cementing - salt solutions

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1 PETE 411 Well Drilling Lesson 32 Cementing - Salt Solutions

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Cementing - Salt Solutions

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Page 1: Cementing - Salt Solutions

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PETE 411

Well Drilling

Lesson 32

Cementing - Salt Solutions

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Cementing - Salt Solutions

Use of salt in Cement Slurries

Unsaturated Salt Solutions

Saturated Salt Solutions

Types Cements

Cement Additives

Examples

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Read:

ADE, Ch. 3

HW #15: Kick, W&W. Due Nov. 16, ‘05 HW #16: Cementing of Conductor Csg.

due November 21, 2005

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Salt in Cement Slurries

Salt Zones

Salt-saturated cements were originally used for cementing casing strings through salt zones.

Fresh or unsaturated salt cement slurries will not bond satisfactorily to salt formations because the slurry tends to dissolve or leach away the salt at the wall of the hole.

Salt-saturated cements will not dissolve any more salt so a good bond can be achieved

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Salt in Cement Slurries

Shale Zones

Many shales are sensitive to fresh water.

Salt helps to protect these shales in that it tends to prevent excessive sloughing or heaving of the shales.

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Salt in Cement Slurries

Accelerator

In low concentrations salt tends to accelerate the setting of cement.

Retarder

In high concentrations ( >5% by wt. of water) the salt will tend to retard the setting of the cement.

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Salt in Cement Slurries

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Salt in Cement Slurries

Expansion

Salt results in a more expansive cement.

Freezing

Salt reduces the freezing temperature of cement slurries.

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9 of solution

EXAMPLE: 200,000 mg of NaCl 800,000 mg of H2O 1,000,000 mg of solution < 1 litre of solution

mg/L

ppm

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Volume of Sodium Chloride Solution

EXAMPLE: Adding 30 lbs of NaCl to 100 lbs of H2O increases the volume of solution by ~10.7%

30% by weight = 13.8% by volume (SG = 2.17) ??

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Density of Sodium Chloride Solution

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Sodium Chloride Solutions at 68 oF

0.96

0.98

1.00

1.02

1.04

1.06

1.08

1.10

1.12

1.14

0 10 20 30 40

Percent Sodium Chloride by Weight of Water

Volu

me

of S

olut

ion

8

8.5

9

9.5

10

10.5

Dens

ity o

f Sol

utio

n, l

b/ga

l

1.068 9.36

, ga

l

20% NaCl 1.67 lbs NaCl / gal H2O 1.068 gal of solution 9.36 lb/gal

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Example: Salt Solutions

30% NaCl (by weight of water) is added to one gallon of fresh water. Calculate the density of the mixture:

(i) Before the salt goes into solution (ii) Using the solubility charts shown above.

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Problem : Salt Solutions

(i) Assuming that

lb/gal 9.51 mix =ρ

8.33) * (2.17 / 8.33) * (0.3011 x 8.33 * 0.301 * 8.33

++

=

mixmixSSWWmixmix2211 VρVρVρVρ...VρVρ =+=++

mix

SSwwmix V

VρVρρ +=

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Problem : Salt Solutions

(ii) From the chart, { 9.51 lb/gal vs. 9.8 lb/gal !! } { what if we had 60% salt? }

lb/gal 8.9mix =ρ

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Problem

Calculate the density and yield of a cement slurry consisting of:

65% Class “A” cement

35% Pozmix cement,

6% bentonite BWOC and

10.9 gal/sk of water.

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Problem

(i) Initial tabulations and calculations: Weight Specific Density Component lbs/sk Gravity lbs/gal Class “A” 94 3.14 8.33*3.14 = 26.16 Pozmix 74 2.46 8.33*2.46 = 20.49 Bentonite 2.65 8.33*2.65 = 22.07 Water 1.00 8.33*1.00 = 8.33

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Problem

(ii) Determine the properties of one sack of dry cement mixture; 65% Class “A” and 35% Pozmix:

(gal) Vol. (lbs) ht Weig Cement

3362.26.1661.1 61.194*0.65 sk 0.65 A,Class ==

2641.20.4925.9 25.974*0.35 sk 0.35 ,Pozmix ==

3.600 87.0

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Problem

(iii) Determine density and yield of final slurry:

14.7365 183.02

10.9 90.808.33*10.9 gal 10.9 Water,

2365.022.075.22 5.2287*0.06 6% Bentonite,

3.600 87.0 sk 1 mix, Cmt.

(gal) Vol. (lbs) Weight Component

=

==

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Problem

←==ρ lb/gal 42.1274.1402.183

mix

←= sk/ft 97.1 3

3gal/ft 48.7gal/sk 14.74Yield =