board authorizes prf grants

3
Board authorizes PRF grants Clémence and ACS's Chapman . . . a class of affiliates may be estab- lished in ACS A. Yes. Technicians will be replac- ing chemists and chemical engineers to a large extent in the routine and repetitive types of jobs in laboratory manipulations and in plant operations. Chemical technicians will not be replaced by automation because many of the tasks they perform cannot be automated and they will be trained to handle the instruments used in auto- mated operations. The progress in new technology, requiring more man- power, will always remain ahead of automation. Q. What will be the continuing edu- cation needs of chemical technicians? A. As technology and scientific meth- ods move forward, technicians as well as professional chemists will require continuing education and training. Q. What part do you see ACS playing in the future? A. In the near future, I doubt that chemical technicians as a class or group will be admitted to the Ameri- can Chemical Society as members, since the great majority of them will not reach the level of training of a pro- fessional and will therefore not qual- ify. However, a few may attain this level and would then qualify under the present procedures. If enough interest and activity on the part of a significant number of technicians and members of the Society is indicated, there is a possibility that a national class of affiliates may be established in ACS. ACS should develop comprehensive continuing education opportunities for chemical technicians to be made avail- able to those local sections, divi- sions, or industrial groups in which significant numbers of chemical tech- nicians would avail themselves of the courses. Other services might be the use of the Employment Clearing House, na- tional meeting attendance, and publi- cations at reduced rates, but these services would all depend on the defi- The ACS Board of Directors, meeting in Washington last month, authorized Petroleum Research Fund grants (for one, two, or three years) totaling $1,048,502, as tabulated below. Re- quests for application forms, directions on the preparation of proposals, and questions about the ACS-PRF program may be addressed to Petroleum Re- search Fund, American Chemical So- ciety, 1155-16th St., N.W., Washing- ton, D.C. 20036. ACS-PRF grants for fundamental research in the petroleum field Subject Hydrogenolysis Investigator and institution E. W. Garbisch, Jr., U of Minnesota J. H. Swinehart, U of California, Davis S. F. Nelsen, U of Wisconsin D. Bradley, U of Leeds, U.K. A. E. Grosser, McGill U D. J. J. Kinsman, Princeton U L H. Germer, Cornell U G. P. Glass, Rice U E. Grunwald, Brandeis U W. M. Sackett, Texas A&M U P. Mukerjee, U of Wisconsin J. K. Beattie, U of Illinois S. Siegel, U of Arkansas G. A. Fisk, Cornell U A. H. Lewin, Brooklyn Poly R. H. Osborne, U of Southern California G. K. Patterson & J. L Zakin, U of Missouri, Rolla A. Davison, MIT J. R. Bolton, U of Minnesota R. G. Griskey, Newark Coll. of Engineering H. R. Ward, Brown U A. I. Meyers, Louisiana State U (N.O.) J. W. Gilje, U of Hawaii J. E. McMurry, U of California, Santa Cruz J. E. Baldwin, Pennsylvania State U A. A. Levinson & P. Bayliss, U of Calgary (Canada) R. A. Olofson, Pennsylvania State U J. B. Fenn & G. L Haller, Yale U P. C. Ford, U of California, Santa Barbara F. Maclntyre, U of California, La Jolla G. M. Whitesides, MIT J. J. Zuckerman, SUNY at Albany Solvation of Cations Aminoradical Formation and Reactions (Type A) Amount $ 24,000 23,304 24,000 Flame Ionization Molecular Beam Chemical Kinetics Early Diagenesis of Carbonate Sedi- ments in a Supratidal Evaporitic Setting Reactions on Crystal Surfaces ESR Studies of Combustion Lifetime of Hydrogen-Bonded Solva- tion Complexes Kinetic Isotope Effects Ionic and Environmental Specificity at Interfaces The Tris(ethylenediamine) Ruthenium(lll) Ion Catalytic Hydrogénation of Aromatic Hydrocarbons Intermolecular Energy Transfer Copper in Organic Chemistry Statistical Analysis of a late Pre- cambrian-Cambrian Sequency in the Cordilleran Frontal Thrust Belt Solid Suspension Drag Reduction Organometallic and Carbonyl Chemistry Flash Photolysis ESR Kinetics Heat Transfer to Molten Flowing Polymers A Study of CI DN Ρ A New Aldehyde Synthesis Phosphorus-Nitrogen Compounds Total Synthesis of Culmorin Bond Formation by Valence Re- arrangement of Hetero-Systems Geochemistry-Mineralogy of the Mackenzie Carbenes from Carbonium Ions Isomerization Dynamics by Molecular Beam Methods Reactions of Ruthenium Complexes Eddy Diffusivity at a Free Surface Fast Kinetics Studies Using NMR Spectroscopy Silicon-Containing Aromatic 14,000 14,000 4,800 24,000 24,000 24,000 24,000 24,000 8,000 24,000 16,000 16,000 20,000 24,000 24,000 20,000 16,000 24,000 16,000 8,000 24,000 21,300 15,000 24,000 24,000 24,000 18,600 24,000 16,000 Heterocycle Table continues on page 46 JAN. 20, 1969 C&EN 45

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Board authorizes PRF grants

Clémence and ACS's Chapman

. . . a class of affiliates may be estab­lished in ACS

A. Yes. Technicians will be replac­ing chemists and chemical engineers to a large extent in the routine and repetitive types of jobs in laboratory manipulations and in plant operations.

Chemical technicians will not be replaced by automation because many of the tasks they perform cannot be automated and they will be trained to handle the instruments used in auto­mated operations. The progress in new technology, requiring more man­power, will always remain ahead of automation. Q. What will be the continuing edu­cation needs of chemical technicians? A. As technology and scientific meth­ods move forward, technicians as well as professional chemists will require continuing education and training. Q. What part do you see ACS playing in the future? A. In the near future, I doubt that chemical technicians as a class or group will be admitted to the Ameri­can Chemical Society as members, since the great majority of them will not reach the level of training of a pro­fessional and will therefore not qual­ify. However, a few may attain this level and would then qualify under the present procedures. If enough interest and activity on the part of a significant number of technicians and members of the Society is indicated, there is a possibility that a national class of affiliates may be established in ACS.

ACS should develop comprehensive continuing education opportunities for chemical technicians to be made avail­able to those local sections, divi­sions, or industrial groups in which significant numbers of chemical tech­nicians would avail themselves of the courses.

Other services might be the use of the Employment Clearing House, na­tional meeting attendance, and publi­cations at reduced rates, but these services would all depend on the defi-

The ACS Board of Directors, meeting in Washington last month, authorized Petroleum Research Fund grants (for one, two, or three years) totaling $1,048,502, as tabulated below. Re­quests for application forms, directions

on the preparation of proposals, and questions about the ACS-PRF program may be addressed to Petroleum Re­search Fund, American Chemical So­ciety, 1155-16th St., N.W., Washing­ton, D.C. 20036.

ACS-PRF grants for fundamental research in the petroleum field Subject

Hydrogenolysis

Investigator and institution

E. W. Garbisch, Jr., U of Minnesota

J. H. Swinehart, U of California, Davis

S. F. Nelsen, U of Wisconsin

D. Bradley, U of Leeds, U.K. A. E. Grosser, McGill U D. J. J. Kinsman, Princeton U

L H. Germer, Cornell U G. P. Glass, Rice U E. Grunwald, Brandeis U

W. M. Sackett, Texas A&M U P. Mukerjee, U of Wisconsin

J. K. Beattie, U of Illinois

S. Siegel, U of Arkansas

G. A. Fisk, Cornell U A. H. Lewin, Brooklyn Poly R. H. Osborne, U of Southern

California

G. K. Patterson & J. L Zakin, U of Missouri, Rolla

A. Davison, MIT

J. R. Bolton, U of Minnesota R. G. Griskey, Newark Coll. of

Engineering H. R. Ward, Brown U A. I. Meyers, Louisiana State U

(N.O.) J. W. Gilje, U of Hawaii J. E. McMurry, U of California,

Santa Cruz J. E. Baldwin, Pennsylvania State U

A. A. Levinson & P. Bayliss, U of Calgary (Canada)

R. A. Olofson, Pennsylvania State U

J. B. Fenn & G. L Haller, Yale U

P. C. Ford, U of California, Santa Barbara

F. Maclntyre, U of California, La Jolla

G. M. Whitesides, MIT

J. J. Zuckerman, SUNY at Albany

Solvation of Cations

Aminoradical Formation and Reactions

(Type A) Amount

$ 24,000

23,304

24,000

Flame Ionization Molecular Beam Chemical Kinetics Early Diagenesis of Carbonate Sedi­

ments in a Supratidal Evaporitic Setting

Reactions on Crystal Surfaces ESR Studies of Combustion Lifetime of Hydrogen-Bonded Solva­

tion Complexes Kinetic Isotope Effects Ionic and Environmental Specificity

at Interfaces The Tris(ethylenediamine)

Ruthenium(lll) Ion Catalytic Hydrogénation of Aromatic

Hydrocarbons Intermolecular Energy Transfer Copper in Organic Chemistry Statistical Analysis of a late Pre-

cambrian-Cambrian Sequency in the Cordilleran Frontal Thrust Belt

Solid Suspension Drag Reduction

Organometallic and Carbonyl Chemistry

Flash Photolysis ESR Kinetics Heat Transfer to Molten Flowing

Polymers A Study of CI DN Ρ A New Aldehyde Synthesis

Phosphorus-Nitrogen Compounds Total Synthesis of Culmorin

Bond Formation by Valence Re­arrangement of Hetero-Systems

Geochemistry-Mineralogy of the Mackenzie

Carbenes from Carbonium Ions

Isomerization Dynamics by Molecular Beam Methods

Reactions of Ruthenium Complexes

Eddy Diffusivity at a Free Surface

Fast Kinetics Studies Using NMR Spectroscopy

Silicon-Containing Aromatic

14,000 14,000 4,800

24,000 24,000 24,000

24,000 24,000

8,000

24,000

16,000 16,000 20,000

24,000

24,000

20,000 16,000

24,000 16,000

8,000 24,000

21,300

15,000

24,000

24,000

24,000

18,600

24,000

16,000 Heterocycle

Table continues on page 46

JAN. 20, 1969 C&EN 45

A flexible travel program has

been developed for members

of the American Chemical

Soc iety utilizing the low

group fares of Pan Am, TWA,

Lufthansa, BOAC and other

major airlines. Several groups

will leave New York this sum­

mer to Europe, the Mediter­

ranean and the Bible Lands.

Round trip jet fares start at

$230 (New York/London/-

New York.) Write for bro­

chure to: Division 'M ' , Travel

Wholesalers I nternational,

1707 L S t r e e t , N.W.,

Washington, D. C , 20036

Subject

Chemistry of Functionally Substituted Organometallic Compounds

Diradicals and Vibrational^ Excited Molecules

The Chemistry of Cyclic Peroxyesters Study of Molecular Structure and

Bonding by Microwave Spectroscopy Surface Effects in Tubular Flow

Reactors During Pyrolysis of Ethyl­ene and Propylene

The Polycyclic C12H12 Hydrocarbons Experimental Studies of the Molec­

ular Zeeman Effect Total

Amount

16,000

24,000

24,000 24,000

16,000

16,000 30,000

$781,004

Investigator and Institution

D. D. Davis, New Mexico State U

R. G. Bergman, Caltech

W. Adam, U of Puerto Rico R. Varma, New York U

B. L. Crynes, Oklahoma State U

D. G. Farnum, Michigan State U W. H. Flygare, U of Illinois

ACS-PRF grants for fundamental research in the petroleum field at the undergraduate level (Type B)

Investigator and institution

R. Maatman, Dordt Coll.

H. F. Koch, Ithaca Coll.

R. C. Burton, West Texas State U

F. W. Breitbeil, III, DePaul U L. D. Wescott, Jr., Christian

Brothers Coll.

H. A. Swain, Jr., Wilkes Coll.

R. S. Borden, Wittenberg U

R. T. Keys, California State Coll.,

LA. E. Block, U of Missouri, St. Louis

ACS-PRF unrestricted grants for established scientists conducting fundamental research in the petroleum field (Type C)

Subject

Electrolyte-Surface Reactions and Catalytic Activity

Reactions of Highly Halogenated Olefins

Microbiostratigraphy of the Palo Duro Basin

Synthesis of 1,2-Cyclopropanediols Synergistic Interaction of Organic

Phosphites and o-hydroxybenzo-phenone Derivatives in the Stabiliza­tion of Polyolefins

Hydrogen Bonding in Long-Chain Fatty Acids

Stereochemistry of Titanium(IV) Complexes

Ion Radical Formation

Studies in Carbocycle Synthesis Total

Amount

$12,000

10,080

12,000

11,820 6,000

12,000

12,000

12,000

12,000 $99,900

Investigator and institution

M. Calvin, U of California, Berkeley

C. A. Hutchison, Jr., U of Chicago

B. P. Dailey, Columbia U

K. B. Wiberg, Yale U G. L. Closs, U of Chicago J. A. Ibers, Northwestern U

F. A. L. Anet, U of California, LA.

Area of research Amount

Organic Geochemistry $ 20,000

Magnetic Resonance Studies on 20,000 Aromatic Hydrocarbons in Single Crystals

Radio Frequency Studies of Molec- 20,000 ular Magnetism

Organic Chemistry 20,000 Chemistry of l,n-Diradicals 20,000 Bonding of Simple Molecules to 20,000

Transition Metals Syntheses of Cyclic Conjugated 20,000

Systems; NMR Studies of Organic Compounds

Total $140,000

ACS-PRF international awards in the petroleum field (Type D) Investigator and institution

A. B. Metzner, U of Delaware

E. C. Perry, Jr., U of Minnesota

Title Amount

Asymptotic Approximations for Vis- $ 5,718 coelastic Media to be performed at U of Cambridge, England

Oxygen Isotope Studies in Pre- 3,580 cambrian Chemical Sediments to be conducted at the U of Wit-watersrand, Johannesburg, South Africa

Total $9,298

Tables continue on page 47

46 C&EN JAN. 20, 1969

nite interest of a number of techni- Special Proposals cians.

At each of the open meetings of the Committee on Technician Affiliation the question has been asked "Should chemical technicians be associated with the American Chemical Society in some form of national affiliation or should ACS help form a daughter soci­ety for them?" The majority of mem­bers and technicians have always indi­cated a preference for association with ACS, not a daughter society. Unless future investigation yields different results, this committee is unlikely to recommend a daughter society.

Investigator and institution

L. Eyring, Arizona State U

G. C. Rodriguez & J. Fco. Sanchez, X Congreso Latino-America no de Quimica

M. A. Paul, NAS-NRC

G. P. Haight, Jr., U of Illinois

Purpose

Toward expenses of a Conference on the Chemistry of Extended Defects in Non-Metallic Solids to be held near Tempe, Ariz., spring

Toward travel expenses of speakers for the 10th Latin American Con­gress of Chemistry to be held in San Jose, Costa Rica, in February

Travel support for the XXIInd IUPAC Congress, Sydney, Australia, Aug. 20-27

Toward travel expenses of speaker for the Mendeleev Symposium, Minneapolis, April Total

Amount

$ 5,000

2,000

10,400

900

$18,300

ACS Short Courses-spring sessions The following ACS Short Courses are newly scheduled for April and May. Other April courses offered in conjunction with the spring national meeting are described in the Jan. 6 issue of C&EN. For a listing of all Short Courses currently scheduled see page 62.

To register or to obtain complete information on any course, convenient lodging, and student discounts, please write to Education

Office, American Chemical Society, 1155—16th St., N.W., Washington, D.C. 20036. During the two-week period prior to a course, registration should be made by telephone: area code 202, 737-3337 ext. 258.

New York City area Emulsions and Dispersions—April 28-30. Dr. Sydney Ross and Dr. Frederick M. Fowkes; three days; fee $80. Required text, S. Ross, éd., "Chemistry and Physics of Interfaces," American Chemical Society Publications, 1965, $7.50.

This course is intended for industrial chemists and chemical engineers who meet problems in the technology of emulsions and dispersions. The purpose of the course is to introduce principles of colloid and surface chemistry that pertain to the behavior of such systems. The main divisions of the course are based on two factors that control the stability of a dispersion —solvation and electrostatic repulsion. The course includes demonstrations of instruments for the measurement of prop­erties related to the stability of colloidal dispersions. A B.S. in chemistry or chemical engineering is sufficient background.

Organometallic Principles in Modern Organic Synthesis-May 3-4. Dr. John J. Eisch; two days; fee $65. Required text, J. J. Eisch, "The Chemistry of Organometallic Compounds," Macmillan Co., 1967, $7.00.

The emphasis in this course is placed on the rational synthesis of organic structures. Organometallic reagents and inter­mediates of significance in inorganic chemistry are also covered. The course is intended for the professional chemist who has little formal knowledge of organometallic chemistry but who would like to acquire an up-to-date insight into the principles governing the reactions and synthetic applications of organo­metallic compounds. Chemists with B.S. or Ph.D. degrees should find the course of interest.

High Temperature Chemistry—May 23-24. Dr. John L. Mar­grave; two days; no textbook required; fee $65.

The course covers various methods for generation and measure­ment of high temperatures and presents selected examples of techniques for studying the chemical processes which occur in high temperature environments. Particular attention is directed toward the synthetic possibilities now available to the chemist through the use of high temperature species. The course is designed especially for industrial and academic chemists who are interested in high temperature phenomena but have no academic background in this specialized area. The course is taught at the level of an introductory graduate course.

Midland, Mich. Oxidation Reactions in Organic Chemistry—April 11-12. Dr. Ross Stewart, Dr. P. M. Henry, and Dr. R. D. Temple; two days; fee $65. Required text, R. Stewart, "Oxidation Mechanisms: Applications to Organic Chemistry," W. A. Benjamin, 1964, $4.00 to registrants.

The course deals with the modes of oxidation of organic com­pounds by various reagents. The mechanisms of these proc­esses are considered in terms of transfer of electrons, hy­drogen atoms, hydride ions, oxygen atoms, and other species. The effects of structural variation in the substrate and varia­tions in reaction conditions on rate and course of reaction are considered. A reasonable background for this course is an understanding of the common reaction mechanisms of or­ganic chemistry—the sort of material that chemistry majors now get in their undergraduate education.

Washington, D.C. Molecular Characterization off Polymers—May 2-5. Dr. Fred W. Billmeyer, Dr. Jack B. Kinsinger, and Dr. Josip P. Kratohvil; four days; no textbook required; fee $100.

This course is designed for the practicing polymer chemist whose duties or interests require a working knowledge of the techniques for measuring molecular weight, molecular weight distribution, and other characteristic parameters of random-coil polymers. In addition to theory, the course covers such practical aspects of measurement methods as preferred tech­niques, commercially available equipment, time, cost, and sample size for analysis, limitations of the method, and pitfalls in data interpretation.

Houston, Tex. Molecular Orbital Theory—May 9-10. Dr. Howard E. Zimmer­man and Dr. Reuben D. Rieke; no textbook required; fee $65.

This course is designed to bring an organic chemist who knows no molecular orbital theory to the point where he can do simple calculations on organic molecules and to provide sufficient background to proceed to more sophisticated methods. The course shows how the calculations are done prior to the in­troduction of the theoretical background. Useful methods for simplifying the calculations are introduced, including a simple and gradual approach to group theory. Some applications of simple MO theory such as the application to correlation dia­grams are presented. Students should know integral calculus, but extensive math background is not required.

JAN. 20, 1969 C&EN 47