c4 tahap 2 noraidah

Upload: mohd-zainal-sappari

Post on 07-Apr-2018

224 views

Category:

Documents


0 download

TRANSCRIPT

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    1/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    CHAPTER 4 : THE PERIODIC TABLE OF ELEMENTS

    A Historical Development Of The Periodic Table

    1 Antoine Lavoiser(1743-1794) The first Scientist classifies substances including . and ., into

    ..and.

    Substances were classified into fourgroups with similar chemical properties.

    His classification was unsuccessful because , and a few

    other compounds were also considered as elements.

    2 Johann Dobereiner(1780-1849) Divided the elements into groups of three elements with similar chemical

    properties, known as .

    The atomic mass of the middle element was approximately the average atomic massof the other two elements in each triad.

    This classification led chemist to realise that there was a relationship between the

    . and the atomic mass of each element.

    Example :

    Element in triad Li Na KAverage relativeatomic mass of Li

    and K

    Relative atomicmass, Ar

    7 39 2

    397 += 23

    3 John Newlands (1837-1898) He arranged the known elements in order ofincreasing atomic mass.

    Elements with similar chemical properties were repeated at every eighth element.

    This was known as the Law of.

    This system was inaccurate because the Law of Octaves was obeyed by the first 17elements only and there were some elements with wrong atomic mass/mass number.

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    38

    ?

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    2/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    However, Newlands was the first chemist to show the existence of.for the properties of elements.

    4 Lothar Meyer(1830-1895) He plotted a graph of.. against for all theknown elements.

    Atomic volume =

    He realised that elements with .. occupied equivalentpositions along the curve.

    He was successful in showing that the properties of the elements formed a periodic

    pattern against their..

    5 Dimitri Mendeleev (1834-1907) Arranged the elements in order of ...

    He grouped the elements according to ...

    [Elements with similar chemical properties were in the same group].

    He left gaps in the table to be filled by .. elements.

    He was able to predict the properties of undiscovered elements.

    [e.g: Ekasilicon, Es is predicted by Mendeleev in 1869 was discovered asGermanium, Ge in 1886 ].

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    39

    Mass of 1 mol (g)

    Density (g cm-3)

    Li

    Atomic

    volume

    Atomic mass

    Na

    K

    Be

    Mg

    Ca

    B

    Al

    What colourshould be here?

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    3/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    6

    Hendry J. G. Moseley (1887-1915)

    Studied the .. of elements.

    [Introduced the concepts ofproton numberof each elements]

    He concluded that should be used as the basis for theperiodic changes of chemical properties of elements instead of the atomic mass.

    He rearranged the elements in order ofincreasing proton numberin the PeriodicTable.

    B Arrangement of Elements in the Periodic Table

    Elements in the Periodic Table are arranged in an .. order of

    .., ranging from 1 to 112.

    Elements with .. are placed in the same vertical column called

    ..

    Lanthanides

    Actinides

    There are vertical columns of elements in the Periodic Table.

    Each vertical column of elements is called a ..

    The vertical columns are known as to .

    There are horizontal rows of elements in the Periodic Table.

    Each of these horizontal rows of elements is called a

    The horizontal rows are known as . to.

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    40

    Horizontal row

    Verticalcolumn

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    4/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    Activity1:-

    In the table below, write :

    (a) Group 1 to 18(b) Period number 1 to 7

    (c) the symbol of each element from Hydrogen to Calcium

    H He

    Lanthanides

    Actinides

    The number ofvalence electrons in an atom decides the .. of anelement in the Periodic Table.

    Example :

    The proton number of sodium, Na is 11.The electron arrangement of sodium atom is 2.8.1The valence electron of sodium is 1Sodium is placed in Group 1 in a Periodic Table.

    For elements with 1 and 2 valence electrons, the group numberof the element is thenumber of valence electrons in its atom.

    For elements with 3 to 8 valence electrons, the group numberof the element is the

    number of valence electrons in its atom plus ten (+10) [ valence electron + 10 ]

    Example :

    The proton number of chlorine is 17The electron arrangement of chlorine is 2.8.7The valence electrons of chlorine is 7Chlorine is placed in Group 17 [ 7 +10 ]

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    41

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    5/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    Elements from Period 3

    Complete the following table.

    The position in theperiodof an

    element in the

    Periodic Table is

    determined by the

    number of

    ..

    occupied/filled with

    electrons in the atom

    of that element.

    Theperiod numberof an element is the number of shell occupied with electrons in itsatom.

    Example :

    The proton number of magnesium is 12The electron arrangement of magnesium is 2.8.2There are 3 shells occupied with electrons in magnesium atom.Theperiodnumber of magnesium in the Period Table is 3

    Activity2:-Complete the following table :

    Element Li C O Ne Mg Al P Cl K Ca

    Proton number 3 6 8 10 12 13 15 17 19 20Electronarrangement

    2.1 2.8.2 2.8.3

    Number ofvalenceelectron

    3

    Group 13

    Number ofshellsoccupied with

    electrons

    3

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    ElementProtonnumber

    Electronarrangement

    Valenceelectron

    Group

    Na 11 2.8.1 1 1

    Mg 12

    Al 13 2.8.3 3 13

    Si 14

    P 15S 16

    Cl 17 2.8.7 7 17

    Ar 18

    42

    Group :

    Valence electrons + 10

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    6/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    Period 3

    Specific name of certain groups :

    Group Specific name

    1 Alkali metal #

    2 Alkali-earth metal

    3 to 12 Transition element #

    17 Halogen #

    18 Noble gas #

    # The important groups that will be studied from the aspect ofphysicaland chemicalproperties.

    Activity3:-

    1 Write the electron arrangement for each element in the following Periodic Table.

    Symbol of element : [ Standard form ]

    GROUP

    1 18

    1H1

    .

    2 13 14 15 16 17

    4 He2

    7 Li3

    ...

    9Be4

    ..

    11 B5

    12 C6

    14 N7

    16 O8

    19F

    9

    20 Ne10

    23 Na11

    ..

    24 Mg12

    .. 3 4 5 6 7 8 910

    11

    12

    27 Al13

    28 Si14

    31 P15

    32 S16

    35 Cl17

    40 Ar18

    39 K19..

    40 Ca20..

    TRANSITION ELEMENTS

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    43

    A

    XZ

    .number

    ..number1

    2

    3

    4

    PERIOD

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    7/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    2 Complete the statement and answer the following questions based on the table below.

    ElementNucleonnumber Number of neutrons

    A 9 4

    B 31 16

    C 35 18

    (i) The proton number of A is and the number of electrons in an atom A is

    . .

    The electron arrangement of atom A is..

    The valence electron of atom A is ..

    Atom A is in Group ..and Period ..

    (ii) Atom B is in Group ..and Period ..

    (iii) A student states that atom C is in Group 17 and Period 3 in Periodic Table of

    Element. Is the statement true or false? Explain your answer.

    .........

    .

    .

    Advantages of Grouping Elements in the Periodic TableThe systematic arrangement of elements in the Periodic Table helps us to study the

    elements systematically, especially in their and .. properties.

    Elements with the .. number of . are placed in the same

    Group because they have the same chemical properties.Elements are arranged systematically in the Periodic Table in the order ofincreasingproton numberwhich enable chemists to study, understand and remember :

    (a) the chemical and physical properties of all the elements and compounds in an orderlymanner.

    (b) the properties of elements and their compounds are predicted based on the position ofelements in the Periodic Table.

    (c) the relationship between the elements from different groups can be known.

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    44

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    8/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    C GROUP 18 ELEMENTS [Refer to Text Book, page 64]

    1. Group 18 elements consists of ., .., .., ,

    . and ..

    2. These elements are known as gases.

    3. Group 18 elements exist as monoatomic at room condition because Noble gases

    achived stable electron arrangement which is for helium and

    for other elements.

    4. Noble gases do not have to lose, gainorshare electrons.

    Physical Properties of Group 18 Elements

    Noble gases have very .. atomic sizes.

    They are . gases at room temperature and pressure.

    Noble gases have .. melting and boiling points and also .. densities.

    Noble gases are in water, conduct electricity and

    . conductors of heat.

    Going down Group 18 [Refer to Text Book, page 64]

    Element

    Relative

    atomicmass

    Protonnumber

    Atomic

    radius(nm)

    Melting

    point(oC)

    Boiling

    point(oC)

    Density(g dm-3)

    Helium, He 4 2

    Neon, Ne 20 10

    Argon, Ar 40 18

    Krypton, Kr 84 36

    Xenon, Xe 131 54

    Radon, Rn 222 86

    When going down Group 18 :

    The atomic size as the number of shells in the atom increases from Helium

    to Radon.

    The melting and boiling points is very low.

    because the atoms of Noble gases are attracted by weak force.

    Less energy is required to overcome it.

    However, the melting and boiling points . when going down Group 18.

    because the atomic size of each element down the group,

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    45

    Increase

    s

    Increase

    s

    Increase

    s

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    9/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    the forces of. between the atoms of each element become stronger

    thus more is required to the stronger forces of ..

    . during melting or boiling.

    The density of an element .. down the group because the atomic mass

    of each element is

    The Inert Property of Group 18 Elements

    All Noble gases are inert which means .. .

    Noble gases and the electron arrangement of their atoms.

    Noble gas Electron arrangement

    Helium 2

    Neon 2.8Argon 2.8.8

    Krypton 2.8.18.8

    Xenon 2.8.18.18.8

    Radon 2.8.18.32.18.8

    Helium has two valence electrons. This is called a . electron arrangement.

    Other Noble gases have eight valence electron called the .. electron arrangement.

    These electron arrangements are very stable.

    That is why Noble gases exist as monoatomicgases and are chemically unreactive;

    because they achived the stable octet/duplet electron arrangement.

    Uses of Group 18 Elements

    Noble gas Uses

    Helium, He

    Neon, Ne

    Argon, Ar

    Krypton, Kr

    Xenon, Xe

    Radon, Rn

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    46

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    10/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    D GROUP 1 ELEMENTS

    1. Write the name and symbols of elements in Group 1 (exceptHydrogen)

    2. Group 1 are also known as which react with water to form alkalinesolutions.

    3. Write the symbols in the boxes for all the elements in Group 1 in the Periodic Table ofElements :

    4. Write the proton number and electron arrangement for all elements in Group 1.

    ElementsProtonnumber

    Electronarrangement

    Density /g cm-3

    Boilingpoint /

    0

    CLi 3 0.534 1360

    Na 0.971 900

    K 0.862 777

    Rb 2.8.18.8.1 1.530 505

    Cs 2.8.18.18.8.1 1.973

    Fr 2.8.18.32.18.8.1

    All Group 1 elements have valence electron in their outermost occupiedshells.

    5. Physical Properties of Group 1 elements :

    metals.

    densities.

    melting points.

    silvery solid with . surface.

    good of heat and electricity.

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    47

    compared to other metals

    such as iron and copper.

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    11/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    Change in the physical properties going down the group :

    The atomic size because the number of shells increases.

    The density because the increasing in atomic mass is fasterthan the increasing in atomic volume/size.

    The melting and boiling points because when the atomic sizeincreases, the metal bond between the metal atoms becomes weaker.

    The hardness of the metal .

    6. Chemical Properties of Group 1 elements :

    (a) React with waterto produce alkaline metal hydroxide solutions [colourless

    solutions] and released gas.

    Metal* Observation

    Li

    Lithium moves .. on water surface with sound.

    The solution formed; turns ..litmus paper to...

    Na

    Sodium moves . on water surface with sound.

    The .. solution formed; turns .litmus paper to..

    K

    Potassium moves . on water surface with .sound.

    The . solution formed; turns .litmus paper to..

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    48

    water

    metal*

    Redlitmus paper

    turnsblueRedlitmus paper

    Reactionbecomes

    morevigorous

    React

    ivityin

    creases

    Metal G1 + H2O metal hydroxide + Hydrogen gas

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    12/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    Chemical equation :

    # Chemical equation

    2Li + 2H2O 2LiOH + H2

    Lithium Water Lithium Hydrogen gashydroxide

    Write the chemical equation for the sodium and potassium.

    ..

    (b) React with oxygen gas to produce metal oxides [white solids].

    Metal* Observations

    Li

    Lithium burns with a flame.

    A . / fume solid is produced.

    Na

    Sodium burns . with a .. flame.

    A .. solid is produced.

    K Potassium burns . with a flame.

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    49

    Gas jar

    Metal*

    Oxygen gas

    White fume

    Gas jar spoon

    Reactionbec

    omes

    morevigorous

    Metal G1 + O2 metal oxide

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    13/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    A solid is produced.

    Chemical equation :

    Example:

    + O2 2Na2O

    4K + O2

    (c) React with chlorine gas to produce metal . [white solids].

    Elements Observations

    Li

    Lithium burns with a .. flame.

    A . solid is produced.

    Na

    Sodium burns .. with a flame.A . solid is produced.

    K

    Potassium burns ... with a ...flame.A solid is produced.

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    50

    Gas jar

    Metal*

    Chlorine gas

    White fume

    Gas jar spoon

    Metal G1 + Cl2 metal chloride

    4Li + O2

    2Li2O

    Lithium Oksigen gas Lithium Oxide

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    14/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    Group 1 elements also react with bromine gas to form metal bromides.

    Complete the chemical equation following.

    2Li + Br2 2LiBr

    Na + Br2 ..

    K + Br2 ..

    7. Reactivity of elements in Group 1 :

    When going down Group 1,

    the proton number are ..

    the number of shells occupied with electrons are

    the atomic size of atoms are

    the single valence electron becomes away from the nucleus.

    the force of attraction between the nucleus and valence electron (nuclei attraction)

    becomes

    it is for the atom to donate the single valence

    electron to achieve the stable octet/duplet electron arrangement of the atom

    of Noble gases.

    Reactivity increases when going down the group!

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    51

    Alkali metals have one valence electron in their outermost occupied shells.Each of them reacts by donating one electron from its outermost occupiedshell to form an ion with a charge of +1, thus achieving the stable electron

    arrangement of the atom of noble gas.

    Example :

    Na Na+ + e K K+ + e2.8.1 2.8 2.8.8.1 2.8.8

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    15/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    Activity4 :-

    1. Table below shows the electron arrangements of element W, X and Y.Arrange the elements in ascendingorder of reactivity.

    Element Proton Number ElectronArrangement

    W 11 2.8.1

    X 3 2.1

    Y 19 2.8.8.1

    Answer: .

    [ Size of atom increases when the number of shells filled with electrons increases]Safety precautions in handling Group 1 elements

    Alkali metals are very reactive. Safety precautions must be taken when handling alkalimetals.

    The elements must be stored in paraffin oil in bottles Do not hold alkali metals with your bare hands Use forceps to take them Wear safety goggles

    Wear safety gloves Use a small piece of alkali metal when conducting experiments

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    52

    X

    a

    W

    b

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    16/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    E GROUP 17 ELEMENTS

    1. Write the symbol of elements in Group 17.

    Fluorine Chlorine Bromine Iodine Astatine

    2. Group 17 elements are known as ..

    3. Halogens exist as diatomic molecules.{ F2, Cl2, Br2, I2 }

    4. Halogens have .. valence electrons.

    5. All Group 17 elements are non-metals.

    6. Write the symbol in the boxes for all the element in Group 17 in thePeriodic Table of Elements :

    17

    7. Write the proton number and electron arrangement :

    Elements Proton number Electron

    arrangement

    F

    Cl

    Br 35 2.8.18.7

    I 53 2.8.18.18.7

    At 85 2.8.18.32.18.7

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    53

    F Cl Br I At

    Proton number : ....

    Number of protons :

    Number of electrons :

    Number of shells occupied with

    electrons : ...

    Atomic size :

    Molecular size : ..

    Going down the group :

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    17/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    8. Physical properties of elements in Group 17 :

    (i) Complete the table below :

    ElementSymbo

    lProtonNumber

    ElectronArrangemen

    t

    Meltingpoint /

    oC

    Boiling

    point /oC

    Physicalstate atroomTemp.

    Colour

    Flourine 9 -220 -188

    Chlorine 17 -101 -34

    Bromine 35 2.8.18.7 -7 59

    Iodine 53 2.8.18.18.7 114 184

    (ii) Physical state of halogens at room temperature, 25 oC :

    Fluorine and chlorine are ............... , bromine is a ..................... and iodine isa ...............

    (iii) The colour of the elements becomes .. going down the group.

    (iv) Halogen have melting and boiling points because their molecules

    are attracted to each other by . inter-molecular forces. (Van der Waals

    force : force of attraction between molecules).

    (v) When going down the group, the melting and boiling points increases /decreases.This is because :

    the molecular size ..

    Forces of attraction between molecules becomes

    Need . energy to overcome the forces of attraction betweenmolecules.

    the melting and boiling points ..

    9. Chemical Properties

    (a) React with waterto produce two acids.

    Example :

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    54

    Chlorine

    gas

    water

    In general :

    Br2 + H2O HBr + HOBr

    Halogen : F, Cl, Br, I

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    18/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    Cl2 + H2O +

    Chlorine gas Hydrochloric acidHypochlorus acid

    Br2 + H2O +

    I2 + H2O +

    (b) React with hot iron/ferum to produce iron(III) halides.

    Example :

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    55

    HX and HOX solutions are ...

    HOX solution exhibits property.

    Hydrobromic acid Hypobromus acid

    Hydroiodic acid Hypoiodus acid

    Potassium

    manganate(VII)

    Iron wool

    Heat

    Concentratedhydrochloric acid

    Combustion tube

    Soda lime

    To absorb excess

    Cl2

    gas that is

    poisonous so that

    it does not escape

    to the enviroment.

    To produce Cl2

    gas

    Bromine

    water

    water

    Heat

    Iodine

    (solid)

    water

    Heat

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    19/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    2Fe + 3Cl2 2FeCl3

    Iron(III) chloride

    Fe + Br2

    Iron(III) .....................

    Fe + I2

    Iron(III) .....................

    (c) Halogen reacts with sodium hydroxide, NaOH solution to produce

    , .. and water.

    Example :

    2KOH + Cl2 KCl + KOCl + H2O

    Potassium Sodiumchloride chlorate(I)

    KOH + Br2 + + H2O

    Potassium Potassiumbromide bromate(I)

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    56

    Chlorine

    gas

    Sodium hydroxide

    solution

    Solid

    iodine

    Heat

    Iron

    wool

    Heat

    Alkali

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    20/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    LiOH + I2 + + H2O

    Chemical properties of all elements are . because the number ofvalence electrons are the same and attain/achive the Noble gas arrangement in asimilar way.

    10. Reactivity of Group 17 elements :

    When going down Group 17,

    the proton number are

    the number of shells occupied with electrons are

    the atomic size of atoms are

    the outermost occupied shell of each halogen atoms becomes

    away from the nucleus.

    the nuclei attraction forces to attract one electron into the outermost occupied

    shell by the nucleus becomes

    it is for the atom to attract one electron to achieve stableoctet/duplet electron arrangement of the atom of Noble gas.

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    57

    Halogens have seven valence electrons in their outermost occupied shells.Each of them reacts by receiving one electron in its outermost occupied shell to forman ion with a charge of -1, orby sharinga pairofelectrons thus achieving the stableelectron arrangement of the atom of noble gas.

    Example :

    F + e F- Cl + e Cl-

    2.7 2.8 2.8.7 2.8.8

    Complete the electron arrangement for the atoms and molecule of flourine below :

    two fluorine atoms Fluorinemolecule ( F

    2)

    Exists as diatomicmolecules [ 2 atoms of elements sharinga pairof its valenceelectron ] to achive the stable octet electron arrangement.

    F F F F

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    21/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    The strength of halogen atom to attract electron decrease from Fluorine to

    Astatine [Electronegativity decreases]

    this causes the reactivity down the group.

    Activity 5 :-

    1

    Chlorine, bromine and iodine have . number ofvalence electrons.

    When halogens take part in chemical reactions, their atom always gain

    . electron to achieve . electron arrangement / a

    stable electron arrangement.

    2

    The explanation

    The atomic size . down the group.

    The distance of the outermost shell becomes from the nucleus.

    The force of attraction of the nucleus on the electrons of the outermost shell

    ..

    The tendency of an atom to receive .. electron to achieve an octet

    electron arrangement .

    3

    The explanation

    The atomicsize of flourine is . than chlorine.

    The between nucleus of fluorine atom and valence

    electrons are .

    Fluorine atom can electron easily.

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    58

    Chlorine, bromine and iodine have similar chemical properties.

    Do you know WHY???

    The reactivity of halogens decrease down the group.

    Do you know WHY???

    Why fluorine atom forms a negative ion more easily

    than chlorine?

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    22/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    Safety precautions in handling Group 17 elements

    1. The vapour of flourine, chlorine and bromine are

    2. The following precaution should be taken when handling halogen :

    a) Halogen gas and liquid should be handled inside a

    b) Wear safety when handling halogen fumes.

    c) Wear safety when handling halogen materials.

    Activity 6 :-

    1. Elements X, Y and Z are in the same group in the Periodic Table of Elements.

    Element X Y Z

    Proton number 9 17 35

    (a) What is the valence electron of the elements X, Y and Z?

    (b) Which group in the periodic table can you find the elements X, Y and Z?

    (c) Element Y can react with water.State two chemical properties of the solution produced?

    (d) Write an equation for the reaction between element Z and hot iron.

    2. (a) List all halogen elements from the top to the bottom of Group 17.

    .

    (b) Which are the most reactive and least reactive halogen?

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    59

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    23/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    Most reactive : , least reactive : .............

    3. Write the chemical equations for the following reaction :

    (a) Chlorine with water : ...

    (b) bromine with iron : ...

    (c) iodine with sodium hydroxide : ...

    4. Explain the changes to the reactivityof halogens when going down Group 17.

    The atomic size of halogen .. down the group.

    The distance of the outermost shell becomes from the

    nucleus.

    Therefore, the force of attraction by the nucleus on the electrons in the

    outermost shell becomes

    The tendency of an atom to . one electron to achieve an

    octet electron arrangement decrease.

    This causes the reactivity down the group.

    5. Explain the changes to the electronegativityof halogens when going down Group17.

    The atomic size of halogen .. down the group.

    The distance of the outermost shell becomes from thenucleus.

    Therefore, the force of attraction by the nucleus on the electrons in the

    outermost shell becomes

    The tendency of an atom to . one electron to achieve an

    octet electron arrangement decrease.

    This causes the electronegativity down the group.

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    60

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    24/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    F ELEMENTS IN A PERIOD

    Properties of elements in Period 3

    Complete the table below.

    Element of Period 3 Na Mg Al Si P S Cl Ar

    Proton number 11 12 13 14 15 16 17 18

    Electronarrangement

    2.8.1 2.8.8

    Valence electron[ Group ]

    1[ 1 ] [ ] [ ] [ ] [ ] [ ] [ ]

    [ ]

    Atomic size

    Physical state atroom temperature

    solid

    Electronegativity

    Electropositivity

    The trends of changes acrossPeriod 3 (from leftto right)

    1. The proton numberincreases by unit from one element tothe next element.

    2. All the atoms of the elements have shells occupied/filledwith electrons.

    3. The number ofvalence electrons in each atom increases from to..

    4. The atomic radius/size of atom of the elements ..

    This is due to increasing of nuclei attraction force on the electrons.

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    61

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    25/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    5. The electronegativity of elements

    This is also due to the ..of the nuclei attraction force on the

    in the outermost shell and the in atomic size.

    6. All the elements in Period 3 exist as .. except chlorine andargon which are

    ACID-BASE properties of oxides ofelements in Period 3.

    Na2O MgO Al2O3 SiO2 P4O10 SO2 Cl2O7

    (oxides) .. oxide (. oxides)

    Basic oxides reacts with acids to form . and ..

    Example :

    Na2O + 2HNO3 2NaNO3 + H2O

    Acidic oxides reacts with alkalis to form . and ..

    Example :

    SO2 + 2NaOH Na2SO3 + H2O

    Amphotericoxides can react with both acids and alkalis.

    Na & Mg are ., Al is ., Si, P, S & Cl are .

    The elements change from metals to metalloid and finally to non-metals across theperiod.

    Uses of semi-metals (metalloids) in Industry

    Semi-metals or metalloids are weakconductors of electricity. Semi-metals such assilicon and germanium are used as semiconductors.

    Semiconductors are used to make diodes and transistors that widely used in themaking of microchips for the manufacture of electrical and microelectronicequipments such as computers, mobile phones, televisions, digital cameras andvideo recorders.

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    62

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    26/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    SEMI-METALSe.g: silicon and germanium

    used to make

    . and .

    widely used in the making of ..

    for the manufacture of :

    Activity 7 :-

    1 Table below shows the symbol of element, proton number and atomic radius ofelements in Period 3.

    Element Na Mg Al Si P S Cl Ar

    Proton number 11 12 13 14 15 16 17 18

    Atomic radius 0.156 0.136 0.125 0.117 0.111 0.104 0.099 -

    Electronarrangement

    (a)Complete the electron arrangement in the above table.

    (b)When crossing the period from left to right, the atomic size decreases. Explain why.

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    63

    ..and ..

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    27/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    (c) Write the symbol of elements for metal, metalloid and non-metal.

    Metal Metalloid Non-metal

    1. .2. .

    3. .

    1. 1..

    2. 3. 4.

    (d) Table below shows the symbol of oxide compound when the elements in period 3 arereacted with oxygen.

    Na2O MgO Al2O3 P4O10 SO2

    Classify the oxides into basic oxide, acidic oxide and amphoteric oxide.

    Basic oxide Acidic oxide Amphotericoxide

    G TRANSITION ELEMENTS

    1. Elements from Group . to Group . in the Periodic Table.

    [ Between Group . to Group .]

    2. All transition elements are ., thus, these elements have thefollowing properties :

    solids with surfaces.

    ductile

    malleable

    high tensile strength

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    64

    . melting and boiling points

    .. densities

    good .. of heat andelectricit

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    28/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    3. Special Characteristics / Superior Properties ofTransition Elements

    (i) ..(ii) (iii) .

    Different Oxidation Numbers

    Transition elements can form ions with different oxidation numbers when formingcompounds.

    TransitionElement

    OxidationNumber

    Name of ion Ionicsymbol

    Example of compoundFormula Name

    Iron, Fe+2 Iron(II) ion Fe2+ FeCl2 Iron(II) chloride

    +3 Fe3+ Iron(III) chloride

    Copper, Cu+1 Copper(I) ion Cu2O

    +2 Cu2+ Copper(II) oxide

    Nickel, Ni+2 Ni(NO3)2

    +3 Ni3+ Ni(NO3)3

    Coloured Ions orCompounds

    The colours of some aqueous solutions of ions of transition elements :

    Name of Ionof transition element

    Formula of Ionof transition element

    Colourin aqueous solution

    Chromate ion

    Dichromate ion

    Manganate(VII) ion

    Iron(II) ion

    Iron(III) ion

    Copper(II) ion

    Cobalt(II) ion

    Manganese(II) ion

    Chromium(III) ion

    Nickel(II) ion

    Examples of someprecious stones and the transition elements present which givetheir distinctive colours :

    Precious Colour Transition Element

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    65

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    29/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    Stone present

    Ruby Red

    Sapphire Blue

    Emerald Green

    Amethyst Purple

    Act as Catalysts

    Transition elements or its compounds can act as catalysts in certain reactions.Catalysts are chemicals which can increase the rate of a reaction.

    Example :

    Industrial Process ProductTransition element used

    as catalyst

    Haber Process

    Contact Process

    Ostwald Process

    Activity 8 :-

    1 Figure 1 below shows part of the Periodic Table of Elements.

    H He

    O

    Mg Al

    FIGURE 1

    Based on Figure 1 above, answer the following questions :

    (a) What is the element represented by the symbol Fe?

    (b) In figure above, mark X in the boxes for all the transition element.

    (c) State one specific characteristic of transition element.

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    66

    Fe

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    30/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    (d) Write the electron arrangement for the Mg atom

    (e) Write the chemical equation for the reaction between aluminium and oxygen

    gas.

    (f) Based on the above informations, which gas is more suitable to be used inmeteorological balloons?Give one reason.

    2 Table 2 shows the proton numbers of element P, Q, R, S and T.

    Element Proton number Electron arrangement

    P 3

    Q 6

    R 9

    S 11

    T 17

    TABLE 2

    (a) Complete the electron arrangement for all elements above.

    (b) In which Group is element S located in the Periodic Table of Elements?

    ......

    (b) State two elements in Table 2 that shows the same chemicalproperties.Explain the answer.

    ...

    JPNT 2009 CHAPTER 4: PERIODIC TABLE OF ELEMENTS

    67

    Helium Gas

    light

    notreactive

    Hydrogen Gas

    light

    flammable colourless

    .

  • 8/4/2019 C4 TAHAP 2 NORAIDAH

    31/31

    4541 CHEMISTRY MODUL P3T (TAHAP 2)

    .

    (c) (i) Between elements P and S, which one is more reactive?Explain your answer.

    ..

    ..

    ..

    ..

    ..

    (d) Arrange the elements P, Q, R, S and T in order ofincreasing of atomic size.

    END OF CHAPTER 4

    68