annexure 9 choice based credit system structure from the academic...

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214 ANNEXURE – 9 CHOICE BASED CREDIT SYSTEM – STRUCTURE FROM THE ACADEMIC YEAR 2014–15 B.Sc CHEMISTRY SEM Part – I Part – II Part – III Part – IV Part – V (6 th Hr) ACC (6 th Hr) SLC I Sem. I Lang (6) II Lang (6) Core (4) Core (3) Allied Maths/Zoo (6/4) Allied Zoo. Lab (2) SBE (2) Total (30) NCC/NSS/PED. (3) Com.Eng (2) Comp.Lit (1) II Sem. I Lang (6) II Lang (6) Core (3) Core (3) Core Lab (3) Allied Maths/Zoo (6/4) Allied Zoo. Lab (2) SBE (2) Elec. EVS (1) Total (30) NCC/NSS/PED. (3) Com.Eng (2) Comp.Lit (1) Law and Society III Sem. I Lang (6) II Lang (6) Core (2) Core Lab (2) Allied Maths/Zoo (6/4) Allied Zoo. Lab (2) Allied Physics (4) Allied Physics Lab (2) NME (2) Total (30) NCC/NSS/PED. (3) Com.Eng (2) Comp.Lit (1) Human Rights IV Sem. I Lang (6) II Lang (6) Core (2) Core Lab (2) Allied Maths/Zoo (6/4) Allied Zoo. Lab (2) Allied Physics (4) Allied Physics Lab (2) NME (2) Total (30) NCC/NSS/PED. (3) Com.Eng (2) Comp.Lit (1) C Programming V Sem. Core (4) Core (4) Core (4) Core (3) Core Lab (3) Core Lab (3) Allied Physics (4) Allied Physics Lab (2) SBE (2) Elec. W.S. (1) Total (30) Com.Eng (2) Comp.Lit (1) Skill Devt – Career Guidance (3) Chemistry in daily life VI Sem. Core (3) Core (4) Core (4) Core Lab (3) Core Lab (3) Allied Physics (4) Allied Physics Lab (2) Elec. Project (5) Elec. VBE (2) Total (30) Com.Eng (2) Comp.Lit (1) Skill Devt – Career Guidance (3) –– Total 180 Hrs I Language Tamil II Language English SBE Skill – Based Electives SLC Self – Learning Course EVS Environmental Studies W.S. Women Studies

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Page 1: ANNEXURE 9 CHOICE BASED CREDIT SYSTEM STRUCTURE FROM THE ACADEMIC …nmssvnc.edu.in/chemistry/uploadsyllabus/a187754a091… ·  · 2017-03-23CHOICE BASED CREDIT SYSTEM – STRUCTURE

214

ANNEXURE – 9

CHOICE BASED CREDIT SYSTEM – STRUCTURE

FROM THE ACADEMIC YEAR 2014–15

B.Sc CHEMISTRY

SEM Part – I Part – II Part – III Part – IV

Part – V

(6th Hr)

ACC

(6th Hr) SLC

I Sem.

I

Lang

(6)

II

Lang

(6)

Core (4)

Core (3)

Allied

Maths/Zoo

(6/4)

Allied Zoo.

Lab

(2)

SBE (2)

– Total (30)

NCC/NSS/PED. (3)

Com.Eng (2)

Comp.Lit (1)

– –

II

Sem.

I

Lang (6)

II

Lang (6)

Core

(3)

Core

(3)

Core Lab

(3)

Allied

Maths/Zoo (6/4)

Allied

Zoo.

Lab

(2)

SBE

(2)

Elec.

EVS (1)

Total

(30)

NCC/NSS/PED.

(3)

Com.Eng

(2)

Comp.Lit

(1) –

Law

and Society

III Sem.

I

Lang

(6)

II

Lang

(6)

Core (2)

Core

Lab

(2)

Allied

Maths/Zoo

(6/4)

Allied Zoo.

Lab

(2)

Allied

Physics

(4)

Allied

Physics

Lab

(2)

NME (2)

– Total (30)

NCC/NSS/PED. (3)

Com.Eng (2)

Comp.Lit (1)

– Human Rights

IV

Sem.

I

Lang

(6)

II Lang

(6)

Core (2)

Core Lab

(2)

Allied Maths/Zoo

(6/4)

Allied Zoo. Lab

(2)

Allied Physics

(4)

Allied Physics

Lab

(2)

NME

(2) –

Total

(30)

NCC/NSS/PED.

(3)

Com.Eng

(2)

Comp.Lit

(1) –

C

Programming

V

Sem.

Core

(4)

Core

(4)

Core

(4)

Core

(3)

Core Lab

(3)

Core Lab

(3)

Allied

Physics

(4)

Allied

Physics

Lab (2)

SBE

(2)

Elec. W.S.

(1)

Total

(30) –

Com.Eng

(2)

Comp.Lit

(1)

Skill Devt –

Career

Guidance (3)

Chemistry in

daily life

VI

Sem.

Core

(3)

Core

(4)

Core

(4)

Core Lab

(3)

Core Lab

(3)

Allied

Physics

(4)

Allied

Physics

Lab (2)

Elec.

Project

(5) –

Elec. VBE

(2)

Total

(30) –

Com.Eng

(2)

Comp.Lit

(1)

Skill Devt –

Career

Guidance (3)

––

Total 180 Hrs

I Language – Tamil

II Language – English

SBE – Skill – Based Electives

SLC – Self – Learning Course

EVS – Environmental Studies

W.S. – Women Studies

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215

CHOICE BASED CREDIT SYSTEM – STRUCTURE

FOR THOSE WHO HAVE JOINED FROM THE ACADEMIC YEAR 2014 – 15 ONWARDS

B.Sc CHEMISTRY

Sem

Part

Course Subject Hrs. 6th

Hr. Cr.

Adl.

Cr.

Exam

(Hrs)

Marks

Allotted

Int. Ext.

I

I Lang. – I Tamil – I 6 3 3 25 75

II Lang. – II General English – I 6 3 3 25 75

III

Core Inorganic Chemistry – I 4 4 3 25 75

Core Organic Chemistry – I 3 3 3 25 75

Core Lab Qualitative Analysis

Lab – I 3 – – – –

Allied

Maths/Zoo

Allied Mathematics

Paper – I / Animal

Diversity

*6/4 5/4 3 25 75

Allied Zoo Lab

Animal Diversity,

Genetics, Cell Biology and Bio chemistry Lab

2 – – – –

IV SBE - I Chemical Purification &

Laboratory Safety 2 2 2 25 75

V Extension

activities NSS / NCC / PED 3 – – –

Additional

Courses

Communicative English–I 2 – – –

Computer Literacy 1 – – –

II

I Lang. – I Tamil – I 6 3 3 25 75

II Lang. – II General English – II 6 3 3 25 75

III

Core Physical Chemistry – I 3 3 3 25 75

Core Inorganic Chemistry – II 3 3 3 25 75

Core Lab Qualitative Analysis Lab 3 3 3 40 60

Allied

Maths/Zoo

Allied Mathematics Paper – II / Genetics,

Cell Biology and Bio

Chemistry

*6/4 5/4 3 25 75

Allied Zoo

Lab

Animal Diversity,

Genetics, Cell Biology

and Bio chemistry Lab

2 2 3 40 60

IV SBE - II

Clinical Chemistry (Blood and Urine)

2 2 2 25 75

EVS Environmental Studies 1 1 2 – 100

V Extension activities

NSS / NCC / PED 3 – – –

Additional Courses

Communicative English-I 2 1 3 25 75

Computer Literacy 1 – – –

SLC Law and Society 3 3 – 100

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216

Sem

Part

Course Subject Hrs. 6th

Hr. Cr.

Adl.

Cr.

Exam

(Hrs)

Marks

Allotted Int. Ext.

III

I Lang. – I Tamil – III 6 3 3 25 75

II Lang. – II General English – III 6 3 3 25 75

III

Core Organic Chemistry – II 2 2 3 25 75

Core Lab Volumetric Analysis Lab 2 – – –

Allied

Maths/

Zoo

Allied Mathematics

Paper – III/ Microbiology

& Immunology

*6/4 5/4 3 25 75

Allied Zoo

Lab

Chordata, Microbiology,

Immunology and

Commercial Zoology 2 - - - -

Allied

Physics

Mechanics Properties of

Matters and Sound 4 4 3 25 75

Allied Physics

Lab

Allied Physics Practical– I 2 – – –

IV NME - I Agricultural chemistry 2 2 2 25 75

V Extension activities

NSS / NCC / PED 3 – – –

Additional

Courses

Communicative English–II 2 – – –

Computer Literacy 1 – – –

SLC Human Rights 3 3 – 100

IV

I Lang. – I Tamil – IV 6 3 3 25 75

II Lang. – II General English – IV 6 3 3 25 75

III

Core Physical Chemistry – II 2 2 3 25 75

Core Lab Volumetric Analysis Lab 2 2 3 40 60

Allied

Maths/ Zoo

Allied Mathematics Paper

– IV / Physiology & Biotechnology

*6/4 5/4 3 25 75

Allied Zoo

Lab

Animal Diversity,

Microbiology, Immunology

Physiology and

Biotechnology

2 2 3 40 60

Allied

Physics Thermal Physics 4 4 3 25 75

Allied

Physics

Lab

Allied Physics Practical–I 2 2 3 40 60

IV NME - II Biological Chemistry 2 2 2 25 75

V Extension activities

NSS / NCC* / PED* 3 1 3 25

*40

75

*60

Additional

Courses

Communicative English–II 2 1 3 25 75

Computer Literacy 1 – – –

SLC C – Programming 4 3 – 100

*6/4 = 6hr for mathematics paper / 4hr for zoology paper (I to IV Sems)

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217

Sem

Part

Course Subject Hrs. 6th

Hr. Cr.

Adl.

Cr.

Exam

(Hrs)

Marks

Allotted

Int. Ext.

V

III

Core Organic Chemistry – III 4 4 3 25 75

Core Inorganic Chemistry – III 4 4 3 25 75

Core Physical Chemistry – III 4 4 3 25 75

Core

Analytical Chemistry and

Applications of Computers

in Chemistry

3 3 3 25 75

Core Lab

Organic Analysis and

Estimation 3 – – – –

Gravimetric Analysis 3 – – – –

Allied

Physics Electricity and Electronics 4 4 3 25 75

Allied

Physics

Lab

Allied Physics

Practical – II 2

– – –

IV SBE - III

Food Processing and Preservation

2 2 2 25 75

WS Women Studies 1 1 2 – 100

Additional Courses

Communicative English–III 2 – – –

Computer Literacy 1 – – –

Skill Development – Career

Guidance 3 – – –

SLC Chemistry in daily life 4 3 – 100

VI

III

Core Applied Chemistry 3 3 3 25 75

Core Organic Chemistry – IV 4 4 3 25 75

Core Physical Chemistry – IV 4 4 3 25 75

Core Lab

Organic Analysis and

Estimation 3 3 6 40 60

Gravimetric Analysis – 2 6 40 60

Physical Chemistry

Experiments 3 3 6 40 60

Allied Physics

Optics and Modern Physics 4 4 3 25 75

Allied

Physics

Lab

Allied Physics Practical–II 2 2 3 40 60

Elect. -III Project

*Report; @Viva 5 5 – 40

*30:@10

60 *50:@1

0

IV VBE Value Based Education 2 2 2 – 100

Additional Courses

Communicative English–III 2 1 3 25 75

Computer Literacy 1 1 3 – 100

Skill Development – Career

Guidance 3 2 3 – 100

TOTAL 180 36 140 20

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218

ALLIED – CHEMISTRY FOR ZOOLOGY

Sem Title of the Paper

Hrs.

Cr. Exam (Hrs)

Marks Allotted

Int Ext

I General Chemistry – I 4 4 3 25 75

II General Chemistry – II 4 4 3 25 75

II Volumetric Analysis Lab – I 2 2 3 40 60

III General Chemistry – III 4 4 3 25 75

IV General Chemistry – IV 4 4 3 25 75

IV Organic Analysis Lab 2 2 3 40 60

ALLIED – CHEMISTRY FOR BIOCHEMISTRY

Sem Title of the Paper

Hrs.

Cr. Exam

(Hrs)

Marks Allotted

Int Ext

I General Chemistry – I 4 4 3 25 75

II General Chemistry – II 4 4 3 25 75

II Volumetric Analysis Lab – I 2 2 3 40 60

ALLIED – CHEMISTRY FOR BIOTECHNOLOGY

Sem Title of the Paper

Hrs.

Cr. Exam

(Hrs)

Marks Allotted

Int. Ext.

I General Chemistry – I 4 4 3 25 75

I Volumetric Analysis Lab – I 2 2 3 40 60

II General Chemistry – II 4 4 3 25 75

III General Chemistry – III 4 4 3 25 75

III Organic Analysis Lab 2 2 3 40 60

IV General Chemistry – IV 4 4 3 25 75

ALLIED – CHEMISTRY FOR PHYSICS

Sem Title of the Paper

Hrs.

Cr.

Exam

(Hrs)

Marks Allotted

Int Ext

III Inorganic, Organic & Physical

Chemistry - I 4 4 3 25 75

IV Inorganic, Organic & Physical

Chemistry - II 4 4 3 25 75

IV Volumetric Analysis Lab 2 2 3 40 60

V Inorganic and Physical Chemistry 4 4 6 25 75

VI Organic and Physical Chemistry 4 4 3 25 75

VI Organic Analysis Lab 2 3 3 40 60

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219

B.Sc CHEMISTRY: Those Who Have Joined From The Academic Year 2014–15 Onwards Under CBCS System

Core Subject ORGANIC CHEMISTRY – III Code: 14223501

SEMESTER V

4 Hrs/Week Credits 4

Objectives:-

To have a knowledge about organic synthesis, Polynuclear hydrocarbons

and aromatic acids.

UNIT – I: Alicyclic Compounds: [12 Hrs]

a) Preparation and propertices of alicyclic compound – Bayer’s

strain theory and its modifications. Civetone and muscone any

one method of synthesis (No structural elucidation).

b) Conformational Analysis: Difference between configuration and

conformations. Fischer and Newman projection formulae –

conformational analysis of ethane and mono substituted

cyclohexane.

UNIT – II: Carbohydrates: [12 Hrs]

a) Introduction and classification: Monosaccharides – preparation,

properties and structure of glucose and fructose – configuration

– Interconversion of glucose and fructose – descending and

ascending of sugar series – epimerization and mutarotation.

b) Disaccharides: Preparation , properties and configuration of

sucrose and maltose (structural elucidation not necessary)

c) Polysaccharides: A general study of starch and cellulose –

applications of cellulose derivatives (celluloid, Nitro cellulose,

collodion, viscose)

UNIT – III: Reagents in Organic Synthesis and Tautomerism: [12 Hrs]

a) Oxidising Agents: Oxidation reactions involving SeO2, OsO4,

Leadtetraacetate, N –bromo succinimide.

b) Reducting agents: Lithium aluminium hydride, Meerwein

Pondorf Verley reduction, clemmenson reduction.

c) Tautomerism – Definition – conditions – difference between

resonance and tautomerism – prototropy and Anionotropy, keto

– enol, Lactam – Lactim tautomerism, Quinone monoxime – p –

Nitrophenol tautomerism.

UNIT – IV: Polynuclear Hydrocarbons and Their Derivatives: [12 Hrs]

a) Isolated systems: Preparation and propertices of diphenyl, and

diphenyl methane.

b) Condensed ring systems: Preparation, properties, uses and

structure of Naphthalene, anthracene, anthraquinone, alizarin,

phenanthrene.

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220

UNIT – V: Aromatic Acids: [12 Hrs]

a) Preparation of benzoic acid – Effect of substituents on acidic

character.

b) Substituted acids: Preparation, properties and uses of salicylic

acid and anthranilic acid.

c) Dicarboxylic acids: Preparation and properties of phthalic acid,

terephthalic acid and phthalimide.

d) Preparation and properties of cinnamic acid.

e) Aromatic sulphonic acids: Preparation and uses of benzene

sulphonic acid, saccharin and chloramines – T.

TEXT BOOKS: 1. Bahl B.S., and Arun Bahl, Advanced Organic Chemistry, S.Chand

& Co., New Delhi, 1999. 2. Finar I.L., Organic chemistry, Vol. II, 5th Edition, ELBS, England,

1975.

3. Morrison R.T.¸ and Boyd R.W., Organic Chemistry, 6th Edition, Prentice – Hall, New Delhi, 1995.

4. Soni P.L., Organic Chemistry, S.Chand & Co., New Delhi.

REFERENCES: 1. Bahl B.S., and Arun Bahl, Advanced Organic Chemistry, S.Chand

& Co., New Delhi, 1999. 2. Finar I.L., Organic Chemistry, Vol. I, 5th Edition, ELBS, England,

1975.

3. Finar I.L., Organic Chemistry, Vol. II, 5th Edition, ELBS, England, 1975.

4. Morrison R.T.¸ and Boyd R.W., Organic Chemistry, 6th Edition,

Prentice – Hall, New Delhi, 1995. 5. Singh and Mukherji, Reaction Machanism in Organic Compounds,

McMillan, India. 6. Soni P.L., Organic Chemistry, S.Chand & Co., New Delhi.

Core Subject INORGANIC CHEMISTRY – III Code: 14223502 SEMESTER V

4 Hrs/Week

Credits 4 Objectives:-

Detailed study of Coordination Compounds and Bio Inorganic Chemistry

UNIT – I: Coordination Compounds: [12 Hrs]

a) Introduction – Nomenclature – isomerism in complexes –

structural and stereo Isomerism – Werner’s theory – EAN rule –

Valence bond theory – magnetic properties – Limitations of VBT

– crystal field theory – spilitting of d-orbitals in octahedral,

tetrahedral and square planar complexes – color of coordination

complexes – low spin and High spin complexes – M.O. theory –

sigma and 𝜋 bonding in octahedral complexes.

UNIT – II: [12 Hrs]

a) Metal carbonyls – bonding and structures of Ni (CO)4,Fe(CO)5,

Cr(CO)6, Fe2(CO)9 and Co2(CO)8.

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221

b) Organometallic compounds – Introduction – nomenclature,

classification based on the nature of metal–carbon bond – Ionic

organometallic compounds – reactivity of Na+( CH2C6 H5) – and

Na+[C6H5]– – Compounds containing metal–carbon bonds.

UNIT – III: The Inner Transition Elements: [12 Hrs]

a) Lanthanide series – occurrence – properties – electronic

configuration. Oxidation states, ionic radii – lanthanide

contraction and its causes, consequences – color of ions,

magnetic properties, oxidation potential, basic characters,

solubility of compounds, double salts, complexes formation –

Extraction of lanthanides from monazite sand – separation of

lanthanides – solvent extraction – Ion exchange

chromatography – uses of lanthanides.

b) Actinides series – sources – Transuranic elements its

preparation – electronic configuration – properties – oxidation

states – Ionic radii – color of ions – Formation of complexes –

comparison of actinides and lanthanides.

UNIT – IV: [12 Hrs]

a) Acids and bases: Arrhenius concept and its limitation – Lowry &

Bronsted concept – conjugate acid – base pairs – relative

strengths of acids and bases – Lux–Flood concept and its

limitations –Lewis concept and its limitations – Levelling effect –

Usanovich concept – HSAB concept(fundamentals only)

b) Non aqueous Solvents: Classification of solvents – chemical

reaction in liquid ammonia – precipitation reaction, Acid base

reactions, protolysis, Ammonolysis and Complex formation

reaction – solution of alkali metals in liquid ammonia.

UNIT – V: Bio Inorganic Chemistry: [12 Hrs]

a) Metallo porphyrins – porphyrins – chlorophyll – Vitamin B12

[structure only]

b) Myoglobin and haemoglobin – structure – Their role in biological

systems – cytochrome P–450.

c) Role of alkali and alkaline earth metal ions in biological systems

–Role of Na+ and K+ ions – sodium pump.

d) Biological functions and toxicity of elements – Cr, Cu, As and

radioactive elements.

TEXT BOOKS:

1. Cotton F.A., and Wilkinson, Basic Inorganic Chemistry, Wiley

Eastern Limited, New York, 1976

2. Madan R.D., Modern Inorganic Chemistry, S.Chand & Co., New

Delhi.

3. Malik, Madan and Tuli, Selected Topics in Inorganic Chemistry,

S.Chand & Co., New Delhi, 1976.

4. Soni P.L., Text book of Inorganic Chemistry, S.Chand & Co., New

Delhi.

5. Bhaghi & Chahoal, Text Book for Bioinorganic Chemistry,

REFERENCES:

1. Cotton F.A., and Wilkinson, Basic Inorganic Chemistry, Wiley

Eastern Limited, New York, 1976.

2. Madan R.D., Modern Inorganic Chemistry, S.Chand & Co., New

Delhi.

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222

3. Malik, Madan and Tuli, Selected topics in Inorganic Chemistry, S.Chand & Co., New Delhi, 1976.

4. Puri, Sharma and Kalia, Principles of Inorganic Chemistry, S.Chand & Co., New Delhi.

5. Soni P.L., Text Book of Inorganic Chemistry, S.Chand & Co., New Delhi.

Core Subject PHYSICAL CHEMISTRY – III Code: 14223503 SEMESTER V

4 Hrs/Week

Credits 4 Objectives:-

Detailed study of Thermodynamics Group Theory and Chemical Kinetics

UNIT – I: Thermodynamics – I: [12 Hrs]

a) Introduction – Types of systems – state of a system –

thermodynamic or state variables – extensive and intensive

properties – state functions and path functions – exact and

inexact differentials – thermodynamic process– reversible and

irreversible processes – work, heat and energy. Zeroth law of

thermodynamics and its significance

b) First law: Statement – mathematical formulation – internal

energy – enthalpy or heat content – heat changes at constant

volume and at constant pressure conditions – relationship

between Cp and Cv – application of I law to non– ideal gas

undergoing reversible isothermal and adiabatic expansion –

Joule Thomson effect – Joule Thomson co– efficient in the case

of ideal and real gases – inversion temperature – Hess’s Law of

heat summation – Kirchoff’s equation – bond enthalpies.

UNIT – II: Second law of Thermodynamics: [12 Hrs]

a) Limitation of I law of thermodynamics – spontaneous process –

statement of II law.

b) Entropy – definition and significance – derivation of the concept

of entropy – entropy changes in reversible and irreversible

(spontaneous) processes. Entropy as a thermodynamic function

– dependence of entropy on the variables of the systems for

ideal gases – entropy of mixing of gases – S for physical

transformation in chemical reactions – entropy and probability.

c) Free energy function – Helmholtz free energy (A) – definition and

its temperature dependence – Gibbs free energy (G) – Definition,

variation of Gibbs free energy with temperature and pressure.

Gibbs – Helmholtz equation and its applications – Maxwell’s

relationships – criteria for reversible and irreversible processes

in terms of entropy and free energy changes.

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223

d) Partial molar quantities – Definition and significance of

chemical potential Gibbs – Duhem equation – variation of

chemical potential with temperature and pressure – Clausius –

Clapeyron equation –derivation and applications.

UNIT – III: [12 Hrs]

a) Thermodynamics III – Nernst heat theorem and its applications

– third law of thermodynamics – a simple treatment of the law –

exception to third law – entropy of CO, N2O, H2O and NO.

b) Application of thermodynamics to various type of equilibria –

equilibrium constant and free energy changes – Van’t Hoff

reaction isotherm and Van’t Hoff isochore – thermodynamic

interpretation of law of mass action and Le–chatelier principle.

c) Thermodynamics of ideal solution – free energy change of

mixing, enthalpy changes of mixing – relation between osmotic

pressure and vapour pressure lowering – thermodynamic

derivation – relation between the depression of freezing point

and concentration – elevation of boiling point and concentration

– thermodynamic derivations.

UNIT – IV: Chemical Kinetics: [12 Hrs] a) Introduction – rate of reaction – rate law and rate constant –

order and molecularity of a reaction. Reaction of first and

pseudo unimolecular reactions.

b) Second, third and zero order reactions – examples – rate

equation – half life period.

c) Influence of temperature on the rate of reaction – Arrhenius rate

equation and its significance – measurement of parameters.

Theory of reaction rates – Bimolecular collision theory –

unimolecular reactions – Lindemann’s hypothesis.

d) Influence of ionic strength on reaction rate – kinetics of fast

reactions – flow method.

UNIT – V: Group Theory: [12 Hrs]

a) Molecular symmetry elements and symmetry operations –

operations – products of symmetry operations –properties of a

group – classes and sub groups – groups multiplication table –

C2V.

b) Point groups – classification of molecule into point groups – C2

V, C3 V. C2 h, D2 h, D3 h,D4 h, D6 h, Td and Oh.

c) Vector and matrix Algebra – symmetry operations and

transformation matrices.

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TEXT BOOKS: 1. Barrow G.M., Physical Chemistry, McGraw – Hill, International

Student Edition, New Delhi, 1973. 2. Puri, Sharma and Pathania, Text Book of Physical Chemistry,

S.Chand & Co., New Delhi. REFERENCES:

1. Barrow G.M., Physical Chemistry, McGraw – Hill, International

Student Edition, New Delhi, 1973. 2. Cotton F.A., Chemical Applications of Group Theory, Wiley Easter

Ltd., New Delhi.

3. Glasstone S., Thermodynamics for Chemists, Van Nostrand Co., Inc., New York.

4. Laidler K.J., Chemical Kinetics, 3rd Edition, McGraw – Hill, New Delhi.

5. Puri, Sharma and Pathania, Text Book of Physical Chemistry,

S.Chand & Co., New Delhi. 6. Rajaram J., and Kuriacose J.C., Thermodynamics, 3rd Edition,

S.Chand & Co., New Delhi, 1999. 7. Soni P.L., Dharmarha O.P., and Dash U.N., Text Book of Physical

Chemistry, S.Chand & Co., New Delhi.

Core Subject ANALYTICAL CHEMISTRY AND APPLICATIONS OF

COMPUTERS IN CHEMISTRY Code: 14223504

SEMESTER V

3 Hrs/Week Credits 3

Objectives:-

To have a basic knowledge about the Electroanalytical Methods and

applications of C language in Chemistry.

UNIT – I: [9 Hrs]

a) Methods of obtaining the precipitate – condition – choice of

precipitants – merits and demerits of organic precipitants –

Types – specific and selective precipitants – sequestering agents

– theory of precipitation – Dendrites – Paneth – Fajans – Hahn

law – co–precipitation – post precipitation from homogeneous

solution.

b) Precision – Accuracy – Absolute and relative error –

classification of errors – confidence limit – students Q test –

Rejection of experimental data – sources and elimination of

errors – significant figures and computation.

UNIT – II: [9 Hrs]

Analysis of Experimental Results:

Graphical method – curve fitting – method of least squares –

problems involving straight line graphs.

Instrumental methods of Analysis:

Beer – Lambert’s law – principles of colorimetric Analysis – visual

colorimeter – standard series method – Balancing method – Estimation of

Ni2+ and Fe2+.

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UNIT – III: [9 Hrs]

Electroanalytical Methods:

Primary and secondary Coulometry titrations – examples –

potentiometric titration – polarography – Basic principle – applications –

Amperometry –voltammetry – basics of cyclic voltammetry –applications.

UNIT – IV: [9 Hrs]

Introduction to computer – Definition of a computer – Generation of

computers – components of a computer – Input unit, CPU, and output

unit – secondary storage devices – Hard disk, Floppy disk and optical

disk – Hardware and software – system software – Application software –

Micro, Mini, Mainframe and super computers – programming languages –

low level languages – Machine languages and Assembly languages – High

level languages – FORTRAN, BASIC, PASCAL and COBOL (basic ideas

only)

UNIT – V: [9 Hrs]

Application of “C” Language in Chemistry:

Introduction of “C” Language – character set – “C” Tokens –

Keywords and identifiers – constants, variables, Data types and

operators – computation of some simple problems in chemistry such as

1. Half life period

2. Normality, Molality and Molarity

3. Root mean square velocity

4. Ionic strength of an electrolyte

5. Lambert’s beer’s law

TEXT BOOKS:

1. Raman K.V., Computers in Chemistry, Tata McGraw – Hill, New

Delhi, 1993.

2. Skoog, West and Holler, Analytical Chemistry – An Introduction,

7th Edition, Saunders College Publishers, New York, 1999.

REFERENCES:

1. Balagurusamy E., Programming in ANSI C, McGraw – Hill.

2. Peter and Nortron, Introduction to Computers, Tata McGraw – Hill.

3. Raman K.V., Computers in Chemistry, Tata McGraw – Hill, New

Delhi, 1993.

4. Skoog, West and Holler, Analytical Chemistry – An Introduction,

7th Edition, Saunders West Press, New Delhi.

5. Willard H., Merit and Deen J.A., Instrumental Methods of Analysis,

East – West Press, New Delhi.

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Part – IV FOOD PROCESSING AND PRESERVATION Code: 14443522

Skill Based Elective–Major SEMESTER V

2 Hr/Week

Credit 2 Objectives:-

To have a basic knowledge of food processing and preservation.

UNIT – I: Food Processing: [6 Hrs]

Aims of food science and technology – Constituents of food, food as a

source of energy. Preparative operations in food industry (cleaning,

storing and grading of food raw materials).

UNIT – II: Principles of Food Preservation: [6 Hrs]

Commercial heat preservation methods (sterilization, pasteurization)

– Evaporation and drying – Types of evaporators, Types of driers. Low–

temperature processing and preservation methods – Refrigeration and

cold storage only.

UNIT – III: Milk and Dairy Products Preservation: [6 Hrs]

Milk production and quality control milk processing operations.

Types of milk and milk products – Butter making – Manufacture of ice

cream.

UNIT – IV: Vegetables and Fruits and their Products Preservation: [6 Hrs]

Storage of vegetables, vegetable products, storage of fruits, fruit

products, fruit juice production.

UNIT – V: Meat, Sea Food and Eggs Preservation: [6 Hrs]

Types of meat, preservation, cooking of meat, storage and processing

of fish and fish products. Egg and Egg products.

TEXT BOOK:

1. Siva Sankar B., Food Processing and Preservation, Prentice Hall of India Private Limited.

REFERENCES: 1. Jay J.M., Modern Food Microbiology, 3rd Edition, CBS Publication,

Delhi, 1987. 2. Geankoplis C.J., Transport Process and Unit Operators, 3rd

Edition, Prentice Hall of India, New Delhi, 1997. 3. Coultate, T.P., Food – The Chemistry of its components, 2nd

Edition, Royal Society of Chemistry, London, 1992. 4. Desrosier N.W., and Desrosier J.N., The Technology of Food

Preservation, 4th Edition, AVI Publications, Inc, Westport, 1977.

Self Learning Course–Major CHEMISTRY IN DAILY LIFE Code: 14803522

SEMESTER V

Addl. Credits 4 Objectives:-

To have a knowledge Pharmaceutical Chemistry and Forensic Science

UNIT – I: Pharmaceutical Chemistry:

Introduction – Classification of drugs – Principle of drug action –

Basic structure and mode of action of analgesics – Sulpha drugs,

antibiotics (pencillin) antineoplastic agents and HIV drugs.

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UNIT – II: Forensic Science:

Physical evidence collection and preservation of physical evidence –

Techniques of analysis of physical evidence. Forensic examination of

hair, fibre, drugs and alcohol. Analysis of finger prints and documents.

UNIT – III: Soil Chemistry:

Introduction – Properties of soil – Colloidal acidity and alkalinity of

soil – Soil PH – Micro and macro nutrients in soil – Soil erosion – Liming

of soil – Application of fertilizers to soil – biofertillizers.

UNIT – IV: Textile Chemistry:

Introduction to fibre polymers – Classification – Fibre properties –

Physical chemical and thermal chemical finishing of textiles – dyeing and

printing – Colour in textiles.

UNIT – V: Non–Conventional Energy:

Need for non–conventional energy – Renewable energy sources –

Solar energy – Collection and storage applications – Wind energy –

Conversion and applications – Biomass energy – Anaerobic and biomass

gasification.

TEXT BOOK:

1. Jayashree Ghose, A Text Book of Pharmaceutical Chemistry, S.Chand and Co, Limited, New Delhi.

REFERENCES:

1. Firman Bear, Chemistry of the Soil, 2nd Edition, Oxford and IBH Publishers, New Delhi, 1964.

2. Rai G.D., Non–Conventional Sources of Energy, Khanna Publishers, New Delhi, 1996 (July).

3. Richard Safarstin, Criminalistics, Prentice Hall of India Private

Limited, New Delhi, 1978.

Core Subject APPLIED CHEMISTRY Code: 14223601

SEMESTER VI

3 Hrs/Week Credits 3

Objectives:-

To be exposed to the applications of chemistry

UNIT – I: [9 Hrs]

a) Rubber: Natural and synthetic rubbers– composition of natural

rubber, Neoprene rubber, styrene butadiene rubber (SBR).

b) Fibres, resins and plastics: Definition – natural and synthetic

fibres – natural and synthetic resins – distinctions between

resins and plastics – classification of plastics – properties –

Bakelite,Urea – formaldehyde resins, Teflon, Nylon – 66 and

Dacron. Recycled plastics and polymers of different grade.

UNIT – II: [9 Hrs]

a) Fertilizers: Definition – Nutrients for plants – Role of various

elements in plant growth – natural and chemical fertilizers –

urea, super phosphate and potassium nitrate – mixed fertilizers

– Fertilizer industry in India.

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b) Preparation of domestically useful chemical products: Washing

powder – cleaning powder – phenoyls ( White, Black and

Coloured) Shampoo, liquid Blue, Blue, red, and Green inks,

Soap oil, Face powder.

UNIT – III: [9 Hrs]

a) Match industry: Pyrotechny and explosives – Raw materials

needed for match industry – manufacturing process –

pyrotechniques – colored smokes – Explosives – Definition –

classification –Nitroglycerine, Dynamite, Cordite, TNT and picric

acid.

b) Silicate industry: Cement, glass and ceramics – Raw materials

and manufacture of cement, glass and ceramics.

UNIT – IV: [9 Hrs]

a) Corrosion of metals: Definition – various methods of preventing

corrosion classification of metals, wet corrosion, corrosion rate

(elementary aspects only) – coating with other metals

(galvanizing, tinning and electroplating) – cathodic protection

and painting – corrosion inhibitors.

UNIT – V: [9 Hrs]

a) Chemotherapy:

Preparation – Structure and uses of the following.

1) Sulpha drugs – sulphadiazine, prontosil and prontosil–

s.

2) Antimalarials – quinine, plasmoquine.

3) Arsenical drugs – salvarasan 606, Neosalvarasan.

4) Antibiotics: Definition, penicillin – Tetracycline

(Auromycin and terramycin) – streptomycin and

chloromyceitin – structure and uses.

TEXT BOOKS:

1. Jain P.C., and Monica Jain, Engineering Chemistry, Dhanpat Rai & Sons, Delhi, 1995.

2. Soni P.L., Organic Chemistry, S.Chand & Co., New Delhi. REFERENCES:

1. Ashutosh kar, Medicinal Chemistry, New Age International

Publishers, New Delhi. 2. Jain P.C., and Monica Jain, Engineering Chemistry, Dhanpat Rai

& Sons, Delhi, 1995.

3. Soni P.L., Organic Chemistry, S.Chand & Co., New Delhi.

Core Subject ORGANIC CHEMISTRY – IV Code: 14223602

SEMESTER VI 4 Hrs/Week Credits 4

Objectives:-

To know the details of Molecular rearrangements Stereoisomerism and

Spectroscopy

UNIT – I: Stereoisomerism: [12 Hrs]

a) Geometrical Isomerism:

Definition – geometrical isomerism of maleic and fumaric

acids – aldoximes and ketoximes – determination of configurations

of geometrical isomers – E – Z notation.

b) Optical Isomerism:

i. Optical activity – specific rotation – definition of optical

isomerism – symmetry elements.

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ii. Optical isomerism of compounds containing asymmetric

carbon atom – racemisation – resolution of racemic

mixtures – Walden inversion – asymmetric synthesis –

chirality – R–S notations.

iii. Optical activity of compounds without asymmetric carbon

atoms; allenes and biphenyls.

UNIT – II: [12 Hrs]

a) Molecular rearrangements: Detailed mechanisms of the

following: pinacol – pinacolone, Hofmann, Beckmann, Benzil –

Benzillic acid, claisen, Fries, and Benzidine.

b) Free radicals: Definition – preparation and reactions of short

lived and long lived free radicals – stability of free radicals –

detection of free radicals – chain reactions – Mechanism of cis –

trans isomerisation and Sand Mayer reaction and Gomberg

reaction.

UNIT – III: Principles and Applications of Spectroscopy: [12 Hrs]

a) UV: Introduction – Types of electronic transition – absorption

laws – bathochromic shift, hypsochromic shift, hyperchromic

shift and hypochromic effect – applications of UV to organic

compounds – Woodward – Fieser rule –calculation of max.

b) IR: Introduction – mode of vibrations – overtone and

combination bands. Applications of IR to organic compounds –

finger print region – effect of hydrogen bonding.

c) NMR: Introduction – chemical shift – shielding and deshielding

effect – factors influencing chemical shift – solvent used –

splitting of signals – coupling constants – NMR spectra of

ethanol – temperature variation NMR.

d) 13C NMR: Basic principle – Difference between 13C and 1H–NMR.

UNIT – IV: [12 Hrs]

a) Heterocyclic compounds: Preparation and properties of furan,

pyrrole, thiophene, pyridine, indole, quinoline, and iso

quinoline.

b) Alkaloids: Definition – occurrence – extraction of alkaloids –

general methods of determining the structure of alkaloids –

classification of alkaloids – structure and synthesis of following

– coniine and piperine.

c) Terpenes: Introduction – classification – isolation. Isoprene rule

– general methods of determining structure – structural

elucidation of Citral, -terpeniol and menthol.

UNIT – V: [12 Hrs]

a) Dyes:

Definition – Theories of colour and constitution – otto witt

theory – VB theory – Mo theory classification of dyes according

to structure and mode of application.

i. azo dyes: Preparation and uses of methyl orange,

congo red and Bismark brown.

ii. Triphenyl methane dyes: Preparation and uses of

Malachite green and Rosaniline.

iii. Phthalein dyes: Preparation and uses of

phenolphthalein, Fluorescein and eosin.

iv. Vat dyes: Preparation and uses of indigo.

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TEXT BOOKS: 1. Bahl S., Arun Bahl, Advanced Organic Chemistry, S.Chand & Co., New

Delhi, 1999, 2. Morrison R.T., and Boyd R.W., Organic Chemistry, 6th Edition,

Prentice – Hall, New Delhi, 1995. 3. Silverstein B.M., Bassler G.C., and Morrill T.C., Spectrometric

Identification of Organic Compound, 5th Edition, Wiley, New Delhi. REFERENCES:

1. Bahl S., Arun Bahl, Advanced Organic Chemistry, S.Chand & Co., New Delhi, 1999.

2. Eliel E.L., Stereo chemistry of carbon compounds, Wiley Eastern, New York, 1991.

3. Finar I.L., Organic Chemistry. Vol. I, 5th Edition, ELBS, England, 1975. 4. Finar I.L., Organic Chemistry. Vol. II, 5th Edition, ELBS, England, 1975. 5. Kalsi P.S., Stereochemistry and Conformational Analysis, 2nd Edition,

Wiley Eastern Limited, New Delhi, 1993. 6. Kemp, Organic Spectroscopy, 3rd Edition, ELBS, Hampshise. 7. Morrison R.T., and Boyd R.W., Organic Chemistry, 6th Edition,

Prentice – Hall, New Delhi, 1995. 8. Silverstein B.M., Bassler G.C., and Morrill T.C., Spectrometric

Identification of Organic Compound, 5th Edition, Wiley, New York. 9. Singh and Mukherji, Reaction Mechanism in Organic compounds,

McMillan, India. 10. Soni P.L., Organic Chemistry, S.Chand & Co., New Delhi.

Core Subject PHYSICAL CHEMISTRY – IV Code: 14223603 SEMESTER VI

4 Hrs/Week Credits 4

Objectives:-

To have a knoeledge of Electrochemistry and Spectroscopy

UNIT – I: Electrochemistry: [12 Hrs]

a) Introduction – definition and determination of specific,

equivalent and molecular conductance – variation of equivalent

conductance with dilution.

b) Strong and weak electrolytes – anomaly of strong electrolytes –

Debye – Huckel – Onsager equation (no derivation).

c) Kohlrauch’s law of ionic mobilities and its applications –

absolute velocity of ions and its determination – transport

number of ions and their determinations.

d) Applications of conductivity measurements – degree of

dissociation –solubility product of a sparingly soluble salt –

conductometric titrations.

e) Ionic equilibrium:

i. pH of solutions and its calculations – buffer solutions –

theory of buffer action – Henderson – Hasselbach

equation.

UNIT – II: Electrochemical Cells: [12 Hrs]

a) Concepts of electrochemical cell – cell diagram and terminology

– conventions regarding signs of cell e. m. f – calculation of cell

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e. m. f. from single electrode potential – standard e. m. f of the

cell – Nernst equation.

b) Reversible and irreversible cells – thermodynamics and

electromotive force – calculation of G, H S and K for

cell reaction.

c) Single electrode potentials and cell emf measurement of single

electrode potential – types of electrodes – reference electrodes.

Standard electrode potential – experimental determination of

cell emf – Weston cadmium cell.

d) Types of electrochemical cells : 1. Chemical cells with and without transference – examples.

liquid junction potential – salt bridge.

2. Concentration cells – definition – types of concentration

cells with examples – emf of electrolyte concentration cells

with and without transference.

UNIT – III: [12 Hrs] a) Commercial cells – primary and secondary cells – dry cell – lead

storage cell – Ni – Cd cell – fuel cell – H2O2 cell.

b) Applications of emf measurements:

1. Determination of solubility and solubility products of

sparingly soluble salt.

2. Determination of pH using hydrogen electrode, glass

electrode and quinhydrone electrode.

3. Potentiometric titrations.

UNIT – IV: Photochemistry: [12 Hrs] a) Definition of photochemical reactions – comparative study of

thermal and photochemical reaction – laws of photochemistry –

Lambert and Beer law – Grothus – Drapper law – Stark –

Einstein law – quantum efficiency and its determination –

consequence of light absorption by atoms and molecules –

photo physical processes – fluorescence and phosphorescence,

Jablonski diagram.

b) Photochemical processes – Importance of photochemical

reactions – kinetics of photochemical reactions .

1. Gaseous reactions : Hydrogen – bromine reaction

2. Photochemical equilibrium – flash photolysis

photosensitization, Chemiluminescence, bioluminescence.

UNIT – V: Spectroscopy: [12 Hrs]

a) Introduction: Electromagnetic radiation – different regions –

absorption spectroscopy – molecular spectra, types of molecular

spectra.

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b) Rotational spectra of diatomic molecules – rigid rotator –

selection rule – determination of moment of inertia and bond

length – intensities of spectral lines – effect of isotopic

substitution.

c) Vibrational spectra – IR spectra of diatomic molecules – Hooke’s

Law – simple harmonic oscillator force constant – selection rule

– vibration energy level diagram – anharmonic oscillator –

applications – force constant determination. Modes of vibration

in polyatomic molecules – vibration spectra of H2O and CO2.

d) Rotational – vibrational spectra of diatomic molecules.

e) Raman spectra – Raman effect – stokes and anti stokes lines –

quantum theory of Raman effect – experimental study –

comparison between IR and Raman spectra – applications of

Raman spectra.

f) Electronic spectra – Franck – Condon principle.

g) Electron spin resonance spectroscopy – principle – difference

between NMR and ESR.

TEXT BOOKS:

1. Banwell C.N., Molecular Spectroscopy, 4th Edition, Tata Mc Graw Hill, New Delhi, 1996.

2. Chang R., Basic principles of Spectroscopy, McGraw – Hill, New

Delhi. 3. Glasstone S., Introduction to Electrochemistry, Van Nostrand Co.,

Inc., New York. 4. Puri, Sharma and Pathania, Text Book of Physical Chemistry,

S.Chand & Co., New Delhi.

REFERENCES: 1. Banwell C.N., Molecular Spectroscopy, 4th Edition, Tata McGraw –

Hill, New Delhi, 1996.

2. Barrow G.M., Physical Chemistry, McGraw – Hill, International Student Edition, New Delhi, 1973.

3. Chang R., Basic Principles of Spectroscopy, McGraw – Hill, New Delhi.

4. Glasstone S., Introduction to Electrochemistry, Van Nostrand Co.,

Inc., New York. 5. Puri, Sharma and Pathania, Text Book of Physical Chemistry

S.Chand & Co., New Delhi. 6. Rohatgi K.K., and Mukherji, Fundamentals of Photochemistry,

Wiley Eastern, New Delhi.

Core Lab ORGANIC ANALYSIS AND ESTIMATION Code: 14223604

SEMESTER V & VI

3 Hrs/Week Credits 3

Objectives:-

To acquire skill in organic qualitative analusis and estimation

1. Organic Analysis : Analysis of an organic compound containing

one functional group and confirmation by preparing a solid

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derivative – Acids, Phenols Aldehydes, Ketones, Esters, Nitro

compounds, Primary amines, Amides, Anilides, Aliphatic

Diamides, Aliphatic Diamides containing sulphur and mono

saccharides.

2. Organic Estimation:

a. Estimation of phenol.

b. Estimation of Aniline.

Core Lab GRAVIMETRIC ANALYSIS Code: 14223605

SEMESTER V & VI

3 Hrs/Week

Credits 2 Objectives:-

To acquire skill in Qualitative analysis and preparation

I. Gravimetric Analysis:

1. Estimation of Barium as Barium chromate.

2. Estimation of Lead as Lead chromate.

3. Estimation of Calcium as calcium oxalate monohydrate.

II. Organic Preparations:

1. m– dinitrobenzene from nitro benzene

2. Benzoic acid from Ethyl Benzoate.

3. p– bromo acetanilide from acetanilide.

4. Tribromo anline from aniline.

5. Nitro solycyclic acid from salicyclic acid.

6. Acetanilide from Aniline.

Core Lab PHYSICAL CHEMISTRY EXPERIMENTS Code: 14223606 SEMESTER VI

3 Hrs/Week Credits 3

Objectives:-

To apply the theory knowledge to laboratory work.

I. Determination of molecular weight by,

a. Transition temperature method – sodium thiosulphate penta

hydrate, sodium acetate trihydrate and strontium chloride

hexa hydrate (Solvent).

b. Cryoscopic method – Rast method – Naphthalene (solvent)

II. Phase diagram involving simple eutectic.

III. Critical solution temperature – Determination of critical solution

temperature of phenol – water system and effect of impurity on

CST– strength of unknown Nacl.

IV. Partition co–efficient experiments: Study of the equilibrium

constant for the reaction, KI + I2 KI3 by determining the partition

co– efficient of I2 between water and CCl4.

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V. Kinetics:– Determination of relative strength of acids by acid

catalyzed hydrolysis of ester.

VI. Electrochemistry:

Determination of strength of acid (or) base by

conductometric titration between an acid and a base.

Core Subject PROJECT Code: 14223607

SEMESTER VI

5 Hrs/Week

Credits 5

Undergraduate students of Chemistry will do projects under the

guidance of staff members of chemistry during VI semester. The projects

will be on chemistry and chemistry related fields. The project diary

signed by the project guide and HOD must be submitted in the month of

April. The viva on project will be conducted jointly by the guide and the

HOD.

Internal = 40 Marks External = 60 Marks

Report = 30

Viva = 10

Report = 50

Viva = 10

Total = 40 Total = 60

Allied Chemistry INORGANIC AND PHYSICAL CHEMISTRY

[Physics Major Students] Code: 14223521

SEMESTER-V 4 Hrs/Week

Credits 4

Objectives:- To have knowledge of Adsorption, Photo chemistry, Solid state, Co –

ordination compounds and Catalysis.

UNIT – I: [12 Hrs]

1. Adsorption : Definition – difference between adsorption and

absorption – adsorbate, adsorbent – Chemical adsorption,

Physical adsorption – differences between these two types –

factors influencing adsorption – adsorption isotherm –

Langmuir isotherm (No derivation, statement only)

2. Chromatographic techniques: Principle and application – thin

layer chromatography – column chromatography – paper

chromatography – gas – solid and gas – liquid

chromatography.

UNIT – II: [12 Hrs]

Photo chemistry: Comparison of thermal and photo chemical

reactions – definition of photochemical reactions – Beer – Lambert’s

Law – Quantum efficiency – reasons for low and high quantum yield

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with examples – Jablonski diagram – fluorescence – phosphorescence

– photosensitization – application of photochemistry.

UNIT – III: Soloid state – I [12 Hrs]

a. Crystallography : Definition – unit cell, face and edge of a

crystal. Interfacial angle and crystal lattice

b. Laws of Crystallography.

i. Laws of symmetry – symmetry elements – plane, axis

and centre of symmetry.

ii. Law of constancy of interfacial angle

iii. Law of rational indices.

c. Crystallographic system: Bravais lattices – simple cubic face

centred cubic and body centered cubic.

d. X-ray diffraction – Braggs equation.

UNIT – IV: Co – ordination compounds [12 Hrs]

Definition, nomenclature – definition of various terms involved in

co–ordination chemistry – Werner’s theory – EAN rule – Valence bond

theory – low spin and High spin complexes – magnetic properties –

limitations of VB theory - Chelates (preliminary idea)

UNIT – V: [12 Hrs]

01. Catalysis: Definition – different types of catalysis – acid –

base catalysis – auto catalyst – catalytic poisoning –

promoters.

02. Polymers: Definition – properties of polymers – addition and

condensation polymerization reactions with examples –

Natural rubber – isoprene unit – preparation and application

of polystyrene, Urea – formaldehyde resin.

TEXT BOOKS:

01. Madan R.D., Satyaprakash, Modern Inorganic Chemistry, S.Chand

and Co., New Delhi.

02. Puri, Sharma, Pathania, Text Book of Physical Chemistry, S.Chand

and Co., New Delhi.

REFERENCES:

01. Bahl.B.S., Tuli G.D. Arun Bahl, Essentials of Physical Chemistry,

S.Chand and Co., New Delhi.

02. Madan R.D., Satyaprakash, Modern Inorganic Chemistry, S.Chand

and Co., New Delhi.

03. Puri, Sharma, Pathania, Text book of Physical Chemistry, S.Chand

and Co., New Delhi.

04. Soni P.L., Text book of Inorganic Chemistry, S.Chand and Co., New

Delhi.

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Allied Chemistry ORGANIC AND PHYSICAL CHEMISTRY

[Physics Major Students] Code: 14223621

SEMESTER - VI 4 Hrs/Week

Credits 4

Objectives:-

To have a knowledge of chemotheraphy, Thermodynamics, solid state,

Chemical Kinetics and Spectroscopy.

UNIT – I: Chemotheraphy, Antibiotics and Vitamins: [12 Hrs]

(a) Chemotherapy: Preparation – structure and uses of the

following: Sulpha drugs – sulphadiazine – Prontosil and

Prontosil-s.

(b) Antibiotics: Definition – Penicillin – Tetracycline (Auromycin and

terramycin) – streptomycin and chloromycetin – structure and

uses.

(c) Vitamins: Classification and biological function of vitamin A, B6,

C, D, E and K (Structural elucidation not necessary)

UNIT – II: [12 Hrs]

Thermodynamics: Importance of thermodynamics – terms used

in thermodynamics – open and closed systems – state functions and

path functions – extensive and intensive properties. Reversible and

irreversible processes – statement and mathematical form of first law of

Thermodynamics – Heat capacity at constant volume and pressure -

relation between Cp and Cv - Statement of second law of

thermodynamics – entropy – physical significance of entropy – Gibb’s

free energy and its significance.

UNIT – III: [12 Hrs]

Chemical Kinetics: Reactions rate – order and molecularity of a

reaction – Zero order – first order – first order rate equation and Half

– life period – derivation – Examples of first order reactions, second

order reactions.

Enzyme catalysis – Michaelis – Menten mechanism –

Lineweaver – Burk Plot – Significance of Km.

UNIT – IV: [12 Hrs]

Solid State - II:

a) Experimental methods of determine interplaner spacing – X-ray

spectrophotometer – Debye – Scherrer method.

b) Types of Crystals – ionic, molecular, covalent and metallic

crystals (Elementary idea).

i. Ionic crystal – Analysis of NaCl, CsCl.

ii. Molecular Crystal – Water

iii. Metallic bonds in metals

iv. Covalent crystals – Diamond and Graphite.

c) Conductors, Insulators and semiconductors – Frankel and

schottky defects.

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UNIT – V: [12 Hrs]

Spectroscopy: Basic principles of UV and IR spectroscopy –

Identification of simple organic molecules – ethanol and dimethyl ether,

acetaldehyde and acetone, ethylene and acetylene, cis – 2 – butene and

trans – 2 – butene, methyl amine, dimethyl amine and trimethyl amine –

proton NMR spectroscopy – Principle – Chemical shift – spectrum of

ethanol.

TEXT BOOKS:

01. Bahl B.S., and Arun Bahl, Advanced Organic Chemistry,

S.Chandand Co., Ltd, 2009, New Delhi.

02. Bahl B.S., and Tuli G.D., Arun Bahl, Essentials of Physical

Chemistry, S.Chand and Co., New Delhi.

03. Puri, Sharma, Pathania, Text Book of Physical Chemistry, S.Chand

and Co., New Delhi.

04. Jayashree ghosh, Fundamental concepts of Appliedchemistry

S.Chand & Co, New Delhi 2008.

REFERENCES:

01. Bahl B.S., and Arun Bahl, Advanced organic chemistry, S.Chand

and Co., Ltd. 2009, New Delhi.

02. Bahl B.S., Tuli G.D., Arun Bahl., Essentials of Physical Chemistry,

S.Chand and Co., New Delhi.

03. Soni P.L., Text book of Organic Chemistry, S.Chand and Co., New

Delhi.

04. Puri, Sharma, Pathania., Text book of Physical Chemistry,

S.Chand and Co., New Delhi.

Allied Chemistry Lab PRACTICAL – II

ORGANIC ANALYSIS LAB

[For Physics Major Students]

SEMESTER V & VI Code: 14223622

2 Hrs/Week

Credits 3

Organic Analysis:

Analysis of an Organic compound containing one functional group

– aliphatic / aromatic – saturated / unsaturated – elements present

other than C, H and O – functional groups – colour reactions for

functional groups (acids, phenols, aldehydes, ketones, esters, amines,

amides, anilides, aliphatic, diamide and monosaccharide.)

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B.Sc CHEMISTRY: Those who have joined from the Academic year 2014 – 15 onwards under CBCS System

EVALUATION PATTERN

Internal : 25 Marks External : 75 Marks

INTERNAL:

Test – 20 (average of the better two of the three tests conducted)

Assignment – 5

Question Paper Pattern:

INTERNAL EXTERNAL

Part – A : 6 1 = 6

(Multiple Choice)

Part – B : 2 7 = 14

(Either /Or)

Part – C : 2/3 10= 20

*40

Part – A :10 1 = 10

(Multiple Choice)

Part – B : 5 7 = 35

(Either /Or)

Part – C : 3/510 = 30

75

* Internal test mark 40 will be converted to 20.

SBE & NME

INTERNAL EXTERNAL

Part – A : 3 1 = 3

(Multiple Choice)

Part – B : 1 7 = 7

(Either /Or)

Part – C : 1/2 10= 10

20

Part – A :15 1 = 15

(Multiple Choice)

Part – B : 3/5 10 = 30

Part – C : 2/415 = 30

75

The Assignment Component of any one of the subjects (except

Non-Major Electives and other Department Papers) in the III and IV

Semesters in UG COURSES (as decided by the Head of the Department

on Rotation Basis) should be in the form of REPORT (as per the

guidelines) on the HANDS ON EXPERIENCE GAINED by the students

from their:

Part-time job (or)

Self-Employment (or)

Making of Hand made Products (or)

Survey on Marketing of goods and services (or)

Maintenance and Servicing of Equipments (or)

How things Work (or)

Working Principles of Toys/gadgets…. Models (or)

Making of working Models using some Concepts

Students should maintain a work diary which should be monitored

by the course teacher guided by a Monitoring Committee of the

concerned department.