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    65

    Chapter 4

    First Law of Thermodynamics

    The first law of thermodynamics is simply the conservation of energy principle

    and can be defined as, the energy can be neither created nor destroyed, it can only

    change from one form to other with certain process such as, combustion, chemical and

    mechanical. The conservation of energy principle may be expressed as follows: the net

    change (increased or decreased) in the total energy of the system during a process is

    equal to the difference between the total energy entering and the total energy leaving the

    system.

    =

    systemtheofenergy

    totalin theChange

    systemtheleaving

    energyTotal

    systemtheentering

    energyTotal

    The above relation is often referred to as the energy balance. The energy is a property

    and the value of a property does not change unless the state of the system changes. Also,

    the first law of thermodynamics is called the law of the conservation of heat and work

    undergoing a cycle, and then for a change of state of a system. Many measurements

    were made during a cycle (control mass) for various amounts of work and heat, and the

    results were compared. The results were always proportional and the observations led to

    the formulation of the first law of thermodynamics as,

    = WQ

    The symbol, Q , which is called the cyclic integral of the heat transfer, represents the

    net heat transfer during the cycle, and W , the cyclic integral of the work, represents

    the net work during the cycle.

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    66

    The First Law of Thermodynamics of a Control Mass

    We now considered the first law of thermodynamics for a control mass that undergoes a

    change of state. We begin by introducing of the energy property, which is given by the

    symbolE. Consider a system that undergoes a cycle, in which it changes from state 1 to

    state 2 by process A, and returns from state 2 to state 1 by process B as shown in Fig. 4-

    1. Considering the two separate processes, we have,

    +=+1

    2

    2

    1

    1

    2

    2

    1 BABA WWQQ

    Now consider another cycle in which the control mass change from state 1 to state 2 by

    process C and returns to state 1 by process B, as before. For this cycle we can write,

    +=+1

    2

    2

    1

    1

    2

    2

    1 BcBC WWQQ

    Subtracting the two equations, we get,

    =2

    1

    2

    1

    2

    1

    2

    1 CACA WWQQ

    or, by rearranging,

    =2

    1

    2

    1)()( CA WQWQ

    Fig. 4-1 Control mass undergoing a cycle

    Since A and C represents arbitrary processes between state 1 and 2, the quantity

    WQ is the same for all processes between state 1 and state 2. Therefore,

    WQ depends only on the initial and final states and not on the path. We conclude

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    67

    that this is a point function and this property is the energy of the mass and is given by

    the symbolE. Thus we can write,

    WdEQ

    dEWQ

    +=

    = or

    BecauseEis a property, its derivative is written dE. The above equation is integrated

    from an initial state 1 to a final state 2, we have,

    121212 WEEQ +=

    The determination of the energy change of a system during a process involves the

    evaluation of the energy of the system at the beginning and at the end of the process as

    follows,

    12 EEEEE initialfinalsystem ==

    The energy can be exist in various forms such as internal (sensible, latent, chemical, and

    nuclear), kinetic, potential, electric, and magnetic, and their sum is the total energyEof

    a system. In the absence of electric, magnetic and surface tension effects ( i.e., for

    simple compressible systems), the change in total energy of a system during a process is

    the sum of the changes in its internal, kinetic, and potential energies and can be

    expressed as,

    PEKEUE ++=

    Where,

    )(

    )vv(2

    1

    )(

    12

    2

    1

    2

    2

    12

    zzmgPE

    mKE

    uumU

    =

    =

    =

    or

    ++= )()vv(

    2

    1)( 12

    2

    1

    2

    212 zzguumE

    Most of engineering systems are stationary and no change of its velocity and elevation

    during process, it means that, 0== PEKE , and the total energy change reduces to

    UE = . The energy can be transferred to or from the system in three forms: Heat,

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    68

    WorkandMass Flow. For a closed system or fixed mass, the only two forms of energy

    are the heat and work interaction.

    Heat Transfer, Q

    The heat transferred to a system (heat gain) increases the internal energy of the

    system, and the heat transferred from a system (heat loss) decreases the internal energy

    of a system.

    Work, W

    The energy interaction that is not caused by a temperature difference between a

    system and surroundings is called work. A rising piston, rotating shaft, and electrical

    wire crossing the system boundaries are work done.

    Energy Balance of Closed System

    Noting that the energy can be transferred in the forms of heat and work and the

    net transfer of a quantity is equal to the difference between the amounts transferred inlet

    and outlet, and the energy balance can be defined as,

    systemoutinoutin EWWQQ = )()(

    The first law of thermodynamics for closed system and fixed boundary (rigid tank) as

    shown in Fig. 4-2, and the kinetic and potential energies are negligible, 0== PEKE ,

    then the thermodynamics first law relation becomes,

    21 muWQmuWQ ooii ++=++

    or )( 12 uumWQ =

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    Fig. 4-2 Closed system and fixed boundary (stationary).

    For no interaction work done and heating process, the first law takes,

    )( 12 uumQ =

    For cooling process, the first law takes,

    )( 12 uumQ =

    The first law of thermodynamics for closed system and moving boundary as shown in

    Fig. 4-3, and the kinetic and potential energies are negligible, 0== PEKE , then the

    thermodynamics first law relation becomes,

    )()( 2211

    2211

    PvumWQPvumWQ

    PVmuWQPVmuWQ

    ooii

    ooii

    +++=++++++=+++

    Fig. 4-3 Closed system and moving boundary (frictionless piston-cylinder).

    or )( 12 hhmWQ =

    For no interaction work done and heating process, the first law takes,

    )( 12 hhmQ =

    For cooling process, the first law takes,

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    70

    )( 12 hhmQ =

    Cooling process with work done from paddle wheelA rigid tank contains a hot fluid that is being stirred by a paddle wheel as shown in Fig.

    4-4. The tank is not insulated and heat transferred to surrounding, the kinetic and

    potential energies are negligible, 0== PEKE , then the first law becomes,

    )( 12 uumWQ =

    Applying the sign role or the directions of heat and work in the system, the first law

    takes the following form,

    )(

    )()(

    12

    12

    uumQW

    uumWQ

    =

    =

    Or applying the sum of energy at inlet that is equal the sum of energy at outlet,

    21 muWQmuWQEE ooiioi ++=++=

    There is no heat transfer inter the system, Qi=0, and no work done leave the system,

    Wo=0,.

    21 muQmuW oi +=+ or the form of, )( 12 uumQW outinpw =

    or )( 12 uumQW =

    Fig. 4-4 Paddle wheel stirred fluid in closed system

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    Electric Heating of Fluid in Insulated Rigid Tank

    A rigid tank contains fluid that is being heat by an electric heater as shown in Fig.

    4-5. The tank is insulated and no heat transferred to surrounding, the kinetic and

    potential energies are negligible, 0== PEKE , then the thermodynamics first law

    becomes,

    )( 12 uumWQ =

    Applying the sign role or the directions of heat and work in the system, the first law

    takes the following form,

    )(

    )(

    )()(

    12

    12

    12

    uumtIV

    uumW

    uumW

    e

    e

    =

    =

    =

    Where, Vis the volt,Iis the current, and tis the heating time.

    Fig. 4-5 Electric heating process

    Energy Balance of Steady-flow System

    A large number of engineering devices such as turbine, compressor, and nozzles

    are operating for long period of time under the same conditions, (steady-flow process).

    During the steady-flow process, no intensive or extensive properties within the control

    volume change with time. Thus, the volume V, the mass m, and the total energy content

    Eof the control volume remain constant as shown in Fig. 4-6.

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    Fig. 4-6 Steady-flow process and control volume

    As a result, the boundary work is zero for steady flow system (because the volume is

    constant in control volume Vcv= constant.), and the sum of mass or energy entering the

    control volume must be equal to the sum of mass or energy leaving the control volume

    (since mcv= constant and Ecv=constant). Then, the rate of the general energy and mass

    balance for steady flow process as follows,

    and, outinoutin mmEE &&&& ==

    or 0and0 == CVCV mE

    During the steady flow process, the fluid properties at inlet or exit remain constant.

    Also, the rate of heat and work interaction between a steady flow system and its

    surrounding do not change with time. For steady flow process, there are some

    applications has multi-inlet and multi-exit as shown in Fig. 4-7.

    Fig. 4-7 Steady flow process in general

    So, the first law of thermodynamics for steady flow process becomes for that case,

    )2

    v()

    2

    v(

    22

    o

    o

    ooooi

    i

    iiii gzhmWQgzhmWQ ++++=++++ &&&&&&

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    For single stream flow, one inlet and one exit as shown in Fig. 4-8, the first low of

    thermodynamics becomes,

    Fig. 4-8 Steady flow process for one inlet and one exit

    )2

    v()

    2

    v(

    22

    o

    o

    ooooi

    i

    iiii gzhmWQgzhmWQ ++++=++++ &&&&&&

    And, )2

    v()

    2

    v(

    22

    o

    o

    oooi

    i

    iii gzhmWQgzhmWQ ++++=++++ &&&&&&

    In such cases, it is common practice to assume that the heat to be transferred into

    the system (heat input) at a rate ofQ& , and work produced by the system (work output) at

    a rate of W& and the inlet and outlet are denoted by subscripts 1 and 2. The first law of

    thermodynamics for single stream steady flow systems becomes,

    )](2

    vv)[(

    )]2

    v()

    2

    v[(

    12

    2

    1

    2

    212

    1

    2

    112

    2

    22

    zzghhmWQ

    gzhgzhmWQ

    +

    +=

    ++++=

    &&&

    &&&

    For specific quantity, the energy balance on a unit mass basis defined as,

    )(2

    vv)( 12

    2

    1

    2

    212 zzghhwq +

    +=

    Some Steady Flow Applications

    Many engineering devices operate under the same conditions for long periods of

    time and never change throughout the operating time such as, turbines, compressors,

    pumps, boilers, heat exchangers, nozzles and diffusers and these devices can be

    analyzed as steady flow processes.

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    Turbine

    A turbine is a rotary machine which used in thermal power station as shown in Fig. 4-9,

    whose purpose is the production of shaft work by expansion the fluid. The work done in

    the turbine is positive since it done by the fluid on the moving blades to causing

    rotational velocity of the turbine shaft.

    Fig. 4-9 Adiabatic turbine process

    The energy balance ofo this steady-flow system is,

    )](

    2

    vv)[( 12

    2

    1

    2

    212 zzghhmWQ +

    += &&&

    If the process occurred in the turbine which insulated fro surrounding (adiabatic process,

    0=Q& ) we get,

    kWzzghhmWPower )](2

    vv)[( 12

    2

    1

    2

    212 +

    +== &

    For some cases, by neglecting the kinetic and potential energy, we obtain,

    kWhhmWPower )( 12 == &

    Compressors and Pumps

    The purpose of compressors (gas) or pumps (liquid) is the same, to increase the pressure

    of a fluid by adding shaft work as shown in Fig. 4-10.

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    Fig. 4-10 Compressor and pump process

    For gas compressors, by neglecting the kinetic energy at inlet only and potential energy

    at inlet and outlet, and some heat transferred to the surrounding, we obtain,

    ]v2

    1)[(

    or]v2

    1)[()(

    2

    212

    2

    212

    kWhhmQWpower

    hhmWQ

    outin ++==

    +=

    &&&

    &&&

    For ideal gas, and the compression is adiabatic process, and neglecting the kinetic

    energy, we get

    kWTTCmpower

    kWhhmWpower

    aveP

    in

    )(

    )(

    12

    12

    =

    ==

    &

    &&

    For pumps, by neglecting the kinetic and potential energy,

    )( 12 kWhhmWpower in == &&

    For pumps, the increasing pressure is usually occurred at constant temperature, and the

    liquid temperature does not change throughout the process. So, the change only in the

    pressure and the steady flow energy equation for pumps can be write as,

    )( 12 kWPPvmWpower in == &&

    Nozzles and Diffusers

    Nozzles and diffusers are usually utilized in jet engine, rockets and air craft. The nozzle

    is a device that increases the velocity of a fluid. A diffuser is a device that increases the

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    pressure of the fluid. That is, nozzles and diffuser perform opposite tasks as shown in

    Fig. 4-11.

    Fig. 4-11 Nozzle and diffuser

    The energy balance for this steady flow system which no heat transferred, no work and

    potential energy is zero, we get for nozzle,

    2

    v

    0inlet vatvelocityfluid2

    vv)(0

    2

    2

    12

    1

    2

    1

    2

    212

    =

    +=

    hh

    hh Q

    For diffuser,

    2

    v

    0outlet vatvelocityfluid2

    vv)(0

    2

    112

    2

    2

    1

    2

    212

    +=

    +=

    hh

    hh Q

    Heat Exchanger

    The heat exchangers are usually used for cooling of a hot fluid inside the coil by using

    cooled fluid outside the coil as Fig. 4-12. The energy balance of heat exchanger, the

    steady flow system which no heat transferred to the surrounding, no work done, and

    kinetic and potential energies are negligible. The heat rejected from hot fluid, 1m& equal

    to the heat added to the cooled fluid 2m& , then we get,

    )()( 342121 hhmhhm = &&

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    Fig. 4-12 Heat exchanger process

    Throttling ProcessA throttling process occurs when a fluid flowing in a line suddenly encounters a

    restriction in the flow passage such as, valves and capillary tubes as shown in Fig. 4-13.

    Fig. 4-13 Throttling process in valves and capillary tubes

    For throttling process, the steady flow system which no heat transferred, no work done,

    and kinetic and potential energies are negligible, we get,

    21 hh =

    Usually the throttling process is called constant enthalpy process.

    Mixing Process

    Fig. 4-14 Mixing chamber process

    In engineering applications, mixing two streams of fluid in a certain system are occurred

    without heat transferred to surrounding, no work done, and kinetic and potential

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    78

    energies are negligible as shown in Fig. 4-14. The energy balance of steady flow

    process as,

    321332211 balancemassforand mmmhmhmhm &&&&&& =+=+

    Examples of First Law of Thermodynamics

    1. Is it possible to compress an ideal gas isothermally in an adiabatic piston-cylinderdevice? Explain.

    Impossible to compress an ideal gas isothermally in an adiabatic piston-cylinder

    device because during the compression process which to keep the temperature

    constant, it is necessary to remove heat from the system boundary, heat is interaction

    out the system.

    2. Consider two identical rooms, one with a refrigerator in it and the refrigerator door isopen, and the other without one. If all the doors and windows are closed, will the

    room that contains the refrigerator be cooler or warmer than the other room? Why?

    The room which contain refrigerator is becoming warmer than the other, because

    electric work done for the compressor is added to room, work is interaction into the

    system.

    3. A 2.5 m3rigid tank contains air at 300 kPa and 150 oC. The air is now cooled until itstemperature drops to 40

    oC. Determine (a) the final pressure in the tank and (b) the

    amount of heat transfer.

    Solution

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    kPaT

    TPP

    T

    T

    P

    P

    P

    mRT

    P

    mRT

    CV

    kgRTVPmmRTVP

    99.221423

    313300

    or,olume,constant vis21Process

    18.6)423287.0/(5.2300/,1,State

    1

    212

    2

    1

    2

    1

    2

    2

    1

    1

    111111

    ===

    ====

    ====

    kJuumQ

    kgkJTCukgkJTCu

    uumUQ

    W,

    V

    V

    096.488)714.303734.224(18.6)(

    /734.224313718.0/714.303423718.0

    airgas,-IdealFor

    )(

    0,0P.E0K.E

    boundary,fixedandvolumeclosedformicsThermodynaofLawFirst

    12

    22

    11

    12

    ===

    ======

    ==

    ===

    4. A mass of 20 kg of air in a frictionless piston-cylinder device is heated from 27 to 80oC by passing current through a resistance heater inside the cylinder. The pressure

    inside the cylinder is held constant at 400 kPa during the process, and a heat loss of

    30 kJ occurs. Determine the electric energy supplied in kWh.

    Solution

    )(

    0,

    0P.E0,K.EAssume,

    boundary,movingandsystemclosedformicsThermodynaofLawFirst

    12

    201

    hhmQQ

    WWhmWQhmWQ

    oi

    oioii

    +=

    ==++=++

    ==

    kgkJTCh P /5.301300005.1

    airgas,IdealFor

    11 ===

    kJQ

    kgkJTCh

    i

    P

    3.1095)5.301765.354(2030

    /765.354353005.122

    =+=

    ===

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    80

    kWhskWQW ie 3043.03600

    3.1095.3.1095Work,Electric ====

    5. Water is being heated in a closed vessel on top of a range while being stirred by apaddle wheel. During the process, 3000 kJ of heat transferred to the water, and 150

    kJ of heat is lost to the surrounding air. The paddle-wheel work amounts to 250 N.m,

    determine the final energy of the system if its initial energy is 200 kJ.

    Solution

    21

    201

    Energy,Final,Energy,Initial0,,

    0P.E0,K.Eboundary,Fixedsystem,closedformicsThermodynaofLawFirst

    umEumEWWWumWQumWQ

    fi

    opwioii

    ====++=++

    ==

    Q

    kJE

    QumWQumE

    f

    oiif

    25.30501502001000

    2503000

    Energy,Final 12

    =++=

    ++==

    6. A classroom that normally contains 60 peoples which one person at rest may beassumed to dissipate heat at a rate of 432 kJ/h. There are 15 light bulbs in the room,

    each with a rating of 150 W. The rate of heat transfer to the classroom through the

    walls and the windows is estimated to be 15000 kJ/h. If the room air is to be

    maintained at a constant temperature of 22oC and the supply fresh air at 35

    oC with

    volume flow rate of 10 L/s for one person is provided .Determine the number of

    window air conditioning units required if the unit cooling capacity is about of 8 kW.

    Solution

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    81

    3/13.1)27335(287.0

    100Denisty,Air

    )(capacity,Cooling

    rate,flowmassSteady

    0k,output wororinputNo,

    0P.E0,K.EAssume

    volume.controlandflowsteadymics,ThermodynaoflawFirst

    mkgRT

    P

    hhmQQ

    mmm

    WWhmWQhmWQ

    a

    oiaio

    aoi

    oiooooiiii

    =+

    ==

    +===

    ==++=++

    ==

    &

    &&&

    &&

    Units381.2

    8

    475.22

    CapacityUnit

    UnitsofNumber

    475.22/475.223600

    052.80909

    /052.809093600)475.29654.309(678.049020

    /475.296295005.1

    /54.309308005.1

    airgas,IdealFor

    /49020

    4326036001000

    1501515000

    /678.010601013.1

    22

    11

    3

    ===

    ===

    =+=

    ===

    ===

    =

    ++=++=

    ===

    o

    o

    o

    P

    P

    i

    personslightwalli

    aa

    Q

    kWskJQ

    hkJQ

    kgkJTCh

    kgkJTCh

    hkJQ

    QQQQ

    skgVm &&

    7. The steam radiator for a heating system has a volume of 20 L and is filled withsuperheated vapor at 300 kPa and 250

    oC. At this moment both inlet and exit valves

    to the radiator are closed. Determine the amount of heat that will be transferred to the

    room when the steam pressure drops to 100 kPa. Also, show the process on a P-v

    diagram with respect to saturation line.

    Solution

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    82

    wet vapor2,statevvv

    7964.0vv,100at,table,steamfrom2,State

    olume,constant vatoccuredprocessCooling

    0251.00.9764

    1020

    vmass,Steam

    07964v72728

    250,300at,vapordsuperheatetable,steamfrom1,State

    2

    211

    21

    3-

    1

    3

    11

    11

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    83

    kgmx

    CVV

    kgkJ

    xkgm

    x

    xandkPaP

    /30747.0vor,water vapsaturated,%100

    olume,constant vatoccuredprocessHeating

    /415.7957.2088181.036.417u

    uuu/30747.0)001043.0694.1(181.0001043.0v

    )vv(vv

    181.0,100at,tablesteamfrom1,State

    3

    22

    21

    2

    fg1f1

    3

    1

    fg1f1

    11

    ==

    ==

    =+=

    +==+=

    +=

    ==

    CT

    kgkJu

    kgkJkgmCT

    kgm

    o

    o

    2

    2

    g

    3

    g

    2

    3

    g2

    160

    /4.2568

    2568.40.30747601

    )/(u)/(v)(

    %100x,/30747.0vvat,table,steamsaturatedfrom2,State

    =

    =

    ===

    hrWWt

    tWW

    skJkWWVIPowerW

    kJuumW

    uumUWQ

    WQ

    ee

    ee

    e

    e

    e

    e

    48.4606088.0

    88.14183/time,Heating

    /

    /88.088.08804220

    88.14183)415.7954.2568(8)(

    )(

    work,electric,0boundary,fixedsystem,closedforamicsthermodynoflawFirst

    12

    12

    =

    ==

    =

    ======

    ===

    ==

    =

    &

    &

    &

    9. A piston-cylinder device contains 1.2 kg of N2 initially at 100 kPa and 27 oC. TheNitrogen is now compressed slowly in a polytropic process during which PV

    1.3= C

    until the volume is reduced by one-half. Determine the work done and the heat

    transfer for this process.

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    84

    Solution

    kPaV

    V

    V

    VPP

    VPVPCPV

    mVVkgkJTCu

    mV

    VmRTVP

    KTkPaP

    n

    nnn

    V

    23.2465.0

    100

    ,Polytropic2,1Process

    53424.00685.15.05.02,State/9.222300743.0

    Nofgasidealfor,0685.1

    3002968.02.1100,equation,gasidealFrom

    300,1001,State

    3.1

    1

    1

    2

    112

    2211

    3

    12

    11

    2

    3

    1

    1111

    11

    =

    =

    =

    ==

    ======

    =

    ==

    ==

    KT

    mR

    VPTmRTVP

    35.369

    2968.02.1

    53424.023.246,equation,gasidealFrom

    2

    222222

    =

    ===

    kJn

    VPVPW

    kgkJTCu V

    32.823.11

    0685.110053424.023.246

    1

    /427.27435.369743.0

    112221

    22

    =

    =

    =

    ===

    ( ) kJuumWQ

    umQumW

    umWQumWQ

    WQWWW

    io

    oi

    ooii

    iib

    15.144424.2749.222(2.132.82

    00

    0,0,ork,boundary w,

    0P.E0,K.Eboundary,movingvolume,closedamics,thermodynoflawFirst

    21

    21

    21

    021

    =+=+=

    ++=++

    ++=++

    ====

    ==

    10.Air enters an adiabatic nozzle steadily at 300 kPa, 200 oC, and 30 m/s and leaves at100 kPa and 180 m/s. The inlet area of the nozzle is 80 cm

    2. Determine (a) the mass

    flow rate through the nozzle, (b) the exit temperature of the air, and (c) the exit area

    of the nozzle.

    Solution

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    85

    222222

    22

    2

    2

    2

    22

    22

    2

    11

    11

    4

    111

    3

    1

    11

    111

    /,rate,flowMass

    99.460,/5.459atairofpropertiesgasidealFrom

    /5.459

    10002

    180

    10002

    3025.475,

    22

    nozzle,throughflowsteadyforamicsthermodynoflawfirstFrom

    /24.475,473atairofpropertiesgasidealFrom

    /5304.0301080209.2rate,flowMass

    /209.2473287.0

    300

    equation,gasidealfrom1,State

    VmAVAm

    KTkkJh

    kgkJh

    hV

    hV

    h

    kgkJhKT

    skgVAm

    mkgRT

    P

    mRTVP

    &&

    &

    ==

    ==

    =

    +=

    ++=+

    ==

    ===

    =

    ==

    =

    223

    2

    3

    2

    22

    98.3810898.3)1807558.0/(5304.0

    /7558.099.460287.0

    100

    cmmA

    mkg

    RT

    P

    ===

    =

    ==

    11.Steam at 5 MPa and 500 oC enters a nozzle steadily with a velocity of 80 m/s, and itleaves at 2 MPa and 400

    oC. The inlet area of the nozzle is 50 cm

    2, and heat is being

    lost at a rate of 90 kJ/s. Determine (a) the mass flow rate of the steam, (b) the exit

    velocity of the steam, and the exit area of the nozzle.

    Solution

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    86

    223

    2

    222222

    2

    2

    2

    22

    22

    2

    11

    4

    1

    11111

    3

    22

    22

    3

    11

    11

    953.14104953.1868.589/1512.08335.5

    /v,rate,flowMass/868.589

    8335.5

    90

    100026.3247

    10002

    808.3433,

    22

    nozzle,throughflowsteadyforamicsthermodynoflawFirst

    /8335.506857.0

    801050

    vrate,flowMass

    /1512.0v,/6.3247

    400,2at,dsuperheatetable,steamfrom2,State

    /06857.0v,/8.3433

    500,5at,dsuperheatetable,steamfrom1,State

    cmmA

    VmAVAmsmV

    VQ

    Vh

    Vh

    skgVA

    VAm

    kgmkgkJh

    CTMPaP

    kgmkgkJh

    CTMPaP

    o

    o

    o

    ===

    ===

    +

    +=

    +++=+

    =

    ===

    ==

    ==

    ==

    ==

    &&

    &

    12.Air at 80 kPa and 127 oC enters an adiabatic diffuser steadily at a rate of 6000 kg/hand leaves at 100 kPa. The velocity of the air stream is decreased from 230 to 30 m/s

    as it passes through the diffuser. Find (a) the exit temperature of the air and (b) the

    exit area of the diffuser.

    Solution

    kgkJh

    hV

    hV

    h

    kgkJhKT

    /98.426

    10002

    30

    10002

    23098.400,

    22

    nozzle,throughflowsteadyforamicsthermodynoflawfirstFrom

    /98.400,400atairofpropertiesgasidealfrom1,State

    2

    2

    2

    22

    22

    2

    11

    11

    =

    +=

    ++=+

    ==

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    87

    2

    222

    3

    2

    22

    222111

    22

    0679.0)308185.0/()3600/6000(/

    /8185.07.425287.0

    100

    rate,flowMass

    7.425,/98.426atairofpropertiesgasidealFrom

    mVmA

    mkgRT

    P

    VAVAm

    KTkgkJh

    ===

    =

    ==

    ==

    ==

    &

    &

    13.Steam flows steadily through an adiabatic turbine. The inlet conditions of the steamare 10 MPa, 450

    oC, and 80 m/s, and the exit conditions are 10 kPa, 90 percent

    quality, and 50 m/s. The mass flow rate of the steam is 12 kg/s. Determine (a) the

    change in kinetic energy, (b) the power output, and (c) the turbine inlet area.Solution

    skJVV

    mEK

    kgkJhhxhh

    xkPaP

    kgmkgkJh

    CTMPaP

    fgf

    o

    /4.2310002

    80

    10002

    5012

    22.

    /35.23458.23929.083.191)(

    %90,10atwet vaportable,steamfrom2,State

    /02975.0v,/9.3240

    450,10at,dsuperheatetable,steamfrom1,State

    222

    1

    2

    2

    22

    22

    3

    11

    11

    =

    =

    =

    =+=+=

    ==

    ==

    ==

    &

    ( ) ( )

    ( )

    223

    1

    111111

    22

    12

    21

    22

    12

    63.44104625.480/02975.012

    /v,v/rate,flowMass

    77.1010770)200

    80509.324035.2345(12

    0.,0,2

    cmmA

    VmAVAm

    MWkWW

    EPQzzgVV

    hhmWQ

    ===

    ==

    ==

    +=

    ==

    ++=

    &&

    &

    &&&&

    14.Refrigerant, R-134a enters an adiabatic compressor as saturated vapor at -20 oC andleaves at 0.7 MPa and 70 oC. The mass flow rate of the refrigerant is 1.5 kg/s.

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    88

    Determine (a) the power input to the compressor and (b) the volume flow rate of the

    refrigerant at the compressor inlet.

    Solution

    kgmkgkJh

    CTx o

    /1464.0v,/31.235

    20%100at,tablesteamfrom1,State

    3

    11

    11

    ==

    ==

    ,CompressoradiabaticthroughflowsteadyforamicsthermodynoflawFirst

    /01.307

    70,7.0atwet vaportable,steamfrom2,State

    2

    22

    kgkJh

    CTMPaP o

    =

    ==

    ( ) ( )

    ( )

    kWW

    kWhhmW

    EPK.EQzzgVVhhmWQ

    55.107PowerInput

    55.107)01.30731.235(5.1

    0.0,0,2

    12

    12

    2

    1

    2

    212

    ==

    ===

    ===

    ++=

    &

    &&

    &&&&

    15.Air enters the compressor of a gas-turbine plant at ambient conditions of 100 kPaand 27

    oC with a low velocity and exit at 1 MPa and 350

    oC with a velocity of 80

    m/s. The compressor is cooled at a rate of 1200 kJ/min, and the power input to the

    compressor is 250 kW. Determine the mass flow rate of the air through the

    compressor.

    Solution

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    89

    ,CompressorthroughflowsteadyforamicsthermodynoflawFirst

    /11.631

    623,1at,airofpropertiesgasidealfrom2,State

    /19.300

    300,100at,airofpropertiesgasidealfrom1,State

    2

    22

    1

    11

    kgkJh

    KTMPaP

    kgkJh

    KTkPaP

    ===

    =

    ==

    ( ) ( )

    ( )

    +=

    =

    +

    +=

    2

    0.,2

    2

    212

    12

    2

    1

    2

    212

    VhhmWQ

    EPzzgVV

    hhmWQ

    &&&

    &&&

    skgm

    m

    /6884.0

    10002

    80)19.30011.631()250(

    60

    1200 2

    =

    +=

    &

    &

    16.A superheated water vapor is throttled from 8 MPa and 500 oC to 6 MPa. Determinethe final temperature of steam.

    Solution

    KT

    kgkJhMPaP

    MPaPkgkJh

    hh

    kgkJh

    CTMPaP o

    08.490

    /3.3398,6at,levapor tabdsuperheateFrom

    6,/3.3398at2,State

    enthalpy,constantatoccured21processThrottling

    /3.3398

    500,8at,vapordsuperheate1,State

    2

    22

    22

    21

    1

    11

    =

    ==

    ==

    =

    =

    ==

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    90

    17.Liquid water at 300 kPa and 20 oC is heated in a chamber by mixing withsuperheated steam at 300 kPa and 300

    oC. Cold water enters the chamber at a rate of

    1.8 kg/s. If the mixture leaves the mixing chamber at 60oC, determine the mass flow

    rate of the superheated steam required.

    Solution

    CTkPaP

    kgkJhh

    CT

    hmmhmhmhm

    mmm

    o

    f

    o

    300,300atvapordsuperheate2,State

    /96.83le,water tabsaturatedFrom

    20at,watersubcooled1,State

    )(balance,Heat

    balance,Mass

    process.mixingstatesteadyFor

    22

    1

    1

    321332211

    321

    ==

    ==

    =

    +==+

    =+

    &&&&&

    &&&

    skgm

    mm

    kgkJhh

    CT

    kgkJh

    f

    o

    /1073.0

    93.251)8.1(3.306996.838.1

    /93.251le,water tabsaturatedFrom

    60at,watersubcooled3,State

    /3.3069le,vapor tabdsuperheateFrom

    2

    22

    3

    3

    2

    =

    +=+

    ==

    =

    =

    &

    &&

    18.Refrigerant, R-134a at 1 MPa and 80 oC is to be cooled to 1 MPA and 30 oC in acondenser by air. The air enters at 100 kPa and 27 oC with a volume flow rate of 1.5

    m3/s and leaves at 95 kPa and 60

    oC. Determine the mass flow rate of the refrigerant.

    Solution

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    91

    kJ/kgTCh

    kgkJCThh

    MPaTCT

    CTMPaP

    kgkJh

    CTMPa,P

    P

    o

    f

    sat

    o

    o

    sat

    o

    5.301300005.1

    air,ofgasidealfor3,State

    side,Air

    /49.9130at

    liquidsubcooledis2,state,1at30

    39.39,1at,tablesaturatedfrom2,ateSt

    /2.313

    801at,levapor tabdsuperheatefrom1,State

    ,side134a-R

    33

    22

    2

    2

    1

    11

    ===

    ===

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    Problems

    1- Consider two identical rooms, one with a refrigerator in it and the other without one.

    If all the doors and windows are closed, will the room that contains the refrigerator

    be cooler or warmer than the other room? Why?

    2- A fixed quantity of fluid is cooled and simultaneously compressed. If the heat

    rejected is 50 kJ and the work done in compression is 34 kJ, determine the change in

    internal energy.

    3- A mass of 20 kg of air in a frictionless piston-cylinder device is heated from 27 to 80

    C by passing current through a resistance heater inside the cylinder. The pressure

    inside the cylinder is held constant at 400 kPa during the process, and a heat loss of

    30 kJ occurs. Determine the electric energy supplied in kWh.

    4- A piston-cylinder device contains 1.2 kg of N2 initially at 100 kPa and 27 C. The

    Nitrogen is now compressed slowly in a polytropic process during which PV1.3

    = C

    until the volume is reduced by one-half. Determine the work done and the heat

    transfer for this process.

    5- 1 kg of air can be expanded between two states as it does 20 kJ of work and receives

    16 kJ of heat. A second kind of expansion can be found between the same initial and

    final states which require a heat input of only 9 kJ. What is the change of internal

    energy in the first expansion and what is the work done by the air in the second

    expansion?

    6- The steam radiator for a heating system has a volume of 20 L and is filled withsuperheated vapor at 300 kPa and 250 C. At this moment both inlet and exit valves

    to the radiator are closed. Determine the amount of heat that will be transferred to the

    room when the steam pressure drops to 100 kPa. Also, show the process on a P-v

    diagram with respect to saturation line.

    7- A well-insulated rigid tank initially contains 8 kg of a saturated liquid-vapor mixture

    of water at 100 kPa. Initially, three-quarters of the mass in the liquid phase. An

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    93

    electric resistor placed in the tank is connected to a source of 220 V and a current of

    4 A flows through the resistor when the switch is turned on. Determine how long it

    will take to vaporized all the liquid in the tank. Also, show the process on a t-v

    diagram with respect to saturation lines.

    8- A piston-cylinder device initially contains 0.5 m3of saturated water vapor at 200 kPa.

    At this state, the piston is resting on a set of stops, and the mass of the piston is such

    that a pressure of 300 kPa is required to move it. Heat is now slowly transferred to

    the steam until the volume doubles. Show the process on a P-v diagram with respect

    to saturation lines and determine (a) the final temperature, (b) the work done during

    this process, and the total heat transfer.

    9- A system receives 180 kJ by heat transfer at constant volume. Next it rejects 200 kJ

    by heat transfer as it receives 50 kJ of work at constant pressure.

    a- If an adiabatic process can be found which will restore it to the initial state, how

    much work transfer is done during the process.

    b-Take the internal energy in the initial state as zero find the corresponding

    internal energy at the other two states.

    10- 1 kg of a certain fluid is contained in a cylinder at an initial pressure of 20 bar. The

    fluid expands according to the law PV2= constant until the volume is doubled. The

    fluid is then cooled at constant pressure until the piston regains its original position;

    heat is added at constant volume until the pressure rises to the original value of 20

    bar. Calculate the network done, for an initial volume of 0.05 m3.

    11- In the turbine of a gas turbine unit the gases flow through the turbine is 17 kg/s and

    the power developed by the turbine is 14 MW. The enthalpies of the gases at inlet

    and outlet are 1200 kJ/kg and 360 kJ/kg respectively, and the velocities of the gases

    at inlet and outlet are 60 m/s and 150 m/s, respectively. Calculate the rate of heat

    transfer.

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    12- Steam flows steadily through an adiabatic turbine. The inlet conditions of the steam

    are 10 MPa, 450 C, and 80 m/s, and the exit conditions are 10 kPa, 90 percent

    quality, and 50 m/s. The mass flow rate of the steam is 12 kg/s. Determine (a) the

    change in kinetic energy, (b) the power output, and (c) the turbine inlet area.

    13- Air enters the compressor of a gas-turbine plant at ambient conditions of 100 kPa

    and 27 C with a low velocity and exit at 1 MPa and 350 C with a velocity of 80

    m/s. The compressor is cooled at a rate of 1200 kJ/min, and the power input to the

    compressor is 250 kW. Determine the mass flow rate of the air through the

    compressor.

    14- Steam at 5 MPa and 500 C enters a nozzle steadily with a velocity of 80 m/s, and it

    leaves at 2 MPa and 400 C. The inlet area of the nozzle is 50 cm2, and heat is

    being lost at a rate of 90 kJ/s. Determine (a) the mass flow rate of the steam, (b) the

    exit velocity of the steam, and the exit area of the nozzle.

    15- Air at 80 kPa and 127 C enters an adiabatic diffuser steadily at a rate of 6000 kg/h

    and leaves at 100 kPa. The velocity of the air stream is decreased from 230 to 30

    m/s as it passes through the diffuser. Find

    a- The exit temperature of the air and

    b- The exit area of the diffuser.