cape physics module 3
TRANSCRIPT
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photoelectric effect
In the photoelectric effect, electrons are emitted from matter (metals and non-metallic
solids, liquids or gases) as a consequence of their absorption of energy
from electromagnetic radiation of very short wavelength, such
as visible or ultraviolet radiation. Electrons emitted in this manner may be referred to asphotoelectrons.
The energy supplied by the photon will be, E =hf. Where h is planck’s
constant and f is the frequency of the light (radiation). t therefore !eans
that the !a" #.E. gained by the liberated electrons will be equi$alent to hf.
%o #.E.!a" = hf.
The photons of a light beam have a characteristic energy proportional to the frequency
of the light. In the photoemission process, if an electron within some material absorbs
the energy of one photon and acquires more energy than the wor function (the electron
binding energy) of the material, it is e!ected. If the photon energy is too low, the electron
is unable to escape the material. Increasing the intensity of the light beam increases the
number of photons in the light beam, and thus increases the number of electrons
e"cited, but does not increase the energy that each electron possesses. The energy of
the emitted electrons does not depend on the intensity of the incoming light, but only on
http://en.wikipedia.org/wiki/Electronhttp://en.wikipedia.org/wiki/Liquidshttp://en.wikipedia.org/wiki/Gaseshttp://en.wikipedia.org/wiki/Electromagnetic_wavehttp://en.wikipedia.org/wiki/Wavelengthhttp://en.wikipedia.org/wiki/Visible_lighthttp://en.wikipedia.org/wiki/Ultraviolet_lighthttp://en.wikipedia.org/wiki/Radiationhttp://en.wikipedia.org/wiki/Photonhttp://en.wikipedia.org/wiki/Work_functionhttp://en.wikipedia.org/wiki/Liquidshttp://en.wikipedia.org/wiki/Gaseshttp://en.wikipedia.org/wiki/Electromagnetic_wavehttp://en.wikipedia.org/wiki/Wavelengthhttp://en.wikipedia.org/wiki/Visible_lighthttp://en.wikipedia.org/wiki/Ultraviolet_lighthttp://en.wikipedia.org/wiki/Radiationhttp://en.wikipedia.org/wiki/Photonhttp://en.wikipedia.org/wiki/Work_functionhttp://en.wikipedia.org/wiki/Electron
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the energy or frequency of the individual photons. It is an interaction between the
incident photon and the outermost electron.
Experimental observations of photoelectric emission
The theory of the photoelectric effect must e"plain the e"perimental observations of the
emission of electrons from an illuminated metal surface.
#or a given metal, there e"ists a certain minimum frequency of incident radiation below
which no photoelectrons are emitted. This frequency is called the threshold frequency.
Increasing the frequency of the incident beam, eeping the number of incident photons
fi"ed (this would result in a proportionate increase in energy) increases the ma"imum
inetic energy of the photoelectrons emitted. Thus the stopping voltage increases. The
number of electrons also changes because the probability that each photon results in an
emitted electron is a function of photon energy.
$bove the threshold frequency, the ma"imum inetic energy of the emitted
photoelectron depends on the frequency of the incident light, but is independent of theintensity of the incident light so long as the latter is not too high %&'
#or a given metal and frequency of incident radiation, the rate at which photoelectrons
are e!ected is directly proportional to the intensity of the incident light. Increase in
intensity of incident beam (eeping the frequency fi"ed) increases the magnitude of the
photoelectric current, though stopping voltage remains the same.
The time lag between the incidence of radiation and the emission of a photoelectron is
very small, less than *& second.
+athematical equation
+a". .E. hf / 0
1or function, 0 / is the minimum energy required to liberate an electron from the
surface of a metal. If no electrons are emitted the .E. , then
hf / 0
hf 0
f 02h , where f is the threshold frequency. Threshold frequency is the
minimum frequency required for photoemission.
&ro! the wa$e equation c = f' , where c is the speed of light , ' is the
wa$elnght.
%o c' = 02h
3 02hc , where 3 is the cut-off wavelength.
http://en.wikipedia.org/wiki/Photoelectric_effect#cite_note-Zhang1996-8http://en.wikipedia.org/wiki/Photoelectric_effect#cite_note-Zhang1996-8
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STOPPING POTENTIAL
The electrons with the !a"i!u! #E can be stopped fro! co!pleting their ourney across the photoelectric tube if there is a stopping potential set*upto i!pede their progress. The for!ula that relates the #E of these
photoelectrons to this stopping potential is Ema" e4stopping
where
4stopping is the stopping potential, and
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e is the magnitude of the charge of an electron, .5 " -& coulombs.
This formula is based on the fact that wor is done on charged particles when they
cross through an electric field. The wor done (q∆4) equals the change in each
electron6s E.
f all the electrons are stpped it !eans the !a". k.e. = +
%o +=hf - * e4stopping
es = hf -
s = hfe * -e
/y plotting a graph of stopping potential $s frequency then
• he represents the gradient
• -e represent the y*intercept
http://online.cctt.org/physicslab/content/phyapb/lessonnotes/electrostatics/lessonelectricpotential.asphttp://online.cctt.org/physicslab/content/phyapb/lessonnotes/electrostatics/lessonelectricpotential.asphttp://online.cctt.org/physicslab/content/phyapb/lessonnotes/electrostatics/lessonelectricpotential.asphttp://online.cctt.org/physicslab/content/phyapb/lessonnotes/electrostatics/lessonelectricpotential.asphttp://online.cctt.org/physicslab/content/phyapb/lessonnotes/electrostatics/lessonelectricpotential.asphttp://online.cctt.org/physicslab/content/phyapb/lessonnotes/electrostatics/lessonelectricpotential.asp
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&ro! the equation 0 +a". .E. hf / 0, the equation can be written in another
way
7 mv8 hf / 0 , where v is the velocity of the liberated electrons.
This graph indicates
The photoelectric e1ect has so!e curious properties that cannot be
e"plained by classical physics. t was found that the nu!ber of electrons
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released by a !etal was proportional to the a!ount of ultra$iolet light, while
the energy of the electrons depended on the frequency of the light. /elow a
threshold frequency, there are no electrons released at all, no !atter how
bright the light is, while abo$e the threshold frequency, there are always
electrons released, no !atter how di! the light is. This contradicted classical
physics because classical wa$e theory stated that either increased intensity
or increased frequency should pro$ide !ore energy in the sa!e way, but the
obser$ed e1ect showed that only increased frequency pro$ided the needed
energy to eect an electron fro! the !etal.
t was proposed that light could not only be wa$es, but could also co!e in
packets of energy, as photons. 2s a photon hit an electron, it would pro$ide it
with a certain a!ount of energy. f it was enough, the electron would be
kicked to the surface of the !etal and be obser$ed, but if it wasn3t enough,
the electron would fall back to its ato!. Therefore, photons with energy
below the threshold had no discernible e1ect and the nu!ber of photons
could only deter!ine how !any electrons were released, as only one photon
at a ti!e was likely to hit an electron.
X-RAY
4*rays are produced when rapidly !o$ing electrons that ha$e been
accelerated through a potential di1erence of order 5 k to 5 6 strikes
a !etal target.
Electrons fro! a hot ele!ent are accelerated onto a target anode.
When the electrons are suddenly decelerated on i!pact, so!e of the
kinetic energy is con$erted into E6 energy, as 4*rays.
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7ess than 5 8 of the energy supplied is con$erted into 4*radiation during this
process. The rest is con$erted into the internal energy of the target
Properties of X-rays
4*rays tra$el in straight lines.
4*rays cannot be de9ected by electric :eld or !agnetic :eld.
4*rays ha$e a high penetrating power.
;hotographic :l! is blackened by 4*rays.
&luorescent !aterials glow when 4*rays are directed at the!.
;hotoelectric e!ission can be produced by 4*rays.
oni
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The graph shows the following features.
2 continuous background of 4*radiation in which the intensity
$aries s!oothly with wa$elength. The background intensity
reaches a !a"i!u! $alue as the wa$elength increases, then the
intensity falls at greater wa$elengths.
6ini!u! wa$elength which depends on the tube $oltage. The
higher the $oltage the s!aller the $alue of the !ini!u!
wa$elength.
%harp peaks of intensity occur at wa$elengths una1ected by
change of tube $oltage.
Minimm !a"elengt# in t#e X-ray Spectra
When an electron hits the target its entire kinetic energy is con$erted
into a photon.
The work done on each electron when it is accelerated onto the anode
is eV.
>ence hf = eV and the !a"i!u! frequency
h
eV f =max
eV
hc=
minλ
$#aracteristic X-ray Spectra
?i1erent target !aterials gi$e di1erent wa$elengths for the peaks in
the 4*ray spectra.
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The peaks are due to electrons knock out inner*shell electrons fro!
target ato!s.
When these inner*shell $acancies are re:lled by free electrons, 4*ray
photons are e!itted.
The peaks for any target ele!ent de:ne its characteristic 4*ray
spectru!
%ses of X-rays
n !edicine
To diagnose illness and for treat!ent.
n industry
To locate cracks in !etals.
4*ray crystallography
To e"plore the structure of !aterials.
Attenuation of X-Rays By Matter
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9-rays are attenuated as they pass through matter. That is, the intensity of an 9-raybeam decreases the farther it penetrates into matter. :asically, each interaction of an 9-ray photon with an atom of the material removes an 9-ray from the beam, decreasing itsintensity.
The amount of decrease in intensity of the 9-ray beam depends upon two factors
• The depth of penetration ( x ) or thicness
• $ characteristic of the material called its ;absorption coefficient; ( A).
The intensity decreases e"ponentially with the distance traveled, or
I I e"p (/ Ax )
where I is the initial 9-ray beam intensity.
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Atomic spectral line
In physics, one thins of atomic spectral lines from two viewpoints.
$n emission line is formed when an electron maes a transition from a
particular discrete energy level E@ of an atom, to a lower energy level E5, emitting a
photon of a particular energy and wavelength. $ spectrum of many such photons will
show an emission spie at the wavelength associated with these photons.
$n absorption line is formed when an electron maes a transition from a
lower, E5, to a higher discrete energy state, E@, with a photon being absorbed in the
process. These absorbed photons generally come from bacground continuum
radiation and a spectrum will show a drop in the continuum radiation at thewavelength associated with the absorbed photons.
The two states must be bound states in which the electron is bound to the atom, so the
transition is sometimes referred to as a ;bound/bound; transition, as opposed to a
transition in which the electron is e!ected out of the atom completely (;bound/free;
transition) into acontinuum state, leaving an ioni@ed atom, and generating continuum
radiation.
$ photon with an energy equal to the difference E 2 − E 1 between the energy levels is
released or absorbed in the process. The frequency ν at which the spectral line occursis related to the photon energy by :ohr6s frequency
condition E 2 - E 1 = hf where h denotes Alanc6s constant.
Energy levels of Hydrogen
http://en.wikipedia.org/wiki/Physicshttp://en.wikipedia.org/wiki/Energy_levelhttp://en.wikipedia.org/wiki/Bound_statehttp://en.wikipedia.org/wiki/Continuous_spectrumhttp://en.wikipedia.org/wiki/Ionizationhttp://en.wikipedia.org/wiki/Photonhttp://en.wikipedia.org/wiki/Planck's_constanthttp://en.wikipedia.org/wiki/Physicshttp://en.wikipedia.org/wiki/Energy_levelhttp://en.wikipedia.org/wiki/Bound_statehttp://en.wikipedia.org/wiki/Continuous_spectrumhttp://en.wikipedia.org/wiki/Ionizationhttp://en.wikipedia.org/wiki/Photonhttp://en.wikipedia.org/wiki/Planck's_constant
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ave ! particle nature of matter
The theory was proposed by =ouis de :roglie in &8B in his AhC thesis.%'. The de
Broglie relations show that the wavelength is inversely proportional to
themomentum of a particle and is also called de Broglie "avelength. $lso
the frequency of matter waves, as deduced by de :roglie, is directly proportional to the
particle6s total energy, i.e. the sum of particle6s inetic energy and rest energy.
$t the end of the &th century, light was thought to consist of waves of electromagnetic
fields which propagated according to +a"wellDs equations, while matter was thought to
consist of locali@ed particles (ee history of wave and particle viewpoints ). This division
was challenged when, in his &F paper on the photoelectric effect, $lbert
Einstein postulated that light was emitted and absorbed as locali@ed pacets, or
GquantaH (now calledphotons). These quanta would have an energy
Ehf
$s a wave light shows interference and diffractive properties.
$s a particle it can be e"plained using the photoelectric effect.
Cerivation for Ce :roglie Equation
?e /roglie, in his research, decided to look at Einstein’s research on
photons or particles of light and how it was possible for light to be
considered both a wa$e and a particle. 7et us look at how there is a
relationship between the!.
We get fro! Einstein (and ;lanck) two equations for energyA
E = h f (photoelectric e1ect) B E = !c@ (Einstein’s %pecial
Celati$ity)
Dow let us oin the two equationsA
E = h f = ! c@
http://en.wikipedia.org/wiki/Louis_de_Brogliehttp://en.wikipedia.org/wiki/Matter_wave#cite_note-0http://en.wikipedia.org/wiki/Wavelengthhttp://en.wikipedia.org/wiki/Inversely_proportionalhttp://en.wikipedia.org/wiki/Momentumhttp://en.wikipedia.org/wiki/Frequencyhttp://en.wikipedia.org/wiki/Total_energyhttp://en.wikipedia.org/wiki/Kinetic_energyhttp://en.wikipedia.org/wiki/Rest_energyhttp://en.wikipedia.org/wiki/Maxwell%E2%80%99s_equationshttp://en.wikipedia.org/wiki/Wave-particle_duality#Brief_history_of_wave_and_particle_viewpointshttp://en.wikipedia.org/wiki/Photoelectric_effecthttp://en.wikipedia.org/wiki/Albert_Einsteinhttp://en.wikipedia.org/wiki/Albert_Einsteinhttp://en.wikipedia.org/wiki/Photonshttp://en.wikipedia.org/wiki/Louis_de_Brogliehttp://en.wikipedia.org/wiki/Matter_wave#cite_note-0http://en.wikipedia.org/wiki/Wavelengthhttp://en.wikipedia.org/wiki/Inversely_proportionalhttp://en.wikipedia.org/wiki/Momentumhttp://en.wikipedia.org/wiki/Frequencyhttp://en.wikipedia.org/wiki/Total_energyhttp://en.wikipedia.org/wiki/Kinetic_energyhttp://en.wikipedia.org/wiki/Rest_energyhttp://en.wikipedia.org/wiki/Maxwell%E2%80%99s_equationshttp://en.wikipedia.org/wiki/Wave-particle_duality#Brief_history_of_wave_and_particle_viewpointshttp://en.wikipedia.org/wiki/Photoelectric_effecthttp://en.wikipedia.org/wiki/Albert_Einsteinhttp://en.wikipedia.org/wiki/Albert_Einsteinhttp://en.wikipedia.org/wiki/Photons
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&ro! there we getA
h f = p c (where p = !c, for the !o!entu! of a photon)
h p = c f
%ubstituting what we know for wa$elengths (' = $ f, or in this
case c f )A
h !c = '
hp ='
?e /roglie saw that this works perfectly for light wa$es, but does
it work for particles other than photons
ELE$TRON &I''RA$TION
• &e (roglie)s !a"es are not EM !a"es
– *e calle+ t#em ,pilot or ,material !a"es
– λB +epen+s on t#e momentm an+ not on p#ysical si.e of
t#e particle
• 'or a non-relati"istic free particle/
– Momentum is p = mv 0 #ere v is t#e spee+ of t#e particle
–
Em
h
mv
h
p
h B
2===λ
'or free particle total energy0 E0 is 1inetic
energy
22
22 mv
m
p K E ===
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ATOMI$ STR%$T%RE
T#omson Mo+el
>e proposed a !odel of the ato! that is so!eti!es called the F;lu!
;uddingG !odel.
2to!s were !ade fro! a positi$ely charged substance with negati$ely
charged electrons scattered about, like raisins in a pudding.
Rt#erfor+)s Gol+ 'oil E2periment
Cutherford’s e"peri!ent n$ol$ed :ring a strea! of tiny positi$ely
charged particles at a thin sheet of gold foil (@+++ ato!s thick)
6ost of the positi$ely charged FbulletsG passed right through the
gold ato!s in the sheet of gold foil without changing course at
all.
%o!e of the positi$ely charged Fbullets,G howe$er, did bounce
away fro! the gold sheet as if they had hit so!ething solid. >e
knew that positi$e charges repel positi$e charges.
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This could only !ean that the gold ato!s in the sheet were !ostlyopen space. 2to!s were not a pudding :lled with a positi$ely charged
!aterial.
Cutherford concluded that an ato! had a s!all, dense, positi$ely
charged center that repelled his positi$ely charged Fbullets.G
>e called the center of the ato! the FnucleusG
The nucleus is tiny co!pared to the ato! as a whole.
Cutherford reasoned that all of an ato!’s positi$ely charged particles
were contained in the nucleus. The negati$ely charged particles were
scattered outside the nucleus around the ato!’s edge
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(o#r Mo+el
2ccording to /ohr’s ato!ic !odel, electrons !o$e in de:nite orbits
around the nucleus, !uch like planets circle the sun. These orbits, or energy
le$els, are located at certain distances fro! the nucleus
&isproof of t#e P++ing
• Cutherford calculated fro! the results **5H55
• To re9ect alpha the I$e charge (and !ost of the !ass) has to be in a
$ery s!all dia!eter
• 2bout 5+*5J ! co!pared to 5+*5+ ! for the dia!eter of the ato!
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Solar System Mo+el
• Positi"ely c#arge+ ncles at centre
• Negati"ely c#arge+ electrons in or3it
• Pro3lem 4
– Or3iting electrons are accelerating 4
– 5ill gi"e o6 energy 4
– 5ill spiral in to centre
• Mo+el not sta3le
S3atomic Particles
Particle Sym3ol $#arge Relati"e
Mass
Electron e- 7- 8
Proton p9 9 7
Netron n 8 7
Atomic Sym3ols
Show the mass nm3er an+ atomic nm3er
Gi"e t#e sym3ol of t#e element
mass nm3er
:; Na so+im-:;
atomic nm3er 77
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Nm3er of Electrons
An atom is netral
T#e net c#arge is .ero
Nm3er of protons < Nm3er of electrons
Atomic nm3er < Nm3er of electrons
Mass Nm3er * Counts the number of protons and neutrons in
an atom
Isotopes Atoms !it# t#e same nm3er of protons0 3t +i6erent
nm3ers of netrons= Atoms of t#e same element >same atomic nm3er? !it#
+i6erent mass nm3ers Isotopes of c#lorine
;@$l ;$l7 7
c#lorine - ;@ c#lorine 4 ;
E2ample of an A"erage Atomic Mass
$l-;@ is a3ot @=@ B an+ $l-; a3ot :C=@B of natral
c#lorine=;@ 2 @=@ < :D=C
788;@=@
; 2 :C=@ < =8788
Milli1an)s oil +rop e2periment=
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6illikan deter!ined the sie showed that there was a s!allest Kunit’ of charge or that charge
is Kquantised’.
>e did this by !easuring the charge on nu!erous !icroscopic
charged oil drops.
2ll the charges were found to co!e in !ultiples of the basic Kunit’A
@e, Le or De where D is any whole nu!ber.
The charge of the electron e= 5.MN5+*5H is the s!allest a!ount
of charge detected.
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Nclear P#ysics
Ra+iationsA
5) a, b*, g are all e!itted0
@) protons and neutrons are DOT e!itted, e"cept in the case of !ass
nu!bers J and H0
L) alphas are e!itted only for !ass nu!bers greater than @+H, e"cept in the
case of !ass nu!ber P.
Alp#a > ? +ecay
e2ample/ :%:;F 8T#:;C 9 :aC 9
(eta mins >3-? +ecay
e2ample/ D$7C N7C 9 -738
$#arge an+ mass nm3ers are conser"e+
General RlesA
5) a e!itted to reduce !ass, only e!itted if !ass nu!ber is abo$e @+H
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@) b* e!itted to change neutron into proton, happens when there are too
!any neutrons
L) g e!itted to conser$e energy in reaction, !ay acco!pany a or b.
Alp#a &ecay
(eta &ecay
Gamma &ecay
Qa!!a rays are not charged particles like a and b particles.
Qa!!a rays are electro!agnetic radiation with high frequency.
When ato!s decay by e!itting a or b particles to for! a new ato!, the
nuclei of the new ato! for!ed !ay still ha$e too !uch energy to be
co!pletely stable.
This e"cess energy is e!itted as ga!!a rays (ga!!a ray photons ha$e
energies of R 5 " 5+*5@ S).
Mass &efect H (in+ing Energy
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/y +enition, !ass of M5@ is 5@.+++++ a!u.
The !ass of a proton (plus electron) is 7=88F: a!u. (The !ass of a
proton by itself is 5.++U@P a!u, and the !ass of an electron is +.+++JJ
a!u.)
The !ass of a netron is 7=88FDD@ am.
Dote that DJmproton9e 9 DJmnetron K m$-7:
T#e missing mass !as con"erte+ into energy >E7=88F: am? 9 D>7=88FDD@ am? - 7:=88888 am
< =8 am
(E < mJc: <
>8=8 am?J>7=DD278-:1gam?J>;278Fms?:
< 7=CF278-77 J>7 e7=D278-7 ? < :=; Me
'or $ar3on-7: !e #a"e/
(E < &mJc:
< :=; Me
If !e consi+er t#e 3in+ing energy per ncleon0 !e #a"e for car3on-
7:/
(Encleon < :=; Me 7: < =8 Mencleon
T#e largest (Encleon #appens for t#e sta3le isotopes of iron
>a3ot F=F Mencleon?=
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'ission an+ fsion
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Rate of +ecay
&ro! e"peri!ent, we :nd that the a!ount of decay of a radioacti$e !aterial
depends only on two thingsA the a!ount of radioacti$e !aterial and the
type of radioacti$e !aterial (the particular isotope).
The rate of decay does DOT depend on te!perature, pressure, che!ical
co!position, etc.
6athe!atically, then, we ha$eA
dDdt = *'ND
where ' is a constant that depends on the particular isotope, D is the
nu!ber of radioacti$e isotopes present, and the !inus sign co!es fro! the
fact that dDdt is ?ECE2%DQ rather than growing.
We can sol$e this di1erential equation for D(t)A dDdt = *'D , or dDD =
*'dt , or log (DDo) = *' t , or N>t? < No e-Qt .
&urther, if we de:ne acti$ity, 2, as
A < -+N+t then A < QD = 'Doe*lt = Aoe
-Qt 0
which !eans that t#e acti"ity +ecreases e2ponentially !it# time also.
*alf Life
N>t? < No e-lt The nu!ber of radioacti$e ato!s does decrease with ti!e.
/ut is there a +enite time in !#ic# t#e nm3er +ecreases 3y #alf ,
regardless of what the beginning nu!ber is VE%A
D(T=half life) = Do@ = Doe*'T , or 5@ = e*'T
or *'T = ln(5@) = ln(5) ln(@) = + * ln(@), or T>#alf life? < ln>:? Q .
Ce$iewA N>t? < No e-Qt
A < lD = Aoe-Qt
T>#alf life? < ln>:? Q .
We can n+ T(half life) if we can wait for D (or 2) to decrease by half.
We can n+ l by !easuring D and 2.
f we know either l or T(half life), we can :nd the other.
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Log grap#
E2ample of carbon datingA
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The present day ratio of *5 to *5@ in the at!osphere is 7=;278-7: . The
half*life of *5 is @0;8 years. What is the acti$ity of a 5 g! sa!ple of
carbon fro! a li$ing plant
A = 'D = Xln(@)JUL+ yearsYNXM"5+@L ato!s!ole N 5!ole5@ gra!s N 5
gra!YNX5.L"5+*5@ Y = U.PM"5+Myr = .@Hsec = 7@=8min
Thus, for one gra! of carbon, 2o = 5J.+!in .
f a 5 gra! carbon sa!ple fro! a dead plant has an acti$ity of H.+!in, then
usingA
A < Aoe-Qt ,
we ha$e H.+!in = 5J.+!in N e*(ln@JUL+yrs)t , or *(ln@JUL+ yrs)Nt = ln(H5J) ,
or
t = JUL+ years N ln(5JH) ln(@) = C0:88 years