arista c-41 developer part a - freestyle photographic supplies€¦ · arista c-41 developer part b...

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MATERIAL SAFETY DATA SHEET ARISTA C-41 DEVELOPER PART A 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc. Product Name: C-41 DEVELOPER PART A Product Number: 101202, 101222 Date Prepared: 04/23/2007 Customer Information Phone Number: 1-800-521-4042 CHEMTREC®: 24 Hour Emergency Transport Phone Number: 1-800-424-9300 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS OHSA PEL ACGIH TLV Weight % POTASSIUM CARBONATE 58-40-7 N.E. N.E. 10-15 TRISODIUM HEDTA MIXTURE N.E. N.E. 1-5 GLACIAL ACETIC ACID 64-19-7 10 ppm TWA 10 ppm TWA 1-3 3. HAZARDOUS IDENTIFICATION POTENTIAL HEALTH EFFECTS Eye Contact: May cause irritation and burns. Inhalation: Mist may cause irritation to respiratory tract. In contact with strong acids or if heated may liberate sulfur dioxide gas which is irritating. Some asthmatics or hypersensitive individuals may experience difficult breathing. Ingestion: May cause irritation to the gastrointestinal tract. Some asthmatics and sulfite-sensitive individuals may experience wheezing, chest tightness, stomach upset, hives, diarrhea. Skin Contact: May cause skin irritation. Signs And Symptoms Of Exposure: Eye and skin irritation, abdominal pain, vomiting and diarrhea upon ingestion., difficulty breathing. 4. FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. Inhalation: If symptomatic, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Skin Contact: Flush skin with plenty of water and wash with a non-alkaline skin cleaner. Wash contaminated clothes before reuse. Get medical attention if irritation develops. Aggravated Medical Conditions: Individuals who are under the care of a physician or have chronic ailments, should consult a physician before using this product. Supplemental Health Information: None of the components in this product is listed by IARC, NTP, or OSHA as carcinogen. 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES Flash Point: Nonflammable Flash Point Method: Not applicable Auto ignition: Not applicable LEL: Not applicable UEL: Not applicable Extinguishing Media: Use agent appropriate for the surrounding area. Date: 6/19/07 C-41 Developer Part A 1 / 4

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Page 1: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET

ARISTA C-41 DEVELOPER PART A 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc. Product Name: C-41 DEVELOPER PART A Product Number: 101202, 101222 Date Prepared: 04/23/2007 Customer Information Phone Number: 1-800-521-4042 CHEMTREC®: 24 Hour Emergency Transport Phone Number: 1-800-424-9300 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS OHSA PEL ACGIH TLV Weight % POTASSIUM CARBONATE 58-40-7 N.E. N.E. 10-15 TRISODIUM HEDTA MIXTURE N.E. N.E. 1-5 GLACIAL ACETIC ACID 64-19-7 10 ppm TWA 10 ppm TWA 1-3 3. HAZARDOUS IDENTIFICATION POTENTIAL HEALTH EFFECTS Eye Contact: May cause irritation and burns. Inhalation: Mist may cause irritation to respiratory tract. In contact with strong acids or if heated may liberate sulfur dioxide gas which is irritating. Some asthmatics or hypersensitive individuals may experience difficult breathing. Ingestion: May cause irritation to the gastrointestinal tract. Some asthmatics and sulfite-sensitive individuals may experience wheezing, chest tightness, stomach upset, hives, diarrhea. Skin Contact: May cause skin irritation. Signs And Symptoms Of Exposure: Eye and skin irritation, abdominal pain, vomiting and diarrhea upon ingestion., difficulty breathing. 4. FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. Inhalation: If symptomatic, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Skin Contact: Flush skin with plenty of water and wash with a non-alkaline skin cleaner. Wash contaminated clothes before reuse. Get medical attention if irritation develops. Aggravated Medical Conditions: Individuals who are under the care of a physician or have chronic ailments, should consult a physician before using this product. Supplemental Health Information: None of the components in this product is listed by IARC, NTP, or OSHA as carcinogen. 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES Flash Point: Nonflammable Flash Point Method: Not applicable Auto ignition: Not applicable LEL: Not applicable UEL: Not applicable Extinguishing Media: Use agent appropriate for the surrounding area.

Date: 6/19/07 C-41 Developer Part A 1 / 4

Page 2: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Fire or excessive heat may produce hazardous decomposition products. Unusual Fire And Explosion Hazards: None Combustion Products: Carbon dioxide and carbon monoxide 6. ACCIDENTAL RELEASE MEASURES Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards and safety precautions before proceeding with cleanup. Use appropriate personal protective equipment. Avoid contact with skin and eyes. Stop the spillage. Dike the spill. Prevent liquid from entering sewers, waterways or low areas. Absorb spillage in inert material. Soak up with sawdust, sand, or other absorbent material. Remove non-usable solid material and/or contaminated soil for disposal in an approved and permitted landfill. Discharge to sewer requires approval of permitting authority. Working solution is able to be flushed to sewer with large amounts of water upon approval. 7. HANDLING AND STORAGE Precautions To Be Taken In Handling And Storage: Store in a cool, dry, well-ventilated area. Keep containers closed. Do not store with incompatible materials. Do not store or consume food, drink, or tobacco where they may become contaminated with this material. Other Precautions: All labeled precautions must be observed when handling, storing and transporting empty containers due to product residues. Triple rinse before disposal. 8. EXPOSURE CONTROL / PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: If use conditions do not maintain vapors or fumes, use a NIOSH approved half-face cartridge respirator with HEPA cartridges. Ventilation: Provide exhaust ventilation sufficient to keep the airborne concentration of this product below its exposure limits. Protective Gloves: Rubber, or neoprene waterproof gloves are recommended. Eye Protection: Safety glasses with side shields (or goggles) and a face shield. Other Protective Clothing or Equipment: Rubber or plastic apron or other protective clothing suitable for the exposure risk. Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands after use, before smoking, or using the toilet. Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Guidelines: See Section 2. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance And Odor: Colorless, odorless solution. Solubility In Water: Complete Boiling Point: N.E. Vapor Pressure: N.E. Specific Gravity: 1.14 Melting Point: Not applicable Freezing Point: N.E. Evaporation Rate: N.E. Vapor Density: N.E. Percent Volatile: 84.06 Ph: 10.52 Molecular Weight: Not applicable Pounds Per Gallon: 9.46 V.O.C. is 19.63 g/L or 1.73% or 0.16 lb./gal.

Date: 6/19/07 C-41 Developer Part A 2 / 4

Page 3: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET 10. STABILITY AND REACTIVITY Stability: Stable Conditions To Avoid: High temperatures. Incompatibility: Strong acids. Hazardous Decomposition Or By Products: May produce oxides of carbon and sulfur. Hazardous Polymerization: Will Not Occur 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS The preferred options for disposal are to send to licensed reclaimers, or to permitted incinerators. Any disposal practice must be in compliance with federal, state, and local regulations. Do not dump into sewers, ground, or any body of water. 14. TRANSPORT INFORMATION DOT Class: NOT REGULATED Hazard Class: NONE UN No.: NOT APPLICABLE Packing Group: Guide No: Ship Name: 15. REGULATORY INFORMATION TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY. SARA TITLE III: NONE CALIF. PROP. 65: Product contains a mixture which includes trace amounts of Trisodium NTA. The State of California’s Safe Drinking Water and Toxic Enforcement Act of 1986, or Proposition 65 requires the following information. This regulation does not address di minimus levels; therefore, even trace amounts of the chemicals included on Proposition 65’s list of chemicals known to the State of California to cause cancer or reproductive toxicity must be noted with the “Safe Harbor” wording. WARNING: This product contains Trisodium NTA – known to the State of California to cause cancer, birth defects or other reproductive harm. CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. SCAQMD Rule 443.1 Photochemically Reactive: No Maximum Grams of VOC per Liter: 19.63 gm/L Vapor Pressure: N.E. mmHg@ 20 °C 16. OTHER INFORMATION (HMIS) Health: 2 Flammability: 0 Reactivity: 0 Protective: B

Date: 6/19/07 C-41 Developer Part A 3 / 4

Page 4: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data available to us and is believed to be accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. We assume no responsibility for the injuries from the use of the product described herein.

Date: 6/19/07 C-41 Developer Part A 4 / 4

Page 5: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET

ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc. Product Name: C-41 DEVELOPER PART B Product Number: 101202, 101222 Date Prepared: 04/23/2007 Customer Information Phone Number: 1-800-521-4042 CHEMTREC®: 24 Hour Emergency Transport Phone Number: 1-800-424-9300 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS OHSA PEL ACGIH TLV Weight % HYDROXYLAMINE SULFATE 10039-54-0 N.E. N.E. 1-5 3. HAZARDOUS IDENTIFICATION POTENTIAL HEALTH EFFECTS Eye Contact: May cause irritation. Inhalation: Low hazard for recommended handling. May cause irritation to the mucous membranes. In contact with strong acids or if heated may liberate sulfur dioxide gas which is irritating. Some asthmatics or hypersensitive may experience difficult breathing. Ingestion: Harmful if swallowed. May cause blood effects (methemoglobinemia and anemia). Symptoms include cyanosis, convulsions, and coma. Skin Contact: Causes irritation. Can cause dermatitis. May be harmful if absorbed through the skin. May cause allergic skin reaction. Signs And Symptoms Of Exposure: Eye and skin irritation, blue skin, difficulty breathing. 4. FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. Inhalation: If symptomatic, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Skin Contact: Flush skin with plenty of water and wash with a non-alkaline skin cleaner. Wash contaminated clothes before reuse. Get medical attention if irritation develops. Aggravated Medical Conditions: Individuals who are under the care of a physician or have chronic ailments, should consult a physician before using this product. Supplemental Health Information: None of the components in this product is listed by IARC, NTP, or OSHA as carcinogen. 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES Flash Point: Noncombustible Flash Point Method: Not applicable Auto ignition: Not applicable LEL: Not applicable UEL: Not applicable Extinguishing Media: Use water spray, carbon dioxide, dry chemical, alcohol foam. Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and acid resistant protective clothing with full face piece to prevent contact with skin and eyes.

Date: 6/19/07 C-41 Developer Part B 1 / 3

Page 6: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET Unusual Fire And Explosion Hazards: Carbon dioxide, carbon monoxide, oxides of sulfur. Combustion Products: None 6. ACCIDENTAL RELEASE MEASURES Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards and safety precautions before proceeding with cleanup. Use appropriate personal protective equipment. Avoid contact with skin and eyes. Stop the spillage. Dike the spill. Prevent liquid from entering sewers, waterways or low areas. Absorb spillage in inert material. Soak up with sawdust, sand, or other absorbent material. Remove non-usable solid material and/or contaminated soil for disposal in an approved and permitted landfill. Discharge to sewer requires approval of permitting authority. Working solution is able to be flushed to sewer with large amounts of water upon approval. 7. HANDLING AND STORAGE Precautions To Be Taken In Handling And Storage: Store in a cool, dry, well-ventilated area. Avoid breathing mist. Keep containers closed. Do not store with incompatible materials. Do not store or consume food, drink, or tobacco where they may become contaminated with this material. Other Precautions: All labeled precautions must be observed when handling, storing and transporting empty containers due to product residues. Triple rinse before disposal. 8. EXPOSURE CONTROL / PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: If use conditions do not maintain vapors or fumes from working solution below exposure limits, use a NIOSH approved respirator with acid gas cartridges. Ventilation: Provide exhaust ventilation sufficient to keep the airborne concentration of this product below its exposure limits, typically 10 air changes per hour. Protective Gloves: Rubber, or neoprene waterproof gloves are recommended. Eye Protection: Safety glasses with side shields (or goggles). Other Protective Clothing or Equipment: Rubber or plastic apron or other protective clothing suitable for the exposure risk. Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands after use, before smoking, or using the toilet. Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Guidelines: See Section 2. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance And Odor: Colorless, odorless liquid. Solubility In Water: Complete Boiling Point: Not applicable Vapor Pressure: 18 mm Hg @ 20°C Ph: 3.71 Specific Gravity: 1.018g/ml Melting Point: Not applicable Freezing Point: N.E. Evaporation Rate: N.E. Vapor Density: 0.6 (air=1) Percent Volatile: 97.0 Molecular Weight: Not applicable Pounds Per Gallon: 8.48 V.O.C. = 0 10. STABILITY AND REACTIVITY Stability: Stable Conditions To Avoid: Extreme temperatures. Incompatibility: Bases, and strong oxidizing agents.

Date: 6/19/07 C-41 Developer Part B 2 / 3

Page 7: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET Hazardous Decomposition Or By Products: May produce oxides of carbon ,sulfur, ammonia. Free hydroxylamine is produced when heated, particularly with alkalis. Hazardous Polymerization: Will Not Occur 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS The preferred options for disposal are to send to licensed reclaimers, or to permitted incinerators. Any disposal practice must be in compliance with federal, state, and local regulations. Do not dump into sewers, ground, or any body of water. 14. TRANSPORT INFORMATION DOT Class: NOT REGULATED Hazard Class: NONE UN No.: NOT APPLICABLE Packing Group: Guide No: Ship Name: 15. REGULATORY INFORMATION TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY. SARA TITLE III: NONE CALIF. PROP. 65: NONE CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. SCAQMD Rule 443.1 Photochemically Reactive: No Maximum Grams of VOC per Liter: 0 gm/L Vapor Pressure: N.E. mmHg@ 20 °C 16. OTHER INFORMATION (HMIS) Health: 2 Flammability: 0 Reactivity: 0 Protective: C OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data available to us and is believed to be accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. We assume no responsibility for the injuries from the use of the product described herein.

Date: 6/19/07 C-41 Developer Part B 3 / 3

Page 8: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET

ARISTA C-41 DEVELOPER PART C 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc. Product Name: C-41 DEVELOPER PART C Product Number: 101202, 101222 Date Prepared: 04/23/2007 Customer Information Phone Number: 1-800-521-4042 CHEMTREC®: 24 Hour Emergency Transport Phone Number: 1-800-424-9300 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS OHSA PEL ACGIH TLV Weight % CD4 25646-77-9 15 mg/m³ (dust) 10 mg/m³ 5-10 SODIUM METABISULFITE 7681-57-4 N.E. 5 mg/m³ 1-3 3. HAZARDOUS IDENTIFICATION POTENTIAL HEALTH EFFECTS Eye Contact: May cause irritation. Inhalation: Harmful if inhaled. Mist may cause irritation to respiratory tract. In contact with strong acids or if heated may liberate sulfur dioxide gas which is irritating. Some asthmatics or hypersensitive individuals may experience difficult breathing. Ingestion: Harmful if swallowed. Toxic. May cause burns to the gastrointestinal tract. Some asthmatics and sulfite-sensitive individuals may experience wheezing, chest tightness, stomach upset, hives, diarrhea. Skin Contact: Prolonged contact will cause burns. Signs And Symptoms Of Exposure: Eye and skin burns, abdominal pain, vomiting and diarrhea upon ingestion, difficulty breathing. 4. FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. Inhalation: If symptomatic, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Skin Contact: Flush skin with plenty of water and wash with a non-alkaline skin cleaner. Wash contaminated clothes before reuse. Get medical attention if irritation develops. Aggravated Medical Conditions: Individuals who are under the care of a physician or have chronic ailments, should consult a physician before using this product. Supplemental Health Information: None of the components in this product is listed by IARC, NTP, or OSHA as carcinogen. 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES Flash Point: Noncombustible Flash Point Method: Not applicable Auto ignition: Not applicable LEL: Not applicable UEL: Not applicable Extinguishing Media: Use agent appropriate for the surrounding area.

Date: 6/19/07 C-41 Developer Part C 1 / 4

Page 9: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Fire or excessive heat may produce hazardous decomposition products. Unusual Fire And Explosion Hazards: None Combustion Products: Carbon dioxide, carbon monoxide, and oxides of sulfur. 6. ACCIDENTAL RELEASE MEASURES Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards and safety precautions before proceeding with cleanup. Use appropriate personal protective equipment. Avoid contact with skin and eyes. Stop the spillage. Dike the spill. Prevent liquid from entering sewers, waterways or low areas. Absorb spillage in inert material. Soak up with sawdust, sand, or other absorbent material. Remove non-usable solid material and/or contaminated soil for disposal in an approved and permitted landfill. Discharge to sewer requires approval of permitting authority. Working solution is able to be flushed to sewer with large amounts of water upon approval. 7. HANDLING AND STORAGE Precautions To Be Taken In Handling And Storage: Store in a cool, dry, well-ventilated area. Keep containers closed. Do not store with incompatible materials. Do not store or consume food, drink, or tobacco where they may become contaminated with this material. Other Precautions: All labeled precautions must be observed when handling, storing and transporting empty containers due to product residues. Triple rinse before disposal. 8. EXPOSURE CONTROL / PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: If use conditions do not maintain vapors or fumes below exposure limits, use a NIOSH approved respirator with acid gas cartridges. Ventilation: Provide exhaust ventilation sufficient to keep the airborne concentration of this product below its exposure limits, typically 10 air changes per hour. Protective Gloves: Rubber, or neoprene waterproof gloves are recommended. Eye Protection: Safety glasses with side shields (or goggles) and a face shield. Other Protective Clothing or Equipment: Rubber or plastic apron or other protective clothing suitable for the exposure risk. Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands after use, before smoking, or using the toilet. Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Guidelines: See Section 2. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance And Odor: Light straw color, sharp vinegar odor. Solubility In Water: Complete Boiling Point: >100°C Vapor Pressure:18 mm Hg @ 20°C Ph: 2.42 Specific Gravity: 1.036/ml Melting Point: Not applicable Freezing Point: N.E. Evaporation Rate: N.E. Vapor Density: 0.6 (air=1) Percent Volatile: 91.32 Molecular Weight: Not applicable Pounds Per Gallon: 8.63 V.O.C. = 0

Date: 6/19/07 C-41 Developer Part C 2 / 4

Page 10: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET 10. STABILITY AND REACTIVITY Stability: Stable Conditions To Avoid: High temperatures Incompatibility: Strong bases and oxidizers. Hazardous Decomposition Or By Products: May produce oxides of sulfur, carbon, and nitrogen. Hazardous Polymerization: Will Not Occur 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS The preferred options for disposal are to send to licensed reclaimers, or to permitted incinerators. Any disposal practice must be in compliance with federal, state, and local regulations. Do not dump into sewers, ground, or any body of water. 14. TRANSPORT INFORMATION DOT Class: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Contains: Ethanol, 2-[(4-Amino-3-Methylphenyl)Ethylamino]-, Sulfate (1:1) (salt) Hazard Class: 8 UN No.: 3265 Packing Group: III Guide No: 153 Ship Name: PHOTOGRAPHIC DEVELOPER Limited Quantity Exception may apply to this product, for “inner packagings not over 1.0L (0.3 gal) for liquids and 1.0 kg (2.2 lb) for solids”. 173.154 (b) (1). Each package must conform to the packaging requirements of Subpart B of Part 173 and may not exceed 30 kg (66 lb) gross weight. For further information consult the 49 CFR. DOT Class: CONSUMER COMMODITY, ORM-D Hazard Class: NOT APPLICABLE UN No.: NOT APPLICABLE Packing Group: NOT APPLICABLE Guide No: NOT APPLICABLE Ship Name: NOT APPLICABLE 15. REGULATORY INFORMATION TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY. SARA TITLE III: NONE CALIF. PROP. 65: NONE CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. SCAQMD Rule 443.1 Photochemically Reactive: No Maximum Grams of VOC per Liter: 0 gm/L Vapor Pressure: N.E. mmHg@ 20 °C

Date: 6/19/07 C-41 Developer Part C 3 / 4

Page 11: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET 16. OTHER INFORMATION (HMIS) Health: 2 Flammability: 0 Reactivity: 0 Protective: C OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data available to us and is believed to be accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. We assume no responsibility for the injuries from the use of the product described herein.

Date: 6/19/07 C-41 Developer Part C 4 / 4

Page 12: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET

ARISTA C-41 BLIX PART A 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc. Product Name: C-41 BLIX PART A Product Number: 101202, 101222 Date Prepared: 04/23/2007 Customer Information Phone Number: 1-800-521-4042 CHEMTREC®: 24 Hour Emergency Transport Phone Number: 1-800-424-9300 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS OHSA PEL ACGIH TLV Weight % AMMONIUM THIOSULFATE 7783-18-8 N.E. N.E. 50-60 SODIUM ACETATE 127-09-3 N.E. N.E. 1-5 3. HAZARDOUS IDENTIFICATION POTENTIAL HEALTH EFFECTS Eye Contact: Causes severe irritation. Inhalation: May cause irritation mucous membranes and to upper respiratory tract. Ingestion: May cause irritation to gastrointestinal track. Some asthmatics or sulfite-sensitive persons may experience wheezing, chest tightness, stomach upset, hives, faintness, weakness, and diarrhea. Skin Contact: May cause irritation or reddening. Signs And Symptoms Of Exposure: Eye irritation, respiratory irritation, dermatitis, difficulty breathing, abdominal pain, skin irritation, mucus membrane irritation, coughing, nausea, diarrhea. 4. FIRST AID MEASURES Eye Contact: Immediately flush eyes with water for at least 15 minutes. Get immediate medical attention. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Skin Contact: Immediately wash skin with plenty of soap. Remove contaminated clothing and shoes. Wash contaminated clothing before reuse. Aggravated Medical Conditions: Asthmatics or hypersensitive individuals may experience difficult breathing. Supplemental Health Information: None of the components in this product is listed by IARC, NTP, or OSHA as carcinogen. 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES Flash Point: Nonflammable Flash Point Method: Not applicable Auto-ignition: Not applicable LEL: Not applicable UEL: Not applicable Extinguishing Media: Any applicable to the primary cause of the fire. Flood with water. Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing

Date: 6/19/07 C-41 Blix Part A 1 / 3

Page 13: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET to prevent contact with skin and eyes. Unusual Fire And Explosion Hazards: None known. Combustion Products: Carbon dioxide, carbon monoxide, oxides of sulfur and nitrogen. 6. ACCIDENTAL RELEASE MEASURES Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards and safety precautions before proceeding with cleanup. Use appropriate personal protective equipment during cleanup. For small amount less than one gallon flush to sewer with large amounts of water. For larger spills, dike the spill. Prevent liquid from entering sewers, waterways or low areas. Soak up with sawdust, sand, oil dry, or other absorbent material. Absorb spillage in inert material. Remove non-usable solid material and/or contaminated soil for disposal. Discharge to sewer may require approval of local authorities. Contaminated surfaces may be cleaned using water. 7. HANDLING AND STORAGE Precautions To Be Taken In Handling And Storage: Store in a cool, dry, well ventilated area. Keep containers closed. Do not store with incompatible materials. Do not store or consume food, drink, or tobacco where they may become contaminated with this material. Other Precautions: All labeled precautions must be observed when handling, storing and transporting empty containers due to product residues. Do not reuse containers. Triple rinse before disposal. 8. EXPOSURE CONTROL / PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: When this product is used in the intended way, no respiratory protection is anticipated to be necessary. Ventilation: Avoid breathing vapors or mist. Local exhaust ventilation is recommended. Ventilation must be adequate to keep hazardous ingredients below their exposure limits. Protective Gloves: Impervious gloves and aprons recommended. Eye Protection: Chemical safety glasses with side shields (or goggles). Other Protective Clothing or Equipment: Rubber or plastic apron. Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands after use, before smoking, or using the toilet. Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Guidelines: See Section 2. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance And Odor: Clear, colorless solution; ammonia odor. Solubility In Water: Complete Boiling Point: 100° C Vapor Pressure: 18m Hg @ 20° C Specific Gravity: 1.28 Melting Point: Not applicable Freezing Point: N.E. Evaporation Rate: N.E. Vapor Density: N.E. Percent Volatile: 53.28 Ph: 8.27 Molecular Weight: Not applicable Pounds Per Gallon: 10.64 V.O.C.= 0 10. STABILITY AND REACTIVITY Stability: Stable Conditions To Avoid: Strong acids and alkali.

Date: 6/19/07 C-41 Blix Part A 2 / 3

Page 14: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET Incompatibility Strong acids will liberate sulfur dioxide, strong bases of sodium hydroxide will liberate ammonia fumes. Hazardous Decomposition Or By Products: Sulfur dioxide, ammonia. Hazardous Polymerization: Will Not Occur 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS The preferred options for disposal are to send to licensed reclaimers. Any disposal practice must be in compliance with federal, state, and local regulations. Do not dump into sewers, ground, or any body of water. 14. TRANSPORT INFORMATION DOT Class: NOT REGULATED Hazard Class: NONE UN No: NOT APPLICABLE Packing Group: Guide No: Ship Name: 15. REGULATORY INFORMATION TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY. SARA TITLE III: NONE CALIF. PROP. 65: NONE CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. SCAQMD Rule 443.1 Photochemically Reactive: No Maximum Grams of VOC per Liter: 0 gm/L Vapor Pressure: N.E. mmHg@ 20 °C 16. OTHER INFORMATION (HMIS) Health: 1 Flammability: 0 Reactivity: 0 Protective: B OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data available to us and is believed to be accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. We assume no responsibility for the injuries from the use of the product described herein.

Date: 6/19/07 C-41 Blix Part A 3 / 3

Page 15: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET

ARISTA C-41 BLIX PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc. Product Name: C-41 BLIX PART B Product Number: 101202, 101222 Date Prepared: 04/23/2007 Customer Information Phone Number: 1-800-521-4042 CHEMTREC®: 24 Hour Emergency Transport Phone Number: 1-800-424-9300 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS OHSA PEL ACGIH TLV Weight % ACETIC ACID 64-19-7 25 mg/m³ TWA = 25 mg/m³ 20-25 STEL = 37 mg/m³ Emergency Overview: Danger! Causes burns to skin and eyes Vapors cause severe respiratory tract irritation. POTENTIAL HEALTH EFFECTS Eye Contact: Corrosive. Direct contact may cause redness, pain, blurred vision, permanent eye damage. Inhalation: May cause severe irritation to respiratory tract. Exposure to vapors and mists may cause chemical pneumonitis, bronchitis and pulmonary edema. Chronic exposure may cause tooth decay. Ingestion: Corrosive. Material causes irritation and burns to the digestive tract. Nausea, abdominal pains, vomiting, hematemesis, and diarrhea. Skin Contact: May cause irritation and burns to the skin. Repeated or prolonged contact may darken the skin. Signs And Symptoms Of Exposure: Eye irritation, respiratory irritation, dermatitis, difficulty breathing, abdominal pain, skin irritation, mucus membrane irritation, coughing, nausea, diarrhea. 4. FIRST AID MEASURES Eye Contact: Immediately flush eyes with water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get immediate medical attention. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, DO NOT induce vomiting. give large quantities of water. Call a physician or poison control center. Skin Contact: Remove contaminated clothing immediately. Immediately wash skin with soap and plenty of water. Aggravated Medical Conditions: Individuals who are under the care of a physician or have chronic ailments, should consult a physician before using this product. Supplemental Health Information: None of the chemicals in this component is listed by IARC, NTP, or OSHA as carcinogen.

Date: 6/19/07 C-41 Blix Part B 1 / 4

Page 16: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES Flash Point: Nonflammable Flash Point Method: Not applicable Auto ignition: Not applicable LEL: Not applicable UEL: Not applicable Extinguishing Media: Carbon dioxide, dry chemical, and alcohol-type foam. Water should be used to cool fire-exposed containers structures and to protect personnel. Special Fire-Fighting Procedures: Wear NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode and full protective clothing to prevent contact with skin and eyes. If leak or spill has not ignited, ventilate area and use water spray to disperse gas or vapor and to protect personnel. Use water to dilute spills and to flush them from sources of ignition Unusual Fire And Explosion Hazards: Vapors form flammable or explosive mixtures with air at room temperature. Vapors may accumulate in low areas. Combustion Products: Carbon dioxide, carbon monoxide, hydrogen gas. 6. ACCIDENTAL RELEASE MEASURES Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards and safety precautions before proceeding with cleanup. Use appropriate personal protective equipment. Stay upwind, keep out of low areas, and ventilate closed spaces before entering. Stop leak if possible. Dike the spill. Prevent liquid from entering sewers, waterways or low areas. For small spills, absorb spillage in inert material. Soak up with sawdust, sand, or other absorbent material.. Remove non-usable solid material and/or contaminated soil for disposal in an approved and permitted landfill. Discharge to sewer requires approval of permitting authority and may require pre-treatment. 7. HANDLING AND STORAGE Precautions To Be Taken In Handling And Storage: Avoid breathing mist Do not get in eyes, on skin, or on clothing. Store in a cool, dry, well ventilated area. Keep containers closed. Do not store with incompatible materials. Do not store or consume food, drink, or tobacco where they may become contaminated with this material. Other Precautions: All labeled precautions must be observed when handling, storing and transporting empty containers due to product residues. Triple rinse before disposal. Store in original container. 8. EXPOSURE CONTROL / PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: If exposure limits are exceeded or if irritation is experienced, a NIOSH approved respirator should be worn. Normally, a NIOSH approved respirator for organic vapors is generally acceptable. Ventilation and other forms of engineering controls are often the preferred means for controlling chemical exposures. Ventilation: Provide exhaust ventilation sufficient to keep the airborne concentration of this product below PEL. Protective Gloves: Rubber, or neoprene waterproof gloves are recommended. Eye Protection: Safety glasses with side shields (or goggles) and full face shield where splashing of solutions is possible. Do not wear contact lenses when working with this substance. Other Protective Clothing or Equipment: Prevent skin contact. Rubber or plastic apron or full body protection. Suggested protective materials are butyl rubber.

Date: 6/19/07 C-41 Blix Part B 2 / 4

Page 17: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands after use, before smoking, or using the toilet. Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Guidelines: See Section 2. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance And Odor: Clear, colorless liquid with a strong vinegar-lie odor. Solubility In Water: Complete Boiling Point: 100 ºC Vapor Pressure: N.E. Specific Gravity: 1.032 Melting Point: Not applicable Freezing Point: N.E. Evaporation Rate: N.E. Vapor Density: N.E. Percent Volatile: 100.0 Ph: 1.82 Molecular Weight: Not applicable Pounds Per Gallon: 8.60 V.O.C. 246.94 g/L or 23.93%, or 2.06 lb./gal. 10. STABILITY AND REACTIVITY Stability: Stable Conditions To Avoid: None Incompatibility: Oxidizers and reducing agents. Hazardous Decomposition Or By Products: Irritating and toxic fumes may be emitted upon decomposition. Combustions may produce carbon dioxide and carbon monoxide. Hazardous Polymerization: Will Not Occur 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Discharge, treatment or disposal may be subject to Federal, State (provincial in Canada) or local laws. 14. TRANSPORT INFORMATION DOT Class: ACETIC ACID SOLUTION, 25% Hazard Class: 8 UN No.: 2790 Packing Group: II Guide No: 154 Ship Name: Acetic Acid Solution, 25 % Limited Quantity Exception may apply to this product, for “inner packagings not over 1.0L (0.3 gal) for liquids and 1.0 kg (2.2 lb) for solids”. 173.154 (b) (1). Each package must conform to the packaging requirements of Subpart B of Part 173 and may not exceed 30 kg (66 lb) gross weight. For further information consult the 49 CFR. DOT Class: CONSUMER COMMODITY, ORM-D Hazard Class: NOT APPLICABLE UN No.: NOT APPLICABLE Packing Group: NOT APPLICABLE Guide No: NOT APPLICABLE Ship Name: NOT APPLICABLE

Date: 6/19/07 C-41 Blix Part B 3 / 4

Page 18: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET

15. REGULATORY INFORMATION TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY. SARA TITLE III: NONE CALIF. PROP. 65: NONE CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. SCAQMD Rule 443.1 Photochemically Reactive: No Maximum Grams of VOC per Liter: 246.94 gm/L Vapor Pressure: N.E. mmHg@ 20 °C 16. OTHER INFORMATION (HMIS) Health: 3 Flammability: 0 Reactivity: 0 Protective: C OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data available to us and is believed to be accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. We assume no responsibility for the injuries from the use of the product described herein.

Date: 6/19/07 C-41 Blix Part B 4 / 4

Page 19: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET

ARISTA C-41 BLIX PART C 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc. Product Name: C-41 BLIX PART C Product Number: 101202, 101222 Date Prepared: 04/23/2007 Customer Information Phone Number: 1-800-521-4042 CHEMTREC®: 24 Hour Emergency Transport Phone Number: 1-800-424-9300 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS OHSA PEL ACGIH TLV Weight % FERRIC AMMONIUM EDTA 21265-50-9 50 ppm 25 ppm 90-100 3. HAZARDOUS IDENTIFICATION POTENTIAL HEALTH EFFECTS Eye Contact: May cause transient irritation. Inhalation: Low hazard for recommended handling. Ingestion: Expected to be low hazard if swallowed. May cause irritation of the mouth, throat, and stomach. Skin Contact: May cause redness and irritation. Signs And Symptoms Of Exposure: Redness of eyes and skin. 4. FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Skin Contact: Flush skin with plenty of water and wash with a non-alkaline skin cleaner. Wash contaminated clothes before reuse. Get medical attention if irritation develops. Aggravated Medical Conditions: Dermatitis, asthma, and sulfite sensitiveness for working solution. Supplemental Health Information: None of the components in this product is listed by IARC, NTP, or OSHA as a carcinogen. 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES Flash Point: Nonflammable Flash Point Method: Not applicable Auto ignition: Not applicable LEL: Not applicable UEL: Not applicable Extinguishing Media: Use agent appropriate for surrounding fire. Special Fire-Fighting Procedures: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Unusual Fire And Explosion Hazards: Not considered a fire hazard. When involved in a fire, does not contribute any unusual hazards. Combustion Products: Oxides of carbon and nitrogen are produced by the combustion of this product.

Date: 6/19/07 C-41 Blix Part C 1 / 3

Page 20: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET 6. ACCIDENTAL RELEASE MEASURES Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards and safety precautions before proceeding with cleanup. Use appropriate personal protective equipment. Avoid contact with skin and eyes. Stop the spillage. Dike the spill. Prevent liquid from entering sewers, waterways or low areas. Absorb spillage in inert material. Soak up with sawdust, sand, or other absorbent material. Remove non-usable solid material and/or contaminated soil for disposal in an approved and permitted landfill. Discharge to sewer requires approval of permitting authority. Working solution should be able to be flushed to sewer with large amounts of water. Contaminated surfaces should be cleaned using water. 7. HANDLING AND STORAGE Precautions To Be Taken In Handling And Storage: Store in a cool, dry, well ventilated area. Keep containers closed. Do not store with incompatible materials. Do not store or consume food, drink, or tobacco where they may become contaminated with this material. Other Precautions: All labeled precautions must be observed when handling, storing and transporting empty containers due to product residues. Do not reuse containers. Triple rinse before disposal. 8. EXPOSURE CONTROL / PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: When this product is used in the intended way, no respiratory protection is anticipated to be necessary. If engineering controls do not maintain airborne concentrations below recommended exposure limits, an approved respirator should be worn of organic vapor type. Ventilation: Good ventilation of 10 room volumes per hour. Ventilation rates should match conditions of use. Protective Gloves: Latex, rubber, or neoprene waterproof gloves are recommended. Eye Protection: Safety glasses with side shields (or goggles). Other Protective Clothing or Equipment: Rubber or plastic apron. Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands after use, before smoking, or using the toilet. Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure: See Section . 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance And Odor: Reddish brown solution; ammonia odor Solubility In Water: Complete Boiling Point: > 100 ºC Specific Gravity: 1.32 Vapor Pressure: 18m Hg @ 20ºC Melting Point: Not applicable Freezing Point: N.E. Evaporation Rate: N.E. Vapor Density: N.E. Percent Volatile: 53.01 Ph: 7.40 Molecular Weight: Not applicable V.O.C. is 0. Pounds Per Gallon: 10.99 10. STABILITY AND REACTIVITY Stability: Stable Conditions To Avoid: Metals such as aluminum, copper, copper alloys, nickel, and zinc. Aqueous solution in contact with aluminum evolves hydrogen. Incompatibility: Strong oxidizers, alkalis, acids.

Date: 6/19/07 C-41 Blix Part C 2 / 3

Page 21: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET Hazardous Decomposition Or By Products: May produce oxides of nitrogen, carbon dioxide, carbon monoxide, and ammonia. Hazardous Polymerization: Will Not Occur Conditions To Avoid: None 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS Discharge, treatment or disposal may be subject to Federal, State (provincial in Canada) or local laws. 14. TRANSPORT INFORMATION DOT Class: NOT REGULATED Hazard Class: NONE UN No.: NOT APPLICABLE Packing Group: Guide No: Ship Name: 15. REGULATORY INFORMATION TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY. SARA TITLE III: NONE CALIF. PROP. 65: Product contains a mixture which includes trace amounts of Trisodium NTA. The State of California’s Safe Drinking Water and Toxic Enforcement Act of 1986, or Proposition 65 requires the following information. This regulation does not address di minimus levels; therefore, even trace amounts of the chemicals included on Proposition 65’s list of chemicals known to the State of California to cause cancer or reproductive toxicity must be noted with the “Safe Harbor” wording. WARNING: This product contains Trisodium NTA – known to the State of California to cause cancer, birth defects or other reproductive harm. CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. SCAQMD Rule 443.1 Photochemically Reactive: No Maximum Grams of VOC per Liter: 0 gm/L Vapor Pressure: N.E. mmHg@ 20 °C 16. OTHER INFORMATION (HMIS) Health: 1 Flammability: 0 Reactivity: 0 Protective: B OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data available to us and is believed to be accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. We assume no responsibility for injuries from the use of the product described herein.

Date: 6/19/07 C-41 Blix Part C 3 / 3

Page 22: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET

ARISTA C-41 STABILIZER 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc. Product Name: C-41 STABILIZER Product Number: 101202, 101222 Date Prepared: 04/23/2007 Customer Information Phone Number: 1-800-521-4042 CHEMTREC®: 24 Hour Emergency Transport Phone Number: 1-800-424-9300 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS OHSA PEL ACGIH TLV Weight % HEXAMINE* 100-97-0 15 mg/m³(dust) 10mg/m³(particulate) 3-7 PHOTOFLO** MIXTURE N.E. N.E. < 2 * Decomposes as formaldehyde and ammonia **Contains Ethylene Glycol 100 mg/m³ Ceiling aerosol 3. HAZARDOUS IDENTIFICATION POTENTIAL HEALTH EFFECTS Eye Contact: Causes irritation to the eyes and may cause damage to lens or cornea. Inhalation: May cause irritation to respiratory tract. Ingestion: May be harmful if swallowed. Skin Contact: Low hazard for recommended handling. May cause itching or reddening. Signs And Symptoms Of Exposure: Irritation of eye, skin, and respiratory tract. 4. FIRST AID MEASURES Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get immediate medical attention. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion: If swallowed, give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Skin Contact: Flush skin with plenty of water and wash with a non-alkaline skin cleaner. Wash contaminated clothes before reuse. Get medical attention if irritation develops. Aggravated Medical Conditions: Individuals who are under the care of a physician or have chronic ailments, should consult a physician before using this product. Some asthmatics or sulfite- sensitive persons may experience wheezing, chest tightness, stomach upset, hives, faintness, weakness, and diarrhea. Supplemental Health Information: None of the components in this product is listed by IARC, NTP, or OSHA as carcinogen. 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES Flash Point: Noncombustible Flash Point Method: Not applicable Auto ignition: Not applicable LEL: Not applicable UEL: Not applicable Extinguishing Media: Dry chemical, foam, carbon dioxide, water fog.

Date: 6/19/07 C-41 Stabilizer 1 / 3

Page 23: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET Special Fire-Fighting Procedures: Firefighters should wear proper protective equipment and self- contained breathing apparatus with full face piece in positive pressure mode. Unusual Fire And Explosion Hazards: Hexamine will hydrolyze in the presence of acids or in an acidic environment. This product also decomposes with heat (150-300º C) while in the presence of water. Under the above conditions, free formaldehyde and ammonia will be liberated. Combustion Products: Oxides of carbon, nitrogen. 6. ACCIDENTAL RELEASE MEASURES Steps To Be Taken In Case Material Is Spilled Or Released: Review fire and explosion hazards and safety precautions before proceeding with cleanup. Use appropriate personal protective equipment. Avoid contact with skin and eyes. Stop the spillage. Dike the spill. Prevent liquid from entering sewers, waterways or low areas. Absorb spillage in inert material. Soak up with sawdust, sand, or other absorbent material. Remove non-usable solid material and/or contaminated soil for disposal in an approved and permitted landfill. Discharge to sewer requires approval of permitting authority and may require pre-treatment. Contaminated surfaces should be cleaned using water. 7. HANDLING AND STORAGE Precautions To Be Taken In Handling And Storage: Store in a cool, dry, well ventilated area. Keep containers closed. Do not store with incompatible materials. Do not store or consume food, drink, or tobacco where they may become contaminated with this material. Other Precautions: All labeled precautions must be observed when handling, storing and transporting empty containers due to product residues. Triple rinse before disposal. Dispose of in a licensed facility. 8. EXPOSURE CONTROL / PERSONAL PROTECTION PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: Avoid breathing mists. A respirator should be worn if hazardous decomposition products are likely to be released. Ventilation: Local exhaust ventilation is recommended. Ventilation must be adequate to keep hazardous ingredients below their exposure limits. Protective Gloves: Latex, rubber, or neoprene waterproof gloves are recommended. Eye Protection: Safety glasses with side shields (or goggles). Other Protective Clothing or Equipment: Rubber or plastic apron. Work/Hygienic Practices: Use good personal hygiene when handling this product. Wash hands after use, before smoking, or using the toilet. Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Guidelines: See Section 2. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance And Odor: Clear solution; formaldehyde odor Solubility In Water: Complete Boiling Point: > 100 ºC Vapor Pressure: 18m Hg @ 20º C Specific Gravity: 1.014 Melting Point: Not applicable Freezing Point: N.E. Evaporation Rate: N.E. Vapor Density: 0.6 (Air=1) Percent Volatile: 92.60 Ph: 9.27 Molecular Weight: Not applicable Pounds Per Gallon: 8.45 V.O.C. is 12.84 g/L or 1.27% or 0.11 lb./gal.

Date: 6/19/07 C-41 Stabilizer 2 / 3

Page 24: ARISTA C-41 DEVELOPER PART A - Freestyle Photographic Supplies€¦ · ARISTA C-41 DEVELOPER PART B 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Photo Systems, Inc

MATERIAL SAFETY DATA SHEET 10. STABILITY AND REACTIVITY Stability: Stable Conditions To Avoid: Heat in the presence of water. Hexamine will hydrolyze in the presence of acids or in acidic environments. Incompatibility: Strong oxidizing agents, strong alkali. Hazardous Decomposition Or By Products: Carbon dioxide and carbon monoxide. Hazardous Polymerization: Will Not Occur Conditions To Avoid: Extreme temperatures. 11. TOXICOLOGICAL INFORMATION 12. ECOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS The preferred options for disposal are to send to licensed reclaimers, or to permitted incinerators. Any disposal practice must be in compliance with federal, state, and local regulations. Do not dump into sewers, ground, or any body of water. 14. TRANSPORT INFORMATION DOT Class: NOT REGULATED Hazard Class: NONE UN No.: NOT APPLICABLE Packing Group: Guide No: Ship Name: 15. REGULATORY INFORMATION TSCA: All ingredients in this finished product are listed on the EPA TSCA INVENTORY. SARA TITLE III: Ethylene Glycol is listed under Sara Title 313. CALIF. PROP. 65: NONE CARCINOGENICITY: NONE OF THE COMPONENTS IN THIS CHEMICAL IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. SCAQMD Rule 443.1 Photochemically Reactive: No Maximum Grams of VOC per Liter: 12.84 gm/L Vapor Pressure: N.E. mmHg@ 20 °C 16. OTHER INFORMATION (HMIS) Health: 2 Flammability: 0 Reactivity: 1 Protective: C OTHER ADDITIONAL INFORMATION: The information contained herein is based on the data available to us and is believed to be accurate. However, no warranty is expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof. We assume no responsibility for the injuries from the use of the product described herein. Date: 6/19/07 C-41 Stabilizer 3 / 3