characterisation of porous solids iv - gbv
TRANSCRIPT
Characterisation of Porous Solids IV
Edited by
B. McEnaney, T. J. Mays University ofBath, UK
J. Rouquerol CTM du CNRS, Marseille, France
F. Rodriguez-Reinoso University ofAlicante, Spain
K.S.W. Sing Universities of Bristol and Exeter, UK
K.K. Unger Johannes Gutenberg University, Mainz, Germany
sjS?*- THE ROYAL g g ? SOCIETY OF •Z& ,CHEMISTRY
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Contents
The Kelvin equation and adsorption hysteresis 1 AJ Brown, CGV Burgess, DH Everett, S Nuttall
Micropore size distribution in carbon molecular sieves by immersion calorimetry 9
JC Gonzales, A Sepülvada-Escribano, M Molina-Sabio, F Rodriguez-Reinoso
Magic angle spinning NMR studies of adsorption onto activated carbons 17 RK Harris, TV Thompson, J Shaw, PR Norman
Analysisof HRADS adsorption 25 E Maglara, R Kaminsky, WC Conner
Neutron scattering investigations of adsorption in porous solids 33 JDF Ramsay, E Hoinkis
A pore width sensitive ordered structure of water molecules in a 41 carbon micropore
T Iijama, K Nishikawa, T Otowa, T Suzuki, K Kaneko
Computer Simulation study of Sorption in cylindrical pores with varying 49 pore wall heterogeneity
WA Steele, MJ Bojan
Transport diffusion of adsorbates in micropores: Simulation in model Systems 57 D Nicholson, RW Adams, RF Cracknell, GK Papadopoulos
Simulation studies of pore blocking phenomena in model porous networks 65 MW Maddox, N Quirke, KE Gubbins
Characterisation of microporous carbons by using molecular Simulation to 73 analyse the adsorption of molecules of different sizes
MV Löpez-Ramön, J Jagiello, TJ Bandosz, NA Seaton
Ordered mesoporous MCM-41 adsorbents: novel routes in synthesis, product 81 characterisation and specification
M Grün, KK Unger, A Matsumoto, K Tsutsumi
Characterisation of zirconia-based ordered mesoporous materials 90 U Ciesla, KK Unger, F Schüth
Physisorption ofgases by MCM-41 98 PJ Branton, PG Hall, KSW Sing
viii Characterisation of Porous Solids IV
Characterisation of porosity during thermal decomposition of nickel hydroxide 103
MML Ribeiro-Carrott, PJM Carrott, AJEG Candeias
A thermodynamic investigation of physisorbed phases within the model 111 mesoporous material: MCM-41
PL Llewellyn, C Sauerland, C Martin, Y Grillet, J-P Coulomb, F Rouquerol, J Rouquerol
Helium adsorption on mesoporous solids at 4.2K - density of adsorbed 118 helium in porous Systems
N Setoyama, S Inoue, Y Hanzawa, PJ Branton, K Kaneko, RW Pekala, MS Dresselhaus, KSW Sing
Estimating the dimensions of ultramicropores using molecular probes 125 B McEnaney, TJ Mays, YF Yin, XS Chen, F Rodriguez-Reinoso
Off-lattice reconstructed biphasic media using Gaussian random fields: 133 evaluation for different disordered porous solids
P Levitz, V Pasquier, I Cousin
Micropore size distributions from experimental isotherm data and 141 grand canonical Monte Carlo simulations
S Samios, AK Stubos, NK Kanellopoulos, R Cracknell, G Papadopoulos, D Nicholson
Measuring and modelling the pore-level properties of meso- and 149 macro-porous media - an overview
GP Matthews
Pore formation in carbons derived from phenol resin and their gas adsorption 156
M Inagaki, M Sunahara
Characterisation of porous solids: adsorption potential distribution and its 163 thermodynamic implications
M Jaroniec, M Kruk, J Choma
Within the hysteresis: insight into the bi-modal pore size distribution of 171 close-packed spheres
H Giesche
Properties of nanoengineered two-dimensional silica-based porous networks 180 PA Sermon, MSW Vong, D Grosso
The presence of "shadowed" macropores in the porous network of an 189 activated alumina
MS Goldstein, JD Carruthers
Characterisation ofPorous Solids IV ix
Nuclear magnetic relaxation study of water adsorbed in mesoporous 196 activated carbons
SV Mikhalovsky, VA Trikhleb, VV Strashko
Analysis of the topological and geometrical characteristics of the pore space 204 of permeable solids using serial tomography, mercury porosimetry and theoretical Simulation
CD Tsakiroglu, AC Payatakes
Morphology of biphasic random media: chord distributions and two-point 213 correlation functions
P Levitz
Interparticle capillary condensation and the pore size distribution of several 221 adsorbents
WD Machin, RJ Murdey
Dual site bond modeis in the presence of correlations 229 A Adrover, M Giona
Determination of the micropore size in carbons by means of experimental 237 and calculated isotherm derivatives
F Ehrburger-Dolle, MT Gonzalez, M Molina-Sabio, F Rodriguez-Reinoso
Study of activated physical adsorption by ESR method 245 VV Strelko
Synthesis and characterisation of a zeolite A with detergent characteristics 253 MJ Perez Zurita, M Matjushi, G Gianetto, C Urbina, L Garcia, C Boliver, C Scott, P Bosch, VH Lara
Gravimetrie and Volumetrie measurements of helium adsorption equilibria 261 on different porous solids
R Staudt, S Bohn, F Dreisbach, JU Keller
Multiscaling texture characterisation of freeze-dried resorcinol-formaldehyde 267 aerogels
B Mathieu, S Blacher, F Brouers, JP Pirard, B Diez, R Sobry, G Van den Bosshe
Comparison oft-plots for carbons, silicas and aluminas v 275 DR Millburn, BH Davis
Fractal analysis of aerogels and carbon blacks using nitrogen adsorption 283 data: comparative study of two methods
B Sahouli, S Blacher, F Brouers
X Characterisation ofPorous Solids IV
Certification of reference materials for pore analysis by the gas adsorption 291 method
B Röhl-Kuhn, K Meyer, P Klobs, K-F Krebs, Th Fritz
Adsorption and displacement of formic acid and acetic acid on microporOus 299 phenolic resin carbons
WH Lawnik, O Dietsche, A Fritz, GH Findenegg, SR Tennison
Characterisation ofsulphated oxides oftitanium: infra-red, adsorption 306 and related studies
CA Philip, SA Selim, N Yacoub, J Ragai
Analysis of pore properties from low pressure hysteresis in nitrogen 314 adsorption isotherms
RR Mather
Adsorption characterisation of H-ZSM-5 319 L Abrams
Surface functional groups and texture characterisation of catalytic supports 327 based on activated carbon
G de la Puente, A Centeno, A Gil, P Grange, B Delmon
Modelling stratified porous media 335 TJ Mathews, GP Matthews
Modelling of pore level properties 343 CJ Ridgway, GP Matthews
Sorptive properties ofcloverite 351 W Schmidt, F Schüth
Comparison of the translational mobility D„ of hydrogen, methane and 359 neo-pentane molecules sorbed on AlP04-5
C Martin, JP Coulomb, Y Grillet, R Kahn
Characterisation of the solid texture of porous particles by application of 366 a non-catalytic gas-solid reaction in a thermobalance
G Aichinger, G Staudinger
Retention mechanisms of phenol on activated carbon in a cement 374 environment studied by high resolution argon adsorption and controlled transformation rate hermal analysis
LJ Michot, F Didier, F Vülieras, JM Cases, Y Grillet, A Bouchelaghem
A model of mercury intrusion in an elliptical or rectangular parallel crack 382 and its influence on porosity histograms of granite
P Couchot, C Dubois, E Boeglin, A Chambaudet
Characterisation ofPorous Solids IV xi
Characterisation of Single pores and porous solids 390 Z Sobotka
Polymerie materials with a novel type of porosity 398 MP Tsyurupa, AS Shabaeva, LA Pavlova, TA Mrachkovskaya, VA Davankov
Processing of microporous/mesoporous sub-micron size silica spheres 406 by means of a template-supported synthesis
Ch Kaiser, G Büchel, S Lüdtke, I Lauer, KK Unger
Observation of interface curvature of capillary Condensed phase in 413 slit-shaped nanopore with a new MD Simulation method
M Miyahara, T Yoshioka, M Okazaki
Textural adsorption characterisation aecording to the two-fold description 421 of porous media
V Mayagoitia, F Rojas, I Kornhauser, J Salmones
Determination of the surface areas and pore sizes of organic matter in soils 429 MC Mittelmeijer-Hazeleger, H de Jonge, A Bliek
Pore strueture and phenol adsorption characteristics of carbonaeeous 437 adsorbents prepared from coal rejeet
F Haghseresht, GQ Lu, HY Zhu, J Keller
Characterisation of silica obtained from the dissolution of olivine: a nitrogen 445 physisorption and thermoporometric study
DJ Lieftink, P van Os, BG Dekker, H Talsina, JW Geus
Characterisation of the porosity of M41S Silicate by adsorption and Xe NMR 452 MA Springuel-Huet, J Fraissard, R Schmidt, M Stöcker, WC Conner
Mercury porosimetry applied to low density xerogels 460 R Pirard, B Heinrichs, JP Pirard
Study of Kelex 100 (metallic ion extraetant) impregnated in porous 467 organic polymers using nitrogen adsorption at 77 K, water adsorption and 129-Xe NMR spectroscopy
S Esteban, JL Bonnardet, G Cote
An anomalous adsorption of ZSM-5 zeolites 475 ME Eleftheriou, CR Theocharis
Effect of thermal treatment on the porosity of silica gels: studies by 481 thermal desorption of liquids
J Goworek, W Stefaniak, T Goworek
xii Characterisation ofPorous Solids IV
Generation of radially non-uniform porous particles - the influence of 489 non-uniformity and of correlation properties on fiuid-solid non-catalytic reactions
A Adrover, M Giona
Effects of carbon surface chemistry on adsorption of polar molecules 497 RH Bradley, A Cuesta
Effect of assumed pore shape and interaction parameters on obtaining pore 504 size distributions from adsorption measurements
KL Boulton, MV Löpez-Ramön, GM Davies, NA Seaton
Adsorbent applications for mesoporous Silicate 512 A Yasutake, N Tomonaga, J Izumi, UM Setogushi, M Iwamoto
Characterisation by thermoporometry of the influence of additives on the 519 porous structure of gels derived from tetraethoxysilane
A Julbe, JF Quinson, A El Mansouri, C Guizard
Reduction of octahedral Fe(III) in saponite: influence in the pillaring ability 527 oftheclay
MA Vincente, MA Baüares-Munoz, M Suarez, JMM Pozas, RM Martin, MLRojas
Texture of impregnated active carbon: effect of burn-off 535 B Buczek, A Swiatkowski, S Zietek
Pore volume and apparent density of fine porous particles 543 B Buczek, E Vogt, W Stefaniak
A Simulation study of nitrogen adsorption in magnesium oxide pores 549 D Nicholson, NA Freeman, MA Day
Adsorption and thermogravimetric characterisation of selected M41S 557 samples
A Sayari, C Danumah, P Liu, M Jaroniec
Analysis of pore structure of isotropic graphite using image processing 565 K Oshida, T Nakazawa, N Ekinaga, M Endo, M Inagaki
Adsorption studies of carbon dioxide on KF1500, X2MH6/8 and PX21 573 by means of a high-pressure Volumetrie device
A Guillot, S Follin, L Poujardieu
Comparison between different techniques to determine the porosity of 581 aerogels
JF Quinson, B Chevalier, E Elaloui, R Begag
Characterisation ofPorous Solids TV xui
Multistep porosity development in clinochlore upon heating 588 F Vülieras, J Yvon, M Francois, G Gerard, JM Cases
Cohesive and swelling behaviour of charged interfaces: a (NVT) 596 Monte-Carlo study
R J-M Pellenq, A Delville, H van Damme
Caku lation of adsorption isotherms and thermodynamic quantities for 604 argon adsorbed in carbon slit-like micropores with different pore widths using the density functional theory
N Neugebauer, M v Szombathely, P Bräuer
Characterisation of heterogeneous adsorbents using data from isotherms 612 at two different temperatures
K Koch, M v Szombathely, N Neugebauer
Organised and confined fluids in a micropore 620 K Murata, K Kaneko
Surface characteristics and pore structure of activated char prepared from 625 a mixture of coal tar pitch and a graphite-FeCl3 intercalation Compound
A Albiniak, E Broniek, J Kaczmarczyk, A Jankowska, T Simieniewska, B McEnaney, XS Chen, G Furdin, D Begin
Modelling of gas sorption processes in shallow, fixed bed adsorbers 633 EPJ Mallens, MPM Cnoops, JJGM van Bokhoven
Changes of surface area and porosity of carbon fibres during their activation 641 SF Grebennikov, AV Koulitchenko, JT Williams
Mesoporous silicas from mixed templates 648 S Ozeki, M Yamamoto, K Nobuhara
Boron distribution in MFI-type zeolites: interest of adsorption 656 microcalorimetry at 77K
C Sauerl, PL LLewellyn, Y Grillet, J Rouquerol
A simple accelerated procedure for carbon tetrachloride activity and 663 retentivity in active carbon
AM Zakareya,
Synthesis and mechanism of swollen MCM-41 668 PJ Branton, J Dougherty G Lockhart, JW White
The preparation and analysis of microporous silica mcmbranes for 675 gas Separation
RM de Vos, A Nijmeijer, K Keizer, H Verweij
XIV Characterisation ofPorous Solids IV
Standardisation of surface geometry characterisation 681 E Robens, K-F Krebs, K Meyer
Characterisation of the porosity of 18"' Century Portuguese decorative tiles 689 MML Ribeiro-Carrott, JL Farinha-Atunes, PJM Carrott
Author Index 696
Subject Index 700