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Braskem: New ways to look at the world
Workshop for Sustainable Production of Biopolymers
and other bio-based products July, 2012
Agenda
Introduction: Braskem
Innovation and Technology
Braskem Green Ethylene and Propylene
NEXT STEPS: Synthetic Biology
Open Innovation
EXTRACTION Raw Material
1a GENERATION Basic Petrochemicals
2a GENERATION Thermoplastics resins
3a GENERATION Plastic Converters
INTEGRADO NA CADEIA
NAFTA CONDENSED GAS
ADDED VALUE COMPETITIVINESS
BRAZILIAN PETROCHEMICAL INDUSTRY
2002 2005 2006
POLITENO
2007
IPIRANGA
COPESUL
2008 2009
PETROQUÍMICA
TRIUNFO
2010
TRIKEM
POLIALDEN
PAULINIA QUATTOR
PP Business
SUNOCO
2011
PP Business DOW
Vision 2020
To be the world leader in sustainable chemistry, innovating to
serve people better.
35 industrial Units
Industrial Presence Source: Braskem
Projects
Bahia - Brazil
1 UNIB
4 PE
1 PP
1 PVC
1 Chlorine Soda
Alagoas - Brazil
1 PVC
1 Chlorine Soda
São Paulo - Brazil
2 UNIB
2 PE
2 PP
Rio de Janeiro - Brazil
1 UNIB
1 PE
1 PP
Rio Grande do Sul - Brazil
2 UNIB
5 PE
2 PP
United States
5 PP Neal | La Porte | Marcus
Hook | Freeport | Seadrift
Germany
2 PP Wesseling | Schkopau
CONSISTENT EVOLUTION OF ECO-EFFICIENCY INDICATORS
2002 2003 2004 2005 2006 2007 2008 2009 2010
3,97
3,83
4,25 4,26 4,29
4,50
3,83
4,14 4,15
Water Consumption (m³/t)
+1%
2002 2003 2004 2005 2006 2007 2008 2009 2010
11,90
11,47
11,12
11,55 11,46 11,47
11,83
11,27
10,65
Energy Consumption (GJ/t)
-10%
Braskem pro forma for 2002
2002 2003 2004 2005 2006 2007 2008 2009 2010
5,78
4,52
3,53 3,28 3,41
3,10 3,38
2,40 2,21
Residue Generation (kg/t)
-62%
2002 2003 2004 2005 2006 2007 2008 2009 2010
1,94 1,74
1,40 1,50 1,34 1,28
1,44 1,40 1,24
Effluent Generation (m³/t)
-36%
GROWTH WITH IMPROVED COMPETITIVENESS
Projects with Petrobras Source: Braskem
PVC Alagoas
Expansion of capacity to 200 kt/year of PVC in Alagoas
Investments of around US$ 500 million, and operational startup expected in the 2nd half of 2012
Butadiene Rio Grande do Sul
Expansion of capacity to 100 kt/year at an investment of R$ 300 million
Partnership with Petrobras for new projects (under appraisal)
Comperj: production and sale of resins and basic petrochemical products. Located in Rio de Janeiro state
BRAZIL
New Projects
Projects with Petrobras Source: Braskem
JVs WITH PEQUIVEN THROUGH FINANCING OF PROJECT WITH NET EQUITY OF JUST 30% (UNDER ANALYSIS)
VENEZUELA
New Projects
Polipropileno del Sur – Propilsur
~350 kt/year of PP
Polietilenos de America – Polimerica
1.3 Mt of ethylene and 1.1 Mt/year of PE
Braskem, Petrobras and PetroPerú concluded studies for the technical and economic pre-feasibility of an integrated project to produce between 600 kt and 1,000 kt/year of ethane and polyethylene using the natural gas available in Peru as raw material
PERU
GROWTH WITH IMPROVED PRODUCTIVITY
Projects with Petrobras Source: Braskem
ETHYLENE XXI PROJECT: Startup in 2015
MEXICO
New Projects
Partnership with the Mexican group IDESA (65% Braskem, 35% IDESA) to build an integrated petrochemical complex to produce 1 Mt/year ethylene and 1 Mt/year of PE using raw material (ethane) supplied by PEMEX
Investments estimated at US$ 3 billion over 5 years
GROWTH WITH IMPROVED PRODUCTIVITY
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Innovation and Technology
298 people (16% PhD, 30% of researchers
MSc and Post – Graduate)
Innovation Pipeline: US$ 1.6 bi (RANPV)
428 Patent applications
24 Laboratories + 8 pilot plants
Global Agreements in Technology
I&T Assets: US$ 240 MM (2011)
BRASKEM TECHNOLOGY CENTER – TRIUNFO/RS (BRAZIL)
BRASKEM TECHNOLOGY CENTER – PITTSBURGH (EUA)
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Laboratory
Technology Center
INNOVATION AND TECHNOLOGY Technology center and laboratories
BIOTECNOLOGY LABORATORY BRASKEM – CAMPINAS/SP (BRAZIL)
13
Laboratory
Technology Center
UHMWPE FIBER LABORATORY BRASKEM– CAMAÇARI/BAHIA (BRAZIL)
INNOVATION AND TECHNOLOGY Technology center and laboratories
14
Braskem Green Polyethylene
Braskem is the leading global supplier of biopolymers
Startup Sept 24, 2010
Volume 200kton/year
Investment US$ 290 MM
Green Polyethylene An alternative to traditional PE
Traditional Sustainable
Ethanol
Polyethylene
Oil
Gas
Green Polyethylene An alternative to traditional PE
Traditional Sustainable
Ethanol
Polyethylene
Oil
Gas
Braskem green Polyethylene Unique product characteristics
Oil Sugar Cane Fully identical characteristics
Petrochemical Polyethylene
Green Polyethylene
Green PE can be recycled in the same stream already established for the petrochemical PE
Green PE can also be incorporated in the current converter’s production systems
Next Steps
New Green PE Plants
New product: Green Polypropylene
First green PP
Lab scale production and Biobased Verification
Ongoing research to develop competitive go to market strategy
Medium term commercialization
Next Steps – PP new technologies
Ethanol Dehydration Ethylene Purification Clarified
Sugarcane Juice (15 wt%)
Ethylene Catalysis Ethylene Catalysis Propylene
1st wave
2nd wave
Intermediate Propylene Clarified
Sugarcane Juice (15 wt%)
3rd wave
Propylene Clarified
Sugarcane Juice (15 wt%)
New biotech laboratory in Campinas + 25 researchers
Green propylene
Cooperation projects with
1st wave 2nd wave 3rd wave
To know To growth To consolidate
the market
200 kta Green PE New Capacities Additional Capacities
(Triunfo RS) Green PE Green PE
30 kta Green PP New Capacity Higher Capacityies
Existing Technology Green PP Green PP
(Improved Tech) (Biotech Route)
Capacity
Green PE
Green PP
Total Capacity 230 kta TBD TBD
2010-2014 2015-2019 2020 - beyond
Ph
ase
s
Bioplastic estrategy
Ethylene
Ethanol
Propylene PE
PP PVC
Poliamida elastomers
Adipic acid
Isobutene
Acrilic acid
Gasoliene 700.000,00
PTA
Isoprene
Volume 1-10 MM ton/ano and price 1500-3000 USD/ton
Butanediol
Butadiene
Estirene PET Phenol
Price versus volume
Natural Gas Refining
Natural Gas
Oil Refining
Oil
GLP (C3 e C4)
Nafta (C5 a C9-C12)
Kerosene (C10 a C18)
Diesel (C10 a C21)
Parafines, etc
Methane
Ethane
Propylene
Butane
Craqueamento
Ehylene
Ethylene Oxide
Ethylene glycol
Propylene Propyle oxide
Polyester
Polyethylene
Propylene glycol
Polyester
Polypropyleno
Buteno
Acrylic acid SAP
Isobuthylene Polyisobuthylne
Butadiene Polybutadiene
Isoprene
Ciclohexene
Polyisoprene
Toluene
Xilene
Adipic acid
Caprolactam
Nylon 66
Nylon 6
Hexene
Toluene Diamina
Benzene
Toluene Diisocianate
Polyurethane
p-xilene Terephatlyc Acid
Polyester
Car
bo
hyd
rate
s
Synthetic Biology
Open Innovation
Request for research projects
FAPESP (The State of São Paulo Research Foundation) – USD ~15 MM BRASKEM + ~15 MM FAPESP for joint projects with Braskem and Universities from the State of São Paulo – results for the second call will be published soon
FAPESB (The State of Bahia Research Foundation) – USD ~950 M BRASKEM + ~950 M FAPESB for joint projects with Braskem and Universities from the State of Bahia – submission open
Focus
Biobased chemicals and polymers
Capture, storage or conversion of CO2
PE, PP, PVC
Open Innovation
Braskem’s Msc and PhD scholarships
A total of 10 masters scholarships and 10 doctorate scholarships will be funded by Braskem.
Topics of interest:
1. Chemical products from renewable raw materials;
2. Post-consumption solutions for plastic;
3. Development in the area of processes, products and catalysts for the petrochemical industry.
Open Innovation
Braskem is looking for researchers in this area: synthetic biology, protein engineering, molecular
biology, chemistry and biochemistry.
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Market - DRIVERS
Environmental
Crisis
Performance
PRODUCTS
Biofuels
Chemicals
Biopolymers
TECHNOLOGIES
Gaseification/Pirolysis
Acid Hydrolisis /Enzimatic
Catalysis/Polimerization
Fermentation
Synthetic Biology
Dowstream
BRASKEM- RENEWABLE ROADMAP
Braskem, company percived as part of the solution to sustainable development by generating economics results with the least intensity of gas emissions and water use in the global chemical industry, positioned as the largest chemical industry based on renewable raw materials and as an agent for human development .
Greenhouse Gases
Water Efficiency
Vision of Sustainable Development
Energy Efficiency
Mateus Lopes
THANK YOU!