380 Harvey Road Manchester New Hampshire 03103-3347 603-623-3600 FAX 603-624-9463 wwwgzacom

I AR-1317 GZA

IncGeoEnvironmental and Engineers

Scientists

VIAEMAn

2012 27 April 00 040029307 No File

Kudrick Bruce Mr Commission Sewer Hooksett Superintendent

Hooksett of Town Drive Egawes 1

03106 Hampshire New Hooksett

Report Data Analytical e RWastewater Treated

Station Merrimack Hampshire New of Service Public

Hampshire New Bow

Bruce Dear

pleased s iInc Environmental Geo GZA (PSNH) Hampshire New of Service Public of behalf On 12205 January on conducted sampling for rt epoRData Analytical attached the submit to

metals low extremely of anticipation In 2012 16 January on submitted previously PA) E(Agency Protection Environmental by performed was analysis previous the concentrations

Inductively by detection metals enable to EPA by developed specifically was which 1638 Method water ambient in concentrations low extremely at (ICP-MS) Spectrometry PlasmaMass Coupled

for Water Ambient Sampling 1669 Method sampling with conjunction in used when Levels Criteria Quality Water EPA at s lMetaTrace of Determination

in time hold sample the within 2008MOD Method using reanalyzed were metals Total sampling any that ring requi001 -WDANo Agreement Disposal Waste with accordance specified is method This 136 CFR 40 to conform methods analytical and handling preservation

of analysis metals trace for (SOP) Procedure Operating Standard draft EPA States United the in below discussed is SOP The wastewater (FGD) desulfurization gas flue

DISCUSSION ANALYTICAL

for interference matrix overcome to techniques analytical specialized ires requwastewater FGD excerpt an offer we further issue this evaluating in you assist To metalstrace of analysis certain

of analysis metals trace for SOP draft their to link a and site web EPA the from below guidance further contains that wastewater FGD

WASTEWATER FGD OF ANALYSIS LABORATORY

interferences matrix cause to known constituents contain can systems FGD from Wastewater commonly elements certain ater tewaswFGD of analysis MS -ICPduring that observed has EPA

andor detection the as ibthat inteiferences polyatomic cause may wastewater the in sent presignificant become may interferences potential These interest of elements certain of quantization

range on iper-bill-partslow the in concentrations at elements trace measuring when

Copyrightcopy 2012 GZA GeoEnvironmental Inc

An Equal Opportunity Employer MFVH

Wimtlpesaukee River Basin Program Wastewater Treatment Plant File No 04002930700

April 27 2012 Page2

As part of a recent sampling effort for the steam electric power generating effluent guidelines rulemaking EPA developed an SOP that was used in conjunction with EPA Method 2008 to conduct ICP-MS analyses of FGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater EPA regulations at 40 CFR 1366 already allow the analytical community flexibility to modify approved methods to lower the costs of measurements overcome matrix interferences or otherwise improve the analysis The draft SOP developed for FGD wastewater takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (ie a synthetic FGD wastewater matrix) EPAs draft SOP is being made available to laboratories contemplating ICP-MS analysis of FGD wastewater either for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOP For further information see

Standard Operating Procedure Inductively Coupled PlasmaMass Spectrometry for Trace Element Analysis in Flue Gas Desulfurization Wastewaters (30 pp 174K) httpwaterepagovscitechlwastetechguideuploadsteam_draft_soppdf EPA May 2011

Considering that specialized analytical techniques are necessary to overcome matrix interference for certain analysis of trace metals in FDG wastewater we recommend any analysis on FGD wastewater be conducted in accordance with the EPA draft SOP for trace metals analysis ofFGD wastewater

Should you have any questions concerning thls report please do not hesitate to contact me at (603) 232-8744

Very truly yours

OZA GEOENVIRONMENTAL INC

Ronald A Breton P E Principal

Michael P North P E ConsultantReviewer

RABMPNtmd IIGZAMANlobltll)IJobs002930004002930700WorkSAMPUNG AND REPORTINGREPORTSHoolslaquotfin~ 04002930700 -1OIOS12 042712docgt

Attachment Analytical Data Report

Wimtlpesaukee River Basin Program Wastewater Treatment Plant File No 04002930700

April 27 2012 Page2

As part of a recent sampling effort for the steam electric power generating effluent guidelines rulemaking EPA developed an SOP that was used in conjunction with EPA Method 2008 to conduct ICP-MS analyses of FGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater EPA regulations at 40 CFR 1366 already allow the analytical community flexibility to modify approved methods to lower the costs of measurements overcome matrix interferences or otherwise improve the analysis The draft SOP developed for FGD wastewater takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (ie a synthetic FGD wastewater matrix) EPAs draft SOP is being made available to laboratories contemplating ICP-MS analysis of FGD wastewater either for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOP For further information see

Standard Operating Procedure Inductively Coupled PlasmaMass Spectrometry for Trace Element Analysis in Flue Gas Desulfurization Wastewaters (30 pp 174K) httpwaterepagovscitechlwastetechguideuploadsteam_draft_soppdf EPA May 2011

Considering that specialized analytical techniques are necessary to overcome matrix interference for certain analysis of trace metals in FDG wastewater we recommend any analysis on FGD wastewater be conducted in accordance with the EPA draft SOP for trace metals analysis ofFGD wastewater

Should you have any questions concerning thls report please do not hesitate to contact me at (603) 232-8744

Very truly yours

OZA GEOENVIRONMENTAL INC

Ronald A Breton P E Principal

Michael P North P E ConsultantReviewer

RABMPNtmd IIGZAMANlobltll)IJobs002930004002930700WorkSAMPUNG AND REPORTINGREPORTSHoolslaquotfin~ 04002930700 -1OIOS12 042712docgt

Attachment Analytical Data Report

ANALYTICAL DATA REPORT

~+J___________e_a_s_t_e_rn_a_n_a_ly_t_i_c_a_l_ bull -(~1 1

1 1 1 ~ 1 middot bull 0

middot 1middot 1 middot 1

Paul Pepler

GZA GeoEnvironmental Inc (NH)

380 Harvey Road

Manchester NH 03103

Subject Laboratory Report

Eastern Analytical Inc ID 107555 Client Identification Merrimack Station

Date Received 152012

Dear Mr Pepler

Enclosed please find the report of analysis for the above identified project As discussed analyses were subcontracted and are listed as follows

Analysis Subcontract - Metals Method 2008

(AlSbBaBeCdCaCrCuFePbMnMoNaNiAgTlZnAsSe amp Hg)

Subcontractor Lab Frontier Global Sciences Inc

A complete copy of the report is attached This report may not be reproduced except in full without the written approval of the laboratory

We appreciate this opportunity to be of service and look forward to your continued patronage

Sincerely

Lorraine Olashaw Lab Direc r Date of pages (excluding cover letter)

- ~ I i c1ihbsw111

SAMPLE CONDITIONS PAGE EAi ID 107555

Client GZA GeoEnvironmental Inc (NH)

Client Designation Merrimack Station

Temperature upon receipt (degC) 47 Received on ice or cold packs (YesNo) Y Acceptable temperature range (0 C) 0-6

Date Date Sample Dry Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation) Lab ID Sample ID

10755501 Treat Tank Eff Composite 1512 1512 aqueous Adheres to Sample Acceptance Policy

10755502 Treat Tank Eff Grab 1512 1512 aqueous Adheres to Sample Acceptance Policy

Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis of solids for pH Flashpoint lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an as received basis

All results contained in this report relate only to the above listed samples

References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992

eastern analytical inc wwweailabscom Phone (603) 228-0525 1

~+J___________e_a_s_t_e_rn_a_n_a_ly_t_i_c_a_l_ bull -(~1 1

1 1 1 ~ 1 middot bull 0

middot 1middot 1 middot 1

Paul Pepler

GZA GeoEnvironmental Inc (NH)

380 Harvey Road

Manchester NH 03103

Subject Laboratory Report

Eastern Analytical Inc ID 107555 Client Identification Merrimack Station

Date Received 152012

Dear Mr Pepler

Enclosed please find the report of analysis for the above identified project As discussed analyses were subcontracted and are listed as follows

Analysis Subcontract - Metals Method 2008

(AlSbBaBeCdCaCrCuFePbMnMoNaNiAgTlZnAsSe amp Hg)

Subcontractor Lab Frontier Global Sciences Inc

A complete copy of the report is attached This report may not be reproduced except in full without the written approval of the laboratory

We appreciate this opportunity to be of service and look forward to your continued patronage

Sincerely

Lorraine Olashaw Lab Direc r Date of pages (excluding cover letter)

- ~ I i c1ihbsw111

SAMPLE CONDITIONS PAGE EAi ID 107555

Client GZA GeoEnvironmental Inc (NH)

Client Designation Merrimack Station

Temperature upon receipt (degC) 47 Received on ice or cold packs (YesNo) Y Acceptable temperature range (0 C) 0-6

Date Date Sample Dry Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation) Lab ID Sample ID

10755501 Treat Tank Eff Composite 1512 1512 aqueous Adheres to Sample Acceptance Policy

10755502 Treat Tank Eff Grab 1512 1512 aqueous Adheres to Sample Acceptance Policy

Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis of solids for pH Flashpoint lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an as received basis

All results contained in this report relate only to the above listed samples

References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992

eastern analytical inc wwweailabscom Phone (603) 228-0525 1

SAMPLE CONDITIONS PAGE EAi ID 107555

Client GZA GeoEnvironmental Inc (NH)

Client Designation Merrimack Station

Temperature upon receipt (degC) 47 Received on ice or cold packs (YesNo) Y Acceptable temperature range (0 C) 0-6

Date Date Sample Dry Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation) Lab ID Sample ID

10755501 Treat Tank Eff Composite 1512 1512 aqueous Adheres to Sample Acceptance Policy

10755502 Treat Tank Eff Grab 1512 1512 aqueous Adheres to Sample Acceptance Policy

Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis of solids for pH Flashpoint lgnitibility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an as received basis

All results contained in this report relate only to the above listed samples

References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992

eastern analytical inc wwweailabscom Phone (603) 228-0525 1

11 720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996~ Fx 425-686-3096 GLOBAL SC I ENCES

25 April 2012

JeffGagne

Eastern Analytical Inc

25 Chenell Drive

Concord NH 03301

RE Merrimack Station

Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control

measurements are within established control limits and there were no analytical difficulties encountered

with the exception of those listed in the case narrative section of this report

Ifyou have any questions concerning this report please feel free to contact me

Sincerely

Liz Siska

Project Manager

2

11720 North Creek Park-way North Suite 400 BotheII WA 98011

Ph 425-686-1996

FRONTIERmiddotmiddot Fx 425-686-3096 GLOBAL SCIENCES

ANALYTICAL REPORT FOR SAMPLES

Laboratory Frontier Global Sciences Inc SDG

Client Eastern Analytical Inc Project Merrimack Station

Sample [D Lab ID Matrix Date Sampled Date Received

Treat Tank EffComposite 1201073-01 Water 05-Jan-12 1000 06-Jan-12 0950

Treat Tank Eff Grab 1201073-02 Water 05-Jan-l2 08 00 06-Jan-l 2 0950

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in 1his report only apply to the samples analyzed in accordance with the chain ofcustody documenL This analytical reporl must be reproduced in its entirety

Page J o26 1201073 Final Report 04252012 3

11720 North Creek Park-way North Suite 400 BotheII WA 98011

Ph 425-686-1996

FRONTIERmiddotmiddot Fx 425-686-3096 GLOBAL SCIENCES

ANALYTICAL REPORT FOR SAMPLES

Laboratory Frontier Global Sciences Inc SDG

Client Eastern Analytical Inc Project Merrimack Station

Sample [D Lab ID Matrix Date Sampled Date Received

Treat Tank EffComposite 1201073-01 Water 05-Jan-12 1000 06-Jan-12 0950

Treat Tank Eff Grab 1201073-02 Water 05-Jan-l2 08 00 06-Jan-l 2 0950

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in 1his report only apply to the samples analyzed in accordance with the chain ofcustody documenL This analytical reporl must be reproduced in its entirety

Page J o26 1201073 Final Report 04252012 3

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

GLOBAL SCIENCES

CASE NARRATIVE

Revised Report 42512

Per client request Boron was removed from report

Revised Report 32812

Per client request samples were prepared and analyzed for total metals in accordance with EPA 2008 (modified)

SAMPLE RECEIPT

Samples were received at Frontier Global Sciences (FGS) on January 6th 2012 The samples were received intact on-ice with temperatures measured at 34 degrees Celsius

SAMPLE PREPARATION AND ANALYSIS

Samples were prepared and analyzed for total metals in accordance with FGS-054EPA 1638

Samples were prepared and analyzed for total mercury in accordance with EPA Method 163lE

ANALYTlCAL AND QUALITY CONTROL ISSUES

There were no analytical difficulties experienced with analysis of these samples with the exceptions flagged in the report

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 2of26 1201073 Final Report 04252012 4

Liz Siska Project Manager

4 P_ ~v N SbullJt~ Pticzi bullY~- ~middot~-S~t~I~ -~r ) lt-~ 5-=tiiIWTts Pli~ a1d A-~~~l Tssmiddot~

~-ydc1rc~ G (ihr ~71micro1e~ FRONTIER (1 i lot jf it( r ff li bull

tmiddot~~middotpound~middotr~ix r11libullw Frf ) ~1$cr

Frontier Global Sciences Inc The results in this report only opply to the samples analyzedin accordance with the chain ofcustody documem This analytical report must be reproduced in its entirety

Page 3 o26 1201073 Final Report 042512012 5

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 98011~ Ph 425-686-1996

FRONTIER Fx 425-686-3096 GLOBAL SCIENCES

CHAIN OF CUSTODY FORMS

Frontier G lobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody documenL This analytical report must be reproduced in its entirety

Liz Siska Project Manager

I I 720 North Creek Parkway North Suite 400 Bothell WA 98011

~ Ph 425-686-1996

ltoNTIEitmiddotmiddotmiddot Fx 425-686-3096 G LO 8 AL SC IE NC ES

ANALYTICAL RESULTS

Treat Tank Eff Composite

Matrix Water Laboratory ID 1201073-01

Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes

Aluminum ND 89 800 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Antimony 0408 0092 0400 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod

Barium 240 054 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Beryllium ND 0454 l20 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Cadmium ND 0083 0400 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Calcium 5010000 16200 200000 microgL 5000 F20327l 2C22005 032212 EPA 2008 Mod

Chromium ND 018 2 00 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Iron ND 260 2middot00 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Manganese 280 015 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Molybdenum 134 012 l20 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Nickel 979 016 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Silver ND 0120 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Sodium 259000 23 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Thallium 556 0250 100 microgL 100 F203314 2C25005 032512 EPA 2008 Mod

Zinc ND 033 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u

Page 4of26 1201073 Final Report 042512012 6

GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 BotheUI WA 98011

Ph 425-686-1996 Fx 425-686-3096

ANALYTICAL RESULTS

Treat Tank Eff Grab

Matrix Water Laboratory ID 120) 073-02

Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes

Arsenic 851 102 300 microgL 20 F20327 l 2C22005 032212 EPA 2008 Mod

Mercury 105 034 202 ngL 4 F20 I063 2A09010 010912 EPA 1631E FB-163 1

Selenium 689 388 120 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody docwnent This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 5 of26 1201073 Final ampport04251202 7

Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in acccrdance with the chain ofcustody document This analytical report must be reproduced in irs entirety

Liz Siska Project Manager

11720 North Creek Parkway No1th Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

GLOBgtAL SCIENCES

MATRIX DUPLICATESffRIPLICATES

SOURCE 1201073-02

Batch F201063

Preparation BrCI Oxidation

Sequence 2A09010

Lab Number F20I063-DUP1

Sample Duplicate Concentration Concentration RPD

Analyte ogL ngL MRL RPD

0617

Limit

24

Method

EPA 163IE

Notes

Mercury 1048 1054 202

Page 6026 J20107 3 Final Report 04252012 8

--=W- - FRONT~

GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 9801 1

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-02

Batch F20 I063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 I 063-MSMSDl

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ngL) (ngL) (ngL) Recovery Method Notes Limits

Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

Spike MSD MSD Recovery RPD Added Concentration Oo

RPD Limits Limit Method Notes (ngL) (ngL) Recovery Analyte

Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in 1his report only apply to 1he samples analyzed in accordance wilh 1he chain ofcustody document This analytical report must be reproduced in its e1tirety

Page 7 of26 1201073 Final Report 04252012 9

11720 North Creek Parkway North Suite 400 Bothell WA 98011~ Ph 425middot686-1996 ~rn-middot Fx 425-686-3096

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1112278-02

Batch F201063 Sequence 2A02010

Prepar-ation BrCI Oxidation Lab Number F201063-MSMSD2

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ogL) (ngL) (ngL) Recovery Method Notes Limits

Mercury 761 20400 2786 992 71- 125 EPA 1631E

Spike MSD MSD Recovery RPDAdded Concentration

RPD Limits Limit Method Notes(ngL) (ngL) RecoveryAnalyte

Mercury 20400 2837 102 l82 71 - 125 24 EPA I631E

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accorda11ce with the chain ofcuslOdy document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page8of26 1201073 Final Report 04252012 10

11720 North Creek Pari-way North Suite 400 BotheI WA 98011

Ph 425-686-1996 Fx 425-686-3096

GLOSAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201029-01

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 I 063-MSMSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ngL) (ngL) (ngL) Recovery Limits Method Notes

Mercury 534 10200 1558 JOO 71 - 125 EPA 1631E

Spike MSD MSD Oo Recovery RPDAdded Concentration

RPO Limits Limit Method Notes(ngL) (ngL) RecoveryAnalyte

Mercury 10200 1407 85 6 102 71 - 125 24 EPA 163JE

F The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

L

rontier Global Sciences Inc

iz Siska Project Manager Page 9of26 1201073 Final Report 042512012 1 1

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096~

GL06Al SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201030-02

Batch F20 I063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F201063-MSMSD4

Analyte

Sample Concentration

(ngL)

Spike Added (ngL)

MS Concentration

(ngL)

MS Oo

Recovery Recovery

Limits Method Notes

Mercury

Analyte

554

Spike Added (ngL)

10200

MSD Concentration

(ngL)

1482

MSD oo

RPD Recovery

910 71 - 125 EPA 1631E

Recovery Limits

RPO Limit Method Notes

Mercury 10200 1461 890 140 71 - 125 24 EPA 1631E

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager PagelO o26 1201073 Final Report 04125202 12

J1720 North Creek Parkway North Suite 400 l Bothell WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD1

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Calcium 5013000 15150 4802000 -13900 70 - 130 EPA 2008 Mod QM-02

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery

Limits RPDLimit Method Notes

Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this leport only apply to he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 11 o26 201073 Final Report 042512012 13

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody docwnenL This analytical report must be reproduced in its entirety

-I~ __-d-lt-~-- ~

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 ~~ Bothell WA 98011

Ph 425-686-1996 -- _ - - --- -~ FRONTIER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

13atch F20327I Sequence 2C22005

Preparation Closed Vessel Nitric Qven Digestion Lab Number f20327 l-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2442 958 70 130 EPA 2008 Mod

Sodium 258800 50500 257700 -213 70 - 130 EPA 2008 Mod QM-02

Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod

Chromium 057 70700 804 106 70 130 EPA 2008 Mod

Manganese 280S 60600 2834 476 70 - 130 EPA 2008 Mod QM-02

Tron ND 50500 5200 103 70 - 130 EPA 2008 Mod

Nickel 979 40400 141 1 107 70 130 EPA 2008 Mod

Copper 055 40400 434 939 70 - 130 EPA 2008 Mod

Zinc 040 10100 842 794 70- 130 EPA 2008 Mod

Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod

Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod

Molybdenum 1338 20200 1367 142 70- 130 EPA 2008 Mod QM-02

Silver ND 15150 l388 916 70 - 130 EPA 2008 Mod

Cadmium 0332 080800 1105 956 70 - 130 EPA 2008 Mod

Antimony 0408 0 80800 1259 105 70 - 130 EPA 2008 Mod

Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod

Lead ND 15150 l542 102 70- 130 EPA 2008 Mod

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits

RPDLimit Method Notes

Beryllium 20200 2561 102 474 70 130 20 EPA 2008 Mod

Sodium 50500 257100 -336 0243 70 130 20 EPA 2008 Mod QM-02

Aluminum 15I50 2034 993 0564 70 130 20 EPA 2008 Mod

Chromium 70700 773 101 385 70 130 20 EPA 2008 Mod

Manganese 60600 2852 769 0625 70 130 20 EPA 2008 Mod

Iron 50500 5187 103 0242 70 130 20 EPA 2008 Mod

Nickel 40400 1381 995 21 3 70 - 130 20 EPA 2008 Mod

Copper 40400 419 902 347 70 130 20 EPA 2008 Mod

Zinc 10100 916 868 849 70 130 20 EPA 2008 Mod

Arsenic 15150 2225 789 831 70 - 130 20 EPA 2008 Mod

Selenium 30300 9400 101 464 70 130 20 EPA 2008 Mod

Molybdenum 20200 1366 137 00771 70 130 20 EPA 2008 Mod QM-02

shy

shyshyshy

shyshy

shy

shy

shy

shy

Page 12 o26 1201073 Final Report 04252012 14

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~~ Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits

RPD Limit Method Notes

Silver 15150 1387 915 00874 70 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 130 20 EPA 2008 Mod Antimony 080800 l274 107 121 70 - 130 20 EPA 2008 Mod Barium 10100 2514 116 0781 70 130 20 EPA 2008 Mod

Lead 15150 1534 101 0525 70 130 20 EPA 2008 Mod

shy

shy

shy

shy

Frontier Global Sciences Inc The results 11 this report only apply to the samples analyzed in accordance bull~ith the chain ofcusLOdy documenL This analytical repogt1 must be reproduced in its entirety

Page 13 o26 1201073 Final Report 04252012

Liz Siska Project Manager

15

11720 North Creek Parkway North Suite 400 Bothell WA 98011~~Lshy

Ph 425-686-1996 Fx 425-686-3096middot~RONTIE~

GLOBAL SCIENCES

MATRIX SPIKE MA TRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327l-MS1MSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte Method Notes (11gL) (microgL) (microgL) Recovery Limits

100 70 - 130 EPA 2008 Mod AS Calcium 5013000 10100000 15120000

Spike MSD MSD Recovery RPDAdded Concentration Oo oo

RPO Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte

Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS

The results in 1his report only apply to 1he samples analyzed in accordanet wtth IheFrontier Global Sciences Inc chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager

Page 14 o26 1201073 Final Report 042512012 16

Frontier Global Sciences Inc The results in this report only apply ta the samples analyzed in accordance 1Yith the chain ofcustody documenL This analytical report must be reproduced in its entirety

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l ~ Ph 425-686-1996

~IER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD4

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2041 985 70 - 130 EPA 2008 Mod AS Sodium 258800 40400 292900 845 70 - 130 EPA 2008 Mod AS

Aluminum 529 40400 3956 966 70 130 EPA 2008 Mod AS

Chromium 057 40400 4301 106 70 130 EPA 2008 Mod AS

Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS

Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS

Nickel 979 50500 51 12 993 70- 130 EPA 2008 Mod AS Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS

Zinc 040 10100 9074 898 70 -130 EPA 2008 Mod AS

Arsenic 1030 40400 4317 104 70 - 130 EPA 2008 Mod AS Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS

Molybdenum 1338 20200 338l 101 70 130 EPA 2008 Mod AS Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS

Cadmium 0332 40400 3937 966 70 - 130 EPA 2008 Mod AS Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS Barium 2397 80800 1056 101 70 - 130 EPA 2008 Mod AS Lead ND 10100 9932 983 70 - 130 EPA 2008 Mod AS

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits

RPO limit Method Notes

Beryllium 20200 2007 968 171 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 - 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 l40 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 -130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 -130 20 EPA 2008 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 bull 130 20 EPA 2008 Mod AS

shy

Page 15 o26 1201073 Final Report 041252012 17

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

CLOBA L SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number J20327 l -MSMSD4

Analyte

Silver

Spike Added (microgL)

20200

MSD Concentration

(microgL)

MSD Oo

Recovery

RPO

Recovery Limits

RPOLimit Method Notes

1895 93 8 242 70 -130 20 EPA 2008 Mod AS

Cadmium 40400 3933 965 0104 70 - 130 20 EPA 2008 Mod AS

Antimony 20200 2107 102 0736 70 shy 130 20 EPA 2008 Mod AS

Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS

Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report 01ry apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 16026 1201073 Final Report 04252012 18

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096FRONTlEit

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo RPD

Recovery Limits

RPDLimit Method Notes

Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 17 o26 1201073 FinaReport 0412512012 19

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE I201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD4

Sample Spike MS MS

Analyte Concentration

(microgL) Added (iagL)

Concentration (microgL)

Oo

Recovery Recovery

Method Limits Notes

Thallium 5563 10100 1033 968 70 - 130 EPA 2008 Mod AS

Spike Added

MSD Concentration

MSD 0o Recovery RPO

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Thallium 10100 1037 971 0341 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This anayzical report must be reproduced in its entirely

Liz Siska Project Manager Page 18af26 1201073 Final Report 042512012 20

11720 North Creek Parkway North Suite 400 ~k~~ Bothell WA 98011

Ph 425-686-I 996 ~ONTI~ Fx 425-686-3096

GLOBAL S C IENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 1063-BSBSD1

LCS Source Nist 1641d

Analyte

Mercury

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1550

LCS Oo

Recovery

988

Recovery Limits

80 shy 120

Method

EPA I63I E

Notes

Analyte

Mercury

Spike Added ngL)

15679

LCSD Concentration

(ngL)

1595

LCSD Oo

Recovery

102

Oo

RPD

289

Recovery Limits

80 - 120

RPD Limit

24

Method

EPA 163IE

Notes

Frontier Global Sciences Inc The results in this repori only apply to the samples analyzed in accordance with the chain ofcustody document This analy1ical reporl must be reproduced in its entirety

Liz Siska Project Manager Page 19026 120l 07 3 Final Report 042512012 21

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

4 P_ ~v N SbullJt~ Pticzi bullY~- ~middot~-S~t~I~ -~r ) lt-~ 5-=tiiIWTts Pli~ a1d A-~~~l Tssmiddot~

~-ydc1rc~ G (ihr ~71micro1e~ FRONTIER (1 i lot jf it( r ff li bull

tmiddot~~middotpound~middotr~ix r11libullw Frf ) ~1$cr

Frontier Global Sciences Inc The results in this report only opply to the samples analyzedin accordance with the chain ofcustody documem This analytical report must be reproduced in its entirety

Page 3 o26 1201073 Final Report 042512012 5

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 98011~ Ph 425-686-1996

FRONTIER Fx 425-686-3096 GLOBAL SCIENCES

CHAIN OF CUSTODY FORMS

Frontier G lobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody documenL This analytical report must be reproduced in its entirety

Liz Siska Project Manager

I I 720 North Creek Parkway North Suite 400 Bothell WA 98011

~ Ph 425-686-1996

ltoNTIEitmiddotmiddotmiddot Fx 425-686-3096 G LO 8 AL SC IE NC ES

ANALYTICAL RESULTS

Treat Tank Eff Composite

Matrix Water Laboratory ID 1201073-01

Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes

Aluminum ND 89 800 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Antimony 0408 0092 0400 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod

Barium 240 054 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Beryllium ND 0454 l20 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Cadmium ND 0083 0400 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Calcium 5010000 16200 200000 microgL 5000 F20327l 2C22005 032212 EPA 2008 Mod

Chromium ND 018 2 00 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Iron ND 260 2middot00 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Manganese 280 015 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Molybdenum 134 012 l20 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Nickel 979 016 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Silver ND 0120 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Sodium 259000 23 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Thallium 556 0250 100 microgL 100 F203314 2C25005 032512 EPA 2008 Mod

Zinc ND 033 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u

Page 4of26 1201073 Final Report 042512012 6

GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 BotheUI WA 98011

Ph 425-686-1996 Fx 425-686-3096

ANALYTICAL RESULTS

Treat Tank Eff Grab

Matrix Water Laboratory ID 120) 073-02

Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes

Arsenic 851 102 300 microgL 20 F20327 l 2C22005 032212 EPA 2008 Mod

Mercury 105 034 202 ngL 4 F20 I063 2A09010 010912 EPA 1631E FB-163 1

Selenium 689 388 120 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody docwnent This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 5 of26 1201073 Final ampport04251202 7

Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in acccrdance with the chain ofcustody document This analytical report must be reproduced in irs entirety

Liz Siska Project Manager

11720 North Creek Parkway No1th Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

GLOBgtAL SCIENCES

MATRIX DUPLICATESffRIPLICATES

SOURCE 1201073-02

Batch F201063

Preparation BrCI Oxidation

Sequence 2A09010

Lab Number F20I063-DUP1

Sample Duplicate Concentration Concentration RPD

Analyte ogL ngL MRL RPD

0617

Limit

24

Method

EPA 163IE

Notes

Mercury 1048 1054 202

Page 6026 J20107 3 Final Report 04252012 8

--=W- - FRONT~

GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 9801 1

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-02

Batch F20 I063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 I 063-MSMSDl

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ngL) (ngL) (ngL) Recovery Method Notes Limits

Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

Spike MSD MSD Recovery RPD Added Concentration Oo

RPD Limits Limit Method Notes (ngL) (ngL) Recovery Analyte

Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in 1his report only apply to 1he samples analyzed in accordance wilh 1he chain ofcustody document This analytical report must be reproduced in its e1tirety

Page 7 of26 1201073 Final Report 04252012 9

11720 North Creek Parkway North Suite 400 Bothell WA 98011~ Ph 425middot686-1996 ~rn-middot Fx 425-686-3096

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1112278-02

Batch F201063 Sequence 2A02010

Prepar-ation BrCI Oxidation Lab Number F201063-MSMSD2

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ogL) (ngL) (ngL) Recovery Method Notes Limits

Mercury 761 20400 2786 992 71- 125 EPA 1631E

Spike MSD MSD Recovery RPDAdded Concentration

RPD Limits Limit Method Notes(ngL) (ngL) RecoveryAnalyte

Mercury 20400 2837 102 l82 71 - 125 24 EPA I631E

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accorda11ce with the chain ofcuslOdy document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page8of26 1201073 Final Report 04252012 10

11720 North Creek Pari-way North Suite 400 BotheI WA 98011

Ph 425-686-1996 Fx 425-686-3096

GLOSAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201029-01

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 I 063-MSMSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ngL) (ngL) (ngL) Recovery Limits Method Notes

Mercury 534 10200 1558 JOO 71 - 125 EPA 1631E

Spike MSD MSD Oo Recovery RPDAdded Concentration

RPO Limits Limit Method Notes(ngL) (ngL) RecoveryAnalyte

Mercury 10200 1407 85 6 102 71 - 125 24 EPA 163JE

F The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

L

rontier Global Sciences Inc

iz Siska Project Manager Page 9of26 1201073 Final Report 042512012 1 1

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096~

GL06Al SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201030-02

Batch F20 I063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F201063-MSMSD4

Analyte

Sample Concentration

(ngL)

Spike Added (ngL)

MS Concentration

(ngL)

MS Oo

Recovery Recovery

Limits Method Notes

Mercury

Analyte

554

Spike Added (ngL)

10200

MSD Concentration

(ngL)

1482

MSD oo

RPD Recovery

910 71 - 125 EPA 1631E

Recovery Limits

RPO Limit Method Notes

Mercury 10200 1461 890 140 71 - 125 24 EPA 1631E

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager PagelO o26 1201073 Final Report 04125202 12

J1720 North Creek Parkway North Suite 400 l Bothell WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD1

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Calcium 5013000 15150 4802000 -13900 70 - 130 EPA 2008 Mod QM-02

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery

Limits RPDLimit Method Notes

Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this leport only apply to he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 11 o26 201073 Final Report 042512012 13

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody docwnenL This analytical report must be reproduced in its entirety

-I~ __-d-lt-~-- ~

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 ~~ Bothell WA 98011

Ph 425-686-1996 -- _ - - --- -~ FRONTIER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

13atch F20327I Sequence 2C22005

Preparation Closed Vessel Nitric Qven Digestion Lab Number f20327 l-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2442 958 70 130 EPA 2008 Mod

Sodium 258800 50500 257700 -213 70 - 130 EPA 2008 Mod QM-02

Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod

Chromium 057 70700 804 106 70 130 EPA 2008 Mod

Manganese 280S 60600 2834 476 70 - 130 EPA 2008 Mod QM-02

Tron ND 50500 5200 103 70 - 130 EPA 2008 Mod

Nickel 979 40400 141 1 107 70 130 EPA 2008 Mod

Copper 055 40400 434 939 70 - 130 EPA 2008 Mod

Zinc 040 10100 842 794 70- 130 EPA 2008 Mod

Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod

Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod

Molybdenum 1338 20200 1367 142 70- 130 EPA 2008 Mod QM-02

Silver ND 15150 l388 916 70 - 130 EPA 2008 Mod

Cadmium 0332 080800 1105 956 70 - 130 EPA 2008 Mod

Antimony 0408 0 80800 1259 105 70 - 130 EPA 2008 Mod

Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod

Lead ND 15150 l542 102 70- 130 EPA 2008 Mod

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits

RPDLimit Method Notes

Beryllium 20200 2561 102 474 70 130 20 EPA 2008 Mod

Sodium 50500 257100 -336 0243 70 130 20 EPA 2008 Mod QM-02

Aluminum 15I50 2034 993 0564 70 130 20 EPA 2008 Mod

Chromium 70700 773 101 385 70 130 20 EPA 2008 Mod

Manganese 60600 2852 769 0625 70 130 20 EPA 2008 Mod

Iron 50500 5187 103 0242 70 130 20 EPA 2008 Mod

Nickel 40400 1381 995 21 3 70 - 130 20 EPA 2008 Mod

Copper 40400 419 902 347 70 130 20 EPA 2008 Mod

Zinc 10100 916 868 849 70 130 20 EPA 2008 Mod

Arsenic 15150 2225 789 831 70 - 130 20 EPA 2008 Mod

Selenium 30300 9400 101 464 70 130 20 EPA 2008 Mod

Molybdenum 20200 1366 137 00771 70 130 20 EPA 2008 Mod QM-02

shy

shyshyshy

shyshy

shy

shy

shy

shy

Page 12 o26 1201073 Final Report 04252012 14

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~~ Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits

RPD Limit Method Notes

Silver 15150 1387 915 00874 70 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 130 20 EPA 2008 Mod Antimony 080800 l274 107 121 70 - 130 20 EPA 2008 Mod Barium 10100 2514 116 0781 70 130 20 EPA 2008 Mod

Lead 15150 1534 101 0525 70 130 20 EPA 2008 Mod

shy

shy

shy

shy

Frontier Global Sciences Inc The results 11 this report only apply to the samples analyzed in accordance bull~ith the chain ofcusLOdy documenL This analytical repogt1 must be reproduced in its entirety

Page 13 o26 1201073 Final Report 04252012

Liz Siska Project Manager

15

11720 North Creek Parkway North Suite 400 Bothell WA 98011~~Lshy

Ph 425-686-1996 Fx 425-686-3096middot~RONTIE~

GLOBAL SCIENCES

MATRIX SPIKE MA TRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327l-MS1MSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte Method Notes (11gL) (microgL) (microgL) Recovery Limits

100 70 - 130 EPA 2008 Mod AS Calcium 5013000 10100000 15120000

Spike MSD MSD Recovery RPDAdded Concentration Oo oo

RPO Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte

Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS

The results in 1his report only apply to 1he samples analyzed in accordanet wtth IheFrontier Global Sciences Inc chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager

Page 14 o26 1201073 Final Report 042512012 16

Frontier Global Sciences Inc The results in this report only apply ta the samples analyzed in accordance 1Yith the chain ofcustody documenL This analytical report must be reproduced in its entirety

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l ~ Ph 425-686-1996

~IER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD4

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2041 985 70 - 130 EPA 2008 Mod AS Sodium 258800 40400 292900 845 70 - 130 EPA 2008 Mod AS

Aluminum 529 40400 3956 966 70 130 EPA 2008 Mod AS

Chromium 057 40400 4301 106 70 130 EPA 2008 Mod AS

Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS

Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS

Nickel 979 50500 51 12 993 70- 130 EPA 2008 Mod AS Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS

Zinc 040 10100 9074 898 70 -130 EPA 2008 Mod AS

Arsenic 1030 40400 4317 104 70 - 130 EPA 2008 Mod AS Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS

Molybdenum 1338 20200 338l 101 70 130 EPA 2008 Mod AS Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS

Cadmium 0332 40400 3937 966 70 - 130 EPA 2008 Mod AS Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS Barium 2397 80800 1056 101 70 - 130 EPA 2008 Mod AS Lead ND 10100 9932 983 70 - 130 EPA 2008 Mod AS

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits

RPO limit Method Notes

Beryllium 20200 2007 968 171 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 - 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 l40 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 -130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 -130 20 EPA 2008 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 bull 130 20 EPA 2008 Mod AS

shy

Page 15 o26 1201073 Final Report 041252012 17

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

CLOBA L SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number J20327 l -MSMSD4

Analyte

Silver

Spike Added (microgL)

20200

MSD Concentration

(microgL)

MSD Oo

Recovery

RPO

Recovery Limits

RPOLimit Method Notes

1895 93 8 242 70 -130 20 EPA 2008 Mod AS

Cadmium 40400 3933 965 0104 70 - 130 20 EPA 2008 Mod AS

Antimony 20200 2107 102 0736 70 shy 130 20 EPA 2008 Mod AS

Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS

Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report 01ry apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 16026 1201073 Final Report 04252012 18

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096FRONTlEit

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo RPD

Recovery Limits

RPDLimit Method Notes

Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 17 o26 1201073 FinaReport 0412512012 19

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE I201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD4

Sample Spike MS MS

Analyte Concentration

(microgL) Added (iagL)

Concentration (microgL)

Oo

Recovery Recovery

Method Limits Notes

Thallium 5563 10100 1033 968 70 - 130 EPA 2008 Mod AS

Spike Added

MSD Concentration

MSD 0o Recovery RPO

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Thallium 10100 1037 971 0341 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This anayzical report must be reproduced in its entirely

Liz Siska Project Manager Page 18af26 1201073 Final Report 042512012 20

11720 North Creek Parkway North Suite 400 ~k~~ Bothell WA 98011

Ph 425-686-I 996 ~ONTI~ Fx 425-686-3096

GLOBAL S C IENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 1063-BSBSD1

LCS Source Nist 1641d

Analyte

Mercury

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1550

LCS Oo

Recovery

988

Recovery Limits

80 shy 120

Method

EPA I63I E

Notes

Analyte

Mercury

Spike Added ngL)

15679

LCSD Concentration

(ngL)

1595

LCSD Oo

Recovery

102

Oo

RPD

289

Recovery Limits

80 - 120

RPD Limit

24

Method

EPA 163IE

Notes

Frontier Global Sciences Inc The results in this repori only apply to the samples analyzed in accordance with the chain ofcustody document This analy1ical reporl must be reproduced in its entirety

Liz Siska Project Manager Page 19026 120l 07 3 Final Report 042512012 21

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

Frontier G lobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody documenL This analytical report must be reproduced in its entirety

Liz Siska Project Manager

I I 720 North Creek Parkway North Suite 400 Bothell WA 98011

~ Ph 425-686-1996

ltoNTIEitmiddotmiddotmiddot Fx 425-686-3096 G LO 8 AL SC IE NC ES

ANALYTICAL RESULTS

Treat Tank Eff Composite

Matrix Water Laboratory ID 1201073-01

Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes

Aluminum ND 89 800 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Antimony 0408 0092 0400 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod

Barium 240 054 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Beryllium ND 0454 l20 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Cadmium ND 0083 0400 microgL 20 F20327l 2C22005 032212 EPA 2008 Mod u Calcium 5010000 16200 200000 microgL 5000 F20327l 2C22005 032212 EPA 2008 Mod

Chromium ND 018 2 00 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Copper ND 020 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Iron ND 260 2middot00 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Lead ND 0078 0800 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Manganese 280 015 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Molybdenum 134 012 l20 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Nickel 979 016 200 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Silver ND 0120 0400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u Sodium 259000 23 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Thallium 556 0250 100 microgL 100 F203314 2C25005 032512 EPA 2008 Mod

Zinc ND 033 400 microgL 20 F203271 2C22005 032212 EPA 2008 Mod u

Page 4of26 1201073 Final Report 042512012 6

GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 BotheUI WA 98011

Ph 425-686-1996 Fx 425-686-3096

ANALYTICAL RESULTS

Treat Tank Eff Grab

Matrix Water Laboratory ID 120) 073-02

Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes

Arsenic 851 102 300 microgL 20 F20327 l 2C22005 032212 EPA 2008 Mod

Mercury 105 034 202 ngL 4 F20 I063 2A09010 010912 EPA 1631E FB-163 1

Selenium 689 388 120 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody docwnent This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 5 of26 1201073 Final ampport04251202 7

Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in acccrdance with the chain ofcustody document This analytical report must be reproduced in irs entirety

Liz Siska Project Manager

11720 North Creek Parkway No1th Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

GLOBgtAL SCIENCES

MATRIX DUPLICATESffRIPLICATES

SOURCE 1201073-02

Batch F201063

Preparation BrCI Oxidation

Sequence 2A09010

Lab Number F20I063-DUP1

Sample Duplicate Concentration Concentration RPD

Analyte ogL ngL MRL RPD

0617

Limit

24

Method

EPA 163IE

Notes

Mercury 1048 1054 202

Page 6026 J20107 3 Final Report 04252012 8

--=W- - FRONT~

GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 9801 1

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-02

Batch F20 I063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 I 063-MSMSDl

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ngL) (ngL) (ngL) Recovery Method Notes Limits

Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

Spike MSD MSD Recovery RPD Added Concentration Oo

RPD Limits Limit Method Notes (ngL) (ngL) Recovery Analyte

Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in 1his report only apply to 1he samples analyzed in accordance wilh 1he chain ofcustody document This analytical report must be reproduced in its e1tirety

Page 7 of26 1201073 Final Report 04252012 9

11720 North Creek Parkway North Suite 400 Bothell WA 98011~ Ph 425middot686-1996 ~rn-middot Fx 425-686-3096

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1112278-02

Batch F201063 Sequence 2A02010

Prepar-ation BrCI Oxidation Lab Number F201063-MSMSD2

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ogL) (ngL) (ngL) Recovery Method Notes Limits

Mercury 761 20400 2786 992 71- 125 EPA 1631E

Spike MSD MSD Recovery RPDAdded Concentration

RPD Limits Limit Method Notes(ngL) (ngL) RecoveryAnalyte

Mercury 20400 2837 102 l82 71 - 125 24 EPA I631E

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accorda11ce with the chain ofcuslOdy document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page8of26 1201073 Final Report 04252012 10

11720 North Creek Pari-way North Suite 400 BotheI WA 98011

Ph 425-686-1996 Fx 425-686-3096

GLOSAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201029-01

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 I 063-MSMSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ngL) (ngL) (ngL) Recovery Limits Method Notes

Mercury 534 10200 1558 JOO 71 - 125 EPA 1631E

Spike MSD MSD Oo Recovery RPDAdded Concentration

RPO Limits Limit Method Notes(ngL) (ngL) RecoveryAnalyte

Mercury 10200 1407 85 6 102 71 - 125 24 EPA 163JE

F The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

L

rontier Global Sciences Inc

iz Siska Project Manager Page 9of26 1201073 Final Report 042512012 1 1

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096~

GL06Al SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201030-02

Batch F20 I063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F201063-MSMSD4

Analyte

Sample Concentration

(ngL)

Spike Added (ngL)

MS Concentration

(ngL)

MS Oo

Recovery Recovery

Limits Method Notes

Mercury

Analyte

554

Spike Added (ngL)

10200

MSD Concentration

(ngL)

1482

MSD oo

RPD Recovery

910 71 - 125 EPA 1631E

Recovery Limits

RPO Limit Method Notes

Mercury 10200 1461 890 140 71 - 125 24 EPA 1631E

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager PagelO o26 1201073 Final Report 04125202 12

J1720 North Creek Parkway North Suite 400 l Bothell WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD1

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Calcium 5013000 15150 4802000 -13900 70 - 130 EPA 2008 Mod QM-02

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery

Limits RPDLimit Method Notes

Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this leport only apply to he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 11 o26 201073 Final Report 042512012 13

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody docwnenL This analytical report must be reproduced in its entirety

-I~ __-d-lt-~-- ~

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 ~~ Bothell WA 98011

Ph 425-686-1996 -- _ - - --- -~ FRONTIER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

13atch F20327I Sequence 2C22005

Preparation Closed Vessel Nitric Qven Digestion Lab Number f20327 l-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2442 958 70 130 EPA 2008 Mod

Sodium 258800 50500 257700 -213 70 - 130 EPA 2008 Mod QM-02

Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod

Chromium 057 70700 804 106 70 130 EPA 2008 Mod

Manganese 280S 60600 2834 476 70 - 130 EPA 2008 Mod QM-02

Tron ND 50500 5200 103 70 - 130 EPA 2008 Mod

Nickel 979 40400 141 1 107 70 130 EPA 2008 Mod

Copper 055 40400 434 939 70 - 130 EPA 2008 Mod

Zinc 040 10100 842 794 70- 130 EPA 2008 Mod

Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod

Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod

Molybdenum 1338 20200 1367 142 70- 130 EPA 2008 Mod QM-02

Silver ND 15150 l388 916 70 - 130 EPA 2008 Mod

Cadmium 0332 080800 1105 956 70 - 130 EPA 2008 Mod

Antimony 0408 0 80800 1259 105 70 - 130 EPA 2008 Mod

Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod

Lead ND 15150 l542 102 70- 130 EPA 2008 Mod

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits

RPDLimit Method Notes

Beryllium 20200 2561 102 474 70 130 20 EPA 2008 Mod

Sodium 50500 257100 -336 0243 70 130 20 EPA 2008 Mod QM-02

Aluminum 15I50 2034 993 0564 70 130 20 EPA 2008 Mod

Chromium 70700 773 101 385 70 130 20 EPA 2008 Mod

Manganese 60600 2852 769 0625 70 130 20 EPA 2008 Mod

Iron 50500 5187 103 0242 70 130 20 EPA 2008 Mod

Nickel 40400 1381 995 21 3 70 - 130 20 EPA 2008 Mod

Copper 40400 419 902 347 70 130 20 EPA 2008 Mod

Zinc 10100 916 868 849 70 130 20 EPA 2008 Mod

Arsenic 15150 2225 789 831 70 - 130 20 EPA 2008 Mod

Selenium 30300 9400 101 464 70 130 20 EPA 2008 Mod

Molybdenum 20200 1366 137 00771 70 130 20 EPA 2008 Mod QM-02

shy

shyshyshy

shyshy

shy

shy

shy

shy

Page 12 o26 1201073 Final Report 04252012 14

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~~ Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits

RPD Limit Method Notes

Silver 15150 1387 915 00874 70 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 130 20 EPA 2008 Mod Antimony 080800 l274 107 121 70 - 130 20 EPA 2008 Mod Barium 10100 2514 116 0781 70 130 20 EPA 2008 Mod

Lead 15150 1534 101 0525 70 130 20 EPA 2008 Mod

shy

shy

shy

shy

Frontier Global Sciences Inc The results 11 this report only apply to the samples analyzed in accordance bull~ith the chain ofcusLOdy documenL This analytical repogt1 must be reproduced in its entirety

Page 13 o26 1201073 Final Report 04252012

Liz Siska Project Manager

15

11720 North Creek Parkway North Suite 400 Bothell WA 98011~~Lshy

Ph 425-686-1996 Fx 425-686-3096middot~RONTIE~

GLOBAL SCIENCES

MATRIX SPIKE MA TRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327l-MS1MSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte Method Notes (11gL) (microgL) (microgL) Recovery Limits

100 70 - 130 EPA 2008 Mod AS Calcium 5013000 10100000 15120000

Spike MSD MSD Recovery RPDAdded Concentration Oo oo

RPO Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte

Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS

The results in 1his report only apply to 1he samples analyzed in accordanet wtth IheFrontier Global Sciences Inc chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager

Page 14 o26 1201073 Final Report 042512012 16

Frontier Global Sciences Inc The results in this report only apply ta the samples analyzed in accordance 1Yith the chain ofcustody documenL This analytical report must be reproduced in its entirety

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l ~ Ph 425-686-1996

~IER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD4

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2041 985 70 - 130 EPA 2008 Mod AS Sodium 258800 40400 292900 845 70 - 130 EPA 2008 Mod AS

Aluminum 529 40400 3956 966 70 130 EPA 2008 Mod AS

Chromium 057 40400 4301 106 70 130 EPA 2008 Mod AS

Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS

Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS

Nickel 979 50500 51 12 993 70- 130 EPA 2008 Mod AS Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS

Zinc 040 10100 9074 898 70 -130 EPA 2008 Mod AS

Arsenic 1030 40400 4317 104 70 - 130 EPA 2008 Mod AS Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS

Molybdenum 1338 20200 338l 101 70 130 EPA 2008 Mod AS Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS

Cadmium 0332 40400 3937 966 70 - 130 EPA 2008 Mod AS Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS Barium 2397 80800 1056 101 70 - 130 EPA 2008 Mod AS Lead ND 10100 9932 983 70 - 130 EPA 2008 Mod AS

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits

RPO limit Method Notes

Beryllium 20200 2007 968 171 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 - 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 l40 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 -130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 -130 20 EPA 2008 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 bull 130 20 EPA 2008 Mod AS

shy

Page 15 o26 1201073 Final Report 041252012 17

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

CLOBA L SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number J20327 l -MSMSD4

Analyte

Silver

Spike Added (microgL)

20200

MSD Concentration

(microgL)

MSD Oo

Recovery

RPO

Recovery Limits

RPOLimit Method Notes

1895 93 8 242 70 -130 20 EPA 2008 Mod AS

Cadmium 40400 3933 965 0104 70 - 130 20 EPA 2008 Mod AS

Antimony 20200 2107 102 0736 70 shy 130 20 EPA 2008 Mod AS

Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS

Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report 01ry apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 16026 1201073 Final Report 04252012 18

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096FRONTlEit

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo RPD

Recovery Limits

RPDLimit Method Notes

Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 17 o26 1201073 FinaReport 0412512012 19

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE I201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD4

Sample Spike MS MS

Analyte Concentration

(microgL) Added (iagL)

Concentration (microgL)

Oo

Recovery Recovery

Method Limits Notes

Thallium 5563 10100 1033 968 70 - 130 EPA 2008 Mod AS

Spike Added

MSD Concentration

MSD 0o Recovery RPO

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Thallium 10100 1037 971 0341 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This anayzical report must be reproduced in its entirely

Liz Siska Project Manager Page 18af26 1201073 Final Report 042512012 20

11720 North Creek Parkway North Suite 400 ~k~~ Bothell WA 98011

Ph 425-686-I 996 ~ONTI~ Fx 425-686-3096

GLOBAL S C IENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 1063-BSBSD1

LCS Source Nist 1641d

Analyte

Mercury

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1550

LCS Oo

Recovery

988

Recovery Limits

80 shy 120

Method

EPA I63I E

Notes

Analyte

Mercury

Spike Added ngL)

15679

LCSD Concentration

(ngL)

1595

LCSD Oo

Recovery

102

Oo

RPD

289

Recovery Limits

80 - 120

RPD Limit

24

Method

EPA 163IE

Notes

Frontier Global Sciences Inc The results in this repori only apply to the samples analyzed in accordance with the chain ofcustody document This analy1ical reporl must be reproduced in its entirety

Liz Siska Project Manager Page 19026 120l 07 3 Final Report 042512012 21

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 BotheUI WA 98011

Ph 425-686-1996 Fx 425-686-3096

ANALYTICAL RESULTS

Treat Tank Eff Grab

Matrix Water Laboratory ID 120) 073-02

Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes

Arsenic 851 102 300 microgL 20 F20327 l 2C22005 032212 EPA 2008 Mod

Mercury 105 034 202 ngL 4 F20 I063 2A09010 010912 EPA 1631E FB-163 1

Selenium 689 388 120 microgL 20 F203271 2C22005 032212 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance with the chain ofcustody docwnent This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 5 of26 1201073 Final ampport04251202 7

Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in acccrdance with the chain ofcustody document This analytical report must be reproduced in irs entirety

Liz Siska Project Manager

11720 North Creek Parkway No1th Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

GLOBgtAL SCIENCES

MATRIX DUPLICATESffRIPLICATES

SOURCE 1201073-02

Batch F201063

Preparation BrCI Oxidation

Sequence 2A09010

Lab Number F20I063-DUP1

Sample Duplicate Concentration Concentration RPD

Analyte ogL ngL MRL RPD

0617

Limit

24

Method

EPA 163IE

Notes

Mercury 1048 1054 202

Page 6026 J20107 3 Final Report 04252012 8

--=W- - FRONT~

GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 9801 1

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-02

Batch F20 I063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 I 063-MSMSDl

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ngL) (ngL) (ngL) Recovery Method Notes Limits

Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

Spike MSD MSD Recovery RPD Added Concentration Oo

RPD Limits Limit Method Notes (ngL) (ngL) Recovery Analyte

Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in 1his report only apply to 1he samples analyzed in accordance wilh 1he chain ofcustody document This analytical report must be reproduced in its e1tirety

Page 7 of26 1201073 Final Report 04252012 9

11720 North Creek Parkway North Suite 400 Bothell WA 98011~ Ph 425middot686-1996 ~rn-middot Fx 425-686-3096

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1112278-02

Batch F201063 Sequence 2A02010

Prepar-ation BrCI Oxidation Lab Number F201063-MSMSD2

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ogL) (ngL) (ngL) Recovery Method Notes Limits

Mercury 761 20400 2786 992 71- 125 EPA 1631E

Spike MSD MSD Recovery RPDAdded Concentration

RPD Limits Limit Method Notes(ngL) (ngL) RecoveryAnalyte

Mercury 20400 2837 102 l82 71 - 125 24 EPA I631E

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accorda11ce with the chain ofcuslOdy document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page8of26 1201073 Final Report 04252012 10

11720 North Creek Pari-way North Suite 400 BotheI WA 98011

Ph 425-686-1996 Fx 425-686-3096

GLOSAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201029-01

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 I 063-MSMSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ngL) (ngL) (ngL) Recovery Limits Method Notes

Mercury 534 10200 1558 JOO 71 - 125 EPA 1631E

Spike MSD MSD Oo Recovery RPDAdded Concentration

RPO Limits Limit Method Notes(ngL) (ngL) RecoveryAnalyte

Mercury 10200 1407 85 6 102 71 - 125 24 EPA 163JE

F The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

L

rontier Global Sciences Inc

iz Siska Project Manager Page 9of26 1201073 Final Report 042512012 1 1

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096~

GL06Al SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201030-02

Batch F20 I063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F201063-MSMSD4

Analyte

Sample Concentration

(ngL)

Spike Added (ngL)

MS Concentration

(ngL)

MS Oo

Recovery Recovery

Limits Method Notes

Mercury

Analyte

554

Spike Added (ngL)

10200

MSD Concentration

(ngL)

1482

MSD oo

RPD Recovery

910 71 - 125 EPA 1631E

Recovery Limits

RPO Limit Method Notes

Mercury 10200 1461 890 140 71 - 125 24 EPA 1631E

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager PagelO o26 1201073 Final Report 04125202 12

J1720 North Creek Parkway North Suite 400 l Bothell WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD1

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Calcium 5013000 15150 4802000 -13900 70 - 130 EPA 2008 Mod QM-02

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery

Limits RPDLimit Method Notes

Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this leport only apply to he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 11 o26 201073 Final Report 042512012 13

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody docwnenL This analytical report must be reproduced in its entirety

-I~ __-d-lt-~-- ~

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 ~~ Bothell WA 98011

Ph 425-686-1996 -- _ - - --- -~ FRONTIER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

13atch F20327I Sequence 2C22005

Preparation Closed Vessel Nitric Qven Digestion Lab Number f20327 l-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2442 958 70 130 EPA 2008 Mod

Sodium 258800 50500 257700 -213 70 - 130 EPA 2008 Mod QM-02

Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod

Chromium 057 70700 804 106 70 130 EPA 2008 Mod

Manganese 280S 60600 2834 476 70 - 130 EPA 2008 Mod QM-02

Tron ND 50500 5200 103 70 - 130 EPA 2008 Mod

Nickel 979 40400 141 1 107 70 130 EPA 2008 Mod

Copper 055 40400 434 939 70 - 130 EPA 2008 Mod

Zinc 040 10100 842 794 70- 130 EPA 2008 Mod

Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod

Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod

Molybdenum 1338 20200 1367 142 70- 130 EPA 2008 Mod QM-02

Silver ND 15150 l388 916 70 - 130 EPA 2008 Mod

Cadmium 0332 080800 1105 956 70 - 130 EPA 2008 Mod

Antimony 0408 0 80800 1259 105 70 - 130 EPA 2008 Mod

Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod

Lead ND 15150 l542 102 70- 130 EPA 2008 Mod

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits

RPDLimit Method Notes

Beryllium 20200 2561 102 474 70 130 20 EPA 2008 Mod

Sodium 50500 257100 -336 0243 70 130 20 EPA 2008 Mod QM-02

Aluminum 15I50 2034 993 0564 70 130 20 EPA 2008 Mod

Chromium 70700 773 101 385 70 130 20 EPA 2008 Mod

Manganese 60600 2852 769 0625 70 130 20 EPA 2008 Mod

Iron 50500 5187 103 0242 70 130 20 EPA 2008 Mod

Nickel 40400 1381 995 21 3 70 - 130 20 EPA 2008 Mod

Copper 40400 419 902 347 70 130 20 EPA 2008 Mod

Zinc 10100 916 868 849 70 130 20 EPA 2008 Mod

Arsenic 15150 2225 789 831 70 - 130 20 EPA 2008 Mod

Selenium 30300 9400 101 464 70 130 20 EPA 2008 Mod

Molybdenum 20200 1366 137 00771 70 130 20 EPA 2008 Mod QM-02

shy

shyshyshy

shyshy

shy

shy

shy

shy

Page 12 o26 1201073 Final Report 04252012 14

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~~ Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits

RPD Limit Method Notes

Silver 15150 1387 915 00874 70 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 130 20 EPA 2008 Mod Antimony 080800 l274 107 121 70 - 130 20 EPA 2008 Mod Barium 10100 2514 116 0781 70 130 20 EPA 2008 Mod

Lead 15150 1534 101 0525 70 130 20 EPA 2008 Mod

shy

shy

shy

shy

Frontier Global Sciences Inc The results 11 this report only apply to the samples analyzed in accordance bull~ith the chain ofcusLOdy documenL This analytical repogt1 must be reproduced in its entirety

Page 13 o26 1201073 Final Report 04252012

Liz Siska Project Manager

15

11720 North Creek Parkway North Suite 400 Bothell WA 98011~~Lshy

Ph 425-686-1996 Fx 425-686-3096middot~RONTIE~

GLOBAL SCIENCES

MATRIX SPIKE MA TRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327l-MS1MSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte Method Notes (11gL) (microgL) (microgL) Recovery Limits

100 70 - 130 EPA 2008 Mod AS Calcium 5013000 10100000 15120000

Spike MSD MSD Recovery RPDAdded Concentration Oo oo

RPO Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte

Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS

The results in 1his report only apply to 1he samples analyzed in accordanet wtth IheFrontier Global Sciences Inc chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager

Page 14 o26 1201073 Final Report 042512012 16

Frontier Global Sciences Inc The results in this report only apply ta the samples analyzed in accordance 1Yith the chain ofcustody documenL This analytical report must be reproduced in its entirety

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l ~ Ph 425-686-1996

~IER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD4

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2041 985 70 - 130 EPA 2008 Mod AS Sodium 258800 40400 292900 845 70 - 130 EPA 2008 Mod AS

Aluminum 529 40400 3956 966 70 130 EPA 2008 Mod AS

Chromium 057 40400 4301 106 70 130 EPA 2008 Mod AS

Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS

Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS

Nickel 979 50500 51 12 993 70- 130 EPA 2008 Mod AS Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS

Zinc 040 10100 9074 898 70 -130 EPA 2008 Mod AS

Arsenic 1030 40400 4317 104 70 - 130 EPA 2008 Mod AS Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS

Molybdenum 1338 20200 338l 101 70 130 EPA 2008 Mod AS Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS

Cadmium 0332 40400 3937 966 70 - 130 EPA 2008 Mod AS Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS Barium 2397 80800 1056 101 70 - 130 EPA 2008 Mod AS Lead ND 10100 9932 983 70 - 130 EPA 2008 Mod AS

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits

RPO limit Method Notes

Beryllium 20200 2007 968 171 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 - 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 l40 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 -130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 -130 20 EPA 2008 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 bull 130 20 EPA 2008 Mod AS

shy

Page 15 o26 1201073 Final Report 041252012 17

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

CLOBA L SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number J20327 l -MSMSD4

Analyte

Silver

Spike Added (microgL)

20200

MSD Concentration

(microgL)

MSD Oo

Recovery

RPO

Recovery Limits

RPOLimit Method Notes

1895 93 8 242 70 -130 20 EPA 2008 Mod AS

Cadmium 40400 3933 965 0104 70 - 130 20 EPA 2008 Mod AS

Antimony 20200 2107 102 0736 70 shy 130 20 EPA 2008 Mod AS

Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS

Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report 01ry apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 16026 1201073 Final Report 04252012 18

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096FRONTlEit

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo RPD

Recovery Limits

RPDLimit Method Notes

Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 17 o26 1201073 FinaReport 0412512012 19

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE I201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD4

Sample Spike MS MS

Analyte Concentration

(microgL) Added (iagL)

Concentration (microgL)

Oo

Recovery Recovery

Method Limits Notes

Thallium 5563 10100 1033 968 70 - 130 EPA 2008 Mod AS

Spike Added

MSD Concentration

MSD 0o Recovery RPO

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Thallium 10100 1037 971 0341 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This anayzical report must be reproduced in its entirely

Liz Siska Project Manager Page 18af26 1201073 Final Report 042512012 20

11720 North Creek Parkway North Suite 400 ~k~~ Bothell WA 98011

Ph 425-686-I 996 ~ONTI~ Fx 425-686-3096

GLOBAL S C IENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 1063-BSBSD1

LCS Source Nist 1641d

Analyte

Mercury

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1550

LCS Oo

Recovery

988

Recovery Limits

80 shy 120

Method

EPA I63I E

Notes

Analyte

Mercury

Spike Added ngL)

15679

LCSD Concentration

(ngL)

1595

LCSD Oo

Recovery

102

Oo

RPD

289

Recovery Limits

80 - 120

RPD Limit

24

Method

EPA 163IE

Notes

Frontier Global Sciences Inc The results in this repori only apply to the samples analyzed in accordance with the chain ofcustody document This analy1ical reporl must be reproduced in its entirety

Liz Siska Project Manager Page 19026 120l 07 3 Final Report 042512012 21

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

Frontier Global Sciences Inc The results in this report only apply lo the samples analyzed in acccrdance with the chain ofcustody document This analytical report must be reproduced in irs entirety

Liz Siska Project Manager

11720 North Creek Parkway No1th Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

GLOBgtAL SCIENCES

MATRIX DUPLICATESffRIPLICATES

SOURCE 1201073-02

Batch F201063

Preparation BrCI Oxidation

Sequence 2A09010

Lab Number F20I063-DUP1

Sample Duplicate Concentration Concentration RPD

Analyte ogL ngL MRL RPD

0617

Limit

24

Method

EPA 163IE

Notes

Mercury 1048 1054 202

Page 6026 J20107 3 Final Report 04252012 8

--=W- - FRONT~

GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 9801 1

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-02

Batch F20 I063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 I 063-MSMSDl

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ngL) (ngL) (ngL) Recovery Method Notes Limits

Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

Spike MSD MSD Recovery RPD Added Concentration Oo

RPD Limits Limit Method Notes (ngL) (ngL) Recovery Analyte

Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in 1his report only apply to 1he samples analyzed in accordance wilh 1he chain ofcustody document This analytical report must be reproduced in its e1tirety

Page 7 of26 1201073 Final Report 04252012 9

11720 North Creek Parkway North Suite 400 Bothell WA 98011~ Ph 425middot686-1996 ~rn-middot Fx 425-686-3096

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1112278-02

Batch F201063 Sequence 2A02010

Prepar-ation BrCI Oxidation Lab Number F201063-MSMSD2

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ogL) (ngL) (ngL) Recovery Method Notes Limits

Mercury 761 20400 2786 992 71- 125 EPA 1631E

Spike MSD MSD Recovery RPDAdded Concentration

RPD Limits Limit Method Notes(ngL) (ngL) RecoveryAnalyte

Mercury 20400 2837 102 l82 71 - 125 24 EPA I631E

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accorda11ce with the chain ofcuslOdy document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page8of26 1201073 Final Report 04252012 10

11720 North Creek Pari-way North Suite 400 BotheI WA 98011

Ph 425-686-1996 Fx 425-686-3096

GLOSAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201029-01

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 I 063-MSMSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ngL) (ngL) (ngL) Recovery Limits Method Notes

Mercury 534 10200 1558 JOO 71 - 125 EPA 1631E

Spike MSD MSD Oo Recovery RPDAdded Concentration

RPO Limits Limit Method Notes(ngL) (ngL) RecoveryAnalyte

Mercury 10200 1407 85 6 102 71 - 125 24 EPA 163JE

F The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

L

rontier Global Sciences Inc

iz Siska Project Manager Page 9of26 1201073 Final Report 042512012 1 1

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096~

GL06Al SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201030-02

Batch F20 I063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F201063-MSMSD4

Analyte

Sample Concentration

(ngL)

Spike Added (ngL)

MS Concentration

(ngL)

MS Oo

Recovery Recovery

Limits Method Notes

Mercury

Analyte

554

Spike Added (ngL)

10200

MSD Concentration

(ngL)

1482

MSD oo

RPD Recovery

910 71 - 125 EPA 1631E

Recovery Limits

RPO Limit Method Notes

Mercury 10200 1461 890 140 71 - 125 24 EPA 1631E

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager PagelO o26 1201073 Final Report 04125202 12

J1720 North Creek Parkway North Suite 400 l Bothell WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD1

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Calcium 5013000 15150 4802000 -13900 70 - 130 EPA 2008 Mod QM-02

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery

Limits RPDLimit Method Notes

Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this leport only apply to he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 11 o26 201073 Final Report 042512012 13

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody docwnenL This analytical report must be reproduced in its entirety

-I~ __-d-lt-~-- ~

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 ~~ Bothell WA 98011

Ph 425-686-1996 -- _ - - --- -~ FRONTIER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

13atch F20327I Sequence 2C22005

Preparation Closed Vessel Nitric Qven Digestion Lab Number f20327 l-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2442 958 70 130 EPA 2008 Mod

Sodium 258800 50500 257700 -213 70 - 130 EPA 2008 Mod QM-02

Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod

Chromium 057 70700 804 106 70 130 EPA 2008 Mod

Manganese 280S 60600 2834 476 70 - 130 EPA 2008 Mod QM-02

Tron ND 50500 5200 103 70 - 130 EPA 2008 Mod

Nickel 979 40400 141 1 107 70 130 EPA 2008 Mod

Copper 055 40400 434 939 70 - 130 EPA 2008 Mod

Zinc 040 10100 842 794 70- 130 EPA 2008 Mod

Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod

Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod

Molybdenum 1338 20200 1367 142 70- 130 EPA 2008 Mod QM-02

Silver ND 15150 l388 916 70 - 130 EPA 2008 Mod

Cadmium 0332 080800 1105 956 70 - 130 EPA 2008 Mod

Antimony 0408 0 80800 1259 105 70 - 130 EPA 2008 Mod

Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod

Lead ND 15150 l542 102 70- 130 EPA 2008 Mod

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits

RPDLimit Method Notes

Beryllium 20200 2561 102 474 70 130 20 EPA 2008 Mod

Sodium 50500 257100 -336 0243 70 130 20 EPA 2008 Mod QM-02

Aluminum 15I50 2034 993 0564 70 130 20 EPA 2008 Mod

Chromium 70700 773 101 385 70 130 20 EPA 2008 Mod

Manganese 60600 2852 769 0625 70 130 20 EPA 2008 Mod

Iron 50500 5187 103 0242 70 130 20 EPA 2008 Mod

Nickel 40400 1381 995 21 3 70 - 130 20 EPA 2008 Mod

Copper 40400 419 902 347 70 130 20 EPA 2008 Mod

Zinc 10100 916 868 849 70 130 20 EPA 2008 Mod

Arsenic 15150 2225 789 831 70 - 130 20 EPA 2008 Mod

Selenium 30300 9400 101 464 70 130 20 EPA 2008 Mod

Molybdenum 20200 1366 137 00771 70 130 20 EPA 2008 Mod QM-02

shy

shyshyshy

shyshy

shy

shy

shy

shy

Page 12 o26 1201073 Final Report 04252012 14

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~~ Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits

RPD Limit Method Notes

Silver 15150 1387 915 00874 70 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 130 20 EPA 2008 Mod Antimony 080800 l274 107 121 70 - 130 20 EPA 2008 Mod Barium 10100 2514 116 0781 70 130 20 EPA 2008 Mod

Lead 15150 1534 101 0525 70 130 20 EPA 2008 Mod

shy

shy

shy

shy

Frontier Global Sciences Inc The results 11 this report only apply to the samples analyzed in accordance bull~ith the chain ofcusLOdy documenL This analytical repogt1 must be reproduced in its entirety

Page 13 o26 1201073 Final Report 04252012

Liz Siska Project Manager

15

11720 North Creek Parkway North Suite 400 Bothell WA 98011~~Lshy

Ph 425-686-1996 Fx 425-686-3096middot~RONTIE~

GLOBAL SCIENCES

MATRIX SPIKE MA TRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327l-MS1MSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte Method Notes (11gL) (microgL) (microgL) Recovery Limits

100 70 - 130 EPA 2008 Mod AS Calcium 5013000 10100000 15120000

Spike MSD MSD Recovery RPDAdded Concentration Oo oo

RPO Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte

Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS

The results in 1his report only apply to 1he samples analyzed in accordanet wtth IheFrontier Global Sciences Inc chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager

Page 14 o26 1201073 Final Report 042512012 16

Frontier Global Sciences Inc The results in this report only apply ta the samples analyzed in accordance 1Yith the chain ofcustody documenL This analytical report must be reproduced in its entirety

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l ~ Ph 425-686-1996

~IER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD4

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2041 985 70 - 130 EPA 2008 Mod AS Sodium 258800 40400 292900 845 70 - 130 EPA 2008 Mod AS

Aluminum 529 40400 3956 966 70 130 EPA 2008 Mod AS

Chromium 057 40400 4301 106 70 130 EPA 2008 Mod AS

Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS

Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS

Nickel 979 50500 51 12 993 70- 130 EPA 2008 Mod AS Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS

Zinc 040 10100 9074 898 70 -130 EPA 2008 Mod AS

Arsenic 1030 40400 4317 104 70 - 130 EPA 2008 Mod AS Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS

Molybdenum 1338 20200 338l 101 70 130 EPA 2008 Mod AS Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS

Cadmium 0332 40400 3937 966 70 - 130 EPA 2008 Mod AS Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS Barium 2397 80800 1056 101 70 - 130 EPA 2008 Mod AS Lead ND 10100 9932 983 70 - 130 EPA 2008 Mod AS

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits

RPO limit Method Notes

Beryllium 20200 2007 968 171 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 - 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 l40 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 -130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 -130 20 EPA 2008 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 bull 130 20 EPA 2008 Mod AS

shy

Page 15 o26 1201073 Final Report 041252012 17

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

CLOBA L SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number J20327 l -MSMSD4

Analyte

Silver

Spike Added (microgL)

20200

MSD Concentration

(microgL)

MSD Oo

Recovery

RPO

Recovery Limits

RPOLimit Method Notes

1895 93 8 242 70 -130 20 EPA 2008 Mod AS

Cadmium 40400 3933 965 0104 70 - 130 20 EPA 2008 Mod AS

Antimony 20200 2107 102 0736 70 shy 130 20 EPA 2008 Mod AS

Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS

Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report 01ry apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 16026 1201073 Final Report 04252012 18

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096FRONTlEit

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo RPD

Recovery Limits

RPDLimit Method Notes

Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 17 o26 1201073 FinaReport 0412512012 19

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE I201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD4

Sample Spike MS MS

Analyte Concentration

(microgL) Added (iagL)

Concentration (microgL)

Oo

Recovery Recovery

Method Limits Notes

Thallium 5563 10100 1033 968 70 - 130 EPA 2008 Mod AS

Spike Added

MSD Concentration

MSD 0o Recovery RPO

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Thallium 10100 1037 971 0341 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This anayzical report must be reproduced in its entirely

Liz Siska Project Manager Page 18af26 1201073 Final Report 042512012 20

11720 North Creek Parkway North Suite 400 ~k~~ Bothell WA 98011

Ph 425-686-I 996 ~ONTI~ Fx 425-686-3096

GLOBAL S C IENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 1063-BSBSD1

LCS Source Nist 1641d

Analyte

Mercury

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1550

LCS Oo

Recovery

988

Recovery Limits

80 shy 120

Method

EPA I63I E

Notes

Analyte

Mercury

Spike Added ngL)

15679

LCSD Concentration

(ngL)

1595

LCSD Oo

Recovery

102

Oo

RPD

289

Recovery Limits

80 - 120

RPD Limit

24

Method

EPA 163IE

Notes

Frontier Global Sciences Inc The results in this repori only apply to the samples analyzed in accordance with the chain ofcustody document This analy1ical reporl must be reproduced in its entirety

Liz Siska Project Manager Page 19026 120l 07 3 Final Report 042512012 21

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

--=W- - FRONT~

GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 9801 1

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-02

Batch F20 I063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 I 063-MSMSDl

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ngL) (ngL) (ngL) Recovery Method Notes Limits

Mercury 1048 20400 3136 102 71 - 125 EPA 1631E

Spike MSD MSD Recovery RPD Added Concentration Oo

RPD Limits Limit Method Notes (ngL) (ngL) Recovery Analyte

Mercury 20400 2708 814 147 71 - 125 24 EPA 1631E

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in 1his report only apply to 1he samples analyzed in accordance wilh 1he chain ofcustody document This analytical report must be reproduced in its e1tirety

Page 7 of26 1201073 Final Report 04252012 9

11720 North Creek Parkway North Suite 400 Bothell WA 98011~ Ph 425middot686-1996 ~rn-middot Fx 425-686-3096

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1112278-02

Batch F201063 Sequence 2A02010

Prepar-ation BrCI Oxidation Lab Number F201063-MSMSD2

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ogL) (ngL) (ngL) Recovery Method Notes Limits

Mercury 761 20400 2786 992 71- 125 EPA 1631E

Spike MSD MSD Recovery RPDAdded Concentration

RPD Limits Limit Method Notes(ngL) (ngL) RecoveryAnalyte

Mercury 20400 2837 102 l82 71 - 125 24 EPA I631E

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accorda11ce with the chain ofcuslOdy document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page8of26 1201073 Final Report 04252012 10

11720 North Creek Pari-way North Suite 400 BotheI WA 98011

Ph 425-686-1996 Fx 425-686-3096

GLOSAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201029-01

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 I 063-MSMSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ngL) (ngL) (ngL) Recovery Limits Method Notes

Mercury 534 10200 1558 JOO 71 - 125 EPA 1631E

Spike MSD MSD Oo Recovery RPDAdded Concentration

RPO Limits Limit Method Notes(ngL) (ngL) RecoveryAnalyte

Mercury 10200 1407 85 6 102 71 - 125 24 EPA 163JE

F The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

L

rontier Global Sciences Inc

iz Siska Project Manager Page 9of26 1201073 Final Report 042512012 1 1

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096~

GL06Al SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201030-02

Batch F20 I063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F201063-MSMSD4

Analyte

Sample Concentration

(ngL)

Spike Added (ngL)

MS Concentration

(ngL)

MS Oo

Recovery Recovery

Limits Method Notes

Mercury

Analyte

554

Spike Added (ngL)

10200

MSD Concentration

(ngL)

1482

MSD oo

RPD Recovery

910 71 - 125 EPA 1631E

Recovery Limits

RPO Limit Method Notes

Mercury 10200 1461 890 140 71 - 125 24 EPA 1631E

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager PagelO o26 1201073 Final Report 04125202 12

J1720 North Creek Parkway North Suite 400 l Bothell WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD1

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Calcium 5013000 15150 4802000 -13900 70 - 130 EPA 2008 Mod QM-02

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery

Limits RPDLimit Method Notes

Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this leport only apply to he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 11 o26 201073 Final Report 042512012 13

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody docwnenL This analytical report must be reproduced in its entirety

-I~ __-d-lt-~-- ~

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 ~~ Bothell WA 98011

Ph 425-686-1996 -- _ - - --- -~ FRONTIER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

13atch F20327I Sequence 2C22005

Preparation Closed Vessel Nitric Qven Digestion Lab Number f20327 l-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2442 958 70 130 EPA 2008 Mod

Sodium 258800 50500 257700 -213 70 - 130 EPA 2008 Mod QM-02

Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod

Chromium 057 70700 804 106 70 130 EPA 2008 Mod

Manganese 280S 60600 2834 476 70 - 130 EPA 2008 Mod QM-02

Tron ND 50500 5200 103 70 - 130 EPA 2008 Mod

Nickel 979 40400 141 1 107 70 130 EPA 2008 Mod

Copper 055 40400 434 939 70 - 130 EPA 2008 Mod

Zinc 040 10100 842 794 70- 130 EPA 2008 Mod

Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod

Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod

Molybdenum 1338 20200 1367 142 70- 130 EPA 2008 Mod QM-02

Silver ND 15150 l388 916 70 - 130 EPA 2008 Mod

Cadmium 0332 080800 1105 956 70 - 130 EPA 2008 Mod

Antimony 0408 0 80800 1259 105 70 - 130 EPA 2008 Mod

Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod

Lead ND 15150 l542 102 70- 130 EPA 2008 Mod

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits

RPDLimit Method Notes

Beryllium 20200 2561 102 474 70 130 20 EPA 2008 Mod

Sodium 50500 257100 -336 0243 70 130 20 EPA 2008 Mod QM-02

Aluminum 15I50 2034 993 0564 70 130 20 EPA 2008 Mod

Chromium 70700 773 101 385 70 130 20 EPA 2008 Mod

Manganese 60600 2852 769 0625 70 130 20 EPA 2008 Mod

Iron 50500 5187 103 0242 70 130 20 EPA 2008 Mod

Nickel 40400 1381 995 21 3 70 - 130 20 EPA 2008 Mod

Copper 40400 419 902 347 70 130 20 EPA 2008 Mod

Zinc 10100 916 868 849 70 130 20 EPA 2008 Mod

Arsenic 15150 2225 789 831 70 - 130 20 EPA 2008 Mod

Selenium 30300 9400 101 464 70 130 20 EPA 2008 Mod

Molybdenum 20200 1366 137 00771 70 130 20 EPA 2008 Mod QM-02

shy

shyshyshy

shyshy

shy

shy

shy

shy

Page 12 o26 1201073 Final Report 04252012 14

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~~ Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits

RPD Limit Method Notes

Silver 15150 1387 915 00874 70 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 130 20 EPA 2008 Mod Antimony 080800 l274 107 121 70 - 130 20 EPA 2008 Mod Barium 10100 2514 116 0781 70 130 20 EPA 2008 Mod

Lead 15150 1534 101 0525 70 130 20 EPA 2008 Mod

shy

shy

shy

shy

Frontier Global Sciences Inc The results 11 this report only apply to the samples analyzed in accordance bull~ith the chain ofcusLOdy documenL This analytical repogt1 must be reproduced in its entirety

Page 13 o26 1201073 Final Report 04252012

Liz Siska Project Manager

15

11720 North Creek Parkway North Suite 400 Bothell WA 98011~~Lshy

Ph 425-686-1996 Fx 425-686-3096middot~RONTIE~

GLOBAL SCIENCES

MATRIX SPIKE MA TRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327l-MS1MSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte Method Notes (11gL) (microgL) (microgL) Recovery Limits

100 70 - 130 EPA 2008 Mod AS Calcium 5013000 10100000 15120000

Spike MSD MSD Recovery RPDAdded Concentration Oo oo

RPO Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte

Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS

The results in 1his report only apply to 1he samples analyzed in accordanet wtth IheFrontier Global Sciences Inc chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager

Page 14 o26 1201073 Final Report 042512012 16

Frontier Global Sciences Inc The results in this report only apply ta the samples analyzed in accordance 1Yith the chain ofcustody documenL This analytical report must be reproduced in its entirety

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l ~ Ph 425-686-1996

~IER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD4

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2041 985 70 - 130 EPA 2008 Mod AS Sodium 258800 40400 292900 845 70 - 130 EPA 2008 Mod AS

Aluminum 529 40400 3956 966 70 130 EPA 2008 Mod AS

Chromium 057 40400 4301 106 70 130 EPA 2008 Mod AS

Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS

Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS

Nickel 979 50500 51 12 993 70- 130 EPA 2008 Mod AS Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS

Zinc 040 10100 9074 898 70 -130 EPA 2008 Mod AS

Arsenic 1030 40400 4317 104 70 - 130 EPA 2008 Mod AS Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS

Molybdenum 1338 20200 338l 101 70 130 EPA 2008 Mod AS Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS

Cadmium 0332 40400 3937 966 70 - 130 EPA 2008 Mod AS Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS Barium 2397 80800 1056 101 70 - 130 EPA 2008 Mod AS Lead ND 10100 9932 983 70 - 130 EPA 2008 Mod AS

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits

RPO limit Method Notes

Beryllium 20200 2007 968 171 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 - 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 l40 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 -130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 -130 20 EPA 2008 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 bull 130 20 EPA 2008 Mod AS

shy

Page 15 o26 1201073 Final Report 041252012 17

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

CLOBA L SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number J20327 l -MSMSD4

Analyte

Silver

Spike Added (microgL)

20200

MSD Concentration

(microgL)

MSD Oo

Recovery

RPO

Recovery Limits

RPOLimit Method Notes

1895 93 8 242 70 -130 20 EPA 2008 Mod AS

Cadmium 40400 3933 965 0104 70 - 130 20 EPA 2008 Mod AS

Antimony 20200 2107 102 0736 70 shy 130 20 EPA 2008 Mod AS

Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS

Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report 01ry apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 16026 1201073 Final Report 04252012 18

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096FRONTlEit

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo RPD

Recovery Limits

RPDLimit Method Notes

Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 17 o26 1201073 FinaReport 0412512012 19

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE I201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD4

Sample Spike MS MS

Analyte Concentration

(microgL) Added (iagL)

Concentration (microgL)

Oo

Recovery Recovery

Method Limits Notes

Thallium 5563 10100 1033 968 70 - 130 EPA 2008 Mod AS

Spike Added

MSD Concentration

MSD 0o Recovery RPO

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Thallium 10100 1037 971 0341 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This anayzical report must be reproduced in its entirely

Liz Siska Project Manager Page 18af26 1201073 Final Report 042512012 20

11720 North Creek Parkway North Suite 400 ~k~~ Bothell WA 98011

Ph 425-686-I 996 ~ONTI~ Fx 425-686-3096

GLOBAL S C IENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 1063-BSBSD1

LCS Source Nist 1641d

Analyte

Mercury

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1550

LCS Oo

Recovery

988

Recovery Limits

80 shy 120

Method

EPA I63I E

Notes

Analyte

Mercury

Spike Added ngL)

15679

LCSD Concentration

(ngL)

1595

LCSD Oo

Recovery

102

Oo

RPD

289

Recovery Limits

80 - 120

RPD Limit

24

Method

EPA 163IE

Notes

Frontier Global Sciences Inc The results in this repori only apply to the samples analyzed in accordance with the chain ofcustody document This analy1ical reporl must be reproduced in its entirety

Liz Siska Project Manager Page 19026 120l 07 3 Final Report 042512012 21

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

11720 North Creek Parkway North Suite 400 Bothell WA 98011~ Ph 425middot686-1996 ~rn-middot Fx 425-686-3096

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1112278-02

Batch F201063 Sequence 2A02010

Prepar-ation BrCI Oxidation Lab Number F201063-MSMSD2

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ogL) (ngL) (ngL) Recovery Method Notes Limits

Mercury 761 20400 2786 992 71- 125 EPA 1631E

Spike MSD MSD Recovery RPDAdded Concentration

RPD Limits Limit Method Notes(ngL) (ngL) RecoveryAnalyte

Mercury 20400 2837 102 l82 71 - 125 24 EPA I631E

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accorda11ce with the chain ofcuslOdy document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page8of26 1201073 Final Report 04252012 10

11720 North Creek Pari-way North Suite 400 BotheI WA 98011

Ph 425-686-1996 Fx 425-686-3096

GLOSAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201029-01

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 I 063-MSMSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ngL) (ngL) (ngL) Recovery Limits Method Notes

Mercury 534 10200 1558 JOO 71 - 125 EPA 1631E

Spike MSD MSD Oo Recovery RPDAdded Concentration

RPO Limits Limit Method Notes(ngL) (ngL) RecoveryAnalyte

Mercury 10200 1407 85 6 102 71 - 125 24 EPA 163JE

F The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

L

rontier Global Sciences Inc

iz Siska Project Manager Page 9of26 1201073 Final Report 042512012 1 1

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096~

GL06Al SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201030-02

Batch F20 I063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F201063-MSMSD4

Analyte

Sample Concentration

(ngL)

Spike Added (ngL)

MS Concentration

(ngL)

MS Oo

Recovery Recovery

Limits Method Notes

Mercury

Analyte

554

Spike Added (ngL)

10200

MSD Concentration

(ngL)

1482

MSD oo

RPD Recovery

910 71 - 125 EPA 1631E

Recovery Limits

RPO Limit Method Notes

Mercury 10200 1461 890 140 71 - 125 24 EPA 1631E

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager PagelO o26 1201073 Final Report 04125202 12

J1720 North Creek Parkway North Suite 400 l Bothell WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD1

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Calcium 5013000 15150 4802000 -13900 70 - 130 EPA 2008 Mod QM-02

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery

Limits RPDLimit Method Notes

Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this leport only apply to he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 11 o26 201073 Final Report 042512012 13

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody docwnenL This analytical report must be reproduced in its entirety

-I~ __-d-lt-~-- ~

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 ~~ Bothell WA 98011

Ph 425-686-1996 -- _ - - --- -~ FRONTIER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

13atch F20327I Sequence 2C22005

Preparation Closed Vessel Nitric Qven Digestion Lab Number f20327 l-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2442 958 70 130 EPA 2008 Mod

Sodium 258800 50500 257700 -213 70 - 130 EPA 2008 Mod QM-02

Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod

Chromium 057 70700 804 106 70 130 EPA 2008 Mod

Manganese 280S 60600 2834 476 70 - 130 EPA 2008 Mod QM-02

Tron ND 50500 5200 103 70 - 130 EPA 2008 Mod

Nickel 979 40400 141 1 107 70 130 EPA 2008 Mod

Copper 055 40400 434 939 70 - 130 EPA 2008 Mod

Zinc 040 10100 842 794 70- 130 EPA 2008 Mod

Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod

Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod

Molybdenum 1338 20200 1367 142 70- 130 EPA 2008 Mod QM-02

Silver ND 15150 l388 916 70 - 130 EPA 2008 Mod

Cadmium 0332 080800 1105 956 70 - 130 EPA 2008 Mod

Antimony 0408 0 80800 1259 105 70 - 130 EPA 2008 Mod

Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod

Lead ND 15150 l542 102 70- 130 EPA 2008 Mod

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits

RPDLimit Method Notes

Beryllium 20200 2561 102 474 70 130 20 EPA 2008 Mod

Sodium 50500 257100 -336 0243 70 130 20 EPA 2008 Mod QM-02

Aluminum 15I50 2034 993 0564 70 130 20 EPA 2008 Mod

Chromium 70700 773 101 385 70 130 20 EPA 2008 Mod

Manganese 60600 2852 769 0625 70 130 20 EPA 2008 Mod

Iron 50500 5187 103 0242 70 130 20 EPA 2008 Mod

Nickel 40400 1381 995 21 3 70 - 130 20 EPA 2008 Mod

Copper 40400 419 902 347 70 130 20 EPA 2008 Mod

Zinc 10100 916 868 849 70 130 20 EPA 2008 Mod

Arsenic 15150 2225 789 831 70 - 130 20 EPA 2008 Mod

Selenium 30300 9400 101 464 70 130 20 EPA 2008 Mod

Molybdenum 20200 1366 137 00771 70 130 20 EPA 2008 Mod QM-02

shy

shyshyshy

shyshy

shy

shy

shy

shy

Page 12 o26 1201073 Final Report 04252012 14

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~~ Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits

RPD Limit Method Notes

Silver 15150 1387 915 00874 70 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 130 20 EPA 2008 Mod Antimony 080800 l274 107 121 70 - 130 20 EPA 2008 Mod Barium 10100 2514 116 0781 70 130 20 EPA 2008 Mod

Lead 15150 1534 101 0525 70 130 20 EPA 2008 Mod

shy

shy

shy

shy

Frontier Global Sciences Inc The results 11 this report only apply to the samples analyzed in accordance bull~ith the chain ofcusLOdy documenL This analytical repogt1 must be reproduced in its entirety

Page 13 o26 1201073 Final Report 04252012

Liz Siska Project Manager

15

11720 North Creek Parkway North Suite 400 Bothell WA 98011~~Lshy

Ph 425-686-1996 Fx 425-686-3096middot~RONTIE~

GLOBAL SCIENCES

MATRIX SPIKE MA TRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327l-MS1MSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte Method Notes (11gL) (microgL) (microgL) Recovery Limits

100 70 - 130 EPA 2008 Mod AS Calcium 5013000 10100000 15120000

Spike MSD MSD Recovery RPDAdded Concentration Oo oo

RPO Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte

Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS

The results in 1his report only apply to 1he samples analyzed in accordanet wtth IheFrontier Global Sciences Inc chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager

Page 14 o26 1201073 Final Report 042512012 16

Frontier Global Sciences Inc The results in this report only apply ta the samples analyzed in accordance 1Yith the chain ofcustody documenL This analytical report must be reproduced in its entirety

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l ~ Ph 425-686-1996

~IER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD4

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2041 985 70 - 130 EPA 2008 Mod AS Sodium 258800 40400 292900 845 70 - 130 EPA 2008 Mod AS

Aluminum 529 40400 3956 966 70 130 EPA 2008 Mod AS

Chromium 057 40400 4301 106 70 130 EPA 2008 Mod AS

Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS

Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS

Nickel 979 50500 51 12 993 70- 130 EPA 2008 Mod AS Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS

Zinc 040 10100 9074 898 70 -130 EPA 2008 Mod AS

Arsenic 1030 40400 4317 104 70 - 130 EPA 2008 Mod AS Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS

Molybdenum 1338 20200 338l 101 70 130 EPA 2008 Mod AS Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS

Cadmium 0332 40400 3937 966 70 - 130 EPA 2008 Mod AS Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS Barium 2397 80800 1056 101 70 - 130 EPA 2008 Mod AS Lead ND 10100 9932 983 70 - 130 EPA 2008 Mod AS

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits

RPO limit Method Notes

Beryllium 20200 2007 968 171 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 - 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 l40 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 -130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 -130 20 EPA 2008 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 bull 130 20 EPA 2008 Mod AS

shy

Page 15 o26 1201073 Final Report 041252012 17

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

CLOBA L SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number J20327 l -MSMSD4

Analyte

Silver

Spike Added (microgL)

20200

MSD Concentration

(microgL)

MSD Oo

Recovery

RPO

Recovery Limits

RPOLimit Method Notes

1895 93 8 242 70 -130 20 EPA 2008 Mod AS

Cadmium 40400 3933 965 0104 70 - 130 20 EPA 2008 Mod AS

Antimony 20200 2107 102 0736 70 shy 130 20 EPA 2008 Mod AS

Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS

Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report 01ry apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 16026 1201073 Final Report 04252012 18

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096FRONTlEit

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo RPD

Recovery Limits

RPDLimit Method Notes

Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 17 o26 1201073 FinaReport 0412512012 19

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE I201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD4

Sample Spike MS MS

Analyte Concentration

(microgL) Added (iagL)

Concentration (microgL)

Oo

Recovery Recovery

Method Limits Notes

Thallium 5563 10100 1033 968 70 - 130 EPA 2008 Mod AS

Spike Added

MSD Concentration

MSD 0o Recovery RPO

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Thallium 10100 1037 971 0341 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This anayzical report must be reproduced in its entirely

Liz Siska Project Manager Page 18af26 1201073 Final Report 042512012 20

11720 North Creek Parkway North Suite 400 ~k~~ Bothell WA 98011

Ph 425-686-I 996 ~ONTI~ Fx 425-686-3096

GLOBAL S C IENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 1063-BSBSD1

LCS Source Nist 1641d

Analyte

Mercury

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1550

LCS Oo

Recovery

988

Recovery Limits

80 shy 120

Method

EPA I63I E

Notes

Analyte

Mercury

Spike Added ngL)

15679

LCSD Concentration

(ngL)

1595

LCSD Oo

Recovery

102

Oo

RPD

289

Recovery Limits

80 - 120

RPD Limit

24

Method

EPA 163IE

Notes

Frontier Global Sciences Inc The results in this repori only apply to the samples analyzed in accordance with the chain ofcustody document This analy1ical reporl must be reproduced in its entirety

Liz Siska Project Manager Page 19026 120l 07 3 Final Report 042512012 21

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

11720 North Creek Pari-way North Suite 400 BotheI WA 98011

Ph 425-686-1996 Fx 425-686-3096

GLOSAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201029-01

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 I 063-MSMSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte (ngL) (ngL) (ngL) Recovery Limits Method Notes

Mercury 534 10200 1558 JOO 71 - 125 EPA 1631E

Spike MSD MSD Oo Recovery RPDAdded Concentration

RPO Limits Limit Method Notes(ngL) (ngL) RecoveryAnalyte

Mercury 10200 1407 85 6 102 71 - 125 24 EPA 163JE

F The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

L

rontier Global Sciences Inc

iz Siska Project Manager Page 9of26 1201073 Final Report 042512012 1 1

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096~

GL06Al SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201030-02

Batch F20 I063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F201063-MSMSD4

Analyte

Sample Concentration

(ngL)

Spike Added (ngL)

MS Concentration

(ngL)

MS Oo

Recovery Recovery

Limits Method Notes

Mercury

Analyte

554

Spike Added (ngL)

10200

MSD Concentration

(ngL)

1482

MSD oo

RPD Recovery

910 71 - 125 EPA 1631E

Recovery Limits

RPO Limit Method Notes

Mercury 10200 1461 890 140 71 - 125 24 EPA 1631E

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager PagelO o26 1201073 Final Report 04125202 12

J1720 North Creek Parkway North Suite 400 l Bothell WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD1

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Calcium 5013000 15150 4802000 -13900 70 - 130 EPA 2008 Mod QM-02

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery

Limits RPDLimit Method Notes

Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this leport only apply to he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 11 o26 201073 Final Report 042512012 13

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody docwnenL This analytical report must be reproduced in its entirety

-I~ __-d-lt-~-- ~

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 ~~ Bothell WA 98011

Ph 425-686-1996 -- _ - - --- -~ FRONTIER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

13atch F20327I Sequence 2C22005

Preparation Closed Vessel Nitric Qven Digestion Lab Number f20327 l-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2442 958 70 130 EPA 2008 Mod

Sodium 258800 50500 257700 -213 70 - 130 EPA 2008 Mod QM-02

Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod

Chromium 057 70700 804 106 70 130 EPA 2008 Mod

Manganese 280S 60600 2834 476 70 - 130 EPA 2008 Mod QM-02

Tron ND 50500 5200 103 70 - 130 EPA 2008 Mod

Nickel 979 40400 141 1 107 70 130 EPA 2008 Mod

Copper 055 40400 434 939 70 - 130 EPA 2008 Mod

Zinc 040 10100 842 794 70- 130 EPA 2008 Mod

Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod

Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod

Molybdenum 1338 20200 1367 142 70- 130 EPA 2008 Mod QM-02

Silver ND 15150 l388 916 70 - 130 EPA 2008 Mod

Cadmium 0332 080800 1105 956 70 - 130 EPA 2008 Mod

Antimony 0408 0 80800 1259 105 70 - 130 EPA 2008 Mod

Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod

Lead ND 15150 l542 102 70- 130 EPA 2008 Mod

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits

RPDLimit Method Notes

Beryllium 20200 2561 102 474 70 130 20 EPA 2008 Mod

Sodium 50500 257100 -336 0243 70 130 20 EPA 2008 Mod QM-02

Aluminum 15I50 2034 993 0564 70 130 20 EPA 2008 Mod

Chromium 70700 773 101 385 70 130 20 EPA 2008 Mod

Manganese 60600 2852 769 0625 70 130 20 EPA 2008 Mod

Iron 50500 5187 103 0242 70 130 20 EPA 2008 Mod

Nickel 40400 1381 995 21 3 70 - 130 20 EPA 2008 Mod

Copper 40400 419 902 347 70 130 20 EPA 2008 Mod

Zinc 10100 916 868 849 70 130 20 EPA 2008 Mod

Arsenic 15150 2225 789 831 70 - 130 20 EPA 2008 Mod

Selenium 30300 9400 101 464 70 130 20 EPA 2008 Mod

Molybdenum 20200 1366 137 00771 70 130 20 EPA 2008 Mod QM-02

shy

shyshyshy

shyshy

shy

shy

shy

shy

Page 12 o26 1201073 Final Report 04252012 14

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~~ Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits

RPD Limit Method Notes

Silver 15150 1387 915 00874 70 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 130 20 EPA 2008 Mod Antimony 080800 l274 107 121 70 - 130 20 EPA 2008 Mod Barium 10100 2514 116 0781 70 130 20 EPA 2008 Mod

Lead 15150 1534 101 0525 70 130 20 EPA 2008 Mod

shy

shy

shy

shy

Frontier Global Sciences Inc The results 11 this report only apply to the samples analyzed in accordance bull~ith the chain ofcusLOdy documenL This analytical repogt1 must be reproduced in its entirety

Page 13 o26 1201073 Final Report 04252012

Liz Siska Project Manager

15

11720 North Creek Parkway North Suite 400 Bothell WA 98011~~Lshy

Ph 425-686-1996 Fx 425-686-3096middot~RONTIE~

GLOBAL SCIENCES

MATRIX SPIKE MA TRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327l-MS1MSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte Method Notes (11gL) (microgL) (microgL) Recovery Limits

100 70 - 130 EPA 2008 Mod AS Calcium 5013000 10100000 15120000

Spike MSD MSD Recovery RPDAdded Concentration Oo oo

RPO Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte

Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS

The results in 1his report only apply to 1he samples analyzed in accordanet wtth IheFrontier Global Sciences Inc chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager

Page 14 o26 1201073 Final Report 042512012 16

Frontier Global Sciences Inc The results in this report only apply ta the samples analyzed in accordance 1Yith the chain ofcustody documenL This analytical report must be reproduced in its entirety

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l ~ Ph 425-686-1996

~IER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD4

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2041 985 70 - 130 EPA 2008 Mod AS Sodium 258800 40400 292900 845 70 - 130 EPA 2008 Mod AS

Aluminum 529 40400 3956 966 70 130 EPA 2008 Mod AS

Chromium 057 40400 4301 106 70 130 EPA 2008 Mod AS

Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS

Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS

Nickel 979 50500 51 12 993 70- 130 EPA 2008 Mod AS Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS

Zinc 040 10100 9074 898 70 -130 EPA 2008 Mod AS

Arsenic 1030 40400 4317 104 70 - 130 EPA 2008 Mod AS Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS

Molybdenum 1338 20200 338l 101 70 130 EPA 2008 Mod AS Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS

Cadmium 0332 40400 3937 966 70 - 130 EPA 2008 Mod AS Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS Barium 2397 80800 1056 101 70 - 130 EPA 2008 Mod AS Lead ND 10100 9932 983 70 - 130 EPA 2008 Mod AS

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits

RPO limit Method Notes

Beryllium 20200 2007 968 171 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 - 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 l40 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 -130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 -130 20 EPA 2008 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 bull 130 20 EPA 2008 Mod AS

shy

Page 15 o26 1201073 Final Report 041252012 17

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

CLOBA L SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number J20327 l -MSMSD4

Analyte

Silver

Spike Added (microgL)

20200

MSD Concentration

(microgL)

MSD Oo

Recovery

RPO

Recovery Limits

RPOLimit Method Notes

1895 93 8 242 70 -130 20 EPA 2008 Mod AS

Cadmium 40400 3933 965 0104 70 - 130 20 EPA 2008 Mod AS

Antimony 20200 2107 102 0736 70 shy 130 20 EPA 2008 Mod AS

Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS

Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report 01ry apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 16026 1201073 Final Report 04252012 18

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096FRONTlEit

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo RPD

Recovery Limits

RPDLimit Method Notes

Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 17 o26 1201073 FinaReport 0412512012 19

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE I201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD4

Sample Spike MS MS

Analyte Concentration

(microgL) Added (iagL)

Concentration (microgL)

Oo

Recovery Recovery

Method Limits Notes

Thallium 5563 10100 1033 968 70 - 130 EPA 2008 Mod AS

Spike Added

MSD Concentration

MSD 0o Recovery RPO

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Thallium 10100 1037 971 0341 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This anayzical report must be reproduced in its entirely

Liz Siska Project Manager Page 18af26 1201073 Final Report 042512012 20

11720 North Creek Parkway North Suite 400 ~k~~ Bothell WA 98011

Ph 425-686-I 996 ~ONTI~ Fx 425-686-3096

GLOBAL S C IENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 1063-BSBSD1

LCS Source Nist 1641d

Analyte

Mercury

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1550

LCS Oo

Recovery

988

Recovery Limits

80 shy 120

Method

EPA I63I E

Notes

Analyte

Mercury

Spike Added ngL)

15679

LCSD Concentration

(ngL)

1595

LCSD Oo

Recovery

102

Oo

RPD

289

Recovery Limits

80 - 120

RPD Limit

24

Method

EPA 163IE

Notes

Frontier Global Sciences Inc The results in this repori only apply to the samples analyzed in accordance with the chain ofcustody document This analy1ical reporl must be reproduced in its entirety

Liz Siska Project Manager Page 19026 120l 07 3 Final Report 042512012 21

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096~

GL06Al SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201030-02

Batch F20 I063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F201063-MSMSD4

Analyte

Sample Concentration

(ngL)

Spike Added (ngL)

MS Concentration

(ngL)

MS Oo

Recovery Recovery

Limits Method Notes

Mercury

Analyte

554

Spike Added (ngL)

10200

MSD Concentration

(ngL)

1482

MSD oo

RPD Recovery

910 71 - 125 EPA 1631E

Recovery Limits

RPO Limit Method Notes

Mercury 10200 1461 890 140 71 - 125 24 EPA 1631E

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager PagelO o26 1201073 Final Report 04125202 12

J1720 North Creek Parkway North Suite 400 l Bothell WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD1

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Calcium 5013000 15150 4802000 -13900 70 - 130 EPA 2008 Mod QM-02

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery

Limits RPDLimit Method Notes

Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this leport only apply to he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 11 o26 201073 Final Report 042512012 13

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody docwnenL This analytical report must be reproduced in its entirety

-I~ __-d-lt-~-- ~

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 ~~ Bothell WA 98011

Ph 425-686-1996 -- _ - - --- -~ FRONTIER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

13atch F20327I Sequence 2C22005

Preparation Closed Vessel Nitric Qven Digestion Lab Number f20327 l-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2442 958 70 130 EPA 2008 Mod

Sodium 258800 50500 257700 -213 70 - 130 EPA 2008 Mod QM-02

Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod

Chromium 057 70700 804 106 70 130 EPA 2008 Mod

Manganese 280S 60600 2834 476 70 - 130 EPA 2008 Mod QM-02

Tron ND 50500 5200 103 70 - 130 EPA 2008 Mod

Nickel 979 40400 141 1 107 70 130 EPA 2008 Mod

Copper 055 40400 434 939 70 - 130 EPA 2008 Mod

Zinc 040 10100 842 794 70- 130 EPA 2008 Mod

Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod

Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod

Molybdenum 1338 20200 1367 142 70- 130 EPA 2008 Mod QM-02

Silver ND 15150 l388 916 70 - 130 EPA 2008 Mod

Cadmium 0332 080800 1105 956 70 - 130 EPA 2008 Mod

Antimony 0408 0 80800 1259 105 70 - 130 EPA 2008 Mod

Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod

Lead ND 15150 l542 102 70- 130 EPA 2008 Mod

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits

RPDLimit Method Notes

Beryllium 20200 2561 102 474 70 130 20 EPA 2008 Mod

Sodium 50500 257100 -336 0243 70 130 20 EPA 2008 Mod QM-02

Aluminum 15I50 2034 993 0564 70 130 20 EPA 2008 Mod

Chromium 70700 773 101 385 70 130 20 EPA 2008 Mod

Manganese 60600 2852 769 0625 70 130 20 EPA 2008 Mod

Iron 50500 5187 103 0242 70 130 20 EPA 2008 Mod

Nickel 40400 1381 995 21 3 70 - 130 20 EPA 2008 Mod

Copper 40400 419 902 347 70 130 20 EPA 2008 Mod

Zinc 10100 916 868 849 70 130 20 EPA 2008 Mod

Arsenic 15150 2225 789 831 70 - 130 20 EPA 2008 Mod

Selenium 30300 9400 101 464 70 130 20 EPA 2008 Mod

Molybdenum 20200 1366 137 00771 70 130 20 EPA 2008 Mod QM-02

shy

shyshyshy

shyshy

shy

shy

shy

shy

Page 12 o26 1201073 Final Report 04252012 14

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~~ Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits

RPD Limit Method Notes

Silver 15150 1387 915 00874 70 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 130 20 EPA 2008 Mod Antimony 080800 l274 107 121 70 - 130 20 EPA 2008 Mod Barium 10100 2514 116 0781 70 130 20 EPA 2008 Mod

Lead 15150 1534 101 0525 70 130 20 EPA 2008 Mod

shy

shy

shy

shy

Frontier Global Sciences Inc The results 11 this report only apply to the samples analyzed in accordance bull~ith the chain ofcusLOdy documenL This analytical repogt1 must be reproduced in its entirety

Page 13 o26 1201073 Final Report 04252012

Liz Siska Project Manager

15

11720 North Creek Parkway North Suite 400 Bothell WA 98011~~Lshy

Ph 425-686-1996 Fx 425-686-3096middot~RONTIE~

GLOBAL SCIENCES

MATRIX SPIKE MA TRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327l-MS1MSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte Method Notes (11gL) (microgL) (microgL) Recovery Limits

100 70 - 130 EPA 2008 Mod AS Calcium 5013000 10100000 15120000

Spike MSD MSD Recovery RPDAdded Concentration Oo oo

RPO Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte

Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS

The results in 1his report only apply to 1he samples analyzed in accordanet wtth IheFrontier Global Sciences Inc chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager

Page 14 o26 1201073 Final Report 042512012 16

Frontier Global Sciences Inc The results in this report only apply ta the samples analyzed in accordance 1Yith the chain ofcustody documenL This analytical report must be reproduced in its entirety

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l ~ Ph 425-686-1996

~IER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD4

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2041 985 70 - 130 EPA 2008 Mod AS Sodium 258800 40400 292900 845 70 - 130 EPA 2008 Mod AS

Aluminum 529 40400 3956 966 70 130 EPA 2008 Mod AS

Chromium 057 40400 4301 106 70 130 EPA 2008 Mod AS

Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS

Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS

Nickel 979 50500 51 12 993 70- 130 EPA 2008 Mod AS Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS

Zinc 040 10100 9074 898 70 -130 EPA 2008 Mod AS

Arsenic 1030 40400 4317 104 70 - 130 EPA 2008 Mod AS Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS

Molybdenum 1338 20200 338l 101 70 130 EPA 2008 Mod AS Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS

Cadmium 0332 40400 3937 966 70 - 130 EPA 2008 Mod AS Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS Barium 2397 80800 1056 101 70 - 130 EPA 2008 Mod AS Lead ND 10100 9932 983 70 - 130 EPA 2008 Mod AS

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits

RPO limit Method Notes

Beryllium 20200 2007 968 171 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 - 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 l40 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 -130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 -130 20 EPA 2008 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 bull 130 20 EPA 2008 Mod AS

shy

Page 15 o26 1201073 Final Report 041252012 17

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

CLOBA L SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number J20327 l -MSMSD4

Analyte

Silver

Spike Added (microgL)

20200

MSD Concentration

(microgL)

MSD Oo

Recovery

RPO

Recovery Limits

RPOLimit Method Notes

1895 93 8 242 70 -130 20 EPA 2008 Mod AS

Cadmium 40400 3933 965 0104 70 - 130 20 EPA 2008 Mod AS

Antimony 20200 2107 102 0736 70 shy 130 20 EPA 2008 Mod AS

Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS

Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report 01ry apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 16026 1201073 Final Report 04252012 18

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096FRONTlEit

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo RPD

Recovery Limits

RPDLimit Method Notes

Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 17 o26 1201073 FinaReport 0412512012 19

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE I201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD4

Sample Spike MS MS

Analyte Concentration

(microgL) Added (iagL)

Concentration (microgL)

Oo

Recovery Recovery

Method Limits Notes

Thallium 5563 10100 1033 968 70 - 130 EPA 2008 Mod AS

Spike Added

MSD Concentration

MSD 0o Recovery RPO

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Thallium 10100 1037 971 0341 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This anayzical report must be reproduced in its entirely

Liz Siska Project Manager Page 18af26 1201073 Final Report 042512012 20

11720 North Creek Parkway North Suite 400 ~k~~ Bothell WA 98011

Ph 425-686-I 996 ~ONTI~ Fx 425-686-3096

GLOBAL S C IENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 1063-BSBSD1

LCS Source Nist 1641d

Analyte

Mercury

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1550

LCS Oo

Recovery

988

Recovery Limits

80 shy 120

Method

EPA I63I E

Notes

Analyte

Mercury

Spike Added ngL)

15679

LCSD Concentration

(ngL)

1595

LCSD Oo

Recovery

102

Oo

RPD

289

Recovery Limits

80 - 120

RPD Limit

24

Method

EPA 163IE

Notes

Frontier Global Sciences Inc The results in this repori only apply to the samples analyzed in accordance with the chain ofcustody document This analy1ical reporl must be reproduced in its entirety

Liz Siska Project Manager Page 19026 120l 07 3 Final Report 042512012 21

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

J1720 North Creek Parkway North Suite 400 l Bothell WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327 I-MSMSD1

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Calcium 5013000 15150 4802000 -13900 70 - 130 EPA 2008 Mod QM-02

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo

RPD Recovery

Limits RPDLimit Method Notes

Calcium 15150 4943000 -4600 289 70 - 130 20 EPA 2008 Mod QM-02

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this leport only apply to he samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 11 o26 201073 Final Report 042512012 13

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody docwnenL This analytical report must be reproduced in its entirety

-I~ __-d-lt-~-- ~

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 ~~ Bothell WA 98011

Ph 425-686-1996 -- _ - - --- -~ FRONTIER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

13atch F20327I Sequence 2C22005

Preparation Closed Vessel Nitric Qven Digestion Lab Number f20327 l-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2442 958 70 130 EPA 2008 Mod

Sodium 258800 50500 257700 -213 70 - 130 EPA 2008 Mod QM-02

Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod

Chromium 057 70700 804 106 70 130 EPA 2008 Mod

Manganese 280S 60600 2834 476 70 - 130 EPA 2008 Mod QM-02

Tron ND 50500 5200 103 70 - 130 EPA 2008 Mod

Nickel 979 40400 141 1 107 70 130 EPA 2008 Mod

Copper 055 40400 434 939 70 - 130 EPA 2008 Mod

Zinc 040 10100 842 794 70- 130 EPA 2008 Mod

Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod

Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod

Molybdenum 1338 20200 1367 142 70- 130 EPA 2008 Mod QM-02

Silver ND 15150 l388 916 70 - 130 EPA 2008 Mod

Cadmium 0332 080800 1105 956 70 - 130 EPA 2008 Mod

Antimony 0408 0 80800 1259 105 70 - 130 EPA 2008 Mod

Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod

Lead ND 15150 l542 102 70- 130 EPA 2008 Mod

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits

RPDLimit Method Notes

Beryllium 20200 2561 102 474 70 130 20 EPA 2008 Mod

Sodium 50500 257100 -336 0243 70 130 20 EPA 2008 Mod QM-02

Aluminum 15I50 2034 993 0564 70 130 20 EPA 2008 Mod

Chromium 70700 773 101 385 70 130 20 EPA 2008 Mod

Manganese 60600 2852 769 0625 70 130 20 EPA 2008 Mod

Iron 50500 5187 103 0242 70 130 20 EPA 2008 Mod

Nickel 40400 1381 995 21 3 70 - 130 20 EPA 2008 Mod

Copper 40400 419 902 347 70 130 20 EPA 2008 Mod

Zinc 10100 916 868 849 70 130 20 EPA 2008 Mod

Arsenic 15150 2225 789 831 70 - 130 20 EPA 2008 Mod

Selenium 30300 9400 101 464 70 130 20 EPA 2008 Mod

Molybdenum 20200 1366 137 00771 70 130 20 EPA 2008 Mod QM-02

shy

shyshyshy

shyshy

shy

shy

shy

shy

Page 12 o26 1201073 Final Report 04252012 14

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~~ Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits

RPD Limit Method Notes

Silver 15150 1387 915 00874 70 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 130 20 EPA 2008 Mod Antimony 080800 l274 107 121 70 - 130 20 EPA 2008 Mod Barium 10100 2514 116 0781 70 130 20 EPA 2008 Mod

Lead 15150 1534 101 0525 70 130 20 EPA 2008 Mod

shy

shy

shy

shy

Frontier Global Sciences Inc The results 11 this report only apply to the samples analyzed in accordance bull~ith the chain ofcusLOdy documenL This analytical repogt1 must be reproduced in its entirety

Page 13 o26 1201073 Final Report 04252012

Liz Siska Project Manager

15

11720 North Creek Parkway North Suite 400 Bothell WA 98011~~Lshy

Ph 425-686-1996 Fx 425-686-3096middot~RONTIE~

GLOBAL SCIENCES

MATRIX SPIKE MA TRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327l-MS1MSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte Method Notes (11gL) (microgL) (microgL) Recovery Limits

100 70 - 130 EPA 2008 Mod AS Calcium 5013000 10100000 15120000

Spike MSD MSD Recovery RPDAdded Concentration Oo oo

RPO Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte

Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS

The results in 1his report only apply to 1he samples analyzed in accordanet wtth IheFrontier Global Sciences Inc chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager

Page 14 o26 1201073 Final Report 042512012 16

Frontier Global Sciences Inc The results in this report only apply ta the samples analyzed in accordance 1Yith the chain ofcustody documenL This analytical report must be reproduced in its entirety

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l ~ Ph 425-686-1996

~IER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD4

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2041 985 70 - 130 EPA 2008 Mod AS Sodium 258800 40400 292900 845 70 - 130 EPA 2008 Mod AS

Aluminum 529 40400 3956 966 70 130 EPA 2008 Mod AS

Chromium 057 40400 4301 106 70 130 EPA 2008 Mod AS

Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS

Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS

Nickel 979 50500 51 12 993 70- 130 EPA 2008 Mod AS Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS

Zinc 040 10100 9074 898 70 -130 EPA 2008 Mod AS

Arsenic 1030 40400 4317 104 70 - 130 EPA 2008 Mod AS Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS

Molybdenum 1338 20200 338l 101 70 130 EPA 2008 Mod AS Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS

Cadmium 0332 40400 3937 966 70 - 130 EPA 2008 Mod AS Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS Barium 2397 80800 1056 101 70 - 130 EPA 2008 Mod AS Lead ND 10100 9932 983 70 - 130 EPA 2008 Mod AS

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits

RPO limit Method Notes

Beryllium 20200 2007 968 171 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 - 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 l40 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 -130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 -130 20 EPA 2008 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 bull 130 20 EPA 2008 Mod AS

shy

Page 15 o26 1201073 Final Report 041252012 17

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

CLOBA L SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number J20327 l -MSMSD4

Analyte

Silver

Spike Added (microgL)

20200

MSD Concentration

(microgL)

MSD Oo

Recovery

RPO

Recovery Limits

RPOLimit Method Notes

1895 93 8 242 70 -130 20 EPA 2008 Mod AS

Cadmium 40400 3933 965 0104 70 - 130 20 EPA 2008 Mod AS

Antimony 20200 2107 102 0736 70 shy 130 20 EPA 2008 Mod AS

Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS

Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report 01ry apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 16026 1201073 Final Report 04252012 18

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096FRONTlEit

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo RPD

Recovery Limits

RPDLimit Method Notes

Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 17 o26 1201073 FinaReport 0412512012 19

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE I201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD4

Sample Spike MS MS

Analyte Concentration

(microgL) Added (iagL)

Concentration (microgL)

Oo

Recovery Recovery

Method Limits Notes

Thallium 5563 10100 1033 968 70 - 130 EPA 2008 Mod AS

Spike Added

MSD Concentration

MSD 0o Recovery RPO

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Thallium 10100 1037 971 0341 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This anayzical report must be reproduced in its entirely

Liz Siska Project Manager Page 18af26 1201073 Final Report 042512012 20

11720 North Creek Parkway North Suite 400 ~k~~ Bothell WA 98011

Ph 425-686-I 996 ~ONTI~ Fx 425-686-3096

GLOBAL S C IENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 1063-BSBSD1

LCS Source Nist 1641d

Analyte

Mercury

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1550

LCS Oo

Recovery

988

Recovery Limits

80 shy 120

Method

EPA I63I E

Notes

Analyte

Mercury

Spike Added ngL)

15679

LCSD Concentration

(ngL)

1595

LCSD Oo

Recovery

102

Oo

RPD

289

Recovery Limits

80 - 120

RPD Limit

24

Method

EPA 163IE

Notes

Frontier Global Sciences Inc The results in this repori only apply to the samples analyzed in accordance with the chain ofcustody document This analy1ical reporl must be reproduced in its entirety

Liz Siska Project Manager Page 19026 120l 07 3 Final Report 042512012 21

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody docwnenL This analytical report must be reproduced in its entirety

-I~ __-d-lt-~-- ~

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 ~~ Bothell WA 98011

Ph 425-686-1996 -- _ - - --- -~ FRONTIER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

13atch F20327I Sequence 2C22005

Preparation Closed Vessel Nitric Qven Digestion Lab Number f20327 l-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2442 958 70 130 EPA 2008 Mod

Sodium 258800 50500 257700 -213 70 - 130 EPA 2008 Mod QM-02

Aluminum 529 15150 2023 986 70 - 130 EPA 2008 Mod

Chromium 057 70700 804 106 70 130 EPA 2008 Mod

Manganese 280S 60600 2834 476 70 - 130 EPA 2008 Mod QM-02

Tron ND 50500 5200 103 70 - 130 EPA 2008 Mod

Nickel 979 40400 141 1 107 70 130 EPA 2008 Mod

Copper 055 40400 434 939 70 - 130 EPA 2008 Mod

Zinc 040 10100 842 794 70- 130 EPA 2008 Mod

Arsenic 1030 15150 2418 916 70 - 130 EPA 2008 Mod

Selenium 6340 30300 8973 869 70 130 EPA 2008 Mod

Molybdenum 1338 20200 1367 142 70- 130 EPA 2008 Mod QM-02

Silver ND 15150 l388 916 70 - 130 EPA 2008 Mod

Cadmium 0332 080800 1105 956 70 - 130 EPA 2008 Mod

Antimony 0408 0 80800 1259 105 70 - 130 EPA 2008 Mod

Barium 2397 10100 2495 968 70 - 130 EPA 2008 Mod

Lead ND 15150 l542 102 70- 130 EPA 2008 Mod

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD Oo

Recovery

RPD

Recovery Limits

RPDLimit Method Notes

Beryllium 20200 2561 102 474 70 130 20 EPA 2008 Mod

Sodium 50500 257100 -336 0243 70 130 20 EPA 2008 Mod QM-02

Aluminum 15I50 2034 993 0564 70 130 20 EPA 2008 Mod

Chromium 70700 773 101 385 70 130 20 EPA 2008 Mod

Manganese 60600 2852 769 0625 70 130 20 EPA 2008 Mod

Iron 50500 5187 103 0242 70 130 20 EPA 2008 Mod

Nickel 40400 1381 995 21 3 70 - 130 20 EPA 2008 Mod

Copper 40400 419 902 347 70 130 20 EPA 2008 Mod

Zinc 10100 916 868 849 70 130 20 EPA 2008 Mod

Arsenic 15150 2225 789 831 70 - 130 20 EPA 2008 Mod

Selenium 30300 9400 101 464 70 130 20 EPA 2008 Mod

Molybdenum 20200 1366 137 00771 70 130 20 EPA 2008 Mod QM-02

shy

shyshyshy

shyshy

shy

shy

shy

shy

Page 12 o26 1201073 Final Report 04252012 14

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~~ Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits

RPD Limit Method Notes

Silver 15150 1387 915 00874 70 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 130 20 EPA 2008 Mod Antimony 080800 l274 107 121 70 - 130 20 EPA 2008 Mod Barium 10100 2514 116 0781 70 130 20 EPA 2008 Mod

Lead 15150 1534 101 0525 70 130 20 EPA 2008 Mod

shy

shy

shy

shy

Frontier Global Sciences Inc The results 11 this report only apply to the samples analyzed in accordance bull~ith the chain ofcusLOdy documenL This analytical repogt1 must be reproduced in its entirety

Page 13 o26 1201073 Final Report 04252012

Liz Siska Project Manager

15

11720 North Creek Parkway North Suite 400 Bothell WA 98011~~Lshy

Ph 425-686-1996 Fx 425-686-3096middot~RONTIE~

GLOBAL SCIENCES

MATRIX SPIKE MA TRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327l-MS1MSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte Method Notes (11gL) (microgL) (microgL) Recovery Limits

100 70 - 130 EPA 2008 Mod AS Calcium 5013000 10100000 15120000

Spike MSD MSD Recovery RPDAdded Concentration Oo oo

RPO Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte

Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS

The results in 1his report only apply to 1he samples analyzed in accordanet wtth IheFrontier Global Sciences Inc chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager

Page 14 o26 1201073 Final Report 042512012 16

Frontier Global Sciences Inc The results in this report only apply ta the samples analyzed in accordance 1Yith the chain ofcustody documenL This analytical report must be reproduced in its entirety

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l ~ Ph 425-686-1996

~IER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD4

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2041 985 70 - 130 EPA 2008 Mod AS Sodium 258800 40400 292900 845 70 - 130 EPA 2008 Mod AS

Aluminum 529 40400 3956 966 70 130 EPA 2008 Mod AS

Chromium 057 40400 4301 106 70 130 EPA 2008 Mod AS

Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS

Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS

Nickel 979 50500 51 12 993 70- 130 EPA 2008 Mod AS Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS

Zinc 040 10100 9074 898 70 -130 EPA 2008 Mod AS

Arsenic 1030 40400 4317 104 70 - 130 EPA 2008 Mod AS Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS

Molybdenum 1338 20200 338l 101 70 130 EPA 2008 Mod AS Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS

Cadmium 0332 40400 3937 966 70 - 130 EPA 2008 Mod AS Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS Barium 2397 80800 1056 101 70 - 130 EPA 2008 Mod AS Lead ND 10100 9932 983 70 - 130 EPA 2008 Mod AS

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits

RPO limit Method Notes

Beryllium 20200 2007 968 171 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 - 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 l40 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 -130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 -130 20 EPA 2008 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 bull 130 20 EPA 2008 Mod AS

shy

Page 15 o26 1201073 Final Report 041252012 17

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

CLOBA L SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number J20327 l -MSMSD4

Analyte

Silver

Spike Added (microgL)

20200

MSD Concentration

(microgL)

MSD Oo

Recovery

RPO

Recovery Limits

RPOLimit Method Notes

1895 93 8 242 70 -130 20 EPA 2008 Mod AS

Cadmium 40400 3933 965 0104 70 - 130 20 EPA 2008 Mod AS

Antimony 20200 2107 102 0736 70 shy 130 20 EPA 2008 Mod AS

Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS

Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report 01ry apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 16026 1201073 Final Report 04252012 18

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096FRONTlEit

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo RPD

Recovery Limits

RPDLimit Method Notes

Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 17 o26 1201073 FinaReport 0412512012 19

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE I201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD4

Sample Spike MS MS

Analyte Concentration

(microgL) Added (iagL)

Concentration (microgL)

Oo

Recovery Recovery

Method Limits Notes

Thallium 5563 10100 1033 968 70 - 130 EPA 2008 Mod AS

Spike Added

MSD Concentration

MSD 0o Recovery RPO

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Thallium 10100 1037 971 0341 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This anayzical report must be reproduced in its entirely

Liz Siska Project Manager Page 18af26 1201073 Final Report 042512012 20

11720 North Creek Parkway North Suite 400 ~k~~ Bothell WA 98011

Ph 425-686-I 996 ~ONTI~ Fx 425-686-3096

GLOBAL S C IENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 1063-BSBSD1

LCS Source Nist 1641d

Analyte

Mercury

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1550

LCS Oo

Recovery

988

Recovery Limits

80 shy 120

Method

EPA I63I E

Notes

Analyte

Mercury

Spike Added ngL)

15679

LCSD Concentration

(ngL)

1595

LCSD Oo

Recovery

102

Oo

RPD

289

Recovery Limits

80 - 120

RPD Limit

24

Method

EPA 163IE

Notes

Frontier Global Sciences Inc The results in this repori only apply to the samples analyzed in accordance with the chain ofcustody document This analy1ical reporl must be reproduced in its entirety

Liz Siska Project Manager Page 19026 120l 07 3 Final Report 042512012 21

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~~ Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD2

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPO

Recovery Limits

RPD Limit Method Notes

Silver 15150 1387 915 00874 70 130 20 EPA 2008 Mod Cadmium 080800 1061 902 403 70 130 20 EPA 2008 Mod Antimony 080800 l274 107 121 70 - 130 20 EPA 2008 Mod Barium 10100 2514 116 0781 70 130 20 EPA 2008 Mod

Lead 15150 1534 101 0525 70 130 20 EPA 2008 Mod

shy

shy

shy

shy

Frontier Global Sciences Inc The results 11 this report only apply to the samples analyzed in accordance bull~ith the chain ofcusLOdy documenL This analytical repogt1 must be reproduced in its entirety

Page 13 o26 1201073 Final Report 04252012

Liz Siska Project Manager

15

11720 North Creek Parkway North Suite 400 Bothell WA 98011~~Lshy

Ph 425-686-1996 Fx 425-686-3096middot~RONTIE~

GLOBAL SCIENCES

MATRIX SPIKE MA TRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327l-MS1MSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte Method Notes (11gL) (microgL) (microgL) Recovery Limits

100 70 - 130 EPA 2008 Mod AS Calcium 5013000 10100000 15120000

Spike MSD MSD Recovery RPDAdded Concentration Oo oo

RPO Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte

Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS

The results in 1his report only apply to 1he samples analyzed in accordanet wtth IheFrontier Global Sciences Inc chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager

Page 14 o26 1201073 Final Report 042512012 16

Frontier Global Sciences Inc The results in this report only apply ta the samples analyzed in accordance 1Yith the chain ofcustody documenL This analytical report must be reproduced in its entirety

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l ~ Ph 425-686-1996

~IER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD4

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2041 985 70 - 130 EPA 2008 Mod AS Sodium 258800 40400 292900 845 70 - 130 EPA 2008 Mod AS

Aluminum 529 40400 3956 966 70 130 EPA 2008 Mod AS

Chromium 057 40400 4301 106 70 130 EPA 2008 Mod AS

Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS

Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS

Nickel 979 50500 51 12 993 70- 130 EPA 2008 Mod AS Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS

Zinc 040 10100 9074 898 70 -130 EPA 2008 Mod AS

Arsenic 1030 40400 4317 104 70 - 130 EPA 2008 Mod AS Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS

Molybdenum 1338 20200 338l 101 70 130 EPA 2008 Mod AS Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS

Cadmium 0332 40400 3937 966 70 - 130 EPA 2008 Mod AS Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS Barium 2397 80800 1056 101 70 - 130 EPA 2008 Mod AS Lead ND 10100 9932 983 70 - 130 EPA 2008 Mod AS

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits

RPO limit Method Notes

Beryllium 20200 2007 968 171 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 - 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 l40 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 -130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 -130 20 EPA 2008 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 bull 130 20 EPA 2008 Mod AS

shy

Page 15 o26 1201073 Final Report 041252012 17

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

CLOBA L SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number J20327 l -MSMSD4

Analyte

Silver

Spike Added (microgL)

20200

MSD Concentration

(microgL)

MSD Oo

Recovery

RPO

Recovery Limits

RPOLimit Method Notes

1895 93 8 242 70 -130 20 EPA 2008 Mod AS

Cadmium 40400 3933 965 0104 70 - 130 20 EPA 2008 Mod AS

Antimony 20200 2107 102 0736 70 shy 130 20 EPA 2008 Mod AS

Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS

Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report 01ry apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 16026 1201073 Final Report 04252012 18

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096FRONTlEit

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo RPD

Recovery Limits

RPDLimit Method Notes

Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 17 o26 1201073 FinaReport 0412512012 19

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE I201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD4

Sample Spike MS MS

Analyte Concentration

(microgL) Added (iagL)

Concentration (microgL)

Oo

Recovery Recovery

Method Limits Notes

Thallium 5563 10100 1033 968 70 - 130 EPA 2008 Mod AS

Spike Added

MSD Concentration

MSD 0o Recovery RPO

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Thallium 10100 1037 971 0341 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This anayzical report must be reproduced in its entirely

Liz Siska Project Manager Page 18af26 1201073 Final Report 042512012 20

11720 North Creek Parkway North Suite 400 ~k~~ Bothell WA 98011

Ph 425-686-I 996 ~ONTI~ Fx 425-686-3096

GLOBAL S C IENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 1063-BSBSD1

LCS Source Nist 1641d

Analyte

Mercury

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1550

LCS Oo

Recovery

988

Recovery Limits

80 shy 120

Method

EPA I63I E

Notes

Analyte

Mercury

Spike Added ngL)

15679

LCSD Concentration

(ngL)

1595

LCSD Oo

Recovery

102

Oo

RPD

289

Recovery Limits

80 - 120

RPD Limit

24

Method

EPA 163IE

Notes

Frontier Global Sciences Inc The results in this repori only apply to the samples analyzed in accordance with the chain ofcustody document This analy1ical reporl must be reproduced in its entirety

Liz Siska Project Manager Page 19026 120l 07 3 Final Report 042512012 21

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

11720 North Creek Parkway North Suite 400 Bothell WA 98011~~Lshy

Ph 425-686-1996 Fx 425-686-3096middot~RONTIE~

GLOBAL SCIENCES

MATRIX SPIKE MA TRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE3

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F20327l-MS1MSD3

Sample Spike MS MS Concentration Added Concentration Recovery

Analyte Method Notes (11gL) (microgL) (microgL) Recovery Limits

100 70 - 130 EPA 2008 Mod AS Calcium 5013000 10100000 15120000

Spike MSD MSD Recovery RPDAdded Concentration Oo oo

RPO Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte

Calcium 10100000 16140000 llO 653 70 - 130 20 EPA 2008 Mod AS

The results in 1his report only apply to 1he samples analyzed in accordanet wtth IheFrontier Global Sciences Inc chain ofcustody documenl This analytical report must be reproduced in its entirety

Liz Siska Project Manager

Page 14 o26 1201073 Final Report 042512012 16

Frontier Global Sciences Inc The results in this report only apply ta the samples analyzed in accordance 1Yith the chain ofcustody documenL This analytical report must be reproduced in its entirety

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l ~ Ph 425-686-1996

~IER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD4

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2041 985 70 - 130 EPA 2008 Mod AS Sodium 258800 40400 292900 845 70 - 130 EPA 2008 Mod AS

Aluminum 529 40400 3956 966 70 130 EPA 2008 Mod AS

Chromium 057 40400 4301 106 70 130 EPA 2008 Mod AS

Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS

Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS

Nickel 979 50500 51 12 993 70- 130 EPA 2008 Mod AS Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS

Zinc 040 10100 9074 898 70 -130 EPA 2008 Mod AS

Arsenic 1030 40400 4317 104 70 - 130 EPA 2008 Mod AS Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS

Molybdenum 1338 20200 338l 101 70 130 EPA 2008 Mod AS Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS

Cadmium 0332 40400 3937 966 70 - 130 EPA 2008 Mod AS Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS Barium 2397 80800 1056 101 70 - 130 EPA 2008 Mod AS Lead ND 10100 9932 983 70 - 130 EPA 2008 Mod AS

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits

RPO limit Method Notes

Beryllium 20200 2007 968 171 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 - 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 l40 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 -130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 -130 20 EPA 2008 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 bull 130 20 EPA 2008 Mod AS

shy

Page 15 o26 1201073 Final Report 041252012 17

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

CLOBA L SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number J20327 l -MSMSD4

Analyte

Silver

Spike Added (microgL)

20200

MSD Concentration

(microgL)

MSD Oo

Recovery

RPO

Recovery Limits

RPOLimit Method Notes

1895 93 8 242 70 -130 20 EPA 2008 Mod AS

Cadmium 40400 3933 965 0104 70 - 130 20 EPA 2008 Mod AS

Antimony 20200 2107 102 0736 70 shy 130 20 EPA 2008 Mod AS

Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS

Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report 01ry apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 16026 1201073 Final Report 04252012 18

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096FRONTlEit

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo RPD

Recovery Limits

RPDLimit Method Notes

Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 17 o26 1201073 FinaReport 0412512012 19

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE I201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD4

Sample Spike MS MS

Analyte Concentration

(microgL) Added (iagL)

Concentration (microgL)

Oo

Recovery Recovery

Method Limits Notes

Thallium 5563 10100 1033 968 70 - 130 EPA 2008 Mod AS

Spike Added

MSD Concentration

MSD 0o Recovery RPO

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Thallium 10100 1037 971 0341 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This anayzical report must be reproduced in its entirely

Liz Siska Project Manager Page 18af26 1201073 Final Report 042512012 20

11720 North Creek Parkway North Suite 400 ~k~~ Bothell WA 98011

Ph 425-686-I 996 ~ONTI~ Fx 425-686-3096

GLOBAL S C IENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 1063-BSBSD1

LCS Source Nist 1641d

Analyte

Mercury

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1550

LCS Oo

Recovery

988

Recovery Limits

80 shy 120

Method

EPA I63I E

Notes

Analyte

Mercury

Spike Added ngL)

15679

LCSD Concentration

(ngL)

1595

LCSD Oo

Recovery

102

Oo

RPD

289

Recovery Limits

80 - 120

RPD Limit

24

Method

EPA 163IE

Notes

Frontier Global Sciences Inc The results in this repori only apply to the samples analyzed in accordance with the chain ofcustody document This analy1ical reporl must be reproduced in its entirety

Liz Siska Project Manager Page 19026 120l 07 3 Final Report 042512012 21

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

Frontier Global Sciences Inc The results in this report only apply ta the samples analyzed in accordance 1Yith the chain ofcustody documenL This analytical report must be reproduced in its entirety

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l ~ Ph 425-686-1996

~IER Fx 425-686-3096 GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-MSMSD4

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Limits Method Notes

Beryllium 0507 20200 2041 985 70 - 130 EPA 2008 Mod AS Sodium 258800 40400 292900 845 70 - 130 EPA 2008 Mod AS

Aluminum 529 40400 3956 966 70 130 EPA 2008 Mod AS

Chromium 057 40400 4301 106 70 130 EPA 2008 Mod AS

Manganese 2805 40400 7042 105 70 - 130 EPA 2008 Mod AS

Iron ND 20200 2121 105 70 - 130 EPA 2008 Mod AS

Nickel 979 50500 51 12 993 70- 130 EPA 2008 Mod AS Copper 055 50500 4754 940 70 - 130 EPA 2008 Mod AS

Zinc 040 10100 9074 898 70 -130 EPA 2008 Mod AS

Arsenic 1030 40400 4317 104 70 - 130 EPA 2008 Mod AS Selenium 6340 40400 4688 100 70 - 130 EPA 2008 Mod AS

Molybdenum 1338 20200 338l 101 70 130 EPA 2008 Mod AS Silver ND 20200 1850 916 70 130 EPA 2008 Mod AS

Cadmium 0332 40400 3937 966 70 - 130 EPA 2008 Mod AS Antimony 0408 20200 2091 102 70 - 130 EPA 2008 Mod AS Barium 2397 80800 1056 101 70 - 130 EPA 2008 Mod AS Lead ND 10100 9932 983 70 - 130 EPA 2008 Mod AS

shy

shy

shy

shy

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

RPD

Recovery Limits

RPO limit Method Notes

Beryllium 20200 2007 968 171 70 - 130 20 EPA 2008 Mod AS Sodium 40400 292600 837 0114 70 - 130 20 EPA 2008 Mod AS Aluminum 40400 3954 966 00362 70 130 20 EPA 2008 Mod AS Chromium 40400 4287 106 0337 70 - 130 20 EPA 2008 Mod AS Manganese 40400 6944 102 l40 70 - 130 20 EPA 2008 Mod AS Iron 20200 2077 103 211 70 - 130 20 EPA 2008 Mod AS Nickel 50500 5126 996 0276 70 -130 20 EPA 2008 Mod AS Copper 50500 4707 931 0997 70 -130 20 EPA 2008 Mod AS Zinc 10100 9059 896 0166 70 - 130 20 EPA 2008 Mod AS Arsenic 40400 4299 104 0419 70 - 130 20 EPA 2008 Mod AS Selenium 40400 4682 100 0141 70 - 130 20 EPA 2008 Mod AS Molybdenum 20200 3365 100 0473 70 bull 130 20 EPA 2008 Mod AS

shy

Page 15 o26 1201073 Final Report 041252012 17

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

CLOBA L SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number J20327 l -MSMSD4

Analyte

Silver

Spike Added (microgL)

20200

MSD Concentration

(microgL)

MSD Oo

Recovery

RPO

Recovery Limits

RPOLimit Method Notes

1895 93 8 242 70 -130 20 EPA 2008 Mod AS

Cadmium 40400 3933 965 0104 70 - 130 20 EPA 2008 Mod AS

Antimony 20200 2107 102 0736 70 shy 130 20 EPA 2008 Mod AS

Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS

Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report 01ry apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 16026 1201073 Final Report 04252012 18

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096FRONTlEit

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo RPD

Recovery Limits

RPDLimit Method Notes

Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 17 o26 1201073 FinaReport 0412512012 19

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE I201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD4

Sample Spike MS MS

Analyte Concentration

(microgL) Added (iagL)

Concentration (microgL)

Oo

Recovery Recovery

Method Limits Notes

Thallium 5563 10100 1033 968 70 - 130 EPA 2008 Mod AS

Spike Added

MSD Concentration

MSD 0o Recovery RPO

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Thallium 10100 1037 971 0341 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This anayzical report must be reproduced in its entirely

Liz Siska Project Manager Page 18af26 1201073 Final Report 042512012 20

11720 North Creek Parkway North Suite 400 ~k~~ Bothell WA 98011

Ph 425-686-I 996 ~ONTI~ Fx 425-686-3096

GLOBAL S C IENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 1063-BSBSD1

LCS Source Nist 1641d

Analyte

Mercury

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1550

LCS Oo

Recovery

988

Recovery Limits

80 shy 120

Method

EPA I63I E

Notes

Analyte

Mercury

Spike Added ngL)

15679

LCSD Concentration

(ngL)

1595

LCSD Oo

Recovery

102

Oo

RPD

289

Recovery Limits

80 - 120

RPD Limit

24

Method

EPA 163IE

Notes

Frontier Global Sciences Inc The results in this repori only apply to the samples analyzed in accordance with the chain ofcustody document This analy1ical reporl must be reproduced in its entirety

Liz Siska Project Manager Page 19026 120l 07 3 Final Report 042512012 21

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

CLOBA L SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE4

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number J20327 l -MSMSD4

Analyte

Silver

Spike Added (microgL)

20200

MSD Concentration

(microgL)

MSD Oo

Recovery

RPO

Recovery Limits

RPOLimit Method Notes

1895 93 8 242 70 -130 20 EPA 2008 Mod AS

Cadmium 40400 3933 965 0104 70 - 130 20 EPA 2008 Mod AS

Antimony 20200 2107 102 0736 70 shy 130 20 EPA 2008 Mod AS

Barium 80800 1058 101 0205 70 - 130 20 EPA 2008 Mod AS

Lead 10100 9877 978 0549 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report 01ry apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 16026 1201073 Final Report 04252012 18

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096FRONTlEit

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo RPD

Recovery Limits

RPDLimit Method Notes

Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 17 o26 1201073 FinaReport 0412512012 19

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE I201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD4

Sample Spike MS MS

Analyte Concentration

(microgL) Added (iagL)

Concentration (microgL)

Oo

Recovery Recovery

Method Limits Notes

Thallium 5563 10100 1033 968 70 - 130 EPA 2008 Mod AS

Spike Added

MSD Concentration

MSD 0o Recovery RPO

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Thallium 10100 1037 971 0341 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This anayzical report must be reproduced in its entirely

Liz Siska Project Manager Page 18af26 1201073 Final Report 042512012 20

11720 North Creek Parkway North Suite 400 ~k~~ Bothell WA 98011

Ph 425-686-I 996 ~ONTI~ Fx 425-686-3096

GLOBAL S C IENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 1063-BSBSD1

LCS Source Nist 1641d

Analyte

Mercury

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1550

LCS Oo

Recovery

988

Recovery Limits

80 shy 120

Method

EPA I63I E

Notes

Analyte

Mercury

Spike Added ngL)

15679

LCSD Concentration

(ngL)

1595

LCSD Oo

Recovery

102

Oo

RPD

289

Recovery Limits

80 - 120

RPD Limit

24

Method

EPA 163IE

Notes

Frontier Global Sciences Inc The results in this repori only apply to the samples analyzed in accordance with the chain ofcustody document This analy1ical reporl must be reproduced in its entirety

Liz Siska Project Manager Page 19026 120l 07 3 Final Report 042512012 21

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

Liz Siska Project Manager

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096FRONTlEit

GLOBAL SCIENCES

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD

SOURCE 1201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F2033 l 4-MSMSD2

Analyte

Sample Concentration

(microgL)

Spike Added (microgL)

MS Concentration

(microgL)

MS

Recovery Recovery

Method Limits Notes

Thallium 5563 040400 5875 773 70 - 130 EPA 2008 Mod

Analyte

Spike Added (microgL)

MSD Concentration

(microgL)

MSD

Recovery

Oo RPD

Recovery Limits

RPDLimit Method Notes

Thallium 040400 5880 785 00859 70 - 130 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Page 17 o26 1201073 FinaReport 0412512012 19

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE I201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD4

Sample Spike MS MS

Analyte Concentration

(microgL) Added (iagL)

Concentration (microgL)

Oo

Recovery Recovery

Method Limits Notes

Thallium 5563 10100 1033 968 70 - 130 EPA 2008 Mod AS

Spike Added

MSD Concentration

MSD 0o Recovery RPO

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Thallium 10100 1037 971 0341 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This anayzical report must be reproduced in its entirely

Liz Siska Project Manager Page 18af26 1201073 Final Report 042512012 20

11720 North Creek Parkway North Suite 400 ~k~~ Bothell WA 98011

Ph 425-686-I 996 ~ONTI~ Fx 425-686-3096

GLOBAL S C IENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 1063-BSBSD1

LCS Source Nist 1641d

Analyte

Mercury

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1550

LCS Oo

Recovery

988

Recovery Limits

80 shy 120

Method

EPA I63I E

Notes

Analyte

Mercury

Spike Added ngL)

15679

LCSD Concentration

(ngL)

1595

LCSD Oo

Recovery

102

Oo

RPD

289

Recovery Limits

80 - 120

RPD Limit

24

Method

EPA 163IE

Notes

Frontier Global Sciences Inc The results in this repori only apply to the samples analyzed in accordance with the chain ofcustody document This analy1ical reporl must be reproduced in its entirety

Liz Siska Project Manager Page 19026 120l 07 3 Final Report 042512012 21

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPO

SOURCE I201073-01RE6

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-MSMSD4

Sample Spike MS MS

Analyte Concentration

(microgL) Added (iagL)

Concentration (microgL)

Oo

Recovery Recovery

Method Limits Notes

Thallium 5563 10100 1033 968 70 - 130 EPA 2008 Mod AS

Spike Added

MSD Concentration

MSD 0o Recovery RPO

Analyte (microgL) (microgL) Recovery RPD Limits Limit Method Notes

Thallium 10100 1037 971 0341 70 - 130 20 EPA 2008 Mod AS

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with rhe chain ofcustody document This anayzical report must be reproduced in its entirely

Liz Siska Project Manager Page 18af26 1201073 Final Report 042512012 20

11720 North Creek Parkway North Suite 400 ~k~~ Bothell WA 98011

Ph 425-686-I 996 ~ONTI~ Fx 425-686-3096

GLOBAL S C IENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 1063-BSBSD1

LCS Source Nist 1641d

Analyte

Mercury

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1550

LCS Oo

Recovery

988

Recovery Limits

80 shy 120

Method

EPA I63I E

Notes

Analyte

Mercury

Spike Added ngL)

15679

LCSD Concentration

(ngL)

1595

LCSD Oo

Recovery

102

Oo

RPD

289

Recovery Limits

80 - 120

RPD Limit

24

Method

EPA 163IE

Notes

Frontier Global Sciences Inc The results in this repori only apply to the samples analyzed in accordance with the chain ofcustody document This analy1ical reporl must be reproduced in its entirety

Liz Siska Project Manager Page 19026 120l 07 3 Final Report 042512012 21

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

11720 North Creek Parkway North Suite 400 ~k~~ Bothell WA 98011

Ph 425-686-I 996 ~ONTI~ Fx 425-686-3096

GLOBAL S C IENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPO

Batch F201063 Sequence 2A09010

Preparation BrCI Oxidation Lab Number F20 1063-BSBSD1

LCS Source Nist 1641d

Analyte

Mercury

Spike Added (ngL)

15679

LCS Concentration

(ngL)

1550

LCS Oo

Recovery

988

Recovery Limits

80 shy 120

Method

EPA I63I E

Notes

Analyte

Mercury

Spike Added ngL)

15679

LCSD Concentration

(ngL)

1595

LCSD Oo

Recovery

102

Oo

RPD

289

Recovery Limits

80 - 120

RPD Limit

24

Method

EPA 163IE

Notes

Frontier Global Sciences Inc The results in this repori only apply to the samples analyzed in accordance with the chain ofcustody document This analy1ical reporl must be reproduced in its entirety

Liz Siska Project Manager Page 19026 120l 07 3 Final Report 042512012 21

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096FRO NTI Elf middot

GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F20327 l Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank Sgike

Spike LCS LCS Added Concentration Oo Recovery

Analyte (microgL) (microgL) Recovery Limits Method Notes

Beryllium 20000 1930 965 85 - 115 EPA 2008 Mod

Sodium 50000 499 998 85 - 115 EPA 2008 Mod

Aluminum 15000 1460 973 85 - 115 EPA 2008 Mod

Calcium 15000 1528 102 85 115 EPA 2008 Mod

Chromium 70000 657 939 85 115 EPA 2008 Mod

Manganese 60000 586 976 85 115 EPA 2008 Mod

Iron 50000 4753 95l 85 - 115 EPA 2008 Mod

Nickel 40000 401 100 85 - 115 EPA 2008 Mod

Copper 40000 418 105 85 115 EPA 2008 Mod

Zinc 10000 1033 103 85 115 EPA 2008 Mod

Arsenic 15000 1437 958 85 115 EPA 2008 Mod

Selenium 30000 2966 989 85 - 115 EPA 2008 Mod

Molybdenum 20000 181 905 85 115 EPA 2008 Mod

Silver 15000 1517 101 85 - 115 EPA 2008 Mod

Cadmium 080000 0781 976 85 115 EPA 2008 Mod

Antimony 080000 0815 102 85 115 EPA 2008 Mod

Barium 10000 969 969 85 - 115 EPA 2008 Mod

Lead 15000 1597 106 85 115 EPA 2008 Mod

shy

shy

shy

shy

shy

shy

shy

shy

shy

shy

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery Oo

RPO Recovery

Limits RPD Limit Method Notes

Beryllium

Sodium

20000

50000

l949

500

974

100

0955

0216

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Aluminum 15000 1485 990 l71 85 - ll5 20 EPA 2008 Mod

Calcium 15000 1544 103 103 85 - 115 20 EPA 2008 Mod

Chromium 70000 667 953 148 85 - 115 20 EPA 2008 Mod

Manganese

Iron

60000

50000

596

4852

994

970

l75

206

85 - 115

85 - 115

20

20

EPA 2008 Mod

EPA 2008 Mod

Nickel 40000 402 101 0246 85 -115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in 1his report only apply Jo the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its enlirety

--~ ---6~~middot Page 20of26 120J07 3 Final Report 04252012

Liz Siska Project Manager 22

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

11720 North Creek Parkway North Suite 400 Bothe I I WA 98011 ~ Ph 425-686-1996

Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203271 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203271-BSBSD1

LCS Source Blank S12ike

Spike LCSD LCSD Added Concentration Oo Oo Recovery RPD

Analyte (microgL) (microgL) Recovery RPO Limits Limit Method Notes

Copper 40000 428 107 224 85 - 115 20 EPA 2008 Mod

Zinc 10000 1039 104 0570 85 - 115 20 EPA 2008 Mod

Arsenic 15000 1452 968 0977 85 - 115 20 EPA 2008 Mod

Selenium 30000 3015 101 166 85 - 115 20 EPA 2008 Mod

Molybdenwn 20000 182 910 0564 85 - 115 20 EPA 2008 Mod

Silver 15000 1502 100 103 85 - 115 20 EPA 2008 Mod

Cadmium 080000 0828 103 585 85 - 115 20 EPA 2008 Mod

Antimony 080000 0808 10 I 0848 85 - 115 20 EPA 2008 Mod

Barium 10000 986 986 177 85 - 115 20 EPA 2008 Mod

Lead 15000 1620 108 142 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcus1ody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 21 o26 1201073 Final Report 04252012 23

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

11720 North Creek Parkway North Suite 400

~~- Bothell WA 98011 Ph 425-686-1996

~RONTIER~ Fx 425-686-3096 GLOBAL SCIENCES

LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE

RECOVERY AND RPD

Batch F203314 Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion Lab Number F203314-BSBSD l

LCS Source Blank Spike

Analyte

Spike Added (microgL)

LCS Concentration

(microgL)

LCS Oo

Recovery Recovery

Limits Method Notes

Thallium 040000 0396 989 85 - 115 EPA 2008 Mod

Analyte

Spike Added (microgL)

LCSD Concentration

(microgL)

LCSD

Recovery

RPD Recovery

Limits RPO Limit Method Notes

Thallium 040000 0391 978 112 85 - 115 20 EPA 2008 Mod

Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report mus be reproduced in its entirety

Liz Siska Project Manager Page 22 o26 1201073 Final Report 04252012 24

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

11720 North Creek Parkway North Suite 400 Bothe WA 98011

Ph 425-686-1996 ~ Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument Hg-17 Sequence 2A090IO

Preparation BrCI Oxidation

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F201063-BLKI

F201063-BLK2

F20I063-BLK3

Mercury

Mercury

Mercury

-0009

-0006

-002

050

050

050

ngL

ngl

ngL

F201063

F201063

F20I063

EPA l631E

EPA1631E

EPA 163IE

u u u

F201063-BLK4

F201063-BLK5

Mercury

Mercury

003

011

050

052

ngL

ngL

F201063

F201063

EPA I631E

EPA 1631E

U QB-04

U QB-06

Frontier middotGlobal Sciences Inc The results in this report only apply 10 the samples analyzed in accordance with 1he chain ofcustody docummt This analylical report must be reproduced in its entirety

Liz Siska Project Manager Page 23 o26 1201073 Final Report04252012 25

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

11720 North Creek Parkway North Suite 400 Bothell WA 980 l l

Ph 425-686-1996 ~ middot FRO NTl E~-- Fx 425-686-3096 GLOBAL SCIENCES

PREPARATION BLANKS

Instrument ICPMS-6 Sequence 2C22005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F20327I-BLK1 Beryllium 000008 0060 microgL F203271 PA 2008 Molt u F203271-BLK1 Sodium 2 20 microgL F203271 PA 2008 Moc u F203 271-BLKI Aluminum -004 40 microgL F20327I PA 2008 Moc u F20327I-BLK1 Calcium I 40 microgL F203271 PA 2008 Moc u F203271-BLKl Chromium -002 010 microgL F203271 PA 2008 Moc u F203271-BLKI Manganese 001 010 microgL F20327l PA 2008 Moc u F203271-BLKI Iron -002 100 microgL F20327l pA 2008 Moc u F203 27 I-BLKl Nickel 0004 010 microgL F203271 PA 2008 Moc u F203 271-BLK l Copper 0003 010 microgL F20327I PA 2008 Moc u F203271-BLKl Zinc 0007 020 microgL F203271 PA 2008 Moc u F203271-BLK1 Arsenic -006 015 microgL F203271 PA 2008 Moc u F203271-BLKI Selenium -002 060 microgL F203271 PA 2008 Moc u F203 27 L-BLK I Molybdenum 001 006 microgL F203271 PA 2008 Moc u F203271-BLK1 Silver -00005 0020 microgL F203271 PA 2008 Moc u F203271-BLK1 Cadmium 0004 0020 microgL F203271 PA 2008 Moc u F203271-BLKI Antimony 0002 0020 microgL F20327I PA 2008 Moc u F203271-BLKI Barium 001 020 microgL F203271 PA 2008 Moc u F203-27l-BLKI Lead 0010 0040 microgL F20327I PA 2008 Moc u

Frontier Global Sciences Inc The results in this report only apply lo the somples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety

Liz Siska Project Manager Page 24 o26 I 201073 Final Report 04252012 26

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

~Jshy~NT-rrr~ GLOBAL SCIENCES

11720 North Creek Parkway North Suite 400 Bothell WA 98011

Ph 425-686-1996 Fx 425-686-3096

Instrument ICPMS-3

PREPARATION BLANKS

Sequence 2C25005

Preparation Closed Vessel Nitric Oven Digestion

Lab Sample ID Analyte Found MRL Units Batch Method Notes

F203314-BLK1 Thallium 00007 0010 microgL F203314 ~PA 2008 Mo( u

Frontier Global Sciences Inc

Liz Siska Project Manager

The results in this report only apply to the samples analyred in acwrdanct with the chain ofcustody document This analytical repon must be reproduced in its entirety

Page 25 o26 1201073 Final Report 04252012 27

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

11720 North Creek Parkway North Suite 400 ~~ shy Bothell WA 980 J l

Ph 425-686-1 996 Fx 425-686-3096 ~RONTIE~

GLOBAL SCIENCES

Notes and Definitions

U Analyte included in the analysis but not detected

QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration Jess than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD

QB-06 The blank was preserved to 5 BrCI rather than l The control limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL

QB-04 The blank was preserved to 2 BrCI rather than I The control limit for blanks preserved to greater than I BrCI is the preservation percentage multiplied by the MRL

FB-1631 Required equipmentfieldfilter blank not submitted by the client The sample has been analyzed according 10 163IE but does not meet 163 lE criteria

AS This MS andor MSD is an analytical spike andor an analytical spike duplicate

DET Analyte Detected

MDL Minimum Detection Limit

MRL Minimum Reporting Limit

ND Analyte Not Detected at or above the reporting limit

wet Sample results reported on a wet weight basis

dry Sample results reported on a dry weight basis

RPD Relative Percent Difference

RSD Relative Standard Deviation

Frontier Global Sciences Inc The results i11 this report only apply to the samples anolyzed In accordance with the chain ofcustody document This analytical report must be reproduced in its entit ety

Liz Siska Project Manager Page 26of26 1201073 FinaReport 04252012 28

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)

CHAIN-OF-USTODY ~ECORD Page of _f_ _J106677

BoLD FtELDs REQUIRED PLEASE CIRCL E REQUESTED ANALYSIS

w Ishy iSAMPLING 0 iii aJ 0 w DATEITtME co D _ 0

I c w

0 IF COMPOSITE

w ~ QQ

~ u gto

INDICATE BoTH ~ middotXbull- -~ I a -

SAMPLE JD START amp FINISH Ishy lt( ~ g lt( c0

DATEITIME I l) ~~ ~~

1shy t middotT -f blr~ishy middotmiddot~ aK e-~Mi III 0 -rz

t5JJ vcc WJ c

ircmicro_ T - G+llt rrl h l s-12 ~~ Cc l bulli t~w 1( y

lmiddot~I- f11 r c~~ 6~-~ l sl) cgtpi WIJ 6shy

~ON MATRIX A-All S~SOIL GW-GROUNO WATpound- SW~UampFACE WATH OW-DAINKING Wm~

WW-WASTE WATER PRHERIATIYE ll-HCl N-HN01 5-llS01 Na-tlaOH M-MEOH

PROJECT MANAGER A0 1L()r AwJ4i--PAvI Kp r COMPANY l)o=Mlts gtf (AH (i ~1 6 ~ A ADP~~Sl 9] fs dltr ed CITY ~ ZIP 6gt o-(

PHONE 22 (-(altmiddot( EXT ____ FAX ______________________

E-MAIL iaht-ebBamp e r11x CtgttA

SITE NAHE Mecrihlaquof ShJ-b P~OJECT -

STATE NH MA ME VT OTHER _________

REGULATORY PROGRAM NPDES RGP POTW STOAHWATER OA

GWP OIL fUND BkOWNFIELO 0~ OTHER _________ _

~~ -

i 8~ d c ~

iE ~ ~ ~ i - sect c = gtshylaquo 0 O 0 - sect $ -o E c - = ~ - s ~x~ sect ~ ~ ic ~ c - g -shy 0 a - gt _

~ - = -- t aQ == =0shyc _ g

~ ~ ~ ~

~ c ~~ a ~~ ~~1~I= = - - IxI

X

I I I I I I Igtlt

D ATE NEEDED --1shy L1_+-1)_-----shy

TEHP J_r QAQC REPORTIN~EL

A (_0

OR

C

PRESUMPTIVE CERTAINTY

RELINQUISHED BY DATE

REPORTING OPTIONS

PAEllHl YH OR No If YES FAX OR PDF

ELECTRONIC OPTIONS

No fAX E-MAIL PDf

THE

ICE G_v No

EQUI

7fshyzo1z

I~

RECEIYEO BY

bullc

107555

I~~ Ii ( ()0

U IltI ~11 NOTES MEOH VIAL

METALS 8 RCRA 13 pp FE MH PB Cu

07HEft METALS -----------shy

DISSOLYIP METALS FIELD flLTERED1 YES No

Noru (IESPECIAL DETECTION LINITS BllllKG KIO IF 01mmr) i(Z) lcJ__s 1 ( Jc ltlr sJ 6~ 6eshy

1 c Co

Ci c Fe I rtbull11 f-1 o Ni AJ Jr middotn t11

3)s-(c CtecJC -ltJ c( cil ~-middotmiddotmiddotr V Ar 5e

1 Hj middot

~ () All MG~r-1) tt res IVI) ~lrioe(l Sm HISTORY (E)Sed Cip- ~f fh IHt~

IT SUSPECTED CONTAMINATION_________QUOTE PO OJ)J-7J-Cl

fp~I ImiddotRELINQUISHED BY DATE T1HE Rm1vro Sr l Fino READINGS

_micro ~ easte~~ analytical_ inc 2s CHENELL DRrve ICoNcono N H 03301 I TEL 6032280525 j 1aoo2a1os2s IFAx 603228~591 E-MA1L cvST0MrnseRv1cEeA1LAssc0Mj w wweA1LAsscoM

- aaJJf-bullbull middotmiddotmiddotmiddotmiddot middotmiddot middot middot (WHITE ORIGINAL GREEN PROJECT MANAGER)