chairman’s message cad news - amazon...
TRANSCRIPT
Chairmanrsquo s Message
Dear SPE Color and Appearance Division Members
Time seems to be accelerating as we race to the end of summer The days aregetting shorter and I wonder if I can sneak in a trip to the beach or short vaca-tion before it is over Very soon it will be time for CAD RETECreg 2014 in NewOrleans The CAD RETECreg 2014 conference chair Earl Balthazar and hiscommittee are working on the final details to make sure the conference meetsthe needs and expectations of CAD members
Past CAD RETECreg typically started with Bob Charvatrsquos seminar on Coloringof Plastics This year was to be Bobrsquos final seminar however his passing earlier this year surprisedand saddened many in the plastic community We will have a small memorial set up for Bob
Charvat so that messages and memories can beshared with fellow CAD members The boardhas decided not to hold the color seminar thisyear in memory of Bob
While in New Orleans you will see many of thesame activities as previous CAD RETECreg The2014 CAD RETECreg Golf Outing will be heldSunday 14th September at TPC Louisianawhich serves as the home of PGA TOURrsquoSZurich Classic of New Orleans Golf enthusi-asts will find the golf outing an enjoyable expe-rience Those looking for a more physical chal-lenge and the opportunity to help the local com-munity can participate in the 5K Fun RunWalkat 7 am on Tuesday 16 September The pro-ceeds from the 5K Fun RunWalk will be donat-ed to the local chapter of Habitat to HumanitySince 2005 SPE CAD has donated more than$25000 Habitat to Humanity Both the golf out-ing and 5K require registration prior to the cor-responding event Refer to the website(specadorg) for more details Those who prefermore social activities will be pleased that theWelcome and Network Receptions will be heldon Sunday and Monday nights respectively
Thanks to the highly favorable response thepanel discussion and New
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SUMMER SUMMER 2014
continued on page 2
CA
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Table of Contents
Chairmanrsquos Message 1-2
Editorrsquos Note 2
Mission Statement 2
Invitation to Attend our Board Meetings 2
Sponsorships 3-4
CAD RETECreg2014 5
CAD RETECreg2014 Golf 6
CAD RETECreg2014 Speaker Program 7-8
CAD RETECreg2014 Fun Run 9
CAD RETECreg2014 Sponsor Recognition 10
Technical Article 11-15
Minutes of Board Link 15
Your Company Our Division 15
Social Media ndash LinkedIn 15
Sponsorships 16
Plastics Courses at Terra Community College 18
Call for Papers ndash ANTECreg2015 19
CAD BOD Directors Listing 20
Other Contact Info 20
SOCIETY OFPLASTICS ENGINEERS
COLOR amp APPEARANCE DIVISION
Technology forum will be included in the 2014 technicalprogram The panel discussion will be Public Perceptionof Plasticsrdquo Audience response devices will be included soattendees can participate in the discussion The NewTechnology Forum will end the presentations for Mondayand play an excellent transition to the Network Receptionwhich will be held in the exhibit hall
If you have not registered for CAD RETECreg 2014 in NewOrleans I recommend that you visit the CAD website(specadorg) and sign up
I would like to close with an update on the CAD Board ofDirectors I was responsible for the board elections earlierthis year We had sixteen excellent candidatesUnfortunately there were only nine positions This yeartwo new board members were elected Tom Chirayil fromBASF and Pete Zillitto from Sudarshan Please join me inwelcoming Tom and Pete as they begin their 3-year term onthe CAD Board Steve Goldstein Sharon Ehr JamiePrzybyliski Austin H Reid Jr Mark Tyler Steve Eskerand Mark Freshwater were reelected
Best RegardsBetty PuckerinCAD Chairperson
DisclaimerThe information submitted in this publication is based on current knowledge and experience In view of the many factors that may affect processibil-ity and application this datainformation does not relieve processors from the responsibility of carrying out their own tests and experiments neitherdo they imply any legally binding assurance of certain properties or of suitability for a specific purpose It is the responsibility of those to whom thisinformation is supplied to ensure that any proprietary rights and existing laws and legislation are observed
Invitation to Attend Our Board Meetings
The Color and Appearance Division regularly holds Board of Director(BOD) meetings at the ANTECreg and the CAD RETECreg In addi-tion a Summer BOD meeting is typically held about 6 weeks prior tothe next CAD RETECreg
The Summer meeting is scheduled in various locations A WinterBOD meeting is held in January The Winter meeting is typically held at a site of a future CADRETECreg
Any SPE CAD members who wish to attend are welcome at thesemeetings If interested in attending the next Board meeting pleasecontact the Division Chairperson for more information
SPE Color amp Appearance Division Mission Statement
The Color and Appearance Division of SPEstrives to educate train inform and to provideprofessional interaction opportunities to theglobal community involved in visual perform-ance and aesthetics of plastics
SPE CAD NEWS Summer 2014 page 2 wwwspecadorg
Editorrsquo s Note
Welcome to the Summer 2014 Editionof the CAD newsletter This editionshould be hitting your mailboxes just
before the CAD RETECreg which marksthe first time since 1991 the conference has
returned to New Orleans Louisiana Of course most of youwill remember that Hurricane Katrina derailed our plans tovisit the Crescent City back in 2005 and so I for one amreally looking forward to this yearrsquos program
This edition of the newsletter also marks my very first offi-cial action as a member of the CAD BOD which I am veryexcited about Having been in this industry since 1989 andnot knowing color from floor sweepings when I started(and maybe I still donrsquot depending on who you ask) thisis a great opportunity for me to try and give somethingback to an industry thatrsquos helped me pay my bills all theseyears I hope to see you all in The Big Easy next month
SincerelyPete ZillittoGuest Editor
Chairmanrsquo s Message (continued)
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nruChselraCh336-255-6673 nLinruChselraCh
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Pigments and Additives for the Plastics Industry
Clariant Corporation4000 Monroe Road Charlotte NC 28205Phone 8004414414wwwclariantcom
Leading Manufacturer of Complex Inorganic Color Pigments (CICP) bull Pigment Brown 24 Yellow 53 Blue 28 Green 50 Black 28 etcbull Environmentally Friendly Pigments Brown 48 etcbull Laser Marking Pigmentsbull Pigments for Biodegradable Plastics
Contact in Americas
73 Cavalier Blvd Suite 207 Florence KY 41042TEL (859) 746-0407 FAX (859) 746-0467tomatecamtomateccomWWWTOMATECCOM
HIGH PERFORMANCE PIGMENTS FOR PLASTICSFerros Geodereg Complex Inorganic Color Pigments offer unsurpassed color quality and stability
The complete Geodereg line includesChrome Titanates Cobalt Blues amp Greens Nickel TitanatesHeat stable Blacks Iron Free Browns IR Reflecting Blacks
Ferro Corporation Performance Pigments amp Colors251 West Wylie Avenue PO Box 519Washington PA 15301Phone 724-223-5900Fax 724 223-2700
wwwferrocom
wwwshepherdcolorcom
Lintech has theColors and Pigments
You Need
Newsletter Sponsorship Opportunity
The Color and Appearance Division (CAD) commits to thepublishing of at least three newsletters a year (four if there is
sufficient material to justify the extra issue) Each newsletter iselectronically distributed to our membership of nearly 1000Each sponsorrsquos art directly links to the companyrsquos website
In addition we print one of these newsletters on 80gloss coat-ed stock All electronic versions are also posted on the SPE web-site where it available for anyone to download
For the small donation of $300 per year we offer a business cardsized (2 x 35 inches) mention in our newsletter
We currently have the following slots available for sponsorship
(2) 2 x 35 inch or (1) 4 x 35 inch
If interested in learning more please contactScott Aumann Phone 9122100175Email ScottAumannedmmilliporecom
Additives and Pigments
Contact Charles Chum336-255-6673 CharlesChumLintechinternationalcom
SPE CAD NEWS Summer 2014 page 3 wwwspecadorg
Organic Pigments Inorganic Pigments Pigment Preparations
Heucotech Ltd 99 Newbold Road Fairless Hills PA 19030wwwheubachcolorcom 215-736-0712
Organic amp InorganicPigments and Preparations
(416) 253-4297 hkennedydominioncolourcomwwwdominioncolourcom
D 72209 217 PM Page 1
QUALITY FORMULATION OFCOLOR amp ADDITIVE CONCENTRATES
wwwtechmerpmcom
18420 Laurel Park Road 1 Quality CircleRancho Dominguez CA 90220 Clinton TN 37716(310) 632-9211(865) 457-6700
COMPETENCE IN COLOR
AT KEYSTONE WE PROVIDE A THREE-TIER CUSTOMER-FOCUSED VALUE PROPOSITION
PRODUCTINNOVATIONS
gt KeyplastTM Dyesand Pigments
gt KeyplastTM GraniteSpecial Effects
gt KeyfluorTM OBrsquos andInvisible Fluorescents
gt ReversacolTM
PhotochromaticColorants
ISHIHARA CORPORATION (USA) TiO2 Ultra-fine TiO2
Nickel Titanates Chrome Titanates Conductive Pigments
601 California Street Tel (415) 421-8207San Francisco California 94108 Fax (415) 397-5403
wwwishiharacom
SPE CAD NEWS Summer 2014 page4 wwwspecadorg
CONFERENCE REGISTRATION
SPE Member RegistrationMust include valid SPE e-mail address with registration $440
SPE Non-Member Registration - Includes 1 Year Membership $590Membership will be processed after RETEC
SPE Non-Member Registration Without SPE Membership $650Conference registration but decline the One Year SPE membership
OTHER REGISTRATION TYPES
SpeakerModerator Registration $170Must be a speaker or moderator at the conference for this registration type This does not include New Technology Forum Speakers
2014 CAD RETECreg Conference Committee Member Registration $170Must be a member of the 2014 CAD RETECreg organizing committee to qualify for this registration type
Student Registration $ 50Must have valid Student ID and working part-time or full-time and paying own travel expenses
SPE Emeritus Member Registration $100Option available for SPE Emeritus Members
SPE Membership Renewal $100Renew your existing SPE membership Requires SPE membership e-mail address to ensure continued membership status Note membership renewal may not be processed until after RETECreg
Tabletop Exhibit Space (if still available) $950Includes two free conference registrations with tabletop Provide names and titles of both attendees in the appropriate fields at the end of this form
The 52st Annual Society of Plastics Engineers Color and Appearance Division CAD RETECreg is located near New OrleansFrench Quarter and will serve as an excellent setting for the theme of this yearrsquos CAD RETECreg ldquoIts a Colorful WorldrdquoCAD RETECreg is the largest technical conference hosted in North America that is specifically dedicated to the color andappearance of plastics
If you have not already registered there is still time to attend the conference A special thanks to all our sponsors organizers and particpants for your involvement creativity and talent
Earl BalthazarConference Chair
2014 SPE CAD RETECreg
ebalthazartxrrcom
CLICK HERE to Register orsee detailed informaton
SPE CAD NEWS Summer 2014 page 5 wwwspecadorg
CAD RETECreg REGISTRANT FORM (Please Print)
SPE Membership Name Address Title
Company
Country of CitizenshipEmailDaytime Phone Date
For Credit Card Payments OnlyCircle One AMEX VISA MasterCardCard No Expiration Date Name on card (if different from above)___________________________________________Signature
If paying by credit card fax to 859-372-6382 ore-mail to brucemulhollandticonacom
REGISTER ONLINE AT wwwspecadorg
For checks make in US dollars only payable to ldquoSPE CADrdquo
Refunds less a $30 fee August 16 to September 5 2014 No refunds after September 5 2014 SPE Memberships are processed after RETEC
If paying by credit card fax to 859-372-6382 ore-mail to brucemulhollandticonacom
REGISTER ONLINE AT wwwspecadorg
CIRCLE ANSWERS BELOW
Is this your first CAD RETECreg Yes No
If no have you attended a CAD RETECreg
in the last five years Yes No
EXTRA CONFERENCE LITERATURE
Additional Copy Conference Proceedings $115 X ____ = $________Additional CAD RETECreg 2014 conference proceedings download pass One copy is already included with each paid registration
SPE CAD Archive DVD (1961 - 2007) and $175 X ____ = $________Color Papers from 1961-2007 ANTEC amp RETEC available on-siteSpecial RETECreg Offer $175 (must also register for the RETECreg conference)Savings from the regular price of $200 for SPE members and $300 for non-members
OTHER EVENT REGISTRATIONRSVP
Sunday Golf Outing $130 X ____ = $________Sunday golf outing at TPC Louisiana If registering more than yourself for golf
please include their names using the tabletop names amp titles fields at the bottom of the
registration page This will allow you to list up to four names using those fields
5K Fun RunWalk $20 X ____ = $________Sign up for Tuesday AM 5K Fun RunWalk CAD will match the $20 donation for charity
Total due from all items checked $_________________
QR CAD mobile app for Android Apple and Windows mobile devices
GOLF OUTING INFORMATION
SPE CAD NEWS Summer 2014 page 6 wwwspecadorg
Price $13000 per golfer
Includes Warm up on the RangeGreen FeesCart FeeScramble formatBox Lunch with DrinkCustomized TPC Bag Tag
Course LocationTPC Louisiana11001 Lapalco BlvdAvondale LA 70094(504) 4368721
Registration 1100 am (CST) Shotgun Start 12 noon (CST)Awards Will be presented at CAD RETECreg
Welcoming Reception
September 14 2014
To Sign Up Online RegistrationQuestions Contact
Mark Tylermarktylercelanesecom 8593723221 or
Mark Freshwatermarkpigmentscom 2016650091
SPE CAD NEWS Summer 2014 page 7 wwwspecadorg
900 am - Golf Outing300 pm
100pm - Registration Desk Open600 pm
100pm - EXHIBITOR SET-UP530 pm
600 pm Welcome Reception Sponsors EMD Chemicals and Kronos800 pm (Pick up your registration packet prior to this event to get your complimentary drink coupons)
Golf Outing Prizes will be presented at the Welcome Reception
730 BREAKFAST (Biffon A) Sponsor Lansco730 Registration Desk Opens
MORNING SESSION MODERATOR BRUCE MULHOLLAND CELANESE815 OPENING REMARKS Earl Balthazar
830 KEYNOTE Public Percepton of Plastics Rudy Underwood American Chemistry Council
930 The Global Economy-Precariousness of Supply Chain Globalization of Regulations and How to Protect YourselfBruce Howie Dominion Color
1000 COFFEE BREAK Sponsor Clariant
1030 Fundamentals of Twin-Screw Extrusion- Color MB Prossessing Common Pitfalls and How to Avoid ThemPaul G Anderson Coperion
1100 Influence of TiO2 Feeding on Twin Screw Extrusion Compounding JD Connolly DuPontTitanium Technologies
1130 Dispersion of Pigments in Plastics Applications Mahesh Mettelloo Sudarshan
1230 - 130 LUNCH (on your own)
CAD RETEC 2014reg
SUNDAY September 14
MONDAY MORNING (Mardi Gras Ballroom) September 15
CONFERENCE HOTEL INFORMATIONMarriott New OrleansTo Reserve by Phone 504-581-1000 or 1-888-364-1200Request Group Rate Society of Plastics Engineers - Color amp Appearance Division
MARRIOTT NEW ORLEANS555 Canal Street New Orleans Louisiana 70130 Phone 504-581-1000 Toll Free 1-888-364-1200
Discounted Conference Room Rate $159night-single occupancyRoom Block Dates Sept 12-17
Rates will increase significantly after August 15 2014 at 5pm or whenever the room block is full Cancellation policy Any hotel reservation canceled within 48 hours of arrival date will be charged for one (1) nights room and tax
AFTERNOON SESSION MODERATOR NATHAN KARSZES NUBIOLA130 Panel Discussion
Audience Response Devices will be available to each audience member for responding to poll questions during the panel discussion
300 COFFEE BREAK Sponsor Shepherd
330 Pigments for Sensitive Applications Tom Chirayil BASF
400 Advances in Liquid Color Technology Inga Lesko Clariant BU Masterbatch
430 New Technology Forum (pdf) Moderator Sandra Davis
500 NETWORKING RECEPTION Sponsor Nubiola
700 5K Fun RunWalk for Habitat for Humanity Plastics (Pregister for this event) Sponsor Dominion
730 BREAKFAST(on your own)
MORNING SESSION MODERATOR AUSTIN REID DUPONT TITANIUM TECHNOLOGIES
900 Colorants for Plastics-Emerging Trends and Technologies Krishnamoorthy Sivakumar PolyOne
930 Iron OxidesInorganic Pigments for Plastics George Podolsky Rockwood Pigments
1000 COFFEE BREAK Sponsor DuPont
1030 Blue Undertone Enhancement of Black and Grey PP Injection Molded PP Nathan Karszes Nubiola
1100 Lighter Faster Stronger Additive Solutions for Automotive Plastics Emilie Meddah Clariant BU Additives
1130 Gaining Competitive Advantage through Digital Appearance Technology in the Automotive Interior Supply ChainPhil Ruggiero Datacolor
1200 AWARDS LUNCHEON PRESERVATION HALL (Included with Registration) Sponsor Tronox
AFTERNOON SESSION MODERATOR JIM FIGANIAK
130 Inorganic Pigments From Caveman to the 21st Century Mark Ryan Shepherd Company
200 Measurement Technology to Evaluate Light Protection What You See May Not Be What You ProtectPhil Miedenzu DuPont Titanium Technologies
230 COFFEE BREAK Sponsor Munzing
300 Effects of Disinfectant Grade Cleaner on Physical Properties of Cell Phone Cases Diane McLendonOtterbox
330 Its a Colorful World Developing Technologies to Keep it that Way Joseph Fay BASF
400 Closing Remarks - Earl Balthazar Survey Raffle - MC-Tracy Phillips Uniform Color Grand Prize TBDOther Prizes Archive DVD Free Night at Westin Free Registration at CAD RETECreg 2015 Emergency RadioCAD RETECreg Limited Edition Art
Must be present to win
MONDAY AFTERNOON (Mardi Gras Ballroom) September 15
TUESDAY MORNING September 16
TUESDAY AFTERNOON (Mardi Gras Ballroom) September 16
SPE CAD NEWS Summer 2014 page 8 wwwspecadorg
SPE CAD NEWS Summer 2014 page 9 wwwspecadorg
Lobby of New Orleans Marriott 555 Canal Street
FREE T-SHIRT FOR THEFIRST 40 RUNNERS
September 16th 7am
$20 Registration Fee bullAll proceeds go to Habitat for HumanitySPE CAD will match every $20 donation
dominioncolourcom
sponsored by
Sponsored by
SPE CAD NEWS Spring 2014 page 10 wwwspecadorg
Gold Level Sponsors
Platinum Level Sponsors
Silver Level Sponsors
WE ARE PROUD TO HIGHLIGHT THESE EXCELLENT COMPANIESPlease visit our generous sponsorsrsquo websites by clicking on their logos below
T H E G O L D S T A N D A R D I N P L A S T I C S
Thank you RETECreg 2014 Sponsors
Cappelle
Celanese
LTL Color Compounders Inc
Pigments colour the world
our passion your colors
C R e A t i N g A d d i t i v e v A L u e
LANSCO COLORS
E C K A R TEffect Pigments
High Performance Pigments for Demanding Applications Rotational MoldingJoseph J Fay PhD amp Peter Zillitto
Plastics Technical Center Pigments DivisionCiba Specialty Chemicals Corporation
Technical Article
INTRODUCTIONColorants for polymer applications are typically incorporated into the polymer by one of several common pathways Colorconcentrates which are widely used in industry enable the end user to conveniently meter in the colorant at the prescribedration with virgin or uncolored polymer in the manufacturing process The benefits of concentrate used as compared to thedirect use of powder pigment during final product conversion processes include predispersion of the pigment in a suit-able carrier system elimination of the need to in-house compounding to incorporate the colorant uniformly and improvedhousekeeping etc Furthermore color concentrates are available ina number of product forms including pelleted concen-trates liquid color systems and pastes the latter used especially for PVC For polymer conversion processes in which anextruder or meld mixing devise is employed these colorant preparations can be used very effectively In some marketswhere high levels of functional fillers modifiers or polymer blends are used compounders may manufacture ldquoprecoloredrdquopolymer by direct addition of the colorant to their compounding line In come cases concentrates are used depending uponspecific product and process capabilities
Rotational molding in contrast is a low shear process in which traditional pellet form color concentrates are not suitableColoration of rotomolding resin is commonly obtained by the use of dry color and liquid color which can be added direct-ly to the ground rotomolding resin Alternatively precolored resin in which the pigment is compounded into to the poly-mer and then ground before use finds applications as well More recently micropellet technology has been advanced as an alternative to the aforementioned methods It is similar to precompounded color but the need for grinding the polymerinto the appropriate mesh size is eliminated as the micropellets can be rotomolded without further processing For each ofthese color incorporation methods there are advantages and disadvantages including economic factors (process equipmentand material cost) ease of use housekeeping and overall quality (physical properties and aesthetics) of the resulting part
As a consequence of the myriad applications the palette of pigments for rotational molding appears to be quite extensivesimilar to that which is used in general purpose polyethylene application requirements However due to the specific processconditions involved in preparing the pigment system the temperature profile of the rota-tional molding process and the end use application requirement the gamut of pigments issignificantly reduced
Pigment selection may also be affected by the method by which the pigment is to be deliv-ered Liquid colorant systems work best with pigments that have the potential to be loadedto high weight percentages while maintaining suitable viscosity Pigments used in drycolor require characteristics that impart dispersibility and minimize agglomeration duringboth dry color manufacture and blending with the rotomolding resin
DISPERSIONWhen pigments are manufactured the smallest pigment particles formed are discreet units referred to as primary particlesAs a result of their high surface energy these particles randomly join together to form aggregates and agglomerates thelatter being formed primarily during subsequent filtration a nd drying processes To achieve a speck-free system the pig-ment must be effectively ldquodispersedrdquo so that the individual pigment particles or aggregates are wetted by the polymer anddiscrete pigment particles are not visible to the naked eye Rotomolding pigment systems (liquid color and dry color) needto be prepared in a manner that ensures visible agglomerates are eliminated and that during subsequent mixing with therotomolding resin the colorant system will be easily distributed Furthermore the dispersion of the pigment needs to effec-tively deliver a colorant that will provide a high color strength potential to maximize economic while not adversely affect-ing other properties Figure 1 illustrates the particle size of the typical azoncondensation pigment continued on page 12
SPE CAD NEWS Summer 2014 page 11 wwwspecadorg
The following Technical Article was published in 1998 at The Color And Appearance Conference in September
continued from page 11
Note that the particle size distribution that would beobtained in a polymeric system will be very dependentupon the effectiveness of the final dispersion
HIGH PERFORMANCE PIGMENTSHigh performance pigments HPP can be defined as pig-ments that have either very good to excellent heat or lightstability and more commonly pigments which offer aunique combination of both heat and light stability Theenhanced UV and heat performance attributes of HPPs setthem apart from traditional or classical pigments such asthe lithol rubines (PR 571) lake red C (PR 531) 2B toner(PR 48 types) monoaso yellows such as PY 62 and oth-ers which have only limited heat stability and mostly mar-ginal to poor lightfastness
The major types of high performance pigment chemistriescan be described in a general fashion as indicated in Table 1Some individual pigments within these chemistries mayhave better or worse performance characteristics depend-ing upon the specific product attribute and applicationbeing considered
HEAT STABILITYOrganic pigments are available not only with a wide vari-ety of hues and chroma but also with considerable variationin performance characteristics Rotational molding withits combination of relatively long cycle times high moldsurface temperatures and abundance of oxygen is moredemanding upon the polymer stabilization package andpigmentation in comparison to many other processes As aconsequence many rotomolded product applicationsrequire the use of higher performance pigments to survivethe molding process even though the pigment with regardto final product requirements may be viewed as ldquoover engi-neeredrdquo Classical pigments such as 2B reds (CI PigmentRed 48rsquos) with only limited thermal stability in high tem-perature olefin polymer applications may not be suitablefor even non durable articles as the color stability duringmolding may be insufficient Figure 2 compares the heatstability of a calcium 2B toner with high performance dike-topyrrolo-pyrrole (DPP) and quinacridone (QA)chemistries In masstone applications it is readily apparentthat the 2B toner is quite deficient when compared withthese high heat stability pigments Furthermore as pigment
SPE CAD NEWS Summer 2014 page 12 wwwspecadorg
heat stability is generally related to concentration at lowerconcentrations the 2B toner would become even moreprone to color change In addition to pigment instabilitycolor change during rotational molding may be affected byother factors The stability of the base resin is an importantconsideration The role of the antioxidant package is criti-cal to controlling the initial color and maintaining the phys-ical properties of the rotomolding resin Judicious selectionof a phenolic antioxidant and phosphite processing stabi-lizer package is essential for the base polymer Dependingupon specific circumstances additional antioxidant mightbe added The most effective stabilization is typicallyobtained when the antioxidant is added directly to the resinitself during manufacture or during compounding whenrecolored resin is prepared For specialty applications
where additional antioxidants are needed to attain the req-uisite performance precolored or preformulated resinwhich is then ground provides additional benefit
LIGHT STABILITYMany applications of rotationally molded articles find enduses which require UV durability These UV performanceapplications encompass a broad variety of applications andmarkets residential waste containers childrenrsquos play-ground toys (both for residential and institutional uses)outdoor sporting goods (kayaks and component of otherrecreational vehicles) and oversize containers (industrialcontainers and agricultural tanks) For outdoor applica-tions careful formulation is required to achieve not onlysuitable color match but also a color combination whichwill have the desired weatherability As delineated inFigure 3 Calcium 2B toners have limited light stability inpolyolefin applications and are not recommended for usewhere any significant UV exposure is intended Althoughnot reflected in the colorimetric data the 2B toner samplesurface was significantly marred by chalking and surfacemicrocracking and is visible via low magnification optical
Quinacridone Copper PhthalocyanineDiketopyrrolo-pyrrole (DPP) AnthraquinoneTetrachchloroisoindolinone IndanthroneAzochondensation PeryleneBenzimidozone Isoindoline
Table 1 High Performance Chemistry Families
continued from page 12
SPE CAD NEWS Summer 2014 page 13 wwwspecadorg
microscopy Such microcracks may ultimately result inpremature physical failures of the product Therefore visu-al inspection of samples following accelerated or real-timeexposure testing is imperative to ensure complete perform-ance analysis As a consequence of the limited weather-ability of many pigments performance assessment is need-ed Applications such as point of sale displays and relateditems and indoor applications where incidental UV expo-sure from lighting fixtures or nearby windows is possibleare best formulated with durable HPP pigments Outdoorapplications require the use of HPP pigments at levels thatcan provide sufficient levels of weather resistance
Figure 5 illustratesthe difference inlong-term UV sta-bility that wasobtained when aDPP red (PR254) was com-pared with a pery-lene red (PR178) Perylenepigments areprone to darken-ing when used inconjunction withhindered amine light stabilizers (HALS) whereas no suchnegative interaction has been observed for DPPchemistries
Other high performance pigment classes such as copperphthalocyanine blue pigments may also be suitable foroutdoor applications when properly formulated PB 151and PB 153 are widely used in rotational molding appli-cations as a consequence of their outstanding performanceproperties Figure 6 and tremendous value in use
Inorganic and heavy metal pigments are also widely usedin some rotational molding applications due to their general-ly good dispersibility characteristics and in many cases thecleanliness of shade that may be obtained when using cer-tain cadmium and lead chromate pigments However aswill be discussed in greater detail regulatory pressureshave resulted in heavy metal deselection in several appli-
cation areas including food packaging and many toy appli-cations There applications however have not always beeneasily reformulated The use of HPP products providesalternatives in many color space applications Additionallywith the recent introduction of several new DPP productsPR 264 (Figure 7) PR 272 and PO 71 and PO 73(Figure 8) into the polyolefin and PVC market areas agreater breadth of high performance organics is availablefor formulating In some case differences in the perform-ance of organic versus heavy metal pigments may result inadditional raw material costs Material selection and mod-ification of base stabilization are required in some casesand additional light stabilization packages are needed
continued on page 14
continued on page 15
continued from page 13
SPE CAD NEWS Summer 2014 page 14 wwwspecadorg
especially when formulating polyolefins for outdoor appli-cations to provide comparable alternatives Nonethelessconsumers (materials specifiers manufacturers and theultimate product purchaser) choosing to avoid use of cad-mium and lead pigments wherever reasonably possibleremains a continuously evolving trend
The formulation of rotationally molded articles for outdoorapplications requires the use of both suitable pigments aswell as the assistance of a well-designed light stabilizerpackage The use of tetramethyl piperidine based hinderedamine light stabilizers especially oligomeric and highmolecular weight types in combination with benzotriazolebased UV absorbers are recommended for use in a varietyof applications The total package loading should be tai-lored to meet the specified requirement of the application
DISTORTION EFFECTSDistortion of rotomolded articles can be effected by sever-al different variables Resin choice and the particular mate-rial being used can affect warpage and shrinkageDifferences in cooling of the mold thickness variationsovercuring and several other process parameters have beenfound to be related to warping Since pigments (and thesystems used to deliver them) may alter the flow character-istics of the polymer and also the cure characteristics oper-ation of a given mold with different pigments or colorantsystems with a single cure cycle may result in differencesin dimensional stability The use of controlled heating andcooling as well as good control over the process itself willhelp to ensure consistent part manufacturing as well as agood data and record keeping can be referred to in case oferratic part quality
IMPACT PROPERTIESImpact properties are commonly tested as a means ofassessing the quality and suitability of colorant systems aswell as for assessing the cure characteristics of the polymerand the properties of the final product The ARM(Association of Rotational Molders) impact test is a com-mon test that is used Alternative instrumented testing pro-vides similar test result capabilities with the advantage ofquantitative and qualitative data acquisition
Impact properties of rotomolded products are importantMany toys containers and other applications require assur-ances of product integrity which can often be affected notonly by the process conditions but also by the incorpora-tion of pigments and other additives Since there is very lit-tle shear in the rotomolding process pigments are likely tobe located at the grain boundary between adjacent polymergranules This localization of pigment and ldquoadditivesrdquo can adversely affect physical properties in sev-eral ways Inhibition of polymer chain entanglementsbetween particles due to additives that form an interfacebetween resin particles can result in weak distinct bound-aries with poor mechanical properties Also pigmentagglomerates which are not broken apart or more trou-bling when they are formed during premixing processesdue to excessive mixing may introduce point defectseffecting physical properties Aesthetic properties may alsobe impacted if agglomerates are present in either signifi-cant size or number Pigment loading which is related toboth the effectiveness in which the pigment can be dis-persed as well as the color requirements of the part isanother factor to be considered in assessing the potentialeffect of coloration on physical properties
REGULATORY ASPECTSWith the variety of applications encountered in rotationalmolding well-publicized legislation and public opinionhave compelled many plastics processors and end-users touse alternatives to cadmium and lead based pigmentsCONEG (COalition of NorthEast Governors) related legis-lation prohibits the sale of packaging materials to whichcadmium lead mercury and hexavalent chromium or theircompounds have been intentionally added Reducing theamount of these elements entering the food chain via wastedisposal sources and the extra precautions needed to dis-pose of post industrial wastes are issues to be addressesCertainly both lead and cadmium-based pigments possessa combination of desireable technical properties that makesthem articularly useful coloring materials for polymersLead based pigments furthermore are particularly eco-nomical in use Nonetheless public opinion and legislationhave had and will likely continue to have a significantimpact on their use particularly in consumer goods
SPE CAD NEWS Summer 2014 page 15 wwwspecadorg
The Color and Appearance Division (CAD) is commit-ted to the publishing of at least three newsletters a year(four if there is sufficient material to justify the extraissue) To that end we would like you to think aboutthe financial side of sponsorship of the newsletter Forthe small donation of $300 per year we offer a businesscard sized (2 x 35) mention in our newsletter whichgoes out to the nearly 1500 members of the CAD aswell as other SPE division members These are peopleactive in every aspect of plastic coloring and additivetechnology Larger sized spots are available at a com-mensurate increase in rate
If you are interested in helping to sponsor theSPECAD Newsletter please contactScott Aumann Phone 912 210 0175
Email ScottAumannedmmilliporecom
Your Company Our Division
Dear Members
Just a reminder that you can view past and currentBOARD MINUTES on the SPECAD website
We do not typically publish the minutes in the elec-tronic versions of our newsletter but they are alwaysavailable for our members to view from our websiteThe site is not completely current at this time as weare in the process of giving it a makeover and newlaunch in January
Click here for the link to viewhttpwwwspecadorgindexphpnavid=28
Board Minutes
CONNECT WITH SPE CAD VIASOCIAL MEDIA
Join SPECADrsquos Group On Linked Into network with industry peers participate in groupdiscussions of industry and technical topics findjob opportunities and get the latest division andconference announcements
Group Name SPE Color amp AppearanceDivision Group ID 152108 wwwlinkedincomgroupsgid=152108
continued from page 14
Colorants for polymers that are suitable for food contactuse according to 21 CFR1783297 by the FDA (Food andDrug Administration) NSF (National SanitationFoundation) listing for Potable water contact applicationsand ASTM toy specifications may further place limitationson which pigments may be used
CONCLUSIONSRotational molding presents specific performance require-ment for colorants due to the process dynamics and end-user application needs High performance organic pig-ments in addition to inorganic pigments provide usefulsolutions for designers and manufacturers of rotationallymolded products However as this market continues togrow due to the many unique product features attributed tothe rotomolding process advancements in pigmentationstabilization resin processes and ancillary products shouldalso grow as well Active research and development in sta-bilization technology continues to advance new productsand uniquely designed chemistries (such as lactone andhydroxylamine process stabilizers) into the market placeNew pigment products such as those based upon DPPchemistry also show promise in rotational molding appli-cations Moreover these new products further broadenproduct development potential by providing ever increas-ing performance and greater value in use
ACKNOWLEDGEMENTSThis paper would not have been possible without the col-laborative efforts os Steve Juhasz and Dick Huska of thePlastics Technical Center in Newport DE and JohnLinehan and Urs Stadler of the Additives DivisionLaboratories in Tarrytown NY Appreciation is also givento colleagues of Ciba Specialty Chemicals PigmentsDivision in Basle Switzerland for additional data
DuPonttrade Ti-Purereg titanium dioxide
DuPont Titanium Technologies8004419485
wwwtitaniumdupontcom
The DuPont Oval DuPont trade The miracles of sciencereg and Ti-Purereg
are trademarks or registered trademarks of EI du Pont de Nemours and Company
POLYMERS LIGHT amp SCIENCE
Polymers Light and the Science of TiO2
BTitanium Dioxide BRutile amp Anatase
BHigh Performance Organic PigmentsB DPP Reds HP Yellows
B PVC AdditivesB Lubricants amp Stabilizers
364 Johnny Mercer Blvd B-7 294 - Savannah GA 31410Tel (912)507-8972 - lwaltersagrofertinccom
wwwagrofertinccom
World Leader in EffectPigments
One International PlazaSuite 300Philadelphia PA 19113(888) 367-3275
wwwemdchemicalscom
A Complete Line of DyestuffsInorganic Pigments and
Organic Pigments forPlastics amp Fibers
LANXESS Corporation111 RIDC Park West Drive 1-800-526-9377Pittsburgh PA 15275-1112 wwwlanxesscom
World Leaders in Ultramarine PigmentswUltramarine Blue wUltramarine VioletwChrome Oxide Green wLead Chromate
wZinc Ferrite wIron Oxide
Phone 77027788196369 Peachtree Street Fax 7702778809Norcross GA 30071 Toll Free 8008866981wwwnubiolacom
We create chemistry for plastics
f
eate chemistry for plastics
basfcomplastic-additiveswww
your plastic applicationsovide solutions for all ofand other additives pr
Our UV light stabilizers antioxidants nucleatorsfect and functional pigments efneeds with color r ef
BASF helps meet your style and functionality
e crWWe cr
eate chemistry for plastics
1 800 431-2360Florham Park NJ
venue100 Park A AvenueBASF Corporation
ovide solutions for all ofOur UV light stabilizers antioxidants nucleators
fect and functional pigmentsBASF helps meet your style and functionality
Color Software ExpertsSince 1986
Quality Control Formulationamp Instrument Profiling
Visit our website and color blogwwwcyberchromeusacom
CyberChrome Inc3642 Main Street tStone Ridge NY 12484
PH 845-687-2671
wwwbasf
Color Concentrates and Single Pigment Dispersionsfor all Thermoplastic Polymers
Corporate Offices400 Old Dublin PikeDoylestown PA 18901(215) 345-6550
Operations amp Research Center2755 Bergey RoadHatfield PA 19440(215) 997-2221wwwpenncolorcom
SPE CAD NEWS Summer 2014 page 16 wwwspecadorg
SPE CAD NEWS Summer 2014 page 17 wwwspecadorg
Special thanks to our our Speakers Sponsors Exhibitors and Participants for your contributions to this yearrsquos CAD RETECreg 2014
Earl Balthazar III CAD RETECreg 2014 Conference Chair Datacolor Inc (817) 719-0224 CAD_RETECtxrrcomMark FreshwaterCAD RETECreg 2014 Vice-ChairLansco Colors(330) 526-8833markpigmentscom
Nathan KarszesCAD RETECreg 2014 Technical Program Co-ChairNubiola Corporation(770) 527-2409nkarszesnubiolacomBrenda MullinsCAD RETECreg2014 Technical Program Co-ChairClariant Corporation(678) 237-2975 brendamullinsclariantcom
SPE CAD NEWS Summer 2014 page 18 wwwspecadorg
LAE
HA WORK AROU
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September 26 2014 ndash 500pm EDT
A SPE ANTECreg
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Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom
Technology forum will be included in the 2014 technicalprogram The panel discussion will be Public Perceptionof Plasticsrdquo Audience response devices will be included soattendees can participate in the discussion The NewTechnology Forum will end the presentations for Mondayand play an excellent transition to the Network Receptionwhich will be held in the exhibit hall
If you have not registered for CAD RETECreg 2014 in NewOrleans I recommend that you visit the CAD website(specadorg) and sign up
I would like to close with an update on the CAD Board ofDirectors I was responsible for the board elections earlierthis year We had sixteen excellent candidatesUnfortunately there were only nine positions This yeartwo new board members were elected Tom Chirayil fromBASF and Pete Zillitto from Sudarshan Please join me inwelcoming Tom and Pete as they begin their 3-year term onthe CAD Board Steve Goldstein Sharon Ehr JamiePrzybyliski Austin H Reid Jr Mark Tyler Steve Eskerand Mark Freshwater were reelected
Best RegardsBetty PuckerinCAD Chairperson
DisclaimerThe information submitted in this publication is based on current knowledge and experience In view of the many factors that may affect processibil-ity and application this datainformation does not relieve processors from the responsibility of carrying out their own tests and experiments neitherdo they imply any legally binding assurance of certain properties or of suitability for a specific purpose It is the responsibility of those to whom thisinformation is supplied to ensure that any proprietary rights and existing laws and legislation are observed
Invitation to Attend Our Board Meetings
The Color and Appearance Division regularly holds Board of Director(BOD) meetings at the ANTECreg and the CAD RETECreg In addi-tion a Summer BOD meeting is typically held about 6 weeks prior tothe next CAD RETECreg
The Summer meeting is scheduled in various locations A WinterBOD meeting is held in January The Winter meeting is typically held at a site of a future CADRETECreg
Any SPE CAD members who wish to attend are welcome at thesemeetings If interested in attending the next Board meeting pleasecontact the Division Chairperson for more information
SPE Color amp Appearance Division Mission Statement
The Color and Appearance Division of SPEstrives to educate train inform and to provideprofessional interaction opportunities to theglobal community involved in visual perform-ance and aesthetics of plastics
SPE CAD NEWS Summer 2014 page 2 wwwspecadorg
Editorrsquo s Note
Welcome to the Summer 2014 Editionof the CAD newsletter This editionshould be hitting your mailboxes just
before the CAD RETECreg which marksthe first time since 1991 the conference has
returned to New Orleans Louisiana Of course most of youwill remember that Hurricane Katrina derailed our plans tovisit the Crescent City back in 2005 and so I for one amreally looking forward to this yearrsquos program
This edition of the newsletter also marks my very first offi-cial action as a member of the CAD BOD which I am veryexcited about Having been in this industry since 1989 andnot knowing color from floor sweepings when I started(and maybe I still donrsquot depending on who you ask) thisis a great opportunity for me to try and give somethingback to an industry thatrsquos helped me pay my bills all theseyears I hope to see you all in The Big Easy next month
SincerelyPete ZillittoGuest Editor
Chairmanrsquo s Message (continued)
ech haintL and PsrrsoloCou Y
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tcatnCo Ch336
moclanoitanretnIh
stgmeniPampvesitidAd
nruChselraCh336-255-6673 nLinruChselraCh
moclanoitanretnIhcetn
Pigments and Additives for the Plastics Industry
Clariant Corporation4000 Monroe Road Charlotte NC 28205Phone 8004414414wwwclariantcom
Leading Manufacturer of Complex Inorganic Color Pigments (CICP) bull Pigment Brown 24 Yellow 53 Blue 28 Green 50 Black 28 etcbull Environmentally Friendly Pigments Brown 48 etcbull Laser Marking Pigmentsbull Pigments for Biodegradable Plastics
Contact in Americas
73 Cavalier Blvd Suite 207 Florence KY 41042TEL (859) 746-0407 FAX (859) 746-0467tomatecamtomateccomWWWTOMATECCOM
HIGH PERFORMANCE PIGMENTS FOR PLASTICSFerros Geodereg Complex Inorganic Color Pigments offer unsurpassed color quality and stability
The complete Geodereg line includesChrome Titanates Cobalt Blues amp Greens Nickel TitanatesHeat stable Blacks Iron Free Browns IR Reflecting Blacks
Ferro Corporation Performance Pigments amp Colors251 West Wylie Avenue PO Box 519Washington PA 15301Phone 724-223-5900Fax 724 223-2700
wwwferrocom
wwwshepherdcolorcom
Lintech has theColors and Pigments
You Need
Newsletter Sponsorship Opportunity
The Color and Appearance Division (CAD) commits to thepublishing of at least three newsletters a year (four if there is
sufficient material to justify the extra issue) Each newsletter iselectronically distributed to our membership of nearly 1000Each sponsorrsquos art directly links to the companyrsquos website
In addition we print one of these newsletters on 80gloss coat-ed stock All electronic versions are also posted on the SPE web-site where it available for anyone to download
For the small donation of $300 per year we offer a business cardsized (2 x 35 inches) mention in our newsletter
We currently have the following slots available for sponsorship
(2) 2 x 35 inch or (1) 4 x 35 inch
If interested in learning more please contactScott Aumann Phone 9122100175Email ScottAumannedmmilliporecom
Additives and Pigments
Contact Charles Chum336-255-6673 CharlesChumLintechinternationalcom
SPE CAD NEWS Summer 2014 page 3 wwwspecadorg
Organic Pigments Inorganic Pigments Pigment Preparations
Heucotech Ltd 99 Newbold Road Fairless Hills PA 19030wwwheubachcolorcom 215-736-0712
Organic amp InorganicPigments and Preparations
(416) 253-4297 hkennedydominioncolourcomwwwdominioncolourcom
D 72209 217 PM Page 1
QUALITY FORMULATION OFCOLOR amp ADDITIVE CONCENTRATES
wwwtechmerpmcom
18420 Laurel Park Road 1 Quality CircleRancho Dominguez CA 90220 Clinton TN 37716(310) 632-9211(865) 457-6700
COMPETENCE IN COLOR
AT KEYSTONE WE PROVIDE A THREE-TIER CUSTOMER-FOCUSED VALUE PROPOSITION
PRODUCTINNOVATIONS
gt KeyplastTM Dyesand Pigments
gt KeyplastTM GraniteSpecial Effects
gt KeyfluorTM OBrsquos andInvisible Fluorescents
gt ReversacolTM
PhotochromaticColorants
ISHIHARA CORPORATION (USA) TiO2 Ultra-fine TiO2
Nickel Titanates Chrome Titanates Conductive Pigments
601 California Street Tel (415) 421-8207San Francisco California 94108 Fax (415) 397-5403
wwwishiharacom
SPE CAD NEWS Summer 2014 page4 wwwspecadorg
CONFERENCE REGISTRATION
SPE Member RegistrationMust include valid SPE e-mail address with registration $440
SPE Non-Member Registration - Includes 1 Year Membership $590Membership will be processed after RETEC
SPE Non-Member Registration Without SPE Membership $650Conference registration but decline the One Year SPE membership
OTHER REGISTRATION TYPES
SpeakerModerator Registration $170Must be a speaker or moderator at the conference for this registration type This does not include New Technology Forum Speakers
2014 CAD RETECreg Conference Committee Member Registration $170Must be a member of the 2014 CAD RETECreg organizing committee to qualify for this registration type
Student Registration $ 50Must have valid Student ID and working part-time or full-time and paying own travel expenses
SPE Emeritus Member Registration $100Option available for SPE Emeritus Members
SPE Membership Renewal $100Renew your existing SPE membership Requires SPE membership e-mail address to ensure continued membership status Note membership renewal may not be processed until after RETECreg
Tabletop Exhibit Space (if still available) $950Includes two free conference registrations with tabletop Provide names and titles of both attendees in the appropriate fields at the end of this form
The 52st Annual Society of Plastics Engineers Color and Appearance Division CAD RETECreg is located near New OrleansFrench Quarter and will serve as an excellent setting for the theme of this yearrsquos CAD RETECreg ldquoIts a Colorful WorldrdquoCAD RETECreg is the largest technical conference hosted in North America that is specifically dedicated to the color andappearance of plastics
If you have not already registered there is still time to attend the conference A special thanks to all our sponsors organizers and particpants for your involvement creativity and talent
Earl BalthazarConference Chair
2014 SPE CAD RETECreg
ebalthazartxrrcom
CLICK HERE to Register orsee detailed informaton
SPE CAD NEWS Summer 2014 page 5 wwwspecadorg
CAD RETECreg REGISTRANT FORM (Please Print)
SPE Membership Name Address Title
Company
Country of CitizenshipEmailDaytime Phone Date
For Credit Card Payments OnlyCircle One AMEX VISA MasterCardCard No Expiration Date Name on card (if different from above)___________________________________________Signature
If paying by credit card fax to 859-372-6382 ore-mail to brucemulhollandticonacom
REGISTER ONLINE AT wwwspecadorg
For checks make in US dollars only payable to ldquoSPE CADrdquo
Refunds less a $30 fee August 16 to September 5 2014 No refunds after September 5 2014 SPE Memberships are processed after RETEC
If paying by credit card fax to 859-372-6382 ore-mail to brucemulhollandticonacom
REGISTER ONLINE AT wwwspecadorg
CIRCLE ANSWERS BELOW
Is this your first CAD RETECreg Yes No
If no have you attended a CAD RETECreg
in the last five years Yes No
EXTRA CONFERENCE LITERATURE
Additional Copy Conference Proceedings $115 X ____ = $________Additional CAD RETECreg 2014 conference proceedings download pass One copy is already included with each paid registration
SPE CAD Archive DVD (1961 - 2007) and $175 X ____ = $________Color Papers from 1961-2007 ANTEC amp RETEC available on-siteSpecial RETECreg Offer $175 (must also register for the RETECreg conference)Savings from the regular price of $200 for SPE members and $300 for non-members
OTHER EVENT REGISTRATIONRSVP
Sunday Golf Outing $130 X ____ = $________Sunday golf outing at TPC Louisiana If registering more than yourself for golf
please include their names using the tabletop names amp titles fields at the bottom of the
registration page This will allow you to list up to four names using those fields
5K Fun RunWalk $20 X ____ = $________Sign up for Tuesday AM 5K Fun RunWalk CAD will match the $20 donation for charity
Total due from all items checked $_________________
QR CAD mobile app for Android Apple and Windows mobile devices
GOLF OUTING INFORMATION
SPE CAD NEWS Summer 2014 page 6 wwwspecadorg
Price $13000 per golfer
Includes Warm up on the RangeGreen FeesCart FeeScramble formatBox Lunch with DrinkCustomized TPC Bag Tag
Course LocationTPC Louisiana11001 Lapalco BlvdAvondale LA 70094(504) 4368721
Registration 1100 am (CST) Shotgun Start 12 noon (CST)Awards Will be presented at CAD RETECreg
Welcoming Reception
September 14 2014
To Sign Up Online RegistrationQuestions Contact
Mark Tylermarktylercelanesecom 8593723221 or
Mark Freshwatermarkpigmentscom 2016650091
SPE CAD NEWS Summer 2014 page 7 wwwspecadorg
900 am - Golf Outing300 pm
100pm - Registration Desk Open600 pm
100pm - EXHIBITOR SET-UP530 pm
600 pm Welcome Reception Sponsors EMD Chemicals and Kronos800 pm (Pick up your registration packet prior to this event to get your complimentary drink coupons)
Golf Outing Prizes will be presented at the Welcome Reception
730 BREAKFAST (Biffon A) Sponsor Lansco730 Registration Desk Opens
MORNING SESSION MODERATOR BRUCE MULHOLLAND CELANESE815 OPENING REMARKS Earl Balthazar
830 KEYNOTE Public Percepton of Plastics Rudy Underwood American Chemistry Council
930 The Global Economy-Precariousness of Supply Chain Globalization of Regulations and How to Protect YourselfBruce Howie Dominion Color
1000 COFFEE BREAK Sponsor Clariant
1030 Fundamentals of Twin-Screw Extrusion- Color MB Prossessing Common Pitfalls and How to Avoid ThemPaul G Anderson Coperion
1100 Influence of TiO2 Feeding on Twin Screw Extrusion Compounding JD Connolly DuPontTitanium Technologies
1130 Dispersion of Pigments in Plastics Applications Mahesh Mettelloo Sudarshan
1230 - 130 LUNCH (on your own)
CAD RETEC 2014reg
SUNDAY September 14
MONDAY MORNING (Mardi Gras Ballroom) September 15
CONFERENCE HOTEL INFORMATIONMarriott New OrleansTo Reserve by Phone 504-581-1000 or 1-888-364-1200Request Group Rate Society of Plastics Engineers - Color amp Appearance Division
MARRIOTT NEW ORLEANS555 Canal Street New Orleans Louisiana 70130 Phone 504-581-1000 Toll Free 1-888-364-1200
Discounted Conference Room Rate $159night-single occupancyRoom Block Dates Sept 12-17
Rates will increase significantly after August 15 2014 at 5pm or whenever the room block is full Cancellation policy Any hotel reservation canceled within 48 hours of arrival date will be charged for one (1) nights room and tax
AFTERNOON SESSION MODERATOR NATHAN KARSZES NUBIOLA130 Panel Discussion
Audience Response Devices will be available to each audience member for responding to poll questions during the panel discussion
300 COFFEE BREAK Sponsor Shepherd
330 Pigments for Sensitive Applications Tom Chirayil BASF
400 Advances in Liquid Color Technology Inga Lesko Clariant BU Masterbatch
430 New Technology Forum (pdf) Moderator Sandra Davis
500 NETWORKING RECEPTION Sponsor Nubiola
700 5K Fun RunWalk for Habitat for Humanity Plastics (Pregister for this event) Sponsor Dominion
730 BREAKFAST(on your own)
MORNING SESSION MODERATOR AUSTIN REID DUPONT TITANIUM TECHNOLOGIES
900 Colorants for Plastics-Emerging Trends and Technologies Krishnamoorthy Sivakumar PolyOne
930 Iron OxidesInorganic Pigments for Plastics George Podolsky Rockwood Pigments
1000 COFFEE BREAK Sponsor DuPont
1030 Blue Undertone Enhancement of Black and Grey PP Injection Molded PP Nathan Karszes Nubiola
1100 Lighter Faster Stronger Additive Solutions for Automotive Plastics Emilie Meddah Clariant BU Additives
1130 Gaining Competitive Advantage through Digital Appearance Technology in the Automotive Interior Supply ChainPhil Ruggiero Datacolor
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130 Inorganic Pigments From Caveman to the 21st Century Mark Ryan Shepherd Company
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230 COFFEE BREAK Sponsor Munzing
300 Effects of Disinfectant Grade Cleaner on Physical Properties of Cell Phone Cases Diane McLendonOtterbox
330 Its a Colorful World Developing Technologies to Keep it that Way Joseph Fay BASF
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Must be present to win
MONDAY AFTERNOON (Mardi Gras Ballroom) September 15
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SPE CAD NEWS Summer 2014 page 8 wwwspecadorg
SPE CAD NEWS Summer 2014 page 9 wwwspecadorg
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SPE CAD NEWS Spring 2014 page 10 wwwspecadorg
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T H E G O L D S T A N D A R D I N P L A S T I C S
Thank you RETECreg 2014 Sponsors
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Pigments colour the world
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C R e A t i N g A d d i t i v e v A L u e
LANSCO COLORS
E C K A R TEffect Pigments
High Performance Pigments for Demanding Applications Rotational MoldingJoseph J Fay PhD amp Peter Zillitto
Plastics Technical Center Pigments DivisionCiba Specialty Chemicals Corporation
Technical Article
INTRODUCTIONColorants for polymer applications are typically incorporated into the polymer by one of several common pathways Colorconcentrates which are widely used in industry enable the end user to conveniently meter in the colorant at the prescribedration with virgin or uncolored polymer in the manufacturing process The benefits of concentrate used as compared to thedirect use of powder pigment during final product conversion processes include predispersion of the pigment in a suit-able carrier system elimination of the need to in-house compounding to incorporate the colorant uniformly and improvedhousekeeping etc Furthermore color concentrates are available ina number of product forms including pelleted concen-trates liquid color systems and pastes the latter used especially for PVC For polymer conversion processes in which anextruder or meld mixing devise is employed these colorant preparations can be used very effectively In some marketswhere high levels of functional fillers modifiers or polymer blends are used compounders may manufacture ldquoprecoloredrdquopolymer by direct addition of the colorant to their compounding line In come cases concentrates are used depending uponspecific product and process capabilities
Rotational molding in contrast is a low shear process in which traditional pellet form color concentrates are not suitableColoration of rotomolding resin is commonly obtained by the use of dry color and liquid color which can be added direct-ly to the ground rotomolding resin Alternatively precolored resin in which the pigment is compounded into to the poly-mer and then ground before use finds applications as well More recently micropellet technology has been advanced as an alternative to the aforementioned methods It is similar to precompounded color but the need for grinding the polymerinto the appropriate mesh size is eliminated as the micropellets can be rotomolded without further processing For each ofthese color incorporation methods there are advantages and disadvantages including economic factors (process equipmentand material cost) ease of use housekeeping and overall quality (physical properties and aesthetics) of the resulting part
As a consequence of the myriad applications the palette of pigments for rotational molding appears to be quite extensivesimilar to that which is used in general purpose polyethylene application requirements However due to the specific processconditions involved in preparing the pigment system the temperature profile of the rota-tional molding process and the end use application requirement the gamut of pigments issignificantly reduced
Pigment selection may also be affected by the method by which the pigment is to be deliv-ered Liquid colorant systems work best with pigments that have the potential to be loadedto high weight percentages while maintaining suitable viscosity Pigments used in drycolor require characteristics that impart dispersibility and minimize agglomeration duringboth dry color manufacture and blending with the rotomolding resin
DISPERSIONWhen pigments are manufactured the smallest pigment particles formed are discreet units referred to as primary particlesAs a result of their high surface energy these particles randomly join together to form aggregates and agglomerates thelatter being formed primarily during subsequent filtration a nd drying processes To achieve a speck-free system the pig-ment must be effectively ldquodispersedrdquo so that the individual pigment particles or aggregates are wetted by the polymer anddiscrete pigment particles are not visible to the naked eye Rotomolding pigment systems (liquid color and dry color) needto be prepared in a manner that ensures visible agglomerates are eliminated and that during subsequent mixing with therotomolding resin the colorant system will be easily distributed Furthermore the dispersion of the pigment needs to effec-tively deliver a colorant that will provide a high color strength potential to maximize economic while not adversely affect-ing other properties Figure 1 illustrates the particle size of the typical azoncondensation pigment continued on page 12
SPE CAD NEWS Summer 2014 page 11 wwwspecadorg
The following Technical Article was published in 1998 at The Color And Appearance Conference in September
continued from page 11
Note that the particle size distribution that would beobtained in a polymeric system will be very dependentupon the effectiveness of the final dispersion
HIGH PERFORMANCE PIGMENTSHigh performance pigments HPP can be defined as pig-ments that have either very good to excellent heat or lightstability and more commonly pigments which offer aunique combination of both heat and light stability Theenhanced UV and heat performance attributes of HPPs setthem apart from traditional or classical pigments such asthe lithol rubines (PR 571) lake red C (PR 531) 2B toner(PR 48 types) monoaso yellows such as PY 62 and oth-ers which have only limited heat stability and mostly mar-ginal to poor lightfastness
The major types of high performance pigment chemistriescan be described in a general fashion as indicated in Table 1Some individual pigments within these chemistries mayhave better or worse performance characteristics depend-ing upon the specific product attribute and applicationbeing considered
HEAT STABILITYOrganic pigments are available not only with a wide vari-ety of hues and chroma but also with considerable variationin performance characteristics Rotational molding withits combination of relatively long cycle times high moldsurface temperatures and abundance of oxygen is moredemanding upon the polymer stabilization package andpigmentation in comparison to many other processes As aconsequence many rotomolded product applicationsrequire the use of higher performance pigments to survivethe molding process even though the pigment with regardto final product requirements may be viewed as ldquoover engi-neeredrdquo Classical pigments such as 2B reds (CI PigmentRed 48rsquos) with only limited thermal stability in high tem-perature olefin polymer applications may not be suitablefor even non durable articles as the color stability duringmolding may be insufficient Figure 2 compares the heatstability of a calcium 2B toner with high performance dike-topyrrolo-pyrrole (DPP) and quinacridone (QA)chemistries In masstone applications it is readily apparentthat the 2B toner is quite deficient when compared withthese high heat stability pigments Furthermore as pigment
SPE CAD NEWS Summer 2014 page 12 wwwspecadorg
heat stability is generally related to concentration at lowerconcentrations the 2B toner would become even moreprone to color change In addition to pigment instabilitycolor change during rotational molding may be affected byother factors The stability of the base resin is an importantconsideration The role of the antioxidant package is criti-cal to controlling the initial color and maintaining the phys-ical properties of the rotomolding resin Judicious selectionof a phenolic antioxidant and phosphite processing stabi-lizer package is essential for the base polymer Dependingupon specific circumstances additional antioxidant mightbe added The most effective stabilization is typicallyobtained when the antioxidant is added directly to the resinitself during manufacture or during compounding whenrecolored resin is prepared For specialty applications
where additional antioxidants are needed to attain the req-uisite performance precolored or preformulated resinwhich is then ground provides additional benefit
LIGHT STABILITYMany applications of rotationally molded articles find enduses which require UV durability These UV performanceapplications encompass a broad variety of applications andmarkets residential waste containers childrenrsquos play-ground toys (both for residential and institutional uses)outdoor sporting goods (kayaks and component of otherrecreational vehicles) and oversize containers (industrialcontainers and agricultural tanks) For outdoor applica-tions careful formulation is required to achieve not onlysuitable color match but also a color combination whichwill have the desired weatherability As delineated inFigure 3 Calcium 2B toners have limited light stability inpolyolefin applications and are not recommended for usewhere any significant UV exposure is intended Althoughnot reflected in the colorimetric data the 2B toner samplesurface was significantly marred by chalking and surfacemicrocracking and is visible via low magnification optical
Quinacridone Copper PhthalocyanineDiketopyrrolo-pyrrole (DPP) AnthraquinoneTetrachchloroisoindolinone IndanthroneAzochondensation PeryleneBenzimidozone Isoindoline
Table 1 High Performance Chemistry Families
continued from page 12
SPE CAD NEWS Summer 2014 page 13 wwwspecadorg
microscopy Such microcracks may ultimately result inpremature physical failures of the product Therefore visu-al inspection of samples following accelerated or real-timeexposure testing is imperative to ensure complete perform-ance analysis As a consequence of the limited weather-ability of many pigments performance assessment is need-ed Applications such as point of sale displays and relateditems and indoor applications where incidental UV expo-sure from lighting fixtures or nearby windows is possibleare best formulated with durable HPP pigments Outdoorapplications require the use of HPP pigments at levels thatcan provide sufficient levels of weather resistance
Figure 5 illustratesthe difference inlong-term UV sta-bility that wasobtained when aDPP red (PR254) was com-pared with a pery-lene red (PR178) Perylenepigments areprone to darken-ing when used inconjunction withhindered amine light stabilizers (HALS) whereas no suchnegative interaction has been observed for DPPchemistries
Other high performance pigment classes such as copperphthalocyanine blue pigments may also be suitable foroutdoor applications when properly formulated PB 151and PB 153 are widely used in rotational molding appli-cations as a consequence of their outstanding performanceproperties Figure 6 and tremendous value in use
Inorganic and heavy metal pigments are also widely usedin some rotational molding applications due to their general-ly good dispersibility characteristics and in many cases thecleanliness of shade that may be obtained when using cer-tain cadmium and lead chromate pigments However aswill be discussed in greater detail regulatory pressureshave resulted in heavy metal deselection in several appli-
cation areas including food packaging and many toy appli-cations There applications however have not always beeneasily reformulated The use of HPP products providesalternatives in many color space applications Additionallywith the recent introduction of several new DPP productsPR 264 (Figure 7) PR 272 and PO 71 and PO 73(Figure 8) into the polyolefin and PVC market areas agreater breadth of high performance organics is availablefor formulating In some case differences in the perform-ance of organic versus heavy metal pigments may result inadditional raw material costs Material selection and mod-ification of base stabilization are required in some casesand additional light stabilization packages are needed
continued on page 14
continued on page 15
continued from page 13
SPE CAD NEWS Summer 2014 page 14 wwwspecadorg
especially when formulating polyolefins for outdoor appli-cations to provide comparable alternatives Nonethelessconsumers (materials specifiers manufacturers and theultimate product purchaser) choosing to avoid use of cad-mium and lead pigments wherever reasonably possibleremains a continuously evolving trend
The formulation of rotationally molded articles for outdoorapplications requires the use of both suitable pigments aswell as the assistance of a well-designed light stabilizerpackage The use of tetramethyl piperidine based hinderedamine light stabilizers especially oligomeric and highmolecular weight types in combination with benzotriazolebased UV absorbers are recommended for use in a varietyof applications The total package loading should be tai-lored to meet the specified requirement of the application
DISTORTION EFFECTSDistortion of rotomolded articles can be effected by sever-al different variables Resin choice and the particular mate-rial being used can affect warpage and shrinkageDifferences in cooling of the mold thickness variationsovercuring and several other process parameters have beenfound to be related to warping Since pigments (and thesystems used to deliver them) may alter the flow character-istics of the polymer and also the cure characteristics oper-ation of a given mold with different pigments or colorantsystems with a single cure cycle may result in differencesin dimensional stability The use of controlled heating andcooling as well as good control over the process itself willhelp to ensure consistent part manufacturing as well as agood data and record keeping can be referred to in case oferratic part quality
IMPACT PROPERTIESImpact properties are commonly tested as a means ofassessing the quality and suitability of colorant systems aswell as for assessing the cure characteristics of the polymerand the properties of the final product The ARM(Association of Rotational Molders) impact test is a com-mon test that is used Alternative instrumented testing pro-vides similar test result capabilities with the advantage ofquantitative and qualitative data acquisition
Impact properties of rotomolded products are importantMany toys containers and other applications require assur-ances of product integrity which can often be affected notonly by the process conditions but also by the incorpora-tion of pigments and other additives Since there is very lit-tle shear in the rotomolding process pigments are likely tobe located at the grain boundary between adjacent polymergranules This localization of pigment and ldquoadditivesrdquo can adversely affect physical properties in sev-eral ways Inhibition of polymer chain entanglementsbetween particles due to additives that form an interfacebetween resin particles can result in weak distinct bound-aries with poor mechanical properties Also pigmentagglomerates which are not broken apart or more trou-bling when they are formed during premixing processesdue to excessive mixing may introduce point defectseffecting physical properties Aesthetic properties may alsobe impacted if agglomerates are present in either signifi-cant size or number Pigment loading which is related toboth the effectiveness in which the pigment can be dis-persed as well as the color requirements of the part isanother factor to be considered in assessing the potentialeffect of coloration on physical properties
REGULATORY ASPECTSWith the variety of applications encountered in rotationalmolding well-publicized legislation and public opinionhave compelled many plastics processors and end-users touse alternatives to cadmium and lead based pigmentsCONEG (COalition of NorthEast Governors) related legis-lation prohibits the sale of packaging materials to whichcadmium lead mercury and hexavalent chromium or theircompounds have been intentionally added Reducing theamount of these elements entering the food chain via wastedisposal sources and the extra precautions needed to dis-pose of post industrial wastes are issues to be addressesCertainly both lead and cadmium-based pigments possessa combination of desireable technical properties that makesthem articularly useful coloring materials for polymersLead based pigments furthermore are particularly eco-nomical in use Nonetheless public opinion and legislationhave had and will likely continue to have a significantimpact on their use particularly in consumer goods
SPE CAD NEWS Summer 2014 page 15 wwwspecadorg
The Color and Appearance Division (CAD) is commit-ted to the publishing of at least three newsletters a year(four if there is sufficient material to justify the extraissue) To that end we would like you to think aboutthe financial side of sponsorship of the newsletter Forthe small donation of $300 per year we offer a businesscard sized (2 x 35) mention in our newsletter whichgoes out to the nearly 1500 members of the CAD aswell as other SPE division members These are peopleactive in every aspect of plastic coloring and additivetechnology Larger sized spots are available at a com-mensurate increase in rate
If you are interested in helping to sponsor theSPECAD Newsletter please contactScott Aumann Phone 912 210 0175
Email ScottAumannedmmilliporecom
Your Company Our Division
Dear Members
Just a reminder that you can view past and currentBOARD MINUTES on the SPECAD website
We do not typically publish the minutes in the elec-tronic versions of our newsletter but they are alwaysavailable for our members to view from our websiteThe site is not completely current at this time as weare in the process of giving it a makeover and newlaunch in January
Click here for the link to viewhttpwwwspecadorgindexphpnavid=28
Board Minutes
CONNECT WITH SPE CAD VIASOCIAL MEDIA
Join SPECADrsquos Group On Linked Into network with industry peers participate in groupdiscussions of industry and technical topics findjob opportunities and get the latest division andconference announcements
Group Name SPE Color amp AppearanceDivision Group ID 152108 wwwlinkedincomgroupsgid=152108
continued from page 14
Colorants for polymers that are suitable for food contactuse according to 21 CFR1783297 by the FDA (Food andDrug Administration) NSF (National SanitationFoundation) listing for Potable water contact applicationsand ASTM toy specifications may further place limitationson which pigments may be used
CONCLUSIONSRotational molding presents specific performance require-ment for colorants due to the process dynamics and end-user application needs High performance organic pig-ments in addition to inorganic pigments provide usefulsolutions for designers and manufacturers of rotationallymolded products However as this market continues togrow due to the many unique product features attributed tothe rotomolding process advancements in pigmentationstabilization resin processes and ancillary products shouldalso grow as well Active research and development in sta-bilization technology continues to advance new productsand uniquely designed chemistries (such as lactone andhydroxylamine process stabilizers) into the market placeNew pigment products such as those based upon DPPchemistry also show promise in rotational molding appli-cations Moreover these new products further broadenproduct development potential by providing ever increas-ing performance and greater value in use
ACKNOWLEDGEMENTSThis paper would not have been possible without the col-laborative efforts os Steve Juhasz and Dick Huska of thePlastics Technical Center in Newport DE and JohnLinehan and Urs Stadler of the Additives DivisionLaboratories in Tarrytown NY Appreciation is also givento colleagues of Ciba Specialty Chemicals PigmentsDivision in Basle Switzerland for additional data
DuPonttrade Ti-Purereg titanium dioxide
DuPont Titanium Technologies8004419485
wwwtitaniumdupontcom
The DuPont Oval DuPont trade The miracles of sciencereg and Ti-Purereg
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World Leaders in Ultramarine PigmentswUltramarine Blue wUltramarine VioletwChrome Oxide Green wLead Chromate
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Phone 77027788196369 Peachtree Street Fax 7702778809Norcross GA 30071 Toll Free 8008866981wwwnubiolacom
We create chemistry for plastics
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Visit our website and color blogwwwcyberchromeusacom
CyberChrome Inc3642 Main Street tStone Ridge NY 12484
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Corporate Offices400 Old Dublin PikeDoylestown PA 18901(215) 345-6550
Operations amp Research Center2755 Bergey RoadHatfield PA 19440(215) 997-2221wwwpenncolorcom
SPE CAD NEWS Summer 2014 page 16 wwwspecadorg
SPE CAD NEWS Summer 2014 page 17 wwwspecadorg
Special thanks to our our Speakers Sponsors Exhibitors and Participants for your contributions to this yearrsquos CAD RETECreg 2014
Earl Balthazar III CAD RETECreg 2014 Conference Chair Datacolor Inc (817) 719-0224 CAD_RETECtxrrcomMark FreshwaterCAD RETECreg 2014 Vice-ChairLansco Colors(330) 526-8833markpigmentscom
Nathan KarszesCAD RETECreg 2014 Technical Program Co-ChairNubiola Corporation(770) 527-2409nkarszesnubiolacomBrenda MullinsCAD RETECreg2014 Technical Program Co-ChairClariant Corporation(678) 237-2975 brendamullinsclariantcom
SPE CAD NEWS Summer 2014 page 18 wwwspecadorg
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September 26 2014 ndash 500pm EDT
A SPE ANTECreg
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Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom
ech haintL and PsrrsoloCou Y
he tsech hastgmeni and P
Needou
cetLinwww
A
tcatnCo Ch336
moclanoitanretnIh
stgmeniPampvesitidAd
nruChselraCh336-255-6673 nLinruChselraCh
moclanoitanretnIhcetn
Pigments and Additives for the Plastics Industry
Clariant Corporation4000 Monroe Road Charlotte NC 28205Phone 8004414414wwwclariantcom
Leading Manufacturer of Complex Inorganic Color Pigments (CICP) bull Pigment Brown 24 Yellow 53 Blue 28 Green 50 Black 28 etcbull Environmentally Friendly Pigments Brown 48 etcbull Laser Marking Pigmentsbull Pigments for Biodegradable Plastics
Contact in Americas
73 Cavalier Blvd Suite 207 Florence KY 41042TEL (859) 746-0407 FAX (859) 746-0467tomatecamtomateccomWWWTOMATECCOM
HIGH PERFORMANCE PIGMENTS FOR PLASTICSFerros Geodereg Complex Inorganic Color Pigments offer unsurpassed color quality and stability
The complete Geodereg line includesChrome Titanates Cobalt Blues amp Greens Nickel TitanatesHeat stable Blacks Iron Free Browns IR Reflecting Blacks
Ferro Corporation Performance Pigments amp Colors251 West Wylie Avenue PO Box 519Washington PA 15301Phone 724-223-5900Fax 724 223-2700
wwwferrocom
wwwshepherdcolorcom
Lintech has theColors and Pigments
You Need
Newsletter Sponsorship Opportunity
The Color and Appearance Division (CAD) commits to thepublishing of at least three newsletters a year (four if there is
sufficient material to justify the extra issue) Each newsletter iselectronically distributed to our membership of nearly 1000Each sponsorrsquos art directly links to the companyrsquos website
In addition we print one of these newsletters on 80gloss coat-ed stock All electronic versions are also posted on the SPE web-site where it available for anyone to download
For the small donation of $300 per year we offer a business cardsized (2 x 35 inches) mention in our newsletter
We currently have the following slots available for sponsorship
(2) 2 x 35 inch or (1) 4 x 35 inch
If interested in learning more please contactScott Aumann Phone 9122100175Email ScottAumannedmmilliporecom
Additives and Pigments
Contact Charles Chum336-255-6673 CharlesChumLintechinternationalcom
SPE CAD NEWS Summer 2014 page 3 wwwspecadorg
Organic Pigments Inorganic Pigments Pigment Preparations
Heucotech Ltd 99 Newbold Road Fairless Hills PA 19030wwwheubachcolorcom 215-736-0712
Organic amp InorganicPigments and Preparations
(416) 253-4297 hkennedydominioncolourcomwwwdominioncolourcom
D 72209 217 PM Page 1
QUALITY FORMULATION OFCOLOR amp ADDITIVE CONCENTRATES
wwwtechmerpmcom
18420 Laurel Park Road 1 Quality CircleRancho Dominguez CA 90220 Clinton TN 37716(310) 632-9211(865) 457-6700
COMPETENCE IN COLOR
AT KEYSTONE WE PROVIDE A THREE-TIER CUSTOMER-FOCUSED VALUE PROPOSITION
PRODUCTINNOVATIONS
gt KeyplastTM Dyesand Pigments
gt KeyplastTM GraniteSpecial Effects
gt KeyfluorTM OBrsquos andInvisible Fluorescents
gt ReversacolTM
PhotochromaticColorants
ISHIHARA CORPORATION (USA) TiO2 Ultra-fine TiO2
Nickel Titanates Chrome Titanates Conductive Pigments
601 California Street Tel (415) 421-8207San Francisco California 94108 Fax (415) 397-5403
wwwishiharacom
SPE CAD NEWS Summer 2014 page4 wwwspecadorg
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The 52st Annual Society of Plastics Engineers Color and Appearance Division CAD RETECreg is located near New OrleansFrench Quarter and will serve as an excellent setting for the theme of this yearrsquos CAD RETECreg ldquoIts a Colorful WorldrdquoCAD RETECreg is the largest technical conference hosted in North America that is specifically dedicated to the color andappearance of plastics
If you have not already registered there is still time to attend the conference A special thanks to all our sponsors organizers and particpants for your involvement creativity and talent
Earl BalthazarConference Chair
2014 SPE CAD RETECreg
ebalthazartxrrcom
CLICK HERE to Register orsee detailed informaton
SPE CAD NEWS Summer 2014 page 5 wwwspecadorg
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SPE Membership Name Address Title
Company
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REGISTER ONLINE AT wwwspecadorg
For checks make in US dollars only payable to ldquoSPE CADrdquo
Refunds less a $30 fee August 16 to September 5 2014 No refunds after September 5 2014 SPE Memberships are processed after RETEC
If paying by credit card fax to 859-372-6382 ore-mail to brucemulhollandticonacom
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in the last five years Yes No
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Additional Copy Conference Proceedings $115 X ____ = $________Additional CAD RETECreg 2014 conference proceedings download pass One copy is already included with each paid registration
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OTHER EVENT REGISTRATIONRSVP
Sunday Golf Outing $130 X ____ = $________Sunday golf outing at TPC Louisiana If registering more than yourself for golf
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SPE CAD NEWS Summer 2014 page 6 wwwspecadorg
Price $13000 per golfer
Includes Warm up on the RangeGreen FeesCart FeeScramble formatBox Lunch with DrinkCustomized TPC Bag Tag
Course LocationTPC Louisiana11001 Lapalco BlvdAvondale LA 70094(504) 4368721
Registration 1100 am (CST) Shotgun Start 12 noon (CST)Awards Will be presented at CAD RETECreg
Welcoming Reception
September 14 2014
To Sign Up Online RegistrationQuestions Contact
Mark Tylermarktylercelanesecom 8593723221 or
Mark Freshwatermarkpigmentscom 2016650091
SPE CAD NEWS Summer 2014 page 7 wwwspecadorg
900 am - Golf Outing300 pm
100pm - Registration Desk Open600 pm
100pm - EXHIBITOR SET-UP530 pm
600 pm Welcome Reception Sponsors EMD Chemicals and Kronos800 pm (Pick up your registration packet prior to this event to get your complimentary drink coupons)
Golf Outing Prizes will be presented at the Welcome Reception
730 BREAKFAST (Biffon A) Sponsor Lansco730 Registration Desk Opens
MORNING SESSION MODERATOR BRUCE MULHOLLAND CELANESE815 OPENING REMARKS Earl Balthazar
830 KEYNOTE Public Percepton of Plastics Rudy Underwood American Chemistry Council
930 The Global Economy-Precariousness of Supply Chain Globalization of Regulations and How to Protect YourselfBruce Howie Dominion Color
1000 COFFEE BREAK Sponsor Clariant
1030 Fundamentals of Twin-Screw Extrusion- Color MB Prossessing Common Pitfalls and How to Avoid ThemPaul G Anderson Coperion
1100 Influence of TiO2 Feeding on Twin Screw Extrusion Compounding JD Connolly DuPontTitanium Technologies
1130 Dispersion of Pigments in Plastics Applications Mahesh Mettelloo Sudarshan
1230 - 130 LUNCH (on your own)
CAD RETEC 2014reg
SUNDAY September 14
MONDAY MORNING (Mardi Gras Ballroom) September 15
CONFERENCE HOTEL INFORMATIONMarriott New OrleansTo Reserve by Phone 504-581-1000 or 1-888-364-1200Request Group Rate Society of Plastics Engineers - Color amp Appearance Division
MARRIOTT NEW ORLEANS555 Canal Street New Orleans Louisiana 70130 Phone 504-581-1000 Toll Free 1-888-364-1200
Discounted Conference Room Rate $159night-single occupancyRoom Block Dates Sept 12-17
Rates will increase significantly after August 15 2014 at 5pm or whenever the room block is full Cancellation policy Any hotel reservation canceled within 48 hours of arrival date will be charged for one (1) nights room and tax
AFTERNOON SESSION MODERATOR NATHAN KARSZES NUBIOLA130 Panel Discussion
Audience Response Devices will be available to each audience member for responding to poll questions during the panel discussion
300 COFFEE BREAK Sponsor Shepherd
330 Pigments for Sensitive Applications Tom Chirayil BASF
400 Advances in Liquid Color Technology Inga Lesko Clariant BU Masterbatch
430 New Technology Forum (pdf) Moderator Sandra Davis
500 NETWORKING RECEPTION Sponsor Nubiola
700 5K Fun RunWalk for Habitat for Humanity Plastics (Pregister for this event) Sponsor Dominion
730 BREAKFAST(on your own)
MORNING SESSION MODERATOR AUSTIN REID DUPONT TITANIUM TECHNOLOGIES
900 Colorants for Plastics-Emerging Trends and Technologies Krishnamoorthy Sivakumar PolyOne
930 Iron OxidesInorganic Pigments for Plastics George Podolsky Rockwood Pigments
1000 COFFEE BREAK Sponsor DuPont
1030 Blue Undertone Enhancement of Black and Grey PP Injection Molded PP Nathan Karszes Nubiola
1100 Lighter Faster Stronger Additive Solutions for Automotive Plastics Emilie Meddah Clariant BU Additives
1130 Gaining Competitive Advantage through Digital Appearance Technology in the Automotive Interior Supply ChainPhil Ruggiero Datacolor
1200 AWARDS LUNCHEON PRESERVATION HALL (Included with Registration) Sponsor Tronox
AFTERNOON SESSION MODERATOR JIM FIGANIAK
130 Inorganic Pigments From Caveman to the 21st Century Mark Ryan Shepherd Company
200 Measurement Technology to Evaluate Light Protection What You See May Not Be What You ProtectPhil Miedenzu DuPont Titanium Technologies
230 COFFEE BREAK Sponsor Munzing
300 Effects of Disinfectant Grade Cleaner on Physical Properties of Cell Phone Cases Diane McLendonOtterbox
330 Its a Colorful World Developing Technologies to Keep it that Way Joseph Fay BASF
400 Closing Remarks - Earl Balthazar Survey Raffle - MC-Tracy Phillips Uniform Color Grand Prize TBDOther Prizes Archive DVD Free Night at Westin Free Registration at CAD RETECreg 2015 Emergency RadioCAD RETECreg Limited Edition Art
Must be present to win
MONDAY AFTERNOON (Mardi Gras Ballroom) September 15
TUESDAY MORNING September 16
TUESDAY AFTERNOON (Mardi Gras Ballroom) September 16
SPE CAD NEWS Summer 2014 page 8 wwwspecadorg
SPE CAD NEWS Summer 2014 page 9 wwwspecadorg
Lobby of New Orleans Marriott 555 Canal Street
FREE T-SHIRT FOR THEFIRST 40 RUNNERS
September 16th 7am
$20 Registration Fee bullAll proceeds go to Habitat for HumanitySPE CAD will match every $20 donation
dominioncolourcom
sponsored by
Sponsored by
SPE CAD NEWS Spring 2014 page 10 wwwspecadorg
Gold Level Sponsors
Platinum Level Sponsors
Silver Level Sponsors
WE ARE PROUD TO HIGHLIGHT THESE EXCELLENT COMPANIESPlease visit our generous sponsorsrsquo websites by clicking on their logos below
T H E G O L D S T A N D A R D I N P L A S T I C S
Thank you RETECreg 2014 Sponsors
Cappelle
Celanese
LTL Color Compounders Inc
Pigments colour the world
our passion your colors
C R e A t i N g A d d i t i v e v A L u e
LANSCO COLORS
E C K A R TEffect Pigments
High Performance Pigments for Demanding Applications Rotational MoldingJoseph J Fay PhD amp Peter Zillitto
Plastics Technical Center Pigments DivisionCiba Specialty Chemicals Corporation
Technical Article
INTRODUCTIONColorants for polymer applications are typically incorporated into the polymer by one of several common pathways Colorconcentrates which are widely used in industry enable the end user to conveniently meter in the colorant at the prescribedration with virgin or uncolored polymer in the manufacturing process The benefits of concentrate used as compared to thedirect use of powder pigment during final product conversion processes include predispersion of the pigment in a suit-able carrier system elimination of the need to in-house compounding to incorporate the colorant uniformly and improvedhousekeeping etc Furthermore color concentrates are available ina number of product forms including pelleted concen-trates liquid color systems and pastes the latter used especially for PVC For polymer conversion processes in which anextruder or meld mixing devise is employed these colorant preparations can be used very effectively In some marketswhere high levels of functional fillers modifiers or polymer blends are used compounders may manufacture ldquoprecoloredrdquopolymer by direct addition of the colorant to their compounding line In come cases concentrates are used depending uponspecific product and process capabilities
Rotational molding in contrast is a low shear process in which traditional pellet form color concentrates are not suitableColoration of rotomolding resin is commonly obtained by the use of dry color and liquid color which can be added direct-ly to the ground rotomolding resin Alternatively precolored resin in which the pigment is compounded into to the poly-mer and then ground before use finds applications as well More recently micropellet technology has been advanced as an alternative to the aforementioned methods It is similar to precompounded color but the need for grinding the polymerinto the appropriate mesh size is eliminated as the micropellets can be rotomolded without further processing For each ofthese color incorporation methods there are advantages and disadvantages including economic factors (process equipmentand material cost) ease of use housekeeping and overall quality (physical properties and aesthetics) of the resulting part
As a consequence of the myriad applications the palette of pigments for rotational molding appears to be quite extensivesimilar to that which is used in general purpose polyethylene application requirements However due to the specific processconditions involved in preparing the pigment system the temperature profile of the rota-tional molding process and the end use application requirement the gamut of pigments issignificantly reduced
Pigment selection may also be affected by the method by which the pigment is to be deliv-ered Liquid colorant systems work best with pigments that have the potential to be loadedto high weight percentages while maintaining suitable viscosity Pigments used in drycolor require characteristics that impart dispersibility and minimize agglomeration duringboth dry color manufacture and blending with the rotomolding resin
DISPERSIONWhen pigments are manufactured the smallest pigment particles formed are discreet units referred to as primary particlesAs a result of their high surface energy these particles randomly join together to form aggregates and agglomerates thelatter being formed primarily during subsequent filtration a nd drying processes To achieve a speck-free system the pig-ment must be effectively ldquodispersedrdquo so that the individual pigment particles or aggregates are wetted by the polymer anddiscrete pigment particles are not visible to the naked eye Rotomolding pigment systems (liquid color and dry color) needto be prepared in a manner that ensures visible agglomerates are eliminated and that during subsequent mixing with therotomolding resin the colorant system will be easily distributed Furthermore the dispersion of the pigment needs to effec-tively deliver a colorant that will provide a high color strength potential to maximize economic while not adversely affect-ing other properties Figure 1 illustrates the particle size of the typical azoncondensation pigment continued on page 12
SPE CAD NEWS Summer 2014 page 11 wwwspecadorg
The following Technical Article was published in 1998 at The Color And Appearance Conference in September
continued from page 11
Note that the particle size distribution that would beobtained in a polymeric system will be very dependentupon the effectiveness of the final dispersion
HIGH PERFORMANCE PIGMENTSHigh performance pigments HPP can be defined as pig-ments that have either very good to excellent heat or lightstability and more commonly pigments which offer aunique combination of both heat and light stability Theenhanced UV and heat performance attributes of HPPs setthem apart from traditional or classical pigments such asthe lithol rubines (PR 571) lake red C (PR 531) 2B toner(PR 48 types) monoaso yellows such as PY 62 and oth-ers which have only limited heat stability and mostly mar-ginal to poor lightfastness
The major types of high performance pigment chemistriescan be described in a general fashion as indicated in Table 1Some individual pigments within these chemistries mayhave better or worse performance characteristics depend-ing upon the specific product attribute and applicationbeing considered
HEAT STABILITYOrganic pigments are available not only with a wide vari-ety of hues and chroma but also with considerable variationin performance characteristics Rotational molding withits combination of relatively long cycle times high moldsurface temperatures and abundance of oxygen is moredemanding upon the polymer stabilization package andpigmentation in comparison to many other processes As aconsequence many rotomolded product applicationsrequire the use of higher performance pigments to survivethe molding process even though the pigment with regardto final product requirements may be viewed as ldquoover engi-neeredrdquo Classical pigments such as 2B reds (CI PigmentRed 48rsquos) with only limited thermal stability in high tem-perature olefin polymer applications may not be suitablefor even non durable articles as the color stability duringmolding may be insufficient Figure 2 compares the heatstability of a calcium 2B toner with high performance dike-topyrrolo-pyrrole (DPP) and quinacridone (QA)chemistries In masstone applications it is readily apparentthat the 2B toner is quite deficient when compared withthese high heat stability pigments Furthermore as pigment
SPE CAD NEWS Summer 2014 page 12 wwwspecadorg
heat stability is generally related to concentration at lowerconcentrations the 2B toner would become even moreprone to color change In addition to pigment instabilitycolor change during rotational molding may be affected byother factors The stability of the base resin is an importantconsideration The role of the antioxidant package is criti-cal to controlling the initial color and maintaining the phys-ical properties of the rotomolding resin Judicious selectionof a phenolic antioxidant and phosphite processing stabi-lizer package is essential for the base polymer Dependingupon specific circumstances additional antioxidant mightbe added The most effective stabilization is typicallyobtained when the antioxidant is added directly to the resinitself during manufacture or during compounding whenrecolored resin is prepared For specialty applications
where additional antioxidants are needed to attain the req-uisite performance precolored or preformulated resinwhich is then ground provides additional benefit
LIGHT STABILITYMany applications of rotationally molded articles find enduses which require UV durability These UV performanceapplications encompass a broad variety of applications andmarkets residential waste containers childrenrsquos play-ground toys (both for residential and institutional uses)outdoor sporting goods (kayaks and component of otherrecreational vehicles) and oversize containers (industrialcontainers and agricultural tanks) For outdoor applica-tions careful formulation is required to achieve not onlysuitable color match but also a color combination whichwill have the desired weatherability As delineated inFigure 3 Calcium 2B toners have limited light stability inpolyolefin applications and are not recommended for usewhere any significant UV exposure is intended Althoughnot reflected in the colorimetric data the 2B toner samplesurface was significantly marred by chalking and surfacemicrocracking and is visible via low magnification optical
Quinacridone Copper PhthalocyanineDiketopyrrolo-pyrrole (DPP) AnthraquinoneTetrachchloroisoindolinone IndanthroneAzochondensation PeryleneBenzimidozone Isoindoline
Table 1 High Performance Chemistry Families
continued from page 12
SPE CAD NEWS Summer 2014 page 13 wwwspecadorg
microscopy Such microcracks may ultimately result inpremature physical failures of the product Therefore visu-al inspection of samples following accelerated or real-timeexposure testing is imperative to ensure complete perform-ance analysis As a consequence of the limited weather-ability of many pigments performance assessment is need-ed Applications such as point of sale displays and relateditems and indoor applications where incidental UV expo-sure from lighting fixtures or nearby windows is possibleare best formulated with durable HPP pigments Outdoorapplications require the use of HPP pigments at levels thatcan provide sufficient levels of weather resistance
Figure 5 illustratesthe difference inlong-term UV sta-bility that wasobtained when aDPP red (PR254) was com-pared with a pery-lene red (PR178) Perylenepigments areprone to darken-ing when used inconjunction withhindered amine light stabilizers (HALS) whereas no suchnegative interaction has been observed for DPPchemistries
Other high performance pigment classes such as copperphthalocyanine blue pigments may also be suitable foroutdoor applications when properly formulated PB 151and PB 153 are widely used in rotational molding appli-cations as a consequence of their outstanding performanceproperties Figure 6 and tremendous value in use
Inorganic and heavy metal pigments are also widely usedin some rotational molding applications due to their general-ly good dispersibility characteristics and in many cases thecleanliness of shade that may be obtained when using cer-tain cadmium and lead chromate pigments However aswill be discussed in greater detail regulatory pressureshave resulted in heavy metal deselection in several appli-
cation areas including food packaging and many toy appli-cations There applications however have not always beeneasily reformulated The use of HPP products providesalternatives in many color space applications Additionallywith the recent introduction of several new DPP productsPR 264 (Figure 7) PR 272 and PO 71 and PO 73(Figure 8) into the polyolefin and PVC market areas agreater breadth of high performance organics is availablefor formulating In some case differences in the perform-ance of organic versus heavy metal pigments may result inadditional raw material costs Material selection and mod-ification of base stabilization are required in some casesand additional light stabilization packages are needed
continued on page 14
continued on page 15
continued from page 13
SPE CAD NEWS Summer 2014 page 14 wwwspecadorg
especially when formulating polyolefins for outdoor appli-cations to provide comparable alternatives Nonethelessconsumers (materials specifiers manufacturers and theultimate product purchaser) choosing to avoid use of cad-mium and lead pigments wherever reasonably possibleremains a continuously evolving trend
The formulation of rotationally molded articles for outdoorapplications requires the use of both suitable pigments aswell as the assistance of a well-designed light stabilizerpackage The use of tetramethyl piperidine based hinderedamine light stabilizers especially oligomeric and highmolecular weight types in combination with benzotriazolebased UV absorbers are recommended for use in a varietyof applications The total package loading should be tai-lored to meet the specified requirement of the application
DISTORTION EFFECTSDistortion of rotomolded articles can be effected by sever-al different variables Resin choice and the particular mate-rial being used can affect warpage and shrinkageDifferences in cooling of the mold thickness variationsovercuring and several other process parameters have beenfound to be related to warping Since pigments (and thesystems used to deliver them) may alter the flow character-istics of the polymer and also the cure characteristics oper-ation of a given mold with different pigments or colorantsystems with a single cure cycle may result in differencesin dimensional stability The use of controlled heating andcooling as well as good control over the process itself willhelp to ensure consistent part manufacturing as well as agood data and record keeping can be referred to in case oferratic part quality
IMPACT PROPERTIESImpact properties are commonly tested as a means ofassessing the quality and suitability of colorant systems aswell as for assessing the cure characteristics of the polymerand the properties of the final product The ARM(Association of Rotational Molders) impact test is a com-mon test that is used Alternative instrumented testing pro-vides similar test result capabilities with the advantage ofquantitative and qualitative data acquisition
Impact properties of rotomolded products are importantMany toys containers and other applications require assur-ances of product integrity which can often be affected notonly by the process conditions but also by the incorpora-tion of pigments and other additives Since there is very lit-tle shear in the rotomolding process pigments are likely tobe located at the grain boundary between adjacent polymergranules This localization of pigment and ldquoadditivesrdquo can adversely affect physical properties in sev-eral ways Inhibition of polymer chain entanglementsbetween particles due to additives that form an interfacebetween resin particles can result in weak distinct bound-aries with poor mechanical properties Also pigmentagglomerates which are not broken apart or more trou-bling when they are formed during premixing processesdue to excessive mixing may introduce point defectseffecting physical properties Aesthetic properties may alsobe impacted if agglomerates are present in either signifi-cant size or number Pigment loading which is related toboth the effectiveness in which the pigment can be dis-persed as well as the color requirements of the part isanother factor to be considered in assessing the potentialeffect of coloration on physical properties
REGULATORY ASPECTSWith the variety of applications encountered in rotationalmolding well-publicized legislation and public opinionhave compelled many plastics processors and end-users touse alternatives to cadmium and lead based pigmentsCONEG (COalition of NorthEast Governors) related legis-lation prohibits the sale of packaging materials to whichcadmium lead mercury and hexavalent chromium or theircompounds have been intentionally added Reducing theamount of these elements entering the food chain via wastedisposal sources and the extra precautions needed to dis-pose of post industrial wastes are issues to be addressesCertainly both lead and cadmium-based pigments possessa combination of desireable technical properties that makesthem articularly useful coloring materials for polymersLead based pigments furthermore are particularly eco-nomical in use Nonetheless public opinion and legislationhave had and will likely continue to have a significantimpact on their use particularly in consumer goods
SPE CAD NEWS Summer 2014 page 15 wwwspecadorg
The Color and Appearance Division (CAD) is commit-ted to the publishing of at least three newsletters a year(four if there is sufficient material to justify the extraissue) To that end we would like you to think aboutthe financial side of sponsorship of the newsletter Forthe small donation of $300 per year we offer a businesscard sized (2 x 35) mention in our newsletter whichgoes out to the nearly 1500 members of the CAD aswell as other SPE division members These are peopleactive in every aspect of plastic coloring and additivetechnology Larger sized spots are available at a com-mensurate increase in rate
If you are interested in helping to sponsor theSPECAD Newsletter please contactScott Aumann Phone 912 210 0175
Email ScottAumannedmmilliporecom
Your Company Our Division
Dear Members
Just a reminder that you can view past and currentBOARD MINUTES on the SPECAD website
We do not typically publish the minutes in the elec-tronic versions of our newsletter but they are alwaysavailable for our members to view from our websiteThe site is not completely current at this time as weare in the process of giving it a makeover and newlaunch in January
Click here for the link to viewhttpwwwspecadorgindexphpnavid=28
Board Minutes
CONNECT WITH SPE CAD VIASOCIAL MEDIA
Join SPECADrsquos Group On Linked Into network with industry peers participate in groupdiscussions of industry and technical topics findjob opportunities and get the latest division andconference announcements
Group Name SPE Color amp AppearanceDivision Group ID 152108 wwwlinkedincomgroupsgid=152108
continued from page 14
Colorants for polymers that are suitable for food contactuse according to 21 CFR1783297 by the FDA (Food andDrug Administration) NSF (National SanitationFoundation) listing for Potable water contact applicationsand ASTM toy specifications may further place limitationson which pigments may be used
CONCLUSIONSRotational molding presents specific performance require-ment for colorants due to the process dynamics and end-user application needs High performance organic pig-ments in addition to inorganic pigments provide usefulsolutions for designers and manufacturers of rotationallymolded products However as this market continues togrow due to the many unique product features attributed tothe rotomolding process advancements in pigmentationstabilization resin processes and ancillary products shouldalso grow as well Active research and development in sta-bilization technology continues to advance new productsand uniquely designed chemistries (such as lactone andhydroxylamine process stabilizers) into the market placeNew pigment products such as those based upon DPPchemistry also show promise in rotational molding appli-cations Moreover these new products further broadenproduct development potential by providing ever increas-ing performance and greater value in use
ACKNOWLEDGEMENTSThis paper would not have been possible without the col-laborative efforts os Steve Juhasz and Dick Huska of thePlastics Technical Center in Newport DE and JohnLinehan and Urs Stadler of the Additives DivisionLaboratories in Tarrytown NY Appreciation is also givento colleagues of Ciba Specialty Chemicals PigmentsDivision in Basle Switzerland for additional data
DuPonttrade Ti-Purereg titanium dioxide
DuPont Titanium Technologies8004419485
wwwtitaniumdupontcom
The DuPont Oval DuPont trade The miracles of sciencereg and Ti-Purereg
are trademarks or registered trademarks of EI du Pont de Nemours and Company
POLYMERS LIGHT amp SCIENCE
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BTitanium Dioxide BRutile amp Anatase
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B PVC AdditivesB Lubricants amp Stabilizers
364 Johnny Mercer Blvd B-7 294 - Savannah GA 31410Tel (912)507-8972 - lwaltersagrofertinccom
wwwagrofertinccom
World Leader in EffectPigments
One International PlazaSuite 300Philadelphia PA 19113(888) 367-3275
wwwemdchemicalscom
A Complete Line of DyestuffsInorganic Pigments and
Organic Pigments forPlastics amp Fibers
LANXESS Corporation111 RIDC Park West Drive 1-800-526-9377Pittsburgh PA 15275-1112 wwwlanxesscom
World Leaders in Ultramarine PigmentswUltramarine Blue wUltramarine VioletwChrome Oxide Green wLead Chromate
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Phone 77027788196369 Peachtree Street Fax 7702778809Norcross GA 30071 Toll Free 8008866981wwwnubiolacom
We create chemistry for plastics
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eate chemistry for plastics
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Our UV light stabilizers antioxidants nucleatorsfect and functional pigments efneeds with color r ef
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1 800 431-2360Florham Park NJ
venue100 Park A AvenueBASF Corporation
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Color Software ExpertsSince 1986
Quality Control Formulationamp Instrument Profiling
Visit our website and color blogwwwcyberchromeusacom
CyberChrome Inc3642 Main Street tStone Ridge NY 12484
PH 845-687-2671
wwwbasf
Color Concentrates and Single Pigment Dispersionsfor all Thermoplastic Polymers
Corporate Offices400 Old Dublin PikeDoylestown PA 18901(215) 345-6550
Operations amp Research Center2755 Bergey RoadHatfield PA 19440(215) 997-2221wwwpenncolorcom
SPE CAD NEWS Summer 2014 page 16 wwwspecadorg
SPE CAD NEWS Summer 2014 page 17 wwwspecadorg
Special thanks to our our Speakers Sponsors Exhibitors and Participants for your contributions to this yearrsquos CAD RETECreg 2014
Earl Balthazar III CAD RETECreg 2014 Conference Chair Datacolor Inc (817) 719-0224 CAD_RETECtxrrcomMark FreshwaterCAD RETECreg 2014 Vice-ChairLansco Colors(330) 526-8833markpigmentscom
Nathan KarszesCAD RETECreg 2014 Technical Program Co-ChairNubiola Corporation(770) 527-2409nkarszesnubiolacomBrenda MullinsCAD RETECreg2014 Technical Program Co-ChairClariant Corporation(678) 237-2975 brendamullinsclariantcom
SPE CAD NEWS Summer 2014 page 18 wwwspecadorg
LAE
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4195592459 866ATTERRA ext 2459jprzybylskiterraedu
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SPE CAD NEWS Summer 2014 page 19 wwwspecadorg
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September 26 2014 ndash 500pm EDT
A SPE ANTECreg
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Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom
Organic Pigments Inorganic Pigments Pigment Preparations
Heucotech Ltd 99 Newbold Road Fairless Hills PA 19030wwwheubachcolorcom 215-736-0712
Organic amp InorganicPigments and Preparations
(416) 253-4297 hkennedydominioncolourcomwwwdominioncolourcom
D 72209 217 PM Page 1
QUALITY FORMULATION OFCOLOR amp ADDITIVE CONCENTRATES
wwwtechmerpmcom
18420 Laurel Park Road 1 Quality CircleRancho Dominguez CA 90220 Clinton TN 37716(310) 632-9211(865) 457-6700
COMPETENCE IN COLOR
AT KEYSTONE WE PROVIDE A THREE-TIER CUSTOMER-FOCUSED VALUE PROPOSITION
PRODUCTINNOVATIONS
gt KeyplastTM Dyesand Pigments
gt KeyplastTM GraniteSpecial Effects
gt KeyfluorTM OBrsquos andInvisible Fluorescents
gt ReversacolTM
PhotochromaticColorants
ISHIHARA CORPORATION (USA) TiO2 Ultra-fine TiO2
Nickel Titanates Chrome Titanates Conductive Pigments
601 California Street Tel (415) 421-8207San Francisco California 94108 Fax (415) 397-5403
wwwishiharacom
SPE CAD NEWS Summer 2014 page4 wwwspecadorg
CONFERENCE REGISTRATION
SPE Member RegistrationMust include valid SPE e-mail address with registration $440
SPE Non-Member Registration - Includes 1 Year Membership $590Membership will be processed after RETEC
SPE Non-Member Registration Without SPE Membership $650Conference registration but decline the One Year SPE membership
OTHER REGISTRATION TYPES
SpeakerModerator Registration $170Must be a speaker or moderator at the conference for this registration type This does not include New Technology Forum Speakers
2014 CAD RETECreg Conference Committee Member Registration $170Must be a member of the 2014 CAD RETECreg organizing committee to qualify for this registration type
Student Registration $ 50Must have valid Student ID and working part-time or full-time and paying own travel expenses
SPE Emeritus Member Registration $100Option available for SPE Emeritus Members
SPE Membership Renewal $100Renew your existing SPE membership Requires SPE membership e-mail address to ensure continued membership status Note membership renewal may not be processed until after RETECreg
Tabletop Exhibit Space (if still available) $950Includes two free conference registrations with tabletop Provide names and titles of both attendees in the appropriate fields at the end of this form
The 52st Annual Society of Plastics Engineers Color and Appearance Division CAD RETECreg is located near New OrleansFrench Quarter and will serve as an excellent setting for the theme of this yearrsquos CAD RETECreg ldquoIts a Colorful WorldrdquoCAD RETECreg is the largest technical conference hosted in North America that is specifically dedicated to the color andappearance of plastics
If you have not already registered there is still time to attend the conference A special thanks to all our sponsors organizers and particpants for your involvement creativity and talent
Earl BalthazarConference Chair
2014 SPE CAD RETECreg
ebalthazartxrrcom
CLICK HERE to Register orsee detailed informaton
SPE CAD NEWS Summer 2014 page 5 wwwspecadorg
CAD RETECreg REGISTRANT FORM (Please Print)
SPE Membership Name Address Title
Company
Country of CitizenshipEmailDaytime Phone Date
For Credit Card Payments OnlyCircle One AMEX VISA MasterCardCard No Expiration Date Name on card (if different from above)___________________________________________Signature
If paying by credit card fax to 859-372-6382 ore-mail to brucemulhollandticonacom
REGISTER ONLINE AT wwwspecadorg
For checks make in US dollars only payable to ldquoSPE CADrdquo
Refunds less a $30 fee August 16 to September 5 2014 No refunds after September 5 2014 SPE Memberships are processed after RETEC
If paying by credit card fax to 859-372-6382 ore-mail to brucemulhollandticonacom
REGISTER ONLINE AT wwwspecadorg
CIRCLE ANSWERS BELOW
Is this your first CAD RETECreg Yes No
If no have you attended a CAD RETECreg
in the last five years Yes No
EXTRA CONFERENCE LITERATURE
Additional Copy Conference Proceedings $115 X ____ = $________Additional CAD RETECreg 2014 conference proceedings download pass One copy is already included with each paid registration
SPE CAD Archive DVD (1961 - 2007) and $175 X ____ = $________Color Papers from 1961-2007 ANTEC amp RETEC available on-siteSpecial RETECreg Offer $175 (must also register for the RETECreg conference)Savings from the regular price of $200 for SPE members and $300 for non-members
OTHER EVENT REGISTRATIONRSVP
Sunday Golf Outing $130 X ____ = $________Sunday golf outing at TPC Louisiana If registering more than yourself for golf
please include their names using the tabletop names amp titles fields at the bottom of the
registration page This will allow you to list up to four names using those fields
5K Fun RunWalk $20 X ____ = $________Sign up for Tuesday AM 5K Fun RunWalk CAD will match the $20 donation for charity
Total due from all items checked $_________________
QR CAD mobile app for Android Apple and Windows mobile devices
GOLF OUTING INFORMATION
SPE CAD NEWS Summer 2014 page 6 wwwspecadorg
Price $13000 per golfer
Includes Warm up on the RangeGreen FeesCart FeeScramble formatBox Lunch with DrinkCustomized TPC Bag Tag
Course LocationTPC Louisiana11001 Lapalco BlvdAvondale LA 70094(504) 4368721
Registration 1100 am (CST) Shotgun Start 12 noon (CST)Awards Will be presented at CAD RETECreg
Welcoming Reception
September 14 2014
To Sign Up Online RegistrationQuestions Contact
Mark Tylermarktylercelanesecom 8593723221 or
Mark Freshwatermarkpigmentscom 2016650091
SPE CAD NEWS Summer 2014 page 7 wwwspecadorg
900 am - Golf Outing300 pm
100pm - Registration Desk Open600 pm
100pm - EXHIBITOR SET-UP530 pm
600 pm Welcome Reception Sponsors EMD Chemicals and Kronos800 pm (Pick up your registration packet prior to this event to get your complimentary drink coupons)
Golf Outing Prizes will be presented at the Welcome Reception
730 BREAKFAST (Biffon A) Sponsor Lansco730 Registration Desk Opens
MORNING SESSION MODERATOR BRUCE MULHOLLAND CELANESE815 OPENING REMARKS Earl Balthazar
830 KEYNOTE Public Percepton of Plastics Rudy Underwood American Chemistry Council
930 The Global Economy-Precariousness of Supply Chain Globalization of Regulations and How to Protect YourselfBruce Howie Dominion Color
1000 COFFEE BREAK Sponsor Clariant
1030 Fundamentals of Twin-Screw Extrusion- Color MB Prossessing Common Pitfalls and How to Avoid ThemPaul G Anderson Coperion
1100 Influence of TiO2 Feeding on Twin Screw Extrusion Compounding JD Connolly DuPontTitanium Technologies
1130 Dispersion of Pigments in Plastics Applications Mahesh Mettelloo Sudarshan
1230 - 130 LUNCH (on your own)
CAD RETEC 2014reg
SUNDAY September 14
MONDAY MORNING (Mardi Gras Ballroom) September 15
CONFERENCE HOTEL INFORMATIONMarriott New OrleansTo Reserve by Phone 504-581-1000 or 1-888-364-1200Request Group Rate Society of Plastics Engineers - Color amp Appearance Division
MARRIOTT NEW ORLEANS555 Canal Street New Orleans Louisiana 70130 Phone 504-581-1000 Toll Free 1-888-364-1200
Discounted Conference Room Rate $159night-single occupancyRoom Block Dates Sept 12-17
Rates will increase significantly after August 15 2014 at 5pm or whenever the room block is full Cancellation policy Any hotel reservation canceled within 48 hours of arrival date will be charged for one (1) nights room and tax
AFTERNOON SESSION MODERATOR NATHAN KARSZES NUBIOLA130 Panel Discussion
Audience Response Devices will be available to each audience member for responding to poll questions during the panel discussion
300 COFFEE BREAK Sponsor Shepherd
330 Pigments for Sensitive Applications Tom Chirayil BASF
400 Advances in Liquid Color Technology Inga Lesko Clariant BU Masterbatch
430 New Technology Forum (pdf) Moderator Sandra Davis
500 NETWORKING RECEPTION Sponsor Nubiola
700 5K Fun RunWalk for Habitat for Humanity Plastics (Pregister for this event) Sponsor Dominion
730 BREAKFAST(on your own)
MORNING SESSION MODERATOR AUSTIN REID DUPONT TITANIUM TECHNOLOGIES
900 Colorants for Plastics-Emerging Trends and Technologies Krishnamoorthy Sivakumar PolyOne
930 Iron OxidesInorganic Pigments for Plastics George Podolsky Rockwood Pigments
1000 COFFEE BREAK Sponsor DuPont
1030 Blue Undertone Enhancement of Black and Grey PP Injection Molded PP Nathan Karszes Nubiola
1100 Lighter Faster Stronger Additive Solutions for Automotive Plastics Emilie Meddah Clariant BU Additives
1130 Gaining Competitive Advantage through Digital Appearance Technology in the Automotive Interior Supply ChainPhil Ruggiero Datacolor
1200 AWARDS LUNCHEON PRESERVATION HALL (Included with Registration) Sponsor Tronox
AFTERNOON SESSION MODERATOR JIM FIGANIAK
130 Inorganic Pigments From Caveman to the 21st Century Mark Ryan Shepherd Company
200 Measurement Technology to Evaluate Light Protection What You See May Not Be What You ProtectPhil Miedenzu DuPont Titanium Technologies
230 COFFEE BREAK Sponsor Munzing
300 Effects of Disinfectant Grade Cleaner on Physical Properties of Cell Phone Cases Diane McLendonOtterbox
330 Its a Colorful World Developing Technologies to Keep it that Way Joseph Fay BASF
400 Closing Remarks - Earl Balthazar Survey Raffle - MC-Tracy Phillips Uniform Color Grand Prize TBDOther Prizes Archive DVD Free Night at Westin Free Registration at CAD RETECreg 2015 Emergency RadioCAD RETECreg Limited Edition Art
Must be present to win
MONDAY AFTERNOON (Mardi Gras Ballroom) September 15
TUESDAY MORNING September 16
TUESDAY AFTERNOON (Mardi Gras Ballroom) September 16
SPE CAD NEWS Summer 2014 page 8 wwwspecadorg
SPE CAD NEWS Summer 2014 page 9 wwwspecadorg
Lobby of New Orleans Marriott 555 Canal Street
FREE T-SHIRT FOR THEFIRST 40 RUNNERS
September 16th 7am
$20 Registration Fee bullAll proceeds go to Habitat for HumanitySPE CAD will match every $20 donation
dominioncolourcom
sponsored by
Sponsored by
SPE CAD NEWS Spring 2014 page 10 wwwspecadorg
Gold Level Sponsors
Platinum Level Sponsors
Silver Level Sponsors
WE ARE PROUD TO HIGHLIGHT THESE EXCELLENT COMPANIESPlease visit our generous sponsorsrsquo websites by clicking on their logos below
T H E G O L D S T A N D A R D I N P L A S T I C S
Thank you RETECreg 2014 Sponsors
Cappelle
Celanese
LTL Color Compounders Inc
Pigments colour the world
our passion your colors
C R e A t i N g A d d i t i v e v A L u e
LANSCO COLORS
E C K A R TEffect Pigments
High Performance Pigments for Demanding Applications Rotational MoldingJoseph J Fay PhD amp Peter Zillitto
Plastics Technical Center Pigments DivisionCiba Specialty Chemicals Corporation
Technical Article
INTRODUCTIONColorants for polymer applications are typically incorporated into the polymer by one of several common pathways Colorconcentrates which are widely used in industry enable the end user to conveniently meter in the colorant at the prescribedration with virgin or uncolored polymer in the manufacturing process The benefits of concentrate used as compared to thedirect use of powder pigment during final product conversion processes include predispersion of the pigment in a suit-able carrier system elimination of the need to in-house compounding to incorporate the colorant uniformly and improvedhousekeeping etc Furthermore color concentrates are available ina number of product forms including pelleted concen-trates liquid color systems and pastes the latter used especially for PVC For polymer conversion processes in which anextruder or meld mixing devise is employed these colorant preparations can be used very effectively In some marketswhere high levels of functional fillers modifiers or polymer blends are used compounders may manufacture ldquoprecoloredrdquopolymer by direct addition of the colorant to their compounding line In come cases concentrates are used depending uponspecific product and process capabilities
Rotational molding in contrast is a low shear process in which traditional pellet form color concentrates are not suitableColoration of rotomolding resin is commonly obtained by the use of dry color and liquid color which can be added direct-ly to the ground rotomolding resin Alternatively precolored resin in which the pigment is compounded into to the poly-mer and then ground before use finds applications as well More recently micropellet technology has been advanced as an alternative to the aforementioned methods It is similar to precompounded color but the need for grinding the polymerinto the appropriate mesh size is eliminated as the micropellets can be rotomolded without further processing For each ofthese color incorporation methods there are advantages and disadvantages including economic factors (process equipmentand material cost) ease of use housekeeping and overall quality (physical properties and aesthetics) of the resulting part
As a consequence of the myriad applications the palette of pigments for rotational molding appears to be quite extensivesimilar to that which is used in general purpose polyethylene application requirements However due to the specific processconditions involved in preparing the pigment system the temperature profile of the rota-tional molding process and the end use application requirement the gamut of pigments issignificantly reduced
Pigment selection may also be affected by the method by which the pigment is to be deliv-ered Liquid colorant systems work best with pigments that have the potential to be loadedto high weight percentages while maintaining suitable viscosity Pigments used in drycolor require characteristics that impart dispersibility and minimize agglomeration duringboth dry color manufacture and blending with the rotomolding resin
DISPERSIONWhen pigments are manufactured the smallest pigment particles formed are discreet units referred to as primary particlesAs a result of their high surface energy these particles randomly join together to form aggregates and agglomerates thelatter being formed primarily during subsequent filtration a nd drying processes To achieve a speck-free system the pig-ment must be effectively ldquodispersedrdquo so that the individual pigment particles or aggregates are wetted by the polymer anddiscrete pigment particles are not visible to the naked eye Rotomolding pigment systems (liquid color and dry color) needto be prepared in a manner that ensures visible agglomerates are eliminated and that during subsequent mixing with therotomolding resin the colorant system will be easily distributed Furthermore the dispersion of the pigment needs to effec-tively deliver a colorant that will provide a high color strength potential to maximize economic while not adversely affect-ing other properties Figure 1 illustrates the particle size of the typical azoncondensation pigment continued on page 12
SPE CAD NEWS Summer 2014 page 11 wwwspecadorg
The following Technical Article was published in 1998 at The Color And Appearance Conference in September
continued from page 11
Note that the particle size distribution that would beobtained in a polymeric system will be very dependentupon the effectiveness of the final dispersion
HIGH PERFORMANCE PIGMENTSHigh performance pigments HPP can be defined as pig-ments that have either very good to excellent heat or lightstability and more commonly pigments which offer aunique combination of both heat and light stability Theenhanced UV and heat performance attributes of HPPs setthem apart from traditional or classical pigments such asthe lithol rubines (PR 571) lake red C (PR 531) 2B toner(PR 48 types) monoaso yellows such as PY 62 and oth-ers which have only limited heat stability and mostly mar-ginal to poor lightfastness
The major types of high performance pigment chemistriescan be described in a general fashion as indicated in Table 1Some individual pigments within these chemistries mayhave better or worse performance characteristics depend-ing upon the specific product attribute and applicationbeing considered
HEAT STABILITYOrganic pigments are available not only with a wide vari-ety of hues and chroma but also with considerable variationin performance characteristics Rotational molding withits combination of relatively long cycle times high moldsurface temperatures and abundance of oxygen is moredemanding upon the polymer stabilization package andpigmentation in comparison to many other processes As aconsequence many rotomolded product applicationsrequire the use of higher performance pigments to survivethe molding process even though the pigment with regardto final product requirements may be viewed as ldquoover engi-neeredrdquo Classical pigments such as 2B reds (CI PigmentRed 48rsquos) with only limited thermal stability in high tem-perature olefin polymer applications may not be suitablefor even non durable articles as the color stability duringmolding may be insufficient Figure 2 compares the heatstability of a calcium 2B toner with high performance dike-topyrrolo-pyrrole (DPP) and quinacridone (QA)chemistries In masstone applications it is readily apparentthat the 2B toner is quite deficient when compared withthese high heat stability pigments Furthermore as pigment
SPE CAD NEWS Summer 2014 page 12 wwwspecadorg
heat stability is generally related to concentration at lowerconcentrations the 2B toner would become even moreprone to color change In addition to pigment instabilitycolor change during rotational molding may be affected byother factors The stability of the base resin is an importantconsideration The role of the antioxidant package is criti-cal to controlling the initial color and maintaining the phys-ical properties of the rotomolding resin Judicious selectionof a phenolic antioxidant and phosphite processing stabi-lizer package is essential for the base polymer Dependingupon specific circumstances additional antioxidant mightbe added The most effective stabilization is typicallyobtained when the antioxidant is added directly to the resinitself during manufacture or during compounding whenrecolored resin is prepared For specialty applications
where additional antioxidants are needed to attain the req-uisite performance precolored or preformulated resinwhich is then ground provides additional benefit
LIGHT STABILITYMany applications of rotationally molded articles find enduses which require UV durability These UV performanceapplications encompass a broad variety of applications andmarkets residential waste containers childrenrsquos play-ground toys (both for residential and institutional uses)outdoor sporting goods (kayaks and component of otherrecreational vehicles) and oversize containers (industrialcontainers and agricultural tanks) For outdoor applica-tions careful formulation is required to achieve not onlysuitable color match but also a color combination whichwill have the desired weatherability As delineated inFigure 3 Calcium 2B toners have limited light stability inpolyolefin applications and are not recommended for usewhere any significant UV exposure is intended Althoughnot reflected in the colorimetric data the 2B toner samplesurface was significantly marred by chalking and surfacemicrocracking and is visible via low magnification optical
Quinacridone Copper PhthalocyanineDiketopyrrolo-pyrrole (DPP) AnthraquinoneTetrachchloroisoindolinone IndanthroneAzochondensation PeryleneBenzimidozone Isoindoline
Table 1 High Performance Chemistry Families
continued from page 12
SPE CAD NEWS Summer 2014 page 13 wwwspecadorg
microscopy Such microcracks may ultimately result inpremature physical failures of the product Therefore visu-al inspection of samples following accelerated or real-timeexposure testing is imperative to ensure complete perform-ance analysis As a consequence of the limited weather-ability of many pigments performance assessment is need-ed Applications such as point of sale displays and relateditems and indoor applications where incidental UV expo-sure from lighting fixtures or nearby windows is possibleare best formulated with durable HPP pigments Outdoorapplications require the use of HPP pigments at levels thatcan provide sufficient levels of weather resistance
Figure 5 illustratesthe difference inlong-term UV sta-bility that wasobtained when aDPP red (PR254) was com-pared with a pery-lene red (PR178) Perylenepigments areprone to darken-ing when used inconjunction withhindered amine light stabilizers (HALS) whereas no suchnegative interaction has been observed for DPPchemistries
Other high performance pigment classes such as copperphthalocyanine blue pigments may also be suitable foroutdoor applications when properly formulated PB 151and PB 153 are widely used in rotational molding appli-cations as a consequence of their outstanding performanceproperties Figure 6 and tremendous value in use
Inorganic and heavy metal pigments are also widely usedin some rotational molding applications due to their general-ly good dispersibility characteristics and in many cases thecleanliness of shade that may be obtained when using cer-tain cadmium and lead chromate pigments However aswill be discussed in greater detail regulatory pressureshave resulted in heavy metal deselection in several appli-
cation areas including food packaging and many toy appli-cations There applications however have not always beeneasily reformulated The use of HPP products providesalternatives in many color space applications Additionallywith the recent introduction of several new DPP productsPR 264 (Figure 7) PR 272 and PO 71 and PO 73(Figure 8) into the polyolefin and PVC market areas agreater breadth of high performance organics is availablefor formulating In some case differences in the perform-ance of organic versus heavy metal pigments may result inadditional raw material costs Material selection and mod-ification of base stabilization are required in some casesand additional light stabilization packages are needed
continued on page 14
continued on page 15
continued from page 13
SPE CAD NEWS Summer 2014 page 14 wwwspecadorg
especially when formulating polyolefins for outdoor appli-cations to provide comparable alternatives Nonethelessconsumers (materials specifiers manufacturers and theultimate product purchaser) choosing to avoid use of cad-mium and lead pigments wherever reasonably possibleremains a continuously evolving trend
The formulation of rotationally molded articles for outdoorapplications requires the use of both suitable pigments aswell as the assistance of a well-designed light stabilizerpackage The use of tetramethyl piperidine based hinderedamine light stabilizers especially oligomeric and highmolecular weight types in combination with benzotriazolebased UV absorbers are recommended for use in a varietyof applications The total package loading should be tai-lored to meet the specified requirement of the application
DISTORTION EFFECTSDistortion of rotomolded articles can be effected by sever-al different variables Resin choice and the particular mate-rial being used can affect warpage and shrinkageDifferences in cooling of the mold thickness variationsovercuring and several other process parameters have beenfound to be related to warping Since pigments (and thesystems used to deliver them) may alter the flow character-istics of the polymer and also the cure characteristics oper-ation of a given mold with different pigments or colorantsystems with a single cure cycle may result in differencesin dimensional stability The use of controlled heating andcooling as well as good control over the process itself willhelp to ensure consistent part manufacturing as well as agood data and record keeping can be referred to in case oferratic part quality
IMPACT PROPERTIESImpact properties are commonly tested as a means ofassessing the quality and suitability of colorant systems aswell as for assessing the cure characteristics of the polymerand the properties of the final product The ARM(Association of Rotational Molders) impact test is a com-mon test that is used Alternative instrumented testing pro-vides similar test result capabilities with the advantage ofquantitative and qualitative data acquisition
Impact properties of rotomolded products are importantMany toys containers and other applications require assur-ances of product integrity which can often be affected notonly by the process conditions but also by the incorpora-tion of pigments and other additives Since there is very lit-tle shear in the rotomolding process pigments are likely tobe located at the grain boundary between adjacent polymergranules This localization of pigment and ldquoadditivesrdquo can adversely affect physical properties in sev-eral ways Inhibition of polymer chain entanglementsbetween particles due to additives that form an interfacebetween resin particles can result in weak distinct bound-aries with poor mechanical properties Also pigmentagglomerates which are not broken apart or more trou-bling when they are formed during premixing processesdue to excessive mixing may introduce point defectseffecting physical properties Aesthetic properties may alsobe impacted if agglomerates are present in either signifi-cant size or number Pigment loading which is related toboth the effectiveness in which the pigment can be dis-persed as well as the color requirements of the part isanother factor to be considered in assessing the potentialeffect of coloration on physical properties
REGULATORY ASPECTSWith the variety of applications encountered in rotationalmolding well-publicized legislation and public opinionhave compelled many plastics processors and end-users touse alternatives to cadmium and lead based pigmentsCONEG (COalition of NorthEast Governors) related legis-lation prohibits the sale of packaging materials to whichcadmium lead mercury and hexavalent chromium or theircompounds have been intentionally added Reducing theamount of these elements entering the food chain via wastedisposal sources and the extra precautions needed to dis-pose of post industrial wastes are issues to be addressesCertainly both lead and cadmium-based pigments possessa combination of desireable technical properties that makesthem articularly useful coloring materials for polymersLead based pigments furthermore are particularly eco-nomical in use Nonetheless public opinion and legislationhave had and will likely continue to have a significantimpact on their use particularly in consumer goods
SPE CAD NEWS Summer 2014 page 15 wwwspecadorg
The Color and Appearance Division (CAD) is commit-ted to the publishing of at least three newsletters a year(four if there is sufficient material to justify the extraissue) To that end we would like you to think aboutthe financial side of sponsorship of the newsletter Forthe small donation of $300 per year we offer a businesscard sized (2 x 35) mention in our newsletter whichgoes out to the nearly 1500 members of the CAD aswell as other SPE division members These are peopleactive in every aspect of plastic coloring and additivetechnology Larger sized spots are available at a com-mensurate increase in rate
If you are interested in helping to sponsor theSPECAD Newsletter please contactScott Aumann Phone 912 210 0175
Email ScottAumannedmmilliporecom
Your Company Our Division
Dear Members
Just a reminder that you can view past and currentBOARD MINUTES on the SPECAD website
We do not typically publish the minutes in the elec-tronic versions of our newsletter but they are alwaysavailable for our members to view from our websiteThe site is not completely current at this time as weare in the process of giving it a makeover and newlaunch in January
Click here for the link to viewhttpwwwspecadorgindexphpnavid=28
Board Minutes
CONNECT WITH SPE CAD VIASOCIAL MEDIA
Join SPECADrsquos Group On Linked Into network with industry peers participate in groupdiscussions of industry and technical topics findjob opportunities and get the latest division andconference announcements
Group Name SPE Color amp AppearanceDivision Group ID 152108 wwwlinkedincomgroupsgid=152108
continued from page 14
Colorants for polymers that are suitable for food contactuse according to 21 CFR1783297 by the FDA (Food andDrug Administration) NSF (National SanitationFoundation) listing for Potable water contact applicationsand ASTM toy specifications may further place limitationson which pigments may be used
CONCLUSIONSRotational molding presents specific performance require-ment for colorants due to the process dynamics and end-user application needs High performance organic pig-ments in addition to inorganic pigments provide usefulsolutions for designers and manufacturers of rotationallymolded products However as this market continues togrow due to the many unique product features attributed tothe rotomolding process advancements in pigmentationstabilization resin processes and ancillary products shouldalso grow as well Active research and development in sta-bilization technology continues to advance new productsand uniquely designed chemistries (such as lactone andhydroxylamine process stabilizers) into the market placeNew pigment products such as those based upon DPPchemistry also show promise in rotational molding appli-cations Moreover these new products further broadenproduct development potential by providing ever increas-ing performance and greater value in use
ACKNOWLEDGEMENTSThis paper would not have been possible without the col-laborative efforts os Steve Juhasz and Dick Huska of thePlastics Technical Center in Newport DE and JohnLinehan and Urs Stadler of the Additives DivisionLaboratories in Tarrytown NY Appreciation is also givento colleagues of Ciba Specialty Chemicals PigmentsDivision in Basle Switzerland for additional data
DuPonttrade Ti-Purereg titanium dioxide
DuPont Titanium Technologies8004419485
wwwtitaniumdupontcom
The DuPont Oval DuPont trade The miracles of sciencereg and Ti-Purereg
are trademarks or registered trademarks of EI du Pont de Nemours and Company
POLYMERS LIGHT amp SCIENCE
Polymers Light and the Science of TiO2
BTitanium Dioxide BRutile amp Anatase
BHigh Performance Organic PigmentsB DPP Reds HP Yellows
B PVC AdditivesB Lubricants amp Stabilizers
364 Johnny Mercer Blvd B-7 294 - Savannah GA 31410Tel (912)507-8972 - lwaltersagrofertinccom
wwwagrofertinccom
World Leader in EffectPigments
One International PlazaSuite 300Philadelphia PA 19113(888) 367-3275
wwwemdchemicalscom
A Complete Line of DyestuffsInorganic Pigments and
Organic Pigments forPlastics amp Fibers
LANXESS Corporation111 RIDC Park West Drive 1-800-526-9377Pittsburgh PA 15275-1112 wwwlanxesscom
World Leaders in Ultramarine PigmentswUltramarine Blue wUltramarine VioletwChrome Oxide Green wLead Chromate
wZinc Ferrite wIron Oxide
Phone 77027788196369 Peachtree Street Fax 7702778809Norcross GA 30071 Toll Free 8008866981wwwnubiolacom
We create chemistry for plastics
f
eate chemistry for plastics
basfcomplastic-additiveswww
your plastic applicationsovide solutions for all ofand other additives pr
Our UV light stabilizers antioxidants nucleatorsfect and functional pigments efneeds with color r ef
BASF helps meet your style and functionality
e crWWe cr
eate chemistry for plastics
1 800 431-2360Florham Park NJ
venue100 Park A AvenueBASF Corporation
ovide solutions for all ofOur UV light stabilizers antioxidants nucleators
fect and functional pigmentsBASF helps meet your style and functionality
Color Software ExpertsSince 1986
Quality Control Formulationamp Instrument Profiling
Visit our website and color blogwwwcyberchromeusacom
CyberChrome Inc3642 Main Street tStone Ridge NY 12484
PH 845-687-2671
wwwbasf
Color Concentrates and Single Pigment Dispersionsfor all Thermoplastic Polymers
Corporate Offices400 Old Dublin PikeDoylestown PA 18901(215) 345-6550
Operations amp Research Center2755 Bergey RoadHatfield PA 19440(215) 997-2221wwwpenncolorcom
SPE CAD NEWS Summer 2014 page 16 wwwspecadorg
SPE CAD NEWS Summer 2014 page 17 wwwspecadorg
Special thanks to our our Speakers Sponsors Exhibitors and Participants for your contributions to this yearrsquos CAD RETECreg 2014
Earl Balthazar III CAD RETECreg 2014 Conference Chair Datacolor Inc (817) 719-0224 CAD_RETECtxrrcomMark FreshwaterCAD RETECreg 2014 Vice-ChairLansco Colors(330) 526-8833markpigmentscom
Nathan KarszesCAD RETECreg 2014 Technical Program Co-ChairNubiola Corporation(770) 527-2409nkarszesnubiolacomBrenda MullinsCAD RETECreg2014 Technical Program Co-ChairClariant Corporation(678) 237-2975 brendamullinsclariantcom
SPE CAD NEWS Summer 2014 page 18 wwwspecadorg
LAE
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4195592459 866ATTERRA ext 2459jprzybylskiterraedu
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September 26 2014 ndash 500pm EDT
A SPE ANTECreg
T Because of this the p Please make a note of this significant change Y
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Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom
CONFERENCE REGISTRATION
SPE Member RegistrationMust include valid SPE e-mail address with registration $440
SPE Non-Member Registration - Includes 1 Year Membership $590Membership will be processed after RETEC
SPE Non-Member Registration Without SPE Membership $650Conference registration but decline the One Year SPE membership
OTHER REGISTRATION TYPES
SpeakerModerator Registration $170Must be a speaker or moderator at the conference for this registration type This does not include New Technology Forum Speakers
2014 CAD RETECreg Conference Committee Member Registration $170Must be a member of the 2014 CAD RETECreg organizing committee to qualify for this registration type
Student Registration $ 50Must have valid Student ID and working part-time or full-time and paying own travel expenses
SPE Emeritus Member Registration $100Option available for SPE Emeritus Members
SPE Membership Renewal $100Renew your existing SPE membership Requires SPE membership e-mail address to ensure continued membership status Note membership renewal may not be processed until after RETECreg
Tabletop Exhibit Space (if still available) $950Includes two free conference registrations with tabletop Provide names and titles of both attendees in the appropriate fields at the end of this form
The 52st Annual Society of Plastics Engineers Color and Appearance Division CAD RETECreg is located near New OrleansFrench Quarter and will serve as an excellent setting for the theme of this yearrsquos CAD RETECreg ldquoIts a Colorful WorldrdquoCAD RETECreg is the largest technical conference hosted in North America that is specifically dedicated to the color andappearance of plastics
If you have not already registered there is still time to attend the conference A special thanks to all our sponsors organizers and particpants for your involvement creativity and talent
Earl BalthazarConference Chair
2014 SPE CAD RETECreg
ebalthazartxrrcom
CLICK HERE to Register orsee detailed informaton
SPE CAD NEWS Summer 2014 page 5 wwwspecadorg
CAD RETECreg REGISTRANT FORM (Please Print)
SPE Membership Name Address Title
Company
Country of CitizenshipEmailDaytime Phone Date
For Credit Card Payments OnlyCircle One AMEX VISA MasterCardCard No Expiration Date Name on card (if different from above)___________________________________________Signature
If paying by credit card fax to 859-372-6382 ore-mail to brucemulhollandticonacom
REGISTER ONLINE AT wwwspecadorg
For checks make in US dollars only payable to ldquoSPE CADrdquo
Refunds less a $30 fee August 16 to September 5 2014 No refunds after September 5 2014 SPE Memberships are processed after RETEC
If paying by credit card fax to 859-372-6382 ore-mail to brucemulhollandticonacom
REGISTER ONLINE AT wwwspecadorg
CIRCLE ANSWERS BELOW
Is this your first CAD RETECreg Yes No
If no have you attended a CAD RETECreg
in the last five years Yes No
EXTRA CONFERENCE LITERATURE
Additional Copy Conference Proceedings $115 X ____ = $________Additional CAD RETECreg 2014 conference proceedings download pass One copy is already included with each paid registration
SPE CAD Archive DVD (1961 - 2007) and $175 X ____ = $________Color Papers from 1961-2007 ANTEC amp RETEC available on-siteSpecial RETECreg Offer $175 (must also register for the RETECreg conference)Savings from the regular price of $200 for SPE members and $300 for non-members
OTHER EVENT REGISTRATIONRSVP
Sunday Golf Outing $130 X ____ = $________Sunday golf outing at TPC Louisiana If registering more than yourself for golf
please include their names using the tabletop names amp titles fields at the bottom of the
registration page This will allow you to list up to four names using those fields
5K Fun RunWalk $20 X ____ = $________Sign up for Tuesday AM 5K Fun RunWalk CAD will match the $20 donation for charity
Total due from all items checked $_________________
QR CAD mobile app for Android Apple and Windows mobile devices
GOLF OUTING INFORMATION
SPE CAD NEWS Summer 2014 page 6 wwwspecadorg
Price $13000 per golfer
Includes Warm up on the RangeGreen FeesCart FeeScramble formatBox Lunch with DrinkCustomized TPC Bag Tag
Course LocationTPC Louisiana11001 Lapalco BlvdAvondale LA 70094(504) 4368721
Registration 1100 am (CST) Shotgun Start 12 noon (CST)Awards Will be presented at CAD RETECreg
Welcoming Reception
September 14 2014
To Sign Up Online RegistrationQuestions Contact
Mark Tylermarktylercelanesecom 8593723221 or
Mark Freshwatermarkpigmentscom 2016650091
SPE CAD NEWS Summer 2014 page 7 wwwspecadorg
900 am - Golf Outing300 pm
100pm - Registration Desk Open600 pm
100pm - EXHIBITOR SET-UP530 pm
600 pm Welcome Reception Sponsors EMD Chemicals and Kronos800 pm (Pick up your registration packet prior to this event to get your complimentary drink coupons)
Golf Outing Prizes will be presented at the Welcome Reception
730 BREAKFAST (Biffon A) Sponsor Lansco730 Registration Desk Opens
MORNING SESSION MODERATOR BRUCE MULHOLLAND CELANESE815 OPENING REMARKS Earl Balthazar
830 KEYNOTE Public Percepton of Plastics Rudy Underwood American Chemistry Council
930 The Global Economy-Precariousness of Supply Chain Globalization of Regulations and How to Protect YourselfBruce Howie Dominion Color
1000 COFFEE BREAK Sponsor Clariant
1030 Fundamentals of Twin-Screw Extrusion- Color MB Prossessing Common Pitfalls and How to Avoid ThemPaul G Anderson Coperion
1100 Influence of TiO2 Feeding on Twin Screw Extrusion Compounding JD Connolly DuPontTitanium Technologies
1130 Dispersion of Pigments in Plastics Applications Mahesh Mettelloo Sudarshan
1230 - 130 LUNCH (on your own)
CAD RETEC 2014reg
SUNDAY September 14
MONDAY MORNING (Mardi Gras Ballroom) September 15
CONFERENCE HOTEL INFORMATIONMarriott New OrleansTo Reserve by Phone 504-581-1000 or 1-888-364-1200Request Group Rate Society of Plastics Engineers - Color amp Appearance Division
MARRIOTT NEW ORLEANS555 Canal Street New Orleans Louisiana 70130 Phone 504-581-1000 Toll Free 1-888-364-1200
Discounted Conference Room Rate $159night-single occupancyRoom Block Dates Sept 12-17
Rates will increase significantly after August 15 2014 at 5pm or whenever the room block is full Cancellation policy Any hotel reservation canceled within 48 hours of arrival date will be charged for one (1) nights room and tax
AFTERNOON SESSION MODERATOR NATHAN KARSZES NUBIOLA130 Panel Discussion
Audience Response Devices will be available to each audience member for responding to poll questions during the panel discussion
300 COFFEE BREAK Sponsor Shepherd
330 Pigments for Sensitive Applications Tom Chirayil BASF
400 Advances in Liquid Color Technology Inga Lesko Clariant BU Masterbatch
430 New Technology Forum (pdf) Moderator Sandra Davis
500 NETWORKING RECEPTION Sponsor Nubiola
700 5K Fun RunWalk for Habitat for Humanity Plastics (Pregister for this event) Sponsor Dominion
730 BREAKFAST(on your own)
MORNING SESSION MODERATOR AUSTIN REID DUPONT TITANIUM TECHNOLOGIES
900 Colorants for Plastics-Emerging Trends and Technologies Krishnamoorthy Sivakumar PolyOne
930 Iron OxidesInorganic Pigments for Plastics George Podolsky Rockwood Pigments
1000 COFFEE BREAK Sponsor DuPont
1030 Blue Undertone Enhancement of Black and Grey PP Injection Molded PP Nathan Karszes Nubiola
1100 Lighter Faster Stronger Additive Solutions for Automotive Plastics Emilie Meddah Clariant BU Additives
1130 Gaining Competitive Advantage through Digital Appearance Technology in the Automotive Interior Supply ChainPhil Ruggiero Datacolor
1200 AWARDS LUNCHEON PRESERVATION HALL (Included with Registration) Sponsor Tronox
AFTERNOON SESSION MODERATOR JIM FIGANIAK
130 Inorganic Pigments From Caveman to the 21st Century Mark Ryan Shepherd Company
200 Measurement Technology to Evaluate Light Protection What You See May Not Be What You ProtectPhil Miedenzu DuPont Titanium Technologies
230 COFFEE BREAK Sponsor Munzing
300 Effects of Disinfectant Grade Cleaner on Physical Properties of Cell Phone Cases Diane McLendonOtterbox
330 Its a Colorful World Developing Technologies to Keep it that Way Joseph Fay BASF
400 Closing Remarks - Earl Balthazar Survey Raffle - MC-Tracy Phillips Uniform Color Grand Prize TBDOther Prizes Archive DVD Free Night at Westin Free Registration at CAD RETECreg 2015 Emergency RadioCAD RETECreg Limited Edition Art
Must be present to win
MONDAY AFTERNOON (Mardi Gras Ballroom) September 15
TUESDAY MORNING September 16
TUESDAY AFTERNOON (Mardi Gras Ballroom) September 16
SPE CAD NEWS Summer 2014 page 8 wwwspecadorg
SPE CAD NEWS Summer 2014 page 9 wwwspecadorg
Lobby of New Orleans Marriott 555 Canal Street
FREE T-SHIRT FOR THEFIRST 40 RUNNERS
September 16th 7am
$20 Registration Fee bullAll proceeds go to Habitat for HumanitySPE CAD will match every $20 donation
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sponsored by
Sponsored by
SPE CAD NEWS Spring 2014 page 10 wwwspecadorg
Gold Level Sponsors
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WE ARE PROUD TO HIGHLIGHT THESE EXCELLENT COMPANIESPlease visit our generous sponsorsrsquo websites by clicking on their logos below
T H E G O L D S T A N D A R D I N P L A S T I C S
Thank you RETECreg 2014 Sponsors
Cappelle
Celanese
LTL Color Compounders Inc
Pigments colour the world
our passion your colors
C R e A t i N g A d d i t i v e v A L u e
LANSCO COLORS
E C K A R TEffect Pigments
High Performance Pigments for Demanding Applications Rotational MoldingJoseph J Fay PhD amp Peter Zillitto
Plastics Technical Center Pigments DivisionCiba Specialty Chemicals Corporation
Technical Article
INTRODUCTIONColorants for polymer applications are typically incorporated into the polymer by one of several common pathways Colorconcentrates which are widely used in industry enable the end user to conveniently meter in the colorant at the prescribedration with virgin or uncolored polymer in the manufacturing process The benefits of concentrate used as compared to thedirect use of powder pigment during final product conversion processes include predispersion of the pigment in a suit-able carrier system elimination of the need to in-house compounding to incorporate the colorant uniformly and improvedhousekeeping etc Furthermore color concentrates are available ina number of product forms including pelleted concen-trates liquid color systems and pastes the latter used especially for PVC For polymer conversion processes in which anextruder or meld mixing devise is employed these colorant preparations can be used very effectively In some marketswhere high levels of functional fillers modifiers or polymer blends are used compounders may manufacture ldquoprecoloredrdquopolymer by direct addition of the colorant to their compounding line In come cases concentrates are used depending uponspecific product and process capabilities
Rotational molding in contrast is a low shear process in which traditional pellet form color concentrates are not suitableColoration of rotomolding resin is commonly obtained by the use of dry color and liquid color which can be added direct-ly to the ground rotomolding resin Alternatively precolored resin in which the pigment is compounded into to the poly-mer and then ground before use finds applications as well More recently micropellet technology has been advanced as an alternative to the aforementioned methods It is similar to precompounded color but the need for grinding the polymerinto the appropriate mesh size is eliminated as the micropellets can be rotomolded without further processing For each ofthese color incorporation methods there are advantages and disadvantages including economic factors (process equipmentand material cost) ease of use housekeeping and overall quality (physical properties and aesthetics) of the resulting part
As a consequence of the myriad applications the palette of pigments for rotational molding appears to be quite extensivesimilar to that which is used in general purpose polyethylene application requirements However due to the specific processconditions involved in preparing the pigment system the temperature profile of the rota-tional molding process and the end use application requirement the gamut of pigments issignificantly reduced
Pigment selection may also be affected by the method by which the pigment is to be deliv-ered Liquid colorant systems work best with pigments that have the potential to be loadedto high weight percentages while maintaining suitable viscosity Pigments used in drycolor require characteristics that impart dispersibility and minimize agglomeration duringboth dry color manufacture and blending with the rotomolding resin
DISPERSIONWhen pigments are manufactured the smallest pigment particles formed are discreet units referred to as primary particlesAs a result of their high surface energy these particles randomly join together to form aggregates and agglomerates thelatter being formed primarily during subsequent filtration a nd drying processes To achieve a speck-free system the pig-ment must be effectively ldquodispersedrdquo so that the individual pigment particles or aggregates are wetted by the polymer anddiscrete pigment particles are not visible to the naked eye Rotomolding pigment systems (liquid color and dry color) needto be prepared in a manner that ensures visible agglomerates are eliminated and that during subsequent mixing with therotomolding resin the colorant system will be easily distributed Furthermore the dispersion of the pigment needs to effec-tively deliver a colorant that will provide a high color strength potential to maximize economic while not adversely affect-ing other properties Figure 1 illustrates the particle size of the typical azoncondensation pigment continued on page 12
SPE CAD NEWS Summer 2014 page 11 wwwspecadorg
The following Technical Article was published in 1998 at The Color And Appearance Conference in September
continued from page 11
Note that the particle size distribution that would beobtained in a polymeric system will be very dependentupon the effectiveness of the final dispersion
HIGH PERFORMANCE PIGMENTSHigh performance pigments HPP can be defined as pig-ments that have either very good to excellent heat or lightstability and more commonly pigments which offer aunique combination of both heat and light stability Theenhanced UV and heat performance attributes of HPPs setthem apart from traditional or classical pigments such asthe lithol rubines (PR 571) lake red C (PR 531) 2B toner(PR 48 types) monoaso yellows such as PY 62 and oth-ers which have only limited heat stability and mostly mar-ginal to poor lightfastness
The major types of high performance pigment chemistriescan be described in a general fashion as indicated in Table 1Some individual pigments within these chemistries mayhave better or worse performance characteristics depend-ing upon the specific product attribute and applicationbeing considered
HEAT STABILITYOrganic pigments are available not only with a wide vari-ety of hues and chroma but also with considerable variationin performance characteristics Rotational molding withits combination of relatively long cycle times high moldsurface temperatures and abundance of oxygen is moredemanding upon the polymer stabilization package andpigmentation in comparison to many other processes As aconsequence many rotomolded product applicationsrequire the use of higher performance pigments to survivethe molding process even though the pigment with regardto final product requirements may be viewed as ldquoover engi-neeredrdquo Classical pigments such as 2B reds (CI PigmentRed 48rsquos) with only limited thermal stability in high tem-perature olefin polymer applications may not be suitablefor even non durable articles as the color stability duringmolding may be insufficient Figure 2 compares the heatstability of a calcium 2B toner with high performance dike-topyrrolo-pyrrole (DPP) and quinacridone (QA)chemistries In masstone applications it is readily apparentthat the 2B toner is quite deficient when compared withthese high heat stability pigments Furthermore as pigment
SPE CAD NEWS Summer 2014 page 12 wwwspecadorg
heat stability is generally related to concentration at lowerconcentrations the 2B toner would become even moreprone to color change In addition to pigment instabilitycolor change during rotational molding may be affected byother factors The stability of the base resin is an importantconsideration The role of the antioxidant package is criti-cal to controlling the initial color and maintaining the phys-ical properties of the rotomolding resin Judicious selectionof a phenolic antioxidant and phosphite processing stabi-lizer package is essential for the base polymer Dependingupon specific circumstances additional antioxidant mightbe added The most effective stabilization is typicallyobtained when the antioxidant is added directly to the resinitself during manufacture or during compounding whenrecolored resin is prepared For specialty applications
where additional antioxidants are needed to attain the req-uisite performance precolored or preformulated resinwhich is then ground provides additional benefit
LIGHT STABILITYMany applications of rotationally molded articles find enduses which require UV durability These UV performanceapplications encompass a broad variety of applications andmarkets residential waste containers childrenrsquos play-ground toys (both for residential and institutional uses)outdoor sporting goods (kayaks and component of otherrecreational vehicles) and oversize containers (industrialcontainers and agricultural tanks) For outdoor applica-tions careful formulation is required to achieve not onlysuitable color match but also a color combination whichwill have the desired weatherability As delineated inFigure 3 Calcium 2B toners have limited light stability inpolyolefin applications and are not recommended for usewhere any significant UV exposure is intended Althoughnot reflected in the colorimetric data the 2B toner samplesurface was significantly marred by chalking and surfacemicrocracking and is visible via low magnification optical
Quinacridone Copper PhthalocyanineDiketopyrrolo-pyrrole (DPP) AnthraquinoneTetrachchloroisoindolinone IndanthroneAzochondensation PeryleneBenzimidozone Isoindoline
Table 1 High Performance Chemistry Families
continued from page 12
SPE CAD NEWS Summer 2014 page 13 wwwspecadorg
microscopy Such microcracks may ultimately result inpremature physical failures of the product Therefore visu-al inspection of samples following accelerated or real-timeexposure testing is imperative to ensure complete perform-ance analysis As a consequence of the limited weather-ability of many pigments performance assessment is need-ed Applications such as point of sale displays and relateditems and indoor applications where incidental UV expo-sure from lighting fixtures or nearby windows is possibleare best formulated with durable HPP pigments Outdoorapplications require the use of HPP pigments at levels thatcan provide sufficient levels of weather resistance
Figure 5 illustratesthe difference inlong-term UV sta-bility that wasobtained when aDPP red (PR254) was com-pared with a pery-lene red (PR178) Perylenepigments areprone to darken-ing when used inconjunction withhindered amine light stabilizers (HALS) whereas no suchnegative interaction has been observed for DPPchemistries
Other high performance pigment classes such as copperphthalocyanine blue pigments may also be suitable foroutdoor applications when properly formulated PB 151and PB 153 are widely used in rotational molding appli-cations as a consequence of their outstanding performanceproperties Figure 6 and tremendous value in use
Inorganic and heavy metal pigments are also widely usedin some rotational molding applications due to their general-ly good dispersibility characteristics and in many cases thecleanliness of shade that may be obtained when using cer-tain cadmium and lead chromate pigments However aswill be discussed in greater detail regulatory pressureshave resulted in heavy metal deselection in several appli-
cation areas including food packaging and many toy appli-cations There applications however have not always beeneasily reformulated The use of HPP products providesalternatives in many color space applications Additionallywith the recent introduction of several new DPP productsPR 264 (Figure 7) PR 272 and PO 71 and PO 73(Figure 8) into the polyolefin and PVC market areas agreater breadth of high performance organics is availablefor formulating In some case differences in the perform-ance of organic versus heavy metal pigments may result inadditional raw material costs Material selection and mod-ification of base stabilization are required in some casesand additional light stabilization packages are needed
continued on page 14
continued on page 15
continued from page 13
SPE CAD NEWS Summer 2014 page 14 wwwspecadorg
especially when formulating polyolefins for outdoor appli-cations to provide comparable alternatives Nonethelessconsumers (materials specifiers manufacturers and theultimate product purchaser) choosing to avoid use of cad-mium and lead pigments wherever reasonably possibleremains a continuously evolving trend
The formulation of rotationally molded articles for outdoorapplications requires the use of both suitable pigments aswell as the assistance of a well-designed light stabilizerpackage The use of tetramethyl piperidine based hinderedamine light stabilizers especially oligomeric and highmolecular weight types in combination with benzotriazolebased UV absorbers are recommended for use in a varietyof applications The total package loading should be tai-lored to meet the specified requirement of the application
DISTORTION EFFECTSDistortion of rotomolded articles can be effected by sever-al different variables Resin choice and the particular mate-rial being used can affect warpage and shrinkageDifferences in cooling of the mold thickness variationsovercuring and several other process parameters have beenfound to be related to warping Since pigments (and thesystems used to deliver them) may alter the flow character-istics of the polymer and also the cure characteristics oper-ation of a given mold with different pigments or colorantsystems with a single cure cycle may result in differencesin dimensional stability The use of controlled heating andcooling as well as good control over the process itself willhelp to ensure consistent part manufacturing as well as agood data and record keeping can be referred to in case oferratic part quality
IMPACT PROPERTIESImpact properties are commonly tested as a means ofassessing the quality and suitability of colorant systems aswell as for assessing the cure characteristics of the polymerand the properties of the final product The ARM(Association of Rotational Molders) impact test is a com-mon test that is used Alternative instrumented testing pro-vides similar test result capabilities with the advantage ofquantitative and qualitative data acquisition
Impact properties of rotomolded products are importantMany toys containers and other applications require assur-ances of product integrity which can often be affected notonly by the process conditions but also by the incorpora-tion of pigments and other additives Since there is very lit-tle shear in the rotomolding process pigments are likely tobe located at the grain boundary between adjacent polymergranules This localization of pigment and ldquoadditivesrdquo can adversely affect physical properties in sev-eral ways Inhibition of polymer chain entanglementsbetween particles due to additives that form an interfacebetween resin particles can result in weak distinct bound-aries with poor mechanical properties Also pigmentagglomerates which are not broken apart or more trou-bling when they are formed during premixing processesdue to excessive mixing may introduce point defectseffecting physical properties Aesthetic properties may alsobe impacted if agglomerates are present in either signifi-cant size or number Pigment loading which is related toboth the effectiveness in which the pigment can be dis-persed as well as the color requirements of the part isanother factor to be considered in assessing the potentialeffect of coloration on physical properties
REGULATORY ASPECTSWith the variety of applications encountered in rotationalmolding well-publicized legislation and public opinionhave compelled many plastics processors and end-users touse alternatives to cadmium and lead based pigmentsCONEG (COalition of NorthEast Governors) related legis-lation prohibits the sale of packaging materials to whichcadmium lead mercury and hexavalent chromium or theircompounds have been intentionally added Reducing theamount of these elements entering the food chain via wastedisposal sources and the extra precautions needed to dis-pose of post industrial wastes are issues to be addressesCertainly both lead and cadmium-based pigments possessa combination of desireable technical properties that makesthem articularly useful coloring materials for polymersLead based pigments furthermore are particularly eco-nomical in use Nonetheless public opinion and legislationhave had and will likely continue to have a significantimpact on their use particularly in consumer goods
SPE CAD NEWS Summer 2014 page 15 wwwspecadorg
The Color and Appearance Division (CAD) is commit-ted to the publishing of at least three newsletters a year(four if there is sufficient material to justify the extraissue) To that end we would like you to think aboutthe financial side of sponsorship of the newsletter Forthe small donation of $300 per year we offer a businesscard sized (2 x 35) mention in our newsletter whichgoes out to the nearly 1500 members of the CAD aswell as other SPE division members These are peopleactive in every aspect of plastic coloring and additivetechnology Larger sized spots are available at a com-mensurate increase in rate
If you are interested in helping to sponsor theSPECAD Newsletter please contactScott Aumann Phone 912 210 0175
Email ScottAumannedmmilliporecom
Your Company Our Division
Dear Members
Just a reminder that you can view past and currentBOARD MINUTES on the SPECAD website
We do not typically publish the minutes in the elec-tronic versions of our newsletter but they are alwaysavailable for our members to view from our websiteThe site is not completely current at this time as weare in the process of giving it a makeover and newlaunch in January
Click here for the link to viewhttpwwwspecadorgindexphpnavid=28
Board Minutes
CONNECT WITH SPE CAD VIASOCIAL MEDIA
Join SPECADrsquos Group On Linked Into network with industry peers participate in groupdiscussions of industry and technical topics findjob opportunities and get the latest division andconference announcements
Group Name SPE Color amp AppearanceDivision Group ID 152108 wwwlinkedincomgroupsgid=152108
continued from page 14
Colorants for polymers that are suitable for food contactuse according to 21 CFR1783297 by the FDA (Food andDrug Administration) NSF (National SanitationFoundation) listing for Potable water contact applicationsand ASTM toy specifications may further place limitationson which pigments may be used
CONCLUSIONSRotational molding presents specific performance require-ment for colorants due to the process dynamics and end-user application needs High performance organic pig-ments in addition to inorganic pigments provide usefulsolutions for designers and manufacturers of rotationallymolded products However as this market continues togrow due to the many unique product features attributed tothe rotomolding process advancements in pigmentationstabilization resin processes and ancillary products shouldalso grow as well Active research and development in sta-bilization technology continues to advance new productsand uniquely designed chemistries (such as lactone andhydroxylamine process stabilizers) into the market placeNew pigment products such as those based upon DPPchemistry also show promise in rotational molding appli-cations Moreover these new products further broadenproduct development potential by providing ever increas-ing performance and greater value in use
ACKNOWLEDGEMENTSThis paper would not have been possible without the col-laborative efforts os Steve Juhasz and Dick Huska of thePlastics Technical Center in Newport DE and JohnLinehan and Urs Stadler of the Additives DivisionLaboratories in Tarrytown NY Appreciation is also givento colleagues of Ciba Specialty Chemicals PigmentsDivision in Basle Switzerland for additional data
DuPonttrade Ti-Purereg titanium dioxide
DuPont Titanium Technologies8004419485
wwwtitaniumdupontcom
The DuPont Oval DuPont trade The miracles of sciencereg and Ti-Purereg
are trademarks or registered trademarks of EI du Pont de Nemours and Company
POLYMERS LIGHT amp SCIENCE
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B PVC AdditivesB Lubricants amp Stabilizers
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LANXESS Corporation111 RIDC Park West Drive 1-800-526-9377Pittsburgh PA 15275-1112 wwwlanxesscom
World Leaders in Ultramarine PigmentswUltramarine Blue wUltramarine VioletwChrome Oxide Green wLead Chromate
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Phone 77027788196369 Peachtree Street Fax 7702778809Norcross GA 30071 Toll Free 8008866981wwwnubiolacom
We create chemistry for plastics
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Our UV light stabilizers antioxidants nucleatorsfect and functional pigments efneeds with color r ef
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Visit our website and color blogwwwcyberchromeusacom
CyberChrome Inc3642 Main Street tStone Ridge NY 12484
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Color Concentrates and Single Pigment Dispersionsfor all Thermoplastic Polymers
Corporate Offices400 Old Dublin PikeDoylestown PA 18901(215) 345-6550
Operations amp Research Center2755 Bergey RoadHatfield PA 19440(215) 997-2221wwwpenncolorcom
SPE CAD NEWS Summer 2014 page 16 wwwspecadorg
SPE CAD NEWS Summer 2014 page 17 wwwspecadorg
Special thanks to our our Speakers Sponsors Exhibitors and Participants for your contributions to this yearrsquos CAD RETECreg 2014
Earl Balthazar III CAD RETECreg 2014 Conference Chair Datacolor Inc (817) 719-0224 CAD_RETECtxrrcomMark FreshwaterCAD RETECreg 2014 Vice-ChairLansco Colors(330) 526-8833markpigmentscom
Nathan KarszesCAD RETECreg 2014 Technical Program Co-ChairNubiola Corporation(770) 527-2409nkarszesnubiolacomBrenda MullinsCAD RETECreg2014 Technical Program Co-ChairClariant Corporation(678) 237-2975 brendamullinsclariantcom
SPE CAD NEWS Summer 2014 page 18 wwwspecadorg
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September 26 2014 ndash 500pm EDT
A SPE ANTECreg
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Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom
GOLF OUTING INFORMATION
SPE CAD NEWS Summer 2014 page 6 wwwspecadorg
Price $13000 per golfer
Includes Warm up on the RangeGreen FeesCart FeeScramble formatBox Lunch with DrinkCustomized TPC Bag Tag
Course LocationTPC Louisiana11001 Lapalco BlvdAvondale LA 70094(504) 4368721
Registration 1100 am (CST) Shotgun Start 12 noon (CST)Awards Will be presented at CAD RETECreg
Welcoming Reception
September 14 2014
To Sign Up Online RegistrationQuestions Contact
Mark Tylermarktylercelanesecom 8593723221 or
Mark Freshwatermarkpigmentscom 2016650091
SPE CAD NEWS Summer 2014 page 7 wwwspecadorg
900 am - Golf Outing300 pm
100pm - Registration Desk Open600 pm
100pm - EXHIBITOR SET-UP530 pm
600 pm Welcome Reception Sponsors EMD Chemicals and Kronos800 pm (Pick up your registration packet prior to this event to get your complimentary drink coupons)
Golf Outing Prizes will be presented at the Welcome Reception
730 BREAKFAST (Biffon A) Sponsor Lansco730 Registration Desk Opens
MORNING SESSION MODERATOR BRUCE MULHOLLAND CELANESE815 OPENING REMARKS Earl Balthazar
830 KEYNOTE Public Percepton of Plastics Rudy Underwood American Chemistry Council
930 The Global Economy-Precariousness of Supply Chain Globalization of Regulations and How to Protect YourselfBruce Howie Dominion Color
1000 COFFEE BREAK Sponsor Clariant
1030 Fundamentals of Twin-Screw Extrusion- Color MB Prossessing Common Pitfalls and How to Avoid ThemPaul G Anderson Coperion
1100 Influence of TiO2 Feeding on Twin Screw Extrusion Compounding JD Connolly DuPontTitanium Technologies
1130 Dispersion of Pigments in Plastics Applications Mahesh Mettelloo Sudarshan
1230 - 130 LUNCH (on your own)
CAD RETEC 2014reg
SUNDAY September 14
MONDAY MORNING (Mardi Gras Ballroom) September 15
CONFERENCE HOTEL INFORMATIONMarriott New OrleansTo Reserve by Phone 504-581-1000 or 1-888-364-1200Request Group Rate Society of Plastics Engineers - Color amp Appearance Division
MARRIOTT NEW ORLEANS555 Canal Street New Orleans Louisiana 70130 Phone 504-581-1000 Toll Free 1-888-364-1200
Discounted Conference Room Rate $159night-single occupancyRoom Block Dates Sept 12-17
Rates will increase significantly after August 15 2014 at 5pm or whenever the room block is full Cancellation policy Any hotel reservation canceled within 48 hours of arrival date will be charged for one (1) nights room and tax
AFTERNOON SESSION MODERATOR NATHAN KARSZES NUBIOLA130 Panel Discussion
Audience Response Devices will be available to each audience member for responding to poll questions during the panel discussion
300 COFFEE BREAK Sponsor Shepherd
330 Pigments for Sensitive Applications Tom Chirayil BASF
400 Advances in Liquid Color Technology Inga Lesko Clariant BU Masterbatch
430 New Technology Forum (pdf) Moderator Sandra Davis
500 NETWORKING RECEPTION Sponsor Nubiola
700 5K Fun RunWalk for Habitat for Humanity Plastics (Pregister for this event) Sponsor Dominion
730 BREAKFAST(on your own)
MORNING SESSION MODERATOR AUSTIN REID DUPONT TITANIUM TECHNOLOGIES
900 Colorants for Plastics-Emerging Trends and Technologies Krishnamoorthy Sivakumar PolyOne
930 Iron OxidesInorganic Pigments for Plastics George Podolsky Rockwood Pigments
1000 COFFEE BREAK Sponsor DuPont
1030 Blue Undertone Enhancement of Black and Grey PP Injection Molded PP Nathan Karszes Nubiola
1100 Lighter Faster Stronger Additive Solutions for Automotive Plastics Emilie Meddah Clariant BU Additives
1130 Gaining Competitive Advantage through Digital Appearance Technology in the Automotive Interior Supply ChainPhil Ruggiero Datacolor
1200 AWARDS LUNCHEON PRESERVATION HALL (Included with Registration) Sponsor Tronox
AFTERNOON SESSION MODERATOR JIM FIGANIAK
130 Inorganic Pigments From Caveman to the 21st Century Mark Ryan Shepherd Company
200 Measurement Technology to Evaluate Light Protection What You See May Not Be What You ProtectPhil Miedenzu DuPont Titanium Technologies
230 COFFEE BREAK Sponsor Munzing
300 Effects of Disinfectant Grade Cleaner on Physical Properties of Cell Phone Cases Diane McLendonOtterbox
330 Its a Colorful World Developing Technologies to Keep it that Way Joseph Fay BASF
400 Closing Remarks - Earl Balthazar Survey Raffle - MC-Tracy Phillips Uniform Color Grand Prize TBDOther Prizes Archive DVD Free Night at Westin Free Registration at CAD RETECreg 2015 Emergency RadioCAD RETECreg Limited Edition Art
Must be present to win
MONDAY AFTERNOON (Mardi Gras Ballroom) September 15
TUESDAY MORNING September 16
TUESDAY AFTERNOON (Mardi Gras Ballroom) September 16
SPE CAD NEWS Summer 2014 page 8 wwwspecadorg
SPE CAD NEWS Summer 2014 page 9 wwwspecadorg
Lobby of New Orleans Marriott 555 Canal Street
FREE T-SHIRT FOR THEFIRST 40 RUNNERS
September 16th 7am
$20 Registration Fee bullAll proceeds go to Habitat for HumanitySPE CAD will match every $20 donation
dominioncolourcom
sponsored by
Sponsored by
SPE CAD NEWS Spring 2014 page 10 wwwspecadorg
Gold Level Sponsors
Platinum Level Sponsors
Silver Level Sponsors
WE ARE PROUD TO HIGHLIGHT THESE EXCELLENT COMPANIESPlease visit our generous sponsorsrsquo websites by clicking on their logos below
T H E G O L D S T A N D A R D I N P L A S T I C S
Thank you RETECreg 2014 Sponsors
Cappelle
Celanese
LTL Color Compounders Inc
Pigments colour the world
our passion your colors
C R e A t i N g A d d i t i v e v A L u e
LANSCO COLORS
E C K A R TEffect Pigments
High Performance Pigments for Demanding Applications Rotational MoldingJoseph J Fay PhD amp Peter Zillitto
Plastics Technical Center Pigments DivisionCiba Specialty Chemicals Corporation
Technical Article
INTRODUCTIONColorants for polymer applications are typically incorporated into the polymer by one of several common pathways Colorconcentrates which are widely used in industry enable the end user to conveniently meter in the colorant at the prescribedration with virgin or uncolored polymer in the manufacturing process The benefits of concentrate used as compared to thedirect use of powder pigment during final product conversion processes include predispersion of the pigment in a suit-able carrier system elimination of the need to in-house compounding to incorporate the colorant uniformly and improvedhousekeeping etc Furthermore color concentrates are available ina number of product forms including pelleted concen-trates liquid color systems and pastes the latter used especially for PVC For polymer conversion processes in which anextruder or meld mixing devise is employed these colorant preparations can be used very effectively In some marketswhere high levels of functional fillers modifiers or polymer blends are used compounders may manufacture ldquoprecoloredrdquopolymer by direct addition of the colorant to their compounding line In come cases concentrates are used depending uponspecific product and process capabilities
Rotational molding in contrast is a low shear process in which traditional pellet form color concentrates are not suitableColoration of rotomolding resin is commonly obtained by the use of dry color and liquid color which can be added direct-ly to the ground rotomolding resin Alternatively precolored resin in which the pigment is compounded into to the poly-mer and then ground before use finds applications as well More recently micropellet technology has been advanced as an alternative to the aforementioned methods It is similar to precompounded color but the need for grinding the polymerinto the appropriate mesh size is eliminated as the micropellets can be rotomolded without further processing For each ofthese color incorporation methods there are advantages and disadvantages including economic factors (process equipmentand material cost) ease of use housekeeping and overall quality (physical properties and aesthetics) of the resulting part
As a consequence of the myriad applications the palette of pigments for rotational molding appears to be quite extensivesimilar to that which is used in general purpose polyethylene application requirements However due to the specific processconditions involved in preparing the pigment system the temperature profile of the rota-tional molding process and the end use application requirement the gamut of pigments issignificantly reduced
Pigment selection may also be affected by the method by which the pigment is to be deliv-ered Liquid colorant systems work best with pigments that have the potential to be loadedto high weight percentages while maintaining suitable viscosity Pigments used in drycolor require characteristics that impart dispersibility and minimize agglomeration duringboth dry color manufacture and blending with the rotomolding resin
DISPERSIONWhen pigments are manufactured the smallest pigment particles formed are discreet units referred to as primary particlesAs a result of their high surface energy these particles randomly join together to form aggregates and agglomerates thelatter being formed primarily during subsequent filtration a nd drying processes To achieve a speck-free system the pig-ment must be effectively ldquodispersedrdquo so that the individual pigment particles or aggregates are wetted by the polymer anddiscrete pigment particles are not visible to the naked eye Rotomolding pigment systems (liquid color and dry color) needto be prepared in a manner that ensures visible agglomerates are eliminated and that during subsequent mixing with therotomolding resin the colorant system will be easily distributed Furthermore the dispersion of the pigment needs to effec-tively deliver a colorant that will provide a high color strength potential to maximize economic while not adversely affect-ing other properties Figure 1 illustrates the particle size of the typical azoncondensation pigment continued on page 12
SPE CAD NEWS Summer 2014 page 11 wwwspecadorg
The following Technical Article was published in 1998 at The Color And Appearance Conference in September
continued from page 11
Note that the particle size distribution that would beobtained in a polymeric system will be very dependentupon the effectiveness of the final dispersion
HIGH PERFORMANCE PIGMENTSHigh performance pigments HPP can be defined as pig-ments that have either very good to excellent heat or lightstability and more commonly pigments which offer aunique combination of both heat and light stability Theenhanced UV and heat performance attributes of HPPs setthem apart from traditional or classical pigments such asthe lithol rubines (PR 571) lake red C (PR 531) 2B toner(PR 48 types) monoaso yellows such as PY 62 and oth-ers which have only limited heat stability and mostly mar-ginal to poor lightfastness
The major types of high performance pigment chemistriescan be described in a general fashion as indicated in Table 1Some individual pigments within these chemistries mayhave better or worse performance characteristics depend-ing upon the specific product attribute and applicationbeing considered
HEAT STABILITYOrganic pigments are available not only with a wide vari-ety of hues and chroma but also with considerable variationin performance characteristics Rotational molding withits combination of relatively long cycle times high moldsurface temperatures and abundance of oxygen is moredemanding upon the polymer stabilization package andpigmentation in comparison to many other processes As aconsequence many rotomolded product applicationsrequire the use of higher performance pigments to survivethe molding process even though the pigment with regardto final product requirements may be viewed as ldquoover engi-neeredrdquo Classical pigments such as 2B reds (CI PigmentRed 48rsquos) with only limited thermal stability in high tem-perature olefin polymer applications may not be suitablefor even non durable articles as the color stability duringmolding may be insufficient Figure 2 compares the heatstability of a calcium 2B toner with high performance dike-topyrrolo-pyrrole (DPP) and quinacridone (QA)chemistries In masstone applications it is readily apparentthat the 2B toner is quite deficient when compared withthese high heat stability pigments Furthermore as pigment
SPE CAD NEWS Summer 2014 page 12 wwwspecadorg
heat stability is generally related to concentration at lowerconcentrations the 2B toner would become even moreprone to color change In addition to pigment instabilitycolor change during rotational molding may be affected byother factors The stability of the base resin is an importantconsideration The role of the antioxidant package is criti-cal to controlling the initial color and maintaining the phys-ical properties of the rotomolding resin Judicious selectionof a phenolic antioxidant and phosphite processing stabi-lizer package is essential for the base polymer Dependingupon specific circumstances additional antioxidant mightbe added The most effective stabilization is typicallyobtained when the antioxidant is added directly to the resinitself during manufacture or during compounding whenrecolored resin is prepared For specialty applications
where additional antioxidants are needed to attain the req-uisite performance precolored or preformulated resinwhich is then ground provides additional benefit
LIGHT STABILITYMany applications of rotationally molded articles find enduses which require UV durability These UV performanceapplications encompass a broad variety of applications andmarkets residential waste containers childrenrsquos play-ground toys (both for residential and institutional uses)outdoor sporting goods (kayaks and component of otherrecreational vehicles) and oversize containers (industrialcontainers and agricultural tanks) For outdoor applica-tions careful formulation is required to achieve not onlysuitable color match but also a color combination whichwill have the desired weatherability As delineated inFigure 3 Calcium 2B toners have limited light stability inpolyolefin applications and are not recommended for usewhere any significant UV exposure is intended Althoughnot reflected in the colorimetric data the 2B toner samplesurface was significantly marred by chalking and surfacemicrocracking and is visible via low magnification optical
Quinacridone Copper PhthalocyanineDiketopyrrolo-pyrrole (DPP) AnthraquinoneTetrachchloroisoindolinone IndanthroneAzochondensation PeryleneBenzimidozone Isoindoline
Table 1 High Performance Chemistry Families
continued from page 12
SPE CAD NEWS Summer 2014 page 13 wwwspecadorg
microscopy Such microcracks may ultimately result inpremature physical failures of the product Therefore visu-al inspection of samples following accelerated or real-timeexposure testing is imperative to ensure complete perform-ance analysis As a consequence of the limited weather-ability of many pigments performance assessment is need-ed Applications such as point of sale displays and relateditems and indoor applications where incidental UV expo-sure from lighting fixtures or nearby windows is possibleare best formulated with durable HPP pigments Outdoorapplications require the use of HPP pigments at levels thatcan provide sufficient levels of weather resistance
Figure 5 illustratesthe difference inlong-term UV sta-bility that wasobtained when aDPP red (PR254) was com-pared with a pery-lene red (PR178) Perylenepigments areprone to darken-ing when used inconjunction withhindered amine light stabilizers (HALS) whereas no suchnegative interaction has been observed for DPPchemistries
Other high performance pigment classes such as copperphthalocyanine blue pigments may also be suitable foroutdoor applications when properly formulated PB 151and PB 153 are widely used in rotational molding appli-cations as a consequence of their outstanding performanceproperties Figure 6 and tremendous value in use
Inorganic and heavy metal pigments are also widely usedin some rotational molding applications due to their general-ly good dispersibility characteristics and in many cases thecleanliness of shade that may be obtained when using cer-tain cadmium and lead chromate pigments However aswill be discussed in greater detail regulatory pressureshave resulted in heavy metal deselection in several appli-
cation areas including food packaging and many toy appli-cations There applications however have not always beeneasily reformulated The use of HPP products providesalternatives in many color space applications Additionallywith the recent introduction of several new DPP productsPR 264 (Figure 7) PR 272 and PO 71 and PO 73(Figure 8) into the polyolefin and PVC market areas agreater breadth of high performance organics is availablefor formulating In some case differences in the perform-ance of organic versus heavy metal pigments may result inadditional raw material costs Material selection and mod-ification of base stabilization are required in some casesand additional light stabilization packages are needed
continued on page 14
continued on page 15
continued from page 13
SPE CAD NEWS Summer 2014 page 14 wwwspecadorg
especially when formulating polyolefins for outdoor appli-cations to provide comparable alternatives Nonethelessconsumers (materials specifiers manufacturers and theultimate product purchaser) choosing to avoid use of cad-mium and lead pigments wherever reasonably possibleremains a continuously evolving trend
The formulation of rotationally molded articles for outdoorapplications requires the use of both suitable pigments aswell as the assistance of a well-designed light stabilizerpackage The use of tetramethyl piperidine based hinderedamine light stabilizers especially oligomeric and highmolecular weight types in combination with benzotriazolebased UV absorbers are recommended for use in a varietyof applications The total package loading should be tai-lored to meet the specified requirement of the application
DISTORTION EFFECTSDistortion of rotomolded articles can be effected by sever-al different variables Resin choice and the particular mate-rial being used can affect warpage and shrinkageDifferences in cooling of the mold thickness variationsovercuring and several other process parameters have beenfound to be related to warping Since pigments (and thesystems used to deliver them) may alter the flow character-istics of the polymer and also the cure characteristics oper-ation of a given mold with different pigments or colorantsystems with a single cure cycle may result in differencesin dimensional stability The use of controlled heating andcooling as well as good control over the process itself willhelp to ensure consistent part manufacturing as well as agood data and record keeping can be referred to in case oferratic part quality
IMPACT PROPERTIESImpact properties are commonly tested as a means ofassessing the quality and suitability of colorant systems aswell as for assessing the cure characteristics of the polymerand the properties of the final product The ARM(Association of Rotational Molders) impact test is a com-mon test that is used Alternative instrumented testing pro-vides similar test result capabilities with the advantage ofquantitative and qualitative data acquisition
Impact properties of rotomolded products are importantMany toys containers and other applications require assur-ances of product integrity which can often be affected notonly by the process conditions but also by the incorpora-tion of pigments and other additives Since there is very lit-tle shear in the rotomolding process pigments are likely tobe located at the grain boundary between adjacent polymergranules This localization of pigment and ldquoadditivesrdquo can adversely affect physical properties in sev-eral ways Inhibition of polymer chain entanglementsbetween particles due to additives that form an interfacebetween resin particles can result in weak distinct bound-aries with poor mechanical properties Also pigmentagglomerates which are not broken apart or more trou-bling when they are formed during premixing processesdue to excessive mixing may introduce point defectseffecting physical properties Aesthetic properties may alsobe impacted if agglomerates are present in either signifi-cant size or number Pigment loading which is related toboth the effectiveness in which the pigment can be dis-persed as well as the color requirements of the part isanother factor to be considered in assessing the potentialeffect of coloration on physical properties
REGULATORY ASPECTSWith the variety of applications encountered in rotationalmolding well-publicized legislation and public opinionhave compelled many plastics processors and end-users touse alternatives to cadmium and lead based pigmentsCONEG (COalition of NorthEast Governors) related legis-lation prohibits the sale of packaging materials to whichcadmium lead mercury and hexavalent chromium or theircompounds have been intentionally added Reducing theamount of these elements entering the food chain via wastedisposal sources and the extra precautions needed to dis-pose of post industrial wastes are issues to be addressesCertainly both lead and cadmium-based pigments possessa combination of desireable technical properties that makesthem articularly useful coloring materials for polymersLead based pigments furthermore are particularly eco-nomical in use Nonetheless public opinion and legislationhave had and will likely continue to have a significantimpact on their use particularly in consumer goods
SPE CAD NEWS Summer 2014 page 15 wwwspecadorg
The Color and Appearance Division (CAD) is commit-ted to the publishing of at least three newsletters a year(four if there is sufficient material to justify the extraissue) To that end we would like you to think aboutthe financial side of sponsorship of the newsletter Forthe small donation of $300 per year we offer a businesscard sized (2 x 35) mention in our newsletter whichgoes out to the nearly 1500 members of the CAD aswell as other SPE division members These are peopleactive in every aspect of plastic coloring and additivetechnology Larger sized spots are available at a com-mensurate increase in rate
If you are interested in helping to sponsor theSPECAD Newsletter please contactScott Aumann Phone 912 210 0175
Email ScottAumannedmmilliporecom
Your Company Our Division
Dear Members
Just a reminder that you can view past and currentBOARD MINUTES on the SPECAD website
We do not typically publish the minutes in the elec-tronic versions of our newsletter but they are alwaysavailable for our members to view from our websiteThe site is not completely current at this time as weare in the process of giving it a makeover and newlaunch in January
Click here for the link to viewhttpwwwspecadorgindexphpnavid=28
Board Minutes
CONNECT WITH SPE CAD VIASOCIAL MEDIA
Join SPECADrsquos Group On Linked Into network with industry peers participate in groupdiscussions of industry and technical topics findjob opportunities and get the latest division andconference announcements
Group Name SPE Color amp AppearanceDivision Group ID 152108 wwwlinkedincomgroupsgid=152108
continued from page 14
Colorants for polymers that are suitable for food contactuse according to 21 CFR1783297 by the FDA (Food andDrug Administration) NSF (National SanitationFoundation) listing for Potable water contact applicationsand ASTM toy specifications may further place limitationson which pigments may be used
CONCLUSIONSRotational molding presents specific performance require-ment for colorants due to the process dynamics and end-user application needs High performance organic pig-ments in addition to inorganic pigments provide usefulsolutions for designers and manufacturers of rotationallymolded products However as this market continues togrow due to the many unique product features attributed tothe rotomolding process advancements in pigmentationstabilization resin processes and ancillary products shouldalso grow as well Active research and development in sta-bilization technology continues to advance new productsand uniquely designed chemistries (such as lactone andhydroxylamine process stabilizers) into the market placeNew pigment products such as those based upon DPPchemistry also show promise in rotational molding appli-cations Moreover these new products further broadenproduct development potential by providing ever increas-ing performance and greater value in use
ACKNOWLEDGEMENTSThis paper would not have been possible without the col-laborative efforts os Steve Juhasz and Dick Huska of thePlastics Technical Center in Newport DE and JohnLinehan and Urs Stadler of the Additives DivisionLaboratories in Tarrytown NY Appreciation is also givento colleagues of Ciba Specialty Chemicals PigmentsDivision in Basle Switzerland for additional data
DuPonttrade Ti-Purereg titanium dioxide
DuPont Titanium Technologies8004419485
wwwtitaniumdupontcom
The DuPont Oval DuPont trade The miracles of sciencereg and Ti-Purereg
are trademarks or registered trademarks of EI du Pont de Nemours and Company
POLYMERS LIGHT amp SCIENCE
Polymers Light and the Science of TiO2
BTitanium Dioxide BRutile amp Anatase
BHigh Performance Organic PigmentsB DPP Reds HP Yellows
B PVC AdditivesB Lubricants amp Stabilizers
364 Johnny Mercer Blvd B-7 294 - Savannah GA 31410Tel (912)507-8972 - lwaltersagrofertinccom
wwwagrofertinccom
World Leader in EffectPigments
One International PlazaSuite 300Philadelphia PA 19113(888) 367-3275
wwwemdchemicalscom
A Complete Line of DyestuffsInorganic Pigments and
Organic Pigments forPlastics amp Fibers
LANXESS Corporation111 RIDC Park West Drive 1-800-526-9377Pittsburgh PA 15275-1112 wwwlanxesscom
World Leaders in Ultramarine PigmentswUltramarine Blue wUltramarine VioletwChrome Oxide Green wLead Chromate
wZinc Ferrite wIron Oxide
Phone 77027788196369 Peachtree Street Fax 7702778809Norcross GA 30071 Toll Free 8008866981wwwnubiolacom
We create chemistry for plastics
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eate chemistry for plastics
basfcomplastic-additiveswww
your plastic applicationsovide solutions for all ofand other additives pr
Our UV light stabilizers antioxidants nucleatorsfect and functional pigments efneeds with color r ef
BASF helps meet your style and functionality
e crWWe cr
eate chemistry for plastics
1 800 431-2360Florham Park NJ
venue100 Park A AvenueBASF Corporation
ovide solutions for all ofOur UV light stabilizers antioxidants nucleators
fect and functional pigmentsBASF helps meet your style and functionality
Color Software ExpertsSince 1986
Quality Control Formulationamp Instrument Profiling
Visit our website and color blogwwwcyberchromeusacom
CyberChrome Inc3642 Main Street tStone Ridge NY 12484
PH 845-687-2671
wwwbasf
Color Concentrates and Single Pigment Dispersionsfor all Thermoplastic Polymers
Corporate Offices400 Old Dublin PikeDoylestown PA 18901(215) 345-6550
Operations amp Research Center2755 Bergey RoadHatfield PA 19440(215) 997-2221wwwpenncolorcom
SPE CAD NEWS Summer 2014 page 16 wwwspecadorg
SPE CAD NEWS Summer 2014 page 17 wwwspecadorg
Special thanks to our our Speakers Sponsors Exhibitors and Participants for your contributions to this yearrsquos CAD RETECreg 2014
Earl Balthazar III CAD RETECreg 2014 Conference Chair Datacolor Inc (817) 719-0224 CAD_RETECtxrrcomMark FreshwaterCAD RETECreg 2014 Vice-ChairLansco Colors(330) 526-8833markpigmentscom
Nathan KarszesCAD RETECreg 2014 Technical Program Co-ChairNubiola Corporation(770) 527-2409nkarszesnubiolacomBrenda MullinsCAD RETECreg2014 Technical Program Co-ChairClariant Corporation(678) 237-2975 brendamullinsclariantcom
SPE CAD NEWS Summer 2014 page 18 wwwspecadorg
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Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
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Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
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Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
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SPE CAD NEWS Summer 2014 page 7 wwwspecadorg
900 am - Golf Outing300 pm
100pm - Registration Desk Open600 pm
100pm - EXHIBITOR SET-UP530 pm
600 pm Welcome Reception Sponsors EMD Chemicals and Kronos800 pm (Pick up your registration packet prior to this event to get your complimentary drink coupons)
Golf Outing Prizes will be presented at the Welcome Reception
730 BREAKFAST (Biffon A) Sponsor Lansco730 Registration Desk Opens
MORNING SESSION MODERATOR BRUCE MULHOLLAND CELANESE815 OPENING REMARKS Earl Balthazar
830 KEYNOTE Public Percepton of Plastics Rudy Underwood American Chemistry Council
930 The Global Economy-Precariousness of Supply Chain Globalization of Regulations and How to Protect YourselfBruce Howie Dominion Color
1000 COFFEE BREAK Sponsor Clariant
1030 Fundamentals of Twin-Screw Extrusion- Color MB Prossessing Common Pitfalls and How to Avoid ThemPaul G Anderson Coperion
1100 Influence of TiO2 Feeding on Twin Screw Extrusion Compounding JD Connolly DuPontTitanium Technologies
1130 Dispersion of Pigments in Plastics Applications Mahesh Mettelloo Sudarshan
1230 - 130 LUNCH (on your own)
CAD RETEC 2014reg
SUNDAY September 14
MONDAY MORNING (Mardi Gras Ballroom) September 15
CONFERENCE HOTEL INFORMATIONMarriott New OrleansTo Reserve by Phone 504-581-1000 or 1-888-364-1200Request Group Rate Society of Plastics Engineers - Color amp Appearance Division
MARRIOTT NEW ORLEANS555 Canal Street New Orleans Louisiana 70130 Phone 504-581-1000 Toll Free 1-888-364-1200
Discounted Conference Room Rate $159night-single occupancyRoom Block Dates Sept 12-17
Rates will increase significantly after August 15 2014 at 5pm or whenever the room block is full Cancellation policy Any hotel reservation canceled within 48 hours of arrival date will be charged for one (1) nights room and tax
AFTERNOON SESSION MODERATOR NATHAN KARSZES NUBIOLA130 Panel Discussion
Audience Response Devices will be available to each audience member for responding to poll questions during the panel discussion
300 COFFEE BREAK Sponsor Shepherd
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730 BREAKFAST(on your own)
MORNING SESSION MODERATOR AUSTIN REID DUPONT TITANIUM TECHNOLOGIES
900 Colorants for Plastics-Emerging Trends and Technologies Krishnamoorthy Sivakumar PolyOne
930 Iron OxidesInorganic Pigments for Plastics George Podolsky Rockwood Pigments
1000 COFFEE BREAK Sponsor DuPont
1030 Blue Undertone Enhancement of Black and Grey PP Injection Molded PP Nathan Karszes Nubiola
1100 Lighter Faster Stronger Additive Solutions for Automotive Plastics Emilie Meddah Clariant BU Additives
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230 COFFEE BREAK Sponsor Munzing
300 Effects of Disinfectant Grade Cleaner on Physical Properties of Cell Phone Cases Diane McLendonOtterbox
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MONDAY AFTERNOON (Mardi Gras Ballroom) September 15
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SPE CAD NEWS Summer 2014 page 8 wwwspecadorg
SPE CAD NEWS Summer 2014 page 9 wwwspecadorg
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FREE T-SHIRT FOR THEFIRST 40 RUNNERS
September 16th 7am
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sponsored by
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SPE CAD NEWS Spring 2014 page 10 wwwspecadorg
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Platinum Level Sponsors
Silver Level Sponsors
WE ARE PROUD TO HIGHLIGHT THESE EXCELLENT COMPANIESPlease visit our generous sponsorsrsquo websites by clicking on their logos below
T H E G O L D S T A N D A R D I N P L A S T I C S
Thank you RETECreg 2014 Sponsors
Cappelle
Celanese
LTL Color Compounders Inc
Pigments colour the world
our passion your colors
C R e A t i N g A d d i t i v e v A L u e
LANSCO COLORS
E C K A R TEffect Pigments
High Performance Pigments for Demanding Applications Rotational MoldingJoseph J Fay PhD amp Peter Zillitto
Plastics Technical Center Pigments DivisionCiba Specialty Chemicals Corporation
Technical Article
INTRODUCTIONColorants for polymer applications are typically incorporated into the polymer by one of several common pathways Colorconcentrates which are widely used in industry enable the end user to conveniently meter in the colorant at the prescribedration with virgin or uncolored polymer in the manufacturing process The benefits of concentrate used as compared to thedirect use of powder pigment during final product conversion processes include predispersion of the pigment in a suit-able carrier system elimination of the need to in-house compounding to incorporate the colorant uniformly and improvedhousekeeping etc Furthermore color concentrates are available ina number of product forms including pelleted concen-trates liquid color systems and pastes the latter used especially for PVC For polymer conversion processes in which anextruder or meld mixing devise is employed these colorant preparations can be used very effectively In some marketswhere high levels of functional fillers modifiers or polymer blends are used compounders may manufacture ldquoprecoloredrdquopolymer by direct addition of the colorant to their compounding line In come cases concentrates are used depending uponspecific product and process capabilities
Rotational molding in contrast is a low shear process in which traditional pellet form color concentrates are not suitableColoration of rotomolding resin is commonly obtained by the use of dry color and liquid color which can be added direct-ly to the ground rotomolding resin Alternatively precolored resin in which the pigment is compounded into to the poly-mer and then ground before use finds applications as well More recently micropellet technology has been advanced as an alternative to the aforementioned methods It is similar to precompounded color but the need for grinding the polymerinto the appropriate mesh size is eliminated as the micropellets can be rotomolded without further processing For each ofthese color incorporation methods there are advantages and disadvantages including economic factors (process equipmentand material cost) ease of use housekeeping and overall quality (physical properties and aesthetics) of the resulting part
As a consequence of the myriad applications the palette of pigments for rotational molding appears to be quite extensivesimilar to that which is used in general purpose polyethylene application requirements However due to the specific processconditions involved in preparing the pigment system the temperature profile of the rota-tional molding process and the end use application requirement the gamut of pigments issignificantly reduced
Pigment selection may also be affected by the method by which the pigment is to be deliv-ered Liquid colorant systems work best with pigments that have the potential to be loadedto high weight percentages while maintaining suitable viscosity Pigments used in drycolor require characteristics that impart dispersibility and minimize agglomeration duringboth dry color manufacture and blending with the rotomolding resin
DISPERSIONWhen pigments are manufactured the smallest pigment particles formed are discreet units referred to as primary particlesAs a result of their high surface energy these particles randomly join together to form aggregates and agglomerates thelatter being formed primarily during subsequent filtration a nd drying processes To achieve a speck-free system the pig-ment must be effectively ldquodispersedrdquo so that the individual pigment particles or aggregates are wetted by the polymer anddiscrete pigment particles are not visible to the naked eye Rotomolding pigment systems (liquid color and dry color) needto be prepared in a manner that ensures visible agglomerates are eliminated and that during subsequent mixing with therotomolding resin the colorant system will be easily distributed Furthermore the dispersion of the pigment needs to effec-tively deliver a colorant that will provide a high color strength potential to maximize economic while not adversely affect-ing other properties Figure 1 illustrates the particle size of the typical azoncondensation pigment continued on page 12
SPE CAD NEWS Summer 2014 page 11 wwwspecadorg
The following Technical Article was published in 1998 at The Color And Appearance Conference in September
continued from page 11
Note that the particle size distribution that would beobtained in a polymeric system will be very dependentupon the effectiveness of the final dispersion
HIGH PERFORMANCE PIGMENTSHigh performance pigments HPP can be defined as pig-ments that have either very good to excellent heat or lightstability and more commonly pigments which offer aunique combination of both heat and light stability Theenhanced UV and heat performance attributes of HPPs setthem apart from traditional or classical pigments such asthe lithol rubines (PR 571) lake red C (PR 531) 2B toner(PR 48 types) monoaso yellows such as PY 62 and oth-ers which have only limited heat stability and mostly mar-ginal to poor lightfastness
The major types of high performance pigment chemistriescan be described in a general fashion as indicated in Table 1Some individual pigments within these chemistries mayhave better or worse performance characteristics depend-ing upon the specific product attribute and applicationbeing considered
HEAT STABILITYOrganic pigments are available not only with a wide vari-ety of hues and chroma but also with considerable variationin performance characteristics Rotational molding withits combination of relatively long cycle times high moldsurface temperatures and abundance of oxygen is moredemanding upon the polymer stabilization package andpigmentation in comparison to many other processes As aconsequence many rotomolded product applicationsrequire the use of higher performance pigments to survivethe molding process even though the pigment with regardto final product requirements may be viewed as ldquoover engi-neeredrdquo Classical pigments such as 2B reds (CI PigmentRed 48rsquos) with only limited thermal stability in high tem-perature olefin polymer applications may not be suitablefor even non durable articles as the color stability duringmolding may be insufficient Figure 2 compares the heatstability of a calcium 2B toner with high performance dike-topyrrolo-pyrrole (DPP) and quinacridone (QA)chemistries In masstone applications it is readily apparentthat the 2B toner is quite deficient when compared withthese high heat stability pigments Furthermore as pigment
SPE CAD NEWS Summer 2014 page 12 wwwspecadorg
heat stability is generally related to concentration at lowerconcentrations the 2B toner would become even moreprone to color change In addition to pigment instabilitycolor change during rotational molding may be affected byother factors The stability of the base resin is an importantconsideration The role of the antioxidant package is criti-cal to controlling the initial color and maintaining the phys-ical properties of the rotomolding resin Judicious selectionof a phenolic antioxidant and phosphite processing stabi-lizer package is essential for the base polymer Dependingupon specific circumstances additional antioxidant mightbe added The most effective stabilization is typicallyobtained when the antioxidant is added directly to the resinitself during manufacture or during compounding whenrecolored resin is prepared For specialty applications
where additional antioxidants are needed to attain the req-uisite performance precolored or preformulated resinwhich is then ground provides additional benefit
LIGHT STABILITYMany applications of rotationally molded articles find enduses which require UV durability These UV performanceapplications encompass a broad variety of applications andmarkets residential waste containers childrenrsquos play-ground toys (both for residential and institutional uses)outdoor sporting goods (kayaks and component of otherrecreational vehicles) and oversize containers (industrialcontainers and agricultural tanks) For outdoor applica-tions careful formulation is required to achieve not onlysuitable color match but also a color combination whichwill have the desired weatherability As delineated inFigure 3 Calcium 2B toners have limited light stability inpolyolefin applications and are not recommended for usewhere any significant UV exposure is intended Althoughnot reflected in the colorimetric data the 2B toner samplesurface was significantly marred by chalking and surfacemicrocracking and is visible via low magnification optical
Quinacridone Copper PhthalocyanineDiketopyrrolo-pyrrole (DPP) AnthraquinoneTetrachchloroisoindolinone IndanthroneAzochondensation PeryleneBenzimidozone Isoindoline
Table 1 High Performance Chemistry Families
continued from page 12
SPE CAD NEWS Summer 2014 page 13 wwwspecadorg
microscopy Such microcracks may ultimately result inpremature physical failures of the product Therefore visu-al inspection of samples following accelerated or real-timeexposure testing is imperative to ensure complete perform-ance analysis As a consequence of the limited weather-ability of many pigments performance assessment is need-ed Applications such as point of sale displays and relateditems and indoor applications where incidental UV expo-sure from lighting fixtures or nearby windows is possibleare best formulated with durable HPP pigments Outdoorapplications require the use of HPP pigments at levels thatcan provide sufficient levels of weather resistance
Figure 5 illustratesthe difference inlong-term UV sta-bility that wasobtained when aDPP red (PR254) was com-pared with a pery-lene red (PR178) Perylenepigments areprone to darken-ing when used inconjunction withhindered amine light stabilizers (HALS) whereas no suchnegative interaction has been observed for DPPchemistries
Other high performance pigment classes such as copperphthalocyanine blue pigments may also be suitable foroutdoor applications when properly formulated PB 151and PB 153 are widely used in rotational molding appli-cations as a consequence of their outstanding performanceproperties Figure 6 and tremendous value in use
Inorganic and heavy metal pigments are also widely usedin some rotational molding applications due to their general-ly good dispersibility characteristics and in many cases thecleanliness of shade that may be obtained when using cer-tain cadmium and lead chromate pigments However aswill be discussed in greater detail regulatory pressureshave resulted in heavy metal deselection in several appli-
cation areas including food packaging and many toy appli-cations There applications however have not always beeneasily reformulated The use of HPP products providesalternatives in many color space applications Additionallywith the recent introduction of several new DPP productsPR 264 (Figure 7) PR 272 and PO 71 and PO 73(Figure 8) into the polyolefin and PVC market areas agreater breadth of high performance organics is availablefor formulating In some case differences in the perform-ance of organic versus heavy metal pigments may result inadditional raw material costs Material selection and mod-ification of base stabilization are required in some casesand additional light stabilization packages are needed
continued on page 14
continued on page 15
continued from page 13
SPE CAD NEWS Summer 2014 page 14 wwwspecadorg
especially when formulating polyolefins for outdoor appli-cations to provide comparable alternatives Nonethelessconsumers (materials specifiers manufacturers and theultimate product purchaser) choosing to avoid use of cad-mium and lead pigments wherever reasonably possibleremains a continuously evolving trend
The formulation of rotationally molded articles for outdoorapplications requires the use of both suitable pigments aswell as the assistance of a well-designed light stabilizerpackage The use of tetramethyl piperidine based hinderedamine light stabilizers especially oligomeric and highmolecular weight types in combination with benzotriazolebased UV absorbers are recommended for use in a varietyof applications The total package loading should be tai-lored to meet the specified requirement of the application
DISTORTION EFFECTSDistortion of rotomolded articles can be effected by sever-al different variables Resin choice and the particular mate-rial being used can affect warpage and shrinkageDifferences in cooling of the mold thickness variationsovercuring and several other process parameters have beenfound to be related to warping Since pigments (and thesystems used to deliver them) may alter the flow character-istics of the polymer and also the cure characteristics oper-ation of a given mold with different pigments or colorantsystems with a single cure cycle may result in differencesin dimensional stability The use of controlled heating andcooling as well as good control over the process itself willhelp to ensure consistent part manufacturing as well as agood data and record keeping can be referred to in case oferratic part quality
IMPACT PROPERTIESImpact properties are commonly tested as a means ofassessing the quality and suitability of colorant systems aswell as for assessing the cure characteristics of the polymerand the properties of the final product The ARM(Association of Rotational Molders) impact test is a com-mon test that is used Alternative instrumented testing pro-vides similar test result capabilities with the advantage ofquantitative and qualitative data acquisition
Impact properties of rotomolded products are importantMany toys containers and other applications require assur-ances of product integrity which can often be affected notonly by the process conditions but also by the incorpora-tion of pigments and other additives Since there is very lit-tle shear in the rotomolding process pigments are likely tobe located at the grain boundary between adjacent polymergranules This localization of pigment and ldquoadditivesrdquo can adversely affect physical properties in sev-eral ways Inhibition of polymer chain entanglementsbetween particles due to additives that form an interfacebetween resin particles can result in weak distinct bound-aries with poor mechanical properties Also pigmentagglomerates which are not broken apart or more trou-bling when they are formed during premixing processesdue to excessive mixing may introduce point defectseffecting physical properties Aesthetic properties may alsobe impacted if agglomerates are present in either signifi-cant size or number Pigment loading which is related toboth the effectiveness in which the pigment can be dis-persed as well as the color requirements of the part isanother factor to be considered in assessing the potentialeffect of coloration on physical properties
REGULATORY ASPECTSWith the variety of applications encountered in rotationalmolding well-publicized legislation and public opinionhave compelled many plastics processors and end-users touse alternatives to cadmium and lead based pigmentsCONEG (COalition of NorthEast Governors) related legis-lation prohibits the sale of packaging materials to whichcadmium lead mercury and hexavalent chromium or theircompounds have been intentionally added Reducing theamount of these elements entering the food chain via wastedisposal sources and the extra precautions needed to dis-pose of post industrial wastes are issues to be addressesCertainly both lead and cadmium-based pigments possessa combination of desireable technical properties that makesthem articularly useful coloring materials for polymersLead based pigments furthermore are particularly eco-nomical in use Nonetheless public opinion and legislationhave had and will likely continue to have a significantimpact on their use particularly in consumer goods
SPE CAD NEWS Summer 2014 page 15 wwwspecadorg
The Color and Appearance Division (CAD) is commit-ted to the publishing of at least three newsletters a year(four if there is sufficient material to justify the extraissue) To that end we would like you to think aboutthe financial side of sponsorship of the newsletter Forthe small donation of $300 per year we offer a businesscard sized (2 x 35) mention in our newsletter whichgoes out to the nearly 1500 members of the CAD aswell as other SPE division members These are peopleactive in every aspect of plastic coloring and additivetechnology Larger sized spots are available at a com-mensurate increase in rate
If you are interested in helping to sponsor theSPECAD Newsletter please contactScott Aumann Phone 912 210 0175
Email ScottAumannedmmilliporecom
Your Company Our Division
Dear Members
Just a reminder that you can view past and currentBOARD MINUTES on the SPECAD website
We do not typically publish the minutes in the elec-tronic versions of our newsletter but they are alwaysavailable for our members to view from our websiteThe site is not completely current at this time as weare in the process of giving it a makeover and newlaunch in January
Click here for the link to viewhttpwwwspecadorgindexphpnavid=28
Board Minutes
CONNECT WITH SPE CAD VIASOCIAL MEDIA
Join SPECADrsquos Group On Linked Into network with industry peers participate in groupdiscussions of industry and technical topics findjob opportunities and get the latest division andconference announcements
Group Name SPE Color amp AppearanceDivision Group ID 152108 wwwlinkedincomgroupsgid=152108
continued from page 14
Colorants for polymers that are suitable for food contactuse according to 21 CFR1783297 by the FDA (Food andDrug Administration) NSF (National SanitationFoundation) listing for Potable water contact applicationsand ASTM toy specifications may further place limitationson which pigments may be used
CONCLUSIONSRotational molding presents specific performance require-ment for colorants due to the process dynamics and end-user application needs High performance organic pig-ments in addition to inorganic pigments provide usefulsolutions for designers and manufacturers of rotationallymolded products However as this market continues togrow due to the many unique product features attributed tothe rotomolding process advancements in pigmentationstabilization resin processes and ancillary products shouldalso grow as well Active research and development in sta-bilization technology continues to advance new productsand uniquely designed chemistries (such as lactone andhydroxylamine process stabilizers) into the market placeNew pigment products such as those based upon DPPchemistry also show promise in rotational molding appli-cations Moreover these new products further broadenproduct development potential by providing ever increas-ing performance and greater value in use
ACKNOWLEDGEMENTSThis paper would not have been possible without the col-laborative efforts os Steve Juhasz and Dick Huska of thePlastics Technical Center in Newport DE and JohnLinehan and Urs Stadler of the Additives DivisionLaboratories in Tarrytown NY Appreciation is also givento colleagues of Ciba Specialty Chemicals PigmentsDivision in Basle Switzerland for additional data
DuPonttrade Ti-Purereg titanium dioxide
DuPont Titanium Technologies8004419485
wwwtitaniumdupontcom
The DuPont Oval DuPont trade The miracles of sciencereg and Ti-Purereg
are trademarks or registered trademarks of EI du Pont de Nemours and Company
POLYMERS LIGHT amp SCIENCE
Polymers Light and the Science of TiO2
BTitanium Dioxide BRutile amp Anatase
BHigh Performance Organic PigmentsB DPP Reds HP Yellows
B PVC AdditivesB Lubricants amp Stabilizers
364 Johnny Mercer Blvd B-7 294 - Savannah GA 31410Tel (912)507-8972 - lwaltersagrofertinccom
wwwagrofertinccom
World Leader in EffectPigments
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LANXESS Corporation111 RIDC Park West Drive 1-800-526-9377Pittsburgh PA 15275-1112 wwwlanxesscom
World Leaders in Ultramarine PigmentswUltramarine Blue wUltramarine VioletwChrome Oxide Green wLead Chromate
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Phone 77027788196369 Peachtree Street Fax 7702778809Norcross GA 30071 Toll Free 8008866981wwwnubiolacom
We create chemistry for plastics
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1 800 431-2360Florham Park NJ
venue100 Park A AvenueBASF Corporation
ovide solutions for all ofOur UV light stabilizers antioxidants nucleators
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Color Software ExpertsSince 1986
Quality Control Formulationamp Instrument Profiling
Visit our website and color blogwwwcyberchromeusacom
CyberChrome Inc3642 Main Street tStone Ridge NY 12484
PH 845-687-2671
wwwbasf
Color Concentrates and Single Pigment Dispersionsfor all Thermoplastic Polymers
Corporate Offices400 Old Dublin PikeDoylestown PA 18901(215) 345-6550
Operations amp Research Center2755 Bergey RoadHatfield PA 19440(215) 997-2221wwwpenncolorcom
SPE CAD NEWS Summer 2014 page 16 wwwspecadorg
SPE CAD NEWS Summer 2014 page 17 wwwspecadorg
Special thanks to our our Speakers Sponsors Exhibitors and Participants for your contributions to this yearrsquos CAD RETECreg 2014
Earl Balthazar III CAD RETECreg 2014 Conference Chair Datacolor Inc (817) 719-0224 CAD_RETECtxrrcomMark FreshwaterCAD RETECreg 2014 Vice-ChairLansco Colors(330) 526-8833markpigmentscom
Nathan KarszesCAD RETECreg 2014 Technical Program Co-ChairNubiola Corporation(770) 527-2409nkarszesnubiolacomBrenda MullinsCAD RETECreg2014 Technical Program Co-ChairClariant Corporation(678) 237-2975 brendamullinsclariantcom
SPE CAD NEWS Summer 2014 page 18 wwwspecadorg
LAE
HA WORK AROU
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YOU
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FOR MORE INFORMATION Program Professor
4195592459 866ATTERRA ext 2459jprzybylskiterraedu
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Section VL
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SPE CAD NEWS Summer 2014 page 19 wwwspecadorg
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September 26 2014 ndash 500pm EDT
A SPE ANTECreg
T Because of this the p Please make a note of this significant change Y
We would consider any paper related to the color andor appearance of plastic and the f
The technical track includes more traditional ANTECreg
For more i
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Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom
AFTERNOON SESSION MODERATOR NATHAN KARSZES NUBIOLA130 Panel Discussion
Audience Response Devices will be available to each audience member for responding to poll questions during the panel discussion
300 COFFEE BREAK Sponsor Shepherd
330 Pigments for Sensitive Applications Tom Chirayil BASF
400 Advances in Liquid Color Technology Inga Lesko Clariant BU Masterbatch
430 New Technology Forum (pdf) Moderator Sandra Davis
500 NETWORKING RECEPTION Sponsor Nubiola
700 5K Fun RunWalk for Habitat for Humanity Plastics (Pregister for this event) Sponsor Dominion
730 BREAKFAST(on your own)
MORNING SESSION MODERATOR AUSTIN REID DUPONT TITANIUM TECHNOLOGIES
900 Colorants for Plastics-Emerging Trends and Technologies Krishnamoorthy Sivakumar PolyOne
930 Iron OxidesInorganic Pigments for Plastics George Podolsky Rockwood Pigments
1000 COFFEE BREAK Sponsor DuPont
1030 Blue Undertone Enhancement of Black and Grey PP Injection Molded PP Nathan Karszes Nubiola
1100 Lighter Faster Stronger Additive Solutions for Automotive Plastics Emilie Meddah Clariant BU Additives
1130 Gaining Competitive Advantage through Digital Appearance Technology in the Automotive Interior Supply ChainPhil Ruggiero Datacolor
1200 AWARDS LUNCHEON PRESERVATION HALL (Included with Registration) Sponsor Tronox
AFTERNOON SESSION MODERATOR JIM FIGANIAK
130 Inorganic Pigments From Caveman to the 21st Century Mark Ryan Shepherd Company
200 Measurement Technology to Evaluate Light Protection What You See May Not Be What You ProtectPhil Miedenzu DuPont Titanium Technologies
230 COFFEE BREAK Sponsor Munzing
300 Effects of Disinfectant Grade Cleaner on Physical Properties of Cell Phone Cases Diane McLendonOtterbox
330 Its a Colorful World Developing Technologies to Keep it that Way Joseph Fay BASF
400 Closing Remarks - Earl Balthazar Survey Raffle - MC-Tracy Phillips Uniform Color Grand Prize TBDOther Prizes Archive DVD Free Night at Westin Free Registration at CAD RETECreg 2015 Emergency RadioCAD RETECreg Limited Edition Art
Must be present to win
MONDAY AFTERNOON (Mardi Gras Ballroom) September 15
TUESDAY MORNING September 16
TUESDAY AFTERNOON (Mardi Gras Ballroom) September 16
SPE CAD NEWS Summer 2014 page 8 wwwspecadorg
SPE CAD NEWS Summer 2014 page 9 wwwspecadorg
Lobby of New Orleans Marriott 555 Canal Street
FREE T-SHIRT FOR THEFIRST 40 RUNNERS
September 16th 7am
$20 Registration Fee bullAll proceeds go to Habitat for HumanitySPE CAD will match every $20 donation
dominioncolourcom
sponsored by
Sponsored by
SPE CAD NEWS Spring 2014 page 10 wwwspecadorg
Gold Level Sponsors
Platinum Level Sponsors
Silver Level Sponsors
WE ARE PROUD TO HIGHLIGHT THESE EXCELLENT COMPANIESPlease visit our generous sponsorsrsquo websites by clicking on their logos below
T H E G O L D S T A N D A R D I N P L A S T I C S
Thank you RETECreg 2014 Sponsors
Cappelle
Celanese
LTL Color Compounders Inc
Pigments colour the world
our passion your colors
C R e A t i N g A d d i t i v e v A L u e
LANSCO COLORS
E C K A R TEffect Pigments
High Performance Pigments for Demanding Applications Rotational MoldingJoseph J Fay PhD amp Peter Zillitto
Plastics Technical Center Pigments DivisionCiba Specialty Chemicals Corporation
Technical Article
INTRODUCTIONColorants for polymer applications are typically incorporated into the polymer by one of several common pathways Colorconcentrates which are widely used in industry enable the end user to conveniently meter in the colorant at the prescribedration with virgin or uncolored polymer in the manufacturing process The benefits of concentrate used as compared to thedirect use of powder pigment during final product conversion processes include predispersion of the pigment in a suit-able carrier system elimination of the need to in-house compounding to incorporate the colorant uniformly and improvedhousekeeping etc Furthermore color concentrates are available ina number of product forms including pelleted concen-trates liquid color systems and pastes the latter used especially for PVC For polymer conversion processes in which anextruder or meld mixing devise is employed these colorant preparations can be used very effectively In some marketswhere high levels of functional fillers modifiers or polymer blends are used compounders may manufacture ldquoprecoloredrdquopolymer by direct addition of the colorant to their compounding line In come cases concentrates are used depending uponspecific product and process capabilities
Rotational molding in contrast is a low shear process in which traditional pellet form color concentrates are not suitableColoration of rotomolding resin is commonly obtained by the use of dry color and liquid color which can be added direct-ly to the ground rotomolding resin Alternatively precolored resin in which the pigment is compounded into to the poly-mer and then ground before use finds applications as well More recently micropellet technology has been advanced as an alternative to the aforementioned methods It is similar to precompounded color but the need for grinding the polymerinto the appropriate mesh size is eliminated as the micropellets can be rotomolded without further processing For each ofthese color incorporation methods there are advantages and disadvantages including economic factors (process equipmentand material cost) ease of use housekeeping and overall quality (physical properties and aesthetics) of the resulting part
As a consequence of the myriad applications the palette of pigments for rotational molding appears to be quite extensivesimilar to that which is used in general purpose polyethylene application requirements However due to the specific processconditions involved in preparing the pigment system the temperature profile of the rota-tional molding process and the end use application requirement the gamut of pigments issignificantly reduced
Pigment selection may also be affected by the method by which the pigment is to be deliv-ered Liquid colorant systems work best with pigments that have the potential to be loadedto high weight percentages while maintaining suitable viscosity Pigments used in drycolor require characteristics that impart dispersibility and minimize agglomeration duringboth dry color manufacture and blending with the rotomolding resin
DISPERSIONWhen pigments are manufactured the smallest pigment particles formed are discreet units referred to as primary particlesAs a result of their high surface energy these particles randomly join together to form aggregates and agglomerates thelatter being formed primarily during subsequent filtration a nd drying processes To achieve a speck-free system the pig-ment must be effectively ldquodispersedrdquo so that the individual pigment particles or aggregates are wetted by the polymer anddiscrete pigment particles are not visible to the naked eye Rotomolding pigment systems (liquid color and dry color) needto be prepared in a manner that ensures visible agglomerates are eliminated and that during subsequent mixing with therotomolding resin the colorant system will be easily distributed Furthermore the dispersion of the pigment needs to effec-tively deliver a colorant that will provide a high color strength potential to maximize economic while not adversely affect-ing other properties Figure 1 illustrates the particle size of the typical azoncondensation pigment continued on page 12
SPE CAD NEWS Summer 2014 page 11 wwwspecadorg
The following Technical Article was published in 1998 at The Color And Appearance Conference in September
continued from page 11
Note that the particle size distribution that would beobtained in a polymeric system will be very dependentupon the effectiveness of the final dispersion
HIGH PERFORMANCE PIGMENTSHigh performance pigments HPP can be defined as pig-ments that have either very good to excellent heat or lightstability and more commonly pigments which offer aunique combination of both heat and light stability Theenhanced UV and heat performance attributes of HPPs setthem apart from traditional or classical pigments such asthe lithol rubines (PR 571) lake red C (PR 531) 2B toner(PR 48 types) monoaso yellows such as PY 62 and oth-ers which have only limited heat stability and mostly mar-ginal to poor lightfastness
The major types of high performance pigment chemistriescan be described in a general fashion as indicated in Table 1Some individual pigments within these chemistries mayhave better or worse performance characteristics depend-ing upon the specific product attribute and applicationbeing considered
HEAT STABILITYOrganic pigments are available not only with a wide vari-ety of hues and chroma but also with considerable variationin performance characteristics Rotational molding withits combination of relatively long cycle times high moldsurface temperatures and abundance of oxygen is moredemanding upon the polymer stabilization package andpigmentation in comparison to many other processes As aconsequence many rotomolded product applicationsrequire the use of higher performance pigments to survivethe molding process even though the pigment with regardto final product requirements may be viewed as ldquoover engi-neeredrdquo Classical pigments such as 2B reds (CI PigmentRed 48rsquos) with only limited thermal stability in high tem-perature olefin polymer applications may not be suitablefor even non durable articles as the color stability duringmolding may be insufficient Figure 2 compares the heatstability of a calcium 2B toner with high performance dike-topyrrolo-pyrrole (DPP) and quinacridone (QA)chemistries In masstone applications it is readily apparentthat the 2B toner is quite deficient when compared withthese high heat stability pigments Furthermore as pigment
SPE CAD NEWS Summer 2014 page 12 wwwspecadorg
heat stability is generally related to concentration at lowerconcentrations the 2B toner would become even moreprone to color change In addition to pigment instabilitycolor change during rotational molding may be affected byother factors The stability of the base resin is an importantconsideration The role of the antioxidant package is criti-cal to controlling the initial color and maintaining the phys-ical properties of the rotomolding resin Judicious selectionof a phenolic antioxidant and phosphite processing stabi-lizer package is essential for the base polymer Dependingupon specific circumstances additional antioxidant mightbe added The most effective stabilization is typicallyobtained when the antioxidant is added directly to the resinitself during manufacture or during compounding whenrecolored resin is prepared For specialty applications
where additional antioxidants are needed to attain the req-uisite performance precolored or preformulated resinwhich is then ground provides additional benefit
LIGHT STABILITYMany applications of rotationally molded articles find enduses which require UV durability These UV performanceapplications encompass a broad variety of applications andmarkets residential waste containers childrenrsquos play-ground toys (both for residential and institutional uses)outdoor sporting goods (kayaks and component of otherrecreational vehicles) and oversize containers (industrialcontainers and agricultural tanks) For outdoor applica-tions careful formulation is required to achieve not onlysuitable color match but also a color combination whichwill have the desired weatherability As delineated inFigure 3 Calcium 2B toners have limited light stability inpolyolefin applications and are not recommended for usewhere any significant UV exposure is intended Althoughnot reflected in the colorimetric data the 2B toner samplesurface was significantly marred by chalking and surfacemicrocracking and is visible via low magnification optical
Quinacridone Copper PhthalocyanineDiketopyrrolo-pyrrole (DPP) AnthraquinoneTetrachchloroisoindolinone IndanthroneAzochondensation PeryleneBenzimidozone Isoindoline
Table 1 High Performance Chemistry Families
continued from page 12
SPE CAD NEWS Summer 2014 page 13 wwwspecadorg
microscopy Such microcracks may ultimately result inpremature physical failures of the product Therefore visu-al inspection of samples following accelerated or real-timeexposure testing is imperative to ensure complete perform-ance analysis As a consequence of the limited weather-ability of many pigments performance assessment is need-ed Applications such as point of sale displays and relateditems and indoor applications where incidental UV expo-sure from lighting fixtures or nearby windows is possibleare best formulated with durable HPP pigments Outdoorapplications require the use of HPP pigments at levels thatcan provide sufficient levels of weather resistance
Figure 5 illustratesthe difference inlong-term UV sta-bility that wasobtained when aDPP red (PR254) was com-pared with a pery-lene red (PR178) Perylenepigments areprone to darken-ing when used inconjunction withhindered amine light stabilizers (HALS) whereas no suchnegative interaction has been observed for DPPchemistries
Other high performance pigment classes such as copperphthalocyanine blue pigments may also be suitable foroutdoor applications when properly formulated PB 151and PB 153 are widely used in rotational molding appli-cations as a consequence of their outstanding performanceproperties Figure 6 and tremendous value in use
Inorganic and heavy metal pigments are also widely usedin some rotational molding applications due to their general-ly good dispersibility characteristics and in many cases thecleanliness of shade that may be obtained when using cer-tain cadmium and lead chromate pigments However aswill be discussed in greater detail regulatory pressureshave resulted in heavy metal deselection in several appli-
cation areas including food packaging and many toy appli-cations There applications however have not always beeneasily reformulated The use of HPP products providesalternatives in many color space applications Additionallywith the recent introduction of several new DPP productsPR 264 (Figure 7) PR 272 and PO 71 and PO 73(Figure 8) into the polyolefin and PVC market areas agreater breadth of high performance organics is availablefor formulating In some case differences in the perform-ance of organic versus heavy metal pigments may result inadditional raw material costs Material selection and mod-ification of base stabilization are required in some casesand additional light stabilization packages are needed
continued on page 14
continued on page 15
continued from page 13
SPE CAD NEWS Summer 2014 page 14 wwwspecadorg
especially when formulating polyolefins for outdoor appli-cations to provide comparable alternatives Nonethelessconsumers (materials specifiers manufacturers and theultimate product purchaser) choosing to avoid use of cad-mium and lead pigments wherever reasonably possibleremains a continuously evolving trend
The formulation of rotationally molded articles for outdoorapplications requires the use of both suitable pigments aswell as the assistance of a well-designed light stabilizerpackage The use of tetramethyl piperidine based hinderedamine light stabilizers especially oligomeric and highmolecular weight types in combination with benzotriazolebased UV absorbers are recommended for use in a varietyof applications The total package loading should be tai-lored to meet the specified requirement of the application
DISTORTION EFFECTSDistortion of rotomolded articles can be effected by sever-al different variables Resin choice and the particular mate-rial being used can affect warpage and shrinkageDifferences in cooling of the mold thickness variationsovercuring and several other process parameters have beenfound to be related to warping Since pigments (and thesystems used to deliver them) may alter the flow character-istics of the polymer and also the cure characteristics oper-ation of a given mold with different pigments or colorantsystems with a single cure cycle may result in differencesin dimensional stability The use of controlled heating andcooling as well as good control over the process itself willhelp to ensure consistent part manufacturing as well as agood data and record keeping can be referred to in case oferratic part quality
IMPACT PROPERTIESImpact properties are commonly tested as a means ofassessing the quality and suitability of colorant systems aswell as for assessing the cure characteristics of the polymerand the properties of the final product The ARM(Association of Rotational Molders) impact test is a com-mon test that is used Alternative instrumented testing pro-vides similar test result capabilities with the advantage ofquantitative and qualitative data acquisition
Impact properties of rotomolded products are importantMany toys containers and other applications require assur-ances of product integrity which can often be affected notonly by the process conditions but also by the incorpora-tion of pigments and other additives Since there is very lit-tle shear in the rotomolding process pigments are likely tobe located at the grain boundary between adjacent polymergranules This localization of pigment and ldquoadditivesrdquo can adversely affect physical properties in sev-eral ways Inhibition of polymer chain entanglementsbetween particles due to additives that form an interfacebetween resin particles can result in weak distinct bound-aries with poor mechanical properties Also pigmentagglomerates which are not broken apart or more trou-bling when they are formed during premixing processesdue to excessive mixing may introduce point defectseffecting physical properties Aesthetic properties may alsobe impacted if agglomerates are present in either signifi-cant size or number Pigment loading which is related toboth the effectiveness in which the pigment can be dis-persed as well as the color requirements of the part isanother factor to be considered in assessing the potentialeffect of coloration on physical properties
REGULATORY ASPECTSWith the variety of applications encountered in rotationalmolding well-publicized legislation and public opinionhave compelled many plastics processors and end-users touse alternatives to cadmium and lead based pigmentsCONEG (COalition of NorthEast Governors) related legis-lation prohibits the sale of packaging materials to whichcadmium lead mercury and hexavalent chromium or theircompounds have been intentionally added Reducing theamount of these elements entering the food chain via wastedisposal sources and the extra precautions needed to dis-pose of post industrial wastes are issues to be addressesCertainly both lead and cadmium-based pigments possessa combination of desireable technical properties that makesthem articularly useful coloring materials for polymersLead based pigments furthermore are particularly eco-nomical in use Nonetheless public opinion and legislationhave had and will likely continue to have a significantimpact on their use particularly in consumer goods
SPE CAD NEWS Summer 2014 page 15 wwwspecadorg
The Color and Appearance Division (CAD) is commit-ted to the publishing of at least three newsletters a year(four if there is sufficient material to justify the extraissue) To that end we would like you to think aboutthe financial side of sponsorship of the newsletter Forthe small donation of $300 per year we offer a businesscard sized (2 x 35) mention in our newsletter whichgoes out to the nearly 1500 members of the CAD aswell as other SPE division members These are peopleactive in every aspect of plastic coloring and additivetechnology Larger sized spots are available at a com-mensurate increase in rate
If you are interested in helping to sponsor theSPECAD Newsletter please contactScott Aumann Phone 912 210 0175
Email ScottAumannedmmilliporecom
Your Company Our Division
Dear Members
Just a reminder that you can view past and currentBOARD MINUTES on the SPECAD website
We do not typically publish the minutes in the elec-tronic versions of our newsletter but they are alwaysavailable for our members to view from our websiteThe site is not completely current at this time as weare in the process of giving it a makeover and newlaunch in January
Click here for the link to viewhttpwwwspecadorgindexphpnavid=28
Board Minutes
CONNECT WITH SPE CAD VIASOCIAL MEDIA
Join SPECADrsquos Group On Linked Into network with industry peers participate in groupdiscussions of industry and technical topics findjob opportunities and get the latest division andconference announcements
Group Name SPE Color amp AppearanceDivision Group ID 152108 wwwlinkedincomgroupsgid=152108
continued from page 14
Colorants for polymers that are suitable for food contactuse according to 21 CFR1783297 by the FDA (Food andDrug Administration) NSF (National SanitationFoundation) listing for Potable water contact applicationsand ASTM toy specifications may further place limitationson which pigments may be used
CONCLUSIONSRotational molding presents specific performance require-ment for colorants due to the process dynamics and end-user application needs High performance organic pig-ments in addition to inorganic pigments provide usefulsolutions for designers and manufacturers of rotationallymolded products However as this market continues togrow due to the many unique product features attributed tothe rotomolding process advancements in pigmentationstabilization resin processes and ancillary products shouldalso grow as well Active research and development in sta-bilization technology continues to advance new productsand uniquely designed chemistries (such as lactone andhydroxylamine process stabilizers) into the market placeNew pigment products such as those based upon DPPchemistry also show promise in rotational molding appli-cations Moreover these new products further broadenproduct development potential by providing ever increas-ing performance and greater value in use
ACKNOWLEDGEMENTSThis paper would not have been possible without the col-laborative efforts os Steve Juhasz and Dick Huska of thePlastics Technical Center in Newport DE and JohnLinehan and Urs Stadler of the Additives DivisionLaboratories in Tarrytown NY Appreciation is also givento colleagues of Ciba Specialty Chemicals PigmentsDivision in Basle Switzerland for additional data
DuPonttrade Ti-Purereg titanium dioxide
DuPont Titanium Technologies8004419485
wwwtitaniumdupontcom
The DuPont Oval DuPont trade The miracles of sciencereg and Ti-Purereg
are trademarks or registered trademarks of EI du Pont de Nemours and Company
POLYMERS LIGHT amp SCIENCE
Polymers Light and the Science of TiO2
BTitanium Dioxide BRutile amp Anatase
BHigh Performance Organic PigmentsB DPP Reds HP Yellows
B PVC AdditivesB Lubricants amp Stabilizers
364 Johnny Mercer Blvd B-7 294 - Savannah GA 31410Tel (912)507-8972 - lwaltersagrofertinccom
wwwagrofertinccom
World Leader in EffectPigments
One International PlazaSuite 300Philadelphia PA 19113(888) 367-3275
wwwemdchemicalscom
A Complete Line of DyestuffsInorganic Pigments and
Organic Pigments forPlastics amp Fibers
LANXESS Corporation111 RIDC Park West Drive 1-800-526-9377Pittsburgh PA 15275-1112 wwwlanxesscom
World Leaders in Ultramarine PigmentswUltramarine Blue wUltramarine VioletwChrome Oxide Green wLead Chromate
wZinc Ferrite wIron Oxide
Phone 77027788196369 Peachtree Street Fax 7702778809Norcross GA 30071 Toll Free 8008866981wwwnubiolacom
We create chemistry for plastics
f
eate chemistry for plastics
basfcomplastic-additiveswww
your plastic applicationsovide solutions for all ofand other additives pr
Our UV light stabilizers antioxidants nucleatorsfect and functional pigments efneeds with color r ef
BASF helps meet your style and functionality
e crWWe cr
eate chemistry for plastics
1 800 431-2360Florham Park NJ
venue100 Park A AvenueBASF Corporation
ovide solutions for all ofOur UV light stabilizers antioxidants nucleators
fect and functional pigmentsBASF helps meet your style and functionality
Color Software ExpertsSince 1986
Quality Control Formulationamp Instrument Profiling
Visit our website and color blogwwwcyberchromeusacom
CyberChrome Inc3642 Main Street tStone Ridge NY 12484
PH 845-687-2671
wwwbasf
Color Concentrates and Single Pigment Dispersionsfor all Thermoplastic Polymers
Corporate Offices400 Old Dublin PikeDoylestown PA 18901(215) 345-6550
Operations amp Research Center2755 Bergey RoadHatfield PA 19440(215) 997-2221wwwpenncolorcom
SPE CAD NEWS Summer 2014 page 16 wwwspecadorg
SPE CAD NEWS Summer 2014 page 17 wwwspecadorg
Special thanks to our our Speakers Sponsors Exhibitors and Participants for your contributions to this yearrsquos CAD RETECreg 2014
Earl Balthazar III CAD RETECreg 2014 Conference Chair Datacolor Inc (817) 719-0224 CAD_RETECtxrrcomMark FreshwaterCAD RETECreg 2014 Vice-ChairLansco Colors(330) 526-8833markpigmentscom
Nathan KarszesCAD RETECreg 2014 Technical Program Co-ChairNubiola Corporation(770) 527-2409nkarszesnubiolacomBrenda MullinsCAD RETECreg2014 Technical Program Co-ChairClariant Corporation(678) 237-2975 brendamullinsclariantcom
SPE CAD NEWS Summer 2014 page 18 wwwspecadorg
LAE
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FOR MORE INFORMATION Program Professor
4195592459 866ATTERRA ext 2459jprzybylskiterraedu
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SPE CAD NEWS Summer 2014 page 19 wwwspecadorg
M
September 26 2014 ndash 500pm EDT
A SPE ANTECreg
T Because of this the p Please make a note of this significant change Y
We would consider any paper related to the color andor appearance of plastic and the f
The technical track includes more traditional ANTECreg
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Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom
SPE CAD NEWS Summer 2014 page 9 wwwspecadorg
Lobby of New Orleans Marriott 555 Canal Street
FREE T-SHIRT FOR THEFIRST 40 RUNNERS
September 16th 7am
$20 Registration Fee bullAll proceeds go to Habitat for HumanitySPE CAD will match every $20 donation
dominioncolourcom
sponsored by
Sponsored by
SPE CAD NEWS Spring 2014 page 10 wwwspecadorg
Gold Level Sponsors
Platinum Level Sponsors
Silver Level Sponsors
WE ARE PROUD TO HIGHLIGHT THESE EXCELLENT COMPANIESPlease visit our generous sponsorsrsquo websites by clicking on their logos below
T H E G O L D S T A N D A R D I N P L A S T I C S
Thank you RETECreg 2014 Sponsors
Cappelle
Celanese
LTL Color Compounders Inc
Pigments colour the world
our passion your colors
C R e A t i N g A d d i t i v e v A L u e
LANSCO COLORS
E C K A R TEffect Pigments
High Performance Pigments for Demanding Applications Rotational MoldingJoseph J Fay PhD amp Peter Zillitto
Plastics Technical Center Pigments DivisionCiba Specialty Chemicals Corporation
Technical Article
INTRODUCTIONColorants for polymer applications are typically incorporated into the polymer by one of several common pathways Colorconcentrates which are widely used in industry enable the end user to conveniently meter in the colorant at the prescribedration with virgin or uncolored polymer in the manufacturing process The benefits of concentrate used as compared to thedirect use of powder pigment during final product conversion processes include predispersion of the pigment in a suit-able carrier system elimination of the need to in-house compounding to incorporate the colorant uniformly and improvedhousekeeping etc Furthermore color concentrates are available ina number of product forms including pelleted concen-trates liquid color systems and pastes the latter used especially for PVC For polymer conversion processes in which anextruder or meld mixing devise is employed these colorant preparations can be used very effectively In some marketswhere high levels of functional fillers modifiers or polymer blends are used compounders may manufacture ldquoprecoloredrdquopolymer by direct addition of the colorant to their compounding line In come cases concentrates are used depending uponspecific product and process capabilities
Rotational molding in contrast is a low shear process in which traditional pellet form color concentrates are not suitableColoration of rotomolding resin is commonly obtained by the use of dry color and liquid color which can be added direct-ly to the ground rotomolding resin Alternatively precolored resin in which the pigment is compounded into to the poly-mer and then ground before use finds applications as well More recently micropellet technology has been advanced as an alternative to the aforementioned methods It is similar to precompounded color but the need for grinding the polymerinto the appropriate mesh size is eliminated as the micropellets can be rotomolded without further processing For each ofthese color incorporation methods there are advantages and disadvantages including economic factors (process equipmentand material cost) ease of use housekeeping and overall quality (physical properties and aesthetics) of the resulting part
As a consequence of the myriad applications the palette of pigments for rotational molding appears to be quite extensivesimilar to that which is used in general purpose polyethylene application requirements However due to the specific processconditions involved in preparing the pigment system the temperature profile of the rota-tional molding process and the end use application requirement the gamut of pigments issignificantly reduced
Pigment selection may also be affected by the method by which the pigment is to be deliv-ered Liquid colorant systems work best with pigments that have the potential to be loadedto high weight percentages while maintaining suitable viscosity Pigments used in drycolor require characteristics that impart dispersibility and minimize agglomeration duringboth dry color manufacture and blending with the rotomolding resin
DISPERSIONWhen pigments are manufactured the smallest pigment particles formed are discreet units referred to as primary particlesAs a result of their high surface energy these particles randomly join together to form aggregates and agglomerates thelatter being formed primarily during subsequent filtration a nd drying processes To achieve a speck-free system the pig-ment must be effectively ldquodispersedrdquo so that the individual pigment particles or aggregates are wetted by the polymer anddiscrete pigment particles are not visible to the naked eye Rotomolding pigment systems (liquid color and dry color) needto be prepared in a manner that ensures visible agglomerates are eliminated and that during subsequent mixing with therotomolding resin the colorant system will be easily distributed Furthermore the dispersion of the pigment needs to effec-tively deliver a colorant that will provide a high color strength potential to maximize economic while not adversely affect-ing other properties Figure 1 illustrates the particle size of the typical azoncondensation pigment continued on page 12
SPE CAD NEWS Summer 2014 page 11 wwwspecadorg
The following Technical Article was published in 1998 at The Color And Appearance Conference in September
continued from page 11
Note that the particle size distribution that would beobtained in a polymeric system will be very dependentupon the effectiveness of the final dispersion
HIGH PERFORMANCE PIGMENTSHigh performance pigments HPP can be defined as pig-ments that have either very good to excellent heat or lightstability and more commonly pigments which offer aunique combination of both heat and light stability Theenhanced UV and heat performance attributes of HPPs setthem apart from traditional or classical pigments such asthe lithol rubines (PR 571) lake red C (PR 531) 2B toner(PR 48 types) monoaso yellows such as PY 62 and oth-ers which have only limited heat stability and mostly mar-ginal to poor lightfastness
The major types of high performance pigment chemistriescan be described in a general fashion as indicated in Table 1Some individual pigments within these chemistries mayhave better or worse performance characteristics depend-ing upon the specific product attribute and applicationbeing considered
HEAT STABILITYOrganic pigments are available not only with a wide vari-ety of hues and chroma but also with considerable variationin performance characteristics Rotational molding withits combination of relatively long cycle times high moldsurface temperatures and abundance of oxygen is moredemanding upon the polymer stabilization package andpigmentation in comparison to many other processes As aconsequence many rotomolded product applicationsrequire the use of higher performance pigments to survivethe molding process even though the pigment with regardto final product requirements may be viewed as ldquoover engi-neeredrdquo Classical pigments such as 2B reds (CI PigmentRed 48rsquos) with only limited thermal stability in high tem-perature olefin polymer applications may not be suitablefor even non durable articles as the color stability duringmolding may be insufficient Figure 2 compares the heatstability of a calcium 2B toner with high performance dike-topyrrolo-pyrrole (DPP) and quinacridone (QA)chemistries In masstone applications it is readily apparentthat the 2B toner is quite deficient when compared withthese high heat stability pigments Furthermore as pigment
SPE CAD NEWS Summer 2014 page 12 wwwspecadorg
heat stability is generally related to concentration at lowerconcentrations the 2B toner would become even moreprone to color change In addition to pigment instabilitycolor change during rotational molding may be affected byother factors The stability of the base resin is an importantconsideration The role of the antioxidant package is criti-cal to controlling the initial color and maintaining the phys-ical properties of the rotomolding resin Judicious selectionof a phenolic antioxidant and phosphite processing stabi-lizer package is essential for the base polymer Dependingupon specific circumstances additional antioxidant mightbe added The most effective stabilization is typicallyobtained when the antioxidant is added directly to the resinitself during manufacture or during compounding whenrecolored resin is prepared For specialty applications
where additional antioxidants are needed to attain the req-uisite performance precolored or preformulated resinwhich is then ground provides additional benefit
LIGHT STABILITYMany applications of rotationally molded articles find enduses which require UV durability These UV performanceapplications encompass a broad variety of applications andmarkets residential waste containers childrenrsquos play-ground toys (both for residential and institutional uses)outdoor sporting goods (kayaks and component of otherrecreational vehicles) and oversize containers (industrialcontainers and agricultural tanks) For outdoor applica-tions careful formulation is required to achieve not onlysuitable color match but also a color combination whichwill have the desired weatherability As delineated inFigure 3 Calcium 2B toners have limited light stability inpolyolefin applications and are not recommended for usewhere any significant UV exposure is intended Althoughnot reflected in the colorimetric data the 2B toner samplesurface was significantly marred by chalking and surfacemicrocracking and is visible via low magnification optical
Quinacridone Copper PhthalocyanineDiketopyrrolo-pyrrole (DPP) AnthraquinoneTetrachchloroisoindolinone IndanthroneAzochondensation PeryleneBenzimidozone Isoindoline
Table 1 High Performance Chemistry Families
continued from page 12
SPE CAD NEWS Summer 2014 page 13 wwwspecadorg
microscopy Such microcracks may ultimately result inpremature physical failures of the product Therefore visu-al inspection of samples following accelerated or real-timeexposure testing is imperative to ensure complete perform-ance analysis As a consequence of the limited weather-ability of many pigments performance assessment is need-ed Applications such as point of sale displays and relateditems and indoor applications where incidental UV expo-sure from lighting fixtures or nearby windows is possibleare best formulated with durable HPP pigments Outdoorapplications require the use of HPP pigments at levels thatcan provide sufficient levels of weather resistance
Figure 5 illustratesthe difference inlong-term UV sta-bility that wasobtained when aDPP red (PR254) was com-pared with a pery-lene red (PR178) Perylenepigments areprone to darken-ing when used inconjunction withhindered amine light stabilizers (HALS) whereas no suchnegative interaction has been observed for DPPchemistries
Other high performance pigment classes such as copperphthalocyanine blue pigments may also be suitable foroutdoor applications when properly formulated PB 151and PB 153 are widely used in rotational molding appli-cations as a consequence of their outstanding performanceproperties Figure 6 and tremendous value in use
Inorganic and heavy metal pigments are also widely usedin some rotational molding applications due to their general-ly good dispersibility characteristics and in many cases thecleanliness of shade that may be obtained when using cer-tain cadmium and lead chromate pigments However aswill be discussed in greater detail regulatory pressureshave resulted in heavy metal deselection in several appli-
cation areas including food packaging and many toy appli-cations There applications however have not always beeneasily reformulated The use of HPP products providesalternatives in many color space applications Additionallywith the recent introduction of several new DPP productsPR 264 (Figure 7) PR 272 and PO 71 and PO 73(Figure 8) into the polyolefin and PVC market areas agreater breadth of high performance organics is availablefor formulating In some case differences in the perform-ance of organic versus heavy metal pigments may result inadditional raw material costs Material selection and mod-ification of base stabilization are required in some casesand additional light stabilization packages are needed
continued on page 14
continued on page 15
continued from page 13
SPE CAD NEWS Summer 2014 page 14 wwwspecadorg
especially when formulating polyolefins for outdoor appli-cations to provide comparable alternatives Nonethelessconsumers (materials specifiers manufacturers and theultimate product purchaser) choosing to avoid use of cad-mium and lead pigments wherever reasonably possibleremains a continuously evolving trend
The formulation of rotationally molded articles for outdoorapplications requires the use of both suitable pigments aswell as the assistance of a well-designed light stabilizerpackage The use of tetramethyl piperidine based hinderedamine light stabilizers especially oligomeric and highmolecular weight types in combination with benzotriazolebased UV absorbers are recommended for use in a varietyof applications The total package loading should be tai-lored to meet the specified requirement of the application
DISTORTION EFFECTSDistortion of rotomolded articles can be effected by sever-al different variables Resin choice and the particular mate-rial being used can affect warpage and shrinkageDifferences in cooling of the mold thickness variationsovercuring and several other process parameters have beenfound to be related to warping Since pigments (and thesystems used to deliver them) may alter the flow character-istics of the polymer and also the cure characteristics oper-ation of a given mold with different pigments or colorantsystems with a single cure cycle may result in differencesin dimensional stability The use of controlled heating andcooling as well as good control over the process itself willhelp to ensure consistent part manufacturing as well as agood data and record keeping can be referred to in case oferratic part quality
IMPACT PROPERTIESImpact properties are commonly tested as a means ofassessing the quality and suitability of colorant systems aswell as for assessing the cure characteristics of the polymerand the properties of the final product The ARM(Association of Rotational Molders) impact test is a com-mon test that is used Alternative instrumented testing pro-vides similar test result capabilities with the advantage ofquantitative and qualitative data acquisition
Impact properties of rotomolded products are importantMany toys containers and other applications require assur-ances of product integrity which can often be affected notonly by the process conditions but also by the incorpora-tion of pigments and other additives Since there is very lit-tle shear in the rotomolding process pigments are likely tobe located at the grain boundary between adjacent polymergranules This localization of pigment and ldquoadditivesrdquo can adversely affect physical properties in sev-eral ways Inhibition of polymer chain entanglementsbetween particles due to additives that form an interfacebetween resin particles can result in weak distinct bound-aries with poor mechanical properties Also pigmentagglomerates which are not broken apart or more trou-bling when they are formed during premixing processesdue to excessive mixing may introduce point defectseffecting physical properties Aesthetic properties may alsobe impacted if agglomerates are present in either signifi-cant size or number Pigment loading which is related toboth the effectiveness in which the pigment can be dis-persed as well as the color requirements of the part isanother factor to be considered in assessing the potentialeffect of coloration on physical properties
REGULATORY ASPECTSWith the variety of applications encountered in rotationalmolding well-publicized legislation and public opinionhave compelled many plastics processors and end-users touse alternatives to cadmium and lead based pigmentsCONEG (COalition of NorthEast Governors) related legis-lation prohibits the sale of packaging materials to whichcadmium lead mercury and hexavalent chromium or theircompounds have been intentionally added Reducing theamount of these elements entering the food chain via wastedisposal sources and the extra precautions needed to dis-pose of post industrial wastes are issues to be addressesCertainly both lead and cadmium-based pigments possessa combination of desireable technical properties that makesthem articularly useful coloring materials for polymersLead based pigments furthermore are particularly eco-nomical in use Nonetheless public opinion and legislationhave had and will likely continue to have a significantimpact on their use particularly in consumer goods
SPE CAD NEWS Summer 2014 page 15 wwwspecadorg
The Color and Appearance Division (CAD) is commit-ted to the publishing of at least three newsletters a year(four if there is sufficient material to justify the extraissue) To that end we would like you to think aboutthe financial side of sponsorship of the newsletter Forthe small donation of $300 per year we offer a businesscard sized (2 x 35) mention in our newsletter whichgoes out to the nearly 1500 members of the CAD aswell as other SPE division members These are peopleactive in every aspect of plastic coloring and additivetechnology Larger sized spots are available at a com-mensurate increase in rate
If you are interested in helping to sponsor theSPECAD Newsletter please contactScott Aumann Phone 912 210 0175
Email ScottAumannedmmilliporecom
Your Company Our Division
Dear Members
Just a reminder that you can view past and currentBOARD MINUTES on the SPECAD website
We do not typically publish the minutes in the elec-tronic versions of our newsletter but they are alwaysavailable for our members to view from our websiteThe site is not completely current at this time as weare in the process of giving it a makeover and newlaunch in January
Click here for the link to viewhttpwwwspecadorgindexphpnavid=28
Board Minutes
CONNECT WITH SPE CAD VIASOCIAL MEDIA
Join SPECADrsquos Group On Linked Into network with industry peers participate in groupdiscussions of industry and technical topics findjob opportunities and get the latest division andconference announcements
Group Name SPE Color amp AppearanceDivision Group ID 152108 wwwlinkedincomgroupsgid=152108
continued from page 14
Colorants for polymers that are suitable for food contactuse according to 21 CFR1783297 by the FDA (Food andDrug Administration) NSF (National SanitationFoundation) listing for Potable water contact applicationsand ASTM toy specifications may further place limitationson which pigments may be used
CONCLUSIONSRotational molding presents specific performance require-ment for colorants due to the process dynamics and end-user application needs High performance organic pig-ments in addition to inorganic pigments provide usefulsolutions for designers and manufacturers of rotationallymolded products However as this market continues togrow due to the many unique product features attributed tothe rotomolding process advancements in pigmentationstabilization resin processes and ancillary products shouldalso grow as well Active research and development in sta-bilization technology continues to advance new productsand uniquely designed chemistries (such as lactone andhydroxylamine process stabilizers) into the market placeNew pigment products such as those based upon DPPchemistry also show promise in rotational molding appli-cations Moreover these new products further broadenproduct development potential by providing ever increas-ing performance and greater value in use
ACKNOWLEDGEMENTSThis paper would not have been possible without the col-laborative efforts os Steve Juhasz and Dick Huska of thePlastics Technical Center in Newport DE and JohnLinehan and Urs Stadler of the Additives DivisionLaboratories in Tarrytown NY Appreciation is also givento colleagues of Ciba Specialty Chemicals PigmentsDivision in Basle Switzerland for additional data
DuPonttrade Ti-Purereg titanium dioxide
DuPont Titanium Technologies8004419485
wwwtitaniumdupontcom
The DuPont Oval DuPont trade The miracles of sciencereg and Ti-Purereg
are trademarks or registered trademarks of EI du Pont de Nemours and Company
POLYMERS LIGHT amp SCIENCE
Polymers Light and the Science of TiO2
BTitanium Dioxide BRutile amp Anatase
BHigh Performance Organic PigmentsB DPP Reds HP Yellows
B PVC AdditivesB Lubricants amp Stabilizers
364 Johnny Mercer Blvd B-7 294 - Savannah GA 31410Tel (912)507-8972 - lwaltersagrofertinccom
wwwagrofertinccom
World Leader in EffectPigments
One International PlazaSuite 300Philadelphia PA 19113(888) 367-3275
wwwemdchemicalscom
A Complete Line of DyestuffsInorganic Pigments and
Organic Pigments forPlastics amp Fibers
LANXESS Corporation111 RIDC Park West Drive 1-800-526-9377Pittsburgh PA 15275-1112 wwwlanxesscom
World Leaders in Ultramarine PigmentswUltramarine Blue wUltramarine VioletwChrome Oxide Green wLead Chromate
wZinc Ferrite wIron Oxide
Phone 77027788196369 Peachtree Street Fax 7702778809Norcross GA 30071 Toll Free 8008866981wwwnubiolacom
We create chemistry for plastics
f
eate chemistry for plastics
basfcomplastic-additiveswww
your plastic applicationsovide solutions for all ofand other additives pr
Our UV light stabilizers antioxidants nucleatorsfect and functional pigments efneeds with color r ef
BASF helps meet your style and functionality
e crWWe cr
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1 800 431-2360Florham Park NJ
venue100 Park A AvenueBASF Corporation
ovide solutions for all ofOur UV light stabilizers antioxidants nucleators
fect and functional pigmentsBASF helps meet your style and functionality
Color Software ExpertsSince 1986
Quality Control Formulationamp Instrument Profiling
Visit our website and color blogwwwcyberchromeusacom
CyberChrome Inc3642 Main Street tStone Ridge NY 12484
PH 845-687-2671
wwwbasf
Color Concentrates and Single Pigment Dispersionsfor all Thermoplastic Polymers
Corporate Offices400 Old Dublin PikeDoylestown PA 18901(215) 345-6550
Operations amp Research Center2755 Bergey RoadHatfield PA 19440(215) 997-2221wwwpenncolorcom
SPE CAD NEWS Summer 2014 page 16 wwwspecadorg
SPE CAD NEWS Summer 2014 page 17 wwwspecadorg
Special thanks to our our Speakers Sponsors Exhibitors and Participants for your contributions to this yearrsquos CAD RETECreg 2014
Earl Balthazar III CAD RETECreg 2014 Conference Chair Datacolor Inc (817) 719-0224 CAD_RETECtxrrcomMark FreshwaterCAD RETECreg 2014 Vice-ChairLansco Colors(330) 526-8833markpigmentscom
Nathan KarszesCAD RETECreg 2014 Technical Program Co-ChairNubiola Corporation(770) 527-2409nkarszesnubiolacomBrenda MullinsCAD RETECreg2014 Technical Program Co-ChairClariant Corporation(678) 237-2975 brendamullinsclariantcom
SPE CAD NEWS Summer 2014 page 18 wwwspecadorg
LAE
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FOR MORE INFORMATION Program Professor
4195592459 866ATTERRA ext 2459jprzybylskiterraedu
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SPE CAD NEWS Summer 2014 page 19 wwwspecadorg
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September 26 2014 ndash 500pm EDT
A SPE ANTECreg
T Because of this the p Please make a note of this significant change Y
We would consider any paper related to the color andor appearance of plastic and the f
The technical track includes more traditional ANTECreg
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Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom
SPE CAD NEWS Spring 2014 page 10 wwwspecadorg
Gold Level Sponsors
Platinum Level Sponsors
Silver Level Sponsors
WE ARE PROUD TO HIGHLIGHT THESE EXCELLENT COMPANIESPlease visit our generous sponsorsrsquo websites by clicking on their logos below
T H E G O L D S T A N D A R D I N P L A S T I C S
Thank you RETECreg 2014 Sponsors
Cappelle
Celanese
LTL Color Compounders Inc
Pigments colour the world
our passion your colors
C R e A t i N g A d d i t i v e v A L u e
LANSCO COLORS
E C K A R TEffect Pigments
High Performance Pigments for Demanding Applications Rotational MoldingJoseph J Fay PhD amp Peter Zillitto
Plastics Technical Center Pigments DivisionCiba Specialty Chemicals Corporation
Technical Article
INTRODUCTIONColorants for polymer applications are typically incorporated into the polymer by one of several common pathways Colorconcentrates which are widely used in industry enable the end user to conveniently meter in the colorant at the prescribedration with virgin or uncolored polymer in the manufacturing process The benefits of concentrate used as compared to thedirect use of powder pigment during final product conversion processes include predispersion of the pigment in a suit-able carrier system elimination of the need to in-house compounding to incorporate the colorant uniformly and improvedhousekeeping etc Furthermore color concentrates are available ina number of product forms including pelleted concen-trates liquid color systems and pastes the latter used especially for PVC For polymer conversion processes in which anextruder or meld mixing devise is employed these colorant preparations can be used very effectively In some marketswhere high levels of functional fillers modifiers or polymer blends are used compounders may manufacture ldquoprecoloredrdquopolymer by direct addition of the colorant to their compounding line In come cases concentrates are used depending uponspecific product and process capabilities
Rotational molding in contrast is a low shear process in which traditional pellet form color concentrates are not suitableColoration of rotomolding resin is commonly obtained by the use of dry color and liquid color which can be added direct-ly to the ground rotomolding resin Alternatively precolored resin in which the pigment is compounded into to the poly-mer and then ground before use finds applications as well More recently micropellet technology has been advanced as an alternative to the aforementioned methods It is similar to precompounded color but the need for grinding the polymerinto the appropriate mesh size is eliminated as the micropellets can be rotomolded without further processing For each ofthese color incorporation methods there are advantages and disadvantages including economic factors (process equipmentand material cost) ease of use housekeeping and overall quality (physical properties and aesthetics) of the resulting part
As a consequence of the myriad applications the palette of pigments for rotational molding appears to be quite extensivesimilar to that which is used in general purpose polyethylene application requirements However due to the specific processconditions involved in preparing the pigment system the temperature profile of the rota-tional molding process and the end use application requirement the gamut of pigments issignificantly reduced
Pigment selection may also be affected by the method by which the pigment is to be deliv-ered Liquid colorant systems work best with pigments that have the potential to be loadedto high weight percentages while maintaining suitable viscosity Pigments used in drycolor require characteristics that impart dispersibility and minimize agglomeration duringboth dry color manufacture and blending with the rotomolding resin
DISPERSIONWhen pigments are manufactured the smallest pigment particles formed are discreet units referred to as primary particlesAs a result of their high surface energy these particles randomly join together to form aggregates and agglomerates thelatter being formed primarily during subsequent filtration a nd drying processes To achieve a speck-free system the pig-ment must be effectively ldquodispersedrdquo so that the individual pigment particles or aggregates are wetted by the polymer anddiscrete pigment particles are not visible to the naked eye Rotomolding pigment systems (liquid color and dry color) needto be prepared in a manner that ensures visible agglomerates are eliminated and that during subsequent mixing with therotomolding resin the colorant system will be easily distributed Furthermore the dispersion of the pigment needs to effec-tively deliver a colorant that will provide a high color strength potential to maximize economic while not adversely affect-ing other properties Figure 1 illustrates the particle size of the typical azoncondensation pigment continued on page 12
SPE CAD NEWS Summer 2014 page 11 wwwspecadorg
The following Technical Article was published in 1998 at The Color And Appearance Conference in September
continued from page 11
Note that the particle size distribution that would beobtained in a polymeric system will be very dependentupon the effectiveness of the final dispersion
HIGH PERFORMANCE PIGMENTSHigh performance pigments HPP can be defined as pig-ments that have either very good to excellent heat or lightstability and more commonly pigments which offer aunique combination of both heat and light stability Theenhanced UV and heat performance attributes of HPPs setthem apart from traditional or classical pigments such asthe lithol rubines (PR 571) lake red C (PR 531) 2B toner(PR 48 types) monoaso yellows such as PY 62 and oth-ers which have only limited heat stability and mostly mar-ginal to poor lightfastness
The major types of high performance pigment chemistriescan be described in a general fashion as indicated in Table 1Some individual pigments within these chemistries mayhave better or worse performance characteristics depend-ing upon the specific product attribute and applicationbeing considered
HEAT STABILITYOrganic pigments are available not only with a wide vari-ety of hues and chroma but also with considerable variationin performance characteristics Rotational molding withits combination of relatively long cycle times high moldsurface temperatures and abundance of oxygen is moredemanding upon the polymer stabilization package andpigmentation in comparison to many other processes As aconsequence many rotomolded product applicationsrequire the use of higher performance pigments to survivethe molding process even though the pigment with regardto final product requirements may be viewed as ldquoover engi-neeredrdquo Classical pigments such as 2B reds (CI PigmentRed 48rsquos) with only limited thermal stability in high tem-perature olefin polymer applications may not be suitablefor even non durable articles as the color stability duringmolding may be insufficient Figure 2 compares the heatstability of a calcium 2B toner with high performance dike-topyrrolo-pyrrole (DPP) and quinacridone (QA)chemistries In masstone applications it is readily apparentthat the 2B toner is quite deficient when compared withthese high heat stability pigments Furthermore as pigment
SPE CAD NEWS Summer 2014 page 12 wwwspecadorg
heat stability is generally related to concentration at lowerconcentrations the 2B toner would become even moreprone to color change In addition to pigment instabilitycolor change during rotational molding may be affected byother factors The stability of the base resin is an importantconsideration The role of the antioxidant package is criti-cal to controlling the initial color and maintaining the phys-ical properties of the rotomolding resin Judicious selectionof a phenolic antioxidant and phosphite processing stabi-lizer package is essential for the base polymer Dependingupon specific circumstances additional antioxidant mightbe added The most effective stabilization is typicallyobtained when the antioxidant is added directly to the resinitself during manufacture or during compounding whenrecolored resin is prepared For specialty applications
where additional antioxidants are needed to attain the req-uisite performance precolored or preformulated resinwhich is then ground provides additional benefit
LIGHT STABILITYMany applications of rotationally molded articles find enduses which require UV durability These UV performanceapplications encompass a broad variety of applications andmarkets residential waste containers childrenrsquos play-ground toys (both for residential and institutional uses)outdoor sporting goods (kayaks and component of otherrecreational vehicles) and oversize containers (industrialcontainers and agricultural tanks) For outdoor applica-tions careful formulation is required to achieve not onlysuitable color match but also a color combination whichwill have the desired weatherability As delineated inFigure 3 Calcium 2B toners have limited light stability inpolyolefin applications and are not recommended for usewhere any significant UV exposure is intended Althoughnot reflected in the colorimetric data the 2B toner samplesurface was significantly marred by chalking and surfacemicrocracking and is visible via low magnification optical
Quinacridone Copper PhthalocyanineDiketopyrrolo-pyrrole (DPP) AnthraquinoneTetrachchloroisoindolinone IndanthroneAzochondensation PeryleneBenzimidozone Isoindoline
Table 1 High Performance Chemistry Families
continued from page 12
SPE CAD NEWS Summer 2014 page 13 wwwspecadorg
microscopy Such microcracks may ultimately result inpremature physical failures of the product Therefore visu-al inspection of samples following accelerated or real-timeexposure testing is imperative to ensure complete perform-ance analysis As a consequence of the limited weather-ability of many pigments performance assessment is need-ed Applications such as point of sale displays and relateditems and indoor applications where incidental UV expo-sure from lighting fixtures or nearby windows is possibleare best formulated with durable HPP pigments Outdoorapplications require the use of HPP pigments at levels thatcan provide sufficient levels of weather resistance
Figure 5 illustratesthe difference inlong-term UV sta-bility that wasobtained when aDPP red (PR254) was com-pared with a pery-lene red (PR178) Perylenepigments areprone to darken-ing when used inconjunction withhindered amine light stabilizers (HALS) whereas no suchnegative interaction has been observed for DPPchemistries
Other high performance pigment classes such as copperphthalocyanine blue pigments may also be suitable foroutdoor applications when properly formulated PB 151and PB 153 are widely used in rotational molding appli-cations as a consequence of their outstanding performanceproperties Figure 6 and tremendous value in use
Inorganic and heavy metal pigments are also widely usedin some rotational molding applications due to their general-ly good dispersibility characteristics and in many cases thecleanliness of shade that may be obtained when using cer-tain cadmium and lead chromate pigments However aswill be discussed in greater detail regulatory pressureshave resulted in heavy metal deselection in several appli-
cation areas including food packaging and many toy appli-cations There applications however have not always beeneasily reformulated The use of HPP products providesalternatives in many color space applications Additionallywith the recent introduction of several new DPP productsPR 264 (Figure 7) PR 272 and PO 71 and PO 73(Figure 8) into the polyolefin and PVC market areas agreater breadth of high performance organics is availablefor formulating In some case differences in the perform-ance of organic versus heavy metal pigments may result inadditional raw material costs Material selection and mod-ification of base stabilization are required in some casesand additional light stabilization packages are needed
continued on page 14
continued on page 15
continued from page 13
SPE CAD NEWS Summer 2014 page 14 wwwspecadorg
especially when formulating polyolefins for outdoor appli-cations to provide comparable alternatives Nonethelessconsumers (materials specifiers manufacturers and theultimate product purchaser) choosing to avoid use of cad-mium and lead pigments wherever reasonably possibleremains a continuously evolving trend
The formulation of rotationally molded articles for outdoorapplications requires the use of both suitable pigments aswell as the assistance of a well-designed light stabilizerpackage The use of tetramethyl piperidine based hinderedamine light stabilizers especially oligomeric and highmolecular weight types in combination with benzotriazolebased UV absorbers are recommended for use in a varietyof applications The total package loading should be tai-lored to meet the specified requirement of the application
DISTORTION EFFECTSDistortion of rotomolded articles can be effected by sever-al different variables Resin choice and the particular mate-rial being used can affect warpage and shrinkageDifferences in cooling of the mold thickness variationsovercuring and several other process parameters have beenfound to be related to warping Since pigments (and thesystems used to deliver them) may alter the flow character-istics of the polymer and also the cure characteristics oper-ation of a given mold with different pigments or colorantsystems with a single cure cycle may result in differencesin dimensional stability The use of controlled heating andcooling as well as good control over the process itself willhelp to ensure consistent part manufacturing as well as agood data and record keeping can be referred to in case oferratic part quality
IMPACT PROPERTIESImpact properties are commonly tested as a means ofassessing the quality and suitability of colorant systems aswell as for assessing the cure characteristics of the polymerand the properties of the final product The ARM(Association of Rotational Molders) impact test is a com-mon test that is used Alternative instrumented testing pro-vides similar test result capabilities with the advantage ofquantitative and qualitative data acquisition
Impact properties of rotomolded products are importantMany toys containers and other applications require assur-ances of product integrity which can often be affected notonly by the process conditions but also by the incorpora-tion of pigments and other additives Since there is very lit-tle shear in the rotomolding process pigments are likely tobe located at the grain boundary between adjacent polymergranules This localization of pigment and ldquoadditivesrdquo can adversely affect physical properties in sev-eral ways Inhibition of polymer chain entanglementsbetween particles due to additives that form an interfacebetween resin particles can result in weak distinct bound-aries with poor mechanical properties Also pigmentagglomerates which are not broken apart or more trou-bling when they are formed during premixing processesdue to excessive mixing may introduce point defectseffecting physical properties Aesthetic properties may alsobe impacted if agglomerates are present in either signifi-cant size or number Pigment loading which is related toboth the effectiveness in which the pigment can be dis-persed as well as the color requirements of the part isanother factor to be considered in assessing the potentialeffect of coloration on physical properties
REGULATORY ASPECTSWith the variety of applications encountered in rotationalmolding well-publicized legislation and public opinionhave compelled many plastics processors and end-users touse alternatives to cadmium and lead based pigmentsCONEG (COalition of NorthEast Governors) related legis-lation prohibits the sale of packaging materials to whichcadmium lead mercury and hexavalent chromium or theircompounds have been intentionally added Reducing theamount of these elements entering the food chain via wastedisposal sources and the extra precautions needed to dis-pose of post industrial wastes are issues to be addressesCertainly both lead and cadmium-based pigments possessa combination of desireable technical properties that makesthem articularly useful coloring materials for polymersLead based pigments furthermore are particularly eco-nomical in use Nonetheless public opinion and legislationhave had and will likely continue to have a significantimpact on their use particularly in consumer goods
SPE CAD NEWS Summer 2014 page 15 wwwspecadorg
The Color and Appearance Division (CAD) is commit-ted to the publishing of at least three newsletters a year(four if there is sufficient material to justify the extraissue) To that end we would like you to think aboutthe financial side of sponsorship of the newsletter Forthe small donation of $300 per year we offer a businesscard sized (2 x 35) mention in our newsletter whichgoes out to the nearly 1500 members of the CAD aswell as other SPE division members These are peopleactive in every aspect of plastic coloring and additivetechnology Larger sized spots are available at a com-mensurate increase in rate
If you are interested in helping to sponsor theSPECAD Newsletter please contactScott Aumann Phone 912 210 0175
Email ScottAumannedmmilliporecom
Your Company Our Division
Dear Members
Just a reminder that you can view past and currentBOARD MINUTES on the SPECAD website
We do not typically publish the minutes in the elec-tronic versions of our newsletter but they are alwaysavailable for our members to view from our websiteThe site is not completely current at this time as weare in the process of giving it a makeover and newlaunch in January
Click here for the link to viewhttpwwwspecadorgindexphpnavid=28
Board Minutes
CONNECT WITH SPE CAD VIASOCIAL MEDIA
Join SPECADrsquos Group On Linked Into network with industry peers participate in groupdiscussions of industry and technical topics findjob opportunities and get the latest division andconference announcements
Group Name SPE Color amp AppearanceDivision Group ID 152108 wwwlinkedincomgroupsgid=152108
continued from page 14
Colorants for polymers that are suitable for food contactuse according to 21 CFR1783297 by the FDA (Food andDrug Administration) NSF (National SanitationFoundation) listing for Potable water contact applicationsand ASTM toy specifications may further place limitationson which pigments may be used
CONCLUSIONSRotational molding presents specific performance require-ment for colorants due to the process dynamics and end-user application needs High performance organic pig-ments in addition to inorganic pigments provide usefulsolutions for designers and manufacturers of rotationallymolded products However as this market continues togrow due to the many unique product features attributed tothe rotomolding process advancements in pigmentationstabilization resin processes and ancillary products shouldalso grow as well Active research and development in sta-bilization technology continues to advance new productsand uniquely designed chemistries (such as lactone andhydroxylamine process stabilizers) into the market placeNew pigment products such as those based upon DPPchemistry also show promise in rotational molding appli-cations Moreover these new products further broadenproduct development potential by providing ever increas-ing performance and greater value in use
ACKNOWLEDGEMENTSThis paper would not have been possible without the col-laborative efforts os Steve Juhasz and Dick Huska of thePlastics Technical Center in Newport DE and JohnLinehan and Urs Stadler of the Additives DivisionLaboratories in Tarrytown NY Appreciation is also givento colleagues of Ciba Specialty Chemicals PigmentsDivision in Basle Switzerland for additional data
DuPonttrade Ti-Purereg titanium dioxide
DuPont Titanium Technologies8004419485
wwwtitaniumdupontcom
The DuPont Oval DuPont trade The miracles of sciencereg and Ti-Purereg
are trademarks or registered trademarks of EI du Pont de Nemours and Company
POLYMERS LIGHT amp SCIENCE
Polymers Light and the Science of TiO2
BTitanium Dioxide BRutile amp Anatase
BHigh Performance Organic PigmentsB DPP Reds HP Yellows
B PVC AdditivesB Lubricants amp Stabilizers
364 Johnny Mercer Blvd B-7 294 - Savannah GA 31410Tel (912)507-8972 - lwaltersagrofertinccom
wwwagrofertinccom
World Leader in EffectPigments
One International PlazaSuite 300Philadelphia PA 19113(888) 367-3275
wwwemdchemicalscom
A Complete Line of DyestuffsInorganic Pigments and
Organic Pigments forPlastics amp Fibers
LANXESS Corporation111 RIDC Park West Drive 1-800-526-9377Pittsburgh PA 15275-1112 wwwlanxesscom
World Leaders in Ultramarine PigmentswUltramarine Blue wUltramarine VioletwChrome Oxide Green wLead Chromate
wZinc Ferrite wIron Oxide
Phone 77027788196369 Peachtree Street Fax 7702778809Norcross GA 30071 Toll Free 8008866981wwwnubiolacom
We create chemistry for plastics
f
eate chemistry for plastics
basfcomplastic-additiveswww
your plastic applicationsovide solutions for all ofand other additives pr
Our UV light stabilizers antioxidants nucleatorsfect and functional pigments efneeds with color r ef
BASF helps meet your style and functionality
e crWWe cr
eate chemistry for plastics
1 800 431-2360Florham Park NJ
venue100 Park A AvenueBASF Corporation
ovide solutions for all ofOur UV light stabilizers antioxidants nucleators
fect and functional pigmentsBASF helps meet your style and functionality
Color Software ExpertsSince 1986
Quality Control Formulationamp Instrument Profiling
Visit our website and color blogwwwcyberchromeusacom
CyberChrome Inc3642 Main Street tStone Ridge NY 12484
PH 845-687-2671
wwwbasf
Color Concentrates and Single Pigment Dispersionsfor all Thermoplastic Polymers
Corporate Offices400 Old Dublin PikeDoylestown PA 18901(215) 345-6550
Operations amp Research Center2755 Bergey RoadHatfield PA 19440(215) 997-2221wwwpenncolorcom
SPE CAD NEWS Summer 2014 page 16 wwwspecadorg
SPE CAD NEWS Summer 2014 page 17 wwwspecadorg
Special thanks to our our Speakers Sponsors Exhibitors and Participants for your contributions to this yearrsquos CAD RETECreg 2014
Earl Balthazar III CAD RETECreg 2014 Conference Chair Datacolor Inc (817) 719-0224 CAD_RETECtxrrcomMark FreshwaterCAD RETECreg 2014 Vice-ChairLansco Colors(330) 526-8833markpigmentscom
Nathan KarszesCAD RETECreg 2014 Technical Program Co-ChairNubiola Corporation(770) 527-2409nkarszesnubiolacomBrenda MullinsCAD RETECreg2014 Technical Program Co-ChairClariant Corporation(678) 237-2975 brendamullinsclariantcom
SPE CAD NEWS Summer 2014 page 18 wwwspecadorg
LAE
HA WORK AROU
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FOR MORE INFORMATION Program Professor
4195592459 866ATTERRA ext 2459jprzybylskiterraedu
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SPE CAD NEWS Summer 2014 page 19 wwwspecadorg
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September 26 2014 ndash 500pm EDT
A SPE ANTECreg
T Because of this the p Please make a note of this significant change Y
We would consider any paper related to the color andor appearance of plastic and the f
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Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom
High Performance Pigments for Demanding Applications Rotational MoldingJoseph J Fay PhD amp Peter Zillitto
Plastics Technical Center Pigments DivisionCiba Specialty Chemicals Corporation
Technical Article
INTRODUCTIONColorants for polymer applications are typically incorporated into the polymer by one of several common pathways Colorconcentrates which are widely used in industry enable the end user to conveniently meter in the colorant at the prescribedration with virgin or uncolored polymer in the manufacturing process The benefits of concentrate used as compared to thedirect use of powder pigment during final product conversion processes include predispersion of the pigment in a suit-able carrier system elimination of the need to in-house compounding to incorporate the colorant uniformly and improvedhousekeeping etc Furthermore color concentrates are available ina number of product forms including pelleted concen-trates liquid color systems and pastes the latter used especially for PVC For polymer conversion processes in which anextruder or meld mixing devise is employed these colorant preparations can be used very effectively In some marketswhere high levels of functional fillers modifiers or polymer blends are used compounders may manufacture ldquoprecoloredrdquopolymer by direct addition of the colorant to their compounding line In come cases concentrates are used depending uponspecific product and process capabilities
Rotational molding in contrast is a low shear process in which traditional pellet form color concentrates are not suitableColoration of rotomolding resin is commonly obtained by the use of dry color and liquid color which can be added direct-ly to the ground rotomolding resin Alternatively precolored resin in which the pigment is compounded into to the poly-mer and then ground before use finds applications as well More recently micropellet technology has been advanced as an alternative to the aforementioned methods It is similar to precompounded color but the need for grinding the polymerinto the appropriate mesh size is eliminated as the micropellets can be rotomolded without further processing For each ofthese color incorporation methods there are advantages and disadvantages including economic factors (process equipmentand material cost) ease of use housekeeping and overall quality (physical properties and aesthetics) of the resulting part
As a consequence of the myriad applications the palette of pigments for rotational molding appears to be quite extensivesimilar to that which is used in general purpose polyethylene application requirements However due to the specific processconditions involved in preparing the pigment system the temperature profile of the rota-tional molding process and the end use application requirement the gamut of pigments issignificantly reduced
Pigment selection may also be affected by the method by which the pigment is to be deliv-ered Liquid colorant systems work best with pigments that have the potential to be loadedto high weight percentages while maintaining suitable viscosity Pigments used in drycolor require characteristics that impart dispersibility and minimize agglomeration duringboth dry color manufacture and blending with the rotomolding resin
DISPERSIONWhen pigments are manufactured the smallest pigment particles formed are discreet units referred to as primary particlesAs a result of their high surface energy these particles randomly join together to form aggregates and agglomerates thelatter being formed primarily during subsequent filtration a nd drying processes To achieve a speck-free system the pig-ment must be effectively ldquodispersedrdquo so that the individual pigment particles or aggregates are wetted by the polymer anddiscrete pigment particles are not visible to the naked eye Rotomolding pigment systems (liquid color and dry color) needto be prepared in a manner that ensures visible agglomerates are eliminated and that during subsequent mixing with therotomolding resin the colorant system will be easily distributed Furthermore the dispersion of the pigment needs to effec-tively deliver a colorant that will provide a high color strength potential to maximize economic while not adversely affect-ing other properties Figure 1 illustrates the particle size of the typical azoncondensation pigment continued on page 12
SPE CAD NEWS Summer 2014 page 11 wwwspecadorg
The following Technical Article was published in 1998 at The Color And Appearance Conference in September
continued from page 11
Note that the particle size distribution that would beobtained in a polymeric system will be very dependentupon the effectiveness of the final dispersion
HIGH PERFORMANCE PIGMENTSHigh performance pigments HPP can be defined as pig-ments that have either very good to excellent heat or lightstability and more commonly pigments which offer aunique combination of both heat and light stability Theenhanced UV and heat performance attributes of HPPs setthem apart from traditional or classical pigments such asthe lithol rubines (PR 571) lake red C (PR 531) 2B toner(PR 48 types) monoaso yellows such as PY 62 and oth-ers which have only limited heat stability and mostly mar-ginal to poor lightfastness
The major types of high performance pigment chemistriescan be described in a general fashion as indicated in Table 1Some individual pigments within these chemistries mayhave better or worse performance characteristics depend-ing upon the specific product attribute and applicationbeing considered
HEAT STABILITYOrganic pigments are available not only with a wide vari-ety of hues and chroma but also with considerable variationin performance characteristics Rotational molding withits combination of relatively long cycle times high moldsurface temperatures and abundance of oxygen is moredemanding upon the polymer stabilization package andpigmentation in comparison to many other processes As aconsequence many rotomolded product applicationsrequire the use of higher performance pigments to survivethe molding process even though the pigment with regardto final product requirements may be viewed as ldquoover engi-neeredrdquo Classical pigments such as 2B reds (CI PigmentRed 48rsquos) with only limited thermal stability in high tem-perature olefin polymer applications may not be suitablefor even non durable articles as the color stability duringmolding may be insufficient Figure 2 compares the heatstability of a calcium 2B toner with high performance dike-topyrrolo-pyrrole (DPP) and quinacridone (QA)chemistries In masstone applications it is readily apparentthat the 2B toner is quite deficient when compared withthese high heat stability pigments Furthermore as pigment
SPE CAD NEWS Summer 2014 page 12 wwwspecadorg
heat stability is generally related to concentration at lowerconcentrations the 2B toner would become even moreprone to color change In addition to pigment instabilitycolor change during rotational molding may be affected byother factors The stability of the base resin is an importantconsideration The role of the antioxidant package is criti-cal to controlling the initial color and maintaining the phys-ical properties of the rotomolding resin Judicious selectionof a phenolic antioxidant and phosphite processing stabi-lizer package is essential for the base polymer Dependingupon specific circumstances additional antioxidant mightbe added The most effective stabilization is typicallyobtained when the antioxidant is added directly to the resinitself during manufacture or during compounding whenrecolored resin is prepared For specialty applications
where additional antioxidants are needed to attain the req-uisite performance precolored or preformulated resinwhich is then ground provides additional benefit
LIGHT STABILITYMany applications of rotationally molded articles find enduses which require UV durability These UV performanceapplications encompass a broad variety of applications andmarkets residential waste containers childrenrsquos play-ground toys (both for residential and institutional uses)outdoor sporting goods (kayaks and component of otherrecreational vehicles) and oversize containers (industrialcontainers and agricultural tanks) For outdoor applica-tions careful formulation is required to achieve not onlysuitable color match but also a color combination whichwill have the desired weatherability As delineated inFigure 3 Calcium 2B toners have limited light stability inpolyolefin applications and are not recommended for usewhere any significant UV exposure is intended Althoughnot reflected in the colorimetric data the 2B toner samplesurface was significantly marred by chalking and surfacemicrocracking and is visible via low magnification optical
Quinacridone Copper PhthalocyanineDiketopyrrolo-pyrrole (DPP) AnthraquinoneTetrachchloroisoindolinone IndanthroneAzochondensation PeryleneBenzimidozone Isoindoline
Table 1 High Performance Chemistry Families
continued from page 12
SPE CAD NEWS Summer 2014 page 13 wwwspecadorg
microscopy Such microcracks may ultimately result inpremature physical failures of the product Therefore visu-al inspection of samples following accelerated or real-timeexposure testing is imperative to ensure complete perform-ance analysis As a consequence of the limited weather-ability of many pigments performance assessment is need-ed Applications such as point of sale displays and relateditems and indoor applications where incidental UV expo-sure from lighting fixtures or nearby windows is possibleare best formulated with durable HPP pigments Outdoorapplications require the use of HPP pigments at levels thatcan provide sufficient levels of weather resistance
Figure 5 illustratesthe difference inlong-term UV sta-bility that wasobtained when aDPP red (PR254) was com-pared with a pery-lene red (PR178) Perylenepigments areprone to darken-ing when used inconjunction withhindered amine light stabilizers (HALS) whereas no suchnegative interaction has been observed for DPPchemistries
Other high performance pigment classes such as copperphthalocyanine blue pigments may also be suitable foroutdoor applications when properly formulated PB 151and PB 153 are widely used in rotational molding appli-cations as a consequence of their outstanding performanceproperties Figure 6 and tremendous value in use
Inorganic and heavy metal pigments are also widely usedin some rotational molding applications due to their general-ly good dispersibility characteristics and in many cases thecleanliness of shade that may be obtained when using cer-tain cadmium and lead chromate pigments However aswill be discussed in greater detail regulatory pressureshave resulted in heavy metal deselection in several appli-
cation areas including food packaging and many toy appli-cations There applications however have not always beeneasily reformulated The use of HPP products providesalternatives in many color space applications Additionallywith the recent introduction of several new DPP productsPR 264 (Figure 7) PR 272 and PO 71 and PO 73(Figure 8) into the polyolefin and PVC market areas agreater breadth of high performance organics is availablefor formulating In some case differences in the perform-ance of organic versus heavy metal pigments may result inadditional raw material costs Material selection and mod-ification of base stabilization are required in some casesand additional light stabilization packages are needed
continued on page 14
continued on page 15
continued from page 13
SPE CAD NEWS Summer 2014 page 14 wwwspecadorg
especially when formulating polyolefins for outdoor appli-cations to provide comparable alternatives Nonethelessconsumers (materials specifiers manufacturers and theultimate product purchaser) choosing to avoid use of cad-mium and lead pigments wherever reasonably possibleremains a continuously evolving trend
The formulation of rotationally molded articles for outdoorapplications requires the use of both suitable pigments aswell as the assistance of a well-designed light stabilizerpackage The use of tetramethyl piperidine based hinderedamine light stabilizers especially oligomeric and highmolecular weight types in combination with benzotriazolebased UV absorbers are recommended for use in a varietyof applications The total package loading should be tai-lored to meet the specified requirement of the application
DISTORTION EFFECTSDistortion of rotomolded articles can be effected by sever-al different variables Resin choice and the particular mate-rial being used can affect warpage and shrinkageDifferences in cooling of the mold thickness variationsovercuring and several other process parameters have beenfound to be related to warping Since pigments (and thesystems used to deliver them) may alter the flow character-istics of the polymer and also the cure characteristics oper-ation of a given mold with different pigments or colorantsystems with a single cure cycle may result in differencesin dimensional stability The use of controlled heating andcooling as well as good control over the process itself willhelp to ensure consistent part manufacturing as well as agood data and record keeping can be referred to in case oferratic part quality
IMPACT PROPERTIESImpact properties are commonly tested as a means ofassessing the quality and suitability of colorant systems aswell as for assessing the cure characteristics of the polymerand the properties of the final product The ARM(Association of Rotational Molders) impact test is a com-mon test that is used Alternative instrumented testing pro-vides similar test result capabilities with the advantage ofquantitative and qualitative data acquisition
Impact properties of rotomolded products are importantMany toys containers and other applications require assur-ances of product integrity which can often be affected notonly by the process conditions but also by the incorpora-tion of pigments and other additives Since there is very lit-tle shear in the rotomolding process pigments are likely tobe located at the grain boundary between adjacent polymergranules This localization of pigment and ldquoadditivesrdquo can adversely affect physical properties in sev-eral ways Inhibition of polymer chain entanglementsbetween particles due to additives that form an interfacebetween resin particles can result in weak distinct bound-aries with poor mechanical properties Also pigmentagglomerates which are not broken apart or more trou-bling when they are formed during premixing processesdue to excessive mixing may introduce point defectseffecting physical properties Aesthetic properties may alsobe impacted if agglomerates are present in either signifi-cant size or number Pigment loading which is related toboth the effectiveness in which the pigment can be dis-persed as well as the color requirements of the part isanother factor to be considered in assessing the potentialeffect of coloration on physical properties
REGULATORY ASPECTSWith the variety of applications encountered in rotationalmolding well-publicized legislation and public opinionhave compelled many plastics processors and end-users touse alternatives to cadmium and lead based pigmentsCONEG (COalition of NorthEast Governors) related legis-lation prohibits the sale of packaging materials to whichcadmium lead mercury and hexavalent chromium or theircompounds have been intentionally added Reducing theamount of these elements entering the food chain via wastedisposal sources and the extra precautions needed to dis-pose of post industrial wastes are issues to be addressesCertainly both lead and cadmium-based pigments possessa combination of desireable technical properties that makesthem articularly useful coloring materials for polymersLead based pigments furthermore are particularly eco-nomical in use Nonetheless public opinion and legislationhave had and will likely continue to have a significantimpact on their use particularly in consumer goods
SPE CAD NEWS Summer 2014 page 15 wwwspecadorg
The Color and Appearance Division (CAD) is commit-ted to the publishing of at least three newsletters a year(four if there is sufficient material to justify the extraissue) To that end we would like you to think aboutthe financial side of sponsorship of the newsletter Forthe small donation of $300 per year we offer a businesscard sized (2 x 35) mention in our newsletter whichgoes out to the nearly 1500 members of the CAD aswell as other SPE division members These are peopleactive in every aspect of plastic coloring and additivetechnology Larger sized spots are available at a com-mensurate increase in rate
If you are interested in helping to sponsor theSPECAD Newsletter please contactScott Aumann Phone 912 210 0175
Email ScottAumannedmmilliporecom
Your Company Our Division
Dear Members
Just a reminder that you can view past and currentBOARD MINUTES on the SPECAD website
We do not typically publish the minutes in the elec-tronic versions of our newsletter but they are alwaysavailable for our members to view from our websiteThe site is not completely current at this time as weare in the process of giving it a makeover and newlaunch in January
Click here for the link to viewhttpwwwspecadorgindexphpnavid=28
Board Minutes
CONNECT WITH SPE CAD VIASOCIAL MEDIA
Join SPECADrsquos Group On Linked Into network with industry peers participate in groupdiscussions of industry and technical topics findjob opportunities and get the latest division andconference announcements
Group Name SPE Color amp AppearanceDivision Group ID 152108 wwwlinkedincomgroupsgid=152108
continued from page 14
Colorants for polymers that are suitable for food contactuse according to 21 CFR1783297 by the FDA (Food andDrug Administration) NSF (National SanitationFoundation) listing for Potable water contact applicationsand ASTM toy specifications may further place limitationson which pigments may be used
CONCLUSIONSRotational molding presents specific performance require-ment for colorants due to the process dynamics and end-user application needs High performance organic pig-ments in addition to inorganic pigments provide usefulsolutions for designers and manufacturers of rotationallymolded products However as this market continues togrow due to the many unique product features attributed tothe rotomolding process advancements in pigmentationstabilization resin processes and ancillary products shouldalso grow as well Active research and development in sta-bilization technology continues to advance new productsand uniquely designed chemistries (such as lactone andhydroxylamine process stabilizers) into the market placeNew pigment products such as those based upon DPPchemistry also show promise in rotational molding appli-cations Moreover these new products further broadenproduct development potential by providing ever increas-ing performance and greater value in use
ACKNOWLEDGEMENTSThis paper would not have been possible without the col-laborative efforts os Steve Juhasz and Dick Huska of thePlastics Technical Center in Newport DE and JohnLinehan and Urs Stadler of the Additives DivisionLaboratories in Tarrytown NY Appreciation is also givento colleagues of Ciba Specialty Chemicals PigmentsDivision in Basle Switzerland for additional data
DuPonttrade Ti-Purereg titanium dioxide
DuPont Titanium Technologies8004419485
wwwtitaniumdupontcom
The DuPont Oval DuPont trade The miracles of sciencereg and Ti-Purereg
are trademarks or registered trademarks of EI du Pont de Nemours and Company
POLYMERS LIGHT amp SCIENCE
Polymers Light and the Science of TiO2
BTitanium Dioxide BRutile amp Anatase
BHigh Performance Organic PigmentsB DPP Reds HP Yellows
B PVC AdditivesB Lubricants amp Stabilizers
364 Johnny Mercer Blvd B-7 294 - Savannah GA 31410Tel (912)507-8972 - lwaltersagrofertinccom
wwwagrofertinccom
World Leader in EffectPigments
One International PlazaSuite 300Philadelphia PA 19113(888) 367-3275
wwwemdchemicalscom
A Complete Line of DyestuffsInorganic Pigments and
Organic Pigments forPlastics amp Fibers
LANXESS Corporation111 RIDC Park West Drive 1-800-526-9377Pittsburgh PA 15275-1112 wwwlanxesscom
World Leaders in Ultramarine PigmentswUltramarine Blue wUltramarine VioletwChrome Oxide Green wLead Chromate
wZinc Ferrite wIron Oxide
Phone 77027788196369 Peachtree Street Fax 7702778809Norcross GA 30071 Toll Free 8008866981wwwnubiolacom
We create chemistry for plastics
f
eate chemistry for plastics
basfcomplastic-additiveswww
your plastic applicationsovide solutions for all ofand other additives pr
Our UV light stabilizers antioxidants nucleatorsfect and functional pigments efneeds with color r ef
BASF helps meet your style and functionality
e crWWe cr
eate chemistry for plastics
1 800 431-2360Florham Park NJ
venue100 Park A AvenueBASF Corporation
ovide solutions for all ofOur UV light stabilizers antioxidants nucleators
fect and functional pigmentsBASF helps meet your style and functionality
Color Software ExpertsSince 1986
Quality Control Formulationamp Instrument Profiling
Visit our website and color blogwwwcyberchromeusacom
CyberChrome Inc3642 Main Street tStone Ridge NY 12484
PH 845-687-2671
wwwbasf
Color Concentrates and Single Pigment Dispersionsfor all Thermoplastic Polymers
Corporate Offices400 Old Dublin PikeDoylestown PA 18901(215) 345-6550
Operations amp Research Center2755 Bergey RoadHatfield PA 19440(215) 997-2221wwwpenncolorcom
SPE CAD NEWS Summer 2014 page 16 wwwspecadorg
SPE CAD NEWS Summer 2014 page 17 wwwspecadorg
Special thanks to our our Speakers Sponsors Exhibitors and Participants for your contributions to this yearrsquos CAD RETECreg 2014
Earl Balthazar III CAD RETECreg 2014 Conference Chair Datacolor Inc (817) 719-0224 CAD_RETECtxrrcomMark FreshwaterCAD RETECreg 2014 Vice-ChairLansco Colors(330) 526-8833markpigmentscom
Nathan KarszesCAD RETECreg 2014 Technical Program Co-ChairNubiola Corporation(770) 527-2409nkarszesnubiolacomBrenda MullinsCAD RETECreg2014 Technical Program Co-ChairClariant Corporation(678) 237-2975 brendamullinsclariantcom
SPE CAD NEWS Summer 2014 page 18 wwwspecadorg
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SPE CAD NEWS Summer 2014 page 19 wwwspecadorg
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September 26 2014 ndash 500pm EDT
A SPE ANTECreg
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Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom
continued from page 11
Note that the particle size distribution that would beobtained in a polymeric system will be very dependentupon the effectiveness of the final dispersion
HIGH PERFORMANCE PIGMENTSHigh performance pigments HPP can be defined as pig-ments that have either very good to excellent heat or lightstability and more commonly pigments which offer aunique combination of both heat and light stability Theenhanced UV and heat performance attributes of HPPs setthem apart from traditional or classical pigments such asthe lithol rubines (PR 571) lake red C (PR 531) 2B toner(PR 48 types) monoaso yellows such as PY 62 and oth-ers which have only limited heat stability and mostly mar-ginal to poor lightfastness
The major types of high performance pigment chemistriescan be described in a general fashion as indicated in Table 1Some individual pigments within these chemistries mayhave better or worse performance characteristics depend-ing upon the specific product attribute and applicationbeing considered
HEAT STABILITYOrganic pigments are available not only with a wide vari-ety of hues and chroma but also with considerable variationin performance characteristics Rotational molding withits combination of relatively long cycle times high moldsurface temperatures and abundance of oxygen is moredemanding upon the polymer stabilization package andpigmentation in comparison to many other processes As aconsequence many rotomolded product applicationsrequire the use of higher performance pigments to survivethe molding process even though the pigment with regardto final product requirements may be viewed as ldquoover engi-neeredrdquo Classical pigments such as 2B reds (CI PigmentRed 48rsquos) with only limited thermal stability in high tem-perature olefin polymer applications may not be suitablefor even non durable articles as the color stability duringmolding may be insufficient Figure 2 compares the heatstability of a calcium 2B toner with high performance dike-topyrrolo-pyrrole (DPP) and quinacridone (QA)chemistries In masstone applications it is readily apparentthat the 2B toner is quite deficient when compared withthese high heat stability pigments Furthermore as pigment
SPE CAD NEWS Summer 2014 page 12 wwwspecadorg
heat stability is generally related to concentration at lowerconcentrations the 2B toner would become even moreprone to color change In addition to pigment instabilitycolor change during rotational molding may be affected byother factors The stability of the base resin is an importantconsideration The role of the antioxidant package is criti-cal to controlling the initial color and maintaining the phys-ical properties of the rotomolding resin Judicious selectionof a phenolic antioxidant and phosphite processing stabi-lizer package is essential for the base polymer Dependingupon specific circumstances additional antioxidant mightbe added The most effective stabilization is typicallyobtained when the antioxidant is added directly to the resinitself during manufacture or during compounding whenrecolored resin is prepared For specialty applications
where additional antioxidants are needed to attain the req-uisite performance precolored or preformulated resinwhich is then ground provides additional benefit
LIGHT STABILITYMany applications of rotationally molded articles find enduses which require UV durability These UV performanceapplications encompass a broad variety of applications andmarkets residential waste containers childrenrsquos play-ground toys (both for residential and institutional uses)outdoor sporting goods (kayaks and component of otherrecreational vehicles) and oversize containers (industrialcontainers and agricultural tanks) For outdoor applica-tions careful formulation is required to achieve not onlysuitable color match but also a color combination whichwill have the desired weatherability As delineated inFigure 3 Calcium 2B toners have limited light stability inpolyolefin applications and are not recommended for usewhere any significant UV exposure is intended Althoughnot reflected in the colorimetric data the 2B toner samplesurface was significantly marred by chalking and surfacemicrocracking and is visible via low magnification optical
Quinacridone Copper PhthalocyanineDiketopyrrolo-pyrrole (DPP) AnthraquinoneTetrachchloroisoindolinone IndanthroneAzochondensation PeryleneBenzimidozone Isoindoline
Table 1 High Performance Chemistry Families
continued from page 12
SPE CAD NEWS Summer 2014 page 13 wwwspecadorg
microscopy Such microcracks may ultimately result inpremature physical failures of the product Therefore visu-al inspection of samples following accelerated or real-timeexposure testing is imperative to ensure complete perform-ance analysis As a consequence of the limited weather-ability of many pigments performance assessment is need-ed Applications such as point of sale displays and relateditems and indoor applications where incidental UV expo-sure from lighting fixtures or nearby windows is possibleare best formulated with durable HPP pigments Outdoorapplications require the use of HPP pigments at levels thatcan provide sufficient levels of weather resistance
Figure 5 illustratesthe difference inlong-term UV sta-bility that wasobtained when aDPP red (PR254) was com-pared with a pery-lene red (PR178) Perylenepigments areprone to darken-ing when used inconjunction withhindered amine light stabilizers (HALS) whereas no suchnegative interaction has been observed for DPPchemistries
Other high performance pigment classes such as copperphthalocyanine blue pigments may also be suitable foroutdoor applications when properly formulated PB 151and PB 153 are widely used in rotational molding appli-cations as a consequence of their outstanding performanceproperties Figure 6 and tremendous value in use
Inorganic and heavy metal pigments are also widely usedin some rotational molding applications due to their general-ly good dispersibility characteristics and in many cases thecleanliness of shade that may be obtained when using cer-tain cadmium and lead chromate pigments However aswill be discussed in greater detail regulatory pressureshave resulted in heavy metal deselection in several appli-
cation areas including food packaging and many toy appli-cations There applications however have not always beeneasily reformulated The use of HPP products providesalternatives in many color space applications Additionallywith the recent introduction of several new DPP productsPR 264 (Figure 7) PR 272 and PO 71 and PO 73(Figure 8) into the polyolefin and PVC market areas agreater breadth of high performance organics is availablefor formulating In some case differences in the perform-ance of organic versus heavy metal pigments may result inadditional raw material costs Material selection and mod-ification of base stabilization are required in some casesand additional light stabilization packages are needed
continued on page 14
continued on page 15
continued from page 13
SPE CAD NEWS Summer 2014 page 14 wwwspecadorg
especially when formulating polyolefins for outdoor appli-cations to provide comparable alternatives Nonethelessconsumers (materials specifiers manufacturers and theultimate product purchaser) choosing to avoid use of cad-mium and lead pigments wherever reasonably possibleremains a continuously evolving trend
The formulation of rotationally molded articles for outdoorapplications requires the use of both suitable pigments aswell as the assistance of a well-designed light stabilizerpackage The use of tetramethyl piperidine based hinderedamine light stabilizers especially oligomeric and highmolecular weight types in combination with benzotriazolebased UV absorbers are recommended for use in a varietyof applications The total package loading should be tai-lored to meet the specified requirement of the application
DISTORTION EFFECTSDistortion of rotomolded articles can be effected by sever-al different variables Resin choice and the particular mate-rial being used can affect warpage and shrinkageDifferences in cooling of the mold thickness variationsovercuring and several other process parameters have beenfound to be related to warping Since pigments (and thesystems used to deliver them) may alter the flow character-istics of the polymer and also the cure characteristics oper-ation of a given mold with different pigments or colorantsystems with a single cure cycle may result in differencesin dimensional stability The use of controlled heating andcooling as well as good control over the process itself willhelp to ensure consistent part manufacturing as well as agood data and record keeping can be referred to in case oferratic part quality
IMPACT PROPERTIESImpact properties are commonly tested as a means ofassessing the quality and suitability of colorant systems aswell as for assessing the cure characteristics of the polymerand the properties of the final product The ARM(Association of Rotational Molders) impact test is a com-mon test that is used Alternative instrumented testing pro-vides similar test result capabilities with the advantage ofquantitative and qualitative data acquisition
Impact properties of rotomolded products are importantMany toys containers and other applications require assur-ances of product integrity which can often be affected notonly by the process conditions but also by the incorpora-tion of pigments and other additives Since there is very lit-tle shear in the rotomolding process pigments are likely tobe located at the grain boundary between adjacent polymergranules This localization of pigment and ldquoadditivesrdquo can adversely affect physical properties in sev-eral ways Inhibition of polymer chain entanglementsbetween particles due to additives that form an interfacebetween resin particles can result in weak distinct bound-aries with poor mechanical properties Also pigmentagglomerates which are not broken apart or more trou-bling when they are formed during premixing processesdue to excessive mixing may introduce point defectseffecting physical properties Aesthetic properties may alsobe impacted if agglomerates are present in either signifi-cant size or number Pigment loading which is related toboth the effectiveness in which the pigment can be dis-persed as well as the color requirements of the part isanother factor to be considered in assessing the potentialeffect of coloration on physical properties
REGULATORY ASPECTSWith the variety of applications encountered in rotationalmolding well-publicized legislation and public opinionhave compelled many plastics processors and end-users touse alternatives to cadmium and lead based pigmentsCONEG (COalition of NorthEast Governors) related legis-lation prohibits the sale of packaging materials to whichcadmium lead mercury and hexavalent chromium or theircompounds have been intentionally added Reducing theamount of these elements entering the food chain via wastedisposal sources and the extra precautions needed to dis-pose of post industrial wastes are issues to be addressesCertainly both lead and cadmium-based pigments possessa combination of desireable technical properties that makesthem articularly useful coloring materials for polymersLead based pigments furthermore are particularly eco-nomical in use Nonetheless public opinion and legislationhave had and will likely continue to have a significantimpact on their use particularly in consumer goods
SPE CAD NEWS Summer 2014 page 15 wwwspecadorg
The Color and Appearance Division (CAD) is commit-ted to the publishing of at least three newsletters a year(four if there is sufficient material to justify the extraissue) To that end we would like you to think aboutthe financial side of sponsorship of the newsletter Forthe small donation of $300 per year we offer a businesscard sized (2 x 35) mention in our newsletter whichgoes out to the nearly 1500 members of the CAD aswell as other SPE division members These are peopleactive in every aspect of plastic coloring and additivetechnology Larger sized spots are available at a com-mensurate increase in rate
If you are interested in helping to sponsor theSPECAD Newsletter please contactScott Aumann Phone 912 210 0175
Email ScottAumannedmmilliporecom
Your Company Our Division
Dear Members
Just a reminder that you can view past and currentBOARD MINUTES on the SPECAD website
We do not typically publish the minutes in the elec-tronic versions of our newsletter but they are alwaysavailable for our members to view from our websiteThe site is not completely current at this time as weare in the process of giving it a makeover and newlaunch in January
Click here for the link to viewhttpwwwspecadorgindexphpnavid=28
Board Minutes
CONNECT WITH SPE CAD VIASOCIAL MEDIA
Join SPECADrsquos Group On Linked Into network with industry peers participate in groupdiscussions of industry and technical topics findjob opportunities and get the latest division andconference announcements
Group Name SPE Color amp AppearanceDivision Group ID 152108 wwwlinkedincomgroupsgid=152108
continued from page 14
Colorants for polymers that are suitable for food contactuse according to 21 CFR1783297 by the FDA (Food andDrug Administration) NSF (National SanitationFoundation) listing for Potable water contact applicationsand ASTM toy specifications may further place limitationson which pigments may be used
CONCLUSIONSRotational molding presents specific performance require-ment for colorants due to the process dynamics and end-user application needs High performance organic pig-ments in addition to inorganic pigments provide usefulsolutions for designers and manufacturers of rotationallymolded products However as this market continues togrow due to the many unique product features attributed tothe rotomolding process advancements in pigmentationstabilization resin processes and ancillary products shouldalso grow as well Active research and development in sta-bilization technology continues to advance new productsand uniquely designed chemistries (such as lactone andhydroxylamine process stabilizers) into the market placeNew pigment products such as those based upon DPPchemistry also show promise in rotational molding appli-cations Moreover these new products further broadenproduct development potential by providing ever increas-ing performance and greater value in use
ACKNOWLEDGEMENTSThis paper would not have been possible without the col-laborative efforts os Steve Juhasz and Dick Huska of thePlastics Technical Center in Newport DE and JohnLinehan and Urs Stadler of the Additives DivisionLaboratories in Tarrytown NY Appreciation is also givento colleagues of Ciba Specialty Chemicals PigmentsDivision in Basle Switzerland for additional data
DuPonttrade Ti-Purereg titanium dioxide
DuPont Titanium Technologies8004419485
wwwtitaniumdupontcom
The DuPont Oval DuPont trade The miracles of sciencereg and Ti-Purereg
are trademarks or registered trademarks of EI du Pont de Nemours and Company
POLYMERS LIGHT amp SCIENCE
Polymers Light and the Science of TiO2
BTitanium Dioxide BRutile amp Anatase
BHigh Performance Organic PigmentsB DPP Reds HP Yellows
B PVC AdditivesB Lubricants amp Stabilizers
364 Johnny Mercer Blvd B-7 294 - Savannah GA 31410Tel (912)507-8972 - lwaltersagrofertinccom
wwwagrofertinccom
World Leader in EffectPigments
One International PlazaSuite 300Philadelphia PA 19113(888) 367-3275
wwwemdchemicalscom
A Complete Line of DyestuffsInorganic Pigments and
Organic Pigments forPlastics amp Fibers
LANXESS Corporation111 RIDC Park West Drive 1-800-526-9377Pittsburgh PA 15275-1112 wwwlanxesscom
World Leaders in Ultramarine PigmentswUltramarine Blue wUltramarine VioletwChrome Oxide Green wLead Chromate
wZinc Ferrite wIron Oxide
Phone 77027788196369 Peachtree Street Fax 7702778809Norcross GA 30071 Toll Free 8008866981wwwnubiolacom
We create chemistry for plastics
f
eate chemistry for plastics
basfcomplastic-additiveswww
your plastic applicationsovide solutions for all ofand other additives pr
Our UV light stabilizers antioxidants nucleatorsfect and functional pigments efneeds with color r ef
BASF helps meet your style and functionality
e crWWe cr
eate chemistry for plastics
1 800 431-2360Florham Park NJ
venue100 Park A AvenueBASF Corporation
ovide solutions for all ofOur UV light stabilizers antioxidants nucleators
fect and functional pigmentsBASF helps meet your style and functionality
Color Software ExpertsSince 1986
Quality Control Formulationamp Instrument Profiling
Visit our website and color blogwwwcyberchromeusacom
CyberChrome Inc3642 Main Street tStone Ridge NY 12484
PH 845-687-2671
wwwbasf
Color Concentrates and Single Pigment Dispersionsfor all Thermoplastic Polymers
Corporate Offices400 Old Dublin PikeDoylestown PA 18901(215) 345-6550
Operations amp Research Center2755 Bergey RoadHatfield PA 19440(215) 997-2221wwwpenncolorcom
SPE CAD NEWS Summer 2014 page 16 wwwspecadorg
SPE CAD NEWS Summer 2014 page 17 wwwspecadorg
Special thanks to our our Speakers Sponsors Exhibitors and Participants for your contributions to this yearrsquos CAD RETECreg 2014
Earl Balthazar III CAD RETECreg 2014 Conference Chair Datacolor Inc (817) 719-0224 CAD_RETECtxrrcomMark FreshwaterCAD RETECreg 2014 Vice-ChairLansco Colors(330) 526-8833markpigmentscom
Nathan KarszesCAD RETECreg 2014 Technical Program Co-ChairNubiola Corporation(770) 527-2409nkarszesnubiolacomBrenda MullinsCAD RETECreg2014 Technical Program Co-ChairClariant Corporation(678) 237-2975 brendamullinsclariantcom
SPE CAD NEWS Summer 2014 page 18 wwwspecadorg
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SPE CAD NEWS Summer 2014 page 19 wwwspecadorg
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September 26 2014 ndash 500pm EDT
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Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom
continued from page 12
SPE CAD NEWS Summer 2014 page 13 wwwspecadorg
microscopy Such microcracks may ultimately result inpremature physical failures of the product Therefore visu-al inspection of samples following accelerated or real-timeexposure testing is imperative to ensure complete perform-ance analysis As a consequence of the limited weather-ability of many pigments performance assessment is need-ed Applications such as point of sale displays and relateditems and indoor applications where incidental UV expo-sure from lighting fixtures or nearby windows is possibleare best formulated with durable HPP pigments Outdoorapplications require the use of HPP pigments at levels thatcan provide sufficient levels of weather resistance
Figure 5 illustratesthe difference inlong-term UV sta-bility that wasobtained when aDPP red (PR254) was com-pared with a pery-lene red (PR178) Perylenepigments areprone to darken-ing when used inconjunction withhindered amine light stabilizers (HALS) whereas no suchnegative interaction has been observed for DPPchemistries
Other high performance pigment classes such as copperphthalocyanine blue pigments may also be suitable foroutdoor applications when properly formulated PB 151and PB 153 are widely used in rotational molding appli-cations as a consequence of their outstanding performanceproperties Figure 6 and tremendous value in use
Inorganic and heavy metal pigments are also widely usedin some rotational molding applications due to their general-ly good dispersibility characteristics and in many cases thecleanliness of shade that may be obtained when using cer-tain cadmium and lead chromate pigments However aswill be discussed in greater detail regulatory pressureshave resulted in heavy metal deselection in several appli-
cation areas including food packaging and many toy appli-cations There applications however have not always beeneasily reformulated The use of HPP products providesalternatives in many color space applications Additionallywith the recent introduction of several new DPP productsPR 264 (Figure 7) PR 272 and PO 71 and PO 73(Figure 8) into the polyolefin and PVC market areas agreater breadth of high performance organics is availablefor formulating In some case differences in the perform-ance of organic versus heavy metal pigments may result inadditional raw material costs Material selection and mod-ification of base stabilization are required in some casesand additional light stabilization packages are needed
continued on page 14
continued on page 15
continued from page 13
SPE CAD NEWS Summer 2014 page 14 wwwspecadorg
especially when formulating polyolefins for outdoor appli-cations to provide comparable alternatives Nonethelessconsumers (materials specifiers manufacturers and theultimate product purchaser) choosing to avoid use of cad-mium and lead pigments wherever reasonably possibleremains a continuously evolving trend
The formulation of rotationally molded articles for outdoorapplications requires the use of both suitable pigments aswell as the assistance of a well-designed light stabilizerpackage The use of tetramethyl piperidine based hinderedamine light stabilizers especially oligomeric and highmolecular weight types in combination with benzotriazolebased UV absorbers are recommended for use in a varietyof applications The total package loading should be tai-lored to meet the specified requirement of the application
DISTORTION EFFECTSDistortion of rotomolded articles can be effected by sever-al different variables Resin choice and the particular mate-rial being used can affect warpage and shrinkageDifferences in cooling of the mold thickness variationsovercuring and several other process parameters have beenfound to be related to warping Since pigments (and thesystems used to deliver them) may alter the flow character-istics of the polymer and also the cure characteristics oper-ation of a given mold with different pigments or colorantsystems with a single cure cycle may result in differencesin dimensional stability The use of controlled heating andcooling as well as good control over the process itself willhelp to ensure consistent part manufacturing as well as agood data and record keeping can be referred to in case oferratic part quality
IMPACT PROPERTIESImpact properties are commonly tested as a means ofassessing the quality and suitability of colorant systems aswell as for assessing the cure characteristics of the polymerand the properties of the final product The ARM(Association of Rotational Molders) impact test is a com-mon test that is used Alternative instrumented testing pro-vides similar test result capabilities with the advantage ofquantitative and qualitative data acquisition
Impact properties of rotomolded products are importantMany toys containers and other applications require assur-ances of product integrity which can often be affected notonly by the process conditions but also by the incorpora-tion of pigments and other additives Since there is very lit-tle shear in the rotomolding process pigments are likely tobe located at the grain boundary between adjacent polymergranules This localization of pigment and ldquoadditivesrdquo can adversely affect physical properties in sev-eral ways Inhibition of polymer chain entanglementsbetween particles due to additives that form an interfacebetween resin particles can result in weak distinct bound-aries with poor mechanical properties Also pigmentagglomerates which are not broken apart or more trou-bling when they are formed during premixing processesdue to excessive mixing may introduce point defectseffecting physical properties Aesthetic properties may alsobe impacted if agglomerates are present in either signifi-cant size or number Pigment loading which is related toboth the effectiveness in which the pigment can be dis-persed as well as the color requirements of the part isanother factor to be considered in assessing the potentialeffect of coloration on physical properties
REGULATORY ASPECTSWith the variety of applications encountered in rotationalmolding well-publicized legislation and public opinionhave compelled many plastics processors and end-users touse alternatives to cadmium and lead based pigmentsCONEG (COalition of NorthEast Governors) related legis-lation prohibits the sale of packaging materials to whichcadmium lead mercury and hexavalent chromium or theircompounds have been intentionally added Reducing theamount of these elements entering the food chain via wastedisposal sources and the extra precautions needed to dis-pose of post industrial wastes are issues to be addressesCertainly both lead and cadmium-based pigments possessa combination of desireable technical properties that makesthem articularly useful coloring materials for polymersLead based pigments furthermore are particularly eco-nomical in use Nonetheless public opinion and legislationhave had and will likely continue to have a significantimpact on their use particularly in consumer goods
SPE CAD NEWS Summer 2014 page 15 wwwspecadorg
The Color and Appearance Division (CAD) is commit-ted to the publishing of at least three newsletters a year(four if there is sufficient material to justify the extraissue) To that end we would like you to think aboutthe financial side of sponsorship of the newsletter Forthe small donation of $300 per year we offer a businesscard sized (2 x 35) mention in our newsletter whichgoes out to the nearly 1500 members of the CAD aswell as other SPE division members These are peopleactive in every aspect of plastic coloring and additivetechnology Larger sized spots are available at a com-mensurate increase in rate
If you are interested in helping to sponsor theSPECAD Newsletter please contactScott Aumann Phone 912 210 0175
Email ScottAumannedmmilliporecom
Your Company Our Division
Dear Members
Just a reminder that you can view past and currentBOARD MINUTES on the SPECAD website
We do not typically publish the minutes in the elec-tronic versions of our newsletter but they are alwaysavailable for our members to view from our websiteThe site is not completely current at this time as weare in the process of giving it a makeover and newlaunch in January
Click here for the link to viewhttpwwwspecadorgindexphpnavid=28
Board Minutes
CONNECT WITH SPE CAD VIASOCIAL MEDIA
Join SPECADrsquos Group On Linked Into network with industry peers participate in groupdiscussions of industry and technical topics findjob opportunities and get the latest division andconference announcements
Group Name SPE Color amp AppearanceDivision Group ID 152108 wwwlinkedincomgroupsgid=152108
continued from page 14
Colorants for polymers that are suitable for food contactuse according to 21 CFR1783297 by the FDA (Food andDrug Administration) NSF (National SanitationFoundation) listing for Potable water contact applicationsand ASTM toy specifications may further place limitationson which pigments may be used
CONCLUSIONSRotational molding presents specific performance require-ment for colorants due to the process dynamics and end-user application needs High performance organic pig-ments in addition to inorganic pigments provide usefulsolutions for designers and manufacturers of rotationallymolded products However as this market continues togrow due to the many unique product features attributed tothe rotomolding process advancements in pigmentationstabilization resin processes and ancillary products shouldalso grow as well Active research and development in sta-bilization technology continues to advance new productsand uniquely designed chemistries (such as lactone andhydroxylamine process stabilizers) into the market placeNew pigment products such as those based upon DPPchemistry also show promise in rotational molding appli-cations Moreover these new products further broadenproduct development potential by providing ever increas-ing performance and greater value in use
ACKNOWLEDGEMENTSThis paper would not have been possible without the col-laborative efforts os Steve Juhasz and Dick Huska of thePlastics Technical Center in Newport DE and JohnLinehan and Urs Stadler of the Additives DivisionLaboratories in Tarrytown NY Appreciation is also givento colleagues of Ciba Specialty Chemicals PigmentsDivision in Basle Switzerland for additional data
DuPonttrade Ti-Purereg titanium dioxide
DuPont Titanium Technologies8004419485
wwwtitaniumdupontcom
The DuPont Oval DuPont trade The miracles of sciencereg and Ti-Purereg
are trademarks or registered trademarks of EI du Pont de Nemours and Company
POLYMERS LIGHT amp SCIENCE
Polymers Light and the Science of TiO2
BTitanium Dioxide BRutile amp Anatase
BHigh Performance Organic PigmentsB DPP Reds HP Yellows
B PVC AdditivesB Lubricants amp Stabilizers
364 Johnny Mercer Blvd B-7 294 - Savannah GA 31410Tel (912)507-8972 - lwaltersagrofertinccom
wwwagrofertinccom
World Leader in EffectPigments
One International PlazaSuite 300Philadelphia PA 19113(888) 367-3275
wwwemdchemicalscom
A Complete Line of DyestuffsInorganic Pigments and
Organic Pigments forPlastics amp Fibers
LANXESS Corporation111 RIDC Park West Drive 1-800-526-9377Pittsburgh PA 15275-1112 wwwlanxesscom
World Leaders in Ultramarine PigmentswUltramarine Blue wUltramarine VioletwChrome Oxide Green wLead Chromate
wZinc Ferrite wIron Oxide
Phone 77027788196369 Peachtree Street Fax 7702778809Norcross GA 30071 Toll Free 8008866981wwwnubiolacom
We create chemistry for plastics
f
eate chemistry for plastics
basfcomplastic-additiveswww
your plastic applicationsovide solutions for all ofand other additives pr
Our UV light stabilizers antioxidants nucleatorsfect and functional pigments efneeds with color r ef
BASF helps meet your style and functionality
e crWWe cr
eate chemistry for plastics
1 800 431-2360Florham Park NJ
venue100 Park A AvenueBASF Corporation
ovide solutions for all ofOur UV light stabilizers antioxidants nucleators
fect and functional pigmentsBASF helps meet your style and functionality
Color Software ExpertsSince 1986
Quality Control Formulationamp Instrument Profiling
Visit our website and color blogwwwcyberchromeusacom
CyberChrome Inc3642 Main Street tStone Ridge NY 12484
PH 845-687-2671
wwwbasf
Color Concentrates and Single Pigment Dispersionsfor all Thermoplastic Polymers
Corporate Offices400 Old Dublin PikeDoylestown PA 18901(215) 345-6550
Operations amp Research Center2755 Bergey RoadHatfield PA 19440(215) 997-2221wwwpenncolorcom
SPE CAD NEWS Summer 2014 page 16 wwwspecadorg
SPE CAD NEWS Summer 2014 page 17 wwwspecadorg
Special thanks to our our Speakers Sponsors Exhibitors and Participants for your contributions to this yearrsquos CAD RETECreg 2014
Earl Balthazar III CAD RETECreg 2014 Conference Chair Datacolor Inc (817) 719-0224 CAD_RETECtxrrcomMark FreshwaterCAD RETECreg 2014 Vice-ChairLansco Colors(330) 526-8833markpigmentscom
Nathan KarszesCAD RETECreg 2014 Technical Program Co-ChairNubiola Corporation(770) 527-2409nkarszesnubiolacomBrenda MullinsCAD RETECreg2014 Technical Program Co-ChairClariant Corporation(678) 237-2975 brendamullinsclariantcom
SPE CAD NEWS Summer 2014 page 18 wwwspecadorg
LAE
HA WORK AROU
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FOR MORE INFORMATION Program Professor
4195592459 866ATTERRA ext 2459jprzybylskiterraedu
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SPE CAD NEWS Summer 2014 page 19 wwwspecadorg
M
September 26 2014 ndash 500pm EDT
A SPE ANTECreg
T Because of this the p Please make a note of this significant change Y
We would consider any paper related to the color andor appearance of plastic and the f
The technical track includes more traditional ANTECreg
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Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom
continued on page 15
continued from page 13
SPE CAD NEWS Summer 2014 page 14 wwwspecadorg
especially when formulating polyolefins for outdoor appli-cations to provide comparable alternatives Nonethelessconsumers (materials specifiers manufacturers and theultimate product purchaser) choosing to avoid use of cad-mium and lead pigments wherever reasonably possibleremains a continuously evolving trend
The formulation of rotationally molded articles for outdoorapplications requires the use of both suitable pigments aswell as the assistance of a well-designed light stabilizerpackage The use of tetramethyl piperidine based hinderedamine light stabilizers especially oligomeric and highmolecular weight types in combination with benzotriazolebased UV absorbers are recommended for use in a varietyof applications The total package loading should be tai-lored to meet the specified requirement of the application
DISTORTION EFFECTSDistortion of rotomolded articles can be effected by sever-al different variables Resin choice and the particular mate-rial being used can affect warpage and shrinkageDifferences in cooling of the mold thickness variationsovercuring and several other process parameters have beenfound to be related to warping Since pigments (and thesystems used to deliver them) may alter the flow character-istics of the polymer and also the cure characteristics oper-ation of a given mold with different pigments or colorantsystems with a single cure cycle may result in differencesin dimensional stability The use of controlled heating andcooling as well as good control over the process itself willhelp to ensure consistent part manufacturing as well as agood data and record keeping can be referred to in case oferratic part quality
IMPACT PROPERTIESImpact properties are commonly tested as a means ofassessing the quality and suitability of colorant systems aswell as for assessing the cure characteristics of the polymerand the properties of the final product The ARM(Association of Rotational Molders) impact test is a com-mon test that is used Alternative instrumented testing pro-vides similar test result capabilities with the advantage ofquantitative and qualitative data acquisition
Impact properties of rotomolded products are importantMany toys containers and other applications require assur-ances of product integrity which can often be affected notonly by the process conditions but also by the incorpora-tion of pigments and other additives Since there is very lit-tle shear in the rotomolding process pigments are likely tobe located at the grain boundary between adjacent polymergranules This localization of pigment and ldquoadditivesrdquo can adversely affect physical properties in sev-eral ways Inhibition of polymer chain entanglementsbetween particles due to additives that form an interfacebetween resin particles can result in weak distinct bound-aries with poor mechanical properties Also pigmentagglomerates which are not broken apart or more trou-bling when they are formed during premixing processesdue to excessive mixing may introduce point defectseffecting physical properties Aesthetic properties may alsobe impacted if agglomerates are present in either signifi-cant size or number Pigment loading which is related toboth the effectiveness in which the pigment can be dis-persed as well as the color requirements of the part isanother factor to be considered in assessing the potentialeffect of coloration on physical properties
REGULATORY ASPECTSWith the variety of applications encountered in rotationalmolding well-publicized legislation and public opinionhave compelled many plastics processors and end-users touse alternatives to cadmium and lead based pigmentsCONEG (COalition of NorthEast Governors) related legis-lation prohibits the sale of packaging materials to whichcadmium lead mercury and hexavalent chromium or theircompounds have been intentionally added Reducing theamount of these elements entering the food chain via wastedisposal sources and the extra precautions needed to dis-pose of post industrial wastes are issues to be addressesCertainly both lead and cadmium-based pigments possessa combination of desireable technical properties that makesthem articularly useful coloring materials for polymersLead based pigments furthermore are particularly eco-nomical in use Nonetheless public opinion and legislationhave had and will likely continue to have a significantimpact on their use particularly in consumer goods
SPE CAD NEWS Summer 2014 page 15 wwwspecadorg
The Color and Appearance Division (CAD) is commit-ted to the publishing of at least three newsletters a year(four if there is sufficient material to justify the extraissue) To that end we would like you to think aboutthe financial side of sponsorship of the newsletter Forthe small donation of $300 per year we offer a businesscard sized (2 x 35) mention in our newsletter whichgoes out to the nearly 1500 members of the CAD aswell as other SPE division members These are peopleactive in every aspect of plastic coloring and additivetechnology Larger sized spots are available at a com-mensurate increase in rate
If you are interested in helping to sponsor theSPECAD Newsletter please contactScott Aumann Phone 912 210 0175
Email ScottAumannedmmilliporecom
Your Company Our Division
Dear Members
Just a reminder that you can view past and currentBOARD MINUTES on the SPECAD website
We do not typically publish the minutes in the elec-tronic versions of our newsletter but they are alwaysavailable for our members to view from our websiteThe site is not completely current at this time as weare in the process of giving it a makeover and newlaunch in January
Click here for the link to viewhttpwwwspecadorgindexphpnavid=28
Board Minutes
CONNECT WITH SPE CAD VIASOCIAL MEDIA
Join SPECADrsquos Group On Linked Into network with industry peers participate in groupdiscussions of industry and technical topics findjob opportunities and get the latest division andconference announcements
Group Name SPE Color amp AppearanceDivision Group ID 152108 wwwlinkedincomgroupsgid=152108
continued from page 14
Colorants for polymers that are suitable for food contactuse according to 21 CFR1783297 by the FDA (Food andDrug Administration) NSF (National SanitationFoundation) listing for Potable water contact applicationsand ASTM toy specifications may further place limitationson which pigments may be used
CONCLUSIONSRotational molding presents specific performance require-ment for colorants due to the process dynamics and end-user application needs High performance organic pig-ments in addition to inorganic pigments provide usefulsolutions for designers and manufacturers of rotationallymolded products However as this market continues togrow due to the many unique product features attributed tothe rotomolding process advancements in pigmentationstabilization resin processes and ancillary products shouldalso grow as well Active research and development in sta-bilization technology continues to advance new productsand uniquely designed chemistries (such as lactone andhydroxylamine process stabilizers) into the market placeNew pigment products such as those based upon DPPchemistry also show promise in rotational molding appli-cations Moreover these new products further broadenproduct development potential by providing ever increas-ing performance and greater value in use
ACKNOWLEDGEMENTSThis paper would not have been possible without the col-laborative efforts os Steve Juhasz and Dick Huska of thePlastics Technical Center in Newport DE and JohnLinehan and Urs Stadler of the Additives DivisionLaboratories in Tarrytown NY Appreciation is also givento colleagues of Ciba Specialty Chemicals PigmentsDivision in Basle Switzerland for additional data
DuPonttrade Ti-Purereg titanium dioxide
DuPont Titanium Technologies8004419485
wwwtitaniumdupontcom
The DuPont Oval DuPont trade The miracles of sciencereg and Ti-Purereg
are trademarks or registered trademarks of EI du Pont de Nemours and Company
POLYMERS LIGHT amp SCIENCE
Polymers Light and the Science of TiO2
BTitanium Dioxide BRutile amp Anatase
BHigh Performance Organic PigmentsB DPP Reds HP Yellows
B PVC AdditivesB Lubricants amp Stabilizers
364 Johnny Mercer Blvd B-7 294 - Savannah GA 31410Tel (912)507-8972 - lwaltersagrofertinccom
wwwagrofertinccom
World Leader in EffectPigments
One International PlazaSuite 300Philadelphia PA 19113(888) 367-3275
wwwemdchemicalscom
A Complete Line of DyestuffsInorganic Pigments and
Organic Pigments forPlastics amp Fibers
LANXESS Corporation111 RIDC Park West Drive 1-800-526-9377Pittsburgh PA 15275-1112 wwwlanxesscom
World Leaders in Ultramarine PigmentswUltramarine Blue wUltramarine VioletwChrome Oxide Green wLead Chromate
wZinc Ferrite wIron Oxide
Phone 77027788196369 Peachtree Street Fax 7702778809Norcross GA 30071 Toll Free 8008866981wwwnubiolacom
We create chemistry for plastics
f
eate chemistry for plastics
basfcomplastic-additiveswww
your plastic applicationsovide solutions for all ofand other additives pr
Our UV light stabilizers antioxidants nucleatorsfect and functional pigments efneeds with color r ef
BASF helps meet your style and functionality
e crWWe cr
eate chemistry for plastics
1 800 431-2360Florham Park NJ
venue100 Park A AvenueBASF Corporation
ovide solutions for all ofOur UV light stabilizers antioxidants nucleators
fect and functional pigmentsBASF helps meet your style and functionality
Color Software ExpertsSince 1986
Quality Control Formulationamp Instrument Profiling
Visit our website and color blogwwwcyberchromeusacom
CyberChrome Inc3642 Main Street tStone Ridge NY 12484
PH 845-687-2671
wwwbasf
Color Concentrates and Single Pigment Dispersionsfor all Thermoplastic Polymers
Corporate Offices400 Old Dublin PikeDoylestown PA 18901(215) 345-6550
Operations amp Research Center2755 Bergey RoadHatfield PA 19440(215) 997-2221wwwpenncolorcom
SPE CAD NEWS Summer 2014 page 16 wwwspecadorg
SPE CAD NEWS Summer 2014 page 17 wwwspecadorg
Special thanks to our our Speakers Sponsors Exhibitors and Participants for your contributions to this yearrsquos CAD RETECreg 2014
Earl Balthazar III CAD RETECreg 2014 Conference Chair Datacolor Inc (817) 719-0224 CAD_RETECtxrrcomMark FreshwaterCAD RETECreg 2014 Vice-ChairLansco Colors(330) 526-8833markpigmentscom
Nathan KarszesCAD RETECreg 2014 Technical Program Co-ChairNubiola Corporation(770) 527-2409nkarszesnubiolacomBrenda MullinsCAD RETECreg2014 Technical Program Co-ChairClariant Corporation(678) 237-2975 brendamullinsclariantcom
SPE CAD NEWS Summer 2014 page 18 wwwspecadorg
LAE
HA WORK AROU
ND
YOU
AND YOUR HEDULE
FOR MORE INFORMATION Program Professor
4195592459 866ATTERRA ext 2459jprzybylskiterraedu
OWAAHHAH
EEEA
DN
UOO
U
RRO
AARKK ARRKO
(online) courses to students who may reside too fprogram is its ability to provide
eature of the Te fy distinctiverA v
(online) courses to students who may reside too fdistance learningrdquoldquoprogram is its ability to provide
ra State plasticsereature of the T
e learned on the job This is a ghavpeople with industrcoloring of plastics These courses are also g
ar(online) courses to students who may reside too fdistance learningrdquo
ra State plastics
ood oppore learned on the job This is a gxperience since many epeople with industr
coloring of plastics These courses are also g
AL
HHRUUROOU
YYODNND
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ortunity food oppory of themxperience since man
orood fcoloring of plastics These courses are also g
UOY
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tificate program It is a relativmembers of our industr
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-educated or undererr or undery of the news program thatra Statersquoer aspect of T Ter
e no color education new hires etc) that havy (technicianse all know people within the industr
earseral yor sev fyy fell as localled studentsvy serlearning program has successfull
ening classroom activities This distanceticipate in full-remont Ohio campus to par
(online) courses to students who may reside too f
benefits including Stude dayy Students completing this cer
them to learn the theore learned on the job This is a ghav
y low-costy is this internet-based three-
-educateds program that
e no color educationy (technicians
ed studentsening classroom activities This distance
ticipate in full-ar(online) courses to students who may reside too f
benefits includingtificate can e Students completing this cer
y behind what they do evthem to learn the theorood oppore learned on the job This is a g
xpecttificate can eyery behind what they do ev
ortunity food oppor
o Cion t o toducIntr
o Pion t o toducIntr
of the Coloring of Plastics industrone wyor ane fknowledg
ollowing three courses provide solid backgroundThe f
ywhere on their schedulecomplete anxible program that the emploel fleno-trav
tificate program It is a relativcourse cer
o Color
icso Plast
yof the Coloring of Plastics industry segmentsorking in the manone w
ollowing three courses provide solid background
ywhere on their scheduleee canyxible program that the emplo
y low-costeltificate program It is a relativ
y segmentsollowing three courses provide solid background
ee cany low-cost
ered Spring 2015 (JfOfall 2014 (Aered FfOf
Books Approees $450 Ohio studentsF
Section VL
y 12 ndash May 7)anuarered Spring 2015 (Jugust 20 ndash December 12)all 2014 (A
y $200ximatelBooks Appro-st$700 out-of f-statees $450 Ohio studentso Pion t to PlasttoducIntrPET 1100Section VL
y 12 ndash May 7)ugust 20 ndash December 12)
etatte(3 Credits)icso Plast
technicians and others to learn more about thematchers quality control technicians production
cellent opporxCourses are an e
or Plasants f o Color
o Cion t o toducIntr
technicians and others to learn more about thematchers quality control technicians production
er coloror newtunity fcellent oppor
icsor Plast
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technicians and others to learn more about thematchers quality control technicians production
er color
ered Spring 2015 (JfOfBooks Approees $600 Ohio studentsF
Section VL
ered Spring 2015 (JfOfall 2014 (Aered FfOf
Books Approees $450 Ohio studentsF
Section VL
ered Spring 2015 (JfOf
y 12 ndash May 7)ered Spring 2015 (Jy $150ximatelBooks Appro
-st$900 out-of f-statees $600 Ohio studentsor Plaants f for PlastPET 2320 ColorSection VL
y 12 ndash May 7anuarered Spring 2015 (Jugust 20 ndash December 12)all 2014 (A
y $200ximatelBooks Appro-st$700 out-of f-statees $450 Ohio studentso Cion t to ColortoducIntrPET 1240Section VL
y 12 ndash May 7)anuarered Spring 2015 (J
y 12 ndash May 7)
etatte (4 Credits)icsor Plast
)y 12 ndash May 7ugust 20 ndash December 12)
etatte (3 Credits)o Color
y 12 ndash May 7)
technicians and others to learn more about the
4195592459
FOR M
aedu
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erritylskjprzybxt 2459 eARRTETAAT866
rofessoram Progrram PP NOTIORMAATIFNIEORREFOR M
xt 2459
technicians and others to learn more about the
rofessor
ered Spring 2015 (JfOf
y the Office of Print Production of TSCProduced b
y 12 ndash May 7)anuarered Spring 2015 (J
C 032614y the Office of Print Production of TSC
y 12 ndash May 7)
For more informationclick here
SPE CAD NEWS Summer 2014 page 19 wwwspecadorg
M
September 26 2014 ndash 500pm EDT
A SPE ANTECreg
T Because of this the p Please make a note of this significant change Y
We would consider any paper related to the color andor appearance of plastic and the f
The technical track includes more traditional ANTECreg
For more i
L
P
S
E
c
E
e
u
r
i
e
l
r
c
o
e
E
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o
o
Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom
SPE CAD NEWS Summer 2014 page 15 wwwspecadorg
The Color and Appearance Division (CAD) is commit-ted to the publishing of at least three newsletters a year(four if there is sufficient material to justify the extraissue) To that end we would like you to think aboutthe financial side of sponsorship of the newsletter Forthe small donation of $300 per year we offer a businesscard sized (2 x 35) mention in our newsletter whichgoes out to the nearly 1500 members of the CAD aswell as other SPE division members These are peopleactive in every aspect of plastic coloring and additivetechnology Larger sized spots are available at a com-mensurate increase in rate
If you are interested in helping to sponsor theSPECAD Newsletter please contactScott Aumann Phone 912 210 0175
Email ScottAumannedmmilliporecom
Your Company Our Division
Dear Members
Just a reminder that you can view past and currentBOARD MINUTES on the SPECAD website
We do not typically publish the minutes in the elec-tronic versions of our newsletter but they are alwaysavailable for our members to view from our websiteThe site is not completely current at this time as weare in the process of giving it a makeover and newlaunch in January
Click here for the link to viewhttpwwwspecadorgindexphpnavid=28
Board Minutes
CONNECT WITH SPE CAD VIASOCIAL MEDIA
Join SPECADrsquos Group On Linked Into network with industry peers participate in groupdiscussions of industry and technical topics findjob opportunities and get the latest division andconference announcements
Group Name SPE Color amp AppearanceDivision Group ID 152108 wwwlinkedincomgroupsgid=152108
continued from page 14
Colorants for polymers that are suitable for food contactuse according to 21 CFR1783297 by the FDA (Food andDrug Administration) NSF (National SanitationFoundation) listing for Potable water contact applicationsand ASTM toy specifications may further place limitationson which pigments may be used
CONCLUSIONSRotational molding presents specific performance require-ment for colorants due to the process dynamics and end-user application needs High performance organic pig-ments in addition to inorganic pigments provide usefulsolutions for designers and manufacturers of rotationallymolded products However as this market continues togrow due to the many unique product features attributed tothe rotomolding process advancements in pigmentationstabilization resin processes and ancillary products shouldalso grow as well Active research and development in sta-bilization technology continues to advance new productsand uniquely designed chemistries (such as lactone andhydroxylamine process stabilizers) into the market placeNew pigment products such as those based upon DPPchemistry also show promise in rotational molding appli-cations Moreover these new products further broadenproduct development potential by providing ever increas-ing performance and greater value in use
ACKNOWLEDGEMENTSThis paper would not have been possible without the col-laborative efforts os Steve Juhasz and Dick Huska of thePlastics Technical Center in Newport DE and JohnLinehan and Urs Stadler of the Additives DivisionLaboratories in Tarrytown NY Appreciation is also givento colleagues of Ciba Specialty Chemicals PigmentsDivision in Basle Switzerland for additional data
DuPonttrade Ti-Purereg titanium dioxide
DuPont Titanium Technologies8004419485
wwwtitaniumdupontcom
The DuPont Oval DuPont trade The miracles of sciencereg and Ti-Purereg
are trademarks or registered trademarks of EI du Pont de Nemours and Company
POLYMERS LIGHT amp SCIENCE
Polymers Light and the Science of TiO2
BTitanium Dioxide BRutile amp Anatase
BHigh Performance Organic PigmentsB DPP Reds HP Yellows
B PVC AdditivesB Lubricants amp Stabilizers
364 Johnny Mercer Blvd B-7 294 - Savannah GA 31410Tel (912)507-8972 - lwaltersagrofertinccom
wwwagrofertinccom
World Leader in EffectPigments
One International PlazaSuite 300Philadelphia PA 19113(888) 367-3275
wwwemdchemicalscom
A Complete Line of DyestuffsInorganic Pigments and
Organic Pigments forPlastics amp Fibers
LANXESS Corporation111 RIDC Park West Drive 1-800-526-9377Pittsburgh PA 15275-1112 wwwlanxesscom
World Leaders in Ultramarine PigmentswUltramarine Blue wUltramarine VioletwChrome Oxide Green wLead Chromate
wZinc Ferrite wIron Oxide
Phone 77027788196369 Peachtree Street Fax 7702778809Norcross GA 30071 Toll Free 8008866981wwwnubiolacom
We create chemistry for plastics
f
eate chemistry for plastics
basfcomplastic-additiveswww
your plastic applicationsovide solutions for all ofand other additives pr
Our UV light stabilizers antioxidants nucleatorsfect and functional pigments efneeds with color r ef
BASF helps meet your style and functionality
e crWWe cr
eate chemistry for plastics
1 800 431-2360Florham Park NJ
venue100 Park A AvenueBASF Corporation
ovide solutions for all ofOur UV light stabilizers antioxidants nucleators
fect and functional pigmentsBASF helps meet your style and functionality
Color Software ExpertsSince 1986
Quality Control Formulationamp Instrument Profiling
Visit our website and color blogwwwcyberchromeusacom
CyberChrome Inc3642 Main Street tStone Ridge NY 12484
PH 845-687-2671
wwwbasf
Color Concentrates and Single Pigment Dispersionsfor all Thermoplastic Polymers
Corporate Offices400 Old Dublin PikeDoylestown PA 18901(215) 345-6550
Operations amp Research Center2755 Bergey RoadHatfield PA 19440(215) 997-2221wwwpenncolorcom
SPE CAD NEWS Summer 2014 page 16 wwwspecadorg
SPE CAD NEWS Summer 2014 page 17 wwwspecadorg
Special thanks to our our Speakers Sponsors Exhibitors and Participants for your contributions to this yearrsquos CAD RETECreg 2014
Earl Balthazar III CAD RETECreg 2014 Conference Chair Datacolor Inc (817) 719-0224 CAD_RETECtxrrcomMark FreshwaterCAD RETECreg 2014 Vice-ChairLansco Colors(330) 526-8833markpigmentscom
Nathan KarszesCAD RETECreg 2014 Technical Program Co-ChairNubiola Corporation(770) 527-2409nkarszesnubiolacomBrenda MullinsCAD RETECreg2014 Technical Program Co-ChairClariant Corporation(678) 237-2975 brendamullinsclariantcom
SPE CAD NEWS Summer 2014 page 18 wwwspecadorg
LAE
HA WORK AROU
ND
YOU
AND YOUR HEDULE
FOR MORE INFORMATION Program Professor
4195592459 866ATTERRA ext 2459jprzybylskiterraedu
OWAAHHAH
EEEA
DN
UOO
U
RRO
AARKK ARRKO
(online) courses to students who may reside too fprogram is its ability to provide
eature of the Te fy distinctiverA v
(online) courses to students who may reside too fdistance learningrdquoldquoprogram is its ability to provide
ra State plasticsereature of the T
e learned on the job This is a ghavpeople with industrcoloring of plastics These courses are also g
ar(online) courses to students who may reside too fdistance learningrdquo
ra State plastics
ood oppore learned on the job This is a gxperience since many epeople with industr
coloring of plastics These courses are also g
AL
HHRUUROOU
YYODNND
AAN
ortunity food oppory of themxperience since man
orood fcoloring of plastics These courses are also g
UOY
D
EELLEUULDDUEEDHHE
tificate program It is a relativmembers of our industr
y of the newcan benefit manbackground One aspect of T
new hire ff new hires etc) that havsales stafe all know people WWe all know people within the industr
ell as locall as wyy as wgloballlearning program has successfull
ening classroom activities This distancetime day or evremont Ohio campus to parfrom the F
(online) courses to students who may reside too f
y low-costeltificate program It is a relativy is this internet-based three-members of our industr
-educated or undererr or undery of the news program thatra Statersquoer aspect of T Ter
e no color education new hires etc) that havy (technicianse all know people within the industr
earseral yor sev fyy fell as localled studentsvy serlearning program has successfull
ening classroom activities This distanceticipate in full-remont Ohio campus to par
(online) courses to students who may reside too f
benefits including Stude dayy Students completing this cer
them to learn the theore learned on the job This is a ghav
y low-costy is this internet-based three-
-educateds program that
e no color educationy (technicians
ed studentsening classroom activities This distance
ticipate in full-ar(online) courses to students who may reside too f
benefits includingtificate can e Students completing this cer
y behind what they do evthem to learn the theorood oppore learned on the job This is a g
xpecttificate can eyery behind what they do ev
ortunity food oppor
o Cion t o toducIntr
o Pion t o toducIntr
of the Coloring of Plastics industrone wyor ane fknowledg
ollowing three courses provide solid backgroundThe f
ywhere on their schedulecomplete anxible program that the emploel fleno-trav
tificate program It is a relativcourse cer
o Color
icso Plast
yof the Coloring of Plastics industry segmentsorking in the manone w
ollowing three courses provide solid background
ywhere on their scheduleee canyxible program that the emplo
y low-costeltificate program It is a relativ
y segmentsollowing three courses provide solid background
ee cany low-cost
ered Spring 2015 (JfOfall 2014 (Aered FfOf
Books Approees $450 Ohio studentsF
Section VL
y 12 ndash May 7)anuarered Spring 2015 (Jugust 20 ndash December 12)all 2014 (A
y $200ximatelBooks Appro-st$700 out-of f-statees $450 Ohio studentso Pion t to PlasttoducIntrPET 1100Section VL
y 12 ndash May 7)ugust 20 ndash December 12)
etatte(3 Credits)icso Plast
technicians and others to learn more about thematchers quality control technicians production
cellent opporxCourses are an e
or Plasants f o Color
o Cion t o toducIntr
technicians and others to learn more about thematchers quality control technicians production
er coloror newtunity fcellent oppor
icsor Plast
o Color
technicians and others to learn more about thematchers quality control technicians production
er color
ered Spring 2015 (JfOfBooks Approees $600 Ohio studentsF
Section VL
ered Spring 2015 (JfOfall 2014 (Aered FfOf
Books Approees $450 Ohio studentsF
Section VL
ered Spring 2015 (JfOf
y 12 ndash May 7)ered Spring 2015 (Jy $150ximatelBooks Appro
-st$900 out-of f-statees $600 Ohio studentsor Plaants f for PlastPET 2320 ColorSection VL
y 12 ndash May 7anuarered Spring 2015 (Jugust 20 ndash December 12)all 2014 (A
y $200ximatelBooks Appro-st$700 out-of f-statees $450 Ohio studentso Cion t to ColortoducIntrPET 1240Section VL
y 12 ndash May 7)anuarered Spring 2015 (J
y 12 ndash May 7)
etatte (4 Credits)icsor Plast
)y 12 ndash May 7ugust 20 ndash December 12)
etatte (3 Credits)o Color
y 12 ndash May 7)
technicians and others to learn more about the
4195592459
FOR M
aedu
technicians and others to learn more about the
erritylskjprzybxt 2459 eARRTETAAT866
rofessoram Progrram PP NOTIORMAATIFNIEORREFOR M
xt 2459
technicians and others to learn more about the
rofessor
ered Spring 2015 (JfOf
y the Office of Print Production of TSCProduced b
y 12 ndash May 7)anuarered Spring 2015 (J
C 032614y the Office of Print Production of TSC
y 12 ndash May 7)
For more informationclick here
SPE CAD NEWS Summer 2014 page 19 wwwspecadorg
M
September 26 2014 ndash 500pm EDT
A SPE ANTECreg
T Because of this the p Please make a note of this significant change Y
We would consider any paper related to the color andor appearance of plastic and the f
The technical track includes more traditional ANTECreg
For more i
L
P
S
E
c
E
e
u
r
i
e
l
r
c
o
e
E
E
o
o
Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom
DuPonttrade Ti-Purereg titanium dioxide
DuPont Titanium Technologies8004419485
wwwtitaniumdupontcom
The DuPont Oval DuPont trade The miracles of sciencereg and Ti-Purereg
are trademarks or registered trademarks of EI du Pont de Nemours and Company
POLYMERS LIGHT amp SCIENCE
Polymers Light and the Science of TiO2
BTitanium Dioxide BRutile amp Anatase
BHigh Performance Organic PigmentsB DPP Reds HP Yellows
B PVC AdditivesB Lubricants amp Stabilizers
364 Johnny Mercer Blvd B-7 294 - Savannah GA 31410Tel (912)507-8972 - lwaltersagrofertinccom
wwwagrofertinccom
World Leader in EffectPigments
One International PlazaSuite 300Philadelphia PA 19113(888) 367-3275
wwwemdchemicalscom
A Complete Line of DyestuffsInorganic Pigments and
Organic Pigments forPlastics amp Fibers
LANXESS Corporation111 RIDC Park West Drive 1-800-526-9377Pittsburgh PA 15275-1112 wwwlanxesscom
World Leaders in Ultramarine PigmentswUltramarine Blue wUltramarine VioletwChrome Oxide Green wLead Chromate
wZinc Ferrite wIron Oxide
Phone 77027788196369 Peachtree Street Fax 7702778809Norcross GA 30071 Toll Free 8008866981wwwnubiolacom
We create chemistry for plastics
f
eate chemistry for plastics
basfcomplastic-additiveswww
your plastic applicationsovide solutions for all ofand other additives pr
Our UV light stabilizers antioxidants nucleatorsfect and functional pigments efneeds with color r ef
BASF helps meet your style and functionality
e crWWe cr
eate chemistry for plastics
1 800 431-2360Florham Park NJ
venue100 Park A AvenueBASF Corporation
ovide solutions for all ofOur UV light stabilizers antioxidants nucleators
fect and functional pigmentsBASF helps meet your style and functionality
Color Software ExpertsSince 1986
Quality Control Formulationamp Instrument Profiling
Visit our website and color blogwwwcyberchromeusacom
CyberChrome Inc3642 Main Street tStone Ridge NY 12484
PH 845-687-2671
wwwbasf
Color Concentrates and Single Pigment Dispersionsfor all Thermoplastic Polymers
Corporate Offices400 Old Dublin PikeDoylestown PA 18901(215) 345-6550
Operations amp Research Center2755 Bergey RoadHatfield PA 19440(215) 997-2221wwwpenncolorcom
SPE CAD NEWS Summer 2014 page 16 wwwspecadorg
SPE CAD NEWS Summer 2014 page 17 wwwspecadorg
Special thanks to our our Speakers Sponsors Exhibitors and Participants for your contributions to this yearrsquos CAD RETECreg 2014
Earl Balthazar III CAD RETECreg 2014 Conference Chair Datacolor Inc (817) 719-0224 CAD_RETECtxrrcomMark FreshwaterCAD RETECreg 2014 Vice-ChairLansco Colors(330) 526-8833markpigmentscom
Nathan KarszesCAD RETECreg 2014 Technical Program Co-ChairNubiola Corporation(770) 527-2409nkarszesnubiolacomBrenda MullinsCAD RETECreg2014 Technical Program Co-ChairClariant Corporation(678) 237-2975 brendamullinsclariantcom
SPE CAD NEWS Summer 2014 page 18 wwwspecadorg
LAE
HA WORK AROU
ND
YOU
AND YOUR HEDULE
FOR MORE INFORMATION Program Professor
4195592459 866ATTERRA ext 2459jprzybylskiterraedu
OWAAHHAH
EEEA
DN
UOO
U
RRO
AARKK ARRKO
(online) courses to students who may reside too fprogram is its ability to provide
eature of the Te fy distinctiverA v
(online) courses to students who may reside too fdistance learningrdquoldquoprogram is its ability to provide
ra State plasticsereature of the T
e learned on the job This is a ghavpeople with industrcoloring of plastics These courses are also g
ar(online) courses to students who may reside too fdistance learningrdquo
ra State plastics
ood oppore learned on the job This is a gxperience since many epeople with industr
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orood fcoloring of plastics These courses are also g
UOY
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ening classroom activities This distancetime day or evremont Ohio campus to parfrom the F
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e no color education new hires etc) that havy (technicianse all know people within the industr
earseral yor sev fyy fell as localled studentsvy serlearning program has successfull
ening classroom activities This distanceticipate in full-remont Ohio campus to par
(online) courses to students who may reside too f
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them to learn the theore learned on the job This is a ghav
y low-costy is this internet-based three-
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benefits includingtificate can e Students completing this cer
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xpecttificate can eyery behind what they do ev
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ollowing three courses provide solid background
ywhere on their scheduleee canyxible program that the emplo
y low-costeltificate program It is a relativ
y segmentsollowing three courses provide solid background
ee cany low-cost
ered Spring 2015 (JfOfall 2014 (Aered FfOf
Books Approees $450 Ohio studentsF
Section VL
y 12 ndash May 7)anuarered Spring 2015 (Jugust 20 ndash December 12)all 2014 (A
y $200ximatelBooks Appro-st$700 out-of f-statees $450 Ohio studentso Pion t to PlasttoducIntrPET 1100Section VL
y 12 ndash May 7)ugust 20 ndash December 12)
etatte(3 Credits)icso Plast
technicians and others to learn more about thematchers quality control technicians production
cellent opporxCourses are an e
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er coloror newtunity fcellent oppor
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Section VL
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Section VL
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y 12 ndash May 7)ered Spring 2015 (Jy $150ximatelBooks Appro
-st$900 out-of f-statees $600 Ohio studentsor Plaants f for PlastPET 2320 ColorSection VL
y 12 ndash May 7anuarered Spring 2015 (Jugust 20 ndash December 12)all 2014 (A
y $200ximatelBooks Appro-st$700 out-of f-statees $450 Ohio studentso Cion t to ColortoducIntrPET 1240Section VL
y 12 ndash May 7)anuarered Spring 2015 (J
y 12 ndash May 7)
etatte (4 Credits)icsor Plast
)y 12 ndash May 7ugust 20 ndash December 12)
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y 12 ndash May 7)
technicians and others to learn more about the
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erritylskjprzybxt 2459 eARRTETAAT866
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rofessor
ered Spring 2015 (JfOf
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y 12 ndash May 7)
For more informationclick here
SPE CAD NEWS Summer 2014 page 19 wwwspecadorg
M
September 26 2014 ndash 500pm EDT
A SPE ANTECreg
T Because of this the p Please make a note of this significant change Y
We would consider any paper related to the color andor appearance of plastic and the f
The technical track includes more traditional ANTECreg
For more i
L
P
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r
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Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom
SPE CAD NEWS Summer 2014 page 17 wwwspecadorg
Special thanks to our our Speakers Sponsors Exhibitors and Participants for your contributions to this yearrsquos CAD RETECreg 2014
Earl Balthazar III CAD RETECreg 2014 Conference Chair Datacolor Inc (817) 719-0224 CAD_RETECtxrrcomMark FreshwaterCAD RETECreg 2014 Vice-ChairLansco Colors(330) 526-8833markpigmentscom
Nathan KarszesCAD RETECreg 2014 Technical Program Co-ChairNubiola Corporation(770) 527-2409nkarszesnubiolacomBrenda MullinsCAD RETECreg2014 Technical Program Co-ChairClariant Corporation(678) 237-2975 brendamullinsclariantcom
SPE CAD NEWS Summer 2014 page 18 wwwspecadorg
LAE
HA WORK AROU
ND
YOU
AND YOUR HEDULE
FOR MORE INFORMATION Program Professor
4195592459 866ATTERRA ext 2459jprzybylskiterraedu
OWAAHHAH
EEEA
DN
UOO
U
RRO
AARKK ARRKO
(online) courses to students who may reside too fprogram is its ability to provide
eature of the Te fy distinctiverA v
(online) courses to students who may reside too fdistance learningrdquoldquoprogram is its ability to provide
ra State plasticsereature of the T
e learned on the job This is a ghavpeople with industrcoloring of plastics These courses are also g
ar(online) courses to students who may reside too fdistance learningrdquo
ra State plastics
ood oppore learned on the job This is a gxperience since many epeople with industr
coloring of plastics These courses are also g
AL
HHRUUROOU
YYODNND
AAN
ortunity food oppory of themxperience since man
orood fcoloring of plastics These courses are also g
UOY
D
EELLEUULDDUEEDHHE
tificate program It is a relativmembers of our industr
y of the newcan benefit manbackground One aspect of T
new hire ff new hires etc) that havsales stafe all know people WWe all know people within the industr
ell as locall as wyy as wgloballlearning program has successfull
ening classroom activities This distancetime day or evremont Ohio campus to parfrom the F
(online) courses to students who may reside too f
y low-costeltificate program It is a relativy is this internet-based three-members of our industr
-educated or undererr or undery of the news program thatra Statersquoer aspect of T Ter
e no color education new hires etc) that havy (technicianse all know people within the industr
earseral yor sev fyy fell as localled studentsvy serlearning program has successfull
ening classroom activities This distanceticipate in full-remont Ohio campus to par
(online) courses to students who may reside too f
benefits including Stude dayy Students completing this cer
them to learn the theore learned on the job This is a ghav
y low-costy is this internet-based three-
-educateds program that
e no color educationy (technicians
ed studentsening classroom activities This distance
ticipate in full-ar(online) courses to students who may reside too f
benefits includingtificate can e Students completing this cer
y behind what they do evthem to learn the theorood oppore learned on the job This is a g
xpecttificate can eyery behind what they do ev
ortunity food oppor
o Cion t o toducIntr
o Pion t o toducIntr
of the Coloring of Plastics industrone wyor ane fknowledg
ollowing three courses provide solid backgroundThe f
ywhere on their schedulecomplete anxible program that the emploel fleno-trav
tificate program It is a relativcourse cer
o Color
icso Plast
yof the Coloring of Plastics industry segmentsorking in the manone w
ollowing three courses provide solid background
ywhere on their scheduleee canyxible program that the emplo
y low-costeltificate program It is a relativ
y segmentsollowing three courses provide solid background
ee cany low-cost
ered Spring 2015 (JfOfall 2014 (Aered FfOf
Books Approees $450 Ohio studentsF
Section VL
y 12 ndash May 7)anuarered Spring 2015 (Jugust 20 ndash December 12)all 2014 (A
y $200ximatelBooks Appro-st$700 out-of f-statees $450 Ohio studentso Pion t to PlasttoducIntrPET 1100Section VL
y 12 ndash May 7)ugust 20 ndash December 12)
etatte(3 Credits)icso Plast
technicians and others to learn more about thematchers quality control technicians production
cellent opporxCourses are an e
or Plasants f o Color
o Cion t o toducIntr
technicians and others to learn more about thematchers quality control technicians production
er coloror newtunity fcellent oppor
icsor Plast
o Color
technicians and others to learn more about thematchers quality control technicians production
er color
ered Spring 2015 (JfOfBooks Approees $600 Ohio studentsF
Section VL
ered Spring 2015 (JfOfall 2014 (Aered FfOf
Books Approees $450 Ohio studentsF
Section VL
ered Spring 2015 (JfOf
y 12 ndash May 7)ered Spring 2015 (Jy $150ximatelBooks Appro
-st$900 out-of f-statees $600 Ohio studentsor Plaants f for PlastPET 2320 ColorSection VL
y 12 ndash May 7anuarered Spring 2015 (Jugust 20 ndash December 12)all 2014 (A
y $200ximatelBooks Appro-st$700 out-of f-statees $450 Ohio studentso Cion t to ColortoducIntrPET 1240Section VL
y 12 ndash May 7)anuarered Spring 2015 (J
y 12 ndash May 7)
etatte (4 Credits)icsor Plast
)y 12 ndash May 7ugust 20 ndash December 12)
etatte (3 Credits)o Color
y 12 ndash May 7)
technicians and others to learn more about the
4195592459
FOR M
aedu
technicians and others to learn more about the
erritylskjprzybxt 2459 eARRTETAAT866
rofessoram Progrram PP NOTIORMAATIFNIEORREFOR M
xt 2459
technicians and others to learn more about the
rofessor
ered Spring 2015 (JfOf
y the Office of Print Production of TSCProduced b
y 12 ndash May 7)anuarered Spring 2015 (J
C 032614y the Office of Print Production of TSC
y 12 ndash May 7)
For more informationclick here
SPE CAD NEWS Summer 2014 page 19 wwwspecadorg
M
September 26 2014 ndash 500pm EDT
A SPE ANTECreg
T Because of this the p Please make a note of this significant change Y
We would consider any paper related to the color andor appearance of plastic and the f
The technical track includes more traditional ANTECreg
For more i
L
P
S
E
c
E
e
u
r
i
e
l
r
c
o
e
E
E
o
o
Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom
SPE CAD NEWS Summer 2014 page 18 wwwspecadorg
LAE
HA WORK AROU
ND
YOU
AND YOUR HEDULE
FOR MORE INFORMATION Program Professor
4195592459 866ATTERRA ext 2459jprzybylskiterraedu
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For more informationclick here
SPE CAD NEWS Summer 2014 page 19 wwwspecadorg
M
September 26 2014 ndash 500pm EDT
A SPE ANTECreg
T Because of this the p Please make a note of this significant change Y
We would consider any paper related to the color andor appearance of plastic and the f
The technical track includes more traditional ANTECreg
For more i
L
P
S
E
c
E
e
u
r
i
e
l
r
c
o
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Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom
SPE CAD NEWS Summer 2014 page 19 wwwspecadorg
M
September 26 2014 ndash 500pm EDT
A SPE ANTECreg
T Because of this the p Please make a note of this significant change Y
We would consider any paper related to the color andor appearance of plastic and the f
The technical track includes more traditional ANTECreg
For more i
L
P
S
E
c
E
e
u
r
i
e
l
r
c
o
e
E
E
o
o
Color amp Appearance DivisionCALL FOR PAPERS
ANTECreg2015Conference Dates March 23 ndash 25 2015Orange County Convention Center
Orlando Florida USA
Paper Submission Deadline September 26 2014 ndash 500pm EDT
ANTECreg is the worldrsquos largest plastics technical conference SPE ANTECreg 2015 will co-locate once again with SPIrsquosNPE 2015 in Orlando FL USA at the Orange County Convention Center The conference will take place early thisyear and is March 23 ndash 25 2015 Because of this the paper submission deadline is earlier than usual Please makea note of this significant change Your paper even in draft form MUST be submitted by that deadline to be includ-ed in the program
The Color amp Appearance Division will be holding our annual technical sessions during this conference and wouldlike to encourage you and your company to participate by presenting a paper We would consider any paper relat-ed to the color andor appearance of plastic and the following categories would be typical topics
Plastics industry professionals who submit papers at ANTECreg2015 have a choice between two tracks technical orcommercial The technical track includes more traditional ANTECreg papers which address new technologies andtechniques currently in development in the plastics industry The commercial track is for papers that speak to com-mercial applications of these technologies and techniques and can be similar to a case study
Papers can be submitted on the ANTECreg website at httpantec2015abstractcentralcomFor more information visit the site or contact Bruce Mulholland at (859) 525-4756
Bruce MulhollandANTECreg 2015 CAD Technical Program Chair(859) 525-4756brucemulhollandcelanesecom
Color Trends Materials (colorants additives and plastics)Decorative or Special Effects Property RetentionDurabilityColor Measurement Troubleshooting or Innovation in the Color AreaColor Matching Techniques Regulatory IssuesInstrumentationTest MethodsQuality Control Processing and EquipmentStabilization of Color Other ColorAppearance Related Topics
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom
SPE CAD NEWS Summer 2014 page 20 wwwspecadorg
OFFICERSChairmanBetty Puckerin 812-466-9828Ampacet CorporationBettypuckerinxxxampacetcom
Chair-ElectJeff Drusda 570-668-8321 Silberline Manufacturing Co Incdrusdajxxxsilberlinecom
Finance ChairBrenda Mullins 678-237-2975Clariant Corporation Brendamullinsxxxclariantcom
Immediate Past ChairmanAnn Smeltzer 412-298-4373Clariant Corporationannsmeltzerxxxclariantcom
CouncilorSandra Davis 302-999-2540DuPontsandrapdavisxxxdupontcom
TreasurerBruce Mulholland 859-525-4756Ticonabrucemulhollandxxxticonacom
SecretaryCheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2017Thomas Charyil 914-785-3819BASFthomaschirayilxxxbasfcom
Sharon Ehr 616-494-7577Uniform Colorsehrxxxuniformcolorcom
Steve Esker 614-679-4677Paramount Colors Incsteveeskerxxxhotmailcom
Mark Freshwater 330-526-8833Lansco Colorsmarkxxxpigmentscom
Steve Goldstein 508-829-3918Clariant Corpstevengoldsteinxxxclariantcom
Jamie Przybylski 419-559-2459Terra Community Collegejprzybylskixxxterraedu
Austin Reid 228-255-2362DuPontAustinhreid-jrxxxusadupontcom
Mark Tyler 859-372-3221Ticonamarktylerxxxticonacom
Pete Zillito 2016522046Sudarshan North Americapzillittoxxxsudarshancom
DIRECTORS until 2015Earl Balthazar 817-719-0224DataColor ebalthazarxxxdatacolorcom
Alan Bodi 419-515-0578Uniform ColorAlanbodixxxuniformcolorcom
Hal Button 330-535-2100Akrochemhalbuttonxxxakrochemcom
Jack Ladson 267-981-7112Color Science Consultancyjackladsonxxxverizonnet
Frank Lavieri 401-461-4100Lansco ColorsFrankxxxPigmentscom
Bruce Mulholland 859-525-4756CelaneseBruceMulhollandxxxcelanesecom
George Rangos 724-229-5371Ferro Corporationrangosgxxxferrocom
Sharyl Reid 864-968-2426A Schulman Incsharyl_reidxxxusaschulmancom
Cheryl Treat 419-217-0862A Schulman IncCheryl_treatxxxusaschulmancom
DIRECTORS until 2016Scott Aumann 912-210-0175EMD Chemicalsscottaumannxxxedmmilliporecom
Doreen Becker 508-756-0002 x264A Schulman CCNEdbeckerxxxecmplasticscom
Paul Bykowski 219-331-6981GB Consultingpaulbykowskixxxhotmailcom
Scott Heitzman 513-681-5950Sun Chemical Corporation scottheitzmanxxxsunchemicalcom
Nathan Karszes 770-527-2409Nubiolankarszesxxxnubiolacom
Tracy Phillips 770-995-0887Uniform Colortlphillipsxxxuniformcolorcom
Tom Rachal 405-775-5014Tronox LLCtomrachalxxxtronoxcom
Jim Rediske 914-785-2203BASFjimrediskexxxbasfcom
Brian West 865-425-2113Techmer PM LLCbwestxxxtechmerpmcom
Please note The email addresses above contain xxx which should be ignored when actually emailing The purpose of the triple ldquoxrdquo is torender the automated spam grabbers useless
SPE Headquarters203-775-0471 phonecustomerservicexxx4speorg
ACE Chair Roberto TodescortodescoxxxinternationalcomNational Plastics Center
OTHER USEFUL CONTACTS
Color amp Appearance Division Board of Directors
6 Berkshire Blvd Suite 306Bethel CT 06801 USA
CAD Newsletter PublicationPeacock Graphics Inc847-341-4066peacockgfxaolcom