basf - multipurpose solutions for surface clean
TRANSCRIPT
Home Care Hard Surface Cleaning
Multipurpose Solutions for Surface Clean
Juraci Marques da Silva,Technical Consultant
August, 2016
3
Multipurpose Solutions for Surface Clean!Claims to choose
Convenient Cleaning
SpotlessDrying
Easy-to-clean-again
Effect
High-Performance Cleaning
Primary Cleaning
BoostGlossy &
Streak-Free
Gentle Cleaning
Skin CareSurface
Care
Sustainable Cleaning
Renewable Base and
Biodegradable
Convenience: Ease of Use, Emotional Purchase
Safeness: Hygiene, Material Protection…
Performance
Sustainable Solutions: Environmentally friendly product, water and energy efficiency, packaging/refill
Convenient Cleaning
4
SpotlessDrying
Easy-to-clean-again Effect
Multipurpose Solutions for Surface Clean!Claims to choose – Convenient Cleaning
Multipurpose Solutions for Surface Clean!The Polyquart® Types
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Aqueous solution of acrylic copolymerYellowish clear liquid
21.5 – 22.5 % active
Stable at pH ranges from 3 – 10
Dosage 0.2% - 1.0% as is
Polyquart® 149
Starch acrylic copolymerYellowish clear liquid
21.5 – 22.5 % active
Stable at pH ranges from 3 – 10
Dosage 0.5% - 1.5% as is
Polyquart® EcocleanAerobic and anaerobicbiodegradability
Surface ModificationPolyquart® 149
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0
20
40
60
80
100
120
Ceramic Glass Stainless Steel Car Panel PVC PP
Con
tact
Ang
le [°
]
Untreated Surface
Polyquart 149
More hydrophobic
More hydrophilic
Uniform and quick drying Uniform wetting
Surface ModificationPolyquart® Ecoclean
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0
10
20
30
40
50
60
70
80
90
Ceramic Glass Stainless Steel Plastics*
Con
tact
Ang
le [°
]
Untreated Surface
Polyquart Ecoclean
More hydrophilic
* PVC
Excellent wetting & uniform drying Unchanged surface
Multipurpose Solutions for Surface Clean!Test Method Water Drainage / Sheeting
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1. Pretreatment with test solution
Test solution ( e.g. 0.5% active surfactant and 0.1% active polymer or a cleaner formulation) is dropped on a ceramic tile 15x15cm by 25 drops, 5x5 drops in square.
These drops are wiped via Kim Wipe in twice, 10 wiping cycles in both directionsto get a homogenous film
2. Air drying
Drying at roomtemperature for 24 hours
3. Rinse with water stream
Pretreated plate is placed vertical and a water stream isplaced on the upper end from the right to the left corner in order to rinse the ceramic.After stopping the water stream,you can evaluate the sheeting effect)
Multipurpose Solutions for Surface Clean!Water Drainage / Sheeting Effect
Water sheeting effect
caused by hydrophilization ofthe surface
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No effect
on a non treated surface
Water drainage effect
caused by hydrophobization ofthe surface
Multipurpose Solutions for Surface Clean!Water Drainage / Sheeting
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1 11
-0.5
1
-0.5
Lutensol® Lutensol®/ Glucopon® 425 (1:3)
0.5% active surfactant 1% active surfactant 2% active surfactant without polymer
hydr
opho
biza
tion
hydr
ophi
lizat
ion
Water drainage
no effect - rip
Water sheeting
Multipurpose Solutions for Surface Clean!Water Drainage by Polyquart® 149
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1 1
4
6
Lutensol® Lutensol®/ Glucopon® 425 (1:3)
0.5% active surfactant 0.5% active surfactant + 0.1% active Polyquart® 149
hydr
opho
biza
tion
hydr
ophi
lizat
ion
Water drainage
Water sheeting
Multipurpose Solutions for Surface Clean!Water Sheeting by Polyquart® Ecoclean
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1 1
-1 -1
Lutensol® Lutensol®/ Glucopon® 425 (1:3)
0.5% active 0.5% active + 0.1% active Polyquart® Ecoclean
hydr
opho
biza
tion
hydr
ophi
lizat
ion
Water drainage
Water sheeting
Multipurpose Solutions for Surface Clean!Water Drainage / Sheeting
Effect on water sheeting / drainage by Polyquart® typesfor a spotless drying:
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Polyquart® 149
Polyquart® Ecoclean
Strength of water sheeting / drainage effect
quick & spotless dryingspotless drying & anti-rain
Convenient Cleaning
14
SpotlessDrying Easy-to-clean-
again Effect
Multipurpose Solutions for Surface Clean!Effect to choose – Convenient Cleaning
Multipurpose Solutions for Surface Clean!Test Method Easy-to-clean-again
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1. Pretreatment with test solutione.g. 1% active surfactant and 0.1% active polymer is dropped on a ceramic tile. 25 drops, 5x5 drops in square for 15x15cm tile.These drops are wiped via Kim Wipe in twice 10 wipingcycles in both directions to get a homogenous film.
2. Air drying
Drying at roomtemperature for 24 hours.
3. Soiling tile with Ca-Stearate by air brush3 ml soil is sprayed homgenous on the hole area of tile.(Soil: 5% Ca-Stearate, 10% Water, 85% Ethanolthe soil should be stirred by Ultra Turrax and Ultra Sonic Bath and stored under usual stiring for 1 day)
4. Heating at for melting the Stearate layer(30 Minutes at 180°C)
5. Wiping with sponge under rinsing tap waterWiping with constant low pressure under water stream for 10 cycles.
6. Evaluation
Multipurpose Solutions for Surface Clean!Easy-to-clean-again Effect
Evaluation:
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left side of tileuntreated
right side of tilepretreated
Grading examples (0 to 3):
0 1 2 3
Multipurpose Solutions for Surface Clean!Easy-to-clean-again: Polyquart® 149
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0
1
0
1
2
3
Lutensol® Lutensol®/ Glucopon® 425 (1:3)
0.5% active surfactant + 0.1% active Polyquart® 1492% active surfactant + 0.1% active Polyquart® 149
0 0
No effect with 0.5% active surfactant, slight effect on Lutensol® and Glucopon® mixtures with 2.0% active surfactant and 0.1%
Polyquart® 149.
Multipurpose Solutions for Surface Clean!Easy-to-clean-again: Polyquart® 149
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1
0
1 1
0
1
2
3
Lutensol® Lutensol®/ Glucopon® 425 (1:3)
0.5% active surfactant + 0.2% active Polyquart® 1492% active surfactant + 0.2% active Polyquart® 149
Slight effect with 0.5% / 2.0% active surfactant and 0.2% Polyquart®149.
Multipurpose Solutions for Surface Clean!Easy-to-clean-again: Polyquart® Ecoclean
198/24/2016
1 1
3
1
0
1
2
3
Lutensol® Lutensol®/ Glucopon® 425 (1:3)
0.5% active surfactant + 0.1% active Polyquart® Ecoclean2% active + 0.1% active Polyquart® Ecoclean
Slight effect with 0.5% active surfactant, excellent effect on Lutensol®but not on Glucopon® mixtures with 2.0% active surfactant and 0.1%
Polyquart® Ecoclean.
Multipurpose Solutions for Surface Clean!Easy-to-clean-again: Polyquart® Ecoclean
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1 1
2 2
0
1
2
3
Lutensol® Lutensol®/ Glucopon® 425 (1:3)
0.5% active surfactant + 0.2% active Polyquart® Ecoclean2% active + 0.2% active Polyquart® Ecoclean
Slight effect with 0.5% active surfactant, significant effect on Lutensol®and Glucopon® mixtures with 2.0% active surfactant and 0.2%
Polyquart® Ecoclean.
Multipurpose Solutions for Surface Clean!Easy-to-clean-again
Easy-to-clean-again effect by Polyquart® types:
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Polyquart® 149
Polyquart® Ecoclean
Strength of easy-to-clean-again effect*
*using Ca-stearate based soil
22
Home CareClaims to choose – High-Performance
Primary Cleaning
BoostGlossy &
Streak-Free
High-Performance Cleaning
Multipurpose Solutions for Surface Clean!Test Method Primary Cleaning
Modified Gardner test method by automatic test equipment
0.5% / 1% / 2 % active surfactant in distilled water
25 °C
Using oil soil (IPP 83/21) on polyvinylchloride (PVC) strips
Evaluation of cleaned PVC strips after 10 wipes
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Oily Soil (IPP 83/21)% Content
17.0 Myritol 318 (caprylic / capric triglyceride)40.0 Nytex 801 (Nynas; processing oil, naphthenic)36.0 Benzine (80/110)
7.0 Special Carbon Black (Orion Engineered Carbons,D-60528 Francfort, Germany)
(1) Soiling by brush (2) Analysis of soiled surface
(4) Wiping with sponge(3) Applying test solution
(6) Analysis of cleaned surface(5) Rinsing with water
Multipurpose Solutions for Surface Clean!Primary Cleaning Performance
Soi
lRem
oval
[%]
Test in distilled water at 25 °C, using the modified Gardner test on PVC with oil soil
50 51
6255
5852
0
10
20
30
40
50
60
70
Lutensol® Lutensol®/ Glucopon® 425 (1:3)
0.5% active surfactant 1% active surfactant 2% active surfactant
Multipurpose Solutions for Surface Clean!Primary Cleaning – Polyquart® 149
Soi
lRem
oval
[%]
Test in distilled water at 25 °C, using modified Gardner test on PVC with oil soil
6255
50 51
6371
0
10
20
30
40
50
60
70
80
Lutensol® Lutensol®/ Glucopon® 425 (1:3)
1% active surfactant0.5% active surfactant0.5% active surfactant + 0.1% active Polyquart® 149
Excellent primary cleaning boost of Lutensol® / Glucopon® combination (3:1) by 0.1% active Polyquart® 149.
Multipurpose Solutions for Surface Clean!Primary Cleaning – Polyquart® Ecoclean
Soi
lRem
oval
[%]
Test in distilled water at 25 °C, using modified Gardner test on PVC with oil soil
6255
50 5158
54
0
10
20
30
40
50
60
70
Lutensol® Lutensol®/ Glucopon® 425 (1:3)
1% active surfactant0.5% active surfactant0.5% active surfactant + 0.1% active Polyquart® Ecoclean
Excellent primary cleaning boost of Lutensol® / Glucopon® combination(3:1) by 0.1% active Polyquart® Ecoclean.
Multipurpose Solutions for Surface Clean!Primary Cleaning
Boost effect on primary cleaning by Polyquart® types:
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Polyquart® 149
Polyquart® Ecoclean
Strength of primary cleaning boost effect
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Home CareClaims to choose – High-Performance
PrimaryCleaning
Boost
Glossy & Streak-
Free
High-Performance Cleaning
Multipurpose Solutions for Surface Clean!Test Method Gloss Retention
1. Measure reflection of clean ceramic tile
2. Pretreatment with test solution (1% active surfactant is dropped on a ceramic tile. 25 drops, 5x5 drops in square for 15x15cm tile. These drops are wiped via Kim Wipe in twice 10 wiping cycles in both directions to get a homogenous film)
3. Air drying at room temperature
4. Measure reflection of treated ceramic tile
5. Calculate gloss retention out of 1. and 4.
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20°
60°
85°
N
Multipurpose Solutions for Surface Clean!Gloss Retention – Polyquart® 149
Glo
ssR
eten
tion
[%]
Test in distilled water at 20 °C on black ceramic tiles
78.2
96.691.8 95.379.7 85.280.4
88.2
0102030405060708090
100
Lutensol® Lutensol®/ Glucopon® 425 (1:3)
0.5% active surfactant0.5% active surfactant + 0.1% Polyquart® 1492.0% active surfactant2.0% active surfactant + 0.1% Polyquart® 149
Gloss retention boost by Polyquart® 149 only on Lutensol® types –mixtures with Glucopon® show already excellent gloss retention; better
results with 0.5% active surfactant.
Multipurpose Solutions for Surface Clean!Gloss Retention – Polyquart® Ecoclean
Glo
ssR
eten
tion
[%]
78.2
96.692.2 98.2
79.7 85.288 87.5
0102030405060708090
100
Lutensol® Lutensol®/ Glucopon® 425 (1:3)
0.5% active surfactant0.5% active surfactant + 0.1% Polyquart® Ecoclean2.0% active surfactant2.0% active surfactant + 0.1% Polyquart® Ecoclean
Gloss retention boost by Polyquart® Ecoclean only on Lutensol® types; better results at 0.5% active surfactant.
Test in distilled water at 20 °C on black ceramic tiles
Multipurpose Solutions for Surface Clean!Gloss Retention / Streak-Free Effect
Effect on gloss retention / streak-free boost with Polyquart® types:
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Polyquart® 149
Polyquart® Ecoclean
Strength of gloss retention / streak-free effect
Only with alkoxylatedsurfactants like Lutensol®types; no boost ofmixtures with Glucopon®
types!
Multipurpose Solutions for Surface Clean!Skin Care – Glucopon®
Glucopon® surfactants are
significantly less skin irritating than
comparable to nonionic and anionic
(LAS) surfactants.
Glucopon® surfactants can even
reduce the skin irritation factor of
other surfactants when being used in
combination.
Perfect mildness to skin.
Test Method:Modified Duhring - Chamber Test
Tested Surfactants: Alkyl Polyglucoside - APG®
Linear Alkylbenzene Sulphonate - LAS Fatty Alcohol Ether Sulfate - FAES Sodium Alkene Sulfate - SAS Fatty Alcohol Sulfate – FAS Mixtures of other surfactants with APG®
Test Conditions:20 subjects (male and female)Mode of application: once, occlusive, for 24 hoursConcentration of the test solution: 1% active substance
Multipurpose Solutions for Surface Clean!Skin Care - Glucopon®
Relative irritation score (%)
APG®
LAS
FAES
SAS
FAS C12/14
LAS / APG® (1:1)
FAES / APG® (1:1)
SAS / APG® (1:1)
FAS / APG® (1:1)
0 100 200 400300
Multipurpose Solutions for Surface Clean!Skin Care - Glucopon®
Test Method: Modified Duhring - Chamber Test
Test Conditions: 20 subjects (male and female). Mode of Application:once, occlusive, for 24 hours The concentration of the test solution was 1% active substance.
Multipurpose Solutions for Surface Clean!Test Method Plastic Compatibility
ISO 22088-4 test method (spline / corrosion test)
A test method to determine the plastic compatibility of hard surface cleaner ingredients like surfactants, solvents, acids, alkaline and further components.
Methodology:
The plastic test strip, containing a stainless steal pin in a hole (tension), is dipped shortly into the test solution (1% active). The test strip is checked visually after
4 hours
3 days
7 days and
14 days test period
388/24/2016
unchanged
fissures
through-cracks
fraction
Multipurpose Solutions for Surface Clean!Plastic Compatibility (PMMA)
4 hours
3 days
7 days14 days
Lutensol®Lutensol® /Glucopon®
425Lutensol® /Glucopon®
425 /Polyquart®
149
Lutensol® /Glucopon®
425 /Polyquart®Ecoclean
Test solution: 1% active surfactant – Lutensol® :Glucopon® 425 (1:3) – w/wo 0.2% Polyquart® typeSubstrate: Plexiglass 8N80 (PMMA - Polymethylmethacrylat)
Superior plastic compatibility with high content of Glucopon® types; noinfluence by Polyquart® types.
unchanged
fissures
through-cracks
fraction
Multipurpose Solutions for Surface Clean!Plastic Compatibility (PC)
4 hours
3 days
7 days14 days
Lutensol®Lutensol® /Glucopon®
425Lutensol® /Glucopon®
425 /Polyquart®
149
Lutensol® /Glucopon®
425 /Polyquart®Ecoclean
Superior plastic compatibility with high content of Glucopon® types; noinfluence by Polyquart® types.
Test solution: 1% active surfactant – Lutensol® :Glucopon® 425 (1:3) – w/wo 0.2% Polyquart® typeSubstrate: Makrolon 3103 (PC - Polycarbonate)
unchanged
fissures
through-cracks
fraction
Multipurpose Solutions for Surface Clean!Plastic Compatibility (ABS)
4 hours
3 days
7 days14 days
Lutensol®Lutensol® /Glucopon®
425Lutensol® /Glucopon®
425 /Polyquart®
149
Lutensol® /Glucopon®
425 /Polyquart®Ecoclean
Superior plastic compatibility with high content of Glucopon® types; noinfluence by Polyquart® types.
Test solution: 1% active surfactant – Lutensol®: Glucopon® 425 (1:3) – w/wo 0.2% Polyquart® typeSubstrate: Polylac PA 727 (ABS - Acrylnitril Butadien Styrol)
unchanged
fissures
through-cracks
fraction
42
Multipurpose Solutions for Surface Clean!Claims to choose – Sustainable Cleaning
Sustainable Cleaning
RenewableBase
Multipurpose Solutions for Surface Clean!Renewable Base
Renewable Base:
Glucopon® types (alkyl polyglucoside) = sugar / fatty alcohol
Polyquart® Ecoclean = teric modified starch
Existing statement for vegetable origin of Polyquart® Ecoclean
Aerobic and anaerobic biodegradability, no labelling for the following products:
Glucopon® types,
Lutensol® types
Polyquart® Ecoclean
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Home Care and I&IGlucopon® types
44
Product information Application: Home Care and I&I
Focus Hard Surface Cleaning
Customer industry: Consumer Goods and I&I
Market: Global
Differentiation potential Customer
Performance in modern formulations
Health and safety
Consumer
Health & safety
Material protection
A balanced surfactant combining efficiency with an excellent eco-tox profile
Sustainability performance Gloss improvement, foam stabilization
Cleaning performance
100% renewable based
Meets eco-label requirements – aerobic and anaerobic biodegradable
Registered in main chemical inventories
Home Care and I&IPolyquart® Ecoclean
45
Product information Application: Home Care and I&I
Focus Hard Surface Cleaners
Customer industry: Consumer Goods and I&I
Market: Global
Differentiation potential Customer
Supported modern claims
Consumer
Health & safety
Convenience
Performance
A product that supports modern consumer needs
Sustainability performance Amphoteric modified starch
Excellent eco-tox profile
Aerobic and anaerobic biodegradable
Supports sustainable convenience claims such as easy-to-clean-again, time-saving, easy-to-use
Multipurpose Solutions for Surface Clean!The Elements
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Multipurpose Solutions!
Lutensol® typesExcellent wetting
EmulsificationDisperging
Polyquart® typesLong-lasting effects
High glossCleaning boost
Glucopon® typesSkin and surface care
FormulabilityFoam stabilization
High gloss
renewables sustainable
Convenient Cleaning
48
Gentle Cleaning
High-Performance Cleaning
Sustainable Cleaning
Multipurpose Solutions for Surface Clean!Summary
Easy-to-clean-again effect
Quick and spotless drying
Time-saving and effortless cleaning
Material protection
Skin protection
Excellent primary cleaning
Glossy and streak-free surfaces
Foam stability
Biodegradable products
Renewable based raw materials
Lutensol®, Glucopon® & Polyquart®:Multipurpose Solutions for Surface Clean!
Juraci M. da Silva [email protected]