chapter 17 section 2 reaction rate p. 568-579 1 reaction kinetics chapter 17 modern chemistry...

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Chapter 17 Section 2 Reaction Rate Chapter 17 Section 2 Reaction Rate p. 568-579 p. 568-579 1 Reaction Reaction Kinetics Kinetics Chapter 17 Chapter 17 Modern Modern Chemistry Chemistry Sections 1 & 2 Sections 1 & 2 The Reaction The Reaction Process Process Reaction Rate Reaction Rate

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Chapter 17 Section 2 Reaction Rate p Chemical Kinetics: The area of chemistry that is concerned with reaction rates and reaction mechanisms. The change in concentration of a reactant (or a product) per unit time as a reaction proceeds is called the reaction rate. Rate of Reaction -  [reactant a]  time  [product b]  time or

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Page 1: Chapter 17 Section 2 Reaction Rate p. 568-579 1 Reaction Kinetics Chapter 17 Modern Chemistry Sections 1 & 2 The Reaction Process Reaction Rate

Chapter 17 Section 2 Reaction Rate p. 568Chapter 17 Section 2 Reaction Rate p. 568-579-579

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Reaction Reaction KineticsKinetics

Chapter 17 Chapter 17 Modern Modern

ChemistryChemistry

Sections 1 & 2Sections 1 & 2The Reaction The Reaction

ProcessProcessReaction RateReaction Rate

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Reaction Reaction RateRate

Section 17.2Section 17.2

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Chemical Kinetics: The area of chemistry that is concerned with reaction rates and reaction mechanisms.

The change in concentration of a reactant (or a product) per unit time as a reaction proceeds is called the reaction rate.

Rate of ReactionRate of Reaction

- [reactant a] time

[product b] timeor

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Any change in reaction conditions that affects the collision frequency, the collision efficiency, or the collision energy affects the reaction rate.

IF COLLISIONS ARE INCREASE, THE RATE WILL INCREASE.

Rate of ReactionRate of Reaction

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Nature of Nature of ReactantsReactants

TemperatureTemperature Surface AreaSurface Area ConcentrationConcentration CatalystCatalyst

Rate Influencing FactorsRate Influencing Factors

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An increase in temperature increases the average kinetic energy of the particles.

This increases the number of collisions and the energy of collision.

To be effective, the energy of the collisions must be equal to or greater than the activation energy.

At higher temperatures, more particles possess enough energy to form the activated complex.

TemperatureTemperature

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Plop, PlopPlop, PlopFizz, FizzFizz, Fizz

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Breaking and making bonds cause a reaction. So….

Reaction rate is dependant on the type of bond and the molecule it’s in.

It cannot be adjusted to improve reaction rate.

Nature of ReactantsNature of Reactants

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In heterogeneous reactions, the reaction rate depends on the area of contact of the reaction substances.

An increase in surface area, increases the rate of heterogeneous reactions.

Surface AreaSurface Area

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To increase surface area, break the substance up into smaller pieces.

Surface AreaSurface Area

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Lycopodium Lycopodium Powder Powder ExplosionExplosion

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Increasing the concentration increases the number of collisions.

As the number of molecules in the system increases, so does the total number of possible collisions between them.

If the number of effective collisions increases, the rate increases.

ConcentrationConcentration

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GummyGummyBearBearSacrificeSacrifice

http://www.woodrow.org/teachers/chemistry/institutes/1988/gummybear.htm

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A catalyst is a substance that changes the rate of a chemical reaction without itself being permanently consumed.

How a Catalyst Worksprovides an alternative energy pathway

or reaction mechanismmay form an alternative activated

complex that requires a lower activation energy

CatalystCatalyst

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A catalyst is not included as a reactant or product – it is written above the arrow.

Two Types of CatalystsHomogeneous Catalyst- A catalyst that is

in the same phase as all the reactants and products in a reaction system.

Heterogeneous Catalyst – A catalyst in a different form than that of the reactants

CatalystCatalyst

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TheTheHeterogeneousHeterogeneousCatalyticCatalyticDecomposition of Decomposition of AcetoneAcetone

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Ch 17 Sec 2 HomeworkCh 17 Sec 2 Homework

Ch 17 Review Sheet

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Ch 17 Sec 2 HomeworkCh 17 Sec 2 Homework

Prepare for Rate of a Chemical Reaction Lab on page 586

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Insert Holt: Visualizing Matter Disc 2

TEMPERATURE

SURFACE AREA

DECREASING RATE

CONTACT OFREACTANTS

CONCENTRATION