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I AP42 Section:
/Reference: Title:
1 .I
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Results of the September 10 and 11, 1991 Mercury Removal Tests on the Units 1 & 2, and Unit 3 Scrubber Systems at the NSP Sherco Plant in Becker, Minnesota. Interpoll Laboratories, In( Circle Pines, Minnesota.
October 30, 199
3
SWTEMBER 10 AhD 11. 1991 TESTS ON THE UNITS 1 6 2.
AN0 UNIT 3 SCRUBBER SYSTEIlS AT THE NSP SiERCO P M I N BECKER. MINNESOTA
2.. I I I I I ? I c I I I I 1 I
I n t e r p o l 1 Labora to r ies . Inc. 4500 B a l l Road N.E.
C i r c l e Pines, Minnesota 55014-1819
TEL: (612) 786-6020 FAX: (612) 786-7854
RESULTS OF THE SEPTEMBER 10 AND 11. 1991 WERCURY REHOVAL TESTS ON THE UNITS 1 6 2.
AND UNIT 3 SCRUBBER SYSTEMS AT THE NSP SHERCO P M I N BECKER. MINNESOTA
Submitted t o :
NORTHERN STATES POYER COHPANY 414 N i c o l l e t M a l l
Minneapol is. Minnesota 55401
A t t e n t i o n : P a t t y BOyCe
Reviewed by:
Report Number 1-3409 October 30. 1991 SP/SlP
Daniel JYDespen’ Manager F i e l d Tes t i ng Support Group
TABLE OF M E W S
ABBREVIATIONS . . . . . . . . . . . . . . . . . . . . . . . . 111
1 INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . 1
2 SUMMARY AND DISCUSSION . . . . . . . . . . . . . . . . . . . . 4
3 RESULTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . B
3 . 1 Resu l ts of Orsat and Mois ture Analyses . . . . . . . . . . 9 0
3 . 2 Resu l ts o f Mercury Determinat ions . . . . . . . . . . . . 14
4 RESULTS OF FUEL ANALYSIS . . . . . . . . . . . . . . . . . . . 19
APPENDICES:
A - Sampling T r a i n C a l l b r a t i o n Data
B - Locat ion of Test Por ts
C - F i e l d Data Sheets
D - I n t e r p o l 1 L a b o r a t o r i e s A n a l y t i c a l Data
E - U n i t s 1 .2 B 3 Trend Logs
F - Procedures
C - C a l c u l a t i o n Equations
ACFM cc i m l ) DSCFH DSML OEG-F ( ' F ) O I A . FP FT/SEC q C PM GR/ACF GR/DSCF
HP HRS I N . 1N.HG. IN.WC. LE LE/ DSC F LB/HR
LB/HMBTU LTPD HW
q/dscm
L W I O ~ B T U
mq/Nmj, ug/Nm- microns (urn) HIN. nq ohm-Cm PM PPH PPH PDmC DDm. d p0m.w D D t P S I SO. F l . TPD uq v /v u/w <
ABBREVIATIONS
actua l cubic t e e t D e r minute cubic cent imeter ( m i l l i l i t e r ) standard Cubic foot of drv gas Der minute d ry standard m i l l i l i t e r aeqrees Fahrenhei t c i ameter f i n i s h e d Drodu i t t o r o l a n t f e e t Der second qram qa.1 Ions Der minute q ra ins Der ac tua l cubic t o o t q ra ins Der d ry standard cubic f o o t grams Der d r v standard Cubic meter horseDOwe r hours inches inches of mercurv inches o f water DOUnd pounds Der a r v standard cubic f o o t Dounas Der hour oounds Der m i l l r o n B r i t i s h Thermal Un a t inDut pounds Der m i l l i o n B r i t i s h Thermal U n i t s heat inDut lonq tons Der dav megawatt m i l l i g r a m s Der d rv standard cubic meter micrograms Der d rv standard cubic meter micrometer minutes nanoqrams ohm-centimeter p a r t i c u l a t e mat te r Dounds Der hour Dar ts D e r m i l l i o n D a r r s D e r m i l l i o n carbon Dar ts Der m i l l i o n . a rv o a r t s D e r m i l l i o n . w e t oa r t s oer t r i l l i o n Dounas Der souare i nch souare f e e t tons oer dav m i crograms Dercent b v volume oercent bv weiqnt - c (when f o l l o w i n q a number)
Standard cond i t i ons are ae t i ned as 68 'F ( 2 0 'C) and 2 9 . 9 2 I N . of mercurv Dressure.
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t h e UDI/EEI database . J e f f has been working w i t h t h e NSP data f o r f i v e y e a r s and, t h e r e f o r e , I a m t a k i n g h i s word on t h i s .
J j
1 INTRODUCTION
On September 10 and 11. 1991, I n t e r p o l l Laborator ies personnel
conducted mercury removal t e s t s on the U n i t s 1 & 2 Scrubber System, and
t h e U n i t 3 Scrubber System a t the Nor thern States Power (NSP) Sherburne
County Generat ing S t a t i o n l oca ted i n Becker. Minnesota. On-si te t e s t i n g
was p e r f o m d by D. Van Hoever. E . Brennan. G. Hove and R. Aschenbach.
Coord ina t ion between t e s t i n g a c t i v i t i e s and p l a n t opera t ion was prov ided
by Bob Catron of NSP. The t e s t s were n o t wi tnessed by a member o f the
Minnesota P o l l u t i o n Cont ro l Agency.
U n i t s 1 8 2 are i d e n t i c a l Combustion Engineer ing 750 megawatt
b o i l e r s which came on l i n e i n 1976. Dur ing the t e s t , both b o i l e r s were
f i r e d w i th 70% Wyoming and 30% Montana p u l v e r i z e d subbituminous coa l .
Emissions are c o n t r o l l e d by a w e t f g d scrubbing system which cons is t s o f
twe lve i n d i v i d u a l rod ven tu r i scrubber spray towers. Cleaned Flue gas i s
exhausted t o the atmosphere by a 6OO-foot r a d i a l s t e e l - l i n e d concrete
s tack c o m n t o U n i t s 1 & 2.
9 4
The Uni t 3 i s a Babcock and Wilcox 860 megawatt b o i l e r which came on
l i n e I n 1987. The b o i l e r i s f i r e d w i t h p u l v e r i z e d subbituminous coal
(1001. Montana (Westmoreland) c o a l ) . P a r t i c u l a t e and s u l f u r d iox ide
emissions are c o n t r o l l e d by a d r y scrubber c o n s i s t i n g o f a sDray d r y e r
absorber (SDA) and baghouse. ScNbbed f l u e gas i s exhausted t o the
atmosphere by a 650-foot h i g h r a d i a l b r i c k - l i n e d concrete stack.
Evaluat ions were performed I n accordance w i th EPA Methods 1 - 4 and
101A. CFR T i t l e 40, Pa r t 60. Appendlx A ( r e v i s e d J u l y 1. 1990). Previous
da ta c o l l e c t e d a t t h i s s i t e was used t o se lec t t h e appropr ia te nozzle
d iameter requ i red For i s o k i n e t i c sample wi thdrawal . An I n t e r p o l l Labs
sampling t r a i n which meets o r exceeds s p e c i f i c a t i o n s i n the above-cited
re fe rence was used t o c o l l e c t mercury samples by means o f a heated g lass-
l i n e d probe. The c o l l e c t e d samples were analyzed by c o l d vaDor atomic
abso rp t i on (CV/AA) .
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An i n t e g r a t e d f l u e gas sample was e x t r a c t e d s i rml taneous ly w i th each
mercury sample us ing a s p e c i a l l y designed gas sampling system. I n t e g r a t e d
Flue gas samples were c o l l e c t e d i n 4 4 - l i t e r Ted lar bags housed i n a
p r o t e c t i v e aluminum c o n t a i n e r . A f t e r sampling was complete, the bags were
sealed and re tu rned t o t h e l abo ra to ry For Orsat ana lys i s . P r i o r t o
sampling, the Ted lar bags are l eak checked a t 15 IN.HG. vacuum w i t h an i n -
l i n e rotameter. Bags w i th any de tec tab le in leakage are d iscarded.
Tes t i ng a t the I n l e t t o t h e U n i t s 1 & 2 Scrubber System was
perfonned a t s i x o f twe lve scrubber modules (Modules 101. 104. 107. 201,
204. and 207). Tes t ing was conducted from a h o r i z o n t a l r o w o f 6 p o r t s on
each o f the module i n l e t s . Two i n l e t s were sampled du r ing each OF the
th ree t e s t runs . A 24-point t r a v e r s e was used t o i s o k i n e t i c a l l y c o l l e c t
rep resen ta t i ve mercury samples f r o m each of t h e module i n l e t s . Each p o i n t
was sampled f o r 2.5 minutes For a t o t a l o f 60 minutes per module. two
modules were t e s t e d p e r run f o r a t o t a l of 120 minutes per run.
Tes t ing a t t h e U n i t s 1 and 2 Comnon Stack was conducted f r o m f o u r
t e s t p o r t s on t h e Stack o r i e n t e d a t 90 degrees. These t e s t p o r t s are
l oca ted seven s tack d iameters downstream o f the breaching i n l e t and e leven
diameters upstream o f t h e s tack e x i t . A 16-point t rave rse was used t o
i s o k i n e t i c a l l y e x t r a c t rep resen ta t i ve mercury samples. Each t rave rse
p o i n t was sampled e i g h t minutes t o g i v e a t o t a l sampling t ime o f 128
minutes per run.
Tes t lng a t the I n l e t t o t h e U n i t 3 Scrubber System was conducted
from a h o r i z o n t a l r o w o f two t e s t p o r t s . A 24-point t rave rse was used t o
i s o k l n e t i c a l l y e x t r a c t rep resen ta t i ve mercury samples. Each t rave rse p o i n t
was sampled For f i v e minutes For a t o t a l OF 120 mlnutes p e r run.
Tes t i ng a t the U n i t 3 Stack was conducted f r o m Four t e s t p o r t s
o r i e n t e d a t 90 degrees. These t e s t p o r t s are l oca ted seven stack
diameters downstream o f t h e breach ing i n l e t and e leven diameters upstream
of the stack o u t l e t . A 16-point t r a v e r s e was used t o i s o k i n e t i c a l l y
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extract representat ive mercury samples. Each traverse point was sampled
e ight minutes t o g ive a t o t a l sampling t ime o f 128 minutes per run.
The important resu l ts of the t e s t are sumnarized i n Section 2 .
Deta i led resul ts ape presented i n Section 3. F i e l d data and a l l other
supporting information are presented i n the appendices.
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SlrmMry of the Emission Factors for the Mercury Determlnatlons
Conducted September 10 and 11. 1991 on U n i t s 1 6 2 and Unf t 3 a t the
Nsp Sherburne County Plant In k c k e r . Hlnnesota.
Concentratl on Oxygen Emission Factor
(UQ/Nm’) (8v/v.d) (LWO~BTU)
pun ( I n l e t ) (Stack) (Irlle t ) I S t ack 1 ( I n l e t ) (Stack),
( U n i t s 1 81 2) 1 8.8 2 13.9
3 12.1
( U n i t 3 )
1 11.3 2 14.7 3 14.1
3.4 9.40 7.20 9.76XlO-* 3.17X10’
2.0 8.20 7.10 1.40X10-’ 1.85XlO’
7.3 7.80 7.10 l.lSXlO-’ 6.75XlO-‘
5.3 6.0 6.4
6.70 6.30 5.60 6.20 7 .oo 6.00
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Table 1. Sumnary of the Results o f t h e September 10. 1991 Mercury Test
on the Units 1 B 2 Wet Scrubber System a t the NSP Sherburne
County Generating Stat ion.
Concentration Mass Rate Removal (ua/Nm’) LB/HR 1 E f f .
Run I n l e t Stack I n l e t Stack ( % . W / W l
1 8 .8 3 . 4 0 .102 0 .042 58.3
2 13 .9 2.0 0 .163 0 .025 04 .4
3 1 2 . 1 1 . 3 0 . 1 3 9 0.090 3 5 . 1
AVg . 11 .6 4 . 2 0 .135 0 .053 59 .3
Table 2 . Sumnary o f the Results o f t h e September 11. 1991 Mercury Test on t h e U n i t 3 D r y Scrubber System a t the NSP Sherburne County
Cenerati ng S ta t ion .
Concentration Mass Rate Removal
(ua/Nm’) ( LB/HR) E f f .
Run In l e t Stack I n l e t Stack ( % . U / U l
1 11 .3 5 . 3 0 . 0 8 1 0 .038 52.8
2 14 .7 6 .0 0.105 0 .043 59.4
3 1 4 . 1 6 . 4 0 . 0 9 1 0 .044 51.4
~
Avg . 1 3 . 4 5 . 9 0 .092 0 . 0 4 2 54 .5
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Table 3 presents mercury mass r a t e s based on coal analyses. One
sample o f U n i t s 1 8 2 coa l and one sample of Un i t 3 coal were analyzed f o r
mercury content . P o t e n t i a l mercury mass ra tes from the U n i t s 1 8 2 and
U n i t 3 b o i l e r s were computed based on the r e s u l t s o f these coa l analyses
and the coal feed r a t e s r e p o r t e d i n the P l a n t l ogs (Appendix E ) . I n the
case o f U n i t 3 the coa l d i d n o t con ta in a measurable q u a n t i t y o f mercury
a t a d e t e c t i o n l i m i t o f 0.02 mg/Kg. Th is de tec t i on l i m i t was used i n
computing the p o t e n t i a l mass r a t e . I t i s impor tant t o no te t h a t an
a d d i t i o n a l source of mercury e x i s t s f o r U n i t 3 . the l ime a d d i t i v e used i n
t h e fgd scrubber. Lime f rom t h l s scrubber was analyzed p r e v i o u s l y (March
1990) and found t o c o n t a i n 0.07 mg/Kg mercury. A t an average l ime feed
r a t e o f 4 .0 LB/HR the l i m e c o n t r l b u t e s 0.001 LB/HR mercury f o r a t o t a l o f
0.021 LB/HR. Exce l l en t c o r r e l a t i o n i s seen t o e x i s t between t h e p o t e n t i a l
mass ra tes c a l c u l a t e d from the feed and the mass ra tes measured a t the
Scrubber I n l e t s ( b o i l e r o u t l e t s ) fo r U n l t s 1 8 2 , the r e s u l t s for U n i t 3
do no t compare as w e l l . The cause o f t h e poor c o r r e l a t i o n f o r U n i t 3 was
i n v e s t i g a t e d and no source f o r the discrepency was detennined.
No d i f f i c u l t i e s were encountered i n t h e f i e l d o r i n the l abo ra to ry
eva lua t i on o f the samples. O n t h e b a s i s o f t h i s f a c t and a complete
review o f the e n t i r e da ta and r e s u l t s , i t i s our op in ion t h a t the r e s u l t s
as q u a l i f i e d above are accurate and c l o s e l y r e f l e c t the ac tua l values
which e x i s t e d a t the t ime the t e s t was performed.
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Table 3 . Sumnary o f Potent ia l Mercury Mass Rates F r o m the Units l&2.
and Uni t 3 B o i l e r s a t the Northern States Power. Sherburne
County Generating S t a t i o n .
Potent i a1
Coal Feed Mass Rate
Run I T P H I ILB/HR) ILB/HR)
( U n l t s laZ) 1 764 1528000 0.138
2 77s 155oooO 0.140
3 766 1532000 0.138
Avg . 0.138
( U n i t 3 )
1 490 980030 0.020
2 494 988ooo 0.020
3 503 1006000 0.020
Avg . 0.020
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3 RESULTS
The r e s u l t s o f a l l f i e l d and l a b o r a t o r y eva lua t i ons are presented i n
t h i s sec t ion . Gas compos i t ion (Orsat and mois tu re) a re presented f i r s t
fo l lowed by t h e computer p r i n t o u t o f the mercury r e s u l t s . Pre l im inary
measurements i n c l u d i n g t e s t p o r t l o c a t i o n s are g i ven i n the appendices.
The r e s u l t s have been c a l c u l a t e d on an IBM PC Computer us ing
programs w r i t t e n i n Extended BASIC s p e c i f i c a l l y for source t e s t i n g c a l -
c u l a t i o n s . EPA-published equat ions have been used as the bas i s of the
c a l c u l a t l o n techniques i n these programs.
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3.1 R e s u l t s o f Orsat and Mois ture Analyses
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I n t e r p o l 1 Labs Report No. 1 - 3 4 0 9 Nor the rn S ta tes Power Company
Becke r, H i nne so t a
T e s t No. 1 U n i t s 1 B 2 Scrubber I n l e t s
R e s u l t s o f Orsat 6 M o i s t u r e Analyses-----Methods 3 6 4 ( * v / v )
Date o f r u n
D r y b a s i s ( o r s a t )
Run 1 Run 2 Run 3 0 9 - 1 0 - 9 1 0 9 - 1 0 - 9 1 0 9 - 1 0 - 9 1
carbon d i o x i d e . . . . . . . . . . . . 10.30 1 1 . 3 0
oxygen .................... 9 . 4 0 8 . 2 0
carbon monoxide . . . . . . . . . . . 0.00 0.00
n i t r o g e n . . . . . . . . . . . . . . . . . . 8 0 . 3 0 80 .50
Wet b a s i s ( o r s a t )
carbon d i o x i d e . . . . . . . . . . . . 9 . 4 8 1 0 . 2 0
oxygen. . . . . . . . . . . . . . . . . . . . 8 . 6 5 7 . 4 1
carbon monoxtde. . . . . . . . . . . 0.00 0.00
n i t r o g e n . . . . . . . . . . . . . . . . . . 7 3 . 9 1 7 2 . 7 0
water vapor . . . . . . . . . . . . . . . 7 . 9 6 9 . 6 9
D r y mo lecu la r we lgh t . . . . . . . . 3 0 . 0 2 3 0 . 1 4
Wet mo lecu la r we igh t . . . . . . . . 2 9 . 0 7 2 8 . 9 6
S p e c i f i c g r a v i t y . . . . . . . . . . . . 1 . 0 0 4 1.000
Water mass f l o w . . . . . . (LB/HR) 0.00 0.00
1 1 . 7 0
7 . 0 0
0.00
80.50
10.60
7 . 0 7
0.00
1 2 . 9 6
9 . 3 6
3 0 . 1 8
2 9 . 0 4
1 . 0 0 3
0.00
1 . 1 1 7 1 .124 1 . 1 2 0 10 F O
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T e s t No. 1 U n i t s 1 & 2 S t a c k
Resul ts o f O r s a t 6 Moisture Ana
D a t e o f run 0
D r y b a s i s ( o r s a t )
c a r b o n d i o x i d e . . . . . . . . . . . . o x y g e n . . . . . . . . . . . . . . . . . . . . c a r b o n m o n o x i d e . . . . . . . . . . . n i t r o g e n . . . . . . . . . . . . . . . . . .
Y e t b a s i s ( o r s a t )
c a r b o n d i o x i d e . . . . . . . . . . . . o x y g e n .................... c a r b o n m o n o x i d e . . . . . . . . . . . n i t r o g e n . . . . . . . . . . . . . . . . . . w a t e r v a p o r . . . . . . . . . . . . . . .
D r y m o l e c u l a r w e i g h t . . . . . . . . Wet m o l e c u l a r w e i g h t . . . . . . . . S p e c i f i c g r a v i t y . . . . . . . . . . . . W a t e r mass f l o w . . . . . . (LB /HR)
F O
I n t e r p o l 1 L a b s R e p o r t No . 1 - 3 4 0 9 N o r t h e r n S t a t e s Power Company
B e c k e r , M i n n e s o t a
yses----- Methods 3 L 4 ( t v / v )
Run 1 Run 2 Run 3 -10-91 0 9 - 1 0 - 9 1 0 9 - 1 0 - 9 1
1 2 . 2 0
7 . 2 0
0.00
8 0 . 6 0
10 .46
6 . 1 7
0.00
6 9 . 1 0
14 .27
30 .24
2 8 . 4 9
0.984
0 .00
1 2 . 4 0 12 .40
7 . 1 0 7 . 1 0
0.00 0.00
8 0 . 5 0 8 0 . 5 0
1 0 . 5 6 10.53
6 .05 6 . 0 3
0.00 0.00
6 8 . 5 4 6 8 . 3 4
14 .86 1 5 . 1 1
3 0 . 2 7 30 .27
2 8 . 4 5 2 8 . 4 1
0 . 9 8 3 0 . 9 8 1
0.00 0.00
' 1 . 1 2 3 1 . 1 1 3 1 . 1 1 3
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I n t e r p o l 1 L a b s R e p o r t N o . 1 - 3 4 0 9 N o r t h e r n S t a t e s Power Company
Bec k e r, M i nne s o t a
T e s t No. 2 U n i t 3 S c r u b b e r I n l e t
R e s u l t s o f O r s a t L M o i s t u r e A n a l y s e s - - - - - M e t h o d s 3 L 4 ( * v / v )
D a t e o f r u n
D r y b a s i s ( o r s a t )
Run 1 Run 2 Run 3 09-11-91 0 9 - 1 1 - 9 1 0 9 - 1 1 - 9 1
c a r b o n d i o x l d e . . . . . . . . . . . . 1 2 . 6 0
o x y g e n .................... 6 . 7 0
c a r b o n m o n o x i d e . . . . . . . . . . . 0.00
n l t r o g e n . . . . . . . . . . . . . . . . . . 80.10
w e t b a s i s ( o r s a t . )
c a r b o n d i o x i d e . . . . . . . . . . . . 11.27
o x y g e n .................... 5 . 9 9
c a r b o n m o n o x i d e . . . . . . . . . . . 0.00
n i t r o g e n . . . . . . . . . . . . . . . . . . 72.20
w a t e r v a p o r . . . . . . . . . . . . . . . 1 0 . 5 3
D r y m o l e c u l a r w e i g h t . . . . . . . . 3 0 . 2 8
Wet m o l e c u l a r w e i g h t . . . . . . . . 2 0 . 9 9
S p e c i f i c g r a v i t y . . . . . . . . . . . . 1.001
W a t e r mass f l o w . . . . . . ( L B / H R ) 0.00
1 3 . 6 0 1 2 . 4 0
5 . 6 0 7 .00
0.00 0.00
80.80 80.60
1 2 . 1 3 1 1 . 3 3
4 . 9 9 6 .40
0.00 0.00
7 2 . 0 1 7 3 . 6 7
10.81 8 . 6 0
3 0 . 4 0 3 0 . 2 6
2 9 . 0 6 2 9 . 2 1
1 . 0 0 4 1 . 0 0 9
0.00 0.00
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I n t e r p o l 1 L a b s R e p o r t N o . 1-3409 N o r t h e r n
B e c k e r . M l n n e s o t a
T e s t N o . 2 U n i t 3 S t a c k
Rr ru l t i o f Orrat L Mol rtura Anrlyrer - - - - - Methods 3 L 4(Qv/v)
D a t e o f r u n
D r y b a s i s ( o r s a t )
c a r b o n d i o x i d e . . . . . . . . . . . . o x y g e n .................... c a r b o n m o n o x l d e . . . . . . . . . . . n l t r o g e n . . . . . . . . . . . . . . . . . .
Wet b a s i s ( o r s a t )
c a r b o n d i o x i d e . . . . . . . . . . . . o x y g e n .................... c a r b o n m o n o x i d e . . . . . . . . . . . n l t r o g e n . . . . . . . . . . . . . . . . . . w a t e r v a p o r . . . . . . . . . . . . . . .
D r y m o l e c u l a r w e i g h t . . . . . . . . Wet m o l e c u l a r w e i g h t . . . . . . . . S p e c l f l c g r a v l t y . . . . . . . . . . . . W a t e r mass f l o w . . . . . . (LBIHR)
F O
Run 1 Run 2 Run 3 09-11-91 09-11-91 09-11-91
13.00
6.30
0.00
00.70
11.17
5.41
0.00
69.35
14.07
30.33
28.60
0.988
0.00
13.10 13.30
6.20 6.00
0.00 0.00
80.70 80.70
11.17
5.28
0.00
68.78
14.77
30.34
28.52
0.985
0.00
11.39
5.14
0.00
69.12
14.34
30.37
28.59
0.988
0.00
, l . 123 1.122 1.120 13
I I: i i i I i i i i i i i i i i i i I
3.2 Results o f Mercury SarnDlinq
1 4
I I I I I I I I I B I i I I I I I I I
I.
I I n t e r p o l 1 L a b s R e p o r t No. 1 - 3 4 0 9
N o r t h e r n S t a t e s Power Company B e c k e r . M i n n e s o t a
T e s t No. 1 U n i t s 1 B 2 S c r u b b e r I n l e t s
Results o? Multl-Metal Modl?lcd Method 5 (4M5) Sampllng .....
D a t e o f r u n Run 1
0 9 - 1 0 - 9 1
T ime r u n s t a r t / e n d . . . . . (HRS) 0 8 1 5 - 1 0 3 0
S t a t i c p r e s s u r e . . . . . . (1N.WC) Cross s e c t i o n a l a r e a ( S Q . F T ) P i t o t t u b e c o e f f i c i e n t . . . . . . W a t e r i n s a m p l e g a s
c o n d e n s e r . . . . . . . . . . . . . ( M L ) i m p i n g e r s . . . . . . . . . . (GRAMS) d e s i c c a n t . . . . . . . . . . (GRAMS) t o t a l . . . . . . . . . . . . . . (GRAMS)
Gas m e t e r c o e f f i c i e n t . . . . . . . B a r o m e t r i c p r e s s u r e . . (1N.HC) Avg . o r i f . p r e s . d r o p . . ( I N . W C ) Avg . g a s m e t e r t e m p . . ( D E F - F )
Vo lume through g a s m e t e r . . . . a t m e t e r c o n d i t i o n s . . . ( C F ) s t a n d a r d c o n d i t i o n s . (DSCF) s t a n d a r d c o n d i t i o n s . . ( N M ’ )
T o t a l s a m p l i n g t i m e . . . . ( M I N ) N o z z l e d i a m e t e r . . . . . . . . . ( I N ) A v g . s t a c k g a s t e m p . . (DEG-F)
V o l u m e t r i c P l o w r a t e . . . . . . . . a c t u a l . . . . . . . . . . . . . . (ACFH) d r y s t a n d a r d . . . . . . . (DSCFM)
I s o k i n e t i c v a r i a t i o n . . . . . ( % )
15
1 1 . 8 8 7 6 . 5 0 0 . 8 4 0
0.0 9 4 . 0 1 3 . 0
1 0 7 . 0
0 . 9 9 9 0 2 9 . 2 0 0.87 8 6 . 2
6 1 . 8 1 5 8 . 3 5 1 . 6 5 2
1 2 0 . 0 0 . 1 8 7 2 8 7
3 2 3 0 5 6 2 1 1 3 6 5
9 2 . 3
Run 2 0 9 - 1 0 - 9 1
1 1 0 5 - 1 3 4 0
1 1 . 8 8 1 6 . 5 0 0 . 8 4 0
0.0 1 1 3 . 0
1 5 . 0 1 2 4 . 0
0 . 9 9 9 0 2 9 . 2 0
0 . 8 1 8 4 . 0
5 9 . 3 4 5 6 . 2 4 1 . 5 9 3
1 2 0 . 0 0 . l e 7
2 9 0
3 0 5 6 2 8 1 9 5 3 9 5
9 6 . 3
Run 3 0 9 - 1 0 - 9 1
1 4 2 0 - 1 6 4 3
1 1 . 8 8 7 6 . 5 0 0 . 8 4 0
0.0 9 9 . 0 11 .o
1 1 0 . 0
0 . 9 9 9 0 2 9 . 2 0
0 . 6 4 8 7 . 3
5 3 . 3 1 5 0 . 2 0 1 . 4 2 2
1 2 0 . 0 0 . l a 7
2 8 2
2 7 4 3 9 6 1 7 7 8 3 8
9 4 . 4
n I 1 I I I 1
I i
i i il I I I I I
I i
,
I n t e r p o l l L a b s R e p o r t No. 1-3409 N o r t h e r n S t a t e s Power Company
B e c k e r . M i n n e s o t a
T e s t No. 1 U n i t s 1 B 2 S t a c k
Raaul t r o f Multi-Metml M o d i f i e d Method 5 (41153 Sampling .....
D a t e o f r u n Run 1
09- 10- 9 1
T ime run s t a r t / e n d . . . . . ( H R S ) 0815-1032
S t a t i c p r e s s u r e . . . . . . ( 1 N . W C ) C r o s s s e c t l o n a l a r e a ( S Q . F T ) P l t o t t u b e c o e f f i c i e n t . . . . . . W a t e r I n samp le g a s
c o n d e n s e r . . . . . . . . . . . . . ( M L ) i m p i n g e r s . . . . . . . . . . (CRAMS) d e s i c c a n t . . . . . . . . . . ( G R A M S ) t o t a l . . . . . . . . . . . . . . ( G R A M S )
Gas m e t e r c o e f f l c i e n t . . . . . . . B a r o m e t r i c p r e s s u r e . . ( I N . H G ) A v g . o r 1 f . p r e s . d r o p . . ( I N . W C ) Avg . g a s m e t e r t e r n p . . ( D E F - F )
Volume t h r o u g h g a s m e t e r . . . . a t m e t e r c o n d l t i o n s . . . ( C F ) s t a n d a r d c o n d l t i o n s . ( O S C F ) s t a n d a r d c o n d l t i o n s . . ( N M 3 )
T o t a l s a m p l i n g t i m e . . . . ( H I N ) N o z z l e d i a m e t e r . . . . . . . . . ( I N ) A v g . s t a c k g a s t e m p . . ( D E C - F )
V o l u m e t r l c f l o w r a t e . . . . . . . . a c t u a l . . . . . . . . . . . . . . (ACFM) d r y s t a n d a r d . . . . . . . (DSCFM)
I s o k i n e t l c v a r i a t i o n . . . . . ( t )
-1.35 829.58 0.840
0.0 297 .O 36.0
333 .O
1.0058 28.77 1.87 79.8
99.30 94.35 2.672
128.00 .184 182
4932144 3334932
99.4
Run 2 09-10-91
1105-1344
-1.35 829.58 0.840
0.0 330.0 24.0
345.0
1.0058 28.77 1.92 80.2
100.73 95.65 2.708
128.00 .le4 181
5021238 3376641
99.5
Run 3 09-10-91
1420-1639
-1.35 829.58 0.840
0.0 340.0 15.0
355.0
1.0058 28.77 1.86 81.7
99.33 94.04 2.663
128.00 .184 181
4946260 33 13486
99.7
16
I 1 1 I I I I I C i
T e s t No. 2 U n i t 3 S c r u b b e r I n l e t
R08ult1 o f H ~ l t i - H ~ t a l Hod
D a t e o f r u n
I n t e r p o l 1 L a b s R e p o r t No. 1 - 3 4 0 9 N o r t h e r n S t a t e s Power Company
B e c k e r , M i nne s o t a
fiad Wathod 6 ( 4 H S ) Sampling .....
Run 1 0 9 - 1 1 - 9 1
T ime run s t a r t / e n d . . . . . ( H R S ) 0 8 3 5 - 1 0 4 2
S t a t i c p r e s s u r e . . . . . . ( I N . W C ) C r o s s s e c t i o n a l a r e a ( S Q . F T ) P i t o t t u b e c o e f f i c i e n t . . . . . . W a t e r i n s a m p l e g a s
c o n d e n s e r . . . . . . . . . . . . . ( M L ) i m p i n g e r s . . . . . . . . . . (GRAMS) d e s i c c a n t . . . . . . . . . . (GRAMS) t o t a l . . . . . . . . . . . . . . (GRAMS)
Gas m e t e r c o e f f i c i e n t . . . . . . . B a r o m e t r i c p r e s s u r e . . ( 1 N . H G ) Avg. o r i f . p r e s . d r o p . . ( I N . W C ) Avg. g a s m e t e r t e m p . . ( D E F - F )
Volume t h r o u g h g a s m e t e r . . . . a t m e t e r c o n d i t i o n s . . . ( C F ) s t a n d a r d c o n d i t i o n s . (DSCF) s t a n d a r d c o n d i t i o n s . .(NM’)
T o t a l s a m p l i n g t i m e . . . . ( M I N ) N o z z l e d i a m e t e r . . . . . . . . . ( I N ) A v g . s t a c k gas t e m p . . ( D E C - F )
V o l u m e t r i c f l o w r a t e . . . . . . . . a c t u a l . . . . . . . . . . . . . . ( A C F M ) d r y s t a n d a r d . . . . . . . ( D S C F M )
I s o k i n e t i c v a r l a t i o n . . . . . ( t )
17
- 1 7 . 0 0 1 0 9 2 . 0 0
0 . 8 4 0
0.0 1 9 0 . 0
6 . 0 1 9 6 . 0
1 . 0 0 6 6 2 9 . 0 4
1 . 4 5 8 0 . 9
8 2 . 0 8 7 8 . 5 3 2 . 2 2 4
1 2 0 . 0 0 . 2 5 1 2 6 8
3467717 2089932
9 9 . 6
Run 2 0 9 - 11-91
1130-1 336
- 1 7 . 0 0 1 0 9 2 . 0 0
0 . 8 4 0
0.0 1 0 9 . 0
6 .0 1 1 4 . 0
1 . 0 0 6 6 2 9 . 0 4
0 . 4 6 8 4 . 2
4 7 . 1 7 4 4 . 7 5 1 . 2 6 7
1 2 0 . 0 0 . 1 8 7 2 7 5
3 5 8 3 2 0 9 2 1 3 1 2 0 8
100.2
Run 3 0 9 - 1 1 - 9 1
1 4 3 0 - 1 6 3 5
- 1 7 . 0 0 1 0 9 2 . 0 0
0 . 8 4 0
0.0 8 3 . 0
5 . 0 8 8 . 0
1.0066 2 9 . 0 4
0 . 4 6 8 5 . 9
46.63 4 4 . 1 0 1 . 2 4 9
1 2 0 . 0 0 .187 2 7 9
3583699 2 1 7 4 6 5 3
I
96.8
I
1 1 i i
I i
I
I n t e r p o l l L a b s R e p o r t No. 1 - 3 4 0 9 N o r t h e r n
B e c k e r . H i n n e s o t a
T e s t No. 2 U n i t 3 S t a c k
Results of Multi-Metal Modified Method 5 (41153 Sampling .....
D a t e o f r un
pi Run 1
09-11-91
T ime run s t a r t / e n d . . . . . ( H R S ) 0 8 3 5 - 1 0 5 4
S t a t i c p r e s s u r e . . . . . . (1N.WC) C r o s s s e c t i o n a l a r e a ( S Q . F T ) P i t o t t u b e c o e f f i c i e n t . . . . . . W a t e r i n s a m p l e g a s
c o n d e n s e r . . . . . . . . . . . . . ( M L ) i m p i n g e r s . . . . . . . . . . (GRAMS) d e s i c c a n t . . . . . . . . . . (GRAMS)
GRAMS) t o t a l . . . . . . . . . . . . . . Cas m e t e r c o e f f i c i e n t . . . . . . B a r o m e t r i c p r e s s u r e . . IN.HG) A v g . o r i f . p r e s . d r o p . . 1N.WC) A v g . g a s m e t e r t e m p . . ( D E F - F )
Vo lume t h r o u g h g a s m e t e r . . . . a t m e t e r c o n d i t i o n s . . . ( C F ) s t a n d a r d c o n d i t i o n s . ( D S C F ) s t a n d a r d c o n d i t i o n s . . ( N M l )
T o t a l s a m p l i n g t i m e . . . . ( M I N ) N o z z l e d i a m e t e r . . . . . . . . . ( I N ) A v g . s t a c k g a s temp . . (DEC-F)
V o l u m e t r i c f l o w r a t e . . . . . . . . a c t u a l . . . . . . . . . . . . . . ( A C F M ) d r y s t a n d a r d . . . . . . . (DSCFM)
I s o k i n e t i c v a r l a t i o n . . ... ( 4 )
- 0 . 4 6 6 8 3 . 4 9
0 . 8 4 0
0.0 363.0
4 1 . 0 404.0
1 . 0 0 5 8 2 8 . 8 4
2 . 8 4 8 3 . 1
1 2 2 . 5 9 1 1 6 . 3 4
3 . 2 9 4
1 2 8 . 0 0 . 2 4 5 110
2 1 5 4 1 2 2 1 9 0 9 7 4 5
99.4
Run 2 0 9 - 1 1 - 9 1
1 1 3 0 - 1 346
- 0 . 4 6 6 8 3 . 4 9
0 . 8 4 0
0 .0 2 2 6 . 0
1 7 . 0 2 4 3 . 0
1 . 0 0 5 8 2 8 . 8 4
0 . 9 2 81.1
6 9 . 1 6 6 6 . 1 2 1 . 8 1 2
1 2 8 . 0 0 . 1 8 4 110
2 7 7 3 9 2 1 1 9 0 8 2 1 5
100.3
Run 3 0 9 - 1 1 - 9 1
1 4 2 2 - 1 6 3 2
-0 .46 6 8 3 . 4 9
0 . 8 4 0
0.0 2 0 9 . 0
11.0 2 2 6 . 0
1 . 0 0 5 8 28 .84
0 . 8 6 9 0 . 5
6 8 . 3 1 6 3 . 6 3 1. BO2
1 2 8 . 0 0 .184 110
2 6 8 0 0 2 0 1850934
99.5
18
1 1 L I I i i
i i i7 h c ll c i I I
4 RESULTS OF FUEL AHALYSIS
19
I I I I I 1 i I i i i k i f i i i I B
INTERPOLL LABORATORIES, I N C . ( 6 1 2 ) 7 8 6 - 6 0 2 0
NSP/Sherco Laboratory Log No. 4201
Results o f Mercury A n a l y s i s
Mercury, 1 Laboratory
Loq No. Sample I d e n t i f i c a t i o n SamDle TvDe ( W / K Q )
4201-55 Test 1 Composite, Uni ts 1 B 2 Coal 0.09
4201-56 Test 2 Composite. U n i t 3 Coal c 0.02
‘Diges Ion by STM Metho’ D 684-78; J S
20
by EPA SI 846 Meth d 7470.
1 I I I I 1 I I 1 1 I I I I 1 1 I I I
APPENDIX A
SAMPLING T R A I N C A L I B R A T I O N DATA
I I I I 1 1 i i i i I i i I I i i i I -
i T t e r p o l 1 L s b o r a t a r i a : . in,. ( a 1 2 ) 786- d'a 1)
EFC\ Method 5 Gas H e t e r l n g System Q u a l i t y C o n t r o l Check Data Sheet
Instructions: Operate t h e c o n t r o l module e t a f l a w r a t e equZ1 t o ,'-.Hi? f o r 10 minLi tcs b e f o r e a t t a c h i n g t h e urn- b i l i c s l . F:ecord the f o l l o w i n g da ta :
Meter Temp. (OF) T i m e Val Lime Im in) ( C F ) I n l e t O u t 1 e t
C a l c u l a t e Y,, a5 f o l l o w s :
. . I C - - - /. oo3
9 ,3
I + Y,, i s n o t w i t h i n t h e range of 0.97 t o 1.03. " t h e volume m e t e r i n g system s h a i l d be i n v e s t i g a t e d b e f o r e beg inn ing .
CFR T i t l e 39, P a r t 60. Fppendi:.: A , Method 5, S e c t i o n 4.4.1 RI
5-432R A- 1
EPA m e t h o d 5 Gas m e t e r i n g Svstem O u a l i t y C o n t r o l C h e c k Da ta S h e e t
T i rnE
! rnin)
J o b Date 9 - I /
O p e r a t o r n d.4 Module No. 5
P l e t s r Temp. i-F)
( C F I I n l a t O u t 1 et Col urns
I n s t r u c t i o n s : O p e r a t e t h e c o n t r z l m o d u l e a t a f l a w rate e q u a l tG ..'.Hi* f o r 11:) m i n u t 2 5 t a f o r e a t t a c h i n g t h e um- L i l i c s l . F :ecord t h e f z l l o w i n g d a t a :
E a r p r e s s 2.ljg+ i n . nq. = /.C:G>-Y ~ W Z 1-5- i n . W . C .
C a l c u l a t e Y,, as follows:
I f 'i=- i s not w i . t h i r : t h e r a n g e OC (:I.?;' t o 1.I:iS. " t h e v o l u m e l n e t s r i n q s y s t + m 5-n~xlld h e i n v e s t i g a t e d b e f o r e b e g i n n i n g . "
CFR T i t l e <(:I , Fsrt b 9 , A p p e n d i x A . M r t t , o d 5, S e c t i o n 4 . 4 . 1
S-432R A-2 Paae I1
I I I I I SI I 1. I I I I I I 0 I I I I
1 Q i e i 1 i i i i c i c i b I I I I
~
T i m e ( m i n )
EPR Method 5 Gas M e t e r i n g Svs tem Q u a l i t y C o n t r o l C h e c k Data S h e e t
Meter T e m p . (OF)
( C F ) I n l e t O u t 1 et Vo1 ume
I n s t r u c t i o n s : O p e r a t e t h e c o n t r o l m o d u l e a t s + l o w ra te e q u a l t o .''.He f a r 1I:I omminutes b e f o r e a t t a c h i n g t h e um- b i l i c a l . R e c o r d t h e f o l l o w i n g d & t a :
C a l c u l a t e Y,, a5 follows:
L
I f Y,, i 5 n o t w i t h i n t h z r a n g e a+ 0.97 t 1 . E . " t h e v o l u m e m e t e F i n g a .ys tcm should b e i n v e s t i g a t e d b e f o r e b e g i n n i n g . "
CFH T i t l e 4 9 , Part 50. Cppendl:.: A . Method 5 , S e c t i o n 4.4.1
5-432R A- 3 Page 11
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3 I fl 1 I i I i I i
l'nterpol l Laborator ies, Inc. (612) 786-6020
Nozzle C a l i b r a t i o n
Data Sheet
Date of Cal ibra t ion: 9-10-91
Technician : Duke Brennan
Nozzle Number 2 -1
The nozzle i s ro ta ted i n 60 degree increments and the diameter a t each
point i s measured t o the nearest 0.001 inch. The observed readings and
average are shown below.
Post t i o n Diameter
(inches )
1 .I87
2 .189
Average : .187
A - 1 1
In te rpo l1 Laborator ies . Inc. (612) 786-6020
Nozzle C a l i b r a t i o n
Data Sheet
Date o f C a l i b r a t i o n : 9-10-91
Technician: Duane VanHoever
Nozzle Number 1-3
-
The nozzle i s ro ta ted i n 60 degree increments and the diameter a t each 1 :! 1-
point i s measured t o the nearest 0.001 inch. The observed readings and
average are shown below.
Posi t ion Diameter
( I nches )
.187
.186
3 ,180
Average : .104
1 .' I. I I I I I I I 1
A- 12
i I i I i I i I i I i i
i i i I I i
I
I n t e r p o l 1 Laborator ies, I n c .
(612) 786-6020
Nozzle C a l i b r a t i o n
Data Sheet
Date o f C a l i b r a t i o n : 9-11-91
Technician: Duke Brennan
Nozzle NumbeF 7-2
The nozzle i s rotated i n 60 degree increments and the diameter a t each
point i s measured t o the nearest 0.001 inch. The observed readings and
average are shown below.
Posi t ion Diameter
( i nches )
1 .188
2 ,186
3 ,181
Average : . I 8 7
A-13
I I n t e r p o l 1 Laborator ies . Inc.
( 6 1 2 ) 786-6020
Nozzle C a l i b r a t i o n
Data Sheet
Date o f C a l i b r a t i o n : 9-11-91
Technician: Duke Brennan
Nozzle Number 7-3
The nozzle i s ro ta ted i n 60 degree increments and the diameter a t each
point i s measured t o the nearest 0.001 inch. The observed readings and
average are shown below.
Posi t i on Diameter
I1 nches )
1 .251
2 .251
1 - I: 1: I ' 1: 1 I '
Average : . 251
I I I I I I
A- 14
I i i i I i 1 I 1 i I i I b I i I i I
I n t e r p o l 1 Laborator ies, I n c .
( 6 1 2 ) 786-6020
Nozzle C a l i b r a t i o n
Data Sheet
Date o f Cal ibrat ion: 9-11-91
Technician: Duane Van Hoever
Nozzle Number 1-4
The nozzle i s rotated i n 60 degree increments and the diameter a t each
point i s measured t o the nearest 0.001 inch. The observed readings and
average are shown below.
Posi t ion Diameter
1 inches)
1 .245
2 .243
3 ,247
Average : ,245
A - 1 5
Interpol1 Laboratories. Inc.
JcmPcratum Measurement Dsvlce 9-
7 R b 7
thiriocmnh i t t b i indicrrrd w t r i t o n .
rBL .8'3 & Ae
Des1 red Temp (OF) Ncmlnal
0 100 200 300 400 500 600 100 800 900
1000 1100 1200 1300 1400 1500 1600 1700 1800 1900 2000 2100
Temmratura of ResPOMe o f Standard or Unl t Under Test
Simulated T o n u (OF) 1% 1
v lat ion
At
3
I
OF = o f f scale reswnse by u n i t under test (OF) I dev : 100 A t / (460 + t)
B u n i t i n tolerance ff u n i t was not i n tolerance: recal ibrated - See new cal ibrat ion sheet.
5-433
A-16
I I I. I I 1 I I I I I I I I I ' I I I 1
i i i 1 i' i i ..
i
i
I
I I
I 1 I i I i I
Intorpoll Llborrtorlrs. Inc.
Jsoerrtura W c a s u m n t R v l a a l l b r a t i o n S h m
b i M 1
0 100 200 300 400 500 600 100 800 900
1000 1100 1200 1300 1400 1500 1600 1700 1800 loa0 two 2100
Tamera tun of
OF = o f f scale responsa by un i t under test (9) X dW = I00 A t / (469 + t)
H u n i t in tolerancm ff Unit was not In tolerance: recallbratad - Sea n w calibration sheet.
A - 1 7 5-433
(612)786-6020
S l y p a P l t n t Tuba Iaspatlal s b n t - P l b k k. 2.3 -6
P 1 M tube dimensions: ._ 1. Extern1 tablag diameta (Dt) . . . 3/3 El. 2. W to fldr A openlag pl8m (PA) 3. B ~ S C to flde B openlng plane WB)
' 5G/ , d&s7 In.
n.
..
8 . Z a.125' d 3 - - - 9. Y <.0625' I L' 3 -
- Distance h r n ~ i t n t t o ~ r o k Components:
lo. P l t o t to 0.500 In. nozzle . 752 111.
11. P l t o t to probe sheath 7. dd 111.
12. PItot to themcouple (parallel to probe) 3.48 In.
13. Pltot to thcmcouple (perpcndlculrr to prok) , 743 XI.
Meets a11 EPA design crlteria thus Cp = 0.84
I fl Doas not reat EPA design criterlm - thur callbrato In wind tunnol 5 =
~ a t o ' of Intpectlm: Inspectad by:
CFR T i t 1 0 40 Part 60 Appcndlr A Mathod 2
A- 18
I I I I
I I I a i i i i 1 I i i I 1 I i I I I
INTERPOLL LABORATORIES (612)786-6020
Stack Sampling Department - QA Aneroid Barometer C a l i b r a t i o n Sheet
Date 7/F/5 /
<?+-I: / F L I Z / L .
Techni c i an Mercury Column Barometer No. Aneroid Barometer No. [4#’f.,-c.7’c .-
Temperature Adjs ted Mercury I n i t i a l Aneriod Di f ference
Factor Barometer Read Barometer Read (Pba-Ph)
Has t h i s barometer shown any cons is ten t problems w i th c a l i b r a t i o n ? Yes/No. yes, explain.
If
Has problem been a l l e v i a t e d ? Yes/No. How?
*Note
Aneroid barometers w i l l be c a l i b r a t e d p e r i o d i c a l l y against a mercury column barometer. The aneroid barometer t o be c a l i b r a t e d should be placed i n c lose p r o x i m i t y t o the mercury barometer and l e f t t o e q u i l i b r a t e f o r 20-30 minutes before c a l i b r a t i n g . Aneriod barometer w i l l be c a l i b r a t e d t o the adjusted mercury barometer readings. 5-312
A- 19
INTERPOLL LABORATORIES (612)786-6020
Stack Sampling Department - QA Aneroid Barometer Ca l i b ra t i on Sheet
Temperature Actual Mercury Ambient Cor rec t ion Adjsted Mercury Barometer Read Temp. Factor Barometer Read
291 13 SI5 D.1SO Z b . 4 r m PLI - a001 2s.qg
Date c 17 -7 I Technician ) x r d g & u + a
Mercury Column Barometer No. Aneroid Barometer No. S/? s-ka W?
yoll/t- I
I n i t i a1 Aner i o d Barometer Read
Has t h i s barometer shown any cons is ten t p rob lem w i th c a l i b r a t i o n ?
yes, expla in . ,vu Yes/No. I f
Has problem been a l l e v i a t e d ? Yes/No. How? Nm
*Note
Aneroid barometers w i l l be c a l i b r a t e d p e r i o d i c a l l y against a mercury c o l m n barometer. The aneroid barometer t o be ca l ib ra ted should be placed i n close P rox im i t y t o the mercury barometer and l e f t t o e q u i l i b r a t e for 20-30 minutes before c a l i b r a t i n g . Aneriod barometer w i l l be c a l i b r a t e d t o the adjusted mercury barometer readings. 5-312
A- 20
I I: 1 - I. 1 : 1 - I I I I I I I I I I I I I
I I I I I I I I I I I I I fl d
fl c I
i
APPENDIX B LOCATION OF TEST PORTS
tPA k t b d 1 Sprclflution
Z04 6.28 dlr. A - 3 x 3 - 10.55 dlr. '- 12.5
101 - Total number o f traverse p i n t s required ( m i n i m )
p4 - 12
i
c RUE OPENIN6
204 '
343' 441 ' 645'
.L
I I: I: II I: I ' I ' I ' I I I I I I I
- I I
I B- 2
I I I I I I I I I I I I I I I I I I I
z 0
I- 4 w W 2 W
I- ;c 0 LL
-
a
r
I- 4 w W 2 W
W 0
VI
El
I
W I-
v)
I- v) W I-
I- W 2 I- 3 0
W I-
I Q
4
-
a
5 I
n I- z
0 V Q W I v)
n. VI JZ
- a
i
LP 11/81 REV 3/0q
NSPSSHERCO UMIT 5
8 - 4
1 I UY
t . roc'
1: I:' I: I: I:
I
I I I I I
Uor r o S u L B I I
I i i i I i 3 i i i I i i I i I i i I
APPENDIX C
F I E L D DATA SHEETS
I I I I I I I I I I I I I I I I I I I
INTERPOLL LABORATORIES. INC, 4500 BALL ROAD N.E. CIRCLE PINES. MINNESOTA 55014.1819 TEL: 6121786-6020 FAX: 6121786-78%
May 27. 1992
Northern States Power Company 414 N i c o l l e t Mal l Minneapolis. Minnesota 55401-1927
A t t e n t i o n : P a t r i c i a Boycc
Dear P a t t i :
Enclosed please f i n d three ( 3 ) copies o f the requested rev ised o r cor rec ted pages f r o m I n t e r p o l 1 Labora tor ies Report No. 1-3409 e n t i t l e d .Results o f the September 10 and 11. 1991 Mercury Removal Tests on the U n i t s 1 B 2. and U n i t 3 Scrubber Systems a t the NSP Sherco Plant i n Becker. Minnesota.. I n add i t i on , one complete copy o f t h i s r e p o r t has a l so been enclosed as you requested.
I f you have any questions. please c a l l .
Sincere 1 y ,
INTERPOLL -TORIES. IK.
Manager F i e l d Test ing Support Cmup
DD: kce
AN EOUAL OPPORTUNITY EMPLOYER
~~ ~~ ~
1. I I I I I I I I I I I I I
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i
INTERPOLL kaBORFITORIES EPFI METHOD 2 FIELD DbTa SHEET
Job / L . 5. P. cj47LK& soUr4w' ' % I L " m 4 p m 7 C
J 3'"' Test Hun Date q / l 6 / w
Stack dimen. IN.
Dry bu lb OF Wet bulb- OF
Manometer: reg. 0 Exp. 0 Elec.
Ba romet r i c p ressu re i G F i i n Hg
S t a t i c p r e s s u r e //.gg i n wc
Schematic of C r os5 Sect i on
Operat o r s 0 4. P i t o t NO. 23-c c p .gq
Dis tance V e l o c i t y f rom Stack f r o m End of Pressure I P o r t ( i n ) I ( i n WE)
T rave rse F r a c t i o n D is tance P o i n t I Dia%er I Wall (in)
~~ ~ _ _ _ ~
I INTERF'OLL LABORATORIES €FA I lETHOD 5/17 SAMPLE LOG SHEET
Samplw T r a i n Leak Check8
F r e t e s t : ( 0.0: cfma a t 15 in. Hg. (vac ) Fastest: - ,oLJcfm a t 2 in. Hg. ( v a c ) Q -
P a r t i c u l a t e C a t c h Data :
~ 0 . 6 o f f i l t e r s used: Recovery s o l v e n t ( 5 )
U& 0 a c e t o n e other(€.) y.2 kjn 4 6 , ,
E74 %so./ No. o f p r o b e ua6h bottles: Sample r e c o v e r e d by:
C o n d e n s a t e Data:
I n t e g r a t e d Gas S a m p l i n g Data:
hag Fump No. &t3 Box No. 4 Bag No.
Bag I l a t e r i a l r %layer A l u m i n i z e d T e d l a r S i ze : 4 3
P r e t e s t lea l : check: on c c / m i n a t lr tn. w. Time s t a r t : FIC tnRS) T i m e end: b 3 0 (HRS)
S a m p l i n g r a t e : 7cL: c c t m i n O p e r a t o r : b 3-
S/N oi O= A n a l y z e r used to m o n i t o r t r a i n o u t l e t :
CF-027
c- 2 S-0046RR
1: 1: 1: 1: 1 - 1: I I " 1 - I I I I I I I I
c- 4
3 - J MM9POO-5 I
I 1 I I 1 I 1 1 I r I I I r I I I I -
~
I 1 I I I \
c . I I
3 - 1 :I :I < 1 :I - 1 : 'I
8 -3
I
I
E I I I I c I 1. I I 1 I I I I I I I I
INTERPOLL LABORATORIES €PA METHOD 2 FIELD D A T A SHEET Job -d%P SdE/aO
Test -1 Run - 3 D a t e y/O,&/ Stack dimen.
D r y b u l b OF W e t b u l b
Nanometer: 3 Reg. 0 Exp. 0 E l e c .
Barometr ic pressure 2p77 a n Hg
% 3 T i n wc
Schematic o i P i t o t No. Cross S e c t i o n
Time end:
R or noth ing= r e g . manometer: S= expanded; E = e l e c t r o n i c S-592. a c -11 . -
INTEKPOLL LAPORnTORIES €Fa METHOD 5/17 SCIMPLE LOG SHEET
Job n / , ~ snr;k’Lo Date ’%0/4/ Test / Run / NO. of t rkverse p o i n t s F i l t e r type: Qofle --- I
Source &. fS I/ + A Sic& nethod 6- /~,4F11 t e r ho lder : f4&
Sample T r a i n Leak Check:
- Pretes t : ( 0.02 cfm a t 15 in. Hg. (vac) Postest: 8 c f m a t A in. Hg. (vac)
P a r t i c u l a t e Catch Data:
N0.s of f i l t e r s used: Recovery solvent ( 5 )
I: I: I :
No. of probe wash b o t t l e s : ,/ Sample recovered by: T&
I. D1 f f erence 1 ’
Impinger No. 2 1 I
Condenrate Data:
Condenser
/ry3 / r u t / 3 6 Desiccant I ’ I 1 : i
Time s t a r t : D p z o (HRS) Time end: ‘ O 3 7 (HRS) I 1
~ ~ _.~ .. .. ._. . -.
In teg ra ted Gas Sampling Data:
Bag No. / bag Pump No. a/ t, Box No.
Bag mater ia l : 5-layer Aluminired Tedlar Size: 4 3
Pretes t leal: check: 0 cc /n in at 19 in. ng.
3 Sampling rate’: zcu’ cc/min Operator:
S/N of 0:. Ana1y:er used t o monitor t r a i n Outlet:
CF-CiZI.
c- 12 5 -0046RR
-I
I I Y
1 i
L- 13
I I I I I 1 I 1 . I 1 I I
I
1
I 1
i
i
i
INTEHFOLL LABORATORIES EPA METHOD 5/17 SCIHPLE LOG SHEET
Sample T r a i n Lmak Check:
Fretest : ( 0.02 c4m at 15 in. Hg. (vac) /$ Postest: 0 cfm a t /o in. Hg. (vac) )B
P a r t i c u l a t e Catch Data:
No.5 of f i l t e r s used: Recovery so lvent ( 5 )
acetone othercs) +KMA,’c . I 0 4d n? L/
I / No. of probe uash b o t t l e s :
Sample recovered by: p/Pc
Condensate Data:
Condenser
I n t r g r a t e d Gas Sampling Data: 8 Hag Fump NO. ?,> BOX NO. b a g No. 2-
Hag Mater ia l : 5-layer Aluminized Tedlar Size:
Pretest leal: check: 0 cc/min a t /b in. Hg.
Time s t a r t : / / / 3 (HHS) Time end: /3+ (HRS)
Sampling ra te : 200 cc/min Operator: D& S I N 0 4 0, Analyzer used t o monitor t r a i n ou t l e t : / / -
CF-023
S-0046RR C-15
C-16 I
I 1 I I I
I INTERFOLL LfiRORATORIES EPfi METHOD S I 1 7 SFIMPLE LOG SHEET
&e I' Job Date YLo// Test - / Run 3 Source / v b z %& NO. of t rave rse p o i n t s /6 Method / & / R F i l t e r ho lder : F i l t e r type: /Lorn e
Sample T r a i n Leak Check8
Pre tes t : ( 0.02 cfm a t 15 in. Hg. (vac)& Post est : C v a c y
- - d c f n a t 3 in. H g .
P a r t i c u l a t e Catch Data:
No.6 of f i l t e r s used: Recovery so lvent ( 6 )
0 acetone othercs)
No. of probe wash bo t t l es : / Sample recovered by: yG+G
Condensate Data:
I tem I 7 lmpinger No. I 1 Impinger NO. z
1 Impinger NO. 3
1 Condenser I
Desiccant + UeightCg)
D i f f erenc
c . In teg ra ted Gas Sampling Data:
Rag pump NO. 3,- B O X NO. Hag NO. 3 Bag Mater ia l : %layer Aluminized Tedlar Size: 4%
Pretes t leal: check: D cc/min a t in. H g .
Time s t a r t : (HHS) Time end:
sampling ra te : 260 cc/min Operator: E) S I N 0 4 O= &naly:er used t o monitor t r a l n ou t le t : d
CF-02;
C- 18 S -0046RR
I ' I' I I .I I I I I I I 1 I 1 I I I I
1
c - 19
I I I I I s 1 1. I I I 1 I I I I I I I
INTERPOLL LfifiORaTORIES EPa METHOD 2 F I E L D DnTA SHEET Job f J 5 .I' 5us4Yo Source unrr 3 ~ ~ 4 ~ 9 f i t 3'11~5.. T e s t R
S t a c k d i m e n .
D r y b u l b OF Wet bulb- - H a n o m e t e r : 0 Reg. 0 Exp. 0 E l e c .
f i a r o m e t r i c p r e s s u r e H a q i n ~g
S t a t i c p r e s s u r e
O p e r a t o r s
P i t o t No. Cr os5 S e c t 1 on
-
S c h e m a t i c of
Temp. m e a s . t o o l & S/N: POT- / b R or n o t h i n g = r e g . manometer : S= e x p a n d e d : E = e l e c t r o n i c 5-392.1
c - 2 1 . -
- ~~
INTERPOLL LfiBORLlTOHIES EPA METHOD 5/17 SCIMPLE LOG SHEET
Date q / / l f q I Test 3 R u n 1 source fi,u/r / ? O#& se +mor No. of t raverse p o i n t s Method / & / A F i l t e r holder: F i l t e r type: Y
Job U j P . % n Z c ~
Sample T r a i n Leak Check1
Pre tes t : ( 0.02 c f r a t 15 in. Hg. (vac) Postest: -003 - c f m a t 2 in. Hg. ivac) f
P a r t i c u l a t e Catch Data:
No.6 of f i l t e r s Llsee: Recovery solvent ( 5 )
0 0 acetone a o the r (6 ) t #CL
1. YO No. of probe uash b o t t l e s : Sample recovered by:
Condensate Data:
Di f ference
Impinger No. 2
Impinger NO. 3 I I I I Condenser I I
I 1342 I L. 0 Desiccant
I I I ...... -- . .......... ._ - _. .- ............ ..... Total ... .
In teg ra ted Gas Sampling Data:
Hag Pump NO. 0 I 3 ox NO. Lb nag NO. I Bag Mater ia l : 5- laye Size:
Pre tes t leak check: . 0 0 c c / n i n a t 15 in. ~ g .
Time s t a r t : 835 (HRS) Time end: /o./z (HAS)
Sampling ra te : LL.0 cc/min Operator: b.4.
S/N of O= Llnalyzer used t o monitor t r a i n ou t le t : - CF-027
c-22
13 1 :' 1: 1: 1 I. I' I ' I I I I I I I I
S-0046RR
-. I
I r I I r I I I
I~ INTERPOLL LABORATORIES EPCI METUOD 5/17 SCIMPLE LOG SHEET
$
I weight (g) 1 tem
Final I Tare Di f f erente
Sampla Train Loak Check:
Pretest: ( 0 . 0 2 cfm at 15 in. Hq. (vac) @ Postest: .oO c f m at /D in. Hg. (vac)
Particulate Catch Data:
NO.^ of filters used: Recovery sol went ( 5 )
0 acetone 0 other(6)
NO. of probe w a s h bottles: Sample recovered By:
tondensate Data:
n I
Imp i nger No.
Impinger No. 2
Impinger No. 3
Condenser
Desiccant . b
. . .. _ _ .. ._._ ..
. . - .. . . . - _- . .. - .. Total
Integrated Gas Sampling Data:
Bag Fump No. 8-13 Box NO. 7-L Bag NO. L
Bag Material: %layer Aluminized Tedlar Size: 4 3
Pretest leak check: .bo cc/min at I S in. Hg.
Time start: If30 (HRS) Time end: /?36 (HRS)
Sampling rate: ZULJ cc/min Operator: b.g~. S/N of O= Analyzer used to monitor t r a i n outlet:
CF-023
S-0046RR C-24
I: I: I: I: I ' I: I: I. I 1 . I I I I I I
. I
I i I I ;
I I
I ; .
C-25
INTERFOLL LABOR~TDRIES EPA IlETHOD 5/17 SFIMPLE LOG SHEET
Inp inger No. 1
Impinqer No. 2
Impinqer No. 3 Clzr
c3 Date ?+/+/ Te6t 1, Hun No. of t raverse p o ~ n t s
nethod / b / & F i l t e r holder: - F i l t e r type:
w 53 9 f3
Samplm T r a i n Lwak Chock1
Pre tes t : ( 0 .02 c f m at in. Hg. (vac) Postest : - .oO c f m a t - '2 in. Hg. ( va t )
P a r t i c u l a t e Catch Data:
N0.s of f i l t e r s used: Recovery solvent ( 6 )
acetone 1 o the r (8 )
No. o f probe wash b o t t l e s : Sample recovered by:
Condensate Data:
~~
I Weight(q1
F i n a l i Tare I D i f f erence I tem
Desiccant
Intogratmd Gas Sampling Data:
bag Pump No. 4/3 Bow No. 2G Bag No. 3 Bag Hate r ia l : 5-layer Aluminized Tedlar S i z e : 4%
Pre tes t leal: check: -00 cc/min a t / c in. Hg.
Time s t a r t : lqw ( H R S ) Time end: 1~35 (HHS)
sampling ra te : -0 cc/min Operator: b R .
S/N ot 0- Analyzer used to monitor t r a i n ou t le t :
CF-027.
C- 26 S-0046RR
I: I: 1 . I . I I I ' I I 1 I I I I I I I
C - 2 7
~~ ~~
Job k5-P SL- Source kmr*3 (park Test & Run - 8 Date d ( I / 4 / Stack dimen. 3sy IN.
Dry bulb OF Wet bu lb OF
Manometer: 0 Reg. 0 Exp. 0 E l e c .
Barometr ic pressure d S . 4 i n Hg
S t a t i c pressure -. VL i n WC
O p e r a t o r 9 AAQyw * C, I ;YOSser P i t o t No. 44-12 Cp 9 4 Schematic o*
Cross Sect ion
I I I I I I I I I I 1 I I I I I I I
13 or nothing= reg. manometer: S= expanded: E = e l e c t r u n i c 5-592. I
c- 28
-
I I I I I I I I I I I I I I I I I I I
Impinger No. 3
Condenser
Desiccant
INTERF'OLL LAPORATORIES EPA METHOD 5/17 SAMPLE LOG SHEET
/ </
/ s - L 5 /+w, &
/ Date qb$ Test - L Hun - NO. of tr verse o i n t s / 6
Job
nethod - 1 0 , ~ F a l t e r holder: nofly F i l t e r type: 2z Source * 3 c k
Sample T r a i n Lmak Check:
Pretest : ( 0.02 cfm a t 15 in. Hg. (vat))$ . Postest: - D c t n a t - / D in. ng. (vat) -
P a r t i c u l a t e Catch Data:
No.6 0 4 f i l t e r s used: Recovery so lvent ( 6 )
~~~~~~) KMUJOy 6 U F f C L
No. of probe uash b o t t es: Sample recovered by: PfY+
Condensate Data:
Weight (g) I tem
F i n a l Tare D i f f erenee - Impinger No. 1 - 1
I n
z-m 36 3 Impinger No. 2
Bgrrtmd Gas Sampling Data:
/ bag pump NO. 3, Z- bo,: NO. .L bag No.
Bag mater ia l : 5-layer Aluminized Tedlar Size: 4-
Pretest leal: check: 3 cc/min a t 13y in . Hg.
Time s t a r t : &% (HRS) Time end: /ass/ (HRS)
Sampling ra te : 20 cc/min Operator: ~ d +
S/N o i O= Analyzer used t o monitor t r a i n ou t le t : / / CF-023
c - 29 S -0046RR
C-30 I
I I I I I
C-31
I I INTEFiFOLL LabORaTORIES EPh METHOD 5/17 SAMPLE LOG SHEET
Job n / X P SX4#LO D i t E 9//'/4/ T e 6 t s o u r c e .Oh,+ *3 a NO. of t r a v e r s e PO n t s n e t h o d / d / A Fi 1 t e r h o l d e r : d.4 F i 1 t e r t y p e : JA Sample T r a i n Leak Check1
F r e t e s t : ( 0 . 0 2 c f m a t 15 i n . Hq. (vacl 7 i n . ng. ( v a c ~ F o s t e s t : C f r n a t 7
-
P a r t i c u l a t e C a t c h Data :
N0.s of f i l t e r s used: R e c o v e r y s o l v e n t ( 5 )
No. of p r o b e w a s h b o t t l e s : / Sample r e c o v e r e d by: VU&
C o n d e n s a t e Data :
We igh t (g)
D e s i c c a n t
I n t e g r a t e d Gas S a m p l i n g Data : - Bag Pump NO. Zi box No. bag No.
Bag M a t e r i a l : 5 - l a y e r A l u m i n i z e d T e d l a r S i z e :
in. Hg. P r e t e s t lea l : check: d c c / m i n a t
Time s t a r t : /iM (HRSI Time end: /3& (HRS)
S a m p l i n g r a t e : c c / m i n O p e r a t o r : ~4 S/N 0 4 O= A n a l y z e r u s e d t o m o n i t o r t r a i n o u t l e t : 3
CF-i:127
C-32 S-0046RR
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c
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I I I I I I I I I 1 I II r r r r r r I
I t e m
I m p i n g e r No. 1
- INTEKFOLL LARORfiTORIES EPA METHOD 5/17 SAMPLE LOG SHEET
W e i g h t t g )
F ina l T a r e D i f f e r e n c e
/ i
Jot
Method (01 F i l t e r h o l d e r : m'4- F i l t e r t y p e : S o u r c e U",f fl 3 r
Sample T r a i n Leak Check;
P r e t e s t : ( 0.02 c f m a t 15 in. Hg. ( v a c ) 0 c f m a t - in. Hg. ( v a c ) P o s t e s t : - - @
P a r t i c u l a t e C a t c h Data:
N0.s of f i l t e r s used: R e c o v e r y s o l v e n t ( 5 )
a c e t o n e o t h e r ( 5 ) ,em&& 94 % /
NO. of p r o b e u a s h b o t t l e s : Sample r e c o v e r e d by:
C o n d e n s a t e Data :
I n t e g r a t e d Gas S a m p l i n g Data :
2- Hag No. 3 Hag pump NO. 3, z- BO,: NO.
Bag M a t e r i a l : % l a y e r A l u m i n i z e d T e d l a r S i z e : 4 3
F r c t o s t l e a l : check: d c c / m i n a t
T i m e s t a r t : /er (HHS) Time end: / L 3 2 (HRS)
' 4. in. Hg.
S a m p l i n g r a t e : ,%@ c c / m i n O p e r a t o r : 9 4 S/tJ o4 O= a n a l y z e r u s e d t o m o n i t o r t r a i n o u t l e t : - f/
CF-#:iZ:
S-0046RR c-35
C-36
I I
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APPENDIX D
INTERPOLL LABORATORIES ANALYTICAL DATA
TABLE OF m E N T S
O r s a t . . . . . . . . . . . . . . . . . . . . . . . . . . 1
M e r c u r y . . . . . . . . . . . . . . . . . . . . . . . . . 5
Sample Vepos l t lon Sheets . . . . . . . . . . . . . . . . 8
Interpol 1 Laboratories (612) 706-6020
EPA tlethod 3 Data Reporting Sheet Orsat Analysia
Avg I I 11.70 I 7.bC 1 1 I I I I
I I I I I I 1 I I I I
r l I I I
Fuel Type F0 Range vFI Within EPA tl-3 Guidelines Coal :
for fue l type. Anthracite/Lignite 1.016-1.1SB bituminous 1. Q 0 Z - 1.2.30
COZ Disti 1 1 ate 1.260-1.413 1.210-1 Z70 Residual
Nat ur a1 1.600- 1.9.76 1 . 4 Z 4 - 1 - 536 Propane
Where F,= 20.9-0, Oil:
Gas:
F=Flask (250 cc all glass) Butane 1 .4D5-1 .553 C,--r - . I? - - c,-- , = . - 7 - \ 1 . 1 - - 4 , 1 . , - - >--, , 7 n n m - 4 1 -m
Job Team- Date SI Test Ns Date o
T e s t /
I n t e r p o l 1 Laboratories (6121 786-6020 I. ~
EPA Method 3 Data Reportxng Sheet Orsat f i n a l y s l s
Source Unr lk /sL I: nkrd Test Site f q l c
C6 aded - ,- Date of Test - -
rm. of Runs Com < n m i t t e d - 9 I q/ Techn I c 1 an Rnalysls 9 - / / - 9 /
i
O B O F I I I . I I I I I
I I I I I
EPA Hethod 3 G u i d e l i n e s Fuel Type
Anthr ac i t e / L i gni t e
Disti 1 l a t e 1.260-1.412 1.210-1.370 Hesi d u a l
N a t u r a l 1.600-1.S36 Propane I. JZJ-1.596
1.016- 1 - 130 Bituminous 1.00;- 1.2z0
I I
Where F,= 20.9-0, O i l : COa
Gas:
F=Flask (250 cc all g lasz . ) But dne I. 405- 1.553 Waod/Wood B a r k 1 000-1. 1z0
L S C - 0 4 - B R D- 2 B = T e d l a r Hag (5-1ayer)
-
EPA Hethod 3 G u i d e l i n e s Fuel Type
Anthr ac i t e / L i gni t e
Disti 1 l a t e Hesi d u a l
N a t u r a l Propane
1.016- 1 - 130 Bituminous 1.00;- 1.270
O i l :
Gas:
F=Flask (250 cc all g lasz . ) But dne B = T e d l a r Hag (5-1ayer) Waod/Wood B a r k
L S C - 0 4 - B R D- 2 -
I I I I I
1 I I I I I
Where F,= 20.9-0, COa I 1.260-1.412
1.210-1.370
1.600-1.S36 I. JZJ-1.596 I. 405- 1.553 1 000-1. 1z0 I
I I I
I n t e r p o l 1 L a b o r a t o r i e s (612) 786-6033
EPA Method 3 D a t a R e p o r t i n g Sheet O r s a t C l n r l v s i o
I I I I I
I ''I I 2 I I I I
m Leak C h e c k
Where L= 20.9-0 Oil:
Gas:
D i s t i 1 l a t e 1.2h0-1.01= R e s i dual 1.110-1.;70
Natura 1 1.600- 1.8% Propane 1.4;4-1-
eo,
- - n..+ 1 .1m=,--l F=Flask ( ? T O c r a l l n l 2 - - )
I
I n t e r p o l l Laboratories ( 5 1 2 ) 786-6QZU
EPCI Method 3 Data R e p o r t i n g S h e o t O r a a t F m a l y c i a
J T D T D
No. of Runs
I I I I I I
I I I I l I I I I I - I I I I I
o B 0 F CIvg1-1 I I
m b i o n t A i r QCI Check EPCI Hothod 3 G u i d e l i n e s Orsat Flnalyzer S y s t e m Leak Check Fuel T y p e F O Range
for fuol typo. 1 FS W i t h i n €PA H - 3 G u i d e l i n e s Coal :
P n t h r a c l t e / L l g n i t e I . 016-1.1-0 61 t urn1 n o u s 1. Q 8 Z - I . 270
P Whoro F,= 20.9-0=
CO I O i l :
Disti 1 l a t e Residual
1.260-1.4 I Z 1.210-1.Z70
Gas: Nat urd 1 I . 600- 1.8;5 Propane 1.3Z4-1.596
! = = F l a s k (250 cc a l l g l a s - , l Butane I . 405- I . 55; Waod/LL'OOd B a r k 1.a00-1.1:0
LSC-Oa-BR D- 4 P Z T e d l a r Bag (5-layer1
I 1 R I I Q I I 9' I I 1 I I I 2 I I I
INTERPOLL LABORATORIES. I N C . ( 6 1 2 ) 7 8 6 - 6 0 2 0
NSP/She K O
L a b o r a t o r y Log No. 4201
R e s u l t s of Mercury A n a l y s i s
Tes t : 1
Source: U n i t s 1 B 2 Scrubber I n l e t
Sample Type: Method l O l A Sampling T r a i n
T o t a l Mass i n Sample (uq)
F i e l d
Met hod B l a n k Run 1 Run 2 Run 3
(4201-09) (4201-10) (4201-11! (4201-12) (Log No.)
Mercury sn-846. 7470 < 0.1 14.5 22 .1 17.2
Tes t : 1
Source: U n i t s 1 B 2 Stack
Sample Type: Method l O l A Sampl ing T ra in
T o t a l Mass i n Sample (us1
F i e l d
Method B lank Run 1 Run 2 Run 3
(Log No.) (4201-27) (4201-28) (4201-29) (4201-30)
Mercury SW-846. 7470 1 .34 10.4 6.79 20.7
INTERPOLL LABORATORIES, I N C . ( 6 1 2 ) 7 8 6 - 6 0 2 0
NSP /She KO Laboratory Log No. 4201
Results of W e f W r Y Analysis
Test: 2
Source : Uni t 3 Scrubber I n l e t
Sample Type, Method l O l A Sampling T r a l n
T o t a l Mass I n Sample Iuq)
Met hod Run 1 Run 2 Run 3
(Log No. ( 4201 -40 ) (4201-41) (4201-42)
Mercury SW-846. 7470 25 .2 18.6 17.6 -
Test: 2
Source: U n l t 3 Stack
Sample Type: Method l O l A Sampling T r a i n
Tota l Mass I n Sample (us1 Met hod Run 1 Run 2 Run 3
(Log No.) (4201-52) (4201-53) (4201-54)
Mercury sn-846. 7470 18.9 12.5 12.8
I n t e r p o l l L a b o r a t o r l e s (512) 796-6020
Chain o f Custody Sample Deposi t i on Sheet
Job d.3.K y)Jzut+ s o u r c e S U ~ M U Zdrf l Team Leader b &fuYJd T e s t SI t err;l-~ch (io/ - W ) & ' - b r ) ~ ~ J - Z ~ :> Da te Submi t ted 9/ /o/4 ' Date of T e s t 4//0/41 T e s t No. * / R M c/- 3) No. of R u n s Completed ?
;amp1 es
Probe Wash:
OD.'. Water
F i l t e r : 04" G. F. 0S.S. Thimble 02.5'' G . F . 047 mm G.F.
I n t e g r a t e d Gas 7 Or ides o f N i t r o g e n (NO,)
Aggregst e
P a r t i c l e S i z e
A u d i t Samples u 1 f ur D I ox I d e
O O x i d e s of N i t .
A n a l y s i s Requ i red
GAs p e r € P A M-5 [ jother
G A S p e r EPA M-5 G A S p e r € P A M-17 nother
[jWN P r o t o c o l [ j W I P r c t o c o l OEFA M-6 or 8 p c i d Gases nFormal dehyde
l
p e r E F F M - 3 p s p e r € P A M-19 GOther
CAS p e r € F A M-74 p h e r
OAttached fue l Form U S - O l 5 l . R R H
OX-Ray Sedigraph p a h c o Wethcd OOther
p s p o r € P A M-6 gfis p e r EPA M-?A c o t h e r
II Date Time (HHS)
Sour c e I n f or ma t 1 or,
1 ) Type of Source: a b o i l e r 0 A s p h a l t P l a n t 0 I n c i n e r a t o r 0 D r y e r
2) Fuel: b Coal 0 Wood 0 Gas 0 O i l 0 KDF 0 Other =) 15 sample combust ib le- tlo [j Y e 5 4) Does sample need specid! h a n d l i n g - d No 0 Y e s If y e 5 , e x p l a i n
IJ Other
r: - 3 7 mc c c r,
1 I 1E c I J I c 1 1' !h
I I t 1 I I I
i
I n t e r p o l 1 L a b o r a t o r i e s (612) 796-6020
Chain of Custody Sampl e D e p o s i t i o n Sheet
Source UA.?S /Q 2- 5-P.eG,e
Job- A'sP .%&?Lo Team Leader 3 L h 4 Test S i t e Date Submit ted ?%/?/ Date of Test q/ /o /4 / Tes t No. / No. o+ Runs Compfete'd 3
Comments I Type of Sample A n a l y s i s Required
' robe Wash: OAce tone OD.'. Water
:i 1 t e r : 04" G.F. 0S.S. Thimble p . 5 " G.F. 047 mm G.F.
OAs p e r EPA M-5 p s per €PA PI-17 OOther
I I 0llN P r o t o c o l gW1 P r o t o c o l OEPA M-6 o r E p c i d Gases nFormal dehyde
.mpinger Catch: OD.'. Water 0'7. H,O,
$4115 Hq Only 04M5 Meta ls 01.0 N NaOH OOther
:n t egr a t ed ;as sample ,
II
H IO/ H- ~~
pe r EPA M-5 p s p e r € P A M-10 mother
II II
>Aides of 4i t r ogen (NO, ) Time (HHS) I 0"s p e r EPA M-?A
OOther
OPlttached f u e l Form #s-0 ISRRR
0 Fuel Sample 0 Aggregate H
) a r t i c l e S i z e OX-Hay Sedigraph OBahco Method OOther
I aud i t Samples OSul fur D i o x i d e OOxides of N i t . OOther
OAs per EPA 11-6 ob5 p e r €PA 11-?A OOther
S o u r c e X n f o r n s t i on
1 ) Type o f Source: M o i l e r 0 Aspha l t P l a n t 0 I n c l n e r a t o r 0 D r y e r IJ Other
0 RDF 0 Other
y o 0 Y e s I f yes, e x p l a i n
S-27SRtiKH
D-a
I n t e r p o l 1 L a b o r a t o r i e s ( 6 12) 796-6020
Chain of Custody Sample Deposi t i o n Sheet
I final y s i 5 Required I No. of II Samp 1 ea I Type o f Sample I Probe Wash: OAs per €PA M-5
gAcetone e -u E t h e r M.f e&'/ p. I . Water
3 F i 1 t e r :
04'' G.F. O F I S p e r EPFI M-5 gS.5. Thimble 12- 5" G. F. OOther 047 mm G.F.
OAs p e r EPFI M-17 c>
4M5 Hg O n l y c i d Gases ormaldehyde
g Fue l Sample OAttached f u e l Form - 0 Aggregate #S-0163RRH
P a r t i c l e S i z e OX-Ray Sedigraph OHahco Method OOther
I
A u d i t Samples - O S u l f u r D i o x i d e gas per EPA M-6 OOxides o f N i t . OAs p e r EPA M-7P gother O O t h e r
S o u r c e I n f o r m a t i o n
Comments. u w
Date Time(HRS)
J1 1 ) Type of Source: B o i l e r 0 Aspha l t P l a n t g I n c i n e r a t o r g Dryer
2) Fuel : a Coal 0 Wood 0 Gas 0 0 1 1 0 KDF 0 Other Z ) Is sample combust ib le - No 0 Y e s 4 ) Does sample need specia! h a n d l i n g - 8 NO 0 Yes
0 Other
If yes, e x p l a i n
S-?70KKKR
I n t e r p o l l L a b o r a t o r i e s ($12) 785-6020
Chain of Custody Sample Deposi t i on Sheet
Job -7 Source bd!,$y2, T p a m Leader Test S i t e Date Submit ted / I Date o i Test est NO. &I NO. of Runs Comp e ted 3
Type o f Sample
' r o b e Wash: OAc e t on e gD.1. Water
-i 1 t e r : 04" G.F. 0S.S. Thimble p . 5 " G.F. 047 mm G.F.
Impi nger Catch: 0 D . I . Water
r HE, Meta ls 01.0 N NaOH p t h e r
UZX H=O= Hq O n l y
I n t e g r a t e d Gas sample
Oxides of N i t r o y (NO,)
M u e l Sample 0 Aggregate
P a r t i c l e S i z e
Aud i t Sampl e5 p u l f cir D i ox i de OOxides o f N i t . OOther
a n a l y s i s Requi red
I
gA5 per EPA M-5 OAs per €PA N-17 OOther
0MN P r o t o c o l IjwI P r o t o c o l OEPA ?I-6 or 8 p c i d G a s e s OFormal dehyde
s per EPA M-10 OOther
p s per EPA M-7A
#S-Q153RRR
OX-Ray Sedigraph OHahco Method no ther
0"s per €Pa M-6 0 A s per EPA ?I-719 OOther
I
r II
I I Source I n f o r m a t i o n
1 ) Type of Source: o i l e r 0 Aspha l t P l a n t 0 I n c l n e r a t o r 0 Drver
4 ) Does sample I f yes, e: :p la ln
5-279FAIiR D-10
~
a' I Y I I
i i i i i i k
i
i
APPENDIX E
UNITS 1.2 3 TREND LOGS
I I
'0 .=, 7- e m
0 P '? u U
VI 0 c U m
m 0 c .z n
. o o . o m * _ . . I
I?
D
N c D
m 0 c
m Cd m . o
c .?>
r)
t w PI
m 3 c
a t.4
t m
N
ul In 5 r) c c m 0 -D 30 - -0 .o w m w 9 m 0 3 v ) . Q o - - ( L & . . . . . . . . . . . . . . . . e . . . . . < m c c r 4 w m Y) v - - 3 0 3 n) *.lo
m m w w m m c .a v) 3 ' 4 ' 0
m .C c c m m (D ID m m m m m m m m lr
1
E- 2
Q N c c W CO CO C 117 2 L7 FI N 0 N N 5 .rl - N c N k.d
4 . . . . . . . . . . o m o m m o o n m n n
Y) m .
P
0 P
-- . . . . . . . . . . . . . - 0 m: N o m. m
- m ' 0.; 0. m - - w - " . m '-m m : m , m n / m
..... . . . . . . I . 9 - t ~ P P P L I N i. . . . I
P
0 m n
V I ! 0 .o e . U N - m
.. ~. m - . 0 - F .. u * m o
t
0
N m
- * * 3 v
.u
I .u ,..I r,, 3 In c PJ m '0 o - - C N C> O - c4 . . . e . . . . . o n n m n n n n n
1 1 1 T N O . . o n < . . .
m o .n c)
v CJ m v :? - a a w m m w n . n n n n o
! . r 'Y) .a ~ D N !-
:e . . . . -.P m .m
im . .m . ,m m - ! . ., -.
. . . . . . . . . . . . -,.- ---.*-.~.-l_ .. .~ . m m P P
! . W .P :v
P P P
! - i i
n . .'- 9 CJ - N
N P N
N C N 0 - 0 n n U P E N
0 1 D m - m .P n
on- P . . .
N
0. * e .n- n . u m L I D , m . o Y)
' Y ) N f o m F P L .
. P m n
n o n c
P P P
C c .
J P 0. P
0 * 1 0
m m
c - . Y)
Y)
P m
O N N I
h N P
-1 v)
P P n 0
Y) 0 P N
0 -
! . . . . . . .P C.1 C.1 '7 r) m c c m m
, - : o m o n n N n P n .,. . . . . . .; '1 m o
n o ~ w - . . . . . . . - *
O P ~ . r n
. . . . . . . . ~ m m m m m ; e. 9 0 . w
u I T : m . 1 m i m . Y): 0: tn . nn
O - L O O O
. a - m - r - e -
. I C N C C - 0 . L . :. . .
0 0 M - N - IU 0 0 O N O N O r J O N O J I e I N I N I F J !
i o o w r n m o o c n v
o rd o N O N O N P N
P, 0. 0. P P 0.
: . . . . . - ( u - - c ,
N ; ' N I N I N , ) I . . . . .; . N ' N N C J i N
. P - Y ) P N . . . . . . 0 t 0.. .; . . . ~ I I P I N..im .... P I 0 1 . e Z Y ) - - . -N- N . N . .
w - - N w P O c U N - N 0 0 l n C L o Y) Y) In 0 - : 0 9 P W W P W P
. . . . . . I, I; c . . . . w . u m . L o Y)
+ m o n o e-* v z o n n v c . r 3 C P '0 \? P b L P P P P M O M N N N rd N m u 0 . 0 0 . 0
. . . . . . . P: * .I, P : LD m : n m n . n
o m I n n P P F 1 N
0 0 0
U 0
t -
i 0 0
m N
.. 1 I I
- 0 P Y I O 0 c I, 0 2 % u " e o w o o L I 3
3 c c z w
cffi
3 - -
W U d
a z a m u m
K W C D
a m C a Y 01
.. - i
W e - c
E- 4
ro 0 - C . U Y ) m - -
n 0 N -
0.
a~ - + - . j . .
. . Y' 3 .
V Y ) n 0 0 L .
0 ' 0 1 0 Lo: 10' -a . t i v 0
I
a r-l m m
P
. . 0 . c 10. . . .
N N CJ
n P . . . > n ' W P n . 0 - . . . . . . . . . - w - 0 N PJ ~ v v o ~ m . . .
N - 3 W * *
P o . 0 " - 0. w o n L O L D U ) -'A - J T J
m N P )
r > . - m 3 P O
rl - CJ C J W N 1- 'a , - I - , -
. . . . . . .
* ) O F , N O 0 td - r.1 - N rJ CJ id 14
N W tJ W N b> IU W N W
. . . . . 1 - 1 - 1 - 1 - 1 -
. . . - 14 - VJ C J W N W CJ YI - 1 - 4 - 0 - . . . . . . . . .
n i N P P 0. F P ' P ZY) N N F J N N N u - . r o c c n m E - . . . . . . c u Y) '0 e L? c '0
In e u, 0 L? Y) &> Lr> - . o Y I c < o w c w - W m W F )
P P P m N N N N
N N W
I , m .r Y)' Lo u, . . .
C Q C ) Q W Y I ~ . . . .
~ ) m n * a c o o n m D Ui e. m ;n 0 . 1 0 0 - Y) 0. m . m . m * m . m * m w m . ~ = ~ . m * . w . Y I I * - ~ * W . P . P . W I W . ' 9 . w
c * . . . . . . V I I * I I * , * * I. I I . I I I * . I O 1 I I I I I * c I I- . * * * * * . * - +
0 5 5 0 0 0 0 0 0 0 0
. . . . . . . . . . - . . . . m e. '1
I nI * c I m . co. I .* I '4 3 w I '0 I
e . . I . . * . - -
- I
1 . 1
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! i ai 0 .
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n~~ .. t 0 d
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n ...
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c 0
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t m. IC) n t. m - . . . . . . . . . .
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.- i . . .
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. . , . . . . . . . ~- ! . L
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. . . . . . . _ . - ,i -: . . . . . . . . . . .
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0 IC)
N. D N P - I -
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-m0.0.. o. Lo; ! n I o.
0 1 t t Q m .om Q m
. . . i t a e
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E- 18
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1 OUl A m u w L I < W * C Y UlJ
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z O W d m Y W
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~~~~
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.? 0 0
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O L D W W t L D l n W W r W N O t O w m n w
0 0 0 0 0 0 0 6 6 6 P 6 P ~ C C + C C S P * * ' 9 ' 9
m c
N O w . . N ~ U I - - ZnLD E N N
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a
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E- 20
I i i i i I i I 1 i i i I
I '1 i 1 I
APPENDIX F
PROCEDURES
I I
I
I I 1 1 i I I I I
I I i I
i
i
i
Environmontol Protodion Agency
MITHOD 101A--Drrwurmon or Punco. um mu GASIOUS m m r Ewxssror8
M m . lOlA FROM S r W A G E %mW h-TOR5
Intmducf (on Thk method Is CW to Method 101.
except v l d l c potrrrlum p- rolu- tlon Ir used LNted of .cldlc lodlne monah- lorlde for collection 1. Applicability ond Prinrlple
Appllmbllltp. Thlr method applle to the detecrmlrutlon of putlculate and yrse- ous mercury (Hg) emLnlons from -age sludge Inclnemtors m d other sources LI,
ipeclfled In the reoulaclonr 1.1 Prlndple. Putlcuhte m d m u 8 Hg
emlsslons u e Wthdmwn Loklnetldly from the mum and mllccted In v l d l c p0Wum pe-euute (KMnO.) mlutlon The H g collected (la the mercurlc form) L reduced to elemental a0. whkh L then .cmrcd from the solutlon Into m optlal all urd meas. ured by atomic absorpUon m p b o b metry.
1.1
1. Range ond Scnritimtv 1.1 Range. MLer LnltW dllutloo. the
range of thlr method L to to 800 n# Hs/ml. The uDDer LMt M be extended by further
method depenb on the -der/- photometer combhtlon rlcctcd 3. InLerlrrlnp A m l r
3.1 Srmpllng. Exceaslve orldtPble oram- k matter la the W g u prematurely dc pletcs the KluLnO. rolutlon u rd thereby pre- venu further coLlecUon of Eg. 3.2 Analysb. Condenmtlon of water
vapor on the optlal cell windoor crusa a m l t i v e Interference. 4. Pncirion Brwd on elght palred-tmlu tats. the
Wthln4abontory rtrndud devhtlon - ea- tlmated (4 be 4.8 pg Eglml In the conen- tmtlon mnge of 50 to 130 pg EWm! 5. Apparutu 5.1 Ssmpllng Tnln and Sample Recov-
ery. S m c u Method 101. SecUons 5.1 m d 5.2. respectively. except for t h e following nrlsrlorus: 5.1.1 Probe LLner. h e LI Method 101.
k t l o n 5.1.2. except that U a fllter Ir used rhea of the tmplnpers. the tester m W w the probe heath.# sysLem (4 mlnlml,r t h e condemtlon of -us Hp.
5.1.2 Fllrer Xolder (Optlonrl). Boroslll. ate gLrss prim a r ldd sulnlerr&?el wire. =reen 1Uter supporL (do not ILV slre frlL mupports) and a allleone rubber or Teflon -Let. deslened lo provide a p a s l t l V C w d agdrut le-e from oublde or uound t h e filter. T h e fUter holder must be e~ulPped with a IUter h e a t h system capable Of
H. 61, App. B, M.HL 1OlA
199 . .
mrlnwntng a temperature ~ u n d the LUIU holder of 120 z 1I' C (248 2 25' P) durlns n m p l h g to dnlmlze both vawr urd #uu- ous HE condewtlon. The tester InW w m fUter In cases where the stream mntJM b e ~uantltles of putlculate matter. 5.2 M y s k The appustus nceded for
d y s k b the sune LI, Method 101. S?cUOnr 5.3 and 5.4. except as follows:
5.2.1 Volumetric pipers. CIrrr d: 1-. 1-. S-
62.2 G r d u r e d Cylinder. 25-mL 5.2.3 Steam Bath.
6. ReapolL Use ACS r e a g e n t - m e chemlals or
qulvalent. u a k s otherwise rpecllled. 6.1 S . m p h g and Recovery. The maam-
uscd In srmplhg and recovery ut m fol- LOWS: 6.1.1 Wmter. Dclonlzed dklllld. mccUn8
k3W SpecUimUons for-- I Re.gcnt Water-- T a t Method D11-77 (In- corpomled by referem- i61.16). If hlgh eonnnVrtlons of o r d c matter u e not expected to be present. t h e mrl9rt may ellmlnate the KMnO , test for oxidbble or- gmlc matter. Use thLr water In all d l l u t b ~ and solutlon prepuatlons.
6.1.2 NlWC Add (HN0.J. 50 Rrrcnt (V/ V). MLX qrul volumes of C O M e n M "0. ud delonlud dlstllled wakr. bchp careful to slowly d d the a d d to the m t r r . U.5 S u a Oel. India- typ. C to 1 6
mah. If prevlouly used dry at 1 W C (tso' P) for 2 hr. The tade MY w e new dllu sel LI, real& 6.1.4 Filter (OpUonrl). 0- flber fUtcr.
dLhout organle blader. exhIbltlrU at 1-t W.95 percent efflclency on 0.3 dloclyl phthalate smoke putlcles. T h e m r may uy Lhe f U k r la CLVS where the ps 8trum mnulM b e quantltles of prrrcvlrrc matter. but be should d y z e bhuk I P k n for Eg content.
6.1.5 Sulfuric M d (ESO.). 10 Pemmt (V/V). Add and mix 100 ml of c o n a c n M ESO. vi& 900 ml of delonlud dLrrpled water.
6.1.8 Ahsorb- Solutloo. 4 Pemnt -0. (W/V). Repare fresh m y . Dis- solve 40 8 of -0. ln sufflclent 10 p e m t -0. to make I llter. Prepare and MR In glrrr botUes to prevent degruht lon
6.2 Analysis. The reagenu nreded for mldysls IR listed below:
82.1 Tin (11) Solution. Rem f r a h dally and keep sealed when not b&u ured Cornpctely dlrrolve 20 0 of Un (II) chlorlde [or 25 g of Un (11) sulfate1 crystab (Baker Anr lmd rewent d e or m y other b m d chat orill dve a cleu mlutlon) In 25 ml of concenrnted ECI. Dllute (4 250 ml With delonlzld dlstllled water. Do not suhstltute "0.. HSO.. or oLher rLrong d d s for the HCI.
, C. C. IO-. Utd 20d.
6.2.2 Sodlwn Chloride-HydroxyLmlne Solullon. Dlrsolve 12 8 of d u m chloride a n d 12 8 of hydroxylrmlne sulfate tor 12 I of hydroxylunlne hydrochlorldci 0 e l o n - ked dlsiUled vater and dlluw to 100 mL 6.2.3 Hydrochlork Acld IHCI). N.
DUute 07 ml of concenrmred ECl Lo 100 ml wllh delorued dbtUled water (rlowb &dd the HCI u, lhe waer) . 6.2.4 NIirlc Add. 15 Puecnt (v/V).
Dilute 15 ml of concentfared “0, LO 100 ml with delonlzed dklllled valcr.
0.2.5 Mercury SKI& Solution 1 mr Eg/ ml. Repare and store rll mercury N D d v d solutions In boraslllcate slus anruiners CompleLely dLssolve 0.1354 e of mercury (111 cNorlde in 75 ml of delonhd dlstJUed WaLer. Add 100 ml of concenlnLed BWO.. m d d J u L Lhe volume Lo exrcLly 100 ml vlth delonlzed dlstllled vater. MLX mor- oughly. Thls solullon Is stable for al larl 1 month.
6.2.6 InLermedlate Mercury Sundud & lutlon. 10 Ira Ag/ml. Repare fresh veekly. Pipe( 5.0 ml of the mercury cluck rolution ISectlon 6.2.5) into a 500.d volumeir~c f h k and add 20 ml of 15 pemnl “0. solution. Adlust l he volume to exae t l~ 500 ml r l l h delonlzed distllled vater. T%oroughly mlx the solutlon.
6.2.7 Workhg Mercury SUndd &lu- tlon. 200 ng Hg/ml. Rep- fm MY. PipeL 5.0 ml from Lhe “InLemedhw M m - ry S u n d u d SoluLlon” (Section 8 1 6 ) Into a 150-ml volumetric W. Add 5 ml of 4 mr- a n t KMnO. absorb- ~01uUon urd 5 ml of 15 percent ”0.. Adlust the volume to ex- M l y 250 ml Slvl de lonhd distilled rrtu. yllx thoroughly.
6.2.8 Porprslum Permamanate. 5 Prrrmt ( W N ) . Dissolve 5 g of -0. In delonked dLstUed water and dllule 10 100 ml.
a.2.9 N r e r . Whatman No. 40 or cqulm- lent. 7. Procedure
7.1 6ampllng. The .unplhg pra&m h Lbe aame as Method 101. except for chrnrrs due to lhe use of -0. h w a d of It3 ab wrblnp solution m d t h e parsble uy of a i l ler . ‘Ihue changes .re u foUom
7.1.1 Re-y Defcrrmruuonr. The Drellmlnary deermlnallons are tbc a m e as those given In Melhod 101. secllon 7.13. except for the absorbing wlution deplelion dm. In Lhk meLhod. Neh oxidiuble o m - k contenc may nuke I t hpa=slble LO mmple for the desbed dn lmum t h e . This vrob- lUa b tndlcared by the amplete bluchlng of the purple color of the -0. mlution In these a e s . the tester may dldde the UUlDle rUn Into t W 0 or more NbrYPI Lo h u e thaL Lhe absorb- mlutlon would not be depleted. Ln cw5 vhem an ex- of mater condenvtlon k encounwrni, WUKL two runs to &e one .unple.
f
200
F-2
7.1.2 Reparallon of S u n p l h g W ?he PrePaiaLlon of the urr.plhp udn b the -e LI that rlven in Method 101. -Ion 7.1.3. except for Lhe e l e m of rbc m- w u e [probe. fUter holder (U d l . Lm- Pingers. m d COMeCLorSl m d Lhc Qvlino of t h c f h t three h p u e a In ~IIS m o d . elem rll the ~ l m eDmponenb by rtprIng r l i h 50 percent BHO, u p water. B N HCI. lap water. and f l r u l l y de lonM U e d water. Then place 50 ml of 4 m n t -0. In the fhl lmplnger urd 100 ml In erch of the m n d and thlrd Imp- If a fUWr Is used use s p.Lr of tseashto
P k e the filter In the fUler holder. Be cure Lo center t h e flltrr and vlue the W e t In proper posllion to prevent the pmpk gas itream from bpprsslng t h e Il ler. clt& the fUkr for tern after -bly Is aomDleltd Be sure .Is0 u1 set the fULer h e a m syslem at the deslred opemtlng lempmturc a fer t h e sampllne vlln hns been -bled
7.1.3 SMplIng ”n Opetatlon In add- Uon to the procedure mven In M e w 101. &Ion 7.1.5. malnwn a tmpawme uound the Uter (U appllablel of 120-214. C (248’:25’ PI.
7.2 Sample Recovery. Be- prom ckm- up procedure ~b CDOD u the probe b R- moved from the stack at the end of the nm- pUne period. AUow the probe LO cml When I t M be a le ly hmdled. dpe off UIP exter- rial putkulak mutm mu t h e up af the probe n a e m d place a QP over It b not rrp off the probe Up UghUy VU Lhc nm- plInp tmln k wollng beerus+ Lhe msubnt
vLnp+n. Before m o m the umple tnln to tbe
clanup Ute, ruaove the probe frm the Cdn. wipe off t h e dllmne prrv. rad a p t h e open outlet of the probe. Be d u l noL ta lose any condenute t h l -1 be present. Wipe off the Ueone from l h e Lmplnger. W a c either #mund%LP crop pus. plrrtlc caps. or =rum ups LO c h c these openings.
M e r the probe. Impher auembly. m d (K appllable) fllter w m b l y la adan- up u e a Uut b dun. protcctcd ftom the rind. mnd free of El# wnlrmllvtlop m e mmbient rlr In hbrrLorler larted In the lmmedlate vleinlty of Hg.ushg f . 9 1 U e s k not normally free of Ep anumlnnlion
h p e c l the train before and d u r u -- bJy. and now any abnormal mndiuw 7 h a L Lhe bample LS foUoprs:
7.2.1 Conlamer No. 1 (Implnger. Robe. and FUter Holder). Use a mduLcd eyh. der. memure the llpuld In t h e Ilrst Im- p-ers rn withlr, 2 1 ml. Record t h e rolumc of llquld presenl 1e.g.. see Figure +3 of Method 5 In put 60 of 40 0). T U mor- msUon Is needed to d c u l n t e the mokiure oDntent of the effluenl N. (Use only grub ut& cylinder and g h s s t a w e blues L ~ L
NUU~ Would ~ I B W llpuld Out Lrom Ibr hn-
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Environmental Protection Agency
have been vrecleaned as ln &on 7.1.2.) Pkce the Contents of the flrzr three h- plnoers Into a 100O+nl E~PSS umple bottle. (Nom: If a filter k used. remove the filter from I& holder. LS outlined under "Conrpln. er No. 3" below.)
T.lrin~ w e that dust on the outside of the probe or other exterior milees does not net lnto the sample. puanUL.tively re- mver the Hg (and MY condensate) from the probe noAe. probe flttlng. probe h e r m d front half of the fllter holder (U applluble) as follows: RLNe there components with a total of 250 to 400 ml of fresh 4 percent KMnO. solution; add 111 washings to the 1ooOml E~PSS sunvle botUe; remove any re. sldual brown deposlts on the E ~ U S W ~ ~ C ushg the mlnlmum amount of 8 N HCI re. puked; and add t u HCI rinse to thk yyllplc container.
Alter rll washings have been mllecttd In the sample contrlner. tlehten the Ild on the contalner to prevent leakage during ship ment to the laboratory. Mark the height of the nuid level to determine whether leakqre oaun dulng t m p O R . h b e l the conWner to clearly identlfy I t s contents. 7.2.2. Contalner No. 2 (Sl l ia Gel). Note
the color of the indlating slllca Eel to dcter- mlne whether I t has been completely spent m d d e a nohtlon of Its condlUon. Tnns. fer the slliu gel from Its LmpInEcr to I& orlpinal conulner m d seal. The tester m y uy u mlds a funnel lo pour the dla Eel and a rubber pollcemm to remove the eu me1 from the LmpLnger. It b not necesary to remove the s n d l amount of putlcles that may adhere to t h e Impinper d and are dUflcult to remove. Slna the gain In welght b to be used for mokture dculatlons. do not use a n y water or other lipulds to trans. fer the slllu gel. If a balance k avrllable ln the fleld. weigh Lhe spent slllca gel (or slllca
7.2.3 Container No. 3 (Wter). If a fUter WLS used. cuefully remove I t from the fllur holder. place I t In a 100-ml i l ~ Ymple bottle. md add 20 to 40 ml of 4 percent KMnO.. If It Is n e c e s u y to fold the filter. be sue that the putlculate cake k Lnslde the fold. Carefully trmrfer to the 150-ml 6mmple bottle any putlculate matter and fllter flbers that &ere to the fllter holder M e r by ushe a dry Nylon brLrUe brush and a sharp-edeed blade. Seal the Conlllncr. k b e l the conulner ta clearly Identlfy Its contenb. Mark the heirht of the nuld level to determine whether leakage ooxrs d W tnmpofl. 7.2.4 Contdner No. 4 (Fllrer Blmk). IJ a
iUter VLS used. treat m unused ruter from the m e fllrer lot used for samvlhg In the rime m e r u Conulner No. 3.
7.2.5 C o n U e r No. 5 (Absorblng Solu- Uon Blank). For a blank. place 500 ml of 4
?I. 61, App. 6, Moth 101A\
percent KMnO. ahrorbhg SOIUUQ In a 1000m1I sample bottle. Seal the conLJoer. 7.3 Sunple prepuatlon. C h d Upuld
level ln each conulner lo see U Muld w m lost durlng t r ~ ~ p o r ~ If a aolkrable amount of leakage occurred. elther .old the 6nmple or use methods suble t 0 the a p proval of the Administrator to auouut for the losses. Then follow the praceduru below. 7.3.1 Containers No. 3 and No. 4 (Wter
md Nter BlanL). If a fUter r a s uwd place the contenu. Including the fllter. of Con- U e r s No. 3 and No. 4 ln sevarak YSO-ml beakers and heat the beaten on a Nrm bath untll most of the llauld has CP.PO~L- ed. Do not ULe to dryness. Add to ml of concentnted "0. to the beak- cover them wlth a ~ l p s f . and heat on a bot plate at 70' C for 2 hours. Remove from the hot plam and IUur the solution th rouh Wht- mm No. 40 fllter paper. Save the fUtnL? for a0 uulysls . Discyd the fUter. 7.3.2 Conulner No. 1 t h p i n u m . Robe.
and Wter Eolder). Pilter the contents of Conmmcr No. 1 throuuh Whatman (0 fllter paver to remove the brown &A prdpl- Ute. Wash the filter with 50 ml of 4 p m n t -0. absorbhe solutlon m d add Lhls wash to the flltmte. DLrard the flltp. Com- bine the flltmtes from Contahers No. I . ad No. 3 (U appliuhlel. rad dilute to a known volume with delonlzed dlstllled water. M h thoroughly. 7.3.3 Contrlner No. S (Absorbing 8olu-
tion Blank). T?e8t chk container m d e cribed in W o n 7.3.2. Combhe tbk mtmk with the fULrate with Contaher No. 4 rad dllute to a known volume with delonhrd & tilled wt ter. MIX thoroughly.
7.4 Analysk. Callbmte the s p e c h p h o b meter and recorder m d prepare the d b m - tlon curve LS descrlbed In sections 8.1 and 8.2. Then repeat the Drocedure U lo cc Ubkh the a l lbn t ion curve vlth appmprl- ately s h d aliauots (1 to 10 ml) of Ihe- ples (from Kctlons 7.3.2 and 7.3.3) una -0 coasecutlve peak helghts rpm wilhln *S percent of thelr avenge value. If the lOml Ymple k below the detectable limlf use a larger a l 1 ~ ~ 0 t (up to 20 ml). but deQarc the volume of water d d e d to the aentlon all rccordlngly to prevent the m1uUon volume from exceeding the cauaclty of the u n t l o n bottle. If the peak m u b u m of a 1.Oml rlipuot Is off scale. fwther dllute the orklnal sample to brlng the Eg conan-. tlon lnto the ullbnt ion mnge of the spec- Lropholometer. If the EIO conlurt of the ab. mrbmg solutlon and filter blank k below the working r ~ e of the rarlytlcrl methd. use zero for W blank. Run a blank m d rtmdud at l eu t after
every flve vmples to check the spectrophw tometer ullbmtlon: r ra l lbmte u 0- w.
20 1
I
Pt. 61, App. B, Moth. 101 40 CFR Ch. I (7-1-91 Ml ion) 1 1
It Ls &o recommended that at lcLFl one n a ~ p l e from erch sIyk lcsl be checked by Lhe Method of Sundmd Addltlom lo mn. fLrm that matrlx effecu have not Interfered ILI the annlysls. 8. Calibrollon and S t a n d a d T h e ullbrntlon and standuds u e the
n m e u Method 101. SecUon 8. exctpr for t h e fouowhg vulatlons:
8.1 Optlcal Cell Heatha System -1-8. Uon. Same u Method 101. SecLlon 8.2. except use a 25-ml graduated c ~ l i n d n tn rdd 25 ml of delonIzed distllled o a u r u) the bottle section of the aeratlon cell.
8.2 SpectrophoLorneter and Recorder C.llbratlon. The mercury reswnse -Y be measured by elrher peak helsht or u e a . (Nom: The lernpernture of Lhc d u . Uon affecls the rate at whlch elcmenul Eg k released from a solutlon and. W T L Y P ~ ~ I L - l ~ . I t affects the sham of the a b m U o n curve t u e a ) m d the point of muimum a b mrbmce (peak height). To obuln repmduc- lble results. r l l solutions must be b m u b t Lo morn temperature before use.) Sct t h e m - trophotorneter wave l e w h at 153.7 nm urd make certain the optical cell Ls at Lhe mini- mum temperature that will DrevenL m & r mndensation.
Then set the recorder U e LS follows: Using a 2 5 m l gradunled cylinder. d d 25 ml of delonlzed distilled water to the u d o n all bottle m d plpct 5.0 ml of Lhe working mercury standard wlution lorn Lhe u d o n all. (Nom: Always d d the Rgoontaioha mlutlon Lo the aeration cell rlur the S ml Of deionized distilled water.) Place a Tefbn. mated st i r r ing bar h the botUe. Add 5 ml of the 4 percent -0. absorbing soluUm fol- loved by 5 d of 15 p e m n l HHO. and 5 ml of 5 percent KhfnO. to the aerntlon btUe M d m i x well. Now. attach the botUe section to the bubbler section of the umUon ell and make c e M that (1) the umtlon ell exlt urn stopcock (Figure 101-3 of Method 101) Is closed (60 that Hg wl l l not p-. turely enler the o p t i d cell when the reduc- h went Is belng d d e d ) m d (1) there Ir no fIOW t h o u g h the bubbler. Add 5 ml Of .odium chlorlde hydroxylsmlne tu 1-ml In- er rmenu untll the solutlon b colorlcrs. How add 5 ml of tin (11) solution to the aenfion bottle through the side arm. and Inundate. b' Stopper the side urn. Srlr the rolution for 15 Seconds. turn on t h e recorder. open L h C Wratlon cell exit ann stopcock. urd Immcdi- .Mly hltlate aerntlon with continued Itir. ring. Detennhc Lhe maximum .hsorhnce Of the standard and set thir vrlue to red 90 Dcrcent of the recorder fu l l d e . 0. Ca&dalions
8.1 Dry Gas Volume. Volume of Water Vapor m d MoLsture Content. Suck Gu Ve- 1mltY. hklne t l c Vuht lon and A m p u l e Ruultr. and Determination of C o m p W . b e LS Method 101. aecrlotu 0.1. 0.2 93.
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202
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Pt. 61, App. 6, Moth. 101 40 CFR Ch. I (7-1-88 Edition) W 5
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APPENDIX G C A L C U L A T I O N E Q U A T I O N S
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CALCULATION EQJATIONS
METHOD 2
.d
Qa
9 dl
RH*
El* ws
60 vs A
* A l t e r n a t e equat ions for c a l c u l a t i n g m o i s t u r e c o n t e n t f r o m wet b u l b and d r y b u l d d a t a .
A
An
b S
CP
Ca
CS
EA
Y
Gd
I
Md
ms
"p
MS
MP
Pbar
p9
SYMBOLS
Cross sectional area of stack, SQ. FT.
Cross sectional area of nozzle, Sa. FI.
Hater vapor in gas stream, proportion by volune
Pitot tube coefficient. dimensionless
Concentration of particulate matter in stack gas, wet basis, 6R/ACF
Concentration of particulate matter in stack gas. dry basis, corrected to standard conditlons, 6R/OSCF
Excess air, percent by volune
Dry test meter correction factor, dimensionless
Specific gravity (relative to air), dimensionless
Isokinetic variation, percent by volume
Molecular weight of stack gas. dry basis, g/g - mole. Mass flow o f wet flue gas, LB/HR
Particulate mass flow, LB/HR
Molecular weight of stack gas. wet basis, g/g. nole.
Total amount of particulate matter collected, g
Atmospheric pressure, IN. HG. (uncompensated)
Stack static gas pressure, IN. UC.
G- 2
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Absolute pressure o f s t a c k gas. IN.HG.
Standard a b s o l u t e p re s su re , 29.92 IN. HG.
Actual volumetr ic s t a c k gas f low r a t e , A C M
Dry volumetr ic s t a c k gas flow r a t e corrected t o s tandard cond i t ions , D S C M
Rela t ive h u m i d i t y , Z
Dry bulb temperature o f s t ack gas. OF
Yet b u l b temperature o f s t ack gas. OF
Absolute average d r y gas meter temperature, OR
Absolute average s t a c k temperature , OF
Standard a b s o l u t e tempera ture , 528 OF (68 OF)
Total sampling t ime, m i n .
Total volume of l i q u i d c o l l e c t e d i n impingers and s l l i c a g e l , m l
Volume of gas sample a s measured by dry gas meter, CF
Volume o f gas sample measured by t h e dry gas meter cor rec ted t o s tandard cond i t ions , DSCF
Volume o f water vapor i n t h e gas sample c o r r e c t e d ' t o s tandard c o n d i t i o n s , SCF
Average a c t u a l s t a c k gas ve loc i ty , FT/SEC
Vapor p re s su re a t Tdb. IN. HG.
"Ptwb = Vapor pressure a t T,b. I N . HG
E Average pressure differential across the orif ice meter, I N . Ut.
AP Veloclty pressure of stack gas. I N . WC.
Y * Dry te s t meter correction coef f ic ient , dimensionless
P Actual gas density, LB/ACF
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G- 4
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WCULATIOW EQUATIONS
METHOD 3
loo(X0, - 1.5% CO) ZEA = b 264% N2 - 202 + 0.5% CO
= 0.44(%C02) + 0.32 (%02) + 0.28 (%N2 + ZCO) Md
Md ( I - B,,) + 0.18 B,, MS
- - “w (std) BWS ’w(std) + “m(std)
WCULATION EQUATIONS
METHOD 5
pbar + ZV13.6
Tm( avg 1 17.65 V,Y ( 1 'm( s t d )
'w(std) = 0.0472 VIS
- - 'w ( s t d )
'w(std) + "m(std)
Ts(avg) V m(std)
5 "s A" "SJ I = 0.0944 (p -
15.43 M c 5 - - =e m(std)
272.3 M Ps
Ts( avg) ('w( std) 'm( s t d ) ) I
'a
(hp)l = 8.5714 x C,
1.3228 x 10-1 Mp A
O *" (hp)2 =
G- 6 ~~
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I
i
SYmOLS
Cross sectional area of stack, SQ. FT.
Cross sectional area of nozzle, SQ. Fr.
Uater vapor in gas stream, proportion by volume
Pitot tube coefficient. dimensionless
Concentration of particulate matter in stack gas. wet basis, W A C F
Concentration o f particulate matter in stack gas. dry basis, corrected to standard conditions, GR/DSCF
Excess alr, percen.: by volume
Dry test meter correction factor, dimensionless
Specific gravity (relative t o air), dimensionless
Isokinetic variation, percent by volume
Molecular weight of stack gas. dry basis, g/g - mole.
Mass flow of wet flue gas. LB/HR
Particulate mass flow, LB/HR
Molecular weight o f stack gas. wet basis, g/g. mole.
Total amount of particulate matter collected, g
Atmospheric pressure, IN. HG. (uncompensated)
Stack static gas pressure, IN. UC.
Absolu te p re s su re o f s t a c k gas. 1It.HG.
I I 1 -
Standard a b s o l u t e p r e s s u r e , 29.92 I N . HG.
Actual vo lumetr ic s t a c k gas flow ra te , ACFM
I I
Dry volumetr ic s t a c k gas flow r a t e co r rec t ed to s tandard I I .
c o n d i t i o n s , DSCFY
Re la t ive humidi ty , Z
Dry bulb temperature o f s t ack gas. O F
Uet bulb tempera ture of s t ack gas. OF
Absolute average d r y gas meter temperature, 03
I I I I I'
Absolute average s t a c k temperature , O F
Standard a b s o l u t e tempera ture . 528 OF, (68 0: )
Total sarniJling t i m e , min.
Total volume o f l i q u i d c o l l e c t e d i n impingers and s i l i c a g e l , m l
I Volume o f gas sample as measured by d ry gas meter, C F
Volume o f gas sample measured by the d ry gas meter co r rec t ed t o s t a n d a r d condi t ions , DSCF
Volume o f water vapor i n t h e gas sample c o r r e c t e d t o s t a n d a r d c o n d i t i o n s , SCF
Average a c t u a l s t a c k gas v e l o c i t y , FT/SEC
Vapor pressure a t Tdb. I N . H;.
I I I
"Ptwb = Vapor pressure a t T,&. I N . HG
5 = Average pressure d i f f e r e n t i a l across the o r i f i c e meter , I N . YC.
AP = V e l o c i t y pressure o f s t a c k gas. I N . WC.
Y = Dry t e s t meter c o r r e c t i o n c o e f f i c i e n t , dimensionless
P Actual gas d e n s i t y , LS/ACF
M e n u r y Mass Balance
NSP - SHERCO
U n i t s 162 Run Coal Feed
1 164 1528000
3 166 1532000
U n i t 3 Run Coal Feed
TPH L W H R
2 775 155oooo
TPH LB/HR 1 490 980000 2 494 908000 3 503 1w6ooo
w m r y i n Coal Sample
Potent ia l Hg Emission Rate
L0/HR 0.130 0.140 0.136
Potent i a1 Hg Emission Rate
LB/HR 0.0002 0.0009 0.0905
0.09 ug/kg 9.00E-08 l b / l b
G- 10
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