chapter 5 - review equations of state (chapter 4, briefly...
TRANSCRIPT
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Lecture 41
Chapter 5p- Review Equations of State (chapter 4, briefly)- Thermodynamic Web (or network for transformations)
Departure Functions- Departure Functions
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Maxwell Relations + Other Useful Ones2
PT
sh
vs sP
vT
5.16PP
p TsT
ThC
5.30
Ps sv
PT
5.17vv
v TsT
TuC
5.28
vT TP
vs
5.18PT
vv
1 5.26
vT
vs
5.19
P
Pv
1 5.27
PT TP
TPv
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Uses for Maxwell Relations3
PC dvTPdT
TCds
v
v
dvPTPTdTCdu
vv
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Example
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Other Relations6
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Other Relations7
vPvP T
PTvTCC
Real gas/fluid
RCC vP Ideal gas
KinTwithETDTCTBTAR
CP 322
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Departure Functions8
For convenience. Also called “Residual Functions”: ..GIPTPT
depPT hhh ,,, PTPTPT
depPT
gasidealPP
gasidealTT
depPT hhhhhh 12 PTPPTTPT 22212111 ,,12
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Departure Function Calculations9
A) Z Data or Equation of State
PdP
TZT
TRh
P
Pdep
0
eqn 6.46, p209, 7th ed. Smith, VanNess, Abbott
P0
0231 32223 BBABZBBAZBZ
Peng-Robinson EOS – S. Sandler, “Chemical & Engineering Thermodynamics”, 3rd ed., Wiley (1999)
BZBZ
b
adTdaT
ZRThdep
2121ln
221 BZb 2122
Lee-Kesler EOS can be used to calculate Z, as before.,
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Departure Function Calculations10
B) Generalized compressibility results:
1
Pr,
0
Pr,
depTr
depTr
dep
TRh
TRh
TRh
(0) and (1) from:-Tables orCharts ccc TRTRTR -Charts
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Departure Function Calculations11
C) Generalized Charts:
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Departure Function Calculations12
C) Generalized Charts: ---use caution
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Departure Function Calculations13
D) Data:
D) Data:
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Joule-Thomson Expansion14
Throttle gas through a porous plug or valve.
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Joule-Thomson Expansion15
T
hJT P
T
llP
JTZRT
vTvT
P
realP
realP
JT TPCC
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Joule-Thomson Expansion16
Data from Perry’s Chemical Engineers Handbook
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Joule-Thomson Applications17
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Problem Solving Exercise19
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Example
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21
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Example
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Example
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Example
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Departure Function Calculations25
D) Data:
D) Data: