACTION/ POLYMERIZATION: Will not occur.
SECTION 11 TOXICOLOGICAL INFORMATION ACUTE TOXICITY VALUES: Petroleum Distillates: Oral LD50 (Rat) = > 5000 mg/kg Dermal LD50 (Rabbit) = > 2000 mg/kg Inhalation LC50 (Rat) = 5000 ppm/4 H Amyl Acetate: Oral LD50 (Rat) = 6500 mg/kg Dermal LD50 (Rabbit) = No data available. Inhalation LC50 (Rat) = No data available. Isopropanol: Oral LD50 (Rat) = 3600 mg/kg Dermal LD50 (Rabbit) = 12,800 mg/kg Inhalation LC50 (Rat) = 16,000 ppm/8 H Triethanolamine: Oral LD50 (Rabbit) = 2200 mg/kg Dermal LD50 (Rabbit) = No data available. Inhalation LC50 (Rat) = No data available. Nonylphenol ethoxylate: Oral LD50 (Rat) = 4000 mg/kg Dermal LD50 (Rabbit) = No data available. Inhalation LC50 (Rat) = No data available. Petroleum Hydrocarbon oil: Oral LD50 (Rat) = > 5000 mg/kg Dermal LD50 (Rabbit) = > 2000 mg/kg Inhalation LC50 (Rat) = 5000 ppm/4 H IRRITANT EFFECT ON THE SKIN: None. IRRITANT EFFECT ON THE EYES: None. SENSITIZATION: None. MUTAGENICITY: No specific data available. CARCINOGENICITY: None known. REPROTOXICITY/TERATOGENICITY: None known. FURTHER INFORMATION ON TOXICOLOGY: None.
SECTION 12 ECOLOGICAL INFORMATION This product is not expected to be harmful to aquatic organisms based on data for the components. INFORMATION ON ELIMINATION (PERSISTENCE AND DEGRADABILITY) BIOACCUMULATION: No specific data available ECOTOXICOLOGICAL EFFECTS: No specific data available FURTHER INFORMATION ON ECOLOGY: Do not allow to contaminate the soil, waterways or waste water.
3306
SECTION 13 DISPOSAL CONSIDERATIONS PROCEDURES: Federal, State and/or Local approved disposal. CONTAINER CLEANING AND DISPOSAL: Federal, State and/or Local approved disposal for alkaline cleaning compounds.
SECTION 14 TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION (DOT) SHIPPING DESCRIPTION: N/A INTERNATIONAL MARITIME ORGANIZATION (IMDG) SHIPPING DESCRIPTION: N/A FREIGHT CLASSIFICATION: Cleaning, Scouring or Washing Compound, NOI (NMFC48580 SUB 3 CLASS 55)
SECTION 15 REGULATORY INFORMATION TOXIC SUBSTANCES CONTROL ACT (TSCA): All hazardous components of this product are listed on the TSCA inventory. CLEAN WATER ACT (CWA): If spilled into waters of the U.S., this product may be reportable under the Clean Water Act. CLEAN AIR ACT (CAA): This product is not considered a hazardous substance under the Clean Air Act. EPCRA 311/312 CATEGORIES: 1. IMMEDIATE (ACUTE) HEALTH EFFECTS 2. DELAYED (CHRONIC) HEALTH EFFECTS 3. FIRE HAZARD 4. SUDDEN RELEASE OF PRESSURE HAZARD 5. REACTIVITY HAZARD THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICAL(S) SUBJECT TO REPORTING REQUIREMENTS OF SARA SECTION 313 (40 CRF 372): N/A THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR REPRODUCTIVE HARM: N/A OSHA HAZARD COMMUNICATION STANDARD: When used for its intended purposes, this material is not classified as hazardous in accordance with OSHA 29 CFR 1910.1200. CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS): N/A. This product is not regulated by WHMIS (Canada). EUROPEAN INVENTORY OF EXISTING CHEMICALS (EINECS): N/A. This product is not regulated under EU.
SECTION 16 OTHER INFORMATION REVISION INDICATOR: New SDS compliant with GHS AND OSHA. DATE OF REVISION: 11/15/2013 SUPERSEDES: 03/05/2013
DISCLAIMER: THIS INFORMATION IS BEING SUPPLIED TO YOU UNDER OSHA "RIGHT TO KNOW" REGULATION 29 CFR 1910.1200 AND IS OFFERED IN GOOD FAITH. THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA
AVAILABLE TO US AND IS BELIEVED TO BE TRUE AND ACCURATE TO THE BEST OF OUR KNOWLEDGE. TEXAS
REFINERY CORP. MAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OF THIS DATE, THE
HAZARDS CONNECTED WITH THE USE OF THE MATERIAL, OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
TEXAS REFINERY CORP. MAKES NO WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, CONCERNING THE SAFE USE OF
THIS MATERIAL IN YOUR PROCESS OR IN COMBINATION WITH OTHER SUBSTANCES. TEXAS REFINERY CORP. ASSUMES
NO RESPONSIBILITY FOR DAMAGE OR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN.
The Procter & Gamble Company P&G Household Care Fabric & Home Care Innovation Center 5299 Spring Grove Avenue Cincinnati, OH 45217-1087
MATERIAL SAFETY DATA SHEET
MSDS #: RQ1000484 Issue Date: March 11, 2013 Supersedes: N/A Issue Date: March 4, 2010
SECTION I - PRODUCT IDENTIFICATION Identity: Disinfecting Multi-Purpose Liquid Hard Surface Cleaner Finished Product Brands: Mr. Clean Antibacterial Multi-Surfaces and Mr. Clean Disinfectant Multi-
Surfaces Liquid (Summer Citrus scent) P&G Telephone Number: 1-800-867-2532 or call Local Poison Control Center or your physician.
SECTION II - HAZARDS IDENTIFICATION Potential Health Hazards (Acute and Chronic): (See Section 11 for more information) Ingestion: May be harmful if swallowed. Eye Contact: Mild eye irritant. Skin Contact: Mild skin irritant. Inhalation: N/A Signs and Symptoms of Exposure: Ingestion: Oral ingestion may result in transient system effects (ataxia and muscle weakness) and/or gastrointestinal irritation with nausea, vomiting or diarrhea. This product contains alcohol ethoxylates. Large ingestions (>2 ml/kg) may also cause symptoms of alcohol-like intoxication, lack of coordination, drowsiness, inarticulateness, headache or ataxia. Alcohol ethoxylates may contribute to central nervous system symptoms. Eye Contact: Instillation into the eye may result in transient superficial effects similar to those produced by mild toilet soaps and detergents. Skin Contact: Use on irritated or extremely dry skin may aggravate the existing condition. Inhalation: N/A Medical Conditions Generally Known to be Aggravated by Exposure: N/A Potential Environmental Effects: (See Section 12 for more information)
SECTION III - COMPOSITION AND INGREDIENTS Active ingredient listed on the product label is the following: Sodium hydroxide .......................................................................................................... 0.34% Other Ingredients (includes grease cutting agents) ...................................................... 99.66% Total ............................................................................................................................ 100.00% Hazardous Ingredients as defined by OSHA, 29 CFR 1910.1200. and/or WHMIS under the HPA:
Chemical Name Common Name CAS No. Composition Range
TLV/LD50/LC50
Alcohol ethoxylates Nonionic surfactants
Confidential 3-7% LD50 (rat, oral) = 200-2000 mg/kg
SECTION IV – FIRST AID INFORMATION
First Aid Procedures: Ingestion: Drink 1-2 glasses of water and call a physician or poison control center (product contains alcohol ethoxylates) – do not induce vomiting unless they tell you to do so. Eye Contact: Hold eyes open and rinse gently with water for 15-20 min. If wearing contacts, remove lenses after first 5 min., and continue rinsing. If irritation persists, call a physician. Skin: Thoroughly wash exposed area with soap and water and discontinue use. Remove contaminated clothing. If irritation persists, call a physician. Inhalation: Remove to fresh air. Note to Physician: (if applicable): N/A Other: Consumer product package has the following precautionary statement: “KEEP OUT OF REACH OF CHILDREN. CAUTION: Eye Irritant. Avoid contact with eyes.
SECTION V - FIRE FIGHTING INFORMATION Flash Point (Method Used): >200°F / >93.3°C (ASTM D-93 Pensky-Martens Closed Cup). Flammable Properties: Upper Flammable Limit: N/A Lower Flammable Limit: N/A Explosive Limits: UEL: N/A LEL: N/A Auto-ignition Temperature: N/A Hazardous Combustion Products: None known. Explosion Data (Sensitivity to Mechanical Impact): N/A Explosion Data (Sensitivity to Static Discharge): N/A Extinguishing Media: Suitable: CO2, water, dry chemical or “alcohol” foam. Use water to keep fire-exposed container cool. Unsuitable: N/A Protection of Firefighters: Specific Hazards Arising from the Material: None Protective Equipment and Precautions for Firefighters: No unusual precautions necessary.
SECTION VI - ACCIDENTAL RELEASE MEASURES Personal Precautions: See Section VIII below. Environmental Precautions: DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE/PROVINCIAL AND LOCAL REGULATIONS. Do not landfill. Small (household) quantities may be disposed of via sewer with large quantities of water. Incineration is preferred where permitted. Methods for Containment: Prevent spills from reaching a waterway. Methods for Cleanup: Use water spray to dilute and/or wash away spills to avoid exposure and to protect persons working to stop/repair leak. Absorb spilled product onto absorbent material. Other Information: (if applicable) N/A
SECTION VII – HANDLING AND STORAGE
Precautions To Be Taken in Handling: Handle in a well ventilated, cool and dry area. Precautions To Be Taken in Storage: Storage must be in a well ventilated, cool and dry area.
SECTION VIII - EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines: N/A Engineering Controls: Ventilation Mechanical (General): Normal/general dilution ventilation is acceptable. Personal Protective Equipment (PPE): Eye/Face Protection: None required with normal consumer use. Occupational Setting: For splash protection, use chemical goggles. Eye Wash fountain is desirable. Skin Protection: None required with normal consumer use. Occupational Setting: Protective gloves (rubber, neoprene) should be used for prolonged direct contact. Respiratory Protection: None required with normal use.
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES Appearance (color, physical form, shape): Colored liquid (orange). Packaged in a pourable plastic bottle.
Flash Point (Method Used): >200F / >93.3°C (ASTM D-93 Pensky-Martens Closed Cup.)
Odor: Product is perfumed. Reserve Alkalinity: N/A Odor Threshold: N/A Solubility in Water: Completely Physical State: Liquid. Decomposition Temperature: N/A Vapor Pressure (mm Hg): N/A Evaporation Rate (nBuOAc=1): Unknown Vapor Density (Air=1): N/A Specific Gravity/Density: 1.019 g/cm3 Boiling Point: N/A Melting/Freezing Point: N/A Partition Coefficient (n-octanol/water): N/A pH (10% solution): 10.3 Volatile Organic Compound (VOC): Product complies with US State and Federal regulations for VOC content.
SECTION X – STABILITY AND REACTIVITY
Chemical Stability: Stable Conditions to Avoid: None Incompatible Materials: None Hazardous Decomposition Products: None known Possibility of Hazardous Reactions: None known
SECTION XI - TOXICOLOGICAL INFORMATION Chronic Effects: No chronic health effects reported. Target Organs: No target organs reported. Carcinogenicity: This finished consumer product is not carcinogenic. NTP: No IARC: No All product ingredients were checked for NTP and IARC carcinogen listings relevant to this product formulation.
SECTION XII - ECOLOGICAL INFORMATION
No concerns at relevant environmental concentrations.
SECTION XIII - DISPOSAL CONSIDERATIONS Waste Disposal Method: Disposal is to be performed in compliance with federal, state/provincial and local regulations. Non-Household Setting (US Federal): Industrial disposal of product in finished, consumer-ready packaging must be disposed of as an organic pesticide. Records must be kept of the disposal that documents the method of disposal, the date of disposal, the location of the disposal site, the type of pesticide disposed of (organic pesticide), and the amount of pesticide disposed of. Disposal records must be retained for 20 years. Incineration is preferred where permitted. Product removed from finished, consumer-ready packaging may be disposed of as non-pesticidal, liquid waste which is non-hazardous waste according to Federal RCRA regulations (40 CFR 261). California Hazardous Waste: Yes Household Use: Consumers may dispose of small (household) quantities down the drain with large quantities of water. Discard empty container in trash or thoroughly rinse and recycle container where facilities exist.
SECTION XIV - TRANSPORT INFORMATION
Ground Transport (US DOT): Not regulated. Air Transport (IATA): Not regulated. Marine/Water Transport (IMDG): Not regulated.
SECTION XV - REGULATORY INFORMATION United States All intentionally-added components of this product are listed on the US TSCA Inventory. EPA Registration Number: 3573-63 SARA 313/302/304/311/312 chemicals: None. California: This product has been evaluated and does not require warning labeling under California Proposition 65. State Right-to-Know and CERCLA: The following ingredients present in the finished product at >1% (or >0.1% for carcinogens) are listed on state right-to-know lists or state worker exposure lists
Ingredient CAS # Max Level
CERCLA RQ
State IL MA NJ PA RI
None
Canada All ingredients are CEPA approved for import to Canada by Procter & Gamble. This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and this MSDS contains all information required by the Controlled Products Regulations.
SECTION XVI - OTHER INFORMATION
Perfumes contained within the products covered by this MSDS comply with appropriate IFRA guidance. P&G Hazard Rating: Health: 1 4=EXTREME Flammability: 0 3=HIGH Reactivity: 0 2=MODERATE 1=SLIGHT 0=NOT SIGNIFICANT *N/A. - Not Applicable *N/K. - Not Known Data supplied is for use only in connection with occupational safety and health. DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance regarding the use of this material. The information contained here has been compiled from sources considered by Procter & Gamble to be dependable and is accurate to the best of the Company’s knowledge. It is not meant to be an all-inclusive document on worldwide hazard communication regulations. This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and design the appropriate protective mechanisms to prevent employee exposures, property damage or release to the environment. Procter & Gamble assumes no responsibility for injury to the recipient or third persons, or for any damage to any property resulting from misuse of the product.
Material Safety Data Sheet
LA9776SULPHURIC ACID 98%
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONProduct Id: LA9776Product Name: SULPHURIC ACID 98%Synonyms: Sulphuric Acid, Hydrogen Sulphate, Oil of Vitriol, Battery Acid.Chemical Family: Inorganic acid.Application: Water treatment. Metal pickling. Petroleum processing. Manufacture of fertilizers, explosives and otheracids.
Distributed By:Univar Canada Ltd.9800 Van Horne WayRichmond, BCV6X 1W5
Prepared By: The Environment, Health and Safety Department of Univar Canada Ltd.Preparation date of MSDS: 13/Jan/2014Telephone number of preparer: 1-866-686-4827
24-Hour Emergency Telephone Number (CANUTEC): (613) 996-6666
2. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients Percentage(W/W)
LD50s and LC50s Route & Species:
Sulphuric Acid7664-93-9
70-100 Oral LD50 (Rat) 2140 mg/kgInhalation LC50 (Rat) 510 mg/m3 (2-hour exposure)
LC50 (Rat): 255 mg/m3 (equivalent 4-hour exposure)LC50 (Mouse): 160 mg/m3 (equivalent 4-hour exposure).
Note: No additional remark.
3. HAZARDS IDENTIFICATIONPotential Acute Health Effects:Eye Contact: Corrosive to eye tissue and may cause severe damage and blindness. Inflammation of the eye ischaracterized by redness, watering, and itching.Skin Contact: Corrosive! Effects on the skin may be delayed and damage may occur without the onset of pain. Causesburns, and brownish or yellow stains. Concentrated solutions may cause second or third degree burns with severenecrosis and may cause permanent scarring. Prolonged and repeated exposure to dilute solutions often causes irritation,redness, pain and drying and cracking of the skin.Inhalation: Inhalation of the mist may produce severe irritation of respiratory tract, characterized by coughing, choking,or shortness of breath. May be fatal if inhaled.
LA9776SULPHURIC ACID 98%
Page 1 of 6
3. HAZARDS IDENTIFICATIONIngestion: Harmful if swallowed. Causes burns to the mouth, throat and stomach.
4. FIRST AID MEASURESEye Contact: Immediately flush eyes with copious quantities of water for at least 20 minutes holding lids apart to ensureflushing of the entire surface. Seek immediate medical attention. Do not transport victim until the recommended flushingperiod is completed, unless flushing can be continued during transport.Skin Contact: Flush affected skin with gently flowing water for 20-60 minutes and remove contaminated clothing whilerinsing. Obtain medical attention immediately. Do not transport victim until the recommended flushing period iscompleted, unless flushing can be continued during transport. Remove contaminated clothing and discard. Removecontaminated shoes and discard.Inhalation: If symptoms are experienced, remove source of contamination or move victim to fresh air. If symptomspersist, get medical attention. If the affected person is not breathing, apply artificial respiration. If breathing is difficult,give oxygen. In situations where administering oxygen is appropriate, first aiders must be trained in the safe use andhandling of oxygen. It is preferable to administer oxygen under a doctor's supervision or advice. If the heart has stopped,trained personnel should begin cardiopulmonary resuscitation (CPR) immediately. Immediate medical assistance isrequired.Ingestion: If conscious, wash out mouth with water. Seek immediate medical attention. Do NOT induce vomiting. Nevergive anything by mouth to an unconscious or convulsing person. If vomiting occurs spontaneously, keep head below hipsto prevent aspiration of liquid into the lungs. Administer artificial respiration if breathing has stopped. If the heart hasstopped, trained personnel should begin cardiopulmonary resuscitation (CPR) immediately.Notes to Physician: Aspiration may cause severe lung damage. Evacuate stomach in a way which avoids aspiration. Ifingestion has occurred less than 2 hours earlier, carry out careful gastric lavage; use endotracheal cuff if available, toprevent aspiration. Observe patient for respiratory difficulty from aspiration pneumonitis. Give artificial resuscitation andappropriate chemotherapy if respiration is depressed. Following exposure the patient should be kept under medicalreview for at least 48 hours as delayed pneumonitis may occur. DO NOT attempt to neutralize the acid with weak basessince the reaction will produce heat that may extend the corrosive injury.
5. FIRE FIGHTING MEASURESFlash Point: None.Flash Point Method: Not applicable.Autoignition Temperature: Not available.Flammable Limits in Air (%): Not Available.Extinguishing Media: Use extinguishing media appropriate for surrounding fire. If water is used, care should be taken,since it can generate heat and cause spattering if applied directly to sulphuric acid.Special Exposure Hazards: Strong dehydrating agent, which may cause ignition of finely divided combustible materialson contact. Reacts violently with water with the evolution of heat. It can react explosively with organic materials. Reactswith metals to generate flammable hydrogen gas. Reacts violently with water with the evolution of heat. It can reactexplosively with organic materials. Reacts with many metals to liberate hydrogen gas that can form explosive mixtureswith air. Hydrogen, a highly flammable gas, can accumulate to explosive concentrations inside drums, or any types ofsteel containers or tanks upon storage.Hazardous Decomposition/Combustion Materials (under fire conditions): Oxides of sulphur.Special Protective Equipment: Fire fighters must wear full face, positive pressure, self-contained breathing apparatusand appropriate protective clothing.NFPA RATINGS FOR THIS PRODUCT ARE: HEALTH 3, FLAMMABILITY 0, INSTABILITY 2HMIS RATINGS FOR THIS PRODUCT ARE: HEALTH 3, FLAMMABILITY 0, REACTIVITY 2
6. ACCIDENTAL RELEASE MEASURESPersonal Precautionary Measures: Restrict access to unprotected personnel. Wear appropriate protective equipment.Environmental Precautionary Measures: Prevent entry into sewers or streams, dike if needed. Consult localauthorities.Procedure for Clean Up: Isolate hazard area and restrict access. Stop leak only if safe to do so. Eliminate all ignitionsources. Handling equipment must be grounded. Ventilate area. Contain spill with sand or other inert materials.Neutralize with lime slurry, limestone, or soda ash. Absorb with an inert dry material and place in an appropriate wastedisposal container.
LA9776SULPHURIC ACID 98%
Page 2 of 6
7. HANDLING AND STORAGEHandling: For industrial use only. Handle and open containers with care. Avoid contact with eyes, skin and clothing. Donot ingest. Avoid inhalation of chemical. Empty containers may contain hazardous product residues. Keep the containersclosed when not in use. Protect against physical damage. Use appropriate personnel protective equipment. Use extremecare when diluting with water. ALWAYS ADD ACID TO WATER. Use with adequate ventilation. CAUTION: Hydrogen, ahighly flammable gas, can accumulate to explosive concentrations inside drums, or any type of steel containers or tanksupon storage. Carbon steel storage tanks must be vented. Use corrosion-resistant transfer equipment when transferringacid.Storage: Store above freezing point. Elevated temperatures will increase the corrosion rate of most metals as well ascause build-up of pressure due to sulfur dioxide generation. Store packaged acid in a dry, well-ventilated location. Avoidstorage with incompatible materials. Storage tanks should be protected from water getting in, be well ventilated, andmaintained structurally in a safe and reliable condition. Sulfuric acid will attack some forms of plastics and coatings.Always add acid to water - not water to acid. If kept in upper floors of building, floors should be acid proof with drains to arecovery tank.
8. EXPOSURE CONTROLS/PERSONAL PROTECTIONEngineering Controls:
Use process enclosure, local exhaust ventilation, or other engineering controls to keep airborne levels belowrecommended exposure limits. Electrical installations should be protected against the corrosive action of acid vapors.Respiratory Protection: A NIOSH/MSHA approved air-purifying respirator equipped with acid gas/fume, dust, mistcartridges for concentrations up to 10 mg/m3. An air-supplied respirator if concentrations are higher or unknown.Gloves:
Neoprene gloves. PVC gloves.Skin Protection: Impervious boots. Butyl rubber acid suit.Eyes: Chemical safety goggles and/or full face shield to protect eyes and face, if product is handled such that it could besplashed into eyes.Other Personal Protection Data: Ensure that eyewash stations and safety showers are proximal to the work-stationlocation.
Ingredients Exposure Limit - ACGIH Exposure Limit - OSHA Immediately Dangerousto Life or Health - IDLH
Sulphuric Acid 0.2 mg/m3 TLV-TWA 1 mg/m3 TWA 15 mg/m3
9. PHYSICAL AND CHEMICAL PROPERTIESPhysical State: Liquid. (Oily).Color: Clear to amber.Odor: Odorless A pungent odor may exist if certain impurities are present in the acid.pH <1Specific Gravity: 1.835Boiling Point: 279°C /535°FFreezing/Melting Point: -35°C / -31°FVapor Pressure: <0.3 mm Hg @ 25°CVapor Density: 3.4% Volatile by Volume: Not Available.Evaporation Rate: Not Available.Solubility: Soluble in water.VOCs: Not Available.Viscosity: Not Available.Molecular Weight: 98.08 g/moleOther: Not Available.
10. STABILITY AND REACTIVITYChemical Stability: Stable.Hazardous Polymerization: Will not occur.Conditions to Avoid: Avoid excessive heat, open flames and all ignition sources. Water.
LA9776SULPHURIC ACID 98%
Page 3 of 6
10. STABILITY AND REACTIVITYMaterials to Avoid: Contact with organic materials (such as alcohol, acrylonitrile, chlorates, carbides, epichlorohydrin,fulminates, isoprene, nitrates and picrates) may cause fire and explosions. Contact with metals may produce flammablehydrogen gas. Reducing agents. Alkalis. Moisture.Hazardous Decomposition Products: Toxic fumes. Sulfuric acid. Oxides of sulphur. Sulfuric acid vapors may bereleased upon heating and sulfur dioxide and sulfur trioxide may be released upon decomposition.Additional Information:
When diluting, add acid to water. DO NOT add water to the acid. Sulfuric acid can be corrosive to most metals,depending on such factors as acid concentration, temperature and impurities. Concentrated sulfuric acid (containingmore than 90% H2SO4) can be safely handled using carbon steel, cast iron, and certain stainless steel alloys. Theresistance of alloys to sulfuric acid corrosion generally increases with increasing chromium, molydbenum, copper andsilicon content.
11. TOXICOLOGICAL INFORMATIONPrinciple Routes of Exposure
Ingestion: Harmful if swallowed. Causes burns to the mouth, throat and stomach.Skin Contact: Corrosive! Effects on the skin may be delayed and damage may occur without the onset of pain. Causesburns, and brownish or yellow stains. Concentrated solutions may cause second or third degree burns with severenecrosis and may cause permanent scarring. Prolonged and repeated exposure to dilute solutions often causes irritation,redness, pain and drying and cracking of the skin.Inhalation: Inhalation of the mist may produce severe irritation of respiratory tract, characterized by coughing, choking,or shortness of breath. May be fatal if inhaled.Eye Contact: Corrosive to eye tissue and may cause severe damage and blindness. Inflammation of the eye ischaracterized by redness, watering, and itching.
Additional Information: Repeated exposure may produce erosion and discoloration of teeth.Acute Test of Product:Acute Oral LD50: 2140 mg/kg (Rat)Acute Dermal LD50: Not Available.Acute Inhalation LC50: 510 mg/m3 (2-hour exposure) (Rat)255 mg/m3 (equivalent 4-hour exposure) (Rat)160 mg/m3 (equivalent 4-hour exposure) (Mouse)
Carcinogenicity:
Ingredients IARC - Carcinogens ACGIH - Carcinogens
Sulphuric Acid Group 1 A2
Carcinogenicity Comment: WHO and IARC have concluded that occupation exposure to strong inorganic acid mistscontaining sulfuric acid is carcinogenic to man, (Group 1) causing cancer of the larynx and, to a lesser extent, the lung.Exposure to any mist or aerosol during the use of this product should be avoided and, in any case, keep exposure belowthe occupational exposure limit for sulfuric acid. IARC's classification is for inorganic acid mists containing sulfuric acidonly and does not apply to sulfuric acid or sulfuric acid solutions.
Reproductive Toxicity/ Teratogenicity/ Embryotoxicity/ Mutagenicity: Not Available.
LA9776SULPHURIC ACID 98%
Page 4 of 6
12. ECOLOGICAL INFORMATIONEcotoxicological Information:
Ingredients Ecotoxicity - Fish SpeciesData
Acute CrustaceansToxicity:
Ecotoxicity - FreshwaterAlgae Data
Sulphuric Acid LC50 (Brachydanio rerio) 500mg/L
LC50 (Oncorhynchus mykiss)2.8 ug/L (96hr)
Not Available. Not Available.
Other Information:Harmful to aquatic life at low concentrations.
13. DISPOSAL CONSIDERATIONSDisposal of Waste Method: Disposal of all wastes must be done in accordance with municipal, provincial and federalregulations.Contaminated Packaging: Empty containers should be recycled or disposed of through an approved wastemanagement facility.
14. TRANSPORT INFORMATIONDOT (U.S.):DOT Shipping Name: SULFURIC ACIDDOT Hazardous Class 8DOT UN Number: UN1830DOT Packing Group: IIDOT Reportable Quantity (lbs): Not Available.Note: No additional remark.Marine Pollutant: No.
TDG (Canada):TDG Shipping Name: SULPHURIC ACIDHazard Class: 8UN Number: UN1830Packing Group: IINote: No additional remark.Marine Pollutant: No.
LA9776SULPHURIC ACID 98%
Page 5 of 6
15. REGULATORY INFORMATIONU.S. TSCA Inventory Status: All components of this product are either on the Toxic Substances Control Act (TSCA)Inventory List or exempt.
Canadian DSL Inventory Status: All components of this product are either on the Domestic Substances List (DSL), theNon-Domestic Substances List (NDSL) or exempt.
Note: Not available.
U.S. Regulatory Rules
Ingredients CERCLA/SARA - Section302:
SARA (311, 312) HazardClass:
CERCLA/SARA - Section313:
Sulphuric Acid Listed Listed Listed
California Proposition 65: Not Listed.MA Right to Know List: Listed.New Jersey Right-to-Know List: Listed.Pennsylvania Right to Know List: Listed.
WHMIS Hazardous Class:D1A VERY TOXIC MATERIALSE CORROSIVE MATERIAL
16. OTHER INFORMATIONAdditional Information: This product has been classified in accordance with the hazard criteria of the
Canadian Controlled Products Regulations (CPR) and the MSDS contains all theinformation required by the CPR.
Disclaimer: NOTICE TO READER:Univar, expressly disclaims all express or implied warranties of merchantability andfitness for a particular purpose, with respect to the product or information providedherein, and shall under no circumstances be liable for incidental or consequentialdamages.
Do not use ingredient information and/or ingredient percentages in this MSDS as aproduct specification. For product specification information refer to a ProductSpecification Sheet and/or a Certificate of Analysis. These can be obtained fromyour local Univar Sales Office.
All information appearing herein is based upon data obtained from the manufacturerand/or recognized technical sources. While the information is believed to beaccurate, Univar makes no representations as to its accuracy or sufficiency.Conditions of use are beyond Univar's control and therefore users are responsible toverify this data under their own operating conditions to determine whether theproduct is suitable for their particular purposes and they assume all risks of their use,handling, and disposal of the product, or from the publication or use of, or relianceupon, information contained herein. This information relates only to the productdesignated herein, and does not relate to its use in combination with any othermaterial or in any other process.
***END OF MSDS***
LA9776SULPHURIC ACID 98%
Page 6 of 6
WD-40
Page 1 of 4
MATERIAL SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
MANUFACTURER/SUPPLIER: US Office: WD-40 Company 1061 Cudahy Place San Diego, CA 92110 Information Phone #: (619) 275-1400 Emergency Phone # 24 hr: Chemtrec: (800) 424-9300 – Designated for use only in the event of chemical emergencies involving a spill, leak, fire exposure or accident involving chemicals.
Canadian Office: WD-40 Products [Canada] Ltd. P.O. Box 220 Toronto, Ontario M9C 4V3 Information Phone #: (416) 622-9881 Emergency Phone # 24 hr: Canutec: (613) 996-6666 – Designated for use only in the event of chemical emergencies involving a spill, leak, fire exposure or accident involving chemicals
PRODUCT NAME: WD-40 Aerosol PRODUCT USE: Cleaner, lubricant. MSDS DATE OF PREPARATION: March 27, 2014
SECTION 2 HAZARDS IDENTIFICATION DANGER! Harmful or fatal if swallowed. Flammable aerosol. Contents under pressure. Avoid eye contact. Use with adequate ventilation. Keep away from heat, sparks and all other sources of ignition. POTENTIAL HEALTH EFFECTS: PRIMARY ROUTES OF ENTRY: Inhalation, skin and eye contact. ACUTE EFFECTS: INGESTION: This product has low oral toxicity. Swallowing of the liquid contents may cause irritation, nausea, vomiting and diarrhea. The liquid contents are an aspiration hazard. If swallowed, can enter the lungs and may cause chemical pneumonitis. EYES: Contact may be mildly irritating to eyes. May cause redness and tearing. SKIN: Prolonged and/or repeated contact may produce mild irritation and defatting with possible dermatitis. INHALATION: High concentrations may cause nasal and respiratory irritation and central nervous system effects such as headache, dizziness and nausea. May aggravate existing respiratory conditions such as asthma. Intentional abuse may be harmful or fatal. CHRONIC EFFECTS: None expected.
SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS
Ingredient CAS Number Percent Aliphatic Petroleum Distillates 64742-47-8
64742-88-7 50-70%
Petroleum Base Oil 64742-58-1 64742-53-6 64742-56-9 64742-65-0
30-35%
Non-Hazardous Ingredients Proprietary <10% Carbon Dioxide 124-38-9 2-3%
WD-40 Aerosol 03/27/14
Page 2 of 4
SECTION 4 FIRST AID MEASURES
For Medical Emergencies Call 1-888-324-7596 (24 hours/day) INGESTION: Aspiration Hazard. DO NOT induce vomiting. Call physician, poison control center or the WD-40 Safety Hotline at 1-888-324-7596 immediately. EYE CONTACT: Flush thoroughly with water. Get medical attention if irritation persists. SKIN CONTACT: Wash with soap and water. If irritation develops and persists, get medical attention. INHALATION: If irritation is experienced, move to fresh air. Get medical attention if irritation or other symptoms develop and persist.
SECTION 5 FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Use water fog, dry chemical, carbon dioxide or foam. Do not use water jet or flooding amounts of water. Burning product will float on the surface and spread fire. SPECIAL FIRE FIGHTING PROCEDURES: Firefighters should always wear positive pressure self-contained breathing apparatus and full protective clothing. Cool fire-exposed containers with water. Use shielding to protect against bursting containers. UNUSUAL FIRE/EXPLOSION HAZARDS: Contents under pressure. Aerosol containers may burst under fire conditions. Vapors are heavier than air and may travel along surfaces to remote ignition sources and flash back.
SECTION 6 ACCIDENTAL RELEASE MEASURES
SPILL RESPONSE: Wear appropriate protective clothing (see Section 8). Eliminate all sources of ignition and ventilate area. Leaking cans should be placed in a plastic bag or open pail until the pressure has dissipated. Contain and collect liquid with an inert absorbent and place in a container for disposal. Clean spill area thoroughly. Report spills to authorities as required.
SECTION 7 HANDLING AND STORAGE
HANDLING: Avoid contact with eyes. Avoid prolonged contact with skin. Avoid breathing vapors or aerosols. Use with adequate ventilation. Keep away from heat, sparks and open flames. Wash thoroughly with soap and water after handling. Do not puncture or incinerate containers. Keep can away from electrical current or battery terminals. Electrical arcing can cause burn-through (puncture) which may result in flash fire, causing serious injury. Keep out of the reach of children. STORAGE: Do not store above 120F or in direct sunlight. U.F.C (NFPA 30B) Level 3 Aerosol.
SECTION 8 EXPOSURE CONTROLE/PERSONAL PROTECTION
OCCUPATIONAL EXPOSURE LIMITS: Aliphatic Petroleum Distillates 1200 mg/m3 TWA Manufacturer Recommended Petroleum Base Oil 5 mg/m3 TWA ACGIH TLV
10 mg/m3 STEL ACGIH TLV Non-Hazardous Ingredients None Established Carbon Dioxide 5000 ppm TWA, 30,000 ppm STEL ACGIH TLV
The Following Controls are Recommended for Normal Consumer Use of this Product Engineering Controls: Use in a well-ventilated area. Personal Protection: Eye Protection: Avoid eye contact. Safety glasses or goggles recommended. Skin Protection: Avoid prolonged skin contact. Chemical resistant gloves recommended for operations where skin contact is likely. Respiratory Protection: None needed for normal use with adequate ventilation.
WD-40 Aerosol 03/27/14
Page 3 of 4
For Bulk Processing or Workplace Use the Following Controls are Recommended Engineering Controls: Use adequate general and local exhaust ventilation to maintain exposure levels below that occupational exposure limits. Personal Protection: Eye Protection: Safety goggles recommended where eye contact is possible. Skin Protection: Wear chemical resistant gloves. Respiratory Protection: None required if ventilation is adequate. If the occupational exposure limits are exceeded, wear a NIOSH approved respirator. Respirator selection and use should be based on contaminant type, form and concentration. Follow applicable regulations and good Industrial Hygiene practice. Work/Hygiene Practices: Wash with soap and water after handling.
SECTION 9 PHYSICAL DATA APPEARANCE AND ODOR: Light amber liquid with a mild odor.
Freezing Point: Not Applicable Odor Threshold: Not Determined Boiling Point: 361 - 369F (183 - 187°C) Specific Gravity: 0.78 – 0.82 @ 60F Solubility in Water: Insoluble pH: Not Applicable Vapor Pressure: 95-115 PSI @ 70F Vapor Density: Greater than 1 Percent Volatile: 70-75% VOC: 533 grams/liter (65%) Coefficient of Water/Oil Distribution:
Not Determined Kinematic Viscosity:
2.79-2.96cSt @ 100F
Flash Point: 122F (49°C) Tag Open Cup (concentrate)
Flammable Limits: (Solvent Portion)
LEL: 0.6% UEL: 8.0%
Pour Point: -63C (-81.4F ) ASTM D-97 Explosion Impact: None
SECTION 10 STABILITY AND REACTIVITY
STABILITY: Stable INCOMPATIBILITY: Strong oxidizing agents. Avoid heat and open flames. Do not puncture or incinerate containers. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide.
SECTION 11 TOXICOLOGICAL INFORMATION The oral toxicity of this product is estimated to be greater than 5,000 mg/kg based on an assessment of the ingredients. This product is not classified as toxic by established criteria. It is an aspiration hazard. None of the components of this product is listed as a carcinogen or suspected carcinogen or is considered a reproductive hazard.
SECTION 12 ECOLOGICAL INFORMATION No data is currently available.
SECTION 13 DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: If this product becomes a waste, it would be expected to meet the criteria of a hazardous waste based on flammability. However, it is the responsibility of the generator to determine at the time of disposal the proper classification and method of disposal. Dispose in accordance with federal, state, and local regulations.
SECTION 14 TRANSPORT INFORMATION DOT Surface Shipping Description: Consumer Commodity, ORM-D After 1/1/2014 UN1950, Aerosols, 2.1 Ltd. Qty (Note: Shipping Papers are not required for Limited
WD-40 Aerosol 03/27/14
Page 4 of 4
Quantities unless transported by air or vessel – each package must be marked with the Limited Quantity Mark) Canadian TDG Classification: Limited Quantity IMDG Code Hazard Classification: UN1950, Aerosols, 2.1.
SECTION 15 REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: CERCLA 103 Reportable Quantity: This product is not subject to CERCLA reporting requirements, however, oil spills are reportable to the National Response Center under the Clean Water Act and many states have more stringent release reporting requirements. Report spills as required under federal, state and local regulations. SARA TITLE III: Hazard Category For Section 311/312: Acute Health, Fire Hazard, Sudden Release of Pressure Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements: None Section 302 Extremely Hazardous Substances (TPQ): None EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are listed on the TSCA inventory. CANADIAN REGULATIONS: Canadian Environmental Protection Act: All of the ingredients are listed on the Canadian Domestic Substances List or exempt from notification Canadian WHMIS Classification: Class B-5 (Flammable Aerosol). This MSDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the MSDS contains all of the information required by the CPR.
SECTION 16 OTHER INFORMATION HMIS Hazard Rating: Health – 1 (slight hazard), Fire Hazard – 4 (severe hazard), Physical Hazard – 0 (minimal hazard) Revision Date: 03/27/14 Supersedes: 03/10/13 Prepared By: Industrial Health & Safety Consultants, Inc. 1-203-929-3473 This MSDS complies with OSHA guidelines set by 29 CFR 1910.1200 and the Canadian WHMIS regulations. The foregoing information has been compiled from sources believed to be accurate but is not warranted to be. Recipients are advised to confirm in advance of need that data is correct. Standards change without notice. It is the responsibility of the recipient to insure that their personnel have been notified of any changes which may affect them. The data provided on this MSDS are not meant to be used as specifications, only as guideline information as to the safe use of this product. User should refer to applicable laws before use. N/D = Not Determined N/E = Not Established N/A = Not Applicable 1014100/No.0084102
Material Safety Data Sheet
Date of issue 02/12/14
Product name REACH NPE FREE
Product code M600Supersedes 04/13/11
Product use Hand Cleaner
Emergency Telephone Numbers
For MSDS Information: Technical Services Group Telephone (780) 453-8100 (Business Hours 8:00am - 5:00pm)
For Medical or Transportation EmergencyCANUTEC (24 Hours) (613) 996-6666 - Call Collect
Prepared By Technical Services Group 11627 178th Street Edmonton, Alberta T5S 1N6
ZEP Inc.11627 178th StreetEdmonton, Alberta T5S 1N61-877-I-BUY-ZEP (428-9937)www.zep.com
Section 1. Chemical Product and Company Identification
Emergency overviewCAUTION !HARMFUL IF SWALLOWED.Do not ingest. Do not get in eyes. Avoid breathing vapor or mist.
Acute Effects
Eyes
Skin
Inhalation
Ingestion
Routes of Entry Eye contact.Irritating to eyes. Inflammation of the eye is characterized by redness, watering and itching.This product is formulated for use on skin but should be rinsed off when possible.Inhalation not likely under normal use conditions. Inhalation of high concentrations of vapor may affect the central nervous system. Symptoms and signs include headache, dizziness, fatigue,muscular weakness, drowsiness and, in extreme cases, loss of consciousness.
Harmful if swallowed. Aspiration hazard if swallowed. Can enter lungs and cause damage.
NOTE: MSDS data pertains to the product as delivered in the original shipping container(s). Risk of adverse effects are lessened by following all prescribed safety precautions, including the use of proper personal protective equipment.
Chronic effects Skin which is repeatedly defatted by contact with this product may be more susceptible to irritation, infection or dermititis.
Additional Information: See Toxicological Information (Section 11)
Section 2. Hazards Identification
Name of Hazardous Ingredients CAS number % by Weight
Section 3. Composition/Information on Ingredients
LIGHT ALIPHATIC NAPHTHA; solvent naphtha (petroleum), medium aliphatics 64742-88-7 15 - 40C12-C14 ETHOXYLATED ALCOHOLS 68551-12-2 1 - 5MONOETHANOLAMINE; 2-aminoethanol; MEA 141-43-5 1 - 5
Eye Contact
Skin Contact
Inhalation
Ingestion
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention.This product is formulated for use on the skin, but should always be immediately rinsed off with plenty of water.
Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Get medical attention if symptoms appear.If material has been swallowed and the exposed person is conscious, give small quantities of water to drink.Never give anything by mouth to an unconscious person. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention immediately.
Section 4. First Aid Measures
Page: 1/3
Material Safety Data Sheet Product Name REACH NPE FREEProduct code M600
Closed cup: 71°C (159.8°F)[Tagliabue.]
Flash Point
Not available.Flammable Limits
Flammability
Fire hazard Gel structure inhibits combustibility of solvent.
Gel structure inhibits combustibility of solvent.
Fire-Fighting Procedures Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. In case of fire, use water spray (fog), foam, dry chemical or CO₂.
Section 5. Fire Fighting Measures
Auto-ignition Temperature
Products of Combustion None known.
Explosion hazard Not available.
Spill Clean up Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble or absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Section 6. Accidental Release Measures
Handling
Storage
Put on appropriate personal protective equipment (see Section 8). Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Do not reuse container. Wash thoroughly after handling. Avoid contact with eyes.Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store between the following temperatures: 40°F - 120°F (4.4°C - 49°C). Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Keep out of the reach of children.
Section 7. Handling and Storage
Personal Protective Equipment (PPE)
Eyes
Hands and BodyRespiratory
Product name Exposure limitsNo exposure limit value known.
Recommended: No special protection is required.Recommended: No special protective clothing is required.
A respirator is not needed under normal and intended conditions of product use.
Section 8. Exposure Controls/Personal Protection
Physical StatepHBoiling Point
Specific GravitySolubility
Liquid. [Gel]8Not available.0.95
ColorOdor
Vapor Pressure
Vapor DensityEvaporation Rate
VOC (Consumer)
Green. [Light]Almond-like.Not available.Not available.Not available.
338 (g/l). 35.7%
Very slightly soluble in the following materials:cold water and hot water. Emulsifies in water.
Section 9. Physical and Chemical Properties
Freezing Point
The product is stable.
Will not occur.
Stability and Reactivity
Hazardous Decomposition Products
Hazardous PolymerizationReactive or incompatible with the following materials: oxidizing materials.Incompatibility
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Section 10. Stability and Reactivity
Page: 2/3
Material Safety Data Sheet Product Name REACH NPE FREEProduct code M600
Section 11. Toxicological Information
Carcinogenicity
Reproductive toxicity
Conclusion/Summary : No results available.
Teratogenicity
No results available.
Mutagenicity
Conclusion/Summary : No results available.
:Conclusion/Summary
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Not available.
Environmental Effects No known significant effects or critical hazards. Aquatic Ecotoxicity
Not available.
Section 12. Ecological Information
Waste Information
Waste Stream Not available.
Section 13. Disposal Considerations
Waste must be disposed of in accordance with applicable regulations. Consult your local or regional authorities for additional information.
PG* : Packing group
Regulatory information UN number Proper shipping name Classes PG* Label
Not available. Not available. Not available. -
Section 14. Transport Information
IMDG Class
TDG Classification Not regulated. - - -
NOTE: DOT classification applies to most package sizes. For specific container size classifications or for size exceptions, refer to the Bill of Lading with your shipment. Limited Quantity: Small quantities of controlled goods are not regulated as Dangerous Goods according to TDG regulations.
Additional information
-
-
Section 15. Regulatory Information
Canada
WHMIS (Canada) Not controlled under WHMIS (Canada).This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution.Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Section 16. Other Information
top related