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Chapter #5 Nomenclature

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Page 1: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Chapter #5Nomenclature

Page 2: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Binary means two different elements

Ionic means metal and nonmetal

Step 1First give the name of the metal, followed by thenonmetal name using the “ide” suffix.

Step 2 If the metal is to the right of group IIA, then aRoman numeral is used after the metal to todescribe the charge of the metal. Except Ag,Zn,and Al

Examples

NaCl Al2O3

FeCl2 FeCl3

NOMENCLATUREI. Binary Ionic compounds

Page 3: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Binary means two different elements

Ionic means metal and nonmetal

Step 1First give the name of the metal, followed by thenonmetal name using the “ide” suffix.

Step 2 If the metal is to the right of group IIA, then aRoman numeral is used after the metal to todescribe the charge of the metal. Except Ag,Zn,and Al

Examples

NaCl Sodium chloride Al2O3

FeCl2 FeCl3

NOMENCLATUREI. Binary Ionic compounds

Page 4: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Binary means two different elements

Ionic means metal and nonmetal

Step 1First give the name of the metal, followed by thenonmetal name using the “ide” suffix.

Step 2 If the metal is to the right of group IIA, then aRoman numeral is used after the metal to todescribe the charge of the metal. Except Ag,Zn,and Al

Examples

NaCl Sodium chloride Al2O3 Aluminum oxide

FeCl2 FeCl3

NOMENCLATUREI. Binary Ionic compounds

Page 5: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Binary means two different elements

Ionic means metal and nonmetal

Step 1First give the name of the metal, followed by thenonmetal name using the “ide” suffix.

Step 2 If the metal is to the right of group IIA, then aRoman numeral is used after the metal to todescribe the charge of the metal. Except Ag,Zn,and Al

Examples

NaCl Sodium chloride Al2O3 Aluminum oxide

FeCl2 Iron(II) chloride FeCl3

NOMENCLATUREI. Binary Ionic compounds

Page 6: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Binary means two different elements

Ionic means metal and nonmetal

Step 1First give the name of the metal, followed by thenonmetal name using the “ide” suffix.

Step 2 If the metal is to the right of group IIA, then aRoman numeral is used after the metal to todescribe the charge of the metal. Except Ag,Zn,and Al

Examples

NaCl Sodium chloride Al2O3 Aluminum oxide

FeCl2 Iron(II) chloride FeCl3 iron(III) chloride

NOMENCLATUREI. Binary Ionic compounds

Page 7: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

II. Nonbinary Ionic compoundsNonbinary means more than two different elements

Step 1

First give the name of the metal, followed by the memorized polyatomic ion name.

Step 2

If the metal is to the right of group IIA, then aRoman numeral is used after the metal to describe the charge of the metal. Except Ag, Zn, and Al.

Examples

NaOH Fe(NO3)3

FeSO4Zn(C2H3O2)2

Page 8: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Formula Name Formula Name

NH4+ Ammonium O2

2- Peroxide

C2H3O2- Acetate NO3

- Nitrate

CO32- Carbonate NO2

- Nitrite

HCO31- Hydorgen

carbonateSO4

2- Sulfate

ClO4- Perchlorate SO3

2- Sulfite

ClO3- Chlorate PO4

3- Phosphate

ClO2- Chlorite PO3

3- Phosphite

ClO- Hypochlorite CrO42- Chromate

CN- Cyanide Cr2O72- Dichromate

OH- Hydroxide

Memorized Polyatomic Ion List

Page 9: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

II. Nonbinary Ionic compoundsNonbinary means more than two different elements

Step 1

First give the name of the metal, followed by the memorized polyatomic ion name.

Step 2

If the metal is to the right of group IIA, then aRoman numeral is used after the metal to describe the charge of the metal. Except Ag, Zn, and Al.

Examples

NaOH Fe(NO3)3

FeSO4Zn(C2H3O2)2

Sodium hydroxide

CO

Page 10: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

II. Nonbinary Ionic compoundsNonbinary means more than two different elements

Step 1

First give the name of the metal, followed by the memorized polyatomic ion name.

Step 2

If the metal is to the right of group IIA, then aRoman numeral is used after the metal to describe the charge of the metal. Except Ag, Zn, and Al.

Examples

NaOH Fe(NO3)3

Fe(SO4)2Zn(C2H3O2)2

Sodium hydroxide

Iron(III) nitrate

Page 11: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

II. Nonbinary Ionic compoundsNonbinary means more than two different elements

Step 1

First give the name of the metal, followed by the memorized polyatomic ion name.

Step 2

If the metal is to the right of group IIA, then aRoman numeral is used after the metal to describe the charge of the metal. Except Ag, Zn, and Al.

Examples

NaOH Fe(NO3)3

Fe(SO4)2Zn(C2H3O2)2

Sodium hydroxide

Iron(III) nitrate

Iron(II) sulfate

Page 12: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

II. Nonbinary Ionic compoundsNonbinary means more than two different elements

Step 1

First give the name of the metal, followed by the memorized polyatomic ion name.

Step 2

If the metal is to the right of group IIA, then aRoman numeral is used after the metal to describe the charge of the metal. Except Ag, Zn, and Al.

Examples

NaOH Fe(NO3)3

Fe(SO4)2Zn(C2H3O2)2

Sodium hydroxide

Iron(III) nitrate

Iron(II) sulfate Zinc acetate

Page 13: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

III. Binary molecular Compounds

Step 1First give the name of the first nonmetal,followed by the nonmetal name using the “ide”

suffix.Step 2

Give each nonmetal a Latin prefix describing the number of atoms present in the compound.

ExamplesCO CO2

P2O5 CCl4

Molecular means nonmetals

Page 14: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

You will need to learn the Greek numerical prefixes (Table 4.6):

Number Prefix

1 Mono-*

2 Di-

3 Tri-

4 Tetra-

5 Penta-

6 Hexa-

7 Hepta-

8 Octa-

9 Nona-

10 Deca-

*Note 1 Compound names never start with mono

Note 2 When adding a prefix two vowls cannot next to each other

Page 15: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

III. Binary Molecular Compounds

Step 1First give the name of the first nonmetal,followed by the nonmetal name using the “ide”

suffix.Step 2

Give each nonmetal a Latin prefix describing the number of atoms present in the compound.

ExamplesCO Carbon monoxide CO2

P2O5 CCl4

Molecular means nonmetals

Page 16: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

III. Binary Molecular Compounds

Step 1First give the name of the first nonmetal,followed by the nonmetal name using the “ide”

suffix.Step 2

Give each nonmetal a Latin prefix describing the number of atoms present in the compound.

ExamplesCO Carbon monoxide CO2 Carbon dioxide

P2O5 CCl4

Molecular means nonmetals

Page 17: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

III. Binary Molecular Compounds

Step 1First give the name of the first nonmetal,followed by the nonmetal name using the “ide”

suffix.Step 2

Give each nonmetal a Latin prefix describing the number of atoms present in the compound.

ExamplesCO Carbon monoxide CO2 Carbon dioxide

P2O5 CCl4

Molecular means nonmetals

Page 18: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

II. Binary Ionic molecular

Step 1First give the name of the first nonmetal,followed by the nonmetal name using the “ide”

suffix.Step 2

Give each nonmetal a Latin prefix describing the number of atoms present in the compound.

ExamplesCO Carbon monoxide CO2 Carbon dioxide

P2O5 Diphosphorus Pentoxide

CCl4

Molecular means combination of nonmetals

Page 19: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

II. Binary Ionic molecular

Step 1First give the name of the first nonmetal,followed by the nonmetal name using the “ide”

suffix.Step 2

Give each nonmetal a Latin prefix describing the number of atoms present in the compound.

ExamplesCO Carbon monoxide CO2 Carbon dioxide

P2O5 Diphosphorus Pentoxide

CCl4 Carbon tetrachloride

Molecular means combination of nonmetals

Page 20: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

III. Nonbinary Molecular Compounds

Step 1

Write down the memorized polyatomic ions present in the compound.

Step 2

Look to see if any monatomic ions are present. If so, then cations use the normal name. If it is an anion, then its name comes last with the “ide” suffix.

Examples

NH4Cl

NH4OH

Note: Do not use Latin prefixes

Page 21: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

III. Nonbinary Molecular Compounds

Step 1

Write down the memorized polyatomic ions present in the compound.

Step 2

Look to see if any monatomic ions are present. If so, then cations use the normal name. If it is an anion, then its name comes last with the “ide” suffix.

Examples

NH4Cl

NH4OH

Note: Do not use Latin prefixes

Ammonium chloride

Page 22: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

III. Nonbinary Molecular Compounds

Step 1

Write down the memorized polyatomic ions present in the compound.

Step 2

Look to see if any monatomic ions are present. If so, then cations use the normal name. If it is an anion, then its name comes last with the “ide” suffix.

Examples

NH4Cl

NH4OH

Note: Do not use Latin prefixes

Ammonium chloride

Ammonium hydroxide

Page 23: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Compounds that Start with HydrogenCase 1

Case 2

Case 3

Case 4

If the anion ends in “ide” and it is aqueous, then use the prefix hydro and suffix “ic acid”

If the anion ends in “ate” then drop it and add the suffix “ic acid”

If the anion ends in “ite” then drop it and add the suffix “ous acid”

If the anion ends in” ide” and is a gas, or liquid, then leave the name and do not use Latin prefiex

Page 24: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Compounds that Start with Hydrogen

Examples

HCl (aq)

HNO3

HNO2

H2O (l)

HCl (g)

Page 25: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Compounds that Start with Hydrogen

Examples

HCl (aq)

HNO3

HNO2

H2O (l)

HCl (g)

chloride

Page 26: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Compounds that Start with Hydrogen

Examples

HCl (aq)

HNO3

HNO2

H2O (l)

HCl (g)

chloride chloric acid

Page 27: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Compounds that Start with Hydrogen

Examples

HCl (aq)

HNO3

HNO2

H2O (l)

HCl (g)

chloride chloric acid hydrochloric acid

Page 28: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Compounds that Start with Hydrogen

Examples

HCl (aq)

HNO3

HNO2

H2O (l)

HCl (g)

chloride chloric acid hydrochloric acid

nitrate

Page 29: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Compounds that Start with Hydrogen

Examples

HCl (aq)

HNO3

HNO2

H2O (l)

HCl (g)

chloride chloric acid hydrochloric acid

nitrate nitric acid

Page 30: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Compounds that Start with Hydrogen

Examples

HCl (aq)

HNO3

HNO2

H2O (l)

HCl (g)

chloride chloric acid hydrochloric acid

nitrate nitric acid

nitrite

Page 31: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Compounds that Start with Hydrogen

Examples

HCl (aq)

HNO3

HNO2

H2O (l)

HCl (g)

chloride chloric acid hydrochloric acid

nitrate nitric acid

nitrite nitrous acid

Page 32: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Compounds that Start with Hydrogen

Examples

HCl (aq)

HNO3

HNO2

H2O (l)

HCl (g)

chloride chloric acid hydrochloric acid

nitrate nitric acid

nitrite nitrous acid

oxide

Page 33: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Compounds that Start with Hydrogen

Examples

HCl (aq)

HNO3

HNO2

H2O (l)

HCl (g)

chloride chloric acid hydrochloric acid

nitrate nitric acid

nitrite nitrous acid

oxide hydrogen oxide

Page 34: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Compounds that Start with Hydrogen

Examples

HCl (aq)

HNO3

HNO2

H2O (l)

HCl (g)

chloride chloric acid hydrochloric acid

nitrate nitric acid

nitrite nitrous acid

oxide hydrogen oxide

chloride

Page 35: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

Compounds that Start with Hydrogen

Examples

HCl (aq)

HNO3

HNO2

H2O (l)

HCl (g)

chloride chloric acid hydrochloric acid

nitrate nitric acid

nitrite nitrous acid

oxide hydrogen oxide

chloride hydrogenchloride

Page 36: Chapter #5 Nomenclature. Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal

The End