appendix to chapter 5, a: status of process …

21
APPENDIX TO CHAPTER 5, A: STATUS OF PROCESS DEVELOPMENT The status of development of coal conversion and oil shale retorting both in this country and abroad are reviewed at length in the literature (Rogers and Hill, 1979; National Coal Association, 1980; Fluor Engineers and Constructors, Inc., 1979a,b,c) . The status of synfuel commercialization is summarized in - “Table - Table - Table the following tables: A: Coal Gasification and Constructors, B: Coal Liquefaction and Constructors, (Fluor Engineers Inc., 1979a) . (Fluor Engineers Inc., 1979b) . c: Shale Oil Retorting (Fluor Engineers and Constructors, Inc., 1979c) . These tables also review the major characteristics of these technologies. More details about the processes are given in Bentz, E.J., 1980. A-1 ejb&a

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Page 1: APPENDIX TO CHAPTER 5, A: STATUS OF PROCESS …

APPENDIX TO CHAPTER 5, A: STATUS OF PROCESS DEVELOPMENT

The status of development of coal conversion andoil shale retorting both in this country and abroad arereviewed at length in the literature (Rogers and Hill,1979; National Coal Association, 1980; Fluor Engineersand Constructors, Inc., 1979a,b,c) .

The status of synfuel commercialization issummarized in

- “Table

- Table

- Table

the following tables:

A: Coal Gasificationand Constructors,

B: Coal Liquefactionand Constructors,

(Fluor EngineersInc., 1979a) .

(Fluor EngineersInc., 1979b) .

c: Shale Oil Retorting (Fluor Engineersand Constructors, Inc., 1979c) .

These tables also review the major characteristicsof these technologies. More details about the processesare given in Bentz, E.J., 1980.

A-1

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Page 2: APPENDIX TO CHAPTER 5, A: STATUS OF PROCESS …

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Page 3: APPENDIX TO CHAPTER 5, A: STATUS OF PROCESS …

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Page 7: APPENDIX TO CHAPTER 5, A: STATUS OF PROCESS …

TABLE A-2’ (continued)COAL LMMJEFACTION – NVDROGENATION PROCESSES

TVPICALPaooucTs

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Page 8: APPENDIX TO CHAPTER 5, A: STATUS OF PROCESS …

TABLE A-3SUMMARY OF RETORTING PROCESSES

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Page 9: APPENDIX TO CHAPTER 5, A: STATUS OF PROCESS …

APPENDIX TO CHAPTER 5, B

Page 10: APPENDIX TO CHAPTER 5, A: STATUS OF PROCESS …

CDt-l.o-m

P

Appendix B-1: EXISTING U.S. AND FOREIGN LOW- AND MEDIUM-BTU GASIFICATION SYSTEMS

(Courtesy: ‘tLow and Medium Btu Gasification Systems:Technology Overviewt’,U.S. EPA, 1978; EPA-600/7/78-061)

Gasifier

Lurgi

Wellman-Galusha

Moodall-Duckman/Gas Intagrale

Koppers-Totxok

Winklor

Chapman (Uilputta)

Riley Norgan

Uellman Incadenmcent

BGC/Lurgi S l a g g i n g

Bi-Gas

Foster bJheeler/Stoic

Pressurized Uellman-Galuaha {NERC)

GFERC Slagging

Te8acoB C R bw-Btu

combustion FmgAne.clng

Hyga.

Synthane

C02 Acceptor

Foster Wheeler

Babcock 6 wi~COX

U-Gas

Uestlrlghouae

Coiilex

under construction.

N-r of gasifioro currently operating (No. .ot gaslflers built)Licenaor/develOper Low-Btu gaa #kdiua-Btti gas Syntheaie gas Iacation

Lurgi Mineralbltechnik CabIl

JtcDowell Wellrsan Iingineering Co.

Woodall-Duckham (USA) Ltd.

Koppera Company, Inc.

Davy Powergas

Uilputte Corp.

Riley Stoker Corp.

Applied Technology Corp.

British Gae Corp. ● nd LurgiHineraloltechnik GebH

%ituminoue Coal Reeearch, Inc. f

Foster ”Wheeler/Stoic Corp

ERDA

ERDA

Texaco Developtaent Corp.

Bitumlnoua Coal Research, Inc.

Combustion Engineering Corp.

Instituto of Gae Technology

ERDA

ERDA

Foster kJheeler Energy Corp.

The Babcock L Wilcox Co,

Institute of Gas Technology,Phillips Petroleum Corp.

Westinghouse ElectrLc C o r p .

Inex R e s o u r c e s , I n c .

5 (39) (22) Foreign

0{150) US/Foroign

(72)@@ (O)** Foreign

(39)** Foreign

(23)** 6(14) Porelgn

Demonstration scale indicates 2000 to IJ),000 lb/hr coal feed.Pilot scale indicates 400 to 1S00 lb/hr coal feed.

9*

ususUS/?oreign

Poroign

usus

us

ususususus

us

us

usus

us

usus

Scale

Commercial

Commercial

Commercial

Commercial

commercial

Commercial

commercial

Commercial/Demonstration

Demonstration

Demonstration

Demonstration

Demonstration

Demonstration

Demonstration

Demonstration

Demonstration

Dewnstratlon(High-atu)

DemonstrationIJligh-Btu)

Demonstration(High-Btu)

Pilot

P i l o t

Pilot (400lb/hr coal)

PilotP i l o t

‘Undoternined number overseas currently in operation.

Page 11: APPENDIX TO CHAPTER 5, A: STATUS OF PROCESS …

Appendix B-2: Continued

POPULATION OF LOW/MEDIUM-BTU GASIFIERS

Gasifier type

Gasifier name Licensor/Developer Stacus

Fixed-Sod, Dry Ash

Lurgi

Wellman-Galusha

Chapman (Willputte)

Woodall-Duckhan/Gas Incqrde

Riley Morgan

Prtimxlxod Uell.maB-CA.Lu8h~OQRC)

?oscar Uhadar/Stoic

kuosg ?* B a d

CoMol ?* M

IB’B Tuo st&

krpsly Produar

MrlmhkA

PincuhRillebraad

U.G.I. Blua Vatar Gas

POu8r Cu

U8uma Inundac9nt

DCUKalsar

mx@ d - B e d . Slag ring Ash

BCC/Lurgi S&g@aB Casifier

CPERCS&ggiag Gasiftir

Thy88al Galoesy

ArluoLurglCorp. (USA)

lMou911 Udlmau ~sr. Co. (USA)

Wupuctc CO-. (USA)

tii~--Cti, Ltd. (USA)

BileyStokarCorp. (UBA)

krgustoun Emrsy RuurchCamtor/ERDA (USA)

~o~ccr Uh-lcr &argy C o r p . ( U S A )

Allis Chalmrs Cerp. (UBA)

m u. Kallou Go. (USA)

Ca9ral Eletcric Ibsurcb andMTd3pnEc (USA)

amwlidacioa-?ial co.(USA)

xac@rMtlOMl YUraac8 QuipmncCo. , Ltd.

Burua of Miae8/zBDA (USA)

Unkawo (a~y)

U.C. I ● Corp. /mPoat

-r * Co. (USA).

(USA)

Applied T8cbaolou (uDA)

u~

British Gas Council (CB)Lurgi Mlnara161technik (W. Garmany)

Grand ?orkg Sxwrgy ResaarchCareer/ERM (USA)

un&oun

Pre9at m9weld operation

tru~c co98rcbl o~ration

Prssenc c-mid o p e r a t i o n

Pres8at c~rcld op~racion

?reaeac drnnscraclon unit testing;~rcldly awalhblc

P r~e dovalo~c unit casctig

Dmmscratlon uaic pbaoad

Pm-t d@v910puat Uait tcscins ;c~rchuy ● vallabla

Pr~ I 1 8 v ’ d o m e Uait tasting

Pr~t devdop9mc unit tasting

Pr8sent d8v9hpuat de tucq

?alsc ~rcid op8r8cioa

Pa8c ~rclal operation; amhracicaor coka ouly

rut ~rtlal oparation

rut c~rcial operatiou; cotta o n l y

?-t ~rcial oporacion,

Pr,kt ~rcial oparacifm

Past klopmac tit Cut*

Pr88ant davalopmnc unit cescins

Presmt dwelopmmt unit tasting;llgnicm only

Put c~rcial operacion; coka only

Put c~rcial op@racfon; coka only

B-2

Page 12: APPENDIX TO CHAPTER 5, A: STATUS OF PROCESS …

—. .

Appendix B-2 : Continued

POPULATION OF LOW/MEDIUM-BTU GASIFIERS

Gasifier type

Gasifier name Licenser/Developer Status

Fluidized-Bed, Dry Ash

Winkler

Hygas

Synthane

Hydrane

Cogas

Exxon

BCR Low-Btu

CO2 Acceptor

Electrofluidic Gasification

LR Fluid Bed

~ Fluidized Bed

BAs?-nasch-ouag

CZCB Marchuood

Edlar

?luidlzed-Bed, Axglomracing Ash

Bactmlle/Carbide

Westinghouse

City Collage of MY Mark 1

Ttm-atag8 ?luidized

ICI -ti~ Burden

Entraiaed-Bed, Dry Ash

Carmct Flash Pyrolysis

Bianchi

Uavp Pouorgaa Co. (USA)

Institute of &s T8chnolocY (Ufi)

Pittsburgh EnergyCentsr/ER.DA (USA)

Pittsburgh Energy

Concm/ERDA (USA)

Cogaa Dsvelopmelac

-n Corp. (USA)

!bmareh

Research

Co. (USA)

Bitwinous Coal Ressarch (USA)

Consolidation coal co. (USA)

Iowa Scat@ Univ./ERDA (USA)

unkaoun(Cmsany)

Hydrocarbon Besaarch Inc. (Uw)

Badisclm Aail.irI und Soda ?abrik(Uestceraany)

UnkaouuUllkaouu(timany)

Iastituca of Gas Technology

Bsctalla hrial Instituta

Westingbousa Electric Corp.

Rydrocarboa Research Inc./A.M. Squires (USA)

(USA)(USA)

(USA)

British Gas Council (England)

Isperial Chemical Induscrias, Ltd.(England)

Prasent

Present

Prssent

Present

Pre8ent

Present

Prssenc

Presmnc

Present

Ps8t

Past

Past

Past

Put

comercial operacion

devologment unit testing

devalopmonc unit tuctng

developaanc unit tescing

development unit cesting

developmsnc unit tsscing

development unit cescing

devslopmenc unic cescing

develo~nt unit cescing

comercid oporacion

development unit tescing

developnnt unit testing

d@v@W=nc unit tasttig

davelopwnt unit tescing

Prmoanc davalopmenc unit r e s t i n g

Presanc devalopmnt uni t testing

Presanc development unit tescing

Present davelopmenc unit csseing

Present devalopwnc unit testing

Pasc dcvelopwnt unit t e s t i n g

Garrect Research and Development Present development unit tsscingco. (USA)UnhOun (France) Past development unit testing;

llgnlce only

B-3

Page 13: APPENDIX TO CHAPTER 5, A: STATUS OF PROCESS …

Appendix B-2 : Continued

POPULATION OF LOIJ/MEDIUM-BTU GASIFIERS

..—~s~fl~r tYD~

tisifiar nam Licenser/Developer status

?aoindeo

UBSM Anau&r titort

UBBM Electrically Eucti

Cacrained-lhd, SlmtSinU Ash

Eeppers=Totx@k

Bi-Cu

T~o

@alu

?AIEO/Po8c8r Uh-lcr

~~~ ~w

BtimYotmguttlTer8ity

Bakockcnduilcox

hhr~Vortex

~Cy~er

In&ndsta*l

m?krwcoum

Crest Borthrn Sdhmy

PM cyc100a

lbltm ltcdia, Slamiax Ash

Kahm Mlteo Sdt

Atga8/Pacw

Bsckgas

-L Sit@e Shaft

S- Guifiacion

Otto-*l Doubla Shaft

Oaknoun (France)

Btuaauotnin8*/BRDA(usA)

Buro8u of MlnedSRDA (USA)

Koppsra co., (USA)

Bittminouc Coal Rasearch, Ioc.(USA)Texaco OCvdopmllt amp. ( U S A )

Pittsburgh ● od RI*8Y Coal Co. /

?st= Wlmalsr (USA)

Brl@m Youq !hdwrmitylBimmiwu8 M lbaarcb (USA)

Y&9 Babcock 4 Wucox co. (USA)

Iasticuta of Cu Toch8010gy (USA)~ stad co. (USA)

lbr~touo bs~ Bssurchhc8r/mnA (USA)Crau Borthara Bailway Co. (USA)

Umbom (Eagland)

n. w. tillou co. (USA)

Applld Tachoolom Corp. (USA)

At-es Iatarmthul (USA)

Union BJmlaischo Braun Kohlenti@ftStOff A. G. (west h-y)

Suo &8urch and Osvalopmsnc Co.(USA)

Dr. C. Otto cad Co.

Past dmmlepment unit tcscing;limito only

Pasc dovelopwnt uait tascing;Llmice only

Puc dovelop9cnc unit Ccscing

Prao8ac cmrcial operation

Prrnut devalopmcnt uni t cascing

Presmc dmmlopwnt unit e a t i n g

Pruant dmmlopunc unit cescing;~rcially ● milabla

Prao-t davalopunt unit cestin~

Pramc demlopmait unit cest:n~

?~ drnlo~ unit eating

Past c~rcti operation

?a8t c~rcial oparacioa

Pastdevelopment unit testing

Past dcvdopment Uait Cmcillg

Put d@w910p9mt de tasclng

Paat dav,lopunt tit tuciq

Put dovd~t unit teacing

Pmsmt development unit testing

Pruont daveio~t unit tasting

Prasaat development unit cescing

Pa8t comcrcial operation

PUC davolopment uni t cescing

Past development unit tesclrq

B-4 ej b~a

Page 14: APPENDIX TO CHAPTER 5, A: STATUS OF PROCESS …

APPENDIX TO CHAPTER 5, C

COOPERATIVE AGREEMENTS AND FEASIBILITYSTUDY GRANTS FOR SYNFUELS

(Source: U.S. DOE 7/80)

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Page 15: APPENDIX TO CHAPTER 5, A: STATUS OF PROCESS …

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Page 16: APPENDIX TO CHAPTER 5, A: STATUS OF PROCESS …

Wycoal Gas $13,155,000 Wycoal plans to construct a facility using Lurgi andTexaco gasification units to process 16,000 tons ofsub-bituminous coal daily to produce high Btu gas.All liquid by-products will also be gasified. Thefacility is to be located in Douglas, Wyoming. TheStatement of work proposed will involve developing adefinitive basis for plant design estimating costs,securing permits and approvals, obtaining financingand identifying long-lead delivery items. There isa market for the SNG via a pipeline system to the#midwest owned by the participants. The project wouldproduce the equivalent of 51,000 barrels of oil per

. day.

m FEASIBILITY STUDY GRANTS

TECHNOLOGY..——.-.——-—!

REQUESTED FROM DOE “. - — — . — — — DESCRIPTI0N/SITE— — — . —— — — .—— —

.

Coal Liquids

Cook Inlet Region $3,900,000 Feasibility study of producing 54,000 barrels per dayAnchorage, Alaska 99509 of methanol from low sulfur coal using Winkler gasi-

fier and ICI methanol synthesis.Site: West side of Cook Inlet, Alaska

W . R. Grace $786,477 ‘Stage 111 of a feasibility study of a coal sourcedDenver, Colorado 80223 methanol plant using a Koppers/Totzek Gasifier.

Site: Moffat County, NW Colorado

Clark Oil & Refining $4,000,000 Feasibility study of producing synthesis gas fromMilwaukee, Wisconsin 53227 coal, steam, oxygen & methanol from synthesis gas

using a KT Gasifier, ICI & the Mobil M Process.Site: S. Illinois

Page 17: APPENDIX TO CHAPTER 5, A: STATUS OF PROCESS …

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Page 20: APPENDIX TO CHAPTER 5, A: STATUS OF PROCESS …

Republic of Texas CoalCo. and Mitchell EnergyCorp.Houston, Texas 77002

Mountain Fuel Supply Co. $1,810,762Salt Lake City, Utah 84139

Peat. — —

Minnesota Gas Co.Minneapolis, Minnesota55402

$3,996,554

Feasibility study of gasification, in-situ deepTexas lignite and conversion of remaining mediumBtu synthesis gas to methanol and high octane gasoline.Site: Calvert, Robertson County, Texas

Two-year feasibility study of unconventional naturalgas in the Pinedale field. Product is natural gasand condensate.Site: Sublette County, Wyoming

Nineteen month feasibility study for the production ofhigh Btu substitute natural gas from peat.Site: Minnesota

nI Shale Liquid Upgrading< .——..——

,Union Oil Energy Mining $4,000,000 Feasibility study for operation of a 10,000 BPD up-Los Angeles, CA 90017 grading plant producing premium quality syncrude.

Site: Grand Valley, Colorado

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Page 21: APPENDIX TO CHAPTER 5, A: STATUS OF PROCESS …

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