appendix 8.1-1 baseline data collection and results...appendix 8.1-1 baseline data collection and...

APPENDIX 8.1-1

Baseline Data Collection and Results

APPENDIX 8.1-1 Baseline Data Collection and Results

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1.0 INTRODUCTION

A baseline sampling program that included both terrestrial and aquatic components was completed for the WesPac

Tilbury Marine Jetty Project (the Project). The terrestrial component was completed on 31 July 2015, and the

aquatic component was completed on 16 and 23June 2015. The Project site is located along the South Arm of the

Fraser River in Delta, BC (Figure 1).

The purpose of the baseline sampling program is to provide site-specific chemistry results that will be used to

estimate baseline exposure concentrations as a part of the Human Health assessment.

The baseline sampling program was designed to be consistent with a country foods guidance document prepared

for Health Canada (Golder 2005). The baseline sampling program was designed to collect country foods that are

consumed by people in the Local and Regional Assessment Areas (LAA and RAA). The targeted country foods

were berries in the terrestrial environment, and fish in the freshwater environment.

The fish tissue chemistry data collected as part of the baseline sampling program is used to evaluate risks related

to the fish consumption pathway. Consumption of shellfish was not considered an operable pathway as shellfish

were not present in the South Arm of the Fraser River within the Study Area and were not observed during the

baseline sampling program. In addition, shellfish areas along the outer estuary are closed to shellfish harvesting

(Department of Fisheries and Oceans 2018).

Fifteen (15) sites located within the LAA and RAA were selected for berry and soil sampling. The terrestrial

sampling locations were selected based on input from the Musqueam Aboriginal assistant and areas people use

for recreational purposes (e.g., parks, campsites). Fish samples were collected from the intertidal shoreline on the

Fraser River adjacent to Tilbury Island in front of the WesPac Project Site.

2.0 FIELD SAMPLING AND ANALYSIS METHODS

2.1 Terrestrial Baseline Sampling

Golder field personnel, accompanied by a Musqueam Aboriginal assistant, conducted sampling on 31 July 2015.

Sampling locations were accessed on foot. Co-located soil and berries were collected in accordance with Golder

(2005). Co-located soil samples were collected adjacent to where the berries were sampled. A summary of the

collection methodology is presented below.

2.1.1 Sampling Methods

At each collection site, the following sampling methods were utilized:

Photographs were taken including: the surrounding area and ground cover; soil in the sample jar, the berry

sample in the collection bag (e.g., Ziploc bag); and, the entire plant including leaves and branches (see

photographs in Attachment 1).

Berry samples were handpicked, avoiding the inclusion of any soil or debris. Berry samples were placed in

clean, labelled Ziploc bags, and were placed on ice in coolers until they could be frozen. Frozen berry samples

were then submitted to the lab for analysis.

Surficial soil samples (top 15 cm) were collected at the base of the plant sampled for berries using a stainless

steel trowel, removing the top layer of litter/fibre and humus. The collected soils were placed in a stainless


2

steel bowl and mixed to create a homogenous sample. The soil sample was then placed in clean, labelled

glass jars. Samples were stored on ice in a cooler and transported to the lab for analysis.

A plant and soil identification form was completed at each site and included date, sample #, photo numbers,

location, growing environment, vegetation type, soil type, soil depth, and field notes.

The following quality assurance measures were taken:

Cross-contamination during sample collection was minimized by wearing disposable nitrile gloves, which were

changed between each sample. Stainless steel equipment (i.e., trowels) were washed with decontamination

soap and rinsed with distilled water between sample collection sites.

Duplicate soil and berry samples were collected at sampling locations 15-Tilbury-1 and 15-Tilbury-8 to assess

reproducibility (see Section 3.2).

The sampling locations where the soil and berries were collected are provided in Table 1 and shown on Figure 2.

Table 1: Soil and Berry Sample Locations

Location Sampling Date UTM Coordinates

Zone Easting Northing

15-Tilbury-1 31-July-2015 10 U 496628 5439875

15-Tilbury-2 31-July-2015 10 U 497452 5440294

15-Tilbury-3 31-July-2015 10 U 497499 5441935

15-Tilbury-4 31-July-2015 10 U 497489 5443381

15-Tilbury-5 31-July-2015 10 U 497098 5442905

15-Tilbury-6 31-July-2015 10 U 496916 5442596

15-Tilbury-7 31-July-2015 10 U 495207 5440970

15-Tilbury-8 31-July-2015 10 U 495911 5441523

15-Tilbury-9 31-July-2015 10 U 494339 5439938

15-Tilbury-10 31-July-2015 10 U 496630 5443756

15-Tilbury-11 31-July-2015 10 U 497151 5444057

15-Tilbury-12 31-July-2015 10 U 493006 5440846

15-Tilbury-13 31-July-2015 10 U 491330 5439918

15-Tilbury-14 31-July-2015 10 U 491508 5440086

15-Tilbury-15 31-July-2015 10 U 485782 5441569

Table 2 summarizes the type of berries and soil collected, and the surrounding growing environment at each

sampling location.


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Table 2: Terrestrial Baseline Sampling Program Summary

Vegetation Sample ID

Soil Sample ID Berry Type Soil Depth (cm)

Soil Type

Growing Environment (%)

Trees Shrubs Grass Moss/ Lichen

Rock/ Bare Ground

15-Tilbury-B-1 15-Tilbury-S-1 Rubus armeniacus (Himalayan blackberry)

0 - 5 fine sandy loam/organic 0 70 30 0 0

15-Tilbury-B-2 15-Tilbury-S-2 Rubus armeniacus (himalayan blackberry)


15-Tilbury -B-3 15-Tilbury-S-3 Rubus armeniacus (himalayan blackberry)

0 - 5 silty/rocks throughout 0 20 80 0 0


0 - 5 gravely sand/organic 50 20 0 0 30


0 - 5 gravely sand 40 20 10 0 30


0 - 5 sand 40 20 10 0 30




0 - 5 gravely sand/organic 30 40 30 0 0

15-Tilbury -B-9 15-Tilbury-S-9 Rubus armeniacus (himalayan blackberry)

0 - 5 sand 20 50 30 0 0

15-Tilbury-B-10 15-Tilbury-S-10 Rubus armeniacus (himalayan blackberry) 0 - 5 sand 0 60 20 0 20

15-Tilbury-B-11 15-Tilbury-S-11 Rubus armeniacus (himalayan blackberry) 0 - 5 sand 40 40 0 0 0

15-Tilbury-B-12 15-Tilbury-S-12 Rubus armeniacus (himalayan blackberry) 5 - 10 silty sand/organic 50 20 20 0 10

15-Tilbury-B-13 15-Tilbury-S-13 Rubus armeniacus (himalayan blackberry) 0 - 10 dry silty sand/organic 50 20 25 0 5

15-Tilbury-B-14 15-Tilbury-S-14 Rubus armeniacus (himalayan blackberry) 0 - 5 dry silty sand/organic 40 40 20 0 0

15-Tilbury-B-15 15-Tilbury-S-15 Rubus armeniacus (himalayan blackberry) 0 - 5

Fine sand with clay throughout

10 30 50 0 10

Notes: % = percent; cm = centimeter.


4

2.1.2 Analysis Methods

Soil and berry samples were submitted to ALS Environmental (ALS; Burnaby, BC) for chemistry analysis.

Soil samples (15 samples plus 2 duplicate samples) were analyzed for:

pH (1:2 H2O extract);

Moisture content (drying/gravimetric);

Metals in soil (Collision/Reaction Cell-ICPMS [inductively coupled plasma mass spectrometry]) including

mercury (Cold Vapour Atomic Fluorescence Spectroscopy [CVAFS]); and,

Polycyclic aromatic hydrocarbons (rotary extraction).

Berry samples (15 samples plus 2 duplicate sample) were analyzed for:

Moisture content (drying/gravimetric);

Metals in tissue (CRC-ICPMS and inductively coupled plasma – optical emissions spectrophotometry

[ICPOES]) including silver (CRC-ICPMS) and mercury (CVAFS); and

Polycyclic aromatic hydrocarbons – low level.

Soil concentrations were compared to applicable guidelines and the results are presented in Appendix 8.1-2. There

are no standards or guidelines available for vegetation.

2.2 Aquatic Baseline Sampling

2.2.1 Sampling Methods

Golder field personnel conducted aquatic baseline sampling between 16 June and 23 June 2015 by. Sampling

locations were accessed by foot. Golder set ten baited minnow traps over two periods in the areas of the intertidal

foreshore that were wetted between the 2.3 and 3.0 m above-sea-level (ASL) tidal cycle. Results of the minnow

trapping are provided in Table 3.

Table 3: Minnow Trapping Results and Sampling Locations

Location Sampling Date Species Life Stage Catch (n)

MT-1 set at approximately 10U 497223 5443132

17-June-2015 Northern pikeminnow

(Pyychocheilus oregonensis)

Juvenile 1

MT-3 set at approximately 10U 497233 5443177

17-June-2015 Prickly sculpin (Cottus asper) Adult 1

MT-5

set at approximately 10U 497255 5443200

17-June-2015 Prickly sculpin (Cottus asper) Adult 2

MT-5 23-June-2015 Peamouth chub

(Mylocheilus caurinus) Adult 1

MT-5 23-June-2015 Sculpin

(Cottus sp.) Adult 2


5

In addition to the minnow trapping activities, Golder conducted beach seining activities at five locations along the

intertidal foreshore in the wetted areas above 2.3 m ASL. Results of the beach seining activities are provided in

Table 4.

Table 4: Beach Seining Results and Sampling Locations


S-1

sampled at approximately 10U 497261 5443212

17-June-2015 Chum Salmon

(Oncorhynchus keta) Fry 32

S-1 17-June-2015 Pink Salmon

(Oncorhynchus gorbuscha)

Fry 9

S-1 17-June-2015 Stickleback sp.

(Gasterosteus sp.) Fry 5

S-2


17-June-2015 Chinook Salmon (Oncorhynchus tshawytscha)

Fry 1

S-2 17-June-2015 Chum Salmon




S-3 sampled at approximately 10U 497219 5443135

17-June-2015 Stickleback sp.



17-June-2015 Sculpin

(Cottus sp.) Juvenile 2

S-5


17-June-2015 Peamouth chub

(Mylocheilus caurinus) Adult 1

S-5 17-June-2015 Redside shiner (Richardsonius

balteatus) Adult 9

S-5 17-June-2015 Sculpin


S-5 17-June-2015 Speckled sanddab

(Citharichthys stigmaeus)

Fry 1

S-1




S-1 23-June-2015 Minnow sp.

(Cyprindae sp.) Fry 10



S-2






S-2 23-June-2015 Northern pikeminnow

(Ptychocheilus oregonensis)

Fry 1


6


S-2 23-June-2015 Starry flounder

(Platichthys stellatus) Fry 1




23-June-2015 Minnow sp.


S-5


23-June-2015 Chum salmon




S-5 23-June-2015 Sculpin




Fish sampled were intended for documentation of fish species present at the Site. A limited number of sculpin

(Cottus sp.) were retained from the sampling effort and submitted for analysis of metals content. Samples

submitted included adult Prickly Sculpin (Cottus asper) caught in minnow trap 3 (MT-2-CC-01), and from minnow

trap 5 (MT-5-CC-01 and MT-5-CC) as well as juvenile sculpin (unidentified species) from beach seining locations

4 and 5(S-4-CC-01, S-4-CC-02, S-5-CC-01 and S-5-CC-02). Sculpin were chosen for analysis over the other fish

species collected because the tissue chemistry would likely be the most representative of exposure to the Site.

Sculpin are generally catadromous, whereby reproductive adults migrate from a fresh water environment to an

estuarine environment to spawn, then the adults and the reared young return to a fresh water environment

(McPhail and McPhail 2007; Krejsa 1967). Specifically, adult Prickly Sculpin in British Columbia generally spawn

between April and late June with the male sculpin guarding the nest for approximately 16 days until the egg mass

has hatched (McPhail and McPhail 2007). As a result, the adult Prickly Sculpin and the juvenile sculpin retained

for analysis would have likely lived out a portion of their lifecycle in or near the Site.

2.2.2 Analysis Methods

Fish samples were submitted to ALS (Burnaby, BC) for chemistry analysis. In some instances, the individual fish

samples were not large enough to obtain appropriate detection limits. As such, sample S-4-CC-01, S-5-CC-02, S-

4-CC-02 and MT-5-CC-02 were composited and analyzed as one sample. Detection limits were also elevated for

the other samples analyzed except for sample MT-2-CC-01 (which had sufficient tissue weight). In total, three fish

samples, MT-2-CC-01, S-5-CC-02, MT-5-CC-01, and a composite sample were analyzed. Fish samples (3

samples plus 1 composite) were analyzed for:

Moisture (drying/gravimetric);

Metals in tissue (CRC-ICPMS and ICPOES) including silver (CRC-ICPMS) and mercury (CVAFS); and

Polycyclic aromatic hydrocarbons – low level.


7

The glass jar containing sample MT-2-CC-01 was received broken after being shipped from ALS Burnaby to ALS

Kelso. Therefore, sample MT-2-CC-01 was not analyzed for PAHs.

Fish concentrations were compared to applicable guidelines and the results are presented in Appendix 8.1-2 for

informational purposes.

2.3 Quality Assurance/Quality Control

2.3.1 Field

For field quality assurance/quality control (QA/QC) purposes, two duplicate samples of berries and two duplicate

samples of soil were collected. The location where the duplicates were collected was chosen randomly and based

on sample availability during the field program. Sample duplicates are collected to provide an indication of natural

sample variation and the reproducibility results from within the same sample plot or plant. For duplicate media

samples, the sampling mass collected was doubled using the same sample procedures outlined above.

2.3.2 Laboratory

In addition to field duplicate QA/QC procedures, analyses conducted by ALS followed appropriate laboratory

QA/QC procedures. Each analytical method and standard sample has control limits that must be met to verify the

results for both the standard materials and the unknown samples submitted. These results were reported with

each laboratory data summary report. Laboratory QA/QC included analysis of method blanks, laboratory control

samples, matrix spikes, and reference materials to assess precision and accuracy of analyses. All laboratory

duplicate samples were analyzed for the suite of analytes listed in Section 2.1.2. Laboratory data QA/QC reports

were reviewed upon receipt to confirm that the laboratory data quality objectives (DQOs) had been met and that

the applicable QA/QC information had been reported.

3.0 RESULTS

3.1 Analytical results

The results of the baseline soil, vegetation and fish sampling program are presented in Attachment 2. The results

for soils are presented in Tables 2-1 and 2-2 for metals and PAHs, respectively. The results of the baseline

vegetation sampling program are presented in Tables 2-3 and 2-4 for metals and PAHs, respectively. The results

of the fish sampling program are presented in Tables 2-5 and 2-6 for metals and PAHs, respectively.

3.2 Quality Assurance/Quality Control

3.2.1 Field

For soil, the duplicate was a sample that was blended and divided into two equal portions, each of which is

analyzed in the same manner. For berries, duplicate collection involves collecting two separate samples of the

same tissue type from the same location.


8

The comparison of the results of a duplicate pair are often expressed as Relative Percent Difference (RPD). The

RPD is an indicator of sample heterogeneity. Lower RPD numbers indicate that samples are homogeneous. The

formula for calculating the RPD is provided below:

𝑅𝑃𝐷 𝑎𝑏𝑠 𝑆𝑎𝑚𝑝𝑙𝑒 𝐷𝑢𝑝

𝑀𝑒𝑎𝑛 𝑥 100

Where:

RPD is the relative percent difference;

abs (Sample - Dup) is the absolute value of the original sample minus the duplicate sample; and

Mean is the average of the two samples.

RPDs were not calculated if concentrations were not detected in one or both of the duplicate sample pairs.

Variability in sample results can be introduced in the field and laboratory. Generally, higher variability is accepted

from field duplicates compared to laboratory duplicates. Field duplicate variability of 30% to 50% (RPD) is common

for soil and could also be expected for berries. However, because berry duplicates are not true “split” samples,

variability could also be higher. Laboratory duplicate variability is generally less than field duplicate variability since

fewer steps are involved and RPDs of 20% may be expected.

The BC Ministry of Environment and Climate Change Strategy (2015) considers a RPD of 20% to be acceptable

for duplicate soil samples. A RPD value of more than 30% was used for berries as tissues are inherently subject

to greater heterogeneity than abiotic media (Golder 2005). Duplicate samples that have larger variation indicate

high sample variability, which can be due to natural sample heterogeneity.

Soil Duplicate QA/QC

The duplicate analyses for soil samples are provided in Tables B-7 for metals and B-8 for PAHs. The RPD was

greater than 20% for the following parameters: arsenic, chromium, anthracene, benz(a)anthracene

benzo(a)pyrene, benzo(b)fluoranthene, benzo(b+j+k)fluoranthene, benzo(g,h,i)perylene, benzo(k)fluoranthene,

fluoranthene, indeno(1,2,3-c,d)pyrene, phenanthrene and pyrene. Duplicate variability is likely attributed to the

natural heterogeneity of soils. Most natural soils are highly variable and rarely homogeneous. Although this

variability could affect the precision of the individual results, selection of the duplicate samples was random,

meaning that there would be no systematic bias in results due to the variability.

Although RPD results for PAHs in soil were high (96 to 163%), the higher, more conservative, parent

concentrations were used in the risk assessment to identify constituents of potential concern in soil. Therefore,

variability in soil concentrations does not affect the results of the risk assessment.

Berry Duplicate QA/QC

The duplicate sample analyses for berry samples are provided in Tables B-9 (metals) and B-10 (PAHs). The RPD

was greater than 30% in one or more sets of duplicate samples for the following: aluminum, barium, cadmium,

copper, molybdenum, tin and zinc. The RPD results for PAHs were below the RPD limit. The observed duplicate

variability is likely attributed to heterogeneity internally in plant tissues or to the adherence of dust or soil on plant


9

surfaces. Although this variability could affect the precision of the individual results, selection of the duplicate

samples was random, meaning that there would be no systematic bias in results due to the variability.

Fish QA/QC

Duplicate samples were not collected for fish tissues. Fish are mobile, and collection of duplicates is not considered

appropriate for evaluating field sample variability and reproducibility. Fish tissues were submitted to ALS, which is

accredited by the Canadian Association for Laboratory Accreditation. ALS analyzed laboratory duplicates, method

blanks, and reference materials to assess precision and accuracy (see Section 3.2.2 for a discussion on laboratory

QA/QC results).

3.2.2 Laboratory

Laboratory data reports for samples collected during field sampling are provided in Attachment 3. The following

data quality issues were identified in the ALS laboratory reports:

Soil

Detection limits were elevated for several parameters due to required dilution, sample matrix effects and

co-eluting interference.

The laboratory may need to dilute samples to account for the following: 1) when the analyst suspects that

concentrations are outside the calibration range of the instrument, 2) when the sample has high dissolved

solids or electrical conductivity. In such cases, the detection limit is adjusted to account for dilution.

Some tests are impacted by either chemical factors or physical factors (colour, turbidity) that make it

impossible to get a valid measurement of the sample “as submitted”. In such cases, the sample may be

diluted to a level that the impact is mitigated. This dilution triggers a corresponding detection limit increase.

Co-elution occurs when chemicals come off the instrument column at the same time, creating matrix

interference. The resulting chromatogram may have some “background”, making it difficult to identify the

analyte with confidence. Therefore, the detection limits were raised to account for the background.

Berries

Detection limits were elevated for benzo(a)pyrene due to matrix interference. The resulting chromatogram

may have some “background”, making it difficult to identify the polycyclic aromatic hydrocarbon with

confidence. Therefore, the detection limits were raised to account for the background.

The results reported for acenaphthene in several samples may contain a slight bias due to matrix interference.

The acenaphthene results for the samples affected by matrix interference may be biased high and may be

more conservative than those without matrix interference.

Fish

The upper control criterion was exceeded by 1% for the fluoranthene surrogate in the sample method blank.

The upper control criterion error is associated with a potential slightly high bias.


10

4.0 CONCLUSIONS

The purpose of the baseline sampling program was to determine the baseline concentrations of metals in

vegetation, soil and fish within the project area. Based on a review of the methods, detection limits and QA/QC

where applicable, the data are considered suitable for inclusion in the Human Health assessment.

5.0 CLOSURE

This appendix has been prepared in support of Section 8.1 (Human Health) of the EAC Application being prepared

for the WesPac Tilbury Project under the joint review of the British Columbia Environmental Assessment Office

and the Canadian Environmental Assessment Agency. This appendix should be read in conjunction with

Section 8.1 (Human Health). Any use which a third party makes of this Appendix, or any reliance on or decisions

made based on it, are the responsibility of such third parties. Golder Associates Ltd. accepts no responsibility for

damages, if any, suffered by any third party as a result of decisions made or actions based on this appendix.

O:\Final\2013\1422\13-1422-0049\1314220049-156-A-Rev0\1314220049-156-A-Rev0-App 8.1-1 Baseline 10OCT_18.docx


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6.0 REFERENCES

BC Ministry of Environment and Climate Change Strategy. 2015, Contaminated Sites – Q&As. Available at:

https://www2.gov.bc.ca/assets/gov/environment/air-land-water/site-remediation/docs/contaminated-

sites/cs_q-a.pdf. Accessed March 2018.

Department of Fisheries and Oceans. 2018. Shellfish harvesting openings and closures. Pacific Region, Area 29.

Available at: http://www.dfo-mpo.gc.ca/shellfish-mollusques/closures-fermetures-eng.htm. Accessed

August 2018.

Golder. 2005. Guidance for Including Country Foods in Human Health Assessments for Federal Contaminated

Sites. HECS-SEP-BC/Yukon/05/06-01. Submitted to Health Canada. Burnaby, BC.

McPhail JD and DL McPhail. 2007. The Freshwater Fishes of British Columbia. 620pp. The University of Alberta

Press. Ring House 2, Edmonton, Alberta, Canada.

Krejsa RJ. 1967. The Systematics of the Prickly Sculpin, Coitus asper Richardson, a Polytypic Species. Part II.

Studies on the Life History, with Especial Reference to Migration. Pacific Science, Vol. XXI, July 1967, pp.

414-422.

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MT-1

MT-10

MT-2MT-3MT-4MT-5MT-6

MT-7MT-8

MT-9S-1S-2

S-3S-4

S-5 15-Tilbury-4

15-Tilbury-5

15-Tilbury-6

15-Tilbury-10

400 0 400



ATTACHMENT 1

Photos

ATTACHMENT 1 Photos

1

Photo 1: Soil and berries (Himalayan blackberry) collected at 15-Tilbury-1, July 2015.



ATTACHMENT 1 Photos

2




ATTACHMENT 1 Photos

3




ATTACHMENT 1 Photos

4




ATTACHMENT 1 Photos

5





ATTACHMENT 2

Analytical Results

Appendix 8.1-1Attachment 2

Table 2-1: Soil Analytical Results - MetalsHuman Health Assessment

WesPac Tilbury Project, Delta, BC

2018-10-05 13-1422-0049

Sample Location Farm Land Farm Land Farm Land Farm LandDyke East of Project Site

Dyke West of Project Site


Deas Park Deas Park Deas Park

Sample ID 15-Tilbury-S-1 15-Tilbury-S-1D 15-Tilbury-S-2 15-Tilbury-S-3 15-Tilbury-S-4 15-Tilbury-S-5 15-Tilbury-S-6 15-Tilbury-S-7 15-Tilbury-S-8 15-Tilbury-S-8DDate Sampled 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015QA/QC FDA FD - - - - - FDA FDPhysical ParametersMoisture % 13.5 13.7 10.4 15.4 4.03 4.27 5.62 6.33 7.53 6.66pH pH units 6.02 6.02 6.16 5.80 6.40 6.76 6.27 6.54 6.43 6.52Organic CarbonTotal Organic Carbon % 3.03 2.99 2.28 2.37 0.97 0.54 1.23 4.79 2.03 2.07MetalsAluminum (Al) mg/kg 21400 21100 11300 16000 16300 15700 8540 10400 10400 10000Antimony (Sb) mg/kg 0.72 0.71 0.39 0.98 0.54 <0.10 0.29 0.28 0.22 0.22Arsenic (As) mg/kg 8.84 9.21 4.19 6.550 5.65 1.88 3.73 2.62 5.38 3.45Barium (Ba) mg/kg 146 133 070 084 059 086 055 051 046 044Beryllium (Be) mg/kg 0.47 0.47 0.23 0.29 0.23 0.31 0.19 0.18 0.17 0.15Bismuth (Bi) mg/kg <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 0.68 <0.20 <0.20Boron (B) mg/kg <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 10.3 <5.0 <5.0Cadmium (Cd) mg/kg 0.49 0.50 0.179 0.350 0.27 0.029 0.09 0.28 0.16 0.14Chromium (Cr) mg/kg 50.90 50.30 29.1 35.10 23.8 04.8 29.80 25.4 39.3 20.6Cobalt (Co) mg/kg 13.40 13.90 8.32 11.30 10.90 5.35 8.01 9.20 08.0 07.9Copper (Cu) mg/kg 42.80 42.30 26.4 44.00 41.70 03.9 15.8 44.90 22.1 19.2Iron (Fe) mg/kg 29600 29600 20100 27700 29300 17500 17600 18600 19400 18200Lead (Pb) mg/kg 25.4 23.9 20.8 65.8 10.0 01.3 05.9 04.9 03.5 03.4Lithium (Li) mg/kg 19.7 19.9 09.4 14.3 14.7 <2.0 7.6 6.4 07.6 07.0Manganese (Mn) mg/kg 0337 0339 310 432 504 370 327 378 364 348Mercury (Hg) mg/kg 0.073 0.077 0.0256 0.032 0.0114 <0.0050 0.0267 0.0350 0.0257 0.0255Molybdenum (Mo) mg/kg 1.75 1.92 0.87 1.26 0.77 0.87 0.46 0.46 0.45 0.45Nickel (Ni) mg/kg 43.10 43.80 21.5 27.50 18.5 04.1 30.1 26.8 23.7 22.4Selenium (Se) mg/kg 0.48 0.47 <0.20 0.28 0.38 <0.20 <0.20 <0.20 <0.20 <0.20Silver (Ag) mg/kg <0.10 <0.10 <0.10 0.11 0.10 <0.10 <0.10 <0.10 <0.10 <0.10Strontium (Sr) mg/kg 44.1 42.1 33.2 33.6 34.7 74.6 31.8 43.7 32.1 28.7Thallium (Tl) mg/kg 0.138 0.130 0.064 0.076 0.060 <0.050 0.057 0.055 <0.050 <0.050Tin (Sn) mg/kg <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0Uranium (U) mg/kg 2.290 2.310 0.573 0.662 0.340 0.660 0.31 0.299 0.273 0.247Vanadium (V) mg/kg 69.30 68.70 47.5 66.20 72.5 24.4 40.5 43.2 48.7 45.5Zinc (Zn) mg/kg 129.0 125.0 131 116.0 90.1 032 037 069 047 045Notes:

Units

< = not measured above the laboratory detection limit; % = percent; mg/kg = milligram per kilogram.

QA/QC = quality assurance/quality control; FDA = field duplicate available; FD = field duplicate.

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Table 2-1: Soil Analytical Results - MetalsHuman Health Assessment


2018-10-05 13-1422-0049

Sample Location

Sample IDDate SampledQA/QCPhysical ParametersMoisture %pH pH unitsOrganic CarbonTotal Organic Carbon %MetalsAluminum (Al) mg/kgAntimony (Sb) mg/kgArsenic (As) mg/kgBarium (Ba) mg/kgBeryllium (Be) mg/kgBismuth (Bi) mg/kgBoron (B) mg/kgCadmium (Cd) mg/kgChromium (Cr) mg/kgCobalt (Co) mg/kgCopper (Cu) mg/kgIron (Fe) mg/kgLead (Pb) mg/kgLithium (Li) mg/kgManganese (Mn) mg/kgMercury (Hg) mg/kgMolybdenum (Mo) mg/kgNickel (Ni) mg/kgSelenium (Se) mg/kgSilver (Ag) mg/kgStrontium (Sr) mg/kgThallium (Tl) mg/kgTin (Sn) mg/kgUranium (U) mg/kgVanadium (V) mg/kgZinc (Zn) mg/kgNotes:

Units

< = not measured above the laboratory detection limit; % = percent; mg/kg = milligram per kilogram.


Boat LaunchDyke North of Project Site

Dyke North of Project Site

Park near Fraser River,

Richmond

South-Dyke Park

Finn Slough Gary Point

15-Tilbury-S-9 15-Tilbury-S-10 15-Tilbury-S-11 15-Tilbury-S-12 15-Tilbury-S-13 15-Tilbury-S-14 15-Tilbury-S-1531-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015

- - - - - - -

3.24 8.30 8.91 27.0 11.0 6.32 13.56.61 7.57 7.89 6.71 6.73 6.37 4.87

0.38 2.95 1.51 3.50 4.28 1.46 1.87

09250 12400 8720 14700 13400 15300 173000.21 1.27 1.34 0.70 0.59 0.47 0.503.49 6.48 16.40 8.23 6.03 4.06 7.76046 070 048 110 79.8 059 67.70.20 0.26 0.16 0.35 0.31 0.22 0.29

<0.20 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.00.091 0.24 0.469 0.414 0.271 0.31 0.13632.3 28.7 17.8 42.8 35.7 26.2 49.18.28 8.59 5.24 13.90 12.10 10.40 8.1814.10 29.9 21.8 35.20 32.70 42.0 35.3020300 22100 15300 29100 25000 27100 321004.47 26.20 33.70 93.70 14.20 36.70 19.9007.3 11.0 05.5 14.8 14.0 14.5 17.1341 294 0314 533 347 499 224

0.0480 0.0611 0.0519 0.0823 0.0633 0.0296 0.06740.37 1.05 0.95 1.04 1.04 0.66 1.3532.8 24.2 15.5 43.4 38.0 18.2 28.5

<0.20 <0.20 <0.20 0.48 0.28 0.34 0.39<0.10 <0.10 0.11 0.10 <0.10 0.10 0.1125.2 47.9 149.0 057 46.0 34.4 40.3

<0.050 0.067 <0.050 0.103 0.084 <0.050 0.105<2.0 <2.0 6 <2.0 <2.0 <2.0 <2.00.297 0.717 1.060 1.230 0.878 0.37 1.0849.8 49.0 30.0 55.0 50.6 73.0 65.642.6 85.6 96.6 129.0 87.1 089 67.7

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Table 2-2: Soil Analytical Results - PAHsHuman Health Assessment


2018-10-05 13-1422-0049




Deas Park Deas Park Deas Park Boat Launch

Sample ID 15-Tilbury-S-1 15-Tilbury-S-1D 15-Tilbury-S-2 15-Tilbury-S-3 15-Tilbury-S-4 15-Tilbury-S-5 15-Tilbury-S-6 15-Tilbury-S-7 15-Tilbury-S-8 15-Tilbury-S-8D 15-Tilbury-S-9Date Sampled 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015QA/QC FDA FD - - - - - FDA FD -Polycyclic Aromatic HydrocarbonsAcenaphthene mg/kg 0.017 <0.013 0.039 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050Acenaphthylene mg/kg 0.019 0.016 <0.010 0.0107 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050Anthracene mg/kg 0.0603 0.012 0.0632 0.0065 <0.0040 <0.0070 <0.0040 <0.0040 <0.0040 <0.0040 <0.0040Benz(a)anthracene mg/kg 0.173 0.025 0.121 0.017 <0.010 <0.020 <0.010 <0.010 <0.010 <0.010 <0.010Benzo(a)pyrene mg/kg 0.311 0.075 0.217 0.024 <0.010 0.024 <0.010 <0.010 <0.010 <0.010 <0.010Benzo(b)fluoranthene mg/kg 0.572 0.133 0.413 0.041 0.011 0.070 <0.010 <0.010 <0.010 <0.010 <0.010Benzo(b+j+k)fluoranthene mg/kg 0.809 0.196 0.585 0.055 <0.015 0.096 <0.015 <0.015 <0.015 <0.015 <0.015Benzo(g,h,i)perylene mg/kg 0.221 0.078 0.175 0.020 <0.010 0.012 <0.010 <0.010 <0.010 <0.010 <0.010Benzo(k)fluoranthene mg/kg 0.237 0.063 0.172 0.014 <0.010 0.026 <0.010 <0.010 <0.010 <0.010 <0.010Chrysene mg/kg 0.269 <0.070 <0.30 0.032 <0.010 0.064 <0.010 <0.010 <0.010 <0.010 <0.010Dibenz(a,h)anthracene mg/kg <0.040 <0.020 <0.040 0.0055 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050Fluoranthene mg/kg 0.586 0.073 0.398 0.031 0.016 0.056 <0.010 <0.010 <0.010 <0.010 <0.010Fluorene mg/kg 0.028 <0.025 0.035 <0.010 <0.010 <0.010 <0.010 <0.020 <0.010 <0.010 <0.010Indeno(1,2,3-c,d)pyrene mg/kg 0.221 0.060 0.139 0.019 <0.010 0.015 <0.010 <0.010 <0.010 <0.010 <0.0102-Methylnaphthalene mg/kg <0.020 <0.025 <0.020 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010Naphthalene mg/kg <0.020 <0.025 0.023 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010Phenanthrene mg/kg 0.40 0.041 0.397 0.028 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010Pyrene mg/kg 0.481 0.073 0.352 0.033 0.013 0.058 <0.010 <0.010 <0.010 <0.010 <0.010B(a)P Total Potency Equivalent mg/kg 0.456 0.114 0.325 0.039 <0.020 0.039 <0.020 <0.020 <0.020 <0.020 <0.020

Notes:

Units

< = not measured above the laboratory detection limit; B(a)P = benzo(a)pyrene; mg/kg = milligram per kilogram.


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Table 2-2: Soil Analytical Results - PAHsHuman Health Assessment


2018-10-05 13-1422-0049

Sample Location

Sample IDDate SampledQA/QCPolycyclic Aromatic HydrocarbonsAcenaphthene mg/kgAcenaphthylene mg/kgAnthracene mg/kgBenz(a)anthracene mg/kgBenzo(a)pyrene mg/kgBenzo(b)fluoranthene mg/kgBenzo(b+j+k)fluoranthene mg/kgBenzo(g,h,i)perylene mg/kgBenzo(k)fluoranthene mg/kgChrysene mg/kgDibenz(a,h)anthracene mg/kgFluoranthene mg/kgFluorene mg/kgIndeno(1,2,3-c,d)pyrene mg/kg2-Methylnaphthalene mg/kgNaphthalene mg/kgPhenanthrene mg/kgPyrene mg/kgB(a)P Total Potency Equivalent mg/kgNotes:

Units

< = not measured above the laboratory detection limit; B(a)P = benzo(a)pyrene; mg/kg = milligram per kilogram.





Richmond

South-Dyke Park


15-Tilbury-S-10 15-Tilbury-S-11 15-Tilbury-S-12 15-Tilbury-S-13 15-Tilbury-S-14 15-Tilbury-S-1531-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015

- - - - - -

0.024 0.0123 <0.0050 <0.010 <0.0050 <0.00500.029 0.0097 0.0076 0.027 <0.0050 0.00960.078 0.0364 0.0088 0.0218 0.0058 0.00670.212 0.099 0.034 0.058 <0.010 0.0240.4 0.084 0.037 0.104 <0.010 0.027

0.554 0.122 0.051 0.17 0.030 0.0460.809 0.173 0.072 0.243 0.030 0.0650.251 0.054 0.021 0.068 0.013 0.0160.255 0.051 0.021 0.074 <0.010 0.0190.274 0.135 0.054 0.091 <0.030 0.041

<0.040 0.0127 0.0056 <0.020 <0.0050 <0.00500.476 0.197 0.073 0.116 0.020 0.0650.028 0.015 <0.010 <0.020 <0.010 <0.0100.219 0.059 0.024 0.059 <0.010 0.02

<0.025 0.012 <0.010 <0.020 <0.010 <0.010<0.025 0.011 0.011 <0.020 <0.010 <0.0100.332 0.180 0.038 0.056 0.010 0.0400.613 0.207 0.077 0.129 0.019 0.060.55 0.132 0.056 0.152 <0.020 0.041

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Table 2-3: Vegetation Analytical Results - MetalsHuman Health Assessment


2018-10-05 13-1422-0049




Deas Park Deas Park Deas Park Boat LaunchDyke North of Project Site



Richmond

South-Dyke Park


Sample ID 15-Tilbury-B-1 15-Tilbury-B-1D 15-Tilbury-B-2 15-Tilbury-B-3 15-Tilbury-B-4 15-Tilbury-B-5 15-Tilbury-B-6 15-Tilbury-B-7 15-Tilbury-S-8 15-Tilbury-S-8D 15-Tilbury-B-9 15-Tilbury-B-10 15-Tilbury-B-11 15-Tilbury-B-12 15-Tilbury-B-13 15-Tilbury-B-14 15-Tilbury-B-15Date Sampled 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015QA/QC FDA FD - - - - - FDA FD - - - - - - -Physical ParametersMoisture % 86.8 85.6 84.4 87.4 83.0 83.9 85.5 82.9 87.6 84.6 86.4 84.2 78.9 87.2 85.6 86.2 87.0MetalsAluminum (Al) mg/kg 29.7 42.8 10.7 20.8 29.8 11.8 18.6 14.5 3.7 5 7.6 26.8 55 12.8 15.3 9.9 17Aluminum (Al) mg/kg wwt 3.94 6.16 1.67 2.62 5.06 1.9 2.71 2.49 0.46 0.76 1.04 4.23 11.6 1.63 2.21 1.37 2.22Antimony (Sb) mg/kg <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 0.014 0.014 <0.010 <0.010 <0.010 <0.010Antimony (Sb) mg/kg wwt <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 0.0022 0.003 <0.0020 <0.0020 <0.0020 <0.0020Arsenic (As) mg/kg <0.020 0.025 <0.020 0.021 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 0.026 0.051 0.036 <0.020 <0.020 <0.020Arsenic (As) mg/kg wwt <0.0040 <0.0040 <0.0040 <0.0040 <0.0040 <0.0040 <0.0040 <0.0040 <0.0040 <0.0040 <0.0040 0.0041 0.0107 0.0046 <0.0040 <0.0040 <0.0040Barium (Ba) mg/kg 12.3 7.58 7.43 21.8 4.16 4.01 7.76 2.46 3.53 3.93 4.38 2.17 1.91 4.37 2.19 14.5 3Barium (Ba) mg/kg wwt 1.64 1.09 1.16 2.75 0.706 0.646 1.13 0.422 0.437 0.604 0.594 0.342 0.404 0.557 0.317 2 0.391Beryllium (Be) mg/kg <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010Beryllium (Be) mg/kg wwt <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020Bismuth (Bi) mg/kg <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010Bismuth (Bi) mg/kg wwt <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020Boron (B) mg/kg 18.6 14.3 12.4 13.5 11.1 11.5 13.1 12.5 18.9 15.4 13.7 12.6 10.4 17.1 13.4 15 19.7Boron (B) mg/kg wwt 2.46 2.05 1.92 1.7 1.88 1.84 1.9 2.15 2.33 2.37 1.86 1.98 2.2 2.18 1.94 2.07 2.57Cadmium (Cd) mg/kg 0.0709 0.0514 0.0408 0.128 0.0228 0.0159 0.0185 0.0505 0.0214 0.035 0.0138 0.0092 0.0208 0.034 0.0197 0.146 0.0801Cadmium (Cd) mg/kg wwt 0.0094 0.0074 0.0064 0.0161 0.0039 0.0026 0.0027 0.0087 0.0026 0.0054 0.0019 0.0015 0.0044 0.0043 0.0028 0.0202 0.0105Chromium (Cr) mg/kg 0.076 0.089 <0.050 0.063 0.056 <0.050 0.054 <0.050 <0.050 <0.050 <0.050 0.062 0.078 0.068 <0.050 <0.050 <0.050Chromium (Cr) mg/kg wwt 0.01 0.013 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 0.016 <0.010 <0.010 <0.010 <0.010Cobalt (Co) mg/kg 0.11 0.13 0.032 0.152 0.047 0.029 0.074 0.039 <0.020 <0.020 0.03 0.047 0.046 0.07 0.072 1.03 0.425Cobalt (Co) mg/kg wwt 0.0145 0.0188 0.005 0.0192 0.008 0.0047 0.0108 0.0068 <0.0040 <0.0040 0.004 0.0075 0.0098 0.0089 0.0104 0.142 0.0554Copper (Cu) mg/kg 10.6 10 8.16 7.12 5.04 5.6 5.64 6.68 8.19 9.32 8.47 7.01 7.42 7.65 6.11 8.04 12.1Copper (Cu) mg/kg wwt 1.4 1.44 1.27 0.898 0.855 0.902 0.82 1.14 1.01 1.43 1.15 1.11 1.57 0.975 0.882 1.11 1.58Iron (Fe) mg/kg 53.9 64.1 27.4 40.6 46.1 37.1 43.9 34 38 35.5 35.7 45 75 29 34.1 29.5 50.8Iron (Fe) mg/kg wwt 7.15 9.22 4.26 5.12 7.82 5.97 6.39 5.82 4.7 5.46 4.85 7.1 15.9 3.7 4.93 4.07 6.63Lead (Pb) mg/kg 0.029 0.035 <0.020 0.042 0.047 0.032 0.038 <0.020 <0.020 <0.020 <0.020 0.044 0.27 <0.020 0.029 0.026 0.031Lead (Pb) mg/kg wwt <0.0040 0.0051 <0.0040 0.0052 0.008 0.0051 0.0055 <0.0040 <0.0040 <0.0040 <0.0040 0.0069 0.0571 <0.0040 0.0041 <0.0040 0.0041Lithium (Li) mg/kg <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50Lithium (Li) mg/kg wwt <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10Manganese (Mn) mg/kg 22.6 18.7 10.5 66.3 20.5 29.7 44.9 22.3 19.1 17.9 17.7 9.93 13 13 12 64.7 40.9Manganese (Mn) mg/kg wwt 2.99 2.69 1.64 8.37 3.48 4.78 6.53 3.81 2.36 2.76 2.41 1.57 2.75 1.66 1.74 8.94 5.34Mercury (Hg) mg/kg 0.0059 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 0.0052 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 0.0052 0.0063Mercury (Hg) mg/kg wwt <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010Molybdenum (Mo) mg/kg 0.54 0.601 0.462 0.159 0.207 0.115 0.35 0.161 0.759 0.317 0.342 0.599 0.427 0.542 0.27 0.217 0.147Molybdenum (Mo) mg/kg wwt 0.0716 0.0864 0.0719 0.0201 0.0351 0.0185 0.0509 0.0275 0.0939 0.0488 0.0464 0.0945 0.0902 0.0692 0.0389 0.03 0.0192Nickel (Ni) mg/kg 2.07 1.88 1.31 4.63 1.69 2.05 3.8 2.18 1.5 1.39 1.33 0.62 0.74 2.23 2.56 6.48 6.67Nickel (Ni) mg/kg wwt 0.275 0.27 0.204 0.585 0.287 0.329 0.553 0.374 0.186 0.214 0.181 0.097 0.155 0.284 0.37 0.896 0.87Selenium (Se) mg/kg <0.050 <0.050 <0.050 <0.050 0.051 <0.050 <0.050 <0.050 <0.050 <0.050 <0.050 <0.050 <0.050 <0.050 <0.050 <0.050 <0.050Selenium (Se) mg/kg wwt <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010Silver (Ag) mg/kg <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 0.0055 <0.0050Silver (Ag) mg/kg wwt <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010Strontium (Sr) mg/kg 15.9 11.7 11.7 16.5 11.5 11.5 14 6.08 11 11.2 11.1 8.34 6.24 21 7.72 20.8 10.1Strontium (Sr) mg/kg wwt 2.11 1.68 1.82 2.09 1.96 1.86 2.03 1.04 1.36 1.73 1.51 1.32 1.32 2.67 1.11 2.87 1.32Thallium (Tl) mg/kg <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020Thallium (Tl) mg/kg wwt <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040Tin (Sn) mg/kg 0.52 0.77 0.33 0.42 0.37 0.84 0.83 0.43 0.94 0.61 0.33 0.47 0.42 0.73 1.21 0.53 0.59Tin (Sn) mg/kg wwt 0.069 0.111 0.052 0.052 0.063 0.135 0.121 0.073 0.117 0.094 0.045 0.075 0.088 0.093 0.175 0.073 0.077Uranium (U) mg/kg <0.0020 0.0024 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 0.0033 <0.0020 <0.0020 <0.0020 <0.0020Uranium (U) mg/kg wwt <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 0.00069 <0.00040 <0.00040 <0.00040 <0.00040Vanadium (V) mg/kg <0.10 0.1 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 0.11 <0.10 <0.10 <0.10 <0.10Vanadium (V) mg/kg wwt <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 0.023 <0.020 <0.020 <0.020 <0.020Zinc (Zn) mg/kg 18.4 14.8 18.3 13.4 10.2 11.4 10.7 13.8 15 17 15.3 10.4 13.4 12.5 11.9 14.6 23.8Zinc (Zn) mg/kg wwt 2.44 2.12 2.86 1.69 1.73 1.84 1.55 2.36 1.86 2.62 2.08 1.65 2.83 1.59 1.72 2.01 3.11Notes:

Units

< = not measured above the laboratory detection limit; % = percent; mg/kg = milligram per kilogram; ww = wet weight.

QA/QC = quality assurance/quality control; FDA = field duplicate available; FD = field duplicate

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Table 2-4: Vegetation Analytical Results - PAHsHuman Health Assessment


2018-10-05 13-1422-0049




Deas Park Deas Park Deas Park Boat LaunchDyke North of Project Site



Richmond

South-Dyke Park


Sample ID 15-Tilbury-S-1 15-Tilbury-S-1D 15-Tilbury-S-2 15-Tilbury-S-3 15-Tilbury-S-4 15-Tilbury-S-5 15-Tilbury-S-6 15-Tilbury-S-7 15-Tilbury-S-8 15-Tilbury-S-8D 15-Tilbury-S-9 15-Tilbury-S-10 15-Tilbury-S-11 15-Tilbury-S-12 15-Tilbury-S-13 15-Tilbury-S-14 15-Tilbury-S-15Date Sampled 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015QA/QC FDA FD - - - - - FDA FD - - - - - - -Physical ParametersMoisture % 86.8 85.6 84.4 87.4 83.0 83.9 85.5 82.9 87.6 84.6 86.4 84.2 78.9 87.2 85.6 86.2 87.0Polycyclic Aromatic HydrocarbonsAcenaphthene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 0.57 0.63 <0.50 <0.49 <0.50 <0.49 <0.51 0.71 <0.50 <0.50 0.58

Acenaphthene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 3.9 3.7 <4.0 <3.2 <3.7 <3.1 <2.5 5.5 <3.5 <3.7 4.4Acenaphthylene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Acenaphthylene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.8Anthracene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Anthracene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.8Benz(a)anthracene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Benz(a)anthracene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.8Benzo(a)pyrene µg/kg wwt <11 <17 <16 <14 <20 <15 <16 <18 <12 <20 <13 <15 <21 <21 <15 <18 <17Benzo(a)pyrene µg/kg <83 <120 <99 <110 <120 <88 <120 <110 <96 <130 <96 <94 <98 <160 <110 <130 <130Benzo(b)fluoranthene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Benzo(b)fluoranthene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.8Benzo(g,h,i)perylene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Benzo(g,h,i)perylene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.8Benzo(k)fluoranthene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Benzo(k)fluoranthene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.8Chrysene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Chrysene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.8Dibenz(a,h)anthracene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Dibenz(a,h)anthracene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.8Dibenzofuran µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Dibenzofuran µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.8Fluoranthene µg/kg wwt <0.50 <0.50 <0.50 <0.48 0.79 0.89 0.5 0.56 0.57 0.56 <0.50 0.58 0.96 1.7 <0.50 0.96 1.8Fluoranthene µg/kg <3.8 <3.5 <3.3 <3.9 4.6 5.5 4.3 3.3 4.6 3.6 <3.7 3.7 4.6 13 <3.5 6.9 14Fluorene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 0.86 <0.50 0.63 0.55Fluorene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 6.7 <3.5 4.6 4.2Indeno(1,2,3-cd)pyrene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Indeno(1,2,3-cd)pyrene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.82-Methylnaphthalene µg/kg wwt <1.0 <1.0 <1.0 <0.96 <0.97 <1.0 <0.99 <1.0 <0.99 <0.98 <1.0 <0.98 <1.1 <0.97 <0.99 <1.0 <0.972-Methylnaphthalene µg/kg <7.6 <7.0 <6.5 <7.7 <5.7 <6.2 <6.9 <5.8 <8.0 <6.4 <7.4 <6.2 <4.9 <7.6 <6.9 <7.3 <7.5Naphthalene µg/kg wwt <1.0 <1.0 <1.0 <0.96 <0.97 <1.0 <0.99 <1.0 <0.99 <0.98 <1.0 <0.98 <1.1 <0.97 <0.99 <1.0 <0.97Naphthalene µg/kg <7.6 <7.0 <6.5 <7.7 <5.7 <6.2 <6.9 <5.8 <8.0 <6.4 <7.4 <6.2 <4.9 <7.6 <6.9 <7.3 <7.5Phenanthrene µg/kg wwt 0.78 0.8 0.9 1.2 2 2.1 1.8 1.3 1.3 1.3 0.75 1.5 2.4 3.9 1.2 3.5 3.8Phenanthrene µg/kg 5.9 5.6 5.8 9.6 12 13 12 7.8 10 8.7 5.5 9.4 11 31 8.5 26 29Pyrene µg/kg wwt <0.50 <0.50 <0.50 <0.48 0.51 0.74 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 0.65 0.72 <0.50 <0.50 0.77Pyrene µg/kg <3.8 <3.5 <3.3 <3.9 3 4.6 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 3.1 5.6 <3.5 <3.7 5.9Notes:

Units

< = not measured above the laboratory detection limit; % = percent; µg/kg = microgram per kilogram; ww = wet weight.

QA/QC = quality assurance/quality control; FDA = field duplicate available; FD = field duplicate

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2018-10-05 Appendix 8.1-1Attachment 2

Table 2-5: Fish Analytical Results - MetalsHuman Health Assessment


13-1422-0049

Sample ID MT-2-CC-01 S-5-CC-02 MT-5-CC-01 COMPOSITE *Date Sampled 17-Jun-2015 17-Jun-2015 17-Jun-2015 17-Jun-2015

Physical ParametersMoisture % 73.4 78.0 76.3 75.6

MetalsAluminum (Al) mg/kg 161 64 473 241Aluminum (Al) mg/kg wwt 42.9 14.1 112 58.7Antimony (Sb) mg/kg 0.014 <0.010 0.017 0.016Antimony (Sb) mg/kg wwt 0.0038 0.0021 0.0041 0.0039Arsenic (As) mg/kg 0.601 0.594 0.862 1.01Arsenic (As) mg/kg wwt 0.16 0.13 0.205 0.246Barium (Ba) mg/kg 6.45 7.49 6.49 8.21Barium (Ba) mg/kg wwt 1.72 1.64 1.54 2Beryllium (Be) mg/kg <0.010 <0.010 <0.010 <0.010Beryllium (Be) mg/kg wwt <0.0020 <0.0020 0.0021 <0.0020Bismuth (Bi) mg/kg <0.010 <0.010 <0.010 <0.010Bismuth (Bi) mg/kg wwt 0.0022 <0.0020 <0.0020 <0.0020Boron (B) mg/kg <1.0 <1.0 <1.0 <1.0Boron (B) mg/kg wwt <0.20 <0.20 <0.20 <0.20Cadmium (Cd) mg/kg 0.0569 0.0872 0.122 0.109Cadmium (Cd) mg/kg wwt 0.0151 0.0191 0.029 0.0265Chromium (Cr) mg/kg 0.344 0.158 0.801 0.653Chromium (Cr) mg/kg wwt 0.092 0.035 0.19 0.159Cobalt (Co) mg/kg 0.215 0.212 0.43 0.395Cobalt (Co) mg/kg wwt 0.0571 0.0466 0.102 0.0963Copper (Cu) mg/kg 3.29 2.81 3.7 3.17Copper (Cu) mg/kg wwt 0.877 0.616 0.878 0.773Iron (Fe) mg/kg 277 141 931 483Iron (Fe) mg/kg wwt 73.6 30.9 221 118Lead (Pb) mg/kg 0.252 0.228 2.32 0.179Lead (Pb) mg/kg wwt 0.0671 0.05 0.55 0.0437Lithium (Li) mg/kg <0.50 <0.50 <0.50 <0.50Lithium (Li) mg/kg wwt <0.10 <0.10 <0.10 <0.10Manganese (Mn) mg/kg 24 11.5 23.3 33.3Manganese (Mn) mg/kg wwt 6.38 2.52 5.53 8.13Mercury (Hg) mg/kg 0.106 0.223 0.157 0.0948Mercury (Hg) mg/kg wwt 0.0282 0.0489 0.0373 0.0231Molybdenum (Mo) mg/kg 0.116 0.057 0.089 0.116Molybdenum (Mo) mg/kg wwt 0.0308 0.0125 0.0211 0.0282Nickel (Ni) mg/kg 0.51 0.26 1.29 0.81Nickel (Ni) mg/kg wwt 0.135 0.057 0.305 0.198Selenium (Se) mg/kg 1.62 2.41 1.85 1.91Selenium (Se) mg/kg wwt 0.432 0.53 0.44 0.465Silver (Ag) mg/kg <0.0050 <0.0050 0.0075 <0.0050Silver (Ag) mg/kg wwt 0.0012 <0.0010 0.0018 0.0012Strontium (Sr) mg/kg 80 104 115 89.5Strontium (Sr) mg/kg wwt 21.3 22.9 27.3 21.8Thallium (Tl) mg/kg 0.0408 0.0449 0.0449 0.0342Thallium (Tl) mg/kg wwt 0.0109 0.00985 0.0107 0.00833Tin (Sn) mg/kg <0.10 0.15 0.18 0.22Tin (Sn) mg/kg wwt 0.024 0.032 0.042 0.053Uranium (U) mg/kg 0.0275 0.0175 0.0479 0.0323Uranium (U) mg/kg wwt 0.00732 0.00384 0.0114 0.00788Vanadium (V) mg/kg 0.65 0.8 2.27 1.21Vanadium (V) mg/kg wwt 0.174 0.176 0.54 0.295Zinc (Zn) mg/kg 64.7 70.3 67 79.8Zinc (Zn) mg/kg wwt 17.2 15.4 15.9 19.5Notes:< = not measured above the laboratory detection limit; % = percent; mg/kg = milligram per kilogram; ww = wet weight.

*composite of samples S-4-CC-01, S-5-CC-01, S-4-CC-02, MT-5-CC-02

Units

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Table 2-6: Fish Analytical Results - PAHsHuman Health Assessment


13-1422-0049

Sample ID S-5-CC-02 MT-5-CC-01 COMPOSITE *Date Sampled 17-Jun-2015 17-Jun-2015 17-Jun-2015QA/QCPhysical ParametersMoisture % 78.0 76.3 75.6Polycyclic Aromatic HydrocarbonsAcenaphthene µg/kg wwt 1.8 3.1 1.9Acenaphthene µg/kg 8 13 7.6Acenaphthylene µg/kg wwt 1.1 0.93 1.4Acenaphthylene µg/kg 5.2 3.9 5.8Anthracene µg/kg wwt 0.52 0.49 0.91Anthracene µg/kg 2.3 2.1 3.7Benz(a)anthracene µg/kg wwt 1.5 1.2 1.9Benz(a)anthracene µg/kg 7 4.2 7.6Benzo(a)pyrene µg/kg wwt 1.1 <0.55 <0.96Benzo(a)pyrene µg/kg 4.9 <2.4 <4.0Benzo(b)fluoranthene µg/kg wwt 1.5 <0.50 <0.86Benzo(b)fluoranthene µg/kg 6.7 <2.1 <3.6Benzo(g,h,i)perylene µg/kg wwt 2.6 <0.66 <1.2Benzo(g,h,i)perylene µg/kg 12 <2.8 <4.7Benzo(k)fluoranthene µg/kg wwt 0.83 <0.33 <0.58Benzo(k)fluoranthene µg/kg 3.8 <1.4 <2.4Chrysene µg/kg wwt 0.86 1 <0.60Chrysene µg/kg 3.9 >1.5 <2.5Dibenz(a,h)anthracene µg/kg wwt <0.81 <0.65 <1.2Dibenz(a,h)anthracene µg/kg <3.7 <2.8 <4.6Dibenzofuran µg/kg wwt 1.9 2.3 1.6Dibenzofuran µg/kg 8.4 9.5 6.6Fluoranthene µg/kg wwt 2.3 2.1 2.8Fluoranthene µg/kg 10 8.9 11Fluorene µg/kg wwt 4.7 5.1 5.3Fluorene µg/kg 22 21 22Indeno(1,2,3-cd)pyrene µg/kg wwt 1.3 <0.66 <1.2Indeno(1,2,3-cd)pyrene µg/kg 6 <2.8 <4.72-Methylnaphthalene µg/kg wwt 1.4 1.9 1.62-Methylnaphthalene µg/kg 6.6 8.2 6.4Naphthalene µg/kg wwt 2.2 2.7 2.9Naphthalene µg/kg 10 11 12Phenanthrene µg/kg wwt 5.2 5.8 5.2Phenanthrene µg/kg 24 24 21Pyrene µg/kg wwt 1.4 1.2 1.3Pyrene µg/kg 6.3 5.1 5.2

Notes:

Units

< = not measured above the laboratory detection limit; % = percent; µg/kg = microgram per kilogram; ww = wet weight.

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Table 2-7: Soil QA/QC Results - MetalsHuman Health Assessment


13-1422-0049

Sample Location Farm Land Farm Land Deas Park Deas ParkSample ID 15-Tilbury-S-1 15-Tilbury-S-1D 15-Tilbury-S-8 15-Tilbury-S-8DDate Sampled 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015QA/QC FDA FD FDA FDPhysical ParametersMoisture % 13.5 13.7 0.25 1% 7.53 6.66 0.25 12%pH pH units 6.02 6.02 0.10 0% 6.43 6.52 0.10 1%Organic CarbonTotal Organic Carbon % 3.03 2.99 0.10 1% 2.03 2.07 0.10 2%MetalsAluminum (Al) mg/kg 21400 21100 50 1% 10400 10000 50 4%Antimony (Sb) mg/kg 0.72 0.71 0.1 1% 0.22 0.22 0.1 NCArsenic (As) mg/kg 8.84 9.21 0.1 4% 5.38 3.45 0.1 44%Barium (Ba) mg/kg 146 133 0.5 9% 45.9 44.3 0.5 4%Beryllium (Be) mg/kg 0.47 0.47 0.1 NC 0.17 0.15 0.1 NCBismuth (Bi) mg/kg <0.20 <0.20 0.2 NC <0.20 <0.20 0.2 NCBoron (B) mg/kg <5.0 <5.0 5 NC <5.0 <5.0 5 NCCadmium (Cd) mg/kg 0.49 0.503 0.02 3% 0.162 0.144 0.02 12%Chromium (Cr) mg/kg 50.9 50.3 0.5 1% 39.3 20.6 0.5 62%Cobalt (Co) mg/kg 13.4 13.9 0.1 4% 7.95 7.94 0.1 0%Copper (Cu) mg/kg 42.8 42.3 0.5 1% 22.1 19.2 0.5 14%Iron (Fe) mg/kg 29600 29600 50 0% 19400 18200 50 6%Lead (Pb) mg/kg 25.4 23.9 0.5 6% 3.54 3.35 0.5 6%Lithium (Li) mg/kg 19.7 19.9 2 1% 7.6 7 2 NCManganese (Mn) mg/kg 337 339 1 1% 364 348 1 4%Mercury (Hg) mg/kg 0.0725 0.0772 0.005 6% 0.0257 0.0255 0.005 1%Molybdenum (Mo) mg/kg 1.75 1.92 0.1 9% 0.45 0.45 0.1 NCNickel (Ni) mg/kg 43.1 43.8 0.5 2% 23.7 22.4 0.5 6%Selenium (Se) mg/kg 0.48 0.47 0.2 NC <0.20 <0.20 0.2 NCSilver (Ag) mg/kg <0.10 <0.10 0.1 NC <0.10 <0.10 0.1 NCStrontium (Sr) mg/kg 44.1 42.1 0.5 5% 32.1 28.7 0.5 11%Thallium (Tl) mg/kg 0.138 0.13 0.05 NC <0.050 <0.050 0.05 NCTin (Sn) mg/kg <2.0 <2.0 2 NC <2.0 <2.0 2 NCUranium (U) mg/kg 2.29 2.31 0.05 1% 0.273 0.247 0.05 10%Vanadium (V) mg/kg 69.3 68.7 0.2 1% 48.7 45.5 0.2 7%Zinc (Zn) mg/kg 129 125 2 3% 46.6 45 2 3%Notes:Relative percent differences were not calculated for chemicals where one or more values were less than detection or if both values were within five times the method detection limit.< = not measured above the laboratory detection limit; % = percent; mg/kg = milligram per kilogram.QA/QC = quality assurance/quality control; FDA = field duplicate available; FD = field duplicateNC = not calculated

Value = exceeds 20%

UnitsMethod

Detection Limit

Relative Percent Difference

(%)

Method Detection Limit


(%)

O:\Final\2013\1422\13-1422-0049\1314220049-156-A-Rev0\ATT\Att 2\Att 2_Analytical Results.xlsx [B-7 RPD Soil Metals] Golder Associates Page 1 of 1


Table 2-8: Soil QA/QC Results - PAHsHuman Health Assessment


13-1422-0049

Sample Location Farm Land Farm Land Deas Park Deas ParkSample ID 15-Tilbury-S-1 15-Tilbury-S-1D 15-Tilbury-S-8 15-Tilbury-S-8DDate Sampled 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015QA/QC FDA FD FDA FDPolycyclic Aromatic HydrocarbonsAcenaphthene mg/kg 0.017 <0.013 0.01 NC <0.0050 <0.0050 0.005 NCAcenaphthylene mg/kg 0.019 0.016 0.01 NC <0.0050 <0.0050 0.005 NCAnthracene mg/kg 0.0603 0.012 0.008 134% <0.0040 <0.0040 0.004 NCBenz(a)anthracene mg/kg 0.173 0.025 0.02 149% <0.010 <0.010 0.01 NCBenzo(a)pyrene mg/kg 0.311 0.075 0.02 122% <0.010 <0.010 0.01 NCBenzo(b)fluoranthene mg/kg 0.572 0.133 0.02 125% <0.010 <0.010 0.01 NCBenzo(b+j+k)fluoranthene mg/kg 0.809 0.196 0.028 122% <0.015 <0.015 0.015 NCBenzo(g,h,i)perylene mg/kg 0.221 0.078 0.02 96% <0.010 <0.010 0.01 NCBenzo(k)fluoranthene mg/kg 0.237 0.063 0.02 116% <0.010 <0.010 0.01 NCChrysene mg/kg 0.269 <0.070 0.02 NC <0.010 <0.010 0.01 NCDibenz(a,h)anthracene mg/kg <0.040 <0.020 0.04 NC <0.0050 <0.0050 0.005 NCFluoranthene mg/kg 0.586 0.073 0.02 156% <0.010 <0.010 0.01 NCFluorene mg/kg 0.028 <0.025 0.02 NC <0.010 <0.010 0.01 NCIndeno(1,2,3-c,d)pyrene mg/kg 0.221 0.060 0.02 115% <0.010 <0.010 0.01 NC2-Methylnaphthalene mg/kg <0.020 <0.025 0.02 NC <0.010 <0.010 0.01 NCNaphthalene mg/kg <0.020 <0.025 0.02 NC <0.010 <0.010 0.01 NCPhenanthrene mg/kg 0.40 0.041 0.02 163% <0.010 <0.010 0.01 NCPyrene mg/kg 0.481 0.073 0.02 147% <0.010 <0.010 0.01 NCB(a)P Total Potency Equivalent mg/kg 0.456 0.114 0.028 120% <0.020 <0.020 0.02 NCNotes:Relative percent differences were not calculated for chemicals where one or more values were less than detection or if both values were within five times the method detection limit.< = not measured above the laboratory detection limit; mg/kg = milligram per kilogram.QA/QC = quality assurance/quality control; FDA = field duplicate available; FD = field duplicateNC = not calculated

Value = exceeds 20%


(%)


UnitsMethod

Detection Limit


(%)

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Table 2-9: Vegetation QA/QC Results - MetalsHuman Health Assessment


13-1422-0049

Sample Location Farm Land Farm Land Deas Park Deas ParkSample ID 15-Tilbury-B-1 15-Tilbury-B-1D 15-Tilbury-B-8 15-Tilbury-B-8DDate Sampled 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015QA/QC FDA FD FDA FDPhysical ParametersMoisture % 86.8 85.6 0.25 1% 87.6 84.6 0.25 3%Metals NCAluminum (Al) mg/kg 29.7 42.8 2 36% 3.7 5 2 NCAluminum (Al) mg/kg wwt 3.94 6.16 0.4 44% 0.46 0.76 0.4 NCAntimony (Sb) mg/kg <0.010 <0.010 0.01 NC <0.010 <0.010 0.01 NCAntimony (Sb) mg/kg wwt <0.0020 <0.0020 0.002 NC <0.0020 <0.0020 0.002 NCArsenic (As) mg/kg <0.020 0.025 0.02 NC <0.020 <0.020 0.02 NCArsenic (As) mg/kg wwt <0.0040 <0.0040 0.004 NC <0.0040 <0.0040 0.004 NCBarium (Ba) mg/kg 12.3 7.58 0.05 47% 3.53 3.93 0.05 11%Barium (Ba) mg/kg wwt 1.64 1.09 0.01 40% 0.437 0.604 0.01 32%Beryllium (Be) mg/kg <0.010 <0.010 0.01 NC <0.010 <0.010 0.01 NCBeryllium (Be) mg/kg wwt <0.0020 <0.0020 0.002 NC <0.0020 <0.0020 0.002 NCBismuth (Bi) mg/kg <0.010 <0.010 0.01 NC <0.010 <0.010 0.01 NCBismuth (Bi) mg/kg wwt <0.0020 <0.0020 0.002 NC <0.0020 <0.0020 0.002 NCBoron (B) mg/kg 18.6 14.3 1 26% 18.9 15.4 1 20%Boron (B) mg/kg wwt 2.46 2.05 0.2 18% 2.33 2.37 0.2 2%Cadmium (Cd) mg/kg 0.0709 0.0514 0.005 32% 0.0214 0.035 0.005 48%Cadmium (Cd) mg/kg wwt 0.0094 0.0074 0.001 24% 0.0026 0.0054 0.001 70%Chromium (Cr) mg/kg 0.076 0.089 0.05 NC <0.050 <0.050 0.05 NCChromium (Cr) mg/kg wwt 0.01 0.013 0.01 NC <0.010 <0.010 0.01 NCCobalt (Co) mg/kg 0.11 0.13 0.02 17% <0.020 <0.020 0.02 NCCobalt (Co) mg/kg wwt 0.0145 0.0188 0.004 NC <0.0040 <0.0040 0.004 NCCopper (Cu) mg/kg 10.6 10 0.1 6% 8.19 9.32 0.1 13%Copper (Cu) mg/kg wwt 1.4 1.44 0.02 3% 1.01 1.43 0.02 34%Iron (Fe) mg/kg 53.9 64.1 3 17% 38 35.5 3 7%Iron (Fe) mg/kg wwt 7.15 9.22 0.6 25% 4.7 5.46 0.6 15%Lead (Pb) mg/kg 0.029 0.035 0.02 NC <0.020 <0.020 0.02 NCLead (Pb) mg/kg wwt <0.0040 0.0051 0.004 NC <0.0040 <0.0040 0.004 NCLithium (Li) mg/kg <0.50 <0.50 0.5 NC <0.50 <0.50 0.5 NCLithium (Li) mg/kg wwt <0.10 <0.10 0.1 NC <0.10 <0.10 0.1 NCManganese (Mn) mg/kg 22.6 18.7 0.05 19% 19.1 17.9 0.05 6%Manganese (Mn) mg/kg wwt 2.99 2.69 0.01 11% 2.36 2.76 0.01 16%Mercury (Hg) mg/kg 0.0059 <0.0050 0.005 NC <0.0050 0.0052 0.005 NCMercury (Hg) mg/kg wwt <0.0010 <0.0010 0.001 NC <0.0010 <0.0010 0.001 NCMolybdenum (Mo) mg/kg 0.54 0.601 0.02 11% 0.759 0.317 0.02 82%Molybdenum (Mo) mg/kg wwt 0.0716 0.0864 0.004 19% 0.0939 0.0488 0.004 63%Nickel (Ni) mg/kg 2.07 1.88 0.2 10% 1.5 1.39 0.2 8%Nickel (Ni) mg/kg wwt 0.275 0.27 0.04 2% 0.186 0.214 0.04 14%Selenium (Se) mg/kg <0.050 <0.050 0.05 NC <0.050 <0.050 0.05 NCSelenium (Se) mg/kg wwt <0.010 <0.010 0.01 NC <0.010 <0.010 0.01 NCSilver (Ag) mg/kg <0.0050 <0.0050 0.005 NC <0.0050 <0.0050 0.005 NCSilver (Ag) mg/kg wwt <0.0010 <0.0010 0.001 NC <0.0010 <0.0010 0.001 NCStrontium (Sr) mg/kg 15.9 11.7 0.05 30% 11 11.2 0.05 2%Strontium (Sr) mg/kg wwt 2.11 1.68 0.01 23% 1.36 1.73 0.01 24%Thallium (Tl) mg/kg <0.0020 <0.0020 0.002 NC <0.0020 <0.0020 0.002 NCThallium (Tl) mg/kg wwt <0.00040 <0.00040 0.0004 NC <0.00040 <0.00040 0.0004 NCTin (Sn) mg/kg 0.52 0.77 0.1 39% 0.94 0.61 0.1 43%Tin (Sn) mg/kg wwt 0.069 0.111 0.02 47% 0.117 0.094 0.02 22%Uranium (U) mg/kg <0.0020 0.0024 0.002 NC <0.0020 <0.0020 0.002 NCUranium (U) mg/kg wwt <0.00040 <0.00040 0.0004 NC <0.00040 <0.00040 0.0004 NCVanadium (V) mg/kg <0.10 0.1 0.1 NC <0.10 <0.10 0.1 NCVanadium (V) mg/kg wwt <0.020 <0.020 0.02 NC <0.020 <0.020 0.02 NCZinc (Zn) mg/kg 18.4 14.8 0.5 22% 15 17 0.5 13%Zinc (Zn) mg/kg wwt 2.44 2.12 0.1 14% 1.86 2.62 0.1 34%Notes:Relative percent differences were not calculated for chemicals where one or more values were less than detection or if both values were within five times the method detection limit.< = not measured above the laboratory detection limit; % = percent; mg/kg = milligram per kilogram; ww = wet weight.QA/QC = quality assurance/quality control; FDA = field duplicate available; FD = field duplicateNC = not calculated

Value = exceeds 30%

UnitsMethod

Detection Limit


(%)



(%)

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Table 2-10: Vegetation QA/QC Results - PAHsHuman Health Assessment


13-1422-0049

Sample Location Farm Land Farm Land Deas Park Deas Park

Sample ID 15-Tilbury-B-1 15-Tilbury-B-1D 15-Tilbury-B-8 15-Tilbury-B-8D

Date Sampled 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015QA/QC FDA FD FDA FDPhysical ParametersMoisture % 86.8 85.6 0.25 1% 87.6 84.6 0.25 3%Polycyclic Aromatic HydrocarbonsAcenaphthene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCAcenaphthene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCAcenaphthylene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCAcenaphthylene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCAnthracene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCAnthracene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCBenz(a)anthracene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCBenz(a)anthracene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCBenzo(a)pyrene µg/kg wwt <11 <17 17 NC <12 <20 12 NCBenzo(a)pyrene µg/kg <83 <120 83 NC <96 <130 96 NCBenzo(b)fluoranthene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCBenzo(b)fluoranthene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCBenzo(g,h,i)perylene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCBenzo(g,h,i)perylene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCBenzo(k)fluoranthene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCBenzo(k)fluoranthene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCChrysene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCChrysene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCDibenz(a,h)anthracene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCDibenz(a,h)anthracene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCDibenzofuran µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCDibenzofuran µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCFluoranthene µg/kg wwt <0.50 <0.50 0.50 NC 0.57 0.56 0.49 NCFluoranthene µg/kg <3.8 <3.5 3.5 NC 4.6 3.6 3.2 NCFluorene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCFluorene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCIndeno(1,2,3-cd)pyrene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCIndeno(1,2,3-cd)pyrene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NC2-Methylnaphthalene µg/kg wwt <1.0 <1.0 1.0 NC <0.99 <0.98 0.98 NC2-Methylnaphthalene µg/kg <7.6 <7.0 7.0 NC <8.0 <6.4 6.4 NCNaphthalene µg/kg wwt <1.0 <1.0 1.0 NC <0.99 <0.98 0.98 NCNaphthalene µg/kg <7.6 <7.0 7.0 NC <8.0 <6.4 6.4 NCPhenanthrene µg/kg wwt 0.78 0.8 0.50 NC 1.3 1.3 0.49 NCPhenanthrene µg/kg 5.9 5.6 3.5 NC 10 8.7 3.2 NCPyrene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCPyrene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCNotes:Relative percent differences were not calculated for chemicals where one or more values were less than detection or if both values were within five times the method detection limit.< = not measured above the laboratory detection limit; % = percent; µg/kg = microgram per kilogram; ww = wet weight.QA/QC = quality assurance/quality control; FDA = field duplicate available; FD = field duplicateNC = not calculated

Value = exceeds 30%

UnitsMethod

Detection Limit


(%)



(%)

O:\Final\2013\1422\13-1422-0049\1314220049-156-A-Rev0\ATT\Att 2\Att 2_Analytical Results.xlsx [B-10 RPD Veg PAH] Golder Associates Page 1 of 1


ATTACHMENT 3

Laboratory Data Reports

[This report shall not be reproduced except in full without the written authority of the Laboratory.]

18-JUN-15

Lab Work Order #: L1628885

Date Received:GOLDER ASSOCIATES LTD.

200-2920 Virtual WayVancouver BC V5M 0C4

ATTN: Audrey WagenaarFINAL 09-FEB-16 12:53 (MT)Report Date:

Version:

Certificate of Analysis

ALS CANADA LTD Part of the ALS Group A Campbell Brothers Limited Company

____________________________________________

Amber Springer, B.ScAccount Manager

ADDRESS: 8081 Lougheed Hwy, Suite 100, Burnaby, BC V5A 1W9 Canada | Phone: +1 604 253 4188 | Fax: +1 604 253 6700

Client Phone: 604-297-2036

13-1422-0049/16000/16010Job Reference: NOT SUBMITTEDProject P.O. #:

10-034387C of C Numbers:Legal Site Desc:

09-FEB-16 12:53 (MT)

Sample ID Description

Client ID

Sampled Date

Grouping Analyte

Sampled Time

ALS ENVIRONMENTAL ANALYTICAL REPORT

L1628885 CONTD....

2PAGE of

Version: FINAL

5

TISSUE

Fish tissue Fish tissue Fish tissue Fish tissue17-JUN-15 17-JUN-15 17-JUN-15

MT-2-CC-01 S-5-CC-02 MT-5-CC-01 COMPOSITE (S-4-CC-01, S-5-CC-01, S-4-CC-02, MT-5-

CC-02)

L1628885-1 L1628885-4 L1628885-5 L1628885-8

% Moisture (%)

Aluminum (Al)-Total (mg/kg)

Aluminum (Al)-Total (mg/kg wwt)

Antimony (Sb)-Total (mg/kg)

Antimony (Sb)-Total (mg/kg wwt)

Arsenic (As)-Total (mg/kg)

Arsenic (As)-Total (mg/kg wwt)

Barium (Ba)-Total (mg/kg)

Barium (Ba)-Total (mg/kg wwt)

Beryllium (Be)-Total (mg/kg)

Beryllium (Be)-Total (mg/kg wwt)

Bismuth (Bi)-Total (mg/kg)

Bismuth (Bi)-Total (mg/kg wwt)

Boron (B)-Total (mg/kg)

Boron (B)-Total (mg/kg wwt)

Cadmium (Cd)-Total (mg/kg)

Cadmium (Cd)-Total (mg/kg wwt)

Chromium (Cr)-Total (mg/kg)

Chromium (Cr)-Total (mg/kg wwt)

Cobalt (Co)-Total (mg/kg)

Cobalt (Co)-Total (mg/kg wwt)

Copper (Cu)-Total (mg/kg)

Copper (Cu)-Total (mg/kg wwt)

Iron (Fe)-Total (mg/kg)

Iron (Fe)-Total (mg/kg wwt)

Lead (Pb)-Total (mg/kg)

Lead (Pb)-Total (mg/kg wwt)

Lithium (Li)-Total (mg/kg)

Lithium (Li)-Total (mg/kg wwt)

Manganese (Mn)-Total (mg/kg)

Manganese (Mn)-Total (mg/kg wwt)

Mercury (Hg)-Total (mg/kg)

Mercury (Hg)-Total (mg/kg wwt)

Molybdenum (Mo)-Total (mg/kg)

Molybdenum (Mo)-Total (mg/kg wwt)

Nickel (Ni)-Total (mg/kg)

Nickel (Ni)-Total (mg/kg wwt)

73.4 78.0 76.3 75.6

161 64.0 473 241

42.9 14.1 112 58.7

0.014 <0.010 0.017 0.016

0.0038 0.0021 0.0041 0.0039

0.601 0.594 0.862 1.01

0.160 0.130 0.205 0.246

6.45 7.49 6.49 8.21

1.72 1.64 1.54 2.00

<0.010 <0.010 <0.010 <0.010

<0.0020 <0.0020 0.0021 <0.0020

<0.010 <0.010 <0.010 <0.010

0.0022 <0.0020 <0.0020 <0.0020

<1.0 <1.0 <1.0 <1.0

<0.20 <0.20 <0.20 <0.20

0.0569 0.0872 0.122 0.109

0.0151 0.0191 0.0290 0.0265

0.344 0.158 0.801 0.653

0.092 0.035 0.190 0.159

0.215 0.212 0.430 0.395

0.0571 0.0466 0.102 0.0963

3.29 2.81 3.70 3.17

0.877 0.616 0.878 0.773

277 141 931 483

73.6 30.9 221 118

0.252 0.228 2.32 0.179

0.0671 0.0500 0.550 0.0437

<0.50 <0.50 <0.50 <0.50

<0.10 <0.10 <0.10 <0.10

24.0 11.5 23.3 33.3

6.38 2.52 5.53 8.13

0.106 0.223 0.157 0.0948

0.0282 0.0489 0.0373 0.0231

0.116 0.057 0.089 0.116

0.0308 0.0125 0.0211 0.0282

0.51 0.26 1.29 0.81

0.135 0.057 0.305 0.198

Physical Tests

Metals

09-FEB-16 12:53 (MT)


Client ID

Sampled Date

Grouping Analyte

Sampled Time


L1628885 CONTD....

3PAGE of

Version: FINAL

5

TISSUE

Fish tissue Fish tissue Fish tissue Fish tissue17-JUN-15 17-JUN-15 17-JUN-15

MT-2-CC-01 S-5-CC-02 MT-5-CC-01 COMPOSITE (S-4-CC-01, S-5-CC-01, S-4-CC-02, MT-5-

CC-02)

L1628885-1 L1628885-4 L1628885-5 L1628885-8

Selenium (Se)-Total (mg/kg)

Selenium (Se)-Total (mg/kg wwt)

Silver (Ag)-Total (mg/kg)

Silver (Ag)-Total (mg/kg wwt)

Strontium (Sr)-Total (mg/kg)

Strontium (Sr)-Total (mg/kg wwt)

Thallium (Tl)-Total (mg/kg)

Thallium (Tl)-Total (mg/kg wwt)

Tin (Sn)-Total (mg/kg)

Tin (Sn)-Total (mg/kg wwt)

Uranium (U)-Total (mg/kg)

Uranium (U)-Total (mg/kg wwt)

Vanadium (V)-Total (mg/kg)

Vanadium (V)-Total (mg/kg wwt)

Zinc (Zn)-Total (mg/kg)

Zinc (Zn)-Total (mg/kg wwt)

1.62 2.41 1.85 1.91

0.432 0.530 0.440 0.465

<0.0050 <0.0050 0.0075 <0.0050

0.0012 <0.0010 0.0018 0.0012

80.0 104 115 89.5

21.3 22.9 27.3 21.8

0.0408 0.0449 0.0449 0.0342

0.0109 0.00985 0.0107 0.00833

<0.10 0.15 0.18 0.22

0.024 0.032 0.042 0.053

0.0275 0.0175 0.0479 0.0323

0.00732 0.00384 0.0114 0.00788

0.65 0.80 2.27 1.21

0.174 0.176 0.540 0.295

64.7 70.3 67.0 79.8

17.2 15.4 15.9 19.5

Metals

Reference Information 09-FEB-16 12:53 (MT)

L1628885 CONTD....

4PAGE of

AG-DRY-CCMS-N-VA

AG-WET-CCMS-N-VA

HG-DRY-CVAFS-N-VA

HG-WET-CVAFS-N-VA

MET-DRY-CCMS-N-VA

MET-WET-CCMS-N-VA

MOISTURE-TISS-VA

Silver in Tissue by CRC ICPMS (DRY)

Silver in Tissue by CRC ICPMS (WET)

Mercury in Tissue by CVAFS (DRY)

Mercury in Tissue by CVAFS (WET)

Metals in Tissue by CRC ICPMS (DRY)

Metals in Tissue by CRC ICPMS (WET)

% Moisture in Tissues

This method is conducted following British Columbia Lab Manual method "Metals in Animal Tissue and Vegetation (Biota) - Prescriptive". Tissue samples are homogenized and sub-sampled prior to hotblock digestion with nitric and hydrochloric acids, in combination with addition of hydrogen peroxide. Instrumental analysis is by collision cell inductively coupled plasma - mass spectrometry (modified from EPA Method 6020A).

Method Limitation: This method employs a strong acid/peroxide digestion, and is intended to provide a conservative estimate of bio-available metals. Near complete recoveries are achieved for most toxicologically important metals, but elements associated with recalcitrant minerals may be only partially recovered.



This method is conducted following British Columbia Lab Manual method "Metals in Animal Tissue and Vegetation (Biota) - Prescriptive". Tissue samples are homogenized and sub-sampled prior to hotblock digestion with nitric and hydrochloric acids, in combination with addition of hydrogen peroxide. Analysis is by atomic fluorescence spectrophotometry or atomic absorption spectrophotometry, adapted from US EPA Method 245.7.






This analysis is carried out gravimetrically by drying the sample at 105 C for a minimum of six hours.

ALS Test Code Test Description

Tissue

Tissue

Tissue

Tissue

Tissue

Tissue

Tissue

EPA 200.3/6020A

EPA 200.3/6020A

EPA 200.3, EPA 245.7

EPA 200.3, EPA 245.7

EPA 200.3/6020A

EPA 200.3/6020A

ASTM D2974-00 Method A

Method Reference**

** ALS test methods may incorporate modifications from specified reference methods to improve performance.

Matrix

The last two letters of the above test code(s) indicate the laboratory that performed analytical analysis for that test. Refer to the list below:

Laboratory Definition Code Laboratory Location

Test Method References:

Chain of Custody Numbers:

10-034387

Version: FINAL

5

Reference Information 09-FEB-16 12:53 (MT)

L1628885 CONTD....

5PAGE of

GLOSSARY OF REPORT TERMSSurrogate - A compound that is similar in behaviour to target analyte(s), but that does not occur naturally in environmental samples. Forapplicable tests, surrogates are added to samples prior to analysis as a check on recovery.mg/kg - milligrams per kilogram based on dry weight of sample.mg/kg wwt - milligrams per kilogram based on wet weight of sample.mg/kg lwt - milligrams per kilogram based on lipid-adjusted weight of sample.mg/L - milligrams per litre.< - Less than.D.L. - The reported Detection Limit, also known as the Limit of Reporting (LOR).N/A - Result not available. Refer to qualifier code and definition for explanation.

Test results reported relate only to the samples as received by the laboratory.UNLESS OTHERWISE STATED, ALL SAMPLES WERE RECEIVED IN ACCEPTABLE CONDITION.Analytical results in unsigned test reports with the DRAFT watermark are subject to change, pending final QC review.

Version: FINAL

5

Quality Control ReportPage 1 of

Client:

Contact:

GOLDER ASSOCIATES LTD. 200-2920 Virtual Way Vancouver BC V5M 0C4Audrey Wagenaar

Report Date: 09-FEB-16Workorder: L1628885

Test Matrix Reference Result Qualifier Units RPD Limit Analyzed

AG-DRY-CCMS-N-VA

AG-WET-CCMS-N-VA

HG-DRY-CVAFS-N-VA

HG-WET-CVAFS-N-VA

Tissue

Tissue

Tissue

Tissue

R3328428

R3328428

R3328399

R3328398

Batch

Batch

Batch

Batch

CRM

DUP

LCS

MB

CRM

DUP

LCS

MB

CRM

DUP

LCS

MB

CRM

DUP

LCS

MB

WG2228293-3

WG2228293-2

WG2228293-4

WG2228293-1

WG2228293-3

WG2228293-2

WG2228293-4

WG2228293-1

WG2228293-3

WG2228293-2

WG2228293-4

WG2228293-1

WG2228293-3

WG2228293-2

WG2228293-4

WG2228293-1

VA-NIST-1566B

L1628885-1

VA-NIST-1566B

L1628885-1

VA-NIST-1566B

L1628885-1

VA-NIST-1566B

L1628885-1

Silver (Ag)-Total

Silver (Ag)-Total

Silver (Ag)-Total

Silver (Ag)-Total

Silver (Ag)-Total

Silver (Ag)-Total

Silver (Ag)-Total

Silver (Ag)-Total

Mercury (Hg)-Total

Mercury (Hg)-Total

Mercury (Hg)-Total

Mercury (Hg)-Total

Mercury (Hg)-Total

Mercury (Hg)-Total

Mercury (Hg)-Total

Mercury (Hg)-Total

103.3

<0.0050

85.8

<0.0050

103.3

0.0011

85.8

<0.0010

91.8

0.113

102.9

<0.0050

91.8

0.0300

102.9

<0.0010

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

10-DEC-15

10-DEC-15

10-DEC-15

10-DEC-15

10-DEC-15

10-DEC-15

10-DEC-15

10-DEC-15

N/A

14

6.3

6.3

40

40

40

40

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

%

mg/kg

%

mg/kg

%

mg/kg wwt

%

mg/kg wwt

%

mg/kg

%

mg/kg

%

mg/kg wwt

%

mg/kg wwt

0.005

0.001

0.005

0.001

RPD-NA<0.0050

0.0012

0.106

0.0282

8

Quality Control ReportPage 2 ofReport Date: 09-FEB-16Workorder: L1628885


MET-DRY-CCMS-N-VA Tissue

R3328428BatchCRM

DUP

WG2228293-3

WG2228293-2

VA-NIST-1566B

L1628885-1

Arsenic (As)-Total

Barium (Ba)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total

Manganese (Mn)-Total

Molybdenum (Mo)-Total

Nickel (Ni)-Total

Selenium (Se)-Total

Strontium (Sr)-Total

Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total

Aluminum (Al)-Total

Antimony (Sb)-Total

Arsenic (As)-Total

Barium (Ba)-Total

Beryllium (Be)-Total

Bismuth (Bi)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total

Lithium (Li)-Total



105.2

105.3

99.1

105.5

97.8

104.3

107.3

106.8

108.1

108.5

106.5

111.2

105.9

96.1

103.2

108.8

103.2

132

0.013

0.585

5.02

<0.010

<0.010

<1.0

0.0557

0.291

0.194

3.26

226

0.207

<0.50

19.4

0.111

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

20

11

2.7

25

N/A

N/A

N/A

2.2

17

10

1.2

20

20

N/A

21

4.0

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

RPD-NA

RPD-NA

RPD-NA

RPD-NA

161

0.014

0.601

6.45

<0.010

<0.010

<1.0

0.0569

0.344

0.215

3.29

277

0.252

<0.50

24.0

0.116

8




R3328428BatchDUP

LCS

MB

WG2228293-2

WG2228293-4

WG2228293-1

L1628885-1Nickel (Ni)-Total

Selenium (Se)-Total


Thallium (Tl)-Total

Tin (Sn)-Total

Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total

Aluminum (Al)-Total

Antimony (Sb)-Total

Arsenic (As)-Total

Barium (Ba)-Total


Bismuth (Bi)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total

Lithium (Li)-Total



Nickel (Ni)-Total

Selenium (Se)-Total


Thallium (Tl)-Total

Tin (Sn)-Total

Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total

Aluminum (Al)-Total

0.44

1.69

66.6

0.0315

<0.10

0.0231

0.54

61.1

101.1

99.8

96.9

98.4

93.0

97.9

92.4

96.2

98.1

98.8

98.5

95.5

97.0

93.1

99.7

97.4

98.9

99.0

95.4

97.5

98.0

95.7

101.3

95.0

<2.0

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

14

4.0

18

26

N/A

17

20

5.7

40

40

60

40

40

40

40

40

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

mg/kg 2

RPD-NA

0.51

1.62

80.0

0.0408

<0.10

0.0275

0.65

64.7

8



MET-DRY-CCMS-N-VA

MET-WET-CCMS-N-VA

Tissue

Tissue

R3328428

R3331853

R3328428

Batch

Batch

Batch

MB

CRM

CRM

WG2228293-1

WG2228293-3

WG2228293-3

VA-NIST-1566B

VA-NIST-1566B

Antimony (Sb)-Total

Arsenic (As)-Total

Barium (Ba)-Total


Bismuth (Bi)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total

Lithium (Li)-Total



Nickel (Ni)-Total

Selenium (Se)-Total


Thallium (Tl)-Total

Tin (Sn)-Total

Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total

Antimony (Sb)-Total

Arsenic (As)-Total

Barium (Ba)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Chromium (Cr)-Total

<0.010

<0.020

<0.050

<0.010

<0.010

<1.0

<0.0050

<0.050

<0.020

<0.10

<3.0

<0.020

<0.50

<0.050

<0.020

<0.20

<0.050

<0.050

<0.0020

<0.10

<0.0020

<0.10

<0.50

0.012

105.2

105.3

99.1

105.5

97.8

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

11-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

0-0.018

70-130

70-130

70-130

70-130

70-130

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

%

%

%

%

%

0.01

0.02

0.05

0.01

0.01

1

0.005

0.05

0.02

0.1

3

0.02

0.5

0.05

0.02

0.2

0.05

0.05

0.002

0.1

0.002

0.1

0.5

8



MET-WET-CCMS-N-VA Tissue

R3328428BatchCRM

DUP

WG2228293-3

WG2228293-2

VA-NIST-1566B

L1628885-1

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total



Nickel (Ni)-Total

Selenium (Se)-Total


Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total

Aluminum (Al)-Total

Antimony (Sb)-Total

Arsenic (As)-Total

Barium (Ba)-Total


Bismuth (Bi)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total

Lithium (Li)-Total



Nickel (Ni)-Total

Selenium (Se)-Total


Thallium (Tl)-Total

Tin (Sn)-Total

104.3

107.3

106.8

108.1

108.5

106.5

111.2

105.9

96.1

103.2

108.8

103.2

35.1

0.0034

0.156

1.34

<0.0020

<0.0020

<0.20

0.0148

0.077

0.0517

0.867

60.1

0.0551

<0.10

5.16

0.0296

0.117

0.450

17.7

0.00837

0.022

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

20

11

2.7

25

N/A

N/A

N/A

2.2

17

10

1.2

20

20

N/A

21

4.0

14

4.0

18

26

8.4

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

60

40

40

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

%

%

%

%

%

%

%

%

%

%

%

%

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

RPD-NA

RPD-NA

RPD-NA

RPD-NA

42.9

0.0038

0.160

1.72

<0.0020

0.0022

<0.20

0.0151

0.092

0.0571

0.877

73.6

0.0671

<0.10

6.38

0.0308

0.135

0.432

21.3

0.0109

0.024

8




R3328428BatchDUP

LCS

MB

WG2228293-2

WG2228293-4

WG2228293-1

L1628885-1Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total

Aluminum (Al)-Total

Antimony (Sb)-Total

Arsenic (As)-Total

Barium (Ba)-Total


Bismuth (Bi)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total

Lithium (Li)-Total



Nickel (Ni)-Total

Selenium (Se)-Total


Thallium (Tl)-Total

Tin (Sn)-Total

Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total

Aluminum (Al)-Total

Antimony (Sb)-Total

Arsenic (As)-Total

Barium (Ba)-Total


Bismuth (Bi)-Total

0.00615

0.143

16.3

101.1

99.8

96.9

98.4

93.0

97.9

92.4

96.2

98.1

98.8

98.5

95.5

97.0

93.1

99.7

97.4

98.9

99.0

95.4

97.5

98.0

95.7

101.3

95.0

<0.40

<0.0020

<0.0040

<0.010

<0.0020

<0.0020

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

17

20

5.7

40

40

40

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

mg/kg wwt

mg/kg wwt

mg/kg wwt

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

0.4

0.002

0.004

0.01

0.002

0.002

0.00732

0.174

17.2

8



MET-WET-CCMS-N-VA

MOISTURE-TISS-VA

Tissue

Tissue

R3328428

R3331853

R3329162

Batch

Batch

Batch

MB

CRM

DUP

WG2228293-1

WG2228293-3

WG2230479-3

VA-NIST-1566B

L1628885-1

Boron (B)-Total

Cadmium (Cd)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total

Lithium (Li)-Total



Nickel (Ni)-Total

Selenium (Se)-Total


Thallium (Tl)-Total

Tin (Sn)-Total

Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total

Antimony (Sb)-Total

% Moisture

<0.20

<0.0010

<0.010

<0.0040

<0.020

<0.60

<0.0040

<0.10

<0.010

<0.0040

<0.040

<0.010

<0.010

<0.00040

<0.020

<0.00040

<0.020

<0.10

0.0118

74.8

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

09-DEC-15

11-DEC-15

11-DEC-151.9 20

0-0.0177

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

%

0.2

0.001

0.01

0.004

0.02

0.6

0.004

0.1

0.01

0.004

0.04

0.01

0.01

0.0004

0.02

0.0004

0.02

0.1

73.4

8


Sample Parameter Qualifier Definitions:

Description Qualifier

RPD-NA Relative Percent Difference Not Available due to result(s) being less than detection limit.

Limit ALS Control Limit (Data Quality Objectives)DUP DuplicateRPD Relative Percent DifferenceN/A Not AvailableLCS Laboratory Control SampleSRM Standard Reference MaterialMS Matrix SpikeMSD Matrix Spike DuplicateADE Average Desorption EfficiencyMB Method BlankIRM Internal Reference MaterialCRM Certified Reference MaterialCCV Continuing Calibration VerificationCVS Calibration Verification StandardLCSD Laboratory Control Sample Duplicate

Legend:

The ALS Quality Control Report is provided to ALS clients upon request. ALS includes comprehensive QC checks with every analysis to ensure our high standards of quality are met. Each QC result has a known or expected target value, which is compared against pre-determined data quality objectives to provide confidence in the accuracy of associated test results.

Please note that this report may contain QC results from anonymous Sample Duplicates and Matrix Spikes that do not originate from this Work Order.

Hold Time Exceedances:

All test results reported with this submission were conducted within ALS recommended hold times.

ALS recommended hold times may vary by province. They are assigned to meet known provincial and/or federal government requirements. In the absence of regulatory hold times, ALS establishes recommendations based on guidelines published by the US EPA, APHA Standard Methods, or Environment Canada (where available). For more information, please contact ALS.

8

February 03, 2016 Analytical Report for Service Request No: K1600229

Ms. Amber SpringerALS Environmental - Canada8081 Lougheed HwyBurnaby, BC V5A 1W9

Analyses were performed according to our laboratory’s NELAP-approved quality assurance program. The test results meet requirements of the current NELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP-accredited analytes, refer to the certifications section at www.alsglobal.com. All results are intended to be considered in their entirety, and ALS Group USA Corp. dba ALS Environmental (ALS) is not responsible for use of less than the complete report. Results apply only to the items submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the report.

For your reference, these analyses have been assigned our service request numberEnclosed are the results of the sample(s) submitted to our laboratory January 08, 2016

RE: L1628885

Dear Ms.Springer,

K1600229.

Please contact me if you have any questions. My extension is 3376. You may also contact me via email at [email protected].

Respectfully submitted,

ALS Group USA, Corp. dba ALS Environmental

Gregory Salata, Ph.D.Client Services Manager

ALS Group USA, Corp1317 South 13th AvenueKelso, WA 98626

+1 360 577 7222+1 360 636 1068

T :F :

ALS Environmental

www.alsglobal.com

RIGHT SOLUTIONS | RIGHT PARTNER

Gregory.Salata

Salata signature

www.alsglobal.com

ALS Environmental

F :T :

+1 360 636 1068+1 360 577 7222

Kelso, WA 986261317 South 13th AvenueALS Group USA, Corp

Table of Contents


Acronyms

Qualifiers

State Certifications, Accreditations, And Licenses

Case Narrative

Chain of Custody

General Chemistry

Polynuclear Aromatic Hydrocarbons

Raw Data


ASTM American Society for Testing and Materials

A2LA American Association for Laboratory Accreditation

CARB California Air Resources Board

CAS Number Chemical Abstract Service registry Number

CFC Chlorofluorocarbon

CFU Colony-Forming Unit

DEC Department of Environmental Conservation

DEQ Department of Environmental Quality

DHS Department of Health Services

DOE Department of Ecology

DOH Department of Health

EPA U. S. Environmental Protection Agency

ELAP Environmental Laboratory Accreditation Program

GC Gas Chromatography

GC/MS Gas Chromatography/Mass Spectrometry

LOD Limit of Detection

LOQ Limit of Quantitation

LUFT Leaking Underground Fuel Tank

M ModifiedMCL Maximum Contaminant Level is the highest permissible concentration of a substance

allowed in drinking water as established by the USEPA.

MDL Method Detection Limit

MPN Most Probable Number

MRL Method Reporting Limit

NA Not Applicable

NC Not Calculated

NCASI National Council of the Paper Industry for Air and Stream Improvement

ND Not Detected

NIOSH National Institute for Occupational Safety and Health

PQL Practical Quantitation Limit

RCRA Resource Conservation and Recovery Act

SIM Selected Ion Monitoring

TPH Total Petroleum Hydrocarbonstr Trace level is the concentration of an analyte that is less than the PQL but greater than or

equal to the MDL.

Acronyms

Inorganic Data Qualifiers

* The result is an outlier. See case narrative.

# The control limit criteria is not applicable. See case narrative.

B The analyte was found in the associated method blank at a level that is significant relative to the sample result as defined by the DOD or NELAC standards.

E The result is an estimate amount because the value exceeded the instrument calibration range.

J The result is an estimated value.

U The analyte was analyzed for, but was not detected ("Non-detect") at or above the MRL/MDL. DOD-QSM 4.2 definition : Analyte was not detected and is reported as less than the LOD or as defined by the project. The detection limit is adjusted for dilution.

i The MRL/MDL or LOQ/LOD is elevated due to a matrix interference.

X See case narrative.

Q See case narrative. One or more quality control criteria was outside the limits.

H The holding time for this test is immediately following sample collection. The samples were analyzed as soon as possible afterreceipt by the laboratory.

Metals Data Qualifiers



E The percent difference for the serial dilution was greater than 10%, indicating a possible matrix interference in the sample.

M The duplicate injection precision was not met.

N The Matrix Spike sample recovery is not within control limits. See case narrative.

S The reported value was determined by the Method of Standard Additions (MSA).


W The post-digestion spike for furnace AA analysis is out of control limits, while sample absorbance is less than 50% of spike absorbance.



+ The correlation coefficient for the MSA is less than 0.995.


Organic Data Qualifiers



A A tentatively identified compound, a suspected aldol-condensation product.


C The analyte was qualitatively confirmed using GC/MS techniques, pattern recognition, or by comparing to historical data.

D The reported result is from a dilution.

E The result is an estimated value.


N The result is presumptive. The analyte was tentatively identified, but a confirmation analysis was not performed.

PThe GC or HPLC confirmation criteria was exceeded. The relative percent difference is greater than 40% between the two analytical results.


i The MRL/MDL or LOQ/LOD is elevated due to a chromatographic interference.



Additional Petroleum Hydrocarbon Specific Qualifiers

F The chromatographic fingerprint of the sample matches the elution pattern of the calibration standard.

L The chromatographic fingerprint of the sample resembles a petroleum product, but the elution pattern indicates the presence of a greater amount of lighter molecular weight constituents than the calibration standard.

H The chromatographic fingerprint of the sample resembles a petroleum product, but the elution pattern indicates the presence of a greater amount of heavier molecular weight constituents than the calibration standard.

O The chromatographic fingerprint of the sample resembles an oil, but does not match the calibration standard.

Y The chromatographic fingerprint of the sample resembles a petroleum product eluting in approximately the correct carbon range, but the elution pattern does not match the calibration standard.

Z The chromatographic fingerprint does not resemble a petroleum product.

Agency Web Site Number

Alaska DEC UST http://dec.alaska.gov/applications/eh/ehllabreports/USTLabs.aspx UST-040

Arizona DHS http://www.azdhs.gov/lab/license/env.htm AZ0339

Arkansas - DEQ http://www.adeq.state.ar.us/techsvs/labcert.htm 88-0637

California DHS (ELAP) http://www.cdph.ca.gov/certlic/labs/Pages/ELAP.aspx 2795

DOD ELAP http://www.denix.osd.mil/edqw/Accreditation/AccreditedLabs.cfm L14-51

Florida DOH http://www.doh.state.fl.us/lab/EnvLabCert/WaterCert.htm E87412

Hawaii DOH Not available -

Idaho DHWhttp://www.healthandwelfare.idaho.gov/Health/Labs/CertificationDrinkingWaterLabs/tabid/1833/Default.aspx -

ISO 17025 http://www.pjlabs.com/ L14-50

Louisiana DEQhttp://www.deq.louisiana.gov/portal/DIVISIONS/PublicParticipationandPermitSupport/LouisianaLaboratoryAccreditationProgram.aspx 03016

Maine DHS Not available WA01276

Michigan DEQ http://www.michigan.gov/deq/0,1607,7-135-3307_4131_4156---,00.html 9949

Minnesota DOH http://www.health.state.mn.us/accreditation 053-999-457

Montana DPHHS http://www.dphhs.mt.gov/publichealth/ CERT0047

Nevada DEP http://ndep.nv.gov/bsdw/labservice.htm WA01276

New Jersey DEP http://www.nj.gov/dep/oqa/ WA005

North Carolina DWQ http://www.dwqlab.org/ 605

Oklahoma DEQ http://www.deq.state.ok.us/CSDnew/labcert.htm 9801

Oregon – DEQ (NELAP)http://public.health.oregon.gov/LaboratoryServices/EnvironmentalLaboratoryAccreditation/Pages/index.aspx WA100010

South Carolina DHEC http://www.scdhec.gov/environment/envserv/ 61002

Texas CEQ http://www.tceq.texas.gov/field/qa/env_lab_accreditation.html T104704427

Washington DOE http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html C544

Wisconsin DNR http://dnr.wi.gov/ 998386840

Wyoming (EPA Region 8) http://www.epa.gov/region8/water/dwhome/wyomingdi.html -

Kelso Laboratory Website www.alsglobal.com NA

ALS Group USA Corp. dba ALS Environmental (ALS) - KelsoState Certifications, Accreditations, and Licenses

Analyses were performed according to our laboratory’s NELAP-approved quality assurance program. A complete listing of specific NELAP-certified analytes, can be found in the certification section at www.ALSGlobal.com or at the accreditation bodies web site.Please refer to the certification and/or accreditation body's web site if samples are submitted for compliance purposes. The states highlighted above, require the analysis be listed on the state certification if used for compliance purposes and if the method/anlayte is offered by that state.

Case Narrative

ALS Environmental—Kelso Laboratory 1317 South 13th Avenue, Kelso, WA 98626 Phone (360)577-7222 Fax (360)636-1068 www.alsglobal.com


Approved by______________________________________________

ALS ENVIRONMENTAL

Client: ALS Environmental - Canada Service Request No.: K1600229 Project: L1628885 Date Received: 01/08/16Sample Matrix: Animal Tissue

Case Narrative

All analyses were performed consistent with the quality assurance program of ALS Environmental. This report contains analytical results for samples designated for Tier II validation deliverables including summary forms and all of the associated raw data for each of the analyses. When appropriate to the method, method blank results have been reported with each analytical test.

Sample Receipt

Four animal tissue samples were received for analysis at ALS Environmental on 01/08/16. The samples were received in good condition and consistent with the accompanying chain of custody form. The samples were stored frozen at –20ºC upon receipt at the laboratory.

Polynuclear Aromatic Hydrocarbons by EPA Method 8270

Surrogate Exceptions: The upper control criterion was exceeded by 1% for the surrogate Fluoranthene-d10 in sample Method Blank (MB) KWG1600316-3. The error associated with elevated recovery equates to a potential slight high bias. The result was flagged to indicate the issue. No further corrective action was taken.

No other anomalies associated with the analysis of these samples were observed.

Gregory.Salata

Salata signature

Chain of Custody



f/11Ltoo2,1A L1628885

~...-. .... ,.., Enu&ronmental

Subcontract Request Form

Subcontract To:

ALS ENVIRONMENTAL- KELSO, WASHINGTON, USA 1317 S. 13TH AVE KELSO,WA 98626

NOTES: Please reference on final report and invoice: PO# L/628885

ALS requires QC data to be provided with your final results.

Please see enclosed

SAMPLE NUMBER

~ sample(s) in

ANALYTICAL REQUIRED

4. Container(s)

DATE SAMPLED

DUE DATE

L1628885-1 MT-2-CC-01 6/17/2015

Special Request- Kelso (SPECIAL REQUEST-KL 14) 12/17/2015

L1628885-4 S-5-CC-02 6/ 17/ 2015


L1628885-5 MT-5-CC-01 6/ 17/ 2015


L1628885-8 COMPOSITE


Subcontract Info Contact:

Analysis and reporting info contact:

Walter Lin (604) 253-4188

Amber Springer, B.Sc 8081 LOUGHEED HWY SUITE 100 BURNABY,BC V5A 1W9

VANCOUVER

Priority Flag

Phone: (604) 253-4188 Email: [email protected]

Please email confirmation of receipt to: [email protected]

Shipped By: ______________ Date Shipped:

i ] 't/ll.c 1 OLJD Received By: '~'"' Date Received: Tl

Verified By: _______________ Date Verified:

Temperature:

Sample Integrity Issues:

Monday, December 21, 2015 11:42 AM Page 1 of 1

Client lfi..:J/:tt~ . ]Sf_,~ Opened· !jo7; ~= PC'Jdu_n-. role'£ 8,, ' ""~•KI6 f}Q;i,:Jq ="'if Unloaded~: 1~/x~/;~~~~+-~ J7 (f? By:~

Cooler Receipt and Preservation Form

1. Samples were received via? UPS DHL PDX Courier Hand Delivered

2. Samples were received in: (circle)

3. Were custody seals on coolers?

Box Envelope Other NA

y@ If yes, how many and where?

If present, were custody seals intact? y N If present, were they signed and dated? y N . ..

Rawr'<J>l, Corrected. Raw Corrected Corr •. · ThermOmeter Cooler/CDC I~ , .· Tracking Number CoolerT p COoler 'rem Tem.P-al~nk nm~·Biailk · Factor . ID N~ . · ...

• NA Filed

~.1' X", {C) ·-·· -· . c/ ;--)~'":~- P:::~N 1'?/RO Lfq I/) ~-

,, li

rylce ~

5. Were custody papers properly filled out (ink, signed, etc.)?

6. Did all bottles arrive in good condition (unbroken)? Indicate in the table below.

7. Were all sample labels complete (i.e analysis, preservation, etc.)?

8. Did all sample labels and tags agree with custody papers? Indicate major discrepancies in the table on page 2.

9. Were appropriate bottles/containers and volumes received for the tests indicated?

l 0. Were the pH-preserved bottles (see SMO GEN SOP) received at the appropriate pH? Indicate in the table below

ll. Were VOA vials received without headspace? Indicate in the table below.

Sam le ID on Bottle Sam le ID on COC Identified by:

.

N NA~ NA . · :_.; '*" NA · 'CJ (fiJ'

'{.!:./ N

NA <J2 NA C) @Y ~ y

-

N

N

N

N

Bottle Count Out of Head· Volume Reagent Lot Sample ID Bottle Type Temp space Broke pH Reagent added Number. Initials Time

L J {.P Z?SK:>S~3 ·( f ·zo~ X ' /ttl .<;aawLtd ~n7. X .

:Lf{g_1Xf&:5 -I aM.uJ:I-f' d /onrKt../1 'f: 'ianz ni"<J fMz0.& ru:rf i f1Ck7rtdualiO bulzkiGLarzyjJ "

1

)/-{- Jnr 1 (/ h1d ,_2412LIJ~cf ~--,]·--·-- l

Page~~of __

General Chemistry



K1600229ALS Environmental - Canada

L1628885


Cover Page - Organic Analysis Data Package

Client:

Project:

Service Request:

Date

Collected

Date

ReceivedLab CodeSample Name


K1600229-002 06/17/2015 01/08/2016L1628885-4 S-5-CC-02

K1600229-003 06/17/2015 01/08/2016L1628885-5 MT-5-CC-01

K1600229-004 06/17/2015 01/08/2016L1628885-8 Composite

Cover Page - Organic 1of1Page

RR185774SuperSet Reference:u:\Stealth\Crystal.rpt\FormSSum.rpt

Analytical Results

ALS Environmental - Canada K1600229

K1600229-002

ug/Kg

Wet

L1628885-4 S-5-CC-02

06/17/2015

01/08/2016

L1628885

Animal tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:

Level: LowExtraction Method:

Analysis Method:

EPA 3541

8270D SIM

NoteMDLMRLQResultAnalyte Name

Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor

8.6 01/12/161 KWG160031601/25/160.40J2.2Naphthalene

8.6 01/12/161 KWG160031601/25/160.66J1.42-Methylnaphthalene

8.6 01/12/161 KWG160031601/25/160.49J1.1Acenaphthylene

8.6 01/12/161 KWG160031601/25/160.88J1.8Acenaphthene

8.6 01/12/161 KWG160031601/25/160.42J1.9Dibenzofuran

8.6 01/12/161 KWG160031601/25/160.50J4.7Fluorene

8.6 01/12/161 KWG160031601/25/160.21J5.2Phenanthrene

8.6 01/12/161 KWG160031601/25/160.31J0.52Anthracene

8.6 01/12/161 KWG160031601/25/160.56J2.3Fluoranthene

8.6 01/12/161 KWG160031601/25/160.30J1.4Pyrene

8.6 01/12/161 KWG160031601/25/160.52J1.5Benz(a)anthracene

8.6 01/12/161 KWG160031601/25/160.43J0.86Chrysene

8.6 01/12/161 KWG160031601/25/160.62J1.5Benzo(b)fluoranthene†

8.6 01/12/161 KWG160031601/25/160.42J0.83Benzo(k)fluoranthene

8.6 01/12/161 KWG160031601/25/160.69J1.1Benzo(a)pyrene

8.6 01/12/161 KWG160031601/25/160.83J1.3Indeno(1,2,3-cd)pyrene

8.6 01/12/161 KWG160031601/25/160.81UNDDibenz(a,h)anthracene

8.6 01/12/161 KWG160031601/25/160.83J2.6Benzo(g,h,i)perylene

Surrogate Name %Rec

Control

Limits NoteDate

Analyzed

39-96 AcceptableFluorene-d10 01/25/1690

41-100 AcceptableFluoranthene-d10 01/25/1699

39-111 AcceptableTerphenyl-d14 01/25/16102

† Analyte Comments

This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene

Comments:

1of1Page10:03:0801/29/2016Printed: Form 1A - Organic

Merged SuperSet Reference: RR185774u:\Stealth\Crystal.rpt\Form1mNew.rpt

Analytical Results


K1600229-003

ug/Kg

Wet

L1628885-5 MT-5-CC-01

06/17/2015

01/08/2016

L1628885

Animal tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






6.9 01/12/161 KWG160031601/25/160.40J5.1Fluorene


6.9 01/12/161 KWG160031601/25/160.25J0.49Anthracene


6.9 01/12/161 KWG160031601/25/160.24J1.2Pyrene


6.9 01/12/161 KWG160031601/25/160.35UNDChrysene

6.9 01/12/161 KWG160031601/25/160.50UNDBenzo(b)fluoranthene†

6.9 01/12/161 KWG160031601/25/160.33UNDBenzo(k)fluoranthene

6.9 01/12/161 KWG160031601/25/160.55UNDBenzo(a)pyrene

6.9 01/12/161 KWG160031601/25/160.66UNDIndeno(1,2,3-cd)pyrene


6.9 01/12/161 KWG160031601/25/160.66UNDBenzo(g,h,i)perylene

Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1600229-004

ug/Kg

Wet

L1628885-8 Composite

06/17/2015

01/08/2016

L1628885

Animal tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor

12 01/12/161 KWG160031601/25/160.55J2.9Naphthalene

12 01/12/161 KWG160031601/25/160.91J1.62-Methylnaphthalene

12 01/12/161 KWG160031601/25/160.67J1.4Acenaphthylene

12 01/12/161 KWG160031601/25/161.3J1.9Acenaphthene

12 01/12/161 KWG160031601/25/160.58J1.6Dibenzofuran

12 01/12/161 KWG160031601/25/160.70J5.3Fluorene

12 01/12/161 KWG160031601/25/160.29J5.2Phenanthrene

12 01/12/161 KWG160031601/25/160.43J0.91Anthracene

12 01/12/161 KWG160031601/25/160.77J2.8Fluoranthene

12 01/12/161 KWG160031601/25/160.41J1.3Pyrene

12 01/12/161 KWG160031601/25/160.72J1.9Benz(a)anthracene

12 01/12/161 KWG160031601/25/160.60UNDChrysene

12 01/12/161 KWG160031601/25/160.86UNDBenzo(b)fluoranthene†

12 01/12/161 KWG160031601/25/160.58UNDBenzo(k)fluoranthene

12 01/12/161 KWG160031601/25/160.96UNDBenzo(a)pyrene

12 01/12/161 KWG160031601/25/161.2UNDIndeno(1,2,3-cd)pyrene

12 01/12/161 KWG160031601/25/161.2UNDDibenz(a,h)anthracene

12 01/12/161 KWG160031601/25/161.2UNDBenzo(g,h,i)perylene

Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


KWG1600316-3

ug/Kg

Wet

Method Blank

NA

NA

L1628885

Animal tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor


6.9 01/12/161 KWG160031601/25/160.53UND2-Methylnaphthalene

6.9 01/12/161 KWG160031601/25/160.39UNDAcenaphthylene

6.9 01/12/161 KWG160031601/25/160.70UNDAcenaphthene

6.9 01/12/161 KWG160031601/25/160.33UNDDibenzofuran

6.9 01/12/161 KWG160031601/25/160.40UNDFluorene


6.9 01/12/161 KWG160031601/25/160.25UNDAnthracene

6.9 01/12/161 KWG160031601/25/160.44UNDFluoranthene

6.9 01/12/161 KWG160031601/25/160.24J0.51Pyrene


6.9 01/12/161 KWG160031601/25/160.35UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed


41-100 Outside Control LimitsFluoranthene-d10 01/25/16101




Comments:




Extraction Method:

QA/QC Report

Surrogate Recovery Summary


Low

Animal tissue

L1628885

Client:

Project:

Sample Matrix:

Service Request:

Units:

Level:

Sample Name Lab Code


EPA 3541

Analysis Method: 8270D SIM

Sur1 Sur2 Sur3

Percent

K1600229-002L1628885-4 S-5-CC-02 90 99 102

K1600229-003L1628885-5 MT-5-CC-01 82 93 94

K1600229-004L1628885-8 Composite 83 98 96

KWG1600316-3 *Method Blank 90 101 110

KWG1600316-1Lab Control Sample 86 95 92

KWG1600316-2Duplicate Lab Control Sample 82 90 88

Form 2A - OrganicPrinted: 01/29/2016 10:03:25 1 of 1

Surrogate Recovery Control Limits (%)

39-96

41-100

39-111

Fluorene-d10

Fluoranthene-d10

Terphenyl-d14

Results flagged with an asterisk (*) indicate values outside control criteria.

Page

Results flagged with a pound (#) indicate the control criteria is not applicable.

RR185774SuperSet Reference:

Sur1

Sur2

Sur3

=

=

=

u:\Stealth\Crystal.rpt\Form2.rpt

Lab Control Spike/Duplicate Lab Control Spike Summary

%Rec

Lab Control Spike

%Rec

Limits

Duplicate Lab Control Spike

%Rec RPD

RPD

Limit

QA/QC Report

Duplicate Lab Control Sample

KWG1600316-2


8270D SIM

ug/Kg

Wet

Lab Control Sample

KWG1600316-1


KWG1600316

Animal tissue

Low

L1628885

Client:

Project:

Sample Matrix:

Service Request:

Extraction Method:

Analysis Method:

Units:

Basis:

Level:

Extraction Lot:

Analyte Name Result Result


Date Extracted:

Date Analyzed:

01/12/2016

01/25/2016

EPA 3541

Spike

Amount

Spike

Amount

43-102500 76 40Naphthalene 500 81 6403 379

43-114500 73 402-Methylnaphthalene 500 77 6387 365

53-100500 78 40Acenaphthylene 500 83 7416 388

52-101500 77 40Acenaphthene 500 83 8413 383

55-103500 79 40Dibenzofuran 500 82 4412 394

56-104500 77 40Fluorene 500 84 9419 385

54-100500 73 40Phenanthrene 500 79 9397 363

57-103500 83 40Anthracene 500 90 9451 413

55-108500 80 40Fluoranthene 500 87 9435 399

48-117500 79 40Pyrene 500 85 7425 394

55-105500 74 40Benz(a)anthracene 500 82 10411 370

58-112500 85 40Chrysene 500 92 8461 425

60-107500 83 40Benzo(b)fluoranthene 500 90 8452 417

58-115500 87 40Benzo(k)fluoranthene 500 95 9474 433

56-110500 75 40Benzo(a)pyrene 500 83 10413 376

50-117500 59 40Indeno(1,2,3-cd)pyrene 500 67 13337 296

52-112500 54 40Dibenz(a,h)anthracene 500 64 17319 268

56-117500 73 40Benzo(g,h,i)perylene 500 79 9397 365

Form 3C - OrganicPrinted: 01/29/2016 10:04:00 Page 1 of 1



Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded.

u:\Stealth\Crystal.rpt\Form3DLC.rpt


L1628885



Client:

Project:

Service Request:

Date

Collected

Date



K1600229-002 06/17/2015 01/08/2016L1628885-4 S-5-CC-02

K1600229-003 06/17/2015 01/08/2016L1628885-5 MT-5-CC-01

K1600229-004 06/17/2015 01/08/2016L1628885-8 Composite



Analytical Results


K1600229-002

ug/Kg

Dry

L1628885-4 S-5-CC-02

06/17/2015

01/08/2016

L1628885

Animal tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor

40 01/12/161 KWG160031601/25/161.8J10Naphthalene





40 01/12/161 KWG160031601/25/162.3J22Fluorene

40 01/12/161 KWG160031601/25/160.94J24Phenanthrene

40 01/12/161 KWG160031601/25/161.5J2.3Anthracene

40 01/12/161 KWG160031601/25/162.6J10Fluoranthene

40 01/12/161 KWG160031601/25/161.4J6.3Pyrene


40 01/12/161 KWG160031601/25/162.0J3.9Chrysene

40 01/12/161 KWG160031601/25/162.9J6.7Benzo(b)fluoranthene†

40 01/12/161 KWG160031601/25/161.9J3.8Benzo(k)fluoranthene

40 01/12/161 KWG160031601/25/163.2J4.9Benzo(a)pyrene

40 01/12/161 KWG160031601/25/163.8J6.0Indeno(1,2,3-cd)pyrene


40 01/12/161 KWG160031601/25/163.8J12Benzo(g,h,i)perylene

Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1600229-003

ug/Kg

Dry

L1628885-5 MT-5-CC-01

06/17/2015

01/08/2016

L1628885

Animal tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor




29 01/12/161 KWG160031601/25/163.0J13Acenaphthene


29 01/12/161 KWG160031601/25/161.7J21Fluorene


29 01/12/161 KWG160031601/25/161.1J2.1Anthracene


29 01/12/161 KWG160031601/25/160.99J5.1Pyrene


29 01/12/161 KWG160031601/25/161.5UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1600229-004

ug/Kg

Dry


06/17/2015

01/08/2016

L1628885

Animal tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






49 01/12/161 KWG160031601/25/162.9J22Fluorene


49 01/12/161 KWG160031601/25/161.8J3.7Anthracene

49 01/12/161 KWG160031601/25/163.2J11Fluoranthene

49 01/12/161 KWG160031601/25/161.7J5.2Pyrene


49 01/12/161 KWG160031601/25/162.5UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


KWG1600316-3

ug/Kg

Dry

Method Blank

NA

NA

L1628885

Animal tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






6.9 01/12/161 KWG160031601/25/160.40UNDFluorene




6.9 01/12/161 KWG160031601/25/160.24J0.51Pyrene


6.9 01/12/161 KWG160031601/25/160.35UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:




Extraction Method:

QA/QC Report



Low

Animal tissue

L1628885

Client:

Project:

Sample Matrix:

Service Request:

Units:

Level:



EPA 3541


Sur1 Sur2 Sur3

Percent

K1600229-002L1628885-4 S-5-CC-02 90 99 102

K1600229-003L1628885-5 MT-5-CC-01 82 93 94

K1600229-004L1628885-8 Composite 83 98 96

KWG1600316-3 *Method Blank 90 101 110





39-96

41-100

39-111

Fluorene-d10

Fluoranthene-d10

Terphenyl-d14


Page



Sur1

Sur2

Sur3

=

=

=



%Rec

Lab Control Spike

%Rec

Limits


%Rec RPD

RPD

Limit

QA/QC Report


KWG1600316-2


8270D SIM

ug/Kg

Dry

Lab Control Sample

KWG1600316-1


KWG1600316

Animal tissue

Low

L1628885

Client:

Project:

Sample Matrix:

Service Request:

Extraction Method:

Analysis Method:

Units:

Basis:

Level:

Extraction Lot:



Date Extracted:

Date Analyzed:

01/12/2016

01/25/2016

EPA 3541

Spike

Amount

Spike

Amount

43-102500 76 40Naphthalene 500 81 6403 379


53-100500 78 40Acenaphthylene 500 83 7416 388

52-101500 77 40Acenaphthene 500 83 8413 383

55-103500 79 40Dibenzofuran 500 82 4412 394

56-104500 77 40Fluorene 500 84 9419 385

54-100500 73 40Phenanthrene 500 79 9397 363

57-103500 83 40Anthracene 500 90 9451 413

55-108500 80 40Fluoranthene 500 87 9435 399

48-117500 79 40Pyrene 500 85 7425 394


58-112500 85 40Chrysene 500 92 8461 425



56-110500 75 40Benzo(a)pyrene 500 83 10413 376

50-117500 59 40Indeno(1,2,3-cd)pyrene 500 67 13337 296









L1628885



Client:

Project:

Service Request:

Date

Collected

Date



K1600229-002 06/17/2015 01/08/2016L1628885-4 S-5-CC-02

K1600229-003 06/17/2015 01/08/2016L1628885-5 MT-5-CC-01

K1600229-004 06/17/2015 01/08/2016L1628885-8 Composite



Analytical Results


K1600229-002

ug/Kg

Wet

L1628885-4 S-5-CC-02

06/17/2015

01/08/2016

L1628885

Animal tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






8.6 01/12/161 KWG160031601/25/160.50J4.7Fluorene


8.6 01/12/161 KWG160031601/25/160.31J0.52Anthracene


8.6 01/12/161 KWG160031601/25/160.30J1.4Pyrene


8.6 01/12/161 KWG160031601/25/160.43J0.86Chrysene

8.6 01/12/161 KWG160031601/25/160.62J1.5Benzo(b)fluoranthene†

8.6 01/12/161 KWG160031601/25/160.42J0.83Benzo(k)fluoranthene

8.6 01/12/161 KWG160031601/25/160.69J1.1Benzo(a)pyrene

8.6 01/12/161 KWG160031601/25/160.83J1.3Indeno(1,2,3-cd)pyrene


8.6 01/12/161 KWG160031601/25/160.83J2.6Benzo(g,h,i)perylene

Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1600229-003

ug/Kg

Wet

L1628885-5 MT-5-CC-01

06/17/2015

01/08/2016

L1628885

Animal tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






6.9 01/12/161 KWG160031601/25/160.40J5.1Fluorene


6.9 01/12/161 KWG160031601/25/160.25J0.49Anthracene


6.9 01/12/161 KWG160031601/25/160.24J1.2Pyrene


6.9 01/12/161 KWG160031601/25/160.35UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1600229-004

ug/Kg

Wet


06/17/2015

01/08/2016

L1628885

Animal tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor

12 01/12/161 KWG160031601/25/160.55J2.9Naphthalene





12 01/12/161 KWG160031601/25/160.70J5.3Fluorene

12 01/12/161 KWG160031601/25/160.29J5.2Phenanthrene

12 01/12/161 KWG160031601/25/160.43J0.91Anthracene


12 01/12/161 KWG160031601/25/160.41J1.3Pyrene


12 01/12/161 KWG160031601/25/160.60UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


KWG1600316-3

ug/Kg

Wet

Method Blank

NA

NA

L1628885

Animal tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






6.9 01/12/161 KWG160031601/25/160.40UNDFluorene




6.9 01/12/161 KWG160031601/25/160.24J0.51Pyrene


6.9 01/12/161 KWG160031601/25/160.35UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:




Extraction Method:

QA/QC Report



Low

Animal tissue

L1628885

Client:

Project:

Sample Matrix:

Service Request:

Units:

Level:



EPA 3541


Sur1 Sur2 Sur3

Percent

K1600229-002L1628885-4 S-5-CC-02 90 99 102

K1600229-003L1628885-5 MT-5-CC-01 82 93 94

K1600229-004L1628885-8 Composite 83 98 96

KWG1600316-3 *Method Blank 90 101 110





39-96

41-100

39-111

Fluorene-d10

Fluoranthene-d10

Terphenyl-d14


Page



Sur1

Sur2

Sur3

=

=

=



%Rec

Lab Control Spike

%Rec

Limits


%Rec RPD

RPD

Limit

QA/QC Report


KWG1600316-2


8270D SIM

ug/Kg

Wet

Lab Control Sample

KWG1600316-1


KWG1600316

Animal tissue

Low

L1628885

Client:

Project:

Sample Matrix:

Service Request:

Extraction Method:

Analysis Method:

Units:

Basis:

Level:

Extraction Lot:



Date Extracted:

Date Analyzed:

01/12/2016

01/25/2016

EPA 3541

Spike

Amount

Spike

Amount

43-102500 76 40Naphthalene 500 81 6403 379


53-100500 78 40Acenaphthylene 500 83 7416 388

52-101500 77 40Acenaphthene 500 83 8413 383

55-103500 79 40Dibenzofuran 500 82 4412 394

56-104500 77 40Fluorene 500 84 9419 385

54-100500 73 40Phenanthrene 500 79 9397 363

57-103500 83 40Anthracene 500 90 9451 413

55-108500 80 40Fluoranthene 500 87 9435 399

48-117500 79 40Pyrene 500 85 7425 394


58-112500 85 40Chrysene 500 92 8461 425



56-110500 75 40Benzo(a)pyrene 500 83 10413 376

50-117500 59 40Indeno(1,2,3-cd)pyrene 500 67 13337 296









31-JUL-15




ATTN: Ann-Marie NorrisFINAL REV. 201-DEC-15 16:59 (MT)Report Date:

Version:



____________________________________________




1-DEC-2015 The list of reported Metals has been adjusted.Comments:

13/1422-0049/16000/16120Job Reference: NOT SUBMITTEDProject P.O. #:

14-475217, 14-475220C of C Numbers:Legal Site Desc:

01-DEC-15 16:59 (MT)


Client ID

Sampled Date

Grouping Analyte

Sampled Time


L1651409 CONTD....

2PAGE of

* Please refer to the Reference Information section for an explanation of any qualifiers detected.

Version: FINAL REV. 2

11

SOIL

SOIL SOIL SOIL SOIL SOIL31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15

15-TILBURY-S-1 15-TILBURY-S-2 15-TILBURY-S-1D 15-TILBURY-S-3 15-TILBURY-S-4

L1651409-1 L1651409-2 L1651409-3 L1651409-4 L1651409-5

Moisture (%)

pH (1:2 soil:water) (pH)

Total Organic Carbon (%)

Aluminum (Al) (mg/kg)

Antimony (Sb) (mg/kg)

Arsenic (As) (mg/kg)

Barium (Ba) (mg/kg)

Beryllium (Be) (mg/kg)

Bismuth (Bi) (mg/kg)

Boron (B) (mg/kg)

Cadmium (Cd) (mg/kg)

Chromium (Cr) (mg/kg)

Cobalt (Co) (mg/kg)

Copper (Cu) (mg/kg)

Iron (Fe) (mg/kg)

Lead (Pb) (mg/kg)

Lithium (Li) (mg/kg)

Manganese (Mn) (mg/kg)

Mercury (Hg) (mg/kg)

Molybdenum (Mo) (mg/kg)

Nickel (Ni) (mg/kg)

Selenium (Se) (mg/kg)

Silver (Ag) (mg/kg)

Strontium (Sr) (mg/kg)

Thallium (Tl) (mg/kg)

Tin (Sn) (mg/kg)

Uranium (U) (mg/kg)

Vanadium (V) (mg/kg)

Zinc (Zn) (mg/kg)

Acenaphthene (mg/kg)

Acenaphthylene (mg/kg)

Anthracene (mg/kg)

Benz(a)anthracene (mg/kg)

Benzo(a)pyrene (mg/kg)

Benzo(b)fluoranthene (mg/kg)

Benzo(b+j+k)fluoranthene (mg/kg)

13.5 10.4 13.7 15.4 4.03

6.02 6.16 6.02 5.80 6.40

3.03 2.28 2.99 2.37 0.97

21400 11300 21100 16000 16300

0.72 0.39 0.71 0.98 0.54

8.84 4.19 9.21 6.55 5.65

146 70.1 133 83.8 59.1

0.47 0.23 0.47 0.29 0.23

<0.20 <0.20 <0.20 <0.20 <0.20

<5.0 <5.0 <5.0 <5.0 <5.0

0.490 0.179 0.503 0.350 0.274

50.9 29.1 50.3 35.1 23.8

13.4 8.32 13.9 11.3 10.9

42.8 26.4 42.3 44.0 41.7

29600 20100 29600 27700 29300

25.4 20.8 23.9 65.8 9.99

19.7 9.4 19.9 14.3 14.7

337 310 339 432 504

0.0725 0.0256 0.0772 0.0322 0.0114

1.75 0.87 1.92 1.26 0.77

43.1 21.5 43.8 27.5 18.5

0.48 <0.20 0.47 0.28 0.38

<0.10 <0.10 <0.10 0.11 0.10

44.1 33.2 42.1 33.6 34.7

0.138 0.064 0.130 0.076 0.060

<2.0 <2.0 <2.0 <2.0 <2.0

2.29 0.573 2.31 0.662 0.340

69.3 47.5 68.7 66.2 72.5

129 131 125 116 90.1

0.017 0.039 <0.013 <0.0050 <0.0050

0.019 <0.010 0.016 0.0107 <0.0050

0.0603 0.0632 0.012 0.0065 <0.0040

0.173 0.121 0.025 0.017 <0.010

0.311 0.217 0.075 0.024 <0.010

0.572 0.413 0.133 0.041 0.011

0.809 0.585 0.196 0.055 <0.015

Physical Tests

Organic / Inorganic Carbon

Metals

Polycyclic Aromatic Hydrocarbons

DLA

DLA

01-DEC-15 16:59 (MT)


Client ID

Sampled Date

Grouping Analyte

Sampled Time


L1651409 CONTD....

3PAGE of



11

SOIL


15-TILBURY-S-5 15-TILBURY-S-6 15-TILBURY-S-7 15-TILBURY-S-8 15-TILBURY-S-9

L1651409-6 L1651409-7 L1651409-8 L1651409-9 L1651409-10

Moisture (%)






Barium (Ba) (mg/kg)



Boron (B) (mg/kg)



Cobalt (Co) (mg/kg)

Copper (Cu) (mg/kg)

Iron (Fe) (mg/kg)

Lead (Pb) (mg/kg)





Nickel (Ni) (mg/kg)


Silver (Ag) (mg/kg)



Tin (Sn) (mg/kg)

Uranium (U) (mg/kg)


Zinc (Zn) (mg/kg)



Anthracene (mg/kg)





4.27 5.62 6.33 7.53 3.24

6.76 6.27 6.54 6.43 6.61

0.54 1.23 4.79 2.03 0.38

15700 8540 10400 10400 9250

<0.10 0.29 0.28 0.22 0.21

1.88 3.73 2.62 5.38 3.49

86.3 54.9 50.8 45.9 45.8

0.31 0.19 0.18 0.17 0.20

<0.20 <0.20 0.68 <0.20 <0.20

<5.0 <5.0 10.3 <5.0 <5.0

0.029 0.094 0.277 0.162 0.091

4.78 29.8 25.4 39.3 32.3

5.35 8.01 9.20 7.95 8.28

3.90 15.8 44.9 22.1 14.1

17500 17600 18600 19400 20300

1.33 5.85 4.93 3.54 4.47

<2.0 7.6 6.4 7.6 7.3

370 327 378 364 341

<0.0050 0.0267 0.0350 0.0257 0.0480

0.87 0.46 0.46 0.45 0.37

4.06 30.1 26.8 23.7 32.8

<0.20 <0.20 <0.20 <0.20 <0.20

<0.10 <0.10 <0.10 <0.10 <0.10

74.6 31.8 43.7 32.1 25.2

<0.050 0.057 0.055 <0.050 <0.050

<2.0 <2.0 <2.0 <2.0 <2.0

0.660 0.307 0.299 0.273 0.297

24.4 40.5 43.2 48.7 49.8

31.6 37.4 69.0 46.6 42.6

<0.0050 <0.0050 <0.0050 <0.0050 <0.0050

<0.0050 <0.0050 <0.0050 <0.0050 <0.0050

<0.0070 <0.0040 <0.0040 <0.0040 <0.0040

<0.020 <0.010 <0.010 <0.010 <0.010

0.024 <0.010 <0.010 <0.010 <0.010

0.070 <0.010 <0.010 <0.010 <0.010

0.096 <0.015 <0.015 <0.015 <0.015

Physical Tests


Metals


DLM

DLQ

01-DEC-15 16:59 (MT)


Client ID

Sampled Date

Grouping Analyte

Sampled Time


L1651409 CONTD....

4PAGE of



11

SOIL


15-TILBURY-S-10 15-TILBURY-S-11 15-TILBURY-S-8-D 15-TILBURY-S-12 15-TILBURY-S-13

L1651409-11 L1651409-12 L1651409-13 L1651409-14 L1651409-15

Moisture (%)






Barium (Ba) (mg/kg)



Boron (B) (mg/kg)



Cobalt (Co) (mg/kg)

Copper (Cu) (mg/kg)

Iron (Fe) (mg/kg)

Lead (Pb) (mg/kg)





Nickel (Ni) (mg/kg)


Silver (Ag) (mg/kg)



Tin (Sn) (mg/kg)

Uranium (U) (mg/kg)


Zinc (Zn) (mg/kg)



Anthracene (mg/kg)





8.30 8.91 6.66 27.0 11.0

7.57 7.89 6.52 6.71 6.73

2.95 1.51 2.07 3.50 4.28

12400 8720 10000 14700 13400

1.27 1.34 0.22 0.70 0.59

6.48 16.4 3.45 8.23 6.03

69.7 47.8 44.3 110 79.8

0.26 0.16 0.15 0.35 0.31

<0.20 <0.20 <0.20 <0.20 <0.20

<5.0 <5.0 <5.0 <5.0 <5.0

0.236 0.469 0.144 0.414 0.271

28.7 17.8 20.6 42.8 35.7

8.59 5.24 7.94 13.9 12.1

29.9 21.8 19.2 35.2 32.7

22100 15300 18200 29100 25000

26.2 33.7 3.35 93.7 14.2

11.0 5.5 7.0 14.8 14.0

294 314 348 533 347

0.0611 0.0519 0.0255 0.0823 0.0633

1.05 0.95 0.45 1.04 1.04

24.2 15.5 22.4 43.4 38.0

<0.20 <0.20 <0.20 0.48 0.28

<0.10 0.11 <0.10 0.10 <0.10

47.9 149 28.7 57.3 46.0

0.067 <0.050 <0.050 0.103 0.084

<2.0 6.0 <2.0 <2.0 <2.0

0.717 1.06 0.247 1.23 0.878

49.0 30.0 45.5 55.0 50.6

85.6 96.6 45.0 129 87.1

0.024 0.0123 <0.0050 <0.0050 <0.010

0.029 0.0097 <0.0050 0.0076 0.027

0.078 0.0364 <0.0040 0.0088 0.0218

0.212 0.099 <0.010 0.034 0.058

0.400 0.084 <0.010 0.037 0.104

0.554 0.122 <0.010 0.051 0.170

0.809 0.173 <0.015 0.072 0.243

Physical Tests


Metals


DLA

01-DEC-15 16:59 (MT)


Client ID

Sampled Date

Grouping Analyte

Sampled Time


L1651409 CONTD....

5PAGE of



11

SOIL

SOIL SOIL31-JUL-15 31-JUL-15

15-TILBURY-S-14 15-TILBURY-S-15

L1651409-16 L1651409-17

Moisture (%)






Barium (Ba) (mg/kg)



Boron (B) (mg/kg)



Cobalt (Co) (mg/kg)

Copper (Cu) (mg/kg)

Iron (Fe) (mg/kg)

Lead (Pb) (mg/kg)





Nickel (Ni) (mg/kg)


Silver (Ag) (mg/kg)



Tin (Sn) (mg/kg)

Uranium (U) (mg/kg)


Zinc (Zn) (mg/kg)



Anthracene (mg/kg)





6.32 13.5

6.37 4.87

1.46 1.87

15300 17300

0.47 0.50

4.06 7.76

58.7 67.7

0.22 0.29

<0.20 <0.20

<5.0 <5.0

0.305 0.136

26.2 49.1

10.4 8.18

42.0 35.3

27100 32100

36.7 19.9

14.5 17.1

499 224

0.0296 0.0674

0.66 1.35

18.2 28.5

0.34 0.39

0.10 0.11

34.4 40.3

<0.050 0.105

<2.0 <2.0

0.372 1.08

73.0 65.6

89.4 67.7

<0.0050 <0.0050

<0.0050 0.0096

0.0058 0.0067

<0.010 0.024

<0.010 0.027

0.030 0.046

0.030 0.065

Physical Tests


Metals


01-DEC-15 16:59 (MT)


Client ID

Sampled Date

Grouping Analyte

Sampled Time


L1651409 CONTD....

6PAGE of



11

SOIL


15-TILBURY-S-1 15-TILBURY-S-2 15-TILBURY-S-1D 15-TILBURY-S-3 15-TILBURY-S-4

L1651409-1 L1651409-2 L1651409-3 L1651409-4 L1651409-5

Benzo(g,h,i)perylene (mg/kg)

Benzo(k)fluoranthene (mg/kg)

Chrysene (mg/kg)

Dibenz(a,h)anthracene (mg/kg)

Fluoranthene (mg/kg)

Fluorene (mg/kg)

Indeno(1,2,3-c,d)pyrene (mg/kg)

2-Methylnaphthalene (mg/kg)

Naphthalene (mg/kg)

Phenanthrene (mg/kg)

Pyrene (mg/kg)

Surrogate: Acenaphthene d10 (%)

Surrogate: Chrysene d12 (%)

Surrogate: Naphthalene d8 (%)

Surrogate: Phenanthrene d10 (%)

B(a)P Total Potency Equivalent (mg/kg)

IACR (CCME) (mg/kg)

0.221 0.175 0.078 0.020 <0.010

0.237 0.172 0.063 0.014 <0.010

0.269 <0.30 <0.070 0.032 <0.010

<0.040 <0.040 <0.020 0.0055 <0.0050

0.586 0.398 0.073 0.031 0.016

0.028 0.035 <0.025 <0.010 <0.010

0.221 0.139 0.060 0.019 <0.010

<0.020 <0.020 <0.025 <0.010 <0.010

<0.020 0.023 <0.025 <0.010 <0.010

0.404 0.397 0.041 0.028 <0.010

0.481 0.352 0.073 0.033 0.013

100.9 123.9 100.2 94.5 97.1

79.3 103.6 80.9 97.5 111.3

76.0 94.8 78.1 84.1 91.8

98.5 120.9 96.2 100.9 111.6

0.456 0.325 0.114 0.039 <0.020

6.75 4.85 1.60 0.51 <0.15


DLM DLM

DLM DLM DLM

DLA

DLA DLA DLM

DLA DLA

01-DEC-15 16:59 (MT)


Client ID

Sampled Date

Grouping Analyte

Sampled Time


L1651409 CONTD....

7PAGE of



11

SOIL


15-TILBURY-S-5 15-TILBURY-S-6 15-TILBURY-S-7 15-TILBURY-S-8 15-TILBURY-S-9

L1651409-6 L1651409-7 L1651409-8 L1651409-9 L1651409-10



Chrysene (mg/kg)



Fluorene (mg/kg)



Naphthalene (mg/kg)


Pyrene (mg/kg)






IACR (CCME) (mg/kg)

0.012 <0.010 <0.010 <0.010 <0.010

0.026 <0.010 <0.010 <0.010 <0.010

0.064 <0.010 <0.010 <0.010 <0.010

<0.0050 <0.0050 <0.0050 <0.0050 <0.0050

0.056 <0.010 <0.010 <0.010 <0.010

<0.010 <0.010 <0.020 <0.010 <0.010

0.015 <0.010 <0.010 <0.010 <0.010

<0.010 <0.010 <0.010 <0.010 <0.010

<0.010 <0.010 <0.010 <0.010 <0.010

<0.010 <0.010 <0.010 <0.010 <0.010

0.058 <0.010 <0.010 <0.010 <0.010

81.0 93.3 100.0 85.4 92.5

90.8 96.1 101.5 93.7 98.3

76.7 81.5 92.2 78.8 85.7

91.1 100.0 102.2 95.9 100.4

0.039 <0.020 <0.020 <0.020 <0.020

0.74 <0.15 <0.15 <0.15 <0.15


DLM

01-DEC-15 16:59 (MT)


Client ID

Sampled Date

Grouping Analyte

Sampled Time


L1651409 CONTD....

8PAGE of



11

SOIL


15-TILBURY-S-10 15-TILBURY-S-11 15-TILBURY-S-8-D 15-TILBURY-S-12 15-TILBURY-S-13

L1651409-11 L1651409-12 L1651409-13 L1651409-14 L1651409-15



Chrysene (mg/kg)



Fluorene (mg/kg)



Naphthalene (mg/kg)


Pyrene (mg/kg)






IACR (CCME) (mg/kg)

0.251 0.054 <0.010 0.021 0.068

0.255 0.051 <0.010 0.021 0.074

0.274 0.135 <0.010 0.054 0.091

<0.040 0.0127 <0.0050 0.0056 <0.020

0.476 0.197 <0.010 0.073 0.116

0.028 0.015 <0.010 <0.010 <0.020

0.219 0.059 <0.010 0.024 0.059

<0.025 0.012 <0.010 <0.010 <0.020

<0.025 0.011 <0.010 0.011 <0.020

0.332 0.180 <0.010 0.038 0.056

0.613 0.207 <0.010 0.077 0.129

97.6 94.4 82.8 89.6 92.2

80.9 99.4 88.3 97.6 77.6

75.8 86.5 77.3 84.0 70.4

92.7 100.7 91.7 100.4 89.9

0.550 0.132 <0.020 0.056 0.152

7.11 1.76 <0.15 0.72 2.10


DLM DLM

DLA

DLA DLA

DLA DLA

01-DEC-15 16:59 (MT)


Client ID

Sampled Date

Grouping Analyte

Sampled Time


L1651409 CONTD....

9PAGE of



11

SOIL

SOIL SOIL31-JUL-15 31-JUL-15

15-TILBURY-S-14 15-TILBURY-S-15

L1651409-16 L1651409-17



Chrysene (mg/kg)



Fluorene (mg/kg)



Naphthalene (mg/kg)


Pyrene (mg/kg)






IACR (CCME) (mg/kg)

0.013 0.016

<0.010 0.019

<0.030 0.041

<0.0050 <0.0050

0.020 0.065

<0.010 <0.010

<0.010 0.020

<0.010 <0.010

<0.010 <0.010

0.010 0.040

0.019 0.060

93.7 81.9

93.9 90.3

84.4 74.8

99.3 93.6

<0.020 0.041

0.27 0.59


DLM

Reference Information

DLA

DLM

DLQ

Detection Limit adjusted for required dilution

Detection Limit Adjusted due to sample matrix effects.

Detection Limit raised due to co-eluting interference. GCMS qualifier ion ratio did not meet acceptance criteria.

Qualifiers for Individual Parameters Listed:


01-DEC-15 16:59 (MT)

L1651409 CONTD....

10PAGE of

C-TOT-ORG-LECO-SK

HG-200.2-CVAF-VA

MET-200.2-CCMS-VA

MOISTURE-VA

PAH-TMB-H/A-MS-VA

PH-1:2-VA

Organic Carbon by combustion method

Mercury in Soil by CVAFS

Metals in Soil by CRC ICPMS

Moisture content

PAH - Rotary Extraction (Hexane/Acetone)

pH in Soil (1:2 Soil:Water Extraction)

Total Organic Carbon (C-TOT-ORG-LECO-SK, C-TOT-ORG-SK)

Total C and inorganic C are determined on separate samples. The total C is determined by combustion and thermal conductivity detection, while inorganic C is determined by weight lass after addition of hydrochloric acid. Organic C is calculated by the difference between these two determinations.

Reference for Total C:Nelson, D.W. and Sommers, L.E. 1996. Total Carbon, organic carbon and organic matter. P. 961-1010 In: J.M. Bartels et al. (ed.) Methods of soil analysis: Part 3 Chemical methods. (3rd ed.) ASA and SSSA, Madison, WI. Book series no. 5

Reference for Inorganic C:Loeppert, R.H. and Suarez, D.L. 1996. Gravimetric Method for Loss of Carbon Dioxide. P. 455-456 In: J.M. Bartels et al. (ed.) Methods of soil analysis:Part 3 Chemical methods. (3rd ed.) ASA and SSSA, Madison, WI. Book series no. 5

Soil samples are digested with nitric and hydrochloric acids, followed by analysis by CVAFS.

Soil samples are digested with nitric and hydrochloric acids, followed by analysis by CRC ICPMS. Method Limitation: This method is not a total digestion technique. It is a very strong acid digestion that is intended to dissolve those metals that may be environmentally available. This method does not dissolve all silicate materials and may result in a partial extraction. depending on the sample matrix, for some metals, including, but not limited to Al, Ba, Be, Cr, Sr, Ti, Tl, and V.


This analysis is carried out using procedures adapted from "Test Methods for Evaluating Solid Waste" SW-846, Methods 3570 & 8270, published by the United States Environmental Protection Agency (EPA). The procedure uses a mechanical shaking technique to extract a subsample of the sediment/soil with a 1:1 mixture of hexane and acetone. The extract is then solvent exchanged to toluene. The final extract is analysed by capillary column gas chromatography with mass spectrometric detection (GC/MS). Surrogate recoveries may not be reported in cases where interferences fromthe sample matrix prevent accurate quantitation. Because the two isomers cannot be readily chromatographically separated, benzo(j)fluoranthene is reported as part of the benzo(b)fluoranthene parameter.

This analysis is carried out in accordance with procedures described in the pH, Electrometric in Soil and Sediment method - Section B Physical/Inorganic and Misc. Constituents, BC Environmental Laboratory Manual 2007. The procedure involves mixing the dried (at <60°C) and sieved(No. 10 / 2mm) sample with deionized/distilled water at a 1:2 ratio of sediment to water. The pH of the solution is then measured using a standard pH probe.


Soil

Soil

Soil

Soil

Soil

Soil

SSSA (1996) p. 973

EPA 200.2/1631E (mod)

EPA 200.2/6020A (mod)


EPA 3570/8270

BC WLAP METHOD: PH, ELECTROMETRIC, SOIL

Method Reference**


Matrix



VA ALS ENVIRONMENTAL - VANCOUVER, BRITISH COLUMBIA, CANADA



14-475217 14-475220


11

Reference Information 01-DEC-15 16:59 (MT)

L1651409 CONTD....

11PAGE of




11


Client:

Contact:

GOLDER ASSOCIATES LTD. 200-2920 Virtual Way Vancouver BC V5M 0C4Ann-Marie Norris

Report Date: 01-DEC-15Workorder: L1651409


C-TOT-ORG-LECO-SK

HG-200.2-CVAF-VA

MET-200.2-CCMS-VA

Soil

Soil

Soil

R3243452

R3237942

R3239578

R3241321

Batch

Batch

Batch

Batch

DUP

IRM

MB

CRM

CRM

LCS

MB

CRM

CRM

DUP

LCS

MB

CRM

WG2143293-1

WG2143293-2

WG2143293-3

WG2141453-4

WG2141453-5

WG2141453-3

WG2141453-1

WG2141475-4

WG2141475-5

WG2141475-2

WG2141475-3

WG2141475-1

WG2141453-4

L1651409-10

08-109_SOIL

VA-NRC-STSD1

VA-NRC-PACS3

VA-NRC-STSD1

VA-NRC-PACS3

L1651409-13

VA-NRC-STSD1

Total Organic Carbon



Mercury (Hg)

Mercury (Hg)

Mercury (Hg)

Mercury (Hg)

Mercury (Hg)

Mercury (Hg)

Mercury (Hg)

Mercury (Hg)

Mercury (Hg)

Aluminum (Al)

Antimony (Sb)

Arsenic (As)

Barium (Ba)

Beryllium (Be)

Bismuth (Bi)

Boron (B)

0.40

0.92

<0.10

101.7

106.9

103.8

<0.0050

103.5

106.5

0.0252

93.9

<0.0050

102.9

91.1

101.1

90.2

104.4

104.0

117.5

10-AUG-15

10-AUG-15

10-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

6.5

1.1

30

40

0.77-1.43

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

%

%

%

%

%

%

mg/kg

%

%

mg/kg

%

mg/kg

%

%

%

%

%

%

%

0.1

0.005

0.005

0.38

0.0255

14

Quality Control ReportPage 2 ofReport Date: 01-DEC-15Workorder: L1651409


MET-200.2-CCMS-VA Soil

R3241321BatchCRM

CRM

WG2141453-4

WG2141453-5

VA-NRC-STSD1

VA-NRC-PACS3

Cadmium (Cd)

Chromium (Cr)

Cobalt (Co)

Copper (Cu)

Iron (Fe)

Lead (Pb)

Lithium (Li)

Manganese (Mn)

Molybdenum (Mo)

Nickel (Ni)

Selenium (Se)

Silver (Ag)

Strontium (Sr)

Thallium (Tl)

Tin (Sn)

Vanadium (V)

Zinc (Zn)

Aluminum (Al)

Antimony (Sb)

Arsenic (As)

Barium (Ba)

Beryllium (Be)

Boron (B)

Cadmium (Cd)

Chromium (Cr)

Cobalt (Co)

Copper (Cu)

Iron (Fe)

Lead (Pb)

Lithium (Li)

Manganese (Mn)

Molybdenum (Mo)

Nickel (Ni)

98.2

104.6

102.2

101.6

102.2

101.9

105.7

99.6

104.2

101.9

101.1

92.7

105.4

107.0

109.5

106.8

102.4

102.2

88.9

93.6

101.5

99.3

101.9

93.9

99.0

98.8

101.8

99.5

99.3

93.5

93.4

95.8

100.3

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

14




R3241321BatchCRM

CRM

CRM

WG2141453-5

WG2141475-4

WG2141475-5

VA-NRC-PACS3

VA-NRC-STSD1

VA-NRC-PACS3

Selenium (Se)

Silver (Ag)

Strontium (Sr)

Thallium (Tl)

Tin (Sn)

Uranium (U)

Vanadium (V)

Zinc (Zn)

Aluminum (Al)

Antimony (Sb)

Arsenic (As)

Barium (Ba)

Beryllium (Be)

Bismuth (Bi)

Boron (B)

Cadmium (Cd)

Chromium (Cr)

Cobalt (Co)

Copper (Cu)

Iron (Fe)

Lead (Pb)

Lithium (Li)

Manganese (Mn)

Molybdenum (Mo)

Nickel (Ni)

Selenium (Se)

Silver (Ag)

Strontium (Sr)

Thallium (Tl)

Tin (Sn)

Vanadium (V)

Zinc (Zn)

Aluminum (Al)

103.6

95.0

101.3

102.6

87.5

106.9

99.9

101.3

98.1

98.3

100.4

89.0

95.5

99.5

100.5

98.1

101.0

101.3

100.8

99.1

102.6

92.0

97.2

108.2

101.6

101.4

100.2

111.7

102.6

103.0

103.0

100.8

96.4

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

14




R3241321BatchCRM

LCS

WG2141475-5

WG2141475-3

VA-NRC-PACS3Antimony (Sb)

Arsenic (As)

Barium (Ba)

Beryllium (Be)

Boron (B)

Cadmium (Cd)

Chromium (Cr)

Cobalt (Co)

Copper (Cu)

Iron (Fe)

Lead (Pb)

Lithium (Li)

Manganese (Mn)

Molybdenum (Mo)

Nickel (Ni)

Selenium (Se)

Silver (Ag)

Strontium (Sr)

Thallium (Tl)

Tin (Sn)

Uranium (U)

Vanadium (V)

Zinc (Zn)

Aluminum (Al)

Antimony (Sb)

Arsenic (As)

Barium (Ba)

Beryllium (Be)

Bismuth (Bi)

Boron (B)

Cadmium (Cd)

Chromium (Cr)

Cobalt (Co)

87.2

91.7

87.5

98.7

96.4

95.3

96.2

97.7

99.5

97.9

101.1

92.2

92.6

97.8

99.4

104.6

94.7

109.2

99.8

85.5

106.0

97.1

101.8

95.5

94.1

101.4

96.2

94.9

100.4

88.8

104.1

100.4

99.5

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

14




R3241321BatchLCS

MB

WG2141475-3

WG2141453-1

Copper (Cu)

Iron (Fe)

Lead (Pb)

Lithium (Li)

Manganese (Mn)

Molybdenum (Mo)

Nickel (Ni)

Selenium (Se)

Silver (Ag)

Strontium (Sr)

Thallium (Tl)

Tin (Sn)

Uranium (U)

Vanadium (V)

Zinc (Zn)

Aluminum (Al)

Antimony (Sb)

Arsenic (As)

Barium (Ba)

Beryllium (Be)

Bismuth (Bi)

Boron (B)

Cadmium (Cd)

Chromium (Cr)

Cobalt (Co)

Copper (Cu)

Iron (Fe)

Lead (Pb)

Lithium (Li)

Manganese (Mn)

Molybdenum (Mo)

Nickel (Ni)

Selenium (Se)

98.7

109.2

104.2

90.5

100.9

109.0

100.2

102.6

93.5

112.4

101.9

102.5

105.9

102.0

97.1

<50

<0.10

<0.10

<0.50

<0.10

<0.20

<5.0

<0.020

<0.50

<0.10

<0.50

<50

<0.50

<2.0

<1.0

<0.10

<0.50

<0.20

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

50

0.1

0.1

0.5

0.1

0.2

5

0.02

0.5

0.1

0.5

50

0.5

2

1

0.1

0.5

0.2

14




R3241321BatchMB

MB

WG2141453-1

WG2141475-1

Silver (Ag)

Strontium (Sr)

Thallium (Tl)

Tin (Sn)

Uranium (U)

Vanadium (V)

Zinc (Zn)

Aluminum (Al)

Antimony (Sb)

Arsenic (As)

Barium (Ba)

Beryllium (Be)

Bismuth (Bi)

Boron (B)

Cadmium (Cd)

Chromium (Cr)

Cobalt (Co)

Copper (Cu)

Iron (Fe)

Lead (Pb)

Lithium (Li)

Manganese (Mn)

Molybdenum (Mo)

Nickel (Ni)

Selenium (Se)

Silver (Ag)

Strontium (Sr)

Thallium (Tl)

Tin (Sn)

Uranium (U)

Vanadium (V)

Zinc (Zn)

<0.10

<0.50

<0.050

<2.0

<0.050

<0.20

<2.0

<50

<0.10

<0.10

<0.50

<0.10

<0.20

<5.0

<0.020

<0.50

<0.10

<0.50

<50

<0.50

<2.0

<1.0

<0.10

<0.50

<0.20

<0.10

<0.50

<0.050

<2.0

<0.050

<0.20

<2.0

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

04-AUG-15

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

0.1

0.5

0.05

2

0.05

0.2

2

50

0.1

0.1

0.5

0.1

0.2

5

0.02

0.5

0.1

0.5

50

0.5

2

1

0.1

0.5

0.2

0.1

0.5

0.05

2

0.05

0.2

2

14




R3242322BatchCRM

CRM

WG2144236-4

WG2144236-5

VA-NRC-STSD1

VA-NRC-PACS3

Aluminum (Al)

Antimony (Sb)

Arsenic (As)

Barium (Ba)

Beryllium (Be)

Bismuth (Bi)

Boron (B)

Cadmium (Cd)

Chromium (Cr)

Cobalt (Co)

Copper (Cu)

Iron (Fe)

Lead (Pb)

Lithium (Li)

Manganese (Mn)

Molybdenum (Mo)

Nickel (Ni)

Selenium (Se)

Silver (Ag)

Strontium (Sr)

Thallium (Tl)

Tin (Sn)

Vanadium (V)

Zinc (Zn)

Aluminum (Al)

Antimony (Sb)

Arsenic (As)

Barium (Ba)

Beryllium (Be)

Boron (B)

Cadmium (Cd)

Chromium (Cr)

Cobalt (Co)

108.9

107.9

106.7

99.7

101.4

104.2

111.4

102.5

108.4

104.8

103.5

105.7

106.5

91.4

101.0

115.3

106.1

108.2

106.5

120.4

104.7

110.8

113.1

105.5

104.2

93.2

89.9

98.2

93.9

96.4

95.4

96.8

95.8

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

14




R3242322BatchCRM

DUP

WG2144236-5

WG2144236-2

VA-NRC-PACS3

L1651409-13

Copper (Cu)

Iron (Fe)

Lead (Pb)

Lithium (Li)

Manganese (Mn)

Molybdenum (Mo)

Nickel (Ni)

Selenium (Se)

Silver (Ag)

Strontium (Sr)

Thallium (Tl)

Tin (Sn)

Uranium (U)

Vanadium (V)

Zinc (Zn)

Aluminum (Al)

Antimony (Sb)

Arsenic (As)

Barium (Ba)

Beryllium (Be)

Bismuth (Bi)

Boron (B)

Cadmium (Cd)

Chromium (Cr)

Cobalt (Co)

Copper (Cu)

Iron (Fe)

Lead (Pb)

Lithium (Li)

Manganese (Mn)

Molybdenum (Mo)

Nickel (Ni)

Selenium (Se)

96.4

100.0

97.6

84.1

95.9

95.4

98.5

102.3

97.3

107.9

95.6

88.4

102.5

100.0

100.2

10800

0.19

3.21

43.9

0.16

<0.20

<5.0

0.138

20.3

7.80

21.5

19800

3.25

7.2

352

0.34

22.1

<0.20

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

7.8

13

7.1

0.8

4.0

N/A

N/A

4.0

1.2

1.7

11

8.3

3.2

1.7

1.1

28

1.0

N/A

40

30

30

40

30

30

30

30

30

30

30

30

40

30

30

40

30

30

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

RPD-NA

RPD-NA

RPD-NA

10000

0.22

3.45

44.3

0.15

<0.20

<5.0

0.144

20.6

7.94

19.2

18200

3.35

7.0

348

0.45

22.4

<0.20

14




R3242322BatchDUP

LCS

MB

WG2144236-2

WG2144236-3

WG2144236-1

L1651409-13Silver (Ag)

Strontium (Sr)

Thallium (Tl)

Tin (Sn)

Uranium (U)

Vanadium (V)

Zinc (Zn)

Aluminum (Al)

Antimony (Sb)

Arsenic (As)

Barium (Ba)

Beryllium (Be)

Bismuth (Bi)

Boron (B)

Cadmium (Cd)

Chromium (Cr)

Cobalt (Co)

Copper (Cu)

Iron (Fe)

Lead (Pb)

Lithium (Li)

Manganese (Mn)

Molybdenum (Mo)

Nickel (Ni)

Selenium (Se)

Silver (Ag)

Strontium (Sr)

Thallium (Tl)

Tin (Sn)

Uranium (U)

Vanadium (V)

Zinc (Zn)

Aluminum (Al)

<0.10

29.0

<0.050

<2.0

0.219

50.9

44.5

103.3

101.3

97.7

100.2

93.1

98.5

84.9

104.0

100.9

100.1

97.5

102.8

102.7

83.4

100.8

104.7

100.3

99.7

97.9

109.3

97.0

97.9

101.4

106.0

97.4

<50

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

N/A

0.9

N/A

N/A

12

11

1.1

40

40

30

40

30

30

30

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

mg/kg 50

RPD-NA

RPD-NA

RPD-NA

<0.10

28.7

<0.050

<2.0

0.247

45.5

45.0

14



MET-200.2-CCMS-VA

MOISTURE-VA

PAH-TMB-H/A-MS-VA

Soil

Soil

Soil

R3242322

R3237047

R3238630

Batch

Batch

Batch

MB

LCS

MB

IRM

WG2144236-1

WG2141467-2

WG2141467-1

WG2142525-4 ALS PAH1 RM

Antimony (Sb)

Arsenic (As)

Barium (Ba)

Beryllium (Be)

Bismuth (Bi)

Boron (B)

Cadmium (Cd)

Chromium (Cr)

Cobalt (Co)

Copper (Cu)

Iron (Fe)

Lead (Pb)

Lithium (Li)

Manganese (Mn)

Molybdenum (Mo)

Nickel (Ni)

Selenium (Se)

Silver (Ag)

Strontium (Sr)

Thallium (Tl)

Tin (Sn)

Uranium (U)

Vanadium (V)

Zinc (Zn)

Moisture

Moisture

Acenaphthene

Acenaphthylene

<0.10

<0.10

<0.50

<0.10

<0.20

<5.0

<0.020

<0.50

<0.10

<0.50

<50

<0.50

<2.0

<1.0

<0.10

<0.50

<0.20

<0.10

<0.50

<0.050

<2.0

<0.050

<0.20

<2.0

100.1

<0.25

103.5

122.7

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

07-AUG-15

01-AUG-15

01-AUG-15

05-AUG-15

05-AUG-15

90-110

60-130

60-130

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

%

%

%

%

0.1

0.1

0.5

0.1

0.2

5

0.02

0.5

0.1

0.5

50

0.5

2

1

0.1

0.5

0.2

0.1

0.5

0.05

2

0.05

0.2

2

0.25

14



PAH-TMB-H/A-MS-VA Soil

R3238630BatchIRM

MB

WG2142525-4

WG2142525-1

ALS PAH1 RMAnthracene

Benz(a)anthracene

Benzo(a)pyrene

Benzo(b)fluoranthene

Benzo(g,h,i)perylene

Benzo(k)fluoranthene

Chrysene

Dibenz(a,h)anthracene

Fluoranthene

Fluorene

Indeno(1,2,3-c,d)pyrene

2-Methylnaphthalene

Naphthalene

Phenanthrene

Pyrene

Acenaphthene

Acenaphthylene

Anthracene

Benz(a)anthracene

Benzo(a)pyrene




Chrysene


Fluoranthene

Fluorene


2-Methylnaphthalene

Naphthalene

Phenanthrene

Pyrene

Surrogate: Naphthalene d8

118.4

119.6

108.2

116.0

127.2

123.9

118.2

119.1

110.4

102.3

119.6

115.3

124.1

111.1

111.2

<0.0050

<0.0050

<0.0040

<0.010

<0.010

<0.010

<0.010

<0.010

<0.010

<0.0050

<0.010

<0.010

<0.010

<0.010

<0.010

<0.010

<0.010

85.5

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

60-130

60-130

60-130

60-130

60-130

60-130

60-130

60-130

60-130

60-130

60-130

60-130

50-130

60-130

60-130

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

%

0.005

0.005

0.004

0.01

0.01

0.01

0.01

0.01

0.01

0.005

0.01

0.01

0.01

0.01

0.01

0.01

0.01

50-130

14



PAH-TMB-H/A-MS-VA Soil

R3238630

R3239587

Batch

Batch

MB

IRM

MB

WG2142525-1

WG2141464-4

WG2141464-1

ALS PAH1 RM

Surrogate: Acenaphthene d10

Surrogate: Phenanthrene d10

Surrogate: Chrysene d12

Acenaphthene

Acenaphthylene

Anthracene

Benz(a)anthracene

Benzo(a)pyrene




Chrysene


Fluoranthene

Fluorene


2-Methylnaphthalene

Naphthalene

Phenanthrene

Pyrene

Acenaphthene

Acenaphthylene

Anthracene

Benz(a)anthracene

Benzo(a)pyrene




Chrysene


Fluoranthene

Fluorene

85.9

85.7

94.0

89.3

111.0

107.9

102.4

104.3

119.3

88.7

120.9

116.7

100.9

115.2

90.7

97.5

113.4

119.3

95.5

112.7

<0.0050

<0.0050

<0.0040

<0.010

<0.010

<0.010

<0.010

<0.010

<0.010

<0.0050

<0.010

<0.010

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

60-130

60-130

60-130

60-130

60-130

60-130

60-130

60-130

60-130

60-130

60-130

60-130

60-130

60-130

50-130

60-130

60-130

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

60-130

60-130

60-130

0.005

0.005

0.004

0.01

0.01

0.01

0.01

0.01

0.01

0.005

0.01

0.01

14



PAH-TMB-H/A-MS-VA

PH-1:2-VA

Soil

Soil

R3239587

R3237899

Batch

Batch

MB

DUP

WG2141464-1

WG2141475-2 L1651409-13


2-Methylnaphthalene

Naphthalene

Phenanthrene

Pyrene

Surrogate: Naphthalene d8

Surrogate: Acenaphthene d10

Surrogate: Phenanthrene d10

Surrogate: Chrysene d12

pH (1:2 soil:water)

<0.010

<0.010

<0.010

<0.010

<0.010

98.8

97.9

90.0

85.7

6.49

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

05-AUG-15

04-AUG-150.03 0.3

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

%

%

%

%

pH

0.01

0.01

0.01

0.01

0.01

50-130

60-130

60-130

60-130

J6.52

14




J

RPD-NA

Duplicate results and limits are expressed in terms of absolute difference.

Relative Percent Difference Not Available due to result(s) being less than detection limit.


Legend:






14


31-JUL-15




ATTN: Ann-Marie NorrisFINAL REV. 201-DEC-15 17:03 (MT)Report Date:

Version:



____________________________________________




1-DEC-2015 The list of reported Metals has been adjusted.Comments:

13-1422-0049/16000/16120Job Reference: NOT SUBMITTEDProject P.O. #:

14-475218, 14-475219C of C Numbers:Legal Site Desc:

01-DEC-15 17:03 (MT)


Client ID

Sampled Date

Grouping Analyte

Sampled Time


L1651410 CONTD....

2PAGE of


11

TISSUE

Tissue Tissue Tissue Tissue Tissue31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15

15-TILBURY-B-1 15-TILBURY-B-1D 15-TILBURY-B-2 15-TILBURY-B-3 15-TILBURY-B-4

L1651410-1 L1651410-2 L1651410-3 L1651410-4 L1651410-5

% Moisture (%)





































86.8 85.6 84.4 87.4 83.0

29.7 42.8 10.7 20.8 29.8

3.94 6.16 1.67 2.62 5.06

<0.010 <0.010 <0.010 <0.010 <0.010

<0.0020 <0.0020 <0.0020 <0.0020 <0.0020

<0.020 0.025 <0.020 0.021 <0.020

<0.0040 <0.0040 <0.0040 <0.0040 <0.0040

12.3 7.58 7.43 21.8 4.16

1.64 1.09 1.16 2.75 0.706

<0.010 <0.010 <0.010 <0.010 <0.010

<0.0020 <0.0020 <0.0020 <0.0020 <0.0020

<0.010 <0.010 <0.010 <0.010 <0.010

<0.0020 <0.0020 <0.0020 <0.0020 <0.0020

18.6 14.3 12.4 13.5 11.1

2.46 2.05 1.92 1.70 1.88

0.0709 0.0514 0.0408 0.128 0.0228

0.0094 0.0074 0.0064 0.0161 0.0039

0.076 0.089 <0.050 0.063 0.056

0.010 0.013 <0.010 <0.010 <0.010

0.110 0.130 0.032 0.152 0.047

0.0145 0.0188 0.0050 0.0192 0.0080

10.6 10.0 8.16 7.12 5.04

1.40 1.44 1.27 0.898 0.855

53.9 64.1 27.4 40.6 46.1

7.15 9.22 4.26 5.12 7.82

0.029 0.035 <0.020 0.042 0.047

<0.0040 0.0051 <0.0040 0.0052 0.0080

<0.50 <0.50 <0.50 <0.50 <0.50

<0.10 <0.10 <0.10 <0.10 <0.10

22.6 18.7 10.5 66.3 20.5

2.99 2.69 1.64 8.37 3.48

0.0059 <0.0050 <0.0050 <0.0050 <0.0050

<0.0010 <0.0010 <0.0010 <0.0010 <0.0010

0.540 0.601 0.462 0.159 0.207

0.0716 0.0864 0.0719 0.0201 0.0351

2.07 1.88 1.31 4.63 1.69

0.275 0.270 0.204 0.585 0.287

Physical Tests

Metals

01-DEC-15 17:03 (MT)


Client ID

Sampled Date

Grouping Analyte

Sampled Time


L1651410 CONTD....

3PAGE of


11

TISSUE


15-TILBURY-B-5 15-TILBURY-B-6 15-TILBURY-B-7 15-TILBURY-B-8 15-TILBURY-B-8D

L1651410-6 L1651410-7 L1651410-8 L1651410-9 L1651410-10

% Moisture (%)





































83.9 85.5 82.9 87.6 84.6

11.8 18.6 14.5 3.7 5.0

1.90 2.71 2.49 0.46 0.76

<0.010 <0.010 <0.010 <0.010 <0.010

<0.0020 <0.0020 <0.0020 <0.0020 <0.0020

<0.020 <0.020 <0.020 <0.020 <0.020

<0.0040 <0.0040 <0.0040 <0.0040 <0.0040

4.01 7.76 2.46 3.53 3.93

0.646 1.13 0.422 0.437 0.604

<0.010 <0.010 <0.010 <0.010 <0.010

<0.0020 <0.0020 <0.0020 <0.0020 <0.0020

<0.010 <0.010 <0.010 <0.010 <0.010

<0.0020 <0.0020 <0.0020 <0.0020 <0.0020

11.5 13.1 12.5 18.9 15.4

1.84 1.90 2.15 2.33 2.37

0.0159 0.0185 0.0505 0.0214 0.0350

0.0026 0.0027 0.0087 0.0026 0.0054

<0.050 0.054 <0.050 <0.050 <0.050

<0.010 <0.010 <0.010 <0.010 <0.010

0.029 0.074 0.039 <0.020 <0.020

0.0047 0.0108 0.0068 <0.0040 <0.0040

5.60 5.64 6.68 8.19 9.32

0.902 0.820 1.14 1.01 1.43

37.1 43.9 34.0 38.0 35.5

5.97 6.39 5.82 4.70 5.46

0.032 0.038 <0.020 <0.020 <0.020

0.0051 0.0055 <0.0040 <0.0040 <0.0040

<0.50 <0.50 <0.50 <0.50 <0.50

<0.10 <0.10 <0.10 <0.10 <0.10

29.7 44.9 22.3 19.1 17.9

4.78 6.53 3.81 2.36 2.76

<0.0050 <0.0050 <0.0050 <0.0050 0.0052

<0.0010 <0.0010 <0.0010 <0.0010 <0.0010

0.115 0.350 0.161 0.759 0.317

0.0185 0.0509 0.0275 0.0939 0.0488

2.05 3.80 2.18 1.50 1.39

0.329 0.553 0.374 0.186 0.214

Physical Tests

Metals

01-DEC-15 17:03 (MT)


Client ID

Sampled Date

Grouping Analyte

Sampled Time


L1651410 CONTD....

4PAGE of


11

TISSUE


15-TILBURY-B-9 15-TILBURY-B-10 15-TILBURY-B-11 15-TILBURY-B-12 15-TILBURY-B-13

L1651410-11 L1651410-12 L1651410-13 L1651410-14 L1651410-15

% Moisture (%)





































86.4 84.2 78.9 87.2 85.6

7.6 26.8 55.0 12.8 15.3

1.04 4.23 11.6 1.63 2.21

<0.010 0.014 0.014 <0.010 <0.010

<0.0020 0.0022 0.0030 <0.0020 <0.0020

<0.020 0.026 0.051 0.036 <0.020

<0.0040 0.0041 0.0107 0.0046 <0.0040

4.38 2.17 1.91 4.37 2.19

0.594 0.342 0.404 0.557 0.317

<0.010 <0.010 <0.010 <0.010 <0.010

<0.0020 <0.0020 <0.0020 <0.0020 <0.0020

<0.010 <0.010 <0.010 <0.010 <0.010

<0.0020 <0.0020 <0.0020 <0.0020 <0.0020

13.7 12.6 10.4 17.1 13.4

1.86 1.98 2.20 2.18 1.94

0.0138 0.0092 0.0208 0.0340 0.0197

0.0019 0.0015 0.0044 0.0043 0.0028

<0.050 0.062 0.078 0.068 <0.050

<0.010 <0.010 0.016 <0.010 <0.010

0.030 0.047 0.046 0.070 0.072

0.0040 0.0075 0.0098 0.0089 0.0104

8.47 7.01 7.42 7.65 6.11

1.15 1.11 1.57 0.975 0.882

35.7 45.0 75.0 29.0 34.1

4.85 7.10 15.9 3.70 4.93

<0.020 0.044 0.270 <0.020 0.029

<0.0040 0.0069 0.0571 <0.0040 0.0041

<0.50 <0.50 <0.50 <0.50 <0.50

<0.10 <0.10 <0.10 <0.10 <0.10

17.7 9.93 13.0 13.0 12.0

2.41 1.57 2.75 1.66 1.74

<0.0050 <0.0050 <0.0050 <0.0050 <0.0050

<0.0010 <0.0010 <0.0010 <0.0010 <0.0010

0.342 0.599 0.427 0.542 0.270

0.0464 0.0945 0.0902 0.0692 0.0389

1.33 0.62 0.74 2.23 2.56

0.181 0.097 0.155 0.284 0.370

Physical Tests

Metals

01-DEC-15 17:03 (MT)


Client ID

Sampled Date

Grouping Analyte

Sampled Time


L1651410 CONTD....

5PAGE of


11

TISSUE

Tissue Tissue31-JUL-15 31-JUL-15

15-TILBURY-B-14 15-TILBURY-B-15

L1651410-16 L1651410-17

% Moisture (%)





































86.2 87.0

9.9 17.0

1.37 2.22

<0.010 <0.010

<0.0020 <0.0020

<0.020 <0.020

<0.0040 <0.0040

14.5 3.00

2.00 0.391

<0.010 <0.010

<0.0020 <0.0020

<0.010 <0.010

<0.0020 <0.0020

15.0 19.7

2.07 2.57

0.146 0.0801

0.0202 0.0105

<0.050 <0.050

<0.010 <0.010

1.03 0.425

0.142 0.0554

8.04 12.1

1.11 1.58

29.5 50.8

4.07 6.63

0.026 0.031

<0.0040 0.0041

<0.50 <0.50

<0.10 <0.10

64.7 40.9

8.94 5.34

0.0052 0.0063

<0.0010 <0.0010

0.217 0.147

0.0300 0.0192

6.48 6.67

0.896 0.870

Physical Tests

Metals

01-DEC-15 17:03 (MT)


Client ID

Sampled Date

Grouping Analyte

Sampled Time


L1651410 CONTD....

6PAGE of


11

TISSUE


15-TILBURY-B-1 15-TILBURY-B-1D 15-TILBURY-B-2 15-TILBURY-B-3 15-TILBURY-B-4

L1651410-1 L1651410-2 L1651410-3 L1651410-4 L1651410-5

















<0.050 <0.050 <0.050 <0.050 0.051

<0.010 <0.010 <0.010 <0.010 <0.010

<0.0050 <0.0050 <0.0050 <0.0050 <0.0050

<0.0010 <0.0010 <0.0010 <0.0010 <0.0010

15.9 11.7 11.7 16.5 11.5

2.11 1.68 1.82 2.09 1.96

<0.0020 <0.0020 <0.0020 <0.0020 <0.0020

<0.00040 <0.00040 <0.00040 <0.00040 <0.00040

0.52 0.77 0.33 0.42 0.37

0.069 0.111 0.052 0.052 0.063

<0.0020 0.0024 <0.0020 <0.0020 <0.0020

<0.00040 <0.00040 <0.00040 <0.00040 <0.00040

<0.10 0.10 <0.10 <0.10 <0.10

<0.020 <0.020 <0.020 <0.020 <0.020

18.4 14.8 18.3 13.4 10.2

2.44 2.12 2.86 1.69 1.73

Metals

01-DEC-15 17:03 (MT)


Client ID

Sampled Date

Grouping Analyte

Sampled Time


L1651410 CONTD....

7PAGE of


11

TISSUE


15-TILBURY-B-5 15-TILBURY-B-6 15-TILBURY-B-7 15-TILBURY-B-8 15-TILBURY-B-8D

L1651410-6 L1651410-7 L1651410-8 L1651410-9 L1651410-10

















<0.050 <0.050 <0.050 <0.050 <0.050

<0.010 <0.010 <0.010 <0.010 <0.010

<0.0050 <0.0050 <0.0050 <0.0050 <0.0050

<0.0010 <0.0010 <0.0010 <0.0010 <0.0010

11.5 14.0 6.08 11.0 11.2

1.86 2.03 1.04 1.36 1.73

<0.0020 <0.0020 <0.0020 <0.0020 <0.0020

<0.00040 <0.00040 <0.00040 <0.00040 <0.00040

0.84 0.83 0.43 0.94 0.61

0.135 0.121 0.073 0.117 0.094

<0.0020 <0.0020 <0.0020 <0.0020 <0.0020

<0.00040 <0.00040 <0.00040 <0.00040 <0.00040

<0.10 <0.10 <0.10 <0.10 <0.10

<0.020 <0.020 <0.020 <0.020 <0.020

11.4 10.7 13.8 15.0 17.0

1.84 1.55 2.36 1.86 2.62

Metals

01-DEC-15 17:03 (MT)


Client ID

Sampled Date

Grouping Analyte

Sampled Time


L1651410 CONTD....

8PAGE of


11

TISSUE


15-TILBURY-B-9 15-TILBURY-B-10 15-TILBURY-B-11 15-TILBURY-B-12 15-TILBURY-B-13

L1651410-11 L1651410-12 L1651410-13 L1651410-14 L1651410-15

















<0.050 <0.050 <0.050 <0.050 <0.050

<0.010 <0.010 <0.010 <0.010 <0.010

<0.0050 <0.0050 <0.0050 <0.0050 <0.0050

<0.0010 <0.0010 <0.0010 <0.0010 <0.0010

11.1 8.34 6.24 21.0 7.72

1.51 1.32 1.32 2.67 1.11

<0.0020 <0.0020 <0.0020 <0.0020 <0.0020

<0.00040 <0.00040 <0.00040 <0.00040 <0.00040

0.33 0.47 0.42 0.73 1.21

0.045 0.075 0.088 0.093 0.175

<0.0020 <0.0020 0.0033 <0.0020 <0.0020

<0.00040 <0.00040 0.00069 <0.00040 <0.00040

<0.10 <0.10 0.11 <0.10 <0.10

<0.020 <0.020 0.023 <0.020 <0.020

15.3 10.4 13.4 12.5 11.9

2.08 1.65 2.83 1.59 1.72

Metals

01-DEC-15 17:03 (MT)


Client ID

Sampled Date

Grouping Analyte

Sampled Time


L1651410 CONTD....

9PAGE of


11

TISSUE

Tissue Tissue31-JUL-15 31-JUL-15

15-TILBURY-B-14 15-TILBURY-B-15

L1651410-16 L1651410-17

















<0.050 <0.050

<0.010 <0.010

0.0055 <0.0050

<0.0010 <0.0010

20.8 10.1

2.87 1.32

<0.0020 <0.0020

<0.00040 <0.00040

0.53 0.59

0.073 0.077

<0.0020 <0.0020

<0.00040 <0.00040

<0.10 <0.10

<0.020 <0.020

14.6 23.8

2.01 3.11

Metals


L1651410 CONTD....

10PAGE of

AG-DRY-CCMS-N-VA

AG-WET-CCMS-N-VA

HG-DRY-CVAFS-N-VA

HG-WET-CVAFS-N-VA

MET-DRY-CCMS-N-VA

MET-WET-CCMS-N-VA

MOISTURE-TISS-VA

Silver in Tissue by CRC ICPMS (DRY)

Silver in Tissue by CRC ICPMS (WET)

Mercury in Tissue by CVAFS (DRY)

Mercury in Tissue by CVAFS (WET)

Metals in Tissue by CRC ICPMS (DRY)

Metals in Tissue by CRC ICPMS (WET)

% Moisture in Tissues













Tissue

Tissue

Tissue

Tissue

Tissue

Tissue

Tissue

EPA 200.3/6020A

EPA 200.3/6020A

EPA 200.3, EPA 245.7

EPA 200.3, EPA 245.7

EPA 200.3/6020A

EPA 200.3/6020A


Method Reference**


Matrix





14-475218 14-475219


11


L1651410 CONTD....

11PAGE of




11


Client:

Contact:

GOLDER ASSOCIATES LTD. 200-2920 Virtual Way Vancouver BC V5M 0C4Ann-Marie Norris

Report Date: 01-DEC-15Workorder: L1651410


AG-DRY-CCMS-N-VA

AG-WET-CCMS-N-VA

HG-DRY-CVAFS-N-VA

HG-WET-CVAFS-N-VA

Tissue

Tissue

Tissue

Tissue

R3252602

R3253959

R3252602

R3253959

R3253404

R3253402

Batch

Batch

Batch

Batch

Batch

Batch

CRM

MB

DUP

LCS

CRM

MB

DUP

LCS

CRM

CRM

DUP

LCS

MB

CRM

CRM

WG2154708-3

WG2154708-1

WG2154708-2

WG2154708-5

WG2154708-3

WG2154708-1

WG2154708-2

WG2154708-5

WG2154708-3

WG2154708-4

WG2154708-2

WG2154708-5

WG2154708-1

WG2154708-3

WG2154708-4

VA-NIST-1566B

L1651410-1

VA-NIST-1566B

L1651410-1

VA-NIST-1566B

VA-NIST-1547

L1651410-1

VA-NIST-1566B

VA-NIST-1547

Silver (Ag)-Total

Silver (Ag)-Total

Silver (Ag)-Total

Silver (Ag)-Total

Silver (Ag)-Total

Silver (Ag)-Total

Silver (Ag)-Total

Silver (Ag)-Total

Mercury (Hg)-Total

Mercury (Hg)-Total

Mercury (Hg)-Total

Mercury (Hg)-Total

Mercury (Hg)-Total

Mercury (Hg)-Total

Mercury (Hg)-Total

76.8

<0.0050

<0.0050

96.9

76.8

<0.0010

<0.0010

96.9

101.1

102.6

0.0054

104.4

<0.0050

101.1

102.6

24-AUG-15

24-AUG-15

25-AUG-15

25-AUG-15

24-AUG-15

24-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

N/A

N/A

9.4

40

40

40

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

%

mg/kg

mg/kg

%

%

mg/kg wwt

mg/kg wwt

%

%

%

mg/kg

%

mg/kg

%

%

0.005

0.001

0.005

RPD-NA

RPD-NA

<0.0050

<0.0010

0.0059

10



HG-WET-CVAFS-N-VA

MET-DRY-CCMS-N-VA

Tissue

Tissue

R3253402

R3252602

Batch

Batch

DUP

LCS

MB

CRM

MB

WG2154708-2

WG2154708-5

WG2154708-1

WG2154708-3

WG2154708-1

L1651410-1

VA-NIST-1566B

Mercury (Hg)-Total

Mercury (Hg)-Total

Mercury (Hg)-Total

Arsenic (As)-Total

Barium (Ba)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total



Nickel (Ni)-Total

Selenium (Se)-Total


Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total

Aluminum (Al)-Total

Antimony (Sb)-Total

Arsenic (As)-Total

Barium (Ba)-Total


Bismuth (Bi)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Chromium (Cr)-Total

<0.0010

104.4

<0.0010

95.0

91.8

93.4

98.0

92.5

89.7

93.3

94.8

94.4

96.9

97.7

98.4

98.9

88.5

89.8

99.7

95.9

<2.0

<0.010

<0.020

<0.050

<0.010

<0.010

<1.0

<0.0050

<0.050

25-AUG-15

25-AUG-15

25-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

N/A 40

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

mg/kg wwt

%

mg/kg wwt

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

0.001

2

0.01

0.02

0.05

0.01

0.01

1

0.005

0.05

RPD-NA<0.0010

10




R3252602

R3253274

Batch

Batch

MB

CRM

CRM

WG2154708-1

WG2154708-3

WG2154708-4

VA-NIST-1566B

VA-NIST-1547

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total

Lithium (Li)-Total



Nickel (Ni)-Total

Selenium (Se)-Total


Thallium (Tl)-Total

Tin (Sn)-Total

Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total

Antimony (Sb)-Total

Aluminum (Al)-Total

Antimony (Sb)-Total

Arsenic (As)-Total

Barium (Ba)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total



Nickel (Ni)-Total

Selenium (Se)-Total


<0.020

<0.10

<3.0

<0.020

<0.50

<0.050

<0.020

<0.20

<0.050

<0.050

<0.0020

<0.10

<0.0020

<0.10

<0.50

0.008

106.0

0.019

0.061

88.5

80.4

90.4

85.2

0.050

98.2

93.6

92.5

90.4

0.044

0.41

0.116

94.0

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

0-0.018

70-130

0.01-0.03

0.04-0.08

70-130

70-130

70-130

70-130

0.034-0.074

70-130

70-130

70-130

70-130

0.026-0.066

0.27-0.67

0.07-0.17

70-130

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

%

mg/kg

mg/kg

%

%

%

%

mg/kg

%

%

%

%

mg/kg

mg/kg

mg/kg

%

0.02

0.1

3

0.02

0.5

0.05

0.02

0.2

0.05

0.05

0.002

0.1

0.002

0.1

0.5

10




R3253274

R3253959

Batch

Batch

CRM

DUP

LCS

WG2154708-4

WG2154708-2

WG2154708-5

VA-NIST-1547

L1651410-1

Thallium (Tl)-Total

Tin (Sn)-Total

Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total

Aluminum (Al)-Total

Antimony (Sb)-Total

Arsenic (As)-Total

Barium (Ba)-Total


Bismuth (Bi)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total

Lithium (Li)-Total



Nickel (Ni)-Total

Selenium (Se)-Total


Thallium (Tl)-Total

Tin (Sn)-Total

Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total

Aluminum (Al)-Total

Antimony (Sb)-Total

Arsenic (As)-Total

101.2

0.10

85.7

0.25

102.0

33.2

<0.010

<0.020

12.3

<0.010

<0.010

18.1

0.0708

0.070

0.110

9.45

53.8

0.028

<0.50

21.6

0.471

2.03

<0.050

15.2

<0.0020

0.46

<0.0020

<0.10

17.4

99.6

101.9

100.9

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

11

N/A

N/A

0.5

N/A

N/A

2.4

0.2

7.3

0.1

11

0.3

5.4

N/A

4.4

14

2.2

N/A

4.9

N/A

12

N/A

N/A

5.5

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

60

40

40

40

40

40

70-130

0.01-0.21

70-130

0.17-0.37

70-130

70-130

70-130

70-130

%

mg/kg

%

mg/kg

%

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

%

%

%

RPD-NA

RPD-NA

RPD-NA

RPD-NA

RPD-NA

RPD-NA

RPD-NA

RPD-NA

RPD-NA

29.7

<0.010

<0.020

12.3

<0.010

<0.010

18.6

0.0709

0.076

0.110

10.6

53.9

0.029

<0.50

22.6

0.540

2.07

<0.050

15.9

<0.0020

0.52

<0.0020

<0.10

18.4

10



MET-DRY-CCMS-N-VA

MET-WET-CCMS-N-VA

Tissue

Tissue

R3253959

R3252602

Batch

Batch

LCS

CRM

WG2154708-5

WG2154708-3 VA-NIST-1566B

Barium (Ba)-Total


Bismuth (Bi)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total

Lithium (Li)-Total



Nickel (Ni)-Total

Selenium (Se)-Total


Thallium (Tl)-Total

Tin (Sn)-Total

Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total

Arsenic (As)-Total

Barium (Ba)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total


102.1

100.7

98.5

93.7

100.0

99.6

98.9

96.9

95.4

98.0

100.9

100.6

101.0

99.9

103.0

95.8

96.6

101.3

97.5

101.3

92.4

95.0

91.8

93.4

98.0

92.5

89.7

93.3

94.8

94.4

96.9

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

10




R3252602BatchCRM

MB

WG2154708-3

WG2154708-1

VA-NIST-1566BMolybdenum (Mo)-Total

Nickel (Ni)-Total

Selenium (Se)-Total


Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total

Aluminum (Al)-Total

Antimony (Sb)-Total

Arsenic (As)-Total

Barium (Ba)-Total


Bismuth (Bi)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total

Lithium (Li)-Total



Nickel (Ni)-Total

Selenium (Se)-Total


Thallium (Tl)-Total

Tin (Sn)-Total

Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total

97.7

98.4

98.9

88.5

89.8

99.7

95.9

<0.40

<0.0020

<0.0040

<0.010

<0.0020

<0.0020

<0.20

<0.0010

<0.010

<0.0040

<0.020

<0.60

<0.0040

<0.10

<0.010

<0.0040

<0.040

<0.010

<0.010

<0.00040

<0.020

<0.00040

<0.020

<0.10

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

70-130

70-130

70-130

70-130

70-130

70-130

70-130

%

%

%

%

%

%

%

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

0.4

0.002

0.004

0.01

0.002

0.002

0.2

0.001

0.01

0.004

0.02

0.6

0.004

0.1

0.01

0.004

0.04

0.01

0.01

0.0004

0.02

0.0004

0.02

0.1

10




R3253274

R3253959

Batch

Batch

CRM

CRM

DUP

WG2154708-3

WG2154708-4

WG2154708-2

VA-NIST-1566B

VA-NIST-1547

L1651410-1

Antimony (Sb)-Total

Aluminum (Al)-Total

Antimony (Sb)-Total

Arsenic (As)-Total

Barium (Ba)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total



Nickel (Ni)-Total

Selenium (Se)-Total


Thallium (Tl)-Total

Tin (Sn)-Total

Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total

Aluminum (Al)-Total

Antimony (Sb)-Total

Arsenic (As)-Total

Barium (Ba)-Total


Bismuth (Bi)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

0.0078

106.0

0.0194

0.0610

88.5

80.4

90.4

85.2

0.0502

98.2

93.6

92.5

90.4

0.0443

0.414

0.116

94.0

101.2

0.100

85.7

0.251

102.0

4.40

<0.0020

<0.0040

1.63

<0.0020

<0.0020

2.40

0.0094

<0.010

0.0145

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

24-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

11

N/A

N/A

0.5

N/A

N/A

2.4

0.2

N/A

0.1

40

40

40

40

40

40

40

40

40

40

0-0.0177

70-130

0.01-0.03

0.04-0.08

70-130

70-130

70-130

70-130

0.0339-0.073

70-130

70-130

70-130

70-130

0.0264-0.066

0.273-0.673

0.07-0.17

70-130

70-130

0.008-0.208

70-130

0.165-0.365

70-130

mg/kg wwt

%

mg/kg wwt

mg/kg wwt

%

%

%

%

mg/kg wwt

%

%

%

%

mg/kg wwt

mg/kg wwt

mg/kg wwt

%

%

mg/kg wwt

%

mg/kg wwt

%

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

RPD-NA

RPD-NA

RPD-NA

RPD-NA

RPD-NA

3.94

<0.0020

<0.0040

1.64

<0.0020

<0.0020

2.46

0.0094

0.010

0.0145

10




R3253959BatchDUP

LCS

WG2154708-2

WG2154708-5

L1651410-1Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total

Lithium (Li)-Total



Nickel (Ni)-Total

Selenium (Se)-Total


Thallium (Tl)-Total

Tin (Sn)-Total

Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total

Aluminum (Al)-Total

Antimony (Sb)-Total

Arsenic (As)-Total

Barium (Ba)-Total


Bismuth (Bi)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total

Lithium (Li)-Total



Nickel (Ni)-Total

Selenium (Se)-Total


1.25

7.12

<0.0040

<0.10

2.86

0.0624

0.269

<0.010

2.01

<0.00040

0.061

<0.00040

<0.020

2.31

99.6

101.9

100.9

102.1

100.7

98.5

93.7

100.0

99.6

98.9

96.9

95.4

98.0

100.9

100.6

101.0

99.9

103.0

95.8

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

11

0.3

N/A

N/A

4.4

14

2.2

N/A

4.9

N/A

12

N/A

N/A

5.5

40

40

40

40

40

40

40

40

60

40

40

40

40

40

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

70-130

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

mg/kg wwt

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

RPD-NA

RPD-NA

RPD-NA

RPD-NA

RPD-NA

RPD-NA

1.40

7.15

<0.0040

<0.10

2.99

0.0716

0.275

<0.010

2.11

<0.00040

0.069

<0.00040

<0.020

2.44

10



MET-WET-CCMS-N-VA

MOISTURE-TISS-VA

Tissue

Tissue

R3253959

R3250930

Batch

Batch

LCS

DUP

WG2154708-5

WG2152817-1 L1651410-5

Thallium (Tl)-Total

Tin (Sn)-Total

Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total

% Moisture

96.6

101.3

97.5

101.3

92.4

83.6

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

25-AUG-15

19-AUG-150.6 20

70-130

70-130

70-130

70-130

70-130

%

%

%

%

%

%83.0

10




RPD-NA Relative Percent Difference Not Available due to result(s) being less than detection limit.


Legend:






10

September 17, 2015 Analytical Report for Service Request No: K1509391

Ms. Amber SpringerALS Environmental - Canada8081 Lougheed HwyBurnaby, BC V5A 1W9

Analyses were performed according to our laboratory’s NELAP-approved quality assurance program. The test results meet requirements of the current NELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP-accredited analytes, refer to the certifications section at www.alsglobal.com. All results are intended to be considered in their entirety, and ALS Group USA Corp. dba ALS Environmental (ALS) is not responsible for use of less than the complete report. Results apply only to the items submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the report.

For your reference, these analyses have been assigned our service request numberEnclosed are the results of the sample(s) submitted to our laboratory August 26, 2015

RE: L1651410

Dear Ms.Springer,

K1509391.

Please contact me if you have any questions. My extension is 3293. You may also contact me via email at [email protected].

Respectfully submitted,


Shar Samy, Ph.D.Project Manager

ALS Group USA, Corp1317 South 13th AvenueKelso, WA 98626

+1 360 577 7222+1 360 636 1068

T :F :

ALS Environmental

www.alsglobal.com

RIGHT SOLUTIONS | RIGHT PARTNERPage 1 of 64

shar.samy

Shar Samy, Ph.D.

www.alsglobal.com

ALS Environmental

F :T :

+1 360 636 1068+1 360 577 7222

Kelso, WA 986261317 South 13th AvenueALS Group USA, Corp

Table of Contents


Acronyms

Qualifiers

State Certifications, Accreditations, And Licenses

Case Narrative

Chain of Custody

General Chemistry



Page 2 of 64

ASTM American Society for Testing and Materials

A2LA American Association for Laboratory Accreditation

CARB California Air Resources Board

CAS Number Chemical Abstract Service registry Number

CFC Chlorofluorocarbon

CFU Colony-Forming Unit

DEC Department of Environmental Conservation

DEQ Department of Environmental Quality

DHS Department of Health Services

DOE Department of Ecology

DOH Department of Health

EPA U. S. Environmental Protection Agency

ELAP Environmental Laboratory Accreditation Program

GC Gas Chromatography

GC/MS Gas Chromatography/Mass Spectrometry

LOD Limit of Detection

LOQ Limit of Quantitation

LUFT Leaking Underground Fuel Tank

M ModifiedMCL Maximum Contaminant Level is the highest permissible concentration of a substance

allowed in drinking water as established by the USEPA.

MDL Method Detection Limit

MPN Most Probable Number

MRL Method Reporting Limit

NA Not Applicable

NC Not Calculated

NCASI National Council of the Paper Industry for Air and Stream Improvement

ND Not Detected

NIOSH National Institute for Occupational Safety and Health

PQL Practical Quantitation Limit

RCRA Resource Conservation and Recovery Act

SIM Selected Ion Monitoring

TPH Total Petroleum Hydrocarbonstr Trace level is the concentration of an analyte that is less than the PQL but greater than or

equal to the MDL.

Acronyms

Page 3 of 64

Inorganic Data Qualifiers




E The result is an estimate amount because the value exceeded the instrument calibration range.






H The holding time for this test is immediately following sample collection. The samples were analyzed as soon as possible afterreceipt by the laboratory.

Metals Data Qualifiers



E The percent difference for the serial dilution was greater than 10%, indicating a possible matrix interference in the sample.

M The duplicate injection precision was not met.

N The Matrix Spike sample recovery is not within control limits. See case narrative.

S The reported value was determined by the Method of Standard Additions (MSA).


W The post-digestion spike for furnace AA analysis is out of control limits, while sample absorbance is less than 50% of spike absorbance.



+ The correlation coefficient for the MSA is less than 0.995.


Organic Data Qualifiers



A A tentatively identified compound, a suspected aldol-condensation product.


C The analyte was qualitatively confirmed using GC/MS techniques, pattern recognition, or by comparing to historical data.

D The reported result is from a dilution.

E The result is an estimated value.


N The result is presumptive. The analyte was tentatively identified, but a confirmation analysis was not performed.

PThe GC or HPLC confirmation criteria was exceeded. The relative percent difference is greater than 40% between the two analytical results.


i The MRL/MDL or LOQ/LOD is elevated due to a chromatographic interference.



Additional Petroleum Hydrocarbon Specific Qualifiers

F The chromatographic fingerprint of the sample matches the elution pattern of the calibration standard.

L The chromatographic fingerprint of the sample resembles a petroleum product, but the elution pattern indicates the presence of a greater amount of lighter molecular weight constituents than the calibration standard.

H The chromatographic fingerprint of the sample resembles a petroleum product, but the elution pattern indicates the presence of a greater amount of heavier molecular weight constituents than the calibration standard.

O The chromatographic fingerprint of the sample resembles an oil, but does not match the calibration standard.

Y The chromatographic fingerprint of the sample resembles a petroleum product eluting in approximately the correct carbon range, but the elution pattern does not match the calibration standard.

Z The chromatographic fingerprint does not resemble a petroleum product.

Page 4 of 64

Agency Web Site Number

Alaska DEC UST http://dec.alaska.gov/applications/eh/ehllabreports/USTLabs.aspx UST-040

Arizona DHS http://www.azdhs.gov/lab/license/env.htm AZ0339

Arkansas - DEQ http://www.adeq.state.ar.us/techsvs/labcert.htm 88-0637

California DHS (ELAP) http://www.cdph.ca.gov/certlic/labs/Pages/ELAP.aspx 2795

DOD ELAP http://www.denix.osd.mil/edqw/Accreditation/AccreditedLabs.cfm L14-51

Florida DOH http://www.doh.state.fl.us/lab/EnvLabCert/WaterCert.htm E87412

Hawaii DOH Not available -

Idaho DHWhttp://www.healthandwelfare.idaho.gov/Health/Labs/CertificationDrinkingWaterLabs/tabid/1833/Default.aspx -

ISO 17025 http://www.pjlabs.com/ L14-50

Louisiana DEQhttp://www.deq.louisiana.gov/portal/DIVISIONS/PublicParticipationandPermitSupport/LouisianaLaboratoryAccreditationProgram.aspx 03016

Maine DHS Not available WA01276

Michigan DEQ http://www.michigan.gov/deq/0,1607,7-135-3307_4131_4156---,00.html 9949

Minnesota DOH http://www.health.state.mn.us/accreditation 053-999-457

Montana DPHHS http://www.dphhs.mt.gov/publichealth/ CERT0047

Nevada DEP http://ndep.nv.gov/bsdw/labservice.htm WA01276

New Jersey DEP http://www.nj.gov/dep/oqa/ WA005

North Carolina DWQ http://www.dwqlab.org/ 605

Oklahoma DEQ http://www.deq.state.ok.us/CSDnew/labcert.htm 9801

Oregon – DEQ (NELAP)http://public.health.oregon.gov/LaboratoryServices/EnvironmentalLaboratoryAccreditation/Pages/index.aspx WA100010

South Carolina DHEC http://www.scdhec.gov/environment/envserv/ 61002

Texas CEQ http://www.tceq.texas.gov/field/qa/env_lab_accreditation.html T104704427

Washington DOE http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html C544

Wisconsin DNR http://dnr.wi.gov/ 998386840

Wyoming (EPA Region 8) http://www.epa.gov/region8/water/dwhome/wyomingdi.html -

Kelso Laboratory Website www.alsglobal.com NA

ALS Group USA Corp. dba ALS Environmental (ALS) - KelsoState Certifications, Accreditations, and Licenses

Analyses were performed according to our laboratory’s NELAP-approved quality assurance program. A complete listing of specific NELAP-certified analytes, can be found in the certification section at www.ALSGlobal.com or at the accreditation bodies web site.Please refer to the certification and/or accreditation body's web site if samples are submitted for compliance purposes. The states highlighted above, require the analysis be listed on the state certification if used for compliance purposes and if the method/anlayte is offered by that state.

Page 5 of 64

Case Narrative



Page 6 of 64

Approved by______________________________________________

ALS ENVIRONMENTAL Client: ALS Environmental - Canada Service Request No.: K1509391 Project: L1651410 Date Received: 08/26/15 Sample Matrix: Plant Tissue

Case Narrative All analyses were performed consistent with the quality assurance program of ALS Environmental. This report contains analytical results for samples designated for Tier II data deliverables. When appropriate to the method, method blank results have been reported with each analytical test. Surrogate recoveries have been reported for all applicable organic analyses. Additional quality control analyses reported herein include: Laboratory Control Sample (LCS), and Laboratory/Duplicate Laboratory Control Sample (LCS/DLCS). Sample Receipt Seventeen plant tissue samples were received for analysis at ALS Environmental on 08/26/15. The samples were received in good condition and consistent with the accompanying chain of custody form. The samples were stored frozen at –20ºC upon receipt at the laboratory. Polynuclear Aromatic Hydrocarbons by EPA Method 8270 Elevated Detection Limits: The detection limits were elevated for Benzo(a)pyrene in the field samples. The chromatogram indicated the presence of non-target background components. The results were flagged to indicate the matrix interference. Sample Notes and Discussion: The results reported for Acenaphthene in several samples may contain a slight bias. The chromatogram indicated the presence of non-target background components. The matrix interference may have resulted in a slight high bias in the affected samples. The results were flagged with “X” to indicate the issue. No other anomalies associated with the analysis of these samples were observed.

Page 7 of 64

shar.samy

Shar Samy, Ph.D.

Chain of Custody



Page 8 of 64




Page 12 of 64


L1651410



Client:

Project:

Service Request:

Date

Collected

Date



K1509391-001 07/31/2015 08/26/2015L1651410-1 15-TILBURY-B-1

K1509391-002 07/31/2015 08/26/2015L1651410-2 15-TILBURY-B-1D

K1509391-003 07/31/2015 08/26/2015L1651410-3 15-TILBURY-B-2

K1509391-004 07/31/2015 08/26/2015L1651410-4 15-TILBURY-B-3

K1509391-005 07/31/2015 08/26/2015L1651410-5 15-TILBURY-B-4

K1509391-006 07/31/2015 08/26/2015L1651410-6 15-TILBURY-B-5

K1509391-007 07/31/2015 08/26/2015L1651410-7 15-TILBURY-B-6

K1509391-008 07/31/2015 08/26/2015L1651410-8 15-TILBURY-B-7

K1509391-009 07/31/2015 08/26/2015L1651410-9 15-TILBURY-B-8

K1509391-010 07/31/2015 08/26/2015L1651410-10 15-TILBURY-B-8D

K1509391-011 07/31/2015 08/26/2015L1651410-11 15-TILBURY-B-9

K1509391-012 07/31/2015 08/26/2015L1651410-12 15-TILBURY-B-10

K1509391-013 07/31/2015 08/26/2015L1651410-13 15-TILBURY-B-11

K1509391-014 07/31/2015 08/26/2015L1651410-14 15-TILBURY-B-12

K1509391-015 07/31/2015 08/26/2015L1651410-15 15-TILBURY-B-13

K1509391-016 07/31/2015 08/26/2015L1651410-16 15-TILBURY-B-14

K1509391-017 07/31/2015 08/26/2015L1651410-17 15-TILBURY-B-15


RR181708SuperSet Reference:u:\Stealth\Crystal.rpt\FormSSum.rpt Page 13 of 64

Analytical Results


K1509391-001

ug/Kg

Wet

L1651410-1 15-TILBURY-B-1

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM

NoteMRLQResultAnalyte Name

Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor

1.0 09/02/151 KWG150812309/08/15UNDNaphthalene

1.0 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene

0.50 09/02/151 KWG150812309/08/15UNDAcenaphthylene

0.50 09/02/151 KWG150812309/08/15UXNDAcenaphthene

0.50 09/02/151 KWG150812309/08/15UNDDibenzofuran

0.50 09/02/151 KWG150812309/08/15UNDFluorene

0.50 09/02/151 KWG150812309/08/150.78Phenanthrene

0.50 09/02/151 KWG150812309/08/15UNDAnthracene

0.50 09/02/151 KWG150812309/08/15UNDFluoranthene

0.50 09/02/151 KWG150812309/08/15UNDPyrene

0.50 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene

0.50 09/02/151 KWG150812309/08/15UNDChrysene

0.50 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†

0.50 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene

11 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene

0.50 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene

0.50 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene

0.50 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene

Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:


Merged SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 14 of 64

Analytical Results


K1509391-002

ug/Kg

Wet

L1651410-2 15-TILBURY-B-1D

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






0.50 09/02/151 KWG150812309/08/15UNDFluorene




0.50 09/02/151 KWG150812309/08/15UNDPyrene


0.50 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-003

ug/Kg

Wet

L1651410-3 15-TILBURY-B-2

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






0.50 09/02/151 KWG150812309/08/15UNDFluorene




0.50 09/02/151 KWG150812309/08/15UNDPyrene


0.50 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-004

ug/Kg

Wet

L1651410-4 15-TILBURY-B-3

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






0.48 09/02/151 KWG150812309/08/15UNDFluorene




0.48 09/02/151 KWG150812309/08/15UNDPyrene


0.48 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-005

ug/Kg

Wet

L1651410-5 15-TILBURY-B-4

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






0.49 09/02/151 KWG150812309/08/15UNDFluorene



0.49 09/02/151 KWG150812309/08/150.79Fluoranthene

0.49 09/02/151 KWG150812309/08/150.51Pyrene


0.49 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-006

ug/Kg

Wet

L1651410-6 15-TILBURY-B-5

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






0.50 09/02/151 KWG150812309/08/15UNDFluorene




0.50 09/02/151 KWG150812309/08/150.74Pyrene


0.50 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-007

ug/Kg

Wet

L1651410-7 15-TILBURY-B-6

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor




0.50 09/02/151 KWG150812309/08/15X0.57Acenaphthene


0.50 09/02/151 KWG150812309/08/15UNDFluorene




0.50 09/02/151 KWG150812309/08/15UNDPyrene


0.50 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-008

ug/Kg

Wet

L1651410-8 15-TILBURY-B-7

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






0.50 09/02/151 KWG150812309/08/15UNDFluorene




0.50 09/02/151 KWG150812309/08/15UXNDPyrene


0.50 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-009

ug/Kg

Wet

L1651410-9 15-TILBURY-B-8

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






0.50 09/02/151 KWG150812309/08/15UNDFluorene




0.50 09/02/151 KWG150812309/08/15UXNDPyrene


0.50 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-010

ug/Kg

Wet

L1651410-10 15-TILBURY-B-8D

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






0.49 09/02/151 KWG150812309/08/15UNDFluorene




0.49 09/02/151 KWG150812309/08/15UXNDPyrene


0.49 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-011

ug/Kg

Wet

L1651410-11 15-TILBURY-B-9

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






0.50 09/02/151 KWG150812309/08/15UNDFluorene




0.50 09/02/151 KWG150812309/08/15UNDPyrene


0.50 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-012

ug/Kg

Wet

L1651410-12 15-TILBURY-B-10

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






0.49 09/02/151 KWG150812309/08/15UNDFluorene




0.49 09/02/151 KWG150812309/08/15UNDPyrene


0.49 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-013

ug/Kg

Wet

L1651410-13 15-TILBURY-B-11

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






0.51 09/02/151 KWG150812309/08/15UNDFluorene




0.51 09/02/151 KWG150812309/08/150.65Pyrene


0.51 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-014

ug/Kg

Wet

L1651410-14 15-TILBURY-B-12

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor




0.49 09/02/151 KWG150812309/08/150.71Acenaphthene


0.49 09/02/151 KWG150812309/08/150.86Fluorene




0.49 09/02/151 KWG150812309/08/150.72Pyrene


0.49 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-015

ug/Kg

Wet

L1651410-15 15-TILBURY-B-13

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






0.50 09/02/151 KWG150812309/08/15UNDFluorene




0.50 09/02/151 KWG150812309/08/15UNDPyrene


0.50 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-016

ug/Kg

Wet

L1651410-16 15-TILBURY-B-14

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






0.50 09/02/151 KWG150812309/08/150.63Fluorene




0.50 09/02/151 KWG150812309/08/15UNDPyrene


0.50 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-017

ug/Kg

Wet

L1651410-17 15-TILBURY-B-15

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






0.49 09/02/151 KWG150812309/08/150.55Fluorene




0.49 09/02/151 KWG150812309/08/150.77Pyrene

0.49 09/02/151 KWG150812309/08/15UXNDBenz(a)anthracene

0.49 09/02/151 KWG150812309/08/15UXNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


KWG1508123-3

ug/Kg

Wet

Method Blank

NA

NA

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor




0.48 09/02/151 KWG150812309/08/15UNDAcenaphthene


0.48 09/02/151 KWG150812309/08/15UNDFluorene

0.48 09/02/151 KWG150812309/08/15UNDPhenanthrene



0.48 09/02/151 KWG150812309/08/15UNDPyrene


0.48 09/02/151 KWG150812309/08/15UNDChrysene



0.48 09/02/151 KWG150812309/08/15UNDBenzo(a)pyrene




Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:




Extraction Method:

QA/QC Report



Low

Plant tissue

L1651410

Client:

Project:

Sample Matrix:

Service Request:

Units:

Level:



EPA 3541


Sur1 Sur2 Sur3

Percent

K1509391-001L1651410-1 15-TILBURY-B-1 63 75 56

K1509391-002L1651410-2 15-TILBURY-B-1D 63 74 61

K1509391-003L1651410-3 15-TILBURY-B-2 66 79 63

K1509391-004L1651410-4 15-TILBURY-B-3 67 77 59

K1509391-005L1651410-5 15-TILBURY-B-4 71 82 65

K1509391-006L1651410-6 15-TILBURY-B-5 60 71 56

K1509391-007L1651410-7 15-TILBURY-B-6 70 80 64

K1509391-008L1651410-8 15-TILBURY-B-7 66 79 64

K1509391-009L1651410-9 15-TILBURY-B-8 70 81 67

K1509391-010L1651410-10 15-TILBURY-B-8D 69 81 66

K1509391-011L1651410-11 15-TILBURY-B-9 69 83 59

K1509391-012L1651410-12 15-TILBURY-B-10 61 74 53

K1509391-013L1651410-13 15-TILBURY-B-11 61 73 52

K1509391-014L1651410-14 15-TILBURY-B-12 69 80 56

K1509391-015L1651410-15 15-TILBURY-B-13 66 77 53

K1509391-016L1651410-16 15-TILBURY-B-14 64 77 54

K1509391-017L1651410-17 15-TILBURY-B-15 64 76 53

KWG1508123-3Method Blank 64 73 56

KWG1508123-1Lab Control Sample D61 82 D D65

KWG1508123-2Duplicate Lab Control Sample D69 88 D D69



39-96

41-100

39-111

Fluorene-d10

Fluoranthene-d10

Terphenyl-d14


Page



Sur1

Sur2

Sur3

=

=

=

u:\Stealth\Crystal.rpt\Form2.rpt Page 32 of 64

QA/QC Report

Internal Standard Area and RT Summary



L1651410

MS14

8270D SIM

KWG1508744-2

09/08/2015

09:22

KWG1508744

J:\MS14\DATA\090815\0908F002.D

Client:

Project:

Instrument ID:

File ID:

Analysis Method:

Lab Code:

Analysis Lot:

Service Request:

Date Analyzed:

Time Analyzed:


Phenanthrene-d10

RTArea

Acenaphthene-d10Naphthalene-d8

RTAreaRTArea

7.51

8.01

7.01

173,034

346,068

86,517

152,646

6.25

6.75

5.75

91,160

182,320

45,580

80,633

4.60

5.10

4.10

163,486

326,972

81,743

132,922

Results ==>

Upper Limit ==>

Lower Limit ==>

ICAL Result ==> 4.70 6.29 7.53Associated Analyses

KWG1508123-3 98,345 6.25 183,896 7.51 170,370 4.59Method Blank

KWG1508123-1 80,893 6.25 151,457 7.51 147,100 4.59Lab Control Sample

KWG1508123-2 81,842 6.25 153,337 7.51 147,927 4.59Duplicate Lab Control Sample

K1509391-001 91,455 6.25 167,196 7.51 156,572 4.59L1651410-1 15-TILBURY-B-1

K1509391-002 89,378 6.25 163,094 7.51 153,578 4.59L1651410-2 15-TILBURY-B-1D

K1509391-003 90,013 6.26 163,732 7.52 153,999 4.60L1651410-3 15-TILBURY-B-2

K1509391-004 89,903 6.26 163,512 7.52 153,617 4.60L1651410-4 15-TILBURY-B-3

K1509391-005 91,402 6.26 166,038 7.52 157,440 4.60L1651410-5 15-TILBURY-B-4

K1509391-006 96,450 6.26 174,850 7.52 161,998 4.61L1651410-6 15-TILBURY-B-5

K1509391-007 92,211 6.27 169,041 7.52 155,852 4.61L1651410-7 15-TILBURY-B-6

K1509391-008 95,830 6.27 174,989 7.53 160,228 4.61L1651410-8 15-TILBURY-B-7

K1509391-009 95,062 6.27 177,174 7.53 161,687 4.61L1651410-9 15-TILBURY-B-8

K1509391-010 97,898 6.27 180,194 7.53 165,470 4.61L1651410-10 15-TILBURY-B-8D

K1509391-011 97,604 6.27 181,778 7.53 176,604 4.61L1651410-11 15-TILBURY-B-9

K1509391-012 98,713 6.27 185,018 7.53 184,428 4.61L1651410-12 15-TILBURY-B-10

K1509391-013 98,315 6.27 185,980 7.53 186,699 4.61L1651410-13 15-TILBURY-B-11

K1509391-014 97,354 6.27 184,891 7.53 183,852 4.61L1651410-14 15-TILBURY-B-12

K1509391-015 97,619 6.27 184,963 7.53 184,958 4.62L1651410-15 15-TILBURY-B-13

K1509391-016 98,253 6.27 183,990 7.53 182,356 4.61L1651410-16 15-TILBURY-B-14

K1509391-017 97,617 6.27 188,446 7.53 185,088 4.61L1651410-17 15-TILBURY-B-15

Form 2B - OrganicPrinted: 09/14/2015 15:39:00 1Page


of

RR181708SuperSet Reference:u:\Stealth\Crystal.rpt\Form2IS3New.rpt

2

Page 33 of 64

QA/QC Report

Internal Standard Area and RT Summary



L1651410

MS14

8270D SIM

KWG1508744-2

09/08/2015

09:22

KWG1508744

J:\MS14\DATA\090815\0908F002.D

Client:

Project:

Instrument ID:

File ID:

Analysis Method:

Lab Code:

Analysis Lot:

Service Request:

Date Analyzed:

Time Analyzed:


Perylene-d12Chrysene-d12

RTAreaRTArea

13.10

13.60

12.60

199,020

398,040

99,510

160,772

10.03

10.53

9.53

210,965

421,930

105,483

164,618

Results ==>

Upper Limit ==>

Lower Limit ==>

ICAL Result ==> 10.05 13.06Associated Analyses

KWG1508123-3 201,228 13.09 219,975 10.03Method Blank

KWG1508123-1 173,657 13.09 182,742 10.03Lab Control Sample

KWG1508123-2 175,893 13.09 186,893 10.03Duplicate Lab Control Sample

K1509391-001 180,815 13.11 195,740 10.03L1651410-1 15-TILBURY-B-1

K1509391-002 175,195 13.14 175,168 10.04L1651410-2 15-TILBURY-B-1D

K1509391-003 176,503 13.16 181,423 10.05L1651410-3 15-TILBURY-B-2

K1509391-004 186,411 13.17 176,142 10.05L1651410-4 15-TILBURY-B-3

K1509391-005 185,965 13.19 179,750 10.06L1651410-5 15-TILBURY-B-4

K1509391-006 195,977 13.20 191,737 10.06L1651410-6 15-TILBURY-B-5

K1509391-007 188,691 13.21 184,820 10.07L1651410-7 15-TILBURY-B-6

K1509391-008 196,094 13.22 193,547 10.07L1651410-8 15-TILBURY-B-7

K1509391-009 196,754 13.22 194,961 10.07L1651410-9 15-TILBURY-B-8

K1509391-010 199,688 13.23 201,853 10.07L1651410-10 15-TILBURY-B-8D

K1509391-011 201,111 13.23 233,533 10.08L1651410-11 15-TILBURY-B-9

K1509391-012 202,203 13.23 239,370 10.07L1651410-12 15-TILBURY-B-10

K1509391-013 202,957 13.23 243,130 10.07L1651410-13 15-TILBURY-B-11

K1509391-014 209,032 13.23 241,659 10.08L1651410-14 15-TILBURY-B-12

K1509391-015 249,658 13.23 245,490 10.08L1651410-15 15-TILBURY-B-13

K1509391-016 245,516 13.24 242,371 10.08L1651410-16 15-TILBURY-B-14

K1509391-017 249,565 13.24 248,400 10.08L1651410-17 15-TILBURY-B-15

Form 2B - OrganicPrinted: 09/14/2015 15:39:00 2Page


of

RR181708SuperSet Reference:u:\Stealth\Crystal.rpt\Form2IS3New.rpt

2

Page 34 of 64


%Rec

Lab Control Spike

%Rec

Limits


%Rec RPD

RPD

Limit

QA/QC Report


KWG1508123-2


8270D SIM

ug/Kg

Wet

Lab Control Sample

KWG1508123-1


KWG1508123

Plant tissue

Low

L1651410

Client:

Project:

Sample Matrix:

Service Request:

Extraction Method:

Analysis Method:

Units:

Basis:

Level:

Extraction Lot:



Date Extracted:

Date Analyzed:

09/02/2015

09/08/2015

EPA 3541

Spike

Amount

Spike

Amount

43-102250 68 40Naphthalene 250 60 13150 171


53-100250 73 40Acenaphthylene 250 64 12161 181

52-101250 73 40Acenaphthene 250 64 12161 181

55-103250 73 40Dibenzofuran 250 63 15156 182

56-104250 74 40Fluorene 250 67 11167 186

54-100250 79 40Phenanthrene 250 71 10178 196

57-103250 85 40Anthracene 250 76 11189 211

55-108250 92 40Fluoranthene 250 85 8213 230

48-117250 81 40Pyrene 250 75 7188 202


58-112250 90 40Chrysene 250 83 8208 225



56-110250 97 40Benzo(a)pyrene 250 89 8223 243

50-117250 89 40Indeno(1,2,3-cd)pyrene 250 84 6209 222







u:\Stealth\Crystal.rpt\Form3DLC.rpt Page 35 of 64


Instrument ID:

File ID: Lab Code:

Sample Name:

Time Analyzed:

Date Analyzed:

Date Extracted:

Service Request:

Sample Matrix:

Project:

Client:

J:\MS14\DATA\090815\0908F003.D

09:48

09/02/2015

MS14

Plant tissue

Method Blank

KWG1508123-3

09/08/2015


Method Blank Summary

K1509391

L1651410

QA/QC Report

ALS Environmental - Canada

This Method Blank applies to the following analyses:

EPA 3541

8270D SIM KWG1508123

LowExtraction Method:

Analysis Method:

Level:

Extraction Lot:

Sample Name Lab Code File ID

Date

Analyzed

Time

Analyzed

KWG1508123-1 10:13J:\MS14\DATA\090815\0908F004.DLab Control Sample 09/08/15

KWG1508123-2 10:39J:\MS14\DATA\090815\0908F005.DDuplicate Lab Control Sample 09/08/15

K1509391-001 11:56J:\MS14\DATA\090815\0908F008.DL1651410-1 15-TILBURY-B-1 09/08/15

K1509391-002 12:22J:\MS14\DATA\090815\0908F009.DL1651410-2 15-TILBURY-B-1D 09/08/15
















Form 4A - Organic 1Printed: of 1Page15:39:1509/14/2015RR181708SuperSet Reference:u:\Stealth\Crystal.rpt\Form4mb.rpt Page 36 of 64

09/08/2015


Instrument ID:

File ID: Lab Code:

Sample Name:

Time Analyzed:

Date Analyzed:

Date Extracted:

Service Request:

Sample Matrix:

Project:

Client:

J:\MS14\DATA\090815\0908F004.D

Lab Control Sample Summary

MS14

KWG1508123-1

Lab Control Sample

10:13

09/02/2015

Plant tissue

L1651410



QA/QC Report

This Lab Control Sample applies to the following analyses:

EPA 3541

8270D SIM

Low

KWG1508123

Extraction Method:

Analysis Method:

Level:

Extraction Lot:


Date

Analyzed

Time

Analyzed

KWG1508123-3 09:48J:\MS14\DATA\090815\0908F003.DMethod Blank 09/08/15


















Form 4B - Organic 1of1PagePrinted: 09/14/2015 15:39:20SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form4LCS.rpt Page 37 of 64

QA/QC Results

Tune Summary


L1651410

K1509391

08:57

J:\MS14\DATA\090815\0908F001.D

MS14

Target

Mass

Relative

to Mass

Lower

Limit%

Upper

Limit%

Relative

Abundance %

Raw

Abundance

Result

Pass/Fail

8270D SIM

KWG1508744


Client:

Project:

Service Request:

Date Analyzed:

Time Analyzed:

File ID:

Instrument ID: Analysis Method:

Analysis Lot: Column:


09/08/2015

198 PASS 10 80 30.5 4778451

69 PASS 0 2 1.0 44868

198 PASS 0 100 27.7 4334969

69 PASS 0 2 1.2 52070

198 PASS 10 80 40.2 62872127

198 PASS 0 2 0.5 806197

442 PASS 30 100 42.3 156445198

198 PASS 5 9 6.3 9869199

198 PASS 10 60 36.6 57326275

442 PASS 1 50 3.0 11082365

443 PASS 0 100 73.0 51599441

442 PASS 100 100 100.0 370226442

442 PASS 15 24 19.1 70638443


Date

Analyzed

Time

Analyzed Q

KWG1508744-2 J:\MS14\DATA\090815\0908F002.D 09:22Continuing Calibration Verification 09/08/2015

KWG1508123-3 J:\MS14\DATA\090815\0908F003.D 09:48Method Blank 09/08/2015

KWG1508123-1 J:\MS14\DATA\090815\0908F004.D 10:13Lab Control Sample 09/08/2015

KWG1508123-2 J:\MS14\DATA\090815\0908F005.D 10:39Duplicate Lab Control Sample 09/08/2015

K1509391-001 J:\MS14\DATA\090815\0908F008.D 11:56L1651410-1 15-TILBURY-B-1 09/08/2015

K1509391-002 J:\MS14\DATA\090815\0908F009.D 12:22L1651410-2 15-TILBURY-B-1D 09/08/2015








K1509391-010 J:\MS14\DATA\090815\0908F017.D 15:57L1651410-10 15-TILBURY-B-8D 09/08/2015








Form 5 - Organic 1of1PagePrinted: 09/14/2015 15:39:30

Results flagged with an asterisk (*) indicate the analysis performed outside specified tune window

RR181708SuperSet Reference:u:\Stealth\Crystal.rpt\Form5.rpt Page 38 of 64

QA/QC Results

Initial Calibration Summary


L1651410

K1509391

06/18/2015


CAL14088

MS14

Client:

Project:

Calibration ID:

Instrument ID:

Service Request:


Calibration Date:

Column: MS

Level ID File ID

J:\MS14\DATA\061815\0618F003.DAJ:\MS14\DATA\061815\0618F004.DBJ:\MS14\DATA\061815\0618F005.DCJ:\MS14\DATA\061815\0618F006.DDJ:\MS14\DATA\061815\0618F007.DEJ:\MS14\DATA\061815\0618F008.DF

Level ID File ID

J:\MS14\DATA\061815\0618F009.DGJ:\MS14\DATA\061815\0618F010.DHJ:\MS14\DATA\061815\0618F011.DIJ:\MS14\DATA\061815\0618F012.DJ

Level

ID Amt RRF

Level

ID Amt RRF

Level

ID Amt RRF

Level

ID Amt RRF

Level

ID Amt RRFAnalyte Name

Naphthalene 4.0 8.0 202.0 1001.02 0.968 0.924 0.968 0.990A B C D E

400 1000 1600200 20000.991 1.01 0.929 0.948 0.942F G H I J

2-Methylnaphthalene 4.0 8.0 202.0 1000.724 0.769 0.709 0.743 0.741A B C D E

400 1000 1600200 20000.740 0.740 0.682 0.691 0.684F G H I J

Acenaphthylene 4.0 8.0 202.0 1001.84 1.84 1.75 1.76 1.85A B C D E

400 1000 1600200 20001.84 1.86 1.74 1.73 1.69F G H I J

Acenaphthene 4.0 8.0 202.0 1001.14 1.10 1.04 1.05 1.06A B C D E

400 1000 1600200 20001.05 1.06 0.998 1.00 0.981F G H I J

Dibenzofuran 4.0 8.0 202.0 1001.73 1.72 1.62 1.64 1.69A B C D E

400 1000 1600200 20001.68 1.68 1.57 1.58 1.53F G H I J

Fluorene 4.0 8.0 202.0 1001.31 1.33 1.26 1.28 1.32A B C D E

400 1000 1600200 20001.30 1.29 1.22 1.22 1.19F G H I J

Phenanthrene 4.0 8.0 202.0 1001.06 1.08 1.03 1.03 1.03A B C D E

400 1000 1600200 20001.01 1.02 0.947 0.938 0.922F G H I J

Anthracene 4.0 8.0 202.0 1001.04 0.976 0.934 0.969 1.01A B C D E

400 1000 1600200 20001.00 1.00 0.935 0.923 0.899F G H I J

Fluoranthene 4.0 8.0 202.0 1001.14 1.08 1.05 1.11 1.17A B C D E

400 1000 1600200 20001.15 1.17 1.08 1.07 1.05F G H I J

Pyrene 4.0 8.0 202.0 1001.20 1.10 1.07 1.11 1.13A B C D E

400 1000 1600200 20001.12 1.15 1.10 1.09 1.08F G H I J

Benz(a)anthracene 4.0 8.0 202.0 1001.23 1.04 0.953 0.927 0.965A B C D E

400 1000 1600200 20000.999 1.07 1.05 1.05 1.04F G H I J

Chrysene 4.0 8.0 202.0 1001.09 0.998 0.978 0.996 0.988A B C D E

400 1000 1600200 20000.976 0.990 0.945 0.949 0.942F G H I J

Benzo(b)fluoranthene 4.0 8.0 202.0 1001.17 1.04 1.00 1.02 1.12A B C D E

400 1000 1600200 20001.14 1.18 1.14 1.15 1.15F G H I J

Benzo(k)fluoranthene 4.0 8.0 202.0 1001.15 1.05 1.03 1.04 1.09A B C D E

400 1000 1600200 20001.11 1.14 1.10 1.12 1.12F G H I J

Form 6A - Organic 3of1PagePrinted: 09/14/2015 15:39:41RR181708SuperSet Reference:


† SPCC Compound ‡ CCC Compound

u:\Stealth\Crystal.rpt\Form6iNew.rpt Page 39 of 64

QA/QC Results



L1651410

K1509391

06/18/2015


CAL14088

MS14

Client:

Project:

Calibration ID:

Instrument ID:

Service Request:


Calibration Date:

Column: MS

Level

ID Amt RRF

Level

ID Amt RRF

Level

ID Amt RRF

Level

ID Amt RRF

Level

ID Amt RRFAnalyte Name

Benzo(a)pyrene 4.0 8.0 202.0 1001.02 0.949 0.902 0.921 1.02A B C D E

400 1000 1600200 20001.05 1.10 1.07 1.09 1.09F G H I J

Indeno(1,2,3-cd)pyrene 4.0 8.0 202.0 1001.06 0.971 0.928 0.969 1.04A B C D E

400 1000 1600200 20001.04 1.05 0.978 0.974 0.962F G H I J

Dibenz(a,h)anthracene 4.0 8.0 202.0 1001.17 1.04 0.955 0.991 0.979A B C D E

400 1000 1600200 20000.960 0.953 0.870 0.852 0.844F G H I J

Benzo(g,h,i)perylene 4.0 8.0 202.0 1001.19 1.11 1.03 1.06 1.07A B C D E

400 1000 1600200 20001.06 1.06 0.963 0.945 0.932F G H I J

Fluorene-d10 4.0 8.0 20 1001.39 1.19 1.29 1.15B C D E

400 1000 1600200 20001.14 1.09 1.03 1.03 0.996F G H I J

Fluoranthene-d10 4.0 8.0 202.0 1001.06 0.982 0.920 1.18 1.08A B C D E

400 1000 1600200 20001.11 1.07 0.995 0.974 0.961F G H I J

Terphenyl-d14 4.0 8.0 202.0 1000.857 0.802 0.748 0.918 0.815A B C D E

400 1000 1600200 20000.817 0.782 0.695 0.672 0.662F G H I J





QA/QC Results



L1651410

K1509391

06/18/2015


CAL14088

MS14

Client:

Project:

Calibration ID:

Instrument ID:

Service Request:


Calibration Date:

Column: MS

Analyte Name

Compound

Type Fit Type Eval.

Eval.

Result Q

Control

Criteria

Average

RRF Q

Minimum

RRF

Calibration Evaluation RRF Evaluation

Naphthalene MS AverageRF % RSD 3.3 £ 20 0.968 0.70

2-Methylnaphthalene MS AverageRF % RSD 4.1 £ 20 0.722 0.40

Acenaphthylene MS AverageRF % RSD 3.5 £ 20 1.79 0.90

Acenaphthene MS AverageRF % RSD 4.5 £ 20 1.05 0.90

Dibenzofuran MS AverageRF % RSD 4.1 £ 20 1.64 0.80

Fluorene MS AverageRF % RSD 3.8 £ 20 1.27 0.90

Phenanthrene MS AverageRF % RSD 5.3 £ 20 1.01 0.70

Anthracene MS AverageRF % RSD 4.7 £ 20 0.969 0.70

Fluoranthene MS AverageRF % RSD 4.2 £ 20 1.11 0.60

Pyrene MS AverageRF % RSD 3.4 £ 20 1.11 0.60

Benz(a)anthracene MS AverageRF % RSD 8.2 £ 20 1.03 0.80

Chrysene MS AverageRF % RSD 4.2 £ 20 0.985 0.70

Benzo(b)fluoranthene MS AverageRF % RSD 5.9 £ 20 1.11 0.70

Benzo(k)fluoranthene MS AverageRF % RSD 3.8 £ 20 1.09 0.70

Benzo(a)pyrene MS AverageRF % RSD 7.1 £ 20 1.02 0.70

Indeno(1,2,3-cd)pyrene MS AverageRF % RSD 4.7 £ 20 0.998 0.50

Dibenz(a,h)anthracene MS AverageRF % RSD 10.2 £ 20 0.962 0.40

Benzo(g,h,i)perylene MS AverageRF % RSD 7.5 £ 20 1.04 0.50

Fluorene-d10 SURR AverageRF % RSD 11.4 £ 20 1.14 0.01

Fluoranthene-d10 SURR AverageRF % RSD 7.8 £ 20 1.03 0.01

Terphenyl-d14 SURR AverageRF % RSD 10.7 £ 20 0.777 0.01





QA/QC Results

Second Source Calibration Verification

Internal Standard

L1651410

Client:

Project:

Service Request:

Date Analyzed:

Analysis Method:

Calibration Type:

Calibration Date:

Calibration ID:

Units:



06/18/2015

06/18/2015


8270D SIM

CAL14088

ng/ml

J:\MS14\DATA\061815\0618X013.DFile ID:

Analyte Name Expected Result

Average

RF

SSV

RF %D %Drift Criteria Curve Fit

AverageRF± 30 %NA-10.9600.968400400Naphthalene

AverageRF± 30 %NA-40.6950.7223904002-Methylnaphthalene

AverageRF± 30 %NA51.871.79420400Acenaphthylene

AverageRF± 30 %NA21.071.05410400Acenaphthene

AverageRF± 30 %NA11.661.64400400Dibenzofuran

AverageRF± 30 %NA31.311.27410400Fluorene

AverageRF± 30 %NA21.031.01410400Phenanthrene

AverageRF± 30 %NA71.030.969430400Anthracene

AverageRF± 30 %NA61.171.11420400Fluoranthene

AverageRF± 30 %NA61.181.11420400Pyrene

AverageRF± 30 %NA51.081.03420400Benz(a)anthracene

AverageRF± 30 %NA41.020.985420400Chrysene

AverageRF± 30 %NA41.151.11410400Benzo(b)fluoranthene

AverageRF± 30 %NA21.121.09410400Benzo(k)fluoranthene

AverageRF± 30 %NA01.021.02400400Benzo(a)pyrene

AverageRF± 30 %NA11.010.998400400Indeno(1,2,3-cd)pyrene

AverageRF± 30 %NA10.9730.962400400Dibenz(a,h)anthracene

AverageRF± 30 %NA01.041.04400400Benzo(g,h,i)perylene

1of1PagePrinted: 9/14/2015 15:39:55 Form 6B - Organic


SuperSet Reference:


RR181708u:\Stealth\Crystal.rpt\Form6SS.rpt Page 42 of 64

QA/QC Results

Continuing Calibration Verification Summary

L1651410

Internal Standard

Client:

Project:

Service Request:

Date Analyzed:

Calibration Type:

Analysis Method:

Calibration Date:

Calibration ID:

Units:

Analysis Lot:



8270D SIM

06/18/2015

CAL14088

KWG1508744

ng/ml


09/08/2015

J:\MS14\DATA\090815\0908F002.DFile ID:

Curve FitCriteria%Drift%D

CCV

RF

Average

RFResultExpectedAnalyte Name

Min

RF

± 20NA-4380400Naphthalene 0.968 AverageRF0.9280.70

± 20NA-93604002-Methylnaphthalene 0.722 AverageRF0.6580.40

± 20NA-5380400Acenaphthylene 1.79 AverageRF1.700.90

± 20NA-3390400Acenaphthene 1.05 AverageRF1.020.90

± 20NA-3390400Dibenzofuran 1.64 AverageRF1.590.80

± 20NA-1400400Fluorene 1.27 AverageRF1.260.90

± 20NA0400400Phenanthrene 1.01 AverageRF1.000.70

± 20NA0400400Anthracene 0.969 AverageRF0.9720.70

± 20NA5420400Fluoranthene 1.11 AverageRF1.160.60

± 20NA-8370400Pyrene 1.11 AverageRF1.030.60

± 20NA2410400Benz(a)anthracene 1.03 AverageRF1.050.80

± 20NA-4380400Chrysene 0.985 AverageRF0.9450.70

± 20NA15460400Benzo(b)fluoranthene 1.11 AverageRF1.280.70

± 20NA7430400Benzo(k)fluoranthene 1.09 AverageRF1.180.70

± 20NA5420400Benzo(a)pyrene 1.02 AverageRF1.070.70

± 20NA2410400Indeno(1,2,3-cd)pyrene 0.998 AverageRF1.010.50

± 20NA-2390400Dibenz(a,h)anthracene 0.962 AverageRF0.9440.40

± 20NA-2390400Benzo(g,h,i)perylene 1.04 AverageRF1.020.50

± 20NA-4380400Fluorene-d10 1.14 AverageRF1.100.01

± 20NA6430400Fluoranthene-d10 1.03 AverageRF1.100.01

± 20NA4410400Terphenyl-d14 0.777 AverageRF0.8040.01

Printed: 9/14/2015 15:39:58 1of1PageForm 7 - Organic


SuperSet Reference: RR181708


u:\Stealth\Crystal.rpt\Form7.rpt Page 43 of 64

QA/QC Results

Analysis Run Log

L1651410

Client:

Project:

Service Request:

Analysis Method: Analysis Lot:




8270D SIM

File ID

Date

Analysis

Started

Start

Time

Date

Analysis

Finished

Finish

Time


KWG1508744

Q

MS14Instrument ID:

KWG1508744-1 9/8/2015 08:57 9/8/2015 09:160908F001.D GC/MS Tuning - Decafluorotriphenylphosph

KWG1508744-2 9/8/2015 09:22 9/8/2015 09:410908F002.D Continuing Calibration Verification

KWG1508123-3 9/8/2015 09:48 9/8/2015 10:070908F003.D Method Blank

KWG1508123-1 9/8/2015 10:13 9/8/2015 10:320908F004.D Lab Control Sample

KWG1508123-2 9/8/2015 10:39 9/8/2015 10:580908F005.D Duplicate Lab Control Sample

ZZZZZZ 9/8/2015 11:04 9/8/2015 11:230908F006.D ZZZZZZ

ZZZZZZ 9/8/2015 11:30 9/8/2015 11:490908F007.D ZZZZZZ

K1509391-001 9/8/2015 11:56 9/8/2015 12:150908F008.D L1651410-1 15-TILBURY-B-1

K1509391-002 9/8/2015 12:22 9/8/2015 12:410908F009.D L1651410-2 15-TILBURY-B-1D

K1509391-003 9/8/2015 12:49 9/8/2015 13:080908F010.D L1651410-3 15-TILBURY-B-2

K1509391-004 9/8/2015 13:15 9/8/2015 13:340908F011.D L1651410-4 15-TILBURY-B-3

K1509391-005 9/8/2015 13:42 9/8/2015 14:010908F012.D L1651410-5 15-TILBURY-B-4

K1509391-006 9/8/2015 14:09 9/8/2015 14:280908F013.D L1651410-6 15-TILBURY-B-5

K1509391-007 9/8/2015 14:36 9/8/2015 14:550908F014.D L1651410-7 15-TILBURY-B-6

K1509391-008 9/8/2015 15:03 9/8/2015 15:220908F015.D L1651410-8 15-TILBURY-B-7

K1509391-009 9/8/2015 15:30 9/8/2015 15:490908F016.D L1651410-9 15-TILBURY-B-8

K1509391-010 9/8/2015 15:57 9/8/2015 16:160908F017.D L1651410-10 15-TILBURY-B-8D

K1509391-011 9/8/2015 16:24 9/8/2015 16:430908F018.D L1651410-11 15-TILBURY-B-9

K1509391-012 9/8/2015 16:51 9/8/2015 17:100908F019.D L1651410-12 15-TILBURY-B-10

K1509391-013 9/8/2015 17:18 9/8/2015 17:370908F020.D L1651410-13 15-TILBURY-B-11

K1509391-014 9/8/2015 17:45 9/8/2015 18:040908F021.D L1651410-14 15-TILBURY-B-12

K1509391-015 9/8/2015 18:12 9/8/2015 18:310908F022.D L1651410-15 15-TILBURY-B-13

K1509391-016 9/8/2015 18:39 9/8/2015 18:580908F023.D L1651410-16 15-TILBURY-B-14

K1509391-017 9/8/2015 19:06 9/8/2015 19:250908F024.D L1651410-17 15-TILBURY-B-15

ZZZZZZ 9/8/2015 19:32 9/8/2015 19:510908F025.D ZZZZZZ

ZZZZZZ 9/8/2015 19:59 9/8/2015 20:180908F026.D ZZZZZZ

ZZZZZZ 9/8/2015 20:26 9/8/2015 20:450908F027.D ZZZZZZ

ZZZZZZ 9/8/2015 20:53 9/8/2015 21:120908F028.D ZZZZZZ


Results flagged with an asterisk (*) indicate the holding time was exceeded for the analysis

RR181708SuperSet Reference:u:\Stealth\Crystal.rpt\Form8.rpt Page 44 of 64

QA/QC Results

Extraction Prep Log



L1651410

K1509391

Final

Volume

KWG1508123

Plant tissue

Low

Client:

Project:

Sample Matrix:

Service Request:

Extraction Method: Extraction Lot:

Level:


Date

Received

Sample

Amount % Solids Note


Date Extracted: 09/02/2015

EPA 3541


Date

Collected

K1509391-001 10.052g 1ml NA08/26/15L1651410-1 15-TILBURY-B-1 07/31/15

K1509391-002 10.017g 1ml NA08/26/15L1651410-2 15-TILBURY-B-1D 07/31/15








K1509391-010 10.253g 1ml NA08/26/15L1651410-10 15-TILBURY-B-8D 07/31/15








KWG1508123-3 10.438g 1ml NANAMethod Blank NA

KWG1508123-1 10.000g 1ml NANALab Control Sample NA

KWG1508123-2 10.000g 1ml NANADuplicate Lab Control Sample NA


Results flagged with an asterisk (*) indicate the holding time was exceeded for the analysis

SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form9L.rpt Page 45 of 64




Page 46 of 64

Analytical Results


K1509391-001

ug/Kg

Dry

L1651410-1 15-TILBURY-B-1

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






3.8 09/02/151 KWG150812309/08/15UNDFluorene




3.8 09/02/151 KWG150812309/08/15UNDPyrene


3.8 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-002

ug/Kg

Dry

L1651410-2 15-TILBURY-B-1D

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






3.5 09/02/151 KWG150812309/08/15UNDFluorene




3.5 09/02/151 KWG150812309/08/15UNDPyrene


3.5 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-003

ug/Kg

Dry

L1651410-3 15-TILBURY-B-2

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






3.3 09/02/151 KWG150812309/08/15UNDFluorene




3.3 09/02/151 KWG150812309/08/15UNDPyrene


3.3 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-004

ug/Kg

Dry

L1651410-4 15-TILBURY-B-3

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






3.9 09/02/151 KWG150812309/08/15UNDFluorene




3.9 09/02/151 KWG150812309/08/15UNDPyrene


3.9 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-005

ug/Kg

Dry

L1651410-5 15-TILBURY-B-4

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






2.9 09/02/151 KWG150812309/08/15UNDFluorene

2.9 09/02/151 KWG150812309/08/1512Phenanthrene



2.9 09/02/151 KWG150812309/08/153.0Pyrene


2.9 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-006

ug/Kg

Dry

L1651410-6 15-TILBURY-B-5

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






3.1 09/02/151 KWG150812309/08/15UNDFluorene




3.1 09/02/151 KWG150812309/08/154.6Pyrene


3.1 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-007

ug/Kg

Dry

L1651410-7 15-TILBURY-B-6

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






3.5 09/02/151 KWG150812309/08/15UNDFluorene




3.5 09/02/151 KWG150812309/08/15UNDPyrene


3.5 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-008

ug/Kg

Dry

L1651410-8 15-TILBURY-B-7

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






2.9 09/02/151 KWG150812309/08/15UNDFluorene




2.9 09/02/151 KWG150812309/08/15UNDPyrene


2.9 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-009

ug/Kg

Dry

L1651410-9 15-TILBURY-B-8

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






4.0 09/02/151 KWG150812309/08/15UNDFluorene




4.0 09/02/151 KWG150812309/08/15UNDPyrene


4.0 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-010

ug/Kg

Dry

L1651410-10 15-TILBURY-B-8D

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






3.2 09/02/151 KWG150812309/08/15UNDFluorene




3.2 09/02/151 KWG150812309/08/15UNDPyrene


3.2 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-011

ug/Kg

Dry

L1651410-11 15-TILBURY-B-9

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






3.7 09/02/151 KWG150812309/08/15UNDFluorene




3.7 09/02/151 KWG150812309/08/15UNDPyrene


3.7 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-012

ug/Kg

Dry

L1651410-12 15-TILBURY-B-10

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






3.1 09/02/151 KWG150812309/08/15UNDFluorene




3.1 09/02/151 KWG150812309/08/15UNDPyrene


3.1 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-013

ug/Kg

Dry

L1651410-13 15-TILBURY-B-11

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






2.5 09/02/151 KWG150812309/08/15UNDFluorene




2.5 09/02/151 KWG150812309/08/153.1Pyrene


2.5 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-014

ug/Kg

Dry

L1651410-14 15-TILBURY-B-12

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor




3.8 09/02/151 KWG150812309/08/155.5Acenaphthene


3.8 09/02/151 KWG150812309/08/156.7Fluorene



3.8 09/02/151 KWG150812309/08/1513Fluoranthene

3.8 09/02/151 KWG150812309/08/155.6Pyrene


3.8 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-015

ug/Kg

Dry

L1651410-15 15-TILBURY-B-13

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






3.5 09/02/151 KWG150812309/08/15UNDFluorene




3.5 09/02/151 KWG150812309/08/15UNDPyrene


3.5 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-016

ug/Kg

Dry

L1651410-16 15-TILBURY-B-14

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






3.7 09/02/151 KWG150812309/08/154.6Fluorene




3.7 09/02/151 KWG150812309/08/15UNDPyrene


3.7 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


K1509391-017

ug/Kg

Dry

L1651410-17 15-TILBURY-B-15

07/31/2015

08/26/2015

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






3.8 09/02/151 KWG150812309/08/154.2Fluorene



3.8 09/02/151 KWG150812309/08/1514Fluoranthene

3.8 09/02/151 KWG150812309/08/155.9Pyrene


3.8 09/02/151 KWG150812309/08/15UNDChrysene







Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



Analytical Results


KWG1508123-3

ug/Kg

Dry

Method Blank

NA

NA

L1651410

Plant tissue

Client:

Project:

Sample Matrix:

Service Request:

Date Collected:

Date Received:


Units:

Basis:

Sample Name:


Lab Code:


Analysis Method:

EPA 3541

8270D SIM


Extraction

Lot

Date

Analyzed

Date

Extracted

Dilution

Factor






0.48 09/02/151 KWG150812309/08/15UNDFluorene

0.48 09/02/151 KWG150812309/08/15UNDPhenanthrene



0.48 09/02/151 KWG150812309/08/15UNDPyrene


0.48 09/02/151 KWG150812309/08/15UNDChrysene



0.48 09/02/151 KWG150812309/08/15UNDBenzo(a)pyrene




Surrogate Name %Rec

Control

Limits NoteDate

Analyzed






Comments:



appendix 8.1-1 baseline data collection and results...appendix 8.1-1 baseline data collection and...

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