annexure-1 terms of referencesenvironmentclearance.nic.in/writereaddata/formb/tor/additional...mass...

ANNEXURE-1

M/s. RAMDEV CHEMICAL INDUSTRIES UNIT-(II)

TERMS OF REFERENCES

• TOR prescribed by MoEF & CC for this sector will be taken into account.

ANNEXURE-2

M/s. RAMDEV CHEMICAL INDUSTRIES (UNIT-II)

LIST OF PRODUCTS

Sr.

No. Products Existing

Quantity as

per CCA-

AWH 73496

(MT/Month)

Quantity as

per EC

J-

11011/993/2

008-IA II

(I)*

(MT/Month)

Additional

Quantity

(MT/

Month)

Total

Quantity

after

proposed

Expansion

(MT/Month)

1. CPC Blue Crude 45 360 655 700

2. Pigment Alpha Blue

(Blue 15.0 & 15.1)

7.5 160 97.5 105

3. Activated CPC Blue

(Only grinding process)

100 300 830 930

4. Phthalocyanine Beta

Blue (Pigment Blue

15.3 & 15.4)

300 630 330 630

5. Phthalocyanine Beta

Blue (Pigment Blue

15.3 & 15.4) (only

grinding process)

200 -- 0 200

6. Recovered Inorganic

products (Ammonium

Sulphate 100% base)

OR

Recovered Inorganic

products (Ammonium

Sulphate Solution )

60

315

305 665

3500

725

3815

7. Calcium Carbonate 45 -- 315 360

8. Copper salt -- -- 5.5 5.5

9. Ammonium Carbonate

Solution (100%)

OR

Ammonium Carbonate

Solution

40

270

-40

-270

0

0

Total 797.5 2858 3655.5

*This EC is converted into CTE. (CTE No:-81416)

ANNEXURE-2


AS PER CTE No: 81416

Sr.

No. Products Existing

Quantity as

per CCA-

AWH 73496

(MT/Month)

Quantity as

per granted

CTE:-81416

1. CPC Blue Crude 45 360

2. Pigment Alpha Blue

(Blue 15.0 & 15.1)

7.5 00

3. Activated CPC Blue

(Only grinding process)

100 930

4. Pthalocyanine Beta Blue

(Pigment Blue 15.3 &

15.4)

(Solvent base, water base)

300 00

5. Pthalocyanine Beta Blue

(Pigment Blue 15.3 &

15.4) (only grinding

process)

200 200

6. Recovered Inorganic

products (Ammonium

Sulphate 100% base)

OR

Recovered Inorganic

products (Ammonium

Sulphate Solution )

60

315

305

7. Calcium Carbonate 45 45

8. Ammonium Carbonate

Solution (100%)

OR

Ammonium Carbonate

Solution

40

270

0

Total 797.5 1840

*This CTE is not converted into CCA.

ANNEXURE-3


LIST OF PARTNERS

Sr.

No. Name of the Partner Address Contact No.

1. Mr. Sureshkumar

Mavjibhai Bhingaradia

507/3, Aavkar Society, G.I.D.C.,

New Colony, Ankleshwar- 393

002.

02646- 252828

2. Mrs.Manju S.

Bhingaradia



002.

02646- 252828

3. Mrs. Viruben M.

Bhingaradia



002.

02646- 252828

4. Mr. Mavjibhai M.

Bhingaradia



002.

02646- 252828

16. MT. W I D E R O A D

SITE PLANSCALE - 1:500

20. MT. W I D E R O A D

²

ANNEXURE 5


EXISTING & PROPOSED PRODUCT RAW MATERIAL LIST

NAME OF THE

PRODUCT

NAME OF RAW MATERIALS QUANTITY

MT/MT OF

PRODUCT

QUANTITY

MT/MONTH

COPPER

PHTHALOCYANINE

BLUE CRUDE

Phthalic Anhydride 1.075 752.5

Carbamide Salt/NH3 gas 1.505 1053.5

Cuprous Chloride 0.193 135.1

Ammonium Molybdate 0.003 2.1

TCB/NB/ONT/ISOL 0.02 14

Spent Sulphuric Acid (30% to 40%) 2.00 1400

TOTAL 4.796 3357.2

AMMONIUM

SULFATE

Ammonium Carbonate Solution

(20 to 22%)

3.9 2827.5

Dilute sulfuric from CPC filtrate

(20 to 25%)

2.4 1740

Sulfuric Acid 70% 0.4 290

TOTAL 6.7 4857.5

PHTHALOCYANINE

BETA BLUE

(PIGMENT BLUE

15.3 & 15.4)

CPC Blue Crude 1.03 648.9

Caustic Soda Flakes 0.011 6.93

Dilute Hydrochloric acid (HCl) 0.02 12.6

Xylene/IBA 0.01 6.3

Salt 0.1 63

TOTAL 1.171 737.73

PIGMENT ALPHA

BLUE

(BLUE 15.0 & 15.1)

CPC Blue Crude 1.1 115.5

Sulphuric Acid (98%) 4 420

Dispersing agent/Additives 0.001 0.105

Caustic Flakes 0.1 10.5

TOTAL 5.201 546.1

ACTIVATED CPC

BLUE

CPC Crude 0.91 846.3

Common Salt 0.09 83.7

ANNEXURE 5


TOTAL 1.00 930

PTHALOCYANINE

BETA BLUE

(PIGMENT BLUE

15.3 & 15.4)

(ONLY GRINDING

PROCESS)

CPC Crude 1.00 200.00

TOTAL 1.00 200

COPPER SALT Acidic filtrate from CPC blue 312.5 1719

TOTAL 312.5 1719

ANNEXURE-6

MANUFACTURING PROCESS

1. COPPER PHTHALOCYANINE BLUE CRUDE

MANUFACTURING PROCESS FOR CPC BLUE CRUDE

Phthalic Anhydride,Carbamide salt/NH3 gas and solvent (TCB/NB/ONT/ISOL) are

mixed in the vessel equipped with heating arrangement (by thermo pack boiler for

circulation of high temperature oil) and stirrer. Cuprous chloride and ammonium

molybdate are then added.

- The Mixture is heated up slowly for 20 hours at 180°C.

- Ammonia gas is liberated with the formation of phthalamide at 135 °C. Formation of

copper phthalocyanine takes place at a temp 185°C with release of ammonia gas and

CO2 gas.

- The ammonia gas and CO2 gas are scrubbed through scrubbers under water circulation.

The generated ammonium carbonate solution is converted into ammonium sulfate.

- The reaction mass is stirred till formation of copper phthalocyanine is completed.

- The reaction mass is then transferred to rotary vacuum drier and solvent is recovered

completely under vacuum from rotary vacuum drier.

- The dried powder of Copper phthalocyanine is then purified in MSRL brick lined vessel

by treating it with acidic effluent (diluted sulphuric acid) generated during manufacture

of pigment Alpha Blue.

- The resulting mixture is filtered in filter press and wet cake is washed with water .

- Filtrate is transferred into collection tank and use for the manufacturing of ammonium

sulfate. Washing water is treated in ETP. While the wet press cake of CPC blue is dried

in dryer/spin flash dryer, pulverized and packed into HDPE bags.

ANNEXURE-6

CHEMICAL REACTION FOR CPC BLUE CRUDE:

PROCESS FLOW DIAGRAM FOR CPC BLUE CRUDE:

Ammonium Carbonate solution

Packing

1. Phthalic Anhydried

2. Carbamide Salt/NH3 gas

3. Cuprous Chloride

4. Ammonium Molybdate

5. Solvent

(ONT/TCB/NB/ISOL)

Glass Lined

Vessel

Ammonia (Gas)

CO2 Gas

Scrubber

Water

Rotary Vacuum

Dryer

Solvent Recovered

MSRL Spent H2SO4

from Alpha

Filter Press

Drying (SFD)

Ammonium Sulfate

Washing water Filterate for Mfg of ammonium sulfate

Washing water To ETP

ANNEXURE-6

Input Kg. Output Kg.

Phthalic Anhydride 1075 Mass 4126

Carbomide salt/Ammonia gas 1505

(NH3) & CO2 gas to water

scrubber 800

Cuprous Chloride 193

Ammonium Molybdate 3

ONT 2150

TOTAL 4926 TOTAL 4926

Input Kg Output Kg.

Mass 4126 Mass 1976

Recovered solvent 2130

Atmospheric solvent loss 20



Mass 1976 Slurry 4526.00

Live steam 550

Dilute sulfuric acid from Alpha

Blue Plant (30% to 40%) 2000

TOTAL 4526 TOTAL 4526.00

Input Kg. Input Kg.

Slurry 4526 Mass 2100

Filterate (20%to 25%) for

mfg of ammonium sulphate 2500

Water 2800

Water from MEE condenset 1780

Effluent water to ETP &

MEE 4506



Mass 2100 Water loss 1100.00

Product 1000


Input Kg Output Kg

Water from MEE condenset 3240 Water loss 40

(NH3) & CO2 gas 800


MASS BALANCE OF TYPICAL BATCH OF CPC BLUE CRUDE

FILTER PRESS

AND WASHING

SFD/DRYER

MASS BALANCE ACROSS SCRUBBER

REACTOR

RVD

MSRL-BL

SCRUBBERAmmonium Carbonate

solution(20 to 22 %) 4000

ANNEXURE-6

2. AMMONIUM SULPHATE

MANUFACTURING PROCESS FOR AMMONIUM SULPHATE

The Ammonium Carbonate solution is generated from the production of CPC Blue which

is reacted with Spent Sulfuric acid/Sulfuric Acid in the reactor. After the completion of

reaction, mass is charged into distillation vessel/MEE for the recovery of ammonium

sulfate and condensate of MEE is reused into Scrubber/Process.

CHEMICAL REACTION FOR AMMONIUM SULPHATE

(NH4)2 CO3 + H2SO4 (NH4)2SO4 + H2O + CO2


Ammonium Carbonate

Solution(20 to 22%) 4000

CPC filtrate (20 to

25%) after copper

recovery 2492

Sulfuric Acid 70% 425


Input Kg Output Kg.

Evaporation loss 882

Water to cpc

manufacturing and

scrubber 5000

Ammonium

Sulphate 1035


AMMONIUM SULFATE

Reaction Mass 6917

Reaction Mass

6917

REACTOR

DISTILLATION/MEE

ANNEXURE-6

3. PIGMENT ALPHA BLUE (BLUE 15.0 & 15.1)

MANUFACTURING PROCESS FOR PIGMENT ALPHA BLUE

(BLUE 15.0 & 15.1)

- CPC blue crude is to be charged in concentrated sulphuric acid and agitated in a suitable

reactor in order to make a homogeneous mass.

- The above reaction mass is to be drown slowly into ice cold water in a rubber lined brick

lined reactor.

- After 2 hours stirring, the slurry is to be filtered in a filter press and washed with water.

- The filtrate, such obtained of around 30% to 40% Sulphuric Acid which is used in the

manufacturing process of CPC Blue.

- while the press cake from the filter press is unloaded and processed further by

neutralizing them along with dispersing agent / additives and caustics soda to attain the

highest color value and chemical properties like light fastness, chemical resistance and

heat stability.

- Such treated reaction mass (pigment slurry) is to be filtered in a filter press, washed with

water and press cake is unloaded and dry in Dryer/SFD.

- Finally, pigment Alpha Blue (Blue 15.0 & 15.1) is classified, Blended and packed in

HDPE Bags/drums.

ANNEXURE-6

PROCESS FLOW DIAGRAM OF PIGMENT ALPHA BLUE (BLUE 15.0 & 15.1)

30% to

40%

98% H2SO4

Reaction Vessels

CPC Blue Crude

Drowning

Vessel

Chill Water

Filtration

Dilute

H2SO4

DRYER/SFD

Washing Water

Pulverizing

Dilute H2SO4

collection tank

for CPC Blue

Packing

TO ETP

ANNEXURE-6

MATERIAL BALANCE FOR PIGMENT ALPHA BLUE (BLUE 15.0 & 15.1)

Input Kg Output Kg

CPC blue crude 1111

Sulfuric acid(98%) 4000

Total 5111 Total 5111

Input Kg Output Kg

Reaction Mass 5111 Reaction mass 9555

Chilled water 4444


Input Kg Output Kg

Reaction mass 9555 Wet cake 2255

Water 6000

Dilute H2SO4 to CPC

plant(30% to 40%) 13300


Input Kg Output Kg

Reaction mass 2255 Reaction mass 2356

Dispersing agent/Additives 1

Caustic Flakes 100


INPUT KG OUTPUT KG

Reaction mass 2356 WET CAKE 2255

water for washing 16900 EFFLUENT TO ETP 17001


Input Kg Output Kg

Wet cake 2255 Alpha blue 1000



DROWING

FILTER PRESS

SFD/DRYER

PULVERISING &

PACKING

REACTION VESSEL

FILTER PRESS AND

WASHING

Reaction mass 5111REACTOR-1

ANNEXURE-6

4. ACTIVATED CPC BLUE (ONLY GRINDING PROCESS)

MANUFACTURING PROCESS FOR ACTIVATED CPC BLUE

CPC Blue Crude is to be charged with salt in the grinding mill. Where sheering,

hammering and grinding process occurs and as a result finest particles of Activated CPC

Blue is obtained, which is called Activated CPC Blue. In this process by which desired

particles shape and size are attained. In this way after the physical process, such obtained

Activated CPC Blue is to be discharged from the grinding mill and packed in HDPE

Bags/Drums.

PROCESS FLOW DIAGRAM FOR ACTIVATED CPC BLUE

BALL MILL

ACTIVATED CPC BLUE

PACKING

1. CRUDE CPC BLUE

2. COMMON SALT

ANNEXURE-6

MATERIAL BALANCE FOR ACTIVATED CPC BLUE (GRINDING PROCESS)

INPUT KG OUTPUT KG

CPC Crude 1000 Activated CPC Blue 1100

Common salt 100


BALL MILL

5. PHTHALOCYANINE BETA BLUE (PIGMENT BLUE 15.3 & 15.4)

(ONLY GRINDING PROCESS)

MANUFACTURING PROCESS OF PHTHALOCYANINE BETA BLUE

(ONLY GRINDING PROCESS)

- CPC Blue Crude is to be charged in the grinding mill. Where sheering, hammering and

grinding process occurs and as a result finest particles of pigment beta Blue is obtained,

which is called Pigment Beta Blue.

- In this process no chemical process or reaction is involved but it is a physical process by

which desired particles shape and size are attained.

- In this way, after the physical process, such obtained Beta Blue is to be discharged from

the grinding mill and packed in HDPE Bags/Jambo.

PROCESS FLOW DIAGRAM FOR PHTHALOCYANINE BETA BLUE

(PIGMENT BLUE 15.3 & 15.4) (ONLY GRINDING PROCESS)

BALL MILL

CPC BLUE CRUDE

FINISHED PRODUCT

ANNEXURE-6

MATERIAL BALANCE OF PHTHALOCYANINE BETA BLUE (PIGMENT

BLUE 15.3 & 15.4) (ONLY GRINDING PROCESS)

INPUT KG OUTPUT KG

CPC Crude 1000

Pthalocyanine Beta

Blue(only grinding

process) 1000


BALL MILL

6. PHTHALOCYANINE BETA BLUE (PIGMENT BLUE 15.3 & 15.4)

MANUFACTURING PROCESS FOR PHTHALOCYANINE BETA BLUE

(PIGMENT BLUE 15.3 & 15.4)

CPC Blue Crude, is used for manufacturing of Beta blue. It is taken into Ball mill with

salt for grinding. Here the particle size of the material gets reduced. Then the grinded

material is taken into the reactor with Caustic Flakes. Caustic flakes are used to get

alkaline pH. The alkaline pH results in better dispersion of particles for pigmentation.

The mass is refluxed for pigmentation. Here the colour of the material gets enhanced due

to fine tuning with IBA/xylene.

This is only a physical process and does not involve any chemical reaction. After

completion of reflux, the mass is distilled for recovery of IBA/xylene. After recovery of

IBA/xylene, the mass is neutralized with hydrochloric acid to increase the particle size of

beta blue. The whole mass is filtered and washed by water in filter press. Generated

effluent from the filter press will be sent to ETP. Wet cake from filter press is dried in

dryer/SFD. Dried cake is the pulverized and packed for dispatch.

ANNEXURE-6

CHEMICAL REACTION FOR PHTHALOCYANINE BETA BLUE


ANNEXURE-6

PROCESS FLOW DIAGRAM FOR PHTHALOCYANINE BETA BLUE


Ball Mill

Reflux/ Pigmentation

Distillation

pH Adjustment

Filtration & Washing

Dryer/SFD

Pulverizing

Packing

Dispatch

CPC Blue

IBA/Xylene

Caustic Flakes

HCl

Recovered IBA/Xylene

Water

TO ETP

Salt

Water

ANNEXURE-6

MATERIAL BALANCE FOR PHTHALOCYANINE BETA BLUE


Input Kg Output Kg

copper phthalocyanine

Blue 1030 Reaction mass 1130

Salt 100


Input Kg Output Kg

Mass 1130 Mass 3461

Dilute HCL 20

Caustic soda flakes 11

Water 1800

IBA/Xyalene 500


Input Kg Output Kg

Mass 3461 Mass 3281

live Steam 320

Recovered IBA/Xylene 490

Atmosphere solvent loss 10


Input Kg Output Kg

Mass 3281 Mass 2730

Water for washing 4930 Effluent to ETP 5481


Input Kg Output Kg

Mass 2730 Pigment Beta Blue 1000



DRYER/SFD

PULVERIRE &

PACKING

DISTILLATION

FILTER PRESS

BALL MILL

REACTION VESSEL

ANNEXURE-6

SOLVENT RECOVERY

Solvents to be used: ONT/NB/TCB/ISOL/IBA/XYLENE

Reactor

Vessel

Primary

condenser

Secondary

condenser

Receiver

Vessel

Steam

Inlet

Steam

Outlet

Reflux line

Distribution box

Cooling water Inlet

Cooling water

Outlet

Vapour Inlet

Vapour Inlet

Cooling water

Outlet

Cooling water Inlet

Solvent

vapour

ANNEXURE-6

7 MANUFACTURING PROCESS OF COPPER SALT

Manufacturing Process :-

During the manufacturing process of CPC blue acidic filtrate is generated which will be sent into

copper recovery system for recovery of copper salt.

MATERIALBALANCE OF COPPER SALT:-

Input Kg Output Kg

Acidic filterate from CPC

blue 2500 Copper salt 8.0

Acidic filtrate to amonium

sulfate plant 2492


COPPR RECOVERY

SYSTEM

ANNEXURE-7

BRIEF DESCRIPTION OF GENERATED EFFLUENT FROM CPC BLUE

During the manufacturing of CPC blue two types of stream are generated.

1) Acidic filtrate(ML)

2) Acidic washing water

1) Generated acidic filtrate is collected in collection tank and sent to ammonium salt

manufacturing plant after copper recovery.

2) Generated acidic washing water is neutralized with lime into neutralization tank.

After neutralization, treated effluent is sent to MEE for further treatment. During the

neutralization process ETP waste is generated, which will be sent to TSDF site and

generated MEE salt is also sent to TSDF site.

MEE condensate will be reused into process.

BRIEF DESCRIPTION OF GENERATED EFFLUENT FROM BETA BLUE ,

ALPHA BLUE AND OTHERS

-Generated effluent form the beta blue, alpha blue and others (Boiler blow-down,

Cooling tower blow-down, Soften water blow down etc) is neutralized with lime into

neutralization tank and send into RO for further treatment.

-During the neutralization generated sludge will be sent to TSDF site.

-RO permeate will be recycled in process and RO rejected will be treated in

conventional ETP.

-After treatment in conventional ETP, treated effluent will be sent to NCTL through

GIDC underground drainage system.

ETP UNITS:

Particulars No. Capacity in m3

Oil and Grease Tank 1 6.9

Equalization/Neutralization Tank 2 72.8

Primary Settling Tank 1 47.2

Filter press 2 36x36

Aeration Tank 1 350

Secondary Settling Tank 1 52.8

Secondary Treated Collection Tank 1 22.5

Treated Water Tank 1 22.5

Pressure Sand Filter 1 1.5

Pressure Carbon Filter 1 1

Holding Tank 4 90

Final Discharge Tank 1 150

Multi Effect Evaporator 1 100 KL

Copper recovery system 1 --

RO (2 stages) 1 200 + 100 KL

ANNEXURE-7

ETP FLOW DIAGRAM

COLLECTION

CUM

NUTRALAZINE

TANK 1

2

COPPER

RECOVER

Y SYSTEM

EFFLUENT COMING

FROM PLANT

MEE

COLLECTION

TANK

(HOLDING

TANK)

4 Nos.

AERATION

TANK

SST

TERTIARY

TREATMENT

TRATED EFFLUENT

STORAGE TANK

TREATED EFFLUENT TO FETP

THROGH GIDC UNDER GROUND

DRAINAGE

FILTER

PRESS

FILTER

PRESS

GENERATED SLUDGE TO TSDF SIDE

2-Stage RO

MEE salt to

TSDF Ro permeate to

recycle

RO reject

GENERATED SLUDGE TO TSDF SIDE

ANNEXURE-7

CHARACTERISTIC OF EFFLUENT

Sr.

No.

Parameters Before

Treatment

(at the ETP

inlet) mg/l

After Treatment

(at the ETP outlet

& FETP inlet)

mg/l

Standard Norms

prescribed

(FETP Inlet norms)

mg/l

1. pH 0-2 6.5-8.0 6.5-8.5

2. T.S.S in mg/L 200-250 100 ----

3. C.O.D. in mg/L 700-1000 < 300 1000

4. Ammonical

Nitrogen in ppm <75 < 25 75

ANNEXURE-8

DETAILS OF WATER CONSUMPTION

Sr.

No

Particulars Existing Water

Consumption

KL/Day

(As per CCA-

73496 AWH )

Proposed Water Consumption

KL/Day

(As per proposed expansion)

Total

Water Consumption

KL/Day

Fresh Recycle Fresh Recycle Total Fresh Recycle Total

1. Domestic 2.5 --- 2.5 0 2.5 5 0 5

2. Gardening /

Other use

0.5 --- 1.5 0 1.5 2 0 2

INDUSTRIAL WATER CONSUMPTION

3. Process 55.87 45.72 9.53 308.88 318.41 65.4 354.6* 420

4. Boiler 12 --- 10 0 10 22 0 22

5. Cooling 16.8 --- 13.2 0 13.2 30 0 30

6. Equip. &

Floor

Washing

2 --- 2 0 2 4 0 4

7. Softener

back wash

1 --- 1 0 1 2 0 2

Total

(Industrial)

87.67 45.72 35.73 308.88 344.61 123.4 354.6 478

TOTAL

(Domestic +

Industrial

+Gardening)

136.39

(Fresh

water=90.67+

Recycle

water=45.72)

348.61

(Fresh water=39.73 + Recycled

Water=308.88)

485

(Fresh water=130.4 +

Recycled water=354.6)

• *Breakup of KL/Day : 354.6 KL/Day

• Recycle from MEE/RO : 237.6 KL/Day

• Internal Recycle (during the mfg of ammonium sulfate) : 117.0 KL/Day

ANNEXURE-8

DETAILS OF WASTE WATER GENERATION

Sr.

No.

Particulars Existing Waste Water

Generation KL/Day (As

per CCA AWH -73496)

Proposed Waste

water

Generation

KL/Day

Total Waste

Water

Generation

after expansion

KL/Day

1. Domestic 1 1 2

2. Industrial

Process & Process

washing

34 246 280

Boiler 2.5 0 2.5

Cooling 1.5 0 1.5

Equip. & Floor

Washing

2 2 4

Softener back wash 1 1 2

Total Industrial 41 249 290

TOTAL (Domestic +

Industrial)

42 250 292*

*Existing industrial waste water discharge permission of the unit is 42 KL/Day

which will be continued after proposed expansion .Due to the proposed expansion

additional effluent generation will be 250 KL/Day from which 9 MTD sludge and

3.4 MTD MEE salt will be generated. Unit will dispose it at available TSDF site.

So due to the proposed expansion additional waste water generation will be

237.6** KLD which will be reused by the unit after treatment.

**237.6 KLD WATER BIFURCATION:-1) 96.6 KLD MEE Condensate

2) 141.0 KLD RO permeate***

***Unit is having booked permission of discharge into NCTL is 183 KLD. Unit will send this

RO (additional 141 KLD) permeate into NCTL when NCTL will start to take our additional

effluent as per booked quantity.

WATER BALANCE DIAGRAM & WASTE WATER GENERATION DIAGRAM

TOTAL WATER REQUIREMENT (130.4 KL/DAY GIDC FRESH WATER+237.6 FROM RO&MEE+117 INTERANAL RECYCLE

TOTAL PROCESS WATER (420 KLD)

(65.4 FRESH+237.6 FROM RO&MEE+

117 INTERNAL RECYCLE

WASHING

(04 KLD)

COOLING TOWER

(30KLD)

GARDENING

(02 KLD)

BOILER

(22KLD

FRESH

Makeup)

Effluent generation

from CPC

(105 KLD)

PRIMARY TREATMENT (187 KLD)

LOSS

(19.5 KLD)

BLOW DOWN

(2.5KL/DAY)

BLOW DOWN

(1.5KL/DAY)

LOSS

(28.5 KL/Day)

WASHING

(04KL/DAY)

Primary Treatment

(105 KLD)

MEE Salt

(3.4 MT/Day)

DOMESTIC

(05 KLD)

Sludge (4 MTD)

SOFT EN

WATER

(02 KLD)

(02 KL/DAY)

(02 KL/Day)

TREATED EFFLUENT TO FETP THROGH GIDC UNDER GROUND DRAINAGE

(42 KL/DAY)

LOSS

(3 KL/Day)

MEE

(100 KLD)

Sludge to

TSDF

(5 MTD)

MEE

permeate

(96.6 KLD)

Effluent generation

from Alpha and

Beta

(175 KLD)

2-STAGE RO

(183 KLD)

RO rejected to ETP

42 KLD

RO permeate

141 KLD

Internal

recycle*

(117 KL/DAY)

ANNEXURE 9

FUEL CONSUMPTION

POWER CONSUMPTION

SR.

NO

FUEL QUANTITY

(As per current CCA-

AWH-73496)

QUANTITY

(As per proposed

expansion)

TOTAL

1. Natural Gas 8000 NM3/Day 2000NM3/Day 10000 NM3/Day

2. LDO/Diesel 400 Lit/Day 1600Lit/Day 2000 Lit/Day

3. Coal/Briquette Coal=6 TPD OR

Briquette=10 TPD

--- Coal=6 TPD OR

Briquette=10

TPD

SR.

NO

POWER QUANTITY

(As per current CCA-

AWH-73496)

QUANTITY

(As per proposed

expansion)

TOTAL

QUANTITY

1. Electricity 1900 KVA 2100 KVA 4000 KVA

ANNEXURE 10

M/S. SUBHASRI PIGMENTS PVT. LTD., ANKLESHWAR

LIST OF HAZARDOUS CHEMICALS

Sr.

No.

List of Hazardous Chemicals

1. Phthalic anhydrides

2. Cuprous Chloride

3. Sulfuric acid

4. Xylene/IBA

5. ONT/NB/ISOL/TCB

6. Caustic Soda Lye/Flakes

7 Carbamide salt/NH3 gas

8 HCl

ANNEXURE-11

M/s. Jyoti Om Chemical Research Centre Pvt Ltd

HAZARDOUS WASTE GENERATION

Sr.

No.

Waste Category Quantity/

Year

(As per CCA-

AWH-73496

Existing)

Quantity/

Year

(As per

Proposed

Expansion)

Total Facility

1. ETP

Sludge

35.3 72-0 MT/Year 2500

MT/Year

3220

MT/Year

Collection, storage,

transportation,

disposal at TSDF-

BEIL

2. Discarded

Bags/Liners,

Discarded

Container

5.1 24,000

Nos/Year

10000

Nos/Year

34000

Nos/Year Collection, storage,

and

decontamination

3. Used/

Spent Oil

33.1 0.06 KL/Year 0.02

KL/Year

0.08

KL/Year


transportation,

disposal by selling

to register

re-refiner or

lubrication for nut

bolt.

4. MEE Salt 35.3 1224 MT/Year -- 1224

MT/Year


transportation,

Disposal by sell or

by send to TSDF

site.

ANNEXURE-12

FLUE GAS EMISSION

Sr.

No.

Stack Attached

To

Stack

Height

(m)

Fuel Consumption APCM

Type

of

Emission

Permissible

Limit

AS PER CCA No:-AWH-73496

1.Boiler

(IBR)(4TPH) 11 Natural gas ----

PM

SO2

NOx

150mg/NM3

100 PPM

50 PPM

2.

Thermic Fluid

Heater

(2 Nos)

(10 Lac Kcal/Hr)

11

(for each) Natural gas ----

PM

SO2

NOx

150mg/NM3

100 PPM

50 PPM

3. D.G.Set (For

emergency use

only)(125 KVA)

9 Diesel ----

PM

SO2

NOx

150mg/NM3

100 PPM

50 PPM

4.

Boiler (IBR)

(6 TPH)

21 Coal/Briquette

Multi cyclone

separator,

Bag filter and

Water scrubber

PM

SO2

NOx

150mg/NM3

100 PPM

50 PPM

AS PER PROPOSED EXPANSION

5.

D.G.Set (For

emergency use

only) (600 KVA)

09 Diesel ----

PM

SO2

NOx

150mg/NM3

100 PPM

50 PPM

6.

Thermic Fluid

Heater

(2 Nos)

(10 Lac Kcal/Hr)

11

for each Natural gas ----

PM

SO2

NOx

150mg/NM3

100 PPM

50 PPM

ANNEXURE-12

AFTER PROPOSED EXPANSION

Sr.

No.

Stack

Attached

To

Stack

Height

(m)

Fuel

Consumption APCM

Type

of

Emission

Permissible

Limit

1. Boiler

(IBR)(4TPH) 11 Natural gas ----

PM

SO2

NOx

150mg/NM3

100 PPM

50 PPM

2.

Thermic

Fluid Heater

(2 Nos)

(10 Lac

Kcal/Hr)

11

(for

each)

Natural gas ----

PM

SO2

NOx

150mg/NM3

100 PPM

50 PPM

3.

D.G.Set (For

emergency

use

only)(125

KVA)

9 Diesel ----

PM

SO2

NOx

150mg/NM3

100 PPM

50 PPM

4.

Boiler (IBR)

(6 TPH)

21 Coal/Briquette

Multi

cyclone

separator,

Bag filter

and

Water

scrubber

PM

SO2

NOx

150mg/NM3

100 PPM

50 PPM

5.

D.G.Set (For

emergency

use only)

(600 KVA)

09 Diesel ----

PM

SO2

NOx

150mg/NM3

100 PPM

50 PPM

6.

Thermic

Fluid Heater

(2 Nos)

(10 Lac

Kcal/Hr)

11

for

each

Natural gas ----

PM

SO2

NOx

150mg/NM3

100 PPM

50 PPM

ANNEXURE-13

PROCESS GAS EMISSION

As per Existing CCA No.: AWH-73496

Sr.

No.

APCM attached to Stack

Height

APCM Pollutant Remarks

1 Spin Flash Dryer

(2 Nos) (2 stack)

11 for each Bag Filter for

each

PM 150 mg/NM3

2. Stack attached with

Reactors

(1 common stack)

16 Water scrubber NH3 175 mg/NM3

For Proposed Expansion

3 Stack attached with

Reactors

(1 common stack)

16 Water

scrubber

NH3 175 mg/NM3

4. Spin Flash Dryer

(2 Nos) (2 stack)


each

PM 150 mg/NM3

ANNEXURE-13

PROCESS GAS EMISSION AFTER PROPOSED

EXPANSION

Sr.

No.

APCM attached to Stack

Height

APCM Pollutant Remarks

1 Spin Flash Dryer

(2 Nos) (2 stack)


each

PM 150 mg/NM3

2. Stack attached with

Reactor (1 common

stack)


3 Stack attached with

Reactor (1 common

stack)


4. Spin Flash Dryer

(2 Nos) (2 stack)


each

PM 150 mg/NM3

annexure-1 terms of referencesenvironmentclearance.nic.in/writereaddata/formb/tor/additional...mass...

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