carbon dioxide capturing and storage

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    CARBON DIOXIDE

    CAPTURING AND STORAGE

    K.RATNAKARARAO08A51A0329

    Mechanical Engineering

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    INTRODUCTION

    Co2 is a greenhouse gas occurs naturally in the atmosphere

    Human activities are increasing the concentration of co2 in theatmosphere

    Currently 3000 Million Metric tons of co2 is emitted per year dueto human activities

    This increases the natural greenhouse effect and there by increasesthe Earths atmospheric temperature

    This leads to a change in earths climate

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    Increase in concentration of co2 in past

    200 years

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    Power plants with and with out CCS

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    Carbon Dioxide Capturing And

    Storage

    [CCS]The process involves three main steps Capturing of CO2

    Transportation of CO2

    Storing the CO2 under ground

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    The three main components of CCS

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    Sources of CO2 emissions suitable for

    Capturing and Storage

    The size of the emission source,

    Whether it is stationary or mobile,

    How near it is to potential storage sites, and

    How concentrated its CO2

    emissions are.

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    Worldwide large stationary CO2 sources with

    emissions of more than 0.1 mtco2 per year.

    Process Number of sources Emissions (MtCO2 yr-1)

    Fossil fuels Power 4,942 10,539

    Cement production 1,175 932

    Refineries 638 798

    Iron and steel industry 269 646

    Petrochemical industry 470 379

    Oil and gas processing N/A 50

    Other sources 90 33Biomass

    Bioethanol and

    bioenergy

    303 91

    Total 7,887 13,466

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    CO2 CAPTURE

    The purpose of CO2 capture is to produce a concentrated

    stream of CO2 at high pressure that can readily be transported

    to a storage site.

    Currently, CO2

    is typically removed to purify other industrial

    gas streams. Removal has been used for storage purposes in

    only a few cases; in most cases, the CO2 is emitted to the

    atmosphere .

    Capture processes also have been used to obtain commercially

    useful amounts of CO2 from flue gas streams generated by thecombustion of coal or natural gas.

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    CO2 CAPTURE SYSTEMS USED IN

    POWER PLANTS

    Post combustion system

    Pre-combustion system

    Oxyfuel combustion system

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    Post-Combustion Systems

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    Pre-Combustion Systems

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    Oxyfuel Combustion Systems

    This system use oxygen instead of air for combustion

    of the primary fuel to produce a flue gas that is

    mainly water vapour and CO2. This results in a flue

    gas with high CO2 concentrations (greater than 80%by volume).

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    CO2 TRANSPORTATIONThe most common and economical method for

    CO2 transportation is using pipe lines.The first long-distance CO2 pipeline came into

    operation in the early 1970s. In the United States,

    over 2,500 km of pipeline transports more than 40MtCO2 per year from natural and anthropogenic

    sources, and it is mainly used for EOR.

    In some situations or locations, transport of CO2by ship may be economically more attractive,

    particularly when the CO2 has to be moved over

    large distances or overseas.

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    CO2 STORAGE (SEQUESTRATION)

    Geological Storage

    Ocean Storage

    Mineral Storage

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    GEOLOGICAL STORAGE

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    OCEAN STORAGE

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    MINERAL STORAGEEarthen Oxide Percent of Crust Carbonate Enthalpy change

    (kJ/mol)

    SiO2 59.71

    Al2O3 15.41

    CaO 4.90 CaCO3 -179

    MgO 4.36 MgCO3 -117

    Na2O 3.55 Na2CO3

    FeO 3.52 FeCO3

    K2O 2.80 K2CO3

    Fe2O3 2.63 FeCO3

    21.76 All Carbonates

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    RISK OF LEAKAGE

    Global risks

    Local risks

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    COST OF CO2 CAPTURE AND

    STOREGE OPERATIONSNatural gas

    combined cycle

    Pulverized coal Integrated

    gasification

    combined cycle

    Without capture

    (reference plant)

    0.03 - 0.05 0.04 - 0.05 0.04 - 0.06

    With capture and

    geological storage

    0.04 - 0.08 0.06 - 0.10 0.06 - 0.09

    With capture and

    Enhanced oil

    recovery

    0.04 - 0.07 0.05 - 0.08 0.04 - 0.08

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    REFERENCES

    IEA Greenhouse Gas R&D Programme, Abatement of Methane

    Emissions, June1998, ISBN 1 898 373 16 7

    IEA Greenhouse Gas R&D Programme, The Reduction of

    Greenhouse Gas Emissions from the Oil Refining and Petrochemical

    Industry, report PH3/8, June 1999 Herzog H, Eliasson B and Kaarstad O, Capturing Greenhouse

    Gases, Scientific American, Feb. 2000, 54-61

    www.ipcc.ch

    www.Greenfacts.org www.ieagreen.org.uk

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    THANK YOU