assessment of heavy metal

8/18/2019 Assessment of Heavy Metal

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ENVIRONMENTAL TOXICOLOGY (MMS4000)

2013/2014

ASSESSMENT OF HEAVY METAL

NURUL ADHA BINTI UJANG

(UK28913)

LIYANA BINTI YAMIN

(UK 28942)

PROGRAMME

BACHELOR OF ALIE! SCIENCE

CONSERVATION AN! MANAGEMENT OF BIO!IVERSITY

LECTURER

!R" HING LEE SHING


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FIELD TRIP

SETIU #ETLAN!

INTRODUCTION

H$%&' $%*+ ,-.%.%-.+ %&$ ,%+$ % $% ,-.,$. $ - + +%5*$ %.

$.&-.$.%* 6$++$.,$ ,%%,$+,+ $+6$,%**' . %7%, $.&-.$. (A*%

$ %*" 2009)" H$%&' $%* 5%+,%**' -,, .%%**' . $% -:$&$ $ - %.

.&-*&$$. 5$,-$ ,-.,$.%$ $&$.%**' *$%. - + '6$ -; ,-.%.%-."

H$%&' $%*+ 6-**%.+ +, %+ C% %. L$% ,%. ,%+$ -$ %. %-. -; -%., %$ %**-: $ -

$$.$ $ 6$+$.,$ -; $ $%&' $%* 6-**%.+ (S%&$ $ %*" 2000) + %*+-

%. $ 6-%. %+ $%&' $%* ,-.%.%-. .,%-+"

T$ %. -5$,&$+ -; + +' + - $$.$ $ $%&' $%* ,-.,$.%-.+ -.+$$. %. -'+$ -; $ S$ *%--." T+ +' %*+- -- .- %,,-. $ :%$

7%*' 6%%$$ -; $ *%--." I. + +' % ,-6%+-. :$$ %$ - $.;'

:$$ $ -'+$ ;- $ S$ L%--. %$ +%;$ ;- ,-.+6-."


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METHODOLOGY

T$ +' %$% $&-*&$+ % S$ #$*%. % *%--. $+%' +'+$ % :%+

.&$+%$ :, $


4/25

!$+$ +%6*$ :$$ %.+;$$ - ?0L -; ,$.;$ 5$" T$. $ +%6*$+

:$$ *$ : * :%$" S-*-. :$$ $. ;*$$ - +$6%%$ $ ,-%+$

6%,*$+ . -'+$ +-*-." A. *%+*' $ $%&' $%* $%.+ -; $ *$

+%6*$+ :$$ $,-$"

S$,-. %- +$6 + $ +$$. 6-,$++ +. ,-:%&$ %, $+-." F+*'

$ +$$.+ %$ .$ +. -% %. 6$+*$ - 5$% 6 $ 6%,*$+" T$.

$ 6%,*$+ :$$ 6*%,$ . % +%; - $.+$ :$ -.*' $ $ ;.$+ 6%,*$" T$

6%,*$+ :$$ $. 6*%,$ .- TFM &$++$* %. 6*%,$ -. % 5%*%.,$" T$ &$++$* :%+

;+ %$ %. :$$" TF# &$++$* :%+ .-,$ .- HTC +%;$' +$*"

$,*-, %, ., %, %. '-$. 6$-


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T%5*$ 1 #%$ %*' %%$$ ;- S$ L%--.

T$6$%$( )ᵒ !O (/*) 6H S%*.'TopS$ 1 30"10"0? 3"90" "820"02 31"340"1

S$ 2 30"20"01 0"20"01 "30"01 18"20"0S$ 3 30"8 0"0 4"?30"1? "80"02 30"80"1S$ 4S$ ? 31"30"00 ?"80"28 "980"00

BottomS$ 1 30"?9 0"0 4"830"21 "800"00? 31"340"09S$ 2 30"40"0? 3"910"1? "00"0 30"840"24S$ 3 30"880"3 4"40 "80 31"090"3S$ 4S$ ? 31"0"0? ?"930"19 "90"00

M$%. &%*$+ %. ± +%.% $&%-."

T%5*$ 2 R$,-&$$+ -; $%*+ ;- $+%.$ +$$. ,$;$ $;$$.,$ %$%*+

Element Certifie !"l#e$ An"l%$e !"l#e Per&ent"'e

re&o!er%

C 0"148 ± 0"00 0"142 9"12

C# 10"01 ± 0"34 0"019 94"91

P( 11" ± 1"2 11"1 9?"44

Cr 40"9 ± 1"9 0"03 89"24

T%5*$ 2" T$ $%&' $%* ,-.,$.%-. . +$$. %. -'+$"

C (66) C (66) C (66) 5 (66)

Seiment

S$ 1 30"00 ± ?"29 "33 ± 1"1? N! N!

S$ 239"33

±

"11 13"33 ±

2"31 1"33 ±

2"31 ?"33 ±

2"31S$ 3 28"00 ± 3"4 ?"33 ± 1"1? 0"80 ± 0"00 N!

S$ 4 ?4"00 ± 3"4 13"33 ± 1"1? 2"00 ± 0"00 0" ± 1"1?

S$ ? ?1"33 ± 4"1 4" ± 1"1? 2" ± 1"1? N!

O%$ter

S$ 1 13"89 ± 2"?? 43"89 ± 0"9 2"8 ± 0"9 N!

S$ 2 10"44 ± 8"? ?2"8 ± 0"9 11" ± 1" N!

S$ 3 1"11 ± 1"92 ?1"11 ± 0"9 ?"00 ± 0"00 N!

S$ 4 2?"00 ± 1" ?2"22 ± 3"8? 10"00 ± 1" N!


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S$ ? 40"00 ± 4"41 44"44 ± 0"9 "22 ± 0"9 N!

N! N- $$,$

C C C 50

?

10

1?20

2?

30

3?

40

4?

?0

Gr"p) of &on&entr"tion "'"in$t )e"!% met"l "t $ite *

S$/($.) O'+)$

T%pe of He"!% Met"l

Con&entr"tion +ppm,

C C C 50

10

20

30

40

?0

0

Gr"p) of &on&entr"tion "'"in$t )e"!% met"l "t $ite -

S$$. O'+$

T%pe of )e"!% met"l$

Con&entr"tion +ppm,


7/25

C C C 50

10

20

30

40

?00

Gr"p) of &on&entr"tion "'"in$t )e"!% met"l "t $ite .

S$$. O'+$

t%pe of )e"!% met"l

&on&entr"tion +ppm,

C C C 50

10

20

30

40

?0

0

Gr"p) of &on&entr"tion "'"in$t )e"!% met"l "t $ite /

t%pe of )e"!% met"l

&on&entr"tion +ppm,


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C C C 50

10

20

30

40?0

0

Gr"p) of &on&entr"tion "'"in$t )e"!% met"l "t $ite 0

t%pe of )e"!% met"l

&on&entr"tion +ppm,

F$ 1 C-6%+-. -; $%&' $%* ,-.,$.%-. . $ +$$. %. -'+$ % $%,

+%6*. +$+" T$ 5%+ %. &$,%* *.$+ $6$+$. $ $%. %. +%.% $&%-.

$+6$,&$*'"

H-:$&$ $ ,-.,$.%-. -; ,-66$ + $ $+ . $ -'+$+ ;-**-:$ 5'

,- ,% %. ;.%**' *$%" F- $ F$ 1 ;- -+ -; $ +$+ $$

%$ +.;,%. ;;$$.,$ . $ ,-.,$.%-. -; $%&' $%*+ 5$:$$. $ +$$.

%. $ -'+$+" T$ ,-.,$.%-. ;- $%, '6$ -; $%&' $%* + $ . -'+$+

%. . $ +$$. $


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$-,$,%* 6-6$$+ - C%*, :, + %. $++$.%* $*$$. ;- -'+$

6-5%5*' $.$+ -'+$ ++$ %+ +5+$ ;- ,%*, (H%.


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FIELD TRIP

%+% %'%.

INTRODUCTION

H$%&' $%*+ . $;.-. %$ $%**, ,$,%* $*$$. % %+ % $*%&$*' $.+' %. %$ -


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RESULT

T%5*$ 1" R$,-&$' -; $%&' $%*+ ;- ,$;$ %$%*+"

E*$$. C$;$ &%*$+ A.%*'+$ &%*$ $,$.%$

$,-&$'

$%, *$%&$+

C 0"02 ± 0"003 0"02? 9"4?

C 3" ± 1"4 3"? 9?"0

5 0"8 ± 0"03 0"88 101"33

C

!- ;+

C 24"3 ± 0"8 20"4 83"9?

C 31"2 ± 1"1 29"3 93"91

5 0"1 ± 0"04 0"14 8"?0

C


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Mango Kundang Guava

0

0.01

0.02

0.03

0.04

0.05

0.06

0.07

0.08

0.09

Copper

Type of fruits

Concentration (ppm)

Mango Kundang Guava

0

0.01

0.02

0.03

0.04

0.05

0.06

Cadmium

Type of fruits

Concentration (ppm)


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Mango Kundang Guava

0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

Lead

Type of fruits

Concentration (ppm)

Mango Kundang Guava

0

0.01

0.01

0.02

0.02

0.030.03

0.04

0.04

0.05

0.05

Chromium

Type of fruits

Concentration (ppm)

F$ 1" H$%&' $%* ,-.,$.%-. . $%, '6$ -; ;+" T$ 5%+ $6$+$. $

$%."


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0

0.01

0.01

0.02

0.02

0.03

Copper

Fish species

Concentration (ppm)

000

0.010.010.01

0.010.010.020.02

Cadmium

Fish species

Concentration (ppm)


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0

0.01

0.02

0.03

0.04

0.05

0.06

0.07

Lead

Fish Species

Concentration (ppm)

000

0.010.010.01

0.010.010.020.02

Chromium

Fish species

Cconcentration (ppm)

F$ 2" H$%&' $%* ,-.,$.%-. . $%, ;+ +6$,$+" T$ 5%+ $6$+$. $

$%."


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00.010.020.030.040.05

0.060.070.080.09

Copper

Type of vegetables

Ccocentration (ppm)

00000

0.010.01

Cadmium

Type of vegetables

Concentration (ppm)

000

0.010.010.010.01

Lead

Type of vegetables

Concentration (ppm)


17/25

F$ 3" H$%&' $%*+ ,-.,$.%-. . $%, '6$ -; &$$%5*$+" T$ 5%+ $6$+$.

$%."

C- &%*$ ;- $%, '6$ -; &$$%5*$+ ,%..- 5$ $$.$"

DISCUSSION

T%5*$ 1 $6$+$. $ $+* %.%*'++ ;- &$$%5*$+ %. ;+ CRM" I ;-. - %&$

%.. &%*$+ 5$:$$. 83J 102J " T+ $%.+ + .- $7$ - 6$;-

,-$,-. -. $%, +%6*$ &%*$"

I. F$ 1 +-:+ ,-66$ 6$+$. % $%, '6$ -; $ ;+ %. $ &%*$+ %$

7$ " H-:$&$ +** .- $


18/25

REFERENCES

A*% A"F"M" I+%* N" A$ A" E%+% A"M" (2009)" A.%*'++ -; $%&' $%*

,-.,$.%-.+ . +$$.+ -; +$*$,$ $+%$+ -; M%*%'+%% +%+,%*

%++$++$." Environ Monit Assess" *0. 19 18?

M%,;%*%.$ G" R" = B,$ M" !" (2000)" C$***% +5-. -; C 5 %. . .

$ $' %.-&$ A&,$..% %.%" Aquatic Botany 123 4??9

A+**- R" !" Y$. I"C" = B$$*$ I"(200?) H$%&' $%*+ . +$$.+ ++$*+

%. -'+$+ ;- T.% %. V$.$>$*% L" Rev. Biol. Trop. 0. 341?3

H-**$ H" K$$ S" K-. N" R-*; U*, M" = B%5$, T" (2003)" A .$:

+$$. ,-.%, %++%' - %++$++ 6%,*%5-. 6-**%.+ +. >$5%;+ (!%.-

$-) $5'-+. Journal of Soils and Sediments" . 19 20

S%&$ S" H$.$+- #" A**$. H"E" (2000) S-*+-*-. 6%-.. -; $%*+ .

,-.%.%$ +-*+ $6$.$.,$ -; 6H -%* $%* 5$. %. -%., %$"

Environ Sci Tech 34" 4112?1131

H%.% I" I%*>% M"S" (2012)" A.%*'++ O; H$%&' M$%*+ I. #%$ A. F+

(T*%6% S6") S%6*$+ F- T%+ M%% ,-." The Malaysian Journal of

Analytical Sciences. *1 34 3?2


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APPENDI6

CALCULATION FOR

¿ (CONCENTRATION OF AAS x50)

MASS OF DRY SAMPLE

F- +$$.

S$ 1

C- (C) R1 Q0.12 X 50

0.25 Q 24 R2 Q0.16 X 50

0.25 Q 32 R3 Q

0.17 X 50

0.25 Q 34

C-66$ (C) R1 Q0.04 X 50

0.25 Q 8 R2 Q0.03 X 50

0.25 Q R3 Q

0.04 X 50

0.25 Q 34

C% (C) R1 Q N! R2 Q N! R3 QN!

L$% (5) R1 Q N! R2 Q N! R3 QN!

S$ 2

C- (C) R1 Q0.23 X 50

0.25 Q 4 R2 Q0.19 X 50

0.25 Q 38 R3 Q

0.17 X 50

0.25 Q 34

C-66$ (C) R1 Q0.06 X 50

0.25 Q 12 R2 Q0.06 X 50

0.25 Q 12 R3 Q

0.08 X 50

0.25 Q 1


20/25

C% (C) R1 Q N! R2 Q N! R3 Q0.002 X 50

0.25

Q 4

L$% (5) R1 Q0.04 X 50

0.25 Q 8 R2 Q0.02 X 50

0.25 Q 4 R3 Q

0.02 X 50

0.25 Q 4

S$ 3

C- (C) R1 Q

0.12 X 50

0.25 Q 24 R2 Q

0.15 X 50

0.25 Q 30 R3 Q

0.15 X 50

0.25 Q 30

C-66$ (C) R1 Q0.03 X 50

0.25 Q R2 Q0.03 X 50

0.25 Q R3 Q

0.02 X 500.25 Q 4

C% (C) R1 Q0.04 X 50

0.25 Q 8 R2 Q0.04 X 50

0.25 Q 8 R3 Q

0.04 X 50

0.25 Q 8

L$% (5) R1 Q N! R2 Q N! R3 QN!

S$ 4

C- (C) R1 Q0.28 X 50

0.25 Q ? R2 Q0.25 X 50

0.25 Q ?0 R3 Q

0.28 X 50

0.25 Q ?


21/25

C-66$ (C) R1 Q0.07 X 50

0.25 Q 14 R2 Q0.06 X 50

0.25 Q 12 R3 Q

0.07 X 50

0.25 Q 14

C% (C) R1 Q0.01 X 50

0.25 Q 2 R2 Q0.01 X 50

0.25 Q 2 R3 Q

0.01 X 50

0.25 Q 2

L$% (5) R1 Q N! R2 Q0.01 X 50

0.25 Q 2 R3 QN!

S$ ?

C- (C) R1 Q0.24 X 50

0.25 Q 4 R2 Q0.25 X 50

0.25 Q ?0 R3 Q

0.28 X 50

0.25 Q ?

C-66$ (C) R1 Q0.07 X 50

0.25 Q 14 R2 Q0.06 X 50

0.25 Q 12 R3 Q

0.07 X 50

0.25 Q 14

C% (C) R1 Q

0.01 X 50

0.25 Q 2 R2 Q

0.01 X 50

0.25 Q 2 R3 Q

0.01 X 50

0.25 Q 2

L$% (5) R1 Q N! R2 Q0.01 X 50

0.25 Q 2 R3 QN!


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OYSTER

S$ 1

C- (C) R1 Q

0.10 X 50

0.3 Q 1" R2 Q

0.07 X 50

0.3 Q 11" R3 Q

0.08 X 50

0.3 Q 13"33

C-66$ (C) R1 Q0.27 X 50

0.3 Q 4? R2 Q0.26 X 50

0.3 Q 43"33 R3 Q

0.26 X 500.3 Q 43"33

C% (C) R1 Q0.01 X 50

0.3 Q 1" R2 Q0.02 X 50

0.3 Q 3"33 R3 Q

0.02 X 50

0.3 Q 3"33

L$% (5) R1 Q N! R2 Q0.01 X 50

0.25 Q 2 R3 QN!

S$ 2

C- (C) R1 Q0.08 X 50

0.3 Q 1"33 R2 Q0.11 X 50

0.3 Q 18"33 R3 Q

0.08 X 50

0.3 Q 11"

C-66$ (C) R1 Q0.31 X 50

0.3 Q ?3"33 R2 Q0.31 X 50

0.3 Q ?1" R3 Q

0.32 X 50

0.3 Q ?3"33


23/25

C% (C) R1 Q0.07 X 50

0.3 Q 11" R2 Q0.06 X 50

0.3 Q 10 R3 Q

0.08 X 50

0.3 Q 13"33

L$% (5) R1 Q N! R2 Q ND R3 QN!

S$ 3

C- (C) R1 Q0.11 X 50

0.3 Q 18"33 R2 Q0.09 X 50

0.3 Q 1? R3 Q

0.09 X 50

0.3 Q 1?

C-66$ (C) R1 Q0.30 X 50

0.3 Q ?0 R2 Q0.31 X 50

0.3 Q ?1" R3 Q

0.31 X 50

0.3 Q ?1"

C% (C) R1 Q0.03 X 50

0.3 Q ? R2 Q0.03 X 50

0.3 Q ? R3 Q

0.03 X 50

0.3 Q ?

L$% (5) R1 Q N! R2 Q ND R3 QN!

S$ 4


24/25

C- (C) R1 Q0.16 X 50

0.3 Q 2" R2 Q0.14 X 50

0.3 Q 23"33 R3 Q

0.15 X 50

0.3 Q 2?

C-66$ (C) R1 Q0.33 X 50

0.3 Q ?" R2 Q0.30 X 50

0.3 Q ?0 R3 Q

0.29 X 50

0.3 Q ?2"22

C% (C) R1 Q0.07 X 50

0.3 Q 11" R2 Q0.05 X 50

0.3 Q 8"33 R3 Q

0.06 X 50

0.3 Q 10

L$% (5) R1 Q N! R2 Q ND R3 QN!

S$ ?

C- (C) R1 Q0.25 X 50

0.3 Q 18"33 R2 Q0.21 X 50

0.3 Q 1? R3 Q

0.26 X 50

0.3 Q 1?

C-66$ (C) R1 Q0.29 X 50

0.3 Q ?0 R2 Q0.26 X 50

0.3 Q ?1" R3 Q

0.27 X 50

0.3 Q ?1"


25/25

C% (C) R1 Q0.04 X 50

0.3 Q ? R2 Q0.05 X 50

0.3 Q ? R3 Q

0.04 X 50

0.3 Q ?

L$% (5) R1Q0.01 X 50

0.3 Q ? R2 Q ND R3 Q ND

assessment of heavy metal

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