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SYLLABUS AND REGULATIONS
UNDER
CHOICE BASED CREDIT SYSTEM (CBCS)
(Those who joined in 2018-2019 and after)
M.Phil., Programme in Chemistry
Regulations 2018
SRI S. RAMASAMY NAIDU MEMORIAL COLLEGE
SATTUR- 626 203
(An Autonomous Institution Affiliated to Madurai Kamaraj University, Madurai)
(Re-Accredited with Grade ‘A’ by NAAC)
Placed at the
meeting of
Academic Council
held on
17.04.2018
SRNMC Regulations-2018 Syllabus
1
Objectives
The syllabus for M. Phil (Chemistry) under the semester system has been designed to
provide the students an in depth knowledge on various fields of research in Chemistry and
prepare for various competitive examinations such as CSIR, GATE, NET etc
Eligibility for admission
Candidates who have passed M.Sc (Chemistry) examination conducted by the Madurai
Kamaraj University or any other university duly recognized by the Syndicates of Madurai
Kamaraj University as equivalent there to are eligible to join this course and the college shall
admit M.Phil students through an Entrance Test conducted by Madurai Kamaraj University. The
admissions will be made once in a year. The candidates for M.Phil shall be admitted only in the
regular (Full Time) mode and not in Part-time or distance learning or any other mode.
Duration of the Course
The duration of the course shall be one academic year comprising two semesters.
Subjects of study
The main subjects of study offered for M. Phil (Chemistry) course shall consist of
the following.
Semester I
There shall be three papers
Paper I – Research Methodology
Paper II – Spectroscopic techniques and their applications
Paper III – Elective
i. Co-ordination complexes and their Applications
ii. Advanced Organic Chemistry
Semester II
Dissertation and Viva-voce only
SRNMC Regulations-2018 Syllabus
2
Evaluation
The performance of a scholar is evaluated in terms of percentage of marks. Evaluation for
each course shall be done by a continuous internal assessment by the concerned teacher as well
as by an end semester examination of 3 hours duration and will be consolidated at the end of the
course. The ratio of the marks to be allotted to continuous internal assessment and to end
semester examination is 25:75 (Internal 25 and External 75)
Internal Test:
a) Maximum marks for test
(Two tests and their average) : 15 marks
b) Maximum marks for (Seminar Activities /
Quiz / Assignment/Presentation Skills) : 10 marks
Total : 25 marks
Passing Minimum
1. 50% of the aggregate (external+ internal).
2. No separate pass minimum for internal.
3. 34 marks out of 75 is the pass minimum for the External
Dissertation (II semester)
4. 1. 50% of the aggregate (Dissertation evaluation + Viva voce)
5. 2. 25 marks out of 50 marks is the pass minimum for Viva voce
6. 3. No separate pass minimum for the internal Dissertation evaluation
7. 4. 34 marks out of 75 marks is the pass minimum for the external Dissertation evaluation
Question Paper Pattern
Part A 5x7=35 Marks
Five questions (either or type).
One from each unit.
Part B 4x10=40 Marks
Four questions out of seven.
Total 75 Marks
SRNMC Regulations-2018 Syllabus
3
M. Phil (Chemistry)
Table – 1: Course Details and Scheme of Examination
(with effect from the academic year 2018 – 2019)
FIRST SEMESTER
Subject Subject
Code
Weekly
Contact
Hours
Credits Exam
/Hours
Marks
Int. Ext Total
Paper I
Research Methodology
MP18CH11 6 5 3 25 75 100
PaperII(core)
Spectroscopic techniques
and their applications
MP18CH12 6 5 3 25 75 100
Paper III Elective
1) Co-ordination
complexes and their
Applications
2) Advanced Organic
Chemistry
MP18CHE11
MP18CHE12
6 5 3 25 75 100
SECOND SEMESTER
Subject Subject
Code Credits
Marks
Int. Ext. Total
Dissertation MP18CHDN 7 75 75 150
Viva Voce MP18CHVV 3 - 50 50
Total 10 200
SRNMC Regulations-2018 Syllabus
4
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR – 626 203.
Department of Chemistry
(For those who are joining in 2018-2019 and after)
SYLLABUS
Programme : M.Phil (Chemistry) Subject Code : MP18CH11
Semester : I No. of Hours allotted : 6 /Week
Subject : Core - Paper I No. of Credits : 5
Title of the Paper: RESEARCH METHODOLOGY
Objectives:
To know the information about research journals for publication and writing the thesis
To introduce the students to C-language and enable to solve simple programs in C.
To gain knowledge on various purification techniques
Unit I: Literature Search
Searching the chemical literature Primary sources – Journals, periodicals, patents,
abstracts; Secondary sources including list of titles, reviews – Annual Reviews – Treatises,
Serials, monographs and text books, encyclopedia, catalogues, index of tabulated data – Science
citration index – Citation searching in Chemical literature – Location of Journal article -
Materials on a given topic – Information about Literature searching online – Popular websites in
Chemistry
Introduction to Internet and its applications – web browsers – World Wide Web – Search
Engines – e-journals - literature Survey in Chemistry – Popular journals and websites in
Chemistry –Databases in Chemistry - literature searching and collection using e-journals
Unit II: Error in chemical analysis and statistics
Classification of errors – accuracy – precision –minimization of errors- Significant
figures – mean – standard deviation – normal or Gaussian distribution – Reliability of results –
confidence interval – comparison of results – Q test-student‘s t-test, F test, paired t-test Analysis
of Variance (ANOVA)– correlation and regression – the least squares method for deriving
calibration plots like straight line – power curve – exponential curve – second degree parabola –
general methods used, standard addition , universal standard method – problems in these
methods using least square fitting – quality assurance and control charts.
SRNMC Regulations-2018 Syllabus
5
Unit III: Methods of separation
General methods of Isolation and purification of Chemicals – Solvent Extraction –
Fractional crystallization – Sublimation – Distillation – Vacuum distillation – Purification of
solvents Chromatography Techniques: - Paper, Column, Ion-exchange, GC and HPLC
techniques and applications
Unit IV-Advanced Instrumentation Techniques
Principle, Instrumentation and applications of the following techniques – Electron
microscope-Scanning Electron Microscope (SEM)- Modern Transmission electron microscope
(TEM)-Scanning probe microscope (SPM)-Atomic force microscope (AFM)-Scanning
Tunneling Microscope (STM)-Thermo gravimetric analysis-Derivative Thermo gravimetric
DTG-Differential scanning calorimetry(DSC)-Enthalpimetric methods.
Unit V-Computers in Chemistry
Application of ‗C‘ language in Chemistry – Introduction of ‗C‘ languages – Character set
in C- C Keywords and Identifiers – Constants, variables, Data types and operators –
Computation of some simple problems in Chemistry such as 1) Half-life period, 2) Normality,
Molarity and Molality of a solution 3) Determination of solubilities of sparingly soluble salts 4)
Ionic strength of an electrolyte 5) computation of 13
C chemical shift in organic compounds.
Reference Books
1. J. March, ―Advanced Organic Chemistry‖, Fourth Edition, John Wiley & Sons, New
Delhi, 2000.
2. J.Mendham, RC Denney, JD Barnes, M.Thomas B.Sivasankar Text Book of Vogel‘s
Quantitative chemical Analysis Sixth Edition Pearson,2013
3. Mick Wilson ,G.Smith,M.Simmons and B.Raguse,Nano technology Basic science and
emerging Tecnologies
4. Er.Rakesh Rathi Nano Technology Revolution of 21st century,S Chand and company
PVT LTd 2013.
5. U.N Dash ,Analytical Chemistry Theory and Practice ,Sultan Chand & Sons Educational
Publishers ,New Delhi Third Edition 2013.
6. Skoog, Holler, Nieman, Thomson, Principles of Instrumental Analysis, Asia Pvt. Ltd.,
Singapore, 2004.
7. K.V. Raman, Computers in Chemistry, Tata McGraw – Hill Publishing Co.Ltd., New
Delhi,1993.
8. 6. E.Balagurusamy, Programming in ANSI-C , 2ndedition, Tata McGraw – Hill
Publishing Co.Ltd., New Delhi,1998.
Prepared by : Dr. T. Kavitha
Signature :
SRNMC Regulations-2018 Syllabus
6
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR – 626 203.
Department of Chemistry
(For those who are joining in 2018-2019 and after)
SYLLABUS
Programme : M.Phil (Chemistry) Subject Code : MP18CH12
Semester : I No. of Hours allotted : 6 /Week
Subject : Core - Paper II No. of Credits : 5
Title of the Paper: Spectroscopic techniques and their Applications
Objectives:
Acquire knowledge about atomic and molecular spectroscopic Techniques
To gain knowledge on Inorganic photo chemistry
Know the principle and applications of 1H and
13 C NMR
Unit 1 - Atomic spectroscopy
Optical atomic spectroscopy - Designs of Optical Instruments - Types of Optical
Instruments - Principles of Fourier Transform Optical Measurements-Atomization Methods –
Sample Introduction Methods Atomic adsorption spectrometry, Atomic fluorescence
spectrometry - Sample Atomization Techniques-Atomic Absorption Instrumentation -
Interferences in Atomic Absorption Spectroscopy - Atomic Absorption Analytical Techniques -
Atomic Fluorescence Spectroscopy Atomic X-ray Spectrometry - Principles and Instrument
Components - X-ray Fluorescence Methods - X-ray Absorption Methods - X-ray Diffraction
Methods - The Electron Microprobe - Instrumental Analysis for heavy metals
Unit II - Molecular spectroscopy
Ultraviolet – Visible molecular absorption spectroscopy - Principle and instrumentation -
The Magnitude of Molar Absorptivities - Absorbing Species – Qualitative Applications -
Spectrophotometric Kinetic Methods - Spectrophotometric Studies of Complex Ions
Infra-red Absorption Spectrometry - IR Instrumentation - IR Sources and Transducers -
Mid-IR Absorption Spectrometry - Mid-IR Reflection Spectrometry - Photo acoustic IR
Spectroscopy - Near-IR Spectroscopy - Far-IR Spectroscopy - IR Emission Spectroscopy - IR
Microscopy
Advances in Raman Spectroscopy - Applications of Raman Spectroscopy - Other Types
of Raman Spectroscopy
Molecular Mass Spectrometry - Molecular Mass Spectra - Ion Sources - Mass
Spectrometers - Applications of Molecular Mass Spectrometry - Quantitative Applications of
Mass Spectrometry - Structure determination of organic compounds by UV-VIS, IR, 1H &
13C
NMR and Mass spectroscopic techniques.
SRNMC Regulations-2018 Syllabus
7
Unit-III -Physical Methods in Chemistry - I and Inorganic Photochemistry
Electronic spectra of transition metal complexes –evaluation of 10 Dq and β values for
cobalt and nickel octahedral complexes –Applications to simple coordination complexes-charge
transfer spectra-combined uses of IR and Raman spectroscopy in the structural elucidation of
simple molecules like N2O, ClF3, NO3- and metal complexes (carbonyl and Cyanides).
Photophysical and Photochemical processes of coordination complexes (Cobalt (III)
complexes, Chromium (III) complexes and Ruthenium complexes) – Adamson‘s Rule - Solar
energy conversion-photo electrochemical cells-water splitting –semiconductor solar cells.
Unit IV-Physical Methods in Chemistry - II
Multinuclear - NMR Spectroscopy – Applications to Inorganic compounds (1H, 31P,
19F and 11B nuclei to structural problems) - Fluxional NMR and Paramagnetic NMR- Contact
shift and Pseudo contact interactions- Lanthanide shift reagents. Applications of EPR to simple
inorganic radicals – Evaluation of g and A tensors - Zero field splitting and Kramer‘s degeneracy
– ESR spectrum of metal complexes – ESR spin trapping techniques Mossbauer spectroscopy –
Applications to iron and tin complexes.
Unit V- Organic Spectroscopy:
Application of 1H and 13C NMR in structural elucidation of organic compounds –
Analysis of complex NMR spectra – Use of multipulse
techniques in NMR – Application of 2D NMR, HETCOR, COSY, NOESY and INADEQUATE
techniques - Problem solving approach involving all the spectroscopic techniques including UV,
IR, NMR and mass spectroscopy.
Reference Books
1. Skoog, Holler, Nieman, Thomson, Principles of Instrumental Analysis 5th
Edition, Asia
Pvt. Ltd., Singapore, 2003.
2. R.S. Drago, Physical Methods in Inorganic Chemistry 3rd ed., Wiley Eastern
Company,1999.
3. E.A.V. Ebsworth, Sturctural Methods in Inorganic Chemistry 3rd ed., ELBS,1987.
4. Huheey, James E, Inorganic chemistry, IV Ed., Principles of ―‖Structure; and Reactivity
Collins College Publishers,1993.
5. Nakamoto and Dazuo, Infrared and Raman spectra of Inorganic and Coordination
Compounds, IV ed., john Whiley and Sons, NY,1986.
6. Jag mohan, Organic Spectroscopy, Narosa Publishers, 2001.
7. William Kemp. Organic Spectroscopy, Macmilan, 3rd ed., 1991
Prepared by : Dr. T. Kavitha
Signature :
SRNMC Regulations-2018 Syllabus
8
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR – 626 203.
Department of Chemistry (For those who are joining in 2018-2019 and after)
SYLLABUS
Programme : M.Phil (Chemistry) Subject Code : MP18CHE11
Semester : I No. of Hours allotted : 6 /Week
Subject : Elective - Paper I No. of Credits : 5
Title of the Paper: Co-ordination complexes and their Applications
Objectives:
To know the applications of UV-Visible, IR spectroscopy and ESR spectroscopy in the
study of coordination compounds
To study applications of organo metallic compounds
To know the applications of metal in medicine
UNIT I - Co-ordination Compounds
Co-ordination chemistry - Methods of preparation of complexes - Isomerism in
complexes - Complexes and their stability - Chelate effect - Stability constants and their
determination – Complexes of Metals in different oxidation states - Applications of complex
formation in analytical chemistry.
UNIT II - Theories in co-ordination chemistry
Term symbols for dn-ions - Energy level diagrams for weak field and strong field – Spin-
orbit coupling - Nephelauxetic effect - Charge transfer spectra - Applications of UV, IR, NMR
and ESR spectroscopy techniques in the study of co-ordination chemistry - Magnetic interactions
– Magnetic susceptibilities determination of co-ordination complexes.
Application of VB, MO, CF and LF theories in co-ordination chemistry - Splitting of d-
orbitals - Spectrochemical series - Jahn Teller distortion.
UNIT III - Organometallic compounds and reaction mechanism
Organometallic compounds - Metallocences - Ferrocene - Arene complexes – Non-
aromatic olefins and acetylenes complexes – Catalysis by organometallic compounds –
Wilkinson‘s catalyst – Oxo process –Wacker process – Ziegler – Natta catalysis.
Inorganic reaction mechanism – Inert and labile complexes – Substitution
reactions in six coordinated and four coordinated complexes – Trans effect –. Mechanism of
electron transfer reactions - Outer sphere mechanism, Inner sphere mechanism, Two electron
transfer reactions.
SRNMC Regulations-2018 Syllabus
9
UNIT IV - Bioinorganic chemistry
Bioinorganic chemistry – Energy sources for life Cytochromes- Dioxygen binding
transport and Utilization-Binding of dioxygen to myoglobin-physiology of myoglobin and
hemoglobin-Structure and functions of hemoglobin- Ferredoxins and rubredoxins –Blue copper
proteins—Vitamin B12 and the B12 Coenzymes -Nitrogen fixation – Role of metal ions in
biological systems.
UNIT V-Metals and Chelation in Medicine
Dependence of biological Growth on the concentration of Essential and toxic Elements-
Disease due to metal deficiency and treatment –Thermodynamic and pharmacokinetic properties
of chelating drugs in metal in detoxification—Antimicrobial activities of metal chelates-anti
inflammatory effects of zinc and copper compounds-anticancer activity of platinum complexes-
anticancer activity of other metal complexes-vanadium complexes in the treatment of diabetes
References
1. Purcell and Kotz, Inorganic chemistry, 2013.
2. Cotton & Wilkinson Advanced Inorganic Chemistry, Wiley Eastern Ltd.
3. James E.Huheey, Inorganic Chemistry, 3rd
Ed., Harper Int. 1996.
4. Tuli, Malik & Madan, Selected Topics in Inorganic Chemistry, S.Chand & Co., 2002.
5. Asim K.Das, BioInorganic ChemistryBooks and Allied (P)Ltd Publishers, 2013.
6. Puri, Sharma & Kalia, Principles of Inorganic Chemistry, S.Chand & Co., 1998.
Prepared by : Dr. T. Kavitha
Signature :
SRNMC Regulations-2018 Syllabus
10
SRI S.RAMASAMY NAIDU MEMORIAL COLLEGE (An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR – 626 203.
Department of Chemistry (For those who are joining in 2018-2019 and after)
SYLLABUS
Programme : M.Phil (Chemistry) Subject Code : MP18CHE12
Semester : I No. of Hours allotted : 6 /Week
Subject : Elective - Paper II No. of Credits : 5
Title of the Paper: Advanced Organic Chemistry
Objectives:
Acquire knowledge about stereochemistry of organic compounds
To know the applications of reagents in organic synthesis
To understand the basic concepts of ultrasonic sound used inorganic synthesis
To learn about microwave assisted reactions
UNIT I -STEREOCHEMISTRY
Introduction to molecular symmetry and point groups.Topicity and prostereoisomerism,
nomenclature of stereotopic ligands and faces, stereoheterotopic ligands – centre of chirality,
assignment of absolute stereochemistry, axial chirality, planar chirality and
helicity.Conformational analysis – acylic systems, cyclic systems, cyclohexane and
decalins.Conformation and reactivity with examples.Stereoselectivity – classification,
terminology, principle of stereoselectivity, examples of diastereoselectivity and
enantioselectivity including few examples from pericyclic reactions.
UNIT II -REACTIVE INTERMEDIATES
Reactive intermediates: Generation, structure and reactivity of carbenes, nitrenes and free
radicals – addition and rearrangement reactions – substitution reactions by free radicals. Name
reactions: Favorskil rearrangement, Stork enamine reaction, Mannich reaction and Baeyer
Villiger oxidation, Diels-Alder Reaction, Hofmann's Rule and Hofmann Elimination reaction.
UNIT III -REAGENTS IN ORGANIC SYNTHESIS
Reagents in organic synthesis: Uses of NBS, lithium diisopropylamide, aluminium
isopropoxide,lithium aluminium hydride, potassium tertiary butoxide and trimethylsilyl iodide.
Reagentscontaining P,S, B, Si - protecting groups – hydroxyl, amino, carbonyl and carboxylic
acid.synthetic analysis and planning – control of stereochemistry.
SRNMC Regulations-2018 Syllabus
11
UNIT IV -Green Chemistry
Introduction about green chemistry-designing a green synthesis-choice of starting
materials-choice of reagent –choice of catalyst-choice of solvent-Green reagent-polymer
supported catalyst –Phase –transfer catalysis in green synthesis-Elimination reactions-C-
alkylations-Darzen‘s reaction-The witting reaction-Alkylation
UNIT V -Microwave Induced Green synthesis
Introduction-Application-Microwave Assistant reactions in water-Hofmann Elimination –
hydrolysis-Hydrolysis of benzyl chloride-hydrolysis of benzamide-oxidation of toluene –
oxidation of alcohols-saponification- orthoester Claisen rearrangement-
Sonochemistry Fundamentals of sound and ultrasound – cavitation and its principle –
instrumentation – homogeneous and heterogeneous processes – sonoluminescence – uses in
chemistry, material science, medicine and life – synthetic applications – esterification,
saponification, hydrolysis, substitution, cannizaro reaction, Strecker‘s synthesis
References
1. J. March, ―Advanced Organic Chemistry‖, Fourth Edition, John Wiley & Sons, New
Delhi, 2000.
2. Stereochemisty of carbon compounds.Ernest L.Eliel.
3. stereochemistry of organic compounds –Principle and applications D.Nasipuri.
4. Stereochemistry –conformation and Mechanism,p.s.Kalsi
5. Green chemistry by V.K.Ahluwalia, M.Kidwai , Anamaya publishers, - Revised edition,
2004
6. Green Chemistry –Environment Friendly Alternatives by Rashmi Sanghi and M M
Srivastava - Narosa Publishing House.-2003
Prepared by : Dr. T. Kavitha
Signature :
SRNMC Regulations-2018 Syllabus
12
SRI S. RAMASAMY NAIDU MEMORIAL COLLEGE
(An Autonomous Institution Re-accredited with ‗A‘ Grade by NAAC)
SATTUR – 626 203
Department of Chemistry
(For those who are joining in 2018-19 and after)
SYLLABUS
Programme: M. Phil (Chemistry) Subject Code : MP18CHDN
Semester : II
Paper : DISSERTATION No. of credits: 10
DISSERTATION AND VIVA-VOCE
OBJECTIVES:
To develop the ability of the students to prepare a Dissertation
To get clear idea about the new concepts in Chemistry Research fields
Regulations for the Dissertation
The topic of the Dissertation may be based on the Chemistry.
Evaluation method for Dissertation:
Max Marks
Internal External Total
(average)
Dissertation 75 75 150
Viva voce 50 50
Total 200
Viva voce examination should be evaluated by the external examiner.
The report of the Dissertation must be in the prescribed format. It should be typed neatly
in Ms Word. The font size of the letter should be 12 with double space.
The format of the Dissertation should have the following components.
First page should contain:
1. Title of the Dissertation
2. Name of the candidate.
3. Register number.
4. Name of the supervisor.
5. Address of the institution.
6. Month & year of submission.
SRNMC Regulations-2018 Syllabus
13
Contents:
1. Declaration by candidate
2. Certificate by supervisor
3. Acknowledgement.
4. List of tables
5. List of figures
6. Chapters(not exceeding six)
7. Bibliography
8. Appendix
The number of pages in the Dissertation may be 100 to 150. Three copies of the
Dissertation with hard binding should be submitted.
Prepared by: Dr. T. Kavitha
Signature :
CHAIRMAN DEAN-ACADEMIC
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