cau hoi tong on truoc khi ra quan 2015

8/19/2019 Cau Hoi Tong on Truoc Khi Ra Quan 2015

1/11

TỔNG ÔN LÍ THUYẾT HỮU CƠ- GV : LÊ THỊ TUYỀN-0909 836583Câu hỏ T!" #$

%&C'() *h+, *() .u/* :.Ankan CnH2n+2

2 2ankan H O COn n n= −

1.AnkenCnH2n

3.Ankadien CnH2n -22.Ankin CnH2n -2

2 2ankin CO H On n n= −

5.Ankylbenzen CnH2n -66.Ankanol ( ancol) CnH2n+2O

2 2ancol H O COn n n= −

2 2O COn 1, 5n=

2

2

CO

ancol H O

mm m

11= −

.Ankanal CnH2nO8.axit Ankanoic CnH2nO29.Ete no !"n c#$c m%c# #& CnH2nO20.C#'t bo ( COO)*C*H5&Cabo#idat Cn(H2O)m1.Amin no !"n c#$c m%c# #& CnH2n+*

2 2H O CO

a min

n nn

1,5

−

=

3.Amin !"n CxHy 2& Amin CxHy t5. Aminoaxit (H2)x(COOH)y6. Aminoaxit no m%c# #& 1 n#m axit ,1n#m amin

CnH2n+1O2 2 2H O CO

a minoaxit

n nn

.,5

−

=

%% 4() hâ( :&T() 7 #( ;* =?() @ ,AB h,hD* ,h+B CEHFC#*

/ 0 ( 2x + 2 y-t)

8& I J() hâ( BE* (K JM( O,h hPC(H1(1

2 n-*

9& I J() hâ( Q7*Q (K JM( O,h hPC(H1(1

2 n-2

10& I J() hâ( B( (KJM( O,h hPC(H1( R 3 N

2 n-1

1& I *! Q7*Q *OK SP )#EQ!K# => ( BE* SK n2

.(n+ 1)11& I Q*Q *OK SP ( B(,K# #> n.(n+ 1)13&I Q** J() hâ( *OK SP (B(KBE*

n 3

12 I *! *Q*!BW( Q** J() hâ( *OK*h>(h *X E B(K BE* #> :

xn

15&4() hâ( ,AB )#u,KK #> : 4ctozo16&4() hâ( ,AB 7B,,B!KK #> : antozo

7a8e o9


2/11

TỔNG ÔN LÍ THUYẾT HỮU CƠ- GV : LÊ THỊ TUYỀN-0909 8365831&ChD* , J() hâ( hZ(h h[, : J\u](- C #( ;* J'- C < ( J' @ h" #( ;* 1 (h

()uF( *^ h/, (hBu

C C

H

CH3H3C

H

cis-:5ten-2

C C

CH3

HH3C

H

trans-:5ten-2

18&I J() hâ( O,h hP ,AB C1H6 2 !;n8 CH*CH2OH ? CH*-O-CH*19&I J() hâ( O,h hP ,AB C3H8 * !CH*CH2CH2OH ? CH*-CHOH-CH* ? CH*-O-CH2 CH*

30&I J() hâ( O,h hP ,AB C3H6 @ ! C2H5CHO ? CH*-CO-CH* ? CH20CH-CH2OHCH*-O-CH0CH23&I J() hâ( O,h hP ,AB C1H21 * !< >CH*COOH ? HCOOCH* ? OH-CH2CHO31&I J() hâ( , =?() SQ(Q( ,ABC8H0

@ !;n8 etylbenzen ? (o,m, H2 -CH2 COOCH* 1 mi > CH20CH-COOH@

%%% T!O() *h/ _T`(h ,hD* =a* #b39&ChD* P *!O() *h/ h` < P J *hc$() @ -Ankan , anken , ankadien , ankin ( tD 1C -@C )

- HCHO ? CH*CHO-Amin ( tD 1C -*C)

20&ChD* P *!O() *h/ #ỏ()< P J *hc$() @ : -Ankan , anken , ankadien , ankin ( tD 5C )-:enzen , tolen , tien-Ancol ? etilen8lycol , 8lixeol , axeton-Axit COOH-Ete , d t#Fc Gt-Anilin

2&ChD* P *!O() *h/ !d( < P J *hc$() @ : - 7#enol- !In8 Gt- Jlcozo , 9ctozo , accaozo , mantozo , tin# bIt , xenlloz-Aminoaxit-7olime

21& C/, ,hD* h'() *B( *!K() (ce, *hc$())f :

- ankan , anken ,ankadien , ankin , benzen , ankylbenzen , tie

23& C/, ,hD* h'() *B( *!K() (ce, *OK ;**AB *hc$() )f

-7#enol ( kKt tin# k#Ln8 mB )-2,@,6- tibom (kKt tMa mB !P 8%c# )

22&ChD* , #( ;* h!K Axit cacboxylic ?


3/11

TỔNG ÔN LÍ THUYẾT HỮU CƠ- GV : LÊ THỊ TUYỀN-0909 836583%V gh"( +() hB h[, :25&Nh() ,hD* h"( +() =e NB CHO , HCOOH , HCOO ,HCOOH@ , 8lcoz" , 9ctoz" , mantoz" .1 n#m CHO t%o 2A8 ? HCHO t%o @A8

50&Nh() ,hD* , h"( +() =e u() j,hl)N3m NH3 , ;* *AB >u =>() (hO*

CHCH ? -CCH

5&Nh() ,hD* , h"( +() =eCu(h u (ce,

COOH B cTc axit L c"

51&Nh() ,hD* , h"( +() =eCu(h u() j,h

h+, J() >u EB(h #B

CTc c#'t c n#iW n#m OH kK cGn > n#X etilen 8lycol ?8lixeol , 8lcoz" ?4ctoz" ? antoz" ? Uaccaoz" .

53&Nh() ,hD* , h"( +() =eCu(h;* *AB , >u Jỏ )O,h Cu1 #>

CTc c#'t c n#m CHO > CHO , HCOOH , HCOO ,HCOOH@ , 8lcoz" , 9ctoz" , mantoz" .1 n#m CHO t%o 1C2O ? HCHO t%o 2C2O

52& Nh() ,hD* , h"( +() u() j,h(ce, S!' : #> D* >u u() j,h(ce, S!'

-CTc c#'t c liYn kKt (!Li #ay liYn kKt ba) >Anken , ankadien , ankin , tien ,CH20CH-CH2OH ? CH20CH-COOH V- xiclo-Hay ]n8 k#Ln8 bWn > ca D* >u u() j,h *hu, *`P (h]* Jn *hc$()

-anken , ankin , ankadien , tien

61& C/, ,hD* h"( +() =e u() j,h -ankylbenzen V.n#X tolen

7a8e 3 o9


4/11

TỔNG ÔN LÍ THUYẾT HỮU CƠ- GV : LÊ THỊ TUYỀN-0909 836583ip(2 #> D* >u u() j,h *hu, *`h Ju( (()V& quF #ua* h"( +() :63&I"( hr ,h`(h ,AB h"( +() *h;hB#K)Q( < J: B7@

-Q#K #alo8en Bo cacbon bGc cao #"n

62&I"( hr ,h`(h ,AB h"( +() *h; ,ABB(F#SQ(Q( B(#( hQ(K# < *h; =>K=?() SQ(Q( @

-Q#K #alo8en Bo Z t^ O #ay 7

65&I"( hr ,h`(h ,AB h"( +() *h; ,AB(*!KSQ(Q( BE*SQ(K, < *h; =>K =?()SQ(Q(

-Q#K -O2 Bo Z t^ m

66& I"( hr ,h`(h ,AB h"( +() ,n()Hs =>K B(Q( SD* J _CtC-

-\ cIn8 Bo C cMa ni !Li c bGc cacbon cao #"n

6& I"( hr ,h`(h ,AB h"( +() */,hHs :

-\ tTc# c_n8 [i H cMa cacbon c bGc cao #"n

68&l(,K# h"( +() =e Cu Ju( (() *OK7"( hâ : -l(Qh* -sQ*K(

-ih'() h"( +() Cu

-`B ancol bGc > CH2OH-`B ancol bGc > CHOH

-`B ancol bGc > ( )*COHV% 4\u ]( h"( +() :69& l(( R H1 < gmgSC3@ 7"( hr #> -anken0& l(( h"( +() =e u() j,hl)N3mNH3 #> :

-Ank-1-in

& Th; hB#K)Q( =>K =?() SQ(Q( J\u ](h"( +() #> :

-\c tTc bIt Nt !n nn8

1& Th; hB#K)Q( =>K (h/(h ,ABB(F#SQ(Q( J\u ]( h"( +() #> :

-n# Tn8 k#Kc# tTn

3& 4u( (() l(B(K# =e H1I2 Jf,00C *hu Jc, 7"( hr #>

-anken mol ancol 0 mol anken 0 mol nX[c

2& 4u( (() l(B(K# =e H1I2 Jf,200C *hu Jc, 7"( hr #> -ete mol ancol 0 2 n ete 02H O2n

/#i lXn8 ancol 0 m ete + m nX[cV%% T( ,/, #KO h"( +() ,( (he :5& gh"( +() ,n() H1 (h l)

8i lB (h hâ(*^ #e(


5/11

TỔNG ÔN LÍ THUYẾT HỮU CƠ- GV : LÊ THỊ TUYỀN-0909 836583- Aminoaxit (H2)x(COOH)y x f y-i cMa axit m%n# baz yK > H@Cl , CH* H*Cl ? Al2(UO@)*?4eCl*V

83&ChD* #> .ux *` hB EB(h hBFhQ(K#h*B#Q( hB h()

-CTc baz kiWm > aOH , /OH , Ca(OH)2 , :a(OH)2-Amin bo > CH* H2 ? C2H5 H2..-AmLniac > H*-Aminoaxit (H2)x(COOH)y x g yi cMa axit yK baz m%n#

CH*COOa ? H2 CH2COOa ? a2CO* , V82&ChD* h'() #> .ux *` J >u : -Q^n# ax^t 't yK > 7#enol V

-Q^n# baz 't yK > Anilin V-Aminoaxit > (H2)x(COOH)y x 0 y-i cMa axit m%n# baz m%n# > aCl , / 2UO@? :a(O*)2

85&ChD* #cy() *`(h - Aminoaxit- i amLni COOH@ ? C6H5OH@ (H@)2CO*

-i Hidocacbonnat*

HCO−

? HU- ,*

HUO−

-Oxit > Al2O* , C 2O* , hnO , :eO

-Hidoxit > Al(OH)* , C(OH)* , hn(OH)2 , :e(OH)2%s h/ (] :

86& H ,hD* hu ,M JM( ,h+, Qon8 H2 - CH2- COOH ,

89& l(,K# : lB #< c#'t #j c" c n#m OH liYn kKt [i n8yYn t cacbonno^ d > CH*OH ? CH20CH-CH2OH ? C6H5CH2OH

90& l(,K# *hM : lB #< c#'t #j c" c n#m OH , c ]n8 benzen , n#m OHk#Ln8 8Nn tFc tiK< Bo ]n8 benzen^ d > C6H5CH2OH

9& ka, ,AB B(,K# : :Gc > -CH2-OH:Gc > -CHOH-:Gc > ()*COH

91&ghQ(K# : lB #< c#'t c n#m OH liYn kKt tFc tiK< [i n8yYn t cacbocMa ]n8 benzen

^ d > C6H5-OH93& l(Qh* : lB #< c#'t #j c" c n#m CHO liYn kKt [i n8yYn t cacbo

#ay n8yYn t #ido >^ d > HCHO ? CH20CH-CHO ? C6H5CHO

92& lE* ,B,SKEF#, : lB #< c#'t #j c" c n#m COOH liYn kKt [i n8yYn tcacbon #ay n8yYn t #ido >^ d > HCOOH ? CH20CH-COOH ?C6H5COOH

95-z7*Q /#i t#ay t#K n#m OH cMa n#m cacboxyl cMa axit cacboxylic bn8 n#m O t#p !Xc ete^ d > HCOOCH* ? CH20CH-COOC2H5 ?C6H5COOCH0CH2

96&L* : li


6/11

TỔNG ÔN LÍ THUYẾT HỮU CƠ- GV : LÊ THỊ TUYỀN-0909 836583ton8 nX[c , tan ton8 cTc dn8 mLi k#Ln8 cFc li


7/11

TỔNG ÔN LÍ THUYẾT HỮU CƠ- GV : LÊ THỊ TUYỀN-0909 836583n#m CH2 n#Xn8 c t^n# c#'t #a #c tX"n8 tF n#a lB n#jn8c#'t !;n8 !n8 , c#n8 #< t#Bn# dy !;n8 !n8^ d ankan > CH@ ? C2H6 , C*HqV.

s :C/, ,âu hỏ S> l(,K# ,( (he :2& l(,K# , H )d( =>K C , #( ;* J'h'() S\(

CH20CHOH k#Ln8 bWn → CH*CHOCH20COH-CH* k#Ln8 bWn→ CH*-CO-CH*

5& l(,K# , (h\u (h H ,o() )d(=>K ()uF( *^ ,B,SK( *hZ h'() S\(

CH*-CH(OH)2 k#Ln8 bWn → CH*CHO + H2OCH*-C(OH)2 CH* k#Ln8 bWn→ CH*-CO-CH*CH*-CH(OH)* k#Ln8 bWn → CH*COOH + H2O

6&l(,K# Ju( =e H1I2 Jf, P 00C ,h}*hu Jc, Q*Q

`B ancol metylic

& CH3-CHH-CH1-CH3 < Su*-1-Q(@ Ju(=e H1I2 Jf, P 00C *hu Jc, SBK(hu B(Q( ~

Hn #< * anken ( k{ cR !;n8 B(Qh* ,( (he :8& K# B(Qh* JM( ,h+, *!/() SO, *huJc, 2 K# l) #> B(Qh*

HCHO

9& K# B(Qh* *!/() SO, *hu Jc, 2

K# l) #> B(Qh*

HCHO #ay (CHO)2

s%%C/, ,âu hỏ S> BE* ,B,SKEF#, ,( (he :10& lE* ,B,SKEF#, JM( ,h+, , h"( +()*!/() SO, #>

HCOOH

s%%% : C/, ,âu hỏ z7*Q :1&V(F# BEQ*B* Jc, J\u ,h; *X :

CH*COOH + CHCH

, o xt t

CH*COO-CH0CH211& ghQ(F# BEQ*B* Jc, J\u ,h; *X :

(CH*CO)2O + C6H5OH

,o

t H +

CH*COOC6H5 +An#idic axetic CH*COOH

13&C/, Q7*Q *hc$() Jc, J\u ,h; *X : 7#Rn $n8 ete #a >!n #;i lX ancol B axit #j c" c xc tTc

H2UO@ !|c COOH + OH2 @H UO

COO + H2O12&%7KBF#BEQ*B* Jc, J\u ,h; *X Axit axetic B ancol io amylic15&s> h?() hB Q7*Q JM( ,h+, 7"( hr*hc$() *hu Jc, #> :

Axit cacboxylic B ancol

COO} + aOH →

.t

COOa + }OH

16&s> h?() hB Q7*Q JM( ,h+, 7"( hr#> u => B(Qh* -COO-CH0CH- + aOH

→

.t

COOa + CHO

CH*-COO-CH0CH2 + aOH

→

.t

CH*COOa + CH* CHO 1&s> h?() hB Q7*Q JM( ,h+, 7"( hr#> u => EQ*K( -COO-C0CH2 + aOH

→

.t

COOa + CH*CO

CH*-COO-C(CH*)0CH2 + aOH →

.t

CH*COOa +CH*COCH*

18&s> h?() hB Q7*Q JM( ,h+, 7"( hr#> 1 u

`B Ete c 8c


8/11

TỔNG ÔN LÍ THUYẾT HỮU CƠ- GV : LÊ THỊ TUYỀN-0909 836583

19&z7*Q , h"( +() *!/() SO, #> : `B Ete c 8c 4omat > HCOO ^ d HCOOCH*V30&z7*Q , h"( +() ,n() h!K #> D*>u u() j,h S!K *!o() h #> :

`B Ete k#Ln8 no ^ d > CH20CH-COOCH* ? CH*COOCH0CH2

3&z7*Q J* ,h/F *hu Jc, ( H1 t (C1 `B ete no !"n c#$c m%c# #& > CnH2nO231& z7*Q *!o() h *OK *h>(h *hAF *(hhu ,M #> :

`B Ete metylmetacylat> CH20C(CH*) -COOCH*

s%V : C/, ,âu hỏ #*- ,hD* SK

33& ChD* SK lB ti ete cMa 8lixeol B axit bo c]n 8i ti8lixeit ( COO)*C32& *!B(*( (C15H*1COO)*C*H5 0q635& *! 7*QB!( ( C1rH*5COO)*C*H5 0 qs36& *!K#Q( (C1rH**COO)*C*H5 0 qq@3& E> h?() hB *! B(*(

(C15H*1COO)*C*H5 + *aOH →

.t

*C15H*1COOaC*H5(OH)*

38& E> h?() hB *! 7*QB!(

(C1rH*5COO)*C*H5 + *aOH →

.t

*C1rH*5COOaC*H5(OH)*

39& E> h?() hB *! K#Q(

(C1rH**COO)*C*H5 + *aOH →

.t

*C1rH**COOa + C*H5(OH)*20& gh"( +() o() *!K() ,'() ()h] J•,h; S;( n* 7 u *h>(h y !d( hBF SM(hâ( *OK #> :

7#Rn $n8 #ido #a

(C1rH**COO)*C*H5 + * H2

, o xt t

(C1rH*5COO)*C*H5 Qiolein Qiteain

sV : C/, ,âu hỏ CB,SKh!B*2& 4• ,h+() (h *!K() hâ( *^)#u,KM , (h\u (h H #( *; (hBu*B o() h"( +() (>K

7#Rn $n8 cMa 8lcozo [i C(OH)2 t%o dn8 dZc# c mB xanlam

21& 4• ,h+() (h *!K() hâ( *^

)#u,KM , 5 (h H #( *; (hBu *B,hK )#u,KM h"( +() =e ,hD* (>K

7#Rn $n8 cMa 8lcozo [i an#idic axetic t%o ete c 5 n#m

c#$c

23& 4• ,h+() (h *!K() hâ( *^)#u,KM , (h CH *B ,hK )#u,KMh"( +() = ,hD* (>K

-7#Rn $n8 cMa 8lcozo [i C(OH)2 }aOH !n nn8 t%o kKttMa !P 8%c#-7#Rn $n8 [i dd A8O*}H* !n nn8 t%o kKt tMa A8

22& I"( hr ,AB h"( +() #( Q()#u,KM #> )Z

Ancol etylic B CO2

enzim

6 12 6 2 5 2C H O 2C H OH 2CO → +

25& I"( hr ,AB h"( +() )B )#u,KM €!u,*KM => h!K < s* @h Ju( (() #> )Z

. i,t c

6 12 6 2 6 1@ 6C H O H C H O+ →

Jlcozo Uobitol26& ghâ( S]* )#u,KM => €!u,*KM *B o(),hD* (>K

~_n8 dn8 dZc# nX[c bom . 8lcozo lBm m't mB dn8 dZc#nX[c bom

2& ghâ( S]* )#u,KM => 7B,,B!KK *Bo() ,hD* (>K

-~_n8 dn8 dZc# nX[c bom . 8lcozo lBm m't mB dn8 dZc#nX[c bom- ~_n8


9/11

TỔNG ÔN LÍ THUYẾT HỮU CƠ- GV : LÊ THỊ TUYỀN-0909 83658350&CB,SKh!B* (>K h *hAF hâ( ,h}*hu Jc, )#u,KK

Qin# bIt , xenllozo , mantozo

5&CB,SKh!B* (>K , h"( +() =eCuu EB(h #B

Jlcozo , 9ctozo , accaozo , mantozo

51&CB,SKh!B* (>K , h"( +() =eCuK #> D* >u u()

j,h S!K

Jlcozo , mantozo

52&CB,SKh!B* (>K , h"( +() *!/()SO,

Jlcozo , 9ctozo , mantozo

55& sQ(#u#KK *!(*!B* Jc, J\u ,h; *Xh"( +() (C6H1O5)n + *n HO*

, o xt t

•C6HrO2(OO2)*€ n + *n H2\ellozo B axit nitic 02srn

56& sQ(#u#KK *!BEQ*B* Jc, J\u ,h; *Xh"( +()

\ellozo B an#idic axetic

(C6H1O5)n + *n (CH*CO)2O

, o xt t

•C6HrO2(OOC-CH*)*€ n + *nCH*COOH5& T!K() ,'() ()h] ()c$ *B J\u ,h;

)#u,KK *X h"( +() (>K :

Q#My K

- ‚ t^m > metylamin lBm ƒ‚ t^m #a xan#-dn8 dZc# nX[c bom > anilin t%o kKt tMa tNn8

6 l(KBE* *!o() ()c() *OK *h>(h N#K(-6 `B axit- 6-amino#exanoic H2 -(CH2)5 -COOH61 l(KBE* *!o() ()c() *OK *h>(h N#K(- `B axit- r-amino#e 7#=n t 8;m 2 8c aminoaxit liYn kKt n#a bn8 1 liYn kKt u Su!Q h'()

C : 2* 0q

0& I *! Q** * JB *OK !B *X 3B(KBE* G#E( B#B(( =B#(

** 02r

& I Q** * JB *OK !B *X 3B(KBE* G#E( B#B(( VB# #> :

*2 0 s

1 I Q** J() hâ( ,h+B J() *h$," 1 B(KBE* #>

23 0 2

3 I *!Q** J() hâ( ,h+B J() *h$," 3 B(KBE* #>

*3 0 6

7a8e 9 o9


10/11

TỔNG ÔN LÍ THUYẾT HỮU CƠ- GV : LÊ THỊ TUYỀN-0909 836583sV%% gK#Q : C„J QH…C2&gK# Q*#Q( i bLn8 ? t" tm

-Q" bTn t†n8 #< > Q" axetat ? t" ico- Q" t†n8 #< > ilon-6( t" ca


11/11

TỔNG ÔN LÍ THUYẾT HỮU CƠ- GV : LÊ THỊ TUYỀN-0909 836583

98&gK#Q S\( *!K() ' *!c$() BE*hBF \ :

7oliamit ,

cau hoi tong on truoc khi ra quan 2015

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