mass relationships in chemical reactions 3 by definition: 1 atom 12 c “weighs” 12 amu on this...

Mass Relationships in Chemical Reactions

3

By definition: 1 atom 12C “weighs” 12 amu

On this scale

1H = 1.008 amu

16O = 16.00 amu

Atomic mass is the mass of an atom in atomic mass units (amu)

Micro Worldatoms & molecules

Macro Worldgrams

4

The average atomic mass is the weighted

average of all of the naturally occurring

isotopes of the element.

Example: 3.1

Copper, a metal known since ancient times, is used in electrical cables and pennies, among other things.

The atomic masses of its two stable isotopes, (69.09 percent) and (30.91 percent), are 62.93 amu and 64.9278 amu, respectively.

Calculate the average atomic mass of copper. The relative abundances are given in parentheses.

Mole

Avogadro’s number: 6.022x1023

(atoms, molecules, particles)

For any element

atomic mass (amu) = molar mass (grams)

Example: 3.2

Helium (He) is a valuable gas used in industry, low-temperature research, deep-sea diving tanks, and balloons.

How many moles of He atoms are in 6.46 g of He?

A scientific research helium balloon.

Molecular Mass

SO2

1S 32.07 amu

2O + 2 x 16.00 amu SO2 64.07 amu

For any molecule

molecular mass (amu) = molar mass (grams)

1 molecule SO2 = 64.07 amu

1 mole SO2 = 64.07 g SO2

Example: 3.5

Calculate the molecular masses (in amu) of the following compound:

(a) caffeine (C8H10N4O2), a stimulant present in tea, coffee, and cola beverages

Example: 3.6

Methane (CH4) is the principal component of natural gas.

How many moles of CH4 are present in 6.07 g of CH4?

Example: 3.7

How many hydrogen atoms are present in 25.6 g of urea [(NH2)2CO], which is used as a fertilizer, in animal feed, and in the manufacture of polymers?

The molar mass of urea is 60.06 g.

urea

Formula Mass

NaCl1Na 22.99 amu

1Cl + 35.45 amuNaCl 58.44 amu

For any ionic compound

formula mass (amu) = molar mass (grams)

1 formula unit NaCl = 58.44 amu

1 mole NaCl = 58.44 g NaCl

Mass Spectrometry

Hea

vy

Hea

vyLi

ght

Ligh

t

Mass Spectrum of Ne

Ligh

t

Mass Spectrum

of Ne

Hea

vy

Percent Composition

n x molar mass of elementmolar mass of compound

x 100%

n is the number of moles of the element in 1 mole of the compound

C2H6O

%C =2 x (12.01 g)

46.07 gx 100% = 52.14%

%H =6 x (1.008 g)

46.07 gx 100% = 13.13%

%O =1 x (16.00 g)

46.07 gx 100% = 34.73%

52.14% + 13.13% + 34.73% = 100.0%

Example: 3.8

Phosphoric acid (H3PO4) is a colorless, syrupy liquid used in detergents, fertilizers, toothpastes, and in carbonated beverages for a “tangy” flavor.

Calculate the percent

composition by mass of H, P, and O in this compound.

Example: 3.10

Chalcopyrite (CuFeS2) is a principal mineral of copper.

Calculate the number of kilograms of Cu in 3.71 × 103 kg of chalcopyrite.

Chalcopyrite.

HydrateSteps:

1. Find the mass of water or mass of anhydrate2. Turn mass of water and mass of anhydrate into moles

(individually)3. Find the mole ratio; mole of anhydrate mole of water

mole of anhydrate mole of anhydrate4. Write the formula of the hydrate

:

ExampleA calcium chloride hydrate has a mass of 4.72 g. After heating for several minutes the mass of the anhydrate is found to be 3.56 g. Use this information to determine the formula for the hydrate.

Empirical Formula

Steps:1. Percent to mass2. Mass to moles3. Divide by small4. Multiply ‘til whole

Example: 3.9

Ascorbic acid (vitamin C) cures scurvy.

It is composed of 40.92 percent carbon (C), 4.58 percent hydrogen (H), and 54.50 percent oxygen (O) by mass.

Determine its empirical formula.

23

g CO2 mol CO2 mol C g C

g H2O mol H2O mol H g H

g of O = g of sample – (g of C + g of H)

Combust 11.5 g ethanol

Collect 22.0 g CO2 and 13.5 g H2O

6.0 g C = 0.5 mol C

1.5 g H = 1.5 mol H

4.0 g O = 0.25 mol O

Divide by smallest (0.25)

Empirical formula C2H6O

ExampleWhen ethanol is burned, carbon dioxide and water are given off. Suppose that in one experiment the combustion of 11.5 g of ethanol produced 22.0 g of CO2 and 13.5 g of H2O. Determine the empirical formula for ethanol.

Molecular Formula

Steps:1. Find empirical formula2. Determine the molar mass of

the empirical formula3. Find multiplier (molar mass

given/empirical molar mass)4. Multiply empirical formula

subscripts by the multiplier

Example: 3.11

A sample of a compound contains 30.46 percent nitrogen and 69.54 percent oxygen by mass, as determined by a mass spectrometer.

In a separate experiment, the molar mass of the compound is found to be between 90 g and 95 g.

Determine the molecular formula and the accurate molar mass of the compound.

Chemical Reactions and Equations

2 H2 (g) + O2 (g) 2 H2O (l)

coefficient

Product(s)Reactants

“Reactants with”

“to produce” or “yield” State of matter

Balancing Chemical Reactions

KClO3 O2+ KCl

Steps:1. List elements present on

each side2. Add coefficients to

balance (“met a non hairy oxen”)

Example: 3.12

When aluminum metal is exposed to air, a protective layer of aluminum oxide (Al2O3) forms on its surface. This layer prevents further reaction between aluminum and oxygen, and it is the reason that aluminum beverage cans do not corrode. [In the case of iron, the rust, or iron(III) oxide, that forms is too porous to protect the iron metal underneath, so rusting continues.]

Write a balanced equation for the formation of Al2O3.

An atomic scale image of aluminum oxide.

Stoichiometry

• Mole method: coefficient in a reaction can be interpreted as the number of moles

• Allows us to write conversion factors from a chemical equation

Example: 3.13The food we eat is degraded, or broken down, in our bodies to provide energy for growth and function. A general overall equation for this very complex process represents the degradation of glucose (C6H12O6) to carbon dioxide (CO2) and water (H2O):

If 856 g of C6H12O6 is consumed by a person over a certain period, what is the mass of CO2 produced?

Example: 3.14

All alkali metals react with water to produce hydrogen gas and the corresponding alkali metal hydroxide.

A typical reaction is that between lithium and water:

How many grams of Li are needed to produce 9.89 g of H2?

Lithium reacting with water to produce hydrogen gas.

Limiting Reagents

CO(g) + 2 H2(g) CH3OH(g)

2NO + O2 2NO2

Example: 3.15

Urea [(NH2)2CO] is prepared by reacting ammonia with carbon dioxide:

In one process, 637.2 g of NH3 are treated with 1142 g of CO2.

(a) Which of the two reactants is the limiting reagent?

(b) Calculate the mass of (NH2)2CO formed.

(c) How much excess reagent (in grams) is left at the end of the reaction?

Reaction Yield

% Yield = Actual Yield

Theoretical Yieldx 100%

Example: 3.17

Titanium is a strong, lightweight, corrosion-resistant metal that is used in rockets, aircraft, jet engines, and bicycle frames. It is prepared by the reaction of titanium(IV) chloride with molten magnesium between 950°C and 1150°C:

In a certain industrial operation 3.54 × 107 g of TiCl4 are reacted with 1.13 × 107 g of Mg.

(a)Calculate the theoretical yield of Ti in grams.

(b)Calculate the percent yield if 7.91 × 106 g of Ti are actually obtained.