analisis termodinamico estireno

8/18/2019 Analisis termodinamico estireno

1/49

ETI L BEN

A GUA IN3

H

A GUA IN A GUA IN2

B 1

B 8 B 11


2/49

RETILBEN

EA T 1 HEA T 2 REA CTIN

REACTOUT

REACOUT 2

A GUA OUT 2

B 2

B 3B 4

B

B 10


3/49

SEP1

HIDROGE N

SEP2

ETYEST A GUA OUT

P URGA

EST IRENO

B 6

B 7

B 9


4/49

REACOUT2 AGUAOUT2 AGUAIN AGUAIN2

B5 B8 B11

B10 B10 B8

VAPOR VAPOR LIQUID VAPOR

Substream: !I"ED

!#$e %$#& $bm#$'(rESTIRENO )*11+5+) 0 0 0

ETILBEN 5*002),2 0 0 0

-IDROGEN 2*)+)2.2 0 0 0

AGUA +*/,5 8*825.,5 +*/,5 +*/,5

T#ta$ %$#& $bm#$'(r 2/*1+/51 8*825.,5 +*/,5 +*/,5

T#ta$ %$#& $b'(r 1/.2*81. 158*++/. 1)8*8+/2 1)8*8+/2

T#ta$ %$#& ut'(r 2128/*,. 5058*812 2*,2185+ )551*5.1

Temerature % 800 /2+*/+.8 ,, 500

Pressure s3a 1.*)+ 1.*)+ 1. 1.*)+

Va#r %ra 1 1 0 1L34u3 %ra 0 0 1 0

S#$3 %ra 0 0 0 0

E6t(a$7 Btu'$bm#$ /*.0E90/ 1*02E905 1*2.E905 1*01E905

E6t(a$7 Btu'$b 58*)+52+ 5)58*2/ )8))*))2 55,8*528

E6t(a$7 Btu'(r ,*88E90. +*00E905 1*1)E90) +*.2E905

E6tr#7 Btu'$bm#$R 11*.8.8, ,*.8/18, .0*10222 5*8/).8.

E6tr#7 Btu'$bR 0*1+8/,02 0*.15/8 2*22)011 0*/2/+,.1

De6s3t7 $bm#$'ut 1*0+E0/ 1*,.E0/ /*..E900 1*./E0/

De6s3t7 $b'ut 0*0)/0+1 0*0/1.2+ )2*050,1 0*025,,+1

Aera;e !< 5,*8+)1/ 18*01528 18*01528 18*01528

L34 V#$ )0% ut'(r 2)*0/).1 2*551,/8 2*,10)2. 2*,10)2.


5/49

AGUAIN/ AGUAOUT ESTIRENO ETILBEN ET=EST -EAT1

B1 B10 B1 B+ B2

B11 B, B+ B, B1

VAPOR LIQUID LIQUID LIQUID LIQUID !I"ED

0 0 2*)8250/ 0 )*108/5/ /*.2585

0 0 0*.15,1)/ /*125 .*+8,1/) ,*)+).18

0 0*00E900 0 0*00E900 2*,/E0/ 2*50E0/

+*/,5 8*825.,5 0 0 0 +*/,5

+*/,5 8*825.,5 /*0+821+ /*125 11*0+822 20*.++,)

1)8*8+/2 158*++/. /2/*522/ //1*,,/1 11)5*),1 1/.2*81.

++88*+.+ 2*5)2/1. )*)20558 )*1.8+,+ 21*15..) ./.,*8))

1000 ,, 2+1*5858 ,, ,, 1+2*+52.

1.*)+ 1.*)+ 1.*)+ 1. 1.*)+ 1.*)+

1 0 0 0 0 0*..+/2,,0 1 1 1 1 0*550),2/

0 0 0 0 0 0

+*)0E90. 1*2.E905 .81,/*,) .,+8*.21 22)8)*5/ /82+2*5.

5//1*.+) )8))*)) .)1*//,2 .5*1+),5 215*++58 58.*58.2

+*00E905 1*0+E90) 1*.+E905 1*50E90. 2*52E905 ,*85E905

2*11.8,5 .0*1022. )5*).8/ 105*1/) 88*,,5+. 50*.2++,

0*11,/+/. 2*22)012 0*)28)82) 0*++0285) 0*8.52255 0*,)+8,,.

+*/+E0. /*...//8 0*.),+)+5 0*50821.. 5*25E01 .*,1E0/

0*01)+08 )2*050,1 .8*8))/2 5/*+558 55*10285 0*/088..5

18*01528 18*01528 10.*.22 10)*1),. 105*0/2/ )5*50/+

2*,10)2. 2*551,/8 5*,/5+81 )*1101./ 20*+)/+8 2.*0.85)


6/49

-EAT2 -IDROGEN PURGA REACTIN REACTOUT RETILBEN

B/ B. B10 B1

B2 B) B+ B/ B. B+

VAPOR VAPOR VAPOR VAPOR VAPOR LIQUID

/*./E900 1*1/E02 ,*.,E0, /*.2585 )*11+5+) /*.2585

,*)+).18 1*55E02 1*.+E0) ,*)+).18 5*002),2 .*5,1.18

2*50E0/ 2*)+E900 2*/5E0. 2*50E0/ 2*)+)2.2 2*50E0/

+*/,5 0*5.+52., 0 +*/,5 +*/,5 0

20*.++,) /*2,E900 2*/,E0. 20*.++,) 2/*1+/51 ,*+++,)/

1/.2*81. 1*81E901 ,*10E0. 1/.2*81. 1/.2*81. 8.2*1.8

1.2.1*0. 1281*511 0*0+18.) 2/.++*,/ 25/,.*, 15*2+85)

500 ,, ,0 1112 10.0 ,0

1.*)+ 1.*)+ 1.*)+ 1.*)+ 1.*)+ 1.*)+

1 1 1 1 1 00 0 0 0 0 1

0 0 0 0 0 0

2115.*.. 1,1+.*8+ 2/0*8552 1.58*15, .885*)5+ 1)/08*0)

/22*+.+. /0+,*,5 ,,*1)101 22*2)0)2 8.*/8))/ 15.*+1.1

.*/.E905 5)22/*++ 5*.8E02 2*++E90. 1*1/E905 1*/0E905

2,*2.,8+ 1*/.8./2 0*)502/,8 +*222085 5*.,28+2 +2*)2))+

0*.15+,/) 0*2.2+2,1 0*21,//5. 0*1.0,8)8 0*0+.52+. 0*8,+8828

1*..E0/ 2*55E0/ 2*58E0/ 8*,2E0. +*1.E0. 0*522+0+,

0*0+.2+1+ 1*.2E02 ,*,/E0/ 0*05,1.1, 0*052+1+. 55*0.,55

)5*50/+ 5*550,), 2*++18). )5*50/+ 5,*8+)1/ 105*2,1)

2.*0.85) 2*52E900 2*0)E0. 2.*0.85) 2)*0/).1 15*22,,+


7/49

SEP1 SEP2

B) B,

B5 B)

!I"ED LIQUID

)*11+)08 )*108/5/

5*002)) .*+8,1/)

2*)+)2/5 2*,/E0/

+*/,5 8*825.,5

2/*1+/5 1+*+2/)+

1/.2*81. 1/2.*)).

),1.*50) 22*+5,,/

200 ,,

1.*)+ 1.*)+

0*)055+). 00*/+..0/) 1

0 0

2).51*.. /+252*,1

.5)*8,,. 5+0*/82,

)*1.E905 ,*82E905

/8*/52,. )/*0,2.2

0*))2..0/ 0*+.8)..5

/*.5E0/ 0*8),8.2.

0*1+++8,1 5,*,001.

5,*8+)1. ))*.8)8+

2)*0/). 2/*515,2


8/49

S>mb#$#s C#rr3e6tes 1 2

LIQUIDO LIQUIDO

Temeratura? @% ,,*000 ,,*0,1

P 1.*)+) 1.*)+)

T Temeratura? R 5/)*),0 /82*5++

- E6ta$>a? Btu'$bm#$ +/20,*)50 )288)*+80

S E6tr#>a? Btu'$bm#$R 5)*/)1 8.*/2,

1*.)/ 0*+,1

V 1180*+./ 1,,8*,10

G G3bbs? Btu'$bm#$ )2+)0*51) /0)2/*,52

e4 C#6sta6te e e4u3$3br3# .*/8/E925 /*122E91,

R C#6sta6te e $#s ;ases? Btu'$bm#$R 1*+8,

PV Pr#ut# PV? Btu'$bm#$ 1*858 2*,++

A -e$m(#$t? Btu'$bm#$ )2+)2*/,. /*0)/E90.

N#ta:

Pres3F6? $b '362

De6s3a $bm#$'t/

V#$me6 m#$ar 36/'$bm#$

L# 4ue esta e6 au$ s#6 at#r#H# es $# 4ue 7# a$u$e? re

as>

= −

=+

K_M).

/

150000*00

100000*00

50000*00

0*00

50000*00

100000*00

Btu/lbmol


9/49

0

200*000

150*000

100*000

50*000

0*000

Btu/lbmol


10/49

/ . 5 ) ,

VAPOR VAPOR VAPOR VAPOR VAPOR

500*000 500*000 12+2*000 1112*000 10.0*000

1.*)+) 1.*)+) 1.*)+) 1.*)+) 1.*)+)

+5+*),0 +5+*),0 1,51*),0 15,1*),0 1.++*),0

2818/*2)0 2818/*2)0 +/258*/)0 5+5/*/5+ .2.*/5.

28*815 28*815 0*/,) 11*0+, )*00)

0*001 0*001 0*001 0*001 0*001

1*211E90) 1*211E90) 2*210E90) 1*+8/E90) 1*8+2E90)

5/0*)18 5/0*)18 +2)00*/5/ 11.8,*22, 8581*++0

1*/21 1*/21 /*58.E911 0*025 0*05)

1+05*))0 1+05*))0 /.,8*/58 /120*+2, 2+,,*+5/

2*./)E90/ 2*./)E90/ +*)08E90. 8*/))E90/ 5*)0.E90/

s t#ma#s e $#s resu$ta#s e $a s3mu$a3F6? $# r#s3ta t3ra6#$e a3se6$# #ra? 36te6t (aer $as ;raJas er# me 4uea6 e3s3mas

4ue a(> $# (ea6 #ra : %a$tF $# e C

Btu/lbmol

0 1 2 / . 5 ) , 8 + 1011121/1.15

H vs Corrientes

- s C#rr3e6tes

Corrientes


11/49

1 2 / . 5 ) , 8 + 10 11 12 1/ 1. 15

S vs Corrientes

S sC#rr3e6tes

Corrientes

Btu/lbmol


12/49

8 + 10 11 12 1/

!ECLA VAPOR LIQUIDO !ECLA LIQUIDO LIQUIDO

,,*000 ,,*000 ,,*000 ,,*000 ,,*000 2+/*,,1

1.*)+) 1.*)+) 1.*)+) 1.*)+) 1.*)+) 1.*)+)

5/)*),0 5/)*),0 5/)*),0 5/)*),0 5/)*),0 ,5/*..1

.2258*120 ,11.*8+. .8/+2*5,0 1),/.*)10 122820*000 5.,+0*,20

5,*.// 1*1+) ),*250 +2*58, /8*85, )2*8.)

0*01, 0*00/ 0*+00 0*..2 /*... 0*.,1

1*02/E905 )*,,2E905 1+20*8)8 /+0)*0,5 501*)+/ /)))*/00

11./5*.,1 ).,2*+8) 12/01*,0) )).2/*0+/ 101+))*,2, 1021.1*1)+

.5.2.*/8+ ./2*,.) 1*02/E905 0*000 /*/,0E9.1 0*000

1)0*+50 10)5*)88 /*02/ )*1., 0*,+0 5*,,0

1*1)0E90. ,*5/+E90/ 12/0.*,2+ )).1)*+.) 101+),*51) 1021/5*.00

500*000 0*000 500*000 1000*000 1500*000

150000*000

100000*000

50000*000

0*000

50000*000

100000*000

150000*000

T vs H T vs G

Ts-

TsG

Temperatura (°F)

Btu/lbm

G vs Corrientes


13/49

0 1 2 / . 5 ) , 8 + 1011121/1.15

150000*000

100000*000

50000*000

0*000

50000*000

100000*000

150000*000

G s C#rr3e6tes

Corrientes

Btu/lbmol


14/49

1.

LIQUIDO

/,,*++/

1.*)+)

81*),,

10015*0/0

1)8*.+.

0*)28

2,.+*)/8

/,.,*00/

0*000

.*/2,

/,.2*),)

0*000 500*000 1000*000 1500*000 2000*000

180*000

1)0*000

1.0*000

120*000

100*000

80*000

)0*000

.0*000

20*000

0*000

T vs S

T s S

Temperatura (°R)

l-R Btu/lbm

A vs Corrientes


15/49

0 1 2 / . 5 ) , 8 + 1011121/1.15

150000*000

100000*000

50000*000

0*000

50000*000

100000*000

150000*000

A s C#rr3e6tes

Corrientes


16/49

500*000 0*000 500*000 1000*000 1500*000

150000*000

100000*000

50000*000

0*000

50000*000

100000*000

150000*000

T vs A

T s A

Temperatura (°F)

l


17/49


18/49

Cp/R A B(T)

Estireno(g) 2*05 5*02E02 1*),E05

H(g) /*2.+ .*22E0. 008/E)

Ben!eno(g) 0*20) /*+1E02 1*//E05 2

Etilben!eno(g) 1*12. 5*5.E02 1*85E05

Etileno(g) 1*.2. 1*..E02 .*/+E0)

Cp" #/mol $

R" #/mol $

Gas $34u3#

Cp prom

Estireno(g) 151*2+ 182*8.

H(g) 28*8. C1;

Ben!eno(g) 82*./ C2;

Etilben!eno(g) 12,*. 185*+) C2$

Etileno(g) .2*+

;36s'J$ema6a;er'J$es'./002,0'a$*'Pr#ert3es20#20Gases20a620L34u3s*

C(%/T)


19/49

R6 1

R6 2

Cp/R A B(T) 1

Estireno(g) 2*05E900 5*02E02 1*),E05

H(g) /*25E900 .*22E0. 8*/0E90.

Etilben!eno(g) 1*12E900 5*5.E02 1*85E05

5*10E900 +*+5E0/ 8*/0E90.

.52*21 'm#$

528*5. 'm#$

& C'H

' ' C

H

" * C

+H

,

C+H

, " C+H+ H

C(%/T)

∆a ∆b ∆


20/49

Cp/R A B(T)

Ben!eno(g) 0*20) /*+1E02 1*//E05

Etileno(g) 1*.2. 1*..E02 .*/+E0)

Etilben!eno(g) 1*12. 5*5.E02 1*85E05

/*,/ 1*+.E01 1*1/E05

C(%/T)

∆a ∆b ∆


21/49

Substream: !I"ED

!#$e %$#& $bm#$'(r

ESTIRENO STR!AIN !OLE%LO< !I"ED ESTIRENO

ETILBEN STR!AIN !OLE%LO< !I"ED ETILBEN

-IDROGEN STR!AIN !OLE%LO< !I"ED -IDROGEN

AGUA STR!AIN !OLE%LO< !I"ED AGUA

T#ta$ %$#& $bm#$'(r STR!AIN !OLE%L!" !I"ED T#ta$ %$#& $b'(r STR!AIN !ASS%L!" !I"ED

T#ta$ %$#& ut'(r STR!AIN VOL%L!" !I"ED

Temerature % STR!AIN TE!P !I"ED

Pressure s3a STR!AIN PRES !I"ED

Va#r %ra STR!AIN V%RAC !I"ED

L34u3 %ra STR!AIN L%RAC !I"ED

S#$3 %ra STR!AIN S%RAC !I"ED

E6t(a$7 Btu'$bm#$ STR!AIN -!" !I"ED

E6t(a$7 Btu'$b STR!AIN -!" !I"ED

Stream ID 1 2 3 4

From B1 B2 B3

To B1 B2 B3 B4

Phase LIQID !I"ED #$P%& #$P%&

S'(stream) !I"ED

!o*e F*o+ *(mo*,hr

ESTI&E-% 0.0 3.774367 3.774367 3.77436

ETILBE- 3.125000 7.847927 7.847927 7.84792

ID&%E- 0.0 2.51951E/3 2.51951E/3 2.51951E/

$$ 0.0 9.375000 9.375000 9.37500

Tota* F*o+ *(mo*,hr 3.125000 20.99981 20.99981 20.99981

Tota* F*o+ *(,hr 331.7731 1395.198 1395.198 1395.19

Tota* F*o+ 't,hr 6.148979 23.05828 15311.68 25260.5

Temerat're F 77.00000 /31.15674 500.0000 1112.00

Press're sia 14.00000 14.00000 14.00000 14.0000

#aor Fra 0.0 1.64536E/5 1.000000 1.00000

Li'i Fra 1.000000 .9999835 0.0 0.

So*i Fra 0.0 0.0 0.0 0.

Entha* Bt',*(mo* /4798.421 /49019.71 /19102.66 3823.09

Entha* Bt',*( /45.19675 /737.8197 /287.5235 57.5432

Entha* Bt',hr /14995.07 /1.0294E6 /4.0115E5 80284.3

Entro Bt',*(mo*/& /105.1360 /72.69617 /27.35766 /9.08260


22/49

Entro Bt',*(/& /.9902856 /1.094186 /.4117735 /.136706

Densit *(mo*,'t .5082144 .9107279 1.37149E/3 8.31329E/

Densit *(,'t 53.95580 60.50749 .0911198 .055232

$era:e !; 106.1674 66.43861 66.43861 66.43861

Li #o* 60F 't,hr 6.110143 24.98444 24.98444 24.9844


23/49

0 $bm#$'(r STR!AIN ! /*,,./)),5 $bm#$'(r

/*125 $bm#$'(r STR!AIN ! ,*8.,+2)8/ $bm#$'(r

0 $bm#$'(r STR!AIN ! 0*00251+5 $bm#$'(r

0 $bm#$'(r STR!AIN ! +*/,5$bm#$'(r

/*125 $bm#$'(r STR!AIN ! 20*+++81/1 $bm#$'(r//1*,,/125 $b'(r STR!AIN ! 1/+5*1+8/5 $b'(r

)*1.8+,+/+ ut'(r STR!AIN V 2/*0582,5/ ut'(r

,, % STR!AIN TE /1*15),.1 %

1. s3a STR!AIN PR 1. s3a

0 STR!AIN V% 1*)5E05

1 STR!AIN L% 0*++++8/55

0 STR!AIN S% 0

.,+8*.21.Btu'$bm#$ STR!AIN - .+01+*,12Btu'$bm#$

.5*1+),5Btu'$b STR!AIN - ,/,*81+)8Btu'$b

Estireno

5 6 7 8 9 10 1

B4 B5 B6 B6 B7 B8 B

B5 B6 B7 B8 B

#$P%& !I"ED #$P%& LIQID LIQID LIQID L

6.521141 6.521141 .0124520 6.508689 0.0 0.0

5.101152 5.101152 .0163449 5.084808 0.0 0.0

2.749294 2.749294 2.746588 2.70601E/3 0.0 0.0

9.375000 9.375000 .5924778 8.782522 8.782522 8.782522

23.74659 23.74659 3.367863 20.37872 8.782522 8.782522

1395.198 1395.198 19.24265 1375.956 158.2196 158.2196

27261.22 1408.800 1384.934 23.86636 2.549844 2.759945

1040.000 77.00000 77.00000 77.00000 77.00000 212.0000

14.00000 14.00000 14.00000 14.00000 14.00000 14.00000

1.000000 .1418251 1.000000 0.0 0.0 0.0

0.0 .8581749 0.0 1.000000 1.000000 1.000000

0.0 0.0 0.0 0.0 0.0 0.0

6914.461 /34519.91 /17994.63 /37250.94 /1.2370E5 /1.2106E5

117.6857 /587.5366 /3149.434 /551.7086 /6866.662 /6720.101

1.64195E5 /8.1973E5 /60603.44 /7.5913E5 /1.0864E6 /1.0633E6

/5.397625 /54.73088 /1.330114 /63.55609 /40.10222 /35.71505


24/49

/.0918687 /.9315318 /.2327975 /.9413036 /2.226011 /1.982487

8.71076E/4 .0168559 2.43179E/3 .8538681 3.444338 3.182136

.0511788 .9903452 .0138942 57.65251 62.05071 57.32708

58.75364 58.75364 5.713608 67.51922 18.01528 18.01528

27.01143 27.01143 2.582452 24.42898 2.539319 2.539319


25/49

STR!AIN ! /*,,./)),5 $bm#$'(r STR!AIN !

STR!AIN ! ,*8.,+2)8/ $bm#$'(r STR!AIN !

STR!AIN ! 0*00251+5 $bm#$'(r STR!AIN !

STR!AIN ! +*/,5$bm#$'(r STR!AIN !

STR!AIN ! 20*+++81/1 $bm#$'(r STR!AIN !STR!AIN ! 1/+5*1+8/5 $b'(r STR!AIN !

STR!AIN VO 15/11*)8// ut'(r STR!AIN V

STR!AIN TE 500 % STR!AIN TE

STR!AIN PR 1. s3a STR!AIN PR

STR!AIN V% 1 STR!AIN V%

STR!AIN L% 0 STR!AIN L%

STR!AIN S% 0 STR!AIN S%

STR!AIN - 1+102*))/ Btu'$bm#$ STR!AIN -

STR!AIN - 28,*52/5/Btu'$b STR!AIN -

12 13 14 15

B9 B9 B9

B1 B1

QID #$P%& LIQID LIQID LIQID

6.508689 6.45080E/7 2.734155 3.774367 0.0

5.084808 1.20724E/6 .3620476 4.722927 0.0

2.70601E/3 1.86507E/4 1.1902E/26 2.51951E/3 0.0

0.0 0.0 0.0 0.0 9.375000

11.59620 1.88360E/4 3.096203 8.499813 9.375000

1217.736 5.71332E/4 323.2041 894.5320 168.8932

22.08979 .0765097 6.594553 16.24009 2.721859

77.00000 70.00000 288.6302 70.00000 77.00000

14.00000 14.00000 14.00000 14.00000 14.00000

0.0 1.000000 0.0 0.0 0.0

1.000000 0.0 1.000000 1.000000 1.000000

0.0 0.0 0.0 0.0 0.0

23229.79 249.8688 48874.02 17097.22 /1.2370E5

221.2116 82.37810 468.1992 162.4572 /6866.662

2.69377E5 .0470652 1.51324E5 1.45323E5 /1.1597E6

/88.48601 /.5753052 /65.46142 /92.18955 /40.10222


26/49

/.8426306 /.1896697 /.6271017 /.8759820 /2.226011

.5249575 2.46191E/3 .4695091 .5233847 3.444338

55.12665 7.46744E/3 49.01076 55.08172 62.05071

105.0116 3.033195 104.3872 105.2414 18.01528

21.88966 1.63552E/4 5.725841 16.16368 2.710624


27/49

/*,,./)),5 $bm#$'(r STR!AIN ! )*5211.11. $bm#$'(r

,*8.,+2)8/ $bm#$'(r STR!AIN ! 5*101152.. $bm#$'(r

0*00251+5 $bm#$'(r STR!AIN ! 2*,.+2+/+ $bm#$'(r

+*/,5 $bm#$'(r STR!AIN ! +*/,5 $bm#$'(r

20*+++81/1 $bm#$'(r STR!AIN ! 2/*,.)58,5 $bm#$'(r1/+5*1+8/5 $b'(r STR!AIN ! 1/+5*1+8/5 $b'(r

252)0*5/.2 ut'(r STR!AIN V 2,2)1*215) ut'(r

1112 % STR!AIN TE 10.0 %


1 STR!AIN V% 1

0 STR!AIN L% 0

0 STR!AIN S% 0

/82/*0+581Btu'$bm#$ STR!AIN - )+1.*.)108Btu'$bm#$

5,*5./2858Btu'$b STR!AIN - 11,*)85),2Btu'$b


28/49


29/49

STR!AIN ! )*5211.11. $bm#$'(r STR!AIN !

STR!AIN ! 5*101152.. $bm#$'(r STR!AIN !

STR!AIN ! 2*,.+2+/+ $bm#$'(r STR!AIN !

STR!AIN ! +*/,5$bm#$'(r STR!AIN !

STR!AIN ! 2/*,.)58,5 $bm#$'(r STR!AIN !STR!AIN ! 1/+5*1+8/5 $b'(r STR!AIN !

STR!AIN VO 1.08*80005 ut'(r STR!AIN V

STR!AIN TE ,, % STR!AIN TE


STR!AIN V% 0*1.182512 STR!AIN V%

STR!AIN L% 0*8581,.88 STR!AIN L%


STR!AIN - /.51+*+1 Btu'$bm#$ STR!AIN -

STR!AIN - 58,*5/)58Btu'$b STR!AIN -


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0*012.520) $bm#$'(r STR!AIN ! )*508)8+08 $bm#$'(r

0*01)/..+. $bm#$'(r STR!AIN ! 5*08.80,5 $bm#$'(r

2*,.)58,8+ $bm#$'(r STR!AIN ! 0*002,0) $bm#$'(r

0*5+2.,,,) $bm#$'(r STR!AIN ! 8*,825222. $bm#$'(r

/*/),8)2)) $bm#$'(r STR!AIN ! 20*/,8,2.8 $bm#$'(r1+*2.2).55 $b'(r STR!AIN ! 1/,5*+55, $b'(r

1/8.*+//)8 ut'(r STR!AIN V 2/*8))/)2. ut'(r

,, % STR!AIN TE ,, %


1 STR!AIN V% 0

0 STR!AIN L% 1

0 STR!AIN S% 0

1,++.*)/Btu'$bm#$ STR!AIN - /,250*+/+Btu'$bm#$

/1.+*./.Btu'$b STR!AIN - 551*,08)2Btu'$b


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STR!AIN ! 0 $bm#$'(r STR!AIN !



STR!AIN ! 8*,825222. $bm#$'(r STR!AIN !

STR!AIN ! 8*,825222. $bm#$'(r STR!AIN !STR!AIN ! 158*21+5+, $b'(r STR!AIN !

STR!AIN VO 2*5.+8./52 ut'(r STR!AIN V

STR!AIN TE ,, % STR!AIN TE





STR!AIN - 12/,0.*85 Btu'$bm#$ STR!AIN -

STR!AIN - )8))*))2/Btu'$b STR!AIN -


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0 $bm#$'(r STR!AIN ! )*508)8+08 $bm#$'(r

0 $bm#$'(r STR!AIN ! 5*08.80,5 $bm#$'(r

0 $bm#$'(r STR!AIN ! 0*002,0)$bm#$'(r

8*,825222. $bm#$'(r STR!AIN ! 0 $bm#$'(r

8*,825222. $bm#$'(r STR!AIN ! 11*5+)202) $bm#$'(r158*21+5+, $b'(r STR!AIN ! 121,*,/)11 $b'(r

2*,5++.5/1 ut'(r STR!AIN V 22*08+,+18 ut'(r

212 % STR!AIN TE ,, %


0 STR!AIN V% 0

1 STR!AIN L% 1

0 STR!AIN S% 0

1210).*51Btu'$bm#$ STR!AIN - 2/22+*,+/)Btu'$bm#$

),20*101/Btu'$b STR!AIN - 221*211)/2Btu'$b


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STR!AIN ! )*.5E0, $bm#$'(r STR!AIN !

STR!AIN ! 1*21E0) $bm#$'(r STR!AIN !

STR!AIN ! 0*00018)5 $bm#$'(r STR!AIN !


STR!AIN ! 0*000188/5 $bm#$'(r STR!AIN !STR!AIN ! 0*0005,1// $b'(r STR!AIN !

STR!AIN VO 0*0,)50+,5 ut'(r STR!AIN V

STR!AIN TE ,0 % STR!AIN TE





STR!AIN - 2.+*8)88., Btu'$bm#$ STR!AIN -

STR!AIN - 82*/,81025Btu'$b STR!AIN -


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39/49

2*,/.15502 $bm#$'(r STR!AIN ! /*,,./)),5 $bm#$'(r

0*/)20.,5, $bm#$'(r STR!AIN ! .*,22+2)8/ $bm#$'(r

1*1+E2) $bm#$'(r STR!AIN ! 0*00251+5 $bm#$'(r

0 $bm#$'(r STR!AIN ! 0 $bm#$'(r

/*0+)2025+ $bm#$'(r STR!AIN ! 8*.++81/0+ $bm#$'(r/2/*20.05 $b'(r STR!AIN ! 8+.*5/1+,5 $b'(r

)*5+.55/1. ut'(r STR!AIN V 1)*2.0088/ ut'(r

288*)/01,+ % STR!AIN TE ,0 %


0 STR!AIN V% 0

1 STR!AIN L% 1

0 STR!AIN S% 0

.88,.*0212Btu'$bm#$ STR!AIN - 1,0+,*221,Btu'$bm#$

.)8*1++1,+Btu'$b STR!AIN - 1)2*.5,2/2Btu'$b


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STR!AIN ! 0 $bm#$'(r



STR!AIN ! +*/,5 $bm#$'(r

STR!AIN ! +*/,5 $bm#$'(rSTR!AIN ! 1)8*8+/25 $b'(r

STR!AIN VO 2*,2185852ut'(r

STR!AIN TE ,,%

STR!AIN PR 1.s3a

STR!AIN V% 0

STR!AIN L% 1

STR!AIN S% 0

STR!AIN - 12/,0.*85 Btu'$bm#$

STR!AIN - )8))*))2/Btu'$b


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Streams 1 2 / .

B1 B2 B/ B+

B1 B2 B/

LIQUID LIQUID VAPOR VAPOR

Substream: !I"ED

!#$e %$#& $bm#$'(r-2O +*/,5 +*/,5 +*/,5 +*/,5

C8-8 0 1*.,8,,) 1*.,8,,) 1*.,8,,)

C8-10 /*125 8*80.+,) 8*80.+,) 8*80.+,)

-2 0 +*),E0/ +*),E0/ +*),E0/

T#ta$ %$#& $bm#$'(r 12*5 1+*))8.2 1+*))8.2 1+*))8.2

T#ta$ %$#& $b'(r 500*))). 125,*,/1 125,*,/1 125,*,/1

T#ta$ %$#& ut'(r 8*5.2,05 20*2.5)1 1*/8E90. 1*/8E90.

Temerature % ,, ,,*0,1/1 500 500

Pressure s3a 1.*)+5+5 1.*)+5+5 1.*)+5+5 1.*)+5+5

Va#r %ra 0 0*00E900 1 1L34u3 %ra 1 1 0 0

S#$3 %ra 0 0 0 0

E6t(a$7 Btu'$bm#$ +/20,*)5 )288)*+8 2818/*2) 2818/*2)

E6t(a$7 Btu'$b 2/2,*0+ +8/*.2,+ ..0*,/0. ..0*,/0.

E6t(a$7 Btu'(r 1*1,E90) 1*2.E90) 5*5.E905 5*5.E905

E6tr#7 Btu'$bm#$R 5)*/)0,, 8.*/2)55 28*81.,. 28*81.,.

E6tr#7 Btu'$bR 1*.0,1.. 1*/18, 0*.50)055 0*.50)055

De6s3t7 $bm#$'ut 1*.)/2/, 0*+,1.+0) 1*./E0/ 1*./E0/

De6s3t7 $b'ut 58*)0,., )2*12/)/ 0*0+1250+ 0*0+1250+

Aera;e !< .0*05//1 )/*+.),1 )/*+.),1 )/*+.),1

L34 V#$ )0% ut'(r 8*820,), 22*).8,8 22*).8,8 22*).8,8


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5 ) , 8 + 10

B. B5 B) B,

B10 B+ B. B5 B) B)

VAPOR VAPOR VAPOR !I"ED VAPOR LIQUID

+*1285,2 +*/,5 +*/,5 +*/,5 0*2.).28/ +*1285,2

0 1*.,8,,) .*5)0518 .*5)0518 0*01,50/5 .*5./01.

0 8*80.+,) 5*,2/2/. 5*,2/2/. 0*0/5/22+ 5*)8,+11

0 +*),E0/ /*0+1.11 /*0+1.11 /*081,.1 +*),E0/

+*1285,2 1+*))8.2 22*,501) 22*,501) /*/80++) 1+*/)+1,

1).*.5/8 125,*,/1 125,*,/1 125,*,/1 1)*2250, 12.1*50)

1*1,E90. 2*2)E90. 2*.+E90. 1/.)*51) 1/2.*+85 21*5/10/

12+2 1112 10.0 ,, ,, ,,

1.*)+5+5 1.*)+5+5 1.*)+5+5 1.*)+5+5 1.*)+5+5 1.*)+5+5

1 1 1 1*.+E01 1 00 0 0 0*851/85+ 0 1

0 0 0 0 0 0

+/258*/) 5+5/*/5+ .2.*/5/5 .*2/E90. ,11.*8+. .*8.E90.

51,)*)2) +/*0+8,) ,*),581, ,).*/,58 1.82*)0+ ,5.*+8+.

8*51E905 1*1,E905 +*)5E90/ +*)1E905 2*.1E90. +*/,E905

0*/,5).55 11*0+)85 )*00555 5,*.//15 1*1+)0+5 ),*2.+).

0*020851. 0*1,/5/2, 0*108)2++ 1*0/88)) 0*2.+2./) 1*0.+185

,*82E0. 8*,1E0. +*1/E0. 0*01)8+55 2*55E0/ 0*8++5+/1

0*01.08.1 0*055,18/ 0*050.8// 0*+/.0)/1 0*0122.5. 5,*))12/

18*01528 )/*+.),1 55*28..8 55*28..8 .*,+8+02 ).*0+,02

2*)/+/,. 22*).8,8 2.*+22+) 2.*+22+) 2*81)/08 22*10))5


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11 12 1/ 1.

B8 B10 B1

B, B, B8 B8

!I"ED LIQUID LIQUID LIQUID

0 +*1285,2 0 0 /*0,E900

.*5./01. 0 /*0).2.) 1*.,8,,) 0*++,.

5*)8,+11 0 ,*+/E0/ 5*),++,)

+*),E0/ 0 1*/5E+2 +*),E0/

10*2.0) +*1285,2 /*0,21,+ ,*1)8.22

10,,*052 1).*.5/8 /1+*+881 ,5,*0).5 /*.828)/),/

2/*1.8.) 2*)50/1/ )*5182.5 11*.0)58

,, ,, 2+/*,,0) /,,*++/. 6#6se6se

1.*)+5+5 1.*)+5+5 1.*)+5+5 1.*)+5+5

8*,8E0. 0 0 00*+++121+ 1 1 1

0 0 0 0

1),/.*)1 1*2/E905 5.,+0*,2 10015*0/

15+*112. )81,*)/1 52)*0.11 +.*82+/5

1*,1E905 1*12E90) 1*)8E905 ,*18E90.

+2*58))) /8*85),+ )2*8.5)/ 1)8*.+.2

0*880/12) 2*15)8,+ 0*)0//,5, 1*5+5.22

0*..2/8,8 /*...//8 0*.,1/1++ 0*)28..).

.)*52802 )2*050,1 .+*0+11. ))*/,088

105*1,., 18*01528 10.*15), 105*)11

1+*.),28 2*)/+/,. 5*)/+2, 1/*82802


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t#6'>a est3re6#


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R6 1

Et3$ Est3re6#

vi A B(T)

Estireno 1 2*05 5*02E02 1*),E05

1 /*2.+ .*22E0. 8*/0E90.

Etilben!eno 1 1*12. 5*5.E02 1*85E05

.*1,5 .*,,E0/ 8*/0E90.

R(J/mol K ) 8*/1. .*18E900 .*,,E0/ 8*/0E90.

Tabla . ΔCp rxn a diferentes Temperaturas GrJ# D

T (K) ΔCp rxn (J/mol k)

550 2.09!""

5#5 2.2$!""

%00 2.&$!""

%25 2.#0!""

%50 2.92!""%#5 '."&!""

#00 '.'$!""

#25 '.%'!""

#50 '.$$!""

##5 &."&!""

$00 &.&2!""

$25 &.#0!""

$50 &.99!""

$#5 5.2$!""900 5.59!""

925 5.90!""

950 %.2'!""

9#5 %.5%!""

Cl!ulo ∆Cp r.n

C(%/T)

H

∆a ∆b ∆

/*00E9

.*00E9

5*00E9

)*00E9

,*00E9

∆ π ρξν


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s T

800 820 8.0 8)0 880 +00 +20 +.0 +)0 +11

11

11

11

11

T($)


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80 1000

analisis termodinamico estireno

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